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Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

ARM - Methane Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane Background Information Outreach Home Room

2

Unconventional gas resources. [Eastern Gas Shales, Western Gas Sands, Coalbed Methane, Methane from Geopressured Systems  

SciTech Connect (OSTI)

This document describes the program goals, research activities, and the role of the Federal Government in a strategic plan to reduce the uncertainties surrounding the reserve potential of the unconventional gas resources, namely, the Eastern Gas Shales, the Western Gas Sands, Coalbed Methane, and methane from Geopressured Aquifers. The intent is to provide a concise overview of the program and to identify the technical activities that must be completed in the successful achievement of the objectives.

Komar, C.A. (ed.)

1980-01-01T23:59:59.000Z

3

Development of gas production type curves for coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists on methane production from the coal seams. The unique coal characteristic results in a dual-porosity system.Ö (more)

Garcia Arenas, Anangela.

2004-01-01T23:59:59.000Z

4

Technical Note Methane gas migration through geomembranes  

E-Print Network [OSTI]

coefficient of PVC, LLDPE, and HDPE geomembranes by performing the standard gas transport test (ASTM D1434). The measured methane gas permeability coefficient through a PVC geomembrane is 7.55 3 104 ml(STP).mil/m2.day thicknesses is proposed using the measured permeability coefficients for PVC, LLDPE, and HDPE geomembranes

5

Natural Gas Infrastructure R&D and Methane Emissions Mitigation...  

Broader source: Energy.gov (indexed) [DOE]

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12, 2014 11:00AM EST to...

6

Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions  

E-Print Network [OSTI]

Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions quantities of CH4 are stored in marine sediment in the form of methane hydrate, bubbles, and dissolved CH4 in pore water. Here I discuss the various pathways for methane to enter the ocean and atmosphere

Zhang, Youxue

7

Measurements of Methane Emissions at Natural Gas Production Sites  

E-Print Network [OSTI]

Measurements of Methane Emissions at Natural Gas Production Sites in the United States #12;Why = 21 #12;Need for Study · Estimates of methane emissions from natural gas production , from academic in assumptions in estimating emissions · Measured data for some sources of methane emissions during natural gas

Lightsey, Glenn

8

Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID (flame ionization)  

E-Print Network [OSTI]

Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID to equilibrate the methane between the air and water. · With the syringe pointing down, eject all the water fromL of gas in the syringe · We will now move to the GC lab in Starr 332 to measure methane. · Repeat

Vallino, Joseph J.

9

Development of gas production type curves for horizontal wells in coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from coal seams .The unique difference between CBM and conventional gas reservoirs isÖ (more)

Nfonsam, Allen Ekahnzok.

2006-01-01T23:59:59.000Z

10

Synthesis Gas Production from Partial Oxidation of Methane with Air in AC Electric Gas Discharge  

E-Print Network [OSTI]

Synthesis Gas Production from Partial Oxidation of Methane with Air in AC Electric Gas Discharge K 73019 Received October 11, 2002 In this study, synthesis gas production in an AC electric gas discharge of methane and air mixtures at room temperature and ambient pressure was investigated. The objective

Mallinson, Richard

11

Dewatering of coalbed methane wells with hydraulic gas pump  

SciTech Connect (OSTI)

The coalbed methane industry has become an important source of natural gas production. Proper dewatering of coalbed methane (CBM) wells is the key to efficient gas production from these reservoirs. This paper presents the Hydraulic Gas Pump as a new alternative dewatering system for CBM wells. The Hydraulic Gas Pump (HGP) concept offers several operational advantages for CBM wells. Gas interference does not affect its operation. It resists solids damage by eliminating the lift mechanism and reducing the number of moving parts. The HGP has a flexible production rate and is suitable for all production phases of CBM wells. It can also be designed as a wireline retrievable system. We conclude that the Hydraulic Gas Pump is a suitable dewatering system for coalbed methane wells.

Amani, M.; Juvkam-Wold, H.C. [Texas A& M Univ., College Station, TX (United States)

1995-12-31T23:59:59.000Z

12

Commodity chemicals from natural gas by methane chlorination  

SciTech Connect (OSTI)

Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

1987-01-01T23:59:59.000Z

13

The presence of natural gas-primarily methane-in the shale layers of sedimen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 andThe MolecularPlaceTheofThe

14

Methanation of gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

Frost, Albert C. (Congers, NY)

1983-01-01T23:59:59.000Z

15

Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines  

E-Print Network [OSTI]

Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines Peter Mauermann1,* , Michael Dornseiffer6 , Frank Amkreutz6 1 Institute for Combustion Engines , RWTH Aachen University, Schinkelstr. 8, D of the hydrocarbon exhaust of internal combustion engines. In contrast to other gaseous hydrocarbons, significant

Dunin-Borkowski, Rafal E.

16

Generating Methane Gas From Manure Charles D. Fulhage, Dennis Sievers and James R. Fischer  

E-Print Network [OSTI]

Generating Methane Gas From Manure Charles D. Fulhage, Dennis Sievers and James R. Fischer Department of Agricultural Engineering At first glance, the idea of generating methane gas has considerable -- the environmental crisis and the energy shortage. Unfortunately, present-day large-scale methane generation requires

Laughlin, Robert B.

17

Reduction of titania by methane-hydrogen-argon gas mixture  

SciTech Connect (OSTI)

Reduction of titania using methane-containing gas was investigated in a laboratory fixed-bed reactor in the temperature range 1,373 to 1,773 K. The reduction production product is titanium oxycarbide, which is a solid solution of TiC and TiO. At 1,373 K, the formation rate of TiC is very slow. The rate and extent of reaction increase with increasing temperature to 1,723 K. A further increase in temperature to 1,773 K does not affect the reaction rate and extent. An increase in methane concentration to 8 vol pct favors the reduction process. A further increase in methane concentration above 8 vol pct causes excessive carbon deposition, which has a negative effect on the reaction rate. Hydrogen partial pressure should be maintained above 35 vol pct to depress the cracking of methane. Addition of water vapor to the reducing gas strongly retards the reduction reaction, even at low concentrations of 1 to 2 vol pct. Carbon monoxide also depresses the reduction process, but its effect is significant only at higher concentrations, above 10 vol pct.

Zhang, G.; Ostrovski, O.

2000-02-01T23:59:59.000Z

18

Gettering of hydrogen and methane from a helium gas mixture  

SciTech Connect (OSTI)

In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H{sub 2} and CH{sub 4} can be removed simultaneously from the mixture using two SAES St 172{sup ģ} getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650?įC to decompose the methane, and the second at 110?įC to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

CŠrdenas, Rosa Elia, E-mail: recarde1@uiwtx.edu [Department of Physics, The University of the Incarnate Word, 4301 Broadway, San Antonio, Texas 78209 (United States); Stewart, Kenneth D.; Cowgill, Donald F., E-mail: dfcowgi@sandia.gov [Sandia National Laboratories, Hydrogen and Metallurgical Sciences, 7011 East Avenue, Livermore, California 94550 (United States)

2014-11-01T23:59:59.000Z

19

Catalyst for the methanation of carbon monoxide in sour gas  

DOE Patents [OSTI]

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

1985-01-01T23:59:59.000Z

20

Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change  

E-Print Network [OSTI]

Potential effects of gas hydrate on human welfare. Proc.W.S. A review of methane and gas hydrates in the dynamic,Geology of Natural Gas Hydrates, M. Max, A.H. Johnson, W.P.

Reagan, Matthew T.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Efficient gas-separation process to upgrade dilute methane stream for use as fuel  

DOE Patents [OSTI]

A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

2012-03-06T23:59:59.000Z

22

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge  

E-Print Network [OSTI]

Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical production from simultaneous steam reforming and partial oxidation of methane using an ac corona discharge production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

Mallinson, Richard

23

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

SciTech Connect (OSTI)

Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

2011-06-01T23:59:59.000Z

24

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory  

E-Print Network [OSTI]

Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory Ricardo B. Metz Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA Abstract Gas such as methanol has attracted great experimental and theoretical interest due to its importance as an industrial

Metz, Ricardo B.

25

Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate accumulation  

E-Print Network [OSTI]

Estimation of methane flux offshore SW Taiwan and the influence of tectonics on gas hydrate simulating reflectors (BSRs) imply the potential existence of gas hydrates offshore southwestern Taiwan that the fluxes are very high in offshore southwestern Taiwan. The depths of the SMI are different at sites GH6

Lin, Andrew Tien-Shun

26

FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

About Gas Hydrates? What Role Do Gas Hydrates Play in Nature? Theme 2 Gas Hydrates as a Potential Energy Resource Are Gas Hydrates a Potential Energy Source? How Big Is the...

27

Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change  

SciTech Connect (OSTI)

Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those predicted under future climate change scenarios, is poorly understood. To determine the fate of the carbon stored in these hydrates, we performed simulations of oceanic gas hydrate accumulations subjected to temperature changes at the seafloor and assessed the potential for methane release into the ocean. Our modeling analysis considered the properties of benthic sediments, the saturation and distribution of the hydrates, the ocean depth, the initial seafloor temperature, and for the first time, estimated the effect of benthic biogeochemical activity. The results show that shallow deposits--such as those found in arctic regions or in the Gulf of Mexico--can undergo rapid dissociation and produce significant methane fluxes of 2 to 13 mol/yr/m{sup 2} over a period of decades, and release up to 1,100 mol of methane per m{sup 2} of seafloor in a century. These fluxes may exceed the ability of the seafloor environment (via anaerobic oxidation of methane) to consume the released methane or sequester the carbon. These results will provide a source term to regional or global climate models in order to assess the coupling of gas hydrate deposits to changes in the global climate.

Reagan, Matthew; Reagan, Matthew T.; Moridis, George J.

2008-04-15T23:59:59.000Z

28

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

SciTech Connect (OSTI)

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

29

Engineering Methane is a major component of shale gas. Recent  

E-Print Network [OSTI]

-added chemicals, (ii) efficient electricity generation through fuel cells, and (iii) methane storage for vehicles), and electrochemical oxidation of CH4 in the solid oxide fuel cell (SOFC). In situ IR studies revealed that adsorbed of solid oxide fuel cells. In 2009, he established FirstEnergyAdvanced Energy Research Center, focusing

30

Functionally gradient material for membrane reactors to convert methane gas into value-added products  

DOE Patents [OSTI]

A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials.

Balachandran, Uthamalingam (Hinsdale, IL); Dusek, Joseph T. (Lombard, IL); Kleefisch, Mark S. (Napersville, IL); Kobylinski, Thadeus P. (Lisle, IL)

1996-01-01T23:59:59.000Z

31

Functionally gradient material for membrane reactors to convert methane gas into value-added products  

DOE Patents [OSTI]

A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials. 7 figs.

Balachandran, U.; Dusek, J.T.; Kleefisch, M.S.; Kobylinski, T.P.

1996-11-12T23:59:59.000Z

32

Demonstration projects for coalbed methane and Devonian shale gas: Final report. [None  

SciTech Connect (OSTI)

In 1979, the US Department of Energy provided the American Public Gas Association (APGA) with a grant to demonstrate the feasibility of bringing unconventional gas such as methane produced from coalbeds or Devonian Shale directly into publicly owned utility system distribution lines. In conjunction with this grant, a seven-year program was initiated where a total of sixteen wells were drilled for the purpose of providing this untapped resource to communities who distribute natural gas. While coalbed degasification ahead of coal mining was already a reality in several parts of the country, the APGA demonstration program was aimed at actual consumer use of the gas. Emphasis was therefore placed on degasification of coals with high methane gas content and on utilization of conventional oil field techniques. 13 figs.

Verrips, A.M.; Gustavson, J.B.

1987-04-01T23:59:59.000Z

33

Analysis and Methane Gas Separations Studies for City of Marsing, Idaho An Idaho National Laboratory Technical Assistance Program Study  

SciTech Connect (OSTI)

Introduction and Background Large amounts of methane in well water is a wide spread problem in North America. Methane gas from decaying biomass and oil and gas deposits escape into water wells typically through cracks or faults in otherwise non-porous rock strata producing saturated water systems. This methane saturated water can pose several problems in the delivery of drinking water. The problems range from pumps vapor locking (cavitating), to pump houses exploding. The City of Marsing requested Idaho National Laboratory (INL) to assist with some water analyses as well as to provide some engineering approaches to methane capture through the INL Technical Assistance Program (TAP). There are several engineering approaches to the removal of methane and natural gas from water sources that include gas stripping followed by compression and/or dehydration; membrane gas separators coupled with dehydration processes, membrane water contactors with dehydration processes.

Christopher Orme

2012-08-01T23:59:59.000Z

34

AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION  

SciTech Connect (OSTI)

Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

Jerry Myers

2005-04-15T23:59:59.000Z

35

Methane contamination of drinking water accompanying gas-well drilling and  

E-Print Network [OSTI]

Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing (received for review January 13, 2011) Directional drilling and hydraulic-fracturing technologies are dra use (1­5). Directional drilling and hydrau- lic-fracturing technologies are allowing expanded natural

36

Methane contamination of drinking water accompanying gas-well drilling and  

E-Print Network [OSTI]

Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing (received for review January 13, 2011) Directional drilling and hydraulic-fracturing technologies are dra of energy use (1­5). Directional drilling and hydrau- lic-fracturing technologies are allowing expanded

Jackson, Robert B.

37

GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS  

SciTech Connect (OSTI)

The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

James Sorensen; Jaroslav Solc; Bethany Bolles

2000-07-01T23:59:59.000Z

38

Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraineís Natural Gas Transmission System  

SciTech Connect (OSTI)

Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own systemís natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraineís transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraineís natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

Roshchanka, Volha; Evans, Meredydd

2014-06-01T23:59:59.000Z

39

Geology, reservoir engineering and methane hydrate potential of the Walakpa Gas Field, North Slope, Alaska  

SciTech Connect (OSTI)

The Walakpa Gas Field, located near the city of Barrow on Alaska's North Slope, has been proven to be methane-bearing at depths of 2000--2550 feet below sea level. The producing formation is a laterally continuous, south-dipping, Lower Cretaceous shelf sandstone. The updip extent of the reservoir has not been determined by drilling, but probably extends to at least 1900 feet below sea level. Reservoir temperatures in the updip portion of the reservoir may be low enough to allow the presence of in situ methane hydrates. Reservoir net pay however, decreases to the north. Depths to the base of permafrost in the area average 940 feet. Drilling techniques and production configuration in the Walakpa field were designed to minimize formation damage to the reservoir sandstone and to eliminate methane hydrates formed during production. Drilling development of the Walakpa field was a sequential updip and lateral stepout from a previously drilled, structurally lower confirmation well. Reservoir temperature, pressure, and gas chemistry data from the development wells confirm that they have been drilled in the free-methane portion of the reservoir. Future studies in the Walakpa field are planned to determine whether or not a component of the methane production is due to the dissociation of updip in situ hydrates.

Glenn, R.K.; Allen, W.W.

1992-12-01T23:59:59.000Z

40

Sulfur resistance of Group VIII transition metal promoted nickel catalysts for synthesis gas methanation  

E-Print Network [OSTI]

SULFUR RESISTANCE OF GROUP VIII TRANSITION METAL PROMOTED NICKEL CATALYSTS FOR SYNTHESIS GAS METHANATION A Thesis by KELLEE HALL HAMLIN Submitted to the Graduate College of Texas AgrM University in partial fulfillment of the requirement...: Aydin Akger n (Chairman of Co 'ttee) Ahme M. Gadalla (Member) Michael . Rosynek (Member) aries D. Holland . ( ead of Department) May 1986 ABSTRACT Sulfur Resistance of Group VIII Transition Metal Promoted Nickel Catalysts For Synthesis Gas...

Hamlin, Kellee Hall

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE  

SciTech Connect (OSTI)

This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses. Depending on the value of gas, simple, low-cost measures, such as adjusting leaking equipment components, or larger-scale measures, such as installing dry seals on compressors, can be applied.

Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

2011-10-01T23:59:59.000Z

42

New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques  

SciTech Connect (OSTI)

Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 įC) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20įC for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned for stranded gas reserves. The recent experiments and their results from the testing within NETL's 15-Liter Hydrate Cell Facility exhibit promising results. Introduction of water at the desired temperature and pressure through an NETL designed nozzle into a temperature controlled methane environment within the 15-Liter Hydrate Cell allowed for instantaneous formation of methane hydrates. The instantaneous and continuous hydrate formation process was repeated over several days while varying the flow rate of water, its' temperature, and the overall temperature of the methane environment. These results clearly indicated that hydrates formed immediately after the methane and water left the nozzle at temperatures above the freezing point of water throughout the range of operating conditions. [1] Oil and Gas Journal Vol. 160.48, Dec 22, 2008. [2] http://www.eia.doe.gov/oiaf/servicerpt/natgas/chapter3.html and http://www.eia.doe.gov/oiaf/servicerpt/natgas/pdf/tbl7.pdf [3] U.S. Geological Survey, ďCircum-Arctic Resource Appraisal: Estimates of Undiscovered Oil and Gas North of the Arctic Circle,Ē May 2008.

Brown, T.D.; Taylor, C.E.; Bernardo, M.

2010-01-01T23:59:59.000Z

43

Methane Gas Utilization Project from Landfill at Ellery (NY)  

SciTech Connect (OSTI)

Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

Pantelis K. Panteli

2012-01-10T23:59:59.000Z

44

Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams  

SciTech Connect (OSTI)

Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

1980-07-01T23:59:59.000Z

45

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

46

Methanation assembly using multiple reactors  

DOE Patents [OSTI]

A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

Jahnke, Fred C.; Parab, Sanjay C.

2007-07-24T23:59:59.000Z

47

Chemical kinetic modeling of oxy-fuel combustion of sour gas for enhanced oil recovery  

E-Print Network [OSTI]

Oxy-fuel combustion of sour gas, a mixture of natural gas (primarily methane (CH 4 )), carbon dioxide (CO 2 ), and hydrogen sulfide (H 2 S), could enable the utilization of large natural gas resources, especially when ...

Bongartz, Dominik

2014-01-01T23:59:59.000Z

48

Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer  

SciTech Connect (OSTI)

Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR√?¬Ę√?¬?√?¬?s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument√?¬Ę√?¬?√?¬?s robustness in a real-world situation.

Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

2012-05-01T23:59:59.000Z

49

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

E-Print Network [OSTI]

Potential distribution of methane hydrate in the world'sisotopic evidence for methane hydrate instability duringHendy, L.L. , and R.J. Behl, Methane hydrates in quaternary

Reagan, M.

2012-01-01T23:59:59.000Z

50

AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION  

SciTech Connect (OSTI)

Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

Jerry Myers

2003-05-13T23:59:59.000Z

51

AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION  

SciTech Connect (OSTI)

Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

Jerry Myers

2004-05-12T23:59:59.000Z

52

AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION  

SciTech Connect (OSTI)

Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

Jerry Myers

2003-11-12T23:59:59.000Z

53

4-102 Methane is heated in a rigid container. The final pressure of the methane is to be determined using the ideal gas equation and the Benedict-Webb-Rubin equation of state.  

E-Print Network [OSTI]

4-54 4-102 Methane is heated in a rigid container. The final pressure of the methane the ideal gas equation of state, Methane 100 kPa 20qC Q kPa229.7 K293 K673 kPa)100( 1 2 12 T T PP The specific molar volume of the methane is /kmolm36.24 kPa100 K)K)(293/kmolmkPa(8.314 3 3 1 1 21 P TRu vv (b

Bahrami, Majid

54

Geology, reservoir engineering and methane hydrate potential of the Walakpa Gas Field, North Slope, Alaska. Final report  

SciTech Connect (OSTI)

The Walakpa Gas Field, located near the city of Barrow on Alaska`s North Slope, has been proven to be methane-bearing at depths of 2000--2550 feet below sea level. The producing formation is a laterally continuous, south-dipping, Lower Cretaceous shelf sandstone. The updip extent of the reservoir has not been determined by drilling, but probably extends to at least 1900 feet below sea level. Reservoir temperatures in the updip portion of the reservoir may be low enough to allow the presence of in situ methane hydrates. Reservoir net pay however, decreases to the north. Depths to the base of permafrost in the area average 940 feet. Drilling techniques and production configuration in the Walakpa field were designed to minimize formation damage to the reservoir sandstone and to eliminate methane hydrates formed during production. Drilling development of the Walakpa field was a sequential updip and lateral stepout from a previously drilled, structurally lower confirmation well. Reservoir temperature, pressure, and gas chemistry data from the development wells confirm that they have been drilled in the free-methane portion of the reservoir. Future studies in the Walakpa field are planned to determine whether or not a component of the methane production is due to the dissociation of updip in situ hydrates.

Glenn, R.K.; Allen, W.W.

1992-12-01T23:59:59.000Z

55

Gas productivity related to cleat volumes derived from focused resistivity tools in coalbed methane (CBM) fields  

SciTech Connect (OSTI)

Cleats are critical for coal-bed methane (CBM) production, but operators usually lack a viable method to determine productivity except for costly well tests. Wireline logs, run over the CBM deposits of the Drunkards Wash Unit located in the Uinta Basin of Utah, were used to develop a new method to relate productivity to the cleat volume. The latter is derived from a focused resistivity log and the wellbore-fluid resistivity. Induction tools are unsuitable for this method, because they are dominated by borehole effects in high resistivity coals and low resistivity mud. Moreover, they read too deep to be significantly affected by the substitution of formation fluid by borehole fluid in the cleats on which the method is based. The method was demonstrated by relating cleat volume to CBM gas productivity in 24 wells, an exercise that clearly separated good from poor producers.

Yang, Y.H.; Peeters, M.; Cloud, T.A.; Van Kirk, C.W. [Kerr McGee Rocky Mountain Corporation, Denver, CO (United States)

2006-06-15T23:59:59.000Z

56

Methane hydrate potential and development of a shallow gas field in the arctic: The Walakpa Field North Slope Alaska  

SciTech Connect (OSTI)

The goal of the North Slope Hydrate Study is to evaluate the methane hydrate potential of the Walakpa gas field, a shallow gas field located near Barrow, Alaska. Observing, understanding, and predicting the production characteristics of the Walakpa field will be accomplished by the analysis of the reservoir geology, and of the individual well production data, derived from reservoir engineering studies conducted in the field.

Glenn, R.K.

1992-01-01T23:59:59.000Z

57

Methane hydrate potential and development of a shallow gas field in the arctic: The Walakpa Field North Slope Alaska  

SciTech Connect (OSTI)

The goal of the North Slope Hydrate Study is to evaluate the methane hydrate potential of the Walakpa gas field, a shallow gas field located near Barrow, Alaska. Observing, understanding, and predicting the production characteristics of the Walakpa field will be accomplished by the analysis of the reservoir geology, and of the individual well production data, derived from reservoir engineering studies conducted in the field.

Glenn, R.K.

1992-06-01T23:59:59.000Z

58

Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture  

SciTech Connect (OSTI)

Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325įC) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700ļC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

2014-01-01T23:59:59.000Z

59

U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)  

SciTech Connect (OSTI)

Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

Heath, G.

2014-04-01T23:59:59.000Z

60

A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry  

E-Print Network [OSTI]

the anaerobic oxidation of methane. Environ. Microbiol. 10(Field observations of methane concentra- tions and oxidationAnaerobic oxidation of methane above gas hydrates at Hydrate

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Pennsylvania Farmland and Forest Land Assessment Act of 1974- Utilization of Land or Conveyance of Rights for Exploration or Extraction of Gas, Oil or Coal Bed Methane  

Broader source: Energy.gov [DOE]

This act prescribes the procedure utilization of land or conveyance of rights for exploration or extraction of gas, oil or coal bed methane in agricultural and forest reserve areas.

62

Subsurface definition of the Allegheny Group coalbed methane prospect interval in Southwestern Pennsylvania and new gas content results  

SciTech Connect (OSTI)

A preliminary reconnaissance of coalbed methane gas content data from exploratory coal cores and pre-existing data implies that the greater the depth and rank, the greater the total and cumulative gas content. The coal seams studied, ranging in age from the Pennsylvanian-Permian Dunkard Group to the Middle Pennsylvanian Allegheny Group, are from the Main Bituminous Field and two of the anthracite fields. Consequently, the Pennsylvania Geological Survey and the West Virginia Geological and Economic Survey conducted a mapping investigation to evaluate the regional geology of the coal-bearing intervals and its influence on coalbed methane potential. Phase I of this study involved the entire Pennsylvanian coal-bearing interval; Phase II focused on a stratigraphic delineation and evaluation of Allegheny coalbeds and associated sandstones. A variety of cross sections and isopach maps show several prospective coalbeds and facies relationships with channel-fill sandstones. This suggests that some of these sandstones may be traps for coalbed methane. Often overlooked in reservoir characterization is the quality of a coal seam. Coal rank, grade, and type influence the reserves and production of coalbed methane; the higher the rank, the greater adsorptive capacity of the coal. The integration of coal quality with other critical tools of exploration may increase the success rate of finding {open_quotes}sweet spots.{close_quotes} Additional Pennsylvania Geological Survey drilling occurred in Beaver, Lawrence, Somerset, and Washington counties. Gas contents were graphically displayed against depth, thickness, and time for a variety of samples from 21 coal seams; average gas composition and Btu values were determined for selected samples.

Markowski, A.K. [Pennsylvania Dept. of Conservation and Natural Resources-Bureau of Topographic and Geologic Survey, Harrisburg, PA (United States)

1996-09-01T23:59:59.000Z

63

Tool to predict the production performance of vertical wells in a coalbed methane reservoir.  

E-Print Network [OSTI]

??Coalbed Methane (CBM) is an unconventional gas resource that consists of methane production from coal seams. Coalbed Methane gas production is controlled be interactions ofÖ (more)

Enoh, Michael E.

2007-01-01T23:59:59.000Z

64

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993  

SciTech Connect (OSTI)

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

Not Available

1993-12-01T23:59:59.000Z

65

Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields  

SciTech Connect (OSTI)

In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work, permitting, barging, ice road/pad construction, drilling, completion, tie-in, long-term production testing and surveillance, data analysis and technology transfer. The PRA project team and North Slope have recommended moving forward to the execution phase of this project.

Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

2010-02-22T23:59:59.000Z

66

Investigation of methane adsorption and its effect on gas transport in shale matrix through microscale and mesoscale simulations  

E-Print Network [OSTI]

Methane adsorption and its effect on fluid flow in shale matrix are investigated through multi-scale simulation scheme by using molecular dynamics (MD) and lattice Boltzmann (LB) methods. Equilibrium MD simulations are conducted to study methane adsorption on the organic and inorganic walls of nanopores in shale matrix with different pore sizes and pressures. Density and pressure distributions within the adsorbed layer and the free gas region are discussed. The illumination of the MD results on larger scale LB simulations is presented. Pressure-dependent thickness of adsorbed layer should be adopted and the transport of adsorbed layer should be properly considered in LB simulations. LB simulations, which are based on a generalized Navier-Stokes equation for flow through low-permeability porous media with slippage, are conducted by taking into consideration the effects of adsorbed layer. It is found that competitive effects of slippage and adsorbed layer exist on the permeability of shale matrix, leading to di...

Li, ZhongZhen; Chen, Li; Kangd, Qinjun; He, Ya-Ling; Tao, Wen-Quan

2015-01-01T23:59:59.000Z

67

Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead  

SciTech Connect (OSTI)

Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

BC Technologies

2009-12-30T23:59:59.000Z

68

Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane  

SciTech Connect (OSTI)

The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

Scott, A R; Mukhopadhyay, B; Balin, D F

2012-09-06T23:59:59.000Z

69

Volumetric strain associated with methane desorption and its impact on coalbed gas production from deep coal seams  

SciTech Connect (OSTI)

For deep coal seams, significant reservoir pressure drawdown is required to promote gas desorption because of the Langmuir-type isotherm that typifies coals. Hence, a large permeability decline may occur because of pressure drawdown and the resulting increase in effective stress, depending on coal properties and the stress field during production. However, the permeability decline can potentially be offset by the permeability enhancement caused by the matrix shrinkage associated with methane desorption. The predictability of varying permeability is critical for coalbed gas exploration and production-well management. We have investigated quantitatively the effects of reservoir pressure and sorption-induced volumetric strain on coal-seam permeability with constraints from the adsorption isotherm and associated volumetric strain measured on a Cretaceous Mesaverde Group coal (Piceance basin) and derived a stress-dependent permeability model. Our results suggest that the favorable coal properties that can result in less permeability reduction during earlier production and an earlier strong permeability rebound (increase in permeability caused by coal shrinkage) with methane desorption include (1) large bulk or Young's modulus; (2) large adsorption or Langmuir volume; (3) high Langmuir pressure; (4) high initial permeability and dense cleat spacing; and (5) low initial reservoir pressure and high in-situ gas content. Permeability variation with gas production is further dependent on the orientation of the coal seam, the reservoir stress field, and the cleat structure. Well completion with injection of N2 and displacement of CH{sub 4} only results in short-term enhancement of permeability and does not promote the overall gas production for the coal studied.

Cui, X.J.; Bustin, R.M. [University of British Columbia, Vancouver, BC (Canada). Dept. of Earth & Ocean Science

2005-09-01T23:59:59.000Z

70

Development of water production type curves for horizontal wells in coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. The key parameters for the evaluation of coalbed methaneÖ (more)

Burka Narayana, Praveen Kumar.

2007-01-01T23:59:59.000Z

71

Diffusional methane fluxes within continental margin sediments and depositional constraints on formation factor estimates  

E-Print Network [OSTI]

Goldberg, E.D. , 1976. Methane production and consumption inanaerobic oxidation of methane. Nature, 407 , 623-626.profiles indicate in situ methane flux from underlying gas

Berg, Richard D.

2008-01-01T23:59:59.000Z

72

Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes  

E-Print Network [OSTI]

V.A. Soloviev, Submarine Gas Hydrates. St. Petersburg, 1998.and stability of gas hydrate-related bottom-simulatingPotential effects of gas hydrate on human welfare, Proc.

Reagan, M.

2012-01-01T23:59:59.000Z

73

The basics of coalbed methane  

SciTech Connect (OSTI)

The report is an overview of coalbed methane (CBM), also known as coal seam gas. It provides an overview of what coalbed methane is and the current status of global coalbed methane exploration and production. Topics covered in the report include: An analysis of the natural gas industry, including current and future production, consumption, and reserves; A detailed description of coalbed methane, its characteristics, and future potential; An analysis of the key business factors that are driving the increased interest in coalbed methane; An analysis of the barriers that are hindering the development of coalbed methane; An overview of the technologies used for coalbed methane production and water treatment; and Profiles of key coalbed methane producing countries. 25 figs., 5 tabs., 1 app.

NONE

2006-12-15T23:59:59.000Z

74

A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry  

E-Print Network [OSTI]

oxidation of methane above gas hydrates at Hydrate Ridge, NEsediment from a marine gas hydrate area. Environ. Microbiol.

2011-01-01T23:59:59.000Z

75

Prediction of coalbed methane reservoir performance with type curves.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists of methane production from the coal seams. CBM reservoirs are dual-porosity systems that are characterized byÖ (more)

Bhavsar, Amol Bhaskar.

2005-01-01T23:59:59.000Z

76

The Optimization of Well Spacing in a Coalbed Methane Reservoir.  

E-Print Network [OSTI]

??Numerical reservoir simulation has been used to describe mechanism of methane gas desorption process, diffusion process, and fluid flow in a coalbed methane reservoir. TheÖ (more)

Sinurat, Pahala Dominicus

2012-01-01T23:59:59.000Z

77

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

1997-09-23T23:59:59.000Z

78

Methane/nitrogen separation process  

DOE Patents [OSTI]

A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

1997-01-01T23:59:59.000Z

79

A conduit dilation model of methane venting from lake sediments  

E-Print Network [OSTI]

Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the ...

Ruppel, Carolyn

80

Methane productivity and nutrient recovery from manure Henrik B. Mller  

E-Print Network [OSTI]

Methane productivity and nutrient recovery from manure Henrik B. MÝller Danish Institute This thesis, entitled "Methane productivity and nutrient recovery from manure" is presented in partial of digested and separated products.................... 13 3. Methane productivity and greenhouse gas emissions

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Method of coalbed methane production  

SciTech Connect (OSTI)

This patent describes a method for producing coalbed methane from a coal seam containing coalbed methane and penetrated by at least one injection well and at least one producing well. It comprises: injecting an inert gas through the injection well and into the coal seam. The inert gas being a gas that does not react with the coal under conditions of use and that does not significantly adsorb to the coal; and producing a gas from the production well which consists essentially of the inert gas, coalbed methane, or mixtures thereof.

Puri, R.; Stein, M.H.

1989-11-28T23:59:59.000Z

82

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2Energy Second Quarter Report 2014 Natural Gas Gas

83

Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers  

SciTech Connect (OSTI)

This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

Evans, Meredydd; Roshchanka, Volha

2014-08-04T23:59:59.000Z

84

Electrochemical methane sensor  

DOE Patents [OSTI]

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, S.; Otagawa, T.; Stetter, J.R.

1984-08-27T23:59:59.000Z

85

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2Energy Second Quarter Report 2014 Natural Gas

86

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2Energy Second Quarter Report 2014 Natural Gas

87

Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2Energy Second Quarter Report 2014 Natural Gas

88

Natural Gas Infrastructure R&D and Methane Mitigation Woekshop Nov. 12-13, 2014  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergyENERGY TAXBalanced Scorecard Federal2Energy Second Quarter Report 2014 Natural Gas

89

Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data  

E-Print Network [OSTI]

of predicted and measured methane gas production data within the heterogeneous porous methane hydrate sample.Global Distribution of Methane Hydrate in Ocean Hydrate.

Gupta, A.

2010-01-01T23:59:59.000Z

90

Synthesis gas formation by catalytic oxidation of methane in fluidized bed reactors  

SciTech Connect (OSTI)

The production of synthesis gas (CO + H[sub 2]) by the catalytic partial oxidation of CH[sub 4] in air or O[sub 2] in static fluidized beds at atmospheric pressure has been examined over Pt, Rh, and Ni catalysts coated on 100-[mu]m [alpha]-Al[sub 2]O[sub 3] beads. With CH[sub 4]/air feeds, CO and H[sub 2] selectivities as high as 95% with >90% CH[sub 4] conversion were obtained on Rh and Ni catalysts at contact times of 0.1-0.5 sec. Pt catalysts were found to have significantly lower selectivities for all the three catalysts were improved by heating the reaction mixture above the autothermal reactor temperature and using O[sub 2] instead of air. The selectivities and conversions were fairly constant over the range of contact time s used. Probable reaction pathways for CH[sub 4] oxidation in fluidized beds are discussed. 31 refs., 6 figs.

Bharadwaj, S.S.; Schmidt, L.D. (Univ. of Minnesota, Minneapolis (United States))

1994-03-01T23:59:59.000Z

91

CULTURAL RATCHETING RESULTS PRIMARILY FROM SEMANTIC COMPRESSION  

E-Print Network [OSTI]

CULTURAL RATCHETING RESULTS PRIMARILY FROM SEMANTIC COMPRESSION JOANNA J. BRYSON Artificial Models that cultural ratcheting requires the communication of beliefs about #12;hypotheses. Clearly, cultural

Bryson, Joanna J.

92

Natural gas cleanup: Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures  

SciTech Connect (OSTI)

This report describes the results of a preliminary evaluation to determine the technical feasibility of using a molecular sieve carbon manufactured by the Takeda Chemical Company of Japan in a pressure owing adsorption cycle for upgrading natural gas (methane) contaminated with nitrogen. Adsorption tests were conducted using this adsorbent in two, four, and five-step adsorption cycles. Separation performance was evaluated in terms of product purity, product recovery, and sorbent productivity for all tests. The tests were conducted in a small, single-column adsorption apparatus that held 120 grams of the adsorbent. Test variables included adsorption pressure, pressurization rate, purge rate and volume, feed rate, and flow direction in the steps from which the product was collected. Sorbent regeneration was accomplished by purging the column with the feed gas mixture for all but one test series where a pure methane purge was used. The ratio between the volumes of the pressurization gas and the purge gas streams was found to be an important factor in determining separation performance. Flow rates in the various cycle steps had no significant effect. Countercurrent flow in the blow-down and purge steps improved separation performance. Separation performance appears to improve with increasing adsorption pressure, but because there are a number of interrelated variables that are also effected by pressure, further testing will be needed to verify this. The work demonstrates that a molecular sieve carbon can be used to separate a mixture of methane and nitrogen when used in a pressure swing cycle with regeneration by purge. Further work is needed to increase product purity and product recovery.

Grimes, R.W.

1994-06-01T23:59:59.000Z

93

Upgrading drained coal mine methane to pipeline quality: a report on the commercial status of system suppliers  

SciTech Connect (OSTI)

In today's scenario of growing energy demand worldwide and rising natural gas prices, any methane emitted into the atmosphere is an untapped resource of energy and potentially a lost opportunity for additional revenue. In 2005, 9.7% of the total US anthropogenic emissions of methane were attributed to coal production. In recent years, many gassy coal mines have seized the opportunity to recover coal mine methane (CMM) and supply it to natural gas pipeline systems. With natural gas prices in the US exceeding $7.00 per million Btu, CMM pipeline sales brought in an annual revenue topping $97 million in 2005. However, significant opportunity still exists for tapping into this resource as 22% of the drained CMM remains unutilized as of 2005, primarily because its quality does not meet the requirements of natural gas pipeline systems. Recent advances in technologies now offer off-the-shelf options in the US that can upgrade the drained CMM to pipeline quality. These gas upgrading technologies are not only opening up the market to lower-quality methane resources but also providing significant means for reducing emissions, since methane is over 20 times a more potent greenhouse gas than carbon dioxide. This report reviews current gas upgrading technologies available in the market for removal of typical CMM contaminants, provides examples of their successful commercial implementation and compiles a list of vendors specific to nitrogen rejection systems, since nitrogen exposes the biggest challenge to upgrading CMM. 2 figs., 3 tabs., 9 apps.

Carothers, F.P.; Schultz, M.L.

2008-01-15T23:59:59.000Z

94

E-Print Network 3.0 - alaskan gas hydrate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and finally the prospects for methane hydrates. NATURAL GAS AND THE RECOVERY PROCESS The primary... Coal Bed Methane Shale Gas Methane Hydrates Volume...

95

Biogeochemistry of Microbial Coal-Bed Methane  

E-Print Network [OSTI]

Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo¬īc,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

Macalady, Jenn

96

Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment  

E-Print Network [OSTI]

this disadvantage include · storing methane as liquefied natural gas (LNG, at 112 K) or compressed natural gas (CNG

Yaghi, Omar M.

97

Presentations from the March 27th - 28th Methane Hydrates Advisory...  

Broader source: Energy.gov (indexed) [DOE]

the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate...

98

Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...  

E-Print Network [OSTI]

of the incident beam's translational energy, and approaches unity for energies greater than 1.3 eV. Comparison for methanol synthesis. One method is the direct partial oxidation of methane, CH4 + 1/2 O2 CO + 2H2. 1 This process has been extensively studied using high surface area supported Rh catalysts in flow reactors

Sibener, Steven

99

Coalbed methane production case histories  

SciTech Connect (OSTI)

The production of methane gas from coal and coal-bearing rocks is one of the prime objectives of the Department of Energy's Methane Recovery from Coalbeds Project. This report contains brief description of wells that are presently producing gas from coal or coal-bearing rocks. Data from three gob gas production areas in Illinois, an in-mine horizontal borehole degasification, and eleven vertical boreholes are presented. Production charts and electric logs of the producing zones are included for some of the wells. Additional information on dry gas production from the San Juan Basin, Colorado/New Mexico and the Greater Green River Coal Region, Colorado/Wyoming is also included.

Not Available

1981-02-01T23:59:59.000Z

100

Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane  

E-Print Network [OSTI]

Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane, ethylene, methane, and two isotopically substituted methanes, CH2D2 and CD4, at a momentum constituent. For example, Fig. 1 of Ref. 2 shows that, for gaseous methane, above a certain momentum transfer

Hitchcock, Adam P.

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Methane Hydrates: Major Energy Source for the Future or Wishful Thinking?  

SciTech Connect (OSTI)

Methane hydrates are methane bearing, ice-like materials that occur in abundance in permafrost areas such as on the North Slope of Alaska and Canada and as well as in offshore continental margin environments throughout the world including the Gulf of Mexico and the East and West Coasts of the United States. Methane hydrate accumulations in the United States are currently estimated to be about 200,000 Tcf, which is enormous when compared to the conventional recoverable resource estimate of 2300 Tcf. On a worldwide basis, the estimate is 700,000 Tcf or about two times the total carbon in coal, oil and conventional gas in the world. The enormous size of this resource, if producible to any degree, has significant implications for U.S. and worldwide clean energy supplies and global environmental issues. Historically the petroleum industry's interests in methane hydrates have primarily been related to safety issues such as wellbore stability while drilling, seafloor stability, platform subsidence, and pipeline plugging. Many questions remain to be answered to determine if any of this potential energy resource is technically and economically viable to produce. Major technical hurdles include: 1) methods to find, characterize, and evaluate the resource; 2) technology to safely and economically produce natural gas from methane hydrate deposits; and 3) safety and seafloor stability issues related to drilling through gas hydrate accumulations to produce conventional oil and gas. The petroleum engineering profession currently deals with gas hydrates in drilling and production operations and will be key to solving the technical and economic problems that must be overcome for methane hydrates to be part of the future energy mix in the world.

Thomas, Charles Phillip

2001-09-01T23:59:59.000Z

102

New Methane Hydrate Research: Investing in Our Energy Future...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Investing in Our Energy Future August 31, 2012 - 1:37pm Addthis Methane hydrates are 3D ice-lattice structures with natural gas locked inside. If methane hydrate is either warmed...

103

Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates  

E-Print Network [OSTI]

Dissociation heat of mixed-gas hydrate composed of methaneInternational Conference on Gas Hydrates (ICGH 2008), 2008,and specific heats of gas hydrates under submarine and

Kwon, T.H.

2012-01-01T23:59:59.000Z

104

Greenhouse gas reduction by recovery and utilization of landfill methane and CO{sub 2} technical and market feasibility study, Boului Landfill, Bucharest, Romania. Final report, September 30, 1997--September 19, 1998  

SciTech Connect (OSTI)

The project is a landfill gas to energy project rated at about 4 megawatts (electric) at startup, increasing to 8 megawatts over time. The project site is Boului Landfill, near Bucharest, Romania. The project improves regional air quality, reduces emission of greenhouse gases, controls and utilizes landfill methane, and supplies electric power to the local grid. The technical and economic feasibility of pre-treating Boului landfill gas with Acrion`s new landfill gas cleanup technology prior to combustion for power production us attractive. Acrion`s gas treatment provides several benefits to the currently structured electric generation project: (1) increase energy density of landfill gas from about 500 Btu/ft{sup 3} to about 750 Btu/ft{sup 3}; (2) remove contaminants from landfill gas to prolong engine life and reduce maintenance;; (3) recover carbon dioxide from landfill gas for Romanian markets; and (4) reduce emission of greenhouse gases methane and carbon dioxide. Greenhouse gas emissions reduction attributable to successful implementation of the landfill gas to electric project, with commercial liquid CO{sub 2} recovery, is estimated to be 53 million metric tons of CO{sub 2} equivalent of its 15 year life.

Cook, W.J.; Brown, W.R.; Siwajek, L. [Acrion Technologies, Inc., Cleveland, OH (United States); Sanders, W.I. [Power Management Corp., Bellevue, WA (United States); Botgros, I. [Petrodesign, SA, Bucharest (Romania)

1998-09-01T23:59:59.000Z

105

Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations  

E-Print Network [OSTI]

Deep Ocean Field Test of Methane Hydrate Formation from aW.J. , and Mason, D.H. , Methane Hydrate Formation inNatural and Laboratory--Formed Methane Gas Hydrate. American

Rees, E.V.L.

2012-01-01T23:59:59.000Z

106

Planetary and Space Science 54 (2006) 11771187 Titan's methane cycle  

E-Print Network [OSTI]

Abstract Methane is key to sustaining Titan's thick nitrogen atmosphere. However, methane is destroyed and the pressure induced opacity in the infrared, particularly by CH4­N2 and H2­N2 collisions in the troposphere), whose reaction with carbon grains or carbon dioxide in the crustal pores produces methane gas

Atreya, Sushil

107

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials  

E-Print Network [OSTI]

Methane-assisted combustion synthesis of nanocomposite tin dioxide materials S.D. Bakrania *, C and flow conditions using methane as a supplemental fuel. The experiments were carried out at atmospheric-phase precursor for metal additives. In the methane-assisted (MA) system, the inert carrier gas was replaced

Wooldridge, Margaret S.

108

Monterey Bay Aquarium Research A robotic sub samples the methane  

E-Print Network [OSTI]

Monterey Bay Aquarium Research Institute A robotic sub samples the methane content of the seafloor.263 News Seafloor probe taps methane reservoir Greenhouse gas found in high abundance but risk of mass release uncertain. Nicola Jones A robotic submarine has been used to measure the amount of methane lurking

Tian, Weidong

109

Methane in lakes and wetlands Microbiological production, ecosystem  

E-Print Network [OSTI]

Methane in lakes and wetlands Microbiological production, ecosystem uptake, climatological significance LAKES AND WETLANDS ­ A RELEVANT METHANE SOURCE Lakes and other wetlands are an important source of methane, the third most important greenhouse gas in the atmosphere. However, the absolute contribution

M√ľhlemann, Oliver

110

Coal Bed Methane Primer  

SciTech Connect (OSTI)

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

111

Hydraulic fracturing and wellbore completion of coalbed methane wells in the Powder River Basin, Wyoming: Implications for water and gas production  

SciTech Connect (OSTI)

Excessive water production (more than 7000 bbl/month per well) from many coalbed methane (CBM) wells in the Powder River Basin of Wyoming is also associated with significant delays in the time it takes for gas production to begin. Analysis of about 550 water-enhancement activities carried out during well completion demonstrates that such activities result in hydraulic fracturing of the coal. Water-enhancement activities, consists of pumping 60 bbl of water/min into the coal seam during approximately 15 min. This is done to clean the well-bore and to enhance CBM production. Hydraulic fracturing is of concern because vertical hydraulic fracture growth could extend into adjacent formations and potentially result in excess CBM water production and inefficient depressurization of coals. Analysis of the pressure-time records of the water-enhancement tests enabled us to determine the magnitude of the least principal stress (S{sub 3}) in the coal seams of 372 wells. These data reveal that because S{sub 3} switches between the minimum horizontal stress and the overburden at different locations, both vertical and horizontal hydraulic fracture growth is inferred to occur in the basin, depending on the exact location and coal layer. Relatively low water production is observed for wells with inferred horizontal fractures, whereas all of the wells associated with excessive water production are characterized by inferred vertical hydraulic fractures. The reason wells with exceptionally high water production show delays in gas production appears to be inefficient depressurization of the coal caused by water production from the formations outside the coal. To minimize CBM water production, we recommend that in areas of known vertical fracture propagation, the injection rate during the water-enhancement tests should be reduced to prevent the propagation of induced fractures into adjacent water-bearing formations.

Colmenares, L.B.; Zoback, M.D. [Stanford University, Stanford, CA (United States). Dept. of Geophysics

2007-01-15T23:59:59.000Z

112

A study of carbon-14 of paleoatmospheric methane for the last glacial termination from ancient glacial ice  

E-Print Network [OSTI]

Kastner, M. , 2001. Gas Hydrates in Convergent Margins:Significance, Natural Gas Hydrates: Occurence, Distributionof methane in natural gas hydrate. Organic Geochemistry 23,

Petrenko, Vasilii Victorovich

2008-01-01T23:59:59.000Z

113

Diffusional methane fluxes within continental margin sediments and depositional constraints on formation factor estimates  

E-Print Network [OSTI]

methane flux from underlying gas hydrate. Geology , 24 (7),overlying the Blake Ridge gas hydrates. In Proceedings ofgas transport in shallow sediments of an accretionary complex, Southern Hydrate

Berg, Richard D.

2008-01-01T23:59:59.000Z

114

Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980  

SciTech Connect (OSTI)

Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

Manilla, R.D.

1980-06-01T23:59:59.000Z

115

A review on recent advances in the numerical simulation for coalbed-methane-recovery process  

SciTech Connect (OSTI)

The recent advances in numerical simulation for primary coalbed methane (CBM) recovery and enhanced coalbed-methane recovery (ECBMR) processes are reviewed, primarily focusing on the progress that has occurred since the late 1980s. Two major issues regarding the numerical modeling will be discussed in this review: first, multicomponent gas transport in in-situ bulk coal and, second, changes of coal properties during methane (CH{sub 4}) production. For the former issues, a detailed review of more recent advances in modeling gas and water transport within a coal matrix is presented. Further, various factors influencing gas diffusion through the coal matrix will be highlighted as well, such as pore structure, concentration and pressure, and water effects. An ongoing bottleneck for evaluating total mass transport rate is developing a reasonable representation of multiscale pore space that considers coal type and rank. Moreover, few efforts have been concerned with modeling water-flow behavior in the coal matrix and its effects on CH{sub 4} production and on the exchange of carbon dioxide (CO{sub 2}) and CH{sub 4}. As for the second issue, theoretical coupled fluid-flow and geomechanical models have been proposed to describe the evolution of pore structure during CH{sub 4} production, instead of traditional empirical equations. However, there is currently no effective coupled model for engineering applications. Finally, perspectives on developing suitable simulation models for CBM production and for predicting CO{sub 2}-sequestration ECBMR are suggested.

Wei, X.R.; Wang, G.X.; Massarotto, P.; Golding, S.D.; Rudolph, V. [University of Queensland, Brisbane, Qld. (Australia)

2007-12-15T23:59:59.000Z

116

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect (OSTI)

''Conventional'' waste landfills emit methane, a potent greenhouse gas, in quantities such that landfill methane is a major factor in global climate change. Controlled landfilling is a novel approach to manage landfills for rapid completion of total gas generation, maximizing gas capture and minimizing emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated and brought to much earlier completion by improving conditions for biological processes (principally moisture levels) in the landfill. Gas recovery efficiency approaches 100% through use of surface membrane cover over porous gas recovery layers operated at slight vacuum. A field demonstration project's results at the Yolo County Central Landfill near Davis, California are, to date, highly encouraging. Two major controlled landfilling benefits would be the reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role in reduction of US greenhouse gas emissions.

Don Augenstein

1999-01-11T23:59:59.000Z

117

Hydrogen and methane production from swine wastewater using microbial electrolysis cells  

E-Print Network [OSTI]

Hydrogen and methane production from swine wastewater using microbial electrolysis cells Rachel C in the wastewater as hydrogen gas. Methane was also produced at a maximum of 13 √? 4% of total gas volume methane produc- tion, increasing the efficiency of converting the organic matter into current

118

X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well  

E-Print Network [OSTI]

T. and Narita, H. , 2006. Methane hydrate crystal growth ina porous medium filled with methane-saturated liquid water.Kneafsey, T.J. et al. , 2007. Methane hydrate formation and

Kneafsey, T.J.

2012-01-01T23:59:59.000Z

119

Biogeochemical modelling of anaerobic vs. aerobic methane oxidation in a meromictic crater lake (Lake Pavin, France)  

E-Print Network [OSTI]

Géosciences, 1A rue de la Férolerie, 45071 Orléans Cedex 2, France Abstract Methane is a powerful greenhouse gas and its concentration in the atmosphere has increased over the past decades. Methane produced

Boyer, Edmond

120

Magnitude and spatio-temporal variability of methane emissions from a eutrophic freshwater lake  

E-Print Network [OSTI]

Methane is the second most important greenhouse gas after carbon dioxide, and it can significantly impact global climate change. Considerable amounts of methane can be released to the atmosphere from freshwater lakes, ...

Varadharajan, Charuleka, 1980-

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

PRELIMINARY CHARACTERIZATION OF CO2 SEPARATION AND STORAGE PROPERTIES OF COAL GAS RESERVOIRS  

SciTech Connect (OSTI)

An attractive alternative of sequestering CO{sub 2} is to inject it into coalbed methane reservoirs, particularly since it has been shown to enhance the production of methane during near depletion stages. The basis for enhanced coalbed methane recovery and simultaneous sequestration of carbon dioxide in deep coals is the preferential sorption property of coal, with its affinity for carbon dioxide being significantly higher than that for methane. Yet, the sorption behavior of coal under competitive sorptive environment is not fully understood. Hence, the original objective of this research study was to carry out a laboratory study to investigate the effect of studying the sorption behavior of coal in the presence of multiple gases, primarily methane, CO{sub 2} and nitrogen, in order to understand the mechanisms involved in displacement of methane and its movement in coal. This had to be modified slightly since the PVT property of gas mixtures is still not well understood, and any laboratory work in the area of sorption of gases requires a definite equation of state to calculate the volumes of different gases in free and adsorbed forms. This research study started with establishing gas adsorption isotherms for pure methane and CO{sub 2}. The standard gas expansion technique based on volumetric analysis was used for the experimental work with the additional feature of incorporating a gas chromatograph for analysis of gas composition. The results were analyzed first using the Langmuir theory. As expected, the Langmuir analysis indicated that CO{sub 2} is more than three times as sorptive as methane. This was followed by carrying out a partial desorption isotherm for methane, and then injecting CO{sub 2} to displace methane. The results indicated that CO{sub 2} injection at low pressure displaced all of the sorbed methane, even when the total pressure continued to be high. However, the displacement appeared to be occurring due to a combination of the preferential sorption property of coal and reduction in the partial pressure of methane. As a final step, the Extended Langmuir (EL) model was used to model the coal-methane-CO{sub 2} binary adsorption system. The EL model was found to be very accurate in predicting adsorption of CO{sub 2}, but not so in predicting desorption of methane. The selectivity of CO{sub 2} over methane was calculated to be 4.3:1. This is, of course, not in very good agreement with the measured values which showed the ratio to be 3.5:1. However, the measured results are in good agreement with the field observation at one of the CO{sub 2} injection sites. Based on the findings of this study, it was concluded that low pressure injection of CO{sub 2} can be fairly effective in displacing methane in coalbed reservoirs although this might be difficult to achieve in field conditions. Furthermore, the displacement of methane appears to be not only due to the preferential sorption of methane, but reduction in partial pressure as well. Hence, using a highly adsorbing gas, such as CO{sub 2}, has the advantages of inert gas stripping and non-mixing since the injected gas does not mix with the recovered methane.

John Kemeny; Satya Harpalani

2004-03-01T23:59:59.000Z

122

Hydroelectric Reservoirs -the Carbon Dioxide and Methane  

E-Print Network [OSTI]

Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

Fischlin, Andreas

123

Direct oxidation of methane to acetic acid catalyzed by Pd2+ and Cu2+ in the presence of molecular oxygen  

E-Print Network [OSTI]

Direct oxidation of methane to acetic acid catalyzed by Pd2+ and Cu2+ in the presence of molecular published as an Advance Article on the web 3rd August 2004 Methane is catalytically converted primarily. The conversion of methane to acetic acid has attracted recent interest as a pathway for the synthesis

Bell, Alexis T.

124

Coalbed methane potential of the Pechora Coalfield, Timan-Pechora Basin, Russia  

SciTech Connect (OSTI)

A comparison of the more important geologic attributes of coal beds in the coalbed methane producing regions of the United States to Permian coal beds in the Pechora Coalfield, Timan-Pechora Basin, Russia indicates a high potential for commercial coalbed methane production. Although the depositional and structural histories, as well as the age, of the coal beds in the Pechora Coalfield are different than coal beds in U.S. basins, coal quality attributes are similar. The more prospective part of the coal-bearing sequence is as thick as 1600 m and contains more than 150 coal beds that individually are as thick as 4 m. These coal beds are composed primarily of rank ranges from subbituminous to anthracite (,0.5->2.5% R[sub 0]), with the highest rank coal located near the city of Vorkuta. Published data indicates that the gas content of coals is as high as 28-35 m[sup 3]/ton, with an average value of 18 m[sup 3]/ton. About 700 MMCM of gas per year is emmitted from coal mines. Pore pressures in the coal beds are unknown, however, interbedded sandstones in some parts of the basin are overpressured. The commonly occurring problem, in mid-latitude coalbed methane well, of excessive amounts of water may be alleviated in this high-latitude coal field. We suggest that the wide-spread occurrence of permafrost in the Pechora Coalfield may form an effective barrier to down-dip water flow, thereby facilitating the dewatering state. In summary, the quality of coal beds in the Pechora Coalfield are similar to methane producing coal beds in the United States and should, therefore, be favorable for commercial rates of gas production.

Yakutseni, V.P.; Petrova, Y.E. (VNIGRI, St. Petersburg (Russian Federation)); Law, B.E.; Ulmishek, G.F. (Geological Survey, Denver, CO (United States))

1996-01-01T23:59:59.000Z

125

Coalbed methane potential of the Pechora Coalfield, Timan-Pechora Basin, Russia  

SciTech Connect (OSTI)

A comparison of the more important geologic attributes of coal beds in the coalbed methane producing regions of the United States to Permian coal beds in the Pechora Coalfield, Timan-Pechora Basin, Russia indicates a high potential for commercial coalbed methane production. Although the depositional and structural histories, as well as the age, of the coal beds in the Pechora Coalfield are different than coal beds in U.S. basins, coal quality attributes are similar. The more prospective part of the coal-bearing sequence is as thick as 1600 m and contains more than 150 coal beds that individually are as thick as 4 m. These coal beds are composed primarily of rank ranges from subbituminous to anthracite (,0.5->2.5% R{sub 0}), with the highest rank coal located near the city of Vorkuta. Published data indicates that the gas content of coals is as high as 28-35 m{sup 3}/ton, with an average value of 18 m{sup 3}/ton. About 700 MMCM of gas per year is emmitted from coal mines. Pore pressures in the coal beds are unknown, however, interbedded sandstones in some parts of the basin are overpressured. The commonly occurring problem, in mid-latitude coalbed methane well, of excessive amounts of water may be alleviated in this high-latitude coal field. We suggest that the wide-spread occurrence of permafrost in the Pechora Coalfield may form an effective barrier to down-dip water flow, thereby facilitating the dewatering state. In summary, the quality of coal beds in the Pechora Coalfield are similar to methane producing coal beds in the United States and should, therefore, be favorable for commercial rates of gas production.

Yakutseni, V.P.; Petrova, Y.E. [VNIGRI, St. Petersburg (Russian Federation); Law, B.E.; Ulmishek, G.F. [Geological Survey, Denver, CO (United States)

1996-12-31T23:59:59.000Z

126

FreezeFrac Improves the Productivity of Gas Shales S. Enayatpour, E. Van Oort, T. Patzek, University of Texas At Austin  

E-Print Network [OSTI]

to unconventional hydrocarbon reservers such as oil shales, gas shales, tight gas sands, coalbed methane, and gas

Patzek, Tadeusz W.

127

Water Management Strategies for Improved Coalbed Methane Production in the Black Warrior Basin  

SciTech Connect (OSTI)

The modern coalbed methane industry was born in the Black Warrior Basin of Alabama and has to date produced more than 2.6 trillion cubic feet of gas and 1.6 billion barrels of water. The coalbed gas industry in this area is dependent on instream disposal of co-produced water, which ranges from nearly potable sodium-bicarbonate water to hypersaline sodium-chloride water. This study employed diverse analytical methods to characterize water chemistry in light of the regional geologic framework and to evaluate the full range of water management options for the Black Warrior coalbed methane industry. Results reveal strong interrelationships among regional geology, water chemistry, and gas chemistry. Coalbed methane is produced from multiple coal seams in Pennsylvanian-age strata of the Pottsville Coal Interval, in which water chemistry is influenced by a structurally controlled meteoric recharge area along the southeastern margin of the basin. The most important constituents of concern in the produced water include chlorides, ammonia compounds, and organic substances. Regional mapping and statistical analysis indicate that the concentrations of most ionic compounds, metallic substances, and nonmetallic substances correlate with total dissolved solids and chlorides. Gas is effectively produced at pipeline quality, and the only significant impurity is N{sub 2}. Geochemical analysis indicates that the gas is of mixed thermogenic-biogenic origin. Stable isotopic analysis of produced gas and calcite vein fills indicates that widespread late-stage microbial methanogenesis occurred primarily along a CO{sub 2} reduction metabolic pathway. Organic compounds in the produced water appear to have helped sustain microbial communities. Ammonia and ammonium levels increase with total dissolved solids content and appear to have played a role in late-stage microbial methanogenesis and the generation of N{sub 2}. Gas production tends to decline exponentially, whereas water production tends to decline hyperbolically. Hyperbolic decline indicates that water volume is of greatest concern early in the life of a coalbed methane project. Regional mapping indicates that gas production is controlled primarily by the ability to depressurize permeable coal seams that are natively within the steep part of the adsorption isotherm. Water production is greatest within the freshwater intrusion and below thick Cretaceous cover strata and is least in areas of underpressure. Water management strategies include instream disposal, which can be applied effectively in most parts of the basin. Deep disposal may be applicable locally, particularly where high salinity limits the ability to dispose into streams. Artificial wetlands show promise for the management of saline water, especially where the reservoir yield is limited. Beneficial use options include municipal water supply, agricultural use, and industrial use. The water may be of use to an inland shrimp farming industry, which is active around the southwestern coalbed methane fields. The best opportunities for beneficial use are reuse of water by the coalbed methane industry for drilling and hydraulic fracturing. This research has further highlighted opportunities for additional research on treatment efficiency, the origin of nitrogen compounds, organic geochemistry, biogenic gas generation, flow modeling, and computer simulation. Results of this study are being disseminated through a vigorous technology transfer program that includes web resources, numerous presentations to stakeholders, and a variety of technical publications.

