National Library of Energy BETA

Sample records for gas hydrate field

  1. Gas hydrates

    SciTech Connect (OSTI)

    Not Available

    1985-04-01

    There is a definite need for the US government to provide leadership for research in gas hydrates and to coordinate its activities with academia, industry, private groups, federal agencies, and their foreign counterparts. In response to this need, the DOE Morgantown Energy Technology Center implemented a gas hydrates R and D program. Understanding the resource will be achieved through: assessment of current technology; characterization of gas hydrate geology and reservoir engineering; and development of diagnostic tools and methods. Research to date has focused on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for future detailed investigation. Initial research activities involved the development of the Geologic Analysis System (GAS); which will provide, through approximately 30 software packages, the capability to manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. Preliminary mapping of hydrate prospects for the Alaskan North Slope is underway. Geological research includes physical system characterization which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran, consolidated rock cores, frost base mixtures, water/ice base mixtures, and water base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by METC. More recently, a natural hydrate sample from the Gulf of Mexico was also acquired and testing of this sample is currently underway. In addition to the development of GAS, modeling and systems analysis work focused on the development of conceptual gas hydrate production models. 16 figs., 6 tabs.

  2. Analysis of the Development of Messoyakha Gas Field: A Commercial Gas Hydrate Reservoir 

    E-Print Network [OSTI]

    Omelchenko, Roman 1987-

    2012-12-11

    Natural gas is an important energy source that contributes up to 25% of the total US energy reserves (DOE 2011). An increase in natural gas demand spurs further development of unconventional resources, including methane hydrate (Rajnauth 2012...

  3. Guest Molecule Exchange Kinetics for the 2012 Ignik Sikumi Gas Hydrate Field Trial

    SciTech Connect (OSTI)

    White, Mark D.; Lee, Won Suk

    2014-05-14

    A commercially viable technology for producing methane from natural gas hydrate reservoirs remains elusive. Short-term depressurization field tests have demonstrated the potential for producing natural gas via dissociation of the clathrate structure, but the long-term performance of the depressurization technology ultimately requires a heat source to sustain the dissociation. A decade of laboratory experiments and theoretical studies have demonstrated the exchange of pure CO2 and N2-CO2 mixtures with CH4 in sI gas hydrates, yielding critical information about molecular mechanisms, recoveries, and exchange kinetics. Findings indicated the potential for producing natural gas with little to no production of water and rapid exchange kinetics, generating sufficient interest in the guest-molecule exchange technology for a field test. In 2012 the U.S. DOE/NETL, ConocoPhillips Company, and Japan Oil, Gas and Metals National Corporation jointly sponsored the first field trial of injecting a mixture of N2-CO2 into a CH4-hydrate bearing formation beneath the permafrost on the Alaska North Slope. Known as the Ignik Sikumi #1 Gas Hydrate Field Trial, this experiment involved three stages: 1) the injection of a N2-CO2 mixture into a targeted hydrate-bearing layer, 2) a 4-day pressurized soaking period, and 3) a sustained depressurization and fluid production period. Data collected during the three stages of the field trial were made available after an extensive quality check. These data included continuous temperature and pressure logs, injected and recovered fluid compositions and volumes. The Ignik Sikumi #1 data set is extensive, but contains no direct evidence of the guest-molecule exchange process. This investigation is directed at using numerical simulation to provide an interpretation of the collected data. A numerical simulator, STOMP-HYDT-KE, was recently completed that solves conservation equations for energy, water, mobile fluid guest molecules, and hydrate guest molecules, for up to three gas hydrate guest molecules: CH4, CO2, and N2. The independent tracking of mobile fluid and hydrate guest molecules allows for the kinetic exchange of guest molecules between the mobile fluids and hydrate. The particular interest of this numerical investigation is to determine whether kinetic exchange parameters, determined from laboratory-scale experiments, are directly applicable to interpreting the Ignik Sikumi #1 data.

  4. Gas hydrates: technology status report

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    The DOE Morgantown Energy Technology Center (METC) implemented a gas hydrates R and D program that emphasized an understanding of the resource through (1) an assessment of current technology, (2) the characterization of gas hydrate geology and reservoir engineering, and (3) the development of diagnostic tools and methods. Recovery of natural gas from gas hydrates will be made possible through (1) improved instrumentation and recovery methods, (2) developing the capability to predict production performance, and (3) field verification of recovery methods. Gas hydrates research has focused primarily on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for detailed investigation. A Geologic Analysis System (GAS) was developed. GAS contains approximately 30 software packages and can manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. The system also contains all well information currently available from the Alaskan North Slope area. Laboratory research on gas hydrates includes the characterization of the physical system, which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran (THF), consolidated rock cores, frost base mixtures, water/ice-base mixtures, and water-base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by DOE/METC. More recently, natural hydrate samples acquired from the Gulf of Mexico are being tested. Modeling and systems analysis work has focused on the development of GAS and preliminary gas hydrate production models. 23 refs., 18 figs., 6 tabs.

  5. Drilling and Production Testing the Methane Hydrate Resource Potential Associated with the Barrow Gas Fields

    SciTech Connect (OSTI)

    Steve McRae; Thomas Walsh; Michael Dunn; Michael Cook

    2010-02-22

    In November of 2008, the Department of Energy (DOE) and the North Slope Borough (NSB) committed funding to develop a drilling plan to test the presence of hydrates in the producing formation of at least one of the Barrow Gas Fields, and to develop a production surveillance plan to monitor the behavior of hydrates as dissociation occurs. This drilling and surveillance plan was supported by earlier studies in Phase 1 of the project, including hydrate stability zone modeling, material balance modeling, and full-field history-matched reservoir simulation, all of which support the presence of methane hydrate in association with the Barrow Gas Fields. This Phase 2 of the project, conducted over the past twelve months focused on selecting an optimal location for a hydrate test well; design of a logistics, drilling, completion and testing plan; and estimating costs for the activities. As originally proposed, the project was anticipated to benefit from industry activity in northwest Alaska, with opportunities to share equipment, personnel, services and mobilization and demobilization costs with one of the then-active exploration operators. The activity level dropped off, and this benefit evaporated, although plans for drilling of development wells in the BGF's matured, offering significant synergies and cost savings over a remote stand-alone drilling project. An optimal well location was chosen at the East Barrow No.18 well pad, and a vertical pilot/monitoring well and horizontal production test/surveillance well were engineered for drilling from this location. Both wells were designed with Distributed Temperature Survey (DTS) apparatus for monitoring of the hydrate-free gas interface. Once project scope was developed, a procurement process was implemented to engage the necessary service and equipment providers, and finalize project cost estimates. Based on cost proposals from vendors, total project estimated cost is $17.88 million dollars, inclusive of design work, permitting, barging, ice road/pad construction, drilling, completion, tie-in, long-term production testing and surveillance, data analysis and technology transfer. The PRA project team and North Slope have recommended moving forward to the execution phase of this project.

  6. Methane Hydrate Field Program

    SciTech Connect (OSTI)

    2013-12-31

    This final report document summarizes the activities undertaken and the output from three primary deliverables generated during this project. This fifteen month effort comprised numerous key steps including the creation of an international methane hydrate science team, determining and reporting the current state of marine methane hydrate research, convening an international workshop to collect the ideas needed to write a comprehensive Marine Methane Hydrate Field Research Plan and the development and publication of that plan. The following documents represent the primary deliverables of this project and are discussed in summary level detail in this final report. • Historical Methane Hydrate Project Review Report • Methane Hydrate Workshop Report • Topical Report: Marine Methane Hydrate Field Research Plan • Final Scientific/Technical Report

  7. Review of the findings of the Ignik Sikumi CO2-CH4 gas hydrate exchange field trial

    SciTech Connect (OSTI)

    Anderson, Brian J.; Boswell, Ray; Collett, Tim S.; Farrell, Helen; Ohtsuka, Satoshi; White, Mark D.

    2014-08-01

    The Ignik Sikumi Gas Hydrate Exchange Field Trial was conducted by ConocoPhillips in partnership with the U.S. Department of Energy, the Japan Oil, Gas, and Metals National Corporation, and the U.S. Geological Survey within the Prudhoe Bay Unit on the Alaska North Slope (ANS) during 2011 and 2012. The 2011 field program included drilling the vertical test well and performing extensive wireline logging through a thick section of gas-hydrate-bearing sand reservoirs that provided substantial new insight into the nature of ANS gas hydrate occurrences. The 2012 field program involved an extended, scientific field trial conducted within a single vertical well (“huff-and-puff” design) through three primary operational phases: 1) injection of a gaseous phase mixture of CO2, N2, and chemical tracers; 2) flowback conducted at down-hole pressures above the stability threshold for native CH4-hydrate, and 3) extended (30-days) flowback at pressures below the stability threshold of native CH4-hydrate. Ignik Sikumi represents the first field investigation of gas hydrate response to chemical injection, and the longest-duration field reservoir response experiment yet conducted. Full descriptions of the operations and data collected have been fully reported by ConocoPhillips and are available to the science community. The 2011 field program indicated the presence of free water within the gas hydrate reservoir, a finding with significant implications to the design of the exchange trial – most notably the use of a mixed gas injectant. While this decision resulted in a complex chemical environment within the reservoir that greatly tests current experimental and modeling capabilities – without such a mixture, it is apparent that injection could not have been achieved. While interpretation of the field data are continuing, the primary scientific findings and implications of the program are: 1) gas hydrate destabilizing is self-limiting, dispelling any notion of the potential for uncontrolled destabilization; 2) wells must be carefully designed to enable rapid remediation of well-bore blockages that will occur during any cessation in operations; 3) appropriate gas mixes can be successfully injected into hydrate-bearing reservoirs; 4) sand production can be well-managed through standard engineering controls; 5) reservoir heat exchange during depressurization was much more favorable than expected – mitigating concerns for near-well-bore freezing and enabling consideration of more aggressive pressure reduction and; 6) CO2-CH4 exchange can be accomplished in natural reservoirs. The next steps in evaluation of exchange technology should feature multiple well applications; however such field programs will require extensive preparatory experimental and numerical modeling studies and will likely be a secondary priority to further field testing of production through depressurization.

  8. Physical Properties of Gas Hydrates: A Review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gabitto, Jorge F.; Tsouris, Costas

    2010-01-01

    Methane gas hydrates in sediments have been studied by several investigators as a possible future energy resource. Recent hydrate reserves have been estimated at approximately 10 16 ? m 3 of methane gas worldwide at standard temperature and pressure conditions. In situ dissociation of natural gas hydrate is necessary in order to commercially exploit the resource from the natural-gas-hydrate-bearing sediment. The presence of gas hydrates in sediments dramatically alters some of the normal physical properties of the sediment. These changes can be detectedmore »by field measurements and by down-hole logs. An understanding of the physical properties of hydrate-bearing sediments is necessary for interpretation of geophysical data collected in field settings, borehole, and slope stability analyses; reservoir simulation; and production models. This work reviews information available in literature related to the physical properties of sediments containing gas hydrates. A brief review of the physical properties of bulk gas hydrates is included. Detection methods, morphology, and relevant physical properties of gas-hydrate-bearing sediments are also discussed. « less

  9. Formation of porous gas hydrates

    E-Print Network [OSTI]

    Salamatin, Andrey N

    2015-01-01

    Gas hydrates grown at gas-ice interfaces are examined by electron microscopy and found to have a submicron porous texture. Permeability of the intervening hydrate layers provides the connection between the two counterparts (gas and water molecules) of the clathration reaction and makes further hydrate formation possible. The study is focused on phenomenological description of principal stages and rate-limiting processes that control the kinetics of the porous gas hydrate crystal growth from ice powders. Although the detailed physical mechanisms involved in the porous hydrate formation still are not fully understood, the initial stage of hydrate film spreading over the ice surface should be distinguished from the subsequent stage which is presumably limited by the clathration reaction at the ice-hydrate interface and develops after the ice grain coating is finished. The model reveals a time dependence of the reaction degree essentially different from that when the rate-limiting step of the hydrate formation at...

  10. Gas hydrates: Technology status report

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    In 1983, the US Department of Energy (DOE) assumed the responsibility for expanding the knowledge base and for developing methods to recover gas from hydrates. These are ice-like mixtures of gas and water where gas molecules are trapped within a framework of water molecules. This research is part of the Unconventional Gas Recovery (UGR) program, a multidisciplinary effort that focuses on developing the technology to produce natural gas from resources that have been classified as unconventional because of their unique geologies and production mechanisms. Current work on gas hydrates emphasizes geological studies; characterization of the resource; and generic research, including modeling of reservoir conditions, production concepts, and predictive strategies for stimulated wells. Complementing this work is research on in situ detection of hydrates and field tests to verify extraction methods. Thus, current research will provide a comprehensive technology base from which estimates of reserve potential can be made, and from which industry can develop recovery strategies. 7 refs., 3 figs., 6 tabs.

  11. Rapid gas hydrate formation process

    DOE Patents [OSTI]

    Brown, Thomas D.; Taylor, Charles E.; Unione, Alfred J.

    2013-01-15

    The disclosure provides a method and apparatus for forming gas hydrates from a two-phase mixture of water and a hydrate forming gas. The two-phase mixture is created in a mixing zone which may be wholly included within the body of a spray nozzle. The two-phase mixture is subsequently sprayed into a reaction zone, where the reaction zone is under pressure and temperature conditions suitable for formation of the gas hydrate. The reaction zone pressure is less than the mixing zone pressure so that expansion of the hydrate-forming gas in the mixture provides a degree of cooling by the Joule-Thompson effect and provides more intimate mixing between the water and the hydrate-forming gas. The result of the process is the formation of gas hydrates continuously and with a greatly reduced induction time. An apparatus for conduct of the method is further provided.

  12. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, M.P.; Kedl, R.J.

    1984-09-12

    The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

  13. Natural Gas Hydrates Update 1998-2000

    Reports and Publications (EIA)

    2001-01-01

    Significant events have transpired on the natural gas hydrate research and development front since "Future Supply Potential of Natural Gas Hydrates" appeared in Natural Gas 1998 Issues and Trends and in the Potential Gas Committee's 1998 biennial report.

  14. Natural gas hydrates on the North Slope of Alaska

    SciTech Connect (OSTI)

    Collett, T.S.

    1991-01-01

    Gas hydrates are crystalline substances composed of water and gas, mainly methane, in which a solid-water lattice accommodates gas molecules in a cage-like structure, or clathrate. These substances often have been regarded as a potential (unconventional) source of natural gas. Significant quantities of naturally occurring gas hydrates have been detected in many regions of the Arctic including Siberia, the Mackenzie River Delta, and the North Slope of Alaska. On the North Slope, the methane-hydrate stability zone is areally extensive beneath most of the coastal plain province and has thicknesses as great as 1000 meters in the Prudhoe Bay area. Gas hydrates have been identified in 50 exploratory and production wells using well-log responses calibrated to the response of an interval in one well where gas hydrates were recovered in a core by ARCO Alaska and EXXON. Most of these gas hydrates occur in six laterally continuous Upper Cretaceous and lower Tertiary sandstone and conglomerate units; all these gas hydrates are geographically restricted to the area overlying the eastern part of the Kuparuk River Oil Field and the western part of the Prudhoe Bay Oil Field. The volume of gas within these gas hydrates is estimated to be about 1.0 {times} 10{sup 12} to 1.2 {times} 10{sup 12} cubic meters (37 to 44 trillion cubic feet), or about twice the volume of conventional gas in the Prudhoe Bay Field. Geochemical analyses of well samples suggest that the identified hydrates probably contain a mixture of deep-source thermogenic gas and shallow microbial gas that was either directly converted to gas hydrate or first concentrated in existing traps and later converted to gas hydrate. The thermogenic gas probably migrated from deeper reservoirs along the same faults thought to be migration pathways for the large volumes of shallow, heavy oil that occur in this area. 51 refs., 11 figs., 3 tabs.

  15. Natural Gas Hydrates Update 2000-2002

    Reports and Publications (EIA)

    2003-01-01

    Natural gas hydrates research and development (R&D) activity expanded significantly during the 2000-2002.

  16. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    data: an electromagnetic survey at Hydrate Ridge, Oregon made possible by funding from Exxon MobilExxon Mobil and from GERD, Japan to study gas hydrates. We only had 3 days of data

  17. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    data: an electromagnetic survey at Hydrate Ridge, Oregon made possible by funding from Exxon MobilExxon Mobil and from GERD, Japan to study gas hydrates. We only had 3 days of data

  18. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, Mark P. (Knoxville, TN); Kedl, Robert J. (Oak Ridge, TN)

    1985-01-01

    This invention is a process for formation of a gas hydrate to be used as a cool storage medium using a refrigerant in water. Mixing of the immiscible refrigerant and water is effected by addition of a surfactant and agitation. The difficult problem of subcooling during the process is overcome by using the surfactant and agitation and performance of the process significantly improves and approaches ideal.

  19. Development of Alaskan gas hydrate resources

    SciTech Connect (OSTI)

    Kamath, V.A.; Sharma, G.D.; Patil, S.L.

    1991-06-01

    The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

  20. Natural gas hydrates - issues for gas production and geomechanical stability 

    E-Print Network [OSTI]

    Grover, Tarun

    2008-10-10

    gases, some liquids like tetrahydrofuran (THF) can also react with water to form hydrates. The formation of natural gas hydrates depends on pressure, temperature, gas composition, and presence of inhibitors such as salts. NGHs are found... deposits constitute the bulk of natural hydrates (Sloan and Koh, 2008). In offshore environments, hydrates are stable in water depths greater than 200 to 600 meters depending on the gas composition and seafloor temperatures (Milkov and Sassen, 2002). Fig...

  1. Gas Hydrates Research Programs: An International Review

    SciTech Connect (OSTI)

    Jorge Gabitto; Maria Barrufet

    2009-12-09

    Gas hydrates sediments have the potential of providing a huge amount of natural gas for human use. Hydrate sediments have been found in many different regions where the required temperature and pressure conditions have been satisfied. Resource exploitation is related to the safe dissociation of the gas hydrate sediments. Basic depressurization techniques and thermal stimulation processes have been tried in pilot efforts to exploit the resource. There is a growing interest in gas hydrates all over the world due to the inevitable decline of oil and gas reserves. Many different countries are interested in this valuable resource. Unsurprisingly, developed countries with limited energy resources have taken the lead in worldwide gas hydrates research and exploration. The goal of this research project is to collect information in order to record and evaluate the relative strengths and goals of the different gas hydrates programs throughout the world. A thorough literature search about gas hydrates research activities has been conducted. The main participants in the research effort have been identified and summaries of their past and present activities reported. An evaluation section discussing present and future research activities has also been included.

  2. Overview: Gas hydrate geology and geography

    SciTech Connect (OSTI)

    Malone, R.D.

    1993-01-01

    Several geological factors which are directly responsible for the presence or absence of gas hydrates have been reviewed and are: tectonic position of the region; sedimentary environments; structural deformation; shale diapirism; hydrocarbon generation and migration; thermal regime in the hydrate formation zone (HFZ); pressure conditions; and hydrocarbon gas supply to the HFZ. Work on gas hydrate formation in the geological environment has made significant advances, but there is still much to be learned. Work is continuing in the deeper offshore areas through the Ocean Drilling Program, Government Agencies, and Industry. The pressure/temperature conditions necessary for formation has been identified for various compositions of natural gas through laboratory investigations and conditions for formation are being advanced through drilling in areas where gas hydrates exist.

  3. Overview: Gas hydrate geology and geography

    SciTech Connect (OSTI)

    Malone, R.D.

    1993-06-01

    Several geological factors which are directly responsible for the presence or absence of gas hydrates have been reviewed and are: tectonic position of the region; sedimentary environments; structural deformation; shale diapirism; hydrocarbon generation and migration; thermal regime in the hydrate formation zone (HFZ); pressure conditions; and hydrocarbon gas supply to the HFZ. Work on gas hydrate formation in the geological environment has made significant advances, but there is still much to be learned. Work is continuing in the deeper offshore areas through the Ocean Drilling Program, Government Agencies, and Industry. The pressure/temperature conditions necessary for formation has been identified for various compositions of natural gas through laboratory investigations and conditions for formation are being advanced through drilling in areas where gas hydrates exist.

  4. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    SciTech Connect (OSTI)

    Moridis, G.J.; Collett, T.S.; Pooladi-Darvish, M.; Hancock, S.; Santamarina, C.; Boswell, R.; Kneafsey, T.; Rutqvist, J.; Kowalsky, M.; Reagan, M.T.; Sloan, E.D.; Sum, A.K.; Koh, C.

    2010-11-01

    The current paper complements the Moridis et al. (2009) review of the status of the effort toward commercial gas production from hydrates. We aim to describe the concept of the gas hydrate petroleum system, to discuss advances, requirement and suggested practices in gas hydrate (GH) prospecting and GH deposit characterization, and to review the associated technical, economic and environmental challenges and uncertainties, including: the accurate assessment of producible fractions of the GH resource, the development of methodologies for identifying suitable production targets, the sampling of hydrate-bearing sediments and sample analysis, the analysis and interpretation of geophysical surveys of GH reservoirs, well testing methods and interpretation of the results, geomechanical and reservoir/well stability concerns, well design, operation and installation, field operations and extending production beyond sand-dominated GH reservoirs, monitoring production and geomechanical stability, laboratory investigations, fundamental knowledge of hydrate behavior, the economics of commercial gas production from hydrates, and the associated environmental concerns.

  5. ConocoPhillips Gas Hydrate Production Test

    SciTech Connect (OSTI)

    Schoderbek, David; Farrell, Helen; Howard, James; Raterman, Kevin; Silpngarmlert, Suntichai; Martin, Kenneth; Smith, Bruce; Klein, Perry

    2013-06-30

    Work began on the ConocoPhillips Gas Hydrates Production Test (DOE award number DE-NT0006553) on October 1, 2008. This final report summarizes the entire project from January 1, 2011 to June 30, 2013.

  6. Videos of Experiments from ORNL Gas Hydrate Research

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gas hydrate research performed by the Environmental Sciences Division utilizes the ORNL Seafloor Process Simulator, the Parr Vessel, the Sapphire Cell, a fiber optic distributed sensing system, and Raman spectroscopy. The group studies carbon sequestration in the ocean, desalination, gas hydrates in the solar system, and nucleation and dissociation kinetics. The videos available at the gas hydrates website are very short clips from experiments.

  7. The Research Path to Determining the Natural Gas Supply Potential of Marine Gas Hydrates

    SciTech Connect (OSTI)

    Boswell, R.M.; Rose, K.K.; Baker, R.C.

    2008-06-01

    A primary goal of the U.S. National Interagency Gas Hydrates R&D program is to determine the natural gas production potential of marine gas hydrates. In pursuing this goal, four primary areas of effort are being conducted in parallel. First, are wide-ranging basic scientific investigations in both the laboratory and in the field designed to advance the understanding of the nature and behavior of gas hydrate bearing sediments (GHBS). This multi-disciplinary work has wide-ranging direct applications to resource recovery, including assisting the development of exploration and production technologies through better rock physics models for GHBS and also in providing key data for numerical simulations of productivity, reservoir geomechanical response, and other phenomena. In addition, fundamental science efforts are essential to developing a fuller understanding of the role gas hydrates play in the natural environment and the potential environmental implications of gas hydrate production, a critical precursor to commercial extraction. A second area of effort is the confirmation of resource presence and viability via a series of multi-well marine drilling expeditions. The collection of data in the field is essential to further clarifying what proportion of the likely immense in-place marine gas hydrate resource exists in accumulations of sufficient quality to represent potential commercial production prospects. A third research focus area is the integration of geologic, geophysical, and geochemical field data into an effective suite of exploration tools that can support the delineation and characterization commercial gas hydrate prospects prior to drilling. The fourth primary research focus is the development and testing of well-based extraction technologies (including drilling, completion, stimulation and production) that can safely deliver commercial gas production rates from gas hydrate reservoirs in a variety of settings. Initial efforts will take advantage of the relatively favorable economics of conducting production tests in Arctic gas-hydrate bearing sandstones with the intent of translating the knowledge gained to later testing in marine sandstone reservoirs. The full and concurrent pusuit of each of these research topics is essential to the determining the future production potential of naturally-occuring gas hydrates.

  8. Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report

    SciTech Connect (OSTI)

    Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

    1988-01-01

    The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

  9. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    Mallik Gas Hydrate Production Research Program, Northwestof Depressurization for Gas Production from Gas Hydrate5L-38 Gas Hydrate Thermal Production Test Through Numerical

  10. CONTENTS Gas Hydrate Assessment in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from the CloudGEGR-N Goods PO 1 of 8 GE4, VolumeGas

  11. Oil and Gas CDT Gas hydrate distribution on tectonically active continental

    E-Print Network [OSTI]

    Henderson, Gideon

    Oil and Gas CDT Gas hydrate distribution on tectonically active continental margins: Impact on gas. Gregory F. Moore, University of Hawaii (USA) http://www.soest.hawaii.edu/moore/ Key Words Gas Hydrates, Faults, Fluid Flow, gas prospectivity Overview Fig. 1. Research on gas hydrates is often undertaken

  12. Development of Alaskan gas hydrate resources. Final report

    SciTech Connect (OSTI)

    Kamath, V.A.; Sharma, G.D.; Patil, S.L.

    1991-06-01

    The research undertaken in this project pertains to study of various techniques for production of natural gas from Alaskan gas hydrates such as, depressurization, injection of hot water, steam, brine, methanol and ethylene glycol solutions through experimental investigation of decomposition characteristics of hydrate cores. An experimental study has been conducted to measure the effective gas permeability changes as hydrates form in the sandpack and the results have been used to determine the reduction in the effective gas permeability of the sandpack as a function of hydrate saturation. A user friendly, interactive, menu-driven, numerical difference simulator has been developed to model the dissociation of natural gas hydrates in porous media with variable thermal properties. A numerical, finite element simulator has been developed to model the dissociation of hydrates during hot water injection process.

  13. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    Exploration for gas hydrates in the deepwater northern Gulf of Mexico, Part I: A seismicexploration (i.e. , reservoir evaluation and resource estimation) is surface seismic.seismic data set from the area of the Milne Point Field as provided to the USGS by BP Exploration

  14. A Study of Formation and Dissociation of Gas Hydrate 

    E-Print Network [OSTI]

    Badakhshan Raz, Sadegh

    2012-07-16

    The estimation of gas hydrate volume in closed systems such as pipelines during shut-in time has a great industrial importance. A method is presented to estimate the volume of formed or decomposed gas hydrate in closed systems. The method was used...

  15. Surfactant process for promoting gas hydrate formation and application of the same

    DOE Patents [OSTI]

    Rogers, Rudy E. (Starkville, MS); Zhong, Yu (Brandon, MS)

    2002-01-01

    This invention relates to a method of storing gas using gas hydrates comprising forming gas hydrates in the presence of a water-surfactant solution that comprises water and surfactant. The addition of minor amounts of surfactant increases the gas hydrate formation rate, increases packing density of the solid hydrate mass and simplifies the formation-storage-decomposition process of gas hydrates. The minor amounts of surfactant also enhance the potential of gas hydrates for industrial storage applications.

  16. Rapid gas hydrate formation processes: Will they work?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-07

    Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETL’s 15-Liter Hydrate Cell. The results from this work demonstrate that the rapid and continuousmore »formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.« less

  17. Rapid Gas Hydrate Formation Processes: Will They Work?

    SciTech Connect (OSTI)

    Brown, Thomas D.; Taylor, Charles E.; Bernardo, Mark P.

    2010-06-01

    Researchers at DOE’s National Energy Technology Laboratory (NETL) have been investigating the formation of synthetic gas hydrates, with an emphasis on rapid and continuous hydrate formation techniques. The investigations focused on unconventional methods to reduce dissolution, induction, nucleation and crystallization times associated with natural and synthetic hydrates studies conducted in the laboratory. Numerous experiments were conducted with various high-pressure cells equipped with instrumentation to study rapid and continuous hydrate formation. The cells ranged in size from 100 mL for screening studies to proof-of-concept studies with NETL’s 15-Liter Hydrate Cell. Results from this work demonstrate that the rapid and continuous formation of methane hydrate is possible at predetermined temperatures and pressures within the stability zone of a Methane Hydrate Stability Curve.

  18. Sensitivity Analysis of Gas Production from Class 2 and Class 3 Hydrate Deposits

    E-Print Network [OSTI]

    Reagan, Matthew

    2009-01-01

    during production from a Class 2 oceanic deposit withinduced gas production from Class 1 hydrate deposits,” (Gas Production From Oceanic Class 3 Hydrate Accumulations”

  19. Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska

    E-Print Network [OSTI]

    Moridis, G.J.

    2010-01-01

    Mallik 2002 Gas Hydrate Production Research Well Program,Of Methane Hydrate Production Methods To Reservoirs WithNumerical Studies of Gas Production From Methane Hydrates,

  20. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

  1. Handbook of gas hydrate properties and occurrence

    SciTech Connect (OSTI)

    Kuustraa, V.A.; Hammershaimb, E.C.

    1983-12-01

    This handbook provides data on the resource potential of naturally occurring hydrates, the properties that are needed to evaluate their recovery, and their production potential. The first two chapters give data on the naturally occurring hydrate potential by reviewing published resource estimates and the known and inferred occurrences. The third and fourth chapters review the physical and thermodynamic properties of hydrates, respectively. The thermodynamic properties of hydrates that are discussed include dissociation energies and a simplified method to calculate them; phase diagrams for simple and multi-component gases; the thermal conductivity; and the kinetics of hydrate dissociation. The final chapter evaluates the net energy balance of recovering hydrates and shows that a substantial positive energy balance can theoretically be achieved. The Appendices of the Handbook summarize physical and thermodynamic properties of gases, liquids and solids that can be used in designing and evaluating recovery processes of hydrates. 158 references, 67 figures, 47 tables.

  2. E ects of the Driving Force on the Composition of Natural Gas Hydrates

    E-Print Network [OSTI]

    Gudmundsson, Jon Steinar

    E ects of the Driving Force on the Composition of Natural Gas Hydrates Odd I. Levik(1) , Jean for storage and transport of natural gas. Storage of natural gas in the form of hydrate at elevated pressure concept) (Gud- mundsson et al. 1998). Natural gas hydrate contains up to 182 Sm3 gas per m3 hydrate

  3. The growth rate of gas hydrate from refrigerant R12

    SciTech Connect (OSTI)

    Kendoush, Abdullah Abbas; Jassim, Najim Abid [Centre of Engineering Physics, Ministry of Sciences and Technology, P.O. Box 765, Baghdad (Iraq); Joudi, Khalid A. [Al-Nahrain University, Baghdad (Iraq)

    2006-07-15

    Experimental and theoretical investigations were presented dealing with three phase direct-contact heat transfer by evaporation of refrigerant drops in an immiscible liquid. Refrigerant R12 was used as the dispersed phase, while water and brine were the immiscible continuous phase. A numerical solution is presented to predict the formation rate of gas hydrates in test column. The solution provided an acceptable agreement when compared with experimental results. The gas hydrate growth rate increased with time. It increased with increasing dispersed phase flow rate. The presence of surface-active sodium chloride in water had a strong inhibiting effect on the gas hydrate formation rate. (author)

  4. Drilling Through Gas Hydrates Formations: Managing Wellbore Stability Risks 

    E-Print Network [OSTI]

    Khabibullin, Tagir R.

    2010-10-12

    As hydrocarbon exploration and development moves into deeper water and onshore arctic environments, it becomes increasingly important to quantify the drilling hazards posed by gas hydrates. To address these concerns, a 1D semi-analytical model...

  5. Drilling through gas hydrates formations: possible problems and suggested solution 

    E-Print Network [OSTI]

    Amodu, Afolabi Ayoola

    2009-05-15

    Gas hydrate research in the last two decades has taken various directions ranging from ways to understand the safe and economical production of this enormous resource to drilling problems. as more rigs and production platforms move into deeper...

  6. Gas hydrate detection and mapping on the US east coast

    SciTech Connect (OSTI)

    Ahlbrandt, T.S.; Dillon, W.P.

    1993-12-31

    Project objectives are to identify and map gas hydrate accumulations on the US eastern continental margin using remote sensing (seismic profiling) techniques and to relate these concentrations to the geological factors that-control them. In order to test the remote sensing methods, gas hydrate-cemented sediments will be tested in the laboratory and an effort will be made to perform similar physical tests on natural hydrate-cemented sediments from the study area. Gas hydrate potentially may represent a future major resource of energy. Furthermore, it may influence climate change because it forms a large reservoir for methane, which is a very effective greenhouse gas; its breakdown probably is a controlling factor for sea-floor landslides; and its presence has significant effect on the acoustic velocity of sea-floor sediments.

  7. Basin scale assessment of gas hydrate dissociation in response to climate change

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.; Cameron-Smith, P.

    2011-07-01

    Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating climate. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those now occurring in the arctic and those predicted under future climate change scenarios, has only recently been investigated. Field investigations have discovered substantial methane gas plumes exiting the seafloor along the Arctic Ocean margin, and the plumes appear at depths corresponding to the upper limit of a receding gas hydrate stability zone. It has been suggested that these plumes may be the first visible signs of the dissociation of shallow hydrate deposits due to ongoing climate change in the arctic. We simulate the release of methane from oceanic deposits, including the effects of fully-coupled heat transfer, fluid flow, hydrate dissociation, and other thermodynamic processes, for systems representative of segments of the Arctic Ocean margins. The modeling encompasses a range of shallow hydrate deposits from the landward limit of the hydrate stability zone down to water depths beyond the expected range of century-scale temperature changes. We impose temperature changes corresponding to predicted rates of climate change-related ocean warming and examine the possibility of hydrate dissociation and the release of methane. The assessment is performed at local-, regional-, and basin-scales. The simulation results are consistent with the hypothesis that dissociating shallow hydrates alone can result in significant methane fluxes at the seafloor. However, the methane release is likely to be confined to a narrow region of high dissociation susceptibility, defined by depth and temperature, and that any release will be continuous and controlled, rather than explosive. This modeling also establishes the first realistic bounds for methane release along the arctic continental shelf for potential hydrate dissociation scenarios, and ongoing work may help confirm whether climate change is already impacting the stability of the vast oceanic hydrate reservoir.

  8. Testing a coupled hydro-thermo-chemo-geomechanical model for gas hydrate bearing sediments using triaxial compression lab experiments

    E-Print Network [OSTI]

    Gupta, Shubhangi; Haeckel, Matthias; Helmig, Rainer; Wohlmuth, Barbara

    2015-01-01

    The presence of gas hydrates influences the stress-strain behavior and increases the load-bearing capacity of sub-marine sediments. This stability is reduced or completely lost when gas hydrates become unstable. Since natural gas hydrate reservoirs are considered as potential resources for gas production on industrial scales, there is a strong need for numerical production simulators with geomechanical capabilities. To reliably predict the mechanical behavior of gas hydrate-bearing sediments during gas production, numerical tools must be sufficiently calibrated against data from controlled experiments or field tests, and the models must consider thermo-hydro-chemo-mechanical process coupling in a suitable manner. In this study, we perform a controlled triaxial volumetric strain test on a sediment sample in which methane hydrate is first formed under controlled isotropic effective stress and then dissociated via depressurization under controlled total stress. Sample deformations were kept small, and under thes...

  9. Gas hydrates in the Gulf of Mexico 

    E-Print Network [OSTI]

    Cox, Henry Benjamin

    1986-01-01

    OCE-8020560. Additional funding and the majority of sample collection was done on geochemical survey cruises in 1983, 1984 and 1985 through the participation of the aforementioned oil companies. Finally, I'd like to thank Kathy York for her love... the sediment. Some hydrates were found associated with oil stained sediments while others were interspersed with carbonate rubble. These hydrated cores represent less than 1% of the approximately 1000 piston cores that have been taken in the Gulf of Mexico...

  10. RESOURCE CHARACTERIZATION AND QUANTIFICATION OF NATURAL GAS-HYDRATE AND ASSOCIATED FREE-GAS ACCUMULATIONS IN THE PRUDHOE BAY - KUPARUK RIVER AREA ON THE NORTH SLOPE OF ALASKA

    SciTech Connect (OSTI)

    Robert Hunter; Shirish Patil; Robert Casavant; Tim Collett

    2003-06-02

    Interim results are presented from the project designed to characterize, quantify, and determine the commercial feasibility of Alaska North Slope (ANS) gas-hydrate and associated free-gas resources in the Prudhoe Bay Unit (PBU), Kuparuk River Unit (KRU), and Milne Point Unit (MPU) areas. This collaborative research will provide practical input to reservoir and economic models, determine the technical feasibility of gas hydrate production, and influence future exploration and field extension of this potential ANS resource. The large magnitude of unconventional in-place gas (40-100 TCF) and conventional ANS gas commercialization evaluation creates industry-DOE alignment to assess this potential resource. This region uniquely combines known gas hydrate presence and existing production infrastructure. Many technical, economical, environmental, and safety issues require resolution before enabling gas hydrate commercial production. Gas hydrate energy resource potential has been studied for nearly three decades. However, this knowledge has not been applied to practical ANS gas hydrate resource development. ANS gas hydrate and associated free gas reservoirs are being studied to determine reservoir extent, stratigraphy, structure, continuity, quality, variability, and geophysical and petrophysical property distribution. Phase 1 will characterize reservoirs, lead to recoverable reserve and commercial potential estimates, and define procedures for gas hydrate drilling, data acquisition, completion, and production. Phases 2 and 3 will integrate well, core, log, and long-term production test data from additional wells, if justified by results from prior phases. The project could lead to future ANS gas hydrate pilot development. This project will help solve technical and economic issues to enable government and industry to make informed decisions regarding future commercialization of unconventional gas-hydrate resources.

  11. Unconventional gas hydrate seals may trap gas off southeast US. [North Carolina, South Carolina

    SciTech Connect (OSTI)

    Dillion, W.P.; Grow, J.A.; Paull, C.K.

    1980-01-07

    Seismic profiles have indicated to the US Geological Survey that an unconventional seal, created by gas hydrates that form in near-bottom sediments, may provide gas traps in continental slopes and rises offshore North and South Carolina. The most frequently cited evidence for the presence of gas hydrate in ocean sediments is the observation of a seismic reflection event that occurs about 1/2 s below and parallel with the seafloor. If gas-hydrate traps do exist, they will occur at very shallow sub-bottom depths of about 1600 ft (500m). Exploration of such traps will probably take place in the federally controlled Blake Ridge area off the coast of South Carolina where seismic data suggest a high incidence of gas hydrates. However, drilling through the gas-hydrate-cemented layer may require new engineering techniques for sealing the casing.

  12. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing. Annual report, January 1--December 31, 1994

    SciTech Connect (OSTI)

    1994-12-31

    Natural gas hydrates are crystalline materials formed of natural gas and water at elevated pressures and reduced temperatures. Because natural gas hydrates can plug drill strings, pipelines, and process equipment, there is much effort expended to prevent their formation. The goal of this project was to provide industry with more economical hydrate inhibitors. The specific goals for the past year were to: define a rational approach for inhibitor design, using the most probable molecular mechanism; improve the performance of inhibitors; test inhibitors on Colorado School of Mines apparatuses and the Exxon flow loop; and promote sharing field and flow loop results. This report presents the results of the progress on these four goals.

  13. Gas hydrates at two sites of an active continental margin

    SciTech Connect (OSTI)

    Kvenvolden, K.A.

    1985-03-01

    Sediment containing gas hydrates from two distant Deep Sea Drilling Project sites (565 and 568), located about 670 km apart or the landward flank of the Middle America Trench, was studied to determine the geochemical conditions that characterize the occurrence of gas hydrates. Site 565 was located in the Pacific Ocean offshore the Nicoya Peninsula of Costa Rica in 3,111 m of water. The depth of the hole at this site was 328 m, and gas hydrates were recovered from 285 and 319 m. Site 568 was located about 670 km to the northwest offshore Guatemala in 2,031 m of water. At this site the hole penetrated to 418 m, and gas hydrates were encountered at 404 m. Both sites are characterized by rates of sedimentation exceeding about 30 m/m.y. and organic carbon contents exceeding about 0.5%. The magnitudes and trends of gas compositions, residual gas concentrations and chlorinity variations are generally similar at both sites. The carbon isotopic compositions are significantly heavier at Site 568 than at Site 565. The isotopic compositions and trends at Site 565 are typical of biogenic methane generation. At Site 568, the isotopic compositions are very heavy. In spite of its heavy carbon isotopic composition, this methane is believed to have a biogenic source.

  14. Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

    E-Print Network [OSTI]

    Moridis, George J.; Sloan, E. Dendy

    2006-01-01

    Page viable gas production. The overall conclusion drawnnot promising targets for gas production. Acknowledgment TheTS. Strategies for gas production from hydrate accumulations

  15. Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor

    DOE Patents [OSTI]

    Wyatt, Douglas E. (Aiken, SC)

    2001-01-01

    A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

  16. Gas Hydrate Characterization in the GoM using Marine EM Methods

    SciTech Connect (OSTI)

    Steven Constable

    2012-03-31

    In spite of the importance of gas hydrate as a low-carbon fuel, a possible contributor to rapid climate change, and a significant natural hazard, our current understanding about the amount and distribution of submarine gas hydrate is somewhat poor; estimates of total volume vary by at least an order of magnitude, and commercially useful concentrations of hydrate have remained an elusive target. This is largely because conventional geophysical tools have intrinsic limitations in their ability to quantitatively image hydrate. It has long been known from well logs that gas hydrate is resistive compared to the host sediments, and electrical and electromagnetic methods have been proposed and occasionally used to image hydrates. This project seeks to expand our capabilities to use electromagnetic methods to explore for gas hydrate in the marine environment. An important basic science aspect of our work was to quantify the resistivity of pure gas hydrate as a function of temperature at seafloor pressures. We designed, constructed, and tested a highpressure cell in which hydrate could be synthesized and then subjected to electrical conductivity measurements. Impedance spectroscopy at frequencies between 20 Hz and 2 MHz was used to separate the effect of the blocking electrodes from the intrinsic conductivity of the hydrate. We obtained very reproducible results that showed that pure methane hydrate was several times more resistive than the water ice that seeded the synthesis, 20,000 {Ohm}m at 0{degrees}#14;C, and that the activation energy is 30.6 kJ/mol over the temperature range of -15 to 15{degrees}#14;C. Adding silica sand to the hydrate, however, showed that the addition of the extra phase caused the conductivity of the assemblage to increase in a counterintuitive way. The fact that the increased conductivity collapsed after a percolation threshold was reached, and that the addition of glass beads does not produce a similar increase in conductivity, together suggest that while the surface of the gas hydrate grains are not intrinsically conductive, the presence of sand does increase their conductivity. In the field component of this project, we carried out an 18day cruise on the R.V. Roger Revelle in the Gulf of Mexico from 7th-Ă?Â?26th October 2008 to collect controlled-source electromagnetic (CSEM) data over four hydrate prospects; blocks AC 818, WR 313, GC 955, and MC 118. During these surveys we deployed 30 ocean bottom electromagnetic (OBEM) recorders a total of 94 times at four survey areas and towed the Scripps Undersea Electromagnetic Source Instrument (SUESI) a total of 103 hours. SUESI transmission was 200 A on a 50 m dipole antenna at heights of 70-100 m above the seafloor. We also towed a neutrally buoyant 3-axis electric field recorder behind the SUESI antenna at a constant offset of 300 m. The use of a towed receiver that is "flown" above the seafloor allowed us to operate in areas where seafloor infrastructure such as wellheads, pipelines, and installed scientific equipment existed. We reduced the data to apparent resistivity psuedosections. The most compelling results come from the hydrate observatory at MC 118, where a localized resistivity anomaly is clearly identified under the southeast crater in an otherwise uniform 1 {Ohm}m background. The data from MC 118 also show that authigenic carbonate does not necessarily express itself as a confounding resistor, as was feared at the start of this project. While the results from the other prospects are much more complicated, the data are well correlated with known geology, and line to line agreement is good. Although these data are not amenable to 1D inversion as was initially hoped, we expect to use a newly developed 2D CSEM inversion code to continue to get useful information from this rich data set.

  17. Site Selection for DOE/JIP Gas Hydrate Drilling in the Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Collett, T.S.; Riedel, M.; Cochran, J.R.; Boswell, R.M.; Kumar, Pushpendra; Sathe, A.V.

    2008-07-01

    Studies of geologic and geophysical data from the offshore of India have revealed two geologically distinct areas with inferred gas hydrate occurrences: the passive continental margins of the Indian Peninsula and along the Andaman convergent margin. The Indian National Gas Hydrate Program (NGHP) Expedition 01 was designed to study the occurrence of gas hydrate off the Indian Peninsula and along the Andaman convergent margin with special emphasis on understanding the geologic and geochemical controls on the occurrence of gas hydrate in these two diverse settings. NGHP Expedition 01 established the presence of gas hydrates in Krishna- Godavari, Mahanadi and Andaman basins. The expedition discovered one of the richest gas hydrate accumulations yet documented (Site 10 in the Krishna-Godavari Basin), documented the thickest and deepest gas hydrate stability zone yet known (Site 17 in Andaman Sea), and established the existence of a fully-developed gas hydrate system in the Mahanadi Basin (Site 19).

  18. Dynamics of lysozyme and its hydration water under electric field

    E-Print Network [OSTI]

    P. M. Favi; Q. Zhang; H. O'Neill; E. Mamontov; S. O. Diallo

    2013-12-06

    The effects of static electric field on the dynamics of lysozyme and its hydration water have been investigated by means of incoherent quasi-elastic neutron scattering (QENS). Measurements were performed on lysozyme samples, hydrated respectively with heavy water (D2O) to capture the protein dynamics, and with light water (H2O), to probe the dynamics of the hydration shell, in the temperature range from 210 $water per gram of dry protein. The field strengths investigated were respectively 0 kV/mm and 2 kV/mm (2 10$^6$ V/m) for the protein hydrated with D2O and 0 kV and 1 kV/mm for the H2O hydrated counterpart. While the overall internal protons dynamics of the protein appears to be unaffected by the application of electric field up to 2 kV/mm, likely due to the stronger intra-molecular interactions, there is also no appreciable quantitative enhancement of the diffusive dynamics of the hydration water, as would be anticipated based on our recent observations in water confined in silica pores under field values of 2.5 kV/mm. This may be due to the difference in surface interactions between water and the two adsorption hosts (silica and protein), or to the existence of a critical threshold field value Ec $\\sim$ 2-3 kV/mm for increased molecular diffusion, for which electrical breakdown is a limitation for our sample.

  19. Anomalous porosity preservation and preferential accumulation of gas hydrate in the Andaman accretionary wedge, NGHP-01 site 17A

    SciTech Connect (OSTI)

    Rose, Kelly K.; Johnson, Joel E.; Torres, Marta E.; Hong, WeiLi; Giosan, Liviu; Solomon, E.; Kastner, Miriam; Cawthern, Thomas; Long, Philip E.; Schaef, Herbert T.

    2014-12-01

    In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.

  20. Increasing gas hydrate formation temperature for desalination of high salinity produced water with secondary guests

    SciTech Connect (OSTI)

    Cha, Jong-Ho [ORISE; Seol, Yongkoo [U.S. DOE

    2013-01-01

    We suggest a new gas hydrate-based desalination process using water-immiscible hydrate formers; cyclopentane (CP) and cyclohexane (CH) as secondary hydrate guests to alleviate temperature requirements for hydrate formation. The hydrate formation reactions were carried out in an isobaric condition of 3.1 MPa to find the upper temperature limit of CO2 hydrate formation. Simulated produced water (8.95 wt % salinity) mixed with the hydrate formers shows an increased upper temperature limit from ?2 °C for simple CO2 hydrate to 16 and 7 °C for double (CO2 + CP) and (CO2 + CH) hydrates, respectively. The resulting conversion rate to double hydrate turned out to be similar to that with simple CO2 hydrate at the upper temperature limit. Hydrate formation rates (Rf) for the double hydrates with CP and CH are shown to be 22 and 16 times higher, respectively, than that of the simple CO2 hydrate at the upper temperature limit. Such mild hydrate formation temperature and fast formation kinetics indicate increased energy efficiency of the double hydrate system for the desalination process. Dissociated water from the hydrates shows greater than 90% salt removal efficiency for the hydrates with the secondary guests, which is also improved from about 70% salt removal efficiency for the simple hydrates.

  1. Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates Formation and Silica Diagenesis

    E-Print Network [OSTI]

    Guerin, Gilles

    Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates Formation and Silica Rights Reserved #12;ABSTRACT Acoustic and Thermal Characterization of Oil Migration, Gas Hydrates-A to Opal-CT, the formation of gas hydrates, fluid substitution in hydrocarbon reservoirs, and fluid

  2. Prediction of gas-hydrate formation conditions in production and surface facilities 

    E-Print Network [OSTI]

    Ameripour, Sharareh

    2006-10-30

    .2 Phase diagram for natural gas hydrocarbons which form hydrates .............9 Fig. 2.3 Formation of gas hydrate plugs a subsea hydrocarbon pipeline................11 Fig. 2.4 Experimental hydrate equilibrium conditions for the ternary... exploration and production operations. Hydrate clathrates can plug gas gathering systems and transmission pipelines subsea and on the surface. In offshore explorations, the main concern is the multiphase transfer lines from the wellhead...

  3. Integrating Natural Gas Hydrates in the Global Carbon Cycle

    SciTech Connect (OSTI)

    David Archer; Bruce Buffett

    2011-12-31

    We produced a two-dimensional geological time- and basin-scale model of the sedimentary margin in passive and active settings, for the simulation of the deep sedimentary methane cycle including hydrate formation. Simulation of geochemical data required development of parameterizations for bubble transport in the sediment column, and for the impact of the heterogeneity in the sediment pore fluid flow field, which represent new directions in modeling methane hydrates. The model is somewhat less sensitive to changes in ocean temperature than our previous 1-D model, due to the different methane transport mechanisms in the two codes (pore fluid flow vs. bubble migration). The model is very sensitive to reasonable changes in organic carbon deposition through geologic time, and to details of how the bubbles migrate, in particular how efficiently they are trapped as they rise through undersaturated or oxidizing chemical conditions and the hydrate stability zone. The active margin configuration reproduces the elevated hydrate saturations observed in accretionary wedges such as the Cascadia Margin, but predicts a decrease in the methane inventory per meter of coastline relative to a comparable passive margin case, and a decrease in the hydrate inventory with an increase in the plate subduction rate.

  4. Ground movements associated with gas hydrate production. Final report

    SciTech Connect (OSTI)

    Siriwardane, H.J.; Kutuk, B.

    1992-03-01

    This report deals with a study directed towards a modeling effort on production related ground movements and subsidence resulting from hydrate dissociation. The goal of this research study was to evaluate whether there could be subsidence related problems that could be an impediment to hydrate production. During the production of gas from a hydrate reservoir, it is expected that porous reservoir matrix becomes more compressible which may cause reservoir compression (compaction) under the influence of overburden weight. The overburden deformations can propagate its influence upwards causing subsidence near the surface where production equipment will be located. In the present study, the reservoir compaction is modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The present study is expected to provide a ``lower bound`` solution to the subsidence caused by hydrate reservoir depletion. The reservoir compaction anticipated during hydrate production was modeled by using the finite element method, which is a powerful computer modeling technique. The ground movements at the reservoir roof (i.e. reservoir compression) cause additional stresses and disturbance in the overburden strata. In this study, the reservoir compaction was modeled by using the conventional ``stress equilibrium`` approach. In this approach, the overburden strata move under the influence of body force (i.e. self weight) in response to the ``cavity`` generated by reservoir depletion. The resulting stresses and ground movements were computed by using the finite element method. Based on the parameters used in this investigation, the maximum ground subsidence could vary anywhere from 0.50 to 6.50 inches depending on the overburden depth and the size of the depleted hydrate reservoir.

  5. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    different example geothermal gradients (0.04°C/m, 0.032°C/m,intersections of the geothermal gradient and the gas-hydrateCollett, 2002). A geothermal gradient of 0.04°C/m projected

  6. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing. Annual report, January 1--December 31, 1993

    SciTech Connect (OSTI)

    1993-12-31

    Natural gas hydrates are crystalline materials formed of natural gas and water at elevated pressures and reduced temperatures. Because natural gas hydrates can plug drill strings, pipelines, and process equipment, there is much effort expended to prevent their formation. The goal of this project was to provide industry with more economical hydrate inhibitors. The specific goals for the past year were to: continue both screening and high pressure experiments to determine optimum inhibitors; investigate molecular mechanisms of hydrate formation/inhibition, through microscopic and macroscopic experiments; begin controlled tests on the Exxon pilot plant loop at their Houston facility; and continue to act as a forum for the sharing of field test results. Progress on these objectives are described in this report.

  7. GULF OF MEXICO SEAFLOOR STABILITY AND GAS HYDRATE MONITORING STATION PROJECT

    SciTech Connect (OSTI)

    J. Robert Woolsey; Thomas M. McGee; Robin C. Buchannon

    2004-11-01

    The gas hydrates research Consortium (HRC), established and administered at the University if Mississippi's Center for Marine Research and Environmental Technology (CMRET) has been active on many fronts in FY 03. Extension of the original contract through March 2004, has allowed completion of many projects that were incomplete at the end of the original project period due, primarily, to severe weather and difficulties in rescheduling test cruises. The primary objective of the Consortium, to design and emplace a remote sea floor station for the monitoring of gas hydrates in the Gulf of Mexico by the year 2005 remains intact. However, the possibility of levering HRC research off of the Joint Industries Program (JIP) became a possibility that has demanded reevaluation of some of the fundamental assumptions of the station format. These provisions are discussed in Appendix A. Landmark achievements of FY03 include: (1) Continuation of Consortium development with new researchers and additional areas of research contribution being incorporated into the project. During this period, NOAA's National Undersea Research Program's (NURP) National Institute for Undersea Science and Technology (NIUST) became a Consortium funding partner, joining DOE and Minerals Management Service (MMS); (2) Very successful annual and semiannual meetings in Oxford Mississippi in February and September, 2003; (3) Collection of piston cores from MC798 in support of the effort to evaluate the site for possible monitoring station installation; (4) Completion of the site evaluation effort including reports of all localities in the northern Gulf of Mexico where hydrates have been documented or are strongly suspected to exist on the sea floor or in the shallow subsurface; (5) Collection and preliminary evaluation of vent gases and core samples of hydrate from sites in Green Canyon and Mississippi Canyon, northern Gulf of Mexico; (6) Monitoring of gas activity on the sea floor, acoustically and thermally; (7) Design, construction, and successful deployment of an in situ pore-water sampling device; (8) Improvements to the original Raman spectrometer (methane sensor); (9) Laboratory demonstration of the impact of bacterially-produced surfactants' rates of hydrate formation; (10) Construction and sea floor emplacement and testing--with both watergun and ship noise sources--of the prototypal vertical line array (VLA); (11) Initiation of studies of spatial controls on hydrates; (12) Compilation and analyses of seismic data, including mapping of surface anomalies; (13) Additional field verification (bottom samples recovered), in support of the site selection effort; (14) Collection and preliminary analyses of gas hydrates from new sites that exhibit variant structures; (15) Initial shear wave tests carried out in shallow water; (16) Isolation of microbes for potential medicinal products development; (17) Preliminary modeling of occurrences of gas hydrates.

  8. Selection of hydrate suppression methods for gas streams

    SciTech Connect (OSTI)

    Behrens, S.D.; Covington, K.K.; Collie, J.T. III

    1999-07-01

    This paper will discuss and compare the methods used to suppress hydrate formation in natural gas streams. Included in the comparison will be regenerated systems using ethylene glycol and non-regenerated systems using methanol. A comparison will be made between the quantities of methanol and ethylene glycol required to achieve a given a suppression. A discussion of BTEX emissions resulting from the ethylene glycol regenerator along with the effect or process variables on these emissions is also given.

  9. Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead

    SciTech Connect (OSTI)

    BC Technologies

    2009-12-30

    Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate >40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate >23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.

  10. Hydrate characterization research overview

    SciTech Connect (OSTI)

    Malone, R.D.

    1993-06-01

    Gas hydrate research has been focused primarily on the development of a basic understanding of hydrate formation and dissociation in the laboratory, as well as in the field. Laboratory research on gas hydrates characterized the physical system, which focused on creating methane hydrates samples, tetrahydrofuran (THF) hydrate samples, consolidated rock samples, frost base mixtures, water/ice-base mixtures, and water-base mixtures. Laboratory work produced measurements of sonic velocity and electrical resistivity of hydrates. As work progressed, areas, such as the Gulf of Mexico and the Guatemala Trench, where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for detailed investigation. The testing of samples and recovered cores from such areas provided information for detection of hydrate formations in the natural environment. Natural gas hydrate samples have been tested for thermal properties, dissociation properties, fracture mechanics, and optical properties. Acoustical properties were investigated both in the laboratory and, as possible, in the field. Sonic velocity and electrical resistivity measurements will continue to be obtained. These activities have been undertaken in hydrate deposits on Alaska`s North Slope, the Gulf of Mexico and the US East coast offshore, as well as other gas hydrate target areas.

  11. The Resource Potential of Natural Gas Hydrates

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE- Non-ResidentialAlliantPGE andOfficeMatt Rogers MattReadiness of theDr.The

  12. Strategies for gas production from oceanic Class 3 hydrate accumulations

    E-Print Network [OSTI]

    Moridis, George J.; Reagan, Matthew T.

    2007-01-01

    during production from the Class 3 oceanic hydrate depositProduction From Oceanic Class 3 Hydrate Accumulations GeorgeAccumulations Houston, Texas, Class 3 May 2007. presented,

  13. Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report

    SciTech Connect (OSTI)

    McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

    2007-09-01

    Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

  14. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    E-Print Network [OSTI]

    Boswell, R.D.

    2010-01-01

    of the reservoir with gas hydrate saturation in excess ofquality reservoirs, consistent with the lower saturationssaturation remains uniformly high wherever the Frio reservoir

  15. A Quantum Chemistry Study of Natural Gas Hydrates Mert Atilhan,1

    E-Print Network [OSTI]

    Pala, Nezih

    1 A Quantum Chemistry Study of Natural Gas Hydrates Mert Atilhan,1 Nezih Pala,2 and Santiago.A.), npala@fiu.edu (N.P.) and sapar@ubu.es (S.A.) ABSTRACT The structure and properties of natural gas to take account of dispersion. Keywords: Natural gas, hydrates, quantum chemistry, density functional

  16. Ethane enrichment and propane depletion in subsurface gases indicate gas hydrate occurrence in marine sediments at southern Hydrate Ridge offshore Oregon

    SciTech Connect (OSTI)

    Milkov, Alexei V.; Claypool, G E.; Lee, Young-Joo; Torres, Marta E.; Borowski, W S.; Tomaru, H; Sassen, Roger; Long, Philip E.

    2004-07-02

    The recognition of finely disseminated gas hydrate in deep marine sediments heavily depends on various indirect techniques because this mineral quickly decomposes upon recovery from in situ pressure and temