National Library of Energy BETA

Sample records for gas primarily methane

  1. ARM - Methane Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach HomepolarizationMeasurementsWarmingMethane BackgroundMethane

  2. Technical Note Methane gas migration through geomembranes

    E-Print Network [OSTI]

    PROOFS Technical Note Methane gas migration through geomembranes T. D. Stark1 and H. Choi2 1 flexible geomembranes, and to measure the methane gas transmission rate, permeance, and permeability). The measured methane gas permeability coefficient through a PVC geomembrane is 7.55 3 104 ml(STP).mil/m2.day

  3. Natural Gas Infrastructure R&D and Methane Emissions Mitigation...

    Energy Savers [EERE]

    Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop The Advanced Manufacturing Office...

  4. Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions

    E-Print Network [OSTI]

    Zhang, Youxue

    Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions quantities of CH4 are stored in marine sediment in the form of methane hydrate, bubbles, and dissolved CH4 in pore water. Here I discuss the various pathways for methane to enter the ocean and atmosphere

  5. Measurements of Methane Emissions at Natural Gas Production Sites

    E-Print Network [OSTI]

    Lightsey, Glenn

    Measurements of Methane Emissions at Natural Gas Production Sites in the United States #12;Why to estimates based on this work (Gg/yr) Production emissions reported in 2011 greenhouse gas inventory (annual is methane important? The role of methane in the national greenhouse gas inventory · Most recent national

  6. Engineering Methane is a major component of shale gas. Recent

    E-Print Network [OSTI]

    Chemical Engineering Methane is a major component of shale gas. Recent oversupply of shale gas has 30% of electricity from natural and shale gas, increasing from 15% in 2010. US chemical industries have begun using ethane from shale gas as a feedstock. The low methane price is expected to push its

  7. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Energy Savers [EERE]

    the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution Controlling Methane Emissions in the...

  8. EIA - Greenhouse Gas Emissions - Methane Emissions

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9...

  9. Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID (flame ionization)

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Determination of Methane Concentration Methane will be measured on the gas chromatogram using a FID the methane between the air and water. With the syringe pointing down, eject all the water from the syringe in the syringe We will now move to the GC lab in Starr 332 to measure methane. Repeat the above procedure

  10. The presence of natural gas-primarily methane-in the shale layers of sedimen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. Jeffrey publication of the GroupofBThe new

  11. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to 93% methane by mass. NETL, 2012. Role of Alternative Energy Sources: Natural Gas Technology Assessment. See ICF, supra note 11 at 78, fn. 40. 39 This report is available...

  12. Dewatering of coalbed methane wells with hydraulic gas pump

    SciTech Connect (OSTI)

    Amani, M.; Juvkam-Wold, H.C.

    1995-12-31

    The coalbed methane industry has become an important source of natural gas production. Proper dewatering of coalbed methane (CBM) wells is the key to efficient gas production from these reservoirs. This paper presents the Hydraulic Gas Pump as a new alternative dewatering system for CBM wells. The Hydraulic Gas Pump (HGP) concept offers several operational advantages for CBM wells. Gas interference does not affect its operation. It resists solids damage by eliminating the lift mechanism and reducing the number of moving parts. The HGP has a flexible production rate and is suitable for all production phases of CBM wells. It can also be designed as a wireline retrievable system. We conclude that the Hydraulic Gas Pump is a suitable dewatering system for coalbed methane wells.

  13. Commodity chemicals from natural gas by methane chlorination

    SciTech Connect (OSTI)

    Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

    1987-01-01

    Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

  14. Direct measurements of methane emissions from abandoned oil and gas wells in Pennsylvania

    E-Print Network [OSTI]

    Mauzerall, Denise

    in unconventional production. Estimates of methane emissions from activities on producing oil and gas sites in unconventional oil and gas production is beinDirect measurements of methane emissions from abandoned oil and gas wells in Pennsylvania Mary

  15. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  16. Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines Peter Mauermann1,* , Michael Dornseiffer6 , Frank Amkreutz6 1 Institute for Combustion Engines , RWTH Aachen University, Schinkelstr. 8, D of the hydrocarbon exhaust of internal combustion engines. In contrast to other gaseous hydrocarbons, significant

  17. Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Methane-to-Methanol Conversion by Gas-Phase Transition Metal Oxide Cations: Experiment and Theory-phase transition metal oxide cations can convert methane to methanol. Methane activation by MO+ is discussed reaction are also presented. Introduction The direct oxidation of methane to an easily transportable liquid

  18. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  19. Gettering of hydrogen and methane from a helium gas mixture

    SciTech Connect (OSTI)

    Cárdenas, Rosa Elia; Stewart, Kenneth D.; Cowgill, Donald F.

    2014-11-01

    In this study, the authors developed an approach for accurately quantifying the helium content in a gas mixture also containing hydrogen and methane using commercially available getters. The authors performed a systematic study to examine how both H{sub 2} and CH{sub 4} can be removed simultaneously from the mixture using two SAES St 172{sup ®} getters operating at different temperatures. The remaining He within the gas mixture can then be measured directly using a capacitance manometer. The optimum combination involved operating one getter at 650?°C to decompose the methane, and the second at 110?°C to remove the hydrogen. This approach eliminated the need to reactivate the getters between measurements, thereby enabling multiple measurements to be made within a short time interval, with accuracy better than 1%. The authors anticipate that such an approach will be particularly useful for quantifying the He-3 in mixtures that include tritium, tritiated methane, and helium-3. The presence of tritiated methane, generated by tritium activity, often complicates such measurements.

  20. Generating Methane Gas From Manure Charles D. Fulhage, Dennis Sievers and James R. Fischer

    E-Print Network [OSTI]

    Laughlin, Robert B.

    potential The immediate and obvious benefit from methane production is the energy value of the gas itself the pH, inhibiting the methane bacteria and stopping gas production. To help buffer the system against of livestock manure. To avoid the problem, loading rates must be carefully controlled. Methane production

  1. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic43,728 243,242ConsumersAnnual CoalOrigin65.6.3.

  2. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    Greater focus needed on methane leakage from natural gasAnthropogenic emissions of methane in the United States,A. R. , et al. (2014), Methane leaks from North American

  3. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    of methane emissions from shale gas development, Proc. Natl.and northeastern Marcellus shale gas production regions, J.Haynesville and Marcellus shale gas production regions, J.

  4. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    natural gas extraction can lead to signi?cant emissions of methane (CH 4 ), volatile organic compounds (VOCs), and nitrogen

  5. METHANE GAS STABILIZES SUPERCOOLED ETHANE DROPLETS IN TITAN'S CLOUDS

    SciTech Connect (OSTI)

    Wang, Chia C.; Lang, E. Kathrin; Signorell, Ruth

    2010-03-20

    Strong evidence for ethane clouds in various regions of Titan's atmosphere has recently been found. Ethane is usually assumed to exist as ice particles in these clouds, although the possible role of liquid and supercooled liquid ethane droplets has been recognized. Here, we report on infrared spectroscopic measurements of ethane aerosols performed in the laboratory under conditions mimicking Titan's lower atmosphere. The results clearly show that liquid ethane droplets are significantly stabilized by methane gas which is ubiquitous in Titan's nitrogen atmosphere-a phenomenon that does not have a counterpart for water droplets in Earth's atmosphere. Our data imply that supercooled ethane droplets are much more abundant in Titan's clouds than previously anticipated. Possibly, these liquid droplets are even more important for cloud processes and the formation of lakes than ethane ice particles.

  6. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    in the Haynesville Shale, Environ. Sci. Technol. , 44(24),of methane emissions from shale gas development, Proc. Natl.and northeastern Marcellus shale gas production regions, J.

  7. Efficient gas-separation process to upgrade dilute methane stream for use as fuel

    DOE Patents [OSTI]

    Wijmans, Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Lin, Haiqing (Mountain View, CA); Thompson, Scott (Brecksville, OH); Daniels, Ramin (San Jose, CA)

    2012-03-06

    A membrane-based gas separation process for treating gas streams that contain methane in low concentrations. The invention involves flowing the stream to be treated across the feed side of a membrane and flowing a sweep gas stream, usually air, across the permeate side. Carbon dioxide permeates the membrane preferentially and is picked up in the sweep air stream on the permeate side; oxygen permeates in the other direction and is picked up in the methane-containing stream. The resulting residue stream is enriched in methane as well as oxygen and has an EMC value enabling it to be either flared or combusted by mixing with ordinary air.

  8. EOS7C Version 1.0: TOUGH2 Module for Carbon Dioxide or Nitrogen in Natural Gas (Methane) Reservoirs

    E-Print Network [OSTI]

    Oldenburg, Curtis M.; Moridis, George J.; Spycher, Nicholas; Pruess, Karsten

    2004-01-01

    as cushion gas for natural gas storage, Energy&Fuels ,of CO 2 injection into natural gas reservoirs for carbonDioxide or Nitrogen in Natural Gas (Methane) Reservoirs

  9. Diffusion of methane and other alkanes in metal-organic frameworks for natural gas storage

    SciTech Connect (OSTI)

    Borah, B; Zhang, HD; Snurr, RQ

    2015-03-03

    Diffusion of methane, ethane, propane and n-butane was studied within the micropores of several metal organic frameworks (MOFs) of varying topologies, including the MOFs PCN-14, NU-125, NU-1100 and DUT-49. Diffusion coefficients of the pure components, as well as methane/ethane, methane/ propane and methane/butane binary mixtures, were calculated using molecular dynamics simulations to understand the effect of the longer alkanes on uptake of natural gas in MOB. The calculated self diffusion coefficients of all four components are on the order of 10(-8) m(2)/s. The diffusion coefficients of the pure components decrease as a function of chain length in all of the MOFs studied and show different behaviour as a function of loading in different MOB. The self-diffusivities follow the trend DPCN-14 < DNU-125 approximate to DNU-1100 < DDUT-49, which is exactly the reverse order of the densities of the MOFs: PCN-14 > NU-125 approximate to NU-1100 > DUT-49. By comparing the diffusion of pure methane and methane mixtures vvith the higher alkancs, it is observed that the diffusivity of methane is unaffected by the presence of the higher alkanes in the MOFs considered, indicating that the diffusion path of methane is not blocked by the higher alkanes present in natural gas. (C) 2014 Elsevier Ltd. All rights reserved.

  10. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

    2011-06-01

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

  11. Experimental and theoretical study of the gas phase reaction of ethynyl radical with methane HCBC CH4

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Experimental and theoretical study of the gas phase reaction of ethynyl radical with methane HCBC September 2000 Abstract Absolute rate coecients of the reaction of ethynyl radical with methane were importance. In this work, we set out to investigate the reactivity of ethynyl radicals to- wards methane

  12. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    of methane emissions from oil and gas production pads using2015), In?uence of oil and gas ?eld operations on spatialux measurements over oil and gas extraction regions •

  13. Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change

    SciTech Connect (OSTI)

    Reagan, Matthew; Reagan, Matthew T.; Moridis, George J.

    2008-04-15

    Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those predicted under future climate change scenarios, is poorly understood. To determine the fate of the carbon stored in these hydrates, we performed simulations of oceanic gas hydrate accumulations subjected to temperature changes at the seafloor and assessed the potential for methane release into the ocean. Our modeling analysis considered the properties of benthic sediments, the saturation and distribution of the hydrates, the ocean depth, the initial seafloor temperature, and for the first time, estimated the effect of benthic biogeochemical activity. The results show that shallow deposits--such as those found in arctic regions or in the Gulf of Mexico--can undergo rapid dissociation and produce significant methane fluxes of 2 to 13 mol/yr/m{sup 2} over a period of decades, and release up to 1,100 mol of methane per m{sup 2} of seafloor in a century. These fluxes may exceed the ability of the seafloor environment (via anaerobic oxidation of methane) to consume the released methane or sequester the carbon. These results will provide a source term to regional or global climate models in order to assess the coupling of gas hydrate deposits to changes in the global climate.

  14. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect (OSTI)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  15. Functionally gradient material for membrane reactors to convert methane gas into value-added products

    DOE Patents [OSTI]

    Balachandran, U.; Dusek, J.T.; Kleefisch, M.S.; Kobylinski, T.P.

    1996-11-12

    A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials. 7 figs.

  16. Functionally gradient material for membrane reactors to convert methane gas into value-added products

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Dusek, Joseph T. (Lombard, IL); Kleefisch, Mark S. (Napersville, IL); Kobylinski, Thadeus P. (Lisle, IL)

    1996-01-01

    A functionally gradient material for a membrane reactor for converting methane gas into value-added-products includes an outer tube of perovskite, which contacts air; an inner tube which contacts methane gas, of zirconium oxide, and a bonding layer between the perovskite and zirconium oxide layers. The bonding layer has one or more layers of a mixture of perovskite and zirconium oxide, with the layers transitioning from an excess of perovskite to an excess of zirconium oxide. The transition layers match thermal expansion coefficients and other physical properties between the two different materials.

  17. Analysis and Methane Gas Separations Studies for City of Marsing, Idaho An Idaho National Laboratory Technical Assistance Program Study

    SciTech Connect (OSTI)

    Christopher Orme

    2012-08-01

    Introduction and Background Large amounts of methane in well water is a wide spread problem in North America. Methane gas from decaying biomass and oil and gas deposits escape into water wells typically through cracks or faults in otherwise non-porous rock strata producing saturated water systems. This methane saturated water can pose several problems in the delivery of drinking water. The problems range from pumps vapor locking (cavitating), to pump houses exploding. The City of Marsing requested Idaho National Laboratory (INL) to assist with some water analyses as well as to provide some engineering approaches to methane capture through the INL Technical Assistance Program (TAP). There are several engineering approaches to the removal of methane and natural gas from water sources that include gas stripping followed by compression and/or dehydration; membrane gas separators coupled with dehydration processes, membrane water contactors with dehydration processes.

  18. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  19. A Path to Reduce Methane Emissions from Gas Systems | Department...

    Broader source: Energy.gov (indexed) [DOE]

    gas. This natural gas revolution is driving economic growth across the country, lowering energy prices and creating jobs. It has also contributed to an American manufacturing...

  20. GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS

    SciTech Connect (OSTI)

    James Sorensen; Jaroslav Solc; Bethany Bolles

    2000-07-01

    The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

  1. Methane contamination of drinking water accompanying gas-well drilling and

    E-Print Network [OSTI]

    Jackson, Robert B.

    Methane contamination of drinking water accompanying gas-well drilling and hydraulic fracturing (received for review January 13, 2011) Directional drilling and hydraulic-fracturing technologies are dra- turing fluids. We conclude that greater stewardship, data, and-- possibly--regulation are needed

  2. Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraine’s Natural Gas Transmission System

    SciTech Connect (OSTI)

    Roshchanka, Volha; Evans, Meredydd

    2014-06-01

    Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own system’s natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraine’s transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraine’s natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

  3. UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

    SciTech Connect (OSTI)

    Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

    2011-10-01

    This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses. Depending on the value of gas, simple, low-cost measures, such as adjusting leaking equipment components, or larger-scale measures, such as installing dry seals on compressors, can be applied.

  4. Methane Gas Utilization Project from Landfill at Ellery (NY)

    SciTech Connect (OSTI)

    Pantelis K. Panteli

    2012-01-10

    Landfill Gas to Electric Energy Generation and Transmission at Chautauqua County Landfill, Town of Ellery, New York. The goal of this project was to create a practical method with which the energy, of the landfill gas produced by the decomposing waste at the Chautauqua County Landfill, could be utilized. This goal was accomplished with the construction of a landfill gas to electric energy plant (originally 6.4MW and now 9.6MW) and the construction of an inter-connection power-line, from the power-plant to the nearest (5.5 miles) power-grid point.

  5. New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques

    SciTech Connect (OSTI)

    Brown, T.D.; Taylor, C.E.; Bernardo, M.

    2010-01-01

    Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 °C) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20°C for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned for stranded gas reserves. The recent experiments and their results from the testing within NETL's 15-Liter Hydrate Cell Facility exhibit promising results. Introduction of water at the desired temperature and pressure through an NETL designed nozzle into a temperature controlled methane environment within the 15-Liter Hydrate Cell allowed for instantaneous formation of methane hydrates. The instantaneous and continuous hydrate formation process was repeated over several days while varying the flow rate of water, its' temperature, and the overall temperature of the methane environment. These results clearly indicated that hydrates formed immediately after the methane and water left the nozzle at temperatures above the freezing point of water throughout the range of operating conditions. [1] Oil and Gas Journal Vol. 160.48, Dec 22, 2008. [2] http://www.eia.doe.gov/oiaf/servicerpt/natgas/chapter3.html and http://www.eia.doe.gov/oiaf/servicerpt/natgas/pdf/tbl7.pdf [3] U.S. Geological Survey, “Circum-Arctic Resource Appraisal: Estimates of Undiscovered Oil and Gas North of the Arctic Circle,” May 2008.

  6. Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams

    SciTech Connect (OSTI)

    Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

    1980-07-01

    Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

  7. Other States Natural Gas Coalbed Methane, Reserves Based Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+Elements) Gas and(Billion Cubic Feet)

  8. Plasma-produced phase-pure cuprous oxide nanowires for methane gas sensing

    SciTech Connect (OSTI)

    Cheng, Qijin Zhang, Fengyan; Yan, Wei; Randeniya, Lakshman; Ostrikov, Kostya

    2014-03-28

    Phase-selective synthesis of copper oxide nanowires is warranted by several applications, yet it remains challenging because of the narrow windows of the suitable temperature and precursor gas composition in thermal processes. Here, we report on the room-temperature synthesis of small-diameter, large-area, uniform, and phase-pure Cu{sub 2}O nanowires by exposing copper films to a custom-designed low-pressure, thermally non-equilibrium, high-density (typically, the electron number density is in the range of 10{sup 11}–10{sup 13}?cm{sup ?3}) inductively coupled plasmas. The mechanism of the plasma-enabled phase selectivity is proposed. The gas sensors based on the synthesized Cu{sub 2}O nanowires feature fast response and recovery for the low-temperature (?140?°C) detection of methane gas in comparison with polycrystalline Cu{sub 2}O thin film-based gas sensors. Specifically, at a methane concentration of 4%, the response and the recovery times of the Cu{sub 2}O nanowire-based gas sensors are 125 and 147?s, respectively. The Cu{sub 2}O nanowire-based gas sensors have a potential for applications in the environmental monitoring, chemical industry, mining industry, and several other emerging areas.

  9. Methanation assembly using multiple reactors

    DOE Patents [OSTI]

    Jahnke, Fred C.; Parab, Sanjay C.

    2007-07-24

    A methanation assembly for use with a water supply and a gas supply containing gas to be methanated in which a reactor assembly has a plurality of methanation reactors each for methanating gas input to the assembly and a gas delivery and cooling assembly adapted to deliver gas from the gas supply to each of said methanation reactors and to combine water from the water supply with the output of each methanation reactor being conveyed to a next methanation reactor and carry the mixture to such next methanation reactor.

  10. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY)

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  11. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    E-Print Network [OSTI]

    Reagan, M.

    2012-01-01

    Potential distribution of methane hydrate in the world'sisotopic evidence for methane hydrate instability duringHendy, L.L. , and R.J. Behl, Methane hydrates in quaternary

  12. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Liukang, Xu; Dayle, McDermitt; Tyler, Anderson; Brad, Riensche; Anatoly, Komissarov; Julie, Howe

    2012-05-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been utilized to randomize the noise introduced from potential etalons. It is expected that all original specifications contained within the initial proposal will be met. We are currently in the beginning stages of assembling the first generation prototypes and finalizing the remaining design elements. The first prototypes will initially be tested in our environmental calibration chamber in which specific gas concentrations, temperature and humidity levels can be controlled. Once operation in this controlled setting is verified, the prototypes will be deployed at LI-COR�¢����s Experimental Research Station (LERS). Deployment at the LERS site will test the instrument�¢����s robustness in a real-world situation.

  13. Development of Atmospheric Tracer Methods To Measure Methane Emissions from Natural Gas Facilities and Urban Areas

    E-Print Network [OSTI]

    1995-01-01

    an urban area is used with crosswind integrated tracerCWI,) and the average crosswind concen- tration of methane (directly, and the crosswind average methane concentration

  14. Chemical kinetic modeling of oxy-fuel combustion of sour gas for enhanced oil recovery

    E-Print Network [OSTI]

    Bongartz, Dominik

    2014-01-01

    Oxy-fuel combustion of sour gas, a mixture of natural gas (primarily methane (CH 4 )), carbon dioxide (CO 2 ), and hydrogen sulfide (H 2 S), could enable the utilization of large natural gas resources, especially when ...

  15. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    SciTech Connect (OSTI)

    W. Steven Holbrook

    2004-11-11

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  16. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  17. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  18. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  19. 4-102 Methane is heated in a rigid container. The final pressure of the methane is to be determined using the ideal gas equation and the Benedict-Webb-Rubin equation of state.

    E-Print Network [OSTI]

    Bahrami, Majid

    4-54 4-102 Methane is heated in a rigid container. The final pressure of the methane the ideal gas equation of state, Methane 100 kPa 20qC Q kPa229.7 K293 K673 kPa)100( 1 2 12 T T PP The specific molar volume of the methane is /kmolm36.24 kPa100 K)K)(293/kmolmkPa(8.314 3 3 1 1 21 P TRu vv (b

  20. Estimating U.S. Methane Emissions from the Natural Gas Supply Chain. Approaches, Uncertainties, Current Estimates, and Future Studies

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-08-01

    A growing number of studies have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain. In particular, a number of measurement studies have suggested that actual levels of CH4 emissions may be higher than estimated by EPA" tm s U.S. GHG Emission Inventory. We reviewed the literature to identify the growing number of studies that have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain.

  1. Applied reaction dynamics: Efficient synthesis gas production via single collision partial oxidation of methane to CO on Rh,,111...

    E-Print Network [OSTI]

    Sibener, Steven

    the yield of CO from the partial oxidation of CH4 on a Rh 111 catalytic substrate, CH4+ 1/2 O2CO+2H2 to the multistep route to methane utilization, namely, steam reforming coupled with the water gas shift reaction.1

  2. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-01-01

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700şC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

  3. A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry

    E-Print Network [OSTI]

    2011-01-01

    the anaerobic oxidation of methane. Environ. Microbiol. 10(Field observations of methane concentra- tions and oxidationAnaerobic oxidation of methane above gas hydrates at Hydrate

  4. U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)

    SciTech Connect (OSTI)

    Heath, G.

    2014-04-01

    Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

  5. Microstructure-Dependent Gas Adsorption: Accurate Predictions of Methane Uptake in Nanoporous Carbons

    SciTech Connect (OSTI)

    Ihm, Yungok; Cooper, Valentino R; Gallego, Nidia C; Contescu, Cristian I; Morris, James R

    2014-01-01

    We demonstrate a successful, efficient framework for predicting gas adsorption properties in real materials based on first-principles calculations, with a specific comparison of experiment and theory for methane adsorption in activated carbons. These carbon materials have different pore size distributions, leading to a variety of uptake characteristics. Utilizing these distributions, we accurately predict experimental uptakes and heats of adsorption without empirical potentials or lengthy simulations. We demonstrate that materials with smaller pores have higher heats of adsorption, leading to a higher gas density in these pores. This pore-size dependence must be accounted for, in order to predict and understand the adsorption behavior. The theoretical approach combines: (1) ab initio calculations with a van der Waals density functional to determine adsorbent-adsorbate interactions, and (2) a thermodynamic method that predicts equilibrium adsorption densities by directly incorporating the calculated potential energy surface in a slit pore model. The predicted uptake at P=20 bar and T=298 K is in excellent agreement for all five activated carbon materials used. This approach uses only the pore-size distribution as an input, with no fitting parameters or empirical adsorbent-adsorbate interactions, and thus can be easily applied to other adsorbent-adsorbate combinations.

  6. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    SciTech Connect (OSTI)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work, permitting, barging, ice road/pad construction, drilling, completion, tie-in, long-term production testing and surveillance, data analysis and technology transfer. The PRA project team and North Slope have recommended moving forward to the execution phase of this project.

  7. Investigation of methane adsorption and its effect on gas transport in shale matrix through microscale and mesoscale simulations

    E-Print Network [OSTI]

    Li, ZhongZhen; Chen, Li; Kangd, Qinjun; He, Ya-Ling; Tao, Wen-Quan

    2015-01-01

    Methane adsorption and its effect on fluid flow in shale matrix are investigated through multi-scale simulation scheme by using molecular dynamics (MD) and lattice Boltzmann (LB) methods. Equilibrium MD simulations are conducted to study methane adsorption on the organic and inorganic walls of nanopores in shale matrix with different pore sizes and pressures. Density and pressure distributions within the adsorbed layer and the free gas region are discussed. The illumination of the MD results on larger scale LB simulations is presented. Pressure-dependent thickness of adsorbed layer should be adopted and the transport of adsorbed layer should be properly considered in LB simulations. LB simulations, which are based on a generalized Navier-Stokes equation for flow through low-permeability porous media with slippage, are conducted by taking into consideration the effects of adsorbed layer. It is found that competitive effects of slippage and adsorbed layer exist on the permeability of shale matrix, leading to di...

  8. Mechanistic Studies on the Hydroxylation of Methane by Methane Monooxygenase

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    of formaldehyde to carbon dioxide provides energy that is stored for later use as NADH.2 The conversion of methane are bacteria that live on methane as their only source of carbon.1 The first step in their utilization gas (it is currently not economical17 to transport and store methane gas from remote sites

  9. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  10. Direct production of hydrogen and aromatics from methane or natural gas: Review of recent U.S. patents

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar

    2012-03-01

    Since the year 2000, the United States Patent and Trademark Office (USPTO) has granted a dozen patents for inventions related to methane dehydroaromatization processes. One of them was granted to UOP LLC (Des Plaines). It relates to a catalyst composition and preparation method. Two patents were granted to Conoco Phillips Company (Houston, TX). One was aimed at securing a process and operating conditions for methane aromatization. The other was aimed at securing a process that may be integrated with separation of wellhead fluids and blending of the aromatics produced from the gas with the crude. Nine patents were granted to ExxonMobil Chemical Patents Inc. (Houston, TX). Most of these were aimed at securing a dehydroaromatization process where methane-containing feedstock moves counter currently to a particulate catalyst. The coked catalyst is heated or regenerated either in the reactor, by cyclic operation, or in annex equipment, and returned to the reactor. The reactor effluent stream may be separated in its main components and used or recycled as needed. A brief summary of those inventions is presented in this review.

  11. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

  12. Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, B; Balin, D F

    2012-09-06

    The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

  13. Diffusional methane fluxes within continental margin sediments and depositional constraints on formation factor estimates

    E-Print Network [OSTI]

    Berg, Richard D.

    2008-01-01

    Goldberg, E.D. , 1976. Methane production and consumption inanaerobic oxidation of methane. Nature, 407 , 623-626.profiles indicate in situ methane flux from underlying gas

  14. Miscibility, solubility and retrograde prediction of methane in liquids. Liquid storage of natural gas (LSNG) for vehicle fuel. Annual report, July 15, 1992-July 15, 1993

    SciTech Connect (OSTI)

    Mansoori, G.A.

    1994-07-01

    The primary focus of this project is to investigate the concept of liquid storage of natural gas (LSNG) for potential natural gas vehicle (NGV) application. The research work consists of developing accurate techniques for modeling of interfacial properties, miscibility and solubility of methane in liquids. By implementing this project it will be possible: To use natural gas as the fuel for internal combustion engines; To increase the gas tank capacity about 200% more over the compressed natural gas (CNG) scheme; To increase the octane-number of low quality liquid fuels through blending them with natural gas.

  15. Methane contamination of drinking water accompanying gas-well drilling and

    E-Print Network [OSTI]

    of drinking water associated with shale- gas extraction. In active gas-extraction areas (one or more gas wells. groundwater organic-rich shale isotopes formation waters water chemistry Increases in natural-gas extraction of such extraction (6, 7) are public concerns about drinking-water contamination from drilling and hydraulic

  16. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, R.W.; Lokhandwala, K.A.; Pinnau, I.; Segelke, S.

    1997-09-23

    A membrane separation process is described for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. The authors have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen. 11 figs.

  17. Methane/nitrogen separation process

    DOE Patents [OSTI]

    Baker, Richard W. (Palo Alto, CA); Lokhandwala, Kaaeid A. (Menlo Park, CA); Pinnau, Ingo (Palo Alto, CA); Segelke, Scott (Mountain View, CA)

    1997-01-01

    A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.

  18. Non-linear response of carbon dioxide and methane emissions to oxygen availability in a drained histosol

    E-Print Network [OSTI]

    McNicol, Gavin; Silver, Whendee L

    2015-01-01

    Keywords: Soil respiration; methane; carbon dioxide; oxygen;response of carbon dioxide and methane emissions to oxygenof carbon dioxide (CO 2 ) and methane (CH 4 ) greenhouse gas

  19. A conduit dilation model of methane venting from lake sediments

    E-Print Network [OSTI]

    Ruppel, Carolyn

    Methane is a potent greenhouse gas, but its effects on Earth's climate remain poorly constrained, in part due to uncertainties in global methane fluxes to the atmosphere. An important source of atmospheric methane is the ...

  20. Development of Atmospheric Tracer Methods To Measure Methane Emissions from Natural Gas Facilities and Urban Areas

    E-Print Network [OSTI]

    1995-01-01

    to coal and 30% less compared to fuel oil, switching fromcoal and fuel oil to natural gas has the potential to reducehydrocarbon emissions from an oil refinery wastewater

  1. Controlling Methane Emissions in the Natural Gas Sector. A Review of Federal and State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution

    SciTech Connect (OSTI)

    Paranhos, Elizabeth; Kozak, Tracy G.; Boyd, William; Bradbury, James; Steinberg, D. C.; Arent, D. J.

    2015-04-23

    This report provides an overview of the regulatory frameworks governing natural gas supply chain infrastructure siting, construction, operation, and maintenance. Information was drawn from a number of sources, including published analyses, government reports, in addition to relevant statutes, court decisions and regulatory language, as needed. The scope includes all onshore facilities that contribute to methane emissions from the natural gas sector, focusing on three areas of state and federal regulations: (1) natural gas pipeline infrastructure siting and transportation service (including gathering, transmission, and distribution pipelines), (2) natural gas pipeline safety, and (3) air emissions associated with the natural gas supply chain. In addition, the report identifies the incentives under current regulatory frameworks to invest in measures to reduce leakage, as well as the barriers facing investment in infrastructure improvement to reduce leakage. Policy recommendations regarding how federal or state authorities could regulate methane emissions are not provided; rather, existing frameworks are identified and some of the options for modifying existing regulations or adopting new regulations to reduce methane leakage are discussed.

  2. Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process in Marcellus Shale

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Continuous, low-permeability, fractured, organic-rich gas shale units are widespread and are possible, organic-rich rocks that are both the source and trap for natural gas (primarily methane). In shale gas1 Impact of Sorption Isotherms on the Simulation of CO2-Enhanced Gas Recovery and Storage Process

  3. Electrochemical methane sensor

    DOE Patents [OSTI]

    Zaromb, S.; Otagawa, T.; Stetter, J.R.

    1984-08-27

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about 1.4 volts vs R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  4. A multi-phase, micro-dispersion reactor for the continuous production of methane gas hydrate

    SciTech Connect (OSTI)

    Taboada Serrano, Patricia L [ORNL; Ulrich, Shannon M [ORNL; Szymcek, Phillip [ORNL; McCallum, Scott [Oak Ridge Associated Universities (ORAU); Phelps, Tommy Joe [ORNL; Palumbo, Anthony Vito [ORNL; Tsouris, Costas [ORNL

    2009-01-01

    A continuous-jet hydrate reactor originally developed to generate a CO2 hydrate stream has been modified to continuously produce CH4 hydrate. The reactor has been tested in the Seafloor Process Simulator (SPS), a 72-L pressure vessel available at Oak Ridge National Laboratory. During experiments, the reactor was submerged in water inside the SPS and received water from the surrounding through a submersible pump and CH4 externally through a gas booster pump. Thermodynamic conditions in the hydrate stability regime were employed in the experiments. The reactor produced a continuous stream of CH4 hydrate, and based on pressure values and amount of gas injected, the conversion of gas to hydrate was estimated. A conversion of up to 70% was achieved using this reactor.

  5. Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers

    SciTech Connect (OSTI)

    Evans, Meredydd; Roshchanka, Volha

    2014-08-04

    This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

  6. Combined Steam Reforming and Partial Oxidation of Methane to Synthesis Gas under Electrical Discharge

    E-Print Network [OSTI]

    Mallinson, Richard

    and carbon monoxide, is an important raw material in chemical manufacture such as, Fischer-Tropsch synthesis and Materials Science, University of Oklahoma, Norman, Oklahoma 73019 An experimental study of synthesis gas production has been steam reforming, shown in reaction 4. It is very useful to use low-cost materials

  7. Conversion of forest residues to a methane-rich gas: Interim Report

    SciTech Connect (OSTI)

    Feldmann, H.G.; Paisley, M.A.; Appelbaum, H.R.

    1986-03-01

    A process is being developed that produces a fuel gas with a heating value of 500 Btu/SCF from diverse forms of biomass, including shredded bark, wood chips, and sawdust. The system uses a high throughput, non-oxygen gasifier that employs sand circulation to supply process heat. Results obtained with a 10-inch I.D. gasifier are presented and compared with those in a 6-inch I.D. reactor. Feed rates up to 12 tons/day (dry) have been achieved corresponding to a specific wood throughput of 2000 lbs/ft/sup 2/-hr. Gas compositions in the two reactors are in excellent agreement and performance in the larger reactor, as measured by carbon conversion, is significantly improved. Cost projections comparing this process with direct combustion are presented that indicate gasification technology should have very significant cost advantages for both generation of plant steam and cogeneration of electricity. 5 refs., 14 figs., 5 tabs.

  8. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIXConcentrating SolarEnergy First Gas Infrastructure

  9. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIXConcentrating SolarEnergy First Gas Infrastructure12-13,

  10. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIXConcentrating SolarEnergy First Gas Infrastructure12-13,

  11. Natural Gas Infrastructure R&D and Methane Mitigation Woekshop Nov. 12-13, 2014

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIXConcentrating SolarEnergy First Gas Infrastructure12-13,

  12. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment ofOffice|in the subsurface is better6, 2015 2:00PM to 3:00PM EST

  13. Controlling Methane Emissions in the Natural Gas Sector: A Review of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle (PEV)Day-June2012 | DepartmentFederal & State

  14. Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data

    E-Print Network [OSTI]

    Gupta, A.

