Sample records for gas processing facilities

  1. Sales and Use Tax Exemption for Gas Processing Facilities

    Broader source: Energy.gov [DOE]

    In North Dakota, materials purchased for building or expending gas processing facilities are exempt from sales and use taxes. Building materials, equipment, and other tangible property are eligible...

  2. RESEARCH AND DEVELOPMENT OF AN INTEGRAL SEPARATOR FOR A CENTRIFUGAL GAS PROCESSING FACILITY

    SciTech Connect (OSTI)

    LANCE HAYS

    2007-02-27T23:59:59.000Z

    A COMPACT GAS PROCESSING DEVICE WAS INVESTIGATED TO INCREASE GAS PRODUCTION FROM REMOTE, PREVIOUSLY UN-ECONOMIC RESOURCES. THE UNIT WAS TESTED ON AIR AND WATER AND WITH NATURAL GAS AND LIQUID. RESULTS ARE REPORTED WITH RECOMMENDATIONS FOR FUTURE WORK.

  3. Stochastic Programming Approaches for the Placement of Gas Detectors in Process Facilities

    E-Print Network [OSTI]

    Legg, Sean W

    2013-05-21T23:59:59.000Z

    of these detectors is required in order to have a well-functioning gas detection system. However, the uncertainty in leak locations, gas composition, process and weather conditions, and process geometries must all be considered when attempting to determine...

  4. Studsvik Processing Facility Update

    SciTech Connect (OSTI)

    Mason, J. B.; Oliver, T. W.; Hill, G. M.; Davin, P. F.; Ping, M. R.

    2003-02-25T23:59:59.000Z

    Studsvik has completed over four years of operation at its Erwin, TN facility. During this time period Studsvik processed over 3.3 million pounds (1.5 million kgs) of radioactive ion exchange bead resin, powdered filter media, and activated carbon, which comprised a cumulative total activity of 18,852.5 Ci (6.98E+08 MBq). To date, the highest radiation level for an incoming resin container has been 395 R/hr (3.95 Sv/h). The Studsvik Processing Facility (SPF) has the capability to safely and efficiently receive and process a wide variety of solid and liquid Low Level Radioactive Waste (LLRW) streams including: Ion Exchange Resins (IER), activated carbon (charcoal), graphite, oils, solvents, and cleaning solutions with contact radiation levels of up to 400 R/hr (4.0 Sv/h). The licensed and heavily shielded SPF can receive and process liquid and solid LLRWs with high water and/or organic content. This paper provides an overview of the last four years of commercial operations processing radioactive LLRW from commercial nuclear power plants. Process improvements and lessons learned will be discussed.

  5. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  6. Advanced Polymer Processing Facility

    SciTech Connect (OSTI)

    Muenchausen, Ross E. [Los Alamos National Laboratory

    2012-07-25T23:59:59.000Z

    Some conclusions of this presentation are: (1) Radiation-assisted nanotechnology applications will continue to grow; (2) The APPF will provide a unique focus for radiolytic processing of nanomaterials in support of DOE-DP, other DOE and advanced manufacturing initiatives; (3) {gamma}, X-ray, e-beam and ion beam processing will increasingly be applied for 'green' manufacturing of nanomaterials and nanocomposites; and (4) Biomedical science and engineering may ultimately be the biggest application area for radiation-assisted nanotechnology development.

  7. Independent Oversight Assessment, Salt Waste Processing Facility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department...

  8. U-GAS process

    SciTech Connect (OSTI)

    Schora, F.C.; Patel, J.G.

    1982-01-01T23:59:59.000Z

    The Institute of Gas Technology (IGT) has developed an advanced coal gasification process. The U-GAS process has been extensively tested in a pilot plant to firmly establish process feasibility and provide a large data base for scale-up and design of the first commercial plant. The U-GAS process is considered to be one of the more flexible, efficient, and economical coal gasification technologies developed in the US during the last decade. The U-GAS technology is presently available for licensing from GDC, Inc., a wholly-owned subsidiary of IGT. The U-GAS process accomplishes four important functions in a single-stage, fluidized-bed gasifier: It decakes coal, devolatilizes coal, gasifies coal, and agglomerates and separates ash from char. Simultaneously with coal gasification, the ash is agglomerated into spherical particles and separated from the bed. Part of the fluidizing gas enters the gasifier through a sloping grid. The remaining gas flows upward at a high velocity through the ash agglomerating device and forms a hot zone within the fluidized bed. High-ash-content particles agglomerate under these conditions and grow into larger and heavier particles. Agglomerates grow in size until they can be selectively separated and discharged from the bed into water-filled ash hoppers where they are withdrawn as a slurry. In this manner, the fluidized bed achieves the same low level of carbon losses in the discharge ash generally associated with the ash-slagging type of gasifier. Coal fines elutriated from the fluidized bed are collected in two external cyclones. Fines from the first cyclone are returned to the bed and fines from the second cyclone are returned to the ash agglomerating zone, where they are gasified, and the ash agglomerated with bed ash. The raw product gas is virtually free of tar and oils, thus simplifying ensuing heat recovery and purification steps.

  9. Compressed Gas Safety for Experimental Fusion Facilities

    SciTech Connect (OSTI)

    Cadwallader, L.C. [Idaho National Engineering and Environmental Laboratory (United States)

    2005-05-15T23:59:59.000Z

    Experimental fusion facilities present a variety of hazards to the operators and staff. There are unique or specialized hazards, including magnetic fields, cryogens, radio frequency emissions, and vacuum reservoirs. There are also more general industrial hazards, such as a wide variety of electrical power, pressurized air and cooling water systems in use, there are crane and hoist loads, working at height, and handling compressed gas cylinders. This paper outlines the projectile hazard associated with compressed gas cylinders and methods of treatment to provide for compressed gas safety. This information should be of interest to personnel at both magnetic and inertial fusion experiments.

  10. Compressed Gas Safety for Experimental Fusion Facilities

    SciTech Connect (OSTI)

    Lee C. Cadwallader

    2004-09-01T23:59:59.000Z

    Experimental fusion facilities present a variety of hazards to the operators and staff. There are unique or specialized hazards, including magnetic fields, cryogens, radio frequency emissions, and vacuum reservoirs. There are also more general industrial hazards, such as a wide variety of electrical power, pressurized air, and cooling water systems in use, there are crane and hoist loads, working at height, and handling compressed gas cylinders. This paper outlines the projectile hazard assoicated with compressed gas cylinders and mthods of treatment to provide for compressed gas safety. This information should be of interest to personnel at both magnetic and inertial fusion experiments.

  11. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM - PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J.; Choi, A.

    2009-03-25T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that come in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter off-gas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

  12. MODELING THE IMPACT OF ELEVATED MERCURY IN DEFENSE WASTE PROCESSING FACILITY MELTER FEED ON THE MELTER OFF-GAS SYSTEM-PRELIMINARY REPORT

    SciTech Connect (OSTI)

    Zamecnik, J.; Choi, A.

    2010-08-18T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is currently evaluating an alternative Chemical Process Cell (CPC) flowsheet to increase throughput. It includes removal of the steam-stripping step, which would significantly reduce the CPC processing time and lessen the sampling needs. However, its downside would be to send 100% of the mercury that comes in with the sludge straight to the melter. For example, the new mercury content in the Sludge Batch 5 (SB5) melter feed is projected to be 25 times higher than that in the SB4 with nominal steam stripping of mercury. This task was initiated to study the impact of the worst-case scenario of zero-mercury-removal in the CPC on the DWPF melter offgas system. It is stressed that this study is intended to be scoping in nature, so the results presented in this report are preliminary. In order to study the impact of elevated mercury levels in the feed, it is necessary to be able to predict how mercury would speciate in the melter exhaust under varying melter operating conditions. A homogeneous gas-phase oxidation model of mercury by chloride was developed to do just that. The model contains two critical parameters pertaining to the partitioning of chloride among HCl, Cl, Cl{sub 2}, and chloride salts in the melter vapor space. The values for these parameters were determined at two different melter vapor space temperatures by matching the calculated molar ratio of HgCl (or Hg{sub 2}Cl{sub 2}) to HgCl{sub 2} with those measured during the Experimental-Scale Ceramic Melter (ESCM) tests run at the Pacific Northwest National Laboratory (PNNL). The calibrated model was then applied to the SB5 simulant used in the earlier flowsheet study with an assumed mercury stripping efficiency of zero; the molar ratio of Cl-to-Hg in the resulting melter feed was only 0.4, compared to 12 for the ESCM feeds. The results of the model run at the indicated melter vapor space temperature of 650 C (TI4085D) showed that due to excessive shortage of chloride, only 6% of the mercury fed is expected to get oxidized, mostly as HgCl, while the remaining mercury would exist either as elemental mercury vapor (90%) or HgO (4%). Noting that the measured chloride level in the SB5 qualification sample was an order of magnitude lower than that used in the SB5 simulant, the degree of chloride shortage will be even greater. As a result, the projected level of HgCl in the actual SB5 melter exhaust will be even lower than 6% of the total mercury fed, while that of elemental mercury is likely to be greater than 90%. The homogeneous oxidation of mercury in the off-gas was deemed to be of primary importance based on the postulation that mercury and other volatile salts form submicron sized aerosols upon condensation and thus remain largely in the gas stream downstream of the quencher where they can deposit in the off-gas lines, Steam-Atomized Scrubbers (SAS), and High-Efficiency Mist Eliminator (HEME). Formation of these submicron semi-volatile salts in the condensate liquid is considered to be unlikely, so the liquid phase reactions were considered to be less important. However, subsequent oxidation of mercury in the liquid phase in the off-gas system was examined in a simplified model of the off-gas condensate. It was found that the condensate chemistry was consistent with further oxidation of elemental mercury to Hg{sub 2}Cl{sub 2} and conversion of HgO to chlorides. The results were consistent with the available experimental data. It should also be noted that the model predictions presented in this report do not include any physically entrained solids, which typically account for much of the off-gas carryover on a mass basis. The high elemental mercury vapor content predicted at the DWPF Quencher inlet means that physically entrained solids could provide the necessary surface onto which elemental mercury vapor could condense, thereby coating the solids as well as the internal surfaces of the off-gas system with mercury. Clearly, there are many process benefits to be gained by removing the steam-stripping step from the CPC c

  13. Facility Configuration Study of the High Temperature Gas-Cooled Reactor Component Test Facility

    SciTech Connect (OSTI)

    S. L. Austad; L. E. Guillen; D. S. Ferguson; B. L. Blakely; D. M. Pace; D. Lopez; J. D. Zolynski; B. L. Cowley; V. J. Balls; E.A. Harvego, P.E.; C.W. McKnight, P.E.; R.S. Stewart; B.D. Christensen

    2008-04-01T23:59:59.000Z

    A test facility, referred to as the High Temperature Gas-Cooled Reactor Component Test Facility or CTF, will be sited at Idaho National Laboratory for the purposes of supporting development of high temperature gas thermal-hydraulic technologies (helium, helium-Nitrogen, CO2, etc.) as applied in heat transport and heat transfer applications in High Temperature Gas-Cooled Reactors. Such applications include, but are not limited to: primary coolant; secondary coolant; intermediate, secondary, and tertiary heat transfer; and demonstration of processes requiring high temperatures such as hydrogen production. The facility will initially support completion of the Next Generation Nuclear Plant. It will secondarily be open for use by the full range of suppliers, end-users, facilitators, government laboratories, and others in the domestic and international community supporting the development and application of High Temperature Gas-Cooled Reactor technology. This pre-conceptual facility configuration study, which forms the basis for a cost estimate to support CTF scoping and planning, accomplishes the following objectives: • Identifies pre-conceptual design requirements • Develops test loop equipment schematics and layout • Identifies space allocations for each of the facility functions, as required • Develops a pre-conceptual site layout including transportation, parking and support structures, and railway systems • Identifies pre-conceptual utility and support system needs • Establishes pre-conceptual electrical one-line drawings and schedule for development of power needs.

  14. Springfield Processing Plant (SPP) Facility Information

    SciTech Connect (OSTI)

    Leach, Janice; Torres, Teresa M.

    2012-10-01T23:59:59.000Z

    The Springfield Processing Plant is a hypothetical facility. It has been constructed for use in training workshops. Information is provided about the facility and its surroundings, particularly security-related aspects such as target identification, threat data, entry control, and response force data.

  15. Gas separation process

    SciTech Connect (OSTI)

    Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

    1988-03-22T23:59:59.000Z

    The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

  16. Integrated flue gas processing method

    SciTech Connect (OSTI)

    Bakke, E.; Willett, H.P.

    1982-12-21T23:59:59.000Z

    A system and process for flue gas processing to remove both gaseous contaminants such as sulfur dioxide and particulate matter such as flyash integrates spray scrubbing apparatus and wet electrostatic precipitation apparatus and provides for the advantageous extraction and utilization of heat present in the flue gas which is being processed. The integrated system and process utilizes a spray scrubbing tower into which the flue gas is introduced and into which aqueous alkali slurry is introduced as spray for sulfur dioxide removal therein. The flue gas leaves the tower moisture laden and enters a wet electrostatic precipitator which includes a heat exchanger where flyash and entrained droplets in the flue gas are removed by electrostatic precipitation and heat is removed from the flue gas. The cleaned flue gas exits from the precipitator and discharges into a stack. The heat removed from the flue gas finds use in the system or otherwise in the steam generation plant. The wet electrostatic precipitator of the integrated system and process includes a portion constructed as a cross flow heat exchanger with flue gas saturated with water vapor moving vertically upwards inside tubes arranged in a staggered pattern and ambient air being pulled horizontally across the outside of those tubes to cool the tube walls and thereby remove heat from the flue gas and cause condensation of water vapor on the inside wall surfaces. The condensate washes the electrostatically collected flyash particles down from the inside tube walls. The heat that is extracted from the saturated flue gas in the wet electrostatic precipitator heat exchanger may be utilized in several different ways, including: (1) for flue gas reheat after the wet electrostatic precipitator; (2) for preheating of combustion air to the steam generator boiler; and, (3) for heating of buildings.

  17. Fabrication of Separator Demonstration Facility process vessel

    SciTech Connect (OSTI)

    Oberst, E.F.

    1985-01-15T23:59:59.000Z

    The process vessel system is the central element in the Separator Development Facility (SDF). It houses the two major process components, i.e., the laser-beam folding optics and the separators pods. This major subsystem is the critical-path procurement for the SDF project. Details of the vaious parts of the process vessel are given.

  18. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15T23:59:59.000Z

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  19. Gas purification process

    SciTech Connect (OSTI)

    Randell, D.R.; Phillips, E.

    1981-02-17T23:59:59.000Z

    Ciba-Geigy claims that anthraquinone sulfonamides have equal or better activity than the anthraquinone disulfonic acids used in the removal of hydrogen sulfide as sulfur from gases by such methods as the Stretford process. Examples of the preferred compounds are N,N'-disulfomethylanthraquinone-2,6-disulfonamide and N,N'-dicarboxymethylanthraquinone-2,7-disulfonamide.

  20. Applications for Certificates for Electric, Gas, or Natural Gas Transmission Facilities (Ohio)

    Broader source: Energy.gov [DOE]

    An applicant for a certificate to site a major electric power, gas, or natural gas transmission facility shall provide a project summary and overview of the proposed project. In general, the...

  1. Natural gas dehydration process and apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Ng, Alvin; Mairal, Anurag P.

    2004-09-14T23:59:59.000Z

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  2. Future use of BI-GAS facility. Final report, Part II. [Other possible uses

    SciTech Connect (OSTI)

    Not Available

    1981-09-01T23:59:59.000Z

    The 120 tpd BI-GAS pilot plant, intended to produce SNG at high pressure, was completed in 1976. For the next three and a half years, the operator, Stearns-Roger Inc., was engaged in operating the plant while overcoming a series of mechanical problems that have prevented the plant from running at design capacity and pressure. Since July 1980, these problems have apparently been corrected and considerable progress was made. In late 1979, the Yates Congressional Committee directed DOE to investigate the possibility of establishing an entrained-bed gasifier test facility at the site. In January 1981, the DOE established a study group composed of DOE and UOP/SDC personnel to determine how best to use the BI-GAS facility. The group considered four possibilities: Continue operation of the facility in accordance with the technical program plan developed by DOE and Stearns-Roger; modify the plant into an entrained-bed facility for testing components and processes; mothball the facility, or dismantle the facility. The group took the view that modifying the plant into a test facility would increase substantially the amount of engineering data available to the designers of commercial gasification plants. Since it appears that syngas plants will be of commercial interest sooner than SNG plants will, it was decided that the facility should test syngas production components and processes at high pressure. Consequently, it was recommended that: Operation of the plant be continued, both to collect data and to prove the BI-GAS process, as long as the schedule of the technical program plan is met; Begin at once to prepare a detailed design for modifying the BI-GAS plant to a high-pressure, entrained flow syngas test facility; and Implement the modification plan as soon as the BI-GAS process is proven or it becomes apparent that progress is unsatisfactory.

  3. Hot gas cleanup test facility for gasification and pressurized combustion project. Quarterly report, October--December 1995

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDs) into the structural and process designs. Substantial progress in construction activities was achieved during this quarter.

  4. Potential For Energy, Peak Demand, and Water Savings in California Tomato Processing Facilities

    E-Print Network [OSTI]

    Trueblood, A. J.; Wu, Y. Y.; Ganji, A. R.

    2013-01-01T23:59:59.000Z

    of electrical energy in these plants will be shown. Results from potential electrical efficiency, demand response, and natural gas efficiency measures that have applications in tomato processing facilities will be presented. Additionally, water conservation...

  5. Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-02-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs. Substantial progress in underground construction activities was achieved during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. MWK equipment at the grade level and the first tier are being set in the structure.

  6. Item No. 3 process facilities cost estimates and schedules for facilities capability assurance program nuclear facilities modernization - FY 1989 line item, authorization No. D79

    SciTech Connect (OSTI)

    NONE

    1989-07-01T23:59:59.000Z

    Data is presented concerning cost estimates and schedules for process facilities and nuclear facilities modernization.

  7. Waste minimization at a plutonium processing facility

    SciTech Connect (OSTI)

    Pillay, K.K.S. [Los Alamos National Laboratory, NM (United States)

    1995-12-31T23:59:59.000Z

    As part of Los Alamos National Laboratory`s (LANL) mission to reduce the nuclear danger throughout the world, the plutonium processing facility at LANL maintains expertise and skills in nuclear weapons technologies as well as leadership in all peaceful applications of plutonium technologies, including fuel fabrication for terrestrial and space reactors and heat sources and thermoelectric generators for space missions. Another near-term challenge resulted from two safety assessments performed by the Defense Nuclear Facilities Safety Board and the U.S. Department of Energy during the past two years. These assessments have necessitated the processing and stabilization of plutonium contained in tons of residues so that they can be stored safely for an indefinite period. This report describes waste streams and approaches to waste reduction of plutonium management.

  8. Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly report, April--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-08-01T23:59:59.000Z

    This quarterly technical progress report summarizes the work completed during the first quarter, April 1 through June 30, 1995. The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasificafion and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel continued at a good pace during the quarter.

  9. Management of a complex cavern storage facility for natural gas

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    The Epe cavern storage facility operated by Ruhrgas AG has developed into one of the largest gas cavern storage facilities in the world. Currently, there are 32 caverns and 18 more are planned in the future. Working gas volume will increase from approximately 1.5 {times} 10{sup 9} to 2 {times} 10{sup 9} m{sup 3}. The stratified salt deposit containing the caverns has a surface area of approximately 7 km{sup 2} and is 250 m thick at the edge and 400 m thick in the center. Caverns are leached by a company that uses the recovered brine in the chlorine industry. Cavern dimensions are determined before leaching. The behavior of each cavern, as well as the thermodynamic properties of natural gas must be considered in cavern management. The full-length paper presents the components of a complex management system covering the design, construction, and operation of the Epe gas-storage caverns.

  10. Safeguards Approaches for Black Box Processes or Facilities

    SciTech Connect (OSTI)

    Diaz-Marcano, Helly; Gitau, Ernest TN; Hockert, John; Miller, Erin; Wylie, Joann

    2013-09-25T23:59:59.000Z

    The objective of this study is to determine whether a safeguards approach can be developed for “black box” processes or facilities. These are facilities where a State or operator may limit IAEA access to specific processes or portions of a facility; in other cases, the IAEA may be prohibited access to the entire facility. The determination of whether a black box process or facility is safeguardable is dependent upon the details of the process type, design, and layout; the specific limitations on inspector access; and the restrictions placed upon the design information that can be provided to the IAEA. This analysis identified the necessary conditions for safeguardability of black box processes and facilities.

  11. Natural gas treatment process using PTMSP membrane

    DOE Patents [OSTI]

    Toy, L.G.; Pinnau, I.

    1996-03-26T23:59:59.000Z

    A process is described for separating C{sub 3}+ hydrocarbons, particularly propane and butane, from natural gas. The process uses a poly(trimethylsilylpropyne) membrane. 6 figs.

  12. Natural gas treatment process using PTMSP membrane

    DOE Patents [OSTI]

    Toy, Lora G. (San Francisco, CA); Pinnau, Ingo (Palo Alto, CA)

    1996-01-01T23:59:59.000Z

    A process for separating C.sub.3 + hydrocarbons, particularly propane and butane, from natural gas. The process uses a poly(trimethylsilylpropyne) membrane.

  13. Accident Fault Trees for Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Sarrack, A.G.

    1999-06-22T23:59:59.000Z

    The purpose of this report is to document fault tree analyses which have been completed for the Defense Waste Processing Facility (DWPF) safety analysis. Logic models for equipment failures and human error combinations that could lead to flammable gas explosions in various process tanks, or failure of critical support systems were developed for internal initiating events and for earthquakes. These fault trees provide frequency estimates for support systems failures and accidents that could lead to radioactive and hazardous chemical releases both on-site and off-site. Top event frequency results from these fault trees will be used in further APET analyses to calculate accident risk associated with DWPF facility operations. This report lists and explains important underlying assumptions, provides references for failure data sources, and briefly describes the fault tree method used. Specific commitments from DWPF to provide new procedural/administrative controls or system design changes are listed in the ''Facility Commitments'' section. The purpose of the ''Assumptions'' section is to clarify the basis for fault tree modeling, and is not necessarily a list of items required to be protected by Technical Safety Requirements (TSRs).

  14. Altering Design Decisions to Better Suit Facilities Management Processes

    E-Print Network [OSTI]

    Jawdeh, H. B.; Abudul-Malak, M. A.; Wood, G.

    2010-01-01T23:59:59.000Z

    Research work reported in this paper tackles the communication between processes of both facilities management (FM) and design, showing the effect of such communication on the capability of newly built facilities in supporting organizations...

  15. Avoca, New York Salt Cavern Gas Storage Facility

    SciTech Connect (OSTI)

    Morrill, D.C. [J. Makowski and Associates, Boston, MA (United States)

    1995-09-01T23:59:59.000Z

    The first salt cavern natural gas storage facility in the northeastern United States designed to serve the interstate gas market is being developed by J Makowski Associates and partners at Avoca in Steuben County, New York. Multiple caverns will be leached at a depth of about 3800 ft from an approximately 100 ft interval of salt within the F unit of the Syracuse Formation of the Upper Silurian Salina Group. The facility is designed to provide 5 Bcf of working gas capacity and 500 MMcfd of deliverability within an operating cavern pressure range between 760 psi and 2850 psi. Fresh water for leaching will be obtained from the Cohocton River aquifer at a maximum rate of 3 million gallons per day and produced brine will be injected into deep permeable Cambrian age sandstones and dolostones. Gas storage service is anticipated to commence in the Fall of 1997 with 2 Bcf of working gas capacity and the full 5 Bcf or storage service is scheduled to be available in the Fall of 1999.

  16. Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion Project. Quarterly report, April--June 1996

    SciTech Connect (OSTI)

    NONE

    1996-12-31T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived as streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed Include the integration of the particulate control devices into coal utilization systems, on-line cleaning, techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing, Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: 1 . Carbonizer/Pressurized Circulating, Fluidized Bed Gas Source; 2. Hot Gas Cleanup Units to mate to all gas streams; 3. Combustion Gas Turbine; 4. Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during, this reporting period was continuing, the detailed design of the FW portion of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is complete and the construction of steel for the coal preparation structure is complete.

  17. Gas treating process and composition

    SciTech Connect (OSTI)

    Byers, D.L.

    1989-06-20T23:59:59.000Z

    This patent describes a process for the removal of H/sub 2/S from a sour gaseous stream. The process consists of: (a) contacting the sour gaseous stream in a contacting zone with an aqueous reaction solution, at a temperature not greater than about 160{sup 0}C, the reaction solution comprising an effective amount of vanadium V-containing ions to oxidize H/sub 2/S to elemental sulfur and being substantially free of anthraquinone disulfonate, and producing a sweet gas stream and an aqueous solution having a pH of 8-11 and containing sulfur and vanadium IV-containing ions, the reaction solution further comprising an amount of phosphate ions sufficient to provide a molar ratio of phosphate ions to vanadium IV-containing ions produced in solution of at least 0.1; (b) removing sulfur from the aqueous solution, producing an aqueous solution having reduced sulfur content; (c) regenerating aqueous solution having reduced sulfur content in a regenerating zone and producing regenerated reactant in the solution; and (d) returning regenerated solution from step (c) to the contacting zone for use as aqueous reaction solution therein.

  18. Worldwide refining and gas processing directory

    SciTech Connect (OSTI)

    NONE

    1999-11-01T23:59:59.000Z

    Statistics are presented on the following: US refining; Canada refining; Europe refining; Africa refining; Asia refining; Latin American refining; Middle East refining; catalyst manufacturers; consulting firms; engineering and construction; US gas processing; international gas processing; plant maintenance providers; process control and simulation systems; and trade associations.

  19. Natural Gas Processing Plant- Sulfur (New Mexico)

    Broader source: Energy.gov [DOE]

    This regulation establishes sulfur emission standards for natural gas processing plants. Standards are stated for both existing and new plants. There are also rules for stack height requirements,...

  20. Waste receiving and processing facility module 1 auditable safetyanalysis

    SciTech Connect (OSTI)

    Bottenus, R.J.

    1997-02-01T23:59:59.000Z

    The Waste Receiving and Processing Facility Module 1 Auditable Safety Analysis analyzes postulated accidents and determines controls to prevent the accidents or mitigate the consequences.

  1. Appendix D: Facility Process Data and Appendix E: Equipment Calibratio...

    Broader source: Energy.gov (indexed) [DOE]

    D: Facility Process Data and Appendix E: Equipment Calibration Data Sheets from Final Report: Particulate Emissions Testing, Unit 1, Potomac River Generating Station, Alexandria,...

  2. Pinellas Plant facts. [Products, processes, laboratory facilities

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    This plant was built in 1956 in response to a need for the manufacture of neutron generators, a principal component in nuclear weapons. The neutron generators consist of a miniaturized linear ion accelerator assembled with the pulsed electrical power supplies required for its operation. The ion accelerator, or neutron tube, requires ultra clean, high vacuum technology: hermetic seals between glass, ceramic, glass-ceramic, and metal materials: plus high voltage generation and measurement technology. The existence of these capabilities at the Pinellas Plant has led directly to the assignment of the lightning arrester connector, specialty capacitor, vacuum switch, and crystal resonator. Active and reserve batteries and the radioisotopically-powered thermoelectric generator draw on the materials measurement and controls technologies which are required to ensure neutron generator life. A product development and production capability in alumina ceramics, cermet (electrical) feedthroughs, and glass ceramics has become a specialty of the plant; the laboratories monitor the materials and processes used by the plant's commercial suppliers of ferroelectric ceramics. In addition to the manufacturing facility, a production development capability is maintained at the Pinellas Plant.

  3. Uranium Processing Facility Site Readiness Subproject Completed...

    National Nuclear Security Administration (NNSA)

    (NNSA) commitment to complete UPF by 2025 and move out of the aging 9212 building facilities it is currently using for a cost not to exceed 6.5 billion. UPF is the...

  4. Preliminary design for hot dirty-gas control-valve test facility. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This report presents the results of a preliminary design and cost estimating effort for a facility for the testing of control valves in Hot Dirty Gas (HDGCV) service. This design was performed by Mittelhauser Corporation for the United States Department of Energy's Morgantown Energy Technology Center (METC). The objective of this effort was to provide METC with a feasible preliminary design for a test facility which could be used to evaluate valve designs under simulated service conditions and provide a technology data base for DOE and industry. In addition to the actual preliminary design of the test facility, final design/construction/operating schedules and a facility cost estimate were prepared to provide METC sufficient information with which to evaluate this design. The bases, assumptions, and limitations of this study effort are given. The tasks carried out were as follows: METC Facility Review, Environmental Control Study, Gas Generation Study, Metallurgy Review, Safety Review, Facility Process Design, Facility Conceptual Layout, Instrumentation Design, Cost Estimates, and Schedules. The report provides information regarding the methods of approach used in the various tasks involved in the completion of this study. Section 5.0 of this report presents the results of the study effort. The results obtained from the above-defined tasks are described briefly. The turnkey cost of the test facility is estimated to be $9,774,700 in fourth quarter 1979 dollars, and the annual operating cost is estimated to be $960,000 plus utilities costs which are not included because unit costs per utility were not available from METC.

  5. Montana Facilities Which Do Not Discharge Process Wastewater...

    Open Energy Info (EERE)

    Which Do Not Discharge Process Wastewater (MDEQ Form 2E) Jump to: navigation, search OpenEI Reference LibraryAdd to library Form: Montana Facilities Which Do Not Discharge Process...

  6. Exhaust gas clean up process

    DOE Patents [OSTI]

    Walker, R.J.

    1988-06-16T23:59:59.000Z

    A method of cleaning an exhaust gas containing particulates, SO/sub 2/ and NO/sub x/ is described. The method involves prescrubbing with water to remove HCl and most of the particulates, scrubbing with an aqueous absorbent containing a metal chelate and dissolved sulfite salt to remove NO/sub x/ and SO/sub 2/, and regenerating the absorbent solution by controlled heating, electrodialysis and carbonate salt addition. The NO/sub x/ is removed as N/sub 2/ gas or nitrogen sulfonate ions and the oxides of sulfur are removed as a valuable sulfate salt. 4 figs.

  7. Gas Test Loop Facilities Alternatives Assessment Report Rev 1

    SciTech Connect (OSTI)

    William J. Skerjanc; William F. Skerjanc

    2005-07-01T23:59:59.000Z

    An important task in the Gas Test Loop (GTL) conceptual design was to determine the best facility to serve as host for this apparatus, which will allow fast-flux neutron testing in an existing nuclear facility. A survey was undertaken of domestic and foreign nuclear reactors and accelerator facilities to arrive at that determination. Two major research reactors in the U.S. were considered in detail, the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR), each with sufficient power to attain the required neutron fluxes. HFIR routinely operates near its design power limit of 100 MW. ATR has traditionally operated at less than half its design power limit of 250 MW. Both of these reactors should be available for at least the next 30 years. The other major U.S. research reactor, the Missouri University Research Reactor, does not have sufficient power to reach the required neutron flux nor do the smaller research reactors. Of the foreign reactors investigated, BOR-60 is perhaps the most attractive. Monju and BN 600 are power reactors for their respective electrical grids. Although the Joyo reactor is vigorously campaigning for customers, local laws regarding transport of radioactive material mean it would be very difficult to retrieve test articles from either Japanese reactor for post irradiation examination. PHENIX is scheduled to close in 2008 and is fully booked until then. FBTR is limited to domestic (Indian) users only. Data quality is often suspect in Russia. The only accelerator seriously considered was the Fuel and Material Test Station (FMTS) currently proposed for operation at Los Alamos National Laboratory. The neutron spectrum in FMTS is similar to that found in a fast reactor, but it has a pronounced high-energy tail that is atypical of fast fission reactor spectra. First irradiation in the FMTS is being contemplated for 2008. Detailed review of these facilities resulted in the recommendation that the ATR would be the best host for the GTL.

  8. Waste Heat Recovery from Refrigeration in a Meat Processing Facility

    E-Print Network [OSTI]

    Murphy, W. T.; Woods, B. E.; Gerdes, J. E.

    1980-01-01T23:59:59.000Z

    A case study is reviewed on a heat recovery system installed in a meat processing facility to preheat water for the plant hot water supply. The system utilizes waste superheat from the facility's 1,350-ton ammonia refrigeration system. The heat...

  9. Electric, Gas, Water, Heating, Refrigeration, and Street Railways Facilities and Service (South Dakota)

    Broader source: Energy.gov [DOE]

    This legislation contains provisions for facilities and service related to electricity, natural gas, water, heating, refrigeration, and street railways. The chapter addresses the construction and...

  10. Gas-Adsorption Processes - An Update

    E-Print Network [OSTI]

    Keller, G. E., II

    1984-01-01T23:59:59.000Z

    points and weak points are delineated. Next, several specific process flow sheets which have been commercialized rather recently and which may be extrapolable to other separations are discussed. Finally, the issue of where gas-adsorption technology...

  11. Alabama Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved Reserves (Billion CubicCubic Feet) Base Gas)1,727Feet)FuelLiquids,

  12. Kansas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15 0 0ExtensionsYear JanFuelProved

  13. Kentucky Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15Industrial Consumers (NumberProved58,899

  14. Louisiana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14343 342 3289 0 0FuelFuel2,208,920 2,175,026

  15. Michigan Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19 15 15 15 3Year Jan Feb2008 2009 2010 2011

  16. Mississippi Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19 15Year Jan Feb (Million2008 2009 2010 2011

  17. Montana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19343 369 384Fuel Consumption

  18. Exhaust gas clean up process

    DOE Patents [OSTI]

    Walker, Richard J. (McMurray, PA)

    1989-01-01T23:59:59.000Z

    A method of cleaning an exhaust gas containing particulates, SO.sub.2 and NO.sub.x includes prescrubbing with water to remove HCl and most of the particulates, scrubbing with an aqueous absorbent containing a metal chelate and dissolved sulfite salt to remove NO.sub.x and SO.sub.2, and regenerating the absorbent solution by controlled heating, electrodialysis and carbonate salt addition. The NO.sub.x is removed as N.sub.2 or nitrogen-sulfonate ions and the oxides of sulfur are removed as a vaulable sulfate salt.

  19. Colorado Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 46 (Million Cubic Feet)FuelProved2008

  20. Pennsylvania Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas,095,3628,527 9,029Cubic Feet) YearFuel Consumption2008 2009

  1. California Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 566 (Million Cubic Feet)Liquids,

  2. TA-55: LANL Plutonium-Processing Facilities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistry; nuclear materials separation, processing, and recovery; plutonium metallurgy, preparation, casting, fabrication, and recovery; machining and metallurgy...

  3. Energy Efficiency Opportunities in California Food Processing Facilities

    E-Print Network [OSTI]

    Wong, T.; Kazama, D; Wang, J.

    2008-01-01T23:59:59.000Z

    the Commission has conducted 10 targeted and plant-wide assessments in industrial facilities associated with the food processing industry. Two of these assessments were Energy Savings Assessments (ESA) funded under the DOE’s “Save Energy Now” Program. All...

  4. Checkout and start-up of the integrated DWPF (Defense Waste Processing Facility) melter system

    SciTech Connect (OSTI)

    Smith, M.E.; Hutson, N.D.; Miller, D.H.; Morrison, J.; Shah, H.; Shuford, J.A.; Glascock, J.; Wurzinger, F.H.; Zamecnik, J.R.

    1989-11-11T23:59:59.000Z

    The Integrated DWPF Melter System (IDMS) is a one-ninth-scale demonstration of the Defense Waste Processing Facility (DWPF) feed preparation, melter, and off-gas systems. The IDMS will be the first engineering-scale melter system at SRL to process mercury and flowsheet levels of halides and sulfates. This report includes a summary of the IDMS program objectives, system and equipment descriptions, and detailed discussions of the system checkout and start-up. 10 refs., 44 figs., 20 tabs.

  5. Opportunities for Process Monitoring Techniques at Delayed Access Facilities

    SciTech Connect (OSTI)

    Curtis, Michael M.; Gitau, Ernest TN; Johnson, Shirley J.; Schanfein, Mark; Toomey, Christopher

    2013-09-20T23:59:59.000Z

    Except for specific cases where the International Atomic Energy Agency (IAEA) maintains a continuous presence at a facility (such as the Japanese Rokkasho Reprocessing Plant), there is always a period of time or delay between the moment a State is notified or aware of an upcoming inspection, and the time the inspector actually enters the material balance area or facility. Termed by the authors as “delayed access,” this period of time between inspection notice and inspector entrance to a facility poses a concern. Delayed access also has the potential to reduce the effectiveness of measures applied as part of the Safeguards Approach for a facility (such as short-notice inspections). This report investigates the feasibility of using process monitoring to address safeguards challenges posed by delayed access at a subset of facility types.

  6. Overview of the Facility Safeguardability Analysis (FSA) Process

    SciTech Connect (OSTI)

    Bari, Robert A.; Hockert, John; Wonder, Edward F.; Johnson, Shirley J.; Wigeland, Roald; Zentner, Michael D.

    2011-10-10T23:59:59.000Z

    The safeguards system of the International Atomic Energy Agency (IAEA) provides the international community with credible assurance that a State is fulfilling its nonproliferation obligations. The IAEA draws such conclusions from the evaluation of all available information. Effective and cost-efficient IAEA safeguards at the facility level are, and will remain, an important element of this “State-level” approach. Efficiently used, the Safeguards by Design (SBD) methodologies , , , now being developed can contribute to effective and cost-efficient facility-level safeguards. The Facility Safeguardability Assessment (FSA) introduced here supports SBD in three areas. 1. It describes necessary interactions between the IAEA, the State regulator, and the owner / designer of a new or modified facility to determine where SBD efforts can be productively applied, 2. It presents a screening approach intended to identify potential safeguard issues for; a) design changes to existing facilities; b) new facilities similar to existing facilities with approved safeguards approaches, and c) new designs, 3. It identifies resources (the FSA toolkit), such as good practice guides, design guidance, and safeguardability evaluation methods that can be used by the owner/designer to develop solutions for potential safeguards issues during the interactions with the State regulator and IAEA. FSA presents a structured framework for the application of the SBD tools developed in other efforts. The more a design evolves, the greater the probability that new safeguards issues could be introduced. Likewise, for first-of-a-kind facilities or research facilities that involve previously unused processes or technologies, it is reasonable to expect that a number of possible safeguards issues might exist. Accordingly, FSA is intended to help the designer and its safeguards experts identify early in the design process: • Areas where elements of previous accepted safeguards approach(es) may be applied to facility modifications or new designs • Modifications of the design that could mitigate a potential safeguards issue or facilitate a more efficient application of the safeguards approach • Possible innovative ideas for more efficient application of safeguards • The potential for changes in elements of the safeguard approach that may be required by IAEA as a result of facility design features and characteristics • Other potential concerns These issues will then be presented to the IAEA and the state regulator to be resolved in a timely manner, ensuring that the planned safeguards approach is acceptable and compatible with the facility design. The proposed approach should be validated by application to suitable facilities to assess its utility, comprehensiveness, and cost-effectiveness. The approach and example application should also be reviewed by industry to confirm the conclusions reached in the DOE review.

  7. Isotopic noble gas signatures released from medical isotope production facilities - Simulations and measurements

    SciTech Connect (OSTI)

    Saey, Paul R.; Bowyer, Ted W.; Ringbom, Anders

    2010-09-09T23:59:59.000Z

    Journal article on the role that radioxenon isotopes play in confirming whether or not an underground explosion was nuclear in nature. Radioxenon isotopes play a major role in confirming whether or not an underground explosion was nuclear in nature. It is then of key importance to understand the sources of environmental radioxenon to be able to distinguish civil sources from those of a nuclear explosion. Based on several years of measurements, combined with advanced atmospheric transport model results, it was recently shown that the main source of radioxenon observations are strong and regular batch releases from a very limited number of medical isotope production facilities. This paper reviews production processes in different medical isotope facilities during which radioxenon is produced. Radioxenon activity concentrations and isotopic compositions are calculated for six large facilities. The results are compared with calculated signals from nuclear explosions. Further, the outcome is compared and found to be consistent with radioxenon measurements recently performed in and around three of these facilities. Some anomalies in measurements in which {sup 131m}Xe was detected were found and a possible explanation is proposed. It was also calculated that the dose rate of the releases is well below regulatory values. Based on these results, it should be possible to better understand, interpret and verify signals measured in the noble gas measurement systems in the International Monitoring of the Comprehensive Nuclear-Test-Ban Treaty.

  8. Facility effluent monitoring plan for the Waste Receiving and Processing Facility Module 1

    SciTech Connect (OSTI)

    Lewis, C.J.

    1995-10-01T23:59:59.000Z

    A facility effluent monitoring plan is required by the US Department of Energy in Order 5400.1 for any operations that involve hazardous materials and radioactive substances that could impact employee or public safety or the environment. This document is prepared using the specific guidelines identified in A Guide for Preparing Hanford Site Facility Effluent Monitoring Plans, WHC-EP-0438. This facility effluent monitoring plan assesses effluent monitoring systems and evaluates whether they are adequate to ensure the public health and safety as specified in applicable federal state, and local requirements. This facility effluent monitoring plan shall ensure lonq-range integrity of the effluent monitoring systems by requiring an update whenever a new process or operation introduces new hazardous materials or significant radioactive materials. This document must be reviewed annually even if there are no operational changes, and it must be updated as a minimum every three years.

  9. POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS AND CO2 METHANATION NOVEMBER 19th 2013 IRES. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis Gas-to-heat Gas-to-mobility Gas-to-power Excess Production = Consumption Distribution and storing

  10. Process for production desulfurized of synthesis gas

    DOE Patents [OSTI]

    Wolfenbarger, James K. (Torrance, CA); Najjar, Mitri S. (Wappingers Falls, NY)

    1993-01-01T23:59:59.000Z

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

  11. EIS-0082: Defense Waste Processing Facility, Savannah River Plant

    Broader source: Energy.gov [DOE]

    The Office of Defense Waste and Byproducts Management developed this EIS to provide environmental input into both the selection of an appropriate strategy for the permanent disposal of the high-level radioactive waste currently stored at the Savannah River Plant (SRP) and the subsequent decision to construct and operate a Defense Waste Processing Facility at the SRP site.

  12. Desulfurization of flue gas by the confined zone dispersion process

    SciTech Connect (OSTI)

    Not Available

    1989-10-01T23:59:59.000Z

    This Confined Zone Dispersion (CZD) process involves injecting a finely atomized slurry of reactive lime into the ductwork of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. The purpose of this project was to prove the CZD process concept by testing it on a limited scale, and then demonstrating the process on a large scale. The scope of work included projecting the cost of commercial implementation. The test facility for the proof-of-concept tests was on a scale equivalent to a 7 MWe generating plant. The large-scale demonstration was made on a scale of 70 MWe. This report describes how data from the two test sites were correlated, and presents conceptual designs for two full-scale retrofit installations. The rationale and data supporting the conclusions are also given in Part 4.

  13. Technical evaluation of proposed Ukrainian Central Radioactive Waste Processing Facility

    SciTech Connect (OSTI)

    Gates, R.; Glukhov, A.; Markowski, F.

    1996-06-01T23:59:59.000Z

    This technical report is a comprehensive evaluation of the proposal by the Ukrainian State Committee on Nuclear Power Utilization to create a central facility for radioactive waste (not spent fuel) processing. The central facility is intended to process liquid and solid radioactive wastes generated from all of the Ukrainian nuclear power plants and the waste generated as a result of Chernobyl 1, 2 and 3 decommissioning efforts. In addition, this report provides general information on the quantity and total activity of radioactive waste in the 30-km Zone and the Sarcophagus from the Chernobyl accident. Processing options are described that may ultimately be used in the long-term disposal of selected 30-km Zone and Sarcophagus wastes. A detailed report on the issues concerning the construction of a Ukrainian Central Radioactive Waste Processing Facility (CRWPF) from the Ukrainian Scientific Research and Design institute for Industrial Technology was obtained and incorporated into this report. This report outlines various processing options, their associated costs and construction schedules, which can be applied to solving the operating and decommissioning radioactive waste management problems in Ukraine. The costs and schedules are best estimates based upon the most current US industry practice and vendor information. This report focuses primarily on the handling and processing of what is defined in the US as low-level radioactive wastes.

  14. Facility Effluent Monitoring Plan for the Waste Receiving and Processing (WRAP) Facility

    SciTech Connect (OSTI)

    DAVIS, W.E.

    2000-03-08T23:59:59.000Z

    A facility effluent monitoring plan is required by the U.S. Department of Energy in Order 5400.1 for any operations that involve hazardous materials and radioactive substances that could impact employee public safety, or the environment. This facility effluent monitoring plan assesses effluent monitoring systems and evaluates whether these systems are adequate to ensure the public health and safety as specified in applicable federal, state, and local requirements. This facility effluent monitoring plan ensures long-range integrity of the effluent monitoring systems by requiring an update whenever a new process or operation introduces new hazardous materials or significant radioactive materials. This document must be reviewed annually even if there are no operational changes, and must be updated, as a minimum, every 3 years.

  15. Gas Composition Transients in the Cold Vacuum Drying (CVD) Facility

    SciTech Connect (OSTI)

    PACKER, M.J.

    1999-07-01T23:59:59.000Z

    Calculations with plotted results presented as confirmation bases for selected problems involving the prediction of transient gas compositions during Cold Vacuum Drying Operations.

  16. Design characteristics for facilities which process hazardous particulate

    SciTech Connect (OSTI)

    Abeln, S.P.; Creek, K.; Salisbury, S.

    1998-12-01T23:59:59.000Z

    Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

  17. The Mixed Waste Management Facility: Technology selection and implementation plan, Part 2, Support processes

    SciTech Connect (OSTI)

    Streit, R.D.; Couture, S.A.

    1995-03-01T23:59:59.000Z

    The purpose of this document is to establish the foundation for the selection and implementation of technologies to be demonstrated in the Mixed Waste Management Facility, and to select the technologies for initial pilot-scale demonstration. Criteria are defined for judging demonstration technologies, and the framework for future technology selection is established. On the basis of these criteria, an initial suite of technologies was chosen, and the demonstration implementation scheme was developed. Part 1, previously released, addresses the selection of the primary processes. Part II addresses process support systems that are considered ``demonstration technologies.`` Other support technologies, e.g., facility off-gas, receiving and shipping, and water treatment, while part of the integrated demonstration, use best available commercial equipment and are not selected against the demonstration technology criteria.

  18. The Sodium Process Facility at Argonne National Laboratory-West

    SciTech Connect (OSTI)

    Michelbacher, J.A.; Henslee, S.P. McDermott, M.D.; Price, J.R.; Rosenberg, K.E.; Wells, P.B.

    1998-07-01T23:59:59.000Z

    Argonne National Laboratory-West (ANL-W) has approximately 680,000 liters of raw sodium stored in facilities on site. As mandated by the State of Idaho and the US Department of Energy (DOE), this sodium must be transformed into a stable condition for land disposal. To comply with this mandate, ANL-W designed and built the Sodium Process Facility (SPF) for the processing of this sodium into a dry, sodium carbonate powder. The major portion of the sodium stored at ANL-W is radioactively contaminated. The sodium will be processed in three separate and distinct campaigns: the 290,000 liters of Fermi-1 primary sodium, the 50,000 liters of the Experimental Breeder Reactor-II (EBR-II) secondary sodium, and the 330,000 liters of the EBR-II primary sodium. The Fermi-1 and the EBR-II secondary sodium contain only low-level of radiation, while the EBR-II primary sodium has radiation levels up to 0.5 mSv (50 mrem) per hour at 1 meter. The EBR-II primary sodium will be processed last, allowing the operating experience to be gained with the less radioactive sodium prior to reacting the most radioactive sodium. The sodium carbonate will be disposed of in 270 liter barrels, four to a pallet. These barrels are square in cross-section, allowing for maximum utilization of the space on a pallet, minimizing the required landfill space required for disposal.

  19. Tritium Facilities Modernization and Consolidation Project Process Waste Assessment (Project S-7726)

    SciTech Connect (OSTI)

    Hsu, R.H. [Westinghouse Savannah River Company, AIKEN, SC (United States); Oji, L.N.

    1997-11-14T23:59:59.000Z

    Under the Tritium Facility Modernization {ampersand} Consolidation (TFM{ampersand}C) Project (S-7726) at the Savannah River Site (SS), all tritium processing operations in Building 232-H, with the exception of extraction and obsolete/abandoned systems, will be reestablished in Building 233-H. These operations include hydrogen isotopic separation, loading and unloading of tritium shipping and storage containers, tritium recovery from zeolite beds, and stripping of nitrogen flush gas to remove tritium prior to stack discharge. The scope of the TFM{ampersand}C Project also provides for a new replacement R&D tritium test manifold in 233-H, upgrading of the 233- H Purge Stripper and 233-H/234-H building HVAC, a new 234-H motor control center equipment building and relocating 232-H Materials Test Facility metallurgical laboratories (met labs), flow tester and life storage program environment chambers to 234-H.

  20. IMPACTS OF ANTIFOAM ADDITIONS AND ARGON BUBBLING ON DEFENSE WASTE PROCESSING FACILITY REDUCTION/OXIDATION

    SciTech Connect (OSTI)

    Jantzen, C.; Johnson, F.