Pashin, Jack; McIntyre-Redden, Marcella; Mann, Steven; Merkel, David

2013-10-31T23:59:59.000Z

128

Development of a Series of National Coalbed Methane Databases  

E-Print Network [OSTI]

Development of a Series of National Coalbed Methane Databases Mohaghegh, S. D., Nunsavathu, U Growing Interest in Coalbed Methane ­ Elevated natural gas prices ­ Demand for clean energy sources DatabaseDatabase One Location Reservoir & Sorption Collection ­ 126 Coalbed Areas ­ 34 Parameters Ordered

Mohaghegh, Shahab

129

Methane Uptake in Urban Forests P E T E R M . G R O F F M A N *  

E-Print Network [OSTI]

Methane Uptake in Urban Forests and Lawns P E T E R M . G R O F F M A N * Cary Institute biological sink for the radiatively active trace gas methane (CH4) is bacteria in soils that consume CH4, these effects do not appear to be significant to statewide greenhouse gas forcing. Introduction Methane (CH4

Berkowitz, Alan R.

130

WATER QUALITY CHANGES AS A RESULT OF COALBED METHANE DEVELOPMENT IN A ROCKY MOUNTAIN WATERSHED1  

E-Print Network [OSTI]

WATER QUALITY CHANGES AS A RESULT OF COALBED METHANE DEVELOPMENT IN A ROCKY MOUNTAIN WATERSHED1 Xixi Wang, Assefa M. Melesse, Michael E. McClain, and Wanhong Yang2 ABSTRACT: Coalbed methane (CBM the Powder River. (KEY TERMS: coalbed methane, produced water; Montana; natural gas; pattern analysis

McClain, Michael

131

Regular Articles Coalbed methane produced water screening tool for treatment technology  

E-Print Network [OSTI]

Regular Articles Coalbed methane produced water screening tool for treatment technology and publicly available coalbed methane produced water screening tool to two simulated case studies to determine the largest volume waste stream in the industry (GWI, 2011). For coalbed methane (CBM) (coalbed natural gas

132

Uncorking the bottle: What triggered the Paleocene/Eocene thermal maximum methane release?  

E-Print Network [OSTI]

Uncorking the bottle: What triggered the Paleocene/Eocene thermal maximum methane release? Miriam E realms that has been attributed to a massive methane (CH4) release from marine gas hydrate reservoirs. Previously proposed mechanisms for this methane release rely on a change in deepwater source region

133

Source of methane and methods to control its formation in single chamber microbial electrolysis cells  

E-Print Network [OSTI]

Source of methane and methods to control its formation in single chamber microbial electrolysis online 31 March 2009 Keywords: Hydrogen Microbial electrolysis cell (MEC) Methane Single chamber Exoelectrogenic a b s t r a c t Methane production occurs during hydrogen gas generation in microbial electrolysis

134

Large scale characterisation of the concentAtion field of supercritical jets of hydrogen and methane  

E-Print Network [OSTI]

and methane E. Ruffin, Y. Mouilleau. J. Chaineaux INERIS - Institut National de l'Environnement Industriel et at INERIS' sought to characterise the clouds formed by supercritical jets of methane and hydrogen out were: the gas used (methane or hydrogen), the vent orifice diameter (25. 50, 75. 100 or 150 mm

Boyer, Edmond

135

Sorption-Enhanced Synthetic Natural Gas (SNG) Production from...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel...

136

Strategies for gas production from oceanic Class 3 hydrate accumulations  

E-Print Network [OSTI]

coexistence of aqueous, gas and hydrate phases, indicatingIntrinsic Rate of Methane Gas Hydrate DecompositionĒ, Chem.Makogon, Y.F. , ďGas hydrates: frozen energy,Ē Recherche

Moridis, George J.; Reagan, Matthew T.

2007-01-01T23:59:59.000Z

137

UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

Anna Lee Tonkovich

2004-01-01T23:59:59.000Z

138

Impact of relative permeability on type curves for coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane (CBM) is considered an unconventional gas resource produced from coal seams usually with low permeability at shallow depths. Analyzing the production performance inÖ (more)

Lakshminarayanan, Sunil.

2006-01-01T23:59:59.000Z

139

Evaluation of factors that influence microbial communities and methane production in coal microcosms.  

E-Print Network [OSTI]

??Vast reserves of coal represent a largely untapped resource that can be used to produce methane gas, a cleaner energy alternative compared to burning oilÖ (more)

Gallagher, Lisa K.

2014-01-01T23:59:59.000Z

140

Methane Hydrate Field Program  

SciTech Connect (OSTI)

This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. ē Historical Methane Hydrate Project Review Report ē Methane Hydrate Workshop Report ē Topical Report: Marine Methane Hydrate Field Research Plan ē Final Scientific/Technical Report

None

2013-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Greenhouse gas emissions in biogas production systems  

E-Print Network [OSTI]

Augustin J et al. Automated gas chromatographic system forof the atmospheric trace gases methane, carbon dioxide, andfuel consumption and of greenhouse gas (GHG) emissions from

Dittert, Klaus; Senbayram, Mehmet; Wienforth, Babette; Kage, Henning; Muehling, Karl H

2009-01-01T23:59:59.000Z

142

Methane Digester Loan Program  

Broader source: Energy.gov [DOE]

Established in 1998, the Minnesota Dept. of Agriculture Methane Digester Loan Program helps livestock producers install on-farm anaerobic digesters used for the production of electricity by...

143

Generating power with drained coal mine methane  

SciTech Connect (OSTI)

The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

NONE

2005-09-01T23:59:59.000Z

144

Mosquito larval habitat mapping using remote sensing and GIS: Implications of coalbed methane development and West Nile virus  

SciTech Connect (OSTI)

Potential larval habitats of the mosquito Culex tarsalis (Coquillett), implicated as a primary vector of West Nile virus in Wyoming, were identified using integrated remote sensing and geographic information system (GIS) analyses. The study area is in the Powder River Basin of north central Wyoming, an area that has been undergoing a significant increase in coalbed methane gas extractions since the late 1990s. Large volumes of water are discharged, impounded, and released during the extraction of methane gas, creating aquatic habitats that have the potential to support immature mosquito development. Landsat TM and ETM + data were initially classified into spectrally distinct water and vegetation classes, which were in turn used to identify suitable larval habitat sites. This initial habitat classification was refined using knowledge-based GIS techniques requiring spatial data layers for topography, streams, and soils to reduce the potential for overestimation of habitat. Accuracy assessment was carried out using field data and high-resolution aerial photography commensurate with one of the Landsat images. The classifier can identify likely habitat for ponds larger than 0.8 ha (2 acres) with generally satisfactory results (72.1%) with a lower detection limit of approximate to 0.4 ha (1 acre). Results show a 75% increase in potential larval habitats from 1999 to 2004 in the study area, primarily because of the large increase in small coalbed methane water discharge ponds. These results may facilitate mosquito abatement programs in the Powder River Basin with the potential for application throughout the state and region.

Zou, L.; Miller, S.N.; Schmidtmann, E.T. [University of Wyoming, Laramie, WY (United States). Dept. of Renewable Resources

2006-09-15T23:59:59.000Z

145

Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase  

E-Print Network [OSTI]

Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase Mu-Hyun Baik, Martin 2393 3.1. KIE in Methane Oxidations 2394 3.2. Primary and Secondary KIEs 2396 3.3. Other KIEs 2396 3 are bacteria that live on methane as their only source of carbon.1 The first step in their utilization

Baik, Mu-Hyun

146

SCREENING TESTS FOR IMPROVED METHANE CRACKING MATERIALS  

SciTech Connect (OSTI)

Bench scale (1 to 6 gram) methane cracking tests have been performed on a variety of pure elements, some alloys, and SAES{reg_sign} commercial getters St 101, St 198, St 707, St 737, and St 909 to determine methane cracking performance (MCP) of 5% methane in a helium carrier at 700 C, 101.3 kPa (760 torr) with a 10 sccm feed. The MCP was almost absent from some materials tested while others showed varying degrees of MCP. Re, Cr, V, Gd, and Mo powders had good MCP, but limited capacities. Nickel supported on kieselguhr (Ni/k), a Zr-Ni alloy, and the SAES{reg_sign} getters had good MCP in a helium carrier. The MCP of these same materials was suppressed in a hydrogen carrier stream and the MCP of the Zr-based materials was reduced by nitride formation when tested with a nitrogen carrier gas.

Klein, J; Jeffrey Holder, J

2007-07-16T23:59:59.000Z

147

Optimal(Estimation(of(North(American(Methane( Emissions(using(GOSAT(data:(  

E-Print Network [OSTI]

Optimal(Estimation(of(North(American(Methane( Emissions(using(GOSAT(data:( A&Sciences&Division,&Lawrence&Berkeley&National&Laboratory,&Berkeley,&CA,&USA.! *aturner@fas.harvard.edu& Harvard(University( #12;Prior Methane Emissions from EDGARv4.2/Kaplan Major/Gas Waste Coal 0 5 10 15 20 Wetlands Livestock Oil/Gas Landfills Coal North America Global #12;Satellites

Jacob, Daniel J.

148

Researchers discover key to spurring methane conversion By Paula Hartman Cohen  

E-Print Network [OSTI]

of methane when exploring for oil. These natural gas pockets generally are contiguous to oil reserves, where- teria living just below the earth's surface can be coaxed to rapidly convert oil to methane gas in oil they can pose serious fire and explosion hazards for oil explorers. According to Lovley, specialized

Lovley, Derek

149

Experimental study on the formation and dissociation conditions of methane hydrates in porous media  

E-Print Network [OSTI]

hydrates formed by methane gas and pure water in porous media. Methane gas hydrates were formed in a cell packed with 0.177-mm (0.007 in) diameter single sand (U.S. Sieve Series Designation Mesh No. 80) and 0.420-mm (0.017 in) diameter single sand (U...

Jung, Woodong

2002-01-01T23:59:59.000Z

150

Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water  

SciTech Connect (OSTI)

Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

Song Jin

2007-05-31T23:59:59.000Z

151

On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide  

E-Print Network [OSTI]

On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide Wei­Lambert law for the detection of methane gas. The device combines slow light in a PC waveguide with high absorption path length. A methane concentration of 100 ppm (parts per million) in nitrogen was measured

Chen, Ray

152

Full Text HTML Methane can be a problem or a solution, depending on one's viewpoint or circumstance. For  

E-Print Network [OSTI]

Abstract Full Text HTML Methane can be a problem or a solution, depending on one's viewpoint the researchers want to make hydrogen gas in microbial electrolysis cells (MECs), because making methane reduces hydrogen yield. The researchers have been studying the formation of methane in MECs in an effort to avoid

153

Exploiting coalbed methane and protecting the global environment  

SciTech Connect (OSTI)

The global climate change caused by greenhouse gases (GHGs) emission has received wide attention from all countries in the world. Global environmental protection as a common problem has confronted the human being. As a main component of coalbed methane, methane is an important factor influencing the production safety of coal mine and threatens the lives of miners. The recent research on environment science shows that methane is a very harmful GHG. Although methane gas has very little proportion in the GHGs emission and its stayed period is also very short, it has very obvious impact on the climate change. From the estimation, methane emission in the coal-mining process is only 10% of the total emission from human`s activities. As a clean energy, Methane has mature recovery technique before, during and after the process of mining. Thus, coalbed methane is the sole GHG generated in the human`s activities and being possible to be reclaimed and utilized. Compared with the global greenhouse effect of other GHGs emission abatement, coalbed methane emission abatement can be done in very low cost with many other benefits: (1) to protect global environment; (2) to improve obviously the safety of coal mine; and (3) to obtain a new kind of clean energy. Coal is the main energy in China, and coalbed contains very rich methane. According to the exploration result in recent years, about 30000{approximately}35000 billion m{sup 2} methane is contained in the coalbed below 2000 m in depth. China has formed a good development base in the field of reclamation and utilization of coalbed methane. The author hopes that wider international technical exchange and cooperation in the field will be carried out.

Yuheng, Gao

1996-12-31T23:59:59.000Z

154

Methyl chloride via oxyhydrochlorination of methane: A building block for chemicals and fuels from natural gas. Quarterly technical progress report No. 01, September 30, 1996--December 31, 1996  

SciTech Connect (OSTI)

The objectives of this cooperative agreement are to develop the oxyhydrochlorination (OHC) process for the conversion of methane to methyl chloride. In the first Phase of the project, Dow Corning has developed a stable selective catalyst and demonstrated the technology on a laboratory and a pilot plant scale. Specific tasks to achieve these objectives have been developed as follows: TASK 1 Fundamental Technical and Economic Evaluation TASK 2 Catalyst Selection Optimization and Characterization Studies TASK 3 Pilot Plant Design TASK 4 Pilot Plant Detailed Engineering, Procurement and Construction TASK 5 Pilot Plant Startup and Operation TASK 6 Pilot Plant Process Optimization TASK 7 Pilot Plant Extended Operation TASK 8 Pilot Plant Economic Evaluation/Scale-up Decision Significant progress has been completed in Task 1 with the objective to complete a fundamental technical and economic evaluation of learning gathered the Phase I effort of this project. A decision to proceed with the project will be made after completion of this Task. A computer model of the reactor system has been developed, which includes heat and mass transfer effects as well as reactions. Model validation is in progress. The Absorber/Stripper technology evaluated and implemented on the Phase I PDU to recover chlorocarbons (including methyl chloride) from reaction products has been scaled to evaluate economics for a commercial scale plant. In a parallel exercise, alternate recovery technologies were investigated for economic evaluation, to assure that the minimum capital option is pursued for the Phase II design. Commercial scale plant equipment and total plant costs are being evaluated using information from the Phase I PDU, reactor modeling and recovery system evaluation to estimate capital and operating costs for a commercial scale OHC unit.

Wineland, J.

1997-01-16T23:59:59.000Z

155

Methane oxidation over dual redox catalysts  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C[sub 2] hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C[sub 2] hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe[sup III] or Sn[sup IV], was found to be essential for the selectivity switch from C[sub 2] coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu[sup II](ion exchanged) Fe[sup III](framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La[sub 2]O[sub 3] has been discovered for potentially commercially attractive process for the conversion of methane to C[sub 2] hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C[sub 2] hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

156

Terr. Atmos. Ocean. Sci., Vol. 17, No. 4, 933-950, December 2006 Methane Venting in Gas Hydrate Potential Area Offshore of SW  

E-Print Network [OSTI]

Potential Area Offshore of SW Taiwan: Evidence of Gas Analysis of Water Column Samples Tsanyao Frank Yang 1 areas offshore of SW Taiwan for analysis of dissolved gases. Some these samples show unusually high-shore and offshore of southwestern Taiwan (e.g., Chow et al. 2000; Yang et al. 2004; Chiu et al. 2006). The gases

Lin, Andrew Tien-Shun

157

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents [OSTI]

A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

Lokhandwala, Kaaeid (Menlo Park, CA)

1997-01-01T23:59:59.000Z

158

Membrane-augmented cryogenic methane/nitrogen separation  

DOE Patents [OSTI]

A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

Lokhandwala, K.

1997-07-15T23:59:59.000Z

159

Method of determining methane and electrochemical sensor therefor  

DOE Patents [OSTI]

A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about about 1.4 volts versus R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

Zaromb, Solomon (Hinsdale, IL); Otagawa, Takaaki (Westmont, IL); Stetter, Joseph R. (Naperville, IL)

1986-01-01T23:59:59.000Z

160

Journal of Electron Spectroscopy and Related Phenomena 155 (2007) 2834 Electron Compton scattering from methane and methane-d4  

E-Print Network [OSTI]

from methane and methane-d4 G. Coopera, A.P. Hitchcocka,, C.A. Chatzidimitriou-Dreismannb, M. Vosc]. © 2006 Elsevier B.V. All rights reserved. Keywords: Quasi-elastic electron scattering; Methane; CD4

Hitchcock, Adam P.

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

DOE Launches Natural Gas Infrastructure R&D Program Enhancing...  

Office of Environmental Management (EM)

DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions DOE Launches Natural Gas...

162

Outlook for U.S. shale oil and gas  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

2035 2040 Associated with oil Coalbed methane Tight gas Shale gas Alaska Non-associated offshore Non-associated onshore Projections History 2012 Adam Sieminski, IAEEAEA January...

163

Coalbed methane resource potential of the Piceance Basin, northwestern Colorado  

SciTech Connect (OSTI)

As predicted, from an evolving coalbed methane producibility model, prolific coalbed methane production is precluded in the Piceance Basin by the absence of coal bed reservoir continuity and dynamic ground-water flow. The best potential for production may lie at the transition zone from hydropressure to hydrocarbon overpressure and/or in conventional traps basinward of where outcrop and subsurface coals are in good reservoir and hydraulic communication. Geologic and hydrologic synergy among tectonic and structural setting, depositional systems and coal distribution, coal rank, gas content, permeability and hydrodynamics are the controls that determine the coalbed methane resource potential of the Piceance Basin. Within the coal-bearing Upper Cretaceous Williams Fork Formation, the prime coalbed methane target, reservoir heterogeneity and thrust faults cause coal beds along the Grand Hogback and in the subsurface to be in modest to poor reservoir and hydraulic communication, restricting meteoric ground water recharge and basinward flow. Total subsurface coalbed methane resources are still estimated to be approximately 99 Tcf (3.09 Tm{sup 3}), although coalbed methane resource estimates range between 80 (2.49 Tm{sup 3}) and 136 Tcf (4.24 Tm{sup 3}), depending on the calculation method used. To explore for high gas contents or fully gas-saturated coals and consequent high productivity in the Piceance Basin, improved geologic and completion technologies including exploration and development for migrated conventionally and hydrodynamically trapped gases, in-situ generated secondary biogenic gases, and solution gases will be required.

Tyler, R.; Scott, A.R.; Kaiser, W.R. [Univ. of Texas, Austin, TX (United States)

1996-06-01T23:59:59.000Z

164

Methane Recovery from Hydrate-bearing Sediments  

SciTech Connect (OSTI)

Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

J. Carlos Santamarina; Costas Tsouris

2011-04-30T23:59:59.000Z

165

ISSUE PAPER METHANE AVOIDANCE FROM  

E-Print Network [OSTI]

ISSUE PAPER METHANE AVOIDANCE FROM COMPOSTING An Issue Paper for the: Climate Action Reserve...........................................................................................................39 6.2. Standard Methods for Quantifying Methane from Organic Waste in Landfills...40 6.3. GHG

Brown, Sally

166

Enhanced coalbed methane recovery  

SciTech Connect (OSTI)

The recovery of coalbed methane can be enhanced by injecting CO{sub 2} in the coal seam at supercritical conditions. Through an in situ adsorption/desorption process the displaced methane is produced and the adsorbed CO{sub 2} is permanently stored. This is called enhanced coalbed methane recovery (ECBM) and it is a technique under investigation as a possible approach to the geological storage of CO{sub 2} in a carbon dioxide capture and storage system. This work reviews the state of the art on fundamental and practical aspects of the technology and summarizes the results of ECBM field tests. These prove the feasibility of ECBM recovery and highlight substantial opportunities for interdisciplinary research at the interface between earth sciences and chemical engineering.

Mazzotti, M.; Pini, R.; Storti, G. [ETH, Zurich (Switzerland). Inst. of Process Engineering

2009-01-15T23:59:59.000Z

167

LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS  

SciTech Connect (OSTI)

This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

VANDOR,D.

1999-03-01T23:59:59.000Z

168

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

169

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect (OSTI)

Controlled landfilling is an approach to manage solid waste landfills, so as to rapidly complete methane generation, while maximizing gas capture and minimizing the usual emissions of methane to the atmosphere. With controlled landfilling, methane generation is accelerated to more rapid and earlier completion to full potential by improving conditions (principally moisture, but also temperature) to optimize biological processes occurring within the landfill. Gas is contained through use of surface membrane cover. Gas is captured via porous layers, under the cover, operated at slight vacuum. A field demonstration project has been ongoing under NETL sponsorship for the past several years near Davis, CA. Results have been extremely encouraging. Two major benefits of the technology are reduction of landfill methane emissions to minuscule levels, and the recovery of greater amounts of landfill methane energy in much shorter times, more predictably, than with conventional landfill practice. With the large amount of US landfill methane generated, and greenhouse potency of methane, better landfill methane control can play a substantial role both in reduction of US greenhouse gas emissions and in US renewable energy. The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

Don Augenstein; Ramin Yazdani; Rick Moore; Michelle Byars; Jeff Kieffer; Professor Morton Barlaz; Rinav Mehta

2000-02-26T23:59:59.000Z

170

5, 94059445, 2005 Methane emissions  

E-Print Network [OSTI]

ACPD 5, 9405­9445, 2005 Methane emissions from SCIAMACHY observations J. F. Meirink et al. Title and Physics Discussions Sensitivity analysis of methane emissions derived from SCIAMACHY observations through, 9405­9445, 2005 Methane emissions from SCIAMACHY observations J. F. Meirink et al. Title Page Abstract

Paris-Sud XI, Université de

171

4, 9931057, 2007 Methane hydrate  

E-Print Network [OSTI]

BGD 4, 993­1057, 2007 Methane hydrate stability and anthropogenic climate change D. Archer Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methane 2007 Correspondence to: D. Archer (d-archer@uchicago.edu) 993 #12;BGD 4, 993­1057, 2007 Methane hydrate

Paris-Sud XI, Université de

172

5, 243270, 2008 Methane emissions  

E-Print Network [OSTI]

BGD 5, 243­270, 2008 Methane emissions from plant biomass I. Vigano et al. Title Page Abstract and temperature on the emission of methane from plant biomass and structural components I. Vigano 1 , H. van.roeckmann@phys.uu.nl) 243 #12;BGD 5, 243­270, 2008 Methane emissions from plant biomass I. Vigano et al. Title Page Abstract

Paris-Sud XI, Université de

173

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;Cirkva, Vladimir; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

174

METHANE OXIDATION (AEROBIC) Helmut Brgmann  

E-Print Network [OSTI]

METHANE OXIDATION (AEROBIC) Helmut B√ľrgmann Eawag, Swiss Federal Institute of Aquatic Science and Technology, Kastanienbaum, Switzerland Synonyms Methanotrophy Definition Methane oxidation is a microbial metabolic process for energy generation and carbon assimilation from methane that is carried out by specific

Wehrli, Bernhard

175

6, 68416852, 2006 Methane emission  

E-Print Network [OSTI]

ACPD 6, 6841­6852, 2006 Methane emission from savanna grasses E. Sanhueza and L. Donoso Title Page Chemistry and Physics Discussions Methane emission from tropical savanna Trachypogon sp. grasses E. Sanhueza;ACPD 6, 6841­6852, 2006 Methane emission from savanna grasses E. Sanhueza and L. Donoso Title Page

Boyer, Edmond

176

The Tri--Methane Rearrangement  

E-Print Network [OSTI]

The Tri--Methane Rearrangement #12;Církva, Vladimír; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

Cirkva, Vladimir

177

5, 23052341, 2008 Anaerobic methane  

E-Print Network [OSTI]

BGD 5, 2305­2341, 2008 Anaerobic methane oxidation in Black Sea sediments N. J. Knab et al. Title of Biogeosciences Regulation of anaerobic methane oxidation in sediments of the Black Sea N. J. Knab1 , B. A. Cragg2­2341, 2008 Anaerobic methane oxidation in Black Sea sediments N. J. Knab et al. Title Page Abstract

Paris-Sud XI, Université de

178

Comparison of Kinetic and Equilibrium Reaction Models in Simulating the Behavior of Gas Hydrates in Porous Media  

E-Print Network [OSTI]

rate constant of methane gas hydrate decomposition, CanadianAdvances in the Study of Gas Hydrates, C. Taylor , J. Qwan,International Conference on Gas Hydrates, Trondheim, Norway,

Kowalsky, Michael B.; Moridis, George J.

2006-01-01T23:59:59.000Z

179

Landfill Gas Fueled HCCI Demonstration System  

E-Print Network [OSTI]

Natural Gas Nitric Oxide/Nitrogen Dioxide Neal Road LandfillThe methane, nitrogen and carbon dioxide concentrations ofmethane, 30% nitrogen and 30% carbon dioxide. The recorded

Blizman, Brandon J.; Makel, Darby B.; Mack, John Hunter; Dibble, Robert W.

2006-01-01T23:59:59.000Z

180

Alternative technologies to steam-methane reforming  

SciTech Connect (OSTI)

Steam-methane reforming (SMR) has been the conventional route for hydrogen and carbon monoxide production from natural gas feedstocks. However, several alternative technologies are currently finding favor for an increasing number of applications. The competing technologies include: steam-methane reforming combined with oxygen secondary reforming (SMR/O2R); autothermal reforming (ATR); thermal partial oxidation (POX). Each of these alternative technologies uses oxygen as a feedstock. Accordingly, if low-cost oxygen is available, they can be an attractive alternate to SMR with natural gas feedstocks. These technologies are composed technically and economically. The following conclusions can be drawn: (1) the SMR/O2R, ATR and POX technologies can be attractive if low-cost oxygen is available; (2) for competing technologies, the H{sub 2}/CO product ratio is typically the most important process parameter; (3) for low methane slip, the SMR/O2R, ATR and POX technologies are favored; (4) for full CO{sub 2} recycle, POX is usually better than ATR; (5) relative to POX, the ATR is a nonlicensed technology that avoids third-party involvement; (6) economics of each technology are dependent on the conditions and requirements for each project and must be evaluated on a case-by-case basis.

Tindall, B.M.; Crews, M.A. [Howe-Baker Engineers, Inc., Tyler, TX (United States)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa  

E-Print Network [OSTI]

SOFC Long Term Operation in Pure Methane by Gradual Internal Reforming S. Georgesa , N. Baillya , M was designed to be operated in pure methane, without reforming or carrier gas. The fuel cell was built up from-CGO catalytic layer. The operation principle is based on Gradual Internal Reforming. After an initiation in H2

Boyer, Edmond

182

Preliminary formation analysis for compressed air energy storage in depleted natural gas reservoirs : a study for the DOE Energy Storage Systems Program.  

SciTech Connect (OSTI)

The purpose of this study is to develop an engineering and operational understanding of CAES performance for a depleted natural gas reservoir by evaluation of relative permeability effects of air, water and natural gas in depleted natural gas reservoirs as a reservoir is initially depleted, an air bubble is created, and as air is initially cycled. The composition of produced gases will be evaluated as the three phase flow of methane, nitrogen and brine are modeled. The effects of a methane gas phase on the relative permeability of air in a formation are investigated and the composition of the produced fluid, which consists primarily of the amount of natural gas in the produced air are determined. Simulations of compressed air energy storage (CAES) in depleted natural gas reservoirs were carried out to assess the effect of formation permeability on the design of a simple CAES system. The injection of N2 (as a proxy to air), and the extraction of the resulting gas mixture in a depleted natural gas reservoir were modeled using the TOUGH2 reservoir simulator with the EOS7c equation of state. The optimal borehole spacing was determined as a function of the formation scale intrinsic permeability. Natural gas reservoir results are similar to those for an aquifer. Borehole spacing is dependent upon the intrinsic permeability of the formation. Higher permeability allows increased injection and extraction rates which is equivalent to more power per borehole for a given screen length. The number of boreholes per 100 MW for a given intrinsic permeability in a depleted natural gas reservoir is essentially identical to that determined for a simple aquifer of identical properties. During bubble formation methane is displaced and a sharp N2methane boundary is formed with an almost pure N2 gas phase in the bubble near the borehole. During cycling mixing of methane and air occurs along the boundary as the air bubble boundary moves. The extracted gas mixture changes as a function of time and proximity of the bubble boundary to the well. For all simulations reported here, with a formation radius above 50 m the maximum methane composition in the produced gas phase was less than 0.5%. This report provides an initial investigation of CAES in a depleted natural gas reservoir, and the results will provide useful guidance in CAES system investigation and design in the future.

Gardner, William Payton

2013-06-01T23:59:59.000Z

183

Exploration strategies based on a coalbed methane producibility model  

SciTech Connect (OSTI)

Knowing geologic and hydrologic characteristics of a basin does not necessarily lead to a determination of its coalbed methane producibility because it is the synergy among key hydrogeologic controls that governs producibility. Detailed studies performed in the San Juan, Piceance, and Sand Wash Basins determined that the key hydrogeologic factors affecting producibility include depositional setting and coal distribution, tectonic and structural setting, coal rank and gas generation, hydrodynamics, permeability, and gas content. The conceptual model based on these factors provides a rationale for exploration and development strategies for unexplored areas or in basins having established or limited production. Exceptionally high productivity requires good permeability; thick, laterally continuous high-rank and high-gas-content coals; dynamic flow of ground water through those coals; generation of secondary biogenic gases; and migration and conventional trapping of thermogenic and biogenic gases. Higher coalbed methane producibility commonly occurs in areas of upward flow associated with permeability barriers (no-flow boundaries). Fluid migration across a large gathering area orthogonal to permeability barriers and/or in situ generation of secondary biogenic gases concentrate the coal gas, resulting in higher gas contents. Low coalbed methane production is typically associated with very low permeability systems; the absence of conventional or hydrodynamic traps; and thin, low-rank coals below the threshold of thermogenic gas generation. Production from relatively low-gas-content coals in highly permeable recharge areas may result in excessive water and limited coalbed methane production. Thus, high permeability can be as detrimental to coalbed methane producibility as is low permeability.

Scott, A.R.; Kaiser, W.R.; Hamilton, D.S.; Tyler, R.; Finley, R.J. [Univ. of Texas, Austin, TX (United States)

1996-12-31T23:59:59.000Z

184

Exploration strategies based on a coalbed methane producibility model  

SciTech Connect (OSTI)

Knowing geologic and hydrologic characteristics of a basin does not necessarily lead to a determination of its coalbed methane producibility because it is the synergy among key hydrogeologic controls that governs producibility. Detailed studies performed in the San Juan, Piceance, and Sand Wash Basins determined that the key hydrogeologic factors affecting producibility include depositional setting and coal distribution, tectonic and structural setting, coal rank and gas generation, hydrodynamics, permeability, and gas content. The conceptual model based on these factors provides a rationale for exploration and development strategies for unexplored areas or in basins having established or limited production. Exceptionally high productivity requires good permeability; thick, laterally continuous high-rank and high-gas-content coals; dynamic flow of ground water through those coals; generation of secondary biogenic gases; and migration and conventional trapping of thermogenic and biogenic gases. Higher coalbed methane producibility commonly occurs in areas of upward flow associated with permeability barriers (no-flow boundaries). Fluid migration across a large gathering area orthogonal to permeability barriers and/or in situ generation of secondary biogenic gases concentrate the coal gas, resulting in higher gas contents. Low coalbed methane production is typically associated with very low permeability systems; the absence of conventional or hydrodynamic traps; and thin, low-rank coals below the threshold of thermogenic gas generation. Production from relatively low-gas-content coals in highly permeable recharge areas may result in excessive water and limited coalbed methane production. Thus, high permeability can be as detrimental to coalbed methane producibility as is low permeability.