    2010-01-01

    of predicted and measured methane gas production data within the heterogeneous porous methane hydrate sample.Global Distribution of Methane Hydrate in Ocean Hydrate.

  15. Formation mechanism for polycyclic aromatic hydrocarbons in methane flames

    E-Print Network [OSTI]

    Sattler, Klaus

    applications including heating systems and gas turbines for electric power generation.62­64 The combustion of natural gas methane is a clean and efficient process. While gas turbines operating with methane pollution than other hydrocarbon fuels. Therefore, gas turbines pow- ered by methane are promising

  16. Biogeochemistry of Microbial Coal-Bed Methane

    E-Print Network [OSTI]

    Macalady, Jenn

    Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo´c,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

  17. Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    Quasielastic electron scattering from methane, methane-d4, methane-d2, ethylene, and 2-methylpropane, ethylene, methane, and two isotopically substituted methanes, CH2D2 and CD4, at a momentum constituent. For example, Fig. 1 of Ref. 2 shows that, for gaseous methane, above a certain momentum transfer

  18. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Office of Environmental Management (EM)

    the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate...

  19. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    emissions from oil and gas production pads using mobileuxes over other oil and gas production regions using eddycompounds (VOCs) from oil and gas production may have large

  20. Effect of bubble size and density on methane conversion to hydrate

    SciTech Connect (OSTI)

    Leske, J.; Taylor, C.E.; Ladner, E.P.

    2007-03-01

    Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methane–water solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

  1. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: • Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. • Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. • Methane oxidation in the waste itself and in soil covers. • Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (“Umweltbundesamt”), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 18–24 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000–135,000 t CO{sub 2-eq.}/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied. It is therefore necessary to generate more data in the future in order to calculate more precise methane emission rates from MBT landfills. This is important for the overall calculation of the climate gas production in Germany which is required once a year by the German Government.

  2. Methane clathrates in the Solar System

    E-Print Network [OSTI]

    Mousis, Olivier; Holm, Nils G; Bouquet, Alexis; Waite, Jack Hunter; Geppert, Wolf Dietrich; Picaud, Sylvain; Aikawa, Yuri; Ali-Dib, Mohamad; Charlou, Jean-Luc; Rousselot, Philippe

    2015-01-01

    We review the reservoirs of methane clathrates that may exist in the different bodies of the Solar System. Methane was formed in the interstellar medium prior to having been embedded in the protosolar nebula gas phase. This molecule was subsequently trapped in clathrates that formed from crystalline water ice during the cooling of the disk and incorporated in this form in the building blocks of comets, icy bodies, and giant planets. Methane clathrates may play an important role in the evolution of planetary atmospheres. On Earth, the production of methane in clathrates is essentially biological, and these compounds are mostly found in permafrost regions or in the sediments of continental shelves. On Mars, methane would more likely derive from hydrothermal reactions with olivine-rich material. If they do exist, martian methane clathrates would be stable only at depth in the cryosphere and sporadically release some methane into the atmosphere via mechanisms that remain to be determined.

  3. 02/09/2009 16:58Warming Of Arctic Current Over 30 Years Triggers Release Of Methane Gas Page 1 of 2http://www.sciencedaily.com/releases/2009/08/090814103231.htm

    E-Print Network [OSTI]

    Rohling, Eelco

    Climate Environmental Issues Renewable Energy Oceanography Water Reference Geologic temperature record Installation Course Solar energy heating installation & renewable energ02/09/2009 16:58Warming Of Arctic Current Over 30 Years Triggers Release Of Methane Gas Page 1 of 2

  4. Conversion of forest residues to a methane-rich gas in a high-throughput gasifier. Summary report

    SciTech Connect (OSTI)

    Feldmann, H.F.; Paisley, M.A.; Folsom, D.W.; Kim, B.C.

    1981-10-31

    Results of the experimental work conducted thus far have shown that wood can be readily gasified in a steam environment into a hydrocarbon rich fuel gas that can be used as a replacement for petroleum-based fuels or natural gas with minimal boiler retrofit. Further, this conversion can be achieved in a compact gasification reactor with heat supplied by a circulating entrained phase, thereby eliminating the need for an oxygen plant. Tars have not been found except at the lowest gasifier temperatures employed, and therefore heat recovery from the product gas should be much simpler than that from commercially available fixed-bed gasification systems where product gas contains significant quantities of tar. The data generated have been used in a preliminary conceptual design. Evaluation of this design has shown that a medium-Btu gas can be produced from wood at a cost competitive with natural gas or petroleum-based fuels.

  5. Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations

    E-Print Network [OSTI]

    Rees, E.V.L.

    2012-01-01

    Deep Ocean Field Test of Methane Hydrate Formation from aW.J. , and Mason, D.H. , Methane Hydrate Formation inNatural and Laboratory--Formed Methane Gas Hydrate. American

  6. Airborne flux measurements of methane and volatile organic compounds over the Haynesville and Marcellus shale gas production regions

    E-Print Network [OSTI]

    2015-01-01

    well sites of the Barnett shale gas play [Eastern Researchof well sites in the Barnett shale play accounted for 70% of

  7. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  8. Distinguishing and understanding thermogenic and biogenic sources of methane using multiply substituted isotopologues

    E-Print Network [OSTI]

    2015-01-01

    the generation and composition of natural gas. Geochimica etcarbon isotopic composition of methane from natural gases of

  9. CO2 sequestration by methanogens in activated sludge for methane Nazlina Haiza Mohd Yasin a

    E-Print Network [OSTI]

    Wood, Thomas K.

    CO2 sequestration by methanogens in activated sludge for methane production Nazlina Haiza Mohd WAS have significant potential for converting the greenhouse gas CO2 into the fuel methane. Methane biofuel (methane) or other valuable products using this single carbon atom. Ó 2015 Elsevier Ltd. All

  10. Bioconversion of natural gas to liquid fuel: Opportunities and challenges

    SciTech Connect (OSTI)

    Fei, Q; Guarnieri, MT; Tao, L; Laurens, LML; Dowe, N; Pienkos, PT

    2014-05-01

    Natural gas is a mixture of low molecular weight hydrocarbon gases that can be generated from either fossil or anthropogenic resources. Although natural gas is used as a transportation fuel, constraints in storage, relatively low energy content (MJ/L), and delivery have limited widespread adoption. Advanced utilization of natural gas has been explored for biofuel production by microorganisms. In recent years, the aerobic bioconversion of natural gas (or primarily the methane content of natural gas) into liquid fuels (Bio-GTL) by biocatalysts (methanotrophs) has gained increasing attention as a promising alternative for drop-in biofuel production. Methanotrophic bacteria are capable of converting methane into microbial lipids, which can in turn be converted into renewable diesel via a hydrotreating process. In this paper, biodiversity, catalytic properties and key enzymes and pathways of these microbes are summarized. Bioprocess technologies are discussed based upon existing literature, including cultivation conditions, fermentation modes, bioreactor design, and lipid extraction and upgrading. This review also outlines the potential of Bio-GTL using methane as an alternative carbon source as well as the major challenges and future research needs of microbial lipid accumulation derived from methane, key performance index, and techno-economic analysis. An analysis of raw material costs suggests that methane-derived diesel fuel has the potential to be competitive with petroleum-derived diesel. (C) 2014 The Authors. Published by Elsevier Inc.

  11. A review on recent advances in the numerical simulation for coalbed-methane-recovery process

    SciTech Connect (OSTI)

    Wei, X.R.; Wang, G.X.; Massarotto, P.; Golding, S.D.; Rudolph, V. [University of Queensland, Brisbane, Qld. (Australia)

    2007-12-15

    The recent advances in numerical simulation for primary coalbed methane (CBM) recovery and enhanced coalbed-methane recovery (ECBMR) processes are reviewed, primarily focusing on the progress that has occurred since the late 1980s. Two major issues regarding the numerical modeling will be discussed in this review: first, multicomponent gas transport in in-situ bulk coal and, second, changes of coal properties during methane (CH{sub 4}) production. For the former issues, a detailed review of more recent advances in modeling gas and water transport within a coal matrix is presented. Further, various factors influencing gas diffusion through the coal matrix will be highlighted as well, such as pore structure, concentration and pressure, and water effects. An ongoing bottleneck for evaluating total mass transport rate is developing a reasonable representation of multiscale pore space that considers coal type and rank. Moreover, few efforts have been concerned with modeling water-flow behavior in the coal matrix and its effects on CH{sub 4} production and on the exchange of carbon dioxide (CO{sub 2}) and CH{sub 4}. As for the second issue, theoretical coupled fluid-flow and geomechanical models have been proposed to describe the evolution of pore structure during CH{sub 4} production, instead of traditional empirical equations. However, there is currently no effective coupled model for engineering applications. Finally, perspectives on developing suitable simulation models for CBM production and for predicting CO{sub 2}-sequestration ECBMR are suggested.

  12. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    E-Print Network [OSTI]

    Kneafsey, T.J.

    2012-01-01

    T. and Narita, H. , 2006. Methane hydrate crystal growth ina porous medium filled with methane-saturated liquid water.Kneafsey, T.J. et al. , 2007. Methane hydrate formation and

  13. Methane oxidation rates by AMS

    E-Print Network [OSTI]

    Pack, M; Heintz, M; ReeburGh, WS; Trumbore, SE; Valentine, DL; Xu, X

    2009-01-01

    second case. Number of cases Methane oxidation rates by AMSIn the marine environment methane (CH 4 ) oxidation consumes

  14. Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-06-01

    Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

  15. Control of substrate access to the active site in methane monooxygenase

    E-Print Network [OSTI]

    Lee, Seung Jae

    Methanotrophs consume methane as their major carbon source and have an essential role in the global carbon cycle by limiting escape of this greenhouse gas to the atmosphere. These bacteria oxidize methane to methanol by ...

  16. Energy Policy Seminar Series: Climate impacts of methane-emitting energy technologies

    E-Print Network [OSTI]

    Chen, Kuang-Yu

    of greenhouse gases, most notably methane and carbon dioxide, and these gases have dissimilar properties. This research finds that methane-emitting energy such as natural gas becomes significantly more carbon dioxide

  17. Hydroelectric Reservoirs -the Carbon Dioxide and Methane

    E-Print Network [OSTI]

    Fischlin, Andreas

    Hydroelectric Reservoirs - the Carbon Dioxide and Methane Emissions of a "Carbon Free" Energy an overview on the greenhouse gas production of hydroelectric reservoirs. The goals are to point out the main how big the greenhouse gas emissions from hydroelectric reservoirs are compared to thermo-power plants

  18. 2008 Nature Publishing Group Mississippi Delta subsidence primarily

    E-Print Network [OSTI]

    Törnqvist, Torbjörn E.

    © 2008 Nature Publishing Group LETTERS Mississippi Delta subsidence primarily caused by compaction online: 17 February 2008; doi:10.1038/ngeo129 Coastal subsidence causes sea-level rise, shoreline erosion of protective wetlands is considered a critical factor in the extensive flood damage. The causes of subsidence

  19. Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska

    E-Print Network [OSTI]

    Moridis, G.J.

    2010-01-01

    Mallik 2002 Gas Hydrate Production Research Well Program,Of Methane Hydrate Production Methods To Reservoirs WithNumerical Studies of Gas Production From Methane Hydrates,

  20. Benchmarking the performance of density functional theory and point charge force fields in their description of sI methane hydrate against diffusion Monte Carlo

    SciTech Connect (OSTI)

    Cox, Stephen J.; Michaelides, Angelos; Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ ; Towler, Michael D.; Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE ; Alfč, Dario; Department of Earth Sciences, University College London Gower Street, London WC1E 6BT

    2014-05-07

    High quality reference data from diffusion Monte Carlo calculations are presented for bulk sI methane hydrate, a complex crystal exhibiting both hydrogen-bond and dispersion dominated interactions. The performance of some commonly used exchange-correlation functionals and all-atom point charge force fields is evaluated. Our results show that none of the exchange-correlation functionals tested are sufficient to describe both the energetics and the structure of methane hydrate accurately, while the point charge force fields perform badly in their description of the cohesive energy but fair well for the dissociation energetics. By comparing to ice I{sub h}, we show that a good prediction of the volume and cohesive energies for the hydrate relies primarily on an accurate description of the hydrogen bonded water framework, but that to correctly predict stability of the hydrate with respect to dissociation to ice I{sub h} and methane gas, accuracy in the water-methane interaction is also required. Our results highlight the difficulty that density functional theory faces in describing both the hydrogen bonded water framework and the dispersion bound methane.

  1. Water Management Strategies for Improved Coalbed Methane Production in the Black Warrior Basin

    SciTech Connect (OSTI)

    Pashin, Jack; McIntyre-Redden, Marcella; Mann, Steven; Merkel, David

    2013-10-31

    The modern coalbed methane industry was born in the Black Warrior Basin of Alabama and has to date produced more than 2.6 trillion cubic feet of gas and 1.6 billion barrels of water. The coalbed gas industry in this area is dependent on instream disposal of co-produced water, which ranges from nearly potable sodium-bicarbonate water to hypersaline sodium-chloride water. This study employed diverse analytical methods to characterize water chemistry in light of the regional geologic framework and to evaluate the full range of water management options for the Black Warrior coalbed methane industry. Results reveal strong interrelationships among regional geology, water chemistry, and gas chemistry. Coalbed methane is produced from multiple coal seams in Pennsylvanian-age strata of the Pottsville Coal Interval, in which water chemistry is influenced by a structurally controlled meteoric recharge area along the southeastern margin of the basin. The most important constituents of concern in the produced water include chlorides, ammonia compounds, and organic substances. Regional mapping and statistical analysis indicate that the concentrations of most ionic compounds, metallic substances, and nonmetallic substances correlate with total dissolved solids and chlorides. Gas is effectively produced at pipeline quality, and the only significant impurity is N{sub 2}. Geochemical analysis indicates that the gas is of mixed thermogenic-biogenic origin. Stable isotopic analysis of produced gas and calcite vein fills indicates that widespread late-stage microbial methanogenesis occurred primarily along a CO{sub 2} reduction metabolic pathway. Organic compounds in the produced water appear to have helped sustain microbial communities. Ammonia and ammonium levels increase with total dissolved solids content and appear to have played a role in late-stage microbial methanogenesis and the generation of N{sub 2}. Gas production tends to decline exponentially, whereas water production tends to decline hyperbolically. Hyperbolic decline indicates that water volume is of greatest concern early in the life of a coalbed methane project. Regional mapping indicates that gas production is controlled primarily by the ability to depressurize permeable coal seams that are natively within the steep part of the adsorption isotherm. Water production is greatest within the freshwater intrusion and below thick Cretaceous cover strata and is least in areas of underpressure. Water management strategies include instream disposal, which can be applied effectively in most parts of the basin. Deep disposal may be applicable locally, particularly where high salinity limits the ability to dispose into streams. Artificial wetlands show promise for the management of saline water, especially where the reservoir yield is limited. Beneficial use options include municipal water supply, agricultural use, and industrial use. The water may be of use to an inland shrimp farming industry, which is active around the southwestern coalbed methane fields. The best opportunities for beneficial use are reuse of water by the coalbed methane industry for drilling and hydraulic fracturing. This research has further highlighted opportunities for additional research on treatment efficiency, the origin of nitrogen compounds, organic geochemistry, biogenic gas generation, flow modeling, and computer simulation. Results of this study are being disseminated through a vigorous technology transfer program that includes web resources, numerous presentations to stakeholders, and a variety of technical publications.

  2. Methane Hydrate Field Program

    SciTech Connect (OSTI)

    2013-12-31

    This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

  3. Source of methane and methods to control its formation in single chamber microbial electrolysis cells

    E-Print Network [OSTI]

    Source of methane and methods to control its formation in single chamber microbial electrolysis online 31 March 2009 Keywords: Hydrogen Microbial electrolysis cell (MEC) Methane Single chamber Exoelectrogenic a b s t r a c t Methane production occurs during hydrogen gas generation in microbial electrolysis

  4. Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge Reactor

    E-Print Network [OSTI]

    Mallinson, Richard

    Production of Organic Oxygenates in the Partial Oxidation of Methane in a Silent Electric Discharge to convert methane into useful products such as higher hydrocarbons, synthesis gas, and organic oxygenate is important for a process to have commercial potential. Thus, this study examines the effect methane

  5. UPGRADING METHANE USING ULTRA-FAST THERMAL SWING ADSORPTION

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2004-01-01

    The purpose of this project is to design and demonstrate an approach to upgrade low-BTU methane streams from coal mines to pipeline-quality natural gas. The objective of Phase I of the project was to assess the feasibility of upgrading low-Btu methane streams using ultra-fast thermal swing adsorption (TSA) using Velocys' modular microchannel process technology. The project is on schedule and under budget. For Task 1.1, the open literature, patent information, and vendor contacts were surveyed to identify adsorbent candidates for experimental validation and subsequent demonstration in an MPT-based ultra-fast TSA separation for methane upgrading. The leading candidates for preferential adsorption of methane over nitrogen are highly microporous carbons. A Molecular Gate{trademark} zeolite from Engelhard Corporation has emerged as a candidate. For Task 1.2, experimental evaluation of adsorbents was initiated, and data were collected on carbon (MGN-101) from PICA, Inc. This carbon demonstrated a preferential capacity for methane over nitrogen, as well as a reasonable thermal swing differential capacity for a 90% methane and 10% nitrogen mixture. A similar methane swing capacity at 2 psig was measured. The mixture composition is relevant because gob gas contains nearly 85% methane and must be purified to 97% methane for pipeline quality.

  6. Methane Storage in Metal-Organic Frameworks: Current Records, Surprise Findings, and Challenges

    E-Print Network [OSTI]

    the transition has been a spectacular recent drop in the price of natural gas1 due to deployment of inexpensive not a renewable fuel, natural gas (NG), comprising chiefly methane, has moved to the forefront as a potential is to store methane at very high pressures (250 bar) as is done currently by most natural gas powered vehicles

  7. 2, 11971241, 2005 Control of methane

    E-Print Network [OSTI]

    Boyer, Edmond

    Version Interactive Discussion EGU Abstract The North Sea hosts large coal, oil and gas reservoirs of giant sulphide- oxidizing bacteria above patches of black sediments and carbonate crusts, which are exposed 10 to 50 cm above seafloor forming small reefs. These Methane-Derived Au- thigenic Carbonates

  8. Generating power with drained coal mine methane

    SciTech Connect (OSTI)

    2005-09-01

    The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

  9. Methane Hydrate Advisory Committee Meeting

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof EnergyPresentation:DaisStatesEMCHIEFMeltingMethane

  10. Coalbed Methane (CBM) is natural

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartment of Energyof the CleanClient educationCoalbed Methane

  11. The Optimization of Well Spacing in a Coalbed Methane Reservoir 

    E-Print Network [OSTI]

    Sinurat, Pahala Dominicus

    2012-02-14

    , such as rank of the coal, coal composition, micropores structure, reservoir pressure, molecular properties of gas adsorbed on the internal surface of coal seam, and reservoir temperature3,7. An idealized model of coalbed methane reservoir consists of a... making process. The uncertainties include the coal density, permeability or gas content as parameters of coal properties. Each coalbed methane reservoir property will govern production performance in a certain degree. Some parameters strongly influence...

  12. Methane activation using Kr and Xe in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Lee, Dae Hoon Kim, Kwan-Tae; Kang, Woo Seok; Song, Young-Hoon

    2014-10-15

    Methane has interested many researchers as a possible new energy source, but the high stability of methane causes a bottleneck in methane activation, limiting its practical utilization. To determine how to effectively activate methane using non-thermal plasma, the conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gases—Ar, Kr, and Xe—as additives. In addition to the methane conversion results at various applied voltages, the discharge characteristics such as electron temperature and electron density were calculated through zero-dimensional calculations. Moreover, the threshold energies of excitation and ionization were used to distinguish the dominant particle for activating methane between electrons, excited atoms, and ionized atoms. From the experiments and calculations, the selection of the additive noble gas is found to affect not only the conversion of methane but also the selectivity of product gases even under similar electron temperature and electron density conditions.

  13. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

  14. Methane activation using noble gases in a dielectric barrier discharge reactor

    SciTech Connect (OSTI)

    Jo, Sungkwon; Hoon Lee, Dae; Seok Kang, Woo; Song, Young-Hoon

    2013-08-15

    The conversion of methane is measured in a planar-type dielectric barrier discharge reactor using three different noble gases—He, Ne, and Ar—as additives. The empirical results obtained clearly indicate that methane activation is considerably affected by thy type of noble gas used. Through 0-D calculations, the discharge parameters inside the reactor, i.e., electron temperature and electron density, are estimated using experiment results. A comparison of the discharge characteristics and experimental results shows that the electron temperature is an important factor in achieving high methane activation and the mixture with Ar gas shows the highest methane conversion. These results are constructed using the mechanisms of energy and charge transfer from excited and ionized noble gas atoms to methane molecules, considering the number density of active atoms of noble gases. Finally, electron temperatures obtained for gas mixtures having different reactant compositions and concentrations are analyzed to estimate methane activation.

  15. Methane sources and sinks in Lake Kivu

    E-Print Network [OSTI]

    2011-01-01

    and G. T. Harvey (1973), Methane in Lake Kivu: New datagenes associated with methane? oxidizing archaea, Appl.Pace, and L. Tranvik (2004), Methane emissions from lakes:

  16. Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water

    SciTech Connect (OSTI)

    Song Jin

    2007-05-31

    Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.

  17. Sequestration of CO2 in the Altmark natural gas field, Germany: Mobility control to extend enhanced gas recovery

    E-Print Network [OSTI]

    Rebscher, D.; May, F.; Oldenburg, C.M.

    2006-01-01

    OF CO 2 IN THE ALTMARK NATURAL GAS FIELD, GERMANY: MOBILITYin the depleted Altmark natural gas reservoir, Germany. Ourdioxide or nitrogen in natural gas (methane) reservoirs,

  18. Journal of Electron Spectroscopy and Related Phenomena 155 (2007) 2834 Electron Compton scattering from methane and methane-d4

    E-Print Network [OSTI]

    Hitchcock, Adam P.

    2007-01-01

    from methane and methane-d4 G. Coopera, A.P. Hitchcocka,, C.A. Chatzidimitriou-Dreismannb, M. Vosc]. © 2006 Elsevier B.V. All rights reserved. Keywords: Quasi-elastic electron scattering; Methane; CD4

  19. On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide

    E-Print Network [OSTI]

    Chen, Ray

    On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide Wei­Lambert law for the detection of methane gas. The device combines slow light in a PC waveguide with high absorption path length. A methane concentration of 100 ppm (parts per million) in nitrogen was measured

  20. Full Text HTML Methane can be a problem or a solution, depending on one's viewpoint or circumstance. For

    E-Print Network [OSTI]

    Abstract Full Text HTML Methane can be a problem or a solution, depending on one's viewpoint the researchers want to make hydrogen gas in microbial electrolysis cells (MECs), because making methane reduces hydrogen yield. The researchers have been studying the formation of methane in MECs in an effort to avoid

  1. Modeling methane emissions from the Alaskan Yukon River basin, 19862005, by coupling a large-scale hydrological model

    E-Print Network [OSTI]

    Zhuang, Qianlai

    gradients, and due to variations in methane production and oxidation due to complex freezing and thawing] Methane (CH4), a greenhouse gas, has a much larger radiative forcing potential than CO2, andModeling methane emissions from the Alaskan Yukon River basin, 1986­2005, by coupling a large

  2. Enhanced Microbial Pathways for Methane Production from Oil Shale

    SciTech Connect (OSTI)

    Paul Fallgren

    2009-02-15

    Methane from oil shale can potentially provide a significant contribution to natural gas industry, and it may be possible to increase and continue methane production by artificially enhancing methanogenic activity through the addition of various substrate and nutrient treatments. Western Research Institute in conjunction with Pick & Shovel Inc. and the U.S. Department of Energy conducted microcosm and scaled-up reactor studies to investigate the feasibility and optimization of biogenic methane production from oil shale. The microcosm study involving crushed oil shale showed the highest yield of methane was produced from oil shale pretreated with a basic solution and treated with nutrients. Incubation at 30 C, which is the estimated temperature in the subsurface where the oil shale originated, caused and increase in methane production. The methane production eventually decreased when pH of the system was above 9.00. In the scaled-up reactor study, pretreatment of the oil shale with a basic solution, nutrient enhancements, incubation at 30 C, and maintaining pH at circumneutral levels yielded the highest rate of biogenic methane production. From this study, the annual biogenic methane production rate was determined to be as high as 6042 cu. ft/ton oil shale.

  3. Methane coupling by membrane reactor. First quarterly report, 1997

    SciTech Connect (OSTI)

    Ma, Yi Hua

    1997-05-01

    The Mn-W-Na/SiO{sub 2} catalyst was studied by running the methane coupling reactions at different methane to oxygen ratios, temperatures and dilution gas flow rates. For methane to oxygen ratios less than 3, the C{sub 2} yield was almost the same; and C{sub 2} yield began to decrease as the methane to oxygen ratio was further increased. The optimal temperature observed was around 800{degrees}C, where the C{sub 2} yield reached a maximum value. Increasing the dilution gas (helium) flow rate resulted in higher C{sub 2} selectivity; however, after a certain dilution gas flow rate the C{sub 2} yield began to decrease due to a decrease in methane conversion as a result of the reduced contact time. The stability study of the catalyst showed that, after five successive run cycles, the C{sub 2} yield obtained decreased from 24% to 19% at 780 {degrees}C, and methane, oxygen and helium flow rates of 12.2, 4.1, and 44. 3 mm/min, respectively. XRD analysis showed that, after the reaction, the XRD peaks of the cristabolite and Na{sub 2}WO{sub 4} phases in the catalyst became smaller than those in the fresh catalyst, and that at least one new, unidentified phase was observed. Mn-W-Na/SiO{sub 2} catalyst was used as the methane oxidative coupling catalyst in a porous membrane reactor and its performance was compared with a packed reactor operated at similar conditions. Although the membrane reactor showed lower methane conversion at the same reaction conditions, it gave higher C{sub 2} selectivity and C{sub 2} yield at similar methane conversions.

  4. Simulation study of the effect of well spacing, effect of permeability anisotropy, and effect of Palmer and Mansoori model on coalbed methane production 

    E-Print Network [OSTI]

    Zulkarnain, Ismail

    2006-04-12

    ............................................. 11 3.2.1 Coalbed Methane Reservoir....................................................... 11 3.2.2 Coal Porosity.............................................................................. 13 3.2.3 Gas Storage Properties.................................................................. 14 3.2.4 Adsorption Isotherm .................................................................. 15 3.2.5 Methane Flow Properties of Coal .............................................. 18 3.2.5.1 Gas Diffusion of Coalbed Methane Reservoir...

  5. Velocity of sound in solid methane near melting temperatures 

    E-Print Network [OSTI]

    Whitehead, John Martin

    1968-01-01

    . At this point, the bellows valve, E, was closed and the thermocouple pressure elements monitored for an increase in pressure; and if after several hours no increase in pressure was registered, the system was considered thoroughly out-gassed and free of leaks... PPM 0. 5 PPM Figure 3 is a block diagram of the system into which methane was admitted. From the storage cylinder the methane passed through a Hoke-Phoenix gas-ballast high purity regulator. From needle valve, A, the integrity of the methane...

  6. Methane recovery from animal manures: A current opportunities casebook

    SciTech Connect (OSTI)

    1995-08-01

    This Casebook examines some of the current opportunities for the recovery of methane from the anaerobic digestion of animal manures US livestock operations currently employ four types of anaerobic digester technology: Slurry, plug flow, complete mix, and covered lagoon. An introduction to the engineering economies of these technologies is provided, and possible end-use applications for the methane gas generated by the digestion process are discussed. The economic evaluations are based on engineering studies of digesters that generate electricity from the recovered methane. Regression models, which can be used to estimate digester cost and internal rate of return, are developed from the evaluations.

  7. Discovery of New Materials to Capture Methane | U.S. DOE Office...

    Office of Science (SC) Website

    Methane, a common gas emitted from natural gas systems, landfills, coal mining, waste water treatment and hydrates in the ocean, is both a great energy source and a greenhouse...

  8. Method of determining methane and electrochemical sensor therefor

    DOE Patents [OSTI]

    Zaromb, Solomon (Hinsdale, IL); Otagawa, Takaaki (Westmont, IL); Stetter, Joseph R. (Naperville, IL)

    1986-01-01

    A method and instrument including an electrochemical cell for the detection and measurement of methane in a gas by the oxidation of methane electrochemically at a working electrode in a nonaqueous electrolyte at a voltage about about 1.4 volts versus R.H.E. (the reversible hydrogen electrode potential in the same electrolyte), and the measurement of the electrical signal resulting from the electrochemical oxidation.

  9. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid (Menlo Park, CA)

    1997-01-01

    A membrane separation process combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C.sub.3+ hydrocarbons that might otherwise freeze and plug the cryogenic equipment.

  10. Membrane-augmented cryogenic methane/nitrogen separation

    DOE Patents [OSTI]

    Lokhandwala, K.

    1997-07-15

    A membrane separation process is described which is combined with a cryogenic separation process for treating a gas stream containing methane, nitrogen and at least one other component. The membrane separation process works by preferentially permeating methane and the other component and rejecting nitrogen. The process is particularly useful in removing components such as water, carbon dioxide or C{sub +2} hydrocarbons that might otherwise freeze and plug the cryogenic equipment. 10 figs.

  11. ISSUE PAPER METHANE AVOIDANCE FROM

    E-Print Network [OSTI]

    Brown, Sally

    ISSUE PAPER METHANE AVOIDANCE FROM COMPOSTING An Issue Paper for the: Climate Action Reserve...........................................................................................................39 6.2. Standard Methods for Quantifying Methane from Organic Waste in Landfills...40 6.3. GHG

  12. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    non-marketed natural gas. g Includes methane emissions related to energy, agriculture, waste management, and industrial processes. h Includes nitrous oxide emissions related...

  13. Enhanced coalbed methane recovery

    SciTech Connect (OSTI)

    Mazzotti, M.; Pini, R.; Storti, G. [ETH, Zurich (Switzerland). Inst. of Process Engineering

    2009-01-15

    The recovery of coalbed methane can be enhanced by injecting CO{sub 2} in the coal seam at supercritical conditions. Through an in situ adsorption/desorption process the displaced methane is produced and the adsorbed CO{sub 2} is permanently stored. This is called enhanced coalbed methane recovery (ECBM) and it is a technique under investigation as a possible approach to the geological storage of CO{sub 2} in a carbon dioxide capture and storage system. This work reviews the state of the art on fundamental and practical aspects of the technology and summarizes the results of ECBM field tests. These prove the feasibility of ECBM recovery and highlight substantial opportunities for interdisciplinary research at the interface between earth sciences and chemical engineering.

  14. The Tri--Methane Rearrangement

    E-Print Network [OSTI]

    Cirkva, Vladimir

    The Tri--Methane Rearrangement #12;Církva, Vladimír; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

  15. The Tri--Methane Rearrangement

    E-Print Network [OSTI]

    Cirkva, Vladimir

    The Tri--Methane Rearrangement #12;Cirkva, Vladimir; Zuraw, Michael J.; Zimmerman, Howard E.* Department of Chemistry, University of Wisconsin, Madison, WI 53706 #12;INTRODUCTION The tri--methane of a cyclopentene 5a, but only in crystalline medium. However, in the solution photochemistry of tri--methane system

  16. GLOBAL SOURCES OF METHANE AND THE BENEFITS OF

    E-Print Network [OSTI]

    Bateman, Ian J.

    ; the flaring of natural gas in oil production; in industrial processes and by the inefficient combustion (ESRC). ISSN 0967-8875 #12;Abstract Methane is an important greenhouse gas, the abatement of which-benefit analysis, such as the discount rate, the future trends in agricultural prices and the value of global

  17. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  18. TITAN'S TRANSPORT-DRIVEN METHANE CYCLE

    SciTech Connect (OSTI)

    Mitchell, Jonathan L.

    2012-09-10

    The mechanisms behind the occurrence of large cloud outbursts and precipitation on Titan have been disputed. A global- and annual-mean estimate of surface fluxes indicated only 1% of the insolation, or {approx}0.04 W m{sup -2}, is exchanged as sensible and/or latent fluxes. Since these fluxes are responsible for driving atmospheric convection, it has been argued that moist convection should be quite rare and precipitation even rarer, even if evaporation globally dominates the surface-atmosphere energy exchange. In contrast, climate simulations indicate substantial cloud formation and/or precipitation. We argue that the top-of-atmosphere (TOA) radiative imbalance is diagnostic of horizontal heat transport by Titan's atmosphere, and thus constrains the strength of the methane cycle. Simple calculations show the TOA radiative imbalance is {approx}0.5-1 W m{sup -2} in Titan's equatorial region, which implies 2-3 MW of latitudinal heat transport by the atmosphere. Our simulation of Titan's climate suggests this transport may occur primarily as latent heat, with net evaporation at the equator and net accumulation at higher latitudes. Thus, the methane cycle could be 10-20 times previous estimates. Opposing seasonal transport at solstices, compensation by sensible heat transport, and focusing of precipitation by large-scale dynamics could further enhance the local, instantaneous strength of Titan's methane cycle by a factor of several. A limited supply of surface liquids in regions of large surface radiative imbalance may throttle the methane cycle, and if so, we predict more frequent large storms over the lakes district during Titan's northern summer.

  19. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect (OSTI)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

  20. Direct Aromaization of Methane

    SciTech Connect (OSTI)

    George Marcelin

    1997-01-15

    The thermal decomposition of methane offers significant potential as a means of producing higher unsaturated and aromatic hydrocarbons when the extent of reaction is limited. Work in the literature previous to this project had shown that cooling the product and reacting gases as the reaction proceeds would significantly reduce or eliminate the formation of solid carbon or heavier (Clo+) materials. This project studied the effect and optimization of the quenching process as a means of increasing the amount of value added products during the pyrolysis of methane. A reactor was designed to rapidly quench the free-radical combustion reaction so as to maximize the yield of aromatics. The use of free-radical generators and catalysts were studied as a means of lowering the reaction temperature. A lower reaction temperature would have the benefits of more rapid quenching as well as a more feasible commercial process due to savings realized in energy and material of construction costs. It was the goal of the project to identify promising routes from methane to higher hydrocarbons based on the pyrolysis of methane.

  1. Development of computer simulations for landfill methane recovery

    SciTech Connect (OSTI)

    Massmann, J.W.; Moore, C.A.; Sykes, R.M.

    1981-12-01

    Two- and three-dimensional finite-difference computer programs simulating methane recovery systems in landfills have been developed. These computer programs model multicomponent combined pressure and diffusional flow in porous media. Each program and the processes it models are described in this report. Examples of the capabilities of each program are also presented. The two-dimensional program was used to simulate methane recovery systems in a cylindrically shaped landfill. The effects of various pump locations, geometries, and extraction rates were determined. The three-dimensional program was used to model the Puente Hills landfill, a field test site in southern California. The biochemical and microbiological details of methane generation in landfills are also given. Effects of environmental factors, such as moisture, oxygen, temperature, and nutrients on methane generation are discussed and an analytical representation of the gas generation rate is developed.

  2. Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartmentEnergy comparingDeep January 2012 PURPOSE ThisProject

  3. Pore-scale mechanisms of gas flow in tight sand reservoirs

    E-Print Network [OSTI]

    Silin, D.

    2011-01-01

    include tight gas sands, gas shales, and coal-bed methane.Figure 3. Although the gas-shale production grows at a

  4. Changes in greenhouse gas emissions such as methane (CH4) and carbon dioxide (CO2) from high-latitude wetlands in a warming climate may have important implications for projections of global warming, due to the large amounts of carbon stored in high-

    E-Print Network [OSTI]

    Washington at Seattle, University of

    potential of methane. As much as 1/3 of global natural methane emissions come from high latitudes. Efforts and Heimann (2000) with modifications described in Walter et al (2001a ) · soil methane production, and transport of methane by diffusion, ebullition, and through plants modeled explicitly · methane production

  5. Shale Gas Application in Hydraulic Fracturing Market is likely...

    Open Energy Info (EERE)

    on unconventional reservoirs such as coal bed methane, tight gas, tight oil, shale gas, and shale oil. Over the period of time, hydraulic fracturing technique has found...

  6. DOE Launches Natural Gas Infrastructure R&D Program Enhancing...

    Energy Savers [EERE]

    DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions DOE Launches Natural Gas...

  7. Methane conversion to methanol

    SciTech Connect (OSTI)

    Noble, R.D.; Falconer, J.L.

    1992-06-01

    The objective of this research study is to demonstrate the effectiveness of a catalytic membrane reactor for the partial oxidation of methane. The specific goals are to demonstrate that we can improve product yield, demonstrate the optimal conditions for membrane reactor operation, determine the transport properties of the membrane, and provide demonstration of the process at the pilot plant scale. The last goal will be performed by Unocal, Inc., our industrial partner, upon successful completion of this study.

  8. Methane conversion to methanol

    SciTech Connect (OSTI)

    Noble, R.D.; Falconer, J.L.

    1992-01-01

    The objective of this research study is to demonstrate the effectiveness of a catalytic membrane reactor for the partial oxidation of methane. The specific goals are to demonstrate that we can improve product yield, demonstrate the optimal conditions for membrane reactor operation, determine the transport properties of the membrane, and provide demonstration of the process at the pilot plant scale. The last goal will be performed by Unocal, Inc., our industrial partner, upon successful completion of this study.

  9. Gas hydrates: technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    The DOE Morgantown Energy Technology Center (METC) implemented a gas hydrates R and D program that emphasized an understanding of the resource through (1) an assessment of current technology, (2) the characterization of gas hydrate geology and reservoir engineering, and (3) the development of diagnostic tools and methods. Recovery of natural gas from gas hydrates will be made possible through (1) improved instrumentation and recovery methods, (2) developing the capability to predict production performance, and (3) field verification of recovery methods. Gas hydrates research has focused primarily on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for detailed investigation. A Geologic Analysis System (GAS) was developed. GAS contains approximately 30 software packages and can manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. The system also contains all well information currently available from the Alaskan North Slope area. Laboratory research on gas hydrates includes the characterization of the physical system, which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran (THF), consolidated rock cores, frost base mixtures, water/ice-base mixtures, and water-base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by DOE/METC. More recently, natural hydrate samples acquired from the Gulf of Mexico are being tested. Modeling and systems analysis work has focused on the development of GAS and preliminary gas hydrate production models. 23 refs., 18 figs., 6 tabs.

  10. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  11. VIBRATION->VIBRATION ENERGY TRANSFER IN METHANE

    E-Print Network [OSTI]

    Hess, Peter

    2012-01-01

    VIBRATION ENERGY TRANSFER IN METHANE Peter Hess, A. H. Kung,Rotation Spectra of Methane, U.S. Nat'L· Tech. Inform.tret t tllll. I. INTRODUCTION Methane is a relatively simple

  12. High Methane Storage Capacity in Aluminum Metal-Organic Felipe Gandara, Hiroyasu Furukawa, Seungkyu Lee, and Omar M. Yaghi*

    E-Print Network [OSTI]

    Yaghi, Omar M.

    Information ABSTRACT: The use of porous materials to store natural gas in vehicles requires large amounts , and between 5 and 80 bar, 230 cm3 cm-3 . Methane is the main component of natural gas and represents about two

  13. Preliminary formation analysis for compressed air energy storage in depleted natural gas reservoirs : a study for the DOE Energy Storage Systems Program.

    SciTech Connect (OSTI)

    Gardner, William Payton

    2013-06-01

    The purpose of this study is to develop an engineering and operational understanding of CAES performance for a depleted natural gas reservoir by evaluation of relative permeability effects of air, water and natural gas in depleted natural gas reservoirs as a reservoir is initially depleted, an air bubble is created, and as air is initially cycled. The composition of produced gases will be evaluated as the three phase flow of methane, nitrogen and brine are modeled. The effects of a methane gas phase on the relative permeability of air in a formation are investigated and the composition of the produced fluid, which consists primarily of the amount of natural gas in the produced air are determined. Simulations of compressed air energy storage (CAES) in depleted natural gas reservoirs were carried out to assess the effect of formation permeability on the design of a simple CAES system. The injection of N2 (as a proxy to air), and the extraction of the resulting gas mixture in a depleted natural gas reservoir were modeled using the TOUGH2 reservoir simulator with the EOS7c equation of state. The optimal borehole spacing was determined as a function of the formation scale intrinsic permeability. Natural gas reservoir results are similar to those for an aquifer. Borehole spacing is dependent upon the intrinsic permeability of the formation. Higher permeability allows increased injection and extraction rates which is equivalent to more power per borehole for a given screen length. The number of boreholes per 100 MW for a given intrinsic permeability in a depleted natural gas reservoir is essentially identical to that determined for a simple aquifer of identical properties. During bubble formation methane is displaced and a sharp N2methane boundary is formed with an almost pure N2 gas phase in the bubble near the borehole. During cycling mixing of methane and air occurs along the boundary as the air bubble boundary moves. The extracted gas mixture changes as a function of time and proximity of the bubble boundary to the well. For all simulations reported here, with a formation radius above 50 m the maximum methane composition in the produced gas phase was less than 0.5%. This report provides an initial investigation of CAES in a depleted natural gas reservoir, and the results will provide useful guidance in CAES system investigation and design in the future.

  14. ARM - Methane Background Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska Outreach HomepolarizationMeasurementsWarmingMethane Background

  15. Sorption of Methane and Ethane on Belgian Black Shale Using a Manometric Setup

    E-Print Network [OSTI]

    Cirpka, Olaf Arie

    Sorption of Methane and Ethane on Belgian Black Shale Using a Manometric Setup Naeeme Danesh . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 2 Fundamentals 3 2.1 Shales.1.2 Shale characteristics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 2.1.3 Shale gas

  16. Determining the Fate of Methane Released from the Seafloor in Deep and Shallow Water Environments 

    E-Print Network [OSTI]

    Du, Mengran

    2014-08-12

    Marine gas seeps and accidental marine oil spills are sources of methane (CH_(4)) to the ocean, and potentially to the atmosphere, though the magnitude of the fluxes and dynamics of these systems are poorly defined. For example, the ultimate...

  17. Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts

    E-Print Network [OSTI]

    Blaylock, Donnie Wayne

    2011-01-01

    The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

  18. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    E-Print Network [OSTI]

    Kwon, T.H.

    2012-01-01

    composed of methane and ethane”; The 6th InternationalGupta et al. (2008) 24 Ethane hydrate (h ? l + g) Nakagawamol gas. 12 On the contrary, ethane (C 2 H 6 ) hydrate (sI

  19. Biofuels: Microbially Generated Methane and

    E-Print Network [OSTI]

    Wood, Thomas K.

    ) and methane (CH4) from renewable biomass has the potential to con- tribute to reducing dependence on fossilBiofuels: Microbially Generated Methane and Hydrogen Michael J McAnulty, Pennsylvania State, USA James G Ferry, Pennsylvania State University, University Park, Pennsylvania, USA The production

  20. RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RICH METHANE PREMIXED LAMINAR FLAMES DOPED BY LIGHT UNSATURATED HYDROCARBONS PART I: ALLENE developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reaction pathways2007 #12;3 INTRODUCTION Soots and polyaromatic hydrocarbons (PAH), which are present in the exhaust gas

  1. Direct Biological Conversion of Electrical Current into Methane by

    E-Print Network [OSTI]

    Building, The Pennsylvania State University, University Park, Pennsylvania 16802 Received December 12, 2008 to a plain carbon cathode where only small amounts of hydrogen gas could be produced. Both produced from renewable energy sources (such as wind, solar, or biomass) into a biofuel (methane) as well

  2. Coal mine methane global review

    SciTech Connect (OSTI)

    2008-07-01

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  3. Methane Stakeholder Roundtables | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy AEnergy Managing Swimming PoolCommercial IndustrialDepartment of68Methane

  4. Kentucky Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillionReservesReserves (BillionCoalbed Methane

  5. MethaneHydrateRD_FC.indd

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Methane Hydrate Program Annual Report to Congress

  6. Field Exploration of Methane Seep Near Atqasuk

    SciTech Connect (OSTI)

    Katey Walter, Dennis Witmer, Gwen Holdmann

    2008-12-31

    Methane (CH{sub 4}) in natural gas is a major energy source in the U.S., and is used extensively on Alaska's North Slope, including the oilfields in Prudhoe Bay, the community of Barrow, and the National Petroleum Reserve, Alaska (NPRA). Smaller villages, however, are dependent on imported diesel fuel for both power and heating, resulting in some of the highest energy costs in the U.S. and crippling local economies. Numerous CH{sub 4} gas seeps have been observed on wetlands near Atqasuk, Alaska (in the NPRA), and initial measurements have indicated flow rates of 3,000-5,000 ft{sup 3} day{sup -1} (60-100 kg CH{sub 4} day{sup -1}). Gas samples collected in 1996 indicated biogenic origin, although more recent sampling indicated a mixture of biogenic and thermogenic gas. In this study, we (1) quantified the amount of CH{sub 4} generated by several seeps and evaluated their potential use as an unconventional gas source for the village of Atqasuk; (2) collected gas and analyzed its composition from multiple seeps several miles apart to see if the source is the same, or if gas is being generated locally from isolated biogenic sources; and (3) assessed the potential magnitude of natural CH{sub 4} gas seeps for future use in climate change modeling.

  7. Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

    SciTech Connect (OSTI)

    Rachor, Ingke; Gebert, Julia; Groengroeft, Alexander; Pfeiffer, Eva-Maria

    2011-05-15

    The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of atmospheric air. For one material with elevated levels of fine particles and high organic matter content, methane production impeded the quantification of methane oxidation potentials. Regarding the design of landfill cover layers it was concluded that the magnitude of the expected methane load, the texture and expected compaction of the cover material are key variables that need to be known. Based on these, a column study can serve as an appropriate testing system to determine the methane oxidation capacity of a soil intended as landfill cover material.

  8. 7.4 Landfill Methane Utilization

    Broader source: Energy.gov [DOE]

    A chapter on Landfill Methane Utilization from the Clean Energy Strategies for Local Governments publication.

  9. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  10. Methane emissions from upland forest soils and vegetation

    E-Print Network [OSTI]

    Megonigal, ABB

    2008-01-01

    Crill. 2006. A source of methane from upland forests in thecontrolling atmospheric methane con- sumption by temperateand T.B. Parkin. 2001. Methane oxidation and produc- tion

  11. MARINE BIOMASS SYSTEM: ANAEROBIC DIGESTION AND PRODUCTION OF METHANE

    E-Print Network [OSTI]

    Haven, Kendall F.

    2011-01-01

    AND PRODUCTION OF METHANE Lawrence Berkeley LaboratoryDIGESTION AND PRODUCTION OF METHANE Kendall F. Haven MarkArrangement Kelp to Methane Processing Plant Schematic.

  12. Microbe-Metazoan interactions at Pacific Ocean methane seeps

    E-Print Network [OSTI]

    Thurber, Andrew R

    2010-01-01

    B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

  13. Microbe-metazoan interactions at Pacific Ocean methane seeps

    E-Print Network [OSTI]

    Thurber, Andrew Reichmann

    2010-01-01

    B) and those present within methane seep Euryarchaea ( PMI,margin: the influence of methane seeps and oxygen minimumisotope signatures and methane use by New Zealand cold seep

  14. Methane and Methanotrophic Bacteria as a Biotechnological Platform

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fuels from methane: a sustainable, abundant resource that does not compete with the human food chain 3 Sustainable Methane * Methane can be captured from anaerobic digestion of...

  15. Identification of the source of methane at a hazardous waste treatment facility using isotopic analysis

    SciTech Connect (OSTI)

    Hackley, K.C.; Liu, C.L. (Illinois State Geological Survey, Peabody, IL (United States)); Trainor, D.P. (Dames and Moore, Madison, WI (United States))

    1992-01-01

    Isotopic analyses have been used to determine the source of methane in subsurface sediments at a hazardous waste treatment facility in the Lake Calumet area of Chicago, Illinois. The study area is surrounded by landfills and other waste management operations and has a long history of waste disposal. The facility property consists of land constructed of approximately 15 feet of fill placed over lake sediments. The fill is underlain by successively older lacustrine and glacial till deposits to a maximum depth of approximately 80 feet. During a subsurface investigation of the site performed for a RCRA Facility Investigation of former solid waste management units (SWMUs) in the fill, significant quantities of methane were encountered in the natural deposits. Gas samples were collected from the headspace of 11 piezometers screened at depths of approximately 30, 40, and 50 feet beneath the surface. Methane concentrations up to 75% by volume were observed in some of the piezometers. Stable isotope analyses were completed on methane and associated CO[sub 2] separated from the gas samples. Radiocarbon (C-14) analyses were also completed on several of the samples. The delta C-13 results for the intermediate and deep zones are indicative of methane produced by microbial reduction of CO[sub 2]. The methane occurring in the shallow zone appears to be a mixture of methane from the intermediate zone and methane produced by microbial fermentation of naturally (nonanthropogenic) buried organic matter within the shallow lacustrine sediments. According to the isotopic and chemical results, the methane does not appear to be related to gas generation from nearby landfills or from organic wastes previously placed in the former facility SWMUs.

  16. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

  17. Characterization of Methane Degradation and Methane-Degrading Microbes in Alaska Coastal Water

    SciTech Connect (OSTI)

    David Kirchman

    2011-12-31

    The net flux of methane from methane hydrates and other sources to the atmosphere depends on methane degradation as well as methane production and release from geological sources. The goal of this project was to examine methane-degrading archaea and organic carbon oxidizing bacteria in methane-rich and methane-poor sediments of the Beaufort Sea, Alaska. The Beaufort Sea system was sampled as part of a multi-disciplinary expedition (â??Methane in the Arctic Shelfâ?ť or MIDAS) in September 2009. Microbial communities were examined by quantitative PCR analyses of 16S rRNA genes and key methane degradation genes (pmoA and mcrA involved in aerobic and anaerobic methane degradation, respectively), tag pyrosequencing of 16S rRNA genes to determine the taxonomic make up of microbes in these sediments, and sequencing of all microbial genes (â??metagenomesâ?ť). The taxonomic and functional make-up of the microbial communities varied with methane concentrations, with some data suggesting higher abundances of potential methane-oxidizing archaea in methane-rich sediments. Sequence analysis of PCR amplicons revealed that most of the mcrA genes were from the ANME-2 group of methane oxidizers. According to metagenomic data, genes involved in methane degradation and other degradation pathways changed with sediment depth along with sulfate and methane concentrations. Most importantly, sulfate reduction genes decreased with depth while the anaerobic methane degradation gene (mcrA) increased along with methane concentrations. The number of potential methane degradation genes (mcrA) was low and inconsistent with other data indicating the large impact of methane on these sediments. The data can be reconciled if a small number of potential methane-oxidizing archaea mediates a large flux of carbon in these sediments. Our study is the first to report metagenomic data from sediments dominated by ANME-2 archaea and is one of the few to examine the entire microbial assemblage potentially involved in anaerobic methane oxidation.

  18. Engineering Development of Ceramic Membrane Reactor System for Converting Natural Gas to Hydrogen and Synthesis Gas for Liquid Transportation Fuels

    SciTech Connect (OSTI)

    Air Products and Chemicals

    2008-09-30

    An Air Products-led team successfully developed ITM Syngas technology from the concept stage to a stage where a small-scale engineering prototype was about to be built. This technology produces syngas, a gas containing carbon monoxide and hydrogen, by reacting feed gas, primarily methane and steam, with oxygen that is supplied through an ion transport membrane. An ion transport membrane operates at high temperature and oxygen ions are transported through the dense membrane's crystal lattice when an oxygen partial pressure driving force is applied. This development effort solved many significant technical challenges and successfully scaled-up key aspects of the technology to prototype scale. Throughout the project life, the technology showed significant economic benefits over conventional technologies. While there are still on-going technical challenges to overcome, the progress made under the DOE-funded development project proved that the technology was viable and continued development post the DOE agreement would be warranted.

  19. Computational Design of Metal-Organic Frameworks Based on Stable Zirconium Building Units for Storage and Delivery of Methane

    E-Print Network [OSTI]

    densification strategies such as compressed natural gas (CNG) (250 bar) or liquefied natural gas (LNG) (111 K applications. 1. INTRODUCTION Natural gas (NG), which is mainly composed of methane, is an attractive midterm widely adopted. Therefore, alternative densification strategies such as adsorbed natural gas (ANG

  20. Reducing Open Cell Landfill Methane Emissions with a Bioactive Alternative Daily

    SciTech Connect (OSTI)

    Helene Hilger; James Oliver; Jean Bogner; David Jones

    2009-03-31

    Methane and carbon dioxide are formed in landfills as wastes degrade. Molecule-for-molecule, methane is about 20 times more potent than carbon dioxide at trapping heat in the earth's atmosphere, and thus, it is the methane emissions from landfills that are scrutinized. For example, if emissions composed of 60% methane and 40% carbon dioxide were changed to a mix that was 40% methane and 60% carbon dioxide, a 30% reduction in the landfill's global warming potential would result. A 10% methane, 90% carbon dioxide ratio will result in a 75% reduction in global warming potential compared to the baseline. Gas collection from a closed landfill can reduce emissions, and it is sometimes combined with a biocover, an engineered system where methane oxidizing bacteria living in a medium such as compost, convert landfill methane to carbon dioxide and water. Although methane oxidizing bacteria merely convert one greenhouse gas (methane) to another (carbon dioxide), this conversion can offer significant reductions in the overall greenhouse gas contribution, or global warming potential, associated with the landfill. What has not been addressed to date is the fact that methane can also escape from a landfill when the active cell is being filled with waste. Federal regulations require that newly deposited solid waste to be covered daily with a 6 in layer of soil or an alternative daily cover (ADC), such as a canvas tarp. The aim of this study was to assess the feasibility of immobilizing methane oxidizing bacteria into a tarp-like matrix that could be used for alternative daily cover at open landfill cells to prevent methane emissions. A unique method of isolating methanotrophs from landfill cover soil was used to create a liquid culture of mixed methanotrophs. A variety of prospective immobilization techniques were used to affix the bacteria in a tarp-like matrix. Both gel encapsulation of methanotrophs and gels with liquid cores containing methanotrophs were readily made but prone to rapid desiccation. Bacterial adsorption onto foam padding, natural sponge, and geotextile was successful. The most important factor for success appeared to be water holding capacity. Prototype biotarps made with geotextiles plus adsorbed methane oxidizing bacteria were tested for their responses to temperature, intermittent starvation, and washing (to simulate rainfall). The prototypes were mesophilic, and methane oxidation activity remained strong after one cycle of starvation but then declined with repeated cycles. Many of the cells detached with vigorous washing, but at least 30% appeared resistant to sloughing. While laboratory landfill simulations showed that four-layer composite biotarps made with two different types of geotextile could remove up to 50% of influent methane introduced at a flux rate of 22 g m{sup -2} d{sup -1}, field experiments did not yield high activity levels. Tests revealed that there were high hour-to-hour flux variations in the field, which, together with frequent rainfall events, confounded the field testing. Overall, the findings suggest that a methanotroph embedded biotarp appears to be a feasible strategy to mitigate methane emission from landfill cells, although the performance of field-tested biotarps was not robust here. Tarps will likely be best suited for spring and summer use, although the methane oxidizer population may be able to shift and adapt to lower temperatures. The starvation cycling of the tarp may require the capacity for intermittent reinoculation of the cells, although it is also possible that a subpopulation will adapt to the cycling and become dominant. Rainfall is not expected to be a major factor, because a baseline biofilm will be present to repopulate the tarp. If strong performance can be achieved and documented, the biotarp concept could be extended to include interception of other compounds beyond methane, such as volatile aromatic hydrocarbons and chlorinated solvents.

  1. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01

    and stable isotope compositions of natural gas hydrates: acarbon isotopic composition of methane from natural gases of

  2. POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE

    E-Print Network [OSTI]

    Chappellaz, Jérôme

    POSSIBLE ROLE OF WETLANDS, PERMAFROST, AND METHANE HYDRATES IN THE METHANE CYCLE UNDER FUTURE the available scientific literature on how natural sources and the atmospheric fate of methane may be affected by future climate change. We discuss how processes governing methane wetland emissions, per- mafrost thawing

  3. VIBRATION->VIBRATION ENERGY TRANSFER IN METHANE

    E-Print Network [OSTI]

    Hess, Peter

    2012-01-01

    Submitted to the Journal of Chemical Physics VIBRATIONVIBRATION ENERGY TRANSFER IN METHANE Peter Hess, A. H. Kung,L K. Fox, Analysis of Vibration-Rotation Spectra of Methane,

  4. Nonequilibrium clumped isotope signals in microbial methane

    E-Print Network [OSTI]

    Wang, David T.

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

  5. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA); D'Este, Joseph R. (Pittsburgh, PA)

    1998-01-01

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time.

  6. Method for the photocatalytic conversion of methane

    DOE Patents [OSTI]

    Noceti, R.P.; Taylor, C.E.; D`Este, J.R.

    1998-02-24

    A method for converting methane to methanol is provided comprising subjecting the methane to visible light in the presence of a catalyst and an electron transfer agent. Another embodiment of the invention provides for a method for reacting methane and water to produce methanol and hydrogen comprising preparing a fluid containing methane, an electron transfer agent and a photolysis catalyst, and subjecting said fluid to visible light for an effective period of time. 3 figs.

  7. Participant Support Costs Participant support is often provided for awards made primarily for organized training,

    E-Print Network [OSTI]

    Salama, Khaled

    Participant Support Costs Participant support is often provided for awards made primarily costs cannot be used for any other purpose and thus cannot be rebudgeted into other areas without sponsor approval. The purpose of these funds is to support the costs of individual participants

  8. Methane adsorption on Devonian shales 

    E-Print Network [OSTI]

    Li, Fan-Chang

    1992-01-01

    METHANE ADSORPTION ON DEVONIAN SHALES A Thesis by FAN-CHANG LI Submitted to thc Office of Graclua4e Sturiics of texas AgiM Ulllvel'sliy in pari, ial fulfilhuent of t, hc requirements I'or t, hc degree of ii IAS'I'Elf OF SCIL'NCE December... 1992 Major Subject, : Chemical Engineering METHANE ADSORPTION ON DEVONIAN SHALES A Thesis l&y I'AN-CHANC LI Approved as to style and contcut by: A. T. 'vtratson (Chair of Commitl. ee) John C. Slattery (Member) Bruce . Hcrhcrt (Memhcr...

  9. Methane Activation Structural and Mechanistic Requirements for

    E-Print Network [OSTI]

    Iglesia, Enrique

    Methane Activation Structural and Mechanistic Requirements for Methane Activation and Chemical and petrochemical processes and in fuel cells. The strong bonds in CH4 (439 kJmolŔ1 [1] ) and the endothermic nature by BP as part of the Methane Conversion Cooperative Research Program at the University of California

  10. Earth'sFuture Remote sensing of fugitive methane emissions from oil and

    E-Print Network [OSTI]

    Dickerson, Russell R.

    Earth'sFuture Remote sensing of fugitive methane emissions from oil and gas production in North and tight oil reservoirs to exploit formerly inaccessible or unprofitable energy resources in rock and oil provide an opportunity to achieve energy self-sufficiency and to reduce greenhouse gas emissions

  11. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  12. Variability of the methane trapping in martian subsurface clathrate hydrates

    E-Print Network [OSTI]

    Caroline Thomas; Olivier Mousis; Sylvain Picaud; Vincent Ballenegger

    2008-10-23

    Recent observations have evidenced traces of methane CH4 heterogeneously distributed in the martian atmosphere. However, because the lifetime of CH4 in the atmosphere of Mars is estimated to be around 300-600 years on the basis of photochemistry, its release from a subsurface reservoir or an active primary source of methane have been invoked in the recent literature. Among the existing scenarios, it has been proposed that clathrate hydrates located in the near subsurface of Mars could be at the origin of the small quantities of the detected CH4. Here, we accurately determine the composition of these clathrate hydrates, as a function of temperature and gas phase composition, by using a hybrid statistical thermodynamic model based on experimental data. Compared to other recent works, our model allows us to calculate the composition of clathrate hydrates formed from a more plausible composition of the martian atmosphere by considering its main compounds, i.e. carbon dioxyde, nitrogen and argon, together with methane. Besides, because there is no low temperature restriction in our model, we are able to determine the composition of clathrate hydrates formed at temperatures corresponding to the extreme ones measured in the polar caps. Our results show that methane enriched clathrate hydrates could be stable in the subsurface of Mars only if a primitive CH4-rich atmosphere has existed or if a subsurface source of CH4 has been (or is still) present.

  13. Analysis of the Development of Messoyakha Gas Field: A Commercial Gas Hydrate Reservoir 

    E-Print Network [OSTI]

    Omelchenko, Roman 1987-

    2012-12-11

    Natural gas is an important energy source that contributes up to 25% of the total US energy reserves (DOE 2011). An increase in natural gas demand spurs further development of unconventional resources, including methane hydrate (Rajnauth 2012...

  14. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

  15. Methane production by attached film

    DOE Patents [OSTI]

    Jewell, William J. (202 Eastwood Ave., Ithaca, NY 14850)

    1981-01-01

    A method for purifying wastewater of biodegradable organics by converting the organics to methane and carbon dioxide gases is disclosed, characterized by the use of an anaerobic attached film expanded bed reactor for the reaction process. Dilute organic waste material is initially seeded with a heterogeneous anaerobic bacteria population including a methane-producing bacteria. The seeded organic waste material is introduced into the bottom of the expanded bed reactor which includes a particulate support media coated with a polysaccharide film. A low-velocity upward flow of the organic waste material is established through the bed during which the attached bacterial film reacts with the organic material to produce methane and carbon dioxide gases, purified water, and a small amount of residual effluent material. The residual effluent material is filtered by the film as it flows upwardly through the reactor bed. In a preferred embodiment, partially treated effluent material is recycled from the top of the bed to the bottom of the bed for further treatment. The methane and carbon dioxide gases are then separated from the residual effluent material and purified water.

  16. Methane generation from waste materials

    DOE Patents [OSTI]

    Samani, Zohrab A. (Las Cruces, NM); Hanson, Adrian T. (Las Cruces, NM); Macias-Corral, Maritza (Las Cruces, NM)

    2010-03-23

    An organic solid waste digester for producing methane from solid waste, the digester comprising a reactor vessel for holding solid waste, a sprinkler system for distributing water, bacteria, and nutrients over and through the solid waste, and a drainage system for capturing leachate that is then recirculated through the sprinkler system.

  17. Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production

    E-Print Network [OSTI]

    Di Camillo, Nicole G.

    2011-01-01

    Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THE2011] METHANE DIGESTERS AND BIOGAS RECOVERY methane, and 64%

  18. OXIDATIVE COUPLING OF METHANE USING INORGANIC MEMBRANE REACTORS

    SciTech Connect (OSTI)

    Dr. Y.H. Ma; Dr. W.R. Moser; Dr. A.G. Dixon; Dr. A.M. Ramachandra; Dr. Y. Lu; C. Binkerd

    1998-04-01

    The objective of this research is to study the oxidative coupling of methane in catalytic inorganic membrane reactors. A specific target is to achieve conversion of methane to C{sub 2} hydrocarbons at very high selectivity and higher yields than in conventional non-porous, co-feed, fixed bed reactors by controlling the oxygen supply through the membrane. A membrane reactor has the advantage of precisely controlling the rate of delivery of oxygen to the catalyst. This facility permits balancing the rate of oxidation and reduction of the catalyst. In addition, membrane reactors minimize the concentration of gas phase oxygen thus reducing non selective gas phase reactions, which are believed to be a main route for the formation of CO{sub x} products. Such gas phase reactions are a cause of decreased selectivity in the oxidative coupling of methane in conventional flow reactors. Membrane reactors could also produce higher product yields by providing better distribution of the reactant gases over the catalyst than the conventional plug flow reactors. Membrane reactor technology also offers the potential for modifying the membranes both to improve catalytic properties as well as to regulate the rate of the permeation/diffusion of reactants through the membrane to minimize by-product generation. Other benefits also exist with membrane reactors, such as the mitigation of thermal hot-spots for highly exothermic reactions such as the oxidative coupling of methane. The application of catalytically active inorganic membranes has potential for drastically increasing the yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity.

  19. Assessing the Efficacy of the Aerobic Methanotrophic Biofilter in Methane Hydrate Environments

    SciTech Connect (OSTI)

    Valentine, David

    2012-09-30

    In October 2008 the University of California at Santa Barbara (UCSB) initiated investigations of water column methane oxidation in methane hydrate environments, through a project funded by the National Energy Technology Laboratory (NETL) entitled: assessing the efficacy of the aerobic methanotrophic biofilter in methane hydrate environments. This Final Report describes the scientific advances and discoveries made under this award as well as the importance of these discoveries in the broader context of the research area. Benthic microbial mats inhabit the sea floor in areas where reduced chemicals such as sulfide reach the more oxidizing water that overlies the sediment. We set out to investigate the role that methanotrophs play in such mats at locations where methane reaches the sea floor along with sulfide. Mats were sampled from several seep environments and multiple sets were grown in-situ at a hydrocarbon seep in the Santa Barbara Basin. Mats grown in-situ were returned to the laboratory and used to perform stable isotope probing experiments in which they were treated with 13C-enriched methane. The microbial community was analyzed, demonstrating that three or more microbial groups became enriched in methane?s carbon: methanotrophs that presumably utilize methane directly, methylotrophs that presumably consume methanol excreted by the methanotrophs, and sulfide oxidizers that presumably consume carbon dioxide released by the methanotrophs and methylotrophs. Methanotrophs reached high relative abundance in mats grown on methane, but other bacterial processes include sulfide oxidation appeared to dominate mats, indicating that methanotrophy is not a dominant process in sustaining these benthic mats, but rather a secondary function modulated by methane availability. Methane that escapes the sediment in the deep ocean typically dissolved into the overlying water where it is available to methanotrophic bacteria. We set out to better understand the efficacy of this process as a biofilter by studying the distribution of methane oxidation and disposition of methanotrophic populations in the Pacific Ocean. We investigated several environments including the basins offshore California, the continental margin off Central America, and the shallow waters around gas seeps. We succeeded in identifying the distributions of activity in these environments, identified potential physical and chemical controls on methanotrophic activity, we further revealed details about the methanotrophic communities active in these settings, and we developed new approaches to study methanotrophic communities. These findings should improve our capacity to predict the methanotrophic response in ocean waters, and further our ability to generate specific hypotheses as to the ecology and efficacy of pelagic methanotrophic communites. The discharge of methane and other hydrocarbons to Gulf of Mexico that followed the sinking of the Deepwater Horizon provided a unique opportunity to study the methanotorphic biofilter in the deep ocean environment. We set out to understand the consumption of methane and the bloom of methanotrophs resulting from this event, as a window into the regional scale release of gas hydrate under rapid warming scenarios. We found that other hydrocarbon gases, notably propane and ethane, were preferred for consumption over methane, but that methane consumption accelerated rapidly and drove the depletion of methane within a matter of months after initial release. These results revealed the identity of the responsible community, and point to the importance of the seed population in determining the rate at which a methanotrophic community is able to respond to an input of methane. Collectively, these results provide a significant advance in our understanding of the marine methanotrohic biofilter, and further provide direction and context for future investigations of this important phenomenon. This project has resulted in fourteen publications to date, with five more circulating in draft form, and several others planned.