    2012-06-05T23:59:59.000Z

    During melting of HLW glass, the REDOX of the melt pool cannot be measured. Therefore, the Fe{sup +2}/{Sigma}Fe ratio in the glass poured from the melter must be related to melter feed organic and oxidant concentrations to ensure production of a high quality glass without impacting production rate (e.g., foaming) or melter life (e.g., metal formation and accumulation). A production facility such as the Defense Waste Processing Facility (DWPF) cannot wait until the melt or waste glass has been made to assess its acceptability, since by then no further changes to the glass composition and acceptability are possible. therefore, the acceptability decision is made on the upstream process, rather than on the downstream melt or glass product. That is, it is based on 'feed foward' statistical process control (SPC) rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. Use of the DWPF REDOX model has controlled the balanjce of feed reductants and oxidants in the Sludge Receipt and Adjustment Tank (SRAT). Once the alkali/alkaline earth salts (both reduced and oxidized) are formed during reflux in the SRAT, the REDOX can only change if (1) additional reductants or oxidants are added to the SRAT, the Slurry Mix Evaporator (SME), or the Melter Feed Tank (MFT) or (2) if the melt pool is bubble dwith an oxidizing gas or sparging gas that imposes a different REDOX target than the chemical balance set during reflux in the SRAT.

  1. Natural Gas Procurement Challenges for a Project Financed Cogeneration Facility

    E-Print Network [OSTI]

    Good, R. L.; Calvert, T. B.; Pavlish, B. A.

    these criteria as inconsistent with UCC project economics and normal procurement practice. A. TERM OF CONTRACT The trend in the industry was strongly moving away from long term fixed price contracts. Natural Gas prices had moved steadily upward through..., by 1986? the problem of long term take or pay contracts in the Industry was overwhelming. Most producers had written some contracts at very low prices that had not expired while consumers were replacing contract written at high prices. However...

  2. Lake Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429Lacey, Washington: Energy ResourcesGas Location Cook County, Illinois

  3. Materials evaluation programs at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Gee, J.T.; Iverson, D.C.; Bickford, D.F.

    1992-01-01T23:59:59.000Z

    The Savannah River Site (SRS) has been operating a nuclear fuel cycle since the 1950s to produce nuclear materials in support of the national defense effort. About 83 million gallons of high-level waste produced since operations began has been consolidated by evaporation into 33 million gallons at the waste tank farm. The Department of Energy authorized the construction of the Defense Waste Processing Facility (DWPF), the function of which is to immobilize the waste as a durable borosilicate glass contained in stainless steel canisters prior to the placement of the canisters in a federal repository. The DWPF is now mechanically complete and is undergoing commissioning and run-in activities. A brief description of the DWPF process is provided.

  4. Materials evaluation programs at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Gee, J.T.; Iverson, D.C.; Bickford, D.F.

    1992-12-31T23:59:59.000Z

    The Savannah River Site (SRS) has been operating a nuclear fuel cycle since the 1950s to produce nuclear materials in support of the national defense effort. About 83 million gallons of high-level waste produced since operations began has been consolidated by evaporation into 33 million gallons at the waste tank farm. The Department of Energy authorized the construction of the Defense Waste Processing Facility (DWPF), the function of which is to immobilize the waste as a durable borosilicate glass contained in stainless steel canisters prior to the placement of the canisters in a federal repository. The DWPF is now mechanically complete and is undergoing commissioning and run-in activities. A brief description of the DWPF process is provided.

  5. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06T23:59:59.000Z

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  6. Settlers Hill Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty Ltd Jump to: navigation, search| Open EnergySermatec JumpSestaSettlers Hill Gas

  7. BJ Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCT BiomassArnprior,Aurantia SACitas Jump to:PáginasBEVBJ Gas

  8. Greene Valley Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio: EnergyGrasslandsGreen2V Jump to:GreenboxGreeneGas Recovery Biomass

  9. Prairie View Gas Recovery Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy ResourcesLoadingPenobscot County, Maine:Plug Power IncPowder River EnergyCubePracticalPower, IncRose,Gas

  10. Model operating permits for natural gas processing plants

    SciTech Connect (OSTI)

    Arend, C. [Hydro-Search, Inc., Houston, TX (United States)

    1995-12-31T23:59:59.000Z

    Major sources as defined in Title V of the Clean Air Act Amendments of 1990 that are required to submit an operating permit application will need to: Evaluate their compliance status; Determine a strategic method of presenting the general and specific conditions of their Model Operating Permit (MOP); Maintain compliance with air quality regulations. A MOP is prepared to assist permitting agencies and affected facilities in the development of operating permits for a specific source category. This paper includes a brief discussion of example permit conditions that may be applicable to various types of Title V sources. A MOP for a generic natural gas processing plant is provided as an example. The MOP should include a general description of the production process and identify emission sources. The two primary elements that comprise a MOP are: Provisions of all existing state and/or local air permits; Identification of general and specific conditions for the Title V permit. The general provisions will include overall compliance with all Clean Air Act Titles. The specific provisions include monitoring, record keeping, and reporting. Although Title V MOPs are prepared on a case-by-case basis, this paper will provide a general guideline of the requirements for preparation of a MOP. Regulatory agencies have indicated that a MOP included in the Title V application will assist in preparation of the final permit provisions, minimize delays in securing a permit, and provide support during the public notification process.

  11. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect (OSTI)

    Rizzo, Jeffrey J. [Phillips66 Company, West Terre Haute, IN (United States)

    2010-04-30T23:59:59.000Z

    The Wabash gasification facility, owned and operated by sgSolutions LLC, is one of the largest single train solid fuel gasification facilities in the world capable of transforming 2,000 tons per day of petroleum coke or 2,600 tons per day of bituminous coal into synthetic gas for electrical power generation. The Wabash plant utilizes Phillips66 proprietary E-Gas (TM) Gasification Process to convert solid fuels such as petroleum coke or coal into synthetic gas that is fed to a combined cycle combustion turbine power generation facility. During plant startup in 1995, reliability issues were realized in the gas filtration portion of the gasification process. To address these issues, a slipstream test unit was constructed at the Wabash facility to test various filter designs, materials and process conditions for potential reliability improvement. The char filtration slipstream unit provided a way of testing new materials, maintenance procedures, and process changes without the risk of stopping commercial production in the facility. It also greatly reduced maintenance expenditures associated with full scale testing in the commercial plant. This char filtration slipstream unit was installed with assistance from the United States Department of Energy (built under DOE Contract No. DE-FC26-97FT34158) and began initial testing in November of 1997. It has proven to be extremely beneficial in the advancement of the E-Gas (TM) char removal technology by accurately predicting filter behavior and potential failure mechanisms that would occur in the commercial process. After completing four (4) years of testing various filter types and configurations on numerous gasification feed stocks, a decision was made to investigate the economic and reliability effects of using a particulate removal gas cyclone upstream of the current gas filtration unit. A paper study had indicated that there was a real potential to lower both installed capital and operating costs by implementing a char cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  12. Waste receiving and processing facility module 1, detailed design report

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    WRAP 1 baseline documents which guided the technical development of the Title design included: (a) A/E Statement of Work (SOW) Revision 4C: This DOE-RL contractual document specified the workscope, deliverables, schedule, method of performance and reference criteria for the Title design preparation. (b) Functional Design Criteria (FDC) Revision 1: This DOE-RL technical criteria document specified the overall operational criteria for the facility. The document was a Revision 0 at the beginning of the design and advanced to Revision 1 during the tenure of the Title design. (c) Supplemental Design Requirements Document (SDRD) Revision 3: This baseline criteria document prepared by WHC for DOE-RL augments the FDC by providing further definition of the process, operational safety, and facility requirements to the A/E for guidance in preparing the design. The document was at a very preliminary stage at the onset of Title design and was revised in concert with the results of the engineering studies that were performed to resolve the numerous technical issues that the project faced when Title I was initiated, as well as, by requirements established during the course of the Title II design.

  13. PEGASUS, a European research project on the effects of gas in underground storage facilities for radioactive waste

    SciTech Connect (OSTI)

    Haijtink, B.; McMenamin, T. [Commission of the European Communities, Brussels (Belgium)

    1993-12-31T23:59:59.000Z

    Whereas the subject of gas generation and possible gas release from radioactive waste repositories has gained in interest on the international scene, the Commission of the European Communities has increased its research efforts on this issue. In particular in the 4th five year R and D program on Management and Storage of Radioactive Waste (1990--1994), a framework has been set up in which research efforts on the subject of gas generation and migration, supported by the CEC, are brought together and coordinated. In this project, called PEGASUS, Project on the Effects of GAS in Underground Storage facilities for radioactive waste, about 20 organizations and research institutes from 7 European countries are involved. The project covers both experimental and theoretical studies of the processes of gas formation and possible gas release from the different waste types, LLW, ILW and HLW, under typical repository conditions in suitable geological formations as clay, salt and granite. In this paper an overview is given of the various studies undertaken in the project as well as some first results presented.

  14. Process for selected gas oxide removal by radiofrequency catalysts

    DOE Patents [OSTI]

    Cha, C.Y.

    1993-09-21T23:59:59.000Z

    This process to remove gas oxides from flue gas utilizes adsorption on a char bed subsequently followed by radiofrequency catalysis enhancing such removal through selected reactions. Common gas oxides include SO[sub 2] and NO[sub x]. 1 figure.

  15. Gas Distribution Modeling using Sparse Gaussian Process Mixture Models

    E-Print Network [OSTI]

    Stachniss, Cyrill

    Gas Distribution Modeling using Sparse Gaussian Process Mixture Models Cyrill Stachniss1 Christian-- In this paper, we consider the problem of learning a two dimensional spatial model of a gas distribution with a mobile robot. Building maps that can be used to accurately predict the gas concentration at query

  16. Mercury Reduction and Removal from High Level Waste at the Defense Waste Processing Facility - 12511

    SciTech Connect (OSTI)

    Behrouzi, Aria [Savannah River Remediation, LLC (United States); Zamecnik, Jack [Savannah River National Laboratory, Aiken, South Carolina, 29808 (United States)

    2012-07-01T23:59:59.000Z

    The Defense Waste Processing Facility processes legacy nuclear waste generated at the Savannah River Site during production of enriched uranium and plutonium required by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. One of the constituents in the nuclear waste is mercury, which is present because it served as a catalyst in the dissolution of uranium-aluminum alloy fuel rods. At high temperatures mercury is corrosive to off-gas equipment, this poses a major challenge to the overall vitrification process in separating mercury from the waste stream prior to feeding the high temperature melter. Mercury is currently removed during the chemical process via formic acid reduction followed by steam stripping, which allows elemental mercury to be evaporated with the water vapor generated during boiling. The vapors are then condensed and sent to a hold tank where mercury coalesces and is recovered in the tank's sump via gravity settling. Next, mercury is transferred from the tank sump to a purification cell where it is washed with water and nitric acid and removed from the facility. Throughout the chemical processing cell, compounds of mercury exist in the sludge, condensate, and off-gas; all of which present unique challenges. Mercury removal from sludge waste being fed to the DWPF melter is required to avoid exhausting it to the environment or any negative impacts to the Melter Off-Gas system. The mercury concentration must be reduced to a level of 0.8 wt% or less before being introduced to the melter. Even though this is being successfully accomplished, the material balances accounting for incoming and collected mercury are not equal. In addition, mercury has not been effectively purified and collected in the Mercury Purification Cell (MPC) since 2008. A significant cleaning campaign aims to bring the MPC back up to facility housekeeping standards. Two significant investigations are being undertaken to restore mercury collection. The SMECT mercury pump has been removed from the tank and will be functionally tested. Also, research is being conducted by the Savannah River National Laboratory to determine the effects of antifoam addition on the behavior of mercury. These path forward items will help us better understand what is occurring in the mercury collection system and ultimately lead to an improved DWPF production rate and mercury recovery rate. (authors)

  17. Building success : the role of the state in the cultural facility development process

    E-Print Network [OSTI]

    Choy, Carolyn (Carolyn Anne)

    2007-01-01T23:59:59.000Z

    This thesis investigates the question of what is the current role of the state in the cultural facility development process, and, in light of facility-related warnings that have been made over the years, what role should ...

  18. Characterization of emissions from scrap metal processing facilities

    SciTech Connect (OSTI)

    Norco, J.E. [Versar, Inc., Lombard, IL (United States); Tyler, T. [Inst. of Scrap Recycling Industries, Inc., Washington, DC (United States)

    1997-12-31T23:59:59.000Z

    To prepare its members for the permitting requirements under Title 5 of the Clean Act, the Institute of Scrap Recycling Industries (ISRI) commissioned a project to develop a Title 5 applicability workbook. A critical element in the preparation of the workbook was the characterization of emissions from processes and equipment typically found in the scrap metal processing industry. This paper describes the approach to the preparation of the workbook with emphasis on characterization of specific emission units which are deemed important for Title 5. The paper describes the methodology employed for acquiring existing emissions information from equipment manufacturers, vendors, and scrap recycling facility operators. The data were aggregated and analyzed to develop a variety of emission tabulations for pollutants requiring analysis under Title 5. The project also involved a survey of numerous state and local air pollution agencies to determine regulatory requirements regarding critical issues in the scrap processing industry. The paper describes a methodology for determining Title 5 applicability with emphasis on the use of emission tabulations and example worksheets. Emissions data are presented for metal shredders to demonstrate the methodology and procedures developed during the project. Finally, the paper discusses the structure of the Title 5 applicability workbook and its dissemination to a major industry trade association.

  19. A survey of decontamination processes applicable to DOE nuclear facilities

    SciTech Connect (OSTI)

    Chen, L.; Chamberlain, D.B.; Conner, C.; Vandegrift, G.F.

    1997-05-01T23:59:59.000Z

    The objective of this survey was to select an appropriate technology for in situ decontamination of equipment interiors as part of the decommissioning of U.S. Department of Energy nuclear facilities. This selection depends on knowledge of existing chemical decontamination methods. This report provides an up-to-date review of chemical decontamination methods. According to available information, aqueous systems are probably the most universally used method for decontaminating and cleaning metal surfaces. We have subdivided the technologies, on the basis of the types of chemical solvents, into acid, alkaline permanganate, highly oxidizing, peroxide, and miscellaneous systems. Two miscellaneous chemical decontamination methods (electrochemical processes and foam and gel systems) are also described. A concise technical description of various processes is given, and the report also outlines technical considerations in the choice of technologies, including decontamination effectiveness, waste handing, fields of application, and the advantages and limitations in application. On the basis of this survey, six processes were identified for further evaluation. 144 refs., 2 tabs.

  20. IMPACT OF THE SMALL COLUMN ION EXCHANGE PROCESS ON THE DEFENSE WASTE PROCESSING FACILITY - 12112

    SciTech Connect (OSTI)

    Koopman, D.; Lambert, D.; Fox, K.; Stone, M.

    2011-11-07T23:59:59.000Z

    The Savannah River Site (SRS) is investigating the deployment of a parallel technology to the Salt Waste Processing Facility (SWPF, presently under construction) to accelerate high activity salt waste processing. The proposed technology combines large waste tank strikes of monosodium titanate (MST) to sorb strontium and actinides with two ion exchange columns packed with crystalline silicotitanate (CST) resin to sorb cesium. The new process was designated Small Column Ion Exchange (SCIX), since the ion exchange columns were sized to fit within a waste storage tank riser. Loaded resins are to be combined with high activity sludge waste and fed to the Defense Waste Processing Facility (DWPF) for incorporation into the current glass waste form. Decontaminated salt solution produced by SCIX will be fed to the SRS Saltstone Facility for on-site immobilization as a grout waste form. Determining the potential impact of SCIX resins on DWPF processing was the basis for this study. Accelerated salt waste treatment is projected to produce a significant savings in the overall life cycle cost of waste treatment at SRS.

  1. An Electrochemically-mediated Gas Separation Process for Carbon Abatement

    E-Print Network [OSTI]

    Stern, Michael C.

    This work describes a promising alternative to conventional thermal processes for absorber/desorber processing of for removal of CO[subscript 2] from flue gas streams at fossil fuel fired power plants. Our electrochemica ...

  2. Defense Waste Processing Facility wasteform and canister description: Revision 2

    SciTech Connect (OSTI)

    Baxter, R.G.

    1988-12-01T23:59:59.000Z

    This document describes the reference wasteform and canister for the Defense Waste Processing Facility (DWPF). The principal changes include revised feed and glass product compositions, an estimate of glass product characteristics as a function of time after the start of vitrification, and additional data on glass leaching performance. The feed and glass product composition data are identical to that described in the DWPF Basic Data Report, Revision 90/91. The DWPF facility is located at the Savannah River Plant in Aiken, SC, and it is scheduled for construction completion during December 1989. The wasteform is borosilicate glass containing approximately 28 wt % sludge oxides, with the balance consisting of glass-forming chemicals, primarily glass frit. Borosilicate glass was chosen because of its stability toward reaction with potential repository groundwaters, its relatively high ability to incorporate nuclides found in the sludge into the solid matrix, and its reasonably low melting temperature. The glass frit contains approximately 71% SiO/sub 2/, 12% B/sub 2/O/sub 3/, and 10% Na/sub 2/O. Tests to quantify the stability of DWPF waste glass have been performed under a wide variety of conditions, including simulations of potential repository environments. Based on these tests, DWPF waste glass should easily meet repository criteria. The canister is filled with about 3700 lb of glass which occupies 85% of the free canister volume. The filled canister will generate approximately 690 watts when filled with oxides from 5-year-old sludge and precipitate from 15-year-old supernate. The radionuclide activity of the canister is about 233,000 curies, with an estimated radiation level of 5600 rad/hour at the canister surface. 14 figs., 28 tabs.

  3. Accuracy improved with analysis of pulsation effects at gas-pipeline metering facilities

    SciTech Connect (OSTI)

    Sparks, C.R.; McKee, R.J.

    1986-12-08T23:59:59.000Z

    Results of recent research have provided means for diagnosing and controlling systems effects - pulsations and other adverse flow conditions at natural-gas metering sites. In recent years both in the U.S. and in the European Economic Community, several programs have been concerned with improving orifice coefficient data. Programs sponsored by the Gas Research Institute (GRI), the American Petroleum Institute (API), and the American Gas Association (AGA) at the National Bureau of Standards (NBS) facilities at Gaithersburg, MD., and Boulder, Colo., and at the Colorado Engineering Experiment Station are notable examples of this work. Parallel test work in the U.K. at British Gas and National Engineering Labs, at Gasunie in The Netherlands; and at Gaz de France have included round-robin comparison testing of a few standardized orifice sizes. In all cases, the primary objective has been substantially to extend the orifice data base, to reduce data scatter, and to define the seriousness of ''facility bias'' effects which appear to be inherent in the various individual test facilities.

  4. Determining the Cause of a Header Failure in a Natural Gas Production Facility

    SciTech Connect (OSTI)

    Matthes, S.A.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.; Holcomb, G.R.

    2007-03-01T23:59:59.000Z

    An investigation was made into the premature failure of a gas-header at the Rocky Mountain Oilfield Testing Center (RMOTC) natural gas production facility. A wide variety of possible failure mechanisms were considered: design of the header, deviation from normal pipe alloy composition, physical orientation of the header, gas composition and flow rate, type of corrosion, protectiveness of the interior oxide film, time of wetness, and erosion-corrosion. The failed header was examined using metallographic techniques, scanning electron microscopy, and microanalysis. A comparison of the failure site and an analogous site that had not failed, but exhibited similar metal thinning was also performed. From these studies it was concluded that failure resulted from erosion-corrosion, and that design elements of the header and orientation with respect to gas flow contributed to the mass loss at the failure point.

  5. Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    This quarterly technical progress report summarizes work completed during the Sixth Quarter of the First Budget Period, January 1 through March 31, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. The major emphasis during this reporting period was expanding the test facility to address system integration issues of hot particulate removal in advanced power generation systems. The conceptual design of the facility was extended to include additional modules for the expansion of the test facility, which is referred to as the Power Systems Development Facility (PSOF). A letter agreement was negotiated between Southern Company Services (SCS) and Foster Wheeler (FW) for the conceptual design of the Advanced Pressurized Fluid-Bed Combustion (APFBC)/Topping Combustor/Gas Turbine System to be added to the facility. The expanded conceptual design also included modifications to the existing conceptual design for the Hot Gas Cleanup Test Facility (HGCTF), facility layout and balance of plant design for the PSOF. Southern Research Institute (SRI) began investigating the sampling requirements for the expanded facility and assisted SCS in contacting Particulate Control Device (PCD) vendors for additional information. SCS also contacted the Electric Power Research Institute (EPRI) and two molten carbonate fuel cell vendors for input on the fuel cell module for the PSDF.

  6. RECENT PROCESS AND EQUIPMENT IMPROVEMENTS TO INCREASE HIGH LEVEL WASTE THROUGHPUT AT THE DEFENSE WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Odriscoll, R; Allan Barnes, A; Jim Coleman, J; Timothy Glover, T; Robert Hopkins, R; Dan Iverson, D; Jeff Leita, J

    2008-01-15T23:59:59.000Z

    The Savannah River Site's (SRS) Defense Waste Processing Facility (DWPF) began stabilizing high level waste (HLW) in a glass matrix in 1996. Over the past few years, there have been several process and equipment improvements at the DWPF to increase the rate at which the high level waste can be stabilized. These improvements have either directly increased waste processing rates or have desensitized the process to upsets, thereby minimizing downtime and increasing production. Improvements due to optimization of waste throughput with increased HLW loading of the glass resulted in a 6% waste throughput increase based upon operational efficiencies. Improvements in canister production include the pour spout heated bellows liner (5%), glass surge (siphon) protection software (2%), melter feed pump software logic change to prevent spurious interlocks of the feed pump with subsequent dilution of feed stock (2%) and optimization of the steam atomized scrubber (SAS) operation to minimize downtime (3%) for a total increase in canister production of 12%. A number of process recovery efforts have allowed continued operation. These include the off gas system pluggage and restoration, slurry mix evaporator (SME) tank repair and replacement, remote cleaning of melter top head center nozzle, remote melter internal inspection, SAS pump J-Tube recovery, inadvertent pour scenario resolutions, dome heater transformer bus bar cooling water leak repair and new Infra-red camera for determination of glass height in the canister are discussed.

  7. [Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion]. Quarterly technical progress report, October 1--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, October 1 through December 31, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: (1) Carbonizer/pressurized circulating fluidized bed gas source; (2) hot gas cleanup units to mate to all gas streams; (3) combustion gas turbine; (4) fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

  8. Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project- February 2013

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Salt Waste Processing Facility Construction Project is continuing to perform at a level deserving DOE-VPP Star recognition.

  9. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  10. A Concept for a Low Pressure Noble Gas Fill Intervention in the IFE Fusion Test Facility (FTF) Target Chamber

    SciTech Connect (OSTI)

    C.A. Gentile, W.R. Blanchard, T.A. Kozub, M. Aristova, C. McGahan, S. Natta, K. Pagdon, J. Zelenty

    2010-01-14T23:59:59.000Z

    An engineering evaluation has been initiated to investigate conceptual engineering methods for implementing a viable gas shield strategy in the Fusion Test Facility (FTF) target chamber. The employment of a low pressure noble gas in the target chamber to thermalize energetic helium ions prior to interaction with the wall could dramatically increase the useful life of the first wall in the FTF reactor1. For the purpose of providing flexibility, two target chamber configurations are addressed: a five meter radius sphere and a ten meter radius sphere. Experimental studies at Nike have indicated that a low pressure, ambient gas resident in the target chamber during laser pulsing does not appear to impair the ability of laser light from illuminating targets2. In addition, current investigations into delivering, maintaining, and processing low pressure gas appear to be viable with slight modification to current pumping and plasma exhaust processing technologies3,4. Employment of a gas fill solution for protecting the dry wall target chamber in the FTF may reduce, or possibly eliminate the need for other attenuating technologies designed for keeping He ions from implanting in first wall structures and components. The gas fill concept appears to provide an effective means of extending the life of the first wall while employing mostly commercial off the shelf (COTS) technologies. Although a gas fill configuration may provide a methodology for attenuating damage inflicted on chamber surfaces, issues associated with target injection need to be further analyzed to ensure that the gas fill concept is viable in the integrated FTF design5. In the proposed system, the ambient noble gas is heated via the energetic helium ions produced by target detonation. The gas is subsequently cooled by the chamber wall to approximately 800oC, removed from the chamber, and processed by the chamber gas processing system (CGPS). In an optimized scenario of the above stated concept, the chamber wall acts as the primary heat exchanger. During removal, gas is pumped through the laser ports by turbo molecular-drag pumps (TM-DP). For the purpose of reducing organic based lubricants and seals, a magnetically levitated TM-DP is being investigated with pump manufacturers. Currently, magnetically levitated turbo molecular pumps are commercially available. The pumps will be exposed to thermal loads and ionizing radiation (tritium, Ar-41, post detonation neutrons). Although the TM-DP's will be subjected to these various radiations, current designs for similar pumping devices have been hardened and have the ability of locating control electronics in remote radiation shielded enclosures4. The radiation hardened TM-DP's will be 5 required to operate with minimal maintenance for periods of up to 18 continuous months. As part of this initial investigation for developing a conceptual engineering strategy for a gas fill solution, commercial suppliers of low pressure gas pumping systems have been contacted and engaged in this evaluation. Current technology in the area of mechanical pumping systems indicates that the development of a robust pumping system to meet the requirements of the FTF gas fill concept is within the limits of COTS equipment3,4.

  11. Process and system for removing impurities from a gas

    DOE Patents [OSTI]

    Henningsen, Gunnar; Knowlton, Teddy Merrill; Findlay, John George; Schlather, Jerry Neal; Turk, Brian S

    2014-04-15T23:59:59.000Z

    A fluidized reactor system for removing impurities from a gas and an associated process are provided. The system includes a fluidized absorber for contacting a feed gas with a sorbent stream to reduce the impurity content of the feed gas; a fluidized solids regenerator for contacting an impurity loaded sorbent stream with a regeneration gas to reduce the impurity content of the sorbent stream; a first non-mechanical gas seal forming solids transfer device adapted to receive an impurity loaded sorbent stream from the absorber and transport the impurity loaded sorbent stream to the regenerator at a controllable flow rate in response to an aeration gas; and a second non-mechanical gas seal forming solids transfer device adapted to receive a sorbent stream of reduced impurity content from the regenerator and transfer the sorbent stream of reduced impurity content to the absorber without changing the flow rate of the sorbent stream.

  12. Wireless Critical Process Control in oil and gas refinery plants

    E-Print Network [OSTI]

    Savazzi, Stefano

    Wireless Critical Process Control in oil and gas refinery plants Stefano Savazzi1, Sergio Guardiano control in in- dustrial plants and oil/gas refineries. In contrast to wireline communication, wireless of an oil refinery is illustrated in Fig. 1: typical locations of wireless devices used for re- mote control

  13. Process for producing dimethyl ether form synthesis gas

    DOE Patents [OSTI]

    Pierantozzi, Ronald (Macungie, PA)

    1985-01-01T23:59:59.000Z

    This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

  14. Development of the CD Symcap platform to study gas-shell mix in implosions at the National Ignition Facility

    SciTech Connect (OSTI)

    Casey, D. T.; Smalyuk, V. A.; Tipton, R. E.; Pino, J. E.; Remington, B. A.; Rowley, D. P.; Weber, S. V.; Barrios, M.; Benedetti, L. R.; Bleuel, D. L.; Bond, E. J.; Bradley, D. K.; Caggiano, J. A.; Callahan, D. A.; Cerjan, C. J.; Edwards, M. J.; Fittinghoff, D.; Glenn, S.; Haan, S. W.; Hamza, A. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

    2014-09-15T23:59:59.000Z

    Surrogate implosions play an important role at the National Ignition Facility (NIF) for isolating aspects of the complex physical processes associated with fully integrated ignition experiments. The newly developed CD Symcap platform has been designed to study gas-shell mix in indirectly driven, pure T{sub 2}-gas filled CH-shell implosions equipped with 4 ?m thick CD layers. This configuration provides a direct nuclear signature of mix as the DT yield (above a characterized D contamination background) is produced by D from the CD layer in the shell, mixing into the T-gas core. The CD layer can be placed at different locations within the CH shell to probe the depth and extent of mix. CD layers placed flush with the gas-shell interface and recessed up to 8??m have shown that most of the mix occurs at the inner-shell surface. In addition, time-gated x-ray images of the hotspot show large brightly radiating objects traversing through the hotspot around bang-time, which are likely chunks of CH/CD plastic. This platform is a powerful new capability at the NIF for understanding mix, one of the key performance issues for ignition experiments.

  15. Plantwide Energy Assessment of a Sugarcane Farming and Processing Facility

    SciTech Connect (OSTI)

    Jakeway, L.A.; Turn, S.Q.; Keffer, V.I.; Kinoshita, C.M.

    2006-02-27T23:59:59.000Z

    A plantwide energy assessment was performed at Hawaiian Commercial & Sugar Co., an integrated sugarcane farming and processing facility on the island of Maui in the State of Hawaii. There were four main tasks performed for the plantwide energy assessment: 1) pump energy assessment in both field and factory operations, 2) steam generation assessment in the power production operations, 3) steam distribution assessment in the sugar manufacturing operation, and 4) electric power distribution assessment of the company system grid. The energy savings identified in each of these tasks were summarized in terms of fuel savings, electricity savings, or opportunity revenue that potentially exists mostly from increased electric power sales to the local electric utility. The results of this investigation revealed eight energy saving projects that can be implemented at HC&S. These eight projects were determined to have potential for $1.5 million in annual fuel savings or 22,337 MWh equivalent annual electricity savings. Most of the savings were derived from pump efficiency improvements and steam efficiency improvements both in generation and distribution. If all the energy saving projects were implemented and the energy savings were realized as less fuel consumed, there would be corresponding reductions in regulated air pollutants and carbon dioxide emissions from supplemental coal fuel. As HC&S is already a significant user of renewable biomass fuel for its operations, the projected reductions in air pollutants and emissions will not be as great compared to using only coal fuel for example. A classification of implementation priority into operations was performed for the identified energy saving projects based on payback period and ease of implementation.

  16. Capturing Process Knowledge for Facility Deactivation and Decommissioning

    Broader source: Energy.gov [DOE]

    The Office of Environmental Management (EM) is responsible for the disposition of a vast number of facilities at numerous sites around the country which have been declared excess to current mission...

  17. DIGITAL SIGNAL PROCESSING AS A DIAGNOSTIC TOOL FOR GAS

    E-Print Network [OSTI]

    Eagar, Thomas W.

    DIGITAL SIGNAL PROCESSING AS A DIAGNOSTIC TOOL FOR GAS TUNGSTEN ARC WELDING Carl D. Sorensen is the welding arc itself. The sensory information is obtained through digital signal processing of the arc vol- tage and current. Experiments performed to test the suitability of digital signal processing as an arc

  18. Kansas-Kansas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15 0Month Previous YearThousand1 3256,268

  19. Kansas-Oklahoma Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15 0Month Previous YearThousand1

  20. Kansas-Texas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15 0Month Previous YearThousand1142 141 121

  1. Kentucky-Kentucky Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15IndustrialVehicleThousand60,941 67,568

  2. Michigan-Michigan Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19 15 15 15 3YearDecade Year-0per9 2011 2012

  3. Mississippi-Mississippi Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19 15Year JanThousand Cubic0 0 0 2011 2012

  4. Montana-Montana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19343 369 384FuelYear125 137 1861,185 11,206

  5. Montana-Wyoming Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19343 369 384FuelYear125 137 1861,185785 656

  6. Colorado-Colorado Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 4623 42 180 208 283,507,467 1,460,433

  7. Colorado-Kansas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 4623 42 180 208 283,507,467 1,460,43378

  8. Colorado-Utah Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 4623 42 180 208 283,507,467

  9. Florida Natural Gas Processed (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 0 0 1979-2013Fuel2009 2010 2011

  10. Gulf of Mexico Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 058.5 57.1CubicVehicle0perLiquids,2008

  11. Indiana Natural Gas Processed (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15 0 0 0 0WithdrawalsPlantSep-14

  12. Pennsylvania-Pennsylvania Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas,095,3628,527 9,029Cubic(Dollars per Thousand Cubic 0 0Cubic2011

  13. Arkansas-Arkansas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 566 8021 1 2 22008 2009 2010 2011 2011 2012

  14. Overview of Fiscal Year 2002 Research and Development for Savannah River Site's Salt Waste Processing Facility

    SciTech Connect (OSTI)

    H. D. Harmon, R. Leugemors, PNNL; S. Fink, M. Thompson, D. Walker, WSRC; P. Suggs, W. D. Clark, Jr

    2003-02-26T23:59:59.000Z

    The Department of Energy's (DOE) Savannah River Site (SRS) high-level waste program is responsible for storage, treatment, and immobilization of high-level waste for disposal. The Salt Processing Program (SPP) is the salt (soluble) waste treatment portion of the SRS high-level waste effort. The overall SPP encompasses the selection, design, construction and operation of treatment technologies to prepare the salt waste feed material for the site's grout facility (Saltstone) and vitrification facility (Defense Waste Processing Facility). Major constituents that must be removed from the salt waste and sent as feed to Defense Waste Processing Facility include actinides, strontium, cesium, and entrained sludge. In fiscal year 2002 (FY02), research and development (R&D) on the actinide and strontium removal and Caustic-Side Solvent Extraction (CSSX) processes transitioned from technology development for baseline process selection to providing input for conceptual design of the Salt Waste Processing Facility. The SPP R&D focused on advancing the technical maturity, risk reduction, engineering development, and design support for DOE's engineering, procurement, and construction (EPC) contractors for the Salt Waste Processing Facility. Thus, R&D in FY02 addressed the areas of actual waste performance, process chemistry, engineering tests of equipment, and chemical and physical properties relevant to safety. All of the testing, studies, and reports were summarized and provided to the DOE to support the Salt Waste Processing Facility, which began conceptual design in September 2002.

  15. Process for making ceramic hot gas filter

    DOE Patents [OSTI]

    Connolly, Elizabeth Sokolinski (Wilmington, DE); Forsythe, George Daniel (Landenberg, PA); Domanski, Daniel Matthew (New Castle, DE); Chambers, Jeffrey Allen (Hockessin, DE); Rajendran, Govindasamy Paramasivam (Boothwyn, PA)

    2001-01-01T23:59:59.000Z

    A ceramic hot-gas candle filter having a porous support of filament-wound oxide ceramic yarn at least partially surrounded by a porous refractory oxide ceramic matrix, and a membrane layer on at least one surface thereof. The membrane layer may be on the outer surface, the inner surface, or both the outer and inner surface of the porous support. The membrane layer may be formed of an ordered arrangement of circularly wound, continuous filament oxide ceramic yarn, a ceramic filler material which is less permeable than the filament-wound support structure, or some combination of continuous filament and filler material. A particularly effective membrane layer features circularly wound filament with gaps intentionally placed between adjacent windings, and a filler material of ceramic particulates uniformly distributed throughout the gap region. The filter can withstand thermal cycling during backpulse cleaning and is resistant to chemical degradation at high temperatures.

  16. Economic comparison of centralizing or decentralizing processing facilities for defense transuranic waste

    SciTech Connect (OSTI)

    Brown, C M

    1980-07-01T23:59:59.000Z

    This study is part of a set of analyses under direction of the Transuranic Waste Management Program designed to provide comprehensive, systematic methodology and support necessary to better understand options for national long-term management of transuranic (TRU) waste. The report summarizes activities to evaluate the economics of possible alternatives in locating facilities to process DOE-managed transuranic waste. The options considered are: (1) Facilities located at all major DOE TRU waste generating sites. (2) Two or three regional facilities. (3) Central processing facility at only one DOE site. The study concludes that processing at only one facility is the lowest cost option, followed, in order of cost, by regional then individual site processing.

  17. Design and construction of the defense waste processing facility project at the Savannah River Plant

    SciTech Connect (OSTI)

    Baxter, R G

    1986-01-01T23:59:59.000Z

    The Du Pont Company is building for the Department of Energy a facility to vitrify high-level radioactive waste at the Savannah River Plant (SRP) near Aiken, South Carolina. The Defense Waste Processing Facility (DWPF) will solidify existing and future radioactive wastes by immobilizing the waste in Processing Facility (DWPF) will solidify existing and future radioactives wastes by immobilizing the waste in borosilicate glass contained in stainless steel canisters. The canisters will be sealed, decontaminated and stored, prior to emplacement in a federal repository. At the present time, engineering and design is 90% complete, construction is 25% complete, and radioactive processing in the $870 million facility is expected to begin by late 1989. This paper describes the SRP waste characteristics, the DWPF processing, building and equipment features, and construction progress of the facility.

  18. Monte Carlo validation experiments for the gas Cherenkov detectors at the National Ignition Facility and Omega

    SciTech Connect (OSTI)

    Rubery, M. S.; Horsfield, C. J. [Plasma Physics Department, AWE plc, Reading RG7 4PR (United Kingdom)] [Plasma Physics Department, AWE plc, Reading RG7 4PR (United Kingdom); Herrmann, H.; Kim, Y.; Mack, J. M.; Young, C.; Evans, S.; Sedillo, T.; McEvoy, A.; Caldwell, S. E. [Plasma Physics Department, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Plasma Physics Department, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Grafil, E.; Stoeffl, W. [Physics, Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Physics, Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Milnes, J. S. [Photek Limited UK, 26 Castleham Road, St. Leonards-on-sea TN38 9NS (United Kingdom)] [Photek Limited UK, 26 Castleham Road, St. Leonards-on-sea TN38 9NS (United Kingdom)

    2013-07-15T23:59:59.000Z

    The gas Cherenkov detectors at NIF and Omega measure several ICF burn characteristics by detecting multi-MeV nuclear ? emissions from the implosion. Of primary interest are ? bang-time (GBT) and burn width defined as the time between initial laser-plasma interaction and peak in the fusion reaction history and the FWHM of the reaction history respectively. To accurately calculate such parameters the collaboration relies on Monte Carlo codes, such as GEANT4 and ACCEPT, for diagnostic properties that cannot be measured directly. This paper describes a series of experiments performed at the High Intensity ? Source (HI?S) facility at Duke University to validate the geometries and material data used in the Monte Carlo simulations. Results published here show that model-driven parameters such as intensity and temporal response can be used with less than 50% uncertainty for all diagnostics and facilities.

  19. Facility Siting and Layout Optimization Based on Process Safety

    E-Print Network [OSTI]

    Jung, Seungho

    2012-02-14T23:59:59.000Z

    ) that identifies potential layouts by minimizing overall costs. This approach gives the coordinates of each facility in a continuous plane, and estimates for the total length of pipes, the land area, and the selection of safety devices. Finally, the 3D...

  20. TECHNICAL AND OPERATING SUPPORT FOR PILOT DEMONSTRATION OF MORPHYSORB ACID GAS REMOVAL PROCESS

    SciTech Connect (OSTI)

    Nagaraju Palla; Dennis Leppin

    2004-02-01T23:59:59.000Z

    Over the past 14 years, the Gas Technology Institute and jointly with Uhde since 1997 developing Morphysorb{reg_sign} a new physical solvent-based acid gas removal process. Based on extensive laboratory, bench, pilot-plant scale experiments and computer simulations, DEGT Gas Transmission Company, Canada (DEGT) has chosen the process for use at its Kwoen processing facility near Chetwynd, British Columbia, Canada as the first commercial application for the Morphysorb process. DOE co-funded the development of the Morphysorb process in various stages of development. DOE funded the production of this report to ensure that the results of the work would be readily available to potential users of the process in the United States. The Kwoen Plant is designed to process 300 MMscfd of raw natural gas at 1,080-psia pressure. The sour natural gas contains 20 to 25 percent H{sub 2}S and CO{sub 2}. The plant reduces the acid gas content by about 50% and injects the removed H{sub 2}S and CO{sub 2} into an injection well. The Kwoen plant has been operating since August 2002. Morphysorb{reg_sign} is a physical solvent-based process used for the bulk removal of CO{sub 2} and/or H{sub 2}S from natural gas and other gaseous streams. The solvent consists of N-Formyl morpholine and other morpholine derivatives. This process is particularly effective for high-pressure and high acid-gas applications and offers substantial savings in investment and operating cost compared to competitive physical solvent-based processes. GTI and DEGT first entered into an agreement in 2002 to test the Morphysorb process at their Kwoen Gas Treating Plant in northern BC. The process is operating successfully without any solvent related problems and has between DEGTC and GTI. As of December 2003, about 90 Bcf of sour gas was processed. Of this about 8 Bcf of acid gas containing mainly H{sub 2}S and CO{sub 2} was injected back into the depleted reservoir and 82 Bcf sent for further processing at DEGTC's Pine River Plant. This report discusses the operational performance at Kwoen plant during the performance test as well as the solvent performance since the plant started up. The Morphysorb performance is assessed by Duke Energy according to five metrics: acid gas pickup, recycle gas flow, total hydrocarbon loss in acid gas stream, Morphysorb solvent losses and foaming related problems. Plant data over a period of one year show that the Morphysorb solvent has performed extremely well in four out of five of these categories. The fifth metric, Morphysorb solvent loss, is being evaluated over a longer-term period in order to accurately assess it. However, the preliminary indications based on makeup solvent used to date are that solvent losses will also be within expectations. The analysis of the solvent samples indicates that the solvent is very stable and did not show any sign of degradation. The operability of the solvent is good and no foaming related problems have been encountered. According to plant operators the Morphysorb unit runs smoothly and requires no special attention.

  1. Facility design philosophy: Tank Waste Remediation System Process support and infrastructure definition

    SciTech Connect (OSTI)

    Leach, C.E.; Galbraith, J.D. [Westinghouse Hanford Co., Richland, WA (United States); Grant, P.R.; Francuz, D.J.; Schroeder, P.J. [Fluor Daniel, Inc., Richland, WA (United States)

    1995-11-01T23:59:59.000Z

    This report documents the current facility design philosophy for the Tank Waste Remediation System (TWRS) process support and infrastructure definition. The Tank Waste Remediation System Facility Configuration Study (FCS) initially documented the identification and definition of support functions and infrastructure essential to the TWRS processing mission. Since the issuance of the FCS, the Westinghouse Hanford Company (WHC) has proceeded to develop information and requirements essential for the technical definition of the TWRS treatment processing programs.

  2. Overview of the Facility Safeguardability Analysis (FSA) Process

    SciTech Connect (OSTI)

    Bari, Robert A.; Hockert, John; Wonder, Edward F.; Johnson, Scott J.; Wigeland, Roald; Zentner, Michael D.

    2012-08-01T23:59:59.000Z

    Executive Summary The safeguards system of the International Atomic Energy Agency (IAEA) is intended to provide the international community with credible assurance that a State is fulfilling its safeguards obligations. Effective and cost-efficient IAEA safeguards at the facility level are, and will remain, an important element of IAEA safeguards as those safeguards evolve towards a “State-Level approach.” The Safeguards by Design (SBD) concept can facilitate the implementation of these effective and cost-efficient facility-level safeguards (Bjornard, et al. 2009a, 2009b; IAEA, 1998; Wonder & Hockert, 2011). This report, sponsored by the National Nuclear Security Administration’s Office of Nuclear Safeguards and Security, introduces a methodology intended to ensure that the diverse approaches to Safeguards by Design can be effectively integrated and consistently used to cost effectively enhance the application of international safeguards.

  3. Tennessee Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear Jan FebThousandProcessed (Million Cubic Feet) Tennessee Natural

  4. Texas Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear JanSeparation, Proved ReservesReservesGrossElements)Processed

  5. Alabama Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear Jan Feb Mar Apr MayProcessed (Million

  6. California Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYearReservesmDecadeDecadeResidentialProcessed

  7. Nebraska Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet) Year Jan Feb Marthrough Monthly2.FuelFuelProcessed (Million Cubic

  8. Process and apparatus for ammonia synthesis gas production

    SciTech Connect (OSTI)

    Fuderer, A.

    1986-06-03T23:59:59.000Z

    An improved process is described for the production of ammonia synthesis gas which consists of: (a) catalytically reacting a hydrocarbon feed stream with steam in a primary reforming unit to form a primary reformed gas mixture containing hydrogen and carbon monoxide; (b) passing the primary reformed gas mixture to a secondary reforming unit for reaction of unconverted methane present therein with air, the amount of the air introduced to the secondary reforming unit being considerably in excess of that required to furnish the stoichiometric amount of nitrogen required for reaction with hydrogen for the ammonia synthesis; (c) subjecting the secondary reformed gas mixture to water gas shift conversion to convert most of the carbon monoxide present in the reformed gas mixture to hydrogen and carbon dioxide; (d) passing the thus-shifted gas mixture containing hydrogen, carbon dioxide, residual carbon monoxide, methane, argon and the excess nitrogen, without necessary treatment for removal of a major portion of the carbon dioxide content thereof and without methanation to remove carbon oxides to low levels, to a pressure swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from the hydrogen and from a portion of the nitrogen present in the gas passed to the system.

  9. Standard practice for dosimetry in electron beam and X-Ray (Bremsstrahlung) irradiation facilities for food processing

    E-Print Network [OSTI]

    International Organization for Standardization. Geneva

    2005-01-01T23:59:59.000Z

    Standard practice for dosimetry in electron beam and X-Ray (Bremsstrahlung) irradiation facilities for food processing

  10. Surface water transport and distribution of uranium in contaminated sediments near a nuclear weapons processing facility

    E-Print Network [OSTI]

    Batson, Vicky Lynn

    1994-01-01T23:59:59.000Z

    The extent of remobilization of uranium from contaminated soils adjacent to a nuclear weapons processing facility during episodic rain events was investigated. In addition, information on the solid phase associations of U in floodplain and suspended...

  11. Criticality Safety Evaluation Report for the Cold Vacuum Drying (CVD) Facilities Process Water Handling System

    SciTech Connect (OSTI)

    KESSLER, S.F.

    2000-08-10T23:59:59.000Z

    This report addresses the criticality concerns associated with process water handling in the Cold Vacuum Drying Facility. The controls and limitations on equipment design and operations to control potential criticality occurrences are identified.

  12. Characterization of decontamination and decommissioning wastes expected from the major processing facilities in the 200 Areas

    SciTech Connect (OSTI)

    Amato, L.C.; Franklin, J.D.; Hyre, R.A.; Lowy, R.M.; Millar, J.S.; Pottmeyer, J.A. [Los Alamos Technical Associates, Kennewick, WA (United States); Duncan, D.R. [Westinghouse Hanford Co., Richland, WA (United States)

    1994-08-01T23:59:59.000Z

    This study was intended to characterize and estimate the amounts of equipment and other materials that are candidates for removal and subsequent processing in a solid waste facility when the major processing and handling facilities in the 200 Areas of the Hanford Site are decontaminated and decommissioned. The facilities in this study were selected based on processing history and on the magnitude of the estimated decommissioning cost cited in the Surplus Facilities Program Plan; Fiscal Year 1993 (Winship and Hughes 1992). The facilities chosen for this study include B Plant (221-B), T Plant (221-T), U Plant (221-U), the Uranium Trioxide (UO{sub 3}) Plant (224-U and 224-UA), the Reduction Oxidation (REDOX) or S Plant (202-S), the Plutonium Concentration Facility for B Plant (224-B), and the Concentration Facility for the Plutonium Finishing Plant (PFP) and REDOX (233-S). This information is required to support planning activities for current and future solid waste treatment, storage, and disposal operations and facilities.

  13. Safeguards assessment of gamma-ray detection for process monitoring at natural uranium conversion facilities.

    E-Print Network [OSTI]

    Dewji, Shaheen Azim

    2014-01-01T23:59:59.000Z

    ??Conversion, the process by which natural uranium ore (yellowcake) is puri?ed and converted through a series of chemical processes into uranium hexa?uoride gas (UF6), has… (more)

  14. Plutonium production story at the Hanford site: processes and facilities history

    SciTech Connect (OSTI)

    Gerber, M.S., Westinghouse Hanford

    1996-06-20T23:59:59.000Z

    This document tells the history of the actual plutonium production process at the Hanford Site. It contains five major sections: Fuel Fabrication Processes, Irradiation of Nuclear Fuel, Spent Fuel Handling, Radiochemical Reprocessing of Irradiated Fuel, and Plutonium Finishing Operations. Within each section the story of the earliest operations is told, along with changes over time until the end of operations. Chemical and physical processes are described, along with the facilities where these processes were carried out. This document is a processes and facilities history. It does not deal with the waste products of plutonium production.

  15. Proceedings of the 1st Annual Gas Processing Symposium

    E-Print Network [OSTI]

    Skogestad, Sigurd

    energy calculations for directly coupled arrangements. Here we give a brief review of the most importantProceedings of the 1st Annual Gas Processing Symposium H. Alfadala, G.V. Rex Reklaitis and M.M. El-Halwagi (Editors) © 2009 Elsevier B.V. All rights reserved. Minimum Energy Operation of Petlyuk Distillation

  16. Progress of the High Level Waste Program at the Defense Waste Processing Facility - 13178

    SciTech Connect (OSTI)

    Bricker, Jonathan M.; Fellinger, Terri L.; Staub, Aaron V.; Ray, Jeff W.; Iaukea, John F. [Savannah River Remediation, Aiken, South Carolina, 29808 (United States)] [Savannah River Remediation, Aiken, South Carolina, 29808 (United States)

    2013-07-01T23:59:59.000Z

    The Defense Waste Processing Facility at the Savannah River Site treats and immobilizes High Level Waste into a durable borosilicate glass for safe, permanent storage. The High Level Waste program significantly reduces environmental risks associated with the storage of radioactive waste from legacy efforts to separate fissionable nuclear material from irradiated targets and fuels. In an effort to support the disposition of radioactive waste and accelerate tank closure at the Savannah River Site, the Defense Waste Processing Facility recently implemented facility and flowsheet modifications to improve production by 25%. These improvements, while low in cost, translated to record facility production in fiscal years 2011 and 2012. In addition, significant progress has been accomplished on longer term projects aimed at simplifying and expanding the flexibility of the existing flowsheet in order to accommodate future processing needs and goals. (authors)

  17. The Uranium Processing Facility Finite Element Meshing Discussion

    Office of Environmental Management (EM)

    * Discuss the mesh criteria * Discuss the evolution of the mesh of the UPF main building model * Discuss how the mesh affects the analysis process October 25, 2011 2 Department of...

  18. Probabilistic Risk Based Decision Support for Oil and Gas Exploration and Production Facilities in Sensitive Ecosystems

    SciTech Connect (OSTI)

    Greg Thoma; John Veil; Fred Limp; Jackson Cothren; Bruce Gorham; Malcolm Williamson; Peter Smith; Bob Sullivan

    2009-05-31T23:59:59.000Z

    This report describes work performed during the initial period of the project 'Probabilistic Risk Based Decision Support for Oil and Gas Exploration and Production Facilities in Sensitive Ecosystems.' The specific region that is within the scope of this study is the Fayetteville Shale Play. This is an unconventional, tight formation, natural gas play that currently has approximately 1.5 million acres under lease, primarily to Southwestern Energy Incorporated and Chesapeake Energy Incorporated. The currently active play encompasses a region from approximately Fort Smith, AR east to Little Rock, AR approximately 50 miles wide (from North to South). The initial estimates for this field put it almost on par with the Barnett Shale play in Texas. It is anticipated that thousands of wells will be drilled during the next several years; this will entail installation of massive support infrastructure of roads and pipelines, as well as drilling fluid disposal pits and infrastructure to handle millions of gallons of fracturing fluids. This project focuses on gas production in Arkansas as the test bed for application of proactive risk management decision support system for natural gas exploration and production. The activities covered in this report include meetings with representative stakeholders, development of initial content and design for an educational web site, and development and preliminary testing of an interactive mapping utility designed to provide users with information that will allow avoidance of sensitive areas during the development of the Fayetteville Shale Play. These tools have been presented to both regulatory and industrial stakeholder groups, and their feedback has been incorporated into the project.

  19. Shale Gas Production Theory and Case Analysis We researched the process of oil recovery and shale gas

    E-Print Network [OSTI]

    Ge, Zigang

    Shale Gas Production Theory and Case Analysis (Siemens) We researched the process of oil recovery and shale gas recovery and compare the difference between conventional and unconventional gas reservoir and recovery technologies. Then we did theoretical analysis on the shale gas production. According

  20. Certification of U.S. instrumentation in Russian nuclear processing facilities

    SciTech Connect (OSTI)

    D.H. Powell; J.N. Sumner

    2000-07-12T23:59:59.000Z

    Agreements between the United States (U.S.) and the Russian Federation (R.F.) require the down-blending of highly enriched uranium (HEU) from dismantled Russian Federation nuclear weapons. The Blend Down Monitoring System (BDMS) was jointly developed by the Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) to continuously monitor the enrichments and flow rates in the HEU blending operations at the R.F. facilities. A significant requirement of the implementation of the BDMS equipment in R.F. facilities concerned the certification of the BDMS equipment for use in a Russian nuclear facility. This paper discusses the certification of the BDMS for installation in R.F. facilities, and summarizes the lessons learned from the process that can be applied to the installation of other U.S. equipment in Russian nuclear facilities.

  1. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  2. Development of submicron particle size classification and collection techniques for nuclear facility off-gas streams. [Diffusion battery and electrofluidized bed

    SciTech Connect (OSTI)

    Hohorst, F.A.; Fernandez, S.J.

    1981-02-01T23:59:59.000Z

    High efficiency particulate air (HEPA) filters are an essential part of nuclear facility off-gas cleanup systems. However, HEPA-rated sampling filters are not the most appropriate samplers for the particle penetrating off-gas cleanup systems. Previous work at the Idaho Chemical Processing Plant (ICPP) estimated perhaps 5% of the radioactivity that challenged sampling filters penetrated them in the form of submicron particles - typically less than 0.2 microns. Accordingly, to evaluate these penetrating aerosols more fully, a suitable robust monitoring system for size differentiation and measurement of submicron particles was developed. A literature survey revealed that the diffusion battery was the best choice for particle size classification and that the electrofluidized bed was the best method for particle collection in ICPP off-gas streams. This report describes the laboratory study and in-plant demonstration of these two techniques.

  3. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01T23:59:59.000Z

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  4. Design of a Gas Test Loop Facility for the Advanced Test Reactor

    SciTech Connect (OSTI)

    C. A. Wemple

    2005-09-01T23:59:59.000Z

    The Office of Nuclear Energy within the U.S. Department of Energy (DOE-NE) has identified the need for irradiation testing of nuclear fuels and materials, primarily in support of the Generation IV (Gen-IV) and Advanced Fuel Cycle Initiative (AFCI) programs. These fuel development programs require a unique environment to test and qualify potential reactor fuel forms. This environment should combine a high fast neutron flux with a hard neutron spectrum and high irradiation temperature. An effort is presently underway at the Idaho National Laboratory (INL) to modify a large flux trap in the Advanced Test Reactor (ATR) to accommodate such a test facility [1,2]. The Gas Test Loop (GTL) Project Conceptual Design was initiated to determine basic feasibility of designing, constructing, and installing in a host irradiation facility, an experimental vehicle that can replicate with reasonable fidelity the fast-flux test environment needed for fuels and materials irradiation testing for advanced reactor concepts. Such a capability will be needed if programs such as the AFCI, Gen-IV, the Next Generation Nuclear Plant (NGNP), and space nuclear propulsion are to meet development objectives and schedules. These programs are beginning some irradiations now, but many call for fast flux testing within this decade.

  5. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect (OSTI)

    Girish Srinivas; Steven C. Gebhard; David W. DeBerry

    2002-07-01T23:59:59.000Z

    This second quarter report of 2002 describes progress on a project funded by the U.S. Department of Energy (DOE) to test a hybrid sulfur recovery process for natural gas upgrading. The process concept represents a low cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day. This process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both on-shore and offshore applications. CrystaSulf (service mark of CrystaTech, Inc.) is a new nonaqueous sulfur recovery process that removes hydrogen sulfide (H{sub 2}S) from gas streams and converts it into elemental sulfur. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, approximately 1/3 of the total H{sub 2}S in the natural gas is first oxidized to SO{sub 2} at low temperatures over a heterogeneous catalyst. Low temperature oxidation is done so that the H{sub 2}S can be oxidized in the presence of methane and other hydrocarbons without oxidation of the hydrocarbons. The project involves the development of a catalyst using laboratory/bench-scale catalyst testing, and then demonstration of the catalyst at CrystaTech's pilot plant in west Texas. Previous reports described development of a catalyst with the required selectivity and efficiency for producing sulfur dioxide from H{sub 2}S. In the laboratory, the catalyst was shown to be robust and stable in the presence of several intentionally added contaminants, including condensate from the pilot plant site. This report describes testing using the laboratory apparatus but operated at the pilot plant using the actual pilot plant gas, which contains far more contaminants than can be simulated in the laboratory. The results are very encouraging, with stable and efficient operation being obtained for a prolonged period of time.

  6. Waste Receiving and Processing Facility Module 2A: Advanced Conceptual Design Report. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1994-03-01T23:59:59.000Z

    This ACDR was performed following completed of the Conceptual Design Report in July 1992; the work encompassed August 1992 to January 1994. Mission of the WRAP Module 2A facility is to receive, process, package, certify, and ship for permanent burial at the Hanford site disposal facilities the Category 1 and 3 contact handled low-level radioactive mixed wastes that are currently in retrievable storage at Hanford and are forecast to be generated over the next 30 years by Hanford, and waste to be shipped to Hanford from about DOE sites. This volume provides an introduction to the ACDR process and the scope of the task along with a project summary of the facility, treatment technologies, cost, and schedule. Major areas of departure from the CDR are highlighted. Descriptions of the facility layout and operations are included.

  7. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S. (Hopewell Junction, NY); Corbeels, Roger J. (Wappingers Falls, NY); Kokturk, Uygur (Wappingers Falls, NY)

    1989-01-01T23:59:59.000Z

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  8. Design of the Waste Receiving and Processing Module 2A Facility

    SciTech Connect (OSTI)

    Lamberd, D.L.

    1993-03-01T23:59:59.000Z

    Westinghouse Hanford Company has determined that a facility is required for the treatment of mixed low-level waste at the Hanford Site. The mission of that facility will be to receive, process/treat, package, certify, and ship the contact-handled, mixed low-level waste that must be handled by Hanford Site to permanent disposal. Preconceptual and conceptual design studies were performed by United Engineers and Constructors, and a conceptual design report was issued. This report presents a summary of the conceptual design for a facility that will meet the mission established.

  9. Preliminary technical data summary No. 3 for the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Landon, L.F. (comp.)

    1980-05-01T23:59:59.000Z

    This document presents an update on the best information presently available for the purpose of establishing the basis for the design of a Defense Waste Processing Facility. Objective of this project is to provide a facility to fix the radionuclides present in Savannah River Plant (SRP) high-level liquid waste in a high-integrity form (glass). Flowsheets and material balances reflect the alternate CAB case including the incorporation of low-level supernate in concrete. (DLC)

  10. Method for treating a nuclear process off-gas stream

    DOE Patents [OSTI]

    Pence, Dallas T. (San Diego, CA); Chou, Chun-Chao (San Diego, CA)

    1984-01-01T23:59:59.000Z

    Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

  11. 324 Facility B-Cell quality process plan

    SciTech Connect (OSTI)

    Carlson, J.L.

    1998-06-10T23:59:59.000Z

    B-Cell is currently being cleaned out (i.e., removal of equipment, fixtures and residual radioactive materials) and deactivated. TPA Milestone M-89-02 dictates that all mixed waste and equipment be removed from B-Cell by 5/31/99. The following sections describe the major activities that remain for completion of the TPA milestone. This includes: (1) Size Reduce Tank 119 and Miscellaneous Equipment. This activity is the restart of hotwork in B-Cell to size reduce the remainder of Tank 119 and other miscellaneous pieces of equipment into sizes that can be loaded into a grout container. This activity also includes the process of preparing the containers for shipment from the cell. The specific activities and procedures used are detailed in a table. (2) Load and Ship Low-Level Waste. This activity covers the process of taking a grouted LLW container from B-Cell and loading it into the cask in the REC airlock and Cask Handling Area (CHA) for shipment to the LLBG. The detailed activities and procedures for this part of cell cleanout are included in second table.

  12. Market Opportunities for Electric Drive Compressors for Gas Transmission, Storage, and Processing

    E-Print Network [OSTI]

    Parent, L. V.; Ralph, H. D.; Schmeal, W. R.

    There is great interest in the large potential market for electric drives in the gas transmission, gas storage, and gas processing industries. Progressive electric utilities and astute vendors are moving to meet the needs of these industries...

  13. Waste Receiving and Processing (WRAP) Facility Final Safety Analysis Report (FSAR)

    SciTech Connect (OSTI)

    TOMASZEWSKI, T.A.

    2000-04-25T23:59:59.000Z

    The Waste Receiving and Processing Facility (WRAP), 2336W Building, on the Hanford Site is designed to receive, confirm, repackage, certify, treat, store, and ship contact-handled transuranic and low-level radioactive waste from past and present U.S. Department of Energy activities. The WRAP facility is comprised of three buildings: 2336W, the main processing facility (also referred to generically as WRAP); 2740W, an administrative support building; and 2620W, a maintenance support building. The support buildings are subject to the normal hazards associated with industrial buildings (no radiological materials are handled) and are not part of this analysis except as they are impacted by operations in the processing building, 2336W. WRAP is designed to provide safer, more efficient methods of handling the waste than currently exist on the Hanford Site and contributes to the achievement of as low as reasonably achievable goals for Hanford Site waste management.

  14. HYBRID SULFUR RECOVERY PROCESS FOR NATURAL GAS UPGRADING

    SciTech Connect (OSTI)

    Dennis Dalrymple

    2004-06-01T23:59:59.000Z

    This final report describes the objectives, technical approach, results and conclusions for a project funded by the U.S. Department of Energy to test a hybrid sulfur recovery process for natural gas upgrading. The process concept is a configuration of CrystaTech, Inc.'s CrystaSulf{reg_sign} process which utilizes a direct oxidation catalyst upstream of the absorber tower to oxidize a portion of the inlet hydrogen sulfide (H{sub 2}S) to sulfur dioxide (SO{sub 2}) and elemental sulfur. This hybrid configuration of CrystaSulf has been named CrystaSulf-DO and represents a low-cost option for direct treatment of natural gas streams to remove H{sub 2}S in quantities equivalent to 0.2-25 metric tons (LT) of sulfur per day and more. This hybrid process is projected to have lower capital and operating costs than the competing technologies, amine/aqueous iron liquid redox and amine/Claus/tail gas treating, and have a smaller plant footprint, making it well suited to both onshore and offshore applications. CrystaSulf is a nonaqueous sulfur recovery process that removes H{sub 2}S from gas streams and converts it to elemental sulfur. In CrystaSulf, H{sub 2}S in the inlet gas is reacted with SO{sub 2} to make elemental sulfur according to the liquid phase Claus reaction: 2H{sub 2}S + SO{sub 2} {yields} 2H{sub 2}O + 3S. The SO{sub 2} for the reaction can be supplied from external sources by purchasing liquid SO{sub 2} and injecting it into the CrystaSulf solution, or produced internally by converting a portion of the inlet gas H{sub 2}S to SO{sub 2} or by burning a portion of the sulfur produced to make SO{sub 2}. CrystaSulf features high sulfur recovery similar to aqueous-iron liquid redox sulfur recovery processes, but differs from the aqueous processes in that CrystaSulf controls the location where elemental sulfur particles are formed. In the hybrid process, the needed SO{sub 2} is produced by placing a bed of direct oxidation catalyst in the inlet gas stream to oxidize a portion of the inlet H{sub 2}S. Oxidation catalysts may also produce some elemental sulfur under these conditions, which can be removed and recovered prior to the CrystaSulf absorber. The CrystaSulf-DO process can utilize direct oxidation catalyst from many sources. Numerous direct oxidation catalysts are available from many suppliers worldwide. They have been used for H{sub 2}S oxidation to sulfur and/or SO{sub 2} for decades. It was believed at the outset of the project that TDA Research, Inc., a subcontractor, could develop a direct oxidation catalyst that would offer advantages over other commercially available catalysts for this CrystaSulf-DO process application. This project involved the development of several of TDA's candidate proprietary direct oxidation catalysts through laboratory bench-scale testing. These catalysts were shown to be effective for conversion of H{sub 2}S to SO{sub 2} and to elemental sulfur under certain operating conditions. One of these catalysts was subsequently tested on a commercial gas stream in a bench-scale reactor at CrystaTech's pilot plant site in west Texas with good results. However, commercial developments have precluded the use of TDA catalysts in the CrystaSulf-DO process. Nonetheless, this project has advanced direct oxidation catalyst technology for H{sub 2}S control in energy industries and led to several viable paths to commercialization. TDA is commercializing the use of its direct oxidation catalyst technology in conjunction with the SulfaTreat{reg_sign} solid scavenger for natural gas applications and in conjunction with ConocoPhillips and DOE for gasification applications using ConocoPhillips gasification technology. CrystaTech is commercializing its CrystaSulf-DO process in conjunction with Gas Technology Institute for natural gas applications (using direct oxidation catalysts from other commercial sources) and in conjunction with ChevronTexaco and DOE for gasification applications using ChevronTexaco's gasification technology.

  15. Waste Receiving and Processing Facility Module 2A: Advanced Conceptual Design Report. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1994-03-01T23:59:59.000Z

    This volume presents the Total Estimated Cost (TEC) for the WRAP (Waste Receiving and Processing) 2A facility. The TEC is $81.9 million, including an overall project contingency of 25% and escalation of 13%, based on a 1997 construction midpoint. (The mission of WRAP 2A is to receive, process, package, certify, and ship for permanent burial at the Hanford site disposal facilities the Category 1 and 3 contact handled low-level radioactive mixed wastes that are currently in retrievable storage, and are forecast to be generated over the next 30 years by Hanford, and waste to be shipped to Hanford site from about 20 DOE sites.)

  16. Trial Application of the Facility Safeguardability Assessment Process to the NuScale SMR Design

    SciTech Connect (OSTI)

    Coles, Garill A.; Gitau, Ernest TN; Hockert, John; Zentner, Michael D.

    2012-11-09T23:59:59.000Z

    FSA is a screening process intended to focus a facility designer’s attention on the aspects of their facility or process design that would most benefit from application of SBD principles and practices. The process is meant to identify the most relevant guidance within the SBD tools for enhancing the safeguardability of the design. In fiscal year (FY) 2012, NNSA sponsored PNNL to evaluate the practical application of FSA by applying it to the NuScale small modular nuclear power plant. This report documents the application of the FSA process, presenting conclusions regarding its efficiency and robustness. It describes the NuScale safeguards design concept and presents functional "infrastructure" guidelines that were developed using the FSA process.

  17. Trial Application of the Facility Safeguardability Assessment Process to the NuScale SMR Design

    SciTech Connect (OSTI)

    Coles, Garill A.; Hockert, John; Gitau, Ernest TN; Zentner, Michael D.

    2013-01-26T23:59:59.000Z

    FSA is a screening process intended to focus a facility designer’s attention on the aspects of their facility or process design that would most benefit from application of SBD principles and practices. The process is meant to identify the most relevant guidance within the SBD tools for enhancing the safeguardability of the design. In fiscal year (FY) 2012, NNSA sponsored PNNL to evaluate the practical application of FSA by applying it to the NuScale small modular nuclear power plant. This report documents the application of the FSA process, presenting conclusions regarding its efficiency and robustness. It describes the NuScale safeguards design concept and presents functional "infrastructure" guidelines that were developed using the FSA process.

  18. A New Concept: Use of Negotiations in the Hazardous Waste Facility Permitting Process in New Mexico

    SciTech Connect (OSTI)

    Johnson, G.J. [Washington TRU Solutions, LLC, Waste Isolation Pilot Plant, New Mexico (United States); Rose, W.M. [U.S. Department of Energy, Carlsbad Field Office, Waste Isolation Pilot Plant, New Mexico (United States); Domenici, P.V.; Hollingsworth, L. [Domenici Law Firm PC, Albuquerque, New Mexico (United States)

    2007-07-01T23:59:59.000Z

    This paper describes a unique negotiation process leading to authorization of the U.S. Department of Energy (DOE) to manage and dispose remote-handled (RH) transuranic (TRU) mixed wastes at the Waste Isolation Pilot Plant (WIPP). The negotiation process involved multiple entities and individuals brought together under authority of the New Mexico Environment Department (NMED) to discuss and resolve technical and facility operational issues flowing from an NMED-issued hazardous waste facility Draft Permit. The novel negotiation process resulted in numerous substantive changes to the Draft Permit, which were ultimately memorialised in a 'Draft Permit as Changed'. This paper discusses various aspects of the negotiation process, including events leading to the negotiations, regulatory basis for the negotiations, negotiation participants, and benefits of the process. (authors)

  19. Standard Guide for Absorbed-Dose Mapping in Radiation Processing Facilities

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2003-01-01T23:59:59.000Z

    1.1 This document provides guidance in determining absorbed-dose distributions in products, materials or substances irradiated in gamma, X-ray (bremsstrahlung) and electron beam facilities. Note 1—For irradiation of food and the radiation sterilization of health care products, other specific ISO and ISO/ASTM standards containing dose mapping requirements exist. For food irradiation, see ISO/ASTM 51204, Practice for Dosimetry in Gamma Irradiation Facilities for Food Processing and ISO/ASTM 51431, Practice for Dosimetry in Electron and Bremsstrahlung Irradiation Facilities for Food Processing. For the radiation sterilization of health care products, see ISO 11137: 1995, Sterilization of Health Care Products Requirements for Validation and Routine Control Radiation Sterilization. In those areas covered by ISO 11137, that standard takes precedence. ISO/ASTM Practice 51608, ISO/ASTM Practice 51649, and ISO/ASTM Practice 51702 also contain dose mapping requirements. 1.2 Methods of analyzing the dose map data ar...

  20. Spent nuclear fuel project cold vacuum drying facility process water conditioning system design description

    SciTech Connect (OSTI)

    IRWIN, J.J.

    1998-11-30T23:59:59.000Z

    This document provides the System Design Description (SDD) for the Cold Vacuum Drying Facility (CVDF) Process Water Conditioning (PWC) System. The SDD was developed in conjunction with HNF-SD-SNF-SAR-002, Safety Analysis Report for the Cold Vacuum Drying Facility, Phase 2, Supporting Installation of Processing Systems (Garvin 1998), the HNF-SD-SNF-DRD-O02, 1998, Cold Vacuum Drying Facility Design Requirements, and the CVDF Design Summary Report. The SDD contains general descriptions of the PWC equipment, the system functions, requirements and interfaces. The SDD provides references for design and fabrication details, operation sequences and maintenance. This SDD has been developed for the SNFP Operations Organization and shall be updated, expanded, and revised in accordance with future design, construction and startup phases of the CVDF until the CVDF final ORR is approved.

  1. Coarse-scale Modeling of Flow in Gas-injection Processes for Enhanced Oil Recovery

    E-Print Network [OSTI]

    Lambers, James

    Coarse-scale Modeling of Flow in Gas-injection Processes for Enhanced Oil Recovery James V. Lambers of gas-injection processes for enhanced oil recovery may exhibit geometrically complex features

  2. Strategies for Facilities Renewal

    E-Print Network [OSTI]

    Good, R. L.

    of steam production is from exothermic chem ical processes. A large gas fired cogeneration unit was completed in 1987 and supplies 90% of the facil ities' electrical needs and 25% of total steam demand (the remaining steam is supplied by process heat...

  3. A facile process for soak-and-peel delamination of CVD graphene from substrates using water

    E-Print Network [OSTI]

    Deshmukh, Mandar M.

    A facile process for soak-and-peel delamination of CVD graphene from substrates using water Priti Ulm, Germany (Dated: 31 July 2013) We demonstrate a simple technique to transfer CVD-grown graphene deionized water. The lack of chemical etchants results in cleaner CVD graphene films minimizing

  4. Supporting Information: A facile process for soak-and-peel delamination of CVD graphene from

    E-Print Network [OSTI]

    Deshmukh, Mandar M.

    Supporting Information: A facile process for soak-and-peel delamination of CVD graphene from equally to this work. 1 #12;I. CVD growth of graphene (a) Continuous graphene layer growth Continuous lms of CVD graphene were grown on 1 cm × 1 cm sized Cu and Pt substrates. Cu foils (Alfa Aesar, 25 µm thick

  5. Dry flue gas desulfurization process for various coals

    SciTech Connect (OSTI)

    Widico, M.J.; Dhargalkar, P.H.

    1985-01-01T23:59:59.000Z

    Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coal-fired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone. Calcium-based wet systems have, in general, satisfied SO/sub 2/ removal requirements; however, reliability of the early systems was affected by some operational problems. Additionally, sludge dewatering and disposal equipment results in overall system complexity. A dry FGD process which minimizes these problems was developed in late 1970's. It incorporates a spray drying concept for removal of SO/sub 2/ by reaction with lime slurry or soda ash solution. The spray dryer absorber is followed by an electrostatic precipitator or a fabric filter where particulates are collected. The waste product, which is a mixture of FGD reaction products, unreacted reagent and fly ash, is dry thus eliminating the need for dewatering equipment.

  6. Final Report - "Foaming and Antifoaming and Gas Entrainment in Radioactive Waste Pretreatment and Immobilization Processes"

    SciTech Connect (OSTI)

    Wasan, Darsh T.

    2007-10-09T23:59:59.000Z

    The Savannah River Site (SRS) and Hanford site are in the process of stabilizing millions of gallons of radioactive waste slurries remaining from production of nuclear materials for the Department of Energy (DOE). The Defense Waste Processing Facility (DWPF) at SRS is currently vitrifying the waste in borosilicate glass, while the facilities at the Hanford site are in the construction phase. Both processes utilize slurry-fed joule-heated melters to vitrify the waste slurries. The DWPF has experienced difficulty during operations. The cause of the operational problems has been attributed to foaming, gas entrainment and the rheological properties of the process slurries. The rheological properties of the waste slurries limit the total solids content that can be processed by the remote equipment during the pretreatment and meter feed processes. Highly viscous material can lead to air entrainment during agitation and difficulties with pump operations. Excessive foaming in waste evaporators can cause carryover of radionuclides and non-radioactive waste to the condensate system. Experimental and theoretical investigations of the surface phenomena, suspension rheology and bubble generation of interactions that lead to foaming and air entrainment problems in the DOE High Level and Low Activity Radioactive Waste separation and immobilization processes were pursued under this project. The first major task accomplished in the grant proposal involved development of a theoretical model of the phenomenon of foaming in a three-phase gas-liquid-solid slurry system. This work was presented in a recently completed Ph.D. thesis (9). The second major task involved the investigation of the inter-particle interaction and microstructure formation in a model slurry by the batch sedimentation method. Both experiments and modeling studies were carried out. The results were presented in a recently completed Ph.D. thesis. The third task involved the use of laser confocal microscopy to study the effectiveness of three slurry rheology modifiers. An effective modifier was identified which resulted in lowering the yield stress of the waste simulant. Therefore, the results of this research have led to the basic understanding of the foaming/antifoaming mechanism in waste slurries as well as identification of a rheology modifier, which enhances the processing throughput, and accelerates the DOE mission. The objectives of this research effort were to develop a fundamental understanding of the physico-chemical mechanisms that produced foaming and air entrainment in the DOE High Level (HLW) and Low Activity (LAW) radioactive waste separation and immobilization processes, and to develop and test advanced antifoam/defoaming/rheology modifier agents. Antifoams/rheology modifiers developed from this research ere tested using non-radioactive simulants of the radioactive wastes obtained from Hanford and the Savannah River Site (SRS).

  7. Safeguards design strategies: designing and constructing new uranium and plutonium processing facilities in the United States

    SciTech Connect (OSTI)

    Scherer, Carolynn P [Los Alamos National Laboratory; Long, Jon D [Los Alamos National Laboratory

    2010-09-28T23:59:59.000Z

    In the United States, the Department of Energy (DOE) is transforming its outdated and oversized complex of aging nuclear material facilities into a smaller, safer, and more secure National Security Enterprise (NSE). Environmental concerns, worker health and safety risks, material security, reducing the role of nuclear weapons in our national security strategy while maintaining the capability for an effective nuclear deterrence by the United States, are influencing this transformation. As part of the nation's Uranium Center of Excellence (UCE), the Uranium Processing Facility (UPF) at the Y-12 National Security Complex in Oak Ridge, Tennessee, will advance the U.S.'s capability to meet all concerns when processing uranium and is located adjacent to the Highly Enriched Uranium Materials Facility (HEUMF), designed for consolidated storage of enriched uranium. The HEUMF became operational in March 2010, and the UPF is currently entering its final design phase. The designs of both facilities are for meeting anticipated security challenges for the 21st century. For plutonium research, development, and manufacturing, the Chemistry and Metallurgy Research Replacement (CMRR) building at the Los Alamos National Laboratory (LANL) in Los Alamos, New Mexico is now under construction. The first phase of the CMRR Project is the design and construction of a Radiological Laboratory/Utility/Office Building. The second phase consists of the design and construction of the Nuclear Facility (NF). The National Nuclear Security Administration (NNSA) selected these two sites as part of the national plan to consolidate nuclear materials, provide for nuclear deterrence, and nonproliferation mission requirements. This work examines these two projects independent approaches to design requirements, and objectives for safeguards, security, and safety (3S) systems as well as the subsequent construction of these modern processing facilities. Emphasis is on the use of Safeguards-by-Design (SBD), incorporating Systems Engineering (SE) principles for these two projects.

  8. Compilation and Presentation of Existing Data on Oil and Gas Leasing Development in a Manner Useful to the NEPA Process

    SciTech Connect (OSTI)

    Amy Childers; Dave Cornue

    2008-11-30T23:59:59.000Z

    In recognition of our nation's increasing energy needs, the George W. Bush Administration's National Energy Policy Development Group report (May 2001) suggested that one way to increase domestic on-shore production of oil and gas is to increase access to undiscovered resources on federal lands. Also recognized is the need to protect and conserve natural resources, which often are located on and around federal lands. The National Environmental Policy Act (NEPA) was designed to create and maintain conditions under which man and nature can exist in productive harmony. NEPA requires that federal agencies prepare an environmental impact statement (EIS) prior to the approval of any development activities. The NEPA scope is broad, with the process applicable to many situations from the building of highways, barge facilities and water outtake facilities, bridges, and watersheds to other less significant projects. The process often involves cooperation among multiple federal agencies, industry, scientists and consultants, and the surrounding community. The objective of the project, titled Compilation and Presentation of Existing Data on Oil and Gas Leasing and Development in a Manner Useful to the NEPA Process, is to facilitate faster and more comprehensive access to current oil and gas data by land management agencies and operators. This will enable key stakeholders in the NEPA process to make decisions that support access to federal resources while at the same time achieving a legitimate balance between environmental protection and appropriate levels of development.

  9. Processing liquid radioactive waste by centrifuge and indrum dehydration facility at NPP Philippsburg

    SciTech Connect (OSTI)

    Grundke, E.; Blaser, W. [NPP Philippsburg (Germany)

    1993-12-31T23:59:59.000Z

    Until 1989 the evaporator and filter concentrates have been treated by concreting. The centrifuge facility is used for the liquid waste from laundry, showers and also for processing filter concentrates and evaporator feedwater. The hot high pressure compacting of filter concentrates gives a volume reduction by a factor of 6. The evaporator concentrate is drained in a 200 l drum and this drum is heated by an external heating device. The indrum-dehydration facility reduces the treated volume by a factor of 12 compared with the former cementation.

  10. Surfactant process for promoting gas hydrate formation and application of the same

    DOE Patents [OSTI]

    Rogers, Rudy E. (Starkville, MS); Zhong, Yu (Brandon, MS)

    2002-01-01T23:59:59.000Z

    This invention relates to a method of storing gas using gas hydrates comprising forming gas hydrates in the presence of a water-surfactant solution that comprises water and surfactant. The addition of minor amounts of surfactant increases the gas hydrate formation rate, increases packing density of the solid hydrate mass and simplifies the formation-storage-decomposition process of gas hydrates. The minor amounts of surfactant also enhance the potential of gas hydrates for industrial storage applications.

  11. Metals Processing Laboratory Users (MPLUS) Facility Annual Report FY 2002 (October 1, 2001-September 30, 2002)

    SciTech Connect (OSTI)

    Angelini, P

    2004-04-27T23:59:59.000Z

    The Metals Processing Laboratory Users Facility (MPLUS) is a Department of Energy (DOE), Energy Efficiency and Renewable Energy, Industrial Technologies Program, user facility designated to assist researchers in key industries, universities, and federal laboratories in improving energy efficiency, improving environmental aspects, and increasing competitiveness. The goal of MPLUS is to provide access to the specialized technical expertise and equipment needed to solve metals processing issues that limit the development and implementation of emerging metals processing technologies. The scope of work can also extend to other types of materials. MPLUS has four primary user centers: (1) Processing--casting, powder metallurgy, deformation processing (including extrusion, forging, rolling), melting, thermomechanical processing, and high-density infrared processing; (2) Joining--welding, monitoring and control, solidification, brazing, and bonding; (3) Characterization--corrosion, mechanical properties, fracture mechanics, microstructure, nondestructive examination, computer-controlled dilatometry, and emissivity; and (4) Materials/Process Modeling--mathematical design and analyses, high-performance computing, process modeling, solidification/deformation, microstructure evolution, thermodynamic and kinetic, and materials databases A fully integrated approach provides researchers with unique opportunities to address technologically related issues to solve metals processing problems and probe new technologies. Access is also available to 16 additional Oak Ridge National Laboratory (ORNL) user facilities ranging from state-of-the-art materials characterization capabilities, and high-performance computing to manufacturing technologies. MPLUS can be accessed through a standardized user-submitted proposal and a user agreement. Nonproprietary (open) or proprietary proposals can be submitted. For open research and development, access to capabilities is provided free of charge, while for proprietary efforts, the user pays the entire project costs based on DOE guidelines for ORNL costs.

  12. Metals Processing Laboratory Users (MPLUS) Facility Annual Report: October 1, 2000 through September 30, 2001

    SciTech Connect (OSTI)

    Angelini, P

    2004-04-27T23:59:59.000Z

    The Metals Processing Laboratory Users Facility (MPLUS) is a Department of Energy (DOE), Energy Efficiency and Renewable Energy, Industrial Technologies Program user facility designated to assist researchers in key industries, universities, and federal laboratories in improving energy efficiency, improving environmental aspects, and increasing competitiveness. The goal of MPLUS is to provide access to the specialized technical expertise and equipment needed to solve metals processing issues that limit the development and implementation of emerging metals processing technologies. The scope of work can also extend to other types of materials. MPLUS has four primary User Centers including: (1) Processing--casting, powder metallurgy, deformation processing including (extrusion, forging, rolling), melting, thermomechanical processing, high density infrared processing; (2) Joining--welding, monitoring and control, solidification, brazing, bonding; (3) Characterization--corrosion, mechanical properties, fracture mechanics, microstructure, nondestructive examination, computer-controlled dilatometry, and emissivity; (4) Materials/Process Modeling--mathematical design and analyses, high performance computing, process modeling, solidification/deformation, microstructure evolution, thermodynamic and kinetic, and materials data bases. A fully integrated approach provides researchers with unique opportunities to address technologically related issues to solve metals processing problems and probe new technologies. Access is also available to 16 additional Oak Ridge National Laboratory (ORNL) user facilities ranging from state of the art materials characterization capabilities, high performance computing, to manufacturing technologies. MPLUS can be accessed through a standardized User-submitted Proposal and a User Agreement. Nonproprietary (open) or proprietary proposals can be submitted. For open research and development, access to capabilities is provides free of charge while for proprietary efforts, the user pays the entire project costs based on DOE guidelines for ORNL costs.

  13. Waste Analysis Plan for the Waste Receiving and Processing (WRAP) Facility

    SciTech Connect (OSTI)

    TRINER, G.C.

    1999-11-01T23:59:59.000Z

    The purpose of this waste analysis plan (WAP) is to document the waste acceptance process, sampling methodologies, analytical techniques, and overall processes that are undertaken for dangerous, mixed, and radioactive waste accepted for confirmation, nondestructive examination (NDE) and nondestructive assay (NDA), repackaging, certification, and/or storage at the Waste Receiving and Processing Facility (WRAP). Mixed and/or radioactive waste is treated at WRAP. WRAP is located in the 200 West Area of the Hanford Facility, Richland, Washington. Because dangerous waste does not include source, special nuclear, and by-product material components of mixed waste, radionuclides are not within the scope of this documentation. The information on radionuclides is provided only for general knowledge.

  14. Project C-018H, 242-A Evaporator/PUREX Plant Process Condensate Treatment Facility, functional design criteria. Revision 3

    SciTech Connect (OSTI)

    Sullivan, N.

    1995-05-02T23:59:59.000Z

    This document provides the Functional Design Criteria (FDC) for Project C-018H, the 242-A Evaporator and Plutonium-Uranium Extraction (PUREX) Plant Condensate Treatment Facility (Also referred to as the 200 Area Effluent Treatment Facility [ETF]). The project will provide the facilities to treat and dispose of the 242-A Evaporator process condensate (PC), the Plutonium-Uranium Extraction (PUREX) Plant process condensate (PDD), and the PUREX Plant ammonia scrubber distillate (ASD).

  15. Air Impacts of Increased Natural Gas Acquisition, Processing, and Use: A Critical Review

    E-Print Network [OSTI]

    Jackson, Robert B.

    Air Impacts of Increased Natural Gas Acquisition, Processing, and Use: A Critical Review to rapid and intensive development of many unconventional natural gas plays (e.g., shale gas, tight sand understanding of local and regional air quality impacts of natural gas extraction, production, and use. Air

  16. Gas Turbines Increase the Energy Efficiency of Industrial Processes

    E-Print Network [OSTI]

    Banchik, I. N.; Bohannan, W. R.; Stork, K.; McGovern, L. J.

    1981-01-01T23:59:59.000Z

    clean fuel gas for the gas turbine is produced by gasification of coal, are presented. Waste heat from the gasifier and the gas turbine exhaust is converted to high pressure steam for steam turbines. Gas turbines may find application in other industrial...

  17. Active constraint regions for a natural gas liquefaction process Magnus G. Jacobsena

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Active constraint regions for a natural gas liquefaction process Magnus G. Jacobsena , Sigurd little attention. this paper addresses optimal operation of a simple natural gas liquefaction process at all times. Keywords: Self-optimizing control, liquefied natural gas, LNG, PRICO, disturbances, optimal

  18. Selection of Controlled Variables for a Natural Gas to Liquids Process Mehdi Panahi and Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Selection of Controlled Variables for a Natural Gas to Liquids Process Mehdi Panahi and Sigurd variables (CVs) for a natural gas to hydrocarbon liquids (GTL) process based on the idea of self of operation are studied. In mode I, where the natural gas flow rate is given, there are three unconstrained

  19. MEMORIAL UNIVERSITY OF NEWFOUNDLAND Three-year Term Appointment in Process (Oil and Gas) Engineering

    E-Print Network [OSTI]

    George, Glyn

    MEMORIAL UNIVERSITY OF NEWFOUNDLAND Three-year Term Appointment in Process (Oil and Gas with oil and gas specialization at the assistant- or associate professor-level, commencing April 12, 2010 in the area of oil and gas, and process engineering, to supervise graduate students, to participate in other

  20. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G. (Bolingbrook, IL); Sandstrom, William A. (Chicago, IL); Tarman, Paul B. (Elmhurst, IL)

    1982-01-01T23:59:59.000Z

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  1. Feasibility Study for a Plasma Dynamo Facility to Investigate Fundamental Processes in Plasma Astrophysics. Final report

    SciTech Connect (OSTI)

    Forest, Cary B.

    2013-09-19T23:59:59.000Z

    The scientific equipment purchased on this grant was used on the Plasma Dynamo Prototype Experiment as part of Professor Forest's feasibility study for determining if it would be worthwhile to propose building a larger plasma physics experiment to investigate various fundamental processes in plasma astrophysics. The initial research on the Plasma Dynamo Prototype Experiment was successful so Professor Forest and Professor Ellen Zweibel at UW-Madison submitted an NSF Major Research Instrumentation proposal titled "ARRA MRI: Development of a Plasma Dynamo Facility for Experimental Investigations of Fundamental Processes in Plasma Astrophysics." They received funding for this project and the Plasma Dynamo Facility also known as the "Madison Plasma Dynamo Experiment" was constructed. This experiment achieved its first plasma in the fall of 2012 and U.S. Dept. of Energy Grant No. DE-SC0008709 "Experimental Studies of Plasma Dynamos," now supports the research.

  2. Identification of Process Energy and Pollution Reduction Opportunities at DoD Industrial Facilities

    E-Print Network [OSTI]

    Lin, M. C.; Northrup, J. I.; Smith, E. D.

    IDENTIFICATION OF PROCESS ENERGY AND POLLUTION REDUCTION OPPORTUNITIES AT DOD INDUSTRIAL FACILITIES Mike C. Lin Jeri 1. Northrup Principal Investigator Principal Investigator USACERL USACERL Champaign, IL Champaign, IL ABSTRACT Industrial... Information System (DEIS). DEIS is the infonnation system with which the DoD monitors its supplies and consumption of energy. It is primarily used as an energy management tool, providing infonnation about each fuel used within the DoD, including bulk...

  3. WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION PROCESS

    SciTech Connect (OSTI)

    Maria Flytzani-Stephanopoulos, PI; Jerry Meldon, Co-PI; Xiaomei Qi

    2002-12-01T23:59:59.000Z

    Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperatures to improve reaction kinetics and permeation. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H{sub 2} removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H{sub 2}-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. The first-year screening studies of WGS catalysts identified Cu-ceria as the most promising high-temperature shift catalyst for integration with H{sub 2}-selective membranes. Formulations containing iron oxide were found to deactivate in the presence of CO{sub 2}, and were thus eliminated from further consideration. Cu-containing ceria catalysts, on the other hand, showed high stability in CO{sub 2}-rich gases. This type gas will be present over much of the catalyst, as the membrane removes the hydrogen produced from the shift reaction. Several catalyst formulations were prepared, characterized and tested in the first year of study. Details from the catalyst development and testing work were given in our first annual technical report. Hydrogen permeation through Pd and Pd-alloy foils was investigated in a small membrane reactor constructed during the first year of the project. The effect of temperature on the hydrogen flux through pure Pd, Pd{sub 60}Cu{sub 40} and Pd{sub 75}Ag{sub 25} alloy membranes, each 25 {micro}m thick, was evaluated in the temperature range from 250 C to 500 C at upstream pressure of 4.4 atm and permeate hydrogen pressure of 1 atm. Flux decay was observed for the Pd-Cu membrane above 500 C. From 350-450 C, an average hydrogen flux value of 0.2 mol H{sub 2}/m{sup 2}/s was measured over this Pd-alloy membrane. These results are in good agreement with literature data. In this year's report, we discuss reaction rate measurements, optimization of catalyst kinetics by proper choice of dopant oxide (lanthana) in ceria, long-term stability studies, and H{sub 2} permeation data collected with unsupported flat, 10 {micro}m-thick Pd-Cu membranes over a wide temperature window and in various gas mixtures. The high-temperature shift catalyst composition was further improved, by proper selection of dopant type and amount. The formulation 10 at%Cu-Ce(30 at%La)Ox was the best; this was selected for further kinetic studies. WGS reaction rates were measured in a simulated coal-gas mixture. The stability of catalyst performance was examined in 40-hr long tests. A series of hydrogen permeation tests were conducted in a small flat-membrane reactor using the 10 m{micro}-thick Pd-Cu membranes. Small inhibitory effects of CO and CO{sub 2} were found at temperatures above 350 C, while H{sub 2}O vapor had no effect on hydrogen permeation. No carbon deposition took place during many hours of membrane operation. The reaction extent on the blank (catalyst-free) membrane was also negligible. A larger flat-membrane reactor will be used next year with the catalyst wash coated on screens close coupled with the Pd-Cu membrane.

  4. Discrete event simulation of the Defense Waste Processing Facility (DWPF) analytical laboratory

    SciTech Connect (OSTI)

    Shanahan, K.L.

    1992-02-01T23:59:59.000Z

    A discrete event simulation of the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) analytical laboratory has been constructed in the GPSS language. It was used to estimate laboratory analysis times at process analytical hold points and to study the effect of sample number on those times. Typical results are presented for three different simultaneous representing increasing levels of complexity, and for different sampling schemes. Example equipment utilization time plots are also included. SRS DWPF laboratory management and chemists found the simulations very useful for resource and schedule planning.

  5. SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2012-05-08T23:59:59.000Z

    This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude necessary to have a dramatic impact on blending, washing, or waste loading strategies for DWPF) for the glasses studied here. In general, the concentrations of those species that significantly improve sulfate solubility in a borosilicate glass must be added in relatively large concentrations (e.g., 13 to 38 wt % or more of the frit) in order to have a substantial impact. For DWPF, these concentrations would constitute too large of a portion of the frit to be practical. Therefore, it is unlikely that specific additives may be introduced into the DWPF glass via the frit to significantly improve sulfate solubility. The results presented here continue to show that sulfate solubility or retention is a function of individual glass compositions, rather than a property of a broad glass composition region. It would therefore be inappropriate to set a single sulfate concentration limit for a range of DWPF glass compositions. Sulfate concentration limits should continue to be identified and implemented for each sludge batch. The current PCCS limit is 0.4 wt % SO{sub 4}{sup 2-} in glass, although frit development efforts have led to an increased limit of 0.6 wt % for recent sludge batches. Slightly higher limits (perhaps 0.7-0.8 wt %) may be possible for future sludge batches. An opportunity for allowing a higher sulfate concentration limit at DWPF may lay lie in improving the laboratory experiments used to set this limit. That is, there are several differences between the crucible-scale testing currently used to define a limit for DWPF operation and the actual conditions within the DWPF melter. In particular, no allowance is currently made for sulfur partitioning (volatility versus retention) during melter processing as the sulfate limit is set for a specific sludge batch. A better understanding of the partitioning of sulfur in a bubbled melter operating with a cold cap as well as the impacts of sulfur on the off-gas system may allow a higher sulfate concentration limit to be established for the melter feed. This approach would have to be taken carefully to ensure that a

  6. Simulation and integration of liquefied natural gas (lng) processes

    E-Print Network [OSTI]

    Al-Sobhi, Saad Ali

    2009-05-15T23:59:59.000Z

    gas (LNG). When there is a considerable distance involved in transporting natural gas, LNG is becoming the preferred method of supply because of technical, economic, and political reasons. Thus, LNG is expected to play a major role in meeting...

  7. DOE final report, phase one startup, Waste Receiving and Processing Facility (WRAP)

    SciTech Connect (OSTI)

    Jasen, W.G.

    1998-01-07T23:59:59.000Z

    This document is to validate that the WRAP facility is physically ready to start up phase 1, and that the managers and operators are prepared to safely manage and operate the facility when all pre-start findings have been satisfactorily corrected. The DOE Readiness Assessment (RA) team spent a week on-site at Waste Receiving and Processing Module 1 (WRAP-1) to validate the readiness for phase 1 start up of facility. The Contractor and DOE staff were exceptionally cooperative and contributed significantly to the overall success of the RA. The procedures and Conduct of Operations areas had significant discrepancies, many of which should have been found by the contractor review team. In addition the findings of the contractor review team should have led the WRAP-1 management team to correcting the root causes of the findings prior to the DOE RA team review. The findings and observations include many issues that the team believes should have been found by the contractor review and corrective actions taken. A significantly improved Operational Readiness Review (ORR) process and corrective actions of root causes must be fully implemented by the contractor prior to the performance of the contractor ORR for phase 2 operations. The pre-start findings as a result of this independent DOE Readiness Assessment are presented.

  8. Waste Receiving and Processing (WRAP) Facility Public Address System Review Findings

    SciTech Connect (OSTI)

    HUMPHRYS, K.L.

    1999-11-03T23:59:59.000Z

    Public address system operation at the Waste Receiving and Processing (WRAP) facility was reviewed. The review was based on an Operational Readiness Review finding that public address performance was not adequate in parts of the WRAP facility. Several improvements were made to the WRAP Public Address (PA) system to correct the deficiencies noted. Speaker gain and position was optimized. A speech processor was installed to boost intelligibility in high noise areas. Additional speakers were added to improve coverage in the work areas. The results of this evaluation indicate that further PA system enhancements are not warranted. Additional speakers cannot compensate for the high background sound and high reverberation levels found in the work areas. Recommendations to improve PA system intelligibility include minor speaker adjustments, enhanced PA announcement techniques, and the use of sound reduction and abatement techniques where economically feasible.

  9. Active constraint regions for a natural gas liquefaction process Magnus G. Jacobsen a

    E-Print Network [OSTI]

    Skogestad, Sigurd

    processes. 2. Optimal operation of a PRICO liquefaction plant 2.1. Plant description The PRICO processActive constraint regions for a natural gas liquefaction process Magnus G. Jacobsen a , Sigurd Keywords: Self-optimizing control Liquefied natural gas LNG PRICO Disturbances Optimal operation a b s t r

  10. Darlington tritium removal facility and station upgrading plant dynamic process simulation

    SciTech Connect (OSTI)

    Busigin, A. [NITEK USA, Inc., 6405 NW 77 PL, Parkland, FL 33067 (United States); Williams, G. I. D.; Wong, T. C. W.; Kulczynski, D.; Reid, A. [Ontario Power Generation Nuclear, Box 4000, Bowmanville, ON L1C 3Z8 (Canada)

    2008-07-15T23:59:59.000Z

    Ontario Power Generation Nuclear (OPGN) has a 4 x 880 MWe CANDU nuclear station at its Darlington Nuclear Div. located in Bowmanville. The station has been operating a Tritium Removal Facility (TRF) and a D{sub 2}O station Upgrading Plant (SUP) since 1989. Both facilities were designed with a Distributed Control System (DCS) and programmable logic controllers (PLC) for process control. This control system was replaced with a DCS only, in 1998. A dynamic plant simulator was developed for the Darlington TRF (DTRF) and the SUP, as part of the computer control system replacement. The simulator was used to test the new software, required to eliminate the PLCs. The simulator is now used for operator training and testing of process control software changes prior to field installation. Dynamic simulation will be essential for the ITER isotope separation system, where the process is more dynamic than the relatively steady-state DTRF process. This paper describes the development and application of the DTRF and SUP dynamic simulator, its benefits, architecture, and the operational experience with the simulator. (authors)

  11. Data acquisition and processing system at the NOVETTE laser fusion facility

    SciTech Connect (OSTI)

    Averbach, J.M.; Kroepfl, D.J.; Severyn, J.R.

