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Sample records for gas phase gip

  1. Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Diagnostics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  2. Sandia Energy - Gas-Phase Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas-Phase Diagnostics Home Transportation Energy Predictive Simulation of Engines Diagnostics Gas-Phase Diagnostics Gas-Phase DiagnosticsAshley Otero2015-10-28T02:24:57+00:00 The...

  3. Surface plasmon sensing of gas phase contaminants using optical...

    Office of Scientific and Technical Information (OSTI)

    plasmon sensing of gas phase contaminants using optical fiber. Citation Details In-Document Search Title: Surface plasmon sensing of gas phase contaminants using optical fiber. ...

  4. Surface plasmon sensing of gas phase contaminants using optical...

    Office of Scientific and Technical Information (OSTI)

    Surface plasmon sensing of gas phase contaminants using optical fiber. Citation Details In-Document Search Title: Surface plasmon sensing of gas phase contaminants using optical...

  5. Gas-phase propane fuel delivery system

    SciTech Connect (OSTI)

    Clements, J.

    1991-04-30

    This patent describes a gas-phase fuel delivery system for delivering a vapor phase fuel independent of exterior temperatures. It comprises:a storage tank for storing a volume of fuel; a regulator in fluid communication with the tank for receiving fuel from the tank and for outputting the fuel in a vapor phase; a pressure sensor in fluid communication with the tank for monitoring pressure within the tank, the pressure sensor being operative to generate a pump enable signal when the pressure within the tank is less than a predetermined threshold; a pump in fluid communication with the tank.

  6. Receptors useful for gas phase chemical sensing

    DOE Patents [OSTI]

    Jaworski, Justyn W; Lee, Seung-Wuk; Majumdar, Arunava; Raorane, Digvijay A

    2015-02-17

    The invention provides for a receptor, capable of binding to a target molecule, linked to a hygroscopic polymer or hydrogel; and the use of this receptor in a device for detecting the target molecule in a gaseous and/or liquid phase. The invention also provides for a method for detecting the presence of a target molecule in the gas phase using the device. In particular, the receptor can be a peptide capable of binding a 2,4,6-trinitrotoluene (TNT) or 2,4,-dinitrotoluene (DNT).

  7. Gas phase thermochemistry of organogermanium compounds

    SciTech Connect (OSTI)

    Engel, J.P.

    1993-12-07

    A variety of silyl- and alkyl-germylene precursors have been synthesized and subsequently pyrolyzed in the gas phase. Arrhenius parameters were obtained employing a pulsed-stirred flow reactor for these unimolecular decompositions. These precursors are divided into two major categories by mechanism of germylene extrusion: {alpha}-elimination precursors and germylacetylenes. The extrusion of germylenes from germylacetylene precursors is of primary interest. A mechanism is proposed employing a germacyclopropene intermediate. Evidence supporting this mechanism is presented. In the process of exploring germylacetylenes as germylene precursors, an apparent dyatropic rearrangement between germanium and silicon was observed. This rearrangement was subsequently explored.

  8. Surface plasmon sensing of gas phase contaminants using optical fiber.

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Surface plasmon sensing of gas phase contaminants using optical fiber. Citation Details In-Document Search Title: Surface plasmon sensing of gas phase contaminants using optical fiber. Fiber-optic gas phase surface plasmon resonance (SPR) detection of several contaminant gases of interest to state-of-health monitoring in high-consequence sealed systems has been demonstrated. These contaminant gases include H{sub 2}, H{sub 2}S, and moisture using a

  9. Selective gas adsorption and unique phase transition properties...

    Office of Scientific and Technical Information (OSTI)

    Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Citation Details In-Document...

  10. Selective gas adsorption and unique phase transition properties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains Previous Next List Yangyang Liu, Ying-Pin...

  11. Hydrocarbon radical thermochemistry: Gas-phase ion chemistry techniques

    SciTech Connect (OSTI)

    Ervin, Kent M.

    2014-03-21

    Final Scientific/Technical Report for the project "Hydrocarbon Radical Thermochemistry: Gas-Phase Ion Chemistry Techniques." The objective of this project is to exploit gas-phase ion chemistry techniques for determination of thermochemical values for neutral hydrocarbon radicals of importance in combustion kinetics.

  12. Calculate Gas Phase Transport Properties of Pure Species and Mixtures

    Energy Science and Technology Software Center (OSTI)

    1997-10-20

    DRFM is a set of routines and data bases used to calculate gas phase transport properties of pure species and mixtures. The program(s) may stand alone or may be used as part of a larger simulation.

  13. Phase-field simulations of gas density within bubbles under irradiatio...

    Office of Scientific and Technical Information (OSTI)

    Phase-field simulations of gas density within bubbles under irradiation Citation Details In-Document Search Title: Phase-field simulations of gas density within bubbles under ...

  14. Constant volume gas cell optical phase-shifter

    DOE Patents [OSTI]

    Phillion, Donald W. (Dublin, CA)

    2002-01-01

    A constant volume gas cell optical phase-shifter, particularly applicable for phase-shifting interferometry, contains a sealed volume of atmospheric gas at a pressure somewhat different than atmospheric. An optical window is present at each end of the cell, and as the length of the cell is changed, the optical path length of a laser beam traversing the cell changes. The cell comprises movable coaxial tubes with seals and a volume equalizing opening. Because the cell is constant volume, the pressure, temperature, and density of the contained gas do not change as the cell changes length. This produces an exactly linear relationship between the change in the length of the gas cell and the change in optical phase of the laser beam traversing it. Because the refractive index difference between the gas inside and the atmosphere outside is very much the same, a large motion must be made to change the optical phase by the small fraction of a wavelength that is required by phase-shifting interferometry for its phase step. This motion can be made to great fractional accuracy.

  15. Freeze drying for gas chromatography stationary phase deposition

    DOE Patents [OSTI]

    Sylwester, Alan P. (Livermore, CA)

    2007-01-02

    The present disclosure relates to methods for deposition of gas chromatography (GC) stationary phases into chromatography columns, for example gas chromatography columns. A chromatographic medium is dissolved or suspended in a solvent to form a composition. The composition may be inserted into a chromatographic column. Alternatively, portions of the chromatographic column may be exposed or filled with the composition. The composition is permitted to solidify, and at least a portion of the solvent is removed by vacuum sublimation.

  16. Gas phase chemical detection with an integrated chemical analysis system

    SciTech Connect (OSTI)

    CASALNUOVO,STEPHEN A.; FRYE-MASON,GREGORY CHARLES; KOTTENSTETTE,RICHARD; HELLER,EDWIN J.; MATZKE,CAROLYN M.; LEWIS,PATRICK R.; MANGINELL,RONALD P.; BACA,ALBERT G.; HIETALA,VINCENT M.

    2000-04-12

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  17. Gas Phase Chemical Detection with an Integrated Chemical Analysis System

    SciTech Connect (OSTI)

    Baca, Albert G.; Casalnuovo, Stephen A.; Frye-Mason, Gregory C.; Heller, Edwin J.; Hietala, Susan L.; Hietala, Vincent M.; Kottenstette, Richard J.; Lewis, Patrick R.; Manginell, Ronald P.; Matzke, Carloyn M.; Reno, John L.; Sasaki, Darryl Y.; Schubert, W. Kent

    1999-07-08

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample concentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described. The design and performance of novel micromachined acoustic wave devices, with the potential for improved chemical sensitivity, are also described.

  18. Gas phase fractionation method using porous ceramic membrane

    DOE Patents [OSTI]

    Peterson, Reid A. (Madison, WI); Hill, Jr., Charles G. (Madison, WI); Anderson, Marc A. (Madison, WI)

    1996-01-01

    Flaw-free porous ceramic membranes fabricated from metal sols and coated onto a porous support are advantageously used in gas phase fractionation methods. Mean pore diameters of less than 40 .ANG., preferably 5-20 .ANG. and most preferably about 15 .ANG., are permeable at lower pressures than existing membranes. Condensation of gases in small pores and non-Knudsen membrane transport mechanisms are employed to facilitate and increase membrane permeability and permselectivity.

  19. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  20. ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT (Technical...

    Office of Scientific and Technical Information (OSTI)

    ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT Citation Details In-Document Search Title: ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT You are accessing...

  1. PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE...

    Office of Scientific and Technical Information (OSTI)

    METALS: PART II: GAS BUBBLE KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS We present a phase-field ...

  2. Phase-field simulations of gas density within bubbles under irradiation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Phase-field simulations of gas density within bubbles under irradiation Citation Details In-Document Search Title: Phase-field simulations of gas density within bubbles under irradiation Phase-field simulations are used to study the evolution of gas density within irradiation-induced bubbles. In our simulations, the dpa rate, gas production rate, and defect diffusivities are systematically varied to understand their effect on bubble nucleation rates,

  3. Application of Phase-field Method in Predicting Gas Bubble Microstructure Evolution in Nuclear Fuels

    SciTech Connect (OSTI)

    Hu, Shenyang Y.; Li, Yulan; Sun, Xin; Gao, Fei; Devanathan, Ramaswami; Henager, Charles H.; Khaleel, Mohammad A.

    2010-04-30

    Fission product accumulation and gas bubble microstructure evolution in nuclear fuels strongly affect thermo-mechanical properties such as thermal conductivity, gas release, volumetric swelling and cracking, and hence the fuel performance. In this paper, a general phase-field model is developed to predict gas bubble formation and evolution. Important materials processes and thermodynamic properties including the generation of gas atoms and vacancies, sinks for vacancies and gas atoms, the elastic interaction among defects, gas re-solution, and inhomogeneity of elasticity and diffusivity are accounted for in the model. The simulations demonstrate the potential application of the phase-field method in investigating 1) heterogeneous nucleation of gas bubbles at defects; 2) effect of elastic interaction, inhomogeneity of material properties, and gas re-solution on gas bubble microstructures; and 3) effective properties from the output of phase-field simulations such as distribution of defects, gas bubbles, and stress fields.

  4. PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect METALS: PART II: GAS BUBBLE KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS We present a phase-field model for inert gas bubble formation and evolution in irradiated metals. The model evolves vacancy, self-interstitial, and fission gas atoms through a coupled set of Cahn-Hilliard and Allen-Cahn equations, capturing the processes of defect generation, recombination, annihilation

  5. Gas Phase Chemical Physics | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Gas Phase Chemical Physics Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Gas Phase Chemical Physics Print Text Size: A A A FeedbackShare Page Gas Phase Chemical Physics (GPCP) research emphasizes studies of the dynamics and rates of chemical reactions at energies characteristic of

  6. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  7. Two-dimensional gas-phase coherent anti-Stokes Raman spectroscopy...

    Office of Scientific and Technical Information (OSTI)

    Two-dimensional gas-phase coherent anti-Stokes Raman spectroscopy (2D-CARS): simultaneous planar imaging and multiplex spectroscopy in a single laser shot. Citation Details...

  8. ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT Citation Details In-Document Search Title: ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT AREVA Federal Services (AFS) is performing a multi-year, multi-phase Advanced Remediation Technologies (ART) project, sponsored by the U.S. Department of Energy (DOE), to evaluate the feasibility and benefits of replacing the existing joule-heated melter (JHM) used to treat high level waste (HLW) in the

  9. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-09-29

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase is dispersed.

  10. Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

    DOE Patents [OSTI]

    Lin, Manhua; Wang, Xiang; Yeom, Younghoon

    2015-03-17

    A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C.sub.3 to C.sub.9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

  11. Measurements and calculations of oscillations and phase relations in the driven gas-phase combustion of acetaldehyde

    SciTech Connect (OSTI)

    Tsujimoto, K.K.; Hjelmfelt, A.; Ross, J. (Department of Chemistry, Stanford University, Stanford, California (USA))

    1991-09-01

    Oscillations in light emission and species concentrations, are measured as periodic perturbations are simultaneously applied to the input rates of acetaldehyde and oxygen in the gas-phase combustion of acetaldehyde in a continuous-flow stirred tank reactor for conditions where the autonomous reaction itself is oscillatory. The experimental results are compared with the predictions of a five-variable thermokinetic model. We measure periodic responses in the fundamental entrainment band (ratio of frequency of perturbation to frequency of response equal to unity) for four different values of phase shift between the acetaldehyde and oxygen perturbation wave forms as we vary the frequency and amplitude of the external periodic perturbations. Outside of the entrainment bands we find quasiperiodic response. We determine the phases of the light emission and six species concentrations, as measured with a mass spectrometer, with respect to the periodic perturbation, the variation of these phases across the fundamental entrainment band for different values of reactant phase shift and for different amplitudes of perturbation, and the effects of the phase shift between the two input perturbations on the light emission response of the system for different frequencies of perturbation. Both the experiments and calculations predict a widening of the entrainment band with an increase in perturbation amplitude, and the same variation in bandwidths for the four values of reactant phase shift studied. The experiments and calculations also predict the same general trends in light phase and species phases (difference between the light emission and species concentrations with respect to the perturbing wave form) as the band is traversed for different amplitudes of perturbation and for different values of reactant phase shift.

  12. Metal-Organic Framework Thin Films as Stationary Phases in Microfabricated Gas-Chromatography Columns.

    SciTech Connect (OSTI)

    Read, Douglas; Sillerud, Colin Halliday

    2016-01-01

    The overarching goal of this project is to integrate Sandia's microfabricated gas-chromatography ( GC) columns with a stationary phase material that is capable of retaining high-volatility chemicals and permanent gases. The successful integration of such a material with GCs would dramatically expand the repertoire of detectable compounds for Sandia's various microanalysis systems. One such promising class of candidate materials is metal-organic frameworks (MOFs). In this report we detail our methods for controlled deposition of HKUST-1 MOF stationary phases within GC columns. We demonstrate: the chromatographic separation of natural gas; a method for determining MOF film thickness from chromatography alone; and the first-reported GC x GC separation of natural gas -- in general -- let alone for two disparate MOF stationary phases. In addition we determine the fundamental thermodynamic constant for mass sorption, the partition coefficient, for HKUST-1 and several light hydrocarbons and select toxic industrial chemicals.

  13. Device for two-dimensional gas-phase separation and characterization of ion mixtures

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Shvartsburg, Alexandre A. (Richland, WA); Smith, Richard D. (Richland, WA)

    2006-12-12

    The present invention relates to a device for separation and characterization of gas-phase ions. The device incorporates an ion source, a field asymmetric waveform ion mobility spectrometry (FAIMS) analyzer, an ion mobility spectrometry (IMS) drift tube, and an ion detector. In one aspect of the invention, FAIMS operating voltages are electrically floated on top of the IMS drift voltage. In the other aspect, the FAIMS/IMS interface is implemented employing an electrodynamic ion funnel, including in particular an hourglass ion funnel. The present invention improves the efficiency (peak capacity) and sensitivity of gas-phase separations; the online FAIMS/IMS coupling creates a fundamentally novel two-dimensional gas-phase separation technology with high peak capacity, specificity, and exceptional throughput.

  14. Plasma-produced phase-pure cuprous oxide nanowires for methane gas sensing

    SciTech Connect (OSTI)

    Cheng, Qijin Zhang, Fengyan; Yan, Wei; Randeniya, Lakshman; Ostrikov, Kostya

    2014-03-28

    Phase-selective synthesis of copper oxide nanowires is warranted by several applications, yet it remains challenging because of the narrow windows of the suitable temperature and precursor gas composition in thermal processes. Here, we report on the room-temperature synthesis of small-diameter, large-area, uniform, and phase-pure Cu{sub 2}O nanowires by exposing copper films to a custom-designed low-pressure, thermally non-equilibrium, high-density (typically, the electron number density is in the range of 10{sup 11}–10{sup 13}?cm{sup ?3}) inductively coupled plasmas. The mechanism of the plasma-enabled phase selectivity is proposed. The gas sensors based on the synthesized Cu{sub 2}O nanowires feature fast response and recovery for the low-temperature (?140?°C) detection of methane gas in comparison with polycrystalline Cu{sub 2}O thin film-based gas sensors. Specifically, at a methane concentration of 4%, the response and the recovery times of the Cu{sub 2}O nanowire-based gas sensors are 125 and 147?s, respectively. The Cu{sub 2}O nanowire-based gas sensors have a potential for applications in the environmental monitoring, chemical industry, mining industry, and several other emerging areas.

  15. Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Gasoline Vehicles | Department of Energy Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon

  16. Experimental on two sensors combination used in horizontal pipe gas-water two-phase flow

    SciTech Connect (OSTI)

    Wu, Hao; Dong, Feng

    2014-04-11

    Gas-water two phase flow phenomenon widely exists in production and living and the measurement of it is meaningful. A new type of long-waist cone flow sensor has been designed to measure two-phase mass flow rate. Six rings structure of conductance probe is used to measure volume fraction and axial velocity. The calibration of them have been made. Two sensors have been combined in horizontal pipeline experiment to measure two-phase flow mass flow rate. Several model of gas-water two-phase flow has been discussed. The calculation errors of total mass flow rate measurement is less than 5% based on the revised homogeneous flow model.

  17. MOLECULAR SPECTROSCPY AND REACTIONS OF ACTINIDES IN THE GAS PHASE AND CRYOGENIC MATRICES

    SciTech Connect (OSTI)

    Heaven, Michael C.; Gibson, John K.; Marcalo, Joaquim

    2009-02-01

    In this chapter we review the spectroscopic data for actinide molecules and the reaction dynamics for atomic and molecular actinides that have been examined in the gas phase or in inert cryogenic matrices. The motivation for this type of investigation is that physical properties and reactions can be studied in the absence of external perturbations (gas phase) or under minimally perturbing conditions (cryogenic matrices). This information can be compared directly with the results from high-level theoretical models. The interplay between experiment and theory is critically important for advancing our understanding of actinide chemistry. For example, elucidation of the role of the 5f electrons in bonding and reactivity can only be achieved through the application of experimentally verified theoretical models. Theoretical calculations for the actinides are challenging due the large numbers of electrons that must be treated explicitly and the presence of strong relativistic effects. This topic has been reviewed in depth in Chapter 17 of this series. One of the goals of the experimental work described in this chapter has been to provide benchmark data that can be used to evaluate both empirical and ab initio theoretical models. While gas-phase data are the most suitable for comparison with theoretical calculations, there are technical difficulties entailed in generating workable densities of gas-phase actinide molecules that have limited the range of species that have been characterized. Many of the compounds of interest are refractory, and problems associated with the use of high temperature vapors have complicated measurements of spectra, ionization energies, and reactions. One approach that has proved to be especially valuable in overcoming this difficulty has been the use of pulsed laser ablation to generate plumes of vapor from refractory actinide-containing materials. The vapor is entrained in an inert gas, which can be used to cool the actinide species to room temperature or below. For many spectroscopic measurements, low temperatures have been achieved by co-condensing the actinide vapor in rare gas or inert molecule host matrices. Spectra recorded in matrices are usually considered to be minimally perturbed. Trapping the products from gas-phase reactions that occur when trace quantities of reactants are added to the inert host gas has resulted in the discovery of many new actinide species. Selected aspects of the matrix isolation data were discussed in chapter 17. In the present chapter we review the spectroscopic matrix data in terms of its relationship to gas-phase measurements, and update the description of the new reaction products found in matrices to reflect the developments that have occurred during the past two years. Spectra recorded in matrix environments are usually considered to be minimally perturbed, and this expectation is borne out for many closed shell actinide molecules. However, there is growing evidence that significant perturbations can occur for open shell molecules, resulting in geometric distortions and/or electronic state reordering. Studies of actinide reactions in the gas phase provide an opportunity to probe the relationship between electronic structure and reactivity. Much of this work has focused on the reactions of ionic species, as these may be selected and controlled using various forms of mass spectrometry. As an example of the type of insight derived from reaction studies, it has been established that the reaction barriers for An+ ions are determined by the promotion energies required to achieve the 5fn6d7s configuration. Gas-phase reaction studies also provide fundamental thermodynamic properties such as bond dissociation and ionization energies. In recent years, an increased number of gas-phase ion chemistry studies of bare (atomic) and ligated (molecular) actinide ions have appeared, in which relevant contributions to fundamental actinide chemistry have been made. These studies were initiated in the 1970's and carried out in an uninterrupted way over the course of the past three d

  18. DYNAMIC MODELING STRATEGY FOR FLOW REGIME TRANSITION IN GAS-LIQUID TWO-PHASE FLOWS

    SciTech Connect (OSTI)

    X. Wang; X. Sun; H. Zhao

    2011-09-01

    In modeling gas-liquid two-phase flows, the concept of flow regime has been used to characterize the global interfacial structure of the flows. Nearly all constitutive relations that provide closures to the interfacial transfers in two-phase flow models, such as the two-fluid model, are often flow regime dependent. Currently, the determination of the flow regimes is primarily based on flow regime maps or transition criteria, which are developed for steady-state, fully-developed flows and widely applied in nuclear reactor system safety analysis codes, such as RELAP5. As two-phase flows are observed to be dynamic in nature (fully-developed two-phase flows generally do not exist in real applications), it is of importance to model the flow regime transition dynamically for more accurate predictions of two-phase flows. The present work aims to develop a dynamic modeling strategy for determining flow regimes in gas-liquid two-phase flows through the introduction of interfacial area transport equations (IATEs) within the framework of a two-fluid model. The IATE is a transport equation that models the interfacial area concentration by considering the creation and destruction of the interfacial area, such as the fluid particle (bubble or liquid droplet) disintegration, boiling and evaporation; and fluid particle coalescence and condensation, respectively. For the flow regimes beyond bubbly flows, a two-group IATE has been proposed, in which bubbles are divided into two groups based on their size and shape (which are correlated), namely small bubbles and large bubbles. A preliminary approach to dynamically identifying the flow regimes is provided, in which discriminators are based on the predicted information, such as the void fraction and interfacial area concentration of small bubble and large bubble groups. This method is expected to be applied to computer codes to improve their predictive capabilities of gas-liquid two-phase flows, in particular for the applications in which flow regime transition occurs.

  19. Luther-Emery Phase and Atomic-Density Waves in a Trapped Fermion Gas

    SciTech Connect (OSTI)

    Gao Xianlong; Rizzi, M.; Polini, Marco; Tosi, M. P.; Fazio, Rosario; Campo, V. L. Jr.; Capelle, K.

    2007-01-19

    The Luther-Emery liquid is a state of matter that is predicted to occur in one-dimensional systems of interacting fermions and is characterized by a gapless charge spectrum and a gapped spin spectrum. In this Letter we discuss a realization of the Luther-Emery phase in a trapped cold-atom gas. We study by means of the density-matrix renormalization-group technique a two-component atomic Fermi gas with attractive interactions subject to parabolic trapping inside an optical lattice. We demonstrate how this system exhibits compound phases characterized by the coexistence of spin pairing and atomic-density waves. A smooth crossover occurs with increasing magnitude of the atom-atom attraction to a state in which tightly bound spin-singlet dimers occupy the center of the trap. The existence of atomic-density waves could be detected in the elastic contribution to the light-scattering diffraction pattern.

  20. Dynamic and spectroscopic characteristics of atmospheric gliding arc in gas-liquid two-phase flow

    SciTech Connect (OSTI)

    Tu, X.; Yu, L.; Yan, J. H.; Cen, K. F.; Cheron, B. G.

    2009-11-15

    In this study, an atmospheric alternating-current gliding arc device in gas-liquid two-phase flow has been developed for the purpose of waste water degradation. The dynamic behavior of the gas-liquid gliding arc is investigated through the oscillations of electrical signals, while the spatial evolution of the arc column is analyzed by high speed photography. Different arc breakdown regimes are reported, and the restrike mode is identified as the typical fluctuation characteristic of the hybrid gliding arc in air-water mixture. Optical emission spectroscopy is employed to investigate the active species generated in the gas-liquid plasma. The axial evolution of the OH (309 nm) intensity is determined, while the rotational and vibrational temperatures of the OH are obtained by a comparison between the experimental and simulated spectra. The significant discrepancy between the rotational and translational temperatures has also been discussed.

  1. Excimer laser photolysis of group 6 metal carbonyls in the gas phase

    SciTech Connect (OSTI)

    Ishikawa, Yoichi; Brown, C.E.; Hackett, P.A.; Rayner, D.M. )

    1990-03-22

    The excimer laser photolysis of Mo(CO){sub 6} in the gas phase has been studied at 351, 308, 248, and 222 nm with laser-based, time-resolved infrared absorption spectroscopy. Results have also been obtained on the 308- and 222-nm photolysis of Cr(CO){sub 6} and on the 222-nm photolysis of W(CO){sub 6}, complementing earlier studies and presenting a complete picture of group 6 metal carbonyl ultraviolet photodecomposition.

  2. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  3. Position for determining gas-phase volatile organic compound concentrations in transuranic waste containers. Revision 2

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1998-06-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering and Environmental Laboratory (INEEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  4. Position for determining gas phase volatile organic compound concentrations in transuranic waste containers. Revision 1

    SciTech Connect (OSTI)

    Connolly, M.J.; Liekhus, K.J.; Djordjevic, S.M.; Loehr, C.A.; Spangler, L.R.