  20. Patterns in wetland microbial community composition and functional gene repertoire associated with methane emissions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, Shaomei; Malfatti, Stephanie A.; McFarland, Jack W.; Anderson, Frank E.; Pati, Amrita; Huntemann, Marcel; Tremblay, Julien; Glavina del Rio, Tijana; Waldrop, Mark P.; Windham-Myers, Lisamarie; et al

    2015-05-19

    Wetland restoration on peat islands previously drained for agriculture has potential to reverse land subsidence and sequester atmospheric carbon dioxide as peat accretes. However, the emission of methane could potentially offset the greenhouse gas benefits of captured carbon. As microbial communities play a key role in governing wetland greenhouse gas fluxes, we are interested in how microbial community composition and functions are associated with wetland hydrology, biogeochemistry, and methane emission, which is critical to modeling the microbial component in wetland methane fluxes and to managing restoration projects for maximal carbon sequestration. Here, we couple sequence-based methods with biogeochemical and greenhousemore »gas measurements to interrogate microbial communities from a pilot-scale restored wetland in the Sacramento-San Joaquin Delta of California, revealing considerable spatial heterogeneity even within this relatively small site. A number of microbial populations and functions showed strong correlations with electron acceptor availability and methane production; some also showed a preference for association with plant roots. Marker gene phylogenies revealed a diversity of major methane-producing and -consuming populations and suggested novel diversity within methanotrophs. Methanogenic archaea were observed in all samples, as were nitrate-, sulfate-, and metal-reducing bacteria, indicating that no single terminal electron acceptor was preferred despite differences in energetic favorability and suggesting spatial microheterogeneity and microniches. Notably, methanogens were negatively correlated with nitrate-, sulfate-, and metal-reducing bacteria and were most abundant at sampling sites with high peat accretion and low electron acceptor availability, where methane production was highest. Wetlands are the largest nonanthropogenic source of atmospheric methane but also a key global carbon reservoir. Characterizing belowground microbial communities that mediate carbon cycling in wetlands is critical to accurately predicting their responses to changes in land management and climate. Here, we studied a restored wetland and revealed substantial spatial heterogeneity in biogeochemistry, methane production, and microbial communities, largely associated with the wetland hydraulic design. We observed patterns in microbial community composition and functions correlated with biogeochemistry and methane production, including diverse microorganisms involved in methane production and consumption. We found that methanogenesis gene abundance is inversely correlated with genes from pathways exploiting other electron acceptors, yet the ubiquitous presence of genes from all these pathways suggests that diverse electron acceptors contribute to the energetic balance of the ecosystem. These investigations represent an important step toward effective management of wetlands to reduce methane flux to the atmosphere and enhance belowground carbon storage.« less

  1. Coalbed Methane Estimated Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948CaliforniaFeet) (Million,914 1,886 1,763 1,655

  2. Coalbed Methane Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table 1.101 (Million Short6RUBUFFALOfor the4XMethane

  3. Turbulent burning rates of methane and methane-hydrogen mixtures

    SciTech Connect (OSTI)

    Fairweather, M. [School of Process, Environmental and Materials Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Ormsby, M.P.; Sheppard, C.G.W. [School of Mechanical Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom); Woolley, R. [Department of Mechanical Engineering, University of Sheffield, Sheffield S1 3JD (United Kingdom)

    2009-04-15

    Methane and methane-hydrogen (10%, 20% and 50% hydrogen by volume) mixtures have been ignited in a fan stirred bomb in turbulence and filmed using high speed cine schlieren imaging. Measurements were performed at 0.1 MPa (absolute) and 360 K. A turbulent burning velocity was determined for a range of turbulence velocities and equivalence ratios. Experimental laminar burning velocities and Markstein numbers were also derived. For all fuels the turbulent burning velocity increased with turbulence velocity. The addition of hydrogen generally resulted in increased turbulent and laminar burning velocity and decreased Markstein number. Those flames that were less sensitive to stretch (lower Markstein number) burned faster under turbulent conditions, especially as the turbulence levels were increased, compared to stretch-sensitive (high Markstein number) flames. (author)

  4. The Methane to Markets Coal Mine Methane Subcommittee meeting

    SciTech Connect (OSTI)

    2008-07-01

    The presentations (overheads/viewgraphs) include: a report from the Administrative Support Group; strategy updates from Australia, India, Italy, Mexico, Nigeria, Poland and the USA; coal mine methane update and IEA's strategy and activities; the power of VAM - technology application update; the emissions trading market; the voluntary emissions reduction market - creating profitable CMM projects in the USA; an Italian perspective towards a zero emission strategies; and the wrap-up and summary.

  5. Methane ignition catalyzed by in situ generated palladium nanoparticles

    SciTech Connect (OSTI)

    Shimizu, T.; Abid, A.D.; Poskrebyshev, G.; Wang, H. [Department of Aerospace and Mechanical Engineering, University of Southern California, Los Angeles, CA 90089 (United States); Nabity, J.; Engel, J.; Yu, J. [TDA Research, Inc., 12345 W. 52nd Ave, Wheat Ridge, CO 80033 (United States); Wickham, D. [Reaction Systems, LLC, 19039 E. Plaza Drive, Suite 290, Parker, CO 80134 (United States); Van Devener, B.; Anderson, S.L. [Department of Chemistry, University of Utah, Salt Lake City, UT 84112 (United States); Williams, S. [Air Force Research Laboratory, Mail Stop RZA, 1950 Fifth Street, WPAFB, OH 45433 (United States)

    2010-03-15

    Catalytic ignition of methane over the surfaces of freely-suspended and in situ generated palladium nanoparticles was investigated experimentally and numerically. The experiments were conducted in a laminar flow reactor. The palladium precursor was a compound (Pd(THD){sub 2}, THD: 2,2,6,6-tetramethyl-3,5-heptanedione) dissolved in toluene and injected into the flow reactor as a fine aerosol, along with a methane-oxygen-nitrogen mixture. For experimental conditions chosen in this study, non-catalytic, homogeneous ignition was observed at a furnace temperature of {proportional_to}1123 K, whereas ignition of the same mixture with the precursor was found to be {proportional_to}973 K. In situ production of Pd/PdO nanoparticles was confirmed by scanning mobility, transmission electron microscopy and X-ray photoelectron spectroscopy analyses of particles collected at the reactor exit. The catalyst particle size distribution was log-normal. Depending on the precursor loading, the median diameter ranged from 10 to 30 nm. The mechanism behind catalytic ignition was examined using a combined gas-phase and gas-surface reaction model. Simulation results match the experiments closely and suggest that palladium nanocatalyst significantly shortens the ignition delay times of methane-air mixtures over a wide range of conditions. (author)

  6. Methane storage in nanoporous media as observed via high field NMR relaxometry

    E-Print Network [OSTI]

    Papaioannou, Antonios

    2015-01-01

    The storage properties of methane gas in Vycor porous glass (5.7 nm) are characterized in a wide pressure range from 0.7 MPa-89.7 MPa using Nuclear Magnetic Resonance (NMR). We demonstrate the capability of high field NMR relaxometry for the determination of the methane gas storage capacity and the measurement of the Hydrogen Index, to a high degree of accuracy. This helps determine the excess gas in the pore space which can be identified to exhibit Langmuir properties in the low pressure regime of 0.7 MPa to 39.6 Mpa. The Langmuir model enables us to determine the equilibrium density of the monolayer of adsorbed gas to be 8.5% lower than that of liquid methane. We also identify the signatures of multilayer adsorption at the high pressure regime from 39.6 Mpa to 89.7 Mpa and use the Brunauer-Emmet-Teller (BET) theory to determine the number of adsorbed layers of methane gas. We show how these measurements help us differentiate the gas stored in the Vycor pore space into free and adsorbed fractions for the ent...

  7. Potential Cost-Effective Opportunities for Methane Emission Abatement

    SciTech Connect (OSTI)

    Warner, Ethan; Steinberg, Daniel; Hodson, Elke; Heath, Garvin

    2015-08-01

    The energy sector was responsible for approximately 84% of carbon dioxide equivalent (CO2e) greenhouse gas (GHG) emissions in the U.S. in 2012 (EPA 2014a). Methane is the second most important GHG, contributing 9% of total U.S. CO2e emissions. A large portion of those methane emissions result from energy production and use; the natural gas, coal, and oil industries produce approximately 39% of anthropogenic methane emissions in the U.S. As a result, fossil-fuel systems have been consistently identified as high priority sectors to contribute to U.S. GHG reduction goals (White House 2015). Only two studies have recently attempted to quantify the abatement potential and cost associated with the breadth of opportunities to reduce GHG emissions within natural gas, oil, and coal supply chains in the United States, namely the U.S. Environmental Protection Agency (EPA) (2013a) and ICF (2014). EPA, in its 2013 analysis, estimated the marginal cost of abatement for non-CO2 GHG emissions from the natural gas, oil, and coal supply chains for multiple regions globally, including the United States. Building on this work, ICF International (ICF) (2014) provided an update and re-analysis of the potential opportunities in U.S. natural gas and oil systems. In this report we synthesize these previously published estimates as well as incorporate additional data provided by ICF to provide a comprehensive national analysis of methane abatement opportunities and their associated costs across the natural gas, oil, and coal supply chains. Results are presented as a suite of marginal abatement cost curves (MACCs), which depict the total potential and cost of reducing emissions through different abatement measures. We report results by sector (natural gas, oil, and coal) and by supply chain segment - production, gathering and boosting, processing, transmission and storage, or distribution - to facilitate identification of which sectors and supply chain segments provide the greatest opportunities for low cost abatement.

  8. Techno-Economic Analysis of Bioconversion of Methane into Biofuel and Biochemical (Poster)

    SciTech Connect (OSTI)

    Fei, Q.; Tao, L.; Pienkos, P .T.; Guarnieri, M.; Palou-Rivera, I.

    2014-10-01

    In light of the relatively low price of natural gas and increasing demands of liquid transportation fuels and high-value chemicals, attention has begun to turn to novel biocatalyst for conversion of methane (CH4) into biofuels and biochemicals [1]. A techno-economic analysis (TEA) was performed for an integrated biorefinery process using biological conversion of methane, such as carbon yield, process efficiency, productivity (both lipid and acid), natural gas and other raw material prices, etc. This analysis is aimed to identify research challenges as well provide guidance for technology development.

  9. The Tri--methane Rearrangement: Mechanistic and Exploratory Organic

    E-Print Network [OSTI]

    Cirkva, Vladimir

    counterpart. Scheme 1 shows the mechanism of the di--methane rearrangement and its potential diversion allylic diradical 4, closure to tri--methane product 6 may compete with 1,3-closure to di--methane product rearrangement. On direct irradiation, tris-diphenylvinyl methane 9 led to 52% of tri--methane product 11

  10. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

  11. Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report

    SciTech Connect (OSTI)

    Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

    1988-01-01

    The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

  12. INTEGRATED POWER GENERATION SYSTEMS FOR COAL MINE WASTE METHANE UTILIZATION

    SciTech Connect (OSTI)

    Peet M. Soot; Dale R. Jesse; Michael E. Smith

    2005-08-01

    An integrated system to utilize the waste coal mine methane (CMM) at the Federal No. 2 Coal Mine in West Virginia was designed and built. The system includes power generation, using internal combustion engines, along with gas processing equipment to upgrade sub-quality waste methane to pipeline quality standards. The power generation has a nominal capacity of 1,200 kw and the gas processing system can treat about 1 million cubic feet per day (1 MMCFD) of gas. The gas processing is based on the Northwest Fuel Development, Inc. (NW Fuel) proprietary continuous pressure swing adsorption (CPSA) process that can remove nitrogen from CMM streams. The two major components of the integrated system are synergistic. The byproduct gas stream from the gas processing equipment can be used as fuel for the power generating equipment. In return, the power generating equipment provides the nominal power requirements of the gas processing equipment. This Phase III effort followed Phase I, which was comprised of a feasibility study for the project, and Phase II, where the final design for the commercial-scale demonstration was completed. The fact that NW Fuel is desirous of continuing to operate the equipment on a commercial basis provides the validation for having advanced the project through all of these phases. The limitation experienced by the project during Phase III was that the CMM available to operate the CPSA system on a commercial basis was not of sufficiently high quality. NW Fuel's CPSA process is limited in its applicability, requiring a relatively high quality of gas as the feed to the process. The CPSA process was demonstrated during Phase III for a limited time, during which the processing capabilities met the expected results, but the process was never capable of providing pipeline quality gas from the available low quality CMM. The NW Fuel CPSA process is a low-cost ''polishing unit'' capable of removing a few percent nitrogen. It was never intended to process CMM streams containing high levels of nitrogen, as is now the case at the Federal No.2 Mine. Even lacking the CPSA pipeline delivery demonstration, the project was successful in laying the groundwork for future commercial applications of the integrated system. This operation can still provide a guide for other coal mines which need options for utilization of their methane resources. The designed system can be used as a complete template, or individual components of the system can be segregated and utilized separately at other mines. The use of the CMM not only provides an energy fuel from an otherwise wasted resource, but it also yields an environmental benefit by reducing greenhouse gas emissions. The methane has twenty times the greenhouse effect as compared to carbon dioxide, which the combustion of the methane generates. The net greenhouse gas emission mitigation is substantial.

  13. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, Douglas C. (Richland, WA); Sealock, Jr., L. John (Richland, WA); Baker, Eddie G. (Richland, WA)

    1997-01-01

    A method for converting organic material into a product gas includes: a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300.degree. C. to about 450.degree. C.; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen.

  14. Method for the catalytic conversion of organic materials into a product gas

    DOE Patents [OSTI]

    Elliott, D.C.; Sealock, L.J. Jr.; Baker, E.G.

    1997-04-01

    A method for converting organic material into a product gas includes: (a) providing a liquid reactant mixture containing liquid water and liquid organic material within a pressure reactor; (b) providing an effective amount of a reduced metal catalyst selected from the group consisting of ruthenium, rhodium, osmium and iridium or mixtures thereof within the pressure reactor; and (c) maintaining the liquid reactant mixture and effective amount of reduced metal catalyst in the pressure reactor at temperature and pressure conditions of from about 300 C to about 450 C; and at least 130 atmospheres for a period of time, the temperature and pressure conditions being effective to maintain the reactant mixture substantially as liquid, the effective amount of reduced metal catalyst and the period of time being sufficient to catalyze a reaction of the liquid organic material to produce a product gas composed primarily of methane, carbon dioxide and hydrogen. 5 figs.

  15. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

  16. Split-estate negotiations: the case of coal-bed methane

    SciTech Connect (OSTI)

    Hayley H. Chouinard; Christina Steinhoff [Washington State University, WA (United States)

    2008-01-15

    Coal-bed methane is an emerging contributor to the US energy supply. Split estates, where landowners control the surface and the energy companies lease the rights to the underground gas from the federal government, often impede successful negotiations for methane extraction. We provide an extensive form representation of the dynamic game of the negotiation process for subsurface access. We then solve for a set of Nash equilibrium outcomes associated with the split estate negotiations. By examining the optimal offers we can identify methods to improve the likelihood of negotiations that do not break down and result in the gas developer resorting to the use of a bond. We examine how changes in transaction costs or entitlements will affect the outcomes, and support our finds with anecdotal evidence from actual negotiations for coal-bed methane access. 55 refs.

  17. New materials for methane capture from dilute and medium-concentration sources

    SciTech Connect (OSTI)

    Kim, J; Maiti, A; Lin, LC; Stolaroff, JK; Smit, B; Aines, RD

    2013-04-16

    Methane (CH4) is an important greenhouse gas, second only to CO2, and is emitted into the atmosphere at different concentrations from a variety of sources. However, unlike CO2, which has a quadrupole moment and can be captured both physically and chemically in a variety of solvents and porous solids, methane is completely non-polar and interacts very weakly with most materials. Thus, methane capture poses a challenge that can only be addressed through extensive material screening and ingenious molecular-level designs. Here we report systematic in silico studies on the methane capture effectiveness of two different materials systems, that is, liquid solvents (including ionic liquids) and nanoporous zeolites. Although none of the liquid solvents appears effective as methane sorbents, systematic screening of over 87,000 zeolite structures led to the discovery of a handful of candidates that have sufficient methane sorption capacity as well as appropriate CH4/CO2 and/or CH4/N-2 selectivity to be technologically promising.

  18. Effect of silane concentration on the supersonic combustion of a silane/methane mixture

    SciTech Connect (OSTI)

    Northam, G.B.; Mc Lain, A.G.; Pellett, G.L.; Diskin, G.S.

    1986-01-01

    A series of direct connect combustor tests was conducted to determine the effect of silane concentration on the supersonic combustion characteristics of silane/methane mixtures. Shock tube ignition delay data indicated more than an order of magnitude reduction in ignition delay times for both 10 and 20 percent silane/methane mixtures as compared to methane. The ignition delay time of the 10 percent mixture was only a factor of 2.3 greater than that of the 20 percent mixture. Supersonic combustion tests were conducted with the fuel injected into a model scramjet combustor. The combustor was mounted at the exit of a Mach 2 nozzle and a hydrogen fired heater was used to provide a variation in test gas total temperature. Tests using the 20 percent silane/methane mixture indicated considerable combustion enhancement when compared to methane alone. This mixture had an autoignition total temperature of 1650 R. The addition of 20 percent silane to methane resulted in a pyrophoric fuel with good supersonic combustion performance. Reducing the silane concentration below this level, however, yielded a less pyrophoric fuel that exhibited poor supersonic combustion performance.

  19. METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.

    SciTech Connect (OSTI)

    Mahajan, Devinder; Jones, Keith W.; Feng, Huan; Winters, William J.

    2004-12-01

    The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

  20. Quantification of the Potential Gross Economic Impacts of Five Methane Reduction Scenarios

    SciTech Connect (OSTI)

    Keyser, David; Warner, Ethan; Curley, Christina

    2015-04-23

    Methane (CH4) is a potent greenhouse gas that is released from the natural gas supply chain into the atmosphere as a result of fugitive emissions1 and venting2 . We assess five potential CH4 reduction scenarios from transmission, storage, and distribution (TS&D) using published literature on the costs and the estimated quantity of CH4 reduced. We utilize cost and methane inventory data from ICF (2014) and Warner et al. (forthcoming) as well as data from Barrett and McCulloch (2014) and the American Gas Association (AGA) (2013) to estimate that the implementation of these measures could support approximately 85,000 jobs annually from 2015 to 2019 and reduce CH4 emissions from natural gas TS&D by over 40%. Based on standard input/output analysis methodology, measures are estimated to support over $8 billion in GDP annually over the same time period and allow producers to recover approximately $912 million annually in captured gas.

  1. Little-Known Truths, Quirky Anecdotes, Seething Scandals, and Even Some Science in the History of (Primarily Achievement) Motivation

    E-Print Network [OSTI]

    Weiner, B

    2013-01-01

    of (Primarily Achievement) Motivation This article examinesthe history of motivation psychology from the start of thegrowth of the science of motivation. Also, the connections

  2. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, A. J.; Jacob, D. J.; Wecht, K. J.; Maasakkers, J. D.; Biraud, S. C.; Boesch, H.; Bowman, K. W.; Deutscher, N. M.; Dubey, M. K.; Griffith, D. W. T.; et al

    2015-02-18

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to constrain global and North American inversions of methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. The GOSAT data are first evaluated with atmospheric methane observations from surface networks (NOAA, TCCON) and aircraft (NOAA/DOE, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. The surface and aircraft data are subsequently usedmore »for independent evaluation of the methane source inversions. Our global adjoint-based inversion yields a total methane source of 539 Tg a?1 and points to a large East Asian overestimate in the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide full error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a?1, as compared to 24.9–27.0 Tg a?1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a?1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the South-Central US, the Central Valley of California, and Florida wetlands, large isolated point sources such as the US Four Corners also contribute. We attribute 29–44% of US anthropogenic methane emissions to livestock, 22–31% to oil/gas, 20% to landfills/waste water, and 11–15% to coal with an additional 9.0–10.1 Tg a?1 source from wetlands.« less

  3. Methane and Methanotrophic Bacteria as a Biotechnological Platform...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methane and Methanotrophic Bacteria as a Biotechnological Platform Methane and Methanotrophic Bacteria as a Biotechnological Platform Breakout Session 2-B: NewEmerging Pathways...

  4. Scientists detect methane levels three times larger than expected...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methane that actually preceded recent concerns about potential emissions from fracking," Dubey said. Scientists detect methane levels three times larger than expected over...

  5. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

  6. Detection and Production of Methane Hydrate

    SciTech Connect (OSTI)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

  7. Extension - Upgrading Methane Using Ultra-Fast Thermal Swing Adsorption

    SciTech Connect (OSTI)

    Anna Lee Tonkovich

    2008-08-11

    The need for cost effective technologies for upgrading coal mine methane to pipeline quality natural gas is becoming ever greater. The current work presents and investigates a new approach to reduce the impact of the most costly step in the conventional technology, nitrogen rejection. The proposed approach is based on the Velocys microchannel platform, which is being developed to commercialize compact and cost efficient chemical processing technology. For this separation, ultra fast thermal swing sorption is enabled by the very high rates of heat and mass transfer inherent in microchannel processing. In a first phase of the project solid adsorbents were explored. Feasibility of ultrafast thermal swing was demonstrated but the available adsorbents had insufficient differential methane capacity to achieve the required commercial economics. In a second phase, ionic liquids were adopted as absorbents of choice, and experimental work and economic analyses, performed to gauge their potential, showed promise for this novel alternative. Final conclusions suggest that a combination of a required cost target for ionic liquids or a methane capacity increase or a combination of both is required for commercialization.

  8. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Bistline, J; Inman, M; Davis, SJ

    2014-01-01

    leaks from North American natural gas systems Science 343of methane emissions at natural gas production sites in theUS exports of natural gas Energy Policy www.bipac.net/dow/

  9. The effect of natural gas supply on US renewable energy and CO2emissions

    E-Print Network [OSTI]

    Shearer, C; Shearer, C; Bistline, J; Inman, M; Davis, SJ; Davis, SJ

    2014-01-01

    leaks from North American natural gas systems Science 343of methane emissions at natural gas production sites in theThe effect of natural gas supply on US renewable energy and

  10. Lifecycle impacts of natural gas to hydrogen pathways on urban air quality

    E-Print Network [OSTI]

    Wang, Guihua; Ogden, Joan M; Nicholas, Michael A

    2007-01-01

    of natural gas to hydrogen pathways on urban air qualityas natural gas extraction and oil re?ning) on air quality inquality impacts for three different hydrogen production and delivery pathways, based on steam methane reforming (SMR) of natural gas,

  11. A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis

    E-Print Network [OSTI]

    Farrell, Alexander E.; Sperling, Dan

    2007-01-01

    chemical industries, primarily from natural gas or other fossil sources. 15 Syngas-based processes like steam methane

  12. A Low-Carbon Fuel Standard for California Part 1: Technical Analysis

    E-Print Network [OSTI]

    2007-01-01

    chemical industries, primarily from natural gas or other fossil sources. 15 Syngas-based processes like steam methane

  13. GAS EXPLORATION Winter 2006 GasTIPS 5

    E-Print Network [OSTI]

    Rubin, Yoram

    GAS EXPLORATION Winter 2006 · GasTIPS 5 T he prediction of reservoir parameters such as gas or oil, but is particularly challenging in the case of gas exploration. Current seismic imaging technol- ogy cannot accurately discriminate between economic and non-eco- nomic concentrations of gas. This is primarily because

  14. The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane 

    E-Print Network [OSTI]

    Hu, Lei

    2012-10-19

    , which was 700 (490 to 920) Gg yr^-1 and -370 (-440 to -280) Gg yr^-1, respectively. The ocean accounts for 10 - 19 % in the global CH3Cl emission and 6 - 9 % in its global sinks. Methane (CH4) is a potent greenhouse gas, which has a warming potential...

  15. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-04-04

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  16. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A. (Idaho Falls, ID); Dugan, Patrick R. (Idaho Falls, ID)

    1995-01-01

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  17. California--State Offshore Coalbed Methane Proved Reserves (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 ArizonaResidential(MillionFeet) Coalbed Methane

  18. METHANE HYDRATE ADVISORY COMMITTEE U.S. Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Energy This Revision 3 ofMARVIN 1EARLY RE: RE:4METHANE

  19. Methane Hydrate Advisory Committee Meeting Minutes | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof EnergyPresentation:DaisStatesEMCHIEFMeltingMethaneJune

  20. Design of New Materials for Methane Storage Tina Duren, Lev Sarkisov, Omar M. Yaghi, and Randall Q. Snurr*,

    E-Print Network [OSTI]

    Yaghi, Omar M.

    the desired characteristics of an optimal adsorbent for gas storage. The U.S. Department of Energy has of gas adsorbed at standard temperature and pressure (STP; 298 K, 1 atm) per volume of the storage vesselDesign of New Materials for Methane Storage Tina Du¨ren, Lev Sarkisov, Omar M. Yaghi, and Randall Q

  1. Impact of different plants on the gas profile of a landfill cover

    SciTech Connect (OSTI)

    Reichenauer, Thomas G.; Watzinger, Andrea; Riesing, Johann; Gerzabek, Martin H.

    2011-05-15

    Research highlights: > Plants influence gas profile and methane oxidation in landfill covers. > Plants regulate water content and increase the availability of oxygen for methane oxidation. > Plant species with deep roots like alfalfa showed more stimulation of methane oxidation than plants with shallow root systems like grasses. - Abstract: Methane is an important greenhouse gas emitted from landfill sites and old waste dumps. Biological methane oxidation in landfill covers can help to reduce methane emissions. To determine the influence of different plant covers on this oxidation in a compost layer, we conducted a lysimeter study. We compared the effect of four different plant covers (grass, alfalfa + grass, miscanthus and black poplar) and of bare soil on the concentration of methane, carbon dioxide and oxygen in lysimeters filled with compost. Plants were essential for a sustainable reduction in methane concentrations, whereas in bare soil, methane oxidation declined already after 6 weeks. Enhanced microbial activity - expected in lysimeters with plants that were exposed to landfill gas - was supported by the increased temperature of the gas in the substrate and the higher methane oxidation potential. At the end of the first experimental year and from mid-April of the second experimental year, the methane concentration was most strongly reduced in the lysimeters containing alfalfa + grass, followed by poplar, miscanthus and grass. The observed differences probably reflect the different root morphology of the investigated plants, which influences oxygen transport to deeper compost layers and regulates the water content.

  2. Cyclic process for producing methane in a tubular reactor with effective heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-Lee (Spring Valley, NY)

    1986-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  3. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C. (Congers, NY); Yang, Chang-lee (Spring Valley, NY)

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  4. Department of Energy Advance Methane Hydrates Science and Technology Projects

    Broader source: Energy.gov [DOE]

    Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

  5. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, A. J.; Jacob, D. J.; Wecht, K. J.; Maasakkers, J. D.; Lundgren, E.; Andrews, A. E.; Biraud, S. C.; Boesch, H.; Bowman, K. W.; Deutscher, N. M.; et al

    2015-06-30

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to estimate global and North American methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. GEOS-Chem and GOSAT data are first evaluated with atmospheric methane observations from surface and tower networks (NOAA/ESRL, TCCON) and aircraft (NOAA/ESRL, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. Our global adjoint-based inversion yields a totalmore »methane source of 539 Tg a?1 with some important regional corrections to the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a-1, as compared to 24.9–27.0 Tg a-1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a-1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the southern–central US, the Central Valley of California, and Florida wetlands; large isolated point sources such as the US Four Corners also contribute. Using prior information on source locations, we attribute 29–44 % of US anthropogenic methane emissions to livestock, 22–31 % to oil/gas, 20 % to landfills/wastewater, and 11–15 % to coal. Wetlands contribute an additional 9.0–10.1 Tg a-1.« less

  6. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, A. J.; Jacob, D. J.; Wecht, K. J.; Maasakkers, J. D.; Lundgren, E.; Andrews, A. E.; Biraud, S. C.; Boesch, H.; Bowman, K. W.; Deutscher, N. M.; et al

    2015-06-30

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to estimate global and North American methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. GEOS-Chem and GOSAT data are first evaluated with atmospheric methane observations from surface and tower networks (NOAA/ESRL, TCCON) and aircraft (NOAA/ESRL, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. Our global adjoint-based inversion yields a totalmore »methane source of 539 Tg a?1 with some important regional corrections to the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a?1, as compared to 24.9–27.0 Tg a?1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a?1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the southern–central US, the Central Valley of California, and Florida wetlands; large isolated point sources such as the US Four Corners also contribute. Using prior information on source locations, we attribute 29–44 % of US anthropogenic methane emissions to livestock, 22–31 % to oil/gas, 20 % to landfills/wastewater, and 11–15 % to coal. Wetlands contribute an additional 9.0–10.1 Tg a?1.« less

  7. Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet at Supercritical Pressures

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet in laminar jet flames of methane at elevated pressures in a high-pressure combustion chamber, we have MPa, after the laminar methane jet flame had been stabilized on a co-flow circular nozzle-type burner

  8. An ab Initio Study on the Oxidative Coupling of Methane over a Lithium-Doped MgO Catalyst: Surface Defects and Mechanism

    E-Print Network [OSTI]

    Truong, Thanh N.

    utilization of methane, the primary component of natural gas, is becoming an immediate goal as we face issues of diminishing natural resources. Unfortunately, the remote locations of most natural gas reserves make transportation of this fuel economically unreasonable.1 One means to exploit the remote gas sources is to first

  9. Sunlight to Gas Pump Michael Bobek

    E-Print Network [OSTI]

    Roy, Subrata

    hydrocarbon fuel: methane (natural gas), butane (lighter fluid), propane(Grill gas), and octane (gasoline, motivated yet?! So now why do we want to convert the sunlight into fuel? The reason is that fuel is much to convert to fuels is that the structure of society already has a strong backbone supporting them, gas

  10. Integrated solar thermochemical reaction system for steam methane reforming

    SciTech Connect (OSTI)

    Zheng, Feng; Diver, Rich; Caldwell, Dustin D.; Fritz, Brad G.; Cameron, Richard J.; Humble, Paul H.; TeGrotenhuis, Ward E.; Dagle, Robert A.; Wegeng, Robert S.

    2015-06-05

    Solar-aided upgrade of the energy content of fossil fuels, such as natural gas, can provide a near-term transition path towards a future solar-fuel economy and reduce carbon dioxide emission from fossil fuel consumption. Both steam and dry reforming a methane-containing fuel stream have been studied with concentrated solar power as the energy input to drive the highly endothermic reactions but the concept has not been demonstrated at a commercial scale. Under a current project with the U.S. Department of Energy, PNNL is developing an integrated solar thermochemical reaction system that combines solar concentrators with micro- and meso-channel reactors and heat exchangers to accomplish more than 20% solar augment of methane higher heating value. The objective of our three-year project is to develop and prepare for commercialization such solar reforming system with a high enough efficiency to serve as the frontend of a conventional natural gas (or biogas) combined cycle power plant, producing power with a levelized cost of electricity less than 6˘/kWh, without subsidies, by the year 2020. In this paper, we present results from the first year of our project that demonstrated a solar-to-chemical energy conversion efficiency as high as 69% with a prototype reaction system.

  11. Integrated solar thermochemical reaction system for steam methane reforming

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Feng; Diver, Rich; Caldwell, Dustin D.; Fritz, Brad G.; Cameron, Richard J.; Humble, Paul H.; TeGrotenhuis, Ward E.; Dagle, Robert A.; Wegeng, Robert S.

    2015-06-05

    Solar-aided upgrade of the energy content of fossil fuels, such as natural gas, can provide a near-term transition path towards a future solar-fuel economy and reduce carbon dioxide emission from fossil fuel consumption. Both steam and dry reforming a methane-containing fuel stream have been studied with concentrated solar power as the energy input to drive the highly endothermic reactions but the concept has not been demonstrated at a commercial scale. Under a current project with the U.S. Department of Energy, PNNL is developing an integrated solar thermochemical reaction system that combines solar concentrators with micro- and meso-channel reactors and heatmore »exchangers to accomplish more than 20% solar augment of methane higher heating value. The objective of our three-year project is to develop and prepare for commercialization such solar reforming system with a high enough efficiency to serve as the frontend of a conventional natural gas (or biogas) combined cycle power plant, producing power with a levelized cost of electricity less than 6˘/kWh, without subsidies, by the year 2020. In this paper, we present results from the first year of our project that demonstrated a solar-to-chemical energy conversion efficiency as high as 69% with a prototype reaction system.« less

  12. Revisiting the Long-Term Hedge Value of Wind Power in an Era of Low Natural Gas Prices

    E-Print Network [OSTI]

    Bolinger, Mark

    2014-01-01

    leaking of methane from shale gas development: response to2012. “The Influence of Shale Gas on U.S. Energy andthe United States’ vast shale gas reserves in recent years

  13. Methane oxidation in the eastern tropical North Pacific Ocean water column

    E-Print Network [OSTI]

    2015-01-01

    PACK ET AL. EASTERN PACIFIC METHANE OXIDATIONA method for measuring methane oxidation rates using low-levels of C-labeled methane and accelerator mass

  14. Methane Digesters and Biogas Recovery - Masking the Environmental Consequences of Industrial Concentrated Livestock Production

    E-Print Network [OSTI]

    Di Camillo, Nicole G.

    2011-01-01

    Methane Digesters and Biogas Recovery-Masking theII. METHANE DIGESTERS AND BIOGAs RECOVERY- IN THEEVEN BEYOND MANURE-ASSOCIATED METHANE EMISSIONS, INDUSTRIAL

  15. Distinguishing and understanding thermogenic and biogenic sources of methane using multiply substituted isotopologues

    E-Print Network [OSTI]

    2015-01-01

    of thermogenic and biogenic methane. Science 344, 1500-1503.2014c. Clumped isotopes of methane: applications to both lowEmerging topics in marine methane biogeochemistry. Annu.

  16. Marine methane cycle simulations for the period of early global warming

    E-Print Network [OSTI]

    Elliott, S.

    2011-01-01

    aspects of atmospheric methane, Global Biogeochem. Cycles 2,Budeus, Fate of vent derived methane in seawater above theHanfland, Pathways of methane in seawater: Plume spreading

  17. Reduced methane growth rate explained by decreased Northern Hemisphere microbial sources

    E-Print Network [OSTI]

    Kai, FM; Kai, FM; Tyler, SC; Tyler, SC; Randerson, JT; Blake, DR

    2011-01-01

    rate of the atmospheric methane burden. Nature 393, 447–of global tropospheric methane. Geophys. Res. Lett. 33,M. J. in Atmospheric Methane: its Role in the Global

  18. Environmental impacts on the diversity of methane-cycling microbes and their resultant function

    E-Print Network [OSTI]

    Aronson, Emma L; Allison, Steven D; Helliker, Brent R

    2013-01-01

    on methane- consuming microbes in rice field and forestof methane- cycling microbes and their resultant function.diversity of methane-cycling microbes and their resultant

  19. Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane

    E-Print Network [OSTI]

    Green, Michael A.

    2005-01-01

    Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

  20. Nitrogen removal from natural gas using two types of membranes

    DOE Patents [OSTI]

    Baker, Richard W.; Lokhandwala, Kaaeid A.; Wijmans, Johannes G.; Da Costa, Andre R.

    2003-10-07

    A process for treating natural gas or other methane-rich gas to remove excess nitrogen. The invention relies on two-stage membrane separation, using methane-selective membranes for the first stage and nitrogen-selective membranes for the second stage. The process enables the nitrogen content of the gas to be substantially reduced, without requiring the membranes to be operated at very low temperatures.

  1. Methane storage capabilities of diamond analogues

    SciTech Connect (OSTI)

    Haranczyk, M; Lin, LC; Lee, K; Martin, RL; Neaton, JB; Smit, B

    2013-01-01

    Methane can be an alternative fuel for vehicular usage provided that new porous materials are developed for its efficient adsorption-based storage. Herein, we search for materials for this application within the family of diamond analogues. We used density functional theory to investigate structures in which tetrahedral C atoms of diamond are separated by-CC-or-BN-groups, as well as ones involving substitution of tetrahedral C atoms with Si and Ge atoms. The adsorptive and diffusive properties of methane are studied using classical molecular simulations. Our results suggest that the all-carbon structure has the highest volumetric methane uptake of 280 VSTP/V at p = 35 bar and T = 298 K. However, it suffers from limited methane diffusion. Alternatively, the considered Si and Ge-containing analogies have fast diffusive properties but their adsorption is lower, ca. 172-179 VSTP/V, at the same conditions.

  2. Methane Hydrate Advisory Committee (MHAC) Meeting

    Broader source: Energy.gov (indexed) [DOE]

    to establish the resource potential of methane hydrates via a sustained, long-term production test in the Arctic. DFO Gant reminded the Committee that on May 1, the MHAC members...

  3. Treatment of gas from an in situ conversion process

    DOE Patents [OSTI]

    Diaz, Zaida (Katy, TX); Del Paggio, Alan Anthony (Spring, TX); Nair, Vijay (Katy, TX); Roes, Augustinus Wilhelmus Maria (Houston, TX)

    2011-12-06

    A method of producing methane is described. The method includes providing formation fluid from a subsurface in situ conversion process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. At least the olefins in the first gas stream are contacted with a hydrogen source in the presence of one or more catalysts and steam to produce a second gas stream. The second gas stream is contacted with a hydrogen source in the presence of one or more additional catalysts to produce a third gas stream. The third gas stream includes methane.

  4. Low-Cost Methane Liquefaction Plant and Vehicle Refueling Station

    SciTech Connect (OSTI)

    B. Wilding; D. Bramwell

    1999-01-01

    The Idaho National Engineering and Environmental Laboratory (INEEL) is currently negotiating a collaborative effort with Pacific Gas and Electric (PG&E) that will advance the use of liquefied natural gas (LNG) as a vehicle fuel. We plan to develop and demonstrate a small-scale methane liquefaction plant (production of 5,000 to 10,000 gallons per day) and a low-cost ($150,000) LNG refueling station to supply fuel to LNG-powered transit buses and other heavy-duty vehicles. INEEL will perform the research and development work. PG&E will deploy the new facilities commercially in two demonstration projects, one in northern California, and one in southern California.

  5. Towards quantifying the reaction network around the sulfate–methane-transition-zone in the Ulleung Basin, East Sea, with a kinetic modeling approach

    SciTech Connect (OSTI)

    Hong, Wei-Li; Torres, Marta E.; Kim, Ji-Hoon; Choi, Jiyoung; Bahk, Jang-Jun

    2014-09-01

    We present a kinetic model based upon pore water data collected from eight sites drilled during the second Ulleung Basin gas hydrate drilling expedition (UBGH2) in 2010. Three sites were drilled at locations where acoustic chimneys were identified in seismic data, and the rest were drilled on non-chimney (i.e. background) environments. Our model, coupled a comprehensive compositional and isotopic data set, is used to illustrate the different biogeochemical processes at play in those two environments, in terms of reactions around the sulfate-methane-transition-zone (SMTZ). Organic matter decomposition is an important process for production of methane, dissolved inorganic carbon (DIC) and consumption of sulfate in the non-chimney sites, whereas anaerobic oxidation of methane (AOM) dominates both carbon and sulfur cycles in the chimney environment. Different sources of methane mediate AOM in the two settings. Internally produced methane through CO? reduction (CR) and methanogenesis fuels AOM in the non-chimney sites, whereas AOM is sustained by methane from external sources in the chimney sites. We also simulate the system evolution from non-chimney to chimney conditions by increasing the bottom methane supply to a non-chimney setting. We show that the higher CH? flux leads to a higher microbial activity of AOM, and more organic matter decomposition through methanogenesis. A higher methanogenesis rate and a smaller CR contribution relative to AOM in the chimney sites is responsible for the isotopically light DIC and heavy methane in this environment, relative to the non-chimney sites.

  6. What product might a renewal of Heavy Ion Fusion development offer that competes with methane microbes and hydrogen HTGRs

    E-Print Network [OSTI]

    2006-01-01

    competes with methane microbes and hydrogen HTGRs? Grantknown. The economics of microbe methane and HTGR hydrogen

  7. Completion methods in thick, multilayered tight gas sands 

    E-Print Network [OSTI]

    Ogueri, Obinna Stavely

    2009-05-15

    Tight gas sands, coal-bed methane, and gas shales are commonly called unconventional reservoirs. Tight gas sands (TGS) are often described as formations with an expected average permeability of 0.1mD or less. Gas production rates from TGS reservoirs...

  8. Additionally, a key based primarily on vegetative features is pro-vided for North Carolina species of Desmodium.

    E-Print Network [OSTI]

    Krings, Alexander

    Additionally, a key based primarily on vegetative features is pro- vided for North Carolina species of Desmodium. METHODS The foliar morphology of North Carolina Desmodium species was critically studied based by Wilbur (1963). RESULTS and DISCUSSION North Carolina Desmodium species can be artificially categorized

  9. STRUCTURAL ENGINEERING MINOR The Minor in Structural Engineering is designed primarily for students in the College of Environmental Design to

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    STRUCTURAL ENGINEERING MINOR GENERAL: The Minor in Structural Engineering is designed primarily with simple models (CE30) Understanding of structures and methods of analysis (CE120, CE121) Design emphasizing either architectural design or engineering. ADVISOR: The Faculty Advisor for the Structural

  10. GEOLOGIC SCREENING CRITERIA FOR SEQUESTRATION OF CO2 IN COAL: QUANTIFYING POTENTIAL OF THE BLACK WARRIOR COALBED METHANE FAIRWAY, ALABAMA

    SciTech Connect (OSTI)

    Jack C. Pashin; Richard E. Carroll; Richard H. Groshong Jr.; Dorothy E. Raymond; Marcella McIntyre; J. Wayne Payton

    2004-01-01

    Sequestration of CO{sub 2} in coal has potential benefits for reducing greenhouse gas emissions from the highly industrialized Carboniferous coal basins of North America and Europe and for enhancing coalbed methane recovery. Hence, enhanced coalbed methane recovery operations provide a basis for a market-based environmental solution in which the cost of sequestration is offset by the production and sale of natural gas. The Black Warrior foreland basin of west-central Alabama contains the only mature coalbed methane production fairway in eastern North America, and data from this basin provide an excellent basis for quantifying the carbon sequestration potential of coal and for identifying the geologic screening criteria required to select sites for the demonstration and commercialization of carbon sequestration technology. Coalbed methane reservoirs in the upper Pottsville Formation of the Black Warrior basin are extremely heterogeneous, and this heterogeneity must be considered to screen areas for the application of CO{sub 2} sequestration and enhanced coalbed methane recovery technology. Major screening factors include stratigraphy, geologic structure, geothermics, hydrogeology, coal quality, sorption capacity, technology, and infrastructure. Applying the screening model to the Black Warrior basin indicates that geologic structure, water chemistry, and the distribution of coal mines and reserves are the principal determinants of where CO{sub 2} can be sequestered. By comparison, coal thickness, temperature-pressure conditions, and coal quality are the key determinants of sequestration capacity and unswept coalbed methane resources. Results of this investigation indicate that the potential for CO{sub 2} sequestration and enhanced coalbed methane recovery in the Black Warrior basin is substantial and can result in significant reduction of greenhouse gas emissions while increasing natural gas reserves. Coal-fired power plants serving the Black Warrior basin in Alabama emit approximately 31 MMst (2.4 Tcf) of CO{sub 2} annually. The total sequestration capacity of the Black Warrior coalbed methane fairway at 350 psi is about 189 MMst (14.9 Tcf), which is equivalent to 6.1 years of greenhouse gas emissions from the coal-fired power plants. Applying the geologic screening model indicates that significant parts of the coalbed methane fairway are not accessible because of fault zones, coal mines, coal reserves, and formation water with TDS content less than 3,000 mg/L. Excluding these areas leaves a sequestration potential of 60 MMst (4.7 Tcf), which is equivalent to 1.9 years of emissions. Therefore, if about10 percent of the flue gas stream from nearby power plants is dedicated to enhanced coalbed methane recovery, a meaningful reduction of CO{sub 2} emissions can be realized for nearly two decades. If the fresh-water restriction were removed for the purposes of CO{sub 2} sequestration, an additional 10 MMst (0.9 Tcf) of CO{sub 2} could feasibly be sequestered. The amount of unswept coalbed methane in the fairway is estimated to be 1.49 Tcf at a pressure of 50 psi. Applying the screening model results in an accessible unswept gas resource of 0.44 Tcf. Removal of the fresh-water restriction would elevate this number to 0.57 Tcf. If a recovery factor of 80 percent can be realized, then enhanced recovery activities can result in an 18 percent expansion of coalbed methane reserves in the Black Warrior basin.

  11. Numerical modeling of methane venting from lake sediments

    E-Print Network [OSTI]

    Scandella, Benjamin P. (Benjamin Paul)

    2010-01-01

    The dynamics of methane transport in lake sediments control the release of methane into the water column above, and the portion that reaches the atmosphere may contribute significantly to the greenhouse effect. The observed ...

  12. Photonic Crystal Slot Waveguide Spectrometer for Detection of Methane

    E-Print Network [OSTI]

    Texas at Austin, University of

    Photonic Crystal Slot Waveguide Spectrometer for Detection of Methane 1 Funded by Environmental-infrared absorption spectrum of methane at 1665.5nm. · Guided mode design in SOI wafer #12;9 Device Fabrication Steps

  13. Conversion of methane and acetylene into gasoline range hydrocarbons 

    E-Print Network [OSTI]

    Alkhawaldeh, Ammar

    2000-01-01

    Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene...

  14. Preliminary relative permeability estimates of methane hydrate-bearing sand

    E-Print Network [OSTI]

    Seol, Yongkoo; Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.

    2006-01-01

    through methane hydrate-bearing sand. X-ray CT was usedin partially saturated sand, 229th ACS National Meeting, SanOF METHANE HYDRATE- BEARING SAND Yongkoo Seol, Timothy J.

  15. METHANE IN SUBSURFACE: MATHEMATICAL MODELING AND COMPUTATIONAL CHALLENGES

    E-Print Network [OSTI]

    Peszynska, Malgorzata

    hydrates in subsea sediments where the major challenge comes from implemen- tation of solubility, and mod- eling methane hydrate evolution in subsea sediments (MH). Coalbed methane is a form of natural

  16. ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    ANALYSIS OF METHANE PRODUCING COMMUNITIES WITHIN UNDERGROUND COAL BEDS by Elliott Paul Barnhart.........................................................................................8 Coal and Metabolite Enrichment Studies ..................................................................................14 Ability of the Consortium to Produce Methane from Coal and Metabolites ................16

  17. Evaluation of Phytoremediation of Coal Bed Methane Product Water and Waters of Quality Similar to that Associated with Coal Bed Methane Reserves of the Powder River Basin, Montana and Wyoming

    SciTech Connect (OSTI)

    James Bauder

    2008-09-30

    U.S. emphasis on domestic energy independence, along with advances in knowledge of vast biogenically sourced coalbed methane reserves at relatively shallow sub-surface depths with the Powder River Basin, has resulted in rapid expansion of the coalbed methane industry in Wyoming and Montana. Techniques have recently been developed which constitute relatively efficient drilling and methane gas recovery and extraction techniques. However, this relatively efficient recovery requires aggressive reduction of hydrostatic pressure within water-saturated coal formations where the methane is trapped. Water removed from the coal formation during pumping is typically moderately saline and sodium-bicarbonate rich, and managed as an industrial waste product. Current approaches to coalbed methane product water management include: surface spreading on rangeland landscapes, managed irrigation of agricultural crop lands, direct discharge to ephermeral channels, permitted discharge of treated and untreated water to perennial streams, evaporation, subsurface injection at either shallow or deep depths. A Department of Energy-National Energy Technology Laboratory funded research award involved the investigation and assessment of: (1) phytoremediation as a water management technique for waste water produced in association with coalbed methane gas extraction; (2) feasibility of commercial-scale, low-impact industrial water treatment technologies for the reduction of salinity and sodicity in coalbed methane gas extraction by-product water; and (3) interactions of coalbed methane extraction by-product water with landscapes, vegetation, and water resources of the Powder River Basin. Prospective, greenhouse studies of salt tolerance and water use potential of indigenous, riparian vegetation species in saline-sodic environments confirmed the hypothesis that species such as Prairie cordgrass, Baltic rush, American bulrush, and Nuttall's alkaligrass will thrive in saline-sodic environments when water supplies sourced from coalbed methane extraction are plentiful. Constructed wetlands, planted to native, salt tolerant species demonstrated potential to utilize substantial volumes of coalbed methane product water, although plant community transitions to mono-culture and limited diversity communities is a likely consequence over time. Additionally, selected, cultured forage quality barley varieties and native plant species such as Quail bush, 4-wing saltbush, and seaside barley are capable of sustainable, high quality livestock forage production, when irrigated with coalbed methane product water sourced from the Powder River Basin. A consequence of long-term plant water use which was enumerated is elevated salinity and sodicity concentrations within soil and shallow alluvial groundwater into which coalbed methane product water might drain. The most significant conclusion of these investigations was the understanding that phytoremediation is not a viable, effective technique for management of coalbed methane product water under the present circumstances of produced water within the Powder River Basin. Phytoremediation is likely an effective approach to sodium and salt removal from salt-impaired sites after product water discharges are discontinued and site reclamation is desired. Coalbed methane product water of the Powder River Basin is most frequently impaired with respect to beneficial use quality by elevated sodicity, a water quality constituent which can cause swelling, slaking, and dispersion of smectite-dominated clay soils, such as commonly occurring within the Powder River Basin. To address this issue, a commercial-scale fluid-bed, cationic resin exchange treatment process and prototype operating treatment plant was developed and beta-tested by Drake Water Technologies under subcontract to this award. Drake Water Technologies secured U.S. Patent No. 7,368,059-B2, 'Method for removal of benevolent cations from contaminated water', a beta Drake Process Unit (DPU) was developed and deployed for operation in the Powder River Basin. First year operatio

  18. Kinetics of Methane Hydrate Decomposition Studied via in Situ Low Temperature X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Keffer, David J.; Mull, Derek L; Payzant, E Andrew; Phelps, Tommy Joe

    2013-01-01

    Gas hydrates are known to have a slowed decomposition rate at ambient pressure and temperatures below the melting point of ice termed self-preservation or anomalous preservation. As hydrate exothermically decomposes, gas is released and water of the clathrate cages transforms into ice. Two regions of slowed decomposition for methane hydrate, 180 200 K and 230 260 K, were observed, and the kinetics were studied by in situ low temperature x-ray powder diffraction. The kinetic constants for ice formation from methane hydrate were determined by the Avrami model within each region and activation energies, Ea, were determined by the Arrhenius plot. Ea determined from the data for 180 200 K was 42 kJ/mol and for 230 260 K was 22 kJ/mol. The higher Ea in the colder temperature range was attributed to a difference in the microstructure of ice between the two regions.

  19. Direct use of methane in coal liquefaction

    DOE Patents [OSTI]

    Sundaram, Muthu S. (Shoreham, NY); Steinberg, Meyer (Melville, NY)

    1987-01-01

    This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20-120 minutes at a temperature of 250.degree.-750.degree. C., preferably 350.degree.-450.degree. C., pressurized up to 6000 psi, and preferably in the 1000-2500 psi range, preferably directly utilizing methane 50-100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0-100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems.

  20. Direct use of methane in coal liquefaction

    DOE Patents [OSTI]

    Sundaram, M.S.; Steinberg, M.

    1985-06-19

    This invention relates to a process for converting solid carbonaceous material, such as coal, to liquid and gaseous hydrocarbons utilizing methane, generally at a residence time of about 20 to 120 minutes at a temperature of 250 to 750/sup 0/C, preferably 350 to 450/sup 0/C, pressurized up to 6000 psi, and preferably in the 1000 to 2500 psi range, preferably directly utilizing methane 50 to 100% by volume in a mix of methane and hydrogen. A hydrogen donor solvent or liquid vehicle such as tetralin, tetrahydroquinoline, piperidine, and pyrolidine may be used in a slurry mix where the solvent feed is 0 to 100% by weight of the coal or carbonaceous feed. Carbonaceous feed material can either be natural, such as coal, wood, oil shale, petroleum, tar sands, etc., or man-made residual oils, tars, and heavy hydrocarbon residues from other processing systems. 1 fig.

  1. Development of Real-Time, Gas Quality Sensor Technology

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 645 operational projects in 48 states. These projects convert a large source of greenhouse gases into a fuel that...

  2. Constraints on Asian and European sources of methane from CH4 -C2H6-CO correlations in Asian outflow

    E-Print Network [OSTI]

    Jacob, Daniel J.

    of emissions from coal mining and landfills. 2 #12;1. Introduction Atmospheric methane (CH4) is an important, landfills, fossil fuel production and consumption (natural gas venting, leakage and coal mining a global CH4 source inventory constrained with NOAA/CMDL surface observations [Wang et al., 2003]. We find

  3. Title: Functioning of wetlands as a source of atmospheric methane: a multi-scale and multi-disciplinary approach

    E-Print Network [OSTI]

    is to determine how climate change affects the interacting processes that determine net CH4 and CO2 emissions from Laboratory Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2 climate-sensitive ecosystems release both CH4 and carbon dioxide (CO2) and it is unknown how these systems

  4. Gas hydrates

    SciTech Connect (OSTI)

    Not Available

    1985-04-01

    There is a definite need for the US government to provide leadership for research in gas hydrates and to coordinate its activities with academia, industry, private groups, federal agencies, and their foreign counterparts. In response to this need, the DOE Morgantown Energy Technology Center implemented a gas hydrates R and D program. Understanding the resource will be achieved through: assessment of current technology; characterization of gas hydrate geology and reservoir engineering; and development of diagnostic tools and methods. Research to date has focused on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for future detailed investigation. Initial research activities involved the development of the Geologic Analysis System (GAS); which will provide, through approximately 30 software packages, the capability to manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. Preliminary mapping of hydrate prospects for the Alaskan North Slope is underway. Geological research includes physical system characterization which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran, consolidated rock cores, frost base mixtures, water/ice base mixtures, and water base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by METC. More recently, a natural hydrate sample from the Gulf of Mexico was also acquired and testing of this sample is currently underway. In addition to the development of GAS, modeling and systems analysis work focused on the development of conceptual gas hydrate production models. 16 figs., 6 tabs.

  5. Introduction In the past two centuries, atmospheric methane

    E-Print Network [OSTI]

    Haak, Hein

    of methane in the atmosphere is controlled by oxidation, mainly in chemical reaction with the hydroxyl by the combination of pre-industrial methane concentration levels from ice cores and bottom-up estimates based important terms in the global methane budget. Anthropogenic source estimates are mainly based on socio

  6. Snowball Earth termination by destabilization of equatorial permafrost methane clathrate

    E-Print Network [OSTI]

    Kennedy, Martin J.

    LETTERS Snowball Earth termination by destabilization of equatorial permafrost methane clathrate-gassing during post-glacial oceanic overturn7 or methane hydrate destabilization8­10 . Here we report the broadest range of oxygen isotope values yet measured in mar- ine sediments (225% to 112%) in methane seeps

  7. ORIGINAL PAPER The influence of plants on atmospheric methane

    E-Print Network [OSTI]

    Minnesota, University of

    ORIGINAL PAPER The influence of plants on atmospheric methane in an agriculture-dominated landscape on atmospheric methane (CH4) in an agriculture-dominated landscape in the Upper Mid- west of the United States role in the landscape-scale CH4 budget. Keywords Methane . Corn . Soybean . Agriculture . Land surface

  8. Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands

    E-Print Network [OSTI]

    Goddard III, William A.

    Methane Activation with Rhenium Catalysts. 1. Bidentate Oxygenated Ligands Jason M. Gonzales, Jonas, California 90089 ReceiVed July 31, 2006 Trends in methane activation have been explored for rhenium complexes proceeds with methane activation through a barrier of less than 35 kcal mol-1 . Study

  9. Carbon and Hydrogen Isotopic Effects in Microbial Methane

    E-Print Network [OSTI]

    Saleska, Scott

    6 Carbon and Hydrogen Isotopic Effects in Microbial Methane from Terrestrial Environments Jeffrey Chanton, Lia Chaser, Paul Glasser,Don Siegel Methane is the ultimate end-product of anaerobic respiration. Methane production via CO2 reduction does not consume CO2. Also, acetate can be written as 2CH20, so Eq. 6

  10. The Production of Non-Methane Hydrocarbons by Marine Plankton

    E-Print Network [OSTI]

    The Production of Non-Methane Hydrocarbons by Marine Plankton Stephanie Lyn Shaw Center for Global://web.mit.edu/cgcs/ Printed on recycled paper #12;1 The Production of Non-Methane Hydrocarbons by Marine Plankton by Stephanie of Non-Methane Hydrocarbons by Marine Plankton by Stephanie Lyn Shaw Submitted to the Department of Earth

  11. Physical Controls on Methane Ebullition from Reservoirs and Lakes

    E-Print Network [OSTI]

    Johnson, Cari

    of methane production and flux in aquatic sediments has important geochemical, geotechnical, and global; Anselmann and Crutzen, 1989; and Reeburgh et al., 1993). Because methane has the potential to con- tributePhysical Controls on Methane Ebullition from Reservoirs and Lakes JENNIFER JOYCE PAUL W. JEWELL

  12. Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the

    E-Print Network [OSTI]

    Toohey, Darin W.

    Methane Production: In the United States cattle emit about 5.5 million metric tons of methane per year into the atmosphere. o Accounts for 20% of methane emissions from human sources. Globally cattle produce about 80 million metric tons of methane annually. o Accounts for 28% of global methane emissions

  13. Remote Sensing and Sea-Truth Measurements of Methane Flux to the Atmosphere (HYFLUX project)

    SciTech Connect (OSTI)

    Ian MacDonald

    2011-05-31

    A multi-disciplinary investigation of distribution and magnitude of methane fluxes from seafloor gas hydrate deposits in the Gulf of Mexico was conducted based on results obtained from satellite synthetic aperture radar (SAR) remote sensing and from sampling conducted during a research expedition to three sites where gas hydrate occurs (MC118, GC600, and GC185). Samples of sediments, water, and air were collected from the ship and from an ROV submersible using sediments cores, niskin bottles attached to the ROV and to a rosette, and an automated sea-air interface collector. The SAR images were used to quantify the magnitude and distribution of natural oil and gas seeps that produced perennial oil slicks on the ocean surface. A total of 176 SAR images were processed using a texture classifying neural network algorithm, which segmented the ocean surface into oil-free and oil-covered water. Geostatistical analysis indicates that there are a total of 1081 seep formations distributed over the entire Gulf of Mexico basin. Oil-covered water comprised an average of 780.0 sq. km (sd 86.03) distributed with an area of 147,370 sq. km. Persistent oil and gas seeps were also detected with SAR sampling on other ocean margins located in the Black Sea, western coast of Africa, and offshore Pakistan. Analysis of sediment cores from all three sites show profiles of sulfate, sulfide, calcium and alkalinity that indicated anaerobic oxidation of methane with precipitation of authigenic carbonates. Difference among the three sampling sites may reflect the relative magnitude of methane flux. Methane concentrations in water column samples collected by ROV and rosette deployments from MC118 ranged from {approx}33,000 nM at the seafloor to {approx}12 nM in the mixed layer with isolated peaks up to {approx}13,670 nM coincident with the top of the gas hydrate stability field. Average plume methane, ethane, and propane concentrations in the mixed layer are 7, 630, and 9,540 times saturation, respectively. Based on the contemporaneous wind speeds at this site, contemporary estimates of the diffusive fluxes from the mixed layer to the atmosphere for methane, ethane, and propane are 26.5, 2.10, and 2.78 {micro}mol/m{sup 2}d, respectively. Continuous measurements of air and sea surface concentrations of methane were made to obtain high spatial and temporal resolution of the diffusive net sea-to-air fluxes. The atmospheric methane fluctuated between 1.70 ppm and 2.40 ppm during the entire cruise except for high concentrations (up to 4.01 ppm) sampled during the end of the occupation of GC600 and the transit between GC600 and GC185. Results from interpolations within the survey areas show the daily methane fluxes to the atmosphere at the three sites range from 0.744 to 300 mol d-1. Considering that the majority of seeps in the GOM are deep (>500 m), elevated CH{sub 4} concentrations in near-surface waters resulting from bubble-mediated CH4 transport in the water column are expected to be widespread in the Gulf of Mexico.

  14. Coal companies hope to receive carbon credits for methane reductions

    SciTech Connect (OSTI)

    2007-09-30

    Each year, underground coal mining in the USA liberates 2.4 million tonnes of coal mine methane (CMM), of which less than 30% is recovered and used. One barrier to CMM recovery is cost. Drainage, collection, and utilization systems are complex and expensive to install. Two coal mines have improved the cost equation, however, by signing on to earn money for CMM emissions they are keeping out of the atmosphere. Jim Walter Resources and PinnOak Resources have joined a voluntary greenhouse gas reduction trading program called the Chicago Climate Exchange (CCX) to turn their avoided emissions into carbon credits. The example they set may encourage other coal mining companies to follow suit, and may bring new projects on the line that would otherwise have not gone forward. 2 refs., 1 fig.

  15. Modeling Methane Adsorption in Interpenetrating Porous Polymer Networks

    SciTech Connect (OSTI)

    Martin, RL; Shahrak, MN; Swisher, JA; Simon, CM; Sculley, JP; Zhou, HC; Smit, B; Haranczyk, M

    2013-10-03

    Porous polymer networks (PPNs) are a class of porous materials of particular interest in a variety of energy-related applications because of their stability, high surface areas, and gas uptake capacities. Computationally derived structures for five recently synthesized PPN frameworks, PPN-2, -3, -4, -5, and -6, were generated for various topologies, optimized using semiempirical electronic structure methods, and evaluated using classical grand canonical Monte Carlo simulations. We show that a key factor in modeling the methane uptake performance of these materials is whether, and how, these material frameworks interpenetrate and demonstrate a computational approach for predicting the presence, degree, and nature of interpenetration in PPNs that enables the reproduction of experimental adsorption data.

  16. Marine methane cycle simulations for the period of early global warming

    SciTech Connect (OSTI)

    Elliott, S.; Maltrud, M.; Reagan, M.T.; Moridis, G.J.; Cameron-Smith, P.J.

    2011-01-02

    Geochemical environments, fates, and effects are modeled for methane released into seawater by the decomposition of climate-sensitive clathrates. A contemporary global background cycle is first constructed, within the framework of the Parallel Ocean Program. Input from organics in the upper thermocline is related to oxygen levels, and microbial consumption is parameterized from available rate measurements. Seepage into bottom layers is then superimposed, representing typical seabed fluid flow. The resulting CH{sub 4} distribution is validated against surface saturation ratios, vertical sections, and slope plume studies. Injections of clathrate-derived methane are explored by distributing a small number of point sources around the Arctic continental shelf, where stocks are extensive and susceptible to instability during the first few decades of global warming. Isolated bottom cells are assigned dissolved gas fluxes from porous-media simulation. Given the present bulk removal pattern, methane does not penetrate far from emission sites. Accumulated effects, however, spread to the regional scale following the modeled current system. Both hypoxification and acidification are documented. Sensitivity studies illustrate a potential for material restrictions to broaden the perturbations, since methanotrophic consumers require nutrients and trace metals. When such factors are considered, methane buildup within the Arctic basin is enhanced. However, freshened polar surface waters act as a barrier to atmospheric transfer, diverting products into the deep return flow. Uncertainties in the logic and calculations are enumerated including those inherent in high-latitude clathrate abundance, buoyant effluent rise through the column, representation of the general circulation, and bacterial growth kinetics.

  17. Carborane-Based Metal-Organic Framework with High Methane and Hydrogen Storage Capacities

    SciTech Connect (OSTI)

    Kennedy, RD; Krungleviciute, V; Clingerman, DJ; Mondloch, JE; Peng, Y; Wilmer, CE; Sarjeant, AA; Snurr, RQ; Hupp, JT; Yildirim, T; Farha, OK; Mirkin, CA

    2013-09-10

    A Cu-carborane-based metal organic framework (MOF), NU-135, which contains a quasi-spherical para-carborane moiety, has been synthesized and characterized. NU-135 exhibits a pore volume of 1.02 cm(3)/g and a gravimetric BET surface area of ca. 2600 m(2)/g, and thus represents the first highly porous carborane-based MOF. As a consequence of the, unique geometry of the carborane unit, NU-135 has a very high volumetric BET surface area of ca. 1900 m(2)/cm(3). CH4, CO2, and H-2 adsorption isotherms were measured over a broad range of pressures and temperatures and are in good agreement with computational predictions. The methane storage capacity of NU-135 at 35 bar and 298 K is ca. 187 v(STP)/v. At 298 K, the pressure required to achieve a methane storage density comparable to that of a compressed natural gas (CNG) tank pressurized to 212 bar, which is a typical storage pressure, is only 65 bar. The methane working capacity (5-65 bar) is 170 v(STP)/v. The volumetric hydrogen storage capacity at 55 bar and 77 K is 49 g/L. These properties are comparable to those of current record holders in the area of methane and hydrogen storage. This initial example lays the groundwork for carborane-based materials with high surface areas.

  18. Reaction dynamics of atomic chlorine with methane: Importance of methane bending and torsional excitation in controlling reactivity

    E-Print Network [OSTI]

    Reaction dynamics of atomic chlorine with methane: Importance of methane bending and torsional with methane vibrationally excited in trace quantities into low-energy bending and torsional modes­7 and detailed the effect on reactivity of C­H stretch vibrational excitation.5­7 This paper concerns our most

  19. Factors influencing methane distribution in Texas ground water

    SciTech Connect (OSTI)

    Zhang, C.; Grossman, E.L.; Ammerman, J.W. [Texas A and M Univ., College Station, TX (United States)

    1998-01-01

    To determine the factors that influence the distribution of methane in Texas ground water, water samples were collected from 40 wells in east-central and central Texas aquifers. Among the chemical parameters examined, sulfate is most important in controlling methane distribution. Methane occurs in high concentration in east-central Texas only where sulfate concentration is low, supporting the hypothesis that abundant microbial methane production does not begin until sulfate is depleted. Because water samples from central Texas are high in either oxygen or sulfate, methane concentrations are low in these waters. A positive correlation between methane and sulfate in these waters indicates a different, perhaps thermogenic, origin for the trace methane. The {sup 13}C/{sup 12}C ratios of dissolved methane ranged from {minus}80{per_thousand} to {minus}21{per_thousand} in east-central Texas and {minus}41.2{per_thousand} to {minus}8.5{per_thousand} in central Texas. Low values of < {minus}50{per_thousand} in the east-central Texas ground water indicate a microbial origin for methane and are consistent with the observed sulfate-methane relationship; high {sup 13}C/{sup 12}C ratios of > {minus}31{per_thousand} likely result from bacterial methane oxidation. Similarly, methane with high {sup 13}C/{sup 12}C ratios in central Texas may reflect partial oxidation of the methane pool. Overall, water samples from both regions show a positive correlation between sulfate concentration and the {sup 13}C/{sup 12}C ratio of methane, suggesting that methane oxidation may be associated with sulfate reduction in Texas ground water.

  20. Methane recovery from coalbeds project. Monthly progress report

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    Progress made on the Methane Recovery from Coalbeds Project (MRCP) is reported in the Raton Mesa Coal Region. The Uinta and Warrior basin reports have been reviewed and will be published and delivered in early December. A cooperative core test with R and P Coal Company on a well in Indiana County, Pennsylvania, was negotiated. In a cooperative effort with the USGS Coal Branch on three wells in the Wind River Basin, desorption of coal samples showed little or no gas. Completed field testing at the Dugan Petroleum well in the San Juan Basin. Coal samples showed minimal gas. Initial desorption of coal samples suggests that at least a moderate amount of gas was obtained from the Coors well test in the Piceance Basin. Field work for the Piceance Basin Detailed Site Investigation was completed. In the Occidental Research Corporation (ORC) project, a higher capacity vacuum pump to increase CH/sub 4/ venting operations has been installed. Drilling of Oxy No. 12 experienced delays caused by mine gas-offs and was eventually terminated at 460 ft after an attempt to drill through a roll which produced a severe dog leg and severely damaged the drill pipe. ORC moved the second drill rig and equipment to a new location in the same panel as Oxy No. 12 and set the stand pipe for Oxy No. 13. Drill rig No. 1 has been moved east of the longwall mining area in anticipation of drilling cross-panel on 500 foot intervals. Waynesburg College project, Equitable Gas Company has received the contract from Waynesburg College and has applied to the Pennsylvania Public Utilities Commission for a new tariff rate. Waynesburg College has identified a contractor to make the piping connections to the gas line after Equitable establishes their meter and valve requirements.

  1. Controlling Methane Emissions in the Natural Gas Sector: A Review...

    Broader source: Energy.gov (indexed) [DOE]

    from this sector have typically occurred as a co-benefit of policies that target air pollution (such as smog) and improve safety. In general, policy strategies that reduce...

  2. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy demands, uncertainty about supplies, and the urgent need to reduce emissions of greenhouse gases mean that the world faces an uncertain energy future. Many countries have...

  3. Methane Gas Conversion Property Tax Exemption | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecial ReportProposal toDepartment of Energy Metering Best

  4. Methane storage in advanced porous materials | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture | Center forDioxide Capture

  5. Methane present in an extrasolar planet atmosphere

    E-Print Network [OSTI]

    Mark R. Swain; Gautam Vasisht; Giovanna Tinetti

    2008-02-07

    Molecules present in exoplanetary atmospheres are expected to strongly influence the atmospheric radiation balance, trace dynamical and chemical processes, and indicate the presence of disequilibrium effects. Since molecules have the potential to reveal the exoplanet atmospheric conditions and chemistry, searching for them is a high priority. The rotational-vibrational transition bands of water, carbon monoxide, and methane are anticipated to be the primary sources of non-continuum opacity in hot-Jovian planets. Since these bands overlap in wavelength, and the corresponding signatures from them are weak, decisive identification requires precision infrared spectroscopy. Here we report on a near-infrared transmission spectrum of the planet HD 189733b showing the presence of methane. Additionally, a resolved water-vapour band at 1.9 microns confirms the recent claim of water in this object. On thermochemical grounds, carbon-monoxide is expected to be abundant in the upper atmosphere of hot-Jovian exoplanets; thus the detection of methane rather than carbon-monoxide in such a hot planet could signal the presence of a horizontal chemical gradient away from the permanent dayside, or it may imply an ill-understood photochemical mechanisms that leads to an enhancement of methane.

  6. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  7. Deep oxidation of methane on particles derived from YSZ-supported Pd-Pt-(O) coatings synthesized by pulsed filtered cathodic arc

    E-Print Network [OSTI]

    Horwat, D.

    2009-01-01

    2009) Deep oxidation of methane on particles derived fromAbstract Methane conversion tests were performed on Pd, PdOFigure captions Figure 1: Methane conversion a), methane

  8. Thermodynamic properties and diffusion of water + methane binary mixtures

    SciTech Connect (OSTI)

    Shvab, I.; Sadus, Richard J.

    2014-03-14

    Thermodynamic and diffusion properties of water + methane mixtures in a single liquid phase are studied using NVT molecular dynamics. An extensive comparison is reported for the thermal pressure coefficient, compressibilities, expansion coefficients, heat capacities, Joule-Thomson coefficient, zero frequency speed of sound, and diffusion coefficient at methane concentrations up to 15% in the temperature range of 298–650 K. The simulations reveal a complex concentration dependence of the thermodynamic properties of water + methane mixtures. The compressibilities, heat capacities, and diffusion coefficients decrease with increasing methane concentration, whereas values of the thermal expansion coefficients and speed of sound increase. Increasing methane concentration considerably retards the self-diffusion of both water and methane in the mixture. These effects are caused by changes in hydrogen bond network, solvation shell structure, and dynamics of water molecules induced by the solvation of methane at constant volume conditions.

  9. A Technical and Economic Study of Completion Techniques In Five Emerging U.S. Gas Shale Plays 

    E-Print Network [OSTI]

    Agrawal, Archna

    2010-07-14

    , energy companies, both majors and independents, are turning to unconventional resources to produce the hydrocarbons required to meet market demand. From coalbed methane to low permeability (tight) gas reservoirs and gas shales, energy companies are making...

  10. Coalbed Methane | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle (PEV) chargingWASHINGTON, DCTheBelow areyou

  11. Approved Module Information for ME1F20, 2014/5 Module Title/Name: Gas Engineering Principles Module Code: ME1F20

    E-Print Network [OSTI]

    Rebollo-Neira, Laura

    , Flow measurement, Coal Bed Methane, Natural Gas Phase Behaviour, Natural Gas Properties, Chemical and calculate the solutions of problems associated with Natural Gas flow and transmission Learn properties and Physical Properties, Gas Specific Gravity, Ideal and Real Gas Laws, Gas Formation Volume Factor, Gas

  12. How unconventional gas prospers without tax incentives

    SciTech Connect (OSTI)

    Kuuskraa, V.A.; Stevens, S.H.

    1995-12-11

    It was widely believed that the development of unconventional natural gas (coalbed methane, gas shales, and tight gas) would die once US Sec. 29 credits stopped. Quieter voices countered, and hoped, that technology advances would keep these large but difficult to produce gas resources alive and maybe even healthy. Sec. 29 tax credits for new unconventional gas development stopped at the end of 1992. Now, nearly three years later, who was right and what has happened? There is no doubt that Sec. 29 tax credits stimulated the development of coalbed methane, gas shales, and tight gas. What is less known is that the tax credits helped spawn and push into use an entire new set of exploration, completion, and production technologies founded on improved understanding of unconventional gas reservoirs. As set forth below, while the incentives inherent in Sec. 29 provided the spark, it has been the base of science and technology that has maintained the vitality of these gas sources. The paper discusses the current status; resource development; technology; unusual production, proven reserves, and well completions if coalbed methane, gas shales, and tight gas; and international aspects.

  13. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  14. POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    · Transportation of energy from production areas to consumption areas Substitute Natural Gas (methane) Myriam DeP · Use of existing natural gas network · Mid or long term storage · Transportation · Production. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis

  15. Natural gas monthly, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The Natural Gas Monthly (NGM) highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the NGM features articles designed to assist readers in using and interpreting natural gas information. The featured article for this month is on US coalbed methane production.

  16. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

    2005-04-01

    The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

  17. Estimating global and North American methane emissions with high spatial resolution using GOSAT satellite data

    SciTech Connect (OSTI)

    Turner, A. J. [Harvard Univ., Cambridge, MA (United States); Jacob, D. J. [Harvard Univ., Cambridge, MA (United States); Wecht, K. J. [National Oceanic and Atmospheric Administration (NOAA), Boulder, CO (United States). Earth System Research Lab.; Maasakkers, J. D. [Harvard Univ., Cambridge, MA (United States); Lundgren, E. [Harvard Univ., Cambridge, MA (United States); Andrews, A. E. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Biraud, S. C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)] (ORCID:000000017697933X); Boesch, H. [Univ. of Leicester (United Kingdom); Bowman, K. W. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab.; Deutscher, N. M. [Univ. of Wollongong, NSW (Australia); Dubey, M. K. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Griffith, D. W. T. [Univ. of Wollongong, NSW (Australia); Hase, F. [Karlsruhe Inst. of Technology (KIT) (Germany). IMK-ASF; Kuze, A. [Japan Aerospace Exploration Agency, Tsukuba (Japan)] (ORCID:0000000154153377); Notholt, J. [Univ. of Bremen (Germany); Ohyama, H. [Japan Aerospace Exploration Agency, Tsukuba (Japan); Parker, R. [Univ. of Leicester (United Kingdom); Payne, V. H. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab.; Sussmann, R. [Karlsruhe Inst. of Technology (KIT) Garmisch-Partenkirchen (Germany). IMK-IFU; Sweeney, C. [Karlsruhe Inst. of Technology (KIT) Garmisch-Partenkirchen (Germany). IMK-IFU; Velazco, V. A. [Univ. of Wollongong, NSW (Australia)] (ORCID:000000021376438X); Warneke, T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Wennberg, P. O. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Jet Propulsion Lab.; Wunch, D. [Pasadena, CA (United States). Jet Propulsion Lab.

    2015-01-01

    We use 2009–2011 space-borne methane observations from the Greenhouse Gases Observing SATellite (GOSAT) to estimate global and North American methane emissions with 4° × 5° and up to 50 km × 50 km spatial resolution, respectively. GEOS-Chem and GOSAT data are first evaluated with atmospheric methane observations from surface and tower networks (NOAA/ESRL, TCCON) and aircraft (NOAA/ESRL, HIPPO), using the GEOS-Chem chemical transport model as a platform to facilitate comparison of GOSAT with in situ data. This identifies a high-latitude bias between the GOSAT data and GEOS-Chem that we correct via quadratic regression. Our global adjoint-based inversion yields a total methane source of 539 Tg a?1 with some important regional corrections to the EDGARv4.2 inventory used as a prior. Results serve as dynamic boundary conditions for an analytical inversion of North American methane emissions using radial basis functions to achieve high resolution of large sources and provide error characterization. We infer a US anthropogenic methane source of 40.2–42.7 Tg a-1, as compared to 24.9–27.0 Tg a-1 in the EDGAR and EPA bottom-up inventories, and 30.0–44.5 Tg a-1 in recent inverse studies. Our estimate is supported by independent surface and aircraft data and by previous inverse studies for California. We find that the emissions are highest in the southern–central US, the Central Valley of California, and Florida wetlands; large isolated point sources such as the US Four Corners also contribute. Using prior information on source locations, we attribute 29–44 % of US anthropogenic methane emissions to livestock, 22–31 % to oil/gas, 20 % to landfills/wastewater, and 11–15 % to coal. Wetlands contribute an additional 9.0–10.1 Tg a-1.

  18. Implications of Representative Concentration Pathway 4.5 Methane Emissions to Stabilize Radiative Forcing

    SciTech Connect (OSTI)

    Emanuel, William R.; Janetos, Anthony C.

    2013-02-01

    Increases in the abundance of methane (CH4) in the Earth’s atmosphere are responsible for significant radiative forcing of climate change (Forster et al., 2007; Wuebbles and Hayhoe, 2002). Since 1750, a 2.5 fold increase in atmospheric CH4 contributed 0.5 W/m2 to direct radiative forcing and an additional 0.2 W/m2 indirectly through changes in atmospheric chemistry. Next to water and carbon dioxide (CO2), methane is the most abundant greenhouse gas in the troposphere. Additionally, CH4 is significantly more effective as a greenhouse gas on a per molecule basis than is CO2, and increasing atmospheric CH4 has been second only to CO2 in radiative forcing (Forster et al., 2007). The chemical reactivity of CH4 is important to both tropospheric and stratospheric chemistry. Along with carbon monoxide, methane helps control the amount of the hydroxyl radical (OH) in the troposphere where oxidation of CH4 by OH leads to the formation of formaldehyde, carbon monoxide, and ozone.

  19. FADD Expression as a Prognosticator in Early-Stage Glottic Squamous Cell Carcinoma of the Larynx Treated Primarily With Radiotherapy

    SciTech Connect (OSTI)

    Schrijvers, Michiel L. [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Pattje, Wouter J. [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Slagter-Menkema, Lorian [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Mastik, Mirjam F.; Gibcus, Johan H. [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Langendijk, Johannes A. [Department of Radiation Oncology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Wal, Jacqueline E. van der [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Laan, Bernard F.A.M. vn der [Department of Otorhinolaryngology/Head and Neck Surgery, University Medical Center Groningen, University of Groningen, Groningen (Netherlands); Schuuring, E., E-mail: e.schuuring@umcg.nl [Department of Pathology, University Medical Center Groningen, University of Groningen, Groningen (Netherlands)

    2012-07-15

    Purpose: We recently reported on the identification of the Fas-associated death domain (FADD) as a possible driver of the chromosome 11q13 amplicon and the association between increased FADD expression and disease-specific survival in advanced-stage laryngeal carcinoma. The aim of this study was to examine whether expression of FADD and its Ser194-phosphorylated isoform (pFADD) predicts local control in patients with early-stage glottic carcinoma primarily treated with radiotherapy only. Methods and Materials: Immunohistochemical staining for FADD and pFADD was performed on pretreatment biopsy specimens of 92 patients with T1-T2 glottic squamous cell carcinoma primarily treated with radiotherapy between 1996 and 2005. Cox regression analysis was used to correlate expression levels with local control. Results: High levels of pFADD were associated with significantly better local control (hazard ratio, 2.40; 95% confidence interval, 1.04-5.55; p = 0.040). FADD overexpression showed a trend toward better local control (hazard ratio, 3.656; 95% confidence interval, 0.853-15.663; p = 0.081). Multivariate Cox regression analysis showed that high pFADD expression was the best predictor of local control after radiotherapy. Conclusions: This study showed that expression of phosphorylated FADD is a new prognostic biomarker for better local control after radiotherapy in patients with early-stage glottic carcinomas.

  20. Self-Diffusion Coefficients of Methane or Ethane Mixtures with Hydrocarbons at High Pressure by NMR

    E-Print Network [OSTI]

    Dysthe, Dag Kristian

    Self-Diffusion Coefficients of Methane or Ethane Mixtures with Hydrocarbons at High Pressure by NMR in homogeneous mixtures of methane + hexane, ethane + hexane, methane + octane, ethane + octan, methane + decane, ethane + decane, and methane + hexane + benzene over the whole concentration range, at 303.2 K and 333

  1. ACTION CONCENTRATION FOR MIXTURES OF VOLATILE ORGANIC COMPOUNDS (VOC) & METHANE & HYDROGEN

    SciTech Connect (OSTI)

    MARUSICH, R.M.

    2006-07-10

    Waste containers may contain volatile organic compounds (VOCs), methane, hydrogen and possibly propane. These constituents may occur individually or in mixtures. Determining if a waste container contains a flammable concentration of flammable gases and vapors (from VOCs) is important to the safety of the handling, repackaging and shipping activities. This report provides the basis for determining the flammability of mixtures of flammable gases and vapors. The concentration of a mixture that is at the lowest flammability limit for that mixture is called the action concentration. The action concentration can be determined using total VOC concentrations or actual concentration of each individual VOC. The concentrations of hydrogen and methane are included with the total VOC or individual VOC concentration to determine the action concentration. Concentrations below this point are not flammable. Waste containers with gas/vapor concentrations at or above the action concentration are considered flammable.

  2. Landfill Gas Conversion to LNG and LCO{sub 2}. Final Report

    SciTech Connect (OSTI)

    Brown, W.R.; Cook, W. J.; Siwajek, L.A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery. Work was done in the following areas: (1) production of natural gas pipeline methane for liquefaction at an existing LNG facility, (2) production of LNG from sewage digester gas, (3) the use of mixed refrigerants for process cooling in the production of LNG, liquid CO{sub 2} and pipeline methane, (4) cost estimates for an LNG production facility at the Arden Landfill in Washington PA.

  3. Methane Hydrate Program Annual Report to Congress

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy May 28 WebinarProtectMessageFY 2010 Methane Hydrate

  4. Process for separating nitrogen from methane using microchannel process technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Marysville, OH); Qiu, Dongming (Dublin, OH); Dritz, Terence Andrew (Worthington, OH); Neagle, Paul (Westerville, OH); Litt, Robert Dwayne (Westerville, OH); Arora, Ravi (Dublin, OH); Lamont, Michael Jay (Hilliard, OH); Pagnotto, Kristina M. (Cincinnati, OH)

    2007-07-31

    The disclosed invention relates to a process for separating methane or nitrogen from a fluid mixture comprising methane and nitrogen, the process comprising: (A) flowing the fluid mixture into a microchannel separator, the microchannel separator comprising a plurality of process microchannels containing a sorption medium, the fluid mixture being maintained in the microchannel separator until at least part of the methane or nitrogen is sorbed by the sorption medium, and removing non-sorbed parts of the fluid mixture from the microchannel separator; and (B) desorbing the methane or nitrogen from the sorption medium and removing the desorbed methane or nitrogen from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources.

  5. Effects of radiation and compression on propagating spherical flames of methane/air mixtures near the lean flammability limit

    SciTech Connect (OSTI)

    Chen, Zheng [State Key Laboratory for Turbulence and Complex Systems, Department of Mechanics and Aerospace Engineering, College of Engineering, Peking University, Beijing 100871 (China)

    2010-12-15

    Large discrepancies between the laminar flame speeds and Markstein lengths measured in experiments and those predicted by simulations for ultra-lean methane/air mixtures bring a great concern for kinetic mechanism validation. In order to quantitatively explain these discrepancies, a computational study is performed for propagating spherical flames of lean methane/air mixtures in different spherical chambers using different radiation models. The emphasis is focused on the effects of radiation and compression. It is found that the spherical flame propagation speed is greatly reduced by the coupling between thermal effect (change of flame temperature or unburned gas temperature) and flow effect (inward flow of burned gas) induced by radiation and/or compression. As a result, for methane/air mixtures near the lean flammability limit, the radiation and compression cause large amounts of under-prediction of the laminar flame speeds and Markstein lengths extracted from propagating spherical flames. Since radiation and compression both exist in the experiments on ultra-lean methane/air mixtures reported in the literature, the measured laminar flame speeds and Markstein lengths are much lower than results from simulation and thus cannot be used for kinetic mechanism validation. (author)

  6. Coupling of nitrous oxide and methane by global atmospheric chemistry

    E-Print Network [OSTI]

    Prather, MJ; Hsu, J

    2010-01-01

    supported by NSF’s Atmospheric Chemistry program (grant ATM-Methane by Global Atmospheric Chemistry Michael J. Prathergas, through atmospheric chemistry that en- hances the

  7. ,"U.S. Coalbed Methane Proved Reserves, Reserves Changes, and...

    U.S. Energy Information Administration (EIA) Indexed Site

    ame","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2013,"06301989"...

  8. ,"New Mexico Coalbed Methane Proved Reserves, Reserves Changes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Coalbed Methane Proved Reserves, Reserves Changes, and Production",10,"Annual",2014,"0...

  9. Microbe-metazoan interactions at Pacific Ocean methane seeps

    E-Print Network [OSTI]

    Thurber, Andrew Reichmann

    2010-01-01

    lipid biomarkers for microbes with chemoautotrophicOF CALIFORNIA, SAN DIEGO Microbe-Metazoan Interactions atxiv xvii xviii Chapter 3. Microbes, Macrofauna, and Methane:

  10. Microbe-Metazoan interactions at Pacific Ocean methane seeps

    E-Print Network [OSTI]

    Thurber, Andrew R

    2010-01-01

    lipid biomarkers for microbes with chemoautotrophicOF CALIFORNIA, SAN DIEGO Microbe-Metazoan Interactions atxiv xvii xviii Chapter 3. Microbes, Macrofauna, and Methane:

  11. Process for separating nitrogen from methane using microchannel...

    Office of Scientific and Technical Information (OSTI)

    from the microchannel separator. The process is suitable for upgrading methane from coal mines, landfills, and other sub-quality sources. Authors: Tonkovich, Anna Lee 1 ;...

  12. Critical Factors Driving the High Volumetric Uptake of Methane...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Critical Factors Driving the High Volumetric Uptake of Methane in Cu-3(btc)(2) Previous Next List Hulvey, Zeric; Vlaisavljevich, Bess; Mason, Jarad A.; Tsivion, Ehud; Dougherty,...

  13. Methane production during the anaerobic decomposition of composted and raw organic refuse in simulated landfill cells 

    E-Print Network [OSTI]

    West, Margrit Evelyn

    1995-01-01

    Methane contributes 20% annually to increases in global warming, and is explosive at concentrations of 5-15% in air. Landfills contribute 15% to total methane emissions. This study was conducted to determine the potential decrease in methane...

  14. Stable carbon and hydrogen isotope measurements on Black Sea water-column methane

    E-Print Network [OSTI]

    Reeburgh, WS; Tyler, SC; Carroll, J

    2006-01-01

    M.A. , Lee, C. , 1994. Methane production during zooplanktonDickens, G.R. , 2003. A methane trigger for global warming?Quinby-Hunt, M.S. , 1994. Methane stability in seawater.

  15. Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions

    E-Print Network [OSTI]

    Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

    2013-01-01

    in tropospheric ozone and methane; global 3-D model studies,hydroxyl radical and methane life- time from the Atmosphericof meteorology and emissions on methane trends, 1990–2004,

  16. Methane Hydrate Dissociation by Depressurization in a Mount Elbert Sandstone Sample: Experimental Observations and Numerical Simulations

    E-Print Network [OSTI]

    Kneafsey, T.

    2012-01-01

    S.S.H. , 1987. Kinetics of Methane Hydrate Decomposition,T. J. , et al. (2007), Methane Hydrate Formation andCharting the future of methane hydrate research in the

  17. Methane from UV-irradiated carbonaceous chondrites under simulated Martian conditions

    E-Print Network [OSTI]

    Schuerger, Andrew C.

    Methane from UV-irradiated carbonaceous chondrites under simulated Martian conditions Andrew C process was studied for the production of methane from carbonaceous chondrites under simulated Martian conditions. Methane evolution rates from carbonaceous chondrites were found to be positively correlated

  18. Analysis of a direct methane conversion to high molecular weight hydrocarbons 

    E-Print Network [OSTI]

    Al-Ghafran, Moh'd. J.

    2000-01-01

    Methane conversion to heavier hydrocarbons was studied using electrical furnaces and a plasma apparatus. The experiments were performed with pure methane for the electrical furnace experiments while pure methane and additions such as hydrogen...

  19. Mechanistic studies of electron transfer, complex formation, C-H bond activation, and product binding in soluble methane monooxygenase

    E-Print Network [OSTI]

    Kopp, Daniel Arthur

    2003-01-01

    Chapter 1. Soluble Methane Monooxygenase: Activation of Dioxygen and Methane The mechanisms by which soluble methane monooxygenase uses dioxygen to convert methane selectively to methanol have come into sharp focus. Diverse ...

  20. SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN Sea Floor Methane Hydrates at Hydrate Ridge, Cascadia Margin

    E-Print Network [OSTI]

    Goldfinger, Chris

    SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN 1 Sea Floor Methane are exposed at the sea floor. A methane-oxidizing bacterial consortium populates the exposures of hydrate; colonies of vent macro-fauna are abundant as well. Discharge of methane from destabilized hydrate

  1. Diffusive Evolution of Gaseous and Diffusive Evolution of Gaseous and Hydrate Horizons of Methane in SeabedHydrate Horizons of Methane in Seabed

    E-Print Network [OSTI]

    Banaji,. Murad

    Diffusive Evolution of Gaseous and Diffusive Evolution of Gaseous and Hydrate Horizons of Methane in SeabedHydrate Horizons of Methane in Seabed Denis S. Goldobin (University of Leicester),Denis S. Goldobin"")) MethaneNetMethaneNet Early Career Workshop Early Career Workshop MiltonMilton KeynesKeynes 2929

  2. Towards quantifying the reaction network around the sulfate–methane-transition-zone in the Ulleung Basin, East Sea, with a kinetic modeling approach

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hong, Wei-Li; Torres, Marta E.; Kim, Ji-Hoon; Choi, Jiyoung; Bahk, Jang-Jun

    2014-09-01

    We present a kinetic model based upon pore water data collected from eight sites drilled during the second Ulleung Basin gas hydrate drilling expedition (UBGH2) in 2010. Three sites were drilled at locations where acoustic chimneys were identified in seismic data, and the rest were drilled on non-chimney (i.e. background) environments. Our model, coupled a comprehensive compositional and isotopic data set, is used to illustrate the different biogeochemical processes at play in those two environments, in terms of reactions around the sulfate-methane-transition-zone (SMTZ). Organic matter decomposition is an important process for production of methane, dissolved inorganic carbon (DIC) and consumptionmore »of sulfate in the non-chimney sites, whereas anaerobic oxidation of methane (AOM) dominates both carbon and sulfur cycles in the chimney environment. Different sources of methane mediate AOM in the two settings. Internally produced methane through CO? reduction (CR) and methanogenesis fuels AOM in the non-chimney sites, whereas AOM is sustained by methane from external sources in the chimney sites. We also simulate the system evolution from non-chimney to chimney conditions by increasing the bottom methane supply to a non-chimney setting. We show that the higher CH? flux leads to a higher microbial activity of AOM, and more organic matter decomposition through methanogenesis. A higher methanogenesis rate and a smaller CR contribution relative to AOM in the chimney sites is responsible for the isotopically light DIC and heavy methane in this environment, relative to the non-chimney sites.« less

  3. 1870 Organometallics 1994,13,1870-1877 Mechanism and Energetics for Dehydrogenation of Methane

    E-Print Network [OSTI]

    Goddard III, William A.

    1870 Organometallics 1994,13,1870-1877 Mechanism and Energetics for Dehydrogenation of Methane also activate CHI. 1. Introduction Becauseof the enormousworldwidereservesof methane (CH4)andthe

  4. Kinetic Consequences of Chemisorbed Oxygen Atoms during Methane Oxidation on Group VIII Metal Clusters

    E-Print Network [OSTI]

    Chin, Ya Huei

    2011-01-01

    Chin, Y-H. ; Resasco, D.E. Catalytic Oxidation of methane onreactions in catalytic partial oxidation, reforming, andoccurrence of direct catalytic partial oxidation of methane

  5. Future methane, hydroxyl, and their uncertainties: key climate and emission parameters for future predictions

    E-Print Network [OSTI]

    Holmes, C. D; Prather, M. J; Sovde, O. A; Myhre, G.

    2013-01-01

    of present-day and future OH and methane lifetime, Atmos.Chemistry and Physics Future methane, hydroxyl, and theirand emission parameters for future predictions C. D. Holmes

  6. Mechanism of Methane Chemical Looping Combustion with Hematite Promoted with CeO2

    SciTech Connect (OSTI)

    Miller, Duane D.; Siriwardane, Ranjani

    2013-08-01

    Chemical looping combustion (CLC) is a promising technology for fossil fuel combustion that produces sequestration-ready CO{sub 2} stream, reducing the energy penalty of CO{sub 2} separation from flue gases. An effective oxygen carrier for CLC will readily react with the fuel gas and will be reoxidized upon contact with oxygen. This study investigated the development of a CeO{sub 2}-promoted Fe{sub 2}O{sub 3}?hematite oxygen carrier suitable for the methane CLC process. Composition of CeO{sub 2} is between 5 and 25 wt % and is lower than what is generally used for supports in Fe{sub 2}O{sub 3} carrier preparations. The incorporation of CeO{sub 2} to the natural ore hematite strongly modifies the reduction behavior in comparison to that of CeO{sub 2} and hematite alone. Temperature-programmed reaction studies revealed that the addition of even 5 wt % CeO{sub 2} enhances the reaction capacity of the Fe{sub 2}O{sub 3} oxygen carrier by promoting the decomposition and partial oxidation of methane. Fixed-bed reactor data showed that the 5 wt % cerium oxides with 95 wt % iron oxide produce 2 times as much carbon dioxide in comparison to the sum of carbon dioxide produced when the oxides were tested separately. This effect is likely due to the reaction of CeO{sub 2} with methane forming intermediates, which are reactive for extracting oxygen from Fe{sub 2}O{sub 3} at a considerably faster rate than the rate of the direct reaction of Fe{sub 2}O{sub 3} with methane. These studies reveal that 5 wt % CeO{sub 2}/Fe{sub 2}O{sub 3} gives stable conversions over 15 reduction/oxidation cycles. Lab-scale reactor studies (pulsed mode) suggest the methane reacts initially with CeO{sub 2} lattice oxygen to form partial oxidation products (CO + H{sub 2}), which continue to react with oxygen from neighboring Fe{sub 2}O{sub 3}, leading to its complete oxidation to form CO{sub 2}. The reduced cerium oxide promotes the methane decomposition reaction to form C + H{sub 2}, which continue to react with Fe{sub 2}O{sub 3}/Fe{sub 3}O{sub 4} to form CO/CO{sub 2} and H{sub 2}O. This mechanism is supported by the characterization studies, which also suggest that the formation of carbonaceous intermediates may affect the reaction rate and selectivity of the oxygen carrier.

  7. Lean methane premixed laminar flames doped by components of diesel fuel II: n-propylcyclohexane

    SciTech Connect (OSTI)

    Pousse, E.; Porter, R.; Warth, V.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F. [Departement de Chimie-Physique des Reactions, Nancy Universite, CNRS, ENSIC, 1 rue Grandville, BP 20451, 54001 Nancy Cedex (France)

    2010-01-15

    For a better understanding of the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-propylcyclohexane has been investigated. The inlet gases contained 7.1% (molar) methane, 36.8% oxygen, and 0.81% n-propylcyclohexane (C{sub 9}H{sub 18}), corresponding to an equivalence ratio of 0.68 and a C{sub 9}H{sub 18}/CH{sub 4} ratio of 11.4%. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr) using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 17 C{sub 3}-C{sub 5} hydrocarbons, seven C{sub 1}-C{sub 3} oxygenated compounds, and only four cyclic C{sub 6+} compounds, namely benzene, 1,3-cyclohexadiene, cyclohexene, and methylenecyclohexane. A new mechanism for the oxidation of n-propylcyclohexane has been proposed. It allows the proper simulation of profiles of most of the products measured in flames, as well as the satisfactory reproduction of experimental results obtained in a jet-stirred reactor. The main reaction pathways of consumption of n-propylcyclohexane have been derived from rate-of-production analysis. (author)

  8. A lean methane premixed laminar flame doped with components of diesel fuel. I. n-Butylbenzene

    SciTech Connect (OSTI)

    Pousse, E.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F. [Departement de Chimie-Physique des Reactions, Nancy Universite, CNRS, ENSIC, 1 rue Grandville, BP 20451, 54001 Nancy Cedex (France)

    2009-05-15

    To better understand the chemistry involved in the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar) methane, 36.8% oxygen, and 0.96% n-butylbenzene corresponding to an equivalence ratio of 0.74 and a ratio C{sub 10}H{sub 14}/CH{sub 4} of 13.5%. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 16 C{sub 3}-C{sub 5} hydrocarbons, and 7 C{sub 1}-C{sub 3} oxygenated compounds, as well as 20 aromatic products. A new mechanism for the oxidation of n-butylbenzene is proposed whose predictions are in satisfactory agreement with measured species profiles in flames and flow reactor experiments. The main reaction pathways of consumption of n-butylbenzene have been derived from flow rate analyses. (author)

  9. Rich methane laminar flames doped with light unsaturated hydrocarbons. Part II: 1,3butadiene

    E-Print Network [OSTI]

    Gueniche, Hadj-Ali; Fournet, René; Battin-Leclerc, Frédérique

    2007-01-01

    In line with the study presented in the part I of this paper, the structure of a laminar rich premixed methane flame doped with 1,3-butadiene has been investigated. The flame contains 20.7% (molar) of methane, 31.4% of oxygen and 3.3% of 1,3-butadiene, corresponding to an equivalence ratio of 1.8, and a ratio C4H6 / CH4 of 16 %. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as dilutant, with a gas velocity at the burner of 36 cm/s at 333 K. The temperature ranged from 600 K close to the burner up to 2150 K. Quantified species included usual methane C0-C2 combustion products and 1,3-butadiene, but also propyne, allene, propene, propane, 1,2-butadiene, butynes, vinylacetylene, diacetylene, 1,3-pentadiene, 2-methyl-1,3-butadiene (isoprene), 1-pentene, 3-methyl-1-butene, benzene and toluene. In order to model these new results, some improvements have been made to a mechanism previously developed in our laboratory for the reactions of C3-C4 unsaturated hydrocarbons. The main reacti...

  10. Rich methane laminar flames doped with light unsaturated hydrocarbons. Part III : cyclopentene

    E-Print Network [OSTI]

    Gueniche, Hadj-Ali; Fournet, René; Battin-Leclerc, Frédérique

    2008-01-01

    In line with the studies presented in the parts I and II of this paper, the structure of a laminar rich premixed methane flame doped with cyclopentene has been investigated. The gases of this flame contains 15.3% (molar) of methane, 26.7% of oxygen and 2.4% cyclopentene corresponding to an equivalence ratio of 1.79 and a ratio C5H8 / CH4 of 16 %. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as dilutant, with a gas velocity at the burner of 36 cm/s at 333 K. The temperature ranged from 627 K close to the burner up to 2027 K. Quantified species included usual methane C0-C2 combustion products, but also propyne, allene, propene, propane, 1-butene, 1,3-butadiene, 1,2-butadiene, vinylacetylene, diacetylene, cyclopentadiene, 1,3-pentadiene, benzene and toluene. A new mechanism for the oxidation of cyclopentene has been proposed. The main reaction pathways of consumption of cyclopentene and of formation of benzene and toluene have been derived from flow rate analyses.

  11. File:Methane.pdf | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpA JumpGmbHFerris State UniversityMethane.pdf Jump

  12. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  13. Analysis of condensate banking dynamics in a gas condensate reservoir under different injection schemes 

    E-Print Network [OSTI]

    Sandoval Rodriguez, Angelica Patricia

    2002-01-01

    condensate reservoir under natural depletion, and injection of methane, injection of carbon dioxide, produced gas recycling and water injection. To monitor the condensate banking dynamics near the wellbore area, such as oil saturation and compositional...

  14. Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

    E-Print Network [OSTI]

    Moridis, George J.; Sloan, E. Dendy

    2006-01-01

    bound gas in marine sediments: how much is really out there?methane hydrate in ocean sediment. Energy & Fuels 2005: 19:Accumulations in Oceanic Sediments George J. Moridis 1 and

  15. PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW

    E-Print Network [OSTI]

    Texas at Arlington, University of

    1 PYROLYSIS OF METHANE IN A SUPERSONIC, ARC-HEATED FLOW F.K. Lu,* C.M. Roseberry, J.M. Meyers and D arc pyrolysis of methane at supersonic conditions, representative of conditions in the reformer location of an aibreathing hypersonic vehicle. The rationale for arc pyrolysis is provided. Major

  16. Homogeneous Catalysis Selective Oxidation of Methane to Methanol

    E-Print Network [OSTI]

    Goddard III, William A.

    Homogeneous Catalysis Selective Oxidation of Methane to Methanol Catalyzed, with CŔH Activation (generated by dissolution[6] of Au2O3) react with methane at 1808C to selectively generate methanol (as a mixture of the ester and methanol) in high yield (Table 1, entries 1 and 2). As expected, the irreversible

  17. Life-cycle analysis of shale gas and natural gas.

    SciTech Connect (OSTI)

    Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M.

    2012-01-27

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

  18. Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope 

    E-Print Network [OSTI]

    Ozgul, Ercin

    2004-09-30

    Mixtures of bacterial and thermogenic methane are found both at vents at the seafloor and in reservoirs in the deep subsurface of the Gulf of Mexico continental slope. The C1-C5 gas that most recently charged reservoirs of Jolliet (GC 184), Genesis...

  19. Economics and Politics of Shale Gas in Europe

    E-Print Network [OSTI]

    Chyong, Chi Kong; Reiner, David M.

    2015-01-01

    In the wake of the dramatic growth in shale gas production in the United States, interest in shale gas exploration in Europe has been driven primarily by concerns over industrial competitiveness and energy security. A number of studies have been...

  20. LATERAL LANDFILL GAS MIGRATION: CHARACTERIZATION AND

    E-Print Network [OSTI]

    Boyer, Edmond

    LATERAL LANDFILL GAS MIGRATION: CHARACTERIZATION AND PRELIMINARY MODELING RESULTS O.BOUR*, E in the geological layer. Prior to drilling new boreholes on the site, a preliminary simplified model will be built with the numerical code TOUGH2-LGM. A description of the geological units, methane flux and the results

  1. Fiscal Year 2007 Greenhouse Gas Inventory

    E-Print Network [OSTI]

    Escher, Christine

    ;Definitions of Key Terms: (1) "Carbon dioxide" (CO2) means the chemical compound containing one atom of carbon" (GWP) means the radiative forcing impact of one mass-based unit of a given greenhouse gas relative to an equivalent unit of carbon dioxide over a given period of time. For instance, methane (CH4) has a GWP of 23

  2. QER- Comment of American Gas Association 2

    Broader source: Energy.gov [DOE]

    Attached please find AGA's comments relating to critical issues facing the natural gas distribution industry, which we believe could be usefully addressed in the first phase of the DOE Quadrennial Energy Review (QER). Our comments as submitted here consist of a cover letter and four additional attachments. My colleague Pam Lacey has previously submitted AGA's comments relating to methane emissions under separate cover.

  3. DIRECT DECOMPOSITION OF METHANE TO HYDROGEN ON METAL LOADED ZEOLITE CATALYST

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar; Kyle C. Burch; Harry W. Rollins

    2005-08-01

    The manufacture of hydrogen from natural gas is essential for the production of ultra clean transportation fuels. Not only is hydrogen necessary to upgrade low quality crude oils to high-quality, low sulfur ultra clean transportation fuels, hydrogen could eventually replace gasoline and diesel as the ultra clean transportation fuel of the future. Currently, refinery hydrogen is produced through the steam reforming of natural gas. Although efficient, the process is responsible for a significant portion of refinery CO2 emissions. This project is examining the direct catalytic decomposition of methane as an alternative to steam reforming. The energy required to produce one mole of hydrogen is slightly lower and the process does not require water-gas-shift or pressure-swing adsorption units. The decomposition process does not produce CO2 emissions and the product is not contaminated with CO -- a poison for PEM fuel cells. In this work we examined the direct catalytic decomposition of methane over a metal modified zeolite catalyst and the recovery of catalyst activity by calcination. A favorable production of hydrogen was obtained, when compared with previously reported nickel-zeolite supported catalysts. Reaction temperature had a strong influence on catalyst activity and on the type of carbon deposits. The catalyst utilized at 873 and 973 K could be regenerated without any significant loss of activity, however the catalyst utilized at 1073 K showed some loss of activity after regeneration.

  4. ,"Texas--RRC District 2 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008Wellhead PriceConsumption by9"CoalbedGas, Wet AfterCoalbed Methane Proved

  5. ,"Texas--RRC District 3 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008Wellhead PriceConsumption by9"CoalbedGas, Wet AfterCoalbed MethaneCoalbed

  6. ,"Texas--RRC District 4 Onshore Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008Wellhead PriceConsumption by9"CoalbedGas, Wet AfterCoalbedCoalbed Methane Proved

  7. ,"Texas--State Offshore Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008Wellhead PriceConsumption by9"CoalbedGas, WetPlantPlant Liquids,Coalbed Methane

  8. ,"Virginia Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA -Annual",2014Proved Reserves, WetGas, Wet After LeaseSummary"Coalbed Methane

  9. ,"Alabama Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008 © OECD/IEA - 2008 © OECD/IEA -Underground Natural Gas Storage -Coalbed Methane

  10. ,"Kansas Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008 © OECD/IEA - 2008LNGUnderground Natural Gas Storage - AllCoalbed Methane Proved

  11. ,"Kentucky Coalbed Methane Proved Reserves (Billion Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA - 2008 © OECD/IEA - 2008LNGUnderground Natural Gas StorageCoalbed Methane Proved Reserves

  12. METHANE AND NITROGEN ABUNDANCES ON PLUTO AND ERIS

    SciTech Connect (OSTI)

    Tegler, S. C.; Cornelison, D. M.; Abernathy, M. R.; Bovyn, M. J.; Burt, J. A.; Evans, D. E.; Maleszewski, C. K.; Thompson, Z.; Grundy, W. M.; Romanishin, W.; Vilas, F. E-mail: David.Cornelison@nau.ed E-mail: wjr@nhn.ou.ed

    2010-12-10

    We present spectra of Eris from the MMT 6.5 m Telescope and Red Channel Spectrograph (5700-9800 A, 5 A pixel{sup -1}) on Mt. Hopkins, AZ, and of Pluto from the Steward Observatory 2.3 m Telescope and Boller and Chivens Spectrograph (7100-9400 A, 2 A pixel{sup -1}) on Kitt Peak, AZ. In addition, we present laboratory transmission spectra of methane-nitrogen and methane-argon ice mixtures. By anchoring our analysis in methane and nitrogen solubilities in one another as expressed in the phase diagram of Prokhvatilov and Yantsevich, and comparing methane bands in our Eris and Pluto spectra and methane bands in our laboratory spectra of methane and nitrogen ice mixtures, we find Eris' bulk methane and nitrogen abundances are {approx}10% and {approx}90% and Pluto's bulk methane and nitrogen abundances are {approx}3% and {approx}97%. Such abundances for Pluto are consistent with values reported in the literature. It appears that the bulk volatile composition of Eris is similar to the bulk volatile composition of Pluto. Both objects appear to be dominated by nitrogen ice. Our analysis also suggests, unlike previous work reported in the literature, that the methane and nitrogen stoichiometry is constant with depth into the surface of Eris. Finally, we point out that our Eris spectrum is also consistent with a laboratory ice mixture consisting of 40% methane and 60% argon. Although we cannot rule out an argon-rich surface, it seems more likely that nitrogen is the dominant species on Eris because the nitrogen ice 2.15 {mu}m band is seen in spectra of Pluto and Triton.

  13. Effects of natural gas composition on ignition delay under diesel conditions

    SciTech Connect (OSTI)

    Naber, J.D.; Siebers, D.L. [Sandia National Labs., Livermore, CA (United States); Di Julio, S.S. [California State Univ., Northridge, CA (United States). Dept. of Mechanical Engineering; Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

    1993-12-03

    Effects of variations in natural gas composition on autoignition of natural gas under direct-injection (DI) diesel engine conditions were studied experimentally in a constant-volume combustion vessel and computationally using a chemical kinetic model. Four fuel blends were investigated: pure methane, a capacity weighted mean natural gas, a high ethane content natural gas, and a natural gas with added propane typical of peak shaving conditions. Experimentally measured ignition delays were longest for pure methane and became progressively shorter as ethane and propane concentrations increased. At conditions characteristic of a DI compression ignition natural gas engine at Top Dead Center (CR=23:1, p = 6.8 MPa, T = 1150K), measured ignition delays for the four fuels varied from 1.8 ms for the peak shaving and high ethane gases to 2.7 ms for pure methane. Numerically predicted variations in ignition delay as a function of natural gas composition agreed with these measurements.

  14. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  15. Computational Design of Metal-Organic Frameworks Based on Stable Zirconium Building Units for Storage and Delivery of Methane

    SciTech Connect (OSTI)

    Gomez-Gualdron, DA; Gutov, OV; Krungleviciute, V; Borah, B; Mondloch, JE; Hupp, JT; Yildirim, T; Farha, OK; Snurr, RQ

    2014-10-14

    A metal organic framework (MOF) with high volumetric deliverable capacity for methane was synthesized after being identified by computational screening of 204 hypothetical MOF structures featuring (Zr6O4)(OH)(4)(CO2)(n) inorganic building blocks. The predicted MOF (NU-800) has an fcu topology in which zirconium nodes are connected via ditopic 1,4-benzenedipropynoic acid linkers. Based on our computer simulations, alkyne groups adjacent to the inorganic zirconium nodes provide more efficient methane packing around the nodes at high pressures. The high predicted gas uptake properties of this new MOF were confirmed by high-pressure isotherm measurements over a large temperature and pressure range. The measured methane deliverable capacity of NU-800 between 65 and 5.8 bar is 167 cc(STP)/cc (0.215 g/g), the highest among zirconium-based MOFs. High-pressure uptake values of H-2 and CO2 are also among the highest reported. These high gas uptake characteristics, along with the expected highly stable structure of NU-800, make it a promising material for gas storage applications.

  16. Flammable Gas Detection for the D-Zero Gas System

    SciTech Connect (OSTI)

    Spires, L.D.; Foglesong, J.; /Fermilab

    1991-02-11

    The use of flammable gas and high voltage in detector systems is common in many experiments at Fermilab. To mitigate the hazards associated with these systems, Fermilab Engineering Standard SD-45B (Ref. 1) was adopted. Since this note is meant to be a guide and not a mandatory standard, each experiment is reviewed for compliance with SD-45B by the flammable gas safety subcommittee. Currently, there are only two types of flammable gas in use, ethane (Appendix A) and methane (Appendix B). The worst flammable-gas case is C2H6 (ethane), which has an estimated flow rate that is 73% of the CH4 (methane) flow but a heat of combustion (in kcal/g-mole) that is 173% of that of methane. In the worst case, if ethane were to spew through its restricting orifice into its gas line at 0 psig and then through a catastrophic leak into Room 215 (TRD) or Room 511 (CDC/FDCNTX), the time that would be required to build up a greater than Class 1 inventory (0.4kg H2 equivalent) would be 5.2 hours (Ref. 2). Therefore a worst-case flammable gas leak would have to go undetected for over 5 hours in order to transform a either mixing room to an environment with a Risk Class greater than Class 1. The mixing systems, gas lines, and detectors themselves will be thoroughly leak checked prior to active service. All vessels that are part of the mixing systems will be protected from overpressure by safety valves vented outside the building. Both the input and output of all detector volumes are protected from overpressure in the same way. The volume immediately outside the central tracking detectors is continuously purged by nitrogen from boiloff from the main nitrogen dewar at the site. However, if flammable gas were to build up in the mixing rooms or particular detector areas, no matter how unlikely, flammable gas detectors that are part of the interlock chain of each gas mixing system will shut down the appropriate system. This includes shutting off the output of flammable gas manifolds within the gas shed. Similarly, if a fire were to break out anywhere in the D-ZERO Hall, fire sensors would stop the output of all flammable gas manifolds within the gas shed, by unpowering electrically controlled solenoid valves that are normally closed in the event of a power failure. Fire sensor contacts have not yet been installed.

  17. Source Characterization and Temporal Variation of Methane Seepage from Thermokarst Lakes on the Alaska North Slope in Response to Arctic Climate Change

    SciTech Connect (OSTI)

    2012-09-30

    The goals of this research were to characterize the source, magnitude and temporal variability of methane seepage from thermokarst lakes (TKL) within the Alaska North Slope gas hydrate province, assess the vulnerability of these areas to ongoing and future arctic climate change and determine if gas hydrate dissociation resulting from permafrost melting is contributing to the current lake emissions. Analyses were focused on four main lake locations referred to in this report: Lake Qalluuraq (referred to as Lake Q) and Lake Teshekpuk (both on Alaska?s North Slope) and Lake Killarney and Goldstream Bill Lake (both in Alaska?s interior). From analyses of gases coming from lakes in Alaska, we showed that ecological seeps are common in Alaska and they account for a larger source of atmospheric methane today than geologic subcap seeps. Emissions from the geologic source could increase with potential implications for climate warming feedbacks. Our analyses of TKL sites showing gas ebullition were complemented with geophysical surveys, providing important insight about the distribution of shallow gas in the sediments and the lake bottom manifestation of seepage (e.g., pockmarks). In Lake Q, Chirp data were limited in their capacity to image deeper sediments and did not capture the thaw bulb. The failure to capture the thaw bulb at Lake Q may in part be related to the fact that the present day lake is a remnant of an older, larger, and now-partially drained lake. These suggestions are consistent with our analyses of a dated core of sediment from the lake that shows that a wetland has been present at the site of Lake Q since approximately 12,000 thousand years ago. Chemical analyses of the core indicate that the availability of methane at the site has changed during the past and is correlated with past environmental changes (i.e. temperature and hydrology) in the Arctic. Discovery of methane seeps in Lake Teshekpuk in the northernmost part of the lake during 2009 reconnaissance surveys provided a strong impetus to visit this area in 2010. The seismic methods applied in Lake Teshekpuk were able to image pockmarks, widespread shallow gas in the sediments, and the relationship among different sediment packages on the lake?s bottom, but even boomer seismics did not detect permafrost beneath the northern part of the lake. By characterizing the biogeochemistry of shallow TKL with methane seeps we showed that the radical seasonal shifts in ice cover and temperature. These seasonal environmental differences result in distinct consumption and production processes of biologically-relevant compounds. The combined effects of temperature, ice-volume and other lithological factors linked to seepage from the lake are manifest in the distribution of sedimentary methane in Lake Q during icecovered and ice-free conditions. The biogeochemistry results illustrated very active methanotrophy in TKLs. Substantial effort was subsequently made to characterize the nature of methanotrophic communities in TKLs. We applied stable isotope probing approaches to genetically characterize the methanotrophs most active in utilizing methane in TKLs. Our study is the first to identify methane oxidizing organisms active in arctic TKLs, and revealing that type I methanotrophs and type II methanotrophs are abundant and active in assimilating methane in TKLs. These organisms play an important role in limiting the flux of methane from these sites. Our investigations indicate that as temperatures increase in the Arctic, oxidation rates and active methanotrophic populations will also shift. Whether these changes can offset predicted increases in methanogenesis is an important question underlying models of future methane flux and resultant climate change. Overall our findings indicate that TKLs and their ability to act as both source and sink of methane are exceedingly sensitive to environmental change.

  18. Large-eddy simulation of lean hydrogenemethane turbulent premixed flames in the methane-

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Large-eddy simulation of lean hydrogenemethane turbulent premixed flames in the methane- dominated to available experimental data. The enriched flame has 20% H2 in terms of mole fraction and lies in the methane methane flame in the methane- dominated regime. Copyright Ş 2014, Hydrogen Energy Publications, LLC

  19. A synthesis of methane emissions from 71 northern, temperate, and subtropical wetlands

    E-Print Network [OSTI]

    A synthesis of methane emissions from 71 northern, temperate, and subtropical wetlands M E R R I of atmospheric methane. Here, we assess controls on methane flux using a database of approximately 19 000 latitude regions. Our analyses confirm general controls on wetland methane emissions from soil temperature

  20. DOI: 10.1002/cctc.201300401 New Insights into the Oxidative Coupling of Methane from

    E-Print Network [OSTI]

    Senkan, Selim M.

    DOI: 10.1002/cctc.201300401 New Insights into the Oxidative Coupling of Methane from Spatially coupling of methane (OCM) is a high-temperature process involving the transformation of methane into ethane oxidation of methane to produce CO and H2 in a Pt- and Rh-coated a-Al2O3 foam.[11­13] Experiments were

  1. Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers

    E-Print Network [OSTI]

    Controls on soil methane fluxes: Tests of biophysical mechanisms using stable isotope tracers November 2006; published 4 May 2007. [1] Understanding factors that control methane exchange between soils-scale variations in soil methane emissions: (1) consumption of methane by methanotrophic bacteria, (2) quantity

  2. Global inventory of methane clathrate: sensitivity to changes in the deep ocean

    E-Print Network [OSTI]

    Global inventory of methane clathrate: sensitivity to changes in the deep ocean Bruce Buffett of methane clathrate in marine sediments, and use it to predict the sensitivity of the steady-state methane inventory to changes in the deep ocean. The methane inventory is determined by binning the seafloor area

  3. Methane Planets and their Mass-Radius Relation

    E-Print Network [OSTI]

    Helled, Ravit; Vos, Eran

    2015-01-01

    Knowledge of both the mass and radius of an exoplanet allows us to estimate its mean density, and therefore, its composition. Exoplanets seem to fill a very large parameter space in terms of mass and composition, and unlike the solar-system's planets, exoplanets also have intermediate masses (~5-50 M_Earth) with various densities. In this letter, we investigate the behavior of the Mass-Radius relation for methane (CH_4) planets and show that when methane planets are massive enough (M_planet > ~15 M_Earth) the methane can dissociate and lead to a differentiated planet with a carbon core, a methane envelope, and a hydrogen atmosphere. The contribution of a rocky core to the behavior of CH_4 planet is considered as well. We also develop interior models for several detected intermediate-mass planets that could, in principle, be methane/methane-rich planets. The example of methane planets emphasizes the complexity of the Mass-Radius relation and the challenge in inferring the planetary composition uniquely.

  4. FreezeFrac Improves the Productivity of Gas Shales S. Enayatpour, E. Van Oort, T. Patzek, University of Texas At Austin

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    SPE 166482 FreezeFrac Improves the Productivity of Gas Shales S. Enayatpour, E. Van Oort, T. Patzek to unconventional hydrocarbon reservers such as oil shales, gas shales, tight gas sands, coalbed methane, and gas; Keaney et al., 2004). Successful production of oil and gas from shales with nano-Darcy range permeability

  5. Enhanced Coal Bed Methane Recovery and CO2 Sequestration in the Powder River Basin

    SciTech Connect (OSTI)

    Eric P. Robertson

    2010-06-01

    Unminable coal beds are potentially large storage reservoirs for the sequestration of anthropogenic CO2 and offer the benefit of enhanced methane production, which can offset some of the costs associated with CO2 sequestration. The objective of this report is to provide a final topical report on enhanced coal bed methane recovery and CO2 sequestration to the U.S. Department of Energy in fulfillment of a Big Sky Carbon Sequestration Partnership milestone. This report summarizes work done at Idaho National Laboratory in support of Phase II of the Big Sky Carbon Sequestration Partnership. Research that elucidates the interaction of CO2 and coal is discussed with work centering on the Powder River Basin of Wyoming and Montana. Sorption-induced strain, also referred to as coal swelling/shrinkage, was investigated. A new method of obtaining sorption-induced strain was developed that greatly decreases the time necessary for data collection and increases the reliability of the strain data. As coal permeability is a strong function of sorption-induced strain, common permeability models were used to fit measured permeability data, but were found inadequate. A new permeability model was developed that can be directly applied to coal permeability data obtained under laboratory stress conditions, which are different than field stress conditions. The coal permeability model can be used to obtain critical coal parameters that can be applied in field models. An economic feasibility study of CO2 sequestration in unminable coal seams in the Powder River Basin of Wyoming was done. Economic analyses of CO2 injection options are compared. Results show that injecting flue gas to recover methane from CBM fields is marginally economical; however, this method will not significantly contribute to the need to sequester large quantities of CO2. Separating CO2 from flue gas and injecting it into the unminable coal zones of the Powder River Basin seam is currently uneconomical, but can effectively sequester over 86,000 tons (78,200 Mg) of CO2 per acre while recovering methane to offset costs. The cost to separate CO2 from flue gas was identified as the major cost driver associated with CO2 sequestration in unminable coal seams. Improvements in separations technology alone are unlikely to drive costs low enough for CO2 sequestration in unminable coal seams in the Powder River Basin to become economically viable. Breakthroughs in separations technology could aid the economics, but in the Powder River Basin, they cannot achieve the necessary cost reductions for breakeven economics without incentives.

  6. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfate–methane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  7. The electronic spectra and structure of bis(2,2'biphenylene) methane 

    E-Print Network [OSTI]

    Hofer, Owen Charles

    1965-01-01

    Transit ion Sysssetries ~ 1 ~ ~ ~ ~ ~ ~ ~ ~ ~ 12 Theuretioal Calculation uf Fluorene and Bis(2iiR bipheuyleme) Methane . ~ ~ ~ ~ ~ ~ 13 Theoretioal Caloulatiun and Experimental Beta Sf Flugrene and Bis(2 2 bkpMenylsne) Methane ~ ~ ~ ~ . ~ e... Calouiation of Fluorene ~ ~ . ~ ~ ~ . ~ ~ 22 P Matrix of Bis(2~2 biphemyleue) Methane ~ ~ ~ 23 P Matrix of Bis(2, 2 biphewylene) Methane (Continued) ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 24 P Matrix of Fluorene ~ ~ 25 Gesssa Matrix of Bis(2, 2 biphenyleue) Methane ~ ~ 26...

  8. TechNotes November 2014www.ll.mit.edu The detection and localization of gas

    E-Print Network [OSTI]

    Herr, Hugh

    such as methane from leaking natural gas pipelines or nitrogen oxides from failing electrical equipment requireTechNotes November 2014www.ll.mit.edu The detection and localization of gas releases high sensitivity to the target gas and insensitivity to non-target gases. Infrared (IR) absorption

  9. Assessment of microbial processes on gas production at radioactive low-level waste disposal sites

    SciTech Connect (OSTI)

    Weiss, A.J.; Tate, R.L. III; Colombo, P.

    1982-05-01

    Factors controlling gaseous emanations from low level radioactive waste disposal sites are assessed. Importance of gaseous fluxes of methane, carbon dioxide, and possible hydrogen from the site, stems from the inclusion of tritium and/or carbon-14 into the elemental composition of these compounds. In that the primary source of these gases is the biodegradation of organic components of the waste material, primary emphasis of the study involved an examination of the biochemical pathways producing methane, carbon dioxide, and hydrogen, and the environmental parameters controlling the activity of the microbial community involved. Initial examination of the data indicates that the ecosystem is anaerobic. As the result of the complexity of the pathway leading to methane production, factors such as substrate availability, which limit the initial reaction in the sequence, greatly affect the overall rate of methane evolution. Biochemical transformations of methane, hydrogen and carbon dioxide as they pass through the soil profile above the trench are discussed. Results of gas studies performed at three commercial low level radioactive waste disposal sites are reviewed. Methods used to obtain trench and soil gas samples are discussed. Estimates of rates of gas production and amounts released into the atmosphere (by the GASFLOW model) are evaluated. Tritium and carbon-14 gaseous compounds have been measured in these studies; tritiated methane is the major radionuclide species in all disposal trenches studied. The concentration of methane in a typical trench increases with the age of the trench, whereas the concentration of carbon dioxide is similar in all trenches.

  10. A survey of methane isotope abundance (14C, 13C, 2H) from five nearshore marine basins that reveals unusual radiocarbon levels in subsurface waters

    E-Print Network [OSTI]

    2008-01-01

    Carbon pool analysis of methane hydrate regions in theAerobic production of methane in the sea, Nat. Geosci. , 1(R. Varela (2005), Fossil methane source dominates Cariaco

  11. Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP)

    E-Print Network [OSTI]

    2013-01-01

    al. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methaneal. : Changes in tropospheric hydroxyl radical and methane

  12. Methane depletion in both polar regions of Uranus inferred from HST/STIS and Keck/NIRC2 observations

    E-Print Network [OSTI]

    Sromovsky, Lawrence; Fry, Patrick; Hammel, Heidi; de Pater, Imke; Rages, Kathy

    2015-01-01

    From STIS observations of Uranus in 2012, we found that the methane volume mixing ratio declined from about 4% at low latitudes to about 2% at 60 deg N and beyond. This is similar to that found in the south polar regions in 2002, in spite of what appears to be strikingly different convective activity in the two regions. Keck and HST imaging observations close to equinox imply that the depletions were simultaneously present in 2007, suggesting they are persistent features. The depletions appear to be mainly restricted to the upper troposphere, with depth increasing poleward from about 30 deg N, reaching ~4 bars at 45 deg N and perhaps much deeper at 70 deg N. The latitudinal variations in degree and depth of the depletions are important constraints on models of meridional circulation. Our observations are qualitatively consistent with previously suggested circulation cells in which rising methane-rich gas at low latitudes is dried out by condensation and sedimentation of methane ice particles as the gas ascend...

  13. The effects of dissolved methane upon liquid argon scintillation light

    E-Print Network [OSTI]

    Alexander, T

    In this paper we report on measurements of the effects of dissolved methane upon argon scintillation light. We monitor the light yield from an alpha source held 20 cm from a cryogenic photomultiplier tube (PMT) assembly ...

  14. Diurnal variations in methane emission from rice plants 

    E-Print Network [OSTI]

    Laskowski, Nicholas Aaron

    2004-11-15

    with uncontrolled soil temperature than for plants with controlled soil temperature. Soil temperature at a 5 cm depth explained 46% of the emission variation. Soil temperature affects the source of methane in the soil while transpiration promotes the uptake...

  15. & CH Activation Rhodium Bis(quinolinyl)benzene Complexes for Methane

    E-Print Network [OSTI]

    Goddard III, William A.

    on using the steam-methane reformation process to convert it to syngas (a CO and H2 mixture catalytic process, many ligand frameworks have been explored for the Pt system,[6] and efforts have been

  16. Biomass Gasification and Methane Digester Property Tax Exemption

    Broader source: Energy.gov [DOE]

    In order to be eligible for the exemption, methane digester equipment must be certified by the Michigan Department of Agriculture (MDA) and the farm must be verified as compliant under the Michig...

  17. Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production

    SciTech Connect (OSTI)

    Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

    2014-10-31

    Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330oC when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted MgO-based sorbent. Under model feed conditions both the sorbent and catalyst exhibited favorable stability after multiple test cycles. The cleanup for warm gas cleanup of inorganics was broken down into three major steps: chloride removal, sulfur removal, and the removal for a multitude of trace metal contaminants. Na2CO3 was found to optimally remove chlorides at an operating temperature of 450şC. For sulfur removal two regenerable ZnO beds are used for bulk H2S removal at 450şC (<5 ppm S) and a non-regenerable ZnO bed for H2S polishing at 300şC (<40 ppb S). It was also found that sulfur from COS could be adsorbed (to levels below our detection limit of 40 ppb) in the presence of water that leads to no detectable slip of H2S. Finally, a sorbent material comprising of Cu and Ni was found to be effective in removing trace metal impurities such as AsH3 and PH3 when operating at 300şC. Proof-of-concept of the integrated cleanup process was demonstrated with gasifier-generated syngas produced at the Western Research Institute using Wyoming Decker Coal. When operating with a ~1 SLPM feed, multiple inorganic contaminant removal sorbents and a tar-reforming bed was able to remove the vast majority of contaminants from the raw syngas. A tar-reforming catalyst was employed due to the production of tars generated from the gasifier used in this particular study. It is envisioned that in a real application a commercial scale gasifier operating at a higher temperature would produce lesser amount of tar. Continuous operation of a poison-sensitive copper-based WGS catalyst located downstream from the cleanup steps resulted in successful demonstration. ?

  18. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    Broader source: Energy.gov [DOE]

    Landfill gas (LFG), composed largely of methane and carbon dioxide, is used in over 450 operational projects in 43 states. These projects convert a large source of greenhouse gases into a fuel that...

  19. Tetrahedral Symmetry for Methane The infrared spectrum of methane shows two absorptions: a bend at 1306 cm-1 and a stretch at 3019 cm-1. Demonstrate that a

    E-Print Network [OSTI]

    Rioux, Frank

    Tetrahedral Symmetry for Methane The infrared spectrum of methane shows two absorptions: a bend symmetry for methane is consistent with this spectroscopic data. Also predict how many Raman active modes methane should have. E C3 C2 S4 A1 : x2 + y2 + z2 A2 C Td 1 1 2 3 3 1 1 1 0 0 1 1 2 1 1 1 1 0 1 1 1 1 0 1

  20. 5616 J. Phys. Chem. 1987, 91, 5616-5623 (parent methane), 105633-27-0;6,109745-47-3;6 (parent methane),

    E-Print Network [OSTI]

    Goddard III, William A.

    5616 J. Phys. Chem. 1987, 91, 5616-5623 (parent methane), 105633-27-0;6,109745-47-3;6 (parent methane), 105633-31-6;7, 109745-48-4;8, 109745-49-5;8 (parent methane), 109745-52-0;9,109745-50-8;9 (parent methane), 105633-32-7;10, 109745-53-1;11, 109745-51-9;1,2,3,4-tetrachlorobenzene,634

  1. Novel strategies for the synthesis of methane adsorbents with controlled porosity and high surface area. Annual report, January 1, 1994-December 31, 1995

    SciTech Connect (OSTI)

    Ventura, S.C.; Kumar, S.K.; Yokoi, S.I.

    1995-04-01

    Natural gas is an attractive alternative to gasoline as fuel for cars because of its desirable emission characteristics, good cold starting characteristics, and high octane number. A major factor that limits widespread use of NGV`s is the low energy density of natural gas. The authors have developed low-cost gel precursors that are excellent binders of high surface area carbon and produce monoliths with piece density of 0.64 g/mL, carbon packing density of 0.62 g/mL and methane volumetric storage capacity of 140 V/V (based on volume of gas delivered) at 500 psia. The authors` preliminary experiments show that piece density may be further increased under suitable processing conditions and that even higher methane volumetric capacities will be attainable.

  2. Synthesis Gas Production from Partial Oxidation of Methane with Air in AC Electric Gas Discharge

    E-Print Network [OSTI]

    Mallinson, Richard

    system and the CH4/air/C2H6 system, respectively. When studying the effect of residence time by varying power or frequency, the CH4/air system had a higher specific energy consumption than the CH4/air/C2H6. Fuel Sci. Technol. Int. 1986, 4, 365. (3) Han, S.; Martenak, D. J.; Palermo, R. E.; Pearson, J. A

  3. Methods for applying microchannels to separate methane using liquid absorbents, especially ionic liquid absorbents from a mixture comprising methane and nitrogen

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y. (Dublin, OH); Litt, Robert D. (Westerville, OH); Dongming, Qiu (Dublin, OH); Silva, Laura J. (Plain City, OH); Lamont, Micheal Jay (Plain City, OH); Fanelli, Maddalena (Plain City, OH); Simmons, Wayne W. (Plain city, OH); Perry, Steven (Galloway, OH)

    2011-10-04

    Methods of using microchannel separation systems including absorbents to improve thermal efficiency and reduce parasitic power loss. Energy is typically added to desorb methane and then energy or heat is removed to absorb methane using a working solution. The working solution or absorbent may comprise an ionic liquid, or other fluids that demonstrate a difference in affinity between methane and nitrogen in a solution.

  4. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2013-01-08

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  5. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  6. Electrochemistry of soluble methane monooxygenase on a modified gold electrode : implications for chemical sensing in natural waters

    E-Print Network [OSTI]

    Chuang, Janet Duanping

    2005-01-01

    This work explored the possibility of using the soluble methane monooxygenase (MMO) enzyme, a three-component enzyme which catalyzes the oxygenation of methane and other substrates, to design a methane sensor for use in ...

  7. Your company may be looking to transition existing datacenter infrastructure (primarily physical and virtualized environments) to deliver a private cloud to your business. While

    E-Print Network [OSTI]

    Chaudhuri, Surajit

    Your company may be looking to transition existing datacenter infrastructure (primarily physical datacenter investments and skill sets to deliver a private cloud today. Pooling and dynamic allocation of datacenter resources. With Virtual Machine Manager, you can pool and virtualize your compute, network

  8. UCF-4.0294 Use of University Facilities; General Requirements. (1) University facilities are reserved and used primarily for the official and regular

    E-Print Network [OSTI]

    Wu, Shin-Tson

    and approved by a University building code official or safety officer. A sketch drawing of the display are reserved and used primarily for the official and regular conduct of the University's business interference and disruption, University officials will look to the standards of University Regulation UCF- 4

  9. Asterix is a reflectometer/diffractometer/grazing-incidence-SANS/SESAME-enabled-SANS spectrometer that is primarily used for experiments or neutron scattering

    E-Print Network [OSTI]

    that is primarily used for experiments or neutron scattering techniques requiring polarized neutron beams detector arm is readily configurable for polarization or energy analysis of the scattered neutron beam be translated in the horizontal and vertical directions. Neutron detector (Spin Echo Scattering Angle

  10. Methane Hydrate Field Program: Development of a Scientific Plan for a Methane Hydrate-Focused Marine Drilling, Logging and Coring Program

    SciTech Connect (OSTI)

    Collett, Tim; Bahk, Jang-Jun; Frye, Matt; Goldberg, Dave; Husebo, Jarle; Koh, Carolyn; Malone, Mitch; Shipp, Craig; Torres, Marta; Myers, Greg; Divins, David; Morell, Margo

    2013-11-30

    This topical report represents a pathway toward better understanding of the impact of marine methane hydrates on safety and seafloor stability and future collection of data that can be used by scientists, engineers, managers and planners to study climate change and to assess the feasibility of marine methane hydrate as a potential future energy resource. Our understanding of the occurrence, distribution and characteristics of marine methane hydrates is incomplete; therefore, research must continue to expand if methane hydrates are to be used as a future energy source. Exploring basins with methane hydrates has been occurring for over 30 years, but these e?orts have been episodic in nature. To further our understanding, these e?orts must be more regular and employ new techniques to capture more data. This plan identifies incomplete areas of methane hydrate research and o?ers solutions by systematically reviewing known methane hydrate “Science Challenges” and linking them with “Technical Challenges” and potential field program locations.

  11. MethaneHydrateRD_FC.indd

    Office of Environmental Management (EM)

    gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a...

  12. Method of making improved gas storage carbon with enhanced thermal conductivity

    DOE Patents [OSTI]

    Burchell, Timothy D. (Oak Ridge, TN); Rogers, Michael R. (Knoxville, TN)

    2002-11-05

    A method of making an adsorbent carbon fiber based monolith having improved methane gas storage capabilities is disclosed. Additionally, the monolithic nature of the storage carbon allows it to exhibit greater thermal conductivity than conventional granular activated carbon or powdered activated carbon storage beds. The storage of methane gas is achieved through the process of physical adsorption in the micropores that are developed in the structure of the adsorbent monolith. The disclosed monolith is capable of storing greater than 150 V/V of methane [i.e., >150 STP (101.325 KPa, 298K) volumes of methane per unit volume of storage vessel internal volume] at a pressure of 3.5 MPa (500 psi).

  13. Production of biodiesel using expanded gas solvents

    SciTech Connect (OSTI)

    Ginosar, Daniel M; Fox, Robert V; Petkovic, Lucia M

    2009-04-07

    A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

  14. Four Critical Needs to Change the Hydrate Energy Paradigm from Assessment to Production: The 2007 Report to Congress by the U.S. Federal methane Hydrate Advisory Committee

    SciTech Connect (OSTI)

    Mahajan,D.; Sloan, D.; Brewer, P.; Dutta, N.; Johnson, A.; Jones, E.; Juenger, K.; Kastner, M.; Masutani, S.; Swenson, R.; Whelan, J.; Wilson, s.; Woolsey, R.

    2009-03-11

    This work summarizes a two-year study by the U.S. Federal Methane Hydrate Advisory Committee recommending the future needs for federally-supported hydrate research. The Report was submitted to the US Congress on August 14, 2007 and includes four recommendations regarding (a) permafrost hydrate production testing, (b) marine hydrate viability assessment (c) climate effect of hydrates, and (d) international cooperation. A secure supply of natural gas is a vital goal of the U.S. national energy policy because natural gas is the cleanest and most widely used of all fossil fuels. The inherent cleanliness of natural gas, with the lowest CO2 emission per unit of heat energy of any fossil fuel, means substituting gas for coal and fuel oil will reduce emissions that can exacerbate the greenhouse effect. Both a fuel and a feedstock, a secure and reasonably priced supply of natural gas is important to industry, electric power generators, large and small commercial enterprises, and homeowners. Because each volume of solid gas hydrate contains as much as 164 standard volumes of methane, hydrates can be viewed as a concentrated form of natural gas equivalent to compressed gas but less concentrated than liquefied natural gas (LNG). Natural hydrate accumulations worldwide are estimated to contain 700,000 TCF of natural gas, of which 200,000 TCF are located within the United States. Compared with the current national annual consumption of 22 TCF, this estimate of in-place gas in enormous. Clearly, if only a fraction of the hydrated methane is recoverable, hydrates could constitute a substantial component of the future energy portfolio of the Nation (Figure 1). However, recovery poses a major technical and commercial challenge. Such numbers have sparked interest in natural gas hydrates as a potential, long-term source of energy, as well as concerns about any potential impact the release of methane from hydrates might have on the environment. Energy-hungry countries such as India and Japan are outspending the United States on hydrate science and engineering R&D by a factor of 10, and may bring this resource to market as much as a decade before the United States.