    1983-02-01T23:59:59.000Z

    This paper describes the computer hardware and software used for acquisition and processing of data from experiments at the NOVETTE laser fusion facility. Nearly two hundred sensors are used to measure the performance of millimeter extent targets irradiated by multi-kilojoule laser pulses. Sensor output is recorded on CAMAC based digitzers, CCD arrays, and film. CAMAC instrument outputs are acquired and collected by a network of LSI-11 microprocessors centrally controlled by a VAX 11/780. The user controls the system through menus presented on color video displays equipped with touch panels. The control VAX collects data from all microprocessors and CCD arrays and stores them in a file for transport to a second VAX 11/780 which is used for processing and final analysis. Transfer is done through a high speed fiber-optic link. Relational data bases are used extensively in the processing and archiving of data.

  12. First Results from the CARIBU Facility: Mass Measurements on the r-Process Path

    E-Print Network [OSTI]

    J. Van Schelt; D. Lascar; G. Savard; J. A. Clark; P. F. Bertone; S. Caldwell; A. Chaudhuri; 1 A. F. Levand; G. Li; G. E. Morgan; R. Orford; R. E. Segel; K. S. Sharma; M. G. Sternberg

    2013-07-01T23:59:59.000Z

    The Canadian Penning Trap mass spectrometer has made mass measurements of 33 neutron-rich nuclides provided by the new Californium Rare Isotope Breeder Upgrade (CARIBU) facility at Argonne National Laboratory. The studied region includes the 132Sn double shell closure and ranges in Z from In to Cs, with Sn isotopes measured out to A = 135, and the typical measurement precision is at the 100 ppb level or better. The region encompasses a possible major waiting point of the astrophysical r process, and the impact of the masses on the r process is shown through a series of simulations. These first-ever simulations with direct mass information on this waiting point show significant increases in waiting time at Sn and Sb in comparison with commonly used mass models, demonstrating the inadequacy of existing models for accurate r-process calculations.

  13. A shielded storage and processing facility for radioisotope thermoelectric generator heat source production

    SciTech Connect (OSTI)

    Sherrell, D.L. (Westinghouse Hanford Company, P.O. Box 1970, Mail Stop N1-42, Richland, Washington 99352 (United States))

    1993-01-15T23:59:59.000Z

    A shielded storage rack has been installed as part of the Radioisotope Power Systems Facility (RPSF) at the U.S. Department of Energy's (DOE) Hanford Site in Washington State. The RPSF is designed to replace an existing facility at DOE's Mound Site near Dayton, Ohio, where General Purpose Heat Source (GPHS) modules are currently assembled and installed into Radioisotope Thermoelectric Generators (RTG). The overall design goal of the RPSF is to increase annual production throughput, while at the same time reducing annual radiation exposure to personnel. The shield rack design successfully achieved this goal for the Module Reduction and Monitoring Facility (MRMF), which processes and stores assembled GPHS modules, prior to their installation into RTGs. The shield rack design is simple and effective, with the result that background radiation levels within Hanford's MRMF room are calculated at just over three percent of those typically experienced during operation of the existing MRMF at Mound, despite the fact that Hanford's calculations assume five times the GPHS inventory of that assumed for Mound.

  14. Seismic margins assessment of the plutonium processing facility Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Goen, L.K. [Los Alamos National Lab., NM (United States); Salmon, M.W. [EQE International, Irwine, CA (United States)

    1995-12-01T23:59:59.000Z

    Results of the recently completed seismic evaluation at the Los Alamos National Laboratory site indicate a need to consider seismic loads greater than design basis for many structures systems and components (SSCs). DOE Order 5480.28 requires that existing SSCs be evaluated to determine their ability to withstand the effects of earthquakes when changes in the understanding of this hazard results in greater loads. In preparation for the implementation of DOE Order 5480.28 and to support the update of the facility Safety Analysis Report, a seismic margin assessment of SSCs necessary for a monitored passive safe shutdown of the Plutonium Processing Facility (PF-4) was performed. The seismic margin methodology is given in EPRI NP-6041-SL, ``A Methodology for Assessment of Nuclear Power Plant Seismic Margin (Revision 1)``. In this methodology, high confidence of low probability of failure (HCLPF) capacities for SSCs are estimated in a deterministic manner. For comparison to the performance goals given in DOE Order 5480.28, the results of the seismic margins assessment were used to estimate the annual probability of failure for the evaluated SSCs. In general, the results show that the capacity for the SSCs comprising PF-4 is high. This is to be expected for a newer facility as PF-4 was designed in the early 1970`s. The methodology and results of this study are presented in this paper.

  15. A shielded storage and processing facility for radioisotope thermoelectric generator heat source production

    SciTech Connect (OSTI)

    Sherrell, D.L.

    1992-06-01T23:59:59.000Z

    This report discusses a shielded storage rack which has been installed as part of the Radioisotope Power Systems Facility (RPSF) at the US Department of Energy's (DOE) Hanford Site in Washington State. The RPSF is designed to replace an existing facility at DOE's Mound Site near Dayton, Ohio, where General Purpose Heat Source (GPHS) modules are currently assembled and installed into Radioisotope Thermoelectric Generators (RTG). The overall design goal of the RPSF is to increase annual production throughput, while at the same time reducing annual radiation exposure to personnel. The shield rack design successfully achieved this goal for the Module Reduction and Monitoring Facility (MRMF), which process and stores assembled GPHS modules, prior to their installation into RTGS. The shield rack design is simple and effective, with the result that background radiation levels within Hanford's MRMF room are calculated at just over three percent of those typically experienced during operation of the existing MRMF at Mound, despite the fact that Hanford's calculations assume five times the GPHS inventory of that assumed for Mound.

  16. A shielded storage and processing facility for radioisotope thermoelectric generator heat source production

    SciTech Connect (OSTI)

    Sherrell, D.L.

    1992-06-01T23:59:59.000Z

    This report discusses a shielded storage rack which has been installed as part of the Radioisotope Power Systems Facility (RPSF) at the US Department of Energy`s (DOE) Hanford Site in Washington State. The RPSF is designed to replace an existing facility at DOE`s Mound Site near Dayton, Ohio, where General Purpose Heat Source (GPHS) modules are currently assembled and installed into Radioisotope Thermoelectric Generators (RTG). The overall design goal of the RPSF is to increase annual production throughput, while at the same time reducing annual radiation exposure to personnel. The shield rack design successfully achieved this goal for the Module Reduction and Monitoring Facility (MRMF), which process and stores assembled GPHS modules, prior to their installation into RTGS. The shield rack design is simple and effective, with the result that background radiation levels within Hanford`s MRMF room are calculated at just over three percent of those typically experienced during operation of the existing MRMF at Mound, despite the fact that Hanford`s calculations assume five times the GPHS inventory of that assumed for Mound.

  17. 200 Area effluent treatment facility process control plan 98-02

    SciTech Connect (OSTI)

    Le, E.Q.

    1998-01-30T23:59:59.000Z

    This Process Control Plan (PCP) provides a description of the background information, key objectives, and operating criteria defining Effluent Treatment Facility (ETF) Campaign 98-02 as required per HNF-IP-0931 Section 37, Process Control Plans. Campaign 98-62 is expected to process approximately 18 millions gallons of groundwater with an assumption that the UP-1 groundwater pump will be shut down on June 30, 1998. This campaign will resume the UP-1 groundwater treatment operation from Campaign 97-01. The Campaign 97-01 was suspended in November 1997 to allow RCRA waste in LERF Basin 42 to be treated to meet the Land Disposal Restriction Clean Out requirements. The decision to utilize ETF as part of the selected interim remedial action of the 200-UP-1 Operable Unit is documented by the Declaration of the Record of Decision, (Ecology, EPA and DOE 1997). The treatment method was chosen in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) as amended by the Superfund Amendments and Reauthorization Act of 1986 (SARA), the Hanford Federal Facility Agreement and Consent Order (known as the Tri-Party Agreement or TPA), and to the extent practicable, the National Oil and Hazardous Substances Pollution Contingency Plan (NCP).

  18. INSTALLATION OF BUBBLERS IN THE SAVANNAH RIVER SITED DEFENSE WASTE PROCESSING FACILITY MELTER

    SciTech Connect (OSTI)

    Smith, M.; Iverson, D.

    2010-12-08T23:59:59.000Z

    Savannah River Remediation (SRR) LLC assumed the liquid waste contract at the Savannah River Site (SRS) in the summer of 2009. The main contractual agreement was to close 22 High Level Waste (HLW) tanks in eight years. To achieve this aggressive commitment, faster waste processing throughout the SRS liquid waste facilities will be required. Part of the approach to achieve faster waste processing is to increase the canister production rate of the Defense Waste Processing Facility (DWPF) from approximately 200 canisters filled with radioactive waste glass per year to 400 canisters per year. To reach this rate for melter throughput, four bubblers were installed in the DWPF Melter in the late summer of 2010. This effort required collaboration between SRR, SRR critical subcontractor EnergySolutions, and Savannah River Nuclear Solutions, including the Savannah River National Laboratory (SRNL). The tasks included design and fabrication of the bubblers and related equipment, testing of the bubblers for various technical issues, the actual installation of the bubblers and related equipment, and the initial successful operation of the bubblers in the DWPF Melter.

  19. An Integrated Approach to Evaluating the Technical and Commercial Options for Cogeneration Facilities in the Process Industry

    E-Print Network [OSTI]

    Cooke, D. H.; McCue, R. H.

    , economic and financial considerations, as well as to the determination of the appropriate degree of thermal integration of the power and process subsystems. An overview of steam and gas turbine cycle options for process/power integration typical...

  20. Defense Waste Processing Facility (DWPF), Modular CSSX Unit (CSSX), and Waste Transfer Line System of Salt Processing Program (U)

    SciTech Connect (OSTI)

    CHANG, ROBERT

    2006-02-02T23:59:59.000Z

    All of the waste streams from ARP, MCU, and SWPF processes will be sent to DWPF for vitrification. The impact these new waste streams will have on DWPF's ability to meet its canister production goal and its ability to support the Salt Processing Program (ARP, MCU, and SWPF) throughput needed to be evaluated. DWPF Engineering and Operations requested OBU Systems Engineering to evaluate DWPF operations and determine how the process could be optimized. The ultimate goal will be to evaluate all of the Liquid Radioactive Waste (LRW) System by developing process modules to cover all facilities/projects which are relevant to the LRW Program and to link the modules together to: (1) study the interfaces issues, (2) identify bottlenecks, and (3) determine the most cost effective way to eliminate them. The results from the evaluation can be used to assist DWPF in identifying improvement opportunities, to assist CBU in LRW strategic planning/tank space management, and to determine the project completion date for the Salt Processing Program.

  1. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, D.E.

    1997-10-21T23:59:59.000Z

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector`s centerline in proceeding toward the downstream side of the collector. Gas flow in the outer channel maintains the fluid on the channel`s wall in the form of a ``wavy film,`` while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator. 4 figs.

  2. Catalyst and process development for synthesis gas conversion to isobutylene

    SciTech Connect (OSTI)

    Anthony, R.G.; Akgerman, A.

    1992-05-26T23:59:59.000Z

    The objectives of this project are to develop a new catalyst, the kinetics for this catalyst, reactor models for trickle bed, slurry and fixed bed, and simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene.

  3. Prediction of gas-hydrate formation conditions in production and surface facilities

    E-Print Network [OSTI]

    Ameripour, Sharareh

    2006-10-30T23:59:59.000Z

    such as methane, ethane, propane, carbon dioxide and hydrogen sulfide to binary, ternary, and natural gas mixtures. I used the Statistical Analysis Software (SAS) to find the best correlations among variables such as specific gravity and pseudoreduced pressure...

  4. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    SciTech Connect (OSTI)

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

    2014-01-07T23:59:59.000Z

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

  5. Process for separating carbon dioxide from flue gas using sweep-based membrane separation and absorption steps

    DOE Patents [OSTI]

    Wijmans, Johannes G.; Baker, Richard W.; Merkel, Timothy C.

    2012-08-21T23:59:59.000Z

    A gas separation process for treating flue gases from combustion processes, and combustion processes including such gas separation. The invention involves routing a first portion of the flue gas stream to be treated to an absorption-based carbon dioxide capture step, while simultaneously flowing a second portion of the flue gas across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas to the combustor.

  6. Simulation, integration, and economic analysis of gas-to-liquid processes

    E-Print Network [OSTI]

    Bao, Buping

    2009-05-15T23:59:59.000Z

    specifications. Next, energy and mass integration studies are performed to address the following items: (a) heating and cooling utilities, (b) combined heat and power (process cogeneration), (c) management of process water, (c) optimization of tail-gas allocation...

  7. Process for off-gas particulate removal and apparatus therefor

    DOE Patents [OSTI]

    Carl, Daniel E. (Orchard Park, NY)

    1997-01-01T23:59:59.000Z

    In the event of a breach in the off-gas line of a melter operation requiring closure of the line, a secondary vessel vent line is provided with a particulate collector utilizing atomization for removal of large particulates from the off-gas. The collector receives the gas containing particulates and directs a portion of the gas through outer and inner annular channels. The collector further receives a fluid, such as water, which is directed through the outer channel together with a second portion of the particulate-laden gas. The outer and inner channels have respective ring-like termination apertures concentrically disposed adjacent one another on the outer edge of the downstream side of the particulate collector. Each of the outer and inner channels curves outwardly away from the collector's centerline in proceeding toward the downstream side of the collector. Gasflow in the outer channel maintains the fluid on the channel's wall in the form of a "wavy film," while the gas stream from the inner channel shears the fluid film as it exits the outer channel in reducing the fluid to small droplets. Droplets formed by the collector capture particulates in the gas stream by one of three mechanisms: impaction, interception or Brownian diffusion in removing the particulates. The particulate-laden droplets are removed from the fluid stream by a vessel vent condenser or mist eliminator.

  8. Processing and Gas Barrier Behavior of Multilayer Thin Nanocomposite Films

    E-Print Network [OSTI]

    Yang, You-Hao

    2012-10-19T23:59:59.000Z

    barrier for goods requiring long shelf life. Current gas barrier technologies like plasma-enhanced vapor deposition (PECVD) often create high barrier metal oxide films, which are prone to cracking when flexed. Bulk composites composed of polymer...

  9. Process Design and Integration of Shale Gas to Methanol

    E-Print Network [OSTI]

    Ehlinger, Victoria M.

    2013-02-04T23:59:59.000Z

    Recent breakthroughs in horizontal drilling and hydraulic fracturing technology have made huge reservoirs of previously untapped shale gas and shale oil formations available for use. These new resources have already made a significant impact...

  10. Method and apparatus for processing exhaust gas with corona discharge

    DOE Patents [OSTI]

    Barlow, S.E.; Orlando, T.M.; Tonkyn, R.G.

    1999-06-22T23:59:59.000Z

    The present invention is placing a catalyst coating upon surfaces surrounding a volume containing corona discharge. In addition, the electrodes are coated with a robust dielectric material. Further, the electrodes are arranged so that at least a surface portion of each electrode extends into a flow path of the exhaust gas to be treated and there is only exhaust gas in the volume between each pair of electrodes. 12 figs.

  11. Microwave off-gas treatment apparatus and process

    DOE Patents [OSTI]

    Schulz, Rebecca L. (Aiken, SC); Clark, David E. (Gainesville, FL); Wicks, George G. (North Aiken, SC)

    2003-01-01T23:59:59.000Z

    The invention discloses a microwave off-gas system in which microwave energy is used to treat gaseous waste. A treatment chamber is used to remediate off-gases from an emission source by passing the off-gases through a susceptor matrix, the matrix being exposed to microwave radiation. The microwave radiation and elevated temperatures within the combustion chamber provide for significant reductions in the qualitative and quantitative emissions of the gas waste stream.

  12. Thief process for the removal of mercury from flue gas

    DOE Patents [OSTI]

    Pennline, Henry W. (Bethel Park, PA); Granite, Evan J. (Wexford, PA); Freeman, Mark C. (South Park Township, PA); Hargis, Richard A. (Canonsburg, PA); O'Dowd, William J. (Charleroi, PA)

    2003-02-18T23:59:59.000Z

    A system and method for removing mercury from the flue gas of a coal-fired power plant is described. Mercury removal is by adsorption onto a thermally activated sorbent produced in-situ at the power plant. To obtain the thermally activated sorbent, a lance (thief) is inserted into a location within the combustion zone of the combustion chamber and extracts a mixture of semi-combusted coal and gas. The semi-combusted coal has adsorptive properties suitable for the removal of elemental and oxidized mercury. The mixture of semi-combusted coal and gas is separated into a stream of gas and semi-combusted coal that has been converted to a stream of thermally activated sorbent. The separated stream of gas is recycled to the combustion chamber. The thermally activated sorbent is injected into the duct work of the power plant at a location downstream from the exit port of the combustion chamber. Mercury within the flue gas contacts and adsorbs onto the thermally activated sorbent. The sorbent-mercury combination is removed from the plant by a particulate collection system.

  13. Demonstration of Natural Gas Engine Driven Air Compressor Technology at Department of Defense Industrial Facilities

    E-Print Network [OSTI]

    Lin, M.; Aylor, S. W.; Van Ormer, H.

    of incorporating the NGEDAC performance data directly into their overall energy management control system. All Army industrial installations will be screened for technology application. Technology transfer will be coordinated with Air Force, Navy, and Defense... Technology & Management Paul A. Wenner Laboratory Services, Inc. XENERGY, Inc. Champaign, Illinois Gaithersburg, Maryland Worthington, Ohio ABSTRACT Recent downsizing and consolidation of Department of Defense (DOD) facilities provides an opportunity...

  14. VERIFICATION OF THE DEFENSE WASTE PROCESSING FACILITY'S (DWPF) PROCESS DIGESTION METHOD FOR THE SLUDGE BATCH 7A QUALIFICATION SAMPLE

    SciTech Connect (OSTI)

    Click, D.; Edwards, T.; Jones, M.; Wiedenman, B.

    2011-03-14T23:59:59.000Z

    For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) performs confirmation of the applicability of the digestion method to be used by the DWPF lab for elemental analysis of Sludge Receipt and Adjustment Tank (SRAT) receipt samples and SRAT product process control samples. DWPF SRAT samples are typically dissolved using a room temperature HF-HNO{sub 3} acid dissolution (i.e., DWPF Cold Chem Method, see DWPF Procedure SW4-15.201) and then analyzed by inductively coupled plasma - atomic emission spectroscopy (ICP-AES). This report contains the results and comparison of data generated from performing the Aqua Regia (AR), Sodium peroxide/Hydroxide Fusion (PF) and DWPF Cold Chem (CC) method digestions of Sludge Batch 7a (SB7a) SRAT Receipt and SB7a SRAT Product samples. The SB7a SRAT Receipt and SB7a SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constituates the SB7a Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 6 (SB6), to form the Sb7a Blend composition.

  15. Title: Using acidic electrolyzed water to reduce objectionable gas emissions from poultry production facilities in Texas.

    E-Print Network [OSTI]

    Mukhtar, Saqib

    Title: Using acidic electrolyzed water to reduce objectionable gas emissions from poultry Summary: There are increasing numbers of poultry production buildings, with large, densely housed flocks to allow producers to meet the increasing demand for poultry products and, yet, reduce the environmental

  16. Basic Data Report -- Defense Waste Processing Facility Sludge Plant, Savannah River Plant 200-S Area

    SciTech Connect (OSTI)

    Amerine, D.B.

    1982-09-01T23:59:59.000Z

    This Basic Data Report for the Defense Waste Processing Facility (DWPF)--Sludge Plant was prepared to supplement the Technical Data Summary. Jointly, the two reports were intended to form the basis for the design and construction of the DWPF. To the extent that conflicting information may appear, the Basic Data Report takes precedence over the Technical Data Summary. It describes project objectives and design requirements. Pertinent data on the geology, hydrology, and climate of the site are included. Functions and requirements of the major structures are described to provide guidance in the design of the facilities. Revision 9 of the Basic Data Report was prepared to eliminate inconsistencies between the Technical Data Summary, Basic Data Report and Scopes of Work which were used to prepare the September, 1982 updated CAB. Concurrently, pertinent data (material balance, curie balance, etc.) have also been placed in the Basic Data Report. It is intended that these balances be used as a basis for the continuing design of the DWPF even though minor revisions may be made in these balances in future revisions to the Technical Data Summary.

  17. Development of polymer concrete for dike insulation at LNG (Liquid Natural Gas) facilities. Final report, August 1983-July 1984

    SciTech Connect (OSTI)

    Fontana, J.J.; Steinberg, M.

    1984-11-01T23:59:59.000Z

    An insulating polymer concrete (IPC) composite has been developed for possible use as a dike insulation material at Liquid Natural Gas (LNG) storage facilities. Using hermetically sealed glass nodules or expanded perlite aggregates and unsaturated polyester resins, a new class of lightweight polymer concretes can be manufactured. Two application procedures have been identified and shown to be feasible in laboratory studies. Precast IPC composite panels 1-in thick can be bonded to concrete substrates using epoxy gel type adhesives or mortars. Cast-in-place IPC to concrete substrates have been shown to have good bonding and insulating characteristics. Modifications of the mix design to improve the workability and sagging of the IPC for installation on vertical or sloped surfaces is necessary.

  18. Multipass optical device and process for gas and analyte determination

    DOE Patents [OSTI]

    Bernacki, Bruce E. (Kennewick, WA)

    2011-01-25T23:59:59.000Z

    A torus multipass optical device and method are described that provide for trace level determination of gases and gas-phase analytes. The torus device includes an optical cavity defined by at least one ring mirror. The mirror delivers optical power in at least a radial and axial direction and propagates light in a multipass optical path of a predefined path length.

  19. Erosion/corrosion concerns in feed preparation systems at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Gee, J.T.; Chandler, C.T.; Daugherty, W.L.; Imrich, K.J.; Jenkins, C.F.

    1997-12-31T23:59:59.000Z

    The Savannah River Site (SRS) has been operating a nuclear fuel cycle since the 1950`s to produce nuclear materials in support of the national defense effort. The Department of Energy authorized the construction of the Defense Waste Processing Facility (DWPF) to immobilize the high level radioactive waste resulting from these processes as a durable borosilicate glass. The DWPF, after having undergone extensive testing, has been approved for operations and is currently immobilizing radioactive waste. To ensure reliability of the DWPF remote canyon processing equipment, a materials evaluation program was performed prior to radioactive operations to determine to what extent erosion/corrosion would impact design life of equipment. The program consisted of performing pre-service baseline inspections on critical equipment and follow-up inspections after completion of DWPF cold chemical demonstration runs. Non-destructive examination (NDE) techniques were used to assess erosion/corrosion as well as evaluation of corrosion coupon racks. These results were used to arrive at predicted equipment life for selected feed preparation equipment. It was concluded with the exception of the coil and agitator for the slurry mix evaporator (SME), which are exposed to erosive glass frit particles, all of the equipment should meet its design life.

  20. Final report on the public involvement process phase 1, Monitored Retrievable Storage Facility Feasibility Study

    SciTech Connect (OSTI)

    Moore, L.; Shanteau, C.

    1992-12-01T23:59:59.000Z

    This report summarizes the pubic involvement component of Phase 1 of the Monitored Retrievable Storage Facility (NM) Feasibility Study in San Juan County, Utah. Part of this summary includes background information on the federal effort to locate a voluntary site for temporary storage of nuclear waste, how San Juan County came to be involved, and a profile of the county. The heart of the report, however, summarizes the activities within the public involvement process, and the issues raised in those various forums. The authors have made every effort to reflect accurately and thoroughly all the concerns and suggestions expressed to us during the five month process. We hope that this report itself is a successful model of partnership with the citizens of the county -- the same kind of partnership the county is seeking to develop with its constituents. Finally, this report offers some suggestions to both county officials and residents alike. These suggestions concern how decision-making about the county's future can be done by a partnership of informed citizens and listening decision-makers. In the Appendix are materials relating to the public involvement process in San Juan County.

  1. Final report on the public involvement process phase 1, Monitored Retrievable Storage Facility Feasibility Study

    SciTech Connect (OSTI)

    Moore, L.; Shanteau, C.

    1992-12-01T23:59:59.000Z

    This report summarizes the pubic involvement component of Phase 1 of the Monitored Retrievable Storage Facility (NM) Feasibility Study in San Juan County, Utah. Part of this summary includes background information on the federal effort to locate a voluntary site for temporary storage of nuclear waste, how San Juan County came to be involved, and a profile of the county. The heart of the report, however, summarizes the activities within the public involvement process, and the issues raised in those various forums. The authors have made every effort to reflect accurately and thoroughly all the concerns and suggestions expressed to us during the five month process. We hope that this report itself is a successful model of partnership with the citizens of the county -- the same kind of partnership the county is seeking to develop with its constituents. Finally, this report offers some suggestions to both county officials and residents alike. These suggestions concern how decision-making about the county`s future can be done by a partnership of informed citizens and listening decision-makers. In the Appendix are materials relating to the public involvement process in San Juan County.

  2. System Design Description and Requirements for Modeling the Off-Gas Systems for Fuel Recycling Facilities

    SciTech Connect (OSTI)

    Daryl R. Haefner; Jack D. Law; Troy J. Tranter

    2010-08-01T23:59:59.000Z

    This document provides descriptions of the off-gases evolved during spent nuclear fuel processing and the systems used to capture the gases of concern. Two reprocessing techniques are discussed, namely aqueous separations and electrochemical (pyrochemical) processing. The unit operations associated with each process are described in enough detail so that computer models to mimic their behavior can be developed. The document also lists the general requirements for the desired computer models.

  3. THE INTEGRATION OF PROCESS HEAT APPLICATIONS TO HIGH TEMPERATURE GAS REACTORS

    SciTech Connect (OSTI)

    Michael G. McKellar

    2011-11-01T23:59:59.000Z

    A high temperature gas reactor, HTGR, can produce industrial process steam, high-temperature heat-transfer gases, and/or electricity. In conventional industrial processes, these products are generated by the combustion of fossil fuels such as coal and natural gas, resulting in significant emissions of greenhouse gases such as carbon dioxide. Heat or electricity produced in an HTGR could be used to supply process heat or electricity to conventional processes without generating any greenhouse gases. Process heat from a reactor needs to be transported by a gas to the industrial process. Two such gases were considered in this study: helium and steam. For this analysis, it was assumed that steam was delivered at 17 MPa and 540 C and helium was delivered at 7 MPa and at a variety of temperatures. The temperature of the gas returning from the industrial process and going to the HTGR must be within certain temperature ranges to maintain the correct reactor inlet temperature for a particular reactor outlet temperature. The returning gas may be below the reactor inlet temperature, ROT, but not above. The optimal return temperature produces the maximum process heat gas flow rate. For steam, the delivered pressure sets an optimal reactor outlet temperature based on the condensation temperature of the steam. ROTs greater than 769.7 C produce no additional advantage for the production of steam.

  4. Power systems development facility. Quarterly report, January 1995--March 1995

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: (1) Carbonizer/Pressurized Circulating Fluidized Bed Gas Source. (2) Hot Gas Cleanup Units to mate to all gas streams. (3) Combustion Gas Turbine. (4) Fuel Cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs.

  5. FEMO, A FLOW AND ENRICHMENT MONITOR FOR VERIFYING COMPLIANCE WITH INTERNATIONAL SAFEGUARDS REQUIREMENTS AT A GAS CENTRIFUGE ENRICHMENT FACILITY

    SciTech Connect (OSTI)

    Gunning, John E [ORNL; Laughter, Mark D [ORNL; March-Leuba, Jose A [ORNL

    2008-01-01T23:59:59.000Z

    A number of countries have received construction licenses or are contemplating the construction of large-capacity gas centrifuge enrichment plants (GCEPs). The capability to independently verify nuclear material flows is a key component of international safeguards approaches, and the IAEA does not currently have an approved method to continuously monitor the mass flow of 235U in uranium hexafluoride (UF6) gas streams. Oak Ridge National Laboratory is investigating the development of a flow and enrichment monitor, or FEMO, based on an existing blend-down monitoring system (BDMS). The BDMS was designed to continuously monitor both 235U mass flow and enrichment of UF6 streams at the low pressures similar to those which exists at GCEPs. BDMSs have been installed at three sites-the first unit has operated successfully in an unattended environment for approximately 10 years. To be acceptable to GCEP operators, it is essential that the instrument be installed and maintained without interrupting operations. A means to continuously verify flow as is proposed by FEMO will likely be needed to monitor safeguards at large-capacity plants. This will enable the safeguards effectiveness that currently exists at smaller plants to be maintained at the larger facilities and also has the potential to reduce labor costs associated with inspections at current and future plants. This paper describes the FEMO design requirements, operating capabilities, and development work required before field demonstration.

  6. Reanalysis of the gas-cooled fast reactor experiments at the zero power facility proteus - Spectral indices

    SciTech Connect (OSTI)

    Perret, G.; Pattupara, R. M. [Paul Scherrer Inst., 5232 Villigen (Switzerland); Girardin, G. [Ecole Polytechnique Federale de Lausanne, 1015 Lausanne (Switzerland); Chawla, R. [Paul Scherrer Inst., 5232 Villigen (Switzerland); Ecole Polytechnique Federale de Lausanne, 1015 Lausanne (Switzerland)

    2012-07-01T23:59:59.000Z

    The gas-cooled fast reactor (GCFR) concept was investigated experimentally in the PROTEUS zero power facility at the Paul Scherrer Inst. during the 1970's. The experimental program was aimed at neutronics studies specific to the GCFR and at the validation of nuclear data in fast spectra. A significant part of the program used thorium oxide and thorium metal fuel either distributed quasi-homogeneously in the reference PuO{sub 2}/UO{sub 2} lattice or introduced in the form of radial and axial blanket zones. Experimental results obtained at the time are still of high relevance in view of the current consideration of the Gas-cooled Fast Reactor (GFR) as a Generation-IV nuclear system, as also of the renewed interest in the thorium cycle. In this context, some of the experiments have been modeled with modern Monte Carlo codes to better account for the complex PROTEUS whole-reactor geometry and to allow validating recent continuous neutron cross-section libraries. As a first step, the MCNPX model was used to test the JEFF-3.1, JEFF-3.1.1, ENDF/B-VII.0 and JENDL-3.3 libraries against spectral indices, notably involving fission and capture of {sup 232}Th and {sup 237}Np, measured in GFR-like lattices. (authors)

  7. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  8. PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS Dr for Energy Efficiency and Renewable Energy Department of Mechanical and Industrial Engineering University of Massachusetts, Amherst, Massachusetts ABSTRACT The study was conducted to evaluate the energy use of natural gas

  9. Process for removal of hydrogen halides or halogens from incinerator gas

    DOE Patents [OSTI]

    Huang, H.S.; Sather, N.F.

    1987-08-21T23:59:59.000Z

    A process for reducing the amount of halogens and halogen acids in high temperature combustion gas and through their removal, the formation of halogenated organics at lower temperatures, with the reduction being carried out electrochemically by contacting the combustion gas with the negative electrode of an electrochemical cell and with the halogen and/or halogen acid being recovered at the positive electrode.

  10. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    Inherently, natural gas combustion produces significantlygas turbines were fuel gas combustion devices and that theyof greenhouse gas emissions released during combustion. 5 0

  11. WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION PROCESS

    SciTech Connect (OSTI)

    Maria Flytzani-Stephanopoulos; Xiaomei Qi; Scott Kronewitter

    2004-02-01T23:59:59.000Z

    This project involved fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H{sub 2} -separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams were examined in the project. Cu-cerium oxide was identified as the most promising high-temperature water-gas shift catalyst for integration with H{sub 2}-selective membranes. Formulations containing iron oxide were found to deactivate in the presence of CO{sub 2}. Cu-containing ceria catalysts, on the other hand, showed high stability in CO{sub 2}-rich gases. This type gas will be present over much of the catalyst, as the membrane removes the hydrogen produced from the shift reaction. The high-temperature shift catalyst composition was optimized by proper selection of dopant type and amount in ceria. The formulation 10at%Cu-Ce(30at%La)O{sub x} showed the best performance, and was selected for further kinetic studies. WGS reaction rates were measured in a simulated coal-gas mixture. The apparent activation energy, measured over aged catalysts, was equal to 70.2 kJ/mol. Reaction orders in CO, H{sub 2}O, CO{sub 2} and H{sub 2} were found to be 0.8, 0.2, -0.3, and -0.3, respectively. This shows that H{sub 2}O has very little effect on the reaction rate, and that both CO{sub 2} and H{sub 2} weakly inhibit the reaction. Good stability of catalyst performance was found in 40-hr long tests. A flat (38 cm{sup 2}) Pd-Cu alloy membrane reactor was used with the catalyst washcoated on oxidized aluminum screens close coupled with the membrane. To achieve higher loadings, catalyst granules were layered on the membrane itself to test the combined HTS activity/ H{sub 2} -separation efficiency of the composite. Simulated coal gas mixtures were used and the effect of membrane on the conversion of CO over the catalyst was evidenced at high space velocities. Equilibrium CO conversion at 400 C was measured at a space velocity of 30,000 h{sup -1} with the 10{micro}m- thick Pd{sub 60}Cu{sub 40} membrane operating under a pressure differential of 100 psi. No carbon deposition took place during operation. The performance of the coupled Cu-ceria catalyst/membrane system at 400 C was stable in {approx} 30 h of continuous operation. The overall conclusion from this project is that Cu-doped ceria catalysts are suitable for use in high-temperature water-gas shift membrane reactors. CO{sub 2}-rich operation does not affect the catalyst activity or stability; neither does it affect hydrogen permeation through the Pd-Cu membrane. Operation in the temperature range of 400-430 C is recommended.

  12. ANION ANALYSES BY ION CHROMATOGRAPHY FOR THE ALTERNATE REDUCTANT DEMONSTRATION FOR THE DEFENSE WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Best, D.

    2010-08-04T23:59:59.000Z

    The Process Science Analytical Laboratory (PSAL) at the Savannah River National Laboratory was requested by the Defense Waste Processing Facility (DWPF) to develop and demonstrate an Ion Chromatography (IC) method for the analysis of glycolate, in addition to eight other anions (fluoride, formate, chloride, nitrite, nitrate, sulfate, oxalate and phosphate) in Sludge Receipt and Adjustment Tank (SRAT) and Slurry Mix Evaporator (SME) samples. The method will be used to analyze anions for samples generated from the Alternate Reductant Demonstrations to be performed for the DWPF at the Aiken County Technology Laboratory (ACTL). The method is specific to the characterization of anions in the simulant flowsheet work. Additional work will be needed for the analyses of anions in radiological samples by Analytical Development (AD) and DWPF. The documentation of the development and demonstration of the method fulfills the third requirement in the TTQAP, SRNL-RP-2010-00105, 'Task Technical and Quality Assurance Plan for Glycolic-Formic Acid Flowsheet Development, Definition and Demonstrations Tasks 1-3'.

  13. Process Parameters and Energy Use of Gas and Electric Ovens in Industrial Applications

    E-Print Network [OSTI]

    Kosanovic, D.; Ambs, L.

    for industrial applications where electric ovens have predominant use. Tests were performed to obtain the process efficiency and examine cost savings potential in converting electric ovens to natural gas. Preliminary results show that, for the plat studied, cost...

  14. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, T.F.; Robin, A.M.; Wolfenbarger, J.K.; Suggitt, R.M.

    1995-03-28T23:59:59.000Z

    A partial oxidation process is described for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H{sub 2}, CO, CO{sub 2}, H{sub 2}O, CH{sub 4}, NH{sub 3}, HCl, HF, H{sub 2}S, COS, N{sub 2}, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N{sub 2} and H{sub 2}. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000 F. 1 figure.

  15. Partial oxidation process for producing a stream of hot purified gas

    DOE Patents [OSTI]

    Leininger, Thomas F. (Chino Hills, CA); Robin, Allen M. (Anaheim, CA); Wolfenbarger, James K. (Torrance, CA); Suggitt, Robert M. (Wappingers Falls, NY)

    1995-01-01T23:59:59.000Z

    A partial oxidation process for the production of a stream of hot clean gas substantially free from particulate matter, ammonia, alkali metal compounds, halides and sulfur-containing gas for use as synthesis gas, reducing gas, or fuel gas. A hydrocarbonaceous fuel comprising a solid carbonaceous fuel with or without liquid hydrocarbonaceous fuel or gaseous hydrocarbon fuel, wherein said hydrocarbonaceous fuel contains halides, alkali metal compounds, sulfur, nitrogen and inorganic ash containing components, is reacted in a gasifier by partial oxidation to produce a hot raw gas stream comprising H.sub.2, CO, CO.sub.2, H.sub.2 O, CH.sub.4, NH.sub.3, HCl, HF, H.sub.2 S, COS, N.sub.2, Ar, particulate matter, vapor phase alkali metal compounds, and molten slag. The hot raw gas stream from the gasifier is split into two streams which are separately deslagged, cleaned and recombined. Ammonia in the gas mixture is catalytically disproportionated into N.sub.2 and H.sub.2. The ammonia-free gas stream is then cooled and halides in the gas stream are reacted with a supplementary alkali metal compound to remove HCl and HF. Alkali metal halides, vaporized alkali metal compounds and residual fine particulate matter are removed from the gas stream by further cooling and filtering. The sulfur-containing gases in the process gas stream are then reacted at high temperature with a regenerable sulfur-reactive mixed metal oxide sulfur sorbent material to produce a sulfided sorbent material which is then separated from the hot clean purified gas stream having a temperature of at least 1000.degree. F.

  16. Automation of process accountability flow diagrams at Los Alamos National Laboratory's Plutonium Facility

    SciTech Connect (OSTI)

    Knepper, P.; Whiteson, R.; Strittmatter, R.; Mousseau, K.

    1999-07-01T23:59:59.000Z

    Many industrial processes (including reprocessing activities; nuclear fuel fabrication; and material storage, measurement and transfer) make use of process flow diagrams. These flows can be used for material accountancy and for data analysis. At Los Alamos National Laboratory (LANL), the Technical Area (TA)-55 Plutonium Facility is home to various research and development activities involving the use of special nuclear material (SNM). A facility conducting research and development (R and D) activities using SNM must satisfy material accountability guidelines. All processes involving SNM or tritium processing, at LANL, require a process accountability flow diagram (PAFD). At LANL a technique was developed to generate PAFDs that can be coupled to a relational database for use in material accountancy. These techniques could also be used for propagation of variance, measurement control, and inventory difference analysis. The PAFD is a graphical representation of the material flow during a specific process. PAFDs are currently stored as PowerPoint files. In the PowerPoint format, the data captured by the PAFD are not easily accessible. Converting the PAFDs to an accessible electronic format is desirable for several reasons. Any program will be able to access the data contained in the PAFD. For the PAFD data to be useful in applications such as an expert system for data checking, SNM accountability, inventory difference evaluation, measurement control, and other kinds of analysis, it is necessary to interface directly with the information contained within the PAFD. The PAFDs can be approved and distributed electronically, eliminating the paper copies of the PAFDs and ensuring that material handlers have the current PAFDs. Modifications to the PAFDs are often global. Storing the data in an accessible format would eliminate the need to manually update each of the PAFDs when a global change has occurred. The goal was to determine a software package that would store the PAFDs in an accessible format that could be interfaced by various programs. After evaluating several commercial relational database and graphing software packages, VISIO Enterprise was selected. LANL is in the process of completing conversion of the existing PAFDs into VISIO Enterprise. A number of the PAFDs have been converted to VISIO Enterprise, and the data from the drawings have been exported to an ACCESS database. After the conversion has taken place, the data contained in the PAFDs will be accessible for various programs. The data that was once stored in PowerPoint will now be available for tools, including expert analysis, propagation of a variance, SNM accountability, inventory difference analysis, measurement control, and other analysis tools that have yet to be identified. Converting from the PowerPoint format to a drawing stored as a relational database will improve the ability of plant personnel to interface with the PAFD.

  17. Process Intensification with Integrated Water-Gas-Shift Membrane...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Key Energy Challenges Across U.S. Industry Energy-Intensive Processes Portfolio: Addressing Key Energy Challenges Across U.S. Industry Gasification Systems 2013 Project Selections...

  18. Thermal Analysis of the Divertor Primary Heat Transfer System Piping During the Gas Baking Process

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L [ORNL; Harvey, Karen [ORNL; Ferrada, Juan J [ORNL

    2011-02-01T23:59:59.000Z

    A preliminary analysis has been performed examining the temperature distribution in the Divertor Primary Heat Transfer System (PHTS) piping and the divertor itself during the gas baking process. During gas baking, it is required that the divertor reach a temperature of 350 C. Thermal losses in the piping and from the divertor itself require that the gas supply temperature be maintained above that temperature in order to ensure that all of the divertor components reach the required temperature. The analysis described in this report was conducted in order to estimate the required supply temperature from the gas heater.

  19. Direct chlorination process for geothermal power plant off-gas - hydrogen sulfide abatement

    SciTech Connect (OSTI)

    Sims, A.V.

    1983-06-01T23:59:59.000Z

    The Direct Chlorination Process removes hydrogen sulfide from geothermal off-gases by reacting hydrogen sulfide with chlorine in the gas phase. Hydrogen chloride and elemental sulfur are formed by this reaction. The Direct Chlorination Process has been successfully demonstrated by an on-site operation of a pilot plant at the 3 M We HPG-A geothermal power plant in the Puna District on the island of Hawaii. Over 99.5 percent hydrogen sulfide removal was achieved in a single reaction state. Chlorine gas did not escape the pilot plant, even when 90 percent excess chlorine gas was used. A preliminary economic evaluation of the Direct Chlorination Process indicates that it is very competitive with the Stretford Process. Compared to the Stretford Process, the Direct Chlorination Process requires about one-third the initial capital investment and about one-fourth the net daily expenditure.

  20. Wyoming Natural Gas Processed in Wyoming (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved Reserves (Billion Cubic Feet)Wyoming (Million Cubic Feet) Wyoming Natural Gas

  1. Texas Onshore-Kansas Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2perSep-14Base Gas)(Million Cubic2011 2012

  2. Texas Onshore-New Mexico Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2perSep-14Base Gas)(Million Cubic2011 2012

  3. Texas Onshore-Oklahoma Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2perSep-14Base Gas)(Million Cubic2011

  4. Texas Onshore-Texas Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2perSep-14Base Gas)(Million

  5. Kentucky-West Virginia Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14 15IndustrialVehicleThousand60,941

  6. Louisiana Offshore-Louisiana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14343 342 3289886,084 889,570 893,400 2012

  7. Louisiana Onshore-Louisiana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14343 342 3289886,084 889,570

  8. Louisiana Onshore-Texas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 14343 342 3289886,084 889,5705,020 4,583 4,920

  9. Montana-North Dakota Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 04 19343 369 384FuelYear125 137 1861,185

  10. Gulf of Mexico-Alabama Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 058.5

  11. Gulf of Mexico-Louisiana Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 058.588,219 719,435 2012-2013 Total

  12. Gulf of Mexico-Mississippi Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 058.588,219 719,435 2012-2013 Total1,618

  13. Gulf of Mexico-Texas Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 6330 0 1 0 058.588,219 719,435 2012-2013

  14. Pennsylvania-West Virginia Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas,095,3628,527 9,029Cubic(Dollars per Thousand Cubic 0 0Cubic2011

  15. California Onshore-California Natural Gas Plant Processing

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 566 (Million0,515,162180,648 169,203 164,401

  16. New Mexico-New Mexico Natural Gas Plant Processing

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet) Year Jan FebFeet) DecadeFeet) Working Natural Gas795,069

  17. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    DOE Patents [OSTI]

    Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

    2012-05-15T23:59:59.000Z

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  18. Qualification of the Nippon Instrumentation for use in Measuring Mercury at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Edwards, T.; Mahannah, R.

    2011-07-05T23:59:59.000Z

    The Nippon Mercury/RA-3000 system installed in 221-S M-14 has been qualified for use. The qualification was a side-by-side comparison of the Nippon Mercury/RA-3000 system with the currently used Bacharach Mercury Analyzer. The side-by-side testing included standards for instrument calibration verifications, spiked samples and unspiked samples. The standards were traceable back to the National Institute of Standards and Technology (NIST). The side-by-side work included the analysis of Sludge Receipt and Adjustment Tank (SRAT) Receipt, SRAT Product, and Slurry Mix Evaporator (SME) samples. With the qualification of the Nippon Mercury/RA-3000 system in M-14, the DWPF lab will be able to perform a head to head comparison of a second Nippon Mercury/RA-3000 system once the system is installed. The Defense Waste Processing Facility (DWPF) analyzes receipt and product samples from the Sludge Receipt and Adjustment Tank (SRAT) to determine the mercury (Hg) concentration in the sludge slurry. The SRAT receipt is typically sampled and analyzed for the first ten SRAT batches of a new sludge batch to obtain an average Hg concentration. This average Hg concentration is then used to determine the amount of steam stripping required during the concentration/reflux step of the SRAT cycle to achieve a less than 0.6 wt% Hg in the SRAT product solids. After processing is complete, the SRAT product is sampled and analyzed for mercury to ensure that the mercury concentration does not exceed the 0.45 wt% limit in the Slurry Mix Evaporator (SME). The DWPF Laboratory utilizes Bacharach Analyzers to support these Hg analyses at this facility. These analyzers are more than 10 years old, and they are no longer supported by the manufacturer. Due to these difficulties, the Bacharach Analyzers are to be replaced by new Nippon Mercury/RA-3000 systems. DWPF issued a Technical Task Request (TTR) for the Savannah River National Laboratory (SRNL) to assist in the qualification of the new systems. SRNL prepared a task technical and quality assurance (TT&QA) plan that outlined the activities that are necessary and sufficient to meet the objectives of the TTR. In addition, TT&QA plan also included a test plan that provided guidance to the DWPF Lab in collecting the data needed to qualify the new Nippon Mercury/RA-3000 systems.

  19. Gasoline from natural gas by sulfur processing. Final technical report, June 1993--July 1996

    SciTech Connect (OSTI)

    Erekson, E.J.

    1996-07-01T23:59:59.000Z

    The overall objective of this research project was to develop a catalytic process to convert natural gas to liquid transportation fuels. The process, called the HSM (Hydrogen Sulfide-Methane) Process, consists of two steps that each use catalysts and sulfur-containing intermediates: (1) to convert natural gas to CS{sub 2} and (2) to convert CS{sub 2} to gasoline-range liquids. Experimental data generated in this project were for use in evaluating the commercial potential of the process.

  20. OPS 9.13 Operations Aspects of Facility Chemistry and Unique Processes 8/24/98

    Broader source: Energy.gov [DOE]

    The objective of this surveillance is to ensure that the contractor has provided for an effective interface between facility operations personnel and personnel responsible for operation of...

  1. CONTAMINATED PROCESS EQUIPMENT REMOVAL FOR THE D&D OF THE 232-Z CONTAMINATED WASTE RECOVERY PROCESS FACILITY AT THE PLUTONIUM FINISHING PLANT (PFP)

    SciTech Connect (OSTI)

    HOPKINS, A.M.; MINETTE, M.J.; KLOS, D.B.

    2007-01-25T23:59:59.000Z

    This paper describes the unique challenges encountered and subsequent resolutions to accomplish the deactivation and decontamination of a plutonium ash contaminated building. The 232-Z Contaminated Waste Recovery Process Facility at the Plutonium Finishing Plant was used to recover plutonium from process wastes such as rags, gloves, containers and other items by incinerating the items and dissolving the resulting ash. The incineration process resulted in a light-weight plutonium ash residue that was highly mobile in air. This light-weight ash coated the incinerator's process equipment, which included gloveboxes, blowers, filters, furnaces, ducts, and filter boxes. Significant airborne contamination (over 1 million derived air concentration hours [DAC]) was found in the scrubber cell of the facility. Over 1300 grams of plutonium held up in the process equipment and attached to the walls had to be removed, packaged and disposed. This ash had to be removed before demolition of the building could take place.

  2. Reduce Natural Gas Use in Your Industrial Process Heating Systems

    SciTech Connect (OSTI)

    Not Available

    2007-09-01T23:59:59.000Z

    This DOE Industrial Program fact sheet describes ten effective ways to save energy and money in industrial process heating systems by making some changes in equipment, operations, and maintenance.

  3. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07T23:59:59.000Z

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  4. DWPF (Defense Waste Processing Facility) canister impact testing and analyses for the Transportation Technology Center

    SciTech Connect (OSTI)

    Farnsworth, R.K.; Mishima, J.

    1988-12-01T23:59:59.000Z

    A legal weight truck cask design has been developed for the US Department of Energy by GA Technologies, Inc. The cask will be used to transport defense high-level waste canisters produced by the Defense Waste Processing Facility (DWPF) at the Savannah River Plant. The development of the cask required the collection of impact data for the DWPF canisters. The Materials Characterization Center (MCC) performed this work under the guidance of the Transportation Technology Center (TTC) at Sandia National Laboratories. Two full-scale DWPF canisters filled with nonradioactive borosilicate glass were impacted under ''normal'' and ''hypothetical'' accident conditions. Two canisters, supplied by the DWPF, were tested. Each canister was vertically dropped on the bottom end from a height of either 0.3 m or 9.1 m (for normal or hypothetical accident conditions, respectively). The structural integrity of each canister was then examined using helium leak and dye penetrant testing. The canisters' diameters and heights, which had been previously measured, were then remeasured to determine how the canister dimensions had changed. Following structural integrity testing, the canisters were flaw leak tested. For transportation flaw leak testing, four holes were fabricated into the shell of canister A-27 (0.3 m drop height). The canister was then transported a total distance of 2069 miles. During transport, the waste form material that fell from each flaw was collected to determine the amount of size distribution of each flaw release. 2 refs., 8 figs., 12 tabs.