Scott, A.R.; Kaiser, W.R.; Hamilton, D.S.; Tyler, R.; Finley, R.J. (Univ. of Texas, Austin, TX (United States))

1996-01-01T23:59:59.000Z

185

Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the technical feasibility and cost of upgrading low-BTU methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys modular microchannel process technology. The objective of Phase II is to demonstrate the process at the bench-scale. Natural gas upgrading systems have six main unit operations: feed compressor, dehydration unit, nitrogen rejection unit, deoxygenator, carbon dioxide scrubber, and a sales compressor. The NRU is the focus of the development program, and a bench-scale demonstration has been initiated. The Velocys NRU system targets producing methane with greater than 96% purity and at least 90% recovery for final commercial operation. A preliminary cost analysis of the methane upgrading system, including the Velocys NRU, suggests that costs below $2.00 per million (MM) BTU methane may be achieved. The cost for a conventional methane upgrading system is well above $2.30 per MM BTU, as benchmarked in an Environmental Protection Agency study. The project is on schedule and on budget. Task 4, a bench-scale demonstration of the ultra-fast TSA system is complete. Rapid thermal swing of an adsorbent bed using microchannels has been successfully demonstrated and the separation of a 70% methane and 30% nitrogen was purified to 92% methane. The bench-scale demonstration unit was small relative to the system dead volume for the initial phase of experiments and a purge step was added to sweep the dead volume prior to desorbing the bed and measuring purity. A technical and economic feasibility assessment was completed in Task 3. The proposed Velocys technology appears feasible for the methane upgrading market. Evaluated categories include adsorbent selection, rapid-cycle valve selection, microchannel manufacturability assessment, and system design and cost. The selected adsorbent, granular microporous carbon from either Barnaby-Sutcliffe or Calgon, experimentally demonstrated sufficient methane capacity under differential temperature at 100 pounds per square inch gauge. Several valve options were identified, including candidates that can operate millions of cycles between refurbishment. The microchannel adsorber and desorber designs were made using internal Velocys manufacturability standards, and the associated costs are acceptable as included with the complete nitrogen rejection unit (NRU) cost projection. A system design and cost estimate was completed for the NRU section of the methane upgrading system. As integrated into the complete system, the cost is in line with the market requirement.

Anna Lee Tonkovich

2005-07-01T23:59:59.000Z

186

Carbon Dioxide Storage in Coal Seams with Enhanced Coalbed Methane Recovery: Geologic Evaluation, Capacity Assessment and Field Validation of the Central Appalachian Basin.  

E-Print Network [OSTI]

??The mitigation of greenhouse gas emissions and enhanced recovery of coalbed methane are benefits to sequestering carbon dioxide in coal seams. This is possible becauseÖ (more)

Ripepi, Nino Samuel

2009-01-01T23:59:59.000Z

187

Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons  

E-Print Network [OSTI]

value. The usual chemical composition range of natural gas is shown in Table I. l. Table 1. 1 Natural Gas Composition Component Methane Ethane Pro ane iso-Butane normal-Butane iso-Pentane normal-Pentane Hexane s lus Nitro en Carbon Dioxide... Acetylene Carbon Ethylene Hydrogen Methane Water Carbon Dioxide CHAPTER I INTRODUCTION Challenge for Natural Gas Natural Gas (NG), which is comprised priinarily of methane, is found throughout the world, burns cleanly, and processes a high caloric...

Yang, Li

2003-01-01T23:59:59.000Z

188

ARM - Methane Background Information  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearchWarmingMethane Background Information Outreach Home Room News

189

Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling  

E-Print Network [OSTI]

and handling of natural gas hydrate. GSC Bulletin, 544: 263-naturally occurring gas hydrates: the structures of methaneDOE-USGS Mount Elbert gas hydrate stratigraphic test well:

Kneafsey, Timothy J.

2010-01-01T23:59:59.000Z

190

Radiochemical Transformation of High Pressure Methane under Gamma, Electron, and Neutron Irradiation  

E-Print Network [OSTI]

The chemical effects of irradiation on high pressure methane and noble gas mixtures were investigated using gamma, electron beam, and neutron irradiation sources. The gamma source used was the La-140 source from the Nuclear Science Center (NSC...

Clemens, Jeffrey Tyler

2014-05-01T23:59:59.000Z

191

Oxygen Pathways and Carbon Dioxide Utilization in Methane Partial Oxidation in Ambient Temperature  

E-Print Network [OSTI]

- ronmental impact. Present technology uses steam reforming to produce synthesis gas which is converted into enhance- ment of the carbon balance of methane conversion by reforming with CO2 in order to "recycle

Mallinson, Richard

192

Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts  

E-Print Network [OSTI]

The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

Blaylock, Donnie Wayne

2011-01-01T23:59:59.000Z

193

Determining the Fate of Methane Released from the Seafloor in Deep and Shallow Water Environments  

E-Print Network [OSTI]

Marine gas seeps and accidental marine oil spills are sources of methane (CH_(4)) to the ocean, and potentially to the atmosphere, though the magnitude of the fluxes and dynamics of these systems are poorly defined. For example, the ultimate...

Du, Mengran

2014-08-12T23:59:59.000Z

194

Field Exploration of Methane Seep Near Atqasuk  

SciTech Connect (OSTI)

Methane (CH{sub 4}) in natural gas is a major energy source in the U.S., and is used extensively on Alaska's North Slope, including the oilfields in Prudhoe Bay, the community of Barrow, and the National Petroleum Reserve, Alaska (NPRA). Smaller villages, however, are dependent on imported diesel fuel for both power and heating, resulting in some of the highest energy costs in the U.S. and crippling local economies. Numerous CH{sub 4} gas seeps have been observed on wetlands near Atqasuk, Alaska (in the NPRA), and initial measurements have indicated flow rates of 3,000-5,000 ft{sup 3} day{sup -1} (60-100 kg CH{sub 4} day{sup -1}). Gas samples collected in 1996 indicated biogenic origin, although more recent sampling indicated a mixture of biogenic and thermogenic gas. In this study, we (1) quantified the amount of CH{sub 4} generated by several seeps and evaluated their potential use as an unconventional gas source for the village of Atqasuk; (2) collected gas and analyzed its composition from multiple seeps several miles apart to see if the source is the same, or if gas is being generated locally from isolated biogenic sources; and (3) assessed the potential magnitude of natural CH{sub 4} gas seeps for future use in climate change modeling.

Katey Walter, Dennis Witmer, Gwen Holdmann

2008-12-31T23:59:59.000Z

195

Bioconversion of biomass to methane  

SciTech Connect (OSTI)

The conversion of biomass to methane is described. The biomethane potentials of various biomass feedstocks from our laboratory and literature is summarized.

Hashimoto, A.G. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

196

Renewable Energy 32 (2007) 12431257 Methane generation in landfills  

E-Print Network [OSTI]

. Some of the modern regulated landfills attempt to capture and utilize landfill biogas, a renewable collecting landfill biogas worldwide. The landfills that capture biogas in the US collect about 2.6 million. All rights reserved. Keywords: Landfill gas; Renewable energy; Municipal solid waste; Biogas; Methane

Columbia University

197

Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments  

E-Print Network [OSTI]

M. World crude and natural gas reserves rebound in 2000. Oilto the conventional gas reserve of 0.15x10 15 m 3 methane (

Moridis, George J.; Sloan, E. Dendy

2006-01-01T23:59:59.000Z

198

VIBRATION->VIBRATION ENERGY TRANSFER IN METHANE  

E-Print Network [OSTI]

VIBRATION ENERGY TRANSFER IN METHANE Peter Hess, A. H. Kung,Rotation Spectra of Methane, U.S. Nat'L∑ Tech. Inform.tret t tllll. I. INTRODUCTION Methane is a relatively simple

Hess, Peter

2012-01-01T23:59:59.000Z

199

Coal Bed Methane Protection Act (Montana)  

Broader source: Energy.gov [DOE]

The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and...

200

Central-northern Appalachian coalbed methane flow grows  

SciTech Connect (OSTI)

Over the past decade in the US, coalbed methane (CBM) has become an increasingly important source of unconventional natural gas. The most significant CBM production occurs in the San Juan basin of Colorado and new Mexico and the Black Warrior basin of Alabama, which collective in 1995 accounted for about 94% of US CBM production. The paper discusses early CBM production, recent production, gas composition, undiscovered potential, and new exploration areas.

Lyons, P.C. [Geological Survey, Reston, VA (United States)

1997-07-07T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Methane Gas Conversion Property Tax Exemption  

Broader source: Energy.gov [DOE]

'''''Note: This exemption is only available to facilities operated in connection or conjunction with a publicly-owned sanitary landfill. The exemption was available to other entities only for...

202

EIA - Greenhouse Gas Emissions - Methane Emissions  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data03. U.S. EIA

203

methane hydrate science plan-final.indd  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2013 Principal Authors: Consor um for Ocean Leadership and the Methane Hydrate Project Science Team December 2013 DOE Award Number: DE-FE0010195 Project Title: Methane Hydrate...

204

Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass  

SciTech Connect (OSTI)

This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

Huffman, Gerald

2012-12-31T23:59:59.000Z

205

Gas Emissions FLOODING THE LAND,  

E-Print Network [OSTI]

signif- icant sources of emissions of the greenhouse gases carbon dioxide and, in particular, methane to bacteria breaking down organic matter in the water. Methane, a much more powerful greenhouse gas than coal plants generating the same amounts of power. Dams and their associated reservoirs are globally

Batiste, Oriol

206

Coalbed Methane Production  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOil andMCKEESPORTfor the 2012Methane

207

Compatibility of selected ceramics with steam-methane reformer environments  

SciTech Connect (OSTI)

Conventional steam reforming of methane to synthesis gas (CO and H{sub 2}) hasa conversion efficiency of about 85%. Replacement of metal tubes in the reformer with ceramic tubes offers the potential for operation at temperatures high enough to increase the efficiency to 98-99%. However, the two candidate ceramic materials being given strongest consideration, sintered alpha Si carbide and Si carbide particulate-strengthened alumina, have been shown to react with components of the reformer environment. Extent of degradation as a function of steam partial pressure and exposure time has been studied, and results suggest limits under which these structural ceramics can be used in advanced steam-methane reformers.

Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Williams, J.J.; Rosenberg, R.A. [Stone and Webster Engineering Corp., Boston, MA (United States)

1996-04-01T23:59:59.000Z

208

Coal mine methane global review  

SciTech Connect (OSTI)

This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

NONE

2008-07-01T23:59:59.000Z

209

H. R. 2998: A bill to amend the Natural Gas Act to permit the development of coalbed methane gas in areas where its development has been impeded or made impossible by uncertainty and litigation over ownership rights, and for other purposes, introduced in the US House of Representatives, One Hundred Second Congress, First Session, July 23, 1991  

SciTech Connect (OSTI)

This bill would direct the Secretary of Energy to compile a list of affected states which are determined to be states in which disputes, uncertainty, or litigation exist or potentially exists regarding the ownership of coalbed methane; in which the development of significant deposits of coalbed methane may be impeded by such disputes; in which statutory or regulatory procedures permitting and encouraging development of coalbed methane prior to final resolution of disputes are not in place; and in which extensive development of coalbed methane does not exist. Colorado, Montana, New Mexico, Wyoming, Utah, Virginia, and Alabama are excluded from such a list since they currently have development of coalbed methane. Until the Secretary of Energy publishes a different list, the affected states are West Virginia, Pennsylvania, Kentucky, Ohio, Tennessee, Indiana, and Illinois, effective on the date of enactment of this bill.

Not Available

1991-01-01T23:59:59.000Z

210

Integrated process for coalbed brine and methane disposal  

SciTech Connect (OSTI)

This paper describes a technology and project to demonstrate and commercialize a brine disposal process for converting the brine stream of a coalbed gas producing site into clean water for agricultural use and dry solids that can be recycled for industrial consumption. The process also utilizes coalbed methane (CBM) released from coal mining for the combustion process thereby substantially reducing the potential for methane emissions to the atmosphere. The technology is ideally suited for the treatment and disposal of produced brines generated from the development of coal mines and coalbed methane resources worldwide. Over the next 10 to 15 years, market potential for brine elimination equipment and services is estimated to be in the range of $1 billion.

Byam, J.W. Jr.; Tait, J.H.; Brandt, H.

1996-12-31T23:59:59.000Z

211

X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well  

E-Print Network [OSTI]

and Englezos, P. , 2009. Gas hydrate formation in a variableDOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test WellFormation of natural gas hydrates in marine sediments. 1.

Kneafsey, T.J.

2012-01-01T23:59:59.000Z

212

Sulfonation of Methane Direct Liquid-Phase Sulfonation of Methane to  

E-Print Network [OSTI]

Sulfonation of Methane Direct Liquid-Phase Sulfonation of Methane to Methanesulfonic Acid by SO3 of methane to value-added prod- ucts is a significant contemporary challenge.[1] Methane is a very unreactive, consider- able effort has been devoted to the oxidation and oxidative carbonylation of methane.[2

Bell, Alexis T.

213

Review article Methane production by ruminants  

E-Print Network [OSTI]

Review article Methane production by ruminants: its contribution to global warming Angela R. MOSSa of methane in the global warming scenario and to examine the contribution to atmospheric methane made by enteric fermentation, mainly by rumi- nants. Agricultural emissions of methane in the EU-15 have recently

Paris-Sud XI, Université de

214

Capture and Use of Coal Mine Ventilation Air Methane  

SciTech Connect (OSTI)

CONSOL Energy Inc., in conjunction with MEGTEC Systems, Inc., and the U.S. Department of Energy with the U.S. Environmental Protection Agency, designed, built, and operated a commercial-size thermal flow reversal reactor (TFRR) to evaluate its suitability to oxidize coal mine ventilation air methane (VAM). Coal mining, and particularly coal mine ventilation air, is a major source of anthropogenic methane emissions, a greenhouse gas. Ventilation air volumes are large and the concentration of methane in the ventilation air is low; thus making it difficult to use or abate these emissions. This test program was conducted with simulated coal mine VAM in advance of deploying the technology on active coal mine ventilation fans. The demonstration project team installed and operated a 30,000 cfm MEGTEC VOCSIDIZER oxidation system on an inactive coal mine in West Liberty, WV. The performance of the unit was monitored and evaluated during months of unmanned operation at mostly constant conditions. The operating and maintenance history and how it impacts the implementation of the technology on mine fans were investigated. Emission tests showed very low levels of all criteria pollutants at the stack. Parametric studies showed that the equipment can successfully operate at the design specification limits. The results verified the ability of the TFRR to oxidize {ge}95% of the low and variable concentration of methane in the ventilation air. This technology provides new opportunities to reduce greenhouse gas emissions by the reduction of methane emissions from coal mine ventilation air. A large commercial-size installation (180,000 cfm) on a single typical mine ventilation bleeder fan would reduce methane emissions by 11,000 to 22,100 short tons per year (the equivalent of 183,000 to 366,000 metric tonnes carbon dioxide).

Deborah Kosmack

2008-10-31T23:59:59.000Z

215

Carbon dioxide, argon, nitrogen and methane clathrate hydrates:1 thermodynamic modelling, investigation of their stability in Martian2  

E-Print Network [OSTI]

1 Carbon dioxide, argon, nitrogen and methane clathrate hydrates:1 thermodynamic modelling-4Dec2012 #12;3 Keywords: Mars, clathrate hydrate, nitrogen, carbon dioxide, argon, methane, equilibrium and allows to simulating a Martian gas, CO2 dominated (95.3%) plus nitrogen6 (2.7%) and argon (2

Paris-Sud XI, Université de

216

Experimental Investigation of Propped Fracture Conductivity in Tight Gas Reservoirs Using The Dynamic Conductivity Test  

E-Print Network [OSTI]

in unconventional reservoirs such as coalbed methane, shale gas and tight gas reservoirs. Developing these types of unconventional gas reservoirs improves our energy security, and benefits the overall economy. Also, natural gas is one of the cleanest and most...

Romero Lugo, Jose 1985-

2012-10-24T23:59:59.000Z

217

Engineering Development of Ceramic Membrane Reactor System for Converting Natural Gas to Hydrogen and Synthesis Gas for Liquid Transportation Fuels  

SciTech Connect (OSTI)

An Air Products-led team successfully developed ITM Syngas technology from the concept stage to a stage where a small-scale engineering prototype was about to be built. This technology produces syngas, a gas containing carbon monoxide and hydrogen, by reacting feed gas, primarily methane and steam, with oxygen that is supplied through an ion transport membrane. An ion transport membrane operates at high temperature and oxygen ions are transported through the dense membrane's crystal lattice when an oxygen partial pressure driving force is applied. This development effort solved many significant technical challenges and successfully scaled-up key aspects of the technology to prototype scale. Throughout the project life, the technology showed significant economic benefits over conventional technologies. While there are still on-going technical challenges to overcome, the progress made under the DOE-funded development project proved that the technology was viable and continued development post the DOE agreement would be warranted.

Air Products and Chemicals

2008-09-30T23:59:59.000Z

218

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

2005-02-01T23:59:59.000Z

219

Partial oxidation of methane to syngas in different reactor types  

SciTech Connect (OSTI)

The performance of Rh/ZnO/{gamma}-Al{sub 2}O{sub 3} catalyst for partial oxidation of methane to syngas was compared in fixed and fluidised bed reactors. Catalyst activity was found not to be a limiting factor under any experimental conditions and complete oxygen conversions were observed in all tests. In the fixed bed reactor both methane conversion and syngas selectivity were increasing with space velocity as the result of an autothermal effect. Satisfactory control of the catalyst temperature at high space velocities could only be achieved with addition of inert diluent or steam to the feed. Different conversion and selectivity patterns were observed in fluidised bed reactor. Methane conversion and carbon monoxide selectivity were decreasing with increasing gas flow. By contrast, hydrogen selectivity showed distinct maximum at medium space velocities. These results are interpreted in terms of catalyst backmixing and its effect on primary and secondary reactions. Improved temperature control was also achieved in fluidised bed reactor. Several experiments using fluidised bed reactor were carried out at elevated pressures. To eliminate the occurrence of non-catalytic gas phase reactions between methane and oxygen very short feed mixing times (< 1 ms) were employed. Despite these measures the reactor could not be successfully operated at pressures above 0.7 MPa. The implications of these findings for process development are discussed.

Lapszewicz, J.A.; Campbell, I.; Charlton, B.G.; Foulds, G.A. [CSIRO Division of Coal and Energy Technology, Menai (Australia)

1995-12-01T23:59:59.000Z

220

State-of-the-art in coalbed methane drilling fluids  

SciTech Connect (OSTI)

The production of methane from wet coalbeds is often associated with the production of significant amounts of water. While producing water is necessary to desorb the methane from the coal, the damage from the drilling fluids used is difficult to assess, because the gas production follows weeks to months after the well is drilled. Commonly asked questions include the following: What are the important parameters for drilling an organic reservoir rock that is both the source and the trap for the methane? Has the drilling fluid affected the gas production? Are the cleats plugged? Does the 'filtercake' have an impact on the flow of water and gas? Are stimulation techniques compatible with the drilling fluids used? This paper describes the development of a unique drilling fluid to drill coalbed methane wells with a special emphasis on horizontal applications. The fluid design incorporates products to match the delicate surface chemistry on the coal, a matting system to provide both borehole stability and minimize fluid losses to the cleats, and a breaker method of removing the matting system once drilling is completed. This paper also discusses how coal geology impacts drilling planning, drilling practices, the choice of drilling fluid, and completion/stimulation techniques for Upper Cretaceous Mannville-type coals drilled within the Western Canadian Sedimentary Basin. A focus on horizontal coalbed methane (CBM) wells is presented. Field results from three horizontal wells are discussed, two of which were drilled with the new drilling fluid system. The wells demonstrated exceptional stability in coal for lengths to 1000 m, controlled drilling rates and ease of running slotted liners. Methods for, and results of, placing the breaker in the horizontal wells are covered in depth.

Baltoiu, L.V.; Warren, B.K.; Natras, T.A.

2008-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Microbe-Metazoan interactions at Pacific Ocean methane seeps  

E-Print Network [OSTI]

B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

Thurber, Andrew R

2010-01-01T23:59:59.000Z

222

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network [OSTI]

AND PRODUCTION OF METHANE Lawrence Berkeley LaboratoryDIGESTION AND PRODUCTION OF METHANE Kendall F. Haven MarkArrangement Kelp to Methane Processing Plant Schematic.

Haven, Kendall F.

2011-01-01T23:59:59.000Z

223

Microbe-metazoan interactions at Pacific Ocean methane seeps  

E-Print Network [OSTI]

B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

Thurber, Andrew Reichmann

2010-01-01T23:59:59.000Z

224

Fluxes of methane between landfills and the atmosphere: Natural and engineered controls  

SciTech Connect (OSTI)

Field measurement of landfill methane emissions indicates natural variability spanning more than 2 seven orders of magnitude, from approximately 0.0004 to more than 4000 g m{sub -2} day{sup -1}. This wide range reflects net emissions resulting from production (methanogenesis), consumption (methanotrophic oxidation), and gaseous transport processes. The determination of an {open_quotes}average{close_quotes} emission rate for a given field site requires sampling designs and statistical techniques which consider spatial and temporal variability. Moreover, particularly at sites with pumped gas recovery systems, it is possible for methanotrophic microorganisms in aerated cover soils to oxidize all of the methane from landfill sources below and, additionally, to oxidize methane diffusing into cover soils from atmospheric sources above. In such cases, a reversed soil gas concentration gradient is observed in shallow cover soils, indicating bidirectional diffusional transport to the depth of optimum methane oxidation. Rates of landfill methane oxidation from field and laboratory incubation studies range up to 166 g m{sup -2} day{sup -1} among the highest for any natural setting, providing an effective natural control on net emissions. Estimates of worldwide landfill methane emissions to the atmosphere have ranged from 9 to 70 Tg yr{sup -1}, differing mainly in assumed methane yields from estimated quantities of landfilled refuse. At highly controlled landfill sites in developed countries, landfill methane is often collected via vertical wells or horizontal collectors. Recovery of landfill methane through engineered systems can provide both environmental and energy benefits by mitigating subsurface migration, reducing surface emissions, and providing an alternative energy resource for industrial boiler use, on-site electrical generation, or upgrading to a substitute natural gas.

Bogner, J. [Argonne National Lab., IL (United States); Meadows, M. [ETSU, Harwell, Oxfordshire (United Kingdom); Czepiel, P. [Harvard Univ., Cambridge, MA (United States)

1997-08-01T23:59:59.000Z

225

Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the technical feasibility and cost of upgrading low-BTU methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys modular microchannel process technology. The objective of Phase II is to demonstrate the process at the bench scale. The project is on schedule and on budget. A technical and economic feasibility assessment was completed in Task 3. The proposed Velocys technology appears feasible for the methane upgrading market. Evaluated categories include adsorbent selection, rapid-cycle valve selection, microchannel manufacturability assessment, and system design and cost. The selected adsorbent, granular microporous carbon from either Barnaby-Sutcliffe or Calgon, experimentally demonstrated sufficient methane capacity under differential temperature at 100 pounds per square inch gauge. Several valve options were identified, including candidates that can operate millions of cycles between refurbishment. The microchannel adsorber and desorber designs were made using internal Velocys manufacturability standards, and the associated costs are acceptable as included with the complete nitrogen rejection unit (NRU) cost projection. A system design and cost estimate was completed for the NRU section of the methane upgrading system. As integrated into the complete system, the cost is in line with the market requirement. The system has six main unit operations: feed compressor, dehydration unit, nitrogen rejection unit, deoxygenator, carbon dioxide scrubber, and a sales compressor. The NRU is the focus of the development program, and a bench-scale demonstration will be initiated in the next fiscal year. The Velocys NRU system targets producing methane with greater than 96% purity and at least 90% recovery for final commercial operation. A preliminary cost analysis of the methane upgrading system, including the Velocys NRU, suggests that costs below $2.00 per million (MM) BTU methane may be achieved. The cost for a conventional methane upgrading system is well above $2.30 per MM BTU, as benchmarked in an Environmental Protection Agency study.

Anna Lee Tonkovich

2004-07-01T23:59:59.000Z

226

Methane/CO{sub 2} sorption modeling for coalbed methane production and CO{sub 2} sequestration  

SciTech Connect (OSTI)

A thorough study of the sorption behavior of coals to methane and carbon dioxide (CO{sub 2}) is critical for carbon sequestration in coal seams and enhanced coalbed methane recovery. This paper discusses the results of an ad/de-sorption study of methane and CO{sub 2}, in single gas environment, on a set of coal samples taken from the San Juan and Illinois Basins. The results indicate that, under similar temperature and pressure conditions, coals exhibit higher affinity to CO{sub 2} as compared to methane and that the preferential sorption ratio varies between 2:1 and 4:1. Furthermore, the experimental data were modeled using Langmuir, BET, and Dubinin-Polanyi equations. The accuracy of the models in quantifying coal-gas sorption was compared using an error analysis technique. The Dubinin-Radushkevich equation failed to model the coal-gas sorption behavior satisfactorily. For methane, Langmuir, BET, and Dubinin-Astakhov (D-A) equations all performed satisfactorily within comparable accuracy. However, for CO{sub 2}, the performance of the D-A equation was found to be significantly better than the other two. Overall, the D-A equation fitted the experimental sorption data the best, followed by the Langmuir and BET equations. Since the D-A equation is capable of deriving isotherms for any temperature using a single isotherm, thus providing added flexibility to model the temperature variation due to injection/depletion, this is the recommended model to use. 49 refs., 9 figs., 5 tabs.

Satya Harpalani; Basanta K. Prusty; Pratik Dutta [Southern Illinois University-Carbondale, Carbondale, IL (United States). Department of Mining and Mineral Resources Engineering

2006-08-15T23:59:59.000Z

227

Methane Hydrate Program  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Program Report to Congress | Page 13 Hutchinson, D., Ruppel, C., Roberts, H., Carney, R., Smith, M., 2011. Gas hydrates in the Gulf of Mexico. In Gulf of Mexico Origin, Waters, and...

228

Methane oxidation over dual redox catalysts. Final report  

SciTech Connect (OSTI)

Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C{sub 2} hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C{sub 2} hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe{sup III} or Sn{sup IV}, was found to be essential for the selectivity switch from C{sub 2} coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu{sup II}(ion exchanged) Fe{sup III}(framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La{sub 2}O{sub 3} has been discovered for potentially commercially attractive process for the conversion of methane to C{sub 2} hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C{sub 2} hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

1992-06-01T23:59:59.000Z

229

A study on coalbed methane reserve of Shanxi: Hedong coalfield reserve and its utilization  

SciTech Connect (OSTI)

Coalbed gas, i.e. coalbed methane, is considered an unconventional gas, formed during coal accumulation and preserved in coal seams. In the past, coalbed gas was considered a major hazard factor to the safety of mining and caused countless explosive events and great losses to the enterprises and even to the country. Early in 1960s and 70s, it was recognized that coalbed gas could be utilized as an energy resource and collected through tunnels in China. In 1995, the output of tunnel gas reached 500Mm{sup 3}, however, surface pumping is still at its beginning stage, test and appraisal; so far, no commercial development is being carried out in China. Hedong coalfield, situated in the west of Shanxi province and bordered by the Yellow River in the northwest and outcrop seams in the southeast, is 540km long (N-S) and 10--40 km wide (E-W) and covers an area of 17,000 km{sup 2} across 13 counties of Xinzou, Luliang, Linfen and Yuncheng prefectures. It is the No. 2 coalfield in Shanxi province and the well-known base of excellent coking coal and power coal in China. Hedong coalfield is not only rich in coal resource, but also in coalbed methane. This paper describes the geology of the coalfield (including structure, magmatic activity, coal seams and coal grade); the regularity of coalbed methane occurrence in the Hedong coalfield; the calculation of coalbed methane resource; and the use of coalbed methane for motor fuels and chemicals production. The total resource is 1468.93Gm{sup 3}. The production of motor fuels can be realized by the following processes: (a) synthetic methanol as substitute of gasoline; (b) F-T synthesis for synthetic gasoline and diesel oil; (c) Compressed natural gas as motor fuel; and (d) Liquefied natural gas as motor fuel. The production of organic chemicals is suggested with the following technology: (a) Two-stage steam reforming to convert methane to synthetic gas various organic chemicals can be produced therefrom; (b) Partial oxidation of methane to produce synthesis gas and acetylene; (c) Coalbed methane to produce hydrogen cyanide and chloromethanes; and (d) Coalbed methane to produce acrylonitrile, acetylene, ethylene, propylene and butylenes.

Kong, X.; Fan, R.; Hu, Y.; Wang, M.; Wang, M.; Chen, Z.; Li, M.; Peng, S. [Taiyuan Ke-jin Technology Development Service (China)

1997-12-31T23:59:59.000Z

230

Airborne observations of methane emissions from rice cultivation in the Sacramento Valley of California  

E-Print Network [OSTI]

, the California Air Resources Board (CARB) greenhouse gas inventory emission rate of 2.7 √? 1010 g CH4/yr is not accounted for in the CARB inventory. Citation: Peischl, J., et al. (2012), Airborne observations of methane California, which include livestock, landfills, wastewater treatment, oil and gas drilling and distribution

Cohen, Ronald C.

231

Sulfur pollution suppression of the wetland methane source in the 20th and 21st centuries  

E-Print Network [OSTI]

. Emission of this powerful greenhouse gas from wet- lands is known to depend on climate, with increasing are likely due to factors other than the global warming of wetlands. Atmospheric methane (CH4) is a powerful greenhouse gas (GHG) that is responsible for an estimated 22% of the present anthropogenically enhanced

232

Earth'sFuture Remote sensing of fugitive methane emissions from oil and  

E-Print Network [OSTI]

Earth'sFuture Remote sensing of fugitive methane emissions from oil and gas production in North and tight oil reservoirs to exploit formerly inaccessible or unprofitable energy resources in rock and oil provide an opportunity to achieve energy self-sufficiency and to reduce greenhouse gas emissions

Dickerson, Russell R.