  15. Physical Properties of Gas Hydrates: A Review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gabitto, Jorge F.; Tsouris, Costas

    2010-01-01

    Methane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 10 16 ? m 3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detectedmore »by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed. « less

  16. 49 new T dwarfs identified using methane imaging

    E-Print Network [OSTI]

    Cardoso, C V; Smart, R L; van Spaandonk, L; Baker, D; Smith, L C; Andrei, A H; Bucciarelli, B; Dhital, S; Jones, H R A; Lattanzi, M G; Magazzu, A; Pinfield, D J; Tinney, C G

    2015-01-01

    We present the discovery of 49 new photometrically classified T dwarfs from the combination of large infrared and optical surveys combined with follow-up TNG photometry. We used multi-band infrared and optical photometry from the UKIRT and Sloan Digital Sky Surveys to identify possible brown dwarf candidates, which were then confirmed using methane filter photometry. We have defined a new photometric conversion between CH4s - CH4l colour and spectral type for T4 to T8 brown dwarfs based on a part of the sample that has been followed up using methane photometry and spectroscopy. Using methane differential photometry as a proxy for spectral type for T dwarfs has proved to be a very efficient technique. Of a subset of 45 methane selected brown dwarfs that were observed spectroscopically, 100% were confirmed as T dwarfs. Future deep imaging surveys will produce large samples of faint brown dwarf candidates, for which spectroscopy will not be feasible. When broad wavelength coverage is unavailable, methane imaging...

  17. Study on small-strain behaviours of methane hydrate sandy sediments using discrete element method

    SciTech Connect (OSTI)

    Yu Yanxin; Cheng Yipik; Xu Xiaomin; Soga, Kenichi

    2013-06-18

    Methane hydrate bearing soil has attracted increasing interest as a potential energy resource where methane gas can be extracted from dissociating hydrate-bearing sediments. Seismic testing techniques have been applied extensively and in various ways, to detect the presence of hydrates, due to the fact that hydrates increase the stiffness of hydrate-bearing sediments. With the recognition of the limitations of laboratory and field tests, wave propagation modelling using Discrete Element Method (DEM) was conducted in this study in order to provide some particle-scale insights on the hydrate-bearing sandy sediment models with pore-filling and cementation hydrate distributions. The relationship between shear wave velocity and hydrate saturation was established by both DEM simulations and analytical solutions. Obvious differences were observed in the dependence of wave velocity on hydrate saturation for these two cases. From the shear wave velocity measurement and particle-scale analysis, it was found that the small-strain mechanical properties of hydrate-bearing sandy sediments are governed by both the hydrate distribution patterns and hydrate saturation.

  18. Top-down methane emissions estimates for the San Francisco Bay Area from 1990 to 2012

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fairley, David; Fischer, Marc L.

    2015-01-30

    Methane is a potent greenhouse gas (GHG) that is now included in both California State and San Francisco Bay Area (SFBA) bottom-up emission inventories as part of California's effort to reduce anthropogenic GHG emissions. Here we provide a top-down estimate of methane (CH4) emissions from the SFBA by combining atmospheric measurements with the comparatively better estimated emission inventory for carbon monoxide (CO). Local enhancements of CH4 and CO are estimated using measurements from 14 air quality sites in the SFBA combined together with global background measurements. Mean annual CH4 emissions are estimated from the product of Bay Area Air Qualitymore »Management District (BAAQMD) emission inventory CO and the slope of ambient local CH4 to CO. The resulting top-down estimates of CH4 emissions are found to decrease slightly from 1990 to 2012, with a mean value of 240 ± 60 GgCH4 yr?ą (at 95% confidence) in the most recent (2009–2012) period, and correspond to reasonably a constant factor of 1.5–2.0 (at 95% confidence) times larger than the BAAQMD CH4 emission inventory. However, we note that uncertainty in these emission estimates is dominated by the variation in CH4:CO enhancement ratios across the observing sites and we expect the estimates could represent a lower-limit on CH4 emissions because BAAQMD monitoring sites focus on urban air quality and may be biased toward CO rather than CH4 sources.« less

  19. IEEE TRANSACTION ON CONTROL SYSTEM TECHNOLOGY, VOL. XX, NO. Y, MONTH 2003 1 Control of Natural Gas Catalytic Partial

    E-Print Network [OSTI]

    Peng, Huei

    IEEE TRANSACTION ON CONTROL SYSTEM TECHNOLOGY, VOL. XX, NO. Y, MONTH 2003 1 Control of Natural Gas that reforms natural gas to hydrogen-rich mixture to feed the anode field of fuel cell stack is considered partial oxidation of the methane in the natural gas. We present a model-based control analysis and design

  20. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    or collectively). EMCON Methane Generation Model: A model for estimating the production of methane from municipal solid waste landfills. Emissions: Anthropogenic releases...

  1. Unconventional gas outlook: resources, economics, and technologies

    SciTech Connect (OSTI)

    Drazga, B.

    2006-08-15

    The report explains the current and potential of the unconventional gas market including country profiles, major project case studies, and new technology research. It identifies the major players in the market and reports their current and forecasted projects, as well as current volume and anticipated output for specific projects. Contents are: Overview of unconventional gas; Global natural gas market; Drivers of unconventional gas sources; Forecast; Types of unconventional gas; Major producing regions Overall market trends; Production technology research; Economics of unconventional gas production; Barriers and challenges; Key regions: Australia, Canada, China, Russia, Ukraine, United Kingdom, United States; Major Projects; Industry Initiatives; Major players. Uneconomic or marginally economic resources such as tight (low permeability) sandstones, shale gas, and coalbed methane are considered unconventional. However, due to continued research and favorable gas prices, many previously uneconomic or marginally economic gas resources are now economically viable, and may not be considered unconventional by some companies. Unconventional gas resources are geologically distinct in that conventional gas resources are buoyancy-driven deposits, occurring as discrete accumulations in structural or stratigraphic traps, whereas unconventional gas resources are generally not buoyancy-driven deposits. The unconventional natural gas category (CAM, gas shales, tight sands, and landfill) is expected to continue at double-digit growth levels in the near term. Until 2008, demand for unconventional natural gas is likely to increase at an AAR corresponding to 10.7% from 2003, aided by prioritized research and development efforts. 1 app.

  2. A Lean Methane Prelixed Laminar Flame Doped witg Components of Diesel Fuel. Part I: n)Butylbenzene

    E-Print Network [OSTI]

    Pousse, Emir; Fournet, René; Battin-Leclerc, Frédérique; 10.1016/j.combustflame.2008.09.012

    2009-01-01

    To better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar) of methane, 36.8% of oxygen and 0.96% of n-butylbenzene corresponding to an equivalence ratio of 0.74 and a ratio C10H14 / CH4 of 13.5%. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C0-C2 combustion products, but also 16 C3-C5 hydrocarbons, 7 C1-C3 oxygenated compounds, as well as 20 aromatic products, namely benzene, toluene, phenylacetylene, styrene, ethylbenzene, xylenes, allylbenzene, propylbenzene, cumene, methylstyrenes, butenylbenzenes, indene, indane, naphthalene, phenol, benzaldehyde, anisole, benzylalcohol, benzofuran, and isomers of C10H10 (1-methylindene, dihydronaphtalene, butadienylbenzene). A new mechanism for the...

  3. New mineralogy of the outer solar system and the high-pressure behaviour of methane 

    E-Print Network [OSTI]

    Maynard-Casely, Helen E.

    2009-01-01

    This thesis will introduce the study of methane as a mineral. Along with ammonia and water, methane is one of the main planetary-forming materials in the outer solar system. The topic of `new mineralogy of the outer solar ...

  4. MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER -METHANE AND WATER -ETHANE MIXTURES

    E-Print Network [OSTI]

    1 MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER - METHANE AND WATER - ETHANE MIXTURES Jeffrey were used to calculate water - methane and water - ethane phase equilibria over a wide range

  5. Methane oxidation in the eastern tropical North Pacific Ocean water column

    E-Print Network [OSTI]

    2015-01-01

    of methane in distilled water and seawater, J. Chem. Eng.Paci?c (ETP) Ocean • Water column MO x strongly mitigatesD. M. Lavoie (1983), Upper water column methane geochemistry

  6. Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane the current study and the previous measurements in similar flames with methane, ethane, and propane flames

  7. Methane drainage with horizontal boreholes in advance of longwall mining: an analysis. Final report

    SciTech Connect (OSTI)

    Gabello, D.P.; Felts, L.L.; Hayoz, F.P.

    1981-05-01

    The US Department of Energy (DOE) Morgantown Energy Technology Center has implemented a comprehensive program to demonstrate the technical and economic viability of coalbed methane as an energy resource. The program is directed toward solution of technical and institutional problems impeding the recovery and use of large quantities of methane contained in the nation's minable and unminable coalbeds. Conducted in direct support of the DOE Methane Recovery from Coalbeds Project, this study analyzes the economic aspects of a horizontal borehole methane recovery system integrated as part of a longwall mine operation. It establishes relationships between methane selling price and annual mine production, methane production rate, and the methane drainage system capital investment. Results are encouraging, indicating that an annual coal production increase of approximately eight percent would offset all associated drainage costs over the range of methane production rates and capital investments considered.

  8. Impact of transport model errors on the global and regional methane emissions estimated by inverse modelling

    E-Print Network [OSTI]

    Locatelli, R.

    A modelling experiment has been conceived to assess the impact of transport model errors on methane emissions estimated in an atmospheric inversion system. Synthetic methane observations, obtained from 10 different model ...

  9. Final report for the Iowa Livestock Industry Waste Characterization and Methane Recovery Information Dissemination Project

    SciTech Connect (OSTI)

    Garrison, M.V.; Richard, Thomas L

    2001-11-13

    This report summarizes analytical methods, characterizes Iowa livestock wastes, determines fossil fuel displacement by methane use, assesses the market potential, and offers recommendations for the implementation of methane recovery technologies.

  10. Climate Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Constraints

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Climate Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Policy Design: Interactions among Carbon Dioxide, Methane, and Urban Air Pollution Constraints by Marcus. The third case examines the benefits of increased policy coordination between air pollution constraints

  11. Timelines for mitigating methane emissions from energy technologies

    E-Print Network [OSTI]

    Roy, Mandira; Trancik, Jessika E

    2015-01-01

    Energy technologies emitting differing proportions of methane and carbon dioxide vary in their relative climate impacts over time, due to the different atmospheric lifetimes of the two gases. Standard technology comparisons using the global warming potential (GWP) emissions equivalency metric do not reveal these dynamic impacts, and may not provide the information needed to assess technologies and emissions mitigation opportunities in the context of broader climate policy goals. Here we formulate a portfolio optimization model that incorporates changes in technology impacts as a radiative forcing (RF) stabilization target is approached. An optimal portfolio, maximizing allowed energy consumption while meeting the RF target, is obtained by year-wise minimization of the marginal RF impact in an intended stabilization year. The optimal portfolio calls for using certain higher methane-emitting technologies prior to an optimal switching year, followed by methane-light technologies as the stabilization year approac...

  12. Landfill Gas Conversion to LNG and LCO{sub 2}. Phase II Final Report for January 25, 1999 - April 30, 2000

    SciTech Connect (OSTI)

    Brown, W. R.; Cook, W. J.; Siwajek, L. A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery.

  13. Method and apparatus for producing synthesis gas

    DOE Patents [OSTI]

    Hemmings, John William (Katy, TX); Bonnell, Leo (Houston, TX); Robinson, Earl T. (Mentor, OH)

    2010-03-03

    A method and apparatus for reacting a hydrocarbon containing feed stream by steam methane reforming reactions to form a synthesis gas. The hydrocarbon containing feed is reacted within a reactor having stages in which the final stage from which a synthesis gas is discharged incorporates expensive high temperature materials such as oxide dispersed strengthened metals while upstream stages operate at a lower temperature allowing the use of more conventional high temperature alloys. Each of the reactor stages incorporate reactor elements having one or more separation zones to separate oxygen from an oxygen containing feed to support combustion of a fuel within adjacent combustion zones, thereby to generate heat to support the endothermic steam methane reforming reactions.

  14. Methane production using resin-wafer electrodeionization

    DOE Patents [OSTI]

    Snyder, Seth W; Lin, YuPo; Urgun-Demirtas, Meltem

    2014-03-25

    The present invention provides an efficient method for creating natural gas including the anaerobic digestion of biomass to form biogas, and the electrodeionization of biogas to form natural gas and carbon dioxide using a resin-wafer deionization (RW-EDI) system. The method may be further modified to include a wastewater treatment system and can include a chemical conditioning/dewatering system after the anaerobic digestion system. The RW-EDI system, which includes a cathode and an anode, can either comprise at least one pair of wafers, each a basic and acidic wafer, or at least one wafer comprising of a basic portion and an acidic portion. A final embodiment of the RW-EDI system can include only one basic wafer for creating natural gas.

  15. Small Thaw Ponds: An Unaccounted Source of Methane in the Canadian High Arctic

    E-Print Network [OSTI]

    2013-01-01

    methane production between runnel and polygonal ponds using stable isotope ratios, 14 C signatures, and investigated potential

  16. Benefits and hurdles for biological methane upgrading; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Fei, Qiang

    2015-09-01

    The presentation will focus on the technical hurdles for bioconversion of methane into chemical and liquid fuel.

  17. Arkansas Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - Natural GasYear Jan Feb

  18. Colorado Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7

  19. Pennsylvania Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3+Elements) Gas6Proved Reserves

  20. Wyoming Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade Year-0 Year-1 Year-2YearWesternYearGasOECD/IEA

  1. Methane Hydrates R&D Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on dark matter ByMentor-ProtegeFromGas Hydrates R&D Program Gas

  2. A 5-step reduced mechanism for combustion of CO/H2/H2O/CH4/CO2 mixtures with low hydrogen/methane and high H2O content

    E-Print Network [OSTI]

    Nicolaou, Z. M.; Chen, J. Y.; Swaminathan, N.

    2012-10-17

    In this study a 5-step reduced chemical kinetic mechanism involving 9 species is developed for combustion of Blast Furnace Gas (BFG), a multi-component fuel containing CO/H2/CH4/CO2, typically with low hydrogen, methane and high water fractions...

  3. Supplanting ecosystem services provided by scavengers raises greenhouse gas

    E-Print Network [OSTI]

    Richner, Heinz

    Supplanting ecosystem services provided by scavengers raises greenhouse gas emissions Zebensui to human-induced increments in atmospheric concentrations of greenhouse gases (GHG) is one of the most concentrations of some gases such as carbon dioxide, methane or nitrous oxide (globally called greenhouse gases

  4. Study of a zirconium getter for purification of xenon gas

    E-Print Network [OSTI]

    Dobi, A; Hall, C; Kaufman, L; Langford, T; Slutsky, S; Yen, Y R

    2010-01-01

    Oxygen, nitrogen and methane purification efficiencies for a common zirconium getter are measured in 1050 Torr of xenon gas. Starting with impurity concentrations near 10^{-6} g/g, the outlet impurity level is found to be less than 120*10^{-12} g/g for O2 and less than 950*10^{-12} g/g for N2. For methane we find residual contamination of the purified gas at concentrations varying over three orders of magnitude, depending on the purifier temperature and the gas flow rate. A slight reduction in the purifier's methane efficiency is observed after 13 mg of this impurity has been absorbed, which we attribute to partial exhaustion of the purifier's capacity for this species. We also find that the purifier's ability to absorb N2 and methane can be extinguished long before any decrease in O2 performance is observed, and slower flow rates should be employed for xenon purification due to the cooling effect that the heavy gas has on the getter.

  5. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  6. Detection of methane on Kuiper Belt Object (50000) Quaoar

    E-Print Network [OSTI]

    E. L. Schaller; M. E. Brown

    2007-10-18

    The near-infrared spectrum of (50000) Quaoar obtained at the Keck Observatory shows distinct absorption features of crystalline water ice, solid methane and ethane, and possibly other higher order hydrocarbons. Quaoar is only the fifth Kuiper belt object on which volatile ices have been detected. The small amount of methane on an otherwise water ice dominated surface suggests that Quaoar is a transition object between the dominant volatile-poor small Kuiper belt objects (KBOs) and the few volatile-rich large KBOs such as Pluto and Eris.

  7. ISOTOPIC RATIOS IN TITAN's METHANE: MEASUREMENTS AND MODELING

    SciTech Connect (OSTI)

    Nixon, C. A.; Achterberg, R. K.; Temelso, B.; Vinatier, S.; Bezard, B.; Coustenis, A.; Teanby, N. A.; Mandt, K. E.; Sherrill, C. D.; Irwin, P. G. J.; Jennings, D. E.; Romani, P. N.; Flasar, F. M.

    2012-04-20

    The existence of methane in Titan's atmosphere ({approx}6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of {approx}20 Myr. In this paper, we examine the clues available from isotopic ratios ({sup 12}C/{sup 13}C and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH{sub 4} collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: {sup 13}CH{sub 4}, {sup 12}CH{sub 3}D, and {sup 13}CH{sub 3}D. From these we compute estimates of {sup 12}C/{sup 13}C = 86.5 {+-} 8.2 and D/H = (1.59 {+-} 0.33) Multiplication-Sign 10{sup -4}, in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH{sub 4} + C{sub 2}H {yields} CH{sub 3} + C{sub 2}H{sub 2}. Using these new measurements and predictions we proceed to model the time evolution of {sup 12}C/{sup 13}C and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH{sub 4}), we find that the present-day {sup 12}C/{sup 13}C implies that the CH{sub 4} entered the atmosphere 60-1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently-most likely less than 10 Myr ago-if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing. We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

  8. Methane production of dairy cows fed cereals with or without protein supplement

    E-Print Network [OSTI]

    consumption 26 Milk yield 29 Weight 31 Feed intake and feeding level 31 #12;2 Discussion 32 Methane productionMethane production of dairy cows fed cereals with or without protein supplement and high quality;#12;Methane production of dairy cows fed cereals with or without protein supplement and high quality silage

  9. Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts

    E-Print Network [OSTI]

    Bao, Xinhe

    are not commercialized yet. Current industrial technologies for the production of chemicals from methane are mainly basedAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan Ć attracted much attention as a potential route to obtain chemicals. Methane, the main component of natural

  10. Implications of the recent fluctuations in the growth rate of tropospheric methane

    E-Print Network [OSTI]

    Post, Wilfred M.

    Implications of the recent fluctuations in the growth rate of tropospheric methane Isobel J] Global measurements show that the mixing ratio of tropo- spheric methane (CH4) increased by 1.1% (19 (0315, 0325) 1. Introduction [2] Methane (CH4) plays critical roles in the chemistry and radiative

  11. FILLING OF METHANE/AIR MIXTURE IN A TUBE FOR PULSE DETONATION ENGINES SHRAVANI DWARAKAPALLY

    E-Print Network [OSTI]

    Texas at Arlington, University of

    FILLING OF METHANE/AIR MIXTURE IN A TUBE FOR PULSE DETONATION ENGINES By SHRAVANI DWARAKAPALLY. Thanks to my god Lord Shiva for his blessings. November 18, 2011 #12;v ABSTRACT FILLING OF METHANE, was studied using the unsteady flow solver methane and air nominally at STP. Three cases were examined: (i

  12. On the volatile inventory of Titan from isotopic abundances in nitrogen and methane

    E-Print Network [OSTI]

    Lorenz, Ralph D.

    On the volatile inventory of Titan from isotopic abundances in nitrogen and methane Jonathan I enhancement. The enrichment in deuterated methane is now much better determined than it was when Pinto et al dissociation rates of normal and deuterated methane. We utilize the improved data and models to compute initial

  13. Airborne observations of methane emissions from rice cultivation in the Sacramento Valley of California

    E-Print Network [OSTI]

    Goldstein, Allen

    Airborne observations of methane emissions from rice cultivation in the Sacramento Valley 2012; accepted 7 October 2012; published 8 December 2012. [1] Airborne measurements of methane (CH4 is not accounted for in the CARB inventory. Citation: Peischl, J., et al. (2012), Airborne observations of methane

  14. ORIGINAL ARTICLE Community structure and nutrition of deep methane-seep

    E-Print Network [OSTI]

    Levin, Lisa

    ORIGINAL ARTICLE Community structure and nutrition of deep methane-seep macrobenthos from the North Methane seeps occur at depths extending to over 7000 m along the world's continental margins signa- tures, the utilization of chemosynthetically fixed and methane-derived organic matter

  15. The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India*

    E-Print Network [OSTI]

    The variability of methane, nitrous oxide and sulfur hexafluoride in Northeast India* A.L. Ganesan of methane, nitrous oxide and sulfur hexafluoride in Northeast India A. L. Ganesan1, A. Chatterjee2, R. G-frequency atmospheric measurements of methane (CH4), nitrous oxide (N2O) and sulfur hexafluo- ride (SF6) from Darjeeling

  16. Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H

    E-Print Network [OSTI]

    Jones, William D.

    Evidence for Methane -Complexes in Reductive Elimination Reactions from TpRh(L)(CH3)H Douglas D of methane from TpRh(L)(CH3)H in benzene/perfluorobenzene solvent mixtures is found to be dependent upon the concentration of benzene, indicating an associative component to the reductive elimination of methane. Both

  17. Asymptotic Analysis of the Structure of Moderately Rich Methane-Air Flames

    E-Print Network [OSTI]

    Pitsch, Heinz

    Asymptotic Analysis of the Structure of Moderately Rich Methane-Air Flames K. SESHADRI,* X. S. BAI Republic of Germany The asymptotic structure of laminar, moderately rich, premixed methane flames structure of laminar, stoichi- ometric, and lean methane flames [1­6]. For rich flames, these analyses did

  18. Methane-related authigenic carbonates from the Black Sea: geochemical characterisation and relation to seeping fluids

    E-Print Network [OSTI]

    Mazzini, Adriano

    Methane-related authigenic carbonates from the Black Sea: geochemical characterisation and relation of carbon derived from the anaerobic oxidation of methane (AOM), the oxidation of organic matter and from sea water. Methane is the dominant component among other hydrocarbon gases in these sediments. Its

  19. Changing boreal methane sources and constant biomass burning during the last termination

    E-Print Network [OSTI]

    Chappellaz, Jérôme

    LETTERS Changing boreal methane sources and constant biomass burning during the last termination. Stocker3 Past atmospheric methane concentrations show strong fluctua- tions in parallel to rapid glacial climate changes in the Northern Hemisphere1,2 superimposed on a glacial­interglacial doubling of methane

  20. Net ecosystem methane and carbon dioxide exchanges in a Lake Erie coastal marsh

    E-Print Network [OSTI]

    Chen, Jiquan

    Net ecosystem methane and carbon dioxide exchanges in a Lake Erie coastal marsh and a nearby ecosystem carbon dioxide (FCO2) and methane (FCH4) exchanges were measured by using the eddy covariance ) at the cropland. At the seasonal scale, soil temperature associated with methane (CH4) production provided

  1. Microscopic Mechanisms and Dynamics Simulations of S3/2) Reacting with Methane

    E-Print Network [OSTI]

    1 Microscopic Mechanisms and Dynamics Simulations of O+ (4 S3/2) Reacting with Methane Lipeng Sun: The reaction O+ (4 S3/2) + methane is studied as a benchmark for developing the theory of polymer erosion by O;2 Microscopic Mechanisms and Dynamics Simulations of O+ (4 S3/2) Reacting with Methane spacecraft,3 surprisingly

  2. Author's personal copy Methane evolution from UV-irradiated spacecraft materials under simulated

    E-Print Network [OSTI]

    Schuerger, Andrew C.

    Author's personal copy Methane evolution from UV-irradiated spacecraft materials under simulated a b s t r a c t Fifteen organic and three inorganic compounds were tested for methane (CH4) evolution methane at the min- imum detection level 0.5 ppm, or above. In contrast, all organic compounds evolved

  3. Small-scale methane dispersion modelling for possible plume sources on the surface of Mars

    E-Print Network [OSTI]

    Strong, Kimberly

    Small-scale methane dispersion modelling for possible plume sources on the surface of Mars K. S 2012; published 11 October 2012. [1] Intense interest in the characteristics of a methane source Laboratory and future landers and orbiters will be tasked with understanding the sources of methane

  4. ADVECTION OF METHANE IN THE HYDRATE ZONE: MODEL, ANALYSIS AND EXAMPLES

    E-Print Network [OSTI]

    ADVECTION OF METHANE IN THE HYDRATE ZONE: MODEL, ANALYSIS AND EXAMPLES MALGORZATA PESZYNSKA, RALPH for the advective-diffusive trans- port of methane in liquid phase through sediment with the accompanying formation and disso- lution of methane hydrate. This free-boundary problem has a unique generalized solution in L1

  5. Fates of methane from different lake habitats: Connecting whole-lake budgets and CH4 emissions

    E-Print Network [OSTI]

    Pace, Michael L.

    Fates of methane from different lake habitats: Connecting whole-lake budgets and CH4 emissions September 2007; revised 3 February 2008; accepted 28 February 2008; published 24 May 2008. [1] Methane (CH4 clear. We quantified internal cycling and methane emissions in three lakes during summer stratification

  6. Tricaine methane-sulfonate (MS-222) application in fish anaesthesia By N. Topic Popovic1

    E-Print Network [OSTI]

    Boynton, Walter R.

    Review Tricaine methane-sulfonate (MS-222) application in fish anaesthesia By N. Topic Popovic1 , I, Croatia Summary Tricaine methane-sulfonate (MS-222) is one of the most widely used anaesthetics in aquaculture and experimental procedures. Tricaine methane-sulphonate (MS-222), C9H11O2N + CH3SO3H, also known

  7. METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1

    E-Print Network [OSTI]

    Brown, Michael E.

    METHANE AND ETHANE ON THE BRIGHT KUIPER BELT OBJECT 2005 FY9 M. E. Brown,1 K. M. Barkume,1 G. A indicates the clear presence of ethane, an expected product of UV photolysis of methane. No evidence for N2 of 2005 FY9 that leads to large methane grains, abundant sites for ethane formation through UV photolysis

  8. Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by FeO

    E-Print Network [OSTI]

    Metz, Ricardo B.

    Electronic spectroscopy of intermediates involved in the conversion of methane to methanol by Fe.1063/1.1448489 I. INTRODUCTION The direct oxidation of methane to an easily transport- able liquid such as methanol process and as the simplest model for alkane oxidation.1,2 Although no direct, efficient methane­methanol

  9. Methane emissions from lakes: Dependence of lake characteristics, two regional assessments, and a global estimate

    E-Print Network [OSTI]

    Notre Dame, University of

    production rate minus potential methane oxidation) and the hydrostatic pressure which has to be overcome 2004. [1] Lake sediments are ``hot spots'' of methane production in the landscape. However, regional. Present evidence from lakes suggests that the majority of methane production occurs in anoxic sediment

  10. ANALYSIS OF ENHANCED COALBED METHANE RECOVERY THROUGH CARBON SEQUESTRATION IN THE CENTRAL

    E-Print Network [OSTI]

    potential of coalbed methane production using carbon dioxide sequestration in the Central Appalachian BasinANALYSIS OF ENHANCED COALBED METHANE RECOVERY THROUGH CARBON SEQUESTRATION IN THE CENTRAL dioxide emissions from power plants, while enhancing the recovery of coalbed methane. Injected carbon

  11. Mars long has been considered a cold, dead planet.However,recent reports of methane

    E-Print Network [OSTI]

    Manning, Craig

    investigations and flight missions. Terrestrial Methane Formation: Potential Analogues for Martian Processes Biogenic methane production results from extant biological activity (microbial metha- nogenesis) as well instance, methane is the meta- bolic by-product of a single related group of microorganisms known

  12. Methane Production in Microbial Reverse-Electrodialysis Methanogenesis Cells (MRMCs) Using Thermolytic Solutions

    E-Print Network [OSTI]

    . These results show that the MRMC has significant potential for production of nearly pure methane using lowMethane Production in Microbial Reverse-Electrodialysis Methanogenesis Cells (MRMCs) Using Supporting Information ABSTRACT: The utilization of bioelectrochemical systems for methane production has

  13. Anaerobic digestion for methane generation and ammonia reforming for hydrogen production

    E-Print Network [OSTI]

    Anaerobic digestion for methane generation and ammonia reforming for hydrogen production to the methane potential alone indicated that at a C:N ratio of 17, the energy output was greater for the ADBH is converted to carbon dioxide and methane, and organic nitrogen is converted to ammonia. Generally, ammonia

  14. Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing

    E-Print Network [OSTI]

    Sessions, Alex L.

    Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section incubating sediment with 13 C-labeled methane, ethane, or propane, we5 confirmed the incorporation of 13 C

  15. Improved methodology to assess modification and completion of landfill gas management in the aftercare period

    SciTech Connect (OSTI)

    Morris, Jeremy W.F.; Crest, Marion; Barlaz, Morton A.; Spokas, Kurt A.; Akerman, Anna; Yuan, Lei

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Performance-based evaluation of landfill gas control system. Black-Right-Pointing-Pointer Analytical framework to evaluate transition from active to passive gas control. Black-Right-Pointing-Pointer Focus on cover oxidation as an alternative means of passive gas control. Black-Right-Pointing-Pointer Integrates research on long-term landfill behavior with practical guidance. - Abstract: Municipal solid waste landfills represent the dominant option for waste disposal in many parts of the world. While some countries have greatly reduced their reliance on landfills, there remain thousands of landfills that require aftercare. The development of cost-effective strategies for landfill aftercare is in society's interest to protect human health and the environment and to prevent the emergence of landfills with exhausted aftercare funding. The Evaluation of Post-Closure Care (EPCC) methodology is a performance-based approach in which landfill performance is assessed in four modules including leachate, gas, groundwater, and final cover. In the methodology, the objective is to evaluate landfill performance to determine when aftercare monitoring and maintenance can be reduced or possibly eliminated. This study presents an improved gas module for the methodology. While the original version of the module focused narrowly on regulatory requirements for control of methane migration, the improved gas module also considers best available control technology for landfill gas in terms of greenhouse gas emissions, air quality, and emissions of odoriferous compounds. The improved module emphasizes the reduction or elimination of fugitive methane by considering the methane oxidation capacity of the cover system. The module also allows for the installation of biologically active covers or other features designed to enhance methane oxidation. A methane emissions model, CALMIM, was used to assist with an assessment of the methane oxidation capacity of landfill covers.

  16. COMPACT QEPAS SENSOR FOR TRACE METHANE AND AMMONIA DETECTION IN IMPURE HYDROGEN

    SciTech Connect (OSTI)

    Wright, J; Ferguson, B; Peters, B; Mcwhorter, S

    2011-11-02

    A compact two-gas sensor based on quartz enhanced photoacoustic spectroscopy (QEPAS) was developed for trace methane and ammonia quantification in impure hydrogen. The sensor is equipped with a micro-resonator to confine the sound wave and enhance QEPAS signal. The normalized noise-equivalent absorption coefficients (1{sigma}) of 2.45 x 10{sup -8} cm{sup -1}W/{radical}Hz and 9.1 x 10{sup -9} cm{sup -1}W/{radical}Hz for CH{sub 4} detection at 200 Torr and NH{sub 3} detection at 50 Torr were demonstrated with the QEPAS sensor configuration, respectively. The influence of water vapor on the CH{sub 4} channel was also investigated.

  17. Assessment of methane-related fuels for automotive fleet vehicles: technical, supply, and economic assessments

    SciTech Connect (OSTI)

    Not Available

    1982-02-01

    The use of methane-related fuels, derived from a variety of sources, in highway vehicles is assessed. Methane, as used here, includes natural gas (NG) as well as synthetic natural gas (SNG). Methanol is included because it can be produced from NG or the same resources as SNG, and because it is a liquid fuel at normal ambient conditions. Technological, operational, efficiency, petroleum displacement, supply, safety, and economic issues are analyzed. In principle, both NG and methanol allow more efficient engine operation than gasoline. In practice, engines are at present rarely optimized for NG and methanol. On the basis of energy expended from resource extraction to end use, only optimized LNG vehicles are more efficient than their gasoline counterparts. By 1985, up to 16% of total petroleum-based highway vehicle fuel could be displaced by large fleets with central NG fueling depots. Excluding diesel vehicles, which need technology advances to use NG, savings of 8% are projected. Methanol use by large fleets could displace up to 8% of petroleum-based highway vehicle fuel from spark-ignition vehicles and another 9% from diesel vehicles with technology advances. The US NG supply appears adequate to accommodate fleet use. Supply projections, future price differential versus gasoline, and user economics are uncertain. In many cases, attractive paybacks can occur. Compressed NG now costs on average about $0.65 less than gasoline, per energy-equivalent gallon. Methanol supply projections, future prices, and user economics are even more uncertain. Current and projected near-term methanol supplies are far from adequate to support fleet use. Methanol presently costs more than gasoline on an equal-energy basis, but is projected to cost less if produced from coal instead of NG or petroleum.

  18. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    SciTech Connect (OSTI)

    Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

    2011-02-15

    Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

  19. Natural gas monthly, October 1991

    SciTech Connect (OSTI)

    Not Available

    1991-11-05

    The Natural Gas Monthly (NGM) is prepared in the Data Operations Branch of the Reserves and Natural Gas Division, Office of Oil and Gas, Energy Information Administration (EIA), US Department of Energy (DOE). The NGM highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. The data in this publication are collected on surveys conducted by the EIA to fulfill its responsibilities for gathering and reporting energy data. Some of the data are collected under the authority of the Federal Energy Regulatory Commission (FERC), an independent commission within the DOE, which has jurisdiction primarily in the regulation of electric utilities and the interstate natural gas industry. Geographic coverage is the 50 States and the District of Columbia. 16 figs., 33 tabs.

  20. Michigan Coalbed Methane Production (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014 MEMORANDUM