  5. CHARACTERIZATION OF A PRECIPITATE REACTOR FEED TANK (PRFT) SAMPLE FROM THE DEFENSE WASTE PROCESSING FACILITY (DWPF)

    SciTech Connect (OSTI)

    Crawford, C.; Bannochie, C.

    2014-05-12T23:59:59.000Z

    A sample of from the Defense Waste Processing Facility (DWPF) Precipitate Reactor Feed Tank (PRFT) was pulled and sent to the Savannah River National Laboratory (SRNL) in June of 2013. The PRFT in DWPF receives Actinide Removal Process (ARP)/ Monosodium Titanate (MST) material from the 512-S Facility via the 511-S Facility. This 2.2 L sample was to be used in small-scale DWPF chemical process cell testing in the Shielded Cells Facility of SRNL. A 1L sub-sample portion was characterized to determine the physical properties such as weight percent solids, density, particle size distribution and crystalline phase identification. Further chemical analysis of the PRFT filtrate and dissolved slurry included metals and anions as well as carbon and base analysis. This technical report describes the characterization and analysis of the PRFT sample from DWPF. At SRNL, the 2.2 L PRFT sample was composited from eleven separate samples received from DWPF. The visible solids were observed to be relatively quick settling which allowed for the rinsing of the original shipping vials with PRFT supernate on the same day as compositing. Most analyses were performed in triplicate except for particle size distribution (PSD), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and thermogravimetric analysis (TGA). PRFT slurry samples were dissolved using a mixed HNO3/HF acid for subsequent Inductively Coupled Plasma Atomic Emission Spectroscopy (ICPAES) and Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) analyses performed by SRNL Analytical Development (AD). Per the task request for this work, analysis of the PRFT slurry and filtrate for metals, anions, carbon and base were primarily performed to support the planned chemical process cell testing and to provide additional component concentrations in addition to the limited data available from DWPF. Analysis of the insoluble solids portion of the PRFT slurry was aimed at detailed characterization of these solids (TGA, PSD, XRD and SEM) in support of the Salt IPT chemistry team. The overall conclusions from analyses performed in this study are that the PRFT slurry consists of 0.61 Wt.% insoluble MST solids suspended in a 0.77 M [Na+] caustic solution containing various anions such as nitrate, nitrite, sulfate, carbonate and oxalate. The corresponding measured sulfur level in the PRFT slurry, a critical element for determining how much of the PRFT slurry gets blended into the SRAT, is 0.437 Wt.% TS. The PRFT slurry does not contain insoluble oxalates nor significant quantities of high activity sludge solids. The lack of sludge solids has been alluded to by the Salt IPT chemistry team in citing that the mixing pump has been removed from Tank 49H, the feed tank to ARP-MCU, thus allowing the sludge solids to settle out. ? The PRFT aqueous slurry from DWPF was found to contain 5.96 Wt.% total dried solids. Of these total dried solids, relatively low levels of insoluble solids (0.61 Wt.%) were measured. The densities of both the filtrate and slurry were 1.05 g/mL. ? Particle size distribution of the PRFT solids in filtered caustic simulant and XRD analysis of washed/dried PRFT solids indicate that the PRFT slurry contains a bimodal distribution of particles in the range of 1 and 6 ?m and that the particles contain sodium titanium oxide hydroxide Na2Ti2O4(OH)2 crystalline material as determined by XRD. These data are in excellent agreement with similar data obtained from laboratory sampling of vendor supplied MST. Scanning Electron Microscopy (SEM) combined with Energy Dispersive X-ray Spectroscopy (EDS) analysis of washed/dried PRFT solids shows the particles to be like previous MST analyses consisting of irregular shaped micron-sized solids consisting primarily of Na and Ti. ? Thermogravimetric analysis of the washed and unwashed PRFT solids shows that the washed solids are very similar to MST solids. The TGA mass loss signal for the unwashed solids shows similar features to TGA performed on cellulose nitrate filter paper indicating significant presence of the deteriorated filter

  6. Screening study for waste biomass to ethanol production facility using the Amoco process in New York State. Final report

    SciTech Connect (OSTI)

    NONE

    1995-08-01T23:59:59.000Z

    This report evaluates the economic feasibility of locating biomass-to-ethanol waste conversion facilities in New York State. Part 1 of the study evaluates 74 potential sites in New York City and identifies two preferred sites on Staten, the Proctor Gamble and the Arthur Kill sites, for further consideration. Part 2 evaluates upstate New York and determines that four regions surrounding the urban centers of Albany, Buffalo, Rochester, and Syracuse provide suitable areas from which to select specific sites for further consideration. A separate Appendix provides supplemental material supporting the evaluations. A conceptual design and economic viability evaluation were developed for a minimum-size facility capable of processing 500 tons per day (tpd) of biomass consisting of wood or paper, or a combination of the two for upstate regions. The facility would use Amoco`s biomass conversion technology and produce 49,000 gallons per day of ethanol and approximately 300 tpd of lignin solid by-product. For New York City, a 1,000-tpd processing facility was also evaluated to examine effects of economies of scale. The reports evaluate the feasibility of building a biomass conversion facility in terms of city and state economic, environmental, and community factors. Given the data obtained to date, including changing costs for feedstock and ethanol, the project is marginally attractive. A facility should be as large as possible and located in a New York State Economic Development Zone to take advantage of economic incentives. The facility should have on-site oxidation capabilities, which will make it more financially viable given the high cost of energy. 26 figs., 121 tabs.

  7. Process and apparatus for separation of components of a gas stream

    SciTech Connect (OSTI)

    Bryan, Charles R.; Torczynski, John R.; Brady, Patrick V.; Gallis, Michail; Brooks, Carlton F.

    2014-06-17T23:59:59.000Z

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  8. Process and apparatus for separation of components of a gas stream

    SciTech Connect (OSTI)

    Bryan, Charles R; Torczynski, John R; Brady, Patrick V; Gallis, Michail; Brooks, Carlton F

    2013-09-17T23:59:59.000Z

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  9. Process and apparatus for separation of components of a gas stream

    DOE Patents [OSTI]

    Bryan, Charles R; Torczynski, John R; Brady, Patrick V; Gallis, Michail; Brooks, Carlton F

    2013-11-19T23:59:59.000Z

    A process and apparatus for separating a gas mixture comprising providing a slot in a gas separation channel (conceptualized as a laterally elongated Clusius-Dickel column), having a length through which a net cross-flow of the gas mixture may be established; applying a higher temperature to one side of the channel and a lower temperature on an opposite side of the channel thereby causing thermal-diffusion and buoyant-convection flow to occur in the slot; and establishing a net cross-flow of a gas mixture comprising at least one higher density gas component and at least one lower density gas component along the length of the slot, wherein the cross-flow causes, in combination with the convection flow, a spiraling flow in the slot; and wherein the spiral flow causes an increasing amount of separation of the higher density gas from the lower density gas along the length of the channel. The process may use one or more slots and/or channels.

  10. Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

  11. 1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important when

    E-Print Network [OSTI]

    Stenstrom, Michael K.

    1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important = CL (CL + HcVG) (6) where CL = liquid phase concentration, VL = liquid volume, CG = gas phase concentration, VG = gas volume, Hc = dimensionless Henry's law coefficient and M = mass of gas. Now use two

  12. Proceedings of the 1st Annual Gas Processing Symposium

    E-Print Network [OSTI]

    Foss, Bjarne A.

    -Halwagi (Editors) © 2009 Elsevier B.V. All rights reserved. 1 Dynamic optimization of the LNG value chain Bjarne A where the upstream part of the system and the LNG process plant are optimized individually. The system at the Snøhvit LNG plant. Use of these quite simple models combined with model-based optimization offers

  13. Dutch gas plant uses polymer process to treat aromatic-saturated water

    SciTech Connect (OSTI)

    NONE

    1998-11-02T23:59:59.000Z

    A gas-processing plant in Harlingen, The Netherlands, operated by Elf Petroland has been running a porous-polymer extraction process since 1994 to remove aromatic compounds from water associated with produced natural gas. In the period, the unit has removed dispersed and dissolved aromatic compounds to a concentration of <1 ppm with energy consumption of only 17% that of a steam stripper, according to Paul Brooks, general manager for Akzo Nobel`s Macro Porous Polymer-Extraction (MPPE) systems. The paper describes glycol treatment the MPPE separation process, and the service contract for the system.

  14. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    SciTech Connect (OSTI)

    Lee Nelson

    2011-09-01T23:59:59.000Z

    This report is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas cooled reactor (HTGR) technology into industrial processes. To avoid an overly optimistic environmental and economic baseline for comparing nuclear integrated and conventional processes, a conservative approach was used for the assumptions and calculations.

  15. Process Intensification with Integrated Water-Gas-Shift Membrane Reactor

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d FNEPA/309Department of EnergyProcess

  16. VolumeExplorer: Roaming Large Volumes to Couple Visualization and Data Processing for Oil and Gas Exploration

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    VolumeExplorer: Roaming Large Volumes to Couple Visualization and Data Processing for Oil and Gas dedicated to oil and gas exploration. Our system combines probe- based volume rendering with data processing Seismic interpretation is an important task in the oil and gas exploration-production (EP) workflow [9, 26

  17. Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration

    DOE Patents [OSTI]

    Golden, Timothy Christopher; Weist Jr., Edward Landis; Hufton, Jeffrey Raymond; Novosat, Paul Anthony

    2010-04-13T23:59:59.000Z

    A process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality of adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

  18. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    gas emissions from conven- tional power sources like coal.total emissions from coal- or natural gas-fired power plantsemissions, the lifecycle for natural gas power production is more complicated than that of coal.

  19. New Mexico Natural Gas Processed (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007 10,998 9,933 10,998 10,643 10,998through 1996) in KansasYearDecade Year-0IndustrialThousandProcessed

  20. Tennessee Natural Gas Processed in Tennessee (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear Jan FebThousandProcessed (Million Cubic Feet) Tennessee Naturalin

  1. Ohio Natural Gas Processed in Ohio (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper Thousand CubicProcessed (Million Cubic Feet) OhioOhio

  2. Ohio Natural Gas Processed in West Virginia (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper Thousand CubicProcessed (Million Cubic Feet)

  3. Pennsylvania Natural Gas Processed in Pennsylvania (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper8,170 8,310 8,304 8,368Processed (Million Cubic

  4. Pennsylvania Natural Gas Processed in West Virginia (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper8,170 8,310 8,304 8,368Processed (Million CubicWest

  5. Gulf Of Mexico Natural Gas Processed (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) YearfromProcessed (Million Cubic

  6. Louisiana Offshore Natural Gas Processed in Louisiana (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear(Billion CubicDecadeYear JanProcessed in

  7. Louisiana Onshore Natural Gas Processed in Louisiana (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear(Billion CubicDecadeYear JanProcessed

  8. Louisiana Onshore Natural Gas Processed in Texas (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear(Billion CubicDecadeYear JanProcessedTexas

  9. U.S. Total Imports Natural Gas Plant Processing

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2007York"Hawaii" "Sector", (MillionDecadeDecadeDecreases (BillionPlant Processing Area:

  10. Surfactant based imbibition and induced solution gas drive process: investigation by nuclear magnetic resonance

    E-Print Network [OSTI]

    Cox, James Calvin

    1993-01-01T23:59:59.000Z

    drive mechanism. This imbibition and induced solution gas drive study employed nuclear magnetic resonance (NMR) spectroscopy techniques to monitor and characterize the progress of oil recovery inside the rock sample core. A specially designed core...SURFACTANT BASED IMBIBITION AND INDUCED SOLUTION GAS DRIVE PROCESS: INVESTIGATION BY NUCLEAR MAGNETIC RESONANCE A Thesis by JAMES CALVIN COX Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  11. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

    2012-03-06T23:59:59.000Z

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  12. HANFORD CONTAINERIZED CAST STONE FACILITY TASK 1 PROCESS TESTING & DEVELOPMENT FINAL TEST REPORT

    SciTech Connect (OSTI)

    LOCKREM, L L

    2005-07-13T23:59:59.000Z

    Laboratory testing and technical evaluation activities on Containerized Cast Stone (CCS) were conducted under the Scope of Work (SOW) contained in CH2M HILL Hanford Group, Inc. (CHG) Contract No. 18548 (CHG 2003a). This report presents the results of testing and demonstration activities discussed in SOW Section 3.1, Task I--''Process Development Testing'', and described in greater detail in the ''Containerized Grout--Phase I Testing and Demonstration Plan'' (CHG, 2003b). CHG (2003b) divided the CCS testing and evaluation activities into six categories, as follows: (1) A short set of tests with simulant to select a preferred dry reagent formulation (DRF), determine allowable liquid addition levels, and confirm the Part 2 test matrix. (2) Waste form performance testing on cast stone made from the preferred DRF and a backup DRF, as selected in Part I, and using low activity waste (LAW) simulant. (3) Waste form performance testing on cast stone made from the preferred DRF using radioactive LAW. (4) Waste form validation testing on a selected nominal cast stone formulation using the preferred DRF and LAW simulant. (5) Engineering evaluations of explosive/toxic gas evolution, including hydrogen, from the cast stone product. (6) Technetium ''getter'' testing with cast stone made with LAW simulant and with radioactive LAW. In addition, nitrate leaching observations were drawn from nitrate leachability data obtained in the course of the Parts 2 and 3 waste form performance testing. The nitrate leachability index results are presented along with other data from the applicable activity categories.

  13. Elimination Of Catalytic Hydrogen Generation In Defense Waste Processing Facility Slurries

    SciTech Connect (OSTI)

    Koopman, D. C.

    2013-01-22T23:59:59.000Z

    Based on lab-scale simulations of Defense Waste Processing Facility (DWPF) slurry chemistry, the addition of sodium nitrite and sodium hydroxide to waste slurries at concentrations sufficient to take the aqueous phase into the alkaline region (pH > 7) with approximately 500 mg nitrite ion/kg slurry (assuming <25 wt% total solids, or equivalently 2,000 mg nitrite/kg total solids) is sufficient to effectively deactivate the noble metal catalysts at temperatures between room temperature and boiling. This is a potential strategy for eliminating catalytic hydrogen generation from the list of concerns for sludge carried over into the DWPF Slurry Mix Evaporator Condensate Tank (SMECT) or Recycle Collection Tank (RCT). These conclusions are drawn in large part from the various phases of the DWPF catalytic hydrogen generation program conducted between 2005 and 2009. The findings could apply to various situations, including a solids carry-over from either the Sludge Receipt and Adjustment Tank (SRAT) or Slurry Mix Evaporator (SME) into the SMECT with subsequent transfer to the RCT, as well as a spill of formic acid into the sump system and transfer into an RCT that already contains sludge solids. There are other potential mitigating factors for the SMECT and RCT, since these vessels are typically operated at temperatures close to the minimum temperatures that catalytic hydrogen has been observed to occur in either the SRAT or SME (pure slurry case), and these vessels are also likely to be considerably more dilute in both noble metals and formate ion (the two essential components to catalytic hydrogen generation) than the two primary process vessels. Rhodium certainly, and ruthenium likely, are present as metal-ligand complexes that are favored under certain concentrations of the surrounding species. Therefore, in the SMECT or RCT, where a small volume of SRAT or SME material would be significantly diluted, conditions would be less optimal for forming or sustaining the catalytic ligand species. Such conditions are likely to adversely impact the ability of the transferred mass to produce hydrogen at the same rate (per unit mass SRAT or SME slurry) as in the SRAT or SME vessels.

  14. Processing capabilties for the elimination of contaminated metal scrapyards at DOE/ORO-managed sites. [Metal smelting facility

    SciTech Connect (OSTI)

    Mack, J.E.; Williams, L.C.

    1982-01-01T23:59:59.000Z

    Capabilities exist for reducing all the contaminated nickel, aluminum, and copper scrap to ingot form by smelting. Processing these metals at existing facilities could be completed in about 5 or 6 years. However, these metals represent only about 20% of the total metal inventories currently on hand at the DOE/ORO-managed sites. No provisions have been made for the ferrous scrap. Most of the ferrous scrap is unclassified and does not require secured storage. Also, the potential resale value of the ferrous scrap at about $100 per ton is very low in comparison. Consequently, this scrap has been allowed to accumulate. With several modifications and equipment additions, the induction melter at PGDP could begin processing ferrous scrap after its commitment to nickel and aluminum. The PGDP smelter is a retrofit installation, and annual throughput capabilities are limited. Processing of the existing ferrous scrap inventories would not be completed until the FY 1995-2000 time frame. An alternative proposal has been the installation of induction melters at the other two enrichment facilities. Conceptual design of a generic metal smelting facility is under way. The design study includes capital and operating costs for scrap preparation through ingot storage at an annual throughput of 10,000 tons per year. Facility design includes an induction melter with the capability of melting both ferrous and nonferrous metals. After three years of operation with scrapyard feed, the smelter would have excess capacity to support on-site decontamination and decomissioning projects or upgrading programs. The metal smelting facility has been proposed for FY 1984 line item funding with start-up operations in FY 1986.

  15. Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Wagirin Ruiz Paidin; Thaer N. N. Mahmoud; Daryl S. Sequeira; Amit P. Sharma

    2006-09-30T23:59:59.000Z

    This is the final report describing the evolution of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' from its conceptual stage in 2002 to the field implementation of the developed technology in 2006. This comprehensive report includes all the experimental research, models developments, analyses of results, salient conclusions and the technology transfer efforts. As planned in the original proposal, the project has been conducted in three separate and concurrent tasks: Task 1 involved a physical model study of the new GAGD process, Task 2 was aimed at further developing the vanishing interfacial tension (VIT) technique for gas-oil miscibility determination, and Task 3 was directed at determining multiphase gas-oil drainage and displacement characteristics in reservoir rocks at realistic pressures and temperatures. The project started with the task of recruiting well-qualified graduate research assistants. After collecting and reviewing the literature on different aspects of the project such gas injection EOR, gravity drainage, miscibility characterization, and gas-oil displacement characteristics in porous media, research plans were developed for the experimental work to be conducted under each of the three tasks. Based on the literature review and dimensional analysis, preliminary criteria were developed for the design of the partially-scaled physical model. Additionally, the need for a separate transparent model for visual observation and verification of the displacement and drainage behavior under gas-assisted gravity drainage was identified. Various materials and methods (ceramic porous material, Stucco, Portland cement, sintered glass beads) were attempted in order to fabricate a satisfactory visual model. In addition to proving the effectiveness of the GAGD process (through measured oil recoveries in the range of 65 to 87% IOIP), the visual models demonstrated three possible multiphase mechanisms at work, namely, Darcy-type displacement until gas breakthrough, gravity drainage after breakthrough and film-drainage in gas-invaded zones throughout the duration of the process. The partially-scaled physical model was used in a series of experiments to study the effects of wettability, gas-oil miscibility, secondary versus tertiary mode gas injection, and the presence of fractures on GAGD oil recovery. In addition to yielding recoveries of up to 80% IOIP, even in the immiscible gas injection mode, the partially-scaled physical model confirmed the positive influence of fractures and oil-wet characteristics in enhancing oil recoveries over those measured in the homogeneous (unfractured) water-wet models. An interesting observation was that a single logarithmic relationship between the oil recovery and the gravity number was obeyed by the physical model, the high-pressure corefloods and the field data.

  16. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Franklin M. Orr, Jr.

    2004-05-01T23:59:59.000Z

    This final technical report describes and summarizes results of a research effort to investigate physical mechanisms that control the performance of gas injection processes in heterogeneous reservoirs and to represent those physical effects in an efficient way in simulations of gas injection processes. The research effort included four main lines of research: (1) Efficient compositional streamline methods for 3D flow; (2) Analytical methods for one-dimensional displacements; (3) Physics of multiphase flow; and (4) Limitations of streamline methods. In the first area, results are reported that show how the streamline simulation approach can be applied to simulation of gas injection processes that include significant effects of transfer of components between phases. In the second area, the one-dimensional theory of multicomponent gas injection processes is extended to include the effects of volume change as components change phase. In addition an automatic algorithm for solving such problems is described. In the third area, results on an extensive experimental investigation of three-phase flow are reported. The experimental results demonstrate the impact on displacement performance of the low interfacial tensions between the gas and oil phases that can arise in multicontact miscible or near-miscible displacement processes. In the fourth area, the limitations of the streamline approach were explored. Results of an experimental investigation of the scaling of the interplay of viscous, capillary, and gravity forces are described. In addition results of a computational investigation of the limitations of the streamline approach are reported. The results presented in this report establish that it is possible to use the compositional streamline approach in many reservoir settings to predict performance of gas injection processes. When that approach can be used, it requires substantially less (often orders of magnitude) computation time than conventional finite difference compositional simulation.

  17. Investigation of Integrated Subsurface Processing of Landfill Gas and Carbon Sequestration, Johnson County, Kansas

    SciTech Connect (OSTI)

    K. David Newell; Timothy R. Carr

    2007-03-31T23:59:59.000Z

    The Johnson County Landfill in Shawnee, KS is operated by Deffenbaugh Industries and serves much of metropolitan Kansas City. Refuse, which is dumped in large plastic-underlined trash cells covering several acres, is covered over with shale shortly after burial. The landfill waste, once it fills the cell, is then drilled by Kansas City LFG, so that the gas generated by anaerobic decomposition of the refuse can be harvested. Production of raw landfill gas from the Johnson County landfill comes from 150 wells. Daily production is approximately 2.2 to 2.5 mmcf, of which approximately 50% is methane and 50% is carbon dioxide and NMVOCs (non-methane volatile organic compounds). Heating value is approximately 550 BTU/scf. A upgrading plant, utilizing an amine process, rejects the carbon dioxide and NMVOCs, and upgrades the gas to pipeline quality (i.e., nominally a heating value >950 BTU/scf). The gas is sold to a pipeline adjacent to the landfill. With coal-bearing strata underlying the landfill, and carbon dioxide a major effluent gas derived from the upgrading process, the Johnson County Landfill is potentially an ideal setting to study the feasibility of injecting the effluent gas in the coals for both enhanced coalbed methane recovery and carbon sequestration. To these ends, coals below the landfill were cored and then were analyzed for their thickness and sorbed gas content, which ranged up to 79 scf/ton. Assuming 1 1/2 square miles of land (960 acres) at the Johnson County Landfill can be utilized for coalbed and shale gas recovery, the total amount of in-place gas calculates to 946,200 mcf, or 946.2 mmcf, or 0.95 bcf (i.e., 985.6 mcf/acre X 960 acres). Assuming that carbon dioxide can be imbibed by the coals and shales on a 2:1 ratio compared to the gas that was originally present, then 1682 to 1720 days (4.6 to 4.7 years) of landfill carbon dioxide production can be sequestered by the coals and shales immediately under the landfill. Three coal--the Bevier, Fleming, and Mulberry coals--are the major coals of sufficient thickness (nominally >1-foot) that can imbibe carbon dioxide gas with an enhanced coalbed injection. Comparison of the adsorption gas content of coals to the gas desorbed from the coals shows that the degree of saturation decreases with depth for the coals.

  18. An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

    SciTech Connect (OSTI)

    Townsend, Aaron K., E-mail: aarontownsend@utexas.edu [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States); Webber, Michael E. [Department of Mechanical Engineering, University of Texas at Austin, 1 University Station C2200, Austin, TX 78712 (United States)

    2012-07-15T23:59:59.000Z

    This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

  19. Gas-chromatographic identification of volatile products from thermal processing of Bitumen

    SciTech Connect (OSTI)

    Zenkevich, I.G.; Ventura, K. [Advanced Chemical Engineering Institute, Pardubice (Czechoslovakia)

    1992-03-10T23:59:59.000Z

    The variety of bitumen industrial brands is evident in the significant variation of composition and ratio of volatile thermal processing products, which makes their detailed characterization difficult. For that reason, in the authors` opinion a simple and easily reproducible method for gas chromatographic analysis and identification of these substances should be of greater interest than gathering more such results. In this report the authors discuss the selection of an optimal combination of group and individual gas chromatographic methods for identification of volatile thermal processing products in the presence of air, using the example of AP bitumen, the main brand used in Czechoslavakia for production of asphalt. 15 refs., 1 tab.

  20. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems

    SciTech Connect (OSTI)

    Nick Soelberg; Joe Enneking

    2011-05-01T23:59:59.000Z

    Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (radioactive and hazardous) wastes. Test programs performed in recent years have shown that mercury in off-gas streams from processes that treat radioactive wastes can be controlled using fixed beds of activated sulfur-impregnated carbon, to levels low enough to comply with air emission regulations such as the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards. Carbon bed hot spots or fires have occurred several times during these tests, and also during a remediation of tanks that contained mixed waste. Hot spots occur when localized areas in a carbon bed become heated to temperatures where oxidation occurs. This heating typically occurs due to heat of absoption of gas species onto the carbon, but it can also be caused through external means such as external heaters used to heat the carbon bed vessel. Hot spots, if not promptly mitigated, can grow into bed fires. Carbon bed hot spots and fires must be avoided in processes that treat radioactive and mixed waste. Hot spots are detected by (a) monitoring in-bed and bed outlet gas temperatures, and (b) more important, monitoring of bed outlet gas CO concentrations. Hot spots are mitigated by (a) designing for appropriate in-bed gas velocity, for avoiding gas flow maldistribution, and for sufficient but not excessive bed depth, (b) appropriate monitoring and control of gas and bed temperatures and compositions, and (c) prompt implementation of corrective actions if bed hot spots are detected. Corrective actions must be implemented quickly if bed hot spots are detected, using a graded approach and sequence starting with corrective actions that are simple, quick, cause the least impact to the process, and are easiest to recover from.

  1. Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443

    SciTech Connect (OSTI)

    Ramsey, William G.; Esparza, Brian P. [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)] [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)

    2013-07-01T23:59:59.000Z

    Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

  2. EVALUATION OF A TURBIDITY METER FOR USE AT THE DEFENSE WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Mahannah, R.; Edwards, T.

    2013-06-04T23:59:59.000Z

    Savannah River Remediation’s (SRR’s) Defense Waste Processing Facility (DWPF) Laboratory currently tests for sludge carry-over into the Recycle Collection Tank (RCT) by evaluating the iron concentration in the Slurry Mix Evaporator Condensate Tank (SMECT) and relating this iron concentration to the amount of sludge solids present. A new method was proposed for detecting the amount of sludge in the SMECT that involves the use of an Optek turbidity sensor. Waste Services Laboratory (WSL) personnel conducted testing on two of these units following a test plan developed by Waste Solidification Engineering (WSE). Both Optek units (SN64217 and SN65164) use sensor model AF16-N and signal converter model series C4000. The sensor body of each unit was modified to hold a standard DWPF 12 cc sample vial, also known as a “peanut” vial. The purpose of this testing was to evaluate the use of this model of turbidity sensor, or meter, to provide a measurement of the sludge solids present in the SMECT based upon samples from that tank. During discussions of the results from this study by WSE, WSL, and Savannah River National Laboratory (SRNL) personnel, an upper limit on the acceptable level of solids in SMECT samples was set at 0.14 weight percent (wt%). A “go/no-go” decision criterion was to be developed for the critical turbidity response, which is expressed in concentration units (CUs), for each Optek unit based upon the 0.14 wt% solids value. An acceptable or a “go” decision for the SMECT should reflect the situation that there is an identified risk (e.g. 5%) for a CU response from the Optek unit to be less than the critical CU value when the solids content of the SMECT is actually 0.14 wt% or greater, while a “no-go” determination (i.e., an Optek CU response above the critical CU value, a conservative decision relative to risk) would lead to additional evaluations of the SMECT to better quantify the possible solids content of the tank. Subsequent to the issuance of the initial version of this report but under the scope of the original request for technical assistance, WSE asked for this report to be revised to include the “go/no-go” CU value corresponding to 0.28 wt% solids. It was this request that led to the preparation of Revision 1 of the report. The results for the 0.28 wt% solids value were developed following the same approach as that utilized for the 0.14 wt% solids value. A sludge simulant was used to develop standards for testing both Optek units and to determine the viability of a “go/no-go” CU response for each of the units. Statistical methods were used by SRNL to develop the critical CU value for the “go/no-go” decision for these standards for each Optek unit. Since only one sludge simulant was available for this testing, the sensitivity of these results to other simulants and to actual sludge material is not known. However, limited testing with samples from the actual DWPF process (both SRAT product samples and SMECT samples) demonstrated that the use of the “go/no-go” criteria developed from the sludge simulant testing was conservative for these samples taken from the sludge batch, Sludge Batch 7b, being processed at the time of this testing. While both of the Optek units performed very reliably during this testing, there were statistically significant differences (although small on a practical scale) between the two units. Thus, testing should be conducted on any new unit of this Optek model to qualify it before it is used to support the DWPF operation.

  3. Qualification of the First ICS-3000 ION Chromatograph for use at the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Edwards, T; Mahannah, R.

    2011-07-05T23:59:59.000Z

    The ICS-3000 Ion Chromatography (IC) system installed in 221-S M-13 has been qualified for use. The qualification was a head to head comparison of the ICS-3000 with the currently used DX-500 IC system. The crosscheck work included standards for instrument calibration and calibration verifications and standards for individual anion analysis, where the standards were traceable back to the National Institute of Standards and Technology (NIST). In addition the crosscheck work included the analysis of simulated Sludge Receipt Adjustment Tank (SRAT) Receipt, SRAT Product, and Slurry Mix Evaporator (SME) samples, along with radioactive Sludge Batch 5 material from the SRAT and SME tanks. Based upon the successful qualification of the ICS-3000 in M-13, it is recommended that this task proceed in developing the data to qualify, by a head to head comparison of the two ICS-3000 instruments, a second ICS-3000 to be installed in M-14. The Defense Waste Processing Facility (DWPF) requires the analysis of specific anions at various stages of its processing of high level waste (HLW). The anions of interest to the DWPF are fluoride, formate, chloride, nitrite, nitrate, sulfate, oxalate, and phosphate. The anion analysis is used to evaluate process chemistry including formic acid/nitric acid additions to establish optimum conditions for mercury stripping, reduction-oxidation (REDOX) chemistry for the melter, nitrite destruction, organic acid constituents, etc. The DWPF Laboratory (Lab) has been using Dionex DX-500 ion chromatography (IC) systems since 1998. The vendor informed DWPF in 2006 that the instruments would no longer be supported by service contracts after 2008. DWPF purchased three new ICS-3000 systems in September of 2006. The ICS-3000 instruments are (a) designed to be more stable using an eluent generator to make eluent, (b) require virtually no daily chemical handling by the analysts, (c) require less line breaks in the hood, and (d) generally require less maintenance due to the pump configuration only using water versus the current system where the pump uses various hydroxide concentrations. The ICS-3000 instruments also allow the DWPF to maintain current service contracts, which support routine preventive maintenance and emergency support for larger problems such as component failure. One of the three new systems was set up in the DWPF Lab trailers in January of 2007 to be used for the development of methods and procedures. This system will continue to be used for training, new method development and potential improvements to current methods. The qualification of the other two ICS-3000 instruments is to be a phased effort. This effort is to be supported by the Applied Computational Engineering and Statistical (ACES) group of the Savannah River National Laboratory (SRNL) as authorized by the Technical Task Request (TTR) and as directed by the corresponding Task Technical and Quality Assurance (TT&QA) plan. The installation of the first 'rad' system into the M-13 Lab module required modifications to both the Lab module and to the radiohood. The installation was completed in July 2008. The testing of this system was conducted as directed by the TT&QA plan. The purpose of this technical report is to provide a review of the data generated by these tests that will lead to the recommendation for the qualification of the M-13 ICS-3000 instrument. With the successful qualification of this first ICS-3000, plans will be developed for the installation of the second 'rad' system in the M-14 Lab module later in fiscal year 2009. When the second 'rad' ICS-3000 system is installed, the DX-500 systems will be removed and retired from service.

  4. Wetland and Sensitive Species Survey Report for Y-12: Proposed Uranium Processing Facility (UPF)

    SciTech Connect (OSTI)

    Giffen, N.; Peterson, M.; Reasor, S.; Pounds, L.; Byrd, G.; Wiest, M. C.; Hill, C. C.

    2009-11-01T23:59:59.000Z

    This report summarizes the results of an environmental survey conducted at sites associated with the proposed Uranium Processing Facility (UPF) at the Y-12 National Security Complex in September-October 2009. The survey was conducted in order to evaluate potential impacts of the overall project. This project includes the construction of a haul road, concrete batch plant, wet soil storage area and dry soil storage area. The environmental surveys were conducted by natural resource experts at ORNL who routinely assess the significance of various project activities on the Oak Ridge Reservation (ORR). Natural resource staff assistance on this project included the collection of environmental information that can aid in project location decisions that minimize impacts to sensitive resource such as significant wildlife populations, rare plants and wetlands. Natural resources work was conducted in various habitats, corresponding to the proposed areas of impact. Thc credentials/qualifications of the researchers are contained in Appendix A. The proposed haul road traverses a number of different habitats including a power-line right-of-way. wetlands, streams, forest and mowed areas. It extends from what is known as the New Salvage Yard on the west to the Polaris Parking Lot on the east. This haul road is meant to connect the proposed concrete batch plant to the UPF building site. The proposed site of the concrete batch plant itself is a highly disturbed fenced area. This area of the project is shown in Fig. 1. The proposed Wet Soils Disposal Area is located on the north side of Bear Creek Road at the former Control Burn Study Area. This is a second growth arce containing thick vegetation, and extensive dead and down woody material. This area of the project is shown in Fig. 2. Thc dry soils storage area is proposed for what is currently known as the West Borrow Area. This site is located on the west side of Reeves Road south of Bear Creek Road. The site is an early successional field. This area of the project is shown in Fig. 2.

  5. Natural Gas Processing: The Crucial Link Between Natural Gas Production and Its Transportation to Market

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month Week 1 Week 2 Week 3Processing: The Crucial

  6. Field Demonstration of a Membrane Process to Separate Nitrogen from Natural Gas

    SciTech Connect (OSTI)

    Kaaeid Lokhandwala

    2007-03-31T23:59:59.000Z

    The original proposal described the construction and operation of a 1 MMscfd treatment system to be operated at a Butcher Energy gas field in Ohio. The gas produced at this field contained 17% nitrogen. During pre-commissioning of the project, a series of well tests showed that the amount of gas in the field was significantly smaller than expected and that the nitrogen content of the wells was very high (25 to 30%). After evaluating the revised cost of the project, Butcher Energy decided that the plant would not be economical and withdrew from the project. Since that time, Membrane Technology and Research, Inc. (MTR) has signed a marketing and sales partnership with ABB Lummus Global, a large multinational corporation. MTR is working with the company's Randall Gas Technology group, a supplier of equipment and processing technology to the natural gas industry. Randall's engineering group found a new site for the project at a North Texas Exploration (NTE) gas processing plant, which met with limited success. However, a small test system was installed at a Twin Bottoms Energy well in Kentucky. This unit operated successfully for six months, and demonstrated the technology's reliability on a small scale. MTR then located an alternative test site with much larger gas flow rates and signed a contract with Towne Exploration in the third quarter of 2006, for a demonstration plant in Rio Vista, California, to be run through May 2007. The demonstration for Towne has already resulted in the sale of two commercial skids to the company; both units will be delivered by the end of 2007. Total sales of nitrogen/natural gas membrane separation units from the partnership with ABB are now approaching $4.0 million.

  7. 6/10/12 UK team advances measurement of gas bubbles in pipelines. | Technology news | Process Engineer... 1/2processengineering.theengineer.co.uk/.../1012631.article

    E-Print Network [OSTI]

    Sóbester, András

    process in the manufacturing, power, oil & gas and petrochemical industries. For instance, the sharp

  8. Power Systems Development Facility. Quarterly report, July--September 1995

    SciTech Connect (OSTI)

    NONE

    1995-11-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a fimction of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and hot gas cleanup units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDS) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter. Delivery and construction of the process structural steel is nearing completion. Nearly all equipment are set in its place and the FW equipment and the PCDs are being set in the structure.

  9. Gas-assisted gravity drainage (GAGD) process for improved oil recovery

    DOE Patents [OSTI]

    Rao, Dandina N. (Baton Rouge, LA)

    2012-07-10T23:59:59.000Z

    A rapid and inexpensive process for increasing the amount of hydrocarbons (e.g., oil) produced and the rate of production from subterranean hydrocarbon-bearing reservoirs by displacing oil downwards within the oil reservoir and into an oil recovery apparatus is disclosed. The process is referred to as "gas-assisted gravity drainage" and comprises the steps of placing one or more horizontal producer wells near the bottom of a payzone (i.e., rock in which oil and gas are found in exploitable quantities) of a subterranean hydrocarbon-bearing reservoir and injecting a fluid displacer (e.g., CO.sub.2) through one or more vertical wells or horizontal wells. Pre-existing vertical wells may be used to inject the fluid displacer into the reservoir. As the fluid displacer is injected into the top portion of the reservoir, it forms a gas zone, which displaces oil and water downward towards the horizontal producer well(s).

  10. Proof-of concept testing of the advanced NOXSO flue gas cleanup process. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-04-01T23:59:59.000Z

    The NOXSO Process uses a regenerable sorbent that removes SO{sub 2} and NO{sub x} simultaneously from flue gas. The sorbent is a stabilized {gamma}-alumina bed impregnated with sodium carbonate. The process was successfully tested at three different scales, equivalent to 0.017, 0.06 and 0.75 MW of flue gas generated from a coal-fired power plant. The Proof-of-Concept (POC) Test is the last test prior to a full-scale demonstration. A slip stream of flue gas equivalent to a 5 MW coal-fired power plant was used for the POC test. This paper summarizes the NOXSO POC plant and its test results.

  11. Task 21 - Evaluation of Artificial Freeze Crystallization and Natural Freeze-Thaw Processes for the Treatment of Contaminated Groundwater at the Strachan Gas Plant in Alberta, Canada - Sour Gas Remediation Technology R{ampersand}D

    SciTech Connect (OSTI)

    NONE

    1997-03-01T23:59:59.000Z

    During the period from 1993 to 1996, a long-term program was initiated to conduct remediation research at the Strachan Gas Plant in Alberta, Canada. As part of this research program, optimization of the existing pump-and-treat (P{ampersand}T) facility was of interest. The cost-effective treatment of contaminated groundwater produced from the P{ampersand}T system was complicated by several factors, including: (1) increased cost and reduced effectiveness of most water treatment processes because of the cold temperatures and severe winter conditions prevalent in Alberta, (2) interference caused by the mixture of inorganic and organic contaminants found in the groundwater that can reduce the effectiveness of many water treatment processes, and (3) pretreatment to prevent scaling in existing treatment process unit operations caused by the iron, manganese, and hardness of the contaminated groundwater.

  12. Design-Build Process for the Research Support Facility (RSF) (Book)

    SciTech Connect (OSTI)

    Not Available

    2012-06-01T23:59:59.000Z

    An in-depth look at how the U.S. DOE and NREL used a performance-based design-build contract to build the Research Support Facility (RSF); one of the most energy efficient office buildings in the world.

  13. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, Hayim (Chicago, IL); Targos, William M. (Palatine, IL)

    1987-01-01T23:59:59.000Z

    A catalyst composition for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  14. Microemulsion impregnated catalyst composite and use thereof in a synthesis gas conversion process

    DOE Patents [OSTI]

    Abrevaya, H.; Targos, W.M.

    1987-12-22T23:59:59.000Z

    A catalyst composition is described for synthesis gas conversion comprising a ruthenium metal component deposited on a support carrier wherein the average metal particle size is less than about 100 A. The method of manufacture of the composition via a reverse micelle impregnation technique and the use of the composition in a Fischer-Tropsch conversion process is also disclosed.

  15. An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters

    E-Print Network [OSTI]

    Nebeker, C. J.

    1982-01-01T23:59:59.000Z

    of these factors, the difference between coal and natural gas prices and the project life are difficult to predict. The resulting uncertainty has caused Monsanto to pursue coal gasification for process heaters with cautious optimism, on a site by site basis....

  16. Flow analysis and nozzle-shape optimization for the cold-gas dynamic-spray process

    E-Print Network [OSTI]

    Grujicic, Mica

    Flow analysis and nozzle-shape optimization for the cold-gas dynamic-spray process M Grujicic1*, W, maximizes the acceleration of the particles. Furthermore, it is found that if the cold-spray nozzle, a significant increase in the average velocity of the particles at the nozzle exit can be obtained

  17. Analysis and modeling of gas exchange processes in Scaevola aemula Soo-Hyung Kim a,*, Paul R. Fisher b

    E-Print Network [OSTI]

    Lieth, J. Heinrich

    Analysis and modeling of gas exchange processes in Scaevola aemula Soo-Hyung Kim a,*, Paul R exchange model previously developed for cut-roses. Utilizing the gas exchange data measured at 25 8C leaf crop cultivated as a bedding plant or for hanging baskets. We characterized gas exchange properties

  18. Geological and Geotechnical Site Investigation for the Design of a CO2 Rich Flue Gas Direct Injection and Storage Facility

    SciTech Connect (OSTI)

    Metz, Paul; Bolz, Patricia

    2013-03-25T23:59:59.000Z

    With international efforts to limit anthropogenic carbon in the atmosphere, various CO{sub 2} sequestration methods have been studied by various facilities worldwide. Basalt rock in general has been referred to as potential host material for mineral carbonation by various authors, without much regard for compositional variations due to depositional environment, subsequent metamorphism, or hydrothermal alteration. Since mineral carbonation relies on the presence of certain magnesium, calcium, or iron silicates, it is necessary to study the texture, mineralogy, petrology, and geochemistry of specific basalts before implying potential for mineral carbonation. The development of a methodology for the characterization of basalts with respect to their susceptibility for mineral carbonation is proposed to be developed as part of this research. The methodology will be developed based on whole rock data, petrography and microprobe analyses for samples from the Caledonia Mine in Michigan, which is the site for a proposed small-scale demonstration project on mineral carbonation in basalt. Samples from the Keweenaw Peninsula will be used to determine general compositional trends using whole rock data and petrography. Basalts in the Keweenaw Peninsula have been subjected to zeolite and prehnite-pumpellyite facies metamorphism with concurrent native copper deposition. Alteration was likely due to the circulation of CO{sub 2}-rich fluids at slightly elevated temperatures and pressures, which is the process that is attempted to be duplicated by mineral carbonation.

  19. Investigation of physico-chemical processes in hypervelocity MHD-gas acceleration wind tunnels

    SciTech Connect (OSTI)

    Alfyorov, V.I.; Dmitriev, L.M.; Yegorov, B.V.; Markachev, Yu.E. [Central Aerohydrodynamic Institute (TsAGI), Zhukovsky (Russian Federation)

    1995-12-31T23:59:59.000Z

    The calculation results for nonequilibrium physicochemical processes in the circuit of the hypersonic MHD-gas acceleration wind tunnel are presented. The flow in the primary nozzle is shown to be in thermodynamic equilibrium at To=3400 K, Po=(2{approximately}3)x10{sup 5} Pa, M=2 used in the plenum chamber. Variations in the static pressure due to oxidation reaction of Na, K are pointed out. The channels of energy transfer from the electric field to different degrees of freedom of an accelerated gas with Na, K seeds are considered. The calculation procedure for gas dynamic and kinetic processes in the MHD-channel using measured parameters is suggested. The calculated results are compared with the data obtained in a thermodynamic gas equilibrium assumption. The flow in the secondary nozzle is calculated under the same assumptions and the gas parameters at its exit are evaluated. Particular attention is given to the influence of seeds on flows over bodies. It is shown that the seeds exert a very small influence on the flow behind a normal shock wave. The seeds behind an oblique shock wave accelerate deactivation of vibrations of N{sub 2}, but this effect is insignificant.

  20. Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs

    E-Print Network [OSTI]

    Nogueira de Mago, Marjorie Carolina

    2005-11-01T23:59:59.000Z

    , corefloods were conducted at 1,500 psig and 70??C, in which flue gas was injected into an Austin chalk core containing initially methane. Two types of flue gases were injected: dehydrated flue gas with 13.574 mole% CO2 (Gas A), and treated flue gas (N2, O2...

  1. RADIOLOGICAL CONTROLS FOR PLUTONIUM CONTAMINATED PROCESS EQUIPMENT REMOVAL FROM 232-Z CONTAMINATED WASTE RECOVERY PROCESS FACILITY AT THE PLUTONIUM FINSHING PLANT (PFP)

    SciTech Connect (OSTI)

    MINETTE, M.J.

    2007-05-30T23:59:59.000Z

    The 232-Z facility at Hanford's Plutonium Finishing Plant operated as a plutonium scrap incinerator for 11 years. Its mission was to recover residual plutonium through incinerating and/or leaching contaminated wastes and scrap material. Equipment failures, as well as spills, resulted in the release of radionuclides and other contamination to the building, along with small amounts to external soil. Based on the potential threat posed by the residual plutonium, the U.S. Department of Energy (DOE) issued an Action Memorandum to demolish Building 232-2, Comprehensive Environmental Response Compensation, and Liability Act (CERC1.A) Non-Time Critical Removal Action Memorandum for Removal of the 232-2 Waste Recovery Process Facility at the Plutonium Finishing Plant (04-AMCP-0486).

  2. MEMBRANE PROCESS TO SEQUESTER CO2 FROM POWER PLANT FLUE GAS

    SciTech Connect (OSTI)

    Tim Merkel; Karl Amo; Richard Baker; Ramin Daniels; Bilgen Friat; Zhenjie He; Haiqing Lin; Adrian Serbanescu

    2009-03-31T23:59:59.000Z

    The objective of this project was to assess the feasibility of using a membrane process to capture CO2 from coal-fired power plant flue gas. During this program, MTR developed a novel membrane (Polaris™) with a CO2 permeance tenfold higher than commercial CO2-selective membranes used in natural gas treatment. The Polaris™ membrane, combined with a process design that uses a portion of combustion air as a sweep stream to generate driving force for CO2 permeation, meets DOE post-combustion CO2 capture targets. Initial studies indicate a CO2 separation and liquefaction cost of $20 - $30/ton CO2 using about 15% of the plant energy at 90% CO2 capture from a coal-fired power plant. Production of the Polaris™ CO2 capture membrane was scaled up with MTR’s commercial casting and coating equipment. Parametric tests of cross-flow and countercurrent/sweep modules prepared from this membrane confirm their near-ideal performance under expected flue gas operating conditions. Commercial-scale, 8-inch diameter modules also show stable performance in field tests treating raw natural gas. These findings suggest that membranes are a viable option for flue gas CO2 capture. The next step will be to conduct a field demonstration treating a realworld power plant flue gas stream. The first such MTR field test will capture 1 ton CO2/day at Arizona Public Service’s Cholla coal-fired power plant, as part of a new DOE NETL funded program.

  3. Transfer Lines to Connect Liquid Waste Facilities and Salt Waste Processing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of EnergyThe EnergyDepartment7 th ,TopDepartment ofTransactionalFacility |

  4. A demonstration of variance and covariance calculations using MAVARIC (Materials Accounting VARIance Calculator) and PROFF (PROcessing and Fuel Facilities calculator)

    SciTech Connect (OSTI)

    Barlich, G.L.; Nasseri, S.S.

    1990-01-01T23:59:59.000Z

    Good decision-making in materials accounting requires a valid calculation of control limits and detection sensitivity for facilities handling special nuclear materials (SNM). A difficult aspect of this calculation is determining the appropriate variance and covariance values for the terms in the materials balance (MB) equation. Computer software such as MAVARIC (Materials Accounting VARIance Calculator) and PROFF (PROcessing and Fuel Facilities calculator) can efficiently select and combine variance terms. These programs determine the variance and covariance of an MB equation by first obtaining relations for the variance and covariance of each term in the MB equation through propagating instrument errors and then substituting the measured quantities and their uncertainties into these relations. MAVARIC is a custom spreadsheet used with the second release of LOTUS 1-2-3.** PROFF is a stand-alone menu-driven program requiring no commercial software. Programs such as MAVARIC and PROFF facilitate the complex calculations required to determine the detection sensitivity of an SNM facility. These programs can also be used to analyze materials accounting systems.

  5. HWMA/RCRA Closure Plan for the TRA Fluorinel Dissolution Process Mockup and Gamma Facilities Waste System

    SciTech Connect (OSTI)

    K. Winterholler

    2007-01-31T23:59:59.000Z

    This Hazardous Waste Management Act/Resource Conservation and Recovery Act closure plan was developed for the Test Reactor Area Fluorinel Dissolution Process Mockup and Gamma Facilities Waste System, located in Building TRA-641 at the Reactor Technology Complex (RTC), Idaho National Laboratory Site, to meet a further milestone established under the Voluntary Consent Order SITE-TANK-005 Action Plan for Tank System TRA-009. The tank system to be closed is identified as VCO-SITE-TANK-005 Tank System TRA-009. This closure plan presents the closure performance standards and methods for achieving those standards.

  6. Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)

    SciTech Connect (OSTI)

    Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

    1999-05-01T23:59:59.000Z

    The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

  7. Energy Department Authorizes Second Proposed Facility to Export...

    Office of Environmental Management (EM)

    Second Proposed Facility to Export Liquefied Natural Gas Energy Department Authorizes Second Proposed Facility to Export Liquefied Natural Gas May 17, 2013 - 12:00pm Addthis News...

  8. Energy Department Authorizes Third Proposed Facility to Export...

    Office of Environmental Management (EM)

    Third Proposed Facility to Export Liquefied Natural Gas Energy Department Authorizes Third Proposed Facility to Export Liquefied Natural Gas August 7, 2013 - 12:00pm Addthis NEWS...