233

Comparison of Nonprecious Metal Cathode Materials for Methane Production by Electromethanogenesis  

E-Print Network [OSTI]

a methanogenic biofilm on the cathode by either direct electron transfer or evolved hydrogen. To optimize methane, Microbial electrolysis cell, Power-to-gas, Microbially influenced corrosion, Carbon black, Graphite, hydro- gen gas production by water electrolysis often requires expensive precious metals to reduce

234

Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily  

SciTech Connect (OSTI)

Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

Helene Hilger; James Oliver; Jean Bogner; David Jones

2009-03-31T23:59:59.000Z

235

Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water  

SciTech Connect (OSTI)

The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (‚??Methane in the Arctic Shelf‚?Ě or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (‚??metagenomes‚?Ě). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

David Kirchman

2011-12-31T23:59:59.000Z

236

Coalbed methane exploration in the Lorraine Basin, France  

SciTech Connect (OSTI)

DuPont Conoco Hydrocarbures has been involved in a Coalbed Methane (CBM) project in France since 1991. Coalbed methane exploration differs noticeably in several aspects from conventional oil and gas exploration. This paper is divided in three parts and discusses some geological, reservoir and drilling considerations relevant to the exploration and appraisal of a coalbed methane prospect. The first part presents geological issues such as data collection and evaluation of its associated value, building expertise to create a geological and geophysical model integrating the work of a multidisciplinary team, and assessing uncertainties of the data interpretation. A short review of the basin activity, geological and tectonic setting, and environment aspects is presented in order to illustrate some CBM exploration issues. The second part describes a comprehensive coalbed methane reservoir data acquisition program incorporating coal sample optical and chemical analyses, gas sample chromatography, canister desorption, fracture density of coal cores, and measurement of in-situ coal permeability and bounding-strata stress. Field practical concerns are then discussed such as on-site and off-site canister desorption, gas sample collection, rapid estimation of gas content, ash content, total bed moisture, and finally well testing alternatives for permeability and rock stress determination. The third part reviews drilling issues such as drilling and coring options for core hole size and casing size, rig site equipment requirements for continuous coring operations, including mud treatment equipment, core handling material and core work stations, alliance of national and foreign drilling contractors to optimize equipment and experience, and finally overview of coring procedures to identify best practices for pending operations. The paper is derived from Conoco`s experience in CBM exploration in the Lorraine Basin, North East of France.

Michaud, B. [DuPont Conoco Hydrocarbures, Paris (France); Briens, F.; Girdler, D.

1995-08-01T23:59:59.000Z

237

Future designs of raw-gas conversion systems  

SciTech Connect (OSTI)

Many different processes are available to convert raw gas to substitute natural gas (SNG). Several additional processes have been proposed and are now in development. An Institute of Gas Technology (IGT) computer program assesses the efficiency of various raw-gas conversion processes for the recovery of high-temperature enthalpy and the net export of high-pressure steam. The steam balance is a prime measure of economic attractiveness of the alternative processes. Of the currently available processes, the sequence that uses sour-gas shift followed by conventional cold sweetening and nickel-based multistage methanation is preferred. Certain novel process concepts beginning with sour-gas shift and hot-gas carbon dioxide removal should be a significant improvement. The improved processes will require either sulfur-tolerant methanation or hot-gas sulfur removal plus conventional methanation. In either case, the gas would not be cooled to room temperature before being entirely converted to methane.

Colton, J.W.; Fleming, D.K.

1981-01-01T23:59:59.000Z

238

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-07-01T23:59:59.000Z

239

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope drilled and cored a well The HOT ICE No.1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report.

Thomas E. Williams; Keith Millheim; Buddy King

2004-06-01T23:59:59.000Z

240

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

Thomas E. Williams; Keith Millheim; Bill Liddell

2005-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE  

E-Print Network [OSTI]

POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE CYCLE UNDER FUTURE the available scientific literature on how natural sources and the atmospheric fate of methane may be affected by future climate change. We discuss how processes governing methane wetland emissions, per- mafrost thawing

Chappellaz, J√©r√īme

242

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A  

E-Print Network [OSTI]

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A Theoretical component (MMOH) of the multicomponent soluble methane monooxygenase (MMO) system catalyzes the oxidation of methane by dioxygen to form methanol and water at non-heme, dinuclear iron active sites. The catalytic

Gherman, Benjamin F.

243

Methane oxidation associated with submerged brown mosses reduces methane emissions from Siberian  

E-Print Network [OSTI]

Methane oxidation associated with submerged brown mosses reduces methane emissions from Siberian, University of Hamburg, Allende-Platz 2, 20146 Hamburg, Germany Summary 1. Methane (CH4) oxidation to Sphagnum species and low-pH peatlands. 2. Moss-associated methane oxidation (MAMO) can be an effective

Wehrli, Bernhard

244

Nonequilibrium clumped isotope signals in microbial methane  

E-Print Network [OSTI]

Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

Wang, David T.

245

EXPENDITURE OBJECT CODES Foundation FOUNDATION EXPENDITURE OBJECT CODES are used primarily by Accounting Services for Foundation  

E-Print Network [OSTI]

EXPENDITURE OBJECT CODES ­ Foundation 2-J page 1 FOUNDATION EXPENDITURE OBJECT CODES are used primarily by Accounting Services for Foundation transactions. 3080 Foundation Service Fee: Allocation of administrative costs to Foundation beneficiary departmental accounts. 3120 LSU Magazine Costs - Foundation

Harms, Kyle E.

246

Method for the photocatalytic conversion of methane  

DOE Patents [OSTI]

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

1998-02-24T23:59:59.000Z

247

Method for the photocatalytic conversion of methane  

DOE Patents [OSTI]

A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA); D'Este, Joseph R. (Pittsburgh, PA)

1998-01-01T23:59:59.000Z

248

Formation and retention of methane in coal. Final report  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

249

Variability of the methane trapping in martian subsurface clathrate hydrates  

E-Print Network [OSTI]

Recent observations have evidenced traces of methane CH4 heterogeneously distributed in the martian atmosphere. However, because the lifetime of CH4 in the atmosphere of Mars is estimated to be around 300-600 years on the basis of photochemistry, its release from a subsurface reservoir or an active primary source of methane have been invoked in the recent literature. Among the existing scenarios, it has been proposed that clathrate hydrates located in the near subsurface of Mars could be at the origin of the small quantities of the detected CH4. Here, we accurately determine the composition of these clathrate hydrates, as a function of temperature and gas phase composition, by using a hybrid statistical thermodynamic model based on experimental data. Compared to other recent works, our model allows us to calculate the composition of clathrate hydrates formed from a more plausible composition of the martian atmosphere by considering its main compounds, i.e. carbon dioxyde, nitrogen and argon, together with methane. Besides, because there is no low temperature restriction in our model, we are able to determine the composition of clathrate hydrates formed at temperatures corresponding to the extreme ones measured in the polar caps. Our results show that methane enriched clathrate hydrates could be stable in the subsurface of Mars only if a primitive CH4-rich atmosphere has existed or if a subsurface source of CH4 has been (or is still) present.

Caroline Thomas; Olivier Mousis; Sylvain Picaud; Vincent Ballenegger

2008-10-23T23:59:59.000Z

250

Methane generation at Grand Gulf Nuclear Station  

SciTech Connect (OSTI)

The methane generation at Grand Gulf has been brought to light twice. The initial event occurred in February 1990 and the second in December 1993. Both events involved the receipt of a cask at Barnwell Waste Management Facility that when opened indicated a gas escaping. The gas was subsequently sampled and indicated a percentage of explosive gas. Both events involved powdered resin and indicated that the generation was from a bacterial attack of the organic materials (cellulose in the powdered resin mixture). The first event occurred and was believed to be isolated in a particular waste stream. The situation was handled and a biocide was found to be effective in treatment of liners until severe cross contamination of another waste stream occurred. This allowed the shipment of a liner that was required to be sampled for explosive gases. The biocide used by GGNS was allowed reintroduction into the floor drains and this allowed the buildup of immunity of the bacterial population to this particular biocide. The approval of a new biocide has currently allowed GGNS to treat liners and ship them offsite.

Carver, M.L. [Entergy Operations, Inc., Grand Gulf Nuclear Station, Port Gibson, MS (United States)

1995-09-01T23:59:59.000Z

251

Methane conversion for application in fuel cells  

SciTech Connect (OSTI)

Conventional steam reformers are large and expensive for small scale fuel cell installations. But also the high endothermicity of the reforming reaction for the production of synthesis gas is a drawback. An alternative to conventional steam reforming is the partial oxidation of methane to synthesis gas. This process is slightly exothermic. The flexibility of the process makes small scale application possible. However, the partial oxidation process seems especially attractive for application within a high temperature fuel cell, because of relatively high CO/H{sub 2}-ratio for the output gases. In this paper the results of the study on the mechanism of the partial oxidation to synthesis gas on silica-supported nickel catalysts are discussed. Moreover, a process for the partial oxidation is proposed in which air instead of oxygen can be used. Based on the results of the mechanistic study two processes for the catalytic partial oxidation are proposed and simulated using the Aspen Plus flowsheeting program with which the mass and heat balances were optimized.

Mulder, A. [Gastec N.V., Apeldoorn (Netherlands); Looy, F. van [Utrecht Univ. (Netherlands). Dept. of Inorganic Chemistry; Waveren, A. van; Wingerden, A.J.M. van

1996-12-31T23:59:59.000Z

252

Methane adsorption on Devonian shales  

E-Print Network [OSTI]

METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

Li, Fan-Chang

1992-01-01T23:59:59.000Z

253

6, 36113626, 2006 Effects of methane  

E-Print Network [OSTI]

ACPD 6, 3611­3626, 2006 Effects of methane outgassing on the Black Sea atmosphere K. Kourtidis et a Creative Commons License. Atmospheric Chemistry and Physics Discussions Effects of methane outgassing Effects of methane outgassing on the Black Sea atmosphere K. Kourtidis et al. Title Page Abstract

Paris-Sud XI, Université de

254

2, 11971241, 2005 Control of methane  

E-Print Network [OSTI]

BGD 2, 1197­1241, 2005 Control of methane efflux at the Tommeliten seep area H. Niemann et al Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methane emission;BGD 2, 1197­1241, 2005 Control of methane efflux at the Tommeliten seep area H. Niemann et al. Title

Boyer, Edmond

255

Electric power generation using a phosphoric acid cell on a municipal solid waste landfill gas stream. Technology verification report, November 1997--July 1998  

SciTech Connect (OSTI)

The report gives results of tests to verify the performance of a landfill gas pretreatment unit (GPU) and a phosphoric acid fuel cell system. The complete system removes contaminants from landfill gas and produces electricity for on-site use or connection to an electric grid. Performance data were collected at two sites determined to be representative of the U.S. landfill market. The Penrose facility, in Los Angeles, CA, was the first test site. The landfill gas at this site represented waste gas recovery from four nearby landfills, consisting primarily of industrial waste material. It produced approximately 3000 scf of gas/minute, and had a higher heating value of 446 Btu/scf at about 44% methane concentration. The second test site, in Groton, CT, was a relatively small landfill, but with greater heat content gas (methane levels were about 57% and the average heating value was 585 Btu/scf). The verification test addressed contaminant removal efficiency, flare destruction efficiency, and the operational capability of the cleanup system, and the power production capability of the fuel cell system.

Masemore, S.; Piccot, S.

1998-08-01T23:59:59.000Z

256

OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS  

SciTech Connect (OSTI)

The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

1998-04-01T23:59:59.000Z

257

Comparison of kinetic and equilibrium reaction models in simulating gas hydrate behavior in porous media  

E-Print Network [OSTI]

with Diapirism and Gas Hydrates at the Head of the Cape FearSea-Level Low Stands Above Gas Hydrate-Bearing Sediments.rate constant of methane gas hydrate decomposition. Canadian

Kowalsky, Michael B.; Moridis, George J.

2006-01-01T23:59:59.000Z

258

Basin scale assessment of gas hydrate dissociation in response to climate change  

E-Print Network [OSTI]

Moridis GJ. Oceanic gas hydrate instability and dissociationKA. Potential effects of gas hydrate on human welfare, Proc.WS. A review of methane and gas hydrates in the dynamic,

Reagan, M.

2012-01-01T23:59:59.000Z

259

Application of the Continuous EUR Method to Estimate Reserves in Unconventional Gas Reservoirs  

E-Print Network [OSTI]

Reservoirs 19. Cheng et al. (2007) Decline Curve Analysis for Multilayered Tight Gas Reservoirs 20. Blasingame and Rushing Method for Gas-in-Place and Reserves Estimation (2005) 21. Clarkson et al. (2007) Production Data Analysis for Coalbed-Methane... Wells 22. Clarkson et al. (2008) Production Data Analysis for Coalbed-Methane Wells 23. Rushing et al. (2008) Production Data Analysis for Coalbed-Methane Wells 24. Lewis and Hughes (2008) Production Data Analysis for Shale Gas Wells 25. Mattar et al...

Currie, Stephanie M.

2010-10-12T23:59:59.000Z

260

Methane production by attached film  

DOE Patents [OSTI]

A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Methane generation from waste materials  

DOE Patents [OSTI]

An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

2010-03-23T23:59:59.000Z

262

Mechanisms of gas migration in flooding post-mining context nils Le gAL,  

E-Print Network [OSTI]

coal. in parallel, several models are in development using the HYTec code to describe mine methane, for example methane from coal beds (e.g. doyle 2001; Scott 2002; Besnard 2004). According to Scott (2002 to study gas transfer and to characterize the influence of hydrostatic pressure on methane release from

Paris-Sud XI, Université de

263

Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments  

SciTech Connect (OSTI)

In October 2008 the University of California at Santa Barbara (UCSB) initiated investigations of water column methane oxidation in methane hydrate environments, through a project funded by the National Energy Technology Laboratory (NETL) entitled: assessing the efficacy of the aerobic methanotrophic biofilter in methane hydrate environments. This Final Report describes the scientific advances and discoveries made under this award as well as the importance of these discoveries in the broader context of the research area. Benthic microbial mats inhabit the sea floor in areas where reduced chemicals such as sulfide reach the more oxidizing water that overlies the sediment. We set out to investigate the role that methanotrophs play in such mats at locations where methane reaches the sea floor along with sulfide. Mats were sampled from several seep environments and multiple sets were grown in-situ at a hydrocarbon seep in the Santa Barbara Basin. Mats grown in-situ were returned to the laboratory and used to perform stable isotope probing experiments in which they were treated with 13C-enriched methane. The microbial community was analyzed, demonstrating that three or more microbial groups became enriched in methane?s carbon: methanotrophs that presumably utilize methane directly, methylotrophs that presumably consume methanol excreted by the methanotrophs, and sulfide oxidizers that presumably consume carbon dioxide released by the methanotrophs and methylotrophs. Methanotrophs reached high relative abundance in mats grown on methane, but other bacterial processes include sulfide oxidation appeared to dominate mats, indicating that methanotrophy is not a dominant process in sustaining these benthic mats, but rather a secondary function modulated by methane availability. Methane that escapes the sediment in the deep ocean typically dissolved into the overlying water where it is available to methanotrophic bacteria. We set out to better understand the efficacy of this process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date, with five more circulating in draft form, and several others planned.

Valentine, David

2012-09-30T23:59:59.000Z

264

Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)  

SciTech Connect (OSTI)

In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

2014-10-01T23:59:59.000Z

265

Coalbed Methane Estimated Production  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 56623 46 47 62CarbonCubic1,966 1,914 1,886

266

Department of Earth Sciences www.rhul.ac.uk/earthsciences Page 1 of 2 Fugitive Methane Emissions in the UK and their Impacts on the Urban  

E-Print Network [OSTI]

Department of Earth Sciences www.rhul.ac.uk/earthsciences Page 1 of 2 Fugitive Methane Emissions James France, Prof Euan Nisbet Project Description: Methane is the second most important greenhouse gas amounts from vehicles, with emissions from landfills, ruminants and in some areas, coal mines

Sheldon, Nathan D.

267

Method for the catalytic conversion of organic materials into a product gas  

DOE Patents [OSTI]

A method for converting organic material into a product gas includes: (a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; (b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and (c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300 C to about 450 C; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen. 5 figs.

Elliott, D.C.; Sealock, L.J. Jr.; Baker, E.G.

1997-04-01T23:59:59.000Z

268

Method for the catalytic conversion of organic materials into a product gas  

DOE Patents [OSTI]

A method for converting organic material into a product gas includes: a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300.degree. C. to about 450.degree. C.; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen.

Elliott, Douglas C. (Richland, WA); Sealock, Jr., L. John (Richland, WA); Baker, Eddie G. (Richland, WA)

1997-01-01T23:59:59.000Z

269

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

270

Semi-annual report for the unconventional gas recovery program, period ending September 30, 1980  

SciTech Connect (OSTI)

Progress is reported in research on methane recovery from coalbeds, eastern gas shales, western gas sands, and geopressured aquifers. In the methane from coalbeds project, data on information evaluation and management, resource and site assessment and characterization, model development, instrumentation, basic research, and production technology development are reported. In the methane from eastern gas shales project, data on resource characterization and inventory, extraction technology, and technology testing and verification are presented. In the western gas sands project, data on resource assessments, field tests and demonstrations and project management are reported. In the methane from geopressured aquifers project, data on resource assessment, supporting research, field tests and demonstrations, and technology transfer are reported.

Manilla, R.D. (ed.)

1980-11-01T23:59:59.000Z

271

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

2005-02-01T23:59:59.000Z

272

Biomimetic methane oxidation. Final report, October 1, 1989--June 1, 1995  

SciTech Connect (OSTI)

Transportation fuels are a critical energy commodity and they impact nearly every sector of this country. The need for transportation fuels is projected well into the next century. Consequently, there is a strong emphasis on the economical conversion of other domestic fossil energy resources to liquid hydrocarbons that can be used as transportation fuels. Natural gas is currently a readily available resource that has a positive future outlook considering its known and anticipated reserves. There is intense government and industrial interest in developing economic technologies to convert natural gas to liquid fuels. Methane, CH{sub 4}, is the primary hydrocarbon (85-95%) in natural gas. This document covers the following: production soluable of methane monooxygenase; production of particulate methane monooxygenase; production of methane monooxygenase in continuous culture; subunit resolution for active site identification of methylosinus trichosporium OB3b soluble methane monooxygenase; the synthesis and characterization of new copper coordination complexes contairing the asymmetric coordinating chelate ligand application to enzyme active site modeling; the synthesis and characterization of new iron coordination complexes utilizing an asymmetric coordinating chelate ligand; further characterization of new bionuclear iron complexes.

Watkins, B.E.; Satcher, J.H. Jr.; Droege, M.W.; Taylor, R.T.

1995-07-01T23:59:59.000Z

273

POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS  

E-Print Network [OSTI]

POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS AND CO2 METHANATION NOVEMBER 19th 2013 IRES. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis Gas-to-heat Gas-to-mobility Gas-to-power Excess Production = Consumption Distribution and storing

Paris-Sud XI, Université de

274

Coalbed methane potential of the Greater Green River, Piceance, Powder River, and Raton Basins. Topical report, January 1991-July 1991  

SciTech Connect (OSTI)

Coalbed methane potential of the Greater Green River, Piceance, Powder River, and Raton Basins was evaluated in the context of geologic and hydrologic characteristics identified in the San Juan Basin, the nation's leading coalbed methane producing basin. The major comparative criteria were (1) coalbed methane resources, (2) geologic and hydrologic factors that predict areas of high gas producibility and high coalbed reservoir permeability, and (3) coalbed thermal maturity. The technical criteria were expanded to include structure, depositional systems, and data base and then combined with economic criteria (production, industry activity, and pipeline availability) to evaluate the coalbed methane potential of the basins. The Greater Green River and Piceance Basins have primary potential to make a significant near-term contribution to the nation's gas supply. These basins have large gas resources, high-rank coals, high gas contents, and established coalbed methane production. The Greater Green River Basin has numerous coalbed methane targets, good coal-seam permeability, and extensive hydrologic areas favorable for production. The Powder River and Raton Basins were judged to have secondary potential. Coal beds in the Powder River Basin are thermally immature and produce large volumes of water; the Raton Basin has a poor data base and has no gas pipeline infrastructure. Low production and minimal industry activity further limit the near-term potential of the Raton Basin. However, if economic criteria are discounted and only major technical criteria are considered, the Greater Green River and Raton Basins are assigned primary potential. The Raton Basin's shallow, thermally mature coal beds of good permeability are attractive coalbed methane targets, but low coal-seam permeability limits the coalbed methane potential of the Piceance Basin.

Tyler, R.; Ambrose, W.A.; Scott, A.R.; Kaiser, W.R.

1991-12-01T23:59:59.000Z

275

INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION  

SciTech Connect (OSTI)

An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogen from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM streams containing high levels of nitrogen, as is now the case at the Federal No.2 Mine. Even lacking the CPSA pipeline delivery demonstration, the project was successful in laying the groundwork for future commercial applications of the integrated system. This operation can still provide a guide for other coal mines which need options for utilization of their methane resources. The designed system can be used as a complete template, or individual components of the system can be segregated and utilized separately at other mines. The use of the CMM not only provides an energy fuel from an otherwise wasted resource, but it also yields an environmental benefit by reducing greenhouse gas emissions. The methane has twenty times the greenhouse effect as compared to carbon dioxide, which the combustion of the methane generates. The net greenhouse gas emission mitigation is substantial.

Peet M. Soot; Dale R. Jesse; Michael E. Smith

2005-08-01T23:59:59.000Z

276

The Methane to Markets Coal Mine Methane Subcommittee meeting  

SciTech Connect (OSTI)

The presentations (overheads/viewgraphs) include: a report from the Administrative Support Group; strategy updates from Australia, India, Italy, Mexico, Nigeria, Poland and the USA; coal mine methane update and IEA's strategy and activities; the power of VAM - technology application update; the emissions trading market; the voluntary emissions reduction market - creating profitable CMM projects in the USA; an Italian perspective towards a zero emission strategies; and the wrap-up and summary.

NONE

2008-07-01T23:59:59.000Z

277

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

2005-02-01T23:59:59.000Z

278

Appalachian basin coal-bed methane: Elephant or flea  

SciTech Connect (OSTI)

Historically, interest in the Appalachian basin coal-bed methane resource extends at least over the last 50 years. The Northern and Central Appalachian basins are estimated to contain 61 tcf and 5 tcf of coal-bed methane gas, respectively. Development of this resource has not kept pace with that of other basins, such as the Black Warrior basin of Alabama of the San Juan basin of northern New Mexico and Colorado. Without the benefit of modern completion, stimulation, and production technology, some older Appalachian basin coal-bed methane wells were reported to have produced in excess of 150 used here to characterize some past projects and their results. This work is not intended to comprise a comprehensive survey of all Appalachian basin projects, but rather to provide background information from which to proceed for those who may be interested in doing so. Several constraints to the development of this resource have been identified, including conflicting legal rights of ownership of the gas produced from the coal seams when coal and conventional oil and gas rights are controlled by separate parties. In addition, large leaseholds have been difficult to acquire and finding costs have been high. However, the threshold of minimum economic production may be relatively low when compared with other areas, because low-pressures pipelines are available and gas prices are among the highest in the nation. Interest in the commercial development of the resource seems to be on the increase with several projects currently active and more reported to be planned for the near future.

Hunt, A.M. (Dames and Moore, Cincinnati, OH (United States))

1991-08-01T23:59:59.000Z

279

Weather encapsulates the state of the atmosphere, primarily involving the component which affects  

E-Print Network [OSTI]

1 #12;2 Weather encapsulates the state of the atmosphere, primarily involving the component which and Telegraph readers tend to use oF #12;5 The human body has an energy balance just like the Earth (solar range in larger on still, clear days, when solar heating is strong at the surface and is not offset

Allan, Richard P.

280

Nickel crystallite thermometry during methanation  

SciTech Connect (OSTI)

A magnetic method to measure the average temperature of superparamagnetic nickel crystallites has been applied during CO methanation. The method takes advantage of the temperature dependence of the low field magnetization of such catalysts; however, the adsorption of carbon monoxide and the formation of surface carbon species complicate the interpretation of results. Calibrations to account for temperature change and the adsorption of reactants are described. The calibration for the effects of CO is based on the assumption that the interaction of CO with nickel is the same for methanation and disproportionation. Interphase heat transfer calculations based on the thermometric data compare favorably with previous results from ethane hyrogenolysis, and give no indication of microscopic temperature differences between the nickel crystallites and support.

Ludlow, D.K.; Cale, T.S.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Reply to Saba and Orzechowski and Schon: Methane contamination of  

E-Print Network [OSTI]

accompanying gas- well drilling and hydraulic fracturing Two letters by Saba and Orzechowski (1) and Schon (2 and hydraulic fracturing (3). We respond briefly here and point readers to a supplementary document for more, primarily to provide a baseline for future sampling after horizontal drilling and hydraulic fracturing occur

Jackson, Robert B.

282

Detection and Production of Methane Hydrate  

SciTech Connect (OSTI)

This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

2011-12-31T23:59:59.000Z

283

EPA Natural Gas STAR Program Accomplishments  

E-Print Network [OSTI]

Established in 1993, the Natural Gas STAR program is a partnership between the U.S. EPA and the oil and natural gas industry designed to cost-effectively reduce methane emissions from voluntary activities undertaken at oil and natural gas operations both

unknown authors

284

Simulation study of the effect of well spacing, effect of permeability anisotropy, and effect of Palmer and Mansoori model on coalbed methane production.  

E-Print Network [OSTI]

??Interference for adjacent wells may be beneficial to Coalbed-Methane production. The effect is the acceleration of de-watering which should lead to earlier and higher gasÖ (more)

Zulkarnain, Ismail

2006-01-01T23:59:59.000Z

285

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation. In addition to the Final Report, several companion Topical Reports are being published.

Thomas E. Williams; Keith Millheim; Bill Liddell

2004-11-01T23:59:59.000Z

286

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

2005-02-01T23:59:59.000Z

287

METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST  

SciTech Connect (OSTI)

Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored a well (the Hot Ice No. 1) on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports. Documenting the results of this effort are key to extracting lessons learned and maximizing the industry's benefits for future hydrate exploitation.

Thomas E. Williams; Keith Millheim; Bill Liddell

2005-02-01T23:59:59.000Z

288

Treatment of gas from an in situ conversion process  

DOE Patents [OSTI]

A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

2011-12-06T23:59:59.000Z

289

Effect of silane concentration on the supersonic combustion of a silane/methane mixture  

SciTech Connect (OSTI)

A series of direct connect combustor tests was conducted to determine the effect of silane concentration on the supersonic combustion characteristics of silane/methane mixtures. Shock tube ignition delay data indicated more than an order of magnitude reduction in ignition delay times for both 10 and 20 percent silane/methane mixtures as compared to methane. The ignition delay time of the 10 percent mixture was only a factor of 2.3 greater than that of the 20 percent mixture. Supersonic combustion tests were conducted with the fuel injected into a model scramjet combustor. The combustor was mounted at the exit of a Mach 2 nozzle and a hydrogen fired heater was used to provide a variation in test gas total temperature. Tests using the 20 percent silane/methane mixture indicated considerable combustion enhancement when compared to methane alone. This mixture had an autoignition total temperature of 1650 R. The addition of 20 percent silane to methane resulted in a pyrophoric fuel with good supersonic combustion performance. Reducing the silane concentration below this level, however, yielded a less pyrophoric fuel that exhibited poor supersonic combustion performance.

Northam, G.B.; Mc Lain, A.G.; Pellett, G.L.; Diskin, G.S.

1986-01-01T23:59:59.000Z

290

Design of New Materials for Methane Storage Tina Duren, Lev Sarkisov, Omar M. Yaghi, and Randall Q. Snurr*,  

E-Print Network [OSTI]

, and Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109 Received August 21, 2003. In Final is to replace gasoline and diesel with alternative fuels such as natural gas. In this report, we elucidate such as gasoline and diesel.1 Natural gas, which consists mainly of methane, fits this definition and is widely

Yaghi, Omar M.

291

Catalytic Reduction of Nitrogen Oxides by Methane over Pd(110) S. M. Vesecky, J. Paul, and D. W. Goodman*  

E-Print Network [OSTI]

emissions.1 The subfield of environ- mental catalysis concerned with air quality control involves and stationary sources2 There are many stationary sources of environmental gas phase pollutants. Methane is perhaps the largest pollutant by volume, emitted from sources such as livestock, gas wells, and landfills

Goodman, Wayne

292

Miscellaneous States Coalbed Methane Proved Reserves Revision...  

U.S. Energy Information Administration (EIA) Indexed Site

Revision Decreases (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

293

,"Colorado Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

294

,"Arkansas Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

295

,"Wyoming Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

296

A guide to coalbed methane operations  

SciTech Connect (OSTI)

A guide to coalbed methane production is presented. The guide provides practical information on siting, drilling, completing, and producing coalbed methane wells. Information is presented for experienced coalbed methane producers and coalbed methane operations. The information will assist in making informed decisions about producing this resource. The information is presented in nine chapters on selecting and preparing of field site, drilling and casing the wellbore, wireline logging, completing the well, fracturing coal seams, selecting production equipment and facilities, operating wells and production equipment, treating and disposing of produced water, and testing the well.

Hollub, V.A.; Schafer, P.S.

1992-01-01T23:59:59.000Z

297

,"Montana Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Montana Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

298

,"Oklahoma Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

299

,"Virginia Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Virginia Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

300

CO2 Sequestration Enhances Coalbed Methane Production.  

E-Print Network [OSTI]

??Since 1980s, petroleum engineers and geologists have conducted researches on Enhanced Coalbed Methane Recovery (ECBM). During this period, many methods are introduced to enhance theÖ (more)

Pang, Yu

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

,"Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

302

,"Miscellaneous Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

303

,"Alabama Coalbed Methane Proved Reserves, Reserves Changes,...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

304

Effect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames  

E-Print Network [OSTI]

], thereby enabling stable combustion at lean mixture conditions. In the case of natural gas engines, enriching the fuel with hydrogen has the proven benefits of improving the combustion stability and reducingEffect of Hydrogen Addition on the Flammability Limit of Stretched Methane/Air Premixed Flames

Im, Hong G.

305

EMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES  

E-Print Network [OSTI]

-produced electricity for battery electric vehicles. Already, vehicles powered by compressed natural gas, propane. LIPMAN AND MARK A. DELUCCHI example, promising strategies for powering motor vehicles with reduced GHGEMISSIONS OF NITROUS OXIDE AND METHANE FROM CONVENTIONAL AND ALTERNATIVE FUEL MOTOR VEHICLES

Kammen, Daniel M.

306

The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane  

E-Print Network [OSTI]

, which was 700 (490 to 920) Gg yr^-1 and -370 (-440 to -280) Gg yr^-1, respectively. The ocean accounts for 10 - 19 % in the global CH3Cl emission and 6 - 9 % in its global sinks. Methane (CH4) is a potent greenhouse gas, which has a warming potential...

Hu, Lei

2012-10-19T23:59:59.000Z

307

Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria  

DOE Patents [OSTI]

An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

Apel, William A. (Idaho Falls, ID); Dugan, Patrick R. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

308

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS  

E-Print Network [OSTI]

ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16.............................................................................................21 Coal and Methane Production

Maxwell, Bruce D.

309

Extension - Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption  

SciTech Connect (OSTI)

The need for cost effective technologies for upgrading coal mine methane to pipeline quality natural gas is becoming ever greater. The current work presents and investigates a new approach to reduce the impact of the most costly step in the conventional technology, nitrogen rejection. The proposed approach is based on the Velocys microchannel platform, which is being developed to commercialize compact and cost efficient chemical processing technology. For this separation, ultra fast thermal swing sorption is enabled by the very high rates of heat and mass transfer inherent in microchannel processing. In a first phase of the project solid adsorbents were explored. Feasibility of ultrafast thermal swing was demonstrated but the available adsorbents had insufficient differential methane capacity to achieve the required commercial economics. In a second phase, ionic liquids were adopted as absorbents of choice, and experimental work and economic analyses, performed to gauge their potential, showed promise for this novel alternative. Final conclusions suggest that a combination of a required cost target for ionic liquids or a methane capacity increase or a combination of both is required for commercialization.

Anna Lee Tonkovich

2008-08-11T23:59:59.000Z

310

Cyclic process for producing methane with catalyst regeneration  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. For practical commercial operations utilizing the two-step process of the invention of a cyclic basis, nickel, cobalt, ruthenium, thenium and alloys thereof are especially prepared for use in a metal state, with CO disproportionation being carried out at temperatures up to about 350.degree. C. and with the conversion of active surface carbon to methane being carried out by reaction with steam. The catalyst is employed in such cyclic operations without the necessity for employing a regeneration step as part of each processing cycle. Inactive carbon or coke that tends to form on the catalyst over the course of continuous operations utilizing such cyclic process is effectively and advantageously removed, on a periodic basis, in place of conventional burn off with an inert stream containing a low concentration of oxygen.

Frost, Albert C. (Congers, NY); Risch, Alan P. (New Fairfield, CT)

1980-01-01T23:59:59.000Z

311

Nitrogen removal from natural gas using two types of membranes  

DOE Patents [OSTI]

A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

2003-10-07T23:59:59.000Z

312

Ammonia synthesis gas purification  

SciTech Connect (OSTI)

This patent describes the purification of a reformed gas mixture following water gas shift conversion to produce a purified ammonia synthesis gas stream. The improved processing sequence consisting essentially of: (A) Selectively catalytically oxidizing the residual carbon monoxide content of the gas mixture to carbon dioxide so as to reduce the carbon monoxide content of the gas mixture to less than about 20 ppm, the selective catalytic oxidation being carried out with an excess of air, with the excess oxygen being catalytically reacted with a small amount of hydrogen so that the residual oxygen level is reduced to less than about 3 ppm; (B) removing the bulk of the carbon dioxide content of the gas mixture by liquid absorption; (C) Removing residual amounts of carbon monoxide, carbon dioxide and water by selective adsorption on the fixed beds of a thermal swing adsorption system, a dry, purified ammonia ammonia synthesis gas stream containing less than a total of 10 ppm of carbon monoxide and carbon dioxide being recovered from the thermal swing adsorption system; (D) Passing the resulting dry, purified ammonia synthesis gas stream having a low content of methane to an ammonia production operation without intermediate passage of the ammonia synthesis gas stream to a methanation unit or to a cryogenic unit for removal of carbon monoxide and carbon dioxide therefrom; whereby the efficiency of the overall purification operation and the effective utilization of hydrogen are enhanced.

Fuderer, A.

1986-02-25T23:59:59.000Z

313

IMPROVEMENT OF METHANE STORAGE IN ACTIVATED CARBON USING METHANE HYDRATE  

E-Print Network [OSTI]

and particles. As the natural gas resources are enormous, it represents a good alternative to oil in term natural gas distribution network. Secondly, at low pressure, the tank geometry can adopt various shapes, gas storage INTRODUCTION. With the massive increase of the urban traffic, coupled with its large

Paris-Sud XI, Université de

314

Three-dimensional model synthesis of the global methane cycle  

E-Print Network [OSTI]

39, Ehhalt, D. H. , The atmoēheric cycle of methane, Tellugworld-wide increase in tēheric methane, 1978-1987, Science,

1991-01-01T23:59:59.000Z

315

Diffusion Characterization of Coal for Enhanced Coalbed Methane Production.  

E-Print Network [OSTI]

??This thesis explores the concept of displacement of sorbed methane and enhancement of methane recovery by injection of CO2 into coal, while sequestering CO2. TheÖ (more)

Chhajed, Pawan

2011-01-01T23:59:59.000Z

316

Direct Observation of the Active Center for Methane Dehydroaromatizati...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Active Center for Methane Dehydroaromatization Using an Ultrahigh Field 95Mo NMR Spectroscopy. Direct Observation of the Active Center for Methane Dehydroaromatization Using an...

317

Studies of the Active Sites for Methane Dehydroaromatization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Active Sites for Methane Dehydroaromatization Using Ultrahigh-Field Solid-State Mo95 NMR Spectroscopy. Studies of the Active Sites for Methane Dehydroaromatization Using...

318

Scientists detect methane levels three times larger than expected...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

methane that actually preceded recent concerns about potential emissions from fracking," Dubey said. Scientists detect methane levels three times larger than expected over...

319

Coalbed methane: A partial solution to Indonesia`s growing energy problems  

SciTech Connect (OSTI)

Indonesia contains the largest resources of coal in Southeast Asia. Indonesian scientists estimate that the in-place coalbed methane resource in 16 onshore basins is about 213 Tcf ({approximately}6 Tcm). This volume is approximately double Indonesia`s current reserves of natural gas. Indonesia is a rapidly industrializing nation of 186 million people, of which 111 million live in Java and 38 million in Sumatra. As industrialization progresses from the present low level, the growth in energy demand will be very rapid. Indonesia`s domestic gas demand is expected to increase form 1.6 Bcf/d (0.05 Bcm/d) in 1991 to 5.7 Bcf/d (0.2 Bcm/d) in 2021. Because the major gas resources of East Kalimantan, North Sumatra, and Natuna are so remote from the main consuming area in northwest Java and are dedicated for export by virtue of the national energy policy, the need is becoming urgent to develop new resources of natural gas, including coalbed methane, for the domestic market. Due to the high geothermal gradient, the coal deposits in the back-arc basins of Sumatra and Java are expected to be of higher than normal rank at depths favorable for coalbed methane production. The oil- and gas-productive Jatibarang sub-basin in northwest Java, with estimated in-place resources of coalbed methane in excess of 20 Tcf (0.6 Tcm), is considered to be the most prospective area in Indonesia for the near-term development of coalbed methane. This area includes Jakarta and vicinity, the most populous and most heavily industrialized part of Indonesia.

Murray, D.K. [D. Keith Murray & Associates, Lakewood, CO (United States); Gold, J.P. [Consulting Geologist, Evergreen, CO (United States)

1995-04-01T23:59:59.000Z

320

Coalbed Methane (CBM) is natural  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuelsDepartmentPolicyClean,Coalbed Methane (CBM)

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Completion methods in thick, multilayered tight gas sands  

E-Print Network [OSTI]

Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

Ogueri, Obinna Stavely

2008-10-10T23:59:59.000Z

322

The 1991 coalbed methane symposium proceedings  

SciTech Connect (OSTI)

The proceedings of the 1991 coalbed methane symposium are presented. The proceedings contains 50 papers on environmental aspects of recovering methane from coal seams, reservoir characterization and testing mine safety and productivity, coalbed stimulation, geology and resource assessment, well completion and production technologies, reservoir modeling and case histories, and resources and technology.

Not Available

1991-01-01T23:59:59.000Z

323

Cyclic process for producing methane in a tubular reactor with effective heat removal  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-Lee (Spring Valley, NY)

1986-01-01T23:59:59.000Z

324

Cyclic process for producing methane from carbon monoxide with heat removal  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

1982-01-01T23:59:59.000Z

325

,"California--State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy SourcesWyoming"Coalbed Methane ProvedDry Natural Gas ExpectedWellheadCrudeCoalbed Methane

326

,"Colorado Coalbed Methane Proved Reserves (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy SourcesWyoming"Coalbed Methane ProvedDry Natural GasMarketedCoalbed Methane Proved

327

Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs  

E-Print Network [OSTI]

, corefloods were conducted at 1,500 psig and 70??C, in which flue gas was injected into an Austin chalk core containing initially methane. Two types of flue gases were injected: dehydrated flue gas with 13.574 mole% CO2 (Gas A), and treated flue gas (N2, O2...

Nogueira de Mago, Marjorie Carolina

2005-11-01T23:59:59.000Z

328

Correlation of producing Fruitland Formation coals within the western outcrop and coalbed methane leakage on the Southern Ute Reservation  

SciTech Connect (OSTI)

The Colorado Geological Survey and Southern Ute Indian Tribe proposed to determine the cause of several gas seeps which are occurring on the western outcrop of the coalbed methane producing Fruitland Formation on the Southern Ute Indian Reservation. Correlation between outcrop coals and subsurface coals was necessary to determine seep source in the northern part of the study area. Subsurface studies include structure and net coal isopach maps, stratigraphy was cross-sections, production maps, and a production database. Detailed coal stratigraphy was correlated through production wells near the outcrop region. These maps and cross-sections were correlated to new surface outcrop maps generated by the Colorado, Geological Survey and the Southern Ute Division of Energy Resources. Methane gas seepage has been noted historically within the study area. The total investigation may help determine if gas seepage is natural, a result of coalbed methane development, or some combination of the above.

Carroll, Christopher J.; Mathews, Stephanie; Wickman, Barbara

2000-07-07T23:59:59.000Z

329

Uncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal  

E-Print Network [OSTI]

analyses involving coal. Greenhouse gas emissions from fuel use and methane releases at coal mines, fuel.5 million metric tons of methane emissions. Close to 95% of domestic coal was consumed by the electricityUncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal Aranya Venkatesh

Jaramillo, Paulina

330

The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling  

E-Print Network [OSTI]

The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling Methane contamination is usually due to natural causes; however, it can also be the result of drilling activities, including shale gas drilling. Monitoring techniques exist for detecting methane and, in some cases

Wang, Z. Jane

331

DEVELOPMENT OF COAL BED METHANE UTILIZING GIS TECHNOLOGIES  

SciTech Connect (OSTI)

During the second half of the 1990's, Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period were the advancements in Geographical Information Systems (GIS) technologies generating terra-bytes of new data for the oil and gas industry. Coupled to these accelerating initiatives are many environmental concerns relating to production wastes and water table depletion of fresh water resources. It is these concerns that prompted a vital need within the industry for the development of Best Management Practices (BMPs) and mitigation strategies utilizing GIS technologies for efficient environmental protection in conjunction with effective production of CBM. This was accomplished by developing a framework to take advantage of a combination of investigative field research joined with leading edge GIS technologies for the creation of environmentally characterized regions of study. Once evaluated these regions had BMP's developed to address their unique situations for Coal Bed Methane production and environmental protection. Results of the project will be used to support the MBOGC's Programmatic Environmental Impact Statement as required by the Montana Environmental Policy Act (MEPA) and by the BLM for NEPA related issues for acreage having federally owned minerals.

J. Daniel Arthur

2003-04-01T23:59:59.000Z

332

Coalbed methane potential assessed in Forest City basin  

SciTech Connect (OSTI)

This paper reports that the Forest City basin is a shallow cratonic depression located in northeastern Kansas, southeastern Nebraska, southern Iowa and northern Missouri. Historically, the Forest City basin in northeastern Kansas has been a shallow oil and gas province with minor coal production. The Iowa and Missouri portion has had minor oil production and moderate coal mining. In recent years there has been little coal mining in the Forest City in Iowa and Kansas and only minor production in Missouri. Before 1940, gas was produced from coal beds and shales in the Kansas portion of the Forest City basin. The Cherokee group (Altokan and Desmoinesian age) includes section containing the largest number of actively mined coals and has the greatest available data for coalbed methane evaluation.

Tedesco, S.A. (CST Oil and Gas Corp., Denver, CO (US))

1992-02-10T23:59:59.000Z

333

Department of Energy Advance Methane Hydrates Science and Technology Projects  

Broader source: Energy.gov [DOE]

Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

334

MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE  

E-Print Network [OSTI]

University, School of Engineering, Ocean .. Engineel'ing-and nutrition, ocean engineering and methane generation. In

Haven, Kendall F.

2011-01-01T23:59:59.000Z

335

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE Full-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY ALLENE OR PROPYNE * E investigated: a pure methane flame and two methane flames doped by allene and propyne, respectively. The gases

Paris-Sud XI, Université de

336

Anaerobic Methane Oxidation in a Landfill-Leachate Plume  

E-Print Network [OSTI]

Anaerobic Methane Oxidation in a Landfill-Leachate Plume E T H A N L . G R O S S M A N , * , L U I, and methane, and (2) negligible oxygen, nitrate, and sulfate concentrations. Methane concentrations and stable carbon isotope (13C) values suggest anaerobic methane oxidation was occurring within the plume and at its

Grossman, Ethan L.

337

I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204  

E-Print Network [OSTI]

in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

Fehn, Udo

338

A car-borne highly sensitive near-IR diode-laser methane detector  

SciTech Connect (OSTI)

A highly sensitive automated car-borne detector for measuring methane concentration in real time is designed, developed and tested under laboratory and field conditions. Measurements were made with the help of an uncooled tunable near-IR 1.65-{mu}m laser diode. The detector consists of a multipass optical cell with a 45-m long optical path and a base length of 0.5 m. The car-borne detector is intended for monitoring the methane concentration in air from the moving car to reveal the leakage of domestic gas. The sensitivity limit (standard deviation) under field conditions is 1 ppm (20 ppb under laboratory conditions) for a measuring time of 0.4 s. The measuring technique based on the detection of a single methane line ensured a high selectivity of methane detector relative to other gases. The methane detector can be easily modified for measuring other simple-molecule gases (e.g., CO, CO{sub 2}, HF, NO{sub 2}, H{sub 2}O) by replacing the diode laser and varying the parameters of the control program. (special issue devoted to the memory of academician a m prokhorov)

Berezin, A G; Ershov, Oleg V; Shapovalov, Yu P [Natural Science Center, A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

2003-08-31T23:59:59.000Z

339

Water management technologies used by Marcellus Shale Gas Producers.  

SciTech Connect (OSTI)

Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

Veil, J. A.; Environmental Science Division

2010-07-30T23:59:59.000Z

340

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet at Supercritical Pressures  

E-Print Network [OSTI]

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet in laminar jet flames of methane at elevated pressures in a high-pressure combustion chamber, we have MPa, after the laminar methane jet flame had been stabilized on a co-flow circular nozzle-type burner

G√ľlder, √?mer L.

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Gas separation with oligomer-modified inorganic membranes  

E-Print Network [OSTI]

-based separation are presented. Alumina membranes with average pore sizes near 5 nm and 10 run were treated with various n-alkyl trichlorosilanes. Pure gas permeation studies using nitrogen, methane, and propane were performed to investigate the effects...

Javaid, Asad

1999-01-01T23:59:59.000Z

342

Hydraulic fracturing accelerates coalbed methane recovery  

SciTech Connect (OSTI)

Methane production from deep coal seams that never will be mined requires hydraulic fracturing for faster, optimal recovery. Since this can be a complex process, proper formation evaluation beforehand is essential, according to this paper.

Holditch, S.A. (Texas A and M Univ. (US)); Ely, J.W.; Semmelbeck, M.E.; Carter, R.H. (S.A. Holditch and Associates (US)); Hinkel, J.J.; Jeffrey, R.G. Jr. (Dowell Schlumberger (US))

1990-11-01T23:59:59.000Z

343

The role of methane in tropospheric chemistry  

E-Print Network [OSTI]

While methane is chemically quite inert to reactions with atmospheric molecular species, it does react with atomic species and molecular radicals. Because of its relatively large abundance in the global troposphere and ...

Golomb, D.

1989-01-01T23:59:59.000Z

344

Virginia Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

345

Oklahoma Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

346

Pennsylvania Coalbed Methane Proved Reserves Revision Decreases...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

347

Virginia Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

348

Arkansas Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

349

Colorado Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

350

Pennsylvania Coalbed Methane Proved Reserves Revision Increases...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

351

Virginia Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

352

Colorado Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

353

Oklahoma Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

354

Montana Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Montana Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

355

Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

356

Wyoming Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

357

Arkansas Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

358

Oklahoma Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

359

Miscellaneous States Coalbed Methane Proved Reserves Adjustments...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Miscellaneous States Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

360

Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Extensions (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

362

Colorado Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

363

Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

364

Colorado Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

365

Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Acquisitions (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

366

Colorado Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Colorado Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

367

Arkansas Coalbed Methane Proved Reserves Revision Decreases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Decreases (Billion Cubic Feet) Arkansas Coalbed Methane Proved Reserves Revision Decreases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

368

Virginia Coalbed Methane Proved Reserves Revision Increases ...  

U.S. Energy Information Administration (EIA) Indexed Site

Increases (Billion Cubic Feet) Virginia Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

369

Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Adjustments (Billion Cubic Feet) Pennsylvania Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

370

Transient Supersonic Methane-Air Flames  

E-Print Network [OSTI]

The purpose of this study was to investigate the thermochemical properties of a transient supersonic flame. Creation of the transient flame was controlled by pulsing air in 200 millisecond intervals into a combustor filled with flowing methane...

Richards, John L.

2012-07-16T23:59:59.000Z

371

Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production  

E-Print Network [OSTI]

Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THEEVEN BEYOND MANURE-ASSOCIATED METHANE EMISSIONS, INDUSTRIAL

Di Camillo, Nicole G.

2011-01-01T23:59:59.000Z

372

Marine methane cycle simulations for the period of early global warming  

E-Print Network [OSTI]

aspects of atmospheric methane, Global Biogeochem. Cycles 2,Budeus, Fate of vent derived methane in seawater above theHanfland, Pathways of methane in seawater: Plume spreading

Elliott, S.

2011-01-01T23:59:59.000Z

373

Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane  

E-Print Network [OSTI]

Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

Green, Michael A.

2005-01-01T23:59:59.000Z

374

Identification of a novel CoA synthase isoform, which is primarily expressed in Brain  

SciTech Connect (OSTI)

CoA and its derivatives Acetyl-CoA and Acyl-CoA are important players in cellular metabolism and signal transduction. CoA synthase is a bifunctional enzyme which mediates the final stages of CoA biosynthesis. In previous studies, we have reported molecular cloning, biochemical characterization, and subcellular localization of CoA synthase (CoASy). Here, we describe the existence of a novel CoA synthase isoform, which is the product of alternative splicing and possesses a 29aa extension at the N-terminus. We termed it CoASy {beta} and originally identified CoA synthase, CoASy {alpha}. The transcript specific for CoASy {beta} was identified by electronic screening and by RT-PCR analysis of various rat tissues. The existence of this novel isoform was further confirmed by immunoblot analysis with antibodies directed to the N-terminal peptide of CoASy {beta}. In contrast to CoASy {alpha}, which shows ubiquitous expression, CoASy {beta} is primarily expressed in Brain. Using confocal microscopy, we demonstrated that both isoforms are localized on mitochondria. The N-terminal extension does not affect the activity of CoA synthase, but possesses a proline-rich sequence which can bring the enzyme into complexes with signalling proteins containing SH3 or WW domains. The role of this novel isoform in CoA biosynthesis, especially in Brain, requires further elucidation.

Nemazanyy, Ivan [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine)]. E-mail: nemazanyy@imbg.org.ua; Panasyuk, Ganna [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine); Breus, Oksana [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine); Zhyvoloup, Alexander [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine); Filonenko, Valeriy [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine); Gout, Ivan T. [Department of Structure and Function of Nucleic Acids, Institute of Molecular Biology and Genetics, 150 Zabolotnogo St, Kyiv 03680 (Ukraine) and Department of Biochemistry and Molecular Biology, Royal Free and University College Medical School, Gower Street, London WC1E 6BT (United Kingdom)]. E-mail: i.gout@ucl.ac.uk

2006-03-24T23:59:59.000Z

375

Feasibility study: utilization of landfill gas for a vehicle fuel system, Rossman's landfill, Clackamas County, Oregon  

SciTech Connect (OSTI)

In 1978, a landfill operator in Oregon became interested in the technical and economic feasibility of recovering the methane generated in the landfill for the refueling of vehicles. DOE awarded a grant for a site-specific feasibility study of this concept. This study investigated the expected methane yield and the development of a conceptual gas-gathering system; gas processing, compressing, and storage systems; and methane-fueled vehicle systems. Cost estimates were made for each area of study. The results of the study are presented. Reasoning that gasoline prices will continue to rise and that approximately 18,000 vehicles in the US have been converted to operate on methane, a project is proposed to use this landfill as a demonstration site to produce and process methane and to fuel a fleet (50 to 400) vehicles with the gas produced in order to obtain performance and economic data on the systems used from gas collection through vehicle operation. (LCL)

None

1981-01-01T23:59:59.000Z

376

Cryogenic treatment of gas  

DOE Patents [OSTI]

Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

2012-04-03T23:59:59.000Z

377

Oil & Natural Gas Technology DOE Award No.: FWP 49462  

E-Print Network [OSTI]

increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have produce enough natural gas from shale formations to make the wells economically viable. Because

Boyer, Elizabeth W.

378

Mid-infrared gas sensing using a photonic bandgap fiber  

E-Print Network [OSTI]

. The gas filling process of the air core is described, and qualitative methane concentrations measurements. Introduction Sensing of gas species and their concentrations is widely used for process control [1-proven technique requires a spectrometer and a sensing volume (gas cell) in which the light can interact

379

The Performance of Fractured Horizontal Well in Tight Gas Reservoir  

E-Print Network [OSTI]

?, including tight gas, gas/oil shale, oil sands, and coal-bed methane. North America has a substantial growth in its unconventional oil and gas market over the last two decades. The primary reason for that growth is because North America, being a mature...

Lin, Jiajing

2012-02-14T23:59:59.000Z

380

GEOLOGIC SCREENING CRITERIA FOR SEQUESTRATION OF CO2 IN COAL: QUANTIFYING POTENTIAL OF THE BLACK WARRIOR COALBED METHANE FAIRWAY, ALABAMA  

SciTech Connect (OSTI)

Sequestration of CO{sub 2} in coal has potential benefits for reducing greenhouse gas emissions from the highly industrialized Carboniferous coal basins of North America and Europe and for enhancing coalbed methane recovery. Hence, enhanced coalbed methane recovery operations provide a basis for a market-based environmental solution in which the cost of sequestration is offset by the production and sale of natural gas. The Black Warrior foreland basin of west-central Alabama contains the only mature coalbed methane production fairway in eastern North America, and data from this basin provide an excellent basis for quantifying the carbon sequestration potential of coal and for identifying the geologic screening criteria required to select sites for the demonstration and commercialization of carbon sequestration technology. Coalbed methane reservoirs in the upper Pottsville Formation of the Black Warrior basin are extremely heterogeneous, and this heterogeneity must be considered to screen areas for the application of CO{sub 2} sequestration and enhanced coalbed methane recovery technology. Major screening factors include stratigraphy, geologic structure, geothermics, hydrogeology, coal quality, sorption capacity, technology, and infrastructure. Applying the screening model to the Black Warrior basin indicates that geologic structure, water chemistry, and the distribution of coal mines and reserves are the principal determinants of where CO{sub 2} can be sequestered. By comparison, coal thickness, temperature-pressure conditions, and coal quality are the key determinants of sequestration capacity and unswept coalbed methane resources. Results of this investigation indicate that the potential for CO{sub 2} sequestration and enhanced coalbed methane recovery in the Black Warrior basin is substantial and can result in significant reduction of greenhouse gas emissions while increasing natural gas reserves. Coal-fired power plants serving the Black Warrior basin in Alabama emit approximately 31 MMst (2.4 Tcf) of CO{sub 2} annually. The total sequestration capacity of the Black Warrior coalbed methane fairway at 350 psi is about 189 MMst (14.9 Tcf), which is equivalent to 6.1 years of greenhouse gas emissions from the coal-fired power plants. Applying the geologic screening model indicates that significant parts of the coalbed methane fairway are not accessible because of fault zones, coal mines, coal reserves, and formation water with TDS content less than 3,000 mg/L. Excluding these areas leaves a sequestration potential of 60 MMst (4.7 Tcf), which is equivalent to 1.9 years of emissions. Therefore, if about10 percent of the flue gas stream from nearby power plants is dedicated to enhanced coalbed methane recovery, a meaningful reduction of CO{sub 2} emissions can be realized for nearly two decades. If the fresh-water restriction were removed for the purposes of CO{sub 2} sequestration, an additional 10 MMst (0.9 Tcf) of CO{sub 2} could feasibly be sequestered. The amount of unswept coalbed methane in the fairway is estimated to be 1.49 Tcf at a pressure of 50 psi. Applying the screening model results in an accessible unswept gas resource of 0.44 Tcf. Removal of the fresh-water restriction would elevate this number to 0.57 Tcf. If a recovery factor of 80 percent can be realized, then enhanced recovery activities can result in an 18 percent expansion of coalbed methane reserves in the Black Warrior basin.

Jack C. Pashin; Richard E. Carroll; Richard H. Groshong Jr.; Dorothy E. Raymond; Marcella McIntyre; J. Wayne Payton

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Structure and Density of Mo and Acid Sites in Mo-Exchanged H-ZSM5 Catalysts for Nonoxidative Methane Conversion  

E-Print Network [OSTI]

of natural gas to higher hydrocar- bons and aromatics remains an important industrial challenge Methane Conversion Richard W. Borry III, Young Ho Kim, Anne Huffsmith, Jeffrey A. Reimer, and Enrique and gas phase transport, exchange at acid sites, and react to form H2O. The amount of H2O evolved during

Iglesia, Enrique

382

LANDFILL OPERATION FOR CARBON SEQUESTRATION AND MAXIMUM METHANE EMISSION CONTROL  

SciTech Connect (OSTI)

The work described in this report, to demonstrate and advance this technology, has used two demonstration-scale cells of size (8000 metric tons [tonnes]), sufficient to replicate many heat and compaction characteristics of larger ''full-scale'' landfills. An enhanced demonstration cell has received moisture supplementation to field capacity. This is the maximum moisture waste can hold while still limiting liquid drainage rate to minimal and safely manageable levels. The enhanced landfill module was compared to a parallel control landfill module receiving no moisture additions. Gas recovery has continued for a period of over 4 years. It is quite encouraging that the enhanced cell methane recovery has been close to 10-fold that experienced with conventional landfills. This is the highest methane recovery rate per unit waste, and thus progress toward stabilization, documented anywhere for such a large waste mass. This high recovery rate is attributed to moisture, and elevated temperature attained inexpensively during startup. Economic analyses performed under Phase I of this NETL contract indicate ''greenhouse cost effectiveness'' to be excellent. Other benefits include substantial waste volume loss (over 30%) which translates to extended landfill life. Other environmental benefits include rapidly improved quality and stabilization (lowered pollutant levels) in liquid leachate which drains from the waste.

Don Augenstein

2001-02-01T23:59:59.000Z

383

Variability of the methane trapping in martian subsurface clathrate hydrates  

E-Print Network [OSTI]

Recent observations have evidenced traces of methane CH4 heterogeneously distributed in the martian atmosphere. However, because the lifetime of CH4 in the atmosphere of Mars is estimated to be around 300-600 years on the basis of photochemistry, its release from a subsurface reservoir or an active primary source of methane have been invoked in the recent literature. Among the existing scenarios, it has been proposed that clathrate hydrates located in the near subsurface of Mars could be at the origin of the small quantities of the detected CH4. Here, we accurately determine the composition of these clathrate hydrates, as a function of temperature and gas phase composition, by using a hybrid statistical thermodynamic model based on experimental data. Compared to other recent works, our model allows us to calculate the composition of clathrate hydrates formed from a more plausible composition of the martian atmosphere by considering its main compounds, i.e. carbon dioxyde, nitrogen and argon, together with met...

Thomas, Caroline; Picaud, Sylvain; Ballenegger, Vincent

2008-01-01T23:59:59.000Z

384

Estimates of Biogenic Methane Production Rates in Deep Marine Sediments at Hydrate Ridge, Cascadia Margin  

SciTech Connect (OSTI)

Methane hydrate found in marine sediments is thought to contain gigaton quantities of methane and is considered an important potential fuel source and climate-forcing agent. Much of the methane in hydrates is biogenic, so models that predict the presence and distribution of hydrates require accurate rates of in situ methanogenesis. We estimated the in situ methanogenesis rates in Hydrate Ridge (HR) sediments by coupling experimentally derived minimal rates of methanogenesis to methanogen biomass determinations for discrete locations in the sediment column. When starved in a biomass recycle reactor Methanoculleus submarinus produced ca. 0.017 fmol methane/cell/day. Quantitative polymerase chain reaction (QPCR) directed at the methyl coenzyme M reductase subunit A (mcrA) gene indicated that 75% of the HR sediments analyzed contained <1000 methanogens/g. The highest methanogen numbers were mostly from sediments <10 meters below seafloor. By combining methanogenesis rates for starved methanogens (adjusted to account for in situ temperatures) and the numbers of methanogens at selected depths we derived an upper estimate of <4.25 fmol methane produced/g sediment/day for the samples with fewer methanogens than the QPCR method could detect. The actual rates could vary depending on the real number of methanogens and various seafloor parameters that influence microbial activity. However, our calculated rate is lower than rates previously reported from such sediments and close to the rate derived using geochemical modeling of the sediments. These data will help to improve models that predict microbial gas generation in marine sediments and determine the potential influence of this source of methane on the global carbon cycle.

F. S. Colwell; S. Boyd; M. E. Delwiche; D. W. Reed; T. J. Phelps; D. T. Newby

2008-06-01T23:59:59.000Z

385

Western cretaceous coal seam project formation evaluation of coalbed methane wells. Topical report, January 1988-December 1991  

SciTech Connect (OSTI)

Procedures are discussed for collecting and interpreting sufficient data required to estimate coalbed methane gas and water production rates. The procedures include the collection of core, drill stem test, and open hole log data during the drilling of exploration and early development wells. The significance and use of the data is illustrated.

Mavor, M.J.; Close, J.C.

1991-11-15T23:59:59.000Z

386

PROOF COPY [JES-11-1229R] 068110JES Comparison of Hydrogen and Methane as fuel in Micro-Tubular  

E-Print Network [OSTI]

for choosing methane is explained below. 23 The major external energy sources in Thailand are from coal and 24 of these particular cells with coal gas in Thailand. 41 At MTEC facility, the cell stack were tested in groups of 500, Columbia, South Carolina 29208, USA 5 b National Metal and Materials Technology Center, Thailand Science

Van Zee, John W.

387

GEOLOGIC SCREENING CRITERIA FOR SEQUESTRATION OF CO2 IN COAL: QUANTIFYING POTENTIAL OF THE BLACK WARRIOR COALBED METHANE FAIRWAY, ALABAMA  

SciTech Connect (OSTI)

Sequestration of CO{sub 2} in coal has potential to reduce greenhouse gas emissions from coal-fired power plants while enhancing coalbed methane recovery. Data from more than 4,000 coalbed methane wells in the Black Warrior basin of Alabama provide an opportunity to quantify the carbon sequestration potential of coal and to develop a geologic screening model for the application of carbon sequestration technology. This report summarizes stratigraphy and sedimentation, structural geology, geothermics, hydrology, coal quality, gas capacity, and production characteristics of coal in the Black Warrior coalbed methane fairway and the implications of geology for carbon sequestration and enhanced coalbed methane recovery. Coal in the Black Warrior basin is distributed among several fluvial-deltaic coal zones in the Lower Pennsylvanian Pottsville Formation. Most coal zones contain one to three coal beds that are significant targets for coalbed methane production and carbon sequestration, and net coal thickness generally increases southeastward. Pottsville strata have effectively no matrix permeability to water, so virtually all flow is through natural fractures. Faults and folds influence the abundance and openness of fractures and, hence, the performance of coalbed methane wells. Water chemistry in the Pottsville Formation ranges from fresh to saline, and zones with TDS content lower than 10,000 mg/L can be classified as USDW. An aquifer exemption facilitating enhanced recovery in USDW can be obtained where TDS content is higher than 3,000 mg/L. Carbon dioxide becomes a supercritical fluid above a temperature of 88 F and a pressure of 1,074 psi. Reservoir temperature exceeds 88 F in much of the study area. Hydrostatic pressure gradients range from normal to extremely underpressured. A large area of underpressure is developed around closely spaced longwall coal mines, and areas of natural underpressure are distributed among the coalbed methane fields. The mobility and reactivity of supercritical CO{sub 2} in coal-bearing strata is unknown, and potential exists for supercritical conditions to develop below a depth of 2,480 feet following abandonment of the coalbed methane fields. High-pressure adsorption isotherms confirm that coal sorbs approximately twice as much CO{sub 2} as CH{sub 4} and approximately four times as much CO{sub 2} as N{sub 2}. Analysis of isotherm data reveals that the sorption performance of each gas can vary by a factor of two depending on rank and ash content. Gas content data exhibit extreme vertical and lateral variability that is the product of a complex burial history involving an early phase of thermogenic gas generation and an ongoing stage of late biogenic gas generation. Production characteristics of coalbed methane wells are helpful for identifying areas that are candidates for carbon sequestration and enhanced coalbed methane recovery. Many geologic and engineering factors, including well construction, well spacing, and regional structure influence well performance. Close fault spacing limits areas where five-spot patterns may be developed for enhanced gas recovery, but large structural panels lacking normal faults are in several gas fields and can be given priority as areas to demonstrate and commercialize carbon sequestration technology in coalbed methane reservoirs.

Jack C. Pashin; Richard E. Carroll; Richard H. Groshong, Jr.; Dorothy E. Raymond; Marcella McIntyre; J. Wayne Payton

2003-01-01T23:59:59.000Z

388

Evaluation of Phytoremediation of Coal Bed Methane Product Water and Waters of Quality Similar to that Associated with Coal Bed Methane Reserves of the Powder River Basin, Montana and Wyoming  

SciTech Connect (OSTI)

U.S. emphasis on domestic energy independence, along with advances in knowledge of vast biogenically sourced coalbed methane reserves at relatively shallow sub-surface depths with the Powder River Basin, has resulted in rapid expansion of the coalbed methane industry in Wyoming and Montana. Techniques have recently been developed which constitute relatively efficient drilling and methane gas recovery and extraction techniques. However, this relatively efficient recovery requires aggressive reduction of hydrostatic pressure within water-saturated coal formations where the methane is trapped. Water removed from the coal formation during pumping is typically moderately saline and sodium-bicarbonate rich, and managed as an industrial waste product. Current approaches to coalbed methane product water management include: surface spreading on rangeland landscapes, managed irrigation of agricultural crop lands, direct discharge to ephermeral channels, permitted discharge of treated and untreated water to perennial streams, evaporation, subsurface injection at either shallow or deep depths. A Department of Energy-National Energy Technology Laboratory funded research award involved the investigation and assessment of: (1) phytoremediation as a water management technique for waste water produced in association with coalbed methane gas extraction; (2) feasibility of commercial-scale, low-impact industrial water treatment technologies for the reduction of salinity and sodicity in coalbed methane gas extraction by-product water; and (3) interactions of coalbed methane extraction by-product water with landscapes, vegetation, and water resources of the Powder River Basin. Prospective, greenhouse studies of salt tolerance and water use potential of indigenous, riparian vegetation species in saline-sodic environments confirmed the hypothesis that species such as Prairie cordgrass, Baltic rush, American bulrush, and Nuttall's alkaligrass will thrive in saline-sodic environments when water supplies sourced from coalbed methane extraction are plentiful. Constructed wetlands, planted to native, salt tolerant species demonstrated potential to utilize substantial volumes of coalbed methane product water, although plant community transitions to mono-culture and limited diversity communities is a likely consequence over time. Additionally, selected, cultured forage quality barley varieties and native plant species such as Quail bush, 4-wing saltbush, and seaside barley are capable of sustainable, high quality livestock forage production, when irrigated with coalbed methane product water sourced from the Powder River Basin. A consequence of long-term plant water use which was enumerated is elevated salinity and sodicity concentrations within soil and shallow alluvial groundwater into which coalbed methane product water might drain. The most significant conclusion of these investigations was the understanding that phytoremediation is not a viable, effective technique for management of coalbed methane product water under the present circumstances of produced water within the Powder River Basin. Phytoremediation is likely an effective approach to sodium and salt removal from salt-impaired sites after product water discharges are discontinued and site reclamation is desired. Coalbed methane product water of the Powder River Basin is most frequently impaired with respect to beneficial use quality by elevated sodicity, a water quality constituent which can cause swelling, slaking, and dispersion of smectite-dominated clay soils, such as commonly occurring within the Powder River Basin. To address this issue, a commercial-scale fluid-bed, cationic resin exchange treatment process and prototype operating treatment plant was developed and beta-tested by Drake Water Technologies under subcontract to this award. Drake Water Technologies secured U.S. Patent No. 7,368,059-B2, 'Method for removal of benevolent cations from contaminated water', a beta Drake Process Unit (DPU) was developed and deployed for operation in the Powder River Basin. First year operatio

James Bauder

2008-09-30T23:59:59.000Z

389

E-Print Network 3.0 - active methane weather Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemistry 48 Universitt Stuttgart Auslandsorientierter Studiengang Summary: Potential of Coalbed Methane Recovery during Active Coalmin- ing... Methane Recovery from Active...

390

Remote Sensing and Sea-Truth Measurements of Methane Flux to the Atmosphere (HYFLUX project)  

SciTech Connect (OSTI)

A multi-disciplinary investigation of distribution and magnitude of methane fluxes from seafloor gas hydrate deposits in the Gulf of Mexico was conducted based on results obtained from satellite synthetic aperture radar (SAR) remote sensing and from sampling conducted during a research expedition to three sites where gas hydrate occurs (MC118, GC600, and GC185). Samples of sediments, water, and air were collected from the ship and from an ROV submersible using sediments cores, niskin bottles attached to the ROV and to a rosette, and an automated sea-air interface collector. The SAR images were used to quantify the magnitude and distribution of natural oil and gas seeps that produced perennial oil slicks on the ocean surface. A total of 176 SAR images were processed using a texture classifying neural network algorithm, which segmented the ocean surface into oil-free and oil-covered water. Geostatistical analysis indicates that there are a total of 1081 seep formations distributed over the entire Gulf of Mexico basin. Oil-covered water comprised an average of 780.0 sq. km (sd 86.03) distributed with an area of 147,370 sq. km. Persistent oil and gas seeps were also detected with SAR sampling on other ocean margins located in the Black Sea, western coast of Africa, and offshore Pakistan. Analysis of sediment cores from all three sites show profiles of sulfate, sulfide, calcium and alkalinity that indicated anaerobic oxidation of methane with precipitation of authigenic carbonates. Difference among the three sampling sites may reflect the relative magnitude of methane flux. Methane concentrations in water column samples collected by ROV and rosette deployments from MC118 ranged from {approx}33,000 nM at the seafloor to {approx}12 nM in the mixed layer with isolated peaks up to {approx}13,670 nM coincident with the top of the gas hydrate stability field. Average plume methane, ethane, and propane concentrations in the mixed layer are 7, 630, and 9,540 times saturation, respectively. Based on the contemporaneous wind speeds at this site, contemporary estimates of the diffusive fluxes from the mixed layer to the atmosphere for methane, ethane, and propane are 26.5, 2.10, and 2.78 {micro}mol/m{sup 2}d, respectively. Continuous measurements of air and sea surface concentrations of methane were made to obtain high spatial and temporal resolution of the diffusive net sea-to-air fluxes. The atmospheric methane fluctuated between 1.70 ppm and 2.40 ppm during the entire cruise except for high concentrations (up to 4.01 ppm) sampled during the end of the occupation of GC600 and the transit between GC600 and GC185. Results from interpolations within the survey areas show the daily methane fluxes to the atmosphere at the three sites range from 0.744 to 300 mol d-1. Considering that the majority of seeps in the GOM are deep (>500 m), elevated CH{sub 4} concentrations in near-surface waters resulting from bubble-mediated CH4 transport in the water column are expected to be widespread in the Gulf of Mexico.

Ian MacDonald

2011-05-31T23:59:59.000Z

391

Selective methane oxidation over promoted oxide catalysts. Quarterly report, March--May 1995  

SciTech Connect (OSTI)

The objective of this research is the selective oxidative coupling of methane to C{sub 2}H{sub 4} hydrocarbons and oxygenates, in particular formaldehyde and methanol. Air, oxygen or carbon dioxide, rather than nitrous oxide will be utilized as the oxidizing gas at high gas hourly space velocity, but mild reaction conditions (500-700 {degrees}C, 1 atm total pressure). All the investigated processes are catalytic, aiming at minimizing gas phase reactions that are difficult to control. The research is divided into the following three tasks: (1) maximizing selective methane oxidation to C{sub 2}H{sub 4} products over promoted Sr/La{sub 2}O{sub 3}; (2) selective methane oxidation to oxygenates; and (3) catalyst characterization and optimization. Task 1 dealt with the preparation, testing, and optimization of acidic promoted lanthana-based catalysts for the synthesis of C{sub 2}H{sub 4} hydrocarbons and is essentially completed. Task 2 aims at the formation and optimization of promoted catalysts for the synthesis of oxygenates, in particular formaldehyde and methanol. Task 3 involves characterization of the most promising catalysts so that optimization can be achieved under Task 2. Accomplishments for this period are presented.

Klier, K.; Herman, R.G.; Wang, Chaun-Bao; Shi, Chunlei; Sun, Qun

1995-08-01T23:59:59.000Z

392

Methane recovery from coalbeds project. Monthly progress report  

SciTech Connect (OSTI)

Progress made on the Methane Recovery from Coalbeds Project (MRCP) is reported in the Raton Mesa Coal Region. The Uinta and Warrior basin reports have been reviewed and will be published and delivered in early December. A cooperative core test with R and P Coal Company on a well in Indiana County, Pennsylvania, was negotiated. In a cooperative effort with the USGS Coal Branch on three wells in the Wind River Basin, desorption of coal samples showed little or no gas. Completed field testing at the Dugan Petroleum well in the San Juan Basin. Coal samples showed minimal gas. Initial desorption of coal samples suggests that at least a moderate amount of gas was obtained from the Coors well test in the Piceance Basin. Field work for the Piceance Basin Detailed Site Investigation was completed. In the Occidental Research Corporation (ORC) project, a higher capacity vacuum pump to increase CH/sub 4/ venting operations has been installed. Drilling of Oxy No. 12 experienced delays caused by mine gas-offs and was eventually terminated at 460 ft after an attempt to drill through a roll which produced a severe dog leg and severely damaged the drill pipe. ORC moved the second drill rig and equipment to a new location in the same panel as Oxy No. 12 and set the stand pipe for Oxy No. 13. Drill rig No. 1 has been moved east of the longwall mining area in anticipation of drilling cross-panel on 500 foot intervals. Waynesburg College project, Equitable Gas Company has received the contract from Waynesburg College and has applied to the Pennsylvania Public Utilities Commission for a new tariff rate. Waynesburg College has identified a contractor to make the piping connections to the gas line after Equitable establishes their meter and valve requirements.

Not Available

1980-11-01T23:59:59.000Z

393

Coalbed-methane pilots - timing, design, and analysis  

SciTech Connect (OSTI)

Four distinct sequential phases form a recommended process for coalbed-methane (CBM)-prospect assessment: initial screening reconnaissance, pilot testing, and final appraisal. Stepping through these four phases provides a program of progressively ramping work and cost, while creating a series of discrete decision points at which analysis of results and risks can be assessed. While discussing each of these phases in some degree, this paper focuses on the third, the critically important pilot-testing phase. This paper contains roughly 30 specific recommendations and the fundamental rationale behind each recommendation to help ensure that a CBM pilot will fulfill its primary objectives of (1) demonstrating whether the subject coal reservoir will desorb and produce consequential gas and (2) gathering the data critical to evaluate and risk the prospect at the next-often most critical-decision point.

Roadifer, R.D.; Moore, T.R.

2009-10-15T23:59:59.000Z

394

Coal companies hope to receive carbon credits for methane reductions  

SciTech Connect (OSTI)

Each year, underground coal mining in the USA liberates 2.4 million tonnes of coal mine methane (CMM), of which less than 30% is recovered and used. One barrier to CMM recovery is cost. Drainage, collection, and utilization systems are complex and expensive to install. Two coal mines have improved the cost equation, however, by signing on to earn money for CMM emissions they are keeping out of the atmosphere. Jim Walter Resources and PinnOak Resources have joined a voluntary greenhouse gas reduction trading program called the Chicago Climate Exchange (CCX) to turn their avoided emissions into carbon credits. The example they set may encourage other coal mining companies to follow suit, and may bring new projects on the line that would otherwise have not gone forward. 2 refs., 1 fig.

NONE

2007-09-30T23:59:59.000Z

395

New thermodynamic diagrams developed for methane and ethane  

SciTech Connect (OSTI)

Thermodynamic diagrams have been developed for methane and ethane. The diagrams determine volume and enthalpy as a function of pressure and temperature. The diagrams cover a wide range of conditions and are designed for ease of use. The enthalpy diagrams also contain constant-entropy lines, which allow engineers to solve second-law problems such as adiabatic expansion and fluid compression. Each diagram includes: a two-phase region for saturated liquid and vapor; a superheated gas region for gases at temperatures above the saturation temperature; a subcooled liquid region for liquids at temperatures below the saturation temperature; and a supercritical region for temperatures and pressures above the critical point. Representative engineering uses are illustrated in three examples.

Yaws, C.L.; Sheth, S.D.; Han, M. [Lamar Univ., Beaumont, TX (United States)

1995-12-04T23:59:59.000Z

396

Natural Gas Infrastructure R&D and Methane Emissions Mitigation...  

Office of Environmental Management (EM)

Agenda Participant List Christopher Freitas, U.S. DOE, Office of Fossil Energy Robert Smith, U.S. DOT, Pipeline and Hazardous Materials Safety Administration Michael Whelan,...

397

Other States Natural Gas Coalbed Methane, Reserves Based Production  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30 2013 Macroeconomicper ThousandResidentialElements)

398

Methane storage in advanced porous materials | Center for Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries & Fuel Cells InDioxide Capture

399

Gas hydrates in the Gulf of Mexico  

E-Print Network [OSTI]

filled by one or more gases. In marine sediments gas hydrates are found in regions where high pressure, low temperature and gas in excess of solubility are present. Low molecular weight hydrocarbons (LMWH), I. e. methane through butane, carbon dioxide... loop at a helium carrier flow of 12 ml/min with an elution order of methane, ethane, carbon dioxide and propane. Each fraction was trapped in a U- shaped Porpak-Q filled glass tube immersed in LN2. Butanes and heartier weight gases were trapped...

Cox, Henry Benjamin

1986-01-01T23:59:59.000Z

400

Utah coalbed gas exploration poised for growth  

SciTech Connect (OSTI)

Coalbed methane production in eastern Utah is growing despite a relaxed pace of exploratory drilling. Leasing has been active the past 2 years, but a delay in issuance of a federal environmental impact statement could retard drilling. Only 19 new wells began producing coalbed gas during 1995, but gas production increased from existing wells as dewatering progressed. The US Bureau of Land Management will allow limited exploration but no field development on federal lands until the EIS is completed, possibly as early as this month. The paper discusses production of coalbed methane in Utah.

Petzet, G.A.

1996-08-05T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Numerical modeling of methane venting from lake sediments  

E-Print Network [OSTI]

The dynamics of methane transport in lake sediments control the release of methane into the water column above, and the portion that reaches the atmosphere may contribute significantly to the greenhouse effect. The observed ...

Scandella, Benjamin P. (Benjamin Paul)

2010-01-01T23:59:59.000Z

402

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network [OSTI]

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

403

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

404

Diurnal variations in methane emission from rice plants  

E-Print Network [OSTI]

A greenhouse study was conducted to investigate the mechanisms causing diurnal variations in methane emission from rice plants (Oryza sativa L.). Methane emission was measured using a closed chamber system on individual rice plants at five stages...

Laskowski, Nicholas Aaron

2004-11-15T23:59:59.000Z

405

Gasification Evaluation of Gas Turbine Combustion  

SciTech Connect (OSTI)

This report provides a preliminary assessment of the potential for use in gas turbines and reciprocating gas engines of gases derived from biomass by pyrolysis or partial oxidation with air. Consideration was given to the use of mixtures of these gases with natural gas as a means of improving heating value and ensuring a steady gas supply. Gas from biomass, and mixtures with natural gas, were compared with natural gas reformates from low temperature partial oxidation or steam reforming. The properties of such reformates were based on computations of gas properties using the ChemCAD computational tools and energy inputs derived from known engine parameters. In general, the biomass derived fuels compare well with reformates, so far as can be judged without engine testing. Mild reforming has potential to produce a more uniform quality of fuel gas from very variable qualities of natural gas, and could possibly be applied to gas from biomass to eliminate organic gases and condensibles other than methane.

Battelle

2003-12-30T23:59:59.000Z

406

Direct use of methane in coal liquefaction  

DOE Patents [OSTI]

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.

Sundaram, Muthu S. (Shoreham, NY); Steinberg, Meyer (Melville, NY)

1987-01-01T23:59:59.000Z

407

Direct use of methane in coal liquefaction  

DOE Patents [OSTI]

This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20 to 120 minutes at a temperature of 250 to 750/sup 0/C, preferably 350 to 450/sup 0/C, pressurized up to 6000 psi, and preferably in the 1000 to 2500 psi range, preferably directly utilizing methane 50 to 100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0 to 100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems. 1 fig.

Sundaram, M.S.; Steinberg, M.

1985-06-19T23:59:59.000Z

408

Marine methane cycle simulations for the period of early global warming  

SciTech Connect (OSTI)

Geochemical environments, fates, and effects are modeled for methane released into seawater by the decomposition of climate-sensitive clathrates. A contemporary global background cycle is first constructed, within the framework of the Parallel Ocean Program. Input from organics in the upper thermocline is related to oxygen levels, and microbial consumption is parameterized from available rate measurements. Seepage into bottom layers is then superimposed, representing typical seabed fluid flow. The resulting CH{sub 4} distribution is validated against surface saturation ratios, vertical sections, and slope plume studies. Injections of clathrate-derived methane are explored by distributing a small number of point sources around the Arctic continental shelf, where stocks are extensive and susceptible to instability during the first few decades of global warming. Isolated bottom cells are assigned dissolved gas fluxes from porous-media simulation. Given the present bulk removal pattern, methane does not penetrate far from emission sites. Accumulated effects, however, spread to the regional scale following the modeled current system. Both hypoxification and acidification are documented. Sensitivity studies illustrate a potential for material restrictions to broaden the perturbations, since methanotrophic consumers require nutrients and trace metals. When such factors are considered, methane buildup within the Arctic basin is enhanced. However, freshened polar surface waters act as a barrier to atmospheric transfer, diverting products into the deep return flow. Uncertainties in the logic and calculations are enumerated including those inherent in high-latitude clathrate abundance, buoyant effluent rise through the column, representation of the general circulation, and bacterial growth kinetics.

Elliott, S.; Maltrud, M.; Reagan, M.T.; Moridis, G.J.; Cameron-Smith, P.J.

2011-01-02T23:59:59.000Z

409

Gravimetric study of adsorbed intermediates in methanation of carbon monoxide  

SciTech Connect (OSTI)

The purpose of this study is to more fully elucidate the adsorbed intermediates and mechanism involved in catalytic methanation of CO on a typical nickel methanation catalyst. Rates of adsorption and desorption of surface species and of gasification of carbon were measured gravimetrically to determine their kinetics and possible roles in methanation. 19 refs.

Gardner, D.C.; Bartholomew, C.H.

1981-08-01T23:59:59.000Z

410

METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES  

E-Print Network [OSTI]

advanced models of adsorption occuring in coalbed methane recovery processes, and discuss the underlying methods, hysteresis, coalbed methane, mean-field equi- librium models AMS(MOS) subject classifications. 76 applications important for global climate and energy studies, namely Enhanced Coalbed Methane (ECBM) recovery

Peszynska, Malgorzata

411

An improved third order dipole moment surface for methane  

E-Print Network [OSTI]

An improved third order dipole moment surface for methane P. Cassam-Chena¨i Laboratoire J and used to calculate the rotational spectrum of methane vibrational ground state, by means. Keywords: Dipole moment surface; methane; generalized mean field configuration interaction. Suggested

Paris-Sud XI, Université de

412

ESTIMATING METHANE EMISSION AND OXIDATION FROM TWO TEMPORARY  

E-Print Network [OSTI]

ESTIMATING METHANE EMISSION AND OXIDATION FROM TWO TEMPORARY COVERS ON LANDFILLED MBT TREATED WASTE to oxidize the methane flux coming from the residual organic fraction. The first plant was operated without recovery of organic fraction and with concentration of the fine fraction in a cell. The methane fluxes were

Paris-Sud XI, Université de

413

PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW  

E-Print Network [OSTI]

1 PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW F.K. Lu,* C.M. Roseberry, J.M. Meyers and D arc pyrolysis of methane at supersonic conditions, representative of conditions in the reformer- cate the feasibility of arc pyrolysis of methane. Introduction he high specific enthalpy of combustion

Texas at Arlington, University of

414

Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands  

E-Print Network [OSTI]

Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands Jason M. Gonzales, Jonas, California 90089 ReceiVed July 31, 2006 Trends in methane activation have been explored for rhenium complexes proceeds with methane activation through a barrier of less than 35 kcal mol-1 . Study

Goddard III, William A.

415

Extreme Methane Emissions from a Swiss Hydropower Reservoir  

E-Print Network [OSTI]

Extreme Methane Emissions from a Swiss Hydropower Reservoir: Contribution from Bubbling Sediments manuscript received February 3, 2010. Accepted February 15, 2010. Methane emission pathways.Methanediffusionfromthesediment was generally low and seasonally stable and did not account for the high concentration of dissolved methane

Wehrli, Bernhard

416

Carbon and Hydrogen Isotopic Effects in Microbial Methane  

E-Print Network [OSTI]

6 Carbon and Hydrogen Isotopic Effects in Microbial Methane from Terrestrial Environments Jeffrey Chanton, Lia Chaser, Paul Glasser,Don Siegel Methane is the ultimate end-product of anaerobic respiration. Methane production via CO2 reduction does not consume CO2. Also, acetate can be written as 2CH20, so Eq. 6

Saleska, Scott

417

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART III: CYCLOPENTENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY CYCLOPENTENE * E-mail : pierre with the studies presented in the parts I and II of this paper, the structure of a laminar rich premixed methane

Paris-Sud XI, Université de

418

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic  

E-Print Network [OSTI]

The Tri--methane Rearrangement: Mechanistic and Exploratory Organic Photochemistry1 Howard E zimmerman@bert.chem.wisc.edu Received May 31, 2000 ABSTRACT The di--methane rearrangement is firmly established as a mode of synthesizing three-membered-ring compounds. We now report the tri-- methane

Cirkva, Vladimir

419

METHANE SOURCES AND SINKS IN UPPER OCEAN WATERS  

E-Print Network [OSTI]

METHANE SOURCES AND SINKS IN UPPER OCEAN WATERS A DISSERTATION SUBMITTED TO THE GRADUATE DIVISION the distribution of dissolved methane in ocean surface waters were investigated. Water column and sediment trap and Antarctic waters to the oliogotrophic ocean off Hawaii. The methane concentrations in most of the surface

Luther, Douglas S.

420

Dissociation of methane under high pressure Guoying Gao,1,a  

E-Print Network [OSTI]

Dissociation of methane under high pressure Guoying Gao,1,a Artem R. Oganov,2,a Yanming Ma,1,b Hui Received 15 May 2010; accepted 18 August 2010; published online 12 October 2010 Methane is an extremely of methane under extreme conditions are of great fundamental interest. Using the ab initio evolutionary

Oganov, Artem R.

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Tropical methane emissions: A revised view from SCIAMACHY onboard ENVISAT  

E-Print Network [OSTI]

Tropical methane emissions: A revised view from SCIAMACHY onboard ENVISAT Christian Frankenberg,1; accepted 26 June 2008; published 12 August 2008. [1] Methane retrievals from near-infrared spectra recorded spectroscopic parameters, causing a substantial overestimation of methane correlated with high water vapor

Haak, Hein

422

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS  

E-Print Network [OSTI]

RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART II: 1,3-BUTADIENE-length article SHORTENED RUNNING TITLE : METHANE FLAMES DOPED BY 1,3-BUTADIENE * E-mail : Pierre of this paper, the structure of a laminar rich premixed methane flame doped with 1,3-butadiene has been

Paris-Sud XI, Université de

423

Introduction In the past two centuries, atmospheric methane  

E-Print Network [OSTI]

90 Introduction In the past two centuries, atmospheric methane (Ch4) concentrations have more than doubled. Despite the about 20o times smaller atmospheric burden of methane compared to carbon dioxide (CO2 ; IPCC 4th assessment report, 2007), because on a per molecule basis methane is a much more effective

Haak, Hein

424

Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the  

E-Print Network [OSTI]

Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the atmosphere. o Accounts for 20% of methane emissions from human sources. Globally cattle produce about 80 million metric tons of methane annually. o Accounts for 28% of global methane emissions

Toohey, Darin W.

425

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry  

E-Print Network [OSTI]

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep heterogeneity. In particular, biogeochemical fluxes of volatiles such as methane remain largely unconstrained

Girguis, Peter R.

426

Life-cycle analysis of shale gas and natural gas.  

SciTech Connect (OSTI)

The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M. (Energy Systems); ( EVS)

2012-01-27T23:59:59.000Z

427

IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION  

SciTech Connect (OSTI)

The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

2005-04-01T23:59:59.000Z

428

High Temperature Solar Splitting of Methane  

E-Print Network [OSTI]

-term commercialization opportunities #12;Why Use Solar Energy?Why Use Solar Energy? · High concentrations possible (>1000High Temperature Solar Splitting of Methane to Hydrogen and Carbon High Temperature Solar Splitting and worldwide) ­ Sufficient to power the world (if we choose to) · Advantages tradeoff against collection area

429

Methane production from ozonated pulp mill effluent  

SciTech Connect (OSTI)

A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

1980-07-01T23:59:59.000Z

430

Methane present in an extrasolar planet atmosphere  

E-Print Network [OSTI]

Molecules present in exoplanetary atmospheres are expected to strongly influence the atmospheric radiation balance, trace dynamical and chemical processes, and indicate the presence of disequilibrium effects. Since molecules have the potential to reveal the exoplanet atmospheric conditions and chemistry, searching for them is a high priority. The rotational-vibrational transition bands of water, carbon monoxide, and methane are anticipated to be the primary sources of non-continuum opacity in hot-Jovian planets. Since these bands overlap in wavelength, and the corresponding signatures from them are weak, decisive identification requires precision infrared spectroscopy. Here we report on a near-infrared transmission spectrum of the planet HD 189733b showing the presence of methane. Additionally, a resolved water-vapour band at 1.9 microns confirms the recent claim of water in this object. On thermochemical grounds, carbon-monoxide is expected to be abundant in the upper atmosphere of hot-Jovian exoplanets; thus the detection of methane rather than carbon-monoxide in such a hot planet could signal the presence of a horizontal chemical gradient away from the permanent dayside, or it may imply an ill-understood photochemical mechanisms that leads to an enhancement of methane.

Mark R. Swain; Gautam Vasisht; Giovanna Tinetti

2008-02-07T23:59:59.000Z

431

Powder River Basin coalbed methane: The USGS role in investigating this ultimate clean coal by-product  

SciTech Connect (OSTI)

For the past few decades, the Fort Union Formation in the Powder River Basin has supplied the Nation with comparatively clean low ash and low sulfur coal. However, within the past few years, coalbed methane from the same Fort Union coal has become an important energy by-product. The recently completed US Geological Survey coal resource assessment of the Fort Union coal beds and zones in the northern Rocky Mountains and Great Plains (Fort Union Coal Assessment Team, 1999) has added useful information to coalbed methane exploration and development in the Powder River Basin in Wyoming and Montana. Coalbed methane exploration and development in the Powder River Basin has rapidly accelerated in the past three years. During this time more than 800 wells have been drilled and recent operator forecasts projected more than 5,000 additional wells to be drilled over the next few years. Development of shallow (less than 1,000 ft. deep) Fort Union coal-bed methane is confined to Campbell and Sheridan Counties, Wyoming, and Big Horn County, Montana. The purpose of this paper is to report on the US Geological Survey's role on a cooperative coalbed methane project with the US Bureau of Land Management (BLM), Wyoming Reservoir Management Group and several gas operators. This paper will also discuss the methodology that the USGS and the BLM will be utilizing for analysis and evaluation of coalbed methane reservoirs in the Powder River Basin. The USGS and BLM need additional information of coalbed methane reservoirs to accomplish their respective resource evaluation and management missions.

Stricker, G.D.; Flores, R.M.; Ochs, A.M.; Stanton, R.W.

2000-07-01T23:59:59.000Z

432

Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process  

DOE Patents [OSTI]

In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

DeGeorge, Charles W. (Chester, NJ)

1981-01-01T23:59:59.000Z

433

SAES ST 909 PILOT SCALE METHANE CRACKING TESTS  

SciTech Connect (OSTI)

Pilot scale (500 gram) SAES St 909 methane cracking tests were conducted to determine material performance for tritium process applications. Tests that ran up to 1400 hours have been performed at 700 C, 202.7 kPa (1520 torr) with a 30 sccm feed of methane, with various impurities, in a 20 vol% hydrogen, balance helium, stream. A 2.5 vol% methane feed was reduced below 30 ppm for 631 hours. A feed of 1.1 vol% methane plus 1.4 vol% carbon dioxide was reduced below 30 ppm for 513 hours. The amount of carbon dioxide gettered by St 909 can be equated to an equivalent amount of methane gettered to estimate a reduced bed life for methane cracking. The effect of 0.4 vol % and 2.1 vol% nitrogen in the feed reduced the time to exceed 30 ppm methane to 362 and 45 hours, respectively, but the nitrogen equivalence to reduced methane gettering capacity was found to be dependent on the nitrogen feed composition. Decreased hydrogen concentrations increased methane getter rates while a drop of 30 C in one bed zone increased methane emissions by over a factor of 30. The impact of gettered nitrogen can be somewhat minimized if the nitrogen feed to the bed has been stopped and sufficient time given to recover the methane cracking rate.

Klein, J; Henry Sessions, H

2007-07-02T23:59:59.000Z

434

Review of Novel Catalysts for Biomass Tar Cracking and Methane Reforming  

SciTech Connect (OSTI)

A review of the literature was conducted to examine the performance of catalysts other than conventional nickel catalysts, and alkaline earth and olivine based catalysts for treating hot raw product gas from a biomass gasifier to convert methane and tars into synthesis gas. Metal catalysts other than Ni included precious metals Rh, Ru, Ir, Pt, and Pd, as well as Cu, Co, and Fe in limited testing. Nickel catalysts promoted with Rh, Zr, Mn, Mo, Ti, Ag, or Sn were also examined, as were Ni catalysts on Ce2O3, TiO2, ZrO2, SiO2, and La2O3. In general, Rh stood out as a consistently superior metal catalyst for methane reforming, tar cracking, and minimizing carbon buildup on the catalyst. Ru and Ir also showed significant improvement over Ni for methane reforming. Ceria stood out as good support material and particularly good promoter material when added in small quantities to another support material such as alumina, zirconia, or olivine. Other promising supports were lanthana, zirconia, and titania.

Gerber, Mark A.

2007-10-10T23:59:59.000Z

435

Geologic and hydrologic controls on coalbed methane producibility, Williams Fork Formation, Piceance Basin, Colorado  

SciTech Connect (OSTI)

Structural and depositional setting, coal rank, gas content, permeability, hydrodynamics, and reservoir heterogeneity control the producibility of coalbed methane in the Piceance Basin. The coal-rich Upper Cretaceous, Williams Fork Formation is genetically defined and regionally correlated to the genetic sequences in the Sand Wash Basin, to the north. Net coal is thickest in north-south oriented belts which accumulated on a coastal plain, behind west-east prograding shoreline sequences. Face cleats of Late Cretaceous age strike E-NE and W-NW in the southern and northern parts of the basin, respectively, normal to the Grand Hogback thrust front. Parallelism between face-cleat strike and present-day maximum horizontal stresses may enhance or inhibit coal permeability in the north and south, respectively. Geopressure and hydropressure are both present in the basin with regional hydrocarbon overpressure dominant in the central part of the basin and hydropressure limited to the basin margins. The most productive gas wells in the basin are associated with structural terraces, anticlines, and/or correspond to Cameo-Wheeler-Fairfield coal-sandstone development, reflecting basement detached thrust-faulting, fracture-enhanced permeability, and reservoir heterogeneity. Depositional heterogeneties and thrusts faults isolate coal reservoirs along the Grand Hogback from the subsurface by restricting meteoric recharge and basinward flow of ground water. An evolving coalbed methane producibility model predicts that in the Piceance Basin extraordinary coalbed methane production is precluded by low permeability and by the absence of dynamic ground-water flow.

Tyler, R.; Scott, A.R.; Kaiser, W.R.; Nance, H.S.; McMurry, R.G. [Univ. of Texas, Austin, TX (United States)

1996-12-31T23:59:59.000Z

436

Geologic and hydrologic controls on coalbed methane producibility, Williams Fork Formation, Piceance Basin, Colorado  

SciTech Connect (OSTI)

Structural and depositional setting, coal rank, gas content, permeability, hydrodynamics, and reservoir heterogeneity control the producibility of coalbed methane in the Piceance Basin. The coal-rich Upper Cretaceous, Williams Fork Formation is genetically defined and regionally correlated to the genetic sequences in the Sand Wash Basin, to the north. Net coal is thickest in north-south oriented belts which accumulated on a coastal plain, behind west-east prograding shoreline sequences. Face cleats of Late Cretaceous age strike E-NE and W-NW in the southern and northern parts of the basin, respectively, normal to the Grand Hogback thrust front. Parallelism between face-cleat strike and present-day maximum horizontal stresses may enhance or inhibit coal permeability in the north and south, respectively. Geopressure and hydropressure are both present in the basin with regional hydrocarbon overpressure dominant in the central part of the basin and hydropressure limited to the basin margins. The most productive gas wells in the basin are associated with structural terraces, anticlines, and/or correspond to Cameo-Wheeler-Fairfield coal-sandstone development, reflecting basement detached thrust-faulting, fracture-enhanced permeability, and reservoir heterogeneity. Depositional heterogeneties and thrusts faults isolate coal reservoirs along the Grand Hogback from the subsurface by restricting meteoric recharge and basinward flow of ground water. An evolving coalbed methane producibility model predicts that in the Piceance Basin extraordinary coalbed methane production is precluded by low permeability and by the absence of dynamic ground-water flow.

Tyler, R.; Scott, A.R.; Kaiser, W.R.; Nance, H.S.; McMurry, R.G. (Univ. of Texas, Austin, TX (United States))

1996-01-01T23:59:59.000Z

437

Implications of Representative Concentration Pathway 4.5 Methane Emissions to Stabilize Radiative Forcing  

SciTech Connect (OSTI)

Increases in the abundance of methane (CH4) in the Earthís atmosphere are responsible for significant radiative forcing of climate change (Forster et al., 2007; Wuebbles and Hayhoe, 2002). Since 1750, a 2.5 fold increase in atmospheric CH4 contributed 0.5 W/m2 to direct radiative forcing and an additional 0.2 W/m2 indirectly through changes in atmospheric chemistry. Next to water and carbon dioxide (CO2), methane is the most abundant greenhouse gas in the troposphere. Additionally, CH4 is significantly more effective as a greenhouse gas on a per molecule basis than is CO2, and increasing atmospheric CH4 has been second only to CO2 in radiative forcing (Forster et al., 2007). The chemical reactivity of CH4 is important to both tropospheric and stratospheric chemistry. Along with carbon monoxide, methane helps control the amount of the hydroxyl radical (OH) in the troposphere where oxidation of CH4 by OH leads to the formation of formaldehyde, carbon monoxide, and ozone.

Emanuel, William R.; Janetos, Anthony C.

2013-02-01T23:59:59.000Z

438

Deep oxidation of methane on particles derived from YSZ-supported Pd-Pt-(O) coatings synthesized by pulsed filtered cathodic arc  

E-Print Network [OSTI]

2009) Deep oxidation of methane on particles derived fromAbstract Methane conversion tests were performed on Pd, PdOFigure captions Figure 1: Methane conversion a), methane

Horwat, D.

2009-01-01T23:59:59.000Z

439

Challenges in assessment, management and development of coalbed methane resources in the Powder River Basin, Wyoming  

SciTech Connect (OSTI)

Coalbed methane development in the Powder River Basin has accelerated rapidly since the mid-1990's. forecasts of coalbed methane (CBM) production and development made during the late 1980's and early 1990's have proven to be distinctly unreliable. Estimates of gas in place and recoverable reserves have also varied widely. This lack of reliable data creates challenges in resource assessment, management and development for public resource management agencies and the CBM operators. These challenges include a variety of complex technical, legal and resource management-related issues. The Bureau of Land Management's Wyoming Reservoir Management Group (WRMG) and US Geological Survey (USGS), with the cooperation and assistance of CBM operators and other interested parties have initiated cooperative studies to address some of these issues. This paper presents results of those studies to date and outlines the agencies' goals and accomplishments expected at the studies' conclusion.

McGarry, D.E.

2000-07-01T23:59:59.000Z

440

ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN  

SciTech Connect (OSTI)

Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

MARUSICH, R.M.

2006-07-10T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Flammable Gas Detection for the D-Zero Gas System  

SciTech Connect (OSTI)

The use of flammable gas and high voltage in detector systems is common in many experiments at Fermilab. To mitigate the hazards associated with these systems, Fermilab Engineering Standard SD-45B (Ref. 1) was adopted. Since this note is meant to be a guide and not a mandatory standard, each experiment is reviewed for compliance with SD-45B by the flammable gas safety subcommittee. Currently, there are only two types of flammable gas in use, ethane (Appendix A) and methane (Appendix B). The worst flammable-gas case is C2H6 (ethane), which has an estimated flow rate that is 73% of the CH4 (methane) flow but a heat of combustion (in kcal/g-mole) that is 173% of that of methane. In the worst case, if ethane were to spew through its restricting orifice into its gas line at 0 psig and then through a catastrophic leak into Room 215 (TRD) or Room 511 (CDC/FDCNTX), the time that would be required to build up a greater than Class 1 inventory (0.4kg H2 equivalent) would be 5.2 hours (Ref. 2). Therefore a worst-case flammable gas leak would have to go undetected for over 5 hours in order to transform a either mixing room to an environment with a Risk Class greater than Class 1. The mixing systems, gas lines, and detectors themselves will be thoroughly leak checked prior to active service. All vessels that are part of the mixing systems will be protected from overpressure by safety valves vented outside the building. Both the input and output of all detector volumes are protected from overpressure in the same way. The volume immediately outside the central tracking detectors is continuously purged by nitrogen from boiloff from the main nitrogen dewar at the site. However, if flammable gas were to build up in the mixing rooms or particular detector areas, no matter how unlikely, flammable gas detectors that are part of the interlock chain of each gas mixing system will shut down the appropriate system. This includes shutting off the output of flammable gas manifolds within the gas shed. Similarly, if a fire were to break out anywhere in the D-ZERO Hall, fire sensors would stop the output of all flammable gas manifolds within the gas shed, by unpowering electrically controlled solenoid valves that are normally closed in the event of a power failure. Fire sensor contacts have not yet been installed.

Spires, L.D.; Foglesong, J.; /Fermilab

1991-02-11T23:59:59.000Z

442

Modeling of homogeneous charge compression ignition (HCCI) of methane  

SciTech Connect (OSTI)

The operation of piston engines on a compression ignition cycle using a lean, homogeneous charge has many potential attractive features. These include the potential for extremely low NO{sub x} and particulate emissions while maintaining high thermal efficiency and not requiring the expensive high pressure injection system of the typical modem diesel engine. Using the HCT chemical kinetics code to simulate autoignition of methane-air mixtures, we have explored the ignition timing, burn duration, NO{sub x} production, indicated efficiency and power output of an engine with a compression ratio of 15:1 at 1200 and 2400 rpm. HCT was modified to include the effects of heat transfer. This study used a single control volume reaction zone that varies as a function of crank angle. The ignition process is controlled by varying the intake equivalence ratio and varying the residual gas trapping (RGT). RGT is internal exhaust gas recirculation which recycles both heat and combustion product species. It is accomplished by varying the timing of the exhaust valve closure. Inlet manifold temperature was held constant at 330 Kelvins. Results show that there is a narrow range of operational conditions that show promise of achieving the control necessary to vary power output while keeping indicated efficiency above 50% and NO{sub x} levels below 100 ppm.

Smith, J.R.; Aceves, S.M.; Westbrook, C.; Pitz, W.

1997-05-01T23:59:59.000Z

443

Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments  

E-Print Network [OSTI]

bound gas in marine sediments: how much is really out there?methane hydrate in ocean sediment. Energy & Fuels 2005: 19:Accumulations in Oceanic Sediments George J. Moridis 1 and

Moridis, George J.; Sloan, E. Dendy

2006-01-01T23:59:59.000Z

444

E-Print Network 3.0 - argon gas backgrounds Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Appl. Phys. 38 (2005) 15771587 doi:10.10880022-37273810013 Summary: mixtures (with a gas density N) of methane and argon subjected to an external constant electric field E......

445

Prediction of gas-hydrate formation conditions in production and surface facilities  

E-Print Network [OSTI]

such as methane, ethane, propane, carbon dioxide and hydrogen sulfide to binary, ternary, and natural gas mixtures. I used the Statistical Analysis Software (SAS) to find the best correlations among variables such as specific gravity and pseudoreduced pressure...

Ameripour, Sharareh

2006-10-30T23:59:59.000Z

446

Analysis of condensate banking dynamics in a gas condensate reservoir under different injection schemes  

E-Print Network [OSTI]

condensate reservoir under natural depletion, and injection of methane, injection of carbon dioxide, produced gas recycling and water injection. To monitor the condensate banking dynamics near the wellbore area, such as oil saturation and compositional...

Sandoval Rodriguez, Angelica Patricia

2002-01-01T23:59:59.000Z

447

Process and apparatus for ammonia synthesis gas production  

SciTech Connect (OSTI)

An improved process is described for the production of ammonia synthesis gas which consists of: (a) catalytically reacting a hydrocarbon feed stream with steam in a primary reforming unit to form a primary reformed gas mixture containing hydrogen and carbon monoxide; (b) passing the primary reformed gas mixture to a secondary reforming unit for reaction of unconverted methane present therein with air, the amount of the air introduced to the secondary reforming unit being considerably in excess of that required to furnish the stoichiometric amount of nitrogen required for reaction with hydrogen for the ammonia synthesis; (c) subjecting the secondary reformed gas mixture to water gas shift conversion to convert most of the carbon monoxide present in the reformed gas mixture to hydrogen and carbon dioxide; (d) passing the thus-shifted gas mixture containing hydrogen, carbon dioxide, residual carbon monoxide, methane, argon and the excess nitrogen, without necessary treatment for removal of a major portion of the carbon dioxide content thereof and without methanation to remove carbon oxides to low levels, to a pressure swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from the hydrogen and from a portion of the nitrogen present in the gas passed to the system.

Fuderer, A.

1986-06-03T23:59:59.000Z

448

Large Greenhouse Gas Emissions from a Temperate Peatland Pasture  

E-Print Network [OSTI]

as a by product of the conversion of organic sediment into oil, so natural gas deposits usually are found is CO2. There are important other drivers: · methane (contributes to warming, one molecule of CH4 fossil fuels (coal, oil, natural gas) to produce energy. Almost all energy on earth ultimately comes from

Kelly, Maggi

449

Gas Separation With Graphene Membranes By Will Soutter  

E-Print Network [OSTI]

applications including fuel cells, batteries, gas sensors and gas purification. The materials, and inorganic membranes made of ceramics, metals or glass. These membranes all have the key properties nanopores in separating gases like methane, carbon dioxide and hydrogen from air using a model based

Bunch, Scott

450

A model for changes in coalbed permeability during primary and enhanced methane, recovery  

SciTech Connect (OSTI)

The natural fracture network of a dual-porosity coalbed reservoir is made up of two sets of orthogonal, and usually subvertically oriented, cleats. Coalbed permeability has been shown to vary exponentially with changes in the effective horizontal stress acting across the cleats through the cleat-volume compressibility, which is analogous to pore compressibility in porous rocks. A formulation for changes in the effective horizontal stress of coalbeds during primary methane recovery, which includes a Langmuir type curve shrinkage term, has been proposed previously. This paper presents a new version of the stress formulation by making a direct link between the volumetric matrix strain and the amount of gas desorbed. The resulting permeability model can be extended readily to account for adsorption-induced matrix swelling as well as matrix shrinkage during enhanced methane recovery involving the injection of an inert gas or gas mixture into the seams. The permeability model is validated against a recently published pressure-dependent permeability multiplier curve representative of the San Juan basin coalbeds at post-dewatering production stages. The extended permeability model is then applied successfully to history matching a micropilot test involving the injection of flue gas (consisting mainly of CO{sub 2} and N{sub 2}) at the Fenn Big Valley, Alberta, Canada.

Shi, J.Q.; Durucan, S. [University of London Imperial College of Science Technology & Medicine, London (United Kingdom). Dept. of Environmental Science & Technology

2005-08-01T23:59:59.000Z

451

Methane Sulfonation A High-Yield Approach to the Sulfonation of  

E-Print Network [OSTI]

Methane Sulfonation A High-Yield Approach to the Sulfonation of Methane to Methanesulfonic Acid Initiated by H2O2 and a Metal Chloride** Sudip Mukhopadhyay and Alexis T. Bell* Methane is abundant reactivity of methane makes it difficult to develop commercially viable processes for methane conversion.[1

Bell, Alexis T.

452

RESEARCH ARTICLE -BASED ON MIR INVESTIGATIONS IN LAKE GENEVA Spatial heterogeneity of benthic methane dynamics  

E-Print Network [OSTI]

methane dynamics in the subaquatic canyons of the Rhone River Delta (Lake Geneva) S. Sollberger ¬∑ J. P methane (CH4) dynam- ics from river deltas with important organic matter accumulation have been recently Methane emission √Ā Methane production Introduction Atmospheric methane (CH4) concentration has dramati

Wehrli, Bernhard

453

RESEARCH ARTICLE -BASED ON MIR INVESTIGATIONS IN LAKE GENEVA Spatial heterogeneity of benthic methane dynamics  

E-Print Network [OSTI]

methane dynamics in the subaquatic canyons of the Rhone River Delta (Lake Geneva) S. Sollberger ¬∑ J. P Abstract Heterogeneous benthic methane (CH4) dynam- ics from river deltas with important organic matter Particle size √Ā Methane emission √Ā Methane production Introduction Atmospheric methane (CH4) concentration

Wehrli, Bernhard

454

METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1  

E-Print Network [OSTI]

METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1 K. M. Barkume,1 G. A regime and by absorption due to methane in the near-infrared. The solid methane absorption lines through the methane. These long path lengths can be parameterized as a methane grain size of approximately

Brown, Michael E.

455

Methane Hydrate Field Studies | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |EnergyonSupport0.pdf5 OPAM SEMIANNUAL REPORTMAMay 20Field Studies Methane Hydrate Field

456

Methane Hydrate Production Feasibility | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |EnergyonSupport0.pdf5 OPAM SEMIANNUAL REPORTMAMay 20Field Studies Methane Hydrate

457

Prognostic Cell Biological Markers in Cervical Cancer Patients Primarily Treated With (Chemo)radiation: A Systematic Review  

SciTech Connect (OSTI)

The aim of this study was to systematically review the prognostic and predictive significance of cell biological markers in cervical cancer patients primarily treated with (chemo)radiation. A PubMed, Embase, and Cochrane literature search was performed. Studies describing a relation between a cell biological marker and survival in {>=}50 cervical cancer patients primarily treated with (chemo)radiation were selected. Study quality was assessed, and studies with a quality score of 4 or lower were excluded. Cell biological markers were clustered on biological function, and the prognostic and predictive significance of these markers was described. In total, 42 studies concerning 82 cell biological markers were included in this systematic review. In addition to cyclooxygenase-2 (COX-2) and serum squamous cell carcinoma antigen (SCC-ag) levels, markers associated with poor prognosis were involved in epidermal growth factor receptor (EGFR) signaling (EGFR and C-erbB-2) and in angiogenesis and hypoxia (carbonic anhydrase 9 and hypoxia-inducible factor-1{alpha}). Epidermal growth factor receptor and C-erbB-2 were also associated with poor response to (chemo)radiation. In conclusion, EGFR signaling is associated with poor prognosis and response to therapy in cervical cancer patients primarily treated with (chemo)radiation, whereas markers involved in angiogenesis and hypoxia, COX-2, and serum SCC-ag levels are associated with a poor prognosis. Therefore, targeting these pathways in combination with chemoradiation may improve survival in advanced-stage cervical cancer patients.

Noordhuis, Maartje G.; Eijsink, Jasper J.H.; Roossink, Frank; Graeff, Pauline de [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Pras, Elisabeth [Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Schuuring, Ed [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Wisman, G. Bea A. [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Bock, Geertruida H. de [Department of Epidemiology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Zee, Ate G.J. van der, E-mail: a.g.j.van.der.zee@og.umcg.n [Department of Gynecologic Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands)

2011-02-01T23:59:59.000Z

458

Carbon dioxide adsorption and methanation on ruthenium  

SciTech Connect (OSTI)

The adsorption and methanation of carbon dioxide on a ruthenium-silica catalyst were studied using temperature-programmed desorption (TPD) and temperature-programmed reaction (TPR). Carbon dioxide adsorption was found to be activated; CO/sub 2/ adsorption increased significantly as the temperature increased from 298 to 435 K. During adsorption, some of the CO/sub 2/ dissociated to carbon monoxide and oxygen; upon hydrogen exposure at room temperature, the oxygen reacted to water. Methanation of adsorbed CO and of adsorbed CO/sub 2/, using TPR in flowing hydrogen, yielded a CH/sub 4/ peak with a peak temperature of 459 K for both adsorbates, indicating that both reactions follow the same mechanism after adsorption. This peak temperature did not change with initial surface coverage of CO, indicating that methanation is first order in CO coverage. The desorption and reaction spectra for Ru/SiO/sub 2/ were similar to those previously obtained for Ni/SiO/sub 2/, but both CO/sub 2/ formation and CH/sub 4/ formation proceeded faster on Ru. Also, the details of CO desorption and the changes in CO/sub 2/ and CO desorptions with initial coverage were different on the two metals. 5 figures, 3 tables.

Zagli, E.; Falconer, J.L.

1981-05-01T23:59:59.000Z

459

Process for separating nitrogen from methane using microchannel process technology  

DOE Patents [OSTI]

The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

2007-07-31T23:59:59.000Z

460

Unconventional gas recovery program. Semi-annual report for the period ending September 30, 1979  

SciTech Connect (OSTI)

This document is the third semi-annual report describing the technical progress of the US DOE projects directed at gas recovery from unconventional sources. Currently the program includes Methane Recovery from Coalbeds Project, Eastern Gas Shales Project, Western Gas Sands Project, and Geopressured Aquifers Project.

Manilla, R.D. (ed.)

1980-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1  

E-Print Network [OSTI]

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Ghosh3 , Huei Peng2 Abstract A fuel processor that reforms natural gas to hydrogen-rich mixture to feed of the hydrogen in the fuel processor is based on catalytic partial oxidation of the methane in the natural gas

Peng, Huei

462

Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations  

SciTech Connect (OSTI)

To study physical properties of methane gas hydrate-bearing sediments, it is necessary to synthesize laboratory samples due to the limited availability of cores from natural deposits. X-ray computed tomography (CT) and other observations have shown gas hydrate to occur in a number of morphologies over a variety of sediment types. To aid in understanding formation and growth patterns of hydrate in sediments, methane hydrate was repeatedly formed in laboratory-packed sand samples and in a natural sediment core from the Mount Elbert Stratigraphic Test Well. CT scanning was performed during hydrate formation and decomposition steps, and periodically while the hydrate samples remained under stable conditions for up to 60 days. The investigation revealed the impact of water saturation on location and morphology of hydrate in both laboratory and natural sediments during repeated hydrate formations. Significant redistribution of hydrate and water in the samples was observed over both the short and long term.

Rees, E.V.L.; Kneafsey, T.J.; Seol, Y.

2010-07-01T23:59:59.000Z

463

Demonstration of the enrichment of medium quality gas from gob wells through interactive well operating practices. Final report, June--December, 1995  

SciTech Connect (OSTI)

Methane released to the atmosphere during coal mining operations is believed to contribute to global warming and represents a waste of a valuable energy resource. Commercial production of pipeline-quality gob well methane through wells drilled from the surface into the area above the gob can, if properly implemented, be the most effective means of reducing mine methane emissions. However, much of the gas produced from gob wells is vented because the quality of the gas is highly variable and is often below current natural gas pipeline specifications. Prior to the initiation of field-testing required to further understand the operational criteria for upgrading gob well gas, a preliminary evaluation and assessment was performed. An assessment of the methane gas in-place and producible methane resource at the Jim Walter Resources, Inc. No. 4 and No. 5 Mines established a potential 15-year supply of 60 billion cubic feet of mien methane from gob wells, satisfying the resource criteria for the test site. To understand the effect of operating conditions on gob gas quality, gob wells producing pipeline quality (i.e., < 96% hydrocarbons) gas at this site will be operated over a wide range of suction pressures. Parameters to be determined will include absolute methane quantity and methane concentration produced through the gob wells; working face, tailgate and bleeder entry methane levels in the mine; and the effect on the economics of production of gob wells at various levels of methane quality. Following this, a field demonstration will be initiated at a mine where commercial gob gas production has not been attempted. The guidelines established during the first phase of the project will be used to design the production program. The economic feasibility of various utilization options will also be tested based upon the information gathered during the first phase. 41 refs., 41 figs., 12 tabs.

Blackburn, S.T.; Sanders, R.G.; Boyer, C.M. II; Lasseter, E.L.; Stevenson, J.W.; Mills, R.A.

1995-12-01T23:59:59.000Z

464

Modeling Coal Matrix Shrinkage and Differential Swelling with CO2 Injection for Enhanced Coalbed Methane Recovery and Carbon Sequestration Applications  

SciTech Connect (OSTI)

Matrix shrinkage and swelling can cause profound changes in porosity and permeability of coalbed methane reservoirs during depletion or when under CO{sub 2} injection processes, with significant implication for primary or enhanced methane recovery. Two models that are used to describe these effects are discussed. The first was developed by Advanced Resources International (ARI) and published in 1990 by Sawyer, et al. The second model was published by Palmer and Mansoori in 1996. This paper shows that the two provide equivalent results for most applications. However, their differences in formulation cause each to have relative advantages and disadvantages under certain circumstances. Specifically, the former appears superior for undersaturated coalbed methane reservoirs while the latter would be better if a case is found where matrix swelling is strongly disproportional to gas concentration. Since its presentation in 1996, the Palmer and Mansoori model has justifiably received much critical praise. However, the model developed by ARI for the COMET reservoir simulation program has been in use since 1990, and has significant advantages in certain settings. A review of data published by Levine in 1996 reveals that carbon dioxide causes a greater degree of coal matrix swelling compared to methane, even when measured on a unit of concentration basis. This effect is described in this report as differential swelling. Differential swelling may have important consequences for enhanced coalbed methane and carbon sequestration projects. To handle the effects of differential swelling, an extension to the matrix shrinkage and swelling model used by the COMET simulator is presented and shown to replicate the data of Levine. Preliminary field results from a carbon dioxide injection project are also presented in support of the extended model. The field evidence supports that considerable changes to coal permeability occur with CO{sub 2} injection, with significant implication for the design, implementation and performance of enhanced coalbed methane recovery and CO{sub 2} sequestration projects.

L. J. Pekot; S. R. Reeves

2002-03-31T23:59:59.000Z

465

Energy Department Expands Research into Methane Hydrates, a Vast...  

Broader source: Energy.gov (indexed) [DOE]

separate project funded by the EU through Universities of Bremen (Germany) and Tromso (Norway), will assess the response of methane hydrates to environmental changes at the...

466

Biomass Gasification and Methane Digester Property Tax Exemption  

Broader source: Energy.gov [DOE]

Michigan exempts certain energy production related farm facilities from real and personal property taxes. Among exempted property are certain methane digesters, biomass gasification equipment,...

467

,"North Louisiana Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

468

,"Ohio Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2010,"630...

469

,"U.S. Coalbed Methane Proved Reserves Extensions (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Extensions (Billion Cubic Feet)",1,"Annual",2013 ,"Release...

470

Ohio Coalbed Methane Proved Reserves Revision Increases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

W Withheld to avoid disclosure of individual company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Reserves Revision Increases...

471

Ohio Coalbed Methane Proved Reserves Adjustments (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Available; W Withheld to avoid disclosure of individual company data. Release Date: 1242014 Next Release Date: 12312015 Referring Pages: Coalbed Methane Reserves Adjustments...

472

,"U.S. Coalbed Methane Proved Reserves New Field Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves New Field Discoveries (Billion Cubic Feet)",1,"Annual",201...

473

,"Kansas Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Kansas Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

474

Oklahoma Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Oklahoma Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0...

475

,"NM, West Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

476

WATERJETTING: A NEW DRILLING TECHNIQUE IN COALBED METHANE RESERVOIRS.  

E-Print Network [OSTI]

??WATERJETTING: A NEW DRILLING TECHNIQUE IN COALBED METHANE RESERVOIRS Applications of waterjeting to drill horizontal wells for the purpose of degassing coalbeds prior to miningÖ (more)

Funmilayo, Gbenga M.

2010-01-01T23:59:59.000Z

477

,"U.S. Coalbed Methane Production (Billion Cubic Feet)"  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Production (Billion Cubic Feet)",1,"Annual",2013 ,"Release Date:","124...

478

,"U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic...

479

,"West Virginia Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","West Virginia Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

480

,"New Mexico Coalbed Methane Proved Reserves, Reserves Changes...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

Note: This page contains sample records for the topic "gas primarily methane" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

,"TX, RRC District 2 Onshore Coalbed Methane Proved Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...

482

,"U.S. Coalbed Methane Proved Reserves Acquisitions (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Acquisitions (Billion Cubic Feet)",1,"Annual",2013...

483

Wyoming Coalbed Methane Proved Reserves New Reservoir Discoveries...  

U.S. Energy Information Administration (EIA) Indexed Site

New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Wyoming Coalbed Methane Proved Reserves New Reservoir Discoveries in Old Fields (Billion Cubic Feet) Decade Year-0...

484

,"U.S. Coalbed Methane Proved Reserves Revision Increases (Billion...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Revision Increases (Billion Cubic Feet)",1,"Annual",2013...

485

,"U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves Adjustments (Billion Cubic Feet)",1,"Annual",2013...

486

,"Utah Coalbed Methane Proved Reserves, Reserves Changes, and...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Utah Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"630...

487

,"TX, RRC District 10 Coalbed Methane Proved Reserves, Reserves...  

U.S. Energy Information Administration (EIA) Indexed Site

Coalbed Methane Proved Reserves, Reserves Changes, and Production" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Late...