    1995-08-01

    In the conditional no-migration determination (NMD) for the test phase of the Waste Isolation Pilot Plant (WIPP), the US Environmental Protection Agency (EPA) imposed certain conditions on the US Department of Energy (DOE) regarding gas phase volatile organic compound (VOC) concentrations in the void space of transuranic (TRU) waste containers. Specifically, the EPA required the DOE to ensure that each waste container has no layer of confinement that contains flammable mixtures of gases or mixtures of gases that could become flammable when mixed with air. The EPA also required that sampling of the headspace of waste containers outside inner layers of confinement be representative of the entire void space of the container. The EPA stated that all layers of confinement in a container would have to be sampled until DOE can demonstrate to the EPA that sampling of all layers is either unnecessary or can be safely reduced. A test program was conducted at the Idaho National Engineering Laboratory (INEL) to demonstrate that the gas phase VOC concentration in the void space of each layer of confinement in vented drums can be estimated from measured drum headspace using a theoretical transport model and that sampling of each layer of confinement is unnecessary. This report summarizes the studies performed in the INEL test program and extends them for the purpose of developing a methodology for determining gas phase VOC concentrations in both vented and unvented TRU waste containers. The methodology specifies conditions under which waste drum headspace gases can be said to be representative of drum gases as a whole and describes a method for predicting drum concentrations in situations where the headspace concentration is not representative. The methodology addresses the approach for determining the drum VOC gas content for two purposes: operational period drum handling and operational period no-migration calculations.

  5. Critical point of gas-liquid type phase transition and phase equilibrium functions in developed two-component plasma model

    SciTech Connect (OSTI)

    Butlitsky, M. A.; Zelener, B. V.

    2014-07-14

    A two-component plasma model, which we called a “shelf Coulomb” model has been developed in this work. A Monte Carlo study has been undertaken to calculate equations of state, pair distribution functions, internal energies, and other thermodynamics properties. A canonical NVT ensemble with periodic boundary conditions was used. The motivation behind the model is also discussed in this work. The “shelf Coulomb” model can be compared to classical two-component (electron-proton) model where charges with zero size interact via a classical Coulomb law. With important difference for interaction of opposite charges: electrons and protons interact via the Coulomb law for large distances between particles, while interaction potential is cut off on small distances. The cut off distance is defined by an arbitrary ? parameter, which depends on system temperature. All the thermodynamics properties of the model depend on dimensionless parameters ? and ? = ?e{sup 2}n{sup 1/3} (where ? = 1/k{sub B}T, n is the particle's density, k{sub B} is the Boltzmann constant, and T is the temperature) only. In addition, it has been shown that the virial theorem works in this model. All the calculations were carried over a wide range of dimensionless ? and ? parameters in order to find the phase transition region, critical point, spinodal, and binodal lines of a model system. The system is observed to undergo a first order gas-liquid type phase transition with the critical point being in the vicinity of ?{sub crit}?13(T{sub crit}{sup *}?0.076),?{sub crit}?1.8(v{sub crit}{sup *}?0.17),P{sub crit}{sup *}?0.39, where specific volume v* = 1/?{sup 3} and reduced temperature T{sup *} = ?{sup ?1}.

  6. Enhanced Generic Phase-field Model of Irradiation Materials: Fission Gas Bubble Growth Kinetics in Polycrystalline UO2

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2012-05-30

    Experiments show that inter-granular and intra-granular gas bubbles have different growth kinetics which results in heterogeneous gas bubble microstructures in irradiated nuclear fuels. A science-based model predicting the heterogeneous microstructure evolution kinetics is desired, which enables one to study the effect of thermodynamic and kinetic properties of the system on gas bubble microstructure evolution kinetics and morphology, improve the understanding of the formation mechanisms of heterogeneous gas bubble microstructure, and provide the microstructure to macroscale approaches to study their impact on thermo-mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking. In our previous report 'Mesoscale Benchmark Demonstration, Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing', we developed a phase-field model to simulate the intra-granular gas bubble evolution in a single crystal during post-irradiation thermal annealing. In this work, we enhanced the model by incorporating thermodynamic and kinetic properties at grain boundaries, which can be obtained from atomistic simulations, to simulate fission gas bubble growth kinetics in polycrystalline UO2 fuels. The model takes into account of gas atom and vacancy diffusion, vacancy trapping and emission at defects, gas atom absorption and resolution at gas bubbles, internal pressure in gas bubbles, elastic interaction between defects and gas bubbles, and the difference of thermodynamic and kinetic properties in matrix and grain boundaries. We applied the model to simulate gas atom segregation at grain boundaries and the effect of interfacial energy and gas mobility on gas bubble morphology and growth kinetics in a bi-crystal UO2 during post-irradiation thermal annealing. The preliminary results demonstrate that the model can produce the equilibrium thermodynamic properties and the morphology of gas bubbles at grain boundaries for given grain boundary properties. More validation of the model capability in polycrystalline is underway.

  7. TRANSITION STATE FOR THE GAS-PHASE REACTION OF URANIUM HEXAFLUORIDE WITH WATER

    SciTech Connect (OSTI)

    Garrison, S; James Becnel, J

    2008-03-18

    Density Functional Theory and small-core, relativistic pseudopotentials were used to look for symmetric and asymmetric transitions states of the gas-phase hydrolysis reaction of uranium hexafluoride, UF{sub 6}, with water. At the B3LYP/6-31G(d,p)/SDD level, an asymmetric transition state leading to the formation of a uranium hydroxyl fluoride, U(OH)F{sub 5}, and hydrogen fluoride was found with an energy barrier of +77.3 kJ/mol and an enthalpy of reaction of +63.0 kJ/mol (both including zero-point energy corrections). Addition of diffuse functions to all atoms except uranium led to only minor changes in the structure and relative energies of the reacting complex and transition state. However, a significant change in the product complex structure was found, significantly reducing the enthalpy of reaction to +31.9 kJ/mol. Similar structures and values were found for PBE0 and MP2 calculations with this larger basis set, supporting the B3LYP results. No symmetric transition state leading to the direct formation of uranium oxide tetrafluoride, UOF{sub 4}, was found, indicating that the reaction under ambient conditions likely includes several more steps than the mechanisms commonly mentioned. The transition state presented here appears to be the first published transition state for the important gas-phase reaction of UF{sub 6} with water.

  8. CASCADER: An M-chain gas-phase radionuclide transport and fate model. Volume 4 -- Users guide to CASCADR9

    SciTech Connect (OSTI)

    Cawlfield, D.E.; Emer, D.F.; Lindstrom, F.T.; Shott, G.J.

    1993-09-01

    Chemicals and radionuclides move either in the gas-phase, liquid-phase, or both phases in soils. They may be acted upon by either biological or abiotic processes through advection and/or dispersion. Additionally during the transport of parent and daughter radionuclides in soil, radionuclide decay may occur. This version of CASCADER called CASCADR9 starts with the concepts presented in volumes one and three of this series. For a proper understanding of how the model works, the reader should read volume one first. Also presented in this volume is a set of realistic scenarios for buried sources of radon gas, and the input and output file structure for CASCADER9.

  9. Femtosecond pure-rotational coherent anti-stokes raman scattering gas phase diagnostics.

    SciTech Connect (OSTI)

    Kearney, Sean Patrick; Serrano, Justin Raymond

    2010-12-01

    We discuss recent experiments for the characterization of our femtosecond pure rotational CARS facility for observation of Raman transients in N{sub 2} and atmospheric air. The construction of a simplified femtosecond four-wave mixing system with only a single laser source is presented. Pure-rotational Raman transients reveal well-ordered time-domain recurrence peaks associated with the near-uniform spacing of rotational Raman peaks in the spectral domain. Long-time, 100-ps duration observations of the transient Raman polarization are presented, and the observed transients are compared to simulated results. Fourier transformation of the transients reveals two distinct sets of beat frequencies. Simulation results for temperatures from 300-700 K are used to illustrate the temperature sensitivity of the time-domain transients and their Fourier-transform counterparts. And strategies for diagnostics are briefly discussed. These results are being utilized to develop gas-phase measurement strategies for temperature and species concentration.

  10. Gas-phase study on uridine: Conformation and X-ray photofragmentation

    SciTech Connect (OSTI)

    Itälä, Eero Kooser, Kuno; Levola, Helena; Rachlew, Elisabeth; Ha, Dang Trinh; Kukk, Edwin

    2015-05-21

    Fragmentation of RNA nucleoside uridine, induced by carbon 1s core ionization, has been studied. The measurements by combined electron and ion spectroscopy have been performed in gas phase utilizing synchrotron radiation. As uridine is a combination of d-ribose and uracil, which have been studied earlier with the same method, this study also considers the effect of chemical environment and the relevant functional groups. Furthermore, since in core ionization the initial core hole is always highly localized, charge migration prior to fragmentation has been studied here. This study also demonstrates the destructive nature of core ionization as in most cases the C 1s ionization of uridine leads to concerted explosions producing only small fragments with masses ?43 amu. In addition to fragmentation patterns, we found out that upon evaporation the sugar part of the uridine molecule attains hexagonal form.

  11. The Northwest Infrared (NWIR) gas-phase spectral database of industrial and environmental chemicals: Recent updates

    SciTech Connect (OSTI)

    Brauer, Carolyn S.; Johnson, Timothy J.; Blake, Thomas A.; Sharpe, Steven W.; Sams, Robert L.; Tonkyn, Russell G.

    2014-05-22

    With continuing improvements in both standoff- and point-sensing techniques, there is an ongoing need for high-quality infrared spectral databases. The Northwest Infrared Database (NWIR) contains quantitative, gas-phase infrared spectra of nearly 500 pure chemical species that can be used for a variety of applications such as atmospheric monitoring, biomass burning studies, etc. The data, recorded at 0.1 cm-1 resolution, are pressure broadened to one atmosphere (N2) in order to mimic atmospheric conditions. Each spectrum is a composite composed of multiple individual measurements. Recent updates to the database include over 60 molecules that are known or suspected biomass-burning effluents. Examples from this set of measurements will be presented and experimental details will be discussed in the context of the utility of NWIR for environmental applications.

  12. The contribution of gas-phase reactions in the Pt-catalyzed conversion of ethane-oxygen mixtures

    SciTech Connect (OSTI)

    Huff, M.C.; Androulakis, I.P.; Sinfelt, J.H.; Reyes, S.C.

    2000-04-01

    This paper presents an analysis of the oxidative dehydrogenation of ethane on platinum-containing monoliths. The purpose of the work is to make a quantitative assessment of the extent to which homogeneous gas-phase reactions contribute to the overall conversion of the ethane. In making the analysis, extensive use is made of kinetic information obtained and compiled by A.M. Dean and associates for elementary homogeneous reaction steps and by L.D. Schmidt and associates for elementary surface reactions. A critical part of the analysis is concerned with accounting for the heat effects and for the reactor temperature gradient resulting therefrom. This is absolutely essential for meeting the objective of this investigation. The rise in temperature as the gases proceed through the reactor is responsible for a very substantial contribution of homogeneous gas-phase reactions in the chemical transformation occurring. one can view the process as a sequential one in which ethane is first oxidized on the platinum surface to CO, CO{sub 2} and H{sub 2}O in the front region of the monolith. The formation of these products causes a substantial temperature increase that drives the dehydrogenation of ethane to ethylene (and acetylene) in the gas phase. The heat required to sustain these endothermic reactions in the tail end of the reaction zone is supplied by exothermic gas-phase oxidation reactions that form additional H{sub 2}O and CO. Overall, the system can be viewed as one in which the catalyst initiates gas-phase chemistry through the acceleration of exothermic reactions at the front of the reactor which increase the downstream temperature to the point where gas-phase reactions occur readily.

  13. Method of monitoring photoactive organic molecules in-situ during gas-phase deposition of the photoactive organic molecules

    SciTech Connect (OSTI)

    Forrest, Stephen R.; Vartanian, Garen; Rolin, Cedric

    2015-06-23

    A method for in-situ monitoring of gas-phase photoactive organic molecules in real time while depositing a film of the photoactive organic molecules on a substrate in a processing chamber for depositing the film includes irradiating the gas-phase photoactive organic molecules in the processing chamber with a radiation from a radiation source in-situ while depositing the film of the one or more organic materials and measuring the intensity of the resulting photoluminescence emission from the organic material. One or more processing parameters associated with the deposition process can be determined from the photoluminescence intensity data in real time providing useful feedback on the deposition process.

  14. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively.more » We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.« less

  15. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    SciTech Connect (OSTI)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

  16. Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide

    SciTech Connect (OSTI)

    Gong, Yu; De Jong, Wibe A.; Gibson, John K.

    2015-05-13

    Activation of the oxo bond of uranyl, UO22+, was achieved by collision induced dissociation (CID) of UO2(N3)Cl2– in a quadrupole ion trap mass spectrometer. The gas phase complex UO2(N3)Cl2– was produced by electrospray ionization of solutions of UO2Cl2 and NaN3. CID of UO2(N3)Cl2– resulted in the loss of N2 to form UO(NO)Cl2–, in which the “inert” uranyl oxo bond has been activated. Formation of UO2Cl2– via N3 loss was also observed. Density functional theory computations predict that the UO(NO)Cl2– complex has nonplanar Cs symmetry and a singlet ground state. Analysis of the bonding of the UO(NO)Cl2– complex shows that the side-on bonded NO moiety can be considered as NO3–, suggesting a formal oxidation state of U(VI). Activation of the uranyl oxo bond in UO2(N3)Cl2– to form UO(NO)Cl2– and N2 was computed to be endothermic by 169 kJ/mol, which is energetically more favorable than formation of NUOCl2– and UO2Cl2–. The observation of UO2Cl2– during CID is most likely due to the absence of an energy barrier for neutral ligand loss.

  17. Mechanism of hydrogenation of ethylene via photoproduced unsaturated iron carbonyl in the gas phase

    SciTech Connect (OSTI)

    Onda, Ken; Takahashi, Makoto ); Ishikawa, Yoishi; Sugita, Kyoko; Tanaka, Kazunori; Arai, Shigeyoshi ); Rayner, D.M.; Hackett, P.A. )

    1991-01-24

    The hydrogenation of ethylene via photoproduced coordinatively unsaturated iron carbonyls in the gas phase has been investigated by measuring deuterium distribution in ethanes produced following photolysis of mixtures of Fe(CO){sub 5}, C{sub 2}H{sub 4}, and hydrogen (D{sub 2} or D{sub 2}/H{sub 2}) by monochromatic CW-UV light (ca. 250 nm). When mixtures of Fe(CO){sub 5}, C{sub 2}H{sub 4}, and D{sub 2} are photolyzed, only ethane-1,2-d{sub 2} and ethane-1,1-d{sub 2} are produced. The ratio of ethane-1,2-d{sub 2} to ethane-1,1-d{sub 2}, ranges from 1.5 to 1.9 but does not depend on the irradiation time. When a mixture containing Fe(CO){sub 5}, C{sub 2}H{sub 4}, H{sub 2}, and D{sub 2} was photolyzed, the only additional product was C{sub 2}H{sub 6}. Ethane-d{sub 1} was not observed. These results suggest that both deuterated ethanes are produced in the primary hydrogenation process and that one ethylene molecule reacts with one hydrogen molecule on the metal. Possible hydrogenation mechanisms are discussed in light of the observed results.

  18. Oxygenates from light alkanes catalyzed by NO{sub x} in the gas phase

    SciTech Connect (OSTI)

    Otsuka, Kiyoshi; Takahashi, Ryo; Yamanaka, Ichiro

    1999-07-01

    The partial oxidations of light alkanes (methane, ethane, propane, and iso-butane) catalyzed by NO{sub x} in the gas phase have been studied at a pressure of less than 1 bar. For all the alkanes tested, the addition of NO to the mixture of alkanes and O{sub 2} enhanced the selectivities and the yields of oxygenates remarkably. It was suggested that NO{sub 2} generated from NO and O{sub 2} initiated the oxidation of alkanes and would specifically accelerate the C-C bond fission, enhancing the formation of C{sub 1}-oxygenates from ethane, propane, and iso-butane. No{sub 2} and NO would be used as a homogeneous catalyst at >600 C because nitroalkanes formed were decomposed completely, releasing the NO{sub x}. The comparison of the product distributions for the decomposition and oxidation of nitroalkanes and alkylnitrites strongly suggested that the oxygenates (HCHO, CH{sub 3}CHO, and CH{sub 3}COCH{sub 3}) were formed from the corresponding alkylnitrites which must be the reaction intermediates during the oxidation of alkanes with an O{sub 2} and NO mixture.

  19. Development of a direct-injected natural gas engine system for heavy-duty vehicles: Final report phase 2

    SciTech Connect (OSTI)

    Cox, G.B.; DelVecchio, K.A.; Hays, W.J.; Hiltner, J.D.; Nagaraj, R.; Emmer, C.

    2000-03-02

    This report summarizes the results of Phase 2 of this contract. The authors completed four tasks under this phase of the subcontract. (1) They developed a computational fluid dynamics (CFD) model of a 3500 direct injected natural gas (DING) engine gas injection/combustion system and used it to identify DING ignition/combustion system improvements. The results were a 20% improvement in efficiency compared to Phase 1 testing. (2) The authors designed and procured the components for a 3126 DING engine (300 hp) and finished assembling it. During preliminary testing, the engine ran successfully at low loads for approximately 2 hours before injector tip and check failures terminated the test. The problems are solvable; however, this phase of the program was terminated. (3) They developed a Decision & Risk Analysis model to compare DING engine technology with various other engine technologies in a number of commercial applications. The model shows the most likely commercial applications for DING technology and can also be used to identify the sensitivity of variables that impact commercial viability. (4) MVE, Inc., completed a preliminary design concept study that examines the major design issues involved in making a reliable and durable 3,000 psi LNG pump. A primary concern is the life of pump seals and piston rings. Plans for the next phase of this program (Phase 3) have been put on indefinite hold. Caterpillar has decided not to fund further DING work at this time due to limited current market potential for the DING engine. However, based on results from this program, the authors believe that DI natural gas technology is viable for allowing a natural gas-fueled engine to achieve diesel power density and thermal efficiency for both the near and long terms.

  20. Underground natural gas storage reservoir management: Phase 2. Final report, June 1, 1995--March 30, 1996

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.

    1996-12-31

    Gas storage operators are facing increased and more complex responsibilities for managing storage operations under Order 636 which requires unbundling of storage from other pipeline services. Low cost methods that improve the accuracy of inventory verification are needed to optimally manage this stored natural gas. Migration of injected gas out of the storage reservoir has not been well documented by industry. The first portion of this study addressed the scope of unaccounted for gas which may have been due to migration. The volume range was estimated from available databases and reported on an aggregate basis. Information on working gas, base gas, operating capacity, injection and withdrawal volumes, current and non-current revenues, gas losses, storage field demographics and reservoir types is contained among the FERC Form 2, EIA Form 191, AGA and FERC Jurisdictional databases. The key elements of this study show that gas migration can result if reservoir limits have not been properly identified, gas migration can occur in formation with extremely low permeability (0.001 md), horizontal wellbores can reduce gas migration losses and over-pressuring (unintentionally) storage reservoirs by reinjecting working gas over a shorter time period may increase gas migration effects.

  1. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  2. Rock matrix and fracture analysis of flow in western tight gas sands: Annual report, Phase 3

    SciTech Connect (OSTI)

    Dandge, V.; Graham, M.; Gonzales, B.; Coker, D.

    1987-12-01

    Tight gas sands are a vast future source of natural gas. These sands are characterized as having very low porosity and permeability. The main resource development problem is efficiently extracting the gas from the reservoir. Future production depends on a combination of gas price and technological advances. Gas production can be enhanced by fracturing. Studies have shown that many aspects of fracture design and gas production are influenced by properties of the rock matrix. Computer models for stimulation procedures require accurate knowledge of flow properties of both the rock matrix and the fractured regions. In the proposed work, these properties will be measured along with advanced core analysis procedure aimed at understanding the relationship between pore structure and properties. The objective of this project is to develop reliable core analysis techniques for measuring the petrophysical properties of tight gas sands. Recent research has indicated that the flow conditions in the reservoir can be greatly enhanced by the presence of natural fractures, which serve as a transport path for gas from the less permeable matrix. The study is mainly concerned with the dependence of flow in tight gas matrix and healed tectonic fractures on water saturation and confining pressure. This dependency is to be related to the detailed pore structure of tight sands as typified by cores recovered in the Multi-Well experiment. 22 refs., 34 figs., 9 tabs.

  3. Performances of a bent-crystal spectrometer adapted to resonant x-ray emission measurements on gas-phase samples

    SciTech Connect (OSTI)

    Journel, Loiec; El Khoury, Lara; Marin, Thierry; Guillemin, Renaud; Carniato, Stephane; Avila, Antoine; Delaunay, Renaud; Hague, Coryn F.; Simon, Marc

    2009-09-15

    We describe a bent-crystal spectrometer adapted to measure x-ray emission resulting from core-level excitation of gas-phase molecules in the 0.8-8 keV energy range. The spectrometer is based on the Johann principle, and uses a microfocused photon beam to provide high-resolution (resolving power of {approx}7500). A gas cell was designed to hold a high-pressure (300 mbar) sample of gas while maintaining a high vacuum (10{sup -9} mbar) in the chamber. The cell was designed to optimize the counting rate (2000 cts/s at the maximum of the Cl K{alpha} emission line), while minimizing self-absorption. Example of the K{alpha} emission lines of CH{sub 3}Cl molecules is presented to illustrate the capabilities of this new instrument.

  4. CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics

    SciTech Connect (OSTI)

    Kee, R.J.; Rupley, F.M.; Meeks, E.; Miller, J.A.

    1996-05-01

    This document is the user`s manual for the third-generation CHEMKIN package. CHEMKIN is a software package whose purpose is to facilitate the formation, solution, and interpretation of problems involving elementary gas-phase chemical kinetics. It provides a flexible and powerful tool for incorporating complex chemical kinetics into simulations of fluid dynamics. The package consists of two major software components: an Interpreter and a Gas-Phase Subroutine Library. The Interpreter is a program that reads a symbolic description of an elementary, user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Gas-Phase Subroutine Library. This library is a collection of about 100 highly modular FORTRAN subroutines that may be called to return information on equations of state, thermodynamic properties, and chemical production rates. CHEMKIN-III includes capabilities for treating multi-fluid plasma systems, that are not in thermal equilibrium. These new capabilities allow researchers to describe chemistry systems that are characterized by more than one temperature, in which reactions may depend on temperatures associated with different species; i.e. reactions may be driven by collisions with electrons, ions, or charge-neutral species. These new features have been implemented in such a way as to require little or no changes to CHEMKIN implementation for systems in thermal equilibrium, where all species share the same gas temperature. CHEMKIN-III now has the capability to handle weakly ionized plasma chemistry, especially for application related to advanced semiconductor processing.

  5. DUST AND GAS IN THE MAGELLANIC CLOUDS FROM THE HERITAGE HERSCHEL KEY PROJECT. II. GAS-TO-DUST RATIO VARIATIONS ACROSS INTERSTELLAR MEDIUM PHASES

    SciTech Connect (OSTI)

    Roman-Duval, Julia; Gordon, Karl D.; Meixner, Margaret; Bot, Caroline; Bolatto, Alberto; Jameson, Katherine; Hughes, Annie; Hony, Sacha; Wong, Tony; Babler, Brian; Bernard, Jean-Philippe; Clayton, Geoffrey C.; Fukui, Yasuo; Galametz, Maud; Galliano, Frederic; Lebouteiller, Vianney; Lee, Min-Young; Israel, Frank; Li, Aigen; and others

    2014-12-20

    The spatial variations of the gas-to-dust ratio (GDR) provide constraints on the chemical evolution and lifecycle of dust in galaxies. We examine the relation between dust and gas at 10-50 pc resolution in the Large and Small Magellanic Clouds (LMC and SMC) based on Herschel far-infrared (FIR), H I 21 cm, CO, and H? observations. In the diffuse atomic interstellar medium (ISM), we derive the GDR as the slope of the dust-gas relation and find GDRs of 380{sub ?130}{sup +250} ± 3 in the LMC, and 1200{sub ?420}{sup +1600} ± 120 in the SMC, not including helium. The atomic-to-molecular transition is located at dust surface densities of 0.05 M {sub ?} pc{sup –2} in the LMC and 0.03 M {sub ?} pc{sup –2} in the SMC, corresponding to A {sub V} ? 0.4 and 0.2, respectively. We investigate the range of CO-to-H{sub 2} conversion factor to best account for all the molecular gas in the beam of the observations, and find upper limits on X {sub CO} to be 6 × 10{sup 20} cm{sup –2} K{sup –1} km{sup –1} s in the LMC (Z = 0.5 Z {sub ?}) at 15 pc resolution, and 4 × 10{sup 21} cm{sup –2} K{sup –1} km{sup –1} s in the SMC (Z = 0.2 Z {sub ?}) at 45 pc resolution. In the LMC, the slope of the dust-gas relation in the dense ISM is lower than in the diffuse ISM by a factor ?2, even after accounting for the effects of CO-dark H{sub 2} in the translucent envelopes of molecular clouds. Coagulation of dust grains and the subsequent dust emissivity increase in molecular clouds, and/or accretion of gas-phase metals onto dust grains, and the subsequent dust abundance (dust-to-gas ratio) increase in molecular clouds could explain the observations. In the SMC, variations in the dust-gas slope caused by coagulation or accretion are degenerate with the effects of CO-dark H{sub 2}. Within the expected 5-20 times Galactic X {sub CO} range, the dust-gas slope can be either constant or decrease by a factor of several across ISM phases. Further modeling and observations are required to break the degeneracy between dust grain coagulation, accretion, and CO-dark H{sub 2}. Our analysis demonstrates that obtaining robust ISM masses remains a non-trivial endeavor even in the local Universe using state-of-the-art maps of thermal dust emission.

  6. Long-Term Changes in Gas- and Particle-Phase Emissions from On...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon deer07ban-weiss.pdf More Documents & Publications Advanced Collaborative Emissions Study (ACES): Phase 2 Status Report Advanced Collaborative Emissions Study (ACES) DOE's ...

  7. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Chien-Chih Liu, J.

    1993-12-31

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of falling molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactor`s central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel. X-rays from the fusion microexplosion will ablate a thin layer of blanket material from the surfaces which face toward the fusion site. This generates a highly energetic vapor, which mostly coalesces in the central cavity. The blast expansion from the central cavity generates a shock which propagates through the segmented blanket - a complex geometry, gas-continuous two-phase medium. The impulse that the blast gives to the liquid as it vents past, the gas shock on the chamber wall, and ultimately the liquid impact on the wall are all important quantities to the HYLIFE structural designers.

  8. Excitonic splitting and coherent electronic energy transfer in the gas-phase benzoic acid dimer

    SciTech Connect (OSTI)

    Ottiger, Philipp; Leutwyler, Samuel

    2012-11-28

    The benzoic acid dimer, (BZA){sub 2}, is a paradigmatic symmetric hydrogen bonded dimer with two strong antiparallel hydrogen bonds. The excitonic S{sub 1}/S{sub 2} state splitting and coherent electronic energy transfer within supersonically cooled (BZA){sub 2} and its {sup 13}C-, d{sub 1}-, d{sub 2}-, and {sup 13}C/d{sub 1}- isotopomers have been investigated by mass-resolved two-color resonant two-photon ionization spectroscopy. The (BZA){sub 2}-(h-h) and (BZA){sub 2}-(d-d) dimers are C{sub 2h} symmetric, hence only the S{sub 2} Leftwards-Arrow S{sub 0} transition can be observed, the S{sub 1} Leftwards-Arrow S{sub 0} transition being strictly electric-dipole forbidden. A single {sup 12}C/{sup 13}C or H/D isotopic substitution reduces the symmetry of the dimer to C{sub s}, so that the isotopic heterodimers (BZA){sub 2}-{sup 13}C, (BZA){sub 2}-(h-d), (BZA){sub 2}-(h{sup 13}C-d), and (BZA){sub 2}-(h-d{sup 13}C) show both S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} bands. The S{sub 1}/S{sub 2} exciton splitting inferred is {Delta}{sub exc}= 0.94 {+-} 0.1 cm{sup -1}. This is the smallest splitting observed so far for any H-bonded gas-phase dimer. Additional isotope-dependent contributions to the splittings, {Delta}{sub iso}, arise from the change of the zero-point vibrational energy upon electronic excitation and range from {Delta}{sub iso}= 3.3 cm{sup -1} upon {sup 12}C/{sup 13}C substitution to 14.8 cm{sup -1} for carboxy H/D substitution. The degree of excitonic localization/delocalization can be sensitively measured via the relative intensities of the S{sub 1} Leftwards-Arrow S{sub 0} and S{sub 2} Leftwards-Arrow S{sub 0} origin bands; near-complete localization is observed even for a single {sup 12}C/{sup 13}C substitution. The S{sub 1}/ S{sub 2} energy gap of (BZA){sub 2} is {Delta}{sub calc}{sup exc}=11 cm{sup -1} when calculated by the approximate second-order perturbation theory (CC2) method. Upon correction for vibronic quenching, this decreases to {Delta}{sub vibron}{sup exc}=2.1 cm{sup -1} [P. Ottiger et al., J. Chem. Phys. 136, 174308 (2012)], in good agreement with the observed {Delta}{sub exc}= 0.94 cm{sup -1}. The observed excitonic splittings can be converted to exciton hopping times {tau}{sub exc}. For the (BZA){sub 2}-(h-h) homodimer {tau}{sub exc}= 18 ps, which is nearly 40 times shorter than the double proton transfer time of (BZA){sub 2} in its excited state [Kalkman et al., ChemPhysChem 9, 1788 (2008)]. Thus, the electronic energy transfer is much faster than the proton-transfer in (BZA){sub 2}{sup *}.

  9. Experimental and numerical investigation of shock wave propagation through complex geometry, gas continuous, two-phase media

    SciTech Connect (OSTI)

    Liu, J. Chien-Chih [California Univ., Berkeley, CA (United States)

    1993-10-01

    The work presented here investigates the phenomenon of shock wave propagation in gas continuous, two-phase media. The motivation for this work stems from the need to understand blast venting consequences in the HYLIFE inertial confinement fusion (ICF) reactor. The HYLIFE concept utilizes lasers or heavy ion beams to rapidly heat and compress D-T targets injected into the center of a reactor chamber. A segmented blanket of failing molten lithium or Li{sub 2}BeF{sub 4} (Flibe) jets encircles the reactors central cavity, shielding the reactor structure from radiation damage, absorbing the fusion energy, and breeding more tritium fuel.

  10. Natural gas powered rotary water chiller development. Phase 1. Final report, September 1991-June 1993

    SciTech Connect (OSTI)

    Sanborn, D.F.; Lakowske, R.L.; Byars, M.

    1993-06-01

    Objectives of the project were to evaluate performance and marketability of a rotary engine driven screw compressor for water chiller applications. Choice of a rotary engine was aimed at rotary compressor. Initial testing done with modified stock 13B rotary engine and experimental open compressor. Engine torque not sufficient for 70 ton compressor. Analysis concluded 50 ton best match for air cooled applications and 60 ton best for water cooled to get highest gas COP. Market analysis covered total water chiller market assuming relative costs of power would lead to gas cooling sales. Allowable cost premium for 3 yr payback determined for areas of country. Premium cost of 100 ton air cooled unit estimated and compared to market allowable premiums. Concluded product acceptance will be primarily in niche markets with high local electric power demand charges.

  11. Engineering research on positive displacement gas expanders. Phase I technical report

    SciTech Connect (OSTI)

    Lord, R. E.

    1984-02-01

    A research, design, and development program related to positive displacement gas expanders is reported. The objective of this program is to develop and demonstrate a more cost effective gas expander for use in those waste heat recovery systems which utilize an Organic Rankine Cycle. To provide a lower cost machine, the gas expander uses a positive displacement concept, rather than a turbine as currently used. Several positive displacement machine concepts were examined, and various performance measures have been developed for each of the concepts. The machine concepts were: single and multiple cylinder reciprocators, radial piston, roller piston, sliding vane, trochoidal, helical screw, and lobed rotor. For each of the concepts, designs were generated for machines operating with three different sets of operating conditions. These designs were then used to develop measures of efficiency and cost, and to examine other characteristics of the machines, such as development risk and ability to operate with different flow, pressure, and temperature levels. Based upon an evaluation of these characteristics, a specific concept was selected for further development. This concept is a double acting, single cylinder reciprocating machine with crossheads and ceramic liners.

  12. Significant Increase in Hydrogen Photoproduction Rates and Yields by Wild-Type Algae is Detected at High Photobioreactor Gas Phase Volume (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-07-01

    This NREL Hydrogen and Fuel Cell Technical Highlight describes how hydrogen photoproduction activity in algal cultures can be improved dramatically by increasing the gas-phase to liquid-phase volume ratio of the photobioreactor. NREL, in partnership with subcontractors from the Institute of Basic Biological Problems in Pushchino, Russia, demonstrated that the hydrogen photoproduction rate in algal cultures always decreases exponentially with increasing hydrogen partial pressure above the culture. The inhibitory effect of high hydrogen concentrations in the photobioreactor gas phase on hydrogen photoproduction by algae is significant and comparable to the effect observed with some anaerobic bacteria.

  13. CASCADER: An m-chain gas-phase radionuclide transport and fate model. Volume 2, User`s manual for CASCADR8

    SciTech Connect (OSTI)

    Cawlfield, D.E.; Been, K.B.; Emer, D.F.; Lindstrom, F.T.; Shott, G.J.

    1993-06-01

    Chemicals and radionuclides move either in the gas-phase, liquid-phase, or both phases in soils. They may be acted upon by either biological or abiotic processes through advection and/or diffusion. Furthermore, parent and daughter radionuclides may decay as they are transported in the soil. This is volume two to the CASCADER series, titled CASCADR8. It embodies the concepts presented in volume one of this series. To properly understand how the CASCADR8 model works, the reader should read volume one first. This volume presents the input and output file structure for CASCADR8, and a set of realistic scenarios for buried sources of radon gas.

  14. Phase-Contrast MRI and CFD Modeling of Apparent 3He Gas Flow in Rat Pulmonary Airways

    SciTech Connect (OSTI)

    Minard, Kevin R.; Kuprat, Andrew P.; Kabilan, Senthil; Jacob, Rick E.; Einstein, Daniel R.; Carson, James P.; Corley, Richard A.

    2012-08-01

    Phase-contrast (PC) magnetic resonance imaging (MRI) with hyperpolarized 3He is potentially useful for developing and testing patient-specific models of pulmonary airflow. One challenge, however, is that PC-MRI provides apparent values of local 3He velocity that not only depend on actual airflow but also on gas diffusion. This not only blurs laminar flow patterns in narrow airways but also introduces anomalous airflow structure that reflects gas-wall interactions. Here, both effects are predicted in a live rat using computational fluid dynamics (CFD), and for the first time, simulated patterns of apparent 3He gas velocity are compared with in-vivo PC-MRI. Results show (1) that correlations (R2) between measured and simulated airflow patterns increase from 0.23 to 0.79 simply by accounting for apparent 3He transport, and that (2) remaining differences are mainly due to uncertain airway segmentation and partial volume effects stemming from relatively coarse MRI resolution. Higher-fidelity testing of pulmonary airflow predictions should therefore be possible with future imaging improvements.

  15. Liquid phase low temperature method for production of methanol from synthesis gas and catalyst formulations therefor

    DOE Patents [OSTI]

    Mahajan, Devinder

    2005-07-26

    The invention provides a homogenous catalyst for the production of methanol from purified synthesis gas at low temperature and low pressure which includes a transition metal capable of forming transition metal complexes with coordinating ligands and an alkoxide, the catalyst dissolved in a methanol solvent system, provided the transition metal complex is not transition metal carbonyl. The coordinating ligands can be selected from the group consisting of N-donor ligands, P-donor ligands, O-donor ligands, C-donor ligands, halogens and mixtures thereof.

  16. Method and apparatus for the gas phase decontamination of chemical and biological agents

    DOE Patents [OSTI]

    O'Neill, Hugh J.; Brubaker, Kenneth L.

    2003-10-07

    An apparatus and method for decontaminating chemical and biological agents using the reactive properties of both the single atomic oxygen and the hydroxyl radical for the decontamination of chemical and biological agents. The apparatus is self contained and portable and allows for the application of gas reactants directly at the required decontamination point. The system provides for the use of ultraviolet light of a specific spectral range to photolytically break down ozone into molecular oxygen and hydroxyl radicals where some of the molecular oxygen is in the first excited state. The excited molecular oxygen will combine with water vapor to produce two hydroxyl radicals.

  17. Low-Level waste phase 1 melter testing off gas and mass balance evaluation

    SciTech Connect (OSTI)

    Wilson, C.N.

    1996-06-28

    Commercially available melter technologies were tested during 1994-95 as part of a multiphase program to test candidate technologies for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of Hanford Site tank wastes. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes were also tested. Various feed material samples, product glass samples, and process offgas streams were characterized to provide data for evaluation of process decontamination factors and material mass balances for each vitrification technology. This report describes the melter mass balance evaluations and results for six of the Phase 1 LLW melter vendor demonstration tests.

  18. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-01-01

    A cobalt Fischer-Tropsch catalyst (CO/MgO/silica) was reduced and slurried in combination with reduced Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst. Combined catalyst system was run at fixed process conditions for more than 400 hours. The system showed stable selectivity. The Cu/ZnO/Al[sub 2]0[sub 3] water-gas-shift catalyst remained reasonably active in the presence of the cobalt catalyst. Hydrocarbon selectivity of the cobalt and Cu/ZnO/Al[sub 2]0[sub 3] catalyst system compared favorably to selectivity of iron-based catalysts. Methane selectivity was slightly higher for the cobalt-based system, but C[sub 5][sup +] selectivity was essentially the same. The hydrocarbon product distribution appeared to exhibit a double-a behavior. a[sub 1] was near 0.80 which is higher than that of iron catalysts, while a[sub 2] was calculated to be 0.86 which is somewhat lower than would be typical for an iron-based catalyst.

  19. Gas-Phase Treatment of Technetium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Qafoku, Nikolla

    2014-09-01

    Technetium-99 (Tc-99) is present in the vadose zone of the Hanford Central Plateau and is a concern with respect to the protection of groundwater. The persistence, limited natural attenuation mechanisms, and geochemical behavior of Tc-99 in oxic vadose zone environments must be considered in developing effective alternatives for remediation. This report describes a new in situ geochemical manipulation technique for decreasing Tc-99 mobility using a combination of geochemical Tc-99 reduction with hydrogen sulfide gas and induced sediment mineral dissolution with ammonia vapor, which create conditions for deposition of stable precipitates that decrease the mobility of Tc-99. Laboratory experiments were conducted to examine changes in Tc-99 mobility in vadose zone sediment samples to evaluate the effectiveness of the treatment under a variety of operational and sediment conditions.

  20. Two-beam ultrabroadband coherent anti-Stokes Raman spectroscopy for high resolution gas-phase multiplex imaging

    SciTech Connect (OSTI)

    Bohlin, Alexis; Kliewer, Christopher J.

    2014-01-20

    We propose and develop a method for wideband coherent anti-Stokes Raman spectroscopy (CARS) in the gas phase and demonstrate the single-shot measurement of N{sub 2}, H{sub 2}, CO{sub 2}, O{sub 2}, and CH{sub 4}. Pure-rotational and vibrational O-, Q-, and S- branch spectra are collected simultaneously, with high spectral and spatial resolution, and within a single-laser-shot. The relative intensity of the rotational and vibrational signals can be tuned arbitrarily using polarization techniques. The ultrashort 7 fs pump and Stokes pulses are automatically overlapped temporally and spatially using a two-beam CARS technique, and the crossed probe beam allows for excellent spatial sectioning of the probed location.

  1. Gas-phase reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms

    SciTech Connect (OSTI)

    Demarais, Nicholas J.; Yang, Zhibo; Bierbaum, Veronica M. [Department of Chemistry and Biochemistry, 215 UCB, University of Colorado, Boulder, CO 80309-0215 (United States); Snow, Theodore P., E-mail: Nicholas.Demarais@Colorado.edu, E-mail: Zhibo.Yang@ou.edu, E-mail: Veronica.Bierbaum@Colorado.edu, E-mail: Theodore.Snow@Colorado.edu [Center for Astrophysics and Space Astronomy, 389 UCB, University of Colorado, Boulder, CO 80309-0389 (United States)

    2014-03-20

    We have studied the reactions of polycyclic aromatic hydrocarbon cations and their nitrogen-containing analogs with H atoms. Reaction rate constants are measured at 300 K using a flowing afterglow-selected ion flow tube. We have implemented the laser induced acoustic desorption technique to allow the study of large, non-volatile species in the gas phase. The extension of this work from previous studies shows that the reactivity of polycyclic aromatic hydrocarbon cations with H atoms reaches a constant value for large cations. There is a small difference in reactivity when comparing molecules of different size and geometry; however, no difference in reactivity was found when nitrogen was incorporated into the ring.

  2. The Effects of Oxy-firing Conditions on Gas-phase Mercury Oxidation by Chlorine and Bromine

    SciTech Connect (OSTI)

    Buitrago, Paula; Silcox, Geoffrey

    2010-06-30

    Bench-scale experiments were conducted in a quartz-lined, natural gas-fired reactor with the combustion air replaced with a blend of 27 mole percent oxygen, with the balance carbon dioxide. Quench rates of 210 and 440 K/s were tested. In the absence of sulfur dioxide, the oxy-firing environment caused a remarkable increase in oxidation of mercury by chlorine. At 400 ppm chlorine (as HCl equivalent), air-firing results in roughly 5 percent oxidation. At the same conditions with oxy-firing, oxidation levels are roughly 80 percent. Oxidation levels with bromine at 25 and 50 ppm (as HBr equivalent) ranged from 80 to 95 percent and were roughly the same for oxy- and air-firing conditions. Kinetic calculations of levels of oxidation at air- and oxy-conditions captured the essential features of the experimental results but have not revealed a mechanistic basis for the oxidative benefits of oxy-firing conditions. Mixtures of 25 ppm bromine and 100 and 400 ppm chlorine gave more than 90 percent oxidation. At all conditions, the effects of quench rate were not significant. The presence of 500 ppm SO2 caused a dramatic decline in the levels of oxidation at all oxy-fired conditions examined. This effect suggests that SO2 may be preventing oxidation in the gas phase or preventing oxidation in the wetconditioning system that was used in quantifying oxidized and elemental mercury concentrations. Similar effects of SO2 have been noted with air-firing. The addition of sodium thiosulfate to the hydroxide impingers that are part of wet conditioning systems may prevent liquid-phase oxidation from occurring.

  3. Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-11

    A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

  4. Genesis of a three-phase subsea metering system. [Oil and gas metering systems for subsea operations

    SciTech Connect (OSTI)

    Dowty, E.L.; Hatton, G.J.; Durrett, M.G. ); Dean, T.L.; Jiskoot, R.J.J.

    1993-08-01

    Periodic well flow testing is necessary to monitor well and reservoir performance over time to optimize decisions on well production rates and new well requirements through improved reservoir models, to determine the timing of well workovers, and to identify when wells become uneconomical to produce. A dedicated test separator' conventionally is used to meter individual wells. Fluids from a well are separated into the three component phases (oil, gas, and water) in a large vessel, and the flow rate of each phase is measured on the respective outlet lines from the vessel. The same method currently is used for subsea satellite developments by providing a dedicated test pipeline' from the subsea field to carry a selected well's production to a test separator for metering on the host platform. The capital cost of these systems rises rapidly with distance. Greater distances between the wellhead and flow test system increase the cost of the test pipeline and require larger and hence more expensive slug catchers and risers. Clearly, a subsea-based well-test system could result in large capital cost savings by eliminating the need for conventional test systems. This paper tracks the development of one subsea well test system from conception to field testing on the Tartan. A platform in the North Sea. This work defines the design requirements of the system, reviews system development and fabrication, describes modifications made as a result of initial field tests, and reports the results of topside tests completed through Dec. 1990.

  5. Application of gas-liquid two-phase cross-flow filtration to pilot-scale methane fermentation

    SciTech Connect (OSTI)

    Imasaka, Takuo; So, Hiroyuki; Matsushita, Kohnosuke; Furukawa, Tomoya; Kanekuni, Nobuhiko )

    1993-01-01

    As part of a national project, Aqua-Renaissance '90,' by the MITI, a pilot-scale evaluation of membrane-enhanced anaerobic fermentation, has progressed for the wastewater from a pulp and paper mill. A novel membrane filtration system was newly proposed with the aim of saving energy. That is, a gas-liquid two-phase cross-flow filtration which was generated with liquid circulation by an air-lift pump effect, was combined in the anaerobic bioreactor. It was confirmed that the membrane filtration not only offered very stable and large permeate flux, but enhanced the processing efficiency by retaining the microorganisms in the bioreactor. Furthermore, the power consumption per unit permeate volume in the membrane system of 1.78 kWh/m[sup 3] was achieved, which was a very high-performance result from the viewpoint of saving energy, as compared with 3-5 kWh/m[sup 3] of conventional liquid single-phase cross-flow filtration.

  6. Microhydrated dihydrogen phosphate clusters probed by gas phase vibrational spectroscopy and first principles calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Shou -Tian; Jiang, Ling; Liu, J. W.; Heine, Nadja; Yacovitch, Tara I.; Wende, Torsten; Asmis, Knut R.; Neumark, Daniel M.; Liu, Zhi -Feng

    2015-06-05

    We report infrared multiple photon dissociation (IRMPD) spectra of cryogenically-cooled H2PO4-(H2O)n anions (n = 2–12) in the spectral range of the stretching and bending modes of the solute anion (600–1800 cm-1). The spectra cannot be fully understood using the standard technique of comparison to harmonic spectra of minimum-energy structures; a satisfactory assignment requires considering anharmonic effects as well as entropy-driven hydrogen bond network fluctuations. Aided by finite temperature ab initio molecular dynamics simulations, the observed changes in the position, width and intensity of the IRMPD bands with cluster size are related to the sequence of microsolvation. Due to stronger hydrogenmore » bonding to the two terminal P=O groups, these are hydrated before the two P–OH groups. By n = 6, all four end groups are involved in the hydrogen bond network and by n = 12, the cluster spectra show similarities to the condensed phase spectrum of H2PO4-(aq). Our results reveal some of the microscopic details concerning the formation of the aqueous solvation environment around H2PO4-, provide ample testing grounds for the design of model solvation potentials for this biologically relevant anion, and support a new paradigm for the interpretation of IRMPD spectra of microhydrated ions.« less

  7. Microhydrated dihydrogen phosphate clusters probed by gas phase vibrational spectroscopy and first principles calculations

    SciTech Connect (OSTI)

    Sun, Shou -Tian; Jiang, Ling; Liu, J. W.; Heine, Nadja; Yacovitch, Tara I.; Wende, Torsten; Asmis, Knut R.; Neumark, Daniel M.; Liu, Zhi -Feng

    2015-06-05

    We report infrared multiple photon dissociation (IRMPD) spectra of cryogenically-cooled H2PO4-(H2O)n anions (n = 2–12) in the spectral range of the stretching and bending modes of the solute anion (600–1800 cm-1). The spectra cannot be fully understood using the standard technique of comparison to harmonic spectra of minimum-energy structures; a satisfactory assignment requires considering anharmonic effects as well as entropy-driven hydrogen bond network fluctuations. Aided by finite temperature ab initio molecular dynamics simulations, the observed changes in the position, width and intensity of the IRMPD bands with cluster size are related to the sequence of microsolvation. Due to stronger hydrogen bonding to the two terminal P=O groups, these are hydrated before the two P–OH groups. By n = 6, all four end groups are involved in the hydrogen bond network and by n = 12, the cluster spectra show similarities to the condensed phase spectrum of H2PO4-(aq). Our results reveal some of the microscopic details concerning the formation of the aqueous solvation environment around H2PO4-, provide ample testing grounds for the design of model solvation potentials for this biologically relevant anion, and support a new paradigm for the interpretation of IRMPD spectra of microhydrated ions.

  8. Potential for Microbial Stimulation in Deep Vadose Zone Sediments by Gas-Phase Nutrients

    SciTech Connect (OSTI)

    Li, S.W.; Plymale, A. E.; Brockman, F.J.

    2006-04-05

    Viable microbial populations are low, typically 10{sup 4} cells per gram, in deep vadose zones in arid climates. There is evidence that microbial distribution in these environments is patchy. In addition, infiltration or injection of nutrient-laden water has the potential to spread and drive contaminants downward to the saturated zone. For these reasons, there are uncertainties regarding the feasibility of bioremediation of recalcitrant contaminants in deep vadose zones. The objectives of this study were to investigate the occurrence of denitrifying activity and gaseous carbon-utilizing activity in arid-climate deep vadose zone sediments contaminated with, and/or affected by past exposure to, carbon tetrachloride (CT). These metabolisms are known to degrade CT and/or its breakdown product chloroform under anoxic conditions. A second objective was to determine if CT would be degraded in these sediments under unsaturated, bulk-phase aerobic incubation conditions. Both denitrifier population (determined by MPN) and microbial heterotrophic activity (measured by mineralization of 14-C labeled glucose and acetate) were relatively low and the sediments with greater in situ moisture (10-21% versus 2-7%) tended to have higher activities. When sediments were amended with gaseous nutrients (nitrous oxide and triethyl/tributyl phosphate) and gaseous C sources (a mixture of methane, ethane, propylene, propane, and butane) and incubated for 6 months, approximately 50% of the samples showed removal of one or more gaseous C sources, with butane most commonly used (44% of samples), followed by propylene (42%), propane (31%), ethane (22%), and methane (4%). Gaseous N and gaseous P did not stimulate removal of gaseous C substrates compared to no addition of N and P. CT and gaseous C sources were spiked into the sediments that removed gaseous C sources to determine if hydrocarbon-degraders have the potential to degrade CT under unsaturated conditions. In summary, gaseous C sources--particularly butane and propylene--have promise for increasing the numbers and activity of indigenous microbial populations in arid-climate deep vadose zone sediments.

  9. Near ultraviolet photochemistry of 2-bromo- and 2-iodothiophene: Revealing photoinduced ring opening in the gas phase?

    SciTech Connect (OSTI)

    Marchetti, Barbara; Karsili, Tolga N. V.; Ashfold, Michael N. R.; Kelly, Orla; Kapetanopoulos, Panos

    2015-06-14

    Velocity map imaging methods, with a new and improved ion optics design, have been used to explore the near ultraviolet photodissociation dynamics of gas phase 2-bromo- and 2-iodothiophene molecules. In both cases, the ground (X) and spin-orbit excited (X*) (where X = Br, I) atom products formed at the longest excitation wavelengths are found to recoil with fast, anisotropic velocity distributions, consistent with prompt C–X bond fission following excitation via a transition whose dipole moment is aligned parallel to the breaking bond. Upon tuning to shorter wavelengths, this fast component fades and is progressively replaced by a slower, isotropic recoil distribution. Complementary electronic structure calculations provide a plausible explanation for this switch in fragmentation behaviour—namely, the opening of a rival C–S bond extension pathway to a region of conical intersection with the ground state potential energy surface. The resulting ground state molecules are formed with more than sufficient internal energy to sample the configuration space associated with several parent isomers and to dissociate to yield X atom products in tandem with both cyclic and ring-opened partner fragments.

  10. A VUV photoionization measurement and ab-initio calculation of the ionization energy of gas phase SiO2

    SciTech Connect (OSTI)

    Kostko, Oleg; Ahmed, Musahid; Metz, Ricardo B.

    2008-12-05

    In this work we report on the detection and vacuum-ultraviolet (VUV) photoionization of gas phase SiO2 generated in situ via laser ablation of silicon in a CO2 molecular beam. The resulting species are investigated by single photon ionization with tunable VUV synchrotron radiation and mass analyzed using reflectron mass spectrometry. Photoionization efficiency (PIE) curves are recorded for SiO and SiO2 and ionization energy estimates are revealed from such measurements. A state-to-state ionizationenergy of 12.60 (+-0.05) eV is recorded by fitting two prominent peaks in the PIE curve for the following process: 1SUM O-Si-O --> 2PRODg [O-Si-O]+. Electronic structure calculations aid in the interpretation of the photoionization process and allow for identification of the symmetric stretch of 2PRODg [O-Si-O]+ which is observed in the PIE spectrum to be 0.11 eV (890 cm-1) above the ground state of the cation and agrees with the 892 cm-1 symmetric stretch frequency calculated at the CCSD(T)/aug-cc-pVTZ level.

  11. Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scott, Jill R.; Ham, Jason E.; Durham, Bill; Tremblay, Paul L.

    2004-01-01

    Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy) 3 ] 1+ trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×10 7 s −1 ,more » while the rate constant using SA was 1×10 7 s −1 . Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy) 3 ] 1+ generated using DHB can decompose to [Ru(bpy) 2 ] 1+ , whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.« less

  12. Gas phase measurements of mono-fluoro-benzoic acids and the dimer of 3-fluoro-benzoic acid

    SciTech Connect (OSTI)

    Daly, Adam M.; Carey, Spencer J.; Pejlovas, Aaron M.; Li, Kexin; Kukolich, Stephen G.; Kang, Lu

    2015-04-14

    The microwave spectrum of the mono-fluoro-benzoic acids, 2-fluoro-, 3-fluoro-, and 4-fluoro-benzoic acid have been measured in the frequency range of 4-14 GHz using a pulsed beam Fourier transform microwave spectrometer. Measured rotational transition lines were assigned and fit using a rigid rotor Hamiltonian. Assignments were made for 3 conformers of 2-fluorobenzoic acid, 2 conformers of 3-fluorobenzoic acid, and 1 conformer of 4-fluorobenzoic acid. Additionally, the gas phase homodimer of 3-fluorobenzoic acid was detected, and the spectra showed evidence of proton tunneling. Experimental rotational constants are A(0{sup +}) = 1151.8(5), B(0{sup +}) = 100.3(5), C(0{sup +}) = 87.64(3) MHz and A(0{sup ?}) = 1152.2(5), B(0{sup ?}) = 100.7(5), C(0{sup ?}) = 88.85(3) MHz for the two ground vibrational states split by the proton tunneling motion. The tunneling splitting (?E) is approximately 560 MHz. This homodimer appears to be the largest carboxylic acid dimer observed with F-T microwave spectroscopy.

  13. Gas-Phase Reactions of Doubly Charged Lanthanide Cations with Alkanes and Alkenes. Trends in Metal(2+) Reactivity

    SciTech Connect (OSTI)

    Gibson, John K.; Marcalo, Joaquim; Santos, Marta; Pires de Matos, Antonio; Haire, Richard G.

    2008-12-08

    The gas-phase reactivity of doubly-charged lanthanide cations, Ln2+ (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu), with alkanes (methane, ethane, propane, n-butane) and alkenes (ethene, propene, 1-butene) was studied by Fourier transform ion cyclotron resonance mass spectrometry. The reaction products consisted of different combinations of doubly-charged organometallic ions?adducts or species formed via metal-ion-induced hydrogen, dihydrogen, alkyl, or alkane eliminations from the hydrocarbons?and singly-charged ions that resulted from electron, hydride, or methide transfers from the hydrocarbons to the metal ions. The only lanthanide cations capable of activating the hydrocarbons to form doubly-charged organometallic ions were La2+, Ce2+, Gd2+, and Tb2+, which have ground-state or low-lying d1 electronic configurations. Lu2+, with an accessible d1 electronic configuration but a rather high electron affinity, reacted only through transfer channels. The remaining Ln2+ reacted via transfer channels or adduct formation. The different accessibilities of d1 electronic configurations and the range of electron affinities of the Ln2+ cations allowed for a detailed analysis of the trends for metal(2+) reactivity and the conditions for occurrence of bond activation, adduct formation, and electron, hydride, and methide transfers.

  14. Implementation and evaluation of online gas-phase chemistry within a regional climate model (RegCM-CHEM4)

    SciTech Connect (OSTI)

    Shalaby, A. K.; Zakey, A. S.; Tawfik, A. B.; Solmon, F.; Giorgi, Filippo; Stordal, F.; Sillman, S.; Zaveri, Rahul A.; Steiner, A. L.

    2012-05-22

    The RegCM-CHEM4 is a new online climate-chemistry model based on the International Centre for Theoretical Physics (ICTP) regional climate model (RegCM4). Tropospheric gas-phase chemistry is integrated into the climate model using the condensed version of the Carbon Bond Mechanism (CBM-Z; Zaveri and Peters, 1999) with a fast solver based on radical balances. We evaluate the model over Continental Europe for two different time scales: (1) an event-based analysis of the ozone episode associated with the heat wave of August 2003 and (2) a climatological analysis of a sixyear simulation (2000-2005). For the episode analysis, model simulations show good agreement with European Monitoring and Evaluation Program (EMEP) observations of hourly ozone over different regions in Europe and capture ozone concentrations during and after the August 2003 heat wave event. For long-term climate simulations, the model captures the seasonal cycle of ozone concentrations with some over prediction of ozone concentrations in non-heat wave summers. Overall, the ozone and ozone precursor evaluation shows the feasibility of using RegCM-CHEM4 for decadal-length simulations of chemistry-climate interactions.

  15. Phase-field simulations of intragranular fission gas bubble evolution in UO2 under post-irradiation thermal annealing

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2013-05-15

    Fission gas bubble is one of evolving microstructures, which affect thermal mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking, in operating nuclear fuels. Therefore, fundamental understanding of gas bubble evolution kinetics is essential to predict the thermodynamic property and performance changes of fuels. In this work, a generic phasefield model was developed to describe the evolution kinetics of intra-granular fission gas bubbles in UO2 fuels under post-irradiation thermal annealing conditions. Free energy functional and model parameters are evaluated from atomistic simulations and experiments. Critical nuclei size of the gas bubble and gas bubble evolution were simulated. A linear relationship between logarithmic bubble number density and logarithmic mean bubble diameter is predicted which is in a good agreement with experimental data.

  16. Cliffs Minerals, Inc. Eastern Gas Shales Project, Ohio No. 5 well - Lorain County. Phase II report. Preliminary laboratory results

    SciTech Connect (OSTI)

    1980-04-01

    The US Department of Energy is funding a research and development program entitled the Eastern Gas Shales Project designed to increase commercial production of natural gas in the eastern United States from Middle and Upper Devonian Shales. The program's objectives are as follows: (1) to evaluate recoverable reserves of gas contained in the shales; (2) to enhanced recovery technology for production from shale gas reservoirs; and (3) to stimulate interest among commercial gas suppliers in the concept of producing large quantities of gas from low-yield, shallow Devonian Shale wells. The EGSP-Ohio No. 5 well was cored under a cooperative cost-sharing agreement between the Department of Energy (METC) and Columbia Gas Transmission Corporation. Detailed characterization of the core was performed at the Eastern Gas Shale Project's Core Laboratory. At the well site, suites of wet and dry hole geophysical logs were run. Characterization work performed at the Laboratory included photographic logs, lithologic logs, fracture logs, measurements of core color variation, and stratigraphic interpretation of the cored intervals. In addition samples were tested for physical properties by Michigan Technological University. Physical properties data obtained were for: directional ultrasonic velocity; directional tensile strength; strength in point load; and trends of microfractures.

  17. Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL) [Pinson, AL; Felix, Larry Gordon (Pelham, AL) [Pelham, AL; Snyder, Todd Robert (Birmingham, AL) [Birmingham, AL

    2008-02-12

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  18. Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl (Pinson, AL); Felix, Larry Gordon (Pelham, AL); Snyder, Todd Robert (Birmingham, AL)

    2009-12-15

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  19. LANDFILL GAS CONVERSION TO LNG AND LCO{sub 2}. PHASE 1, FINAL REPORT FOR THE PERIOD MARCH 1998-FEBRUARY 1999

    SciTech Connect (OSTI)

    COOK,W.J.; NEYMAN,M.; SIWAJEK,L.A.; BROWN,W.R.; VAN HAUWAERT,P.M.; CURREN,E.D.

    1998-02-25

    Process designs and economics were developed to produce LNG and liquid carbon dioxide (CO{sub 2}) from landfill gas (LFG) using the Acrion CO{sub 2} wash process. The patented Acrion CO{sub 2} wash process uses liquid CO{sub 2} to absorb contaminants from the LFG. The process steps are compression, drying, CO{sub 2} wash contaminant removal and CO{sub 2} recovery, residual CO{sub 2} removal and methane liquefaction. Three flowsheets were developed using different residual CO{sub 2} removal schemes. These included physical solvent absorption (methanol), membranes and molecular sieves. The capital and operating costs of the flowsheets were very similar. The LNG production cost was around ten cents per gallon. In parallel with process flowsheet development, the business aspects of an eventual commercial project have been explored. The process was found to have significant potential commercial application. The business plan effort investigated the economics of LNG transportation, fueling, vehicle conversion, and markets. The commercial value of liquid CO{sub 2} was also investigated. This Phase 1 work, March 1998 through February 1999, was funded under Brookhaven National laboratory contract 725089 under the research program entitled ``Liquefied Natural Gas as a Heavy Vehicle Fuel.'' The Phase 2 effort will develop flowsheets for the following: (1) CO{sub 2} and pipeline gas production, with the pipeline methane being liquefied at a peak shaving site, (2) sewage digester gas as an alternate feedstock to LFG and (3) the use of mixed refrigerants for process cooling. Phase 2 will also study the modification of Acrion's process demonstration unit for the production of LNG and a market site for LNG production.

  20. Cliffs Minerals, Inc. Eastern Gas Shales Project, Ohio No. 6 series: Gallia County. Phase II report. Preliminary laboratory results

    SciTech Connect (OSTI)

    1980-06-01

    The US Department of Energy is funding a research and development program entitled the Eastern Gas Shales Project designed to increase commercial production of natural gas in the eastern United States from Middle and Upper Devonian Shales. On September 28, 1978 the Department of Energy entered into a cooperative agreement with Mitchell Energy Corporation to explore Devonian shale gas potential in Gallia County, Ohio. Objectives of the cost-sharing contract were the following: (1) to select locations for a series of five wells to be drilled around the periphery of a possible gas reservoir in Gallia County, Ohio; (2) to drill, core, log, case, fracture, clean up, and test each well, and to monitor production from the wells for a five-year period. This report summarizes the procedures and results of core characterization work performed at the Eastern Gas Shales Project Core Laboratory on core retrieved from the Gallia County EGSP wells, designated OH No. 6/1, OH No. 6/2, OH No. 6/3, OH No. 6/4, and OH No. 6/5. Characterization work performed includes photographic logs, fracture logs, measurements of core color variation, and stratigraphic interpretation of the cored intervals. In addition the following tests were performed by Michigan Technological University to obtain the following data: directional ultrasonic velocity; directional tensile strength, strength in point load; trends of microfractures; and hydraulic fracturing characteristics.

  1. Flowing afterglow measurements of the density dependence of gas-phase ion-ion mutual neutralization reactions

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Viggiano, Albert A.; Johnsen, Rainer

    2013-05-28

    We have studied the dependence of several ion-ion mutual neutralization (MN) reactions on helium density in the range from 1.6 Multiplication-Sign 10{sup 16} to 1.5 Multiplication-Sign 10{sup 17} cm{sup -3} at 300 K, using the Variable Electron and Neutral Density Attachment Mass Spectrometry method. The rate coefficients of the reactions Ar{sup +}+ Br{sub 2}{sup -}, Ar{sup +}+ SF{sub 6}{sup -}, and Ar{sup +}+ C{sub 7}F{sub 14}{sup -} were found to be independent of gas density over the range studied, in disagreement with earlier observations that similar MN reactions are strongly enhanced at the same gas densities. The cause of the previous enhancement with density is traced to the use of 'orbital-motion-limit' theory to infer ion densities from the currents collected by ion-attracting Langmuir probes in a region where it is not applicable.

  2. Search for particle emission from a gas-loaded deuterium-palladium system in the alpha-beta phase

    SciTech Connect (OSTI)

    Nicholson, J.P.

    1996-12-01

    Neutron and proton emission due to possible solid state fusion events is monitored from a palladium sample loaded with deuterium gas to atomic fractions up to 0.7. Most of the experimental runs show no detectable activity above background rates, indicating a fusion rate <2.7x10{sup -22} s{sup -1}/deuterium-deuterium (D-D) pair. Two brief excursions by the proton counter might indicate a temporary rate of 3.5x10{sup -21} s{sup -1}/D-D pair. 25 refs., 1 fig.

  3. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of the CO{sub 2} in the original process as converted to methane. The process could under another option avoid emissions following the conversion to SNG through an adjunct algae conversion process. The algae would then be converted to fuels or other products. An additional application of the algae process at the end use natural gas fired plant could further reduce emissions. The APS team fully recognizes the competition facing the process from natural gas and imported liquid natural gas. While we expect those resources to set the price for methane in the near-term, the team's work to date indicates that the AHP process can be commercially competitive, with the added benefit of assuring long-term energy supplies from North American resources. Conversion of coal to a more readily transportable fuel that can be employed near load centers with an overall reduction of greenhouses gases is edging closer to reality.

  4. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  5. Identification of Explosives from Porous Materials: Applications Using Reverse Phase High Performance Liquid Chromatography and Gas Chromatography

    SciTech Connect (OSTI)

    C.J. Miller; G. Elias; N.C. Schmitt; C. Rae

    2010-06-01

    High performance liquid chromatography and gas chromatography techniques are well documented and widely used for the detection of trace explosives from organic solvents. These techniques were modified to specifically identify and quantify explosives extracted from various materials taken from people who had recently handled explosives. Documented techniques were modified to specifically detect and quantify RDX, TNT, and PETN from denim, colored flannel, vinyl, and canvas extracted in methanol using no sample cleanup prior to analysis. The methanol extracts were injected directly into several different column types and analyzed by HPLC-UV and/or GC-ECD. This paper describes general screening methods that were used to determine the presence of explosives in unknown samples and techniques that have been optimized for quantification of each explosive from the substrate extracts.

  6. An innovative catalyst system for slurry-phase Fischer-Tropsch synthesis: Cobalt plus a water-gas-shift catalyst

    SciTech Connect (OSTI)

    Satterfield, C.N.; Yates, I.C.; Chanenchuk, C.

    1991-07-01

    The feasibility of using a mechanical mixture of a Co/MgO/SiO{sub 2} Fischer-Tropsch catalyst and a Cu-ZnO/Al{sub 2}O{sub 3} water-gas-shift (WGS) catalyst for hydrocarbon synthesis in a slurry reactor has been established. Such a mixture can combine the superior product distribution from cobalt with the high activity for the WGS reaction characteristic of iron. Weight ratios of Co/MgO/SiO{sub 2} to Cu-ZnO/Al{sub 2}O{sub 3} of 0.27 and 0.51 for the two catalysts were studied at 240{degrees}C, 0.79 MPa, and in situ H{sub 2}/CO ratios between 0.8 and 3.0. Each catalyst mixture showed stable Fischer-Tropsch activity for about 400 hours-on-stream at a level comparable to the cobalt catalyst operating alone. The Cu-ZnO/Al{sub 2}O{sub 3} catalyst exhibited a very slow loss of activity under these conditions, but when operated alone it was stable in a slurry reactor at 200--220{degrees}C, 0.79--1.48 MPa, and H{sub 2}/CO in situ ratios between 1.0 and 2.0. The presence of the water-gas-shift catalyst did not affect the long-term stability of the primary Fischer-Tropsch selectivity, but did increase the extent of secondary reactions, such as l-alkene hydrogenation and isomerization.

  7. Application of Two Phase (Liquid/Gas) Xenon Gamma-Camera for the Detection of Special Nuclear Material and PET Medical Imaging

    SciTech Connect (OSTI)

    McKinsey, Daniel Nicholas

    2013-08-27

    The McKinsey group at Yale has been awarded a grant from DTRA for the building of a Liquid Xenon Gamma Ray Color Camera (LXe-GRCC), which combines state-of-the-art detection of LXe scintillation light and time projection chamber (TPC) charge readout. The DTRA application requires a movable detector and hence only a single phase (liquid) xenon detector can be considered in this case. We propose to extend the DTRA project to applications that allow a two phase (liquid/gas) xenon TPC. This entails additional (yet minimal) hardware and extension of the research effort funded by DTRA. The two phase detector will have better energy and angular resolution. Such detectors will be useful for PET medical imaging and detection of special nuclear material in stationary applications (e.g. port of entry). The expertise of the UConn group in gas phase TPCs will enhance the capabilities of the Yale group and the synergy between the two groups will be very beneficial for this research project as well as the education and research projects of the two universities. The LXe technology to be used in this project has matured rapidly over the past few years, developed for use in detectors for nuclear physics and astrophysics. This technology may now be applied in a straightforward way to the imaging of gamma rays. According to detailed Monte Carlo simulations recently performed at Yale University, energy resolution of 1% and angular resolution of 3 degrees may be obtained for 1.0 MeV gamma rays, using existing technology. With further research and development, energy resolution of 0.5% and angular resolution of 1.3 degrees will be possible at 1.0 MeV. Because liquid xenon is a high density, high Z material, it is highly efficient for scattering and capturing gamma rays. In addition, this technology scales elegantly to large detector areas, with several square meter apertures possible. The Yale research group is highly experienced in the development and use of noble liquid detectors for astrophysics, most recently in the XENON10 experiment. The existing facilities at Yale are fully adequate for the completion of this project. The facilities of the UConn group at the LNS at Avery Point include a (clean) lab for detector development and this group recently delivered an Optical Readout TPC (O-TPC) for research in Nuclear Astrophysics at the TUNL in Duke University. The machine shop at UConn will be used (free of charge) for producing the extra hardware needed for this project including grids and frames.

  8. Fluorohydrogenate Cluster Ions in the Gas Phase: Electrospray Ionization Mass Spectrometry of the [1-Ethyl-3-methylimidazolium+][F(HF)2.3–] Ionic Liquid

    SciTech Connect (OSTI)

    Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

    2013-12-01

    Electrospray ionization of the fluorohydrogenate ionic liquid [1-ethyl-3-methylimidazolium][F(HF)2.3] ionic liquid was conducted to understand the nature of the anionic species as they exist in the gas phase. Abundant fluorohydrogenate clusters were produced; however, the dominant anion in the clusters was [FHF-], and not the fluoride-bound HF dimers or trimers that are seen in solution. Density functional theory (DFT) calculations suggest that HF molecules are bound to the clusters by about 30 kcal/mol. The DFT-calculated structures of the [FHF-]-bearing clusters show that the favored interactions of the anions are with the methynic and acetylenic hydrogen atoms on the imidazolium cation, forming planar structures similar to those observed in the solid state. A second series of abundant negative ions was also formed that contained [SiF5-] together with the imidazolium cation and the fluorohydrogenate anions that originate from reaction of the spray solution with silicate surfaces.

  9. Dynamic density functional theory with hydrodynamic interactions: Theoretical development and application in the study of phase separation in gas-liquid systems

    SciTech Connect (OSTI)

    Kikkinides, E. S.; Monson, P. A.

    2015-03-07

    Building on recent developments in dynamic density functional theory, we have developed a version of the theory that includes hydrodynamic interactions. This is achieved by combining the continuity and momentum equations eliminating velocity fields, so the resulting model equation contains only terms related to the fluid density and its time and spatial derivatives. The new model satisfies simultaneously continuity and momentum equations under the assumptions of constant dynamic or kinematic viscosity and small velocities and/or density gradients. We present applications of the theory to spinodal decomposition of subcritical temperatures for one-dimensional and three-dimensional density perturbations for both a van der Waals fluid and for a lattice gas model in mean field theory. In the latter case, the theory provides a hydrodynamic extension to the recently studied dynamic mean field theory. We find that the theory correctly describes the transition from diffusive phase separation at short times to hydrodynamic behaviour at long times.

  10. Effect of resistivity profile on current decay time of initial phase of current quench in neon-gas-puff inducing disruptions of JT-60U

    SciTech Connect (OSTI)

    Kawakami, S.; Ohno, N.; Shibata, Y.; Isayama, A.; Kawano, Y.; Watanabe, K. Y.; National Institute for Fusion Science, Toki 509-5292 ; Takizuka, T.; Okamoto, M.

    2013-11-15

    According to an early work [Y. Shibata et al., Nucl. Fusion 50, 025015 (2010)] on the behavior of the plasma current decay in the JT-60U disruptive discharges caused by the radiative collapse with a massive neon-gas-puff, the increase of the internal inductance mainly determined the current decay time of plasma current during the initial phase of current quench. To investigate what determines the increase of the internal inductance, we focus attention on the relationship between the electron temperature (or the resistivity) profile and the time evolution of the current density profile and carry out numerical calculations. As a result, we find the reason of the increase of the internal inductance: The current density profile at the start of the current quench is broader than an expected current density profile in the steady state, which is determined by the temperature (or resistivity) profile. The current density profile evolves into peaked one and the internal inductance is increasing.

  11. ENHANCED GROWTH RATE AND SILANE UTILIZATION IN AMORPHOUS SILICON AND NANOCRYSTALLINE-SILICON SOLAR CELL DEPOSITION VIA GAS PHASE ADDITIVES

    SciTech Connect (OSTI)

    Ridgeway, R.G.; Hegedus, S.S.; Podraza, N.J.

    2012-08-31

    Air Products set out to investigate the impact of additives on the deposition rate of both ���µCSi and ���±Si-H films. One criterion for additives was that they could be used in conventional PECVD processing, which would require sufficient vapor pressure to deliver material to the process chamber at the required flow rates. The flow rate required would depend on the size of the substrate onto which silicon films were being deposited, potentially ranging from 200 mm diameter wafers to the 5.7 m2 glass substrates used in GEN 8.5 flat-panel display tools. In choosing higher-order silanes, both disilane and trisilane had sufficient vapor pressure to withdraw gas at the required flow rates of up to 120 sccm. This report presents results obtained from testing at Air Products�¢���� electronic technology laboratories, located in Allentown, PA, which focused on developing processes on a commercial IC reactor using silane and mixtures of silane plus additives. These processes were deployed to compare deposition rates and film properties with and without additives, with a goal of maximizing the deposition rate while maintaining or improving film properties.

  12. Rapid, reversible, solid–gas and solution-phase insertion of CO2 into In–P bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore » 2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(μ-Cl)[μ-(i-Pr2P)2N)].« less

  13. Rapid, Reversible, Solid–Gas and Solution-Phase Insertion of CO 2 into In–P Bonds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less thanmore »2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(?-Cl)[?-(i-Pr2P)2N)].« less

  14. Rapid, Reversible, Solid–Gas and Solution-Phase Insertion of CO 2 into In–P Bonds

    SciTech Connect (OSTI)

    Dickie, Diane A.; Barker, Madeline T.; Land, Michael A.; Hughes, Kira E.; Clyburne, Jason A. C.; Kemp, Richard A.

    2015-11-17

    The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with 2 equiv of (i-Pr2P)2NLi in Et2O/tetrahydrofuran solution. Samples of [(i-Pr2P)2N]2InCl in a pentane slurry, a CH2Cl2 solution, or in the solid state were exposed to CO2, resulting in the insertion of CO2 into two of the four M–P bonds to produce [O2CP(i-Pr2)NP(i-Pr2)]2InCl in each case. These compounds were characterized by multinuclear NMR and IR spectroscopy, as well as single-crystal X-ray diffraction. ReactIR solution studies show that the reaction is complete in less than 1 min at room temperature in solution and in less than 2 h in the solid–gas reaction. The CO2 complex is stable up to at least 60 °C under vacuum, but the starting material is regenerated with concomitant loss of carbon dioxide upon heating above 75 °C. Furthermore, the compound [(i-Pr2P)2N]2InCl also reacts with CS2 to give a complicated mixture of products, one of which was identified as the CS2 cleavage product [S=P(i-Pr2)NP(i-Pr2)]2InCl]2(?-Cl)[?-(i-Pr2P)2N)].

  15. Stereochemical effects in the gas-phase pinacol rearrangement. 2. Ring contraction versus methyl migration in cis- and trans-1,2-dimethylcyclohexane-1,2-diol

    SciTech Connect (OSTI)

    de Petris, G.; Giacomello, P.; Pizzabiocca, A.; Renzi, G.; Speranza, M.

    1988-02-17

    The gas-phase pinacol rearrangement of cis- and trans-1,2-dimethylcyclohexane-1,2-diols, promoted by D/sub 3//sup +/, CH/sub 5//sup +//C/sub 2/H/sub 5//sup +/ and t-C/sub 4/H/sub 9//sup +/ ions, was studied by mass spectrometric and radiolytic methods in the pressure range 0.5-760 Torr. When product isomerization is inhibited, by using N(CH/sub 3/)/sub 3/ as a trapping reagent at high pressure, mixtures of 2,2-dimethylcyclohexanone and 1-acetyl-1-methylcyclopentane were recovered from the reaction. In methane, the trend of the measured relative rates for ring contraction (k/sub 5/), methyl or hydroxyl group migration (k/sub 6/) versus the rearrangement rate of pincaol itself (k/sub p/), is k/sub 6/(trans) approx. k/sub 5/(trans) greater than or equal to k/sub 5/(cis) > k/sub 6/(cis) greater than or equal to k/sub p/. No evidence for the formation of an intermediate carbenium ion was found. Stereochemical aspects of the mechanism are discussed and compared with solution data.

  16. SURFACE CHEMKIN-III: A Fortran package for analyzing heterogeneous chemical kinetics at a solid-surface - gas-phase interface

    SciTech Connect (OSTI)

    Coltrin, M.E.; Kee, R.J.; Rupley, F.M.; Meeks, E.

    1996-05-01

    This document is the user`s manual for the SURFACE CHEMKIN-III package. Together with CHEMKIN-III, this software facilitates the formation, solution, and interpretation of problems involving elementary heterogeneous and gas-phase chemical kinetics in the presence of a solid surface. The package consists of two major software components: an Interpreter and a Surface Subroutine Library. The Interpreter is a program that reads a symbolic description of a user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Surface Subroutine Library, which is a collection of about seventy modular Fortran subroutines that may be called from a user`s application code to return information on chemical production rates and thermodynamic properties. This version of SURFACE CHEMKIN-III includes many modifications to allow treatment of multi-fluid plasma systems, for example modeling the reactions of highly energetic ionic species with a surface. Optional rate expressions allow reaction rates to depend upon ion energy rather than a single thermodynamic temperature. In addition, subroutines treat temperature as an array, allowing an application code to define a different temperature for each species. This version of SURFACE CHEMKIN-III allows use of real (non-integer) stoichiometric coefficients; the reaction order with respect to species concentrations can also be specified independent of the reaction`s stoichiometric coefficients. Several different reaction mechanisms can be specified in the Interpreter input file through the new construct of multiple materials.

  17. Environmental, Health and Safety Assessment: ATS 7H Program (Phase 3R) Test Activities at the GE Power Systems Gas Turbine Manufacturing Facility, Greenville, SC

    SciTech Connect (OSTI)

    1998-11-17

    International Technology Corporation (IT) was contracted by General Electric Company (GE) to assist in the preparation of an Environmental, Health and Safety (HI&3) assessment of the implementation of Phase 3R of the Advanced Turbine System (ATS) 7H program at the GE Gas Turbines facility located in Greenville, South Carolina. The assessment was prepared in accordance with GE's contractual agreement with the U.S. Department of Energy (GE/DOE Cooperative Agreement DE-FC21-95MC3 1176) and supports compliance with the requirements of the National Environmental Policy Act of 1970. This report provides a summary of the EH&S review and includes the following: General description of current site operations and EH&S status, Description of proposed ATS 7H-related activities and discussion of the resulting environmental, health, safety and other impacts to the site and surrounding area. Listing of permits and/or licenses required to comply with federal, state and local regulations for proposed 7H-related activities. Assessment of adequacy of current and required permits, licenses, programs and/or plans.

  18. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  19. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M. (Antioch, CA)

    1996-01-01

    A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

  20. Scale-Up Information for Gas-Phase Ammonia Treatment of Uranium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Thomle, Jonathan N.; Johnson, Timothy C.

    2014-09-01

    Uranium is present in the vadose zone at the Hanford Central Plateau and is of concern for protection of groundwater. The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau identified gas-phase treatment and geochemical manipulation as potentially effective treatment approaches for uranium and technetium in the Hanford Central Plateau vadose zone. Based on laboratory evaluation, use of ammonia vapor was selected as the most promising uranium treatment candidate for further development and field testing. While laboratory tests have shown that ammonia treatment effectively reduces the mobility of uranium, additional information is needed to enable deployment of this technology for remediation. Of importance for field applications are aspects of the technology associated with effective distribution of ammonia to a targeted treatment zone, understanding the fate of injected ammonia and its impact on subsurface conditions, and identifying effective monitoring approaches. In addition, information is needed to select equipment and operational parameters for a field design. As part of development efforts for the ammonia technology for remediation of vadose zone uranium contamination, field scale-up issues were identified and have been addressed through a series of laboratory and modeling efforts. This report presents a conceptual description for field application of the ammonia treatment process, engineering calculations to support treatment design, ammonia transport information, field application monitoring approaches, and a discussion of processes affecting the fate of ammonia in the subsurface. The report compiles this information from previous publications and from recent research and development activities. The intent of this report is to provide technical information about these scale-up elements to support the design and operation of a field test for the ammonia treatment technology.

  1. Excimer laser photolysis of V(CO)/sub 6/: time-resolved infrared studies of gas-phase V(CO)/sub x/ (x = 5-2)

    SciTech Connect (OSTI)

    Ishikawa, Y.; Hackett, P.A.; Rayner, D.M.

    1987-10-28

    The photolysis of gas-phase vanadium hexacarbonyl V(CO)/sub 6/, has been studied at excimer laser wavelengths (351, 308, 248, and 193 nm) by observing the coordinatively unsaturated transient products, V(CO)/sub x/ (x = 5-3 and possibly 2), via time-resolved infrared kinetic absorption spectroscopy. The dependence of the initial fragment distribution on photolysis wavelength is consistent with the model of sequential CO elimination established by similar studies on Fe(CO)/sub 5/, Cr(CO)/sub 6/, and Co(CO)/sub 3/NO. The high reactivity of unsaturated metal carbonyl species with saturated carbonyls to form binuclear complexes is again observed, with rate constants for the reaction of V(CO)/sub 3/ and V(CO)/sub 4/ with V(CO)/sub 6/ found to be of the order 3 x 10/sup -10/ cm/sup 3/ molecule/sup -1/ s/sup -1/. Infrared assignments for V(CO)/sub x/ are supported by kinetic measurements in the presence of added CO. Rate constants for the reaction of CO with V(CO)/sub 3/, V(CO)/sub 4/, and V(CO)/sub 5/ are found as (0.4 +/- 0.1) x 10/sup -10/, (0.5 +/- 0.1) x 10/sup -10/, and (0.5 +/- 0.1) x 10/sup -10/ cm/sup 3/ molecule/sup -1/ s/sup -1/, respectively, leading to the expectation that ground-state V(CO)/sub 3-5/ share the doublet character of V(CO)/sub 6/. The infrared assignments are in disagreement with infrared absorption and some ESR studies of V(CO)/sub x/ fragments in low-temperature matrices.

  2. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  3. Towards bio-silicon interfaces: Formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan deposited in high vacuum from the gas-phase

    SciTech Connect (OSTI)

    Retamal, María J. Cisternas, Marcelo A.; Seifert, Birger; Volkmann, Ulrich G.; Gutierrez-Maldonado, Sebastian E.; Perez-Acle, Tomas; Busch, Mark; Huber, Patrick

    2014-09-14

    The recent combination of nanoscale developments with biological molecules for biotechnological research has opened a wide field related to the area of biosensors. In the last years, device manufacturing for medical applications adapted the so-called bottom-up approach, from nanostructures to larger devices. Preparation and characterization of artificial biological membranes is a necessary step for the formation of nano-devices or sensors. In this paper, we describe the formation and characterization of a phospholipid bilayer (dipalmitoylphosphatidylcholine, DPPC) on a mattress of a polysaccharide (Chitosan) that keeps the membrane hydrated. The deposition of Chitosan (?25 Å) and DPPC (?60 Å) was performed from the gas phase in high vacuum onto a substrate of Si(100) covered with its native oxide layer. The layer thickness was controlled in situ using Very High Resolution Ellipsometry (VHRE). Raman spectroscopy studies show that neither Chitosan nor DPPC molecules decompose during evaporation. With VHRE and Atomic Force Microscopy we have been able to detect phase transitions in the membrane. The presence of the Chitosan interlayer as a water reservoir is essential for both DPPC bilayer formation and stability, favoring the appearance of phase transitions. Our experiments show that the proposed sample preparation from the gas phase is reproducible and provides a natural environment for the DPPC bilayer. In future work, different Chitosan thicknesses should be studied to achieve a complete and homogeneous interlayer.

  4. Landfill Gas Conversion to LNG and LCO{sub 2}. Phase II Final Report for January 25, 1999 - April 30, 2000

    SciTech Connect (OSTI)

    Brown, W. R.; Cook, W. J.; Siwajek, L. A.

    2000-10-20

    This report summarizes work on the development of a process to produce LNG (liquefied methane) for heavy vehicle use from landfill gas (LFG) using Acrion's CO{sub 2} wash process for contaminant removal and CO{sub 2} recovery.

  5. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  6. Photo-induced isomerization of ethylene-bridged azobenzene explored by ab initio based non-adiabatic dynamics simulation: A comparative investigation of the isomerization in the gas and solution phases

    SciTech Connect (OSTI)

    Cao Jun; Liu Lihong; Fang Weihai; Xie Zhizhong; Zhang Yong

    2013-04-07

    Azobenzene is one of the most widely used photoactive units and recently an ethylene-bridged azobenzene (BAB) was reported to have greatly enhanced conversion efficiency, quantum yield, and other favorable properties. As the first step towards exploring its photo-switchable character in real systems, we report here a systematic study on the photoisomerization dynamics between trans (E) and cis (Z) isomers in the gas phase and the CH{sub 3}OH solution, using ab initio based surface hopping and molecular dynamics, which is the first report of dynamics simulation to reveal the environmental effects on BAB photoreactions. Results show that while the relatively faster S{sub 1} relaxation of the photo-induced E{yields}Z process is only mildly affected by the solvent effect, the relatively slower S{sub 1} relaxation of the reverse reaction becomes even slower in the solution compared to the gas phase. The subsequent S{sub 0} dynamics from the conical intersection between S{sub 1} and S{sub 0} (CI{sub E}) to Z is accelerated in solution compared to the gas phase because of avoided re-crossing to the S{sub 1} state, while the S{sub 0} dynamics from the conical intersection between S{sub 1} and S{sub 0} (CI{sub Z}) to E are basically the same in both phases. Overall, the solvent effect was found to enhance the back-and-forth photo-switch efficiency between the Z and E isomers compared to the gas phase, while the quantum yields are reduced. But the solution yields of both the forward and backward photoreactions are still around 0.4. Therefore, BAB may have good photo-responsive properties if used as a photoactive unit in real systems. These results will facilitate future experimental and theoretical studies in this area to help design new azobenzene derivatives as photoactive units in biological processes, nanoscale devices, and photo-responsive materials.

  7. Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.

    1995-03-01

    This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.

  8. Three phase downhole separator process

    DOE Patents [OSTI]

    Cognata, Louis John (Baytown, TX)

    2008-06-24

    Three Phase Downhole Separator Process (TPDSP) is a process which results in the separation of all three phases, (1) oil, (2) gas, and (3) water, at the downhole location in the well bore, water disposal injection downhole, and oil and gas production uphole.

  9. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1989-01-01

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  10. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D. (Alliance, OH); Downs, William (Alliance, OH); Jankura, Bryan J. (Mogadore, OH); McCoury, Jr., John M. (Mineral City, OH)

    1990-01-01

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  11. Slurry phase Fischer-Tropsch synthesis: Cobalt plus a water-gas shift catalyst. [Quarterly] report, October 1, 1988--December 31, 1988

    SciTech Connect (OSTI)

    Yates, I.C.; Satterfield, C.N.

    1988-12-31

    A cobalt Fischer-Tropsch catalyst (CO/MgO/silica) was reduced and slurried in combination with reduced Cu/ZnO/Al{sub 2}0{sub 3} water-gas-shift catalyst. Combined catalyst system was run at fixed process conditions for more than 400 hours. The system showed stable selectivity. The Cu/ZnO/Al{sub 2}0{sub 3} water-gas-shift catalyst remained reasonably active in the presence of the cobalt catalyst. Hydrocarbon selectivity of the cobalt and Cu/ZnO/Al{sub 2}0{sub 3} catalyst system compared favorably to selectivity of iron-based catalysts. Methane selectivity was slightly higher for the cobalt-based system, but C{sub 5}{sup +} selectivity was essentially the same. The hydrocarbon product distribution appeared to exhibit a double-a behavior. a{sub 1} was near 0.80 which is higher than that of iron catalysts, while a{sub 2} was calculated to be 0.86 which is somewhat lower than would be typical for an iron-based catalyst.

  12. An innovative catalyst system for slurry-phase Fischer-Tropsch synthesis: Cobalt plus a water-gas-shift catalyst. Final technical report

    SciTech Connect (OSTI)

    Satterfield, C.N.; Yates, I.C.; Chanenchuk, C.

    1991-07-01

    The feasibility of using a mechanical mixture of a Co/MgO/SiO{sub 2} Fischer-Tropsch catalyst and a Cu-ZnO/Al{sub 2}O{sub 3} water-gas-shift (WGS) catalyst for hydrocarbon synthesis in a slurry reactor has been established. Such a mixture can combine the superior product distribution from cobalt with the high activity for the WGS reaction characteristic of iron. Weight ratios of Co/MgO/SiO{sub 2} to Cu-ZnO/Al{sub 2}O{sub 3} of 0.27 and 0.51 for the two catalysts were studied at 240{degrees}C, 0.79 MPa, and in situ H{sub 2}/CO ratios between 0.8 and 3.0. Each catalyst mixture showed stable Fischer-Tropsch activity for about 400 hours-on-stream at a level comparable to the cobalt catalyst operating alone. The Cu-ZnO/Al{sub 2}O{sub 3} catalyst exhibited a very slow loss of activity under these conditions, but when operated alone it was stable in a slurry reactor at 200--220{degrees}C, 0.79--1.48 MPa, and H{sub 2}/CO in situ ratios between 1.0 and 2.0. The presence of the water-gas-shift catalyst did not affect the long-term stability of the primary Fischer-Tropsch selectivity, but did increase the extent of secondary reactions, such as l-alkene hydrogenation and isomerization.

  13. A versatile elevated-pressure reactor combined with an ultrahigh vacuum surface setup for efficient testing of model and powder catalysts under clean gas-phase conditions

    SciTech Connect (OSTI)

    Morfin, Franck; Piccolo, Laurent

    2013-09-15

    A small-volume reaction cell for catalytic or photocatalytic testing of solid materials at pressures up to 1000 Torr has been coupled to a surface-science setup used for standard sample preparation and characterization under ultrahigh vacuum (UHV). The reactor and sample holder designs allow easy sample transfer from/to the UHV chamber, and investigation of both planar and small amounts of powder catalysts under the same conditions. The sample is heated with an infrared laser beam and its temperature is measured with a compact pyrometer. Combined in a regulation loop, this system ensures fast and accurate temperature control as well as clean heating. The reaction products are automatically sampled and analyzed by mass spectrometry and/or gas chromatography (GC). Unlike previous systems, our GC apparatus does not use a recirculation loop and allows working in clean conditions at pressures as low as 1 Torr while detecting partial pressures smaller than 10{sup ?4} Torr. The efficiency and versatility of the reactor are demonstrated in the study of two catalytic systems: butadiene hydrogenation on Pd(100) and CO oxidation over an AuRh/TiO{sub 2} powder catalyst.

  14. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  15. CATALYST ACTIVITY MAINTENANCE FOR THE LIQUID PHASE SYNTHESIS GAS-TO-DIMETHYL ETHER PROCESS PART II: DEVELOPMENT OF ALUMINUM PHOSPHATE AS THE DEHYDRATION CATALYST FOR THE SINGLE-STEP LIQUID PHASE SYNGAS-TO-DME PROCESS

    SciTech Connect (OSTI)

    Xiang-Dong Peng

    2002-05-01

    At the heart of the single-step liquid phase syngas-to-DME process (LPDME{trademark}) is a catalyst system that can be active as well as stable. In the Alternative Fuels I program, a dual-catalyst system containing a Cu-based commercial methanol synthesis catalyst (BASF S3-86) and a commercial dehydration material ({gamma}-alumina) was demonstrated. It provided the productivity and selectivity expected from the LPDME process. However, the catalyst system deactivated too rapidly to warrant a viable commercial process [1]. The mechanistic investigation in the early part of the DOE's Alternative Fuels II program revealed that the accelerated catalyst deactivation under LPDME conditions is due to detrimental interaction between the methanol synthesis catalyst and methanol dehydration catalyst [2,3]. The interaction was attributed to migration of Cu- and/or Zn-containing species from the synthesis catalyst to the dehydration catalyst. Identification of a dehydration catalyst that did not lead to this detrimental interaction while retaining adequate dehydration activity was elusive. Twenty-nine different dehydration materials were tested, but none showed the desired performance [2]. The search came to a turning point when aluminum phosphate was tested. This amorphous material is prepared by precipitating a solution containing Al(NO{sub 3}){sub 3} and H{sub 3}PO{sub 4} with NH{sub 4}OH, followed by washing, drying and calcination. The aluminum phosphate catalyst has adequate dehydration activity and good stability. It can co-exist with the Cu-based methanol synthesis catalyst without negatively affecting the latter catalyst's stability. This report documents the details of the development of this catalyst. These include initial leads, efforts in improving activity and stability, investigation and development of the best preparation parameters and procedures, mechanistic understanding and resulting preparation guidelines, and the accomplishments of this work.

  16. High-volume, high-value usage of Flue Gas Desulfurization (FGD) by-products in underground mines Phase 1: Laboratory investigations. Quarterly report, July 1994--September 1994

    SciTech Connect (OSTI)

    1994-12-01

    During the quarter a second series of samples were collected and partially characterized chemically and mineralogically. The samples were collected at the disposal site operated by Freeman United Coal Co. The second collection was necessary because of deterioration due to hydration of the original samples. A study of the hydration characteristics was completed during the quarter. Important reactions included the immediate formation of ettringite and portlandite. The hydration and transformation was found to be a slow process. A second phase of gypsum formation from ettringite deterioration was identified. The slow hydration of anhydrite with its resultant swell is a potential problem which will be addressed further. Geotechnical characterization, during the quarter included completion of the preliminary characterization, analysis of the findings, experimentation with sample preparation for the final characterization/mix design, and design of the final experimental program. The analysis of the coals collected during the core drilling and hydrologic planning were completed. Also during the quarter a meeting was held with representatives of the shotcrete industry to discuss transport systems for emplacement. The pros and cons of pneumatic and hydraulic systems were discussed and plans formulated for further investigations.

  17. Infrared Multiphoton Dissociation Spectroscopy of a Gas-Phase Complex of Uranyl and 3-Oxa-Glutaramide: An Extreme Red-Shift of the [O=U=O]²? Asymmetric Stretch

    SciTech Connect (OSTI)

    Gibson, John K.; Hu, Hanshi; Van Stipdonk, Michael J.; Berden, Giel; Oomens, Jos; Li, Jun

    2015-04-09

    The gas-phase complex UO?(TMOGA)?²? (TMOGA = tetramethyl-3-oxa-glutaramide) prepared by electrospray ionization was characterized by infrared multiphoton dissociation (IRMPD) spectroscopy. The IRMPD spectrum from 700–1800 cm?¹ was interpreted using a computational study based on density functional theory. The predicted vibrational frequencies are in good agreement with the measured values, with an average deviation of only 8 cm?¹ (<1%) and a maximum deviation of 21 cm?¹ (<2%). The only IR peak assigned to the linear uranyl moiety was the asymmetric ?? mode, which appeared at 965 cm?¹ and was predicted by DFT as 953 cm?¹. This ?? frequency is red-shifted relative to bare uranyl, UO?²?, by ca. 150 cm?¹ due to electron donation from the TMOGA ligands. Based on the degree of red-shifting, it is inferred that two TMOGA oxygen-donor ligands have a greater effective gas basicity than the four monodentate acetone ligands in UO?(acetone)?²?. The uranyl ?? frequency was also computed for uranyl coordinated by two TMGA ligands, in which the central Oether of TMOGA has been replaced by CH?. The computed ?? for UO?(TMGA)?²?, 950 cm?¹, is essentially the same as that for UO?(TMOGA)?²?, suggesting that electron donation to uranyl from the Oether of TMOGA is minor. The computed ?? asymmetric stretching frequencies for the three actinyl complexes, UO?(TMOGA)?²?, NpO?(TMOGA)?²? and PuO?(TMOGA)?²?, are comparable. This similarity is discussed in the context of the relationship between ?? and intrinsic actinide-oxygen bond energies in actinyl complexes.

  18. The dynamics of two-phase (gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the critical point. The aim for CASL's implementation is to allow faster evaluation of prop- erties. The IAPWS95 model equation uses density and temperature as independent...

  19. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  20. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  1. Virginia Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  2. Colorado Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Colorado Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  3. Nebraska Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  4. Missouri Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  5. Michigan Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  6. Kentucky Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  7. Tennessee Natural Gas Number of Gas and Gas Condensate Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Tennessee Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  8. Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  9. Mississippi Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  10. Oklahoma Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Oklahoma Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  11. Illinois Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Illinois Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  12. Arkansas Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Arkansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  13. Maryland Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  14. Louisiana Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  15. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.W.

    1997-05-01

    Cryenco and Los Alamos are collaborating to develop a natural-gas-powered natural-gas liquefier that will have no moving parts and require no electrical power. It will have useful efficiency, remarkable reliability, and low cost. The liquefaction of natural gas, which occurs at only 115 Kelvin at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 invention of the thermoacoustically driven orifice pulse-tube refrigerator (TA-DOPTR) provides cryogenic refrigeration with no moving parts for the first time. In short, this invention uses acoustic phenomena to produce refrigeration from heat. The required apparatus consists of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. In the Cryenco-Los Alamos collaboration, the authors are developing a version of this invention suitable for use in the natural-gas industry. The project is known as acoustic liquefier for short. The present program plans call for a two-phase development. Phase 1, with capacity of 500 gallon per day (i.e., approximately 40,000 scfd, requiring a refrigeration power of about 7 kW), is large enough to illuminate all the issues of large-scale acoustic liquefaction without undue cost, and to demonstrate the liquefaction of 60--70% of input gas, while burning 30--40%. Phase 2 will target versions of approximately 10{sup 6} scfd = 10,000 gallon per day capacity. In parallel with both, they continue fundamental research on the technology, directed toward increased efficiency, to build scientific foundations and a patent portfolio for future acoustic liquefiers.

  16. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  17. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  18. Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic ...

  19. Microsoft Word - Phase1-Final_Report4.doc

    Office of Scientific and Technical Information (OSTI)

    ... This section describes the work and results of the Phase I research. Background Current ... This failure of established methodology results in many US oil and gas deposits being ...

  20. Combustion 2000: Phase II

    SciTech Connect (OSTI)

    Unknown

    1999-11-01

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard); coal providing {ge} 65% of heat input; all solid wastes benign; and cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This Phase, Phase 2, had as its initial objective the development of a complete design base for the construction and operation of a HIPPS prototype plant to be constructed in Phase 3. As part of a descoping initiative, the Phase 3 program has been eliminated and work related to the commercial plant design has been ended. The rescoped program retained a program of engineering research and development focusing on high temperature heat exchangers, e.g. HITAF development (Task 2); a rescoped Task 6 that is pertinent to Vision 21 objectives and focuses on advanced cycle analysis and optimization, integration of gas turbines into complex cycles, and repowering designs; and preparation of the Phase 2 Technical Report (Task 8). This rescoped program deleted all subsystem testing (Tasks 3, 4,and 5) and the development of a site-specific engineering design and test plan for the HIPPS prototype plant (Task 7). Work reported herein is from: Task 2.1 HITAF Combustors; Task 2.2 HITAF Air Heaters; and Task 6 HIPPS Commercial Plant Design Update.

  1. High-Speed, Temperature Programmable Gas Chromatography Utilizing...

    Office of Scientific and Technical Information (OSTI)

    High-Speed, Temperature Programmable Gas Chromatography Utilizing a Microfabricated Chip with an Improved Carbon Nanotube Stationary Phase Citation Details In-Document Search...

  2. The Greenhouse Gas Protocol Initiative: Measurement and Estimation...

    Open Energy Info (EERE)

    GHG Emissions AgencyCompany Organization: World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Greenhouse Gas Phase:...

  3. Variations in dissolved gas compositions of reservoir fluids...

    Open Energy Info (EERE)

    distinct regions of single-phase (liquid) reservoir are present and possess distinctive gas and liquid compositions. Relationships in soluble and insoluble gases preclude...

  4. The Greenhouse Gas Protocol Initiative: Sector Specific Tools...

    Open Energy Info (EERE)

    World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Industry, Greenhouse Gas Phase: Determine Baseline, Evaluate...

  5. Stationary phase deposition based on onium salts

    DOE Patents [OSTI]

    Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

    2008-01-01

    Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

  6. Natural Gas Resources of the Greater Green River and Wind River Basins of Wyoming (Assessing the Technology Needs of Sub-economic Resources, Phase I: Greater Green River and Wind river Basins, Fall 2002)

    SciTech Connect (OSTI)

    Boswell, Ray; Douds, Ashley; Pratt, Skip; Rose, Kelly; Pancake, Jim; Bruner, Kathy; Kuuskraa, Vello; Billingsley, Randy

    2003-02-28

    In 2000, NETL conducted a review of the adequacy of the resource characterization databases used in its Gas Systems Analysis Model (GSAM). This review indicated that the most striking deficiency in GSAM’s databases was the poor representation of the vast resource believed to exist in low-permeability sandstone accumulations in western U.S. basins. The model’s databases, which are built primarily around the United States Geological Survey (USGS) 1995 National Assessment (for undiscovered resources), reflected an estimate of the original-gas-inplace (OGIP) only in accumulations designated “technically-recoverable” by the USGS –roughly 3% to 4% of the total estimated OGIP of the region. As these vast remaining resources are a prime target of NETL programs, NETL immediately launched an effort to upgrade its resource characterizations. Upon review of existing data, NETL concluded that no existing data were appropriate sources for its modeling needs, and a decision was made to conduct new, detailed log-based, gas-in-place assessments.

  7. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  8. Production of biodiesel using expanded gas solvents

    SciTech Connect (OSTI)

    Ginosar, Daniel M; Fox, Robert V; Petkovic, Lucia M

    2009-04-07

    A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

  9. Natural gas recovery, storage, and utilization SBIR program

    SciTech Connect (OSTI)

    Shoemaker, H.D.

    1993-12-31

    A Fossil Energy natural-gas topic has been a part of the DOE Small Business Innovation Research (SBIR) program since 1988. To date, 50 Phase SBIR natural-gas applications have been funded. Of these 50, 24 were successful in obtaining Phase II SBIR funding. The current Phase II natural-gas research projects awarded under the SBIR program and managed by METC are presented by award year. The presented information on these 2-year projects includes project title, awardee, and a project summary. The 1992 Phase II projects are: landfill gas recovery for vehicular natural gas and food grade carbon dioxide; brine disposal process for coalbed gas production; spontaneous natural as oxidative dimerization across mixed conducting ceramic membranes; low-cost offshore drilling system for natural gas hydrates; motorless directional drill for oil and gas wells; and development of a multiple fracture creation process for stimulation of horizontally drilled wells.The 1993 Phase II projects include: process for sweetening sour gas by direct thermolysis of hydrogen sulfide; remote leak survey capability for natural gas transport storage and distribution systems; reinterpretation of existing wellbore log data using neural-based patter recognition processes; and advanced liquid membrane system for natural gas purification.

  10. Underground natural gas storage reservoir management

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.

    1995-06-01

    The objective of this study is to research technologies and methodologies that will reduce the costs associated with the operation and maintenance of underground natural gas storage. This effort will include a survey of public information to determine the amount of natural gas lost from underground storage fields, determine the causes of this lost gas, and develop strategies and remedial designs to reduce or stop the gas loss from selected fields. Phase I includes a detailed survey of US natural gas storage reservoirs to determine the actual amount of natural gas annually lost from underground storage fields. These reservoirs will be ranked, the resultant will include the amount of gas and revenue annually lost. The results will be analyzed in conjunction with the type (geologic) of storage reservoirs to determine the significance and impact of the gas loss. A report of the work accomplished will be prepared. The report will include: (1) a summary list by geologic type of US gas storage reservoirs and their annual underground gas storage losses in ft{sup 3}; (2) a rank by geologic classifications as to the amount of gas lost and the resultant lost revenue; and (3) show the level of significance and impact of the losses by geologic type. Concurrently, the amount of storage activity has increased in conjunction with the net increase of natural gas imports as shown on Figure No. 3. Storage is playing an ever increasing importance in supplying the domestic energy requirements.

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas demand, thereby contributing to larger net injections of natural gas into storage. Other Market Trends: EIA Releases The Natural Gas Annual 2006: The Energy...

  12. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil...

  13. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  14. Advanced Gas Storage Concepts: Technologies for the Future

    SciTech Connect (OSTI)

    Freeway, Katy; Rogers, R.E.; DeVries, Kerry L.; Nieland, Joel D.; Ratigan, Joe L.; Mellegard, Kirby D.

    2000-02-01

    This full text product includes: 1) A final technical report titled Advanced Underground Gas Storage Concepts, Refrigerated-Mined Cavern Storage and presentations from two technology transfer workshops held in 1998 in Houston, Texas, and Pittsburgh, Pennsylvania (both on the topic of Chilled Gas Storage in Mined Caverns); 2) A final technical report titled Natural Gas Hydrates Storage Project, Final Report 1 October 1997 - 31 May 1999; 3) A final technical report titled Natural Gas Hydrates Storage Project Phase II: Conceptual Design and Economic Study, Final Report 9 June - 10 October 1999; 4) A final technical report titled Commerical Potential of Natural Gas Storage in Lined Rock Caverns (LRC) and presentations from a DOE-sponsored workshop on Alternative Gas Storage Technologies, held Feb 17, 2000 in Pittsburgh, PA; and 5) Phase I and Phase II topical reports titled Feasibility Study for Lowering the Minimum Gas Pressure in Solution-Mined Caverns Based on Geomechanical Analyses of Creep-Induced Damage and Healing.

  15. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  16. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  17. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  18. THE DARK MOLECULAR GAS

    SciTech Connect (OSTI)

    Wolfire, Mark G.; Hollenbach, David; McKee, Christopher F. E-mail: dhollenbach@seti.or

    2010-06-20

    The mass of molecular gas in an interstellar cloud is often measured using line emission from low rotational levels of CO, which are sensitive to the CO mass, and then scaling to the assumed molecular hydrogen H{sub 2} mass. However, a significant H{sub 2} mass may lie outside the CO region, in the outer regions of the molecular cloud where the gas-phase carbon resides in C or C{sup +}. Here, H{sub 2} self-shields or is shielded by dust from UV photodissociation, whereas CO is photodissociated. This H{sub 2} gas is 'dark' in molecular transitions because of the absence of CO and other trace molecules, and because H{sub 2} emits so weakly at temperatures 10 K gas and far-infrared/submillimeter wavelength dust continuum radiation. In this paper, we theoretically model this dark mass and find that the fraction of the molecular mass in this dark component is remarkably constant ({approx}0.3 for average visual extinction through the cloud A-bar{sub V{approx_equal}}8) and insensitive to the incident ultraviolet radiation field strength, the internal density distribution, and the mass of the molecular cloud as long as A-bar{sub V}, or equivalently, the product of the average hydrogen nucleus column and the metallicity through the cloud, is constant. We also find that the dark mass fraction increases with decreasing A-bar{sub V}, since relatively more molecular H{sub 2} material lies outside the CO region in this case.

  19. High-Speed, Temperature Programmable Gas Chromatography Utilizing a

    Office of Scientific and Technical Information (OSTI)

    Microfabricated Chip with an Improved Carbon Nanotube Stationary Phase (Journal Article) | SciTech Connect High-Speed, Temperature Programmable Gas Chromatography Utilizing a Microfabricated Chip with an Improved Carbon Nanotube Stationary Phase Citation Details In-Document Search Title: High-Speed, Temperature Programmable Gas Chromatography Utilizing a Microfabricated Chip with an Improved Carbon Nanotube Stationary Phase Authors: Stadermann, M ; Bakajin, O ; Reid, V ; Synovec, R

  20. System and method for cooling a combustion gas charge

    DOE Patents [OSTI]

    Massey, Mary Cecelia; Boberg, Thomas Earl

    2010-05-25

    The present invention relates to a system and method for cooling a combustion gas charge prior. The combustion gas charge may include compressed intake air, exhaust gas, or a mixture thereof. An evaporator is provided that may then receive a relatively high temperature combustion gas charge and discharge at a relatively lower temperature. The evaporator may be configured to operate with refrigeration cycle components and/or to receive a fluid below atmospheric pressure as the phase-change cooling medium.

  1. ARM - Measurement - Hydrometeor phase

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    : Hydrometeor phase Hydrometeor phase such as liquid ice or mixed phase Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  2. Cummins Power Generation SECA Phase 1

    SciTech Connect (OSTI)

    Charles Vesely

    2007-08-17

    The following report documents the progress of the Cummins Power Generation (CPG) SECA Phase 1 SOFC development and final testing under the U.S. Department of Energy Solid State Energy Conversion Alliance (SECA) contract DE-FC26-01NT41244. This report overviews and summarizes CPG and partner research development leading to successful demonstration of the SECA Phase 1 objectives and significant progress towards SOFC commercialization. Significant Phase 1 Milestones: (1) Demonstrated: (a) Operation meeting Phase 1 requirements on commercial natural gas. (b) LPG and Natural Gas CPOX fuel reformers. (c) SOFC systems on dry CPOX reformate. (c) Steam reformed Natural Gas operation. (d) Successful start-up and shut-down of SOFC system without inert gas purge. (e) Utility of stack simulators as a tool for developing balance of plant systems. (2) Developed: (a) Low cost balance of plant concepts and compatible systems designs. (b) Identified low cost, high volume components for balance of plant systems. (c) Demonstrated high efficiency SOFC output power conditioning. (d) Demonstrated SOFC control strategies and tuning methods. The Phase 1 performance test was carried out at the Cummins Power Generation facility in Minneapolis, Minnesota starting on October 2, 2006. Performance testing was successfully completed on January 4, 2007 including the necessary steady-state, transient, efficiency, and peak power operation tests.

  3. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A.

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  4. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  6. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  7. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  8. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  9. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  10. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  11. Natural Gas Regulation - Other Gas-Related Information Sources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Regulation - Other Gas-Related Information Sources Natural Gas Regulation - Other Gas-Related Information Sources The single largest source of energy information...

  12. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of the Alaska gas pipeline. The opening of ANWR might reduce the gas resource risk of building an Alaska gas pipeline, as the area has an estimated 3.6 trillion cubic...

  14. Gas amplified ionization detector for gas chromatography

    DOE Patents [OSTI]

    Huston, Gregg C. (LaBelle, PA)

    1992-01-01

    A gas-amplified ionization detector for gas chromatrography which possesses increased sensitivity and a very fast response time. Solutes eluding from a gas chromatographic column are ionized by UV photoionization of matter eluting therefrom. The detector is capable of generating easily measured voltage signals by gas amplification/multiplication of electron products resulting from the UV photoionization of at least a portion of each solute passing through the detector.

  15. Shale gas is natural gas trapped inside

    Energy Savers [EERE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary rocks that can be rich sources of petroleum and natural gas. Just a few years ago, much of this resource was considered uneconomical to produce. But Office of Fossil Energy (FE) research helped refine cost-effective horizontal drilling and hydraulic fracturing technologies, protective environmental practices and data development, making hundreds of trillions of cubic feet of gas technically recoverable where

  16. Carbonyl sulfide hydrolysis in natural gas

    SciTech Connect (OSTI)

    Russo, F.; Caribotti, P.; Garofalo, N.

    1988-01-01

    Carbonyl sulfide may naturally occur in high H/sub 2/S - CO/sub 2/ content sour natural gases. Furthermore part of the H/sub 2/S present in natural gases may be converted into COS if molecular sieves are used as H/sub 2/S removal substances in natural gas desulphurization plants. Carbonyl sulfide might then hydrolize to H/sub 2/S in the gas storage fields and transmission lines. This paper illustrates experimental data relevant to the kinetics and thermodynamics of the reaction between carbonyl sulfide and water both at gas and gas/liquid phases. Results may suggest whether carbonyl sulfide should be included in natural gas quality specifications.

  17. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J. (Oak Ridge, TN); Lowrie, Robert S. (Oak Ridge, TN); Sease, John D. (Knoxville, TN)

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Sources & Uses Petroleum & Other Liquids Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas...

  19. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  20. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    , 2008 Next Release: July 10, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 25, natural gas spot prices...

  2. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  3. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  4. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  5. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    cooling demand for natural gas. Meanwhile, it became increasingly clear that Hurricane Frances likely would not pose a significant threat to natural gas production in the Gulf of...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    more from the system than they nominate. Other pipeline companies, such as CenterPoint Energy Gas Transmission Company and Southern Star Central Gas Pipeline Corporation, both...

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    that had been in place since February 1. Other pipeline companies, such as CenterPoint Energy Gas Transmission Company and Southern Star Central Gas Pipeline Corporation, both...

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas vehicles. The Department of Energys Office of Energy Efficiency and Renewable Energy reports that there were 841 compressed natural gas (CNG) fuel stations and 41...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5, 2009 Next Release: July 2, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 24, 2009) Natural gas...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    ability to process gas. The company's Main Pass 260 line to Pascagoula Gas Plant in Jackson, Mississippi, will not be available for transportation services. While the plant is...

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Market Trends: MMS Announces New Incentives for Gulf Gas Production: The Minerals Management Service (MMS) unveiled proposed new incentives to increase deep gas production...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 6, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, October 29) Natural gas...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2008 Next Release: June 26, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 11, natural gas spot prices...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    prices using spot prices from producing areas, plus an allowance for interstate natural gas pipeline and local distribution company charges to transport the gas to market. Such a...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 12, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Spot gas at most market locations (outside the Rocky Mountain Region) traded...

  18. Methods for deacidizing gaseous mixtures by phase enhanced absorption

    DOE Patents [OSTI]

    Hu, Liang

    2012-11-27

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  19. High harmonic phase in molecular nitrogen

    SciTech Connect (OSTI)

    McFarland, Brian K.

    2009-10-17

    Electronic structure in atoms and molecules modulates the amplitude and phase of high harmonic generation (HHG). We report measurements of the high harmonic spectral amplitude and phase in N{sub 2}. The phase is measured interferometrically by beating the N{sub 2} harmonics with those of an Ar reference oscillator in a gas mixture. A rapid phase shift of 0.2{pi} is observed in the vicinity of the HHG spectral minimum, where a shift of {pi} had been presumed [J. Itatani et al., Nature 432, 867 (2004)]. We compare the phase measurements to a simulation of the HHG recombination step in N{sub 2} that is based on a simple interference model. The results of the simulation suggest that modifications beyond the simple interference model are needed to explain HHG spectra in molecules.

  20. Shock dynamics of phase diagrams

    SciTech Connect (OSTI)

    Moro, Antonio

    2014-04-15

    A thermodynamic phase transition denotes a drastic change of state of a physical system due to a continuous change of thermodynamic variables, as for instance pressure and temperature. The classical van der Waals equation of state is the simplest model that predicts the occurrence of a critical point associated with the gas–liquid phase transition. Nevertheless, below the critical temperature theoretical predictions of the van der Waals theory significantly depart from the observed physical behaviour. We develop a novel approach to classical thermodynamics based on the solution of Maxwell relations for a generalised family of nonlocal entropy functions. This theory provides an exact mathematical description of discontinuities of the order parameter within the phase transition region, it explains the universal form of the equations of state and the occurrence of triple points in terms of the dynamics of nonlinear shock wave fronts. -- Highlights: •A new generalisation of van der Waals equation of state. •Description of phase transitions in terms of shock dynamics of state curves. •Proof of the universality of equations of state for a general class of models. •Interpretation of triple points as confluence of classical shock waves. •Correspondence table between thermodynamics and nonlinear conservation laws.

  1. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

    2001-01-01

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  2. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  3. QER- Comment of American Gas Association 3

    Broader source: Energy.gov [DOE]

    Dear Ms. Pickett: Attached please find AGA's comments on natural gas vehicle fueling infrastructure as part of our response to the first phase of the DOE Quadrennial Energy Review (QER), consisting of a cover letter and attachments. Respectfully submitted, Kathryn Clay

  4. QER- Comment of American Gas Association 2

    Broader source: Energy.gov [DOE]

    Attached please find AGA's comments relating to critical issues facing the natural gas distribution industry, which we believe could be usefully addressed in the first phase of the DOE Quadrennial Energy Review (QER). Our comments as submitted here consist of a cover letter and four additional attachments. My colleague Pam Lacey has previously submitted AGA's comments relating to methane emissions under separate cover.

  5. NGNP PHASE I REVIEW

    Broader source: Energy.gov (indexed) [DOE]

    NGNP PHASE I REVIEW NEAC REACTOR TECHNOLOGY SUBCOMMITTEE CURRENT STATUS DECEMBER 9, 2010 EPACT 2005 REQUIREMENTS * FIRST PROJECT PHASE REVIEW-On a determination by the Secretary...

  6. Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    William Eleazer, PE Brown and Caldwell Project Design Manager St. Petersburg, FL: Vehicle Use of Recycled Natural Gas Derived from Wastewater Biosolids U.S Department of Energy - Biomass 2014 John Willis, PE, BCEE Brown and Caldwell Project Technical Supervisor Steven Marshall, PE St. Petersburg City Project Manager Eron Jacobson, PE Brown and Caldwell Gas Upgrade Systems Process Area Manager Project Summary Biogas to Recycled Natural Gas Technology Evaluation and Design Phase Future

  7. Future of Natural Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts * Supply vs. Capacity * Sources * Consumption * Pipeline system * Gas Interruptions - Operational Flow Orders * Pricing Federal Utility Partnership Working Group November 5-6, 2014 Cape Canaveral, FL Sources of Natural Gas * Mine * Import * Remove from storage Federal Utility Partnership Working Group November 5-6,

  8. Process for production desulfurized of synthesis gas

    DOE Patents [OSTI]

    Wolfenbarger, James K. (Torrance, CA); Najjar, Mitri S. (Wappingers Falls, NY)

    1993-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

  9. Non-planar microfabricated gas chromatography column

    DOE Patents [OSTI]

    Lewis, Patrick R.; Wheeler, David R.

    2007-09-25

    A non-planar microfabricated gas chromatography column comprises a planar substrate having a plurality of through holes, a top lid and a bottom lid bonded to opposite surfaces of the planar substrate, and inlet and outlet ports for injection of a sample gas and elution of separated analytes. A plurality of such planar substrates can be aligned and stacked to provide a longer column length having a small footprint. Furthermore, two or more separate channels can enable multi-channel or multi-dimensional gas chromatography. The through holes preferably have a circular cross section and can be coated with a stationary phase material or packed with a porous packing material. Importantly, uniform stationary phase coatings can be obtained and band broadening can be minimized with the circular channels. A heating or cooling element can be disposed on at least one of the lids to enable temperature programming of the column.

  10. CrowdPhase: crowdsourcing the phase problem

    SciTech Connect (OSTI)

    Jorda, Julien; Sawaya, Michael R. [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Yeates, Todd O., E-mail: yeates@mbi.ucla.edu [Institute for Genomics and Proteomics, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); Molecular Biology Institute, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States); University of California, 611 Charles Young Drive East, Los Angeles, CA 90095 (United States)

    2014-06-01

    The idea of attacking the phase problem by crowdsourcing is introduced. Using an interactive, multi-player, web-based system, participants work simultaneously to select phase sets that correspond to better electron-density maps in order to solve low-resolution phasing problems. The human mind innately excels at some complex tasks that are difficult to solve using computers alone. For complex problems amenable to parallelization, strategies can be developed to exploit human intelligence in a collective form: such approaches are sometimes referred to as ‘crowdsourcing’. Here, a first attempt at a crowdsourced approach for low-resolution ab initio phasing in macromolecular crystallography is proposed. A collaborative online game named CrowdPhase was designed, which relies on a human-powered genetic algorithm, where players control the selection mechanism during the evolutionary process. The algorithm starts from a population of ‘individuals’, each with a random genetic makeup, in this case a map prepared from a random set of phases, and tries to cause the population to evolve towards individuals with better phases based on Darwinian survival of the fittest. Players apply their pattern-recognition capabilities to evaluate the electron-density maps generated from these sets of phases and to select the fittest individuals. A user-friendly interface, a training stage and a competitive scoring system foster a network of well trained players who can guide the genetic algorithm towards better solutions from generation to generation via gameplay. CrowdPhase was applied to two synthetic low-resolution phasing puzzles and it was shown that players could successfully obtain phase sets in the 30° phase error range and corresponding molecular envelopes showing agreement with the low-resolution models. The successful preliminary studies suggest that with further development the crowdsourcing approach could fill a gap in current crystallographic methods by making it possible to extract meaningful information in cases where limited resolution might otherwise prevent initial phasing.

  11. Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Alabama Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  12. Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Ohio Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  13. Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Wyoming Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  14. Texas Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Texas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  15. Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Indiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  16. New York Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) New York Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  17. Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Alaska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  18. North Dakota Natural Gas Number of Gas and Gas Condensate Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) North Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  19. West Virginia Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) West Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  20. South Dakota Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) South Dakota Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  1. Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Oregon Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  2. U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) U.S. Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  3. Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Nevada Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  4. Utah Natural Gas Number of Gas and Gas Condensate Wells (Number...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Utah Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  5. Cryogenic recovery of LPG from natural gas

    SciTech Connect (OSTI)

    Gray, M.L.; McClintock, W.A.

    1984-02-07

    In accordance with the present invention a natural gas stream predominating in methane and containing significant amounts of C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is cooled in a plurality of cooling stages to a temperature sufficient to produce at least one liquid phase portion predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons. Then at least one liquid phase portion predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is separated from the main gas stream during the course of the cooling. The thus separated liquid phase portion or portions predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is further separated into a vapor phase portion predominating in C/sub 2/, C/sub 3/, and C/sub 4/ hydrocarbons and at least one liquid phase portion predominating in C/sub 5/ and higher molecular weight hydrocarbons, at least one second separation step, at least one portion of the at least one vapor phase portion predominating in C/sub 2/, C/sub 3/ and C/sub 4/, hydrocarbons is recovered as at least one product of the process and at least one portion of the remaining portion of the at least one phase portion predominating in C/sub 2/, C/sub 3/ and C/sub 4/ hydrocarbons is recycled to and recombined with the main gas stream as a liquid phase.

  6. Quantum phase transition of condensed bosons in optical lattices

    SciTech Connect (OSTI)

    Liang Junjun; Liang, J.-Q.; Liu, W.-M.

    2003-10-01

    In this paper we study the superfluid-Mott-insulator phase transition of ultracold dilute gas of bosonic atoms in an optical lattice by means of Green function method and Bogliubov transformation as well. The superfluid-Mott-insulator phase transition condition is determined by the energy-band structure with an obvious interpretation of the transition mechanism. Moreover the superfluid phase is explained explicitly from the energy spectrum derived in terms of Bogliubov approach.

  7. DOE Commercial Building Energy Asset Score: Software Development for Phase

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    II Building Types | Department of Energy Score: Software Development for Phase II Building Types DOE Commercial Building Energy Asset Score: Software Development for Phase II Building Types DOE Commercial Building Energy Asset Score: Software Development for Phase II Building Types PDF icon asset_score_assumptions_july_2013.pdf More Documents & Publications Weekend/Weekday Ozone Study in the South Coast Air Basin Users Perspective on Advanced Fuel Cell Bus Technology Tankless Gas Water

  8. Phase I A Phase I B Phase I C

    Office of Legacy Management (LM)

    Parcel 9 Parcel 8 Phase I A Phase I B Phase I C Parcel 7 Parcel 6 Parcel 4 Parcel 3 Parcel D Parcel H Parcel 6A T 61 87 3 105 2 OSE 63 28 126 45 COS OSW 100 GH 102 STP SST 301 300 Mag-82 Mag-81 Mag-80 Mag-83 Mag-84 Mound Closure Project - Current Parcels and Buildings FILE NAME: mnd_bldg_parcel_owner_c.mxd DATE: Legend Parcel - DOE Parcel - MMCIC Pond Building Ownership DOE Leased MMCIC Road - paved Railroad 200 0 200 100 Feet O:\Sites\OH\Mound\ProjectWorkArea\PawelS\mnd_bldg_parcel_owner_c.mxd

  9. EIA - Natural Gas Pipeline Network - Combined Natural Gas Transportation

    Gasoline and Diesel Fuel Update (EIA)

    Maps Combined Natural Gas Transportation Maps About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates U.S. Natural Gas Pipeline Network Map of U.S. Natural Gas Pipeline Network Major Natural Gas Supply Basins Relative to Natural Gas Pipeline Transportation Corridors Map of Major Natural Gas Supply Basins Relative to Natural Gas Pipeline Transportation Corridors see related text enlarge see related text enlarge U.S. Regional Breakdown

  10. Nonisothermal Two-Phase Porous Flow

    Energy Science and Technology Software Center (OSTI)

    1992-02-21

    NORIA is a finite element program that simultaneously solves four nonlinear parabolic, partial differential equations that describe the transport of water, water vapor, air, and energy through partially saturated porous media. NORIA is designed for the analysis of two-dimensional, non-isothermal, unsaturated porous flow problems. Nearly all material properties, such as permeability, can either be set to constant values or defined as functions of the dependent and independent variables by user-supplied subroutines. The gas phase ismore » taken to be ideal. NORIA is intended to solve nonisothermal problems in which large gradients are expected in the gas pressure.« less

  11. EIA - Natural Gas Pipeline Network - Natural Gas Pipeline Mileage...

    U.S. Energy Information Administration (EIA) Indexed Site

    Mileage by State About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Estimated Natural Gas Pipeline Mileage in the...

  12. EIA - Natural Gas Pipeline Network - Natural Gas Transmission...

    U.S. Energy Information Administration (EIA) Indexed Site

    Transmission Path Diagram About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates Natural Gas Transmission Path Natural...

  13. Quantum Dynamics of Elementary Reactions in the Gas Phase and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a promising route for producing hydrogen from primary fuels is via steam reforming of methanol. Thus, future studies will concentrate on HO + CO --> H + CO2, which is also the...

  14. World Natural Gas Model

    Energy Science and Technology Software Center (OSTI)

    1994-12-01

    RAMSGAS, the Research and Development Analysis Modeling System World Natural Gas Model, was developed to support planning of unconventional gaseoues fuels research and development. The model is a scenario analysis tool that can simulate the penetration of unconventional gas into world markets for oil and gas. Given a set of parameter values, the model estimates the natural gas supply and demand for the world for the period from 1980 to 2030. RAMSGAS is based onmore » a supply/demand framwork and also accounts for the non-renewable nature of gas resources. The model has three fundamental components: a demand module, a wellhead production cost module, and a supply/demand interface module. The demand for gas is a product of total demand for oil and gas in each of 9 demand regions and the gas share. Demand for oil and gas is forecast from the base year of 1980 through 2030 for each demand region, based on energy growth rates and price-induced conservation. For each of 11 conventional and 19 unconventional gas supply regions, wellhead production costs are calculated. To these are added transportation and distribution costs estimates associated with moving gas from the supply region to each of the demand regions and any economic rents. Based on a weighted average of these costs and the world price of oil, fuel shares for gas and oil are computed for each demand region. The gas demand is the gas fuel share multiplied by the total demand for oil plus gas. This demand is then met from the available supply regions in inverse proportion to the cost of gas from each region. The user has almost complete control over the cost estimates for each unconventional gas source in each year and thus can compare contributions from unconventional resources under different cost/price/demand scenarios.« less

  15. Quantum Phase Transition in a Two-Dimensional System of Dipoles

    SciTech Connect (OSTI)

    Astrakharchik, G. E.; Boronat, J.; Kurbakov, I. L.; Lozovik, Yu. E.

    2007-02-09

    The ground-state phase diagram of a two-dimensional Bose system with dipole-dipole interactions is studied by means of a quantum Monte Carlo technique. Our calculation predicts a quantum phase transition from a gas to a solid phase when the density increases. In the gas phase, the condensate fraction is calculated as a function of the density. Using the Feynman approximation, the collective excitation branch is studied and the appearance of a roton minimum is observed. The results of the static structure factor at both sides of the gas-solid phase are also presented. The Lindemann ratio at the transition point becomes {gamma}=0.230(6). The condensate fraction in the gas phase is estimated as a function of the density.

  16. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage was 2,414 Bcf as of Friday, January 9,...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage was 821 Bcf as of May 2, according to...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Natural gas stocks stood at 2,155 Bcf as of Friday, July 9,...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage as of September 2 totaled 2,669 Bcf,...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the Northeast were expected to be in the single digits. Prices off Transcontinental Gas Pipe Line in New York and Algonquin Gas Transmission in the New England region yesterday...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    by 14.4 percent. During this period, U.S. manufacturers used less petroleum and coal in manufacturing processes. This expansion of gas use occurred although natural gas prices to...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    withdrawal from working gas storage reported last Thursday. A contributing factor to the run-up in natural gas prices could be climbing crude oil prices, which rallied late last...

  3. EIA - Natural Gas Publications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    these data from 2005 to 2009 are presented for each State. (12282010) U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves: 2009 National and State...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    week's gas markets. As of Friday, May 11, 2001, the spot price of natural gas at the Henry Hub dropped 0.24 from the previous Friday to 4.25 per MMBtu. The NYMEX price of...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.217 per MMBtu on Wednesday. The natural gas rotary rig...

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    York Mercantile Exchange (NYMEX), the August 2011 natural gas contract price also lost ground over the week, closing at 4.315 per MMBtu on Wednesday. The natural gas rotary rig...

  7. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas into storage. However, shut-in natural gas production in the Gulf of Mexico reduced available current supplies, and so limited net injections during the report...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    while the OFO was in effect. Pacific Gas and Electric Company extended a systemwide high-inventory OFO on its California Gas Transmission system through Saturday, July 5. It was...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    the OFO customers who delivered more than 110 percent of their actual gas usage into the system would be assessed for charges. Pacific Gas and Electric Company issued a...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Btu per cubic foot as published in Table A4 of the Annual Energy Review 2002. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in...

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in storage...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    gas in storage, as well as decreases in the price of crude oil. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage increased to 2,905 Bcf as of...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas in...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of natural gas into storage, despite robust inventories. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage increased to 3,258 Bcf as of...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    to withdraw natural gas from storage to meet current demand. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage decreased to 2,406 Bcf as of...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Btu per cubic foot as published in Table A2 of the Annual Energy Review 2001. Source: Energy Information Administration, Office of Oil and Gas. Storage: Working gas inventories...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Working gas in storage was 3,121 Bcf as of Friday, Oct 24, 2003, according to the Energy Information Administration (EIA) Weekly Natural Gas Storage Report. This is 2.7...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    gas in combination with water. Gas hydrate is thought to exist in great abundance in nature and has the potential to be a significant new energy source to meet future energy...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    heating-related demand for natural gas that limited the size of the net addition to storage. The economic incentives for storing natural gas for next winter are considerably...

  1. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on Thursday, May 9, 2002. A sample of EIA's report can be seen at: Weekly Gas Storage Test Page. The Natural Gas Weekly Market Update report will convert to the new data series...

  2. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    The report provides an overview of U.S. international trade in 2008 as well as historical data on natural gas imports and exports. Net natural gas imports accounted for only 13...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of 1 Tcf from the 1994 estimate of 51 Tcf. Ultimate potential for natural gas is a science-based estimate of the total amount of conventional gas in the province and is an...

  4. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, John F. (601 Oakwood Loop, NE., Albuquerque, NM 87123)

    1992-01-01

    A positive displacement, recirculating Roots-type rotary gas compressor which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits (24 and 26) which return compressed discharge gas to the compressor housing (14), where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers (10 and 12) and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor.

  5. Recirculating rotary gas compressor

    DOE Patents [OSTI]

    Weinbrecht, J.F.

    1992-02-25

    A positive displacement, recirculating Roots-type rotary gas compressor is described which operates on the basis of flow work compression. The compressor includes a pair of large diameter recirculation conduits which return compressed discharge gas to the compressor housing, where it is mixed with low pressure inlet gas, thereby minimizing adiabatic heating of the gas. The compressor includes a pair of involutely lobed impellers and an associated port configuration which together result in uninterrupted flow of recirculation gas. The large diameter recirculation conduits equalize gas flow velocities within the compressor and minimize gas flow losses. The compressor is particularly suited to applications requiring sustained operation at higher gas compression ratios than have previously been feasible with rotary pumps, and is particularly applicable to refrigeration or other applications requiring condensation of a vapor. 12 figs.

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    10 (next release 2:00 p.m. on March 17) Natural gas spot prices increased this week (Wednesday to Wednesday, March 2-9) as a late season cold front moved into major gas-consuming...

  7. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    next heating season. Net injections reported in today's release of EIA's Weekly Natural Gas Storage Report brought natural gas storage supplies to 2,163 Bcf as of Friday, June 1,...

  8. Natural gas annual 1996

    SciTech Connect (OSTI)

    1997-09-01

    This document provides information on the supply and disposition of natural gas to a wide audience. The 1996 data are presented in a sequence that follows natural gas from it`s production to it`s end use.

  9. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    delivery volumes. Northern Natural Gas Company issued a system overrun limitation (SOL) for all market-area zones for gas day February 21, 2008. The SOL was the result of...

  10. Landfill Gas | Open Energy Information

    Open Energy Info (EERE)

    Gas Jump to: navigation, search TODO: Add description List of Landfill Gas Incentives Retrieved from "http:en.openei.orgwindex.php?titleLandfillGas&oldid267173...

  11. Natural gas annual 1995

    SciTech Connect (OSTI)

    1996-11-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1995 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1991 to 1995 for each Census Division and each State. Annual historical data are shown at the national level.

  12. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M. (Peralta, NM)

    2012-07-31

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  13. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels | Prices | States | International | Country Analysis...

  14. ARM - Methane Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Gas Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Methane Gas Methane gas is another naturally occurring greenhouse gas. It is produced as a result of microbial activity in the absence of oxygen. Pre-industrial concentrations of methane were about 700 ppb and in 1994 they were up

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Independence Avenue, SW Washington, DC 20585 . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels |...

  16. Static gas expansion cooler

    DOE Patents [OSTI]

    Guzek, J.C.; Lujan, R.A.

    1984-01-01

    Disclosed is a cooler for television cameras and other temperature sensitive equipment. The cooler uses compressed gas ehich is accelerated to a high velocity by passing it through flow passageways having nozzle portions which expand the gas. This acceleration and expansion causes the gas to undergo a decrease in temperature thereby cooling the cooler body and adjacent temperature sensitive equipment.

  17. Natural gas industry directory

    SciTech Connect (OSTI)

    1999-11-01

    This directory has information on the following: associations and organizations; exploration and production; gas compression; gas processors; gathering and transmission companies; liquefied natural gas; local distribution companies; marketing firms; regulatory agencies; service companies; suppliers and manufacturers; and regional buyer`s guide.

  18. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, C.A.; Rurbage, C.H.

    1982-03-17

    The invention is pneumatically operated valve assembly for simulatenously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two on the lines so closed. The value assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  19. A gas-loading system for LANL two-stage gas guns

    SciTech Connect (OSTI)

    Gibson, Lloyd Lee; Bartram, Brian Douglas; Dattelbaum, Dana Mcgraw; Lang, John Michael; Morris, John Scott

    2015-09-01

    A novel gas loading system was designed for the specific application of remotely loading high purity gases into targets for gas-gun driven plate impact experiments. The high purity gases are loaded into well-defined target configurations to obtain Hugoniot states in the gas phase at greater than ambient pressures.The small volume of the gas samples is challenging, as slight changing in the ambient temperature result in measurable pressure changes. Therefore, the ability to load a gas gun target and continually monitor the sample pressure prior to firing provides the most stable and reliable target fielding approach. We present the design and evaluation of a gas loading system built for the LANL 50 mm bore two-stage light gas gun. Targets for the gun are made of 6061 Al or OFHC Cu, and assembled to form a gas containment cell with a volume of approximately 1.38 cc. The compatibility of materials was a major consideration in the design of the system, particularly for its use with corrosive gases. Piping and valves are stainless steel with wetted seals made from Kalrez® and Teflon®. Preliminary testing was completed to ensure proper flow rate and that the proper safety controls were in place. The system has been used to successfully load Ar, Kr, Xe, and anhydrous ammonia with purities of up to 99.999 percent. The design of the system and example data from the plate impact experiments will be shown.

  20. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    1998-12-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE?s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, James A. (Idaho Falls, ID); Johnson, John A. (Idaho Falls, ID)

    1992-01-01

    A system for detecting the phase of a frequency of phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2.pi. when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2.pi. when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention.

  2. Digital quadrature phase detection

    DOE Patents [OSTI]

    Smith, J.A.; Johnson, J.A.

    1992-05-26

    A system for detecting the phase of a frequency or phase modulated signal that includes digital quadrature sampling of the frequency or phase modulated signal at two times that are one quarter of a cycle of a reference signal apart, determination of the arctangent of the ratio of a first sampling of the frequency or phase modulated signal to the second sampling of the frequency or phase modulated signal, and a determination of quadrant in which the phase determination is increased by 2[pi] when the quadrant changes from the first quadrant to the fourth quadrant and decreased by 2[pi] when the quadrant changes from the fourth quadrant to the first quadrant whereby the absolute phase of the frequency or phase modulated signal can be determined using an arbitrary reference convention. 6 figs.

  3. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  4. Gas revenue increasingly significant

    SciTech Connect (OSTI)

    Megill, R.E.

    1991-09-01

    This paper briefly describes the wellhead prices of natural gas compared to crude oil over the past 70 years. Although natural gas prices have never reached price parity with crude oil, the relative value of a gas BTU has been increasing. It is one of the reasons that the total amount of money coming from natural gas wells is becoming more significant. From 1920 to 1955 the revenue at the wellhead for natural gas was only about 10% of the money received by producers. Most of the money needed for exploration, development, and production came from crude oil. At present, however, over 40% of the money from the upstream portion of the petroleum industry is from natural gas. As a result, in a few short years natural gas may become 50% of the money revenues generated from wellhead production facilities.

  5. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, Kwan H. (Lisle, IL); Ahluwalia, Rajesh K. (Clarendon Hills, IL)

    1985-01-01

    A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

  6. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a lower heat transfer rate in the internal heat exchanger than was designed. It is believed that the fins on the heat-exchanger tubes did not make proper contact with the tubes transporting the chilled glycol, and pairs of fins were too close for interior areas of fins to serve as hydrate collection sites. A correction of the fabrication fault in the heat exchanger fin attachments could be easily made to provide faster formation rates. The storage success with the POC process provides valuable information for making the process an economically viable process for safe, aboveground natural-gas storage.

  7. High temperature coatings for gas turbines

    DOE Patents [OSTI]

    Zheng, Xiaoci Maggie

    2003-10-21

    Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

  8. U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Refinery Gas (Million Cubic Feet) U.S. Natural Gas Supplemental Gas - Refinery Gas (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...

  9. BASIN-CENTERED GAS SYSTEMS OF THE U.S.

    SciTech Connect (OSTI)

    Marin A. Popov; Vito F. Nuccio; Thaddeus S. Dyman; Timothy A. Gognat; Ronald C. Johnson; James W. Schmoker; Michael S. Wilson; Charles Bartberger

    2000-11-01

    The USGS is re-evaluating the resource potential of basin-centered gas accumulations in the U.S. because of changing perceptions of the geology of these accumulations, and the availability of new data since the USGS 1995 National Assessment of United States oil and gas resources (Gautier et al., 1996). To attain these objectives, this project used knowledge of basin-centered gas systems and procedures such as stratigraphic analysis, organic geochemistry, modeling of basin thermal dynamics, reservoir characterization, and pressure analysis. This project proceeded in two phases which had the following objectives: Phase I (4/1998 through 5/1999): Identify and describe the geologic and geographic distribution of potential basin-centered gas systems, and Phase II (6/1999 through 11/2000): For selected systems, estimate the location of those basin-centered gas resources that are likely to be produced over the next 30 years. In Phase I, we characterize thirty-three (33) potential basin-centered gas systems (or accumulations) based on information published in the literature or acquired from internal computerized well and reservoir data files. These newly defined potential accumulations vary from low to high risk and may or may not survive the rigorous geologic scrutiny leading towards full assessment by the USGS. For logistical reasons, not all basins received the level of detail desired or required.

  10. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  11. Method and apparatus for pressurizing a liquefied gas

    DOE Patents [OSTI]

    Bingham, Dennis N.

    2005-07-26

    Apparatus providing at least one thermoelectric device for pressurizing a liquefied gas container and methods employing same are disclosed. A thermoelectric device including a heating surface and a cooling surface is used for pressurizing a container by vaporizing liquefied gas within the container by transferring heat energy from a portion of the liquefied gas in contact with the cooling surface to another portion of the liquefied gas in contact with the heating surface of the thermoelectric device to convert some of the liquefied gas to a vapor state. Liquefied gas vapor and/or liquid phase may be supplied by disclosed apparatus and methods. The apparatus may also be used as a vapor pump or a liquid pump, or fluid pump. Methods of operation are also disclosed.

  12. Dewatering of coalbed methane wells with hydraulic gas pump

    SciTech Connect (OSTI)

    Amani, M.; Juvkam-Wold, H.C.

    1995-12-31

    The coalbed methane industry has become an important source of natural gas production. Proper dewatering of coalbed methane (CBM) wells is the key to efficient gas production from these reservoirs. This paper presents the Hydraulic Gas Pump as a new alternative dewatering system for CBM wells. The Hydraulic Gas Pump (HGP) concept offers several operational advantages for CBM wells. Gas interference does not affect its operation. It resists solids damage by eliminating the lift mechanism and reducing the number of moving parts. The HGP has a flexible production rate and is suitable for all production phases of CBM wells. It can also be designed as a wireline retrievable system. We conclude that the Hydraulic Gas Pump is a suitable dewatering system for coalbed methane wells.

  13. Phase-field Modeling of Displacive Phase Transformations in Elasticall...

    Office of Scientific and Technical Information (OSTI)

    Phase-field Modeling of Displacive Phase Transformations in Elastically Anisotropic and Inhomogeneous Polycrystals Citation Details In-Document Search Title: Phase-field Modeling...

  14. Critical point analysis of phase envelope diagram

    SciTech Connect (OSTI)

    Soetikno, Darmadi; Siagian, Ucok W. R.; Kusdiantara, Rudy Puspita, Dila Sidarto, Kuntjoro A. Soewono, Edy; Gunawan, Agus Y.

    2014-03-24

    Phase diagram or phase envelope is a relation between temperature and pressure that shows the condition of equilibria between the different phases of chemical compounds, mixture of compounds, and solutions. Phase diagram is an important issue in chemical thermodynamics and hydrocarbon reservoir. It is very useful for process simulation, hydrocarbon reactor design, and petroleum engineering studies. It is constructed from the bubble line, dew line, and critical point. Bubble line and dew line are composed of bubble points and dew points, respectively. Bubble point is the first point at which the gas is formed when a liquid is heated. Meanwhile, dew point is the first point where the liquid is formed when the gas is cooled. Critical point is the point where all of the properties of gases and liquids are equal, such as temperature, pressure, amount of substance, and others. Critical point is very useful in fuel processing and dissolution of certain chemicals. Here in this paper, we will show the critical point analytically. Then, it will be compared with numerical calculations of Peng-Robinson equation by using Newton-Raphson method. As case studies, several hydrocarbon mixtures are simulated using by Matlab.

  15. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Office of Environmental Management (EM)

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows: *How does exported liquefied natural gas (LNG) from the U.S. compare

  16. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1985-12-31

    An apparatus is disclosed for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area. 3 figs.

  17. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, Daniel (Los Alamos, NM)

    1985-01-01

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  18. Gas shielding apparatus

    DOE Patents [OSTI]

    Brandt, D.

    1984-06-05

    An apparatus for preventing oxidation by uniformly distributing inert shielding gas over the weld area of workpieces such as pipes being welded together. The apparatus comprises a chamber and a gas introduction element. The chamber has an annular top wall, an annular bottom wall, an inner side wall and an outer side wall connecting the top and bottom walls. One side wall is a screen and the other has a portion defining an orifice. The gas introduction element has a portion which encloses the orifice and can be one or more pipes. The gas introduction element is in fluid communication with the chamber and introduces inert shielding gas into the chamber. The inert gas leaves the chamber through the screen side wall and is dispersed evenly over the weld area.

  19. Hydrate Control for Gas Storage Operations

    SciTech Connect (OSTI)

    Jeffrey Savidge

    2008-10-31

    The overall objective of this project was to identify low cost hydrate control options to help mitigate and solve hydrate problems that occur in moderate and high pressure natural gas storage field operations. The study includes data on a number of flow configurations, fluids and control options that are common in natural gas storage field flow lines. The final phase of this work brings together data and experience from the hydrate flow test facility and multiple field and operator sources. It includes a compilation of basic information on operating conditions as well as candidate field separation options. Lastly the work is integrated with the work with the initial work to provide a comprehensive view of gas storage field hydrate control for field operations and storage field personnel.

  20. Pulsed gas laser

    DOE Patents [OSTI]

    Anderson, Louis W.; Fitzsimmons, William A.

    1978-01-01

    A pulsed gas laser is constituted by Blumlein circuits wherein space metal plates function both as capacitors and transmission lines coupling high frequency oscillations to a gas filled laser tube. The tube itself is formed by spaced metal side walls which function as connections to the electrodes to provide for a high frequency, high voltage discharge in the tube to cause the gas to lase. Also shown is a spark gap switch having structural features permitting a long life.

  1. Natural Gas Citygate Price

    Gasoline and Diesel Fuel Update (EIA)

    Citygate Price Residential Price Commercial Price Industrial Price Electric Power Price Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas Wells Gross Withdrawals From Coalbed Wells Repressuring Nonhydrocarbon Gases Removed Vented and Flared Marketed Production NGPL Production, Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports By Pipeline LNG Exports Underground Storage Capacity Gas in Underground

  2. Natural Gas Industrial Price

    Gasoline and Diesel Fuel Update (EIA)

    Citygate Price Residential Price Commercial Price Industrial Price Electric Power Price Gross Withdrawals Gross Withdrawals From Gas Wells Gross Withdrawals From Oil Wells Gross Withdrawals From Shale Gas Wells Gross Withdrawals From Coalbed Wells Repressuring Nonhydrocarbon Gases Removed Vented and Flared Marketed Production NGPL Production, Gaseous Equivalent Dry Production Imports By Pipeline LNG Imports Exports Exports By Pipeline LNG Exports Underground Storage Capacity Gas in Underground

  3. Valve for gas centrifuges

    DOE Patents [OSTI]

    Hahs, Charles A.; Burbage, Charles H.

    1984-01-01

    The invention is a pneumatically operated valve assembly for simultaneously (1) closing gas-transfer lines connected to a gas centrifuge or the like and (2) establishing a recycle path between two of the lines so closed. The valve assembly is especially designed to be compact, fast-acting, reliable, and comparatively inexpensive. It provides large reductions in capital costs for gas-centrifuge cascades.

  4. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    over the next few days. To avoid penalties, Northwest requested that customers stay within their scheduled volumes, and asked customers who owe gas to Northwest north of...

  6. Breathable gas distribution apparatus

    DOE Patents [OSTI]

    Garcia, Elmer D. (Los Alamos, NM)

    1985-01-01

    The disclosure is directed to an apparatus for safely supplying breathable gas or air through individual respirators to personnel working in a contaminated area.

  7. Unconventional Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 4.2.1.1 Shale Gas Drilling and Fracturing Fluids ......86 4.2.1.2 Coalbed Methane Drilling and Fracturing ...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    kept up significant downward pressure on both cash and futures prices. Lower prices may eventually lead to fewer rigs exploring for gas, thereby stemming the growth in production....

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6, 2009 Next Release: August 13, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 5, 2009) Natural...

  10. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, July 1, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 23, 2010)...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 9, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 1,...

  12. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, January 14, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 6,...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, November 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 11,...

  14. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, June 17, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 9, 2010)...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 12, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 4, 2010)...

  16. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, September 2, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 25,...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, August 5, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 28, 2010)...

  18. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: Thursday, May 13, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 5, 2010)...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2009 Next Release: April 16, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 8, 2009) Since...

  20. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Next Release: January 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 14, 2009) In...

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16, 2009 Next Release: April 23, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 15, 2009) Since...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 to Wednesday, December 12) Released: December 13 Next release: December 20, 2007 Natural gas spot and futures prices increased this report week (Wednesday to Wednesday,...

  3. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, April 15, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 7, 2010) Since...

  4. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, February 25, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 17, 2010)...

  5. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, March 18, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 10, 2010) Since...

  6. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 24, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 16, 2011) With...

  7. Natural gas annual 1997

    SciTech Connect (OSTI)

    1998-10-01

    The Natural Gas Annual provides information on the supply and disposition of natural gas to a wide audience including industry, consumers, Federal and State agencies, and educational institutions. The 1997 data are presented in a sequence that follows natural gas (including supplemental supplies) from its production to its end use. This is followed by tables summarizing natural gas supply and disposition from 1993 to 1997 for each Census Division and each State. Annual historical data are shown at the national level. 27 figs., 109 tabs.

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Market Trends: The Minerals Management Service Reports Royalty Gas Sale for the First Time in Offshore Louisiana. On November 4, the Minerals Management Service (MMS) of the...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    constraint. Pacific Gas and Electric Company issued a systemwide Stage 2 high-inventory OFO for Saturday, May 5, because of projections that linepack on the California...

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Other Market Trends EIA Proposes Extending Oil and Natural Gas Reserves Survey Forms. The Energy Information Administration (EIA) on July 15 published a notice in the Federal...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on December 9, falling from somewhat higher intraweek levels. Wellhead Prices Annual Energy Review More Price Data Storage Working gas in storage dropped 64 Bcf during the...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    and October 2010 contracts all fell by less than 1 cent. Wellhead Prices Annual Energy Review More Price Data Storage Working natural gas inventories set a new record,...

  13. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    recorded last year. Other Market Trends: FERC Releases Report on Underground Natural Gas Storage: The Federal Energy Regulatory Commission (FERC) issued a report last week that...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Estimates Database. Other Market Trends: Comments Received on Proposed Weekly Natural Gas Storage Report Revision Policy: The Energy Information Administration (EIA) solicited...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    compared with its settlement price a week ago, ending yesterday at 5.974 per MMBtu. The Energy Information Administration (EIA) reported that natural gas inventories in...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    storage facilities. Other Market Trends: EIA Releases Report on Underground Natural Gas Storage Developments: The Energy Information Administration (EIA) released a special...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    oil and gas resources will be necessary even as efficiency improvements reduce demand and renewable sources become more available. In order to retain public trust environmentally...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: July 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 2, 2009) Since...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6, 2008 Next Release: November 14, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, November 5) Since...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    0, 2009 Next Release: August 6, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, July 29, 2009) Since...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    7, 2008 Next Release: July 24, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview The report week ended July 16 registered significant...

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Inventory of Onshore Federal Lands' Oil and Gas Resources and the Extent and Nature of Restrictions or Impediments to Their Development. The report, which was...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Accounting Standards Board. The changes will allow FERC an understanding of the nature and extent to which hedging activities are used by electric utilities and gas...

  4. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    storm activity has been above average this year, there has been little impact on natural gas markets. Tropical Depression 6 showed up in the eastern Caribbean early this...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: December 11, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the week ending Wednesday, December 3, 2008) Since...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    9, 2009 Next Release: March 26, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 18, 2009) Warmer...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    P.M. Next Release: October 29, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 21, 2009) Since...

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2008 Next Release: October 2, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, September 17, to Wednesday, September 24)...

  9. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, January 20, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 12, 2011)...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    with hopes for the eventual return of winter was likely the catalyst enabling natural gas prices to recapture the 4 mark this week despite an environment of negative...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Release: Thursday, May 19, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 11, 2011) Natural...

  12. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Thursday, September 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 8, 2010) Price...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thursday, September 23, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, September 15, 2010)...

  14. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Next Release: Thursday, May 12, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, May 4, 2011) Wholesale...

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    which summarizes the likely demand, supply, and prices for natural gas, heating oil, propane, and electricity during the upcoming winter (October 2004 - March 2005). According to...

  16. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Storage Estimates Database. Other Market Trends: EIA Releases New Report on the Fundamentals of Natural Gas Storage: EIA prepared a new report to provide general background...

  17. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Significant New Deepwater Oil and Natural Gas Discovery: A successful production test in the deepwater Gulf of Mexico has confirmed a significant new oil play in the lower...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Other Market Trends: MMS Issues Final Notice of Western Gulf Lease Sale: The Minerals Management Service (MMS) will offer several incentives to increase domestic oil and gas...

  19. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    average, the general price level in the natural gas market has shown surprising resilience over the past few weeks. After an extended price decline since mid December, spot...

  20. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    planning information that will assist in maintaining the operational integrity and reliability of pipeline service, as well as providing gas-fired power plant operators with...

  1. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 7, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 16, 2009)...

  2. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    P.M. Next Release: November 5, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 28, 2009)...

  3. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, March 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 24, 2010)...

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, April 28, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 20, 2011) Natural...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Release: Thursday, January 6, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 15, 2010)...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the technology that drove Enron's North American wholesale electricity and natural gas trading unit. That technology, together with reportedly over 600 former Enron...

  7. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, August 26, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 18, 2010) Natural...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    , 2009 Next Release: April 9, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, April 1, 2009) Despite a...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    2009 Next Release: February 19, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, February 11, 2009)...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, November 4, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 27, 2010) As the...

  11. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: November 20, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (Wednesday, November 5, to Thursday, November 13)...

  12. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Release: Thursday, October 28, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, October 20, 2010)...

  13. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 3, 2008) Released: January 4, 2008 Next release: January 10, 2008 Natural gas spot and futures prices increased this report week (Wednesday to Thursday, December 26,...

  14. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Wednesday, November 10, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, November 3, 2010) Price...

  15. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, August 19, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, August 11, 2010) Summer...

  16. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2008 Next Release: October 23, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For week ending Wednesday, October 15) Since Wednesday,...

  17. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, February 3, 2011 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 26, 2011)...

  18. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    requested by Secretary of Energy Spencer Abraham in an effort to enhance natural gas market information and efficiency. Survey respondents would include all operators of...

  19. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Thursday, December 16, 2010 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, December 8, 2010) In...

  20. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    Historical Natural Gas Annual . 1996 Published October 1997 1997 Published October 1998 1998 Published October 1999 1999 Published October 2000 2000 Published December 2001

  1. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the New York Mercantile Exchange (NYMEX), futures prices also increased this week in tandem with the crude oil prices. The natural gas futures contract for delivery in June...

  2. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  3. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, January 7, 2009) Since Wednesday, December...

  4. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    March 12, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, March 4, 2009) A late winter cold spell in...

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    data to EIA. The number of companies reporting increased by 3 from 2008, to include Alon USA, Chalmette Refining LLC, and Western Refining, Inc. Natural Gas Transportation Update...

  6. Polyport atmospheric gas sampler

    DOE Patents [OSTI]

    Guggenheim, S. Frederic (Teaneck, NJ)

    1995-01-01

    An atmospheric gas sampler with a multi-port valve which allows for multi, sequential sampling of air through a plurality of gas sampling tubes mounted in corresponding gas inlet ports. The gas sampler comprises a flow-through housing which defines a sampling chamber and includes a gas outlet port to accommodate a flow of gases through the housing. An apertured sample support plate defining the inlet ports extends across and encloses the sampling chamber and supports gas sampling tubes which depend into the sampling chamber and are secured across each of the inlet ports of the sample support plate in a flow-through relation to the flow of gases through the housing during sampling operations. A normally closed stopper means mounted on the sample support plate and operatively associated with each of the inlet ports blocks the flow of gases through the respective gas sampling tubes. A camming mechanism mounted on the sample support plate is adapted to rotate under and selectively lift open the stopper spring to accommodate a predetermined flow of gas through the respective gas sampling tubes when air is drawn from the housing through the outlet port.

  7. Shale Gas Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Production (Billion Cubic Feet) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes 2009 2010 2011 2012...

  8. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    As of February 14, Northern Natural Gas implemented a system overrun limitation (SOL) affecting all market area zones. These zones are located in the northern part of the...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Gas Company, for example, on Tuesday, October 21, issued a system overrun limitation (SOL) that allows for penalties on variances between flows and nominations. The SOL is in...

  10. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Government Accountability Office into specific leases that excluded price threshold language and a court action by Kerr-McGee Oil and Gas Corporation challenging the Department...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Upward pressure on prices at the NYMEX also appears related to concerns over events in Japan that could affect energy markets. Japan, the worlds largest liquefied natural gas...

  12. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Historical Natural Gas Annual . 1996 Published October 1997 1997 Published October 1998 1998 Published October 1999 1999 Published October 2000 2000 Published December 2001

  13. Crystal phase identification

    DOE Patents [OSTI]

    Michael, Joseph R. (Albuquerque, NM); Goehner, Raymond P. (Albuquerque, NM); Schlienger, Max E. (Albuquerque, NM)

    2001-01-01

    A method and apparatus for determining the crystalline phase and crystalline characteristics of a sample. This invention provides a method and apparatus for unambiguously identifying and determining the crystalline phase and crystalline characteristics of a sample by using an electron beam generator, such as a scanning electron microscope, to obtain a backscattered electron Kikuchi pattern of a sample, and extracting crystallographic and composition data that is matched to database information to provide a quick and automatic method to identify crystalline phases.

  14. Phase Change | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Change June 16, 2009 Phase change is a phrase used in physics to indicate a change of the state of matter. For example, some materials can be in the solid, liquid or gaseous phases. Water can be ice liquid water, or steam. Chemically, it is essentially the same entity, but looks, feels and behaves quite differently. Sometimes the change of phase happens very quickly, sometimes relatively slowly. Toss an ice cube into a hot fire and the water doesn't stay very long as a solid, passing

  15. Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas

    SciTech Connect (OSTI)

    Huang, Hann-Sheng; Livengood, Charles David

    1997-12-01

    A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

  16. Alabama Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  17. Louisiana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 159,456 166,570 164,270 166,973 161,280 163,799 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  18. Indiana Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  19. Maryland Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  20. Nevada Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  1. Virginia Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  2. Illinois Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  3. Colorado Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 139,822 143,397 138,325 144,845 139,698 141,947 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  4. Kentucky Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  5. Texas Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 752,341 754,086 731,049 739,603 714,788 720,593 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  6. Pennsylvania Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 398,737 408,325 396,931 404,431 403,683 429,251 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  7. Wyoming Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Gross Withdrawals 168,548 167,539 162,880 167,555 163,345 165,658 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  8. Missouri Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  9. Tennessee Natural Gas Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    Production (Million Cubic Feet) Gross Withdrawals NA NA NA NA NA NA 1991-2015 From Gas Wells NA NA NA NA NA NA 1991-2015 From Oil Wells NA NA NA NA NA NA 1991-2015 From Shale Gas ...

  10. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  11. Gas pump with movable gas pumping panels

    DOE Patents [OSTI]

    Osher, John E. (Alamo, CA)

    1984-01-01

    Apparatus for pumping gas continuously a plurality of articulated panels of getter material, each of which absorbs gases on one side while another of its sides is simultaneously reactivated in a zone isolated by the panels themselves from a working space being pumped.

  12. Thermoacoustic natural gas liquefier

    SciTech Connect (OSTI)

    Swift, G.; Gardner, D.; Hayden, M.; Radebaugh, R.; Wollan, J.

    1996-07-01

    This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop a natural-gas-powered natural-gas liquefier that has absolutely no moving parts and requires no electrical power. It should have high efficiency, remarkable reliability, and low cost. The thermoacoustic natural-gas liquefier (TANGL) is based on our recent invention of the first no-moving-parts cryogenic refrigerator. In short, our invention uses acoustic phenomena to produce refrigeration from heat, with no moving parts. The required apparatus comprises nothing more than heat exchangers and pipes, made of common materials, without exacting tolerances. Its initial experimental success in a small size lead us to propose a more ambitious application: large-energy liquefaction of natural gas, using combustion of natural gas as the energy source. TANGL was designed to be maintenance-free, inexpensive, portable, and environmentally benign.

  13. Supersonic gas compressor

    DOE Patents [OSTI]

    Lawlor, Shawn P. (Bellevue, WA); Novaresi, Mark A. (San Diego, CA); Cornelius, Charles C. (Kirkland, WA)

    2007-11-13

    A gas compressor based on the use of a driven rotor having a compression ramp traveling at a local supersonic inlet velocity (based on the combination of inlet gas velocity and tangential speed of the ramp) which compresses inlet gas against a stationary sidewall. In using this method to compress inlet gas, the supersonic compressor efficiently achieves high compression ratios while utilizing a compact, stabilized gasdynamic flow path. Operated at supersonic speeds, the inlet stabilizes an oblique/normal shock system in the gasdyanamic flow path formed between the rim of the rotor, the strakes, and a stationary external housing. Part load efficiency is enhanced by the use of a pre-swirl compressor, and using a bypass stream to bleed a portion of the intermediate pressure gas after passing through the pre-swirl compressor back to the inlet of the pre-swirl compressor. Inlet guide vanes to the compression ramp enhance overall efficiency.

  14. Cryogenic treatment of gas

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

    2012-04-03

    Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

  15. Baltimore Gas & Electric Company (Gas)- Residential Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    The Baltimore Gas & Electric Company (BGE) offers Natural Gas Connection program to residential customers to switch from electric to natural gas for heat. The program waives connection charge (...

  16. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  17. Virginia Natural Gas in Underground Storage (Working Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Virginia Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0...

  18. Tennessee Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Tennessee Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0...

  19. Texas Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Texas Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 134,707 134,707...

  20. Washington Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Washington Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 21,300 21,300...

  1. Alaska Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Alaska Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 7,622 14,197...

  2. Utah Natural Gas in Underground Storage (Base Gas) (Million Cubic...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Utah Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 46,944 46,944...

  3. Virginia Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Virginia Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0 0 0 0...

  4. Missouri Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Missouri Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 21,600 21,600...

  5. Maryland Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Maryland Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 46,677 46,677...

  6. Indiana Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Indiana Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 74,572 74,572...

  7. Kentucky Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Kentucky Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 105,889 105,889...

  8. Washington Natural Gas in Underground Storage (Working Gas) ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Washington Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 8,882...

  9. Missouri Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Missouri Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 8,081...

  10. Michigan Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Michigan Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 395,529 395,529...

  11. Louisiana Natural Gas in Underground Storage (Working Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Louisiana Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 115,418...

  12. Minnesota Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Minnesota Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 4,655 4,655...

  13. Colorado Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Colorado Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 27,491...

  14. Pennsylvania Natural Gas in Underground Storage (Working Gas...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Pennsylvania Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990...

  15. Ohio Natural Gas in Underground Storage (Base Gas) (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Ohio Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 338,916 338,916...

  16. Alabama Natural Gas in Underground Storage (Working Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Working Gas) (Million Cubic Feet) Alabama Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 499 497...

  17. Wyoming Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Wyoming Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 31,205 31,205...

  18. Ohio Natural Gas in Underground Storage (Working Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Ohio Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 100,467...

  19. Arkansas Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Arkansas Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 19,202 19,202...

  20. Arkansas Natural Gas in Underground Storage (Working Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Arkansas Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 8,676...

  1. Oklahoma Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Oklahoma Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 167,385 163,458...

  2. Oregon Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Oregon Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 3,291 3,291 3,291...

  3. Utah Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Utah Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 12,862 9,993...

  4. Mississippi Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Mississippi Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 46,050...

  5. Louisiana Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Louisiana Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 262,136...

  6. Alabama Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) Alabama Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1995 880 880 880 880...

  7. Nebraska Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Nebraska Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 55,226...

  8. Nebraska Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Nebraska Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 27,312 27,312...

  9. Iowa Natural Gas in Underground Storage (Base Gas) (Million Cubic...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Iowa Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 153,933 153,933...

  10. Oklahoma Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Oklahoma Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 129,245...

  11. Oregon Natural Gas in Underground Storage (Working Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Oregon Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 3,705 2,366...

  12. Maryland Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Maryland Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 4,303...

  13. Colorado Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) Colorado Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 39,062 39,062...

  14. Alaska Natural Gas in Underground Storage (Working Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Working Gas) (Million Cubic Feet) Alaska Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2013 8,956...

  15. Tennessee Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) Tennessee Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1997 0 0 0 0 0 0 0...

  16. Mississippi Natural Gas in Underground Storage (Working Gas)...

    Gasoline and Diesel Fuel Update (EIA)

    Working Gas) (Million Cubic Feet) Mississippi Natural Gas in Underground Storage (Working Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 33,234...

  17. EIA - Natural Gas Pipeline Network - Natural Gas Supply Basins...

    U.S. Energy Information Administration (EIA) Indexed Site

    Corridors About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 20072008 with selected updates U.S. Natural Gas Supply Basins Relative to Major Natural...

  18. New York Natural Gas in Underground Storage (Base Gas) (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Base Gas) (Million Cubic Feet) New York Natural Gas in Underground Storage (Base Gas) (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1990 88,911 88,911...

  19. Nevada Natural Gas Gross Withdrawals from Gas Wells (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    from Gas Wells (Million Cubic Feet) Nevada Natural Gas Gross Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

  20. Texas--State Offshore Natural Gas Withdrawals from Gas Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Texas--State Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  1. Alaska--State Offshore Natural Gas Withdrawals from Gas Wells...

    Gasoline and Diesel Fuel Update (EIA)

    Gas Wells (Million Cubic Feet) Alaska--State Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  2. Federal Offshore--Alabama Natural Gas Withdrawals from Gas Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Federal Offshore--Alabama Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  3. Louisiana--State Offshore Natural Gas Withdrawals from Gas Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) Louisiana--State Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  4. Federal Offshore--Texas Natural Gas Withdrawals from Gas Wells...

    Gasoline and Diesel Fuel Update (EIA)

    Gas Wells (Million Cubic Feet) Federal Offshore--Texas Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  5. Alabama--State Offshore Natural Gas Withdrawals from Gas Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Withdrawals from Gas Wells (Million Cubic Feet) Alabama--State Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  6. US--Federal Offshore Natural Gas Withdrawals from Gas Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Wells (Million Cubic Feet) US--Federal Offshore Natural Gas Withdrawals from Gas Wells (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  7. Widget:GasMap | Open Energy Information

    Open Energy Info (EERE)

    GasMap Jump to: navigation, search Gas map widget: The Gas Map displays real-time gas prices for the United States Example Output Gas map widget: Denver Gas Prices provided by...

  8. What is shale gas? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    What is shale gas? What is shale gas? PDF icon What is shale gas? More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Glossary How is shale gas produced?

  9. UPVG phase 2 report

    SciTech Connect (OSTI)

    1995-08-01

    The Utility PhotoVoltaic Group (UPVG), supported by member dues and a grant from the US Department of Energy, has as its mission the acceleration of the use of cost-effective small-scale and emerging large-scale applications of photovoltaics for the benefit of electric utilities and their customers. Formed in October, 1992, with the support of the American Public Power Association, Edison Electric Institute, and the National Rural Electric Cooperative Association, the UPVG currently has 90 members from all sectors of the electric utility industry. The UPVG`s efforts as conceived were divided into four phases: Phase 0--program plan; Phase 1--organization and strategy development; Phase 2--creating market assurance; and Phase 3--higher volume purchases. The Phase 0 effort developed the program plan and was completed early in 1993. The Phase 1 goal was to develop the necessary background information and analysis to lead to a decision as to which strategies could be undertaken by utilities to promote greater understanding of PV markets and achieve increased volumes of PV purchases. This report provides the details of the UPVG`s Phase 2 efforts to initiate TEAM-UP, its multiyear, 50-MW hardware initiative.

  10. RESOURCE CHARACTERIZATION AND QUANTIFICATION OF NATURAL GAS-HYDRATE AND ASSOCIATED FREE-GAS ACCUMULATIONS IN THE PRUDHOE BAY - KUPARUK RIVER AREA ON THE NORTH SLOPE OF ALASKA

    SciTech Connect (OSTI)

    Robert Hunter; Shirish Patil; Robert Casavant; Tim Collett

    2003-06-02

    Interim results are presented from the project designed to characterize, quantify, and determine the commercial feasibility of Alaska North Slope (ANS) gas-hydrate and associated free-gas resources in the Prudhoe Bay Unit (PBU), Kuparuk River Unit (KRU), and Milne Point Unit (MPU) areas. This collaborative research will provide practical input to reservoir and economic models, determine the technical feasibility of gas hydrate production, and influence future exploration and field extension of this potential ANS resource. The large magnitude of unconventional in-place gas (40-100 TCF) and conventional ANS gas commercialization evaluation creates industry-DOE alignment to assess this potential resource. This region uniquely combines known gas hydrate presence and existing production infrastructure. Many technical, economical, environmental, and safety issues require resolution before enabling gas hydrate commercial production. Gas hydrate energy resource potential has been studied for nearly three decades. However, this knowledge has not been applied to practical ANS gas hydrate resource development. ANS gas hydrate and associated free gas reservoirs are being studied to determine reservoir extent, stratigraphy, structure, continuity, quality, variability, and geophysical and petrophysical property distribution. Phase 1 will characterize reservoirs, lead to recoverable reserve and commercial potential estimates, and define procedures for gas hydrate drilling, data acquisition, completion, and production. Phases 2 and 3 will integrate well, core, log, and long-term production test data from additional wells, if justified by results from prior phases. The project could lead to future ANS gas hydrate pilot development. This project will help solve technical and economic issues to enable government and industry to make informed decisions regarding future commercialization of unconventional gas-hydrate resources.

  11. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States On May 29, 2014, the Department of Energy's (DOE) Office of Fossil Energy announced the availability for public review and comment the report Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States (LCA GHG Report).

  12. High order harmonic generation in dual gas multi-jets

    SciTech Connect (OSTI)

    Tosa, Valer E-mail: calin.hojbota@itim-cj.ro; Hojbota, Calin E-mail: calin.hojbota@itim-cj.ro

    2013-11-13

    High order harmonic generation (HHG) in gas media suffers from a low conversion efficiency that has its origins in the interaction of the atom/molecule with the laser field. Phase matching is the main way to enhance the harmonic flux and several solutions have been designed to achieve it. Here we present numerical results modeling HHG in a system of multi-jets in which two gases alternate: the first gas jet (for example Ne) generates harmonics and the second one which ionizes easier, recover the phase matching condition. We obtain configurations which are experimentally feasible with respect to pressures and dimensions of the jets.

  13. ,"Federal Offshore California Natural Gas Withdrawals from Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Federal Offshore California Natural Gas Withdrawals from Gas Wells (MMcf)",1,"Annual",2014 ,"Release...

  14. natural gas+ condensing flue gas heat recovery+ water creation...

    Open Energy Info (EERE)

    natural gas+ condensing flue gas heat recovery+ water creation+ CO2 reduction+ cool exhaust gases+ Energy efficiency+ commercial building energy efficiency+ industrial energy...

  15. ,"New Mexico Natural Gas Gross Withdrawals from Gas Wells (MMcf...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas Gross Withdrawals from Gas Wells (MMcf)",1,"Annual",2014 ,"Release...

  16. EIA - Natural Gas Pipeline Network - Natural Gas Market Centers...

    U.S. Energy Information Administration (EIA) Indexed Site

    Source: Energy Information Administration, Office of Oil and Gas, Natural Gas Division, ... The EIA has determined that the informational map displays here do not raise security ...

  17. EIA - Natural Gas Pipeline Network - Intrastate Natural Gas Pipeline...

    U.S. Energy Information Administration (EIA) Indexed Site

    SoCal and PG&E are two of the largest distribution companies in the entire United States. ... Intrastate Natural Gas Pipeline Companies -spreadsheet Other Natural Gas ...

  18. Natural Gas | Open Energy Information

    Open Energy Info (EERE)

    133. Lower 48 Natural Gas Production and Wellhead Prices by Supply Region Table 134. Oil and Gas End-of-Year Reserves and Annual Reserve Additions Table 135. Natural Gas...

  19. International Natural Gas Workshop Presnetations

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Session 3: Asian Natural Gas Outlook Asian Natural Gas: A Softer Market is coming Robert Smith, FGE Dubai PDF Session 4: LNG Exports and the Future International Natural Gas Market ...

  20. Mass Save (Gas)- Residential Rebate Program

    Broader source: Energy.gov [DOE]

    Mass Save, through Gas Networks, organizes residential conservation services for programs administered by Massachusetts gas companies. These gas providers include Columbia Gas of Massachusetts,...