  9. Energy Department Authorizes Dominion's Proposed Cove Point Facility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dominion's Proposed Cove Point Facility to Export Liquefied Natural Gas Energy Department Authorizes Dominion's Proposed Cove Point Facility to Export Liquefied Natural Gas...

  10. Process Flow Chart for Immobilizing of Radioactive High Concentration Sodium Hydroxide Product from the Sodium Processing Facility at the BN-350 Nuclear power plant in Aktau, Kazakhstan

    SciTech Connect (OSTI)

    Burkitbayev, M.; Omarova, K.; Tolebayev, T. [Ai-Farabi Kazakh National University, Chemical Faculty, Republic of Kazakhstan (Kazakhstan); Galkin, A. [KATEP Ltd., Republic of Kazakhstan (Kazakhstan); Bachilova, N. [NIISTROMPROEKT Ltd., Republic of Kazakhstan (Kazakhstan); Blynskiy, A. [Nuclear Technology Safety Centre, Republic of Kazakhstan (Kazakhstan); Maev, V. [MAEK-Kazatomprom Ltd., Republic of Kazakhstan (Kazakhstan); Wells, D. [NUKEM Limited- a member of the Freyssinet Group, Winfrith Technology Centre, Dorchester, Dorset (United Kingdom); Herrick, A. [NUKEM Limited- a member of the Freyssinet Group, Caithness (United Kingdom); Michelbacher, J. [Idaho National Laboratory, Idaho Falls (United States)

    2008-07-01T23:59:59.000Z

    This paper describes the results of a joint research investigations carried out by the group of Kazakhstan, British and American specialists in development of a new material for immobilization of radioactive 35% sodium hydroxide solutions from the sodium coolant processing facility of the BN-350 nuclear power plant. The resulting solid matrix product, termed geo-cement stone, is capable of isolating long lived radionuclides from the environment. The physico-mechanical properties of geo-cement stone have been investigated and the flow chart for its production verified in a full scale experiments. (author)

  11. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    SciTech Connect (OSTI)

    Lee O. Nelson

    2011-04-01T23:59:59.000Z

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  12. Process for the manufacture of an attrition resistant sorbent used for gas desulfurization

    DOE Patents [OSTI]

    Venkataramani, Venkat S.; Ayala, Raul E.

    2003-09-16T23:59:59.000Z

    This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

  13. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-12-22T23:59:59.000Z

    The order establishes facility and programmatic safety requirements for nuclear and explosives safety design criteria, fire protection, criticality safety, natural phenomena hazards (NPH) mitigation, and the System Engineer Program.Chg 1 incorporates the use of DOE-STD-1189-2008, Integration of Safety into the Design Process, mandatory for Hazard Category 1, 2 and 3 nuclear facilities. Cancels DOE O 420.1A.

  14. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31T23:59:59.000Z

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  15. Mechanistic facility safety and source term analysis

    SciTech Connect (OSTI)

    PLYS, M.G.

    1999-06-09T23:59:59.000Z

    A PC-based computer program was created for facility safety and source term analysis at Hanford The program has been successfully applied to mechanistic prediction of source terms from chemical reactions in underground storage tanks, hydrogen combustion in double contained receiver tanks, and proccss evaluation including the potential for runaway reactions in spent nuclear fuel processing. Model features include user-defined facility room, flow path geometry, and heat conductors, user-defined non-ideal vapor and aerosol species, pressure- and density-driven gas flows, aerosol transport and deposition, and structure to accommodate facility-specific source terms. Example applications are presented here.

  16. Fracture Dissolution of Carbonate Rock: An Innovative Process for Gas Storage

    SciTech Connect (OSTI)

    James W. Castle; Ronald W. Falta; David Bruce; Larry Murdoch; Scott E. Brame; Donald Brooks

    2006-10-31T23:59:59.000Z

    The goal of the project is to develop and assess the feasibility and economic viability of an innovative concept that may lead to commercialization of new gas-storage capacity near major markets. The investigation involves a new approach to developing underground gas storage in carbonate rock, which is present near major markets in many areas of the United States. Because of the lack of conventional gas storage and the projected growth in demand for storage capacity, many of these areas are likely to experience shortfalls in gas deliverability. Since depleted gas reservoirs and salt formations are nearly non-existent in many areas, alternatives to conventional methods of gas storage are required. The need for improved methods of gas storage, particularly for ways to meet peak demand, is increasing. Gas-market conditions are driving the need for higher deliverability and more flexibility in injection/withdrawal cycling. In order to meet these needs, the project involves an innovative approach to developing underground storage capacity by creating caverns in carbonate rock formations by acid dissolution. The basic concept of the acid-dissolution method is to drill to depth, fracture the carbonate rock layer as needed, and then create a cavern using an aqueous acid to dissolve the carbonate rock. Assessing feasibility of the acid-dissolution method included a regional geologic investigation. Data were compiled and analyzed from carbonate formations in six states: Indiana, Ohio, Kentucky, West Virginia, Pennsylvania, and New York. To analyze the requirements for creating storage volume, the following aspects of the dissolution process were examined: weight and volume of rock to be dissolved; gas storage pressure, temperature, and volume at depth; rock solubility; and acid costs. Hydrochloric acid was determined to be the best acid to use because of low cost, high acid solubility, fast reaction rates with carbonate rock, and highly soluble products (calcium chloride) that allow for the easy removal of calcium waste from the well. Physical and chemical analysis of core samples taken from prospective geologic formations for the acid dissolution process confirmed that many of the limestone samples readily dissolved in concentrated hydrochloric acid. Further, some samples contained oily residues that may help to seal the walls of the final cavern structure. These results suggest that there exist carbonate rock formations well suited for the dissolution technology and that the presence of inert impurities had no noticeable effect on the dissolution rate for the carbonate rock. A sensitivity analysis was performed for characteristics of hydraulic fractures induced in carbonate formations to enhance the dissolution process. Multiple fracture simulations were conducted using modeling software that has a fully 3-D fracture geometry package. The simulations, which predict the distribution of fracture geometry and fracture conductivity, show that the stress difference between adjacent beds is the physical property of the formations that has the greatest influence on fracture characteristics by restricting vertical growth. The results indicate that by modifying the fracturing fluid, proppant type, or pumping rate, a fracture can be created with characteristics within a predictable range, which contributes to predicting the geometry of storage caverns created by acid dissolution of carbonate formations. A series of three-dimensional simulations of cavern formation were used to investigate three different configurations of the acid-dissolution process: (a) injection into an open borehole with production from that same borehole and no fracture; (b) injection into an open borehole with production from that same borehole, with an open fracture; and (c) injection into an open borehole connected by a fracture to an adjacent borehole from which the fluids are produced. The two-well configuration maximizes the overall mass transfer from the rock to the fluid, but it results in a complex cavern shape. Numerical simulations were performed to evalua

  17. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    associated with coal generation occur at the smokestack. Theassociated with coal-fired electricity generation by up toCoal, Domestic Natural Gas, LNG, and SNG for Electricity Generation,

  18. Summary of flammable gas hazard and potential consequences in tank waste remediation system facility at the Hanford site

    SciTech Connect (OSTI)

    Van Vleet, R.J., Westinghouse Hanford

    1996-12-11T23:59:59.000Z

    This document provides a summary of the flammable gas program since 1992. It provides the best understanding of generation, retention, release of flammable gases. It gives a composition for each of the flammable gas tanks, calculates postulated concentrations in the event of a release, calculates the pressure obtained during a burn, and provides radiological and toxicological consequences. Controls from the analysis are found in WHC-SD-WM-SAR-067.

  19. RESULTS OF THE EXTRACTION-SCRUB-STRIP TESTING USING AN IMPROVED SOLVENT FORMULATION AND SALT WASTE PROCESSING FACILITY SIMULATED WASTE

    SciTech Connect (OSTI)

    Peters, T.; Washington, A.; Fink, S.

    2012-01-09T23:59:59.000Z

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent - also known as the next generation solvent (NGS) - for deployment at the Savannah River Site to remove cesium from High Level Waste. The technical effort is a collaborative effort between Oak Ridge National Laboratory (ORNL) and Savannah River National Laboratory (SRNL). As part of the program, the Savannah River National Laboratory (SRNL) has performed a number of Extraction-Scrub-Strip (ESS) tests. These batch contact tests serve as first indicators of the cesium mass transfer solvent performance with actual or simulated waste. The test detailed in this report used simulated Tank 49H material, with the addition of extra potassium. The potassium was added at 1677 mg/L, the maximum projected (i.e., a worst case feed scenario) value for the Salt Waste Processing Facility (SWPF). The results of the test gave favorable results given that the potassium concentration was elevated (1677 mg/L compared to the current 513 mg/L). The cesium distribution value, DCs, for extraction was 57.1. As a comparison, a typical D{sub Cs} in an ESS test, using the baseline solvent formulation and the typical waste feed, is {approx}15. The Modular Caustic Side Solvent Extraction Unit (MCU) uses the Caustic-Side Solvent Extraction (CSSX) process to remove cesium (Cs) from alkaline waste. This process involves the use of an organic extractant, BoBCalixC6, in an organic matrix to selectively remove cesium from the caustic waste. The organic solvent mixture flows counter-current to the caustic aqueous waste stream within centrifugal contactors. After extracting the cesium, the loaded solvent is stripped of cesium by contact with dilute nitric acid and the cesium concentrate is transferred to the Defense Waste Processing Facility (DWPF), while the organic solvent is cleaned and recycled for further use. The Salt Waste Processing Facility (SWPF), under construction, will use the same process chemistry. The Office of Waste Processing (EM-31) expressed an interest in investigating the further optimization of the organic solvent by replacing the BoBCalixC6 extractant with a more efficient extractant. This replacement should yield dividends in improving cesium removal from the caustic waste stream, and in the rate at which the caustic waste can be processed. To that end, EM-31 provided funding for both the Savannah River National Laboratory (SRNL) and the Oak Ridge National Laboratory (ORNL). SRNL wrote a Task Technical Quality and Assurance Plan for this work. As part of the envisioned testing regime, it was decided to perform an ESS test using a simulated waste that simulated a typical envisioned SWPF feed, but with added potassium to make the waste more challenging. Potassium interferes in the cesium removal, and its concentration is limited in the feed to <1950 mg/L. The feed to MCU has typically contained <500 mg/L of potassium.

  20. Regeneration of an aqueous solution from an acid gas absorption process by matrix stripping

    DOE Patents [OSTI]

    Rochelle, Gary T. (Austin, TX); Oyenekan, Babatunde A. (Katy, TX)

    2011-03-08T23:59:59.000Z

    Carbon dioxide and other acid gases are removed from gaseous streams using aqueous absorption and stripping processes. By replacing the conventional stripper used to regenerate the aqueous solvent and capture the acid gas with a matrix stripping configuration, less energy is consumed. The matrix stripping configuration uses two or more reboiled strippers at different pressures. The rich feed from the absorption equipment is split among the strippers, and partially regenerated solvent from the highest pressure stripper flows to the middle of sequentially lower pressure strippers in a "matrix" pattern. By selecting certain parameters of the matrix stripping configuration such that the total energy required by the strippers to achieve a desired percentage of acid gas removal from the gaseous stream is minimized, further energy savings can be realized.

  1. CHALLENGES OF PRESERVING HISTORIC RESOURCES DURING THE D & D OF HIGHLY CONTAMINATED HISTORICALLY SIGNIFICANT PLUTONIUM PROCESS FACILITIES

    SciTech Connect (OSTI)

    HOPKINS, A.M.

    2006-03-17T23:59:59.000Z

    The Manhattan Project was initiated to develop nuclear weapons for use in World War II. The Hanford Engineer Works (HEW) was established in eastern Washington State as a production complex for the Manhattan Project. A major product of the HEW was plutonium. The buildings and process equipment used in the early phases of nuclear weapons development are historically significant because of the new and unique work that was performed. When environmental cleanup became Hanford's central mission in 1991, the Department of Energy (DOE) prepared for the deactivation and decommissioning of many of the old process facilities. In many cases, the process facilities were so contaminated, they faced demolition. The National Historic Preservation Act (NHPA) requires federal agencies to evaluate the historic significance of properties under their jurisdiction for eligibility for inclusion in the National Register of Historic Places before altering or demolishing them so that mitigation through documentation of the properties can occur. Specifically, federal agencies are required to evaluate their proposed actions against the effect the actions may have on districts, sites, buildings or structures that ere included or eligible for inclusion in the National Register. In an agreement between the DOE'S Richland Operations Office (RL), the Washington State Historic Preservation Office (SHPO) and the Advisory Council on Historic Preservation (ACHP), the agencies concurred that the Hanford Site Historic District is eligible for listing on the National Register of Historic Places and that a Sitewide Treatment Plan would streamline compliance with the NHPA while allowing RL to manage the cleanup of the Hanford Site. Currently, many of the old processing buildings at the Plutonium Finishing Plant (PFP) are undergoing deactivation and decommissioning. RL and Fluor Hanford project managers at the PFP are committed to preserving historical artifacts of the plutonium production process. They must also ensure the safety of workers and the full decontamination of buildings or artifacts if they are to be preserved. This paper discusses the real time challenges of working safely, decontaminating process equipment, preserving historical structures and artifacts and documenting their history at PFP.

  2. The Challenges of Preserving Historic Resources During the Deactivation and Decommissioning of Highly Contaminated Historically Significant Plutonium Process Facilities

    SciTech Connect (OSTI)

    Hopkins, A.; Minette, M.; Sorenson, D.; Heineman, R.; Gerber, M. [Fluor Hanford, Inc., PO Box 1000 Richland WA 99352 (United States); Charboneau, S. [US Department of Energy PO Box 550, Richland WA 99352 (United States); Bond, F. [Washington State Department of Ecology, WDOE 3100 Port of Benton Blvd., Richland WA, 99354 (United States)

    2006-07-01T23:59:59.000Z

    The Manhattan Project was initiated to develop nuclear weapons for use in World War II. The Hanford Engineer Works (HEW) was established in eastern Washington State as a production complex for the Manhattan Project. A major product of the HEW was plutonium. The buildings and process equipment used in the early phases of nuclear weapons development are historically significant because of the new and unique work that was performed. When environmental cleanup became Hanford's central mission in 1991, the Department of Energy (DOE) prepared for the deactivation and decommissioning of many of the old process facilities. In many cases, the process facilities were so contaminated, they faced demolition. The National Historic Preservation Act (NHPA) requires federal agencies to evaluate the historic significance of properties under their jurisdiction for eligibility for inclusion in the National Register of Historic Places before altering or demolishing them so that mitigation through documentation of the properties can occur. Specifically, federal agencies are required to evaluate their proposed actions against the effect the actions may have on districts, sites, buildings or structures that are included or eligible for inclusion in the National Register. In an agreement between the DOE's Richland Operations Office (RL), the Washington State Historic Preservation Office (SHPO) and the Advisory Council on Historic Preservation (ACHP), the agencies concurred that the Hanford Site Historic District is eligible for listing on the National Register of Historic Places and that a Site-wide Treatment Plan would streamline compliance with the NHPA while allowing RL to manage the cleanup of the Hanford Site. Currently, many of the old processing buildings at the Plutonium Finishing Plant (PFP) are undergoing deactivation and decommissioning. RL and Fluor Hanford project managers at the PFP are committed to preserving historical artifacts of the plutonium production process. They must also ensure the safety of workers and the full decontamination of buildings or artifacts if they are to be preserved. This paper discusses the real time challenges of working safely, decontaminating process equipment, preserving historical structures and artifacts and documenting their history at PFP. (authors)

  3. Steady-State and Dynamic Modeling of Gas-Phase Polypropylene Processes Using Stirred-Bed Reactors

    E-Print Network [OSTI]

    Liu, Y. A.

    Steady-State and Dynamic Modeling of Gas-Phase Polypropylene Processes Using Stirred-Bed Reactors for the continuous gas-phase synthesis of polypropylene using stirred-bed reactors. The model considers the important- terization, and reactor residence time, in addition to the traditional Ziegler-Natta polymerization kinetics

  4. 6th International Conference on CFD in Oil & Gas, Metallurgical and Process Industries SINTEF/NTNU, Trondheim NORWAY

    E-Print Network [OSTI]

    Bothe, Dieter

    INTRODUCTION The efficiency of gas-liquid rectors like bubble columns, air-lift or agitated stirred reactors. Especially in case of fast reactions the effi- ciency of chemical reactors significantly depends on the mass6th International Conference on CFD in Oil & Gas, Metallurgical and Process Industries SINTEF

  5. Savannah River Site - Salt Waste Processing Facility: Briefing on the Salt

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energy fromCommentsRevolving STATEMENT OFSanEnergyWaste Processing

  6. Reevaluation Of Vitrified High-Level Waste Form Criteria For Potential Cost Savings At The Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Ray, J. W.; Marra, S. L.; Herman, C. C.

    2013-01-09T23:59:59.000Z

    At the Savannah River Site (SRS) the Defense Waste Processing Facility (DWPF) has been immobilizing SRS's radioactive high level waste (HLW) sludge into a durable borosilicate glass since 1996. Currently the DWPF has poured over 3,500 canisters, all of which are compliant with the U. S. Department of Energy's (DOE) Waste Acceptance Product Specifications for Vitrified High-Level Waste Forms (WAPS) and therefore ready to be shipped to a federal geologic repository for permanent disposal. Due to DOE petitioning to withdraw the Yucca Mountain License Application (LA) from the Nuclear Regulatory Commission (NRC) in 2010 and thus no clear disposal path for SRS canistered waste forms, there are opportunities for cost savings with future canister production at DWPF and other DOE producer sites by reevaluating high-level waste form requirements and compliance strategies and reducing/eliminating those that will not negatively impact the quality of the canistered waste form.

  7. Reevaluation of Vitrified High-Level Waste Form Criteria for Potential Cost Savings at the Defense Waste Processing Facility - 13598

    SciTech Connect (OSTI)

    Ray, J.W. [Savannah River Remediation (United States)] [Savannah River Remediation (United States); Marra, S.L.; Herman, C.C. [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)] [Savannah River National Laboratory, Savannah River Site, Aiken, SC 29808 (United States)

    2013-07-01T23:59:59.000Z

    At the Savannah River Site (SRS) the Defense Waste Processing Facility (DWPF) has been immobilizing SRS's radioactive high level waste (HLW) sludge into a durable borosilicate glass since 1996. Currently the DWPF has poured over 3,500 canisters, all of which are compliant with the U. S. Department of Energy's (DOE) Waste Acceptance Product Specifications for Vitrified High-Level Waste Forms (WAPS) and therefore ready to be shipped to a federal geologic repository for permanent disposal. Due to DOE petitioning to withdraw the Yucca Mountain License Application (LA) from the Nuclear Regulatory Commission (NRC) in 2010 and thus no clear disposal path for SRS canistered waste forms, there are opportunities for cost savings with future canister production at DWPF and other DOE producer sites by reevaluating high-level waste form requirements and compliance strategies and reducing/eliminating those that will not negatively impact the quality of the canistered waste form. (authors)

  8. 1M. Panahi, S. Skogestad ' Controlled Variables Selection for a Natural Gas to Liquids (GTL) process' Controlled Variables Selection for a

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1M. Panahi, S. Skogestad ' Controlled Variables Selection for a Natural Gas to Liquids (GTL) process' Controlled Variables Selection for a Natural Gas to Liquids (GTL) process Mehdi Panahi Sigurd for a Natural Gas to Liquids (GTL) process' Skogestad plantwide control procedure* I Top Down · Step 1: Identify

  9. Removal site evaluation report L-area rubble pile (131-3L) gas cylinder disposal facility (131-2L)

    SciTech Connect (OSTI)

    Palmer, E.R. [Westinghouse Savannah River Company, AIKEN, SC (United States); Mason, J.T.

    1997-10-01T23:59:59.000Z

    This Removal Site Evaluation Report (RSER) is prepared in accordance with Sections 300.410 and 300.415 of the National Contingency Plan and Section XIV of the Savannah River Site (SRS) Federal Facility Agreement (FFA). The purpose of this investigation is to report information concerning conditions at the L-Area Rubble Pile (LRP) (131-3L) and the L-Area Gas Cylinder Disposal Facility (LGCDF) (131- 2L) sufficient to assess the threat posed to human health and the environment. This investigation also assesses the need for additional Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) actions. The scope of this investigation included a review of files, limited sampling efforts, and visits to the area. An investigation of the LRP (1131-3L) indicates the presence of semi volatile organic compounds (SVOCs), volatile organic compounds (VOCs), metals, and asbestos. Potential contaminants in the waste piles could migrate into the secondary media (soils and groundwater), and the presence of some of the contaminants in the piles poses an exposure threat to site works. The Department of Energy (DOE), United States Environmental Protection Agency (EPA) and South Carolina Department of Health and Environmental Control (SCDHEC) discussed the need for a removal action at the Resource Conservation and Recovery Act (RCRA) Facility Investigation/Remedial Investigation (RFI/RI) work plan scoping meetings on the waste unit, and agreed that the presence of the waste piles limits the access to secondary media for sampling, and the removal of the piles would support future characterization of the waste unit. In addition, the DOE, EPA, and SCDHEC agreed that the proposed removal action for the LRP (131-3L) would be documented in the RFI/RI work plan. The LGCDF (131-2L) consists of a backfilled pit containing approximately 28 gas cylinders. The gas cylinders were supposed to have been vented prior to burial; however, there is a potential that a number of the cylinders are still pressurized. (Abstract Truncated)

  10. Guide to research facilities

    SciTech Connect (OSTI)

    Not Available

    1993-06-01T23:59:59.000Z

    This Guide provides information on facilities at US Department of Energy (DOE) and other government laboratories that focus on research and development of energy efficiency and renewable energy technologies. These laboratories have opened these facilities to outside users within the scientific community to encourage cooperation between the laboratories and the private sector. The Guide features two types of facilities: designated user facilities and other research facilities. Designated user facilities are one-of-a-kind DOE facilities that are staffed by personnel with unparalleled expertise and that contain sophisticated equipment. Other research facilities are facilities at DOE and other government laboratories that provide sophisticated equipment, testing areas, or processes that may not be available at private facilities. Each facility listing includes the name and phone number of someone you can call for more information.

  11. Hazardous Waste Facilities Siting (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations describe the siting and permitting process for hazardous waste facilities and reference rules for construction, operation, closure, and post-closure of these facilities.

  12. Process centrifuge operating problems and equipment failures in canyon reprocessing facilities at the Savannah River Site

    SciTech Connect (OSTI)

    Durant, W.S.; Baughman, D.F.

    1990-03-01T23:59:59.000Z

    The Savannah River Laboratory (SRL) maintains a compilation of operating problems and equipment failures that have occurred in the fuel reprocessing areas of the Savannah River Site (SRS). At present, the data bank contains more than 230,000 entries ranging from minor equipment malfunctions to incidents with the potential for injury or contamination of personnel, or for economic loss. The data bank has been used extensively for a wide variety of purposes, such as failure analyses, trend analyses, and preparation of safety analyses. Typical of the data are problems associated with the canyon process centrifuges. This report contains a compilation of the centrifuge operating problems and equipment failures primarily as an aid to organizations with related equipment. Publication of these data was prompted by a number of requests for this information by other Department of Energy (DOE) sites. 11 refs., 2 figs., 4 tabs.

  13. Process for simultaneous removal of SO[sub 2] and NO[sub x] from gas streams

    DOE Patents [OSTI]

    Rosenberg, H.S.

    1987-02-03T23:59:59.000Z

    A process is described for simultaneous removal of SO[sub 2] and NO[sub x] from a gas stream that includes flowing the gas stream to a spray dryer and absorbing a portion of the SO[sub 2] content of the gas stream and a portion of the NO[sub x] content of the gas stream with ZnO by contacting the gas stream with a spray of an aqueous ZnO slurry; controlling the gas outlet temperature of the spray dryer to within the range of about a 0 to 125 F approach to the adiabatic saturation temperature; flowing the gas, unreacted ZnO and absorbed SO[sub 2] and NO[sub x] from the spray dryer to a fabric filter and collecting any solids therein and absorbing a portion of the SO[sub 2] remaining in the gas stream and a portion of the NO[sub x] remaining in the gas stream with ZnO; and controlling the ZnO content of the aqueous slurry so that sufficient unreacted ZnO is present in the solids collected in the fabric filter to react with SO[sub 2] and NO[sub x] as the gas passes through the fabric filter whereby the overall feed ratio of ZnO to SO[sub 2] plus NO[sub x] is about 1.0 to 4.0 moles of ZnO per of SO[sub 2] and about 0.5 to 2.0 moles of ZnO per mole of NO[sub x]. Particulates may be removed from the gas stream prior to treatment in the spray dryer. The process further allows regeneration of ZnO that has reacted to absorb SO[sub 2] and NO[sub x] from the gas stream and acid recovery. 4 figs.

  14. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Amit P. Sharma

    2004-10-01T23:59:59.000Z

    This report describes the progress of the project ''Development and Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the second project year (October 1, 2003--September 30, 2004). There are three main tasks in this research project. Task 1 is scaled physical model study of GAGD process. Task 2 is further development of vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. In Section I, preliminary design of the scaled physical model using the dimensional similarity approach has been presented. Scaled experiments on the current physical model have been designed to investigate the effect of Bond and capillary numbers on GAGD oil recovery. Experimental plan to study the effect of spreading coefficient and reservoir heterogeneity has been presented. Results from the GAGD experiments to study the effect of operating mode, Bond number and capillary number on GAGD oil recovery have been reported. These experiments suggest that the type of the gas does not affect the performance of GAGD in immiscible mode. The cumulative oil recovery has been observed to vary exponentially with Bond and capillary numbers, for the experiments presented in this report. A predictive model using the bundle of capillary tube approach has been developed to predict the performance of free gravity drainage process. In Section II, a mechanistic Parachor model has been proposed for improved prediction of IFT as well as to characterize the mass transfer effects for miscibility development in reservoir crude oil-solvent systems. Sensitivity studies on model results indicate that provision of a single IFT measurement in the proposed model is sufficient for reasonable IFT predictions. An attempt has been made to correlate the exponent (n) in the mechanistic model with normalized solute compositions present in both fluid phases. IFT measurements were carried out in a standard ternary liquid system of benzene, ethanol and water using drop shape analysis and capillary rise techniques. The experimental results indicate strong correlation among the three thermodynamic properties solubility, miscibility and IFT. The miscibility determined from IFT measurements for this ternary liquid system is in good agreement with phase diagram and solubility data, which clearly indicates the sound conceptual basis of VIT technique to determine fluid-fluid miscibility. Model fluid systems have been identified for VIT experimentation at elevated pressures and temperatures. Section III comprises of the experimental study aimed at evaluating the multiphase displacement characteristics of the various gas injection EOR process performances using Berea sandstone cores. During this reporting period, extensive literature review was completed to: (1) study the gravity drainage concepts, (2) identify the various factors influencing gravity stable gas injection processes, (3) identify various multiphase mechanisms and fluid dynamics operative during the GAGD process, and (4) identify important dimensionless groups governing the GAGD process performance. Furthermore, the dimensional analysis of the GAGD process, using Buckingham-Pi theorem to isolate the various dimensionless groups, as well as experimental design based on these dimensionless quantities have been completed in this reporting period. On the experimental front, recommendations from previous WAG and CGI have been used to modify the experimental protocol. This report also includes results from scaled preliminary GAGD displacements as well as the details of the planned GAGD corefloods for the next quarter. The technology transfer activities have mainly consisted of preparing technical papers, progress reports and discussions with industry personnel for possible GAGD field tests.

  15. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16T23:59:59.000Z

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  16. Start up results from a specialized flue gas cleaning facility in a power station using refinery residues

    SciTech Connect (OSTI)

    Beiers, H.G.; Gilgen, R.; Weiler, H.

    1998-07-01T23:59:59.000Z

    In eastern Germany STEAG--the biggest German IPP--has erected a power plant consisting of three combustion lines burning oil distillation residues from the new Mider refinery to provide the refinery with power, steam, water and compressed air. Each of the three flue gas cleaning lines consists of a high dust SCR-system, quench, wet electrostatic precipitator, scrubber, steam reheater and ID-fan. Common systems are the storage and handling of the absorbent, the gypsum dewatering and the waste water treatment. The installed high dust SCR system attains the expected NO{sub x}-reduction efficiency and an excellent NO{sub x} outlet distribution and low ammonia slip. After commissioning problems occurred with the wet ESP in all three lines due to improper function of the upstream quenches. Modifications of the quench system have been made which assure a temperature of the flue gas after quench near saturation temperature and correct functioning of the quench and wet ESP. To reduce pressure loss of the absorber concurrent spray nozzles were installed. Strong vibrations of the absorber tower, the connected pipes and the steel structure along with an insufficient SO{sub x} removal efficiency at high inlet concentration were observed. After changing the concurrent operation of the spray nozzles to counter current operation the vibrations of the absorber tower became smaller and the removal efficiency achieved the guaranteed value. Problems arose in the waste water treatment plant caused by the high solid concentration of up to 1,000 g/l in the thickener. By diluting the settled sludge with overflow water from the thickener the problems in the waste water treatment plant could be minimized to an acceptable degree. Despite these problems the flue gas cleaning system is in continuous operation and the emission values of flue gas and waste water meet the required standards.

  17. FACILITY SAFETY (FS)

    Broader source: Energy.gov (indexed) [DOE]

    FACILITY SAFETY (FS) OBJECTIVE FS.1 - (Core Requirement 7) Facility safety documentation in support of SN process operations,is in place and has been implemented that describes the...

  18. Analyses by the Defense Waste Processing Facility Laboratory of Thorium Glasses from the Sludge Batch 6 Variability Study

    SciTech Connect (OSTI)

    Edwards, T.; Click, D.; Feller, M.

    2011-02-28T23:59:59.000Z

    The Savannah River Remediation (SRR) Defense Waste Processing Facility (DWPF) is currently processing Sludge Batch 6 (SB6) with Frit 418. At times during the processing of this glass system, thorium is expected to be at concentrations in the final wasteform that make it a reportable element for the first time since startup of radioactive operations at the DWPF. The Savannah River National Laboratory (SRNL) supported the qualification of the processing of this glass system at the DWPF. A recommendation from the SRNL studies was the need for the DWPF Laboratory to establish a method to measure thorium by Inductively Coupled Plasma - Atomic Emission Spectroscopy (ICPAES). This recommendation led to the set of thorium-bearing glasses from the SB6 Variability Study (VS) being submitted to the DWPF Laboratory for chemical composition measurement. The measurements were conducted by the DWPF Laboratory using the sodium peroxide fusion preparation method routinely employed for analysis of samples from the Slurry Mix Evaporator (SME). These measurements are presented and reviewed in this report. The review indicates that the measurements provided by the DWPF Laboratory are comparable to those provided by Analytical Development's laboratory at SRNL for these same glasses. As a result, the authors of this report recommend that the DWPF Laboratory begin using its routine peroxide fusion dissolution method for the measurement of thorium in SME samples of SB6. The purpose of this technical report is to present the measurements generated by the DWPF Laboratory for the SB6 VS glasses and to compare the measurements to the targeted compositions for these VS glasses as well as to SRNL's measurements (both sets, targeted and measured, of compositional values were reported by SRNL in [2]). The goal of these comparisons is to provide information that will lead to the qualification of peroxide fusion dissolution as a method for the measurement by the DWPF Laboratory of thorium in SME glass samples.

  19. Advanced hybrid gasification facility

    SciTech Connect (OSTI)

    Sadowski, R.S.; Skinner, W.H. [CRS Sirrine, Inc., Greenville, SC (United States); Johnson, S.A. [PSI Technology Co., Andover, MA (United States); Dixit, V.B. [Riley Stoker Corp., Worcester, MA (United States). Riley Research Center

    1993-08-01T23:59:59.000Z

    The objective of this procurement is to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology for electric power generation applications. The proprietary CRS Sirrine Engineers, Inc. PyGas{trademark} staged gasifier has been selected as the initial gasifier to be developed under this program. The gasifier is expected to avoid agglomeration when used on caking coals. It is also being designed to crack tar vapors and ammonia, and to provide an environment in which volatilized alkali may react with aluminosilicates in the coal ash thereby minimizing their concentration in the hot raw coal gas passing through the system to the gas turbine. This paper describes a novel, staged, airblown, fixed-bed gasifier designed to solve both through the incorporation of pyrolysis (carbonization) with gasification. It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration which occurs in a fixed-bed process when coal is gradually heated through the 400{degrees}F to 900{degrees}F range. In a pyrolyzer, the coal is rapidly heated such that coal tar is immediately vaporized. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can be chemically bound to aluminosilicates in (or added to) the ash. To reduce NOx from fuel home nitrogen, moisture is minimized to control ammonia generation, and HCN in the upper gasifier region is partially oxidized to NO which reacts with NH3/HCN to form N2.

  20. Materials processing issues for non-destructive laser gas sampling (NDLGS)

    SciTech Connect (OSTI)

    Lienert, Thomas J [Los Alamos National Laboratory

    2010-12-09T23:59:59.000Z

    The Non-Destructive Laser Gas Sampling (NDLGS) process essentially involves three steps: (1) laser drilling through the top of a crimped tube made of 304L stainles steel (Hammar and Svennson Cr{sub eq}/Ni{sub eq} = 1.55, produced in 1985); (2) gas sampling; and (3) laser re-welding of the crimp. All three steps are performed in a sealed chamber with a fused silica window under controlled vacuum conditions. Quality requirements for successful processing call for a hermetic re-weld with no cracks or other defects in the fusion zone or HAZ. It has been well established that austenitic stainless steels ({gamma}-SS), such as 304L, can suffer from solidification cracking if their Cr{sub eq}/Ni{sub eq} is below a critical value that causes solidification to occur as austenite (fcc structure) and their combined impurity level (%P+%S) is above {approx}0.02%. Conversely, for Cr{sub eq}/Ni{sub eq} values above the critical level, solidification occurs as ferrite (bcc structure), and cracking propensity is greatly reduced at all combined impurity levels. The consensus of results from studies of several researchers starting in the late 1970's indicates that the critical Cr{sub eq}/Ni{sub eq} value is {approx}1.5 for arc welds. However, more recent studies by the author and others show that the critical Cr{sub eq}/Ni{sub eq} value increases to {approx}1 .6 for weld processes with very rapid thermal cycles, such as the pulsed Nd:YAG laser beam welding (LBW) process used here. Initial attempts at NDLGS using pulsed LBW resulted in considerable solidification cracking, consistent with the results of work discussed above. After a brief introduction to the welding metallurgy of {gamma}-SS, this presentation will review the results of a study aimed at developing a production-ready process that eliminates cracking. The solution to the cracking issue, developed at LANL, involved locally augmenting the Cr content by applying either Cr or a Cr-rich stainless steel (ER 312) to the top of the crimp using the electro-spark deposition (ESD) process followed by laser mixing, drilling and rewelding. Results of a study of the ESD parameters on deposition rate and efficiency will be discussed along with mass balance calculations for determining the desired Cr content to eliminate cracking. The study also required purchase of new pulsed Nd:YAG laser welders. Evaluation of the performance of the new lasers, including beam profiling results, will also be presented. Development of a mixing, drilling and re-welding process at atmospheric pressure with inert gas shielding demonstrated the efficacy of the Cr-augmentation approach. However, extending the process to vacuum conditions proved more challenging owing to loss of laser transmission through the window from spatter and condensation of metal vapors. Solutions developed to circumvent hese issues will be reviewed. Weld microstructures found with various Cr levels will be presented and discussed.

  1. Process Modeling Phase I Summary Report for the Advanced Gas Reactor Fuel Development and Qualification Program

    SciTech Connect (OSTI)

    Pannala, Sreekanth [ORNL; Daw, C Stuart [ORNL; Boyalakuntla, Dhanunjay S [ORNL; FINNEY, Charles E A [ORNL

    2006-09-01T23:59:59.000Z

    This report summarizes the results of preliminary work at Oak Ridge National Laboratory (ORNL) to demonstrate application of computational fluid dynamics modeling to the scale-up of a Fluidized Bed Chemical Vapor Deposition (FBCVD) process for nuclear fuels coating. Specifically, this work, referred to as Modeling Scale-Up Phase I, was conducted between January 1, 2006 and March 31, 2006 in support of the Advanced Gas Reactor (AGR) Program. The objective was to develop, demonstrate and "freeze" a version of ORNL's computational model of the TRI ISOtropic (TRISO) fuel-particle coating process that can be specifically used to assist coater scale-up activities as part of the production of AGR-2 fuel. The results in this report are intended to serve as input for making decisions about initiating additional FBCVD modeling work (referred to as Modeling Scale-Up Phase II) in support of AGR-2. The main computational tool used to implement the model is the general-purpose multiphase fluid-dynamics computer code known as MFIX (Multiphase Flow with Interphase eXchanges), which is documented in detail on the DOE-sponsored website http://www.mfix.org. Additional computational tools are also being developed by ORNL for post-processing MFIX output to efficiently summarize the important information generated by the coater simulations. The summarized information includes quantitative spatial and temporal measures (referred to as discriminating characteristics, or DCs) by which different coater designs and operating conditions can be compared and correlated with trends in product quality. The ORNL FBCVD modeling work is being conducted in conjunction with experimental coater studies at ORNL with natural uranium CO (NUCO) and surrogate fuel kernels. Data are also being obtained from ambient-temperature, spouted-bed characterization experiments at the University of Tennessee and theoretical studies of carbon and silicon carbide chemical vapor deposition kinetics at Iowa State University. Prior to the current scale-up activity, considerable effort has gone in to adapting the MFIX code to incorporate the unique features of fuel coating reactors and also in validating the resulting simulation features with experimental observations. Much of this work is documented in previous AGR reports and publications (Pannala et al., 2004, Pannala et al., 2005, Boyalakuntla et al., 2005a, Boyalakuntla et al., 2005b and Finney et al., 2005). As a result of the previous work described above, the ORNL coater model now has the capability for simulating full spatio-temporal details of the gas-particle hydrodynamics and gas-particle heat and mass transfer in the TRISO coater. This capability provides a great deal of information about many of the processes believed to control quality, but the model is not yet sufficiently developed to fully predict coating quality for any given coater design and/or set of operating conditions because the detailed chemical reaction kinetics needed to make the model fully predictive are not yet available. Nevertheless, the model at its current stage of development already provides the most comprehensive and detailed quantitative information available about gas flows, solid flows, temperatures, and species inside the coater during operation. This level of information ought to be highly useful in expediting the scale-up process (e.g., in correlating observations and minimizing the number of pilot-scale tests required). However, previous work had not yet demonstrated that the typical design and/or operating changes known to affect product quality at the lab scale could be clearly discriminated by the existing model. The Modeling Scale-Up Phase I work was initiated to produce such a demonstration, and two detailed examples are discussed in this report.

  2. Gas Metal Arc Welding Process Modeling and Prediction of Weld Microstructure in MIL A46100 Armor-Grade

    E-Print Network [OSTI]

    Grujicic, Mica

    Gas Metal Arc Welding Process Modeling and Prediction of Weld Microstructure in MIL A46100 Armor metal arc welding (GMAW) butt-joining process has been modeled using a two-way fully coupled, transient in the form of heat, and the mechanical material model of the workpiece and the weld is made temperature

  3. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao; Subhash C. Ayirala; Madhav M. Kulkarni; Thaer N.N. Mahmoud; Wagirin Ruiz Paidin

    2006-01-01T23:59:59.000Z

    This report describes the progress of the project ''Development And Optimization of Gas-Assisted Gravity Drainage (GAGD) Process for Improved Light Oil Recovery'' for the duration of the thirteenth project quarter (Oct 1, 2005 to Dec 30, 2005). There are three main tasks in this research project. Task 1 is a scaled physical model study of the GAGD process. Task 2 is further development of a vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 is determination of multiphase displacement characteristics in reservoir rocks. Section I reports experimental work designed to investigate wettability effects of porous medium, on secondary and tertiary mode GAGD performance. The experiments showed a significant improvement of oil recovery in the oil-wet experiments versus the water-wet runs, both in secondary as well as tertiary mode. When comparing experiments conducted in secondary mode to those run in tertiary mode an improvement in oil recovery was also evident. Additionally, this section summarizes progress made with regard to the scaled physical model construction and experimentation. The purpose of building a scaled physical model, which attempts to include various multiphase mechanics and fluid dynamic parameters operational in the field scale, was to incorporate visual verification of the gas front for viscous instabilities, capillary fingering, and stable displacement. Preliminary experimentation suggested that construction of the 2-D model from sintered glass beads was a feasible alternative. During this reporting quarter, several sintered glass mini-models were prepared and some preliminary experiments designed to visualize gas bubble development were completed. In Section II, the gas-oil interfacial tensions measured in decane-CO{sub 2} system at 100 F and live decane consisting of 25 mole% methane, 30 mole% n-butane and 45 mole% n-decane against CO{sub 2} gas at 160 F have been modeled using the Parachor and newly proposed mechanistic Parachor models. In the decane-CO{sub 2} binary system, Parachor model was found to be sufficient for interfacial tension calculations. The predicted miscibility from the Parachor model deviated only by about 2.5% from the measured VIT miscibility. However, in multicomponent live decane-CO{sub 2} system, the performance of the Parachor model was poor, while good match of interfacial tension predictions has been obtained experimentally using the proposed mechanistic Parachor model. The predicted miscibility from the mechanistic Parachor model accurately matched with the measured VIT miscibility in live decane-CO2 system, which indicates the suitability of this model to predict miscibility in complex multicomponent hydrocarbon systems. In the previous reports to the DOE (15323R07, Oct 2004; 15323R08, Jan 2005; 15323R09, Apr 2005; 15323R10, July 2005 and 154323, Oct 2005), the 1-D experimental results from dimensionally scaled GAGD and WAG corefloods were reported for Section III. Additionally, since Section I reports the experimental results from 2-D physical model experiments; this section attempts to extend this 2-D GAGD study to 3-D (4-phase) flow through porous media and evaluate the performance of these processes using reservoir simulation. Section IV includes the technology transfer efforts undertaken during the quarter. This research work resulted in one international paper presentation in Tulsa, OK; one journal publication; three pending abstracts for SCA 2006 Annual Conference and an invitation to present at the Independents Day session at the IOR Symposium 2006.

  4. Methods to estimate equipment and materials that are candidates for removal during the decontamination of fuel processing facilities

    SciTech Connect (OSTI)

    Duncan, D.R.; Valero, O.J. [Westinghouse Hanford Co., Richland, WA (United States); Hyre, R.A.; Pottmeyer, J.A.; Millar, J.S.; Reddick, J.A. [Los Alamos Technical Associates, Inc., Kennewick, WA (United States)

    1995-02-01T23:59:59.000Z

    The methodology presented in this report provides a model for estimating the volume and types of waste expected from the removal of equipment and other materials during Decontamination and Decommissioning (D and D) of canyon-type fuel reprocessing facilities. This methodology offers a rough estimation technique based on a comparative analysis for a similar, previously studied, reprocessing facility. This approach is especially useful as a planning tool to save time and money while preparing for final D and D. The basic methodology described here can be extended for use at other types of facilities, such as glovebox or reactor facilities.

  5. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Franklin M. Orr, Jr.

    2003-03-31T23:59:59.000Z

    This report outlines progress in the second quarter of the third year of the DOE project ''High Resolution Prediction of Gas Injection Process Performance for Heterogeneous Reservoirs''. This report presents results of an investigation of the effects of variation in interfacial tension (IFT) on three-phase relative permeability. We report experimental results that demonstrate the effect of low IFT between two of three phases on the three-phase relative permeabilities. In order to create three-phase systems, in which IFT can be controlled systematically, we employed analog liquids composing of hexadecane, n-butanol, isopropanol, and water. Phase composition, phase density and viscosity, and IFT of three-phase system were measured and are reported here. We present three-phase relative permeabilities determined from recovery and pressure drop data using the Johnson-Bossler-Naumann (JBN) method. The phase saturations were obtained from recovery data by the Welge method. The experimental results indicate that the wetting phase relative permeability was not affected by IFT variation whereas the other two-phase relative permeabilities were clearly affected. As IFT decreases the ''oil'' and ''gas'' phases become more mobile at the same phase saturations.

  6. Field Demonstration of a Membrane Process to Recover Heavy Hydrocarbons and to Remove Water from Natural Gas

    SciTech Connect (OSTI)

    R. Baker; T. Hofmann; K. A. Lokhandwala

    2006-09-29T23:59:59.000Z

    The objective of this project is to design, construct and field demonstrate a membrane system to recover natural gas liquids (NGL) and remove water from raw natural gas. An extended field test to demonstrate system performance under real-world high-pressure conditions is being conducted to convince industry users of the efficiency and reliability of the process. The system was designed and fabricated by Membrane Technology and Research, Inc. (MTR) and installed and operated at BP Amoco's Pascagoula, MS plant. The Gas Research Institute is partially supporting the field demonstration and BP-Amoco helped install the unit and provides onsite operators and utilities. The gas processed by the membrane system meets pipeline specifications for dew point and BTU value and can be delivered without further treatment to the pipeline. Based on data from prior membrane module tests, the process is likely to be significantly less expensive than glycol dehydration followed by propane refrigeration, the principal competitive technology. During the course of this project, MTR has sold 13 commercial units related to the field test technology, and by the end of this demonstration project the process will be ready for broader commercialization. A route to commercialization has been developed during this project and involves collaboration with other companies already servicing the natural gas processing industry.

  7. Power Systems Development Facility. Quarterly report, January--March 1996

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particular control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the Foster Wheeler portion of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDs) into the structural and process designs. Substantial progress in construction activities was achieved during the quarter.

  8. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, J.; May, C.P.; Pemberton, B.E.; Shinn, J.; Sprague, K.

    1999-03-30T23:59:59.000Z

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus. 8 figs.

  9. Industrial Compositional Streamline Simulation for Efficient and Accurate Prediction of Gas Injection and WAG Processes

    SciTech Connect (OSTI)

    Margot Gerritsen

    2008-10-31T23:59:59.000Z

    Gas-injection processes are widely and increasingly used for enhanced oil recovery (EOR). In the United States, for example, EOR production by gas injection accounts for approximately 45% of total EOR production and has tripled since 1986. The understanding of the multiphase, multicomponent flow taking place in any displacement process is essential for successful design of gas-injection projects. Due to complex reservoir geometry, reservoir fluid properties and phase behavior, the design of accurate and efficient numerical simulations for the multiphase, multicomponent flow governing these processes is nontrivial. In this work, we developed, implemented and tested a streamline based solver for gas injection processes that is computationally very attractive: as compared to traditional Eulerian solvers in use by industry it computes solutions with a computational speed orders of magnitude higher and a comparable accuracy provided that cross-flow effects do not dominate. We contributed to the development of compositional streamline solvers in three significant ways: improvement of the overall framework allowing improved streamline coverage and partial streamline tracing, amongst others; parallelization of the streamline code, which significantly improves wall clock time; and development of new compositional solvers that can be implemented along streamlines as well as in existing Eulerian codes used by industry. We designed several novel ideas in the streamline framework. First, we developed an adaptive streamline coverage algorithm. Adding streamlines locally can reduce computational costs by concentrating computational efforts where needed, and reduce mapping errors. Adapting streamline coverage effectively controls mass balance errors that mostly result from the mapping from streamlines to pressure grid. We also introduced the concept of partial streamlines: streamlines that do not necessarily start and/or end at wells. This allows more efficient coverage and avoids the redundant work generally done in the near-well regions. We improved the accuracy of the streamline simulator with a higher order mapping from pressure grid to streamlines that significantly reduces smoothing errors, and a Kriging algorithm is used to map from the streamlines to the background grid. The higher accuracy of the Kriging mapping means that it is not essential for grid blocks to be crossed by one or more streamlines. The higher accuracy comes at the price of increased computational costs, but allows coarser coverage and so does not generally increase the overall costs of the computations. To reduce errors associated with fixing the pressure field between pressure updates, we developed a higher order global time-stepping method that allows the use of larger global time steps. Third-order ENO schemes are suggested to propagate components along streamlines. Both in the two-phase and three-phase experiments these ENO schemes outperform other (higher order) upwind schemes. Application of the third order ENO scheme leads to overall computational savings because the computational grid used can be coarsened. Grid adaptivity along streamlines is implemented to allow sharp but efficient resolution of solution fronts at reduced computational costs when displacement fronts are sufficiently separated. A correction for Volume Change On Mixing (VCOM) is implemented that is very effective at handling this effect. Finally, a specialized gravity operator splitting method is proposed for use in compositional streamline methods that gives an effective correction of gravity segregation. A significant part of our effort went into the development of a parallelization strategy for streamline solvers on the next generation shared memory machines. We found in this work that the built-in dynamic scheduling strategies of OpenMP lead to parallel efficiencies that are comparable to optimal schedules obtained with customized explicit load balancing strategies as long as the ratio of number of streamlines to number of threads is sufficiently high, which is the case in real-fie

  10. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, Joseph (105 Michael Ct., Aiken, SC 29801); May, Christopher P. (5002 Hesperus Dr., Columbia, MD 21044); Pemberton, Bradley E. (131 Glencarin Dr., Aiken, SC 29803); Shinn, Jim (Box 65, RFD. #1, South Royalton, VT 05068); Sprague, Keith (Box 234 Rte. 14, Brookfield, VT 05036)

    1999-01-01T23:59:59.000Z

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus.

  11. Pyrolysis process for producing condensed stabilized hydrocarbons utilizing a beneficially reactive gas

    DOE Patents [OSTI]

    Durai-Swamy, Kandaswamy (Culver City, CA)

    1982-01-01T23:59:59.000Z

    In a process for recovery of values contained in solid carbonaceous material, the solid carbonaceous material is comminuted and then subjected to pyrolysis, in the presence of a carbon containing solid particulate source of heat and a beneficially reactive transport gas in a transport flash pyrolysis reactor, to form a pyrolysis product stream. The pyrolysis product stream contains a gaseous mixture and particulate solids. The solids are separated from the gaseous mixture to form a substantially solids-free gaseous stream which comprises volatilized hydrocarbon free radicals newly formed by pyrolysis. Preferably the solid particulate source of heat is formed by oxidizing part of the separated particulate solids. The beneficially reactive transport gas inhibits the reactivity of the char product and the carbon-containing solid particulate source of heat. Condensed stabilized hydrocarbons are obtained by quenching the gaseous mixture stream with a quench fluid which contains a capping agent for stabilizing and terminating newly formed volatilized hydrocarbon free radicals. The capping agent is partially depleted of hydrogen by the stabilization and termination reaction. Hydrocarbons of four or more carbon atoms in the gaseous mixture stream are condensed. A liquid stream containing the stabilized liquid product is then treated or separated into various fractions. A liquid containing the hydrogen depleted capping agent is hydrogenated to form a regenerated capping agent. At least a portion of the regenerated capping agent is recycled to the quench zone as the quench fluid. In another embodiment capping agent is produced by the process, separated from the liquid product mixture, and recycled.

  12. CO{sub 2} Capture Membrane Process for Power Plant Flue Gas

    SciTech Connect (OSTI)

    Lora Toy; Atish Kataria; Raghubir Gupta

    2011-09-30T23:59:59.000Z

    Because the fleet of coal-fired power plants is of such importance to the nationâ??s energy production while also being the single largest emitter of CO{sub 2}, the development of retrofit, post-combustion CO{sub 2} capture technologies for existing and new, upcoming coal power plants will allow coal to remain a major component of the U.S. energy mix while mitigating global warming. Post-combustion carbon capture technologies are an attractive option for coal-fired power plants as they do not require modification of major power-plant infrastructures, such as fuel processing, boiler, and steam-turbine subsystems. In this project, the overall objective was to develop an advanced, hollow-fiber, polymeric membrane process that could be cost-effectively retrofitted into current pulverized coal-fired power plants to capture at least 90% of the CO{sub 2} from plant flue gas with 95% captured CO{sub 2} purity. The approach for this project tackled the technology development on three different fronts in parallel: membrane materials R&D, hollow-fiber membrane module development, and process development and engineering. The project team consisted of RTI (prime) and two industrial partners, Arkema, Inc. and Generon IGS, Inc. Two CO{sub 2}-selective membrane polymer platforms were targeted for development in this project. For the near term, a next-generation, high-flux polycarbonate membrane platform was spun into hollow-fiber membranes that were fabricated into both lab-scale and larger prototype (~2,200 ft{sup 2}) membrane modules. For the long term, a new fluoropolymer membrane platform based on poly(vinylidene fluoride) [PVDF] chemistry was developed using a copolymer approach as improved capture membrane materials with superior chemical resistance to flue-gas contaminants (moisture, SO{sub 2}, NOx, etc.). Specific objectives were: ď?· Development of new, highly chemically resistant, fluorinated polymers as membrane materials with minimum selectivity of 30 for CO{sub 2} over N{sub 2} and CO{sub 2} permeance greater than 300 gas permeation units (GPU) targeted; ď?· Development of next-generation polycarbonate hollow-fiber membranes and membrane modules with higher CO{sub 2} permeance than current commercial polycarbonate membranes; ď?· Development and fabrication of membrane hollow fibers and modules from candidate polymers; ď?· Development of a CO{sub 2} capture membrane process design and integration strategy suitable for end-of-pipe, retrofit installation; and ď?· Techno-economic evaluation of the "best" integrated CO{sub 2} capture membrane process design package In this report, the results of the project research and development efforts are discussed and include the post-combustion capture properties of the two membrane material platforms and the hollow-fiber membrane modules developed from them and the multi-stage process design and analysis developed for 90% CO{sub 2} capture with 95% captured CO{sub 2} purity.

  13. The project RTPPP (Development of a realtime PPP processing facility) is planned to be a followup project of RAPPP (Innovative Algorithms for Rapid Precise Point Positioning),

    E-Print Network [OSTI]

    Schuh, Harald

    RTPPP The project RTPPP (Development of a realtime PPP processing facility) is planned to be a followup project of RAPPP (Innovative Algorithms for Rapid Precise Point Positioning), which has RAPPP, the proposed project RTPPP concentrates on the possibilities of the PPP technique within a real

  14. Type B Accident Investigation of the April 8, 2003, Electrical Arc Blast at the Foster Wheeler Environmental Corporation TRU Waste Processing Facility, Oak Ridge, Tennessee

    Broader source: Energy.gov [DOE]

    At approximately 0330 hours on April 8, 2003, a phase-to-phase arc blast occurred in the boiler electrical control panel at the Foster Wheeler Environmental Corporation (FWENC) Transuranic (TRU) Waste Processing Facility. The boiler was providing steam for the evaporator and was reportedly operating at about 10% of its capacity.

  15. Proposed Use of a Constructed Wetland for the Treatment of Metals in the S-04 Outfall of the Defense Waste Processing Facility at the Savannah River Site

    SciTech Connect (OSTI)

    Glover, T.

    1999-11-23T23:59:59.000Z

    The DWPF is part of an integrated waste treatment system at the SRS to treat wastes containing radioactive contaminants. In the early 1980s the DOE recognized that there would be significant safety and cost advantages associated with immobilizing the radioactive waste in a stable solid form. The Defense Waste Processing Facility was designed and constructed to accomplish this task.

  16. Dismantling of Highly Contaminated Process Installations of the German Reprocessing Facility (WAK) - Status of New Remote Handling Technology - 13287

    SciTech Connect (OSTI)

    Dux, Joachim; Friedrich, Daniel; Lutz, Werner; Ripholz, Martina [WAK Rueckbau- und Entsorgungs- GmbH, P.O. Box 12 63, 76339 Eggenstein-Leopoldshafen (Germany)] [WAK Rueckbau- und Entsorgungs- GmbH, P.O. Box 12 63, 76339 Eggenstein-Leopoldshafen (Germany)

    2013-07-01T23:59:59.000Z

    Decommissioning and dismantling of the former German Pilot Reprocessing Plant Karlsruhe (WAK) including the Vitrification Facility (VEK) is being executed in different Project steps related to the reprocessing, HLLW storage and vitrification complexes /1/. While inside the reprocessing building the total inventory of process equipment has already been dismantled and disposed of, the HLLW storage and vitrification complex has been placed out of operation since vitrification and tank rinsing procedures where finalized in year 2010. This paper describes the progress made in dismantling of the shielded boxes of the highly contaminated laboratory as a precondition to get access to the hot cells of the HLLW storage. The major challenges of the dismantling of this laboratory were the high dose rates up to 700 mSv/h and the locking technology for the removal of the hot cell installations. In parallel extensive prototype testing of different carrier systems and power manipulators to be applied to dismantle the HLLW-tanks and other hot cell equipment is ongoing. First experiences with the new manipulator carrier system and a new master slave manipulator with force reflection will be reported. (authors)

  17. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-01-01T23:59:59.000Z

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700şC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

  18. Screening study for waste biomass to ethanol production facility using the Amoco process in New York State. Appendices to the final report

    SciTech Connect (OSTI)

    NONE

    1995-08-01T23:59:59.000Z

    The final report evaluates the economic feasibility of locating biomass-to-ethanol waste conversion facilities in New York State. Part 1 of the study evaluates 74 potential sites in New York City and identifies two preferred sites on Staten Island, the Proctor and Gamble and the Arthur Kill sites for further consideration. Part 2 evaluates upstate New York and determines that four regions surrounding the urban centers of Albany, Buffalo, Rochester, and Syracuse provide suitable areas from which to select specific sites for further consideration. A conceptual design and economic viability evaluation were developed for a minimum-size facility capable of processing 500 tons per day (tpd) of biomass consisting of wood or paper, or a combination of the two for upstate regions. The facility would use Amoco`s biomass conversion technology and produce 49,000 gallons per day of ethanol and approximately 300 tpd of lignin solid by-product. For New York City, a 1,000-tpd processing facility was also evaluated to examine effects of economies of scale. The reports evaluate the feasibility of building a biomass conversion facility in terms of city and state economic, environmental, and community factors. Given the data obtained to date, including changing costs for feedstock and ethanol, the project is marginally attractive. A facility should be as large as possible and located in a New York State Economic Development Zone to take advantage of economic incentives. The facility should have on-site oxidation capabilities, which will make it more financially viable given the high cost of energy. This appendix to the final report provides supplemental material supporting the evaluations.

  19. Low Cost Chemical Feedstocks Using an Improved and Energy Efficient Natural Gas Liquid (NGL) Removal Process, Final Technical Report

    SciTech Connect (OSTI)

    Meyer, Howard, S.; Lu, Yingzhong

    2012-08-10T23:59:59.000Z

    The overall objective of this project is to develop a new low-cost and energy efficient Natural Gas Liquid (NGL) recovery process - through a combination of theoretical, bench-scale and pilot-scale testing - so that it could be offered to the natural gas industry for commercialization. The new process, known as the IROA process, is based on U.S. patent No. 6,553,784, which if commercialized, has the potential of achieving substantial energy savings compared to currently used cryogenic technology. When successfully developed, this technology will benefit the petrochemical industry, which uses NGL as feedstocks, and will also benefit other chemical industries that utilize gas-liquid separation and distillation under similar operating conditions. Specific goals and objectives of the overall program include: (i) collecting relevant physical property and Vapor Liquid Equilibrium (VLE) data for the design and evaluation of the new technology, (ii) solving critical R&D issues including the identification of suitable dehydration and NGL absorbing solvents, inhibiting corrosion, and specifying proper packing structure and materials, (iii) designing, construction and operation of bench and pilot-scale units to verify design performance, (iv) computer simulation of the process using commercial software simulation platforms such as Aspen-Plus and HYSYS, and (v) preparation of a commercialization plan and identification of industrial partners that are interested in utilizing the new technology. NGL is a collective term for C2+ hydrocarbons present in the natural gas. Historically, the commercial value of the separated NGL components has been greater than the thermal value of these liquids in the gas. The revenue derived from extracting NGLs is crucial to ensuring the overall profitability of the domestic natural gas production industry and therefore of ensuring a secure and reliable supply in the 48 contiguous states. However, rising natural gas prices have dramatically reduced the economic incentive to extract NGLs from domestically produced natural gas. Successful gas processors will be those who adopt technologies that are less energy intensive, have lower capital and operating costs and offer the flexibility to tailor the plant performance to maximize product revenue as market conditions change, while maintaining overall system efficiency. Presently, cryogenic turbo-expander technology is the dominant NGL recovery process and it is used throughout the world. This process is known to be highly energy intensive, as substantial energy is required to recompress the processed gas back to pipeline pressure. The purpose of this project is to develop a new NGL separation process that is flexible in terms of ethane rejection and can reduce energy consumption by 20-30% from current levels, particularly for ethane recoveries of less than 70%. The new process integrates the dehydration of the raw natural gas stream and the removal of NGLs in such a way that heat recovery is maximized and pressure losses are minimized so that high-value equipment such as the compressor, turbo-expander, and a separate dehydration unit are not required. GTI completed a techno-economic evaluation of the new process based on an Aspen-HYSYS simulation model. The evaluation incorporated purchased equipment cost estimates obtained from equipment suppliers and two different commercial software packages; namely, Aspen-Icarus and Preliminary Design and Quoting Service (PDQ$). For a 100 MMscfd gas processing plant, the annualized capital cost for the new technology was found to be about 10% lower than that of conventional technology for C2 recovery above 70% and about 40% lower than that of conventional technology for C2 recovery below 50%. It was also found that at around 40-50% C2 recovery (which is economically justifiable at the current natural gas prices), the energy cost to recover NGL using the new technology is about 50% of that of conventional cryogenic technology.

  20. Implementing an Energy Management System at TOTAL Prot Arthur Refinery: The process to improving and sustaining energy efficiency performance at a facility.

    E-Print Network [OSTI]

    Hoyle, A.

    2013-01-01T23:59:59.000Z

    PROPRIETARY INFORMATION? 2011 KBC Advanced Technologies plc. All Rights Reserved. Implementing an Energy Management System at TOTAL Port Arthur Refinery: The process to improving and sustaining energy efficiency performance at a facility May... Improvements ? Cost-savings initiatives ? Increasing environmental awareness ? Increasing throughput by debottlenecking processes ? Increasing government mandates 2May 2013 Energy Costs for a 200kBPD Complex refinery Typically, energy efficiency programs...

  1. Indirect ultraviolet photodesorption from CO:N2 binary ices - an efficient grain-gas process

    E-Print Network [OSTI]

    Bertin, Mathieu; Romanzin, Claire; Poderoso, Hugo A M; Michaut, Xavier; Philippe, Laurent; Jeseck, Pascal; Öberg, Karin I; Linnartz, Harold; Fillion, Jean-Hugues

    2013-01-01T23:59:59.000Z

    UV ice photodesorption is an important non-thermal desorption pathway in many interstellar environments that has been invoked to explain observations of cold molecules in disks, clouds and cloud cores. Systematic laboratory studies of the photodesorption rates, between 7 and 14 eV, from CO:N2 binary ices, have been performed at the DESIRS vacuum UV beamline of the synchrotron facility SOLEIL. The photodesorption spectral analysis demonstrates that the photodesorption process is indirect, i.e. the desorption is induced by a photon absorption in sub-surface molecular layers, while only surface molecules are actually desorbing. The photodesorption spectra of CO and N2 in binary ices therefore depend on the absorption spectra of the dominant species in the subsurface ice layer, which implies that the photodesorption efficiency and energy dependence are dramatically different for mixed and layered ices compared to pure ices. In particular, a thin (1-2 ML) N2 ice layer on top of CO will effectively quench CO photod...

  2. Economics of natural gas upgrading

    SciTech Connect (OSTI)

    Hackworth, J.H.; Koch, R.W.

    1995-07-01T23:59:59.000Z

    Natural gas could be an important alternative energy source in meeting some of the market demand presently met by liquid products from crude oil. This study was initiated to analyze three energy markets to determine if greater use could be made of natural gas or natural gas derived products and if those products could be provided on an economically competitive basis. The three markets targeted for possible increases in gas use were motor fuels, power generation, and the chemical feedstocks market. The economics of processes to convert natural gas to transportation fuels, chemical products, and power were analyzed. The economic analysis was accomplished by drawing on a variety of detailed economic studies, updating them and bringing the results to a common basis. The processes analyzed included production of methanol, MTBE, higher alcohols, gasoline, CNG, and LNG for the transportation market. Production and use of methanol and ammonia in the chemical feedstock market and use of natural gas for power generation were also assessed. Use of both high and low quality gas as a process feed stream was evaluated. The analysis also explored the impact of various gas price growth rates and process facility locations, including remote gas areas. In assessing the transportation fuels market the analysis examined production and use of both conventional and new alternative motor fuels.

  3. Gasification Product Improvement Facility (GPIF)

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brooks, K.S.; Skinner, W.H.; Brown, M.J.

    1992-11-01T23:59:59.000Z

    The objective is to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology electric power generation applications. The proprietary CRS Sirrine Engineers, Inc. PyGas{trademark} staged gasifier has been selected as the initial gasifier to be developed under this program. The gasifier is expected to avoid agglomeration when used on caking coals. It is also being designed to crack tar vapors and ammonia, and to provide an environment in which volatilized alkali may condense onto aluminosilicates in the coal ash thereby minimizing their exiting with the hot raw coal gas and passing through the system to the gas turbine. The management plan calls for a three phased program. The initial phase (Phase 1), includes the CRS Sinine Engineers, Inc. proprietary gasification invention called PyGas{trademark}, necessary coal and limestone receiving/storage/reclaim systems to allow closely metered coal and limestone to be fed into the gasifier for testing. The coal gas is subsequently piped to and combusted in an existing burner of the Monongahela Power Fort Martin Generating Station Unit No. 2. Continuous gasification process steam is generated by a small GPIF packaged boiler using light oil fuel at startup, and by switching from light oil to coal gas after startup. The major peripheral equipment such as foundations, process water system, ash handling, ash storage silo, emergency vent pipe, building, lavatory, electrical interconnect, control room, provisions for Phases II & III, and control system are all included in Phase I. A future hot gas cleanup unit conceptualized to be a zinc ferrite based fluidized bed process constitutes the following phase (Phase H). The final phase (Phase III) contemplates the addition of a combustion turbine and generator set sized to accommodate the parasitic load of the entire system.

  4. Gasification Product Improvement Facility (GPIF)

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brooks, K.S.; Skinner, W.H.; Brown, M.J.

    1992-01-01T23:59:59.000Z

    The objective is to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology electric power generation applications. The proprietary CRS Sirrine Engineers, Inc. PyGas[trademark] staged gasifier has been selected as the initial gasifier to be developed under this program. The gasifier is expected to avoid agglomeration when used on caking coals. It is also being designed to crack tar vapors and ammonia, and to provide an environment in which volatilized alkali may condense onto aluminosilicates in the coal ash thereby minimizing their exiting with the hot raw coal gas and passing through the system to the gas turbine. The management plan calls for a three phased program. The initial phase (Phase 1), includes the CRS Sinine Engineers, Inc. proprietary gasification invention called PyGas[trademark], necessary coal and limestone receiving/storage/reclaim systems to allow closely metered coal and limestone to be fed into the gasifier for testing. The coal gas is subsequently piped to and combusted in an existing burner of the Monongahela Power Fort Martin Generating Station Unit No. 2. Continuous gasification process steam is generated by a small GPIF packaged boiler using light oil fuel at startup, and by switching from light oil to coal gas after startup. The major peripheral equipment such as foundations, process water system, ash handling, ash storage silo, emergency vent pipe, building, lavatory, electrical interconnect, control room, provisions for Phases II III, and control system are all included in Phase I. A future hot gas cleanup unit conceptualized to be a zinc ferrite based fluidized bed process constitutes the following phase (Phase H). The final phase (Phase III) contemplates the addition of a combustion turbine and generator set sized to accommodate the parasitic load of the entire system.

  5. Canastota Renewable Energy Facility Project

    SciTech Connect (OSTI)

    Blake, Jillian; Hunt, Allen

    2013-12-13T23:59:59.000Z

    The project was implemented at the Madison County Landfill located in the Town of Lincoln, Madison County, New York. Madison County has owned and operated the solid waste and recycling facilities at the Buyea Road site since 1974. At the onset of the project, the County owned and operated facilities there to include three separate landfills, a residential solid waste disposal and recycled material drop-off facility, a recycling facility and associated administrative, support and environmental control facilities. This putrescible waste undergoes anaerobic decomposition within the waste mass and generates landfill gas, which is approximately 50% methane. In order to recover this gas, the landfill was equipped with gas collection systems on both the east and west sides of Buyea Road which bring the gas to a central point for destruction. In order to derive a beneficial use from the collected landfill gases, the County decided to issue a Request for Proposals (RFP) for the future use of the generated gas.

  6. Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke

    SciTech Connect (OSTI)

    Zubilin, I.G.; Umanskii, V.E.

    1984-01-01T23:59:59.000Z

    The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

  7. Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry

    E-Print Network [OSTI]

    Qiao, Li

    Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas: Coal gasification Carbon gasification Detailed chemistry Heterogeneous surface reactions Radiation Multi-physics numerical modeling a b s t r a c t Fuel synthesis through coal and biomass gasification

  8. Fabrication of gas turbine water-cooled composite nozzle and bucket hardware employing plasma spray process

    DOE Patents [OSTI]

    Schilke, Peter W. (4 Hempshire Ct., Scotia, NY 12302); Muth, Myron C. (R.D. #3, Western Ave., Amsterdam, NY 12010); Schilling, William F. (301 Garnsey Rd., Rexford, NY 12148); Rairden, III, John R. (6 Coronet Ct., Schenectady, NY 12309)

    1983-01-01T23:59:59.000Z

    In the method for fabrication of water-cooled composite nozzle and bucket hardware for high temperature gas turbines, a high thermal conductivity copper alloy is applied, employing a high velocity/low pressure (HV/LP) plasma arc spraying process, to an assembly comprising a structural framework of copper alloy or a nickel-based super alloy, or combination of the two, and overlying cooling tubes. The copper alloy is plamsa sprayed to a coating thickness sufficient to completely cover the cooling tubes, and to allow for machining back of the copper alloy to create a smooth surface having a thickness of from 0.010 inch (0.254 mm) to 0.150 inch (3.18 mm) or more. The layer of copper applied by the plasma spraying has no continuous porosity, and advantageously may readily be employed to sustain a pressure differential during hot isostatic pressing (HIP) bonding of the overall structure to enhance bonding by solid state diffusion between the component parts of the structure.

  9. Oil and Gas Environmental Review and Approval Processes (New Brunswick, Canada)

    Broader source: Energy.gov [DOE]

    Oil and natural gas companies engaged in exploration, development and production in New Brunswick will be required by the Department of Environment to undergo a Phased Environmental Impact...

  10. EXAMINE AND EVALUATE A PROCESS TO USE SALT CAVERNS TO RECEIVE SHIP BORNE LIQUEFIED NATURAL GAS

    SciTech Connect (OSTI)

    Michael M. McCall; William M. Bishop; D. Braxton Scherz

    2003-04-24T23:59:59.000Z

    The goal of the U.S. Department of Energy cooperative research project is to define, describe, and validate, a process to utilize salt caverns to receive and store the cargoes of LNG ships. The project defines the process as receiving LNG from a ship, pumping the LNG up to cavern injection pressures, warming it to cavern compatible temperatures, injecting the warmed vapor directly into salt caverns for storage, and distribution to the pipeline network. The performance of work under this agreement is based on U.S. Patent 5,511,905, and other U.S. and Foreign pending patent applications. The cost sharing participants in the research are The National Energy Technology Laboratory (U.S. Department of Energy), BP America Production Company, Bluewater Offshore Production Systems (U.S.A.), Inc., and HNG Storage, L.P. Initial results indicate that a salt cavern based receiving terminal could be built at about half the capital cost, less than half the operating costs and would have significantly higher delivery capacity, shorter construction time, and be much more secure than a conventional liquid tank based terminal. There is a significant body of knowledge and practice concerning natural gas storage in salt caverns, and there is a considerable body of knowledge and practice in handling LNG, but there has never been any attempt to develop a process whereby the two technologies can be combined. Salt cavern storage is infinitely more secure than surface storage tanks, far less susceptible to accidents or terrorist acts, and much more acceptable to the community. The project team developed conceptual designs of two salt cavern based LNG terminals, one with caverns located in Calcasieu Parish Louisiana, and the second in Vermilion block 179 about 50 miles offshore Louisiana. These conceptual designs were compared to conventional tank based LNG terminals and demonstrate superior security, economy and capacity. The potential for the development of LNG receiving terminals, utilizing salt caverns for storage and the existing comprehensive pipeline system has profound implications for the next generation of LNG terminals. LNG imports are expected to become an increasingly more important part of the U.S. energy supply and the capacities to receive LNG securely, safely, and economically must be expanded. Salt cavern LNG receiving terminals both in onshore and offshore locations can be quickly built and provide additional import capacity into the U.S. exceeding 6-10 Bcf/day in the aggregate.

  11. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    SciTech Connect (OSTI)

    Lee Nelson

    2009-10-01T23:59:59.000Z

    This report is a preliminary comparison of conventional and potential HTGR-integrated processesa in several common industrial areas: ? Producing electricity via a traditional power cycle ? Producing hydrogen ? Producing ammonia and ammonia-derived products, such as fertilizer ? Producing gasoline and diesel from natural gas or coal ? Producing substitute natural gas from coal, and ? Steam-assisted gravity drainage (extracting oil from tar sands).

  12. HIGH RESOLUTION PREDICTION OF GAS INJECTION PROCESS PERFORMANCE FOR HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Franklin M. Orr, Jr.

    2003-09-30T23:59:59.000Z

    This report outlines progress in the first quarter of the extension of the DOE project ''High Resolution Prediction of Gas Injection Process Performance for Heterogeneous Reservoirs''. This report presents experimental results that demonstrate combined scaling effects of viscous, capillary, and gravity crossflow mechanisms that apply to the situations in which streamline models are used. We designed and ran a series of experiments to investigate combined effects of capillary, viscous, and gravity forces on displacement efficiency in layered systems. Analog liquids (isooctane, isopropanol, and water) were employed to control scaling parameters by changing interfacial tension (IFT), flow rate, and density difference. The porous medium was a two-dimensional (2-D) 2-layered glass bead model with a permeability ratio of about 1:4. In order to analyze the combined effect of only capillary and viscous forces, gravity effects were eliminated by changing the orientation of the glass bead model. We employed a commercial simulator, Eclipse100 to calculate displacement behavior for comparison with the experimental data. Experimental results with minimized gravity effects show that the IFT and flow rate determine how capillary and viscous forces affect behavior of displacement. The limiting behavior for scaling groups for two-phase displacement was verified by experimental results. Analysis of the 2-D images indicates that displacements having a capillary-viscous equilibrium give the best sweep efficiency. Experimental results with gravity effects, but with low IFT fluid systems show that slow displacements produce larger area affected by crossflow. This, in turn, enhances sweep efficiency. The simulation results represent the experimental data well, except for the situations where capillary forces dominate the displacement.

  13. Gasification Product Improvement Facility (GPIF). Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

  14. Integration of a Process Waste Gas into a Site's Energy Concept

    E-Print Network [OSTI]

    Peterson, J.

    In 1996, the BASF Corporation's Geismar, Louisiana site determined that the increased steam demands of their aggressive investment program would require them to expand their steam generation capacity. The site had operated a gas turbine based...

  15. Optimal Process Design for Coupled CO2 Sequestration and Enhanced Gas Recovery in Carbonate Reservoirs

    E-Print Network [OSTI]

    Odi, Uchenna

    2013-12-09T23:59:59.000Z

    Increasing energy demand combined with public concern for the environment obligates the oil industry to supply oil and natural gas to the public while minimizing the carbon footprint due to its activities. Today, fossil fuels are essential...

  16. Solar production of industrial process steam. Phase III. Operation and evaluation of the Johnson and Johnson solar facility. Final report, January 1, 1980-March 31, 1981

    SciTech Connect (OSTI)

    Brink, D.F.; Kendall, J.M.; Youngblood, S.B.

    1981-03-01T23:59:59.000Z

    A solar facility that generates 177/sup 0/C (350/sup 0/F) process steam has been designed and constructed by Acurex Corporation and has operated for 1 yr supplying steam to the Johnson and Johnson manufacturing plant in Sherman, Texas. The facility consists of 1068 m/sup 2/ (11,520 ft/sup 2/) of parabolic trough concentrating collectors, a 18,900 1 (5000 gal) flash boiler, and an 18.6 kW (25 hp) circulating pump. In the first year of operation the system was available 97 percent of the days, and with sufficient solar radiation available it operated 70 percent of the days during this period. The measured data showed that the collector field operated at an efficiency of 25.4 percent for the year, and that at least 75 percent of the energy reaching the flash boiler was delivered to the plant as steam. A total of 309,510 kg (682,400 lb) of steam was produced by the solar facility for the first year. An analysis of the data showed that the delivered energy was within 90 to 100 percent of the predicted value. The successful completion of the first year of operation has demonstrated the technical feasibility of generating industrial process steam with solar energy.

  17. THE DEACTIVATION DECONTAMINATION & DECOMMISSIONING OF THE PLUTONIUM FINISHING PLANT (PFP) A FORMER PLUTONIUM PROCESSING FACILITY AT DOE HANFORD SITE

    SciTech Connect (OSTI)

    CHARBONEAU, S.L.

    2006-02-01T23:59:59.000Z

    The Plutonium Finishing Plant (PFP) was constructed as part of the Manhattan Project during World War II. The Manhattan Project was developed to usher in the use of nuclear weapons to end the war. The primary mission of the PFP was to provide plutonium used as special nuclear material (SNM) for fabrication of nuclear devices for the war effort. Subsequent to the end of World War II, the PFP's mission expanded to support the Cold War effort through plutonium production during the nuclear arms race and later the processing of fuel grade mixed plutonium-uranium oxide to support DOE's breeder reactor program. In October 1990, at the close of the production mission for PFP, a shutdown order was prepared by the Department of Energy (DOE) in Washington, DC and issued to the Richland DOE field office. Subsequent to the shutdown order, a team from the Defense Nuclear Facilities Safety Board (DNFSB) analyzed the hazards at PFP associated with the continued storage of certain forms of plutonium solutions and solids. The assessment identified many discrete actions that were required to stabilize the different plutonium forms into stable form and repackage the material in high integrity containers. These actions were technically complicated and completed as part of the PFP nuclear material stabilization project between 1995 and early 2005. The completion of the stabilization project was a necessary first step in deactivating PFP. During stabilization, DOE entered into negotiations with the U.S. Environmental Protection Agency (EPA) and the State of Washington and established milestones for the Deactivation and Decommissioning (D&D) of the PFP. The DOE and its contractor, Fluor Hanford (Fluor), have made great progress in deactivating, decontaminating and decommissioning the PFP at the Hanford Site as detailed in this paper. Background information covering the PFP D&D effort includes descriptions of negotiations with the State of Washington concerning consent-order milestones, milestones completed to date, and the vision of bringing PFP to slab-on-grade. Innovative approaches in planning and regulatory strategies, as well new technologies from within the United States and from other countries and field decontamination techniques developed by workforce personnel, such as the ''turkey roaster'' and the ''lazy Susan'' are covered in detail in the paper. Critical information on issues and opportunities during the performance of the work such as concerns regarding the handling and storage of special nuclear material, concerns regarding criticality safety and the impact of SNM de-inventory at PFP are also provided. The continued success of the PFP D&D effort is due to the detailed, yet flexible, approach to planning that applied innovative techniques and tools, involved a team of experienced independent reviewers, and incorporated previous lessons learned at the Hanford site, Rocky Flats, and commercial nuclear D&D projects. Multi-disciplined worker involvement in the planning and the execution of the work has produced a committed workforce that has developed innovative techniques, resulting in safer and more efficient work evolutions.

  18. DEVELOPMENT AND OPTIMIZATION OF GAS-ASSISTED GRAVITY DRAINAGE (GAGD) PROCESS FOR IMPROVED LIGHT OIL RECOVERY

    SciTech Connect (OSTI)

    Dandina N. Rao

    2003-10-01T23:59:59.000Z

    This is the first Annual Technical Progress Report being submitted to the U. S. Department of Energy on the work performed under the Cooperative Agreement DE-FC26-02NT15323. This report follows two other progress reports submitted to U.S. DOE during the first year of the project: The first in April 2003 for the project period from October 1, 2002 to March 31, 2003, and the second in July 2003 for the period April 1, 2003 to June 30, 2003. Although the present Annual Report covers the first year of the project from October 1, 2002 to September 30, 2003, its contents reflect mainly the work performed in the last quarter (July-September, 2003) since the work performed during the first three quarters has been reported in detail in the two earlier reports. The main objective of the project is to develop a new gas-injection enhanced oil recovery process to recover the oil trapped in reservoirs subsequent to primary and/or secondary recovery operations. The project is divided into three main tasks. Task 1 involves the design and development of a scaled physical model. Task 2 consists of further development of the vanishing interfacial tension (VIT) technique for miscibility determination. Task 3 involves the determination of multiphase displacement characteristics in reservoir rocks. Each technical progress report, including this one, reports on the progress made in each of these tasks during the reporting period. Section I covers the scaled physical model study. A survey of literature in related areas has been conducted. Test apparatus has been under construction throughout the reporting period. A bead-pack visual model, liquid injection system, and an image analysis system have been completed and used for preliminary experiments. Experimental runs with decane and paraffin oil have been conducted in the bead pack model. The results indicate the need for modifications in the apparatus, which are currently underway. A bundle of capillary tube model has been considered and formulated aiming to reveal the interplay of the viscous, interfacial and gravity forces and to predict the gravity drainage performance. Scaling criteria for the scaled physical model design have been proposed based on an inspectional analysis. In Section II, equation of state (EOS) calculations were extended to study the effect of different tuning parameters on MMP for two reservoir crude oils of Rainbow Keg River and Terra Nova. This study indicates that tuning of EOS may not always be advisable for miscibility determination. Comparison of IFT measurements for benzene in water, ethanol mixtures with the solubility data from the literature showed that a strong mutual relationship between these two thermodynamic properties exists. These preliminary experiments indicate applicability of the new vanishing interfacial tension (VIT) technique to determine miscibility of ternary liquid systems. The VIT experimental apparatus is under construction with considerations of expanded capacity of using equilibrated fluids and a new provision for low IFT measurement in gas-oil systems. In Section III, recommendations in the previous progress reports have been investigated in this reporting period. WAG coreflood experiments suggest the use of ''Hybrid''-WAG type floods for improved CO{sub 2} utilization factors and recoveries. The effect of saturating the injection water with CO{sub 2} for core-floods has been investigated further in this quarter. Miscible WAG floods using CO{sub 2} saturated brine showed higher recoveries (89.2% ROIP) compared to miscible WAG floods using normal brine (72.5%). Higher tertiary recovery factors (TRF) were also observed for WAG floods using CO{sub 2} saturated brine due to improved mobility ratio and availability of CO{sub 2}. Continued experimentation for evaluation of both, ''Hybrid''-WAG and gravity stable type displacements, in Berea sandstone cores using synthetic as well as real reservoir fluids are planned for the next quarter.

  19. Process for forming a long gas turbine engine blade having a main wall with a thin portion near a tip

    DOE Patents [OSTI]

    Campbell, Christian X; Thomaidis, Dimitrios

    2014-05-13T23:59:59.000Z

    A process is provided for forming an airfoil for a gas turbine engine involving: forming a casting of a gas turbine engine airfoil having a main wall and an interior cavity, the main wall having a wall thickness extending from an external surface of the outer wall to the interior cavity, an outer section of the main wall extending from a location between a base and a tip of the airfoil casting to the tip having a wall thickness greater than a final thickness. The process may further involve effecting movement, using a computer system, of a material removal apparatus and the casting relative to one another such that a layer of material is removed from the casting at one or more radial portions along the main wall of the casting.

  20. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  1. Preliminary evaluation of a concept using microwave energy to improve an adsorption-based, natural gas clean-up process

    SciTech Connect (OSTI)

    Grimes, R.W.

    1992-12-01T23:59:59.000Z

    This report describes the results of a preliminary evaluation performed to: (1) determine if microwave energy could be used to regenerate a zeolite adsorbent and (2) to evaluate the feasibility of using microwave energy to improve the desorption phase of a pressure swing adsorption process applied to upgrading natural gas (methane) contaminated with nitrogen. Microwave regeneration was evaluated by comparing the adsorption characteristics of a zeolite preconditioned by heating under vacuum to the characteristics of the same zeolite after various lengths of exposure to microwave energy. The applicability of microwave regeneration to natural gas cleanup was evaluated by measuring the rise in adsorbent temperature resulting from the microwave exposure. Microwave energy consumed by heating the adsorbent is not productive and must therefore be minimal for a process to be economically viable. Exposure of the methane-saturated chabazite for 2 minutes to microwave energy effectively regenerated the adsorbent, but resulted in a 75{degrees}F (42{degrees}C) rise in adsorbent temperature. This temperature rise indicates that the concept is unacceptable for natural gas processing due to excessive energy consumption.

  2. Energy Performance Contracting in State Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contracting in State Facilities Energy Performance Contracting in State Facilities Provides a brief overview of the performance contracting process, the benefits of using...

  3. UK FT PDU Facility Draft EA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Process Development Unit Facility February 2014 The facility is sized as a small-scale pilot CBTL plant that would produce research quantities of FT liquid fuels at...

  4. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07T23:59:59.000Z

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  5. A dynamic process model of a natural gas combined cycle -- Model development with startup and shutdown simulations

    SciTech Connect (OSTI)

    Liese, Eric [U.S. DOE; Zitney, Stephen E. [U.S. DOE

    2013-01-01T23:59:59.000Z

    Research in dynamic process simulation for integrated gasification combined cycles (IGCC) with carbon capture has been ongoing at the National Energy Technology Laboratory (NETL), culminating in a full operator training simulator (OTS) and immersive training simulator (ITS) for use in both operator training and research. A derivative work of the IGCC dynamic simulator has been a modification of the combined cycle section to more closely represent a typical natural gas fired combined cycle (NGCC). This paper describes the NGCC dynamic process model and highlights some of the simulator’s current capabilities through a particular startup and shutdown scenario.

  6. Facility Microgrids

    SciTech Connect (OSTI)

    Ye, Z.; Walling, R.; Miller, N.; Du, P.; Nelson, K.

    2005-05-01T23:59:59.000Z

    Microgrids are receiving a considerable interest from the power industry, partly because their business and technical structure shows promise as a means of taking full advantage of distributed generation. This report investigates three issues associated with facility microgrids: (1) Multiple-distributed generation facility microgrids' unintentional islanding protection, (2) Facility microgrids' response to bulk grid disturbances, and (3) Facility microgrids' intentional islanding.

  7. Process and catalyst for converting synthesis gas to liquid hydrocarbon mixture

    DOE Patents [OSTI]

    Rao, V. Udaya S. (Monroeville, PA); Gormley, Robert J. (Pittsburgh, PA)

    1987-01-01T23:59:59.000Z

    Synthesis gas containing CO and H.sub.2 is converted to a high-octane hydrocarbon liquid in the gasoline boiling point range by bringing the gas into contact with a heterogeneous catalyst including, in physical mixture, a zeolite molecular sieve, cobalt at 6-20% by weight, and thoria at 0.5-3.9% by weight. The contacting occurs at a temperature of 250.degree.-300.degree. C., and a pressure of 10-30 atmospheres. The conditions can be selected to form a major portion of the hydrocarbon product in the gasoline boiling range with a research octane of more than 80 and less than 10% by weight aromatics.

  8. Electro-Mechanical Manipulator for Use in the Remote Equipment Decontamination Cell at the Defense Waste Processing Facility, Savannah River Site - 12454

    SciTech Connect (OSTI)

    Lambrecht, Bill; Dixon, Joe [Par Systems, Shoreview, Minnesota, 55126 (United States); Neuville, John R. [Savannah River Remediation, Savannah River Site, Aiken, South Carolina, 29808 (United States)

    2012-07-01T23:59:59.000Z

    One of the legacies of the cold war is millions of liters of radioactive waste. One of the locations where this waste is stored is at the Savannah River Site (SRS) in South Carolina. A major effort to clean up this waste is on-going at the defense waste processing facility (DWPF) at SRS. A piece of this effort is decontamination of the equipment used in the DWPF to process the waste. The remote equipment decontamination cell (REDC) in the DWPF uses electro-mechanical manipulators (EMM) arms manufactured and supplied by PaR Systems to decontaminate DWPF process equipment. The decontamination fluid creates a highly corrosive environment. After 25 years of operational use the original EMM arms are aging and need replacement. To support continued operation of the DWPF, two direct replacement EMM arms were delivered to the REDC in the summer of 2011. (authors)

  9. Rates for Alternate Energy Production Facilities (Iowa)

    Broader source: Energy.gov [DOE]

    The Utilities Board may require public utilities furnishing gas, electricity, communications, or water to public consumers, to own alternate energy production facilities, enter into long-term...

  10. Implementing waste minimization at an active plutonium processing facility: Successes and progress at technical area (TA) -55 of the Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Balkey, J.J.; Robinson, M.A.; Boak, J.

    1997-12-01T23:59:59.000Z

    The Los Alamos National Laboratory has ongoing national security missions that necessitate increased plutonium processing. The bulk of this activity occurs at Technical Area -55 (TA-55), the nations only operable plutonium facility. TA-55 has developed and demonstrated a number of technologies that significantly minimize waste generation in plutonium processing (supercritical CO{sub 2}, Mg(OH){sub 2} precipitation, supercritical H{sub 2}O oxidation, WAND), disposition of excess fissile materials (hydride-dehydride, electrolytic decontamination), disposition of historical waste inventories (salt distillation), and Decontamination & Decommissioning (D&D) of closed nuclear facilities (electrolytic decontamination). Furthermore, TA-55 is in the process of developing additional waste minimization technologies (molten salt oxidation, nitric acid recycle, americium extraction) that will significantly reduce ongoing waste generation rates and allow volume reduction of existing waste streams. Cost savings from reduction in waste volumes to be managed and disposed far exceed development and deployment costs in every case. Waste minimization is also important because it reduces occupational exposure to ionizing radiation, risks of transportation accidents, and transfer of burdens from current nuclear operations to future generations.

  11. Rheology Of MonoSodium Titanate (MST) And Modified Mst (mMST) Mixtures Relevant To The Salt Waste Processing Facility

    SciTech Connect (OSTI)

    Koopman, D. C.; Martino, C. J.; Shehee, T. C.; Poirier, M. R.

    2013-07-31T23:59:59.000Z

    The Savannah River National Laboratory performed measurements of the rheology of suspensions and settled layers of treated material applicable to the Savannah River Site Salt Waste Processing Facility. Suspended solids mixtures included monosodium titanate (MST) or modified MST (mMST) at various solid concentrations and soluble ion concentrations with and without the inclusion of kaolin clay or simulated sludge. Layers of settled solids were MST/sludge or mMST/sludge mixtures, either with or without sorbed strontium, over a range of initial solids concentrations, soluble ion concentrations, and settling times.

  12. Environmental assessment operation of the HB-Line facility and frame waste recovery process for production of Pu-238 oxide at the Savannah River Site

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0948, addressing future operations of the HB-Line facility and the Frame Waste Recovery process at the Savannah River Site (SRS), near Aiken, South Carolina. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969. Therefore, DOE has concluded that, the preparation of an environmental impact statement is not required, and is issuing this Finding of No Significant Impact.

  13. HYTEST Phase I Facility Commissioning and Modeling

    SciTech Connect (OSTI)

    Lee P. Shunn; Richard D. Boardman; Shane J. Cherry; Craig G. Rieger

    2009-09-01T23:59:59.000Z

    The purpose of this document is to report the first year accomplishments of two coordinated Laboratory Directed Research and Development (LDRD) projects that utilize a hybrid energy testing laboratory that couples various reactors to investigate system reactance behavior. This work is the first phase of a series of hybrid energy research and testing stations - referred to hereafter as HYTEST facilities – that are planned for construction and operation at the Idaho National Laboratory (INL). A HYTEST Phase I facility was set up and commissioned in Bay 9 of the Bonneville County Technology Center (BCTC). The purpose of this facility is to utilize the hydrogen and oxygen that is produced by the High Temperature Steam Electrolysis test reactors operating in Bay 9 to support the investigation of kinetic phenomena and transient response of integrated reactor components. This facility provides a convenient scale for conducting scoping tests of new reaction concepts, materials performance, new instruments, and real-time data collection and manipulation for advance process controls. An enclosed reactor module was assembled and connected to a new ventilation system equipped with a variable-speed exhaust blower to mitigate hazardous gas exposures, as well as contract with hot surfaces. The module was equipped with a hydrogen gas pump and receiver tank to supply high quality hydrogen to chemical reactors located in the hood.

  14. Process for CO.sub.2 capture using zeolites from high pressure and moderate temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV); Stevens, Robert W. (Morgantown, WV)

    2012-03-06T23:59:59.000Z

    A method for separating CO.sub.2 from a gas stream comprised of CO.sub.2 and other gaseous constituents using a zeolite sorbent in a swing-adsorption process, producing a high temperature CO.sub.2 stream at a higher CO.sub.2 pressure than the input gas stream. The method utilizes CO.sub.2 desorption in a CO.sub.2 atmosphere and effectively integrates heat transfers for optimizes overall efficiency. H.sub.2O adsorption does not preclude effective operation of the sorbent. The cycle may be incorporated in an IGCC for efficient pre-combustion CO.sub.2 capture. A particular application operates on shifted syngas at a temperature exceeding 200.degree. C. and produces a dry CO.sub.2 stream at low temperature and high CO.sub.2 pressure, greatly reducing any compression energy requirements which may be subsequently required.

  15. Preferential oxidation of methanol and carbon monoxide for gas cleanup during methanol fuel processing

    SciTech Connect (OSTI)

    Birdsell, S.A.; Vanderborgh, N.E.; Inbody, M.A. [Los Alamos National Lab., NM (United States)

    1993-07-01T23:59:59.000Z

    Methanol fuel processing generates hydrogen for low-temperature, PEM fuel cell systems now being considered for transportation and other applications. Although liquid methanol fuel is convenient for this application, existing fuel processing techniques generate contaminants that degrade fuel cell performance. Through mathematical models and laboratory experiments chemical processing is described that removes CO and other contaminants from the anode feed stream.

  16. Pipelines and Underground Gas Storage (Iowa)

    Broader source: Energy.gov [DOE]

    These rules apply to intrastate transport of natural gas and other substances via pipeline, as well as underground gas storage facilities. The construction and operation of such infrastructure...

  17. NSTAR (Gas)- Commercial Energy Efficiency Programs

    Broader source: Energy.gov [DOE]

    NSTAR Gas offers incentives for their commercial customers to save energy in existing facilities. Rebates are for high efficiency gas space heating equipment, water heating equipment, infrared...

  18. Catalyst and process for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K. (Yorktown Heights, NY)

    1987-01-01T23:59:59.000Z

    The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  19. Process for generation of hydrogen gas from various feedstocks using thermophilic bacteria

    DOE Patents [OSTI]

    Ooteghem, Suellen Van (Morgantown, WV)

    2005-09-13T23:59:59.000Z

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45.degree. C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  20. Process for Generation of Hydrogen Gas from Various Feedstocks Using Thermophilic Bacteria

    SciTech Connect (OSTI)

    Ooteghem Van, Suellen

    2005-09-13T23:59:59.000Z

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45 degrees C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  1. Assessment of microbial processes on gas production at radioactive low-level waste disposal sites

    SciTech Connect (OSTI)

    Weiss, A.J.; Tate, R.L. III; Colombo, P.

    1982-05-01T23:59:59.000Z

    Factors controlling gaseous emanations from low level radioactive waste disposal sites are assessed. Importance of gaseous fluxes of methane, carbon dioxide, and possible hydrogen from the site, stems from the inclusion of tritium and/or carbon-14 into the elemental composition of these compounds. In that the primary source of these gases is the biodegradation of organic components of the waste material, primary emphasis of the study involved an examination of the biochemical pathways producing methane, carbon dioxide, and hydrogen, and the environmental parameters controlling the activity of the microbial community involved. Initial examination of the data indicates that the ecosystem is anaerobic. As the result of the complexity of the pathway leading to methane production, factors such as substrate availability, which limit the initial reaction in the sequence, greatly affect the overall rate of methane evolution. Biochemical transformations of methane, hydrogen and carbon dioxide as they pass through the soil profile above the trench are discussed. Results of gas studies performed at three commercial low level radioactive waste disposal sites are reviewed. Methods used to obtain trench and soil gas samples are discussed. Estimates of rates of gas production and amounts released into the atmosphere (by the GASFLOW model) are evaluated. Tritium and carbon-14 gaseous compounds have been measured in these studies; tritiated methane is the major radionuclide species in all disposal trenches studied. The concentration of methane in a typical trench increases with the age of the trench, whereas the concentration of carbon dioxide is similar in all trenches.

  2. Reducing Plug and Process Loads for a Large Scale, Low Energy Office Building: NREL's Research Support Facility; Preprint

    SciTech Connect (OSTI)

    Lobato, C.; Pless, S.; Sheppy, M.; Torcellini, P.

    2011-02-01T23:59:59.000Z

    This paper documents the design and operational plug and process load energy efficiency measures needed to allow a large scale office building to reach ultra high efficiency building goals. The appendices of this document contain a wealth of documentation pertaining to plug and process load design in the RSF, including a list of equipment was selected for use.

  3. Environmental report for the Gasification Product Improvement Facility (GPIF)

    SciTech Connect (OSTI)

    Sadowski, R.S.; Skinner, W.H.; Norris, E.S.; Duck, R.R.; Hass, R.B.; Morgan, M.E.; Helble, J.J.; Johnson, S.A.

    1993-01-01T23:59:59.000Z

    The Fossil Energy Program has a mission to develop energy systems that utilize national coal resources in power systems with increased efficiency and environmental compatibility. Coal gasification technology is a versatile candidate that meets this goal. This two phased project consists primarily of the design, construction and operation of a 5-foot inside diameter (minimum) fixed-bed gasifier called PyGas{trademark} and supporting infrastructure (Phase I), and an additional follow on phase consisting of the design, construction and operation of a hot fuel gas cleanup unit (Phase II). Issues expected to be successfully overcome by PyGas{trademark} through its application in this test facility include the processing of high-swelling coals, which causes agglomeration in conventional fixed-bed gasifiers. Such coals comprise 87% of all eastern coals. Other issues expected to be eliminated or significantly reduced include: production of ash clinkers, production of ammonia, the presence of significant tars and fines, and the volatilization of alkalinity in the product fuel gas. A second portion of the NEPA report is concerned with the emission of toxic metal compounds by the gasification process improvement facility (GPIF). The GPIF facility will be located on site at the Fort Martin facility of Allegheny Power Company, and the energy produced (steam) will be directly used by Fort Martin to produce electricity. The coal used at the GPIF facility will be the same coal used by the utility. Therefore, the emissions of the GPIF will be put in context of the entire facility. The GPIF assessment will be divided into four sections: Estimation of the toxic metals content of the raw coal; calculation of the emissions from Fort Martin normally; an estimate of the emission from the GPIF; and a comparison of the two flows.

  4. Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas

    E-Print Network [OSTI]

    Yang, Zhenyu

    Plant-wide Control for Better De-oiling of Produced Water in Offshore Oil & Gas Production Zhenyu (PWT) in offshore oil & gas production processes. Different from most existing facility- or material offshore and the oil industry expects this share to grow continuously in the future. In last decade, oil

  5. The effective spectral irradiance of ultra-violet radiations from inert-gas-shielded welding processes in relation to the ARC current density

    E-Print Network [OSTI]

    DeVore, Robin Kent

    1973-01-01T23:59:59.000Z

    THE EFFECTIVE SPECTRAL IRRADIANCE OF ULTRAVIOLET RADIATIONS FROM INERT-GAS-SHIELDED MELDING PROCESSES IN RELATION TO THE ARC CURRENT DENSITY A Thesis by ROBIN KENT DEVORE Submitted to the Graduate College of Texas A&M University in partial... fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1973 Major Subject: Industrial Hygiene THE EFFECTIVE SPECTRAL IRRADIANCE OF ULTRAVIOLET RADIATIONS FROM INERT-GAS-SHIELDED WELDING PROCESSES IN RELATION TO THE ARC CURRENT...

  6. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1996-10-24T23:59:59.000Z

    Establishes facility safety requirements related to: nuclear safety design, criticality safety, fire protection and natural phenomena hazards mitigation.

  7. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1995-11-16T23:59:59.000Z

    Establishes facility safety requirements related to: nuclear safety design, criticality safety, fire protection and natural phenomena hazards mitigation.

  8. Integration of analysis and experiment for Stirling cycle processes: Part 1, Gas spring hysteresis loss

    SciTech Connect (OSTI)

    Kornhauser, A.A.; Smith, J.L. Jr.

    1988-01-01T23:59:59.000Z

    Heat transfer-related hysteresis loss can be an important factor in the performance of Stirling and other reciprocating machines. Analytical predictions of hysteresis loss have been available to designers, but until now they were not experimentally verified. Hysteresis loss was measured in a piston-cylinder gas spring over a range of speeds, pressures, gases, bore/stroke ratios, volume ratios, and internal extended surface geometries. An analysis of a simplified one-dimensional energy equation produced non-dimensional parameters that were used to correlate the experimental data. The loss expression from the analysis was adjusted to fit the correlated data. 7 refs., 8 figs.

  9. New Mexico Natural Gas Processed in New Mexico (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomic team:6-2015(Million Cubic Feet) New Mexico Natural GasNew

  10. ,"U.S. Total Exports Natural Gas Plant Processing"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: EnergyShale ProvedTexas"BruneiReserves in Nonproducing Reservoirs (MillionNatural Gas Plant

  11. Natural Gas Processing Plants in the United States: 2010 Update / Figure 6

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet) Year Jan Feb Marthrough Monthly Download Series8826. Natural Gas

  12. Gas injection to inhibit migration during an in situ heat treatment process

    DOE Patents [OSTI]

    Kuhlman, Myron Ira (Houston, TX); Vinegar; Harold J. (Bellaire, TX); Baker, Ralph Sterman (Fitchburg, MA); Heron, Goren (Keene, CA)

    2010-11-30T23:59:59.000Z

    Methods of treating a subsurface formation are described herein. Methods for treating a subsurface treatment area in a formation may include introducing a fluid into the formation from a plurality of wells offset from a treatment area of an in situ heat treatment process to inhibit outward migration of formation fluid from the in situ heat treatment process.

  13. Geohydrologic study of the Michigan Basin for the applicability of Jack W. McIntyre`s patented process for simultaneous gas recovery and water disposal in production wells

    SciTech Connect (OSTI)

    Maryn, S.

    1994-03-01T23:59:59.000Z

    Geraghty & Miller, Inc. of Midland, Texas conducted a geohydrologic study of the Michigan Basin to evaluate the applicability of Jack McIntyre`s patented process for gas recovery and water disposal in production wells. A review of available publications was conducted to identify, (1) natural gas reservoirs which generate large quantities of gas and water, and (2) underground injection zones for produced water. Research efforts were focused on unconventional natural gas formations. The Antrim Shale is a Devonian gas shale which produces gas and large quantities of water. Total 1992 production from 2,626 wells was 74,209,916 Mcf of gas and 25,795,334 bbl of water. The Middle Devonian Dundee Limestone is a major injection zone for produced water. ``Waterless completion`` wells have been completed in the Antrim Shale for gas recovery and in the Dundee Limestone for water disposal. Jack McIntyre`s patented process has potential application for the recovery of gas from the Antrim Shale and simultaneous injection of produced water into the Dundee Limestone.

  14. A new process for volume reduction of radwaste, drying and calcination of crystals

    SciTech Connect (OSTI)

    Krapukhin, V.B.; Kareta, V.I.; Zurin, V.D.; Lavricov, V.A.; Grushevsky, S.E. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Physical Chemistry

    1993-12-31T23:59:59.000Z

    The facility COMPLEX-1 designed for carrying out the processes of mass crystallization from solutions, separation of the resulting solid phase from mother liquor, drying of crystals, their calcination and loading the product obtained into containers, is described. The facility is entirely hermetic. It works in vacuum and has an autonomous system of gas purification, excluding the carryover of dust during the thermal treatment of the product obtained. All the technological processes are continuous and carried out in a minimum volume without pumping the products from apparatus to apparatus. The facility is compact and ecologically safer than the familiar analogous facilities. Each unit of the facility may be of special interest for users.

  15. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01T23:59:59.000Z

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  16. Wet processing of palladium for use in the tritium facility at Westinghouse, Savannah River, SC. Preparation of palladium using the Mound Muddy Water process

    SciTech Connect (OSTI)

    Baldwin, D.P.; Zamzow, D.S.

    1998-11-10T23:59:59.000Z

    Palladium used at Savannah River for tritium storage is currently obtained from a commercial source. In order to better understand the processes involved in preparing this material, Savannah River is supporting investigations into the chemical reactions used to synthesize this material and into the conditions necessary to produce palladium powder that meets their specifications. This better understanding may help to guarantee a continued reliable source for this material in the future. As part of this evaluation, a work-for-others contract between Westinghouse Savannah River Company and the Ames Laboratory Metallurgy and Ceramics Program was initiated. During FY98, the process for producing palladium powder developed in 1986 by Dan Grove of Mound Applied Technologies (USDOE) was studied to understand the processing conditions that lead to changes in morphology in the final product. This report details the results of this study of the Mound Muddy Water process, along with the results of a round-robin analysis of well-characterized palladium samples that was performed by Savannah River and Ames Laboratory. The Mound Muddy Water process is comprised of three basic wet chemical processes, palladium dissolution, neutralization, and precipitation, with a number of filtration steps to remove unwanted impurity precipitates.

  17. International Facility Management Association Strategic Facility

    Broader source: Energy.gov (indexed) [DOE]

    Facility Management Association Strategic Facility Planning: A WhIte PAPer Strategic Facility Planning: A White Paper on Strategic Facility Planning 2009 | International...

  18. Carbon capture by sorption-enhanced water-gas shift reaction process using hydrotalcite-based material

    SciTech Connect (OSTI)

    van Selow, E.R.; Cobden, P.D.; Verbraeken, P.A.; Hufton, J.R.; van den Brink, R.W. [Energy research Center of the Netherlands, Petten (Netherlands)

    2009-05-15T23:59:59.000Z

    A novel route for precombustion decarbonization is the sorption-enhanced water-gas shift (SEWGS) process. In this process carbon dioxide is removed from a synthesis gas at elevated temperature by adsorption. Simultaneously, carbon monoxide is converted to carbon dioxide by the water-gas shift reaction. The periodic adsorption and desorption of carbon dioxide is induced by a pressure swing cycle, and the cyclic capacity can be amplified by purging with steam. From previous studies is it known that for SEWGS applications, hydrotalcite-based materials are particularly attractive as sorbent, and commercial high-temperature shift catalysts can be used for the conversion of carbon monoxide. Tablets of a potassium promoted hydrotalcite-based material are characterized in both breakthrough and cyclic experiments in a 2 m tall fixed-bed reactor. When exposed to a mixture of carbon dioxide, steam, and nitrogen at 400{sup o}C, the material shows a breakthrough capacity of 1.4 mmol/g. In subsequent experiments the material was mixed with tablets of promoted iron-chromium shift catalyst and exposed to a mixture of carbon dioxide, carbon monoxide, steam, hydrogen, and nitrogen. It is demonstrated that carbon monoxide conversion can be enhanced to 100% in the presence of a carbon dioxide sorbent. At breakthrough, carbon monoxide and carbon dioxide simultaneously appear at the end of the bed. During more than 300 cycles of adsorption/reaction and desorption, the capture rate, and carbon monoxide conversion are confirmed to be stable. Two different cycle types are investigated: one cycle with a CO{sub 2} rinse step and one cycle with a steam rinse step. The performance of both SEWGS cycles are discussed.

  19. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30T23:59:59.000Z

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature of the vapor phase components of the conveyed sample gas. In addition, to minimize adsorption or chemical changes in the syngas components prior to analysis, the temperature of the transported stream is maintained as hot as is practical, while still being cooled only as much necessary prior to entering the analyzer(s). The successful transport of the sample gas stream to the analyzer(s) is accomplished through the managed combination of four basic gas conditioning methods that are applied as specifically called for by the process conditions, the gas constituent concentrations, the analyzer requirements, and the objectives of the syngas analyses: 1) removing entrained particulate matter from the sample stream; 2) maintaining the temperature of the sample gas stream; 3) lowering the pressure of the sample gas stream to decrease the vapor pressures of all the component vapor species in the sample stream; and 4) diluting the gas stream with a metered, inert gas, such as nitrogen. Proof-of-concept field demonstrations of the sampling approach were conducted for gasification process streams from a black liquor gasifier, and from the gasification of biomass and coal feedstocks at GTI’s Flex-Fuel Test Facility. In addition to the descriptions and data included in this Final Report, GTI produced a Special Topical Report, Design and Protocol for Monitoring Gaseous Species in Thermochemical Processes, that explains and describes in detail the objectives, principles, design, hardware, installation, operation and representative data produced during this successful developmental effort. Although the specific analyzers used under Cooperative Agreement DE-FC36-02GO12024 were referenced in the Topical Report and this Final Report, the sampling interface design they present is generic enough to adapt to other analyzers that may be more appropriate to alternate process streams or facilities.

  20. Advanced conceptual design report solid waste retrieval facility, phase I, project W-113

    SciTech Connect (OSTI)

    Smith, K.E.

    1994-03-21T23:59:59.000Z

    Project W-113 will provide the equipment and facilities necessary to retrieve suspect transuranic (TRU) waste from Trench 04 of the 218W-4C burial ground. As part of the retrieval process, waste drums will be assayed, overpacked, vented, head-gas sampled, and x-rayed prior to shipment to the Phase V storage facility in preparation for receipt at the Waste Receiving and Processing Facility (WRAP). Advanced Conceptual Design (ACD) studies focused on project items warranting further definition prior to Title I design and areas where the potential for cost savings existed. This ACD Report documents the studies performed during FY93 to optimize the equipment and facilities provided in relation to other SWOC facilities and to provide additional design information for Definitive Design.

  1. Integration of High Temperature Gas-cooled Reactor Technology with Oil Sands Processes

    SciTech Connect (OSTI)

    L.E. Demick

    2011-10-01T23:59:59.000Z

    This paper summarizes an evaluation of siting an HTGR plant in a remote area supplying steam, electricity and high temperature gas for recovery and upgrading of unconventional crude oil from oil sands. The area selected for this evaluation is the Alberta Canada oil sands. This is a very fertile and active area for bitumen recovery and upgrading with significant quantities piped to refineries in Canada and the U.S Additionally data on the energy consumption and other factors that are required to complete the evaluation of HTGR application is readily available in the public domain. There is also interest by the Alberta oil sands producers (OSP) in identifying alternative energy sources for their operations. It should be noted, however, that the results of this evaluation could be applied to any similar oil sands area.

  2. Electrochemical machining process for forming surface roughness elements on a gas turbine shroud

    DOE Patents [OSTI]

    Lee, Ching-Pang (Cincinnati, OH); Johnson, Robert Alan (Simpsonville, SC); Wei, Bin (Mechanicville, NY); Wang, Hsin-Pang (Rexford, NY)

    2002-01-01T23:59:59.000Z

    The back side recessed cooling surface of a shroud defining in part the hot gas path of a turbine is electrochemically machined to provide surface roughness elements and spaces therebetween to increase the heat transfer coefficient. To accomplish this, an electrode with insulating dielectric portions and non-insulating portions is disposed in opposition to the cooling surface. By passing an electrolyte between the cooling surface and electrode and applying an electrical current between the electrode and a shroud, roughness elements and spaces therebetween are formed in the cooling surface in opposition to the insulating and non-insulating portions of the electrode, hence increasing the surface area and heat transfer coefficient of the shroud.

  3. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30T23:59:59.000Z

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology also addressed safety concerns associated with thermochemical process operation that constrain the location and configuration of potential gas analysis equipment. Initial analyzer costs, reliability, accuracy, and operating and maintenance costs were also considered prior to the assembly of suitable analyzers for this work. Initial tests at GTI’s Flex-Fuel Test Facility (FFTF) in late 2004 and early 2005 successfully demonstrated the transport and subsequent analysis of a single depressurized, heat-traced syngas stream to a single analyzer (an Industrial Machine and Control Corporation (IMACC) Fourier-transform infrared spectrometer (FT-IR)) provided by GTI. In March 2005, our sampling approach was significantly expanded when this project participated in the U.S. DOE’s Novel Gas Cleaning (NGC) project. Syngas sample streams from three process locations were transported to a distribution manifold for selectable analysis by the IMACC FT-IR, a Stanford Research Systems QMS300 Mass Spectrometer (SRS MS) obtained under this Cooperative Agreement, and a Varian micro gas chromatograph with thermal conductivity detector (?GC) provided by GTI. A syngas stream from a fourth process location was transported to an Agilent Model 5890 Series II gas chromatograph for highly sensitive gas analyses. The on-line analyses made possible by this sampling system verified the syngas cleaning achieved by the NGC process. In June 2005, GTI collaborated with Weyerhaeuser to characterize the ChemrecTM black liquor gasifier at Weyerhaeuser’s New Bern, North Carolina pulp mill. Over a ten-day period, a broad range of process operating conditions were characterized with the IMACC FT-IR, the SRS MS, the Varian ?GC, and an integrated Gas Chromatograph, Mass Selective Detector, Flame Ionization Detector and Sulfur Chemiluminescence Detector (GC/MSD/FID/SCD) system acquired under this Cooperative Agreement from Wasson-ECE. In this field application, a single sample stream was extracted from this low-pressure, low-temperature process and successfully analyzed by these devices. In late 2005,

  4. Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01T23:59:59.000Z

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  5. Chemical Engineering and Processing 43 (2004) 149160 Minimum superficial gas velocity for onset of foaming

    E-Print Network [OSTI]

    Pilon, Laurent

    ; Foam fractionation; Slag foaming; Glass foam 1. Introduction Semi-batch foams or pneumatic foams protein concentration [2]. In food processes or in glass melting furnaces, foam is unde- sirable since of foaming Laurent Pilona,, Raymond Viskantab a Mechanical and Aerospace Engineering Department, University

  6. TREATMENT TANK OFF-GAS TESTING FOR THE ENHANCED CHEMICAL CLEANING PROCESS

    SciTech Connect (OSTI)

    Wiersma, B.

    2011-08-29T23:59:59.000Z

    The purpose of this activity was to provide a bounding estimate of the volume of hydrogen gas generated during Enhanced Chemical Cleaning (ECC) of residual sludge remaining in a Type I or Type II treatment tank as well as to provide results independent of the sludge volume in the waste tank to be cleaned. Previous testing to support Chemical Cleaning was based on a 20:1 oxalic acid to sludge ratio. Hydrogen gas evolution is the primary safety concern. Sealed vessel coupon tests were performed to estimate the hydrogen generation rate due to corrosion of carbon steel by 2.5 wt.% oxalic acid. These tests determined the maximum instantaneous hydrogen generation rate, the rate at which the generation rate decays, and the total hydrogen generated. These values were quantified based on a small scale methodology similar to the one described in WSRC-STI-2007-00209, Rev. 0. The measured rates support identified Safety Class functions. The tests were performed with ASTM A285 Grade C carbon steel coupons. Bounding conditions were determined for the solution environment. The oxalic acid concentration was 2.5 wt.% and the test temperature was 75 C. The test solution was agitated and contained no sludge simulant. Duplicate tests were performed and showed excellent reproducibility for the hydrogen generation rate and total hydrogen generated. The results showed that the hydrogen generation rate was initially high, but decayed rapidly within a couple of days. A statistical model was developed to predict the instantaneous hydrogen generation rate as a function of exposure time by combining both sets of data. An upper bound on the maximum hydrogen generation rate was determined from the upper 95% confidence limit. The upper bound confidence limit for the hydrogen generation rate is represented by the following equation. ln (G{sub v}) = -8.22-0.0584 t + 0.0002 t{sup 2}. This equation should be utilized to estimate the instantaneous hydrogen generation rate per unit surface area, G{sub v}, at a given time, t. The units for G{sub v} and t are ft{sup 3}/ft{sup 2}/min and hours, respectively. The total volume of hydrogen gas generated during the test was calculated from the model equation. An upper bound on the total gas generated was determined from the upper 95% confidence limit. The upper bound limit on the total hydrogen generated during the 163 hour test was 0.332 ft{sup 3}/ft{sup 2}. The maximum instantaneous hydrogen generation rate for this scenario is greater than that previously measured in the 8 wt.% oxalic acid tests due to both the absence of sludge in the test (i.e., greater than 20:1 ratio of acid to sludge) and the use of polished coupons (vs. mill scale coupons). However, due to passivation of the carbon steel surface, the corrosion rate decays by an order of magnitude within the first three days of exposure such that the instantaneous hydrogen generation rates are less than that previously measure in the 8 wt.% oxalic acid tests. While the results of these tests are bounding, the conditions used in this study may not be representative of the ECC flowsheet, and the applicability of these results to the flowsheet should be evaluated for the following reasons: (1) The absence of sludge results in higher instantaneous hydrogen generation rates than when the sludge is present; and (2) Polished coupons do not represent the condition of the carbon steel interior of the tank, which are covered with mill scale. Based on lower instantaneous corrosion rates measured on mill scale coupons exposed to oxalic acid, lower instantaneous hydrogen generation rates are expected for the tank interior than measured on the polished coupons. Corrosion rates were determined from the coupon tests and also calculated from the measured hydrogen generation rates. Excellent agreement was achieved between the time averaged corrosion rate calculated from the hydrogen generation rates and the corrosion rates determined from the coupon tests. The corrosion rates were on the order of 18 to 28 mpy. Good agreement was also observed between the maximum instantaneo

  7. Development Of Ion Chromatography Methods To Support Testing Of The Glycolic Acid Reductant Flowsheet In The Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Wiedenman, B. J.; White, T. L.; Mahannah, R. N.; Best, D. R.; Stone, M. E.; Click, D. R.; Lambert, D. P.; Coleman, C. J.

    2013-10-01T23:59:59.000Z

    Ion Chromatography (IC) is the principal analytical method used to support studies of Sludge Reciept and Adjustment Tank (SRAT) chemistry at DWPF. A series of prior analytical ''Round Robin'' (RR) studies included both supernate and sludge samples from SRAT simulant, previously reported as memos, are tabulated in this report.2,3 From these studies it was determined to standardize IC column size to 4 mm diameter, eliminating the capillary column from use. As a follow on test, the DWPF laboratory, the PSAL laboratory, and the AD laboratory participated in the current analytical RR to determine a suite of anions in SRAT simulant by IC, results also are tabulated in this report. The particular goal was to confirm the laboratories ability to measure and quantitate glycolate ion. The target was + or - 20% inter-lab agreement of the analyte averages for the RR. Each of the three laboratories analyzed a batch of 12 samples. For each laboratory, the percent relative standard deviation (%RSD) of the averages on nitrate, glycolate, and oxalate, was 10% or less. The three laboratories all met the goal of 20% relative agreement for nitrate and glycolate. For oxalate, the PSAL laboratory reported an average value that was 20% higher than the average values reported by the DWPF laboratory and the AD laboratory. Because of this wider window of agreement, it was concluded to continue the practice of an additional acid digestion for total oxalate measurement. It should also be noted that large amounts of glycolate in the SRAT samples will have an impact on detection limits of near eluting peaks, namely Fluoride and Formate. A suite of scoping experiments are presented in the report to identify and isolate other potential interlaboratory disceprancies. Specific ion chromatography inter-laboratory method conditions and differences are tabulated. Most differences were minor but there are some temperature control equipment differences that are significant leading to a recommendation of a heated jacket for analytical columns that are remoted for use in radiohoods. A suggested method improvement would be to implement column temperture control at a temperature slightly above ambient to avoid peak shifting due to temperature fluctuations. Temperature control in this manner would improve short and longer term peak retention time stability. An unknown peak was observed during the analysis of glycolic acid and SRAT simulant. The unknown peak was determined to best match diglycolic acid. The development of a method for acetate is summaraized, and no significant amount of acetate was observed in the SRAT products tested. In addition, an alternative Gas Chromatograph (GC) method for glycolate is summarized.

  8. Continuous process preparation of activated silica with low carbon dioxide content gas

    E-Print Network [OSTI]

    Burdett, Joseph Walton

    1954-01-01T23:59:59.000Z

    Iiroduced. Activated silica is the term used to designate a negatively charged colloidal particle formed by the reactien of a dilute sodium silicate solution with a dilute solution of' an acidic material or other activant. Used as a coagulant sid to alum.... paylis (5) at Chicago found that, sodium silicate could. 'be used with paper maker's alum (aluminum sulfate) as an effective c~t aid. in treating Lake l4. chigan water. Since that time several. batch processes have been cleveloyed using various...

  9. Gulf Of Mexico Natural Gas Processed in Alabama (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) YearfromProcessed (Million

  10. Gulf Of Mexico Natural Gas Processed in Louisiana (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) YearfromProcessed

  11. Gulf Of Mexico Natural Gas Processed in Mississippi (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) YearfromProcessedMississippi

  12. Gulf Of Mexico Natural Gas Processed in Texas (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) YearfromProcessedMississippiTexas

  13. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30T23:59:59.000Z

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

  14. Redox cycle stability of mixed oxides used for hydrogen generation in the cyclic water gas shift process

    SciTech Connect (OSTI)

    Datta, Pradyot, E-mail: pradyot.datta@gmail.com

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • Fe{sub 2}O{sub 3} modified with CaO, SiO{sub 2} and Al{sub 2}O{sub 3} was studied in cyclic water gas shift reactor. • For the first time stability of such oxides were tested for 100 redox cycles. • Optimally added oxides significantly improved the activity and the stability of Fe{sub 2}O{sub 3}. • Increased stability was attributed to the impediment of neck formation. - Abstract: Repeated cycles of the reduction of Fe{sub 3}O{sub 4} with reductive gas, e.g. hydrogen and subsequent oxidation of the reduced iron material with water vapor can be harnessed as a process for the production of pure hydrogen. The redox behavior of iron oxide modified with various amounts of SiO{sub 2}, CaO and Al{sub 2}O{sub 3} was investigated in the present study. The total amount of the additional metal oxides was always below 15 wt%. The samples were prepared by co-precipitation using urea hydrolysis method. The influence of various metal oxides on the hydrogen production capacity and the material stability was studied in detail in terms of temperature-programmed reduction (TPR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET analysis. Furthermore, the activity and the stability of the samples were tested in repeated reduction with diluted H{sub 2} and re-oxidation cycles with H{sub 2}O. The results indicate that combination of several oxides as promoter increases the stability of the iron oxide material by mitigating the sintering process. The positive influence of the oxides in stabilizing the iron oxide material is attributed to the impediment of neck formation responsible for sintering.

  15. Impact of mine closure and access facilities on gas emissions from old mine workings to surface: examples of French iron and coal

    E-Print Network [OSTI]

    Boyer, Edmond

    : examples of French iron and coal Lorraine basins C. Lagny, R. Salmon, Z. Pokryszka and S. Lafortune (INERIS of mine shafts located in the iron Lorraine basin, in the Lorraine and in North-East coal basins are quite in mine workings but gas entrance and exit are allowed. Coal shafts are secured and can be equipped

  16. Flare Gas Recovery in Shell Canada Refineries

    E-Print Network [OSTI]

    Allen, G. D.; Wey, R. E.; Chan, H. H.

    1983-01-01T23:59:59.000Z

    Two of Shell Canada's refineries have logged about six years total operating experience with modern flare gas recovery facilities. The flare gas recovery systems were designed to recover the normal continuous flare gas flow for use in the refinery...

  17. Screening Level Risk Assessment for the New Waste Calcining Facility

    SciTech Connect (OSTI)

    M. L. Abbott; K. N. Keck; R. E. Schindler; R. L. VanHorn; N. L. Hampton; M. B. Heiser

    1999-05-01T23:59:59.000Z

    This screening level risk assessment evaluates potential adverse human health and ecological impacts resulting from continued operations of the calciner at the New Waste Calcining Facility (NWCF) at the Idaho Nuclear Technology and Engineering Center (INTEC), Idaho National Engineering and Environmental Laboratory (INEEL). The assessment was conducted in accordance with the Environmental Protection Agency (EPA) report, Guidance for Performing Screening Level Risk Analyses at Combustion Facilities Burning Hazardous Waste. This screening guidance is intended to give a conservative estimate of the potential risks to determine whether a more refined assessment is warranted. The NWCF uses a fluidized-bed combustor to solidify (calcine) liquid radioactive mixed waste from the INTEC Tank Farm facility. Calciner off volatilized metal species, trace organic compounds, and low-levels of radionuclides. Conservative stack emission rates were calculated based on maximum waste solution feed samples, conservative assumptions for off gas partitioning of metals and organics, stack gas sampling for mercury, and conservative measurements of contaminant removal (decontamination factors) in the off gas treatment system. Stack emissions were modeled using the ISC3 air dispersion model to predict maximum particulate and vapor air concentrations and ground deposition rates. Results demonstrate that NWCF emissions calculated from best-available process knowledge would result in maximum onsite and offsite health and ecological impacts that are less then EPA-established criteria for operation of a combustion facility.

  18. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-12-22T23:59:59.000Z

    This Order establishes facility and programmatic safety requirements for Department of Energy facilities, which includes nuclear and explosives safety design criteria, fire protection, criticality safety, natural phenomena hazards mitigation, and the System Engineer Program. Cancels DOE O 420.1A. DOE O 420.1B Chg 1 issued 4-19-10.

  19. Developing a gas purchasing strategy using a linear model

    SciTech Connect (OSTI)

    Alst, K.M. Van [Midland Cogeneration Venture Limited Partnership, Midland, MI (United States)

    1995-12-31T23:59:59.000Z

    This paper outlines the process of developing a gas purchasing strategy with the use of a linear programming model. The linear model is used to determine the least cost approach regarding the acquisition of natural gas which has a considerable impact on the company`s financial performance. The author discusses the importance of optimizing gas costs from an end-user`s perspective. The Midland Cogeneration Venture (MCV) is the country`s largest cogeneration facility. The Facility has been certified by FERC (Federal Energy Regulatory Commission) as a Q.F. (Qualifying Facility) under PURPA (Public Utility Regulatory Policies Act of 1978). Unlike utilities, who have the ability to pass costs through to customers, MCV`s revenues are based on long-term contracts with its utility and industrial customers. Therefore, MCV cannot pass costs through to its customers. As such, effectively managing costs is vital to the success of the company.

  20. IGNITION IMPROVEMENT OF LEAN NATURAL GAS MIXTURES

    SciTech Connect (OSTI)

    Jason M. Keith

    2005-02-01T23:59:59.000Z

    This report describes work performed during a thirty month project which involves the production of dimethyl ether (DME) on-site for use as an ignition-improving additive in a compression-ignition natural gas engine. A single cylinder spark ignition engine was converted to compression ignition operation. The engine was then fully instrumented with a cylinder pressure transducer, crank shaft position sensor, airflow meter, natural gas mass flow sensor, and an exhaust temperature sensor. Finally, the engine was interfaced with a control system for pilot injection of DME. The engine testing is currently in progress. In addition, a one-pass process to form DME from natural gas was simulated with chemical processing software. Natural gas is reformed to synthesis gas (a mixture of hydrogen and carbon monoxide), converted into methanol, and finally to DME in three steps. Of additional benefit to the internal combustion engine, the offgas from the pilot process can be mixed with the main natural gas charge and is expected to improve engine performance. Furthermore, a one-pass pilot facility was constructed to produce 3.7 liters/hour (0.98 gallons/hour) DME from methanol in order to characterize the effluent DME solution and determine suitability for engine use. Successful production of DME led to an economic estimate of completing a full natural gas-to-DME pilot process. Additional experimental work in constructing a synthesis gas to methanol reactor is in progress. The overall recommendation from this work is that natural gas to DME is not a suitable pathway to improved natural gas engine performance. The major reasons are difficulties in handling DME for pilot injection and the large capital costs associated with DME production from natural gas.

  1. Life cycle assessment of hydrogen production from S-I thermochemical process coupled to a high temperature gas reactor

    SciTech Connect (OSTI)

    Giraldi, M. R.; Francois, J. L.; Castro-Uriegas, D. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac No. 8532, Col. Progreso, C.P. 62550, Jiutepec, Morelos (Mexico)

    2012-07-01T23:59:59.000Z

    The purpose of this paper is to quantify the greenhouse gas (GHG) emissions associated to the hydrogen produced by the sulfur-iodine thermochemical process, coupled to a high temperature nuclear reactor, and to compare the results with other life cycle analysis (LCA) studies on hydrogen production technologies, both conventional and emerging. The LCA tool was used to quantify the impacts associated with climate change. The product system was defined by the following steps: (i) extraction and manufacturing of raw materials (upstream flows), (U) external energy supplied to the system, (iii) nuclear power plant, and (iv) hydrogen production plant. Particular attention was focused to those processes where there was limited information from literature about inventory data, as the TRISO fuel manufacture, and the production of iodine. The results show that the electric power, supplied to the hydrogen plant, is a sensitive parameter for GHG emissions. When the nuclear power plant supplied the electrical power, low GHG emissions were obtained. These results improve those reported by conventional hydrogen production methods, such as steam reforming. (authors)

  2. Hanford facility contingency plan

    SciTech Connect (OSTI)

    Sutton, L.N.

    1996-07-01T23:59:59.000Z

    The Hanford Facility Contingency Plan, together with each TSD unit- specific contingency plan, meets the WAC 173-303 requirements for a contingency plan. Applicability of this plan to Hanford Facility activities is described in the Hanford Facility RCRA Permit, Dangerous Waste Portion, General Condition II.A. General Condition II.A applies to Part III TSD units, Part V TSD units, and to releases of hazardous substances which threaten human health or the environment. Additional information about the applicability of this document may also be found in the Hanford Facility RCRA Permit Handbook (DOE/RL-96-10). This plan includes descriptions of responses to a nonradiological hazardous substance spill or release at Hanford Facility locations not covered by TSD unit-specific contingency plans or building emergency plans. The term hazardous substances is defined in WAC 173-303-040 as: ``any liquid, solid, gas, or sludge, including any material, substance, product, commodity, or waste, regardless of quantity, that exhibits any of the physical, chemical or biological properties described in WAC 173-303-090 or 173-303-100.`` Whenever the term hazardous substances is used in this document, it will be used in the context of this definition. This plan includes descriptions of responses for spills or releases of hazardous substances occurring at areas between TSD units that may, or may not, threaten human health or the environment.

  3. Design/installation and structural integrity assessment of Bethel Valley low-level waste collection and transfer system upgrade for Building 3092 (Central Off-Gas Scrubber Facility) at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    NONE

    1995-01-01T23:59:59.000Z

    This document describes and assesses planned modifications to be made to the Building 3092 Central Off-Gas Scrubber Facility of the Oak Ridge National Laboratory, Oak Ridge, Tennessee. The modifications are made in responsible to the requirements of 40CFR264 Subpart J, relating to environmental protection requirements for buried tank systems. The modifications include the provision of a new scrubber recirculation tank in a new, below ground, lines concrete vault, replacing and existing recirculation sump that does not provide double containment. A new buried, double contained pipeline is provided to permit discharge of spent scrubber recirculation fluid to the Central Waste Collection Header. The new vault, tank, and discharge line are provided with leak detection and provisions to remove accumulated liquid. New scrubber recirculation pumps, piping, and accessories are also provided. This assessment concludes that the planned modifications comply with applicable requirements of 40CFR264 Subpart J, as set forth in Appendix F to the Federal Facility Agreement, Docket No. 89-04-FF, covering the Oak Ridge Reservation.

  4. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Swanson, Michael; Henderson, Ann

    2012-04-01T23:59:59.000Z

    The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

  5. CANISTER HANDLING FACILITY DESCRIPTION DOCUMENT

    SciTech Connect (OSTI)

    J.F. Beesley

    2005-04-21T23:59:59.000Z

    The purpose of this facility description document (FDD) is to establish requirements and associated bases that drive the design of the Canister Handling Facility (CHF), which will allow the design effort to proceed to license application. This FDD will be revised at strategic points as the design matures. This FDD identifies the requirements and describes the facility design, as it currently exists, with emphasis on attributes of the design provided to meet the requirements. This FDD is an engineering tool for design control; accordingly, the primary audience and users are design engineers. This FDD is part of an iterative design process. It leads the design process with regard to the flowdown of upper tier requirements onto the facility. Knowledge of these requirements is essential in performing the design process. The FDD follows the design with regard to the description of the facility. The description provided in this FDD reflects the current results of the design process.

  6. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2002-05-20T23:59:59.000Z

    To establish facility safety requirements for the Department of Energy, including National Nuclear Security Administration. Cancels DOE O 420.1. Canceled by DOE O 420.1B.

  7. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2013-06-21T23:59:59.000Z

    DOE-STD-1104 contains the Department's method and criteria for reviewing and approving nuclear facility's documented safety analysis (DSA). This review and approval formally document the basis for DOE, concluding that a facility can be operated safely in a manner that adequately protects workers, the public, and the environment. Therefore, it is appropriate to formally require implementation of the review methodology and criteria contained in DOE-STD-1104.

  8. Facility Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-11-20T23:59:59.000Z

    The objective of this Order is to establish facility safety requirements related to: nuclear safety design, criticality safety, fire protection and natural phenomena hazards mitigation. The Order has Change 1 dated 11-16-95, Change 2 dated 10-24-96, and the latest Change 3 dated 11-22-00 incorporated. The latest change satisfies a commitment made to the Defense Nuclear Facilities Safety Board (DNFSB) in response to DNFSB recommendation 97-2, Criticality Safety.

  9. Verification of the Accountability Method as a Means to Classify Radioactive Wastes Processed Using THOR Fluidized Bed Steam Reforming at the Studsvik Processing Facility in Erwin, Tennessee, USA - 13087

    SciTech Connect (OSTI)

    Olander, Jonathan [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States)] [Studsvik Processing Facility Erwin, 151 T.C. Runnion Rd., Erwin, TN 37650 (United States); Myers, Corey [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)] [Studsvik, Inc., 5605 Glenridge Drive, Suite 705, Atlanta, GA 30342 (United States)

    2013-07-01T23:59:59.000Z

    Studsviks' Processing Facility Erwin (SPFE) has been treating Low-Level Radioactive Waste using its patented THOR process for over 13 years. Studsvik has been mixing and processing wastes of the same waste classification but different chemical and isotopic characteristics for the full extent of this period as a general matter of operations. Studsvik utilizes the accountability method to track the movement of radionuclides from acceptance of waste, through processing, and finally in the classification of waste for disposal. Recently the NRC has proposed to revise the 1995 Branch Technical Position on Concentration Averaging and Encapsulation (1995 BTP on CA) with additional clarification (draft BTP on CA). The draft BTP on CA has paved the way for large scale blending of higher activity and lower activity waste to produce a single waste for the purpose of classification. With the onset of blending in the waste treatment industry, there is concern from the public and state regulators as to the robustness of the accountability method and the ability of processors to prevent the inclusion of hot spots in waste. To address these concerns and verify the accountability method as applied by the SPFE, as well as the SPFE's ability to control waste package classification, testing of actual waste packages was performed. Testing consisted of a comprehensive dose rate survey of a container of processed waste. Separately, the waste package was modeled chemically and radiologically. Comparing the observed and theoretical data demonstrated that actual dose rates were lower than, but consistent with, modeled dose rates. Moreover, the distribution of radioactivity confirms that the SPFE can produce a radiologically homogeneous waste form. The results of the study demonstrate: 1) the accountability method as applied by the SPFE is valid and produces expected results; 2) the SPFE can produce a radiologically homogeneous waste; and 3) the SPFE can effectively control the waste package classification. (authors)

  10. NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE

    SciTech Connect (OSTI)

    Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

    2005-12-01T23:59:59.000Z

    Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the individual gas cleaning stages, and the probable operating conditions of the gas cleaning stages to conceptually satisfy the gas cleaning requirements; (2) Estimate process material & energy balances for the major plant sections and for each gas cleaning stage; (3) Conceptually size and specify the major gas cleaning process equipment; (4) Determine the resulting overall performance of the application; and (5) Estimate the investment cost and operating cost for each application. Analogous evaluation steps were applied for each application using conventional gas cleaning technology, and comparison was made to extract the potential benefits, issues, and development needs of the Filter-Reactor Novel Gas Cleaning technology. The gas cleaning process and related gas conditioning steps were also required to meet specifications that address plant environmental emissions, the protection of the gas turbine and other Power Island components, and the protection of the methanol synthesis reactor. Detailed material & energy balances for the gas cleaning applications, coupled with preliminary thermodynamic modeling and laboratory testing of candidate sorbents, identified the probable sorbent types that should be used, their needed operating conditions in each stage, and their required levels of performance. The study showed that Filter-Reactor Novel Gas Cleaning technology can be configured to address and conceptually meet all of the gas cleaning requirements for IGCC, and that it can potentially overcome several of the conventional IGCC power plant availability issues, resulting in improved power plant thermal efficiency and cost. For IGCC application, Filter-Reactor Novel Gas Cleaning yields 6% greater generating capacity and 2.3 percentage-points greater efficiency under the Current Standards case, and more than 9% generating capacity increase and 3.6 percentage-points higher efficiency in the Future Standards case. While the conceptual equipment costs are estimated to be only slightly lower for the Filter-Reactor Novel Gas Cleaning processes than for the conventional processes, the improved power plant capacity results in the potentia

  11. MEASUREMENT AND CALCULATION OF RADIONUCLIDE ACTIVITIES IN SAVANNAH RIVER SITE HIGH LEVEL WASTE SLUDGE FOR ACCEPTANCE OF DEFENSE WASTE PROCESSING FACILITY GLASS IN A FEDERAL REPOSITORY

    SciTech Connect (OSTI)

    Bannochie, C; David Diprete, D; Ned Bibler, N

    2008-12-31T23:59:59.000Z

    This paper describes the results of the analyses of High Level Waste (HLW) sludge slurry samples and of the calculations necessary to decay the radionuclides to meet the reporting requirement in the Waste Acceptance Product Specifications (WAPS) [1]. The concentrations of 45 radionuclides were measured. The results of these analyses provide input for radioactive decay calculations used to project the radionuclide inventory at the specified index years, 2015 and 3115. This information is necessary to complete the Production Records at Savannah River Site's Defense Waste Processing Facility (DWPF) so that the final glass product resulting from Macrobatch 5 (MB5) can eventually be submitted to a Federal Repository. Five of the necessary input radionuclides for the decay calculations could not be measured directly due to their low concentrations and/or analytical interferences. These isotopes are Nb-93m, Pd-107, Cd-113m, Cs-135, and Cm-248. Methods for calculating these species from concentrations of appropriate other radionuclides will be discussed. Also the average age of the MB5 HLW had to be calculated from decay of Sr-90 in order to predict the initial concentration of Nb-93m. As a result of the measurements and calculations, thirty-one WAPS reportable radioactive isotopes were identified for MB5. The total activity of MB5 sludge solids will decrease from 1.6E+04 {micro}Ci (1 {micro}Ci = 3.7E+04 Bq) per gram of total solids in 2008 to 2.3E+01 {micro}Ci per gram of total solids in 3115, a decrease of approximately 700 fold. Finally, evidence will be given for the low observed concentrations of the radionuclides Tc-99, I-129, and Sm-151 in the HLW sludges. These radionuclides were reduced in the MB5 sludge slurry to a fraction of their expected production levels due to SRS processing conditions.

  12. Cold End Inserts for Process Gas Waste Heat Boilers Air Products, operates hydrogen production plants, which utilize large waste heat boilers (WHB)

    E-Print Network [OSTI]

    Demirel, Melik C.

    Cold End Inserts for Process Gas Waste Heat Boilers Overview Air Products, operates hydrogen walls. Air Products tasked our team to design an insert to place in the tubes of the WHB to increase flow velocity, thereby reducing fouling of the WHB. Objectives Air Products wishes that our team

  13. Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (Oakland, CA); Griffiths, Elizabeth A. (Neston, GB2); Littlejohn, David (Oakland, CA)

    1988-01-01T23:59:59.000Z

    The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of: (A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group; (B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash; (C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8; (D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3; (E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12; (F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and (G) recycling the aqueous slurry of step (F) to the contacting zone of step (A). Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E). In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

  14. EVALUATION OF THE IMPACT OF THE DEFENSE WASTE PROCESSING FACILITY (DWPF) LABORATORY GERMANIUM OXIDE USE ON RECYCLE TRANSFERS TO THE H-TANK FARM

    SciTech Connect (OSTI)

    Jantzen, C.; Laurinat, J.

    2011-08-15T23:59:59.000Z

    When processing High Level Waste (HLW) glass, the Defense Waste Processing Facility (DWPF) cannot wait until the melt or waste glass has been made to assess its acceptability, since by then no further changes to the glass composition and acceptability are possible. Therefore, the acceptability decision is made on the upstream feed stream, rather than on the downstream melt or glass product. This strategy is known as 'feed forward statistical process control.' The DWPF depends on chemical analysis of the feed streams from the Sludge Receipt and Adjustment Tank (SRAT) and the Slurry Mix Evaporator (SME) where the frit plus adjusted sludge from the SRAT are mixed. The SME is the last vessel in which any chemical adjustments or frit additions can be made. Once the analyses of the SME product are deemed acceptable, the SME product is transferred to the Melter Feed Tank (MFT) and onto the melter. The SRAT and SME analyses have been analyzed by the DWPF laboratory using a 'Cold Chemical' method but this dissolution did not adequately dissolve all the elemental components. A new dissolution method which fuses the SRAT or SME product with cesium nitrate (CsNO{sub 3}), germanium (IV) oxide (GeO{sub 2}) and cesium carbonate (Cs{sub 2}CO{sub 3}) into a cesium germanate glass at 1050 C in platinum crucibles has been developed. Once the germanium glass is formed in that fusion, it is readily dissolved by concentrated nitric acid (about 1M) to solubilize all the elements in the SRAT and/or SME product for elemental analysis. When the chemical analyses are completed the acidic cesium-germanate solution is transferred from the DWPF analytic laboratory to the Recycle Collection Tank (RCT) where the pH is increased to {approx}12 M to be released back to the tank farm and the 2H evaporator. Therefore, about 2.5 kg/yr of GeO{sub 2}/year will be diluted into 1.4 million gallons of recycle. This 2.5 kg/yr of GeO{sub 2} may increase to 4 kg/yr when improvements are implemented to attain an annual canister production goal of 400 canisters. Since no Waste Acceptance Criteria (WAC) exists for germanium in the Tank Farm, the Effluent Treatment Project, or the Saltstone Production Facility, DWPF has requested an evaluation of the fate of the germanium in the caustic environment of the RCT, the 2H evaporator, and the tank farm. This report evaluates the effect of the addition of germanium to the tank farm based on: (1) the large dilution of Ge in the RCT and tank farm; (2) the solubility of germanium in caustic solutions (pH 12-13); (3) the potential of germanium to precipitate as germanium sodalites in the 2H Evaporator; and (4) the potential of germanium compounds to precipitate in the evaporator feed tank. This study concludes that the impacts of transferring up to 4 kg/yr germanium to the RCT (and subsequently the 2H evaporator feed tank and the 2H evaporator) results in <2 ppm per year (1.834 mg/L) which is the maximum instantaneous concentration expected from DWPF. This concentration is insignificant as most sodium germanates are soluble at the high pH of the feed tank and evaporator solutions. Even if sodium aluminosilicates form in the 2H evaporator, the Ge will likely substitute for some small amount of the Si in these structures and will be insignificant. It is recommended that the DWPF continue with their strategy to add germanium as a laboratory chemical to Attachment 8.2 of the DWPF Waste Compliance Plan (WCP).

  15. Process studies for a new method of removing H/sub 2/S from industrial gas streams

    SciTech Connect (OSTI)

    Neumann, D.W.; Lynn, S.

    1986-07-01T23:59:59.000Z

    A process for the removal of hydrogen sulfide from coal-derived gas streams has been developed. The basis for the process is the absorption of H/sub 2/S into a polar organic solvent where it is reacted with dissolved sulfur dioxide to form elemental sulfur. After sulfur is crystallized from solution, the solvent is stripped to remove dissolved gases and water formed by the reaction. The SO/sub 2/ is generated by burning a portion of the sulfur in a furnace where the heat of combustion is used to generate high pressure steam. The SO/sub 2/ is absorbed into part of the lean solvent to form the solution necessary for the first step. The kinetics of the reaction between H/sub 2/S and SO/sub 2/ dissolved in mixtures of N,N-Dimethylaniline (DMA)/ Diethylene Glycol Monomethyl Ether and DMA/Triethylene Glycol Dimethyl Ether was studied by following the temperature rise in an adiabatic calorimeter. This irreversible reaction was found to be first-order in both H/sub 2/S and SO/sub 2/, with an approximates heat of reaction of 28 kcal/mole of SO/sub 2/. The sole products of the reaction appear to be elemental sulfur and water. The presence of DMA increases the value of the second-order rate constant by an order of magnitude over that obtained in the glycol ethers alone. Addition of other tertiary aromatic amines enhances the observed kinetics; heterocyclic amines (e.g., pyridine derivatives) have been found to be 10 to 100 times more effective as catalysts when compared to DMA.

  16. Natural Gas Processed

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0,InformationU.S. Crude Oil31 E Annual Download Series

  17. Natural Gas Processed (Summary)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet) Year Jan Feb Marthrough Monthly Download Series882 1,232 Annual

  18. Co-conversion of Biomass, Shale-natural gas, and process-derived CO2 into Fuels and Chemicals

    Broader source: Energy.gov [DOE]

    Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Suresh Babu, Senior Program Manager, Biomass Program Development, Brookhaven National Laboratory

  19. In the field. Pilot project uses innovative process to capture CO{sub 2} from flue gas

    SciTech Connect (OSTI)

    NONE

    2008-04-01T23:59:59.000Z

    A pilot project at We Energies' Pleasant Prairie Power Plant uses chilled ammonia to capture CO{sub 2} from flue gas. 3 photos.

  20. Process system evaluation-consolidated letters. Volume 1. Alternatives for the off-gas treatment system for the low-level waste vitrification process

    SciTech Connect (OSTI)

    Peurrung, L.M.; Deforest, T.J; Richards, J.R.

    1996-03-01T23:59:59.000Z

    This report provides an evaluation of alternatives for treating off-gas from the low-level waste (LLW) melter. The study used expertise obtained from the commercial nonradioactive off-gas treatment industry. It was assumed that contact maintenance is possible, although the subsequent risk to maintenance personnel was qualitatively considered in selecting equipment. Some adaptations to the alternatives described may be required, depending on the extent of contact maintenance that can be achieved. This evaluation identified key issues for the off-gas system design. To provide background information, technology reviews were assembled for various classifications of off-gas treatment equipment, including off-gas cooling, particulate control, acid gas control, mist elimination, NO{sub x} reduction, and SO{sub 2} removal. An order-of-magnitude cost estimate for one of the off-gas systems considered is provided using both the off-gas characteristics associated with the Joule-heated and combustion-fired melters. The key issues identified and a description of the preferred off-gas system options are provided below. Five candidate treatment systems were evaluated. All of the systems are appropriate for the different melting/feed preparations currently being considered. The lowest technical risk is achieved using option 1, which is similar to designs for high-level waste (HLW) vitrification in the Hanford Waste Vitrification Project (HWVP) and the West Valley. Demonstration Project. Option 1 uses a film cooler, submerged bed scrubber (SBS), and high-efficiency mist eliminator (HEME) prior to NO{sub x} reduction and high-efficiency particulate air (HEPA) filtration. However, several advantages were identified for option 2, which uses high-temperature filtration. Based on the evaluation, option 2 was identified as the preferred alternative. The characteristics of this option are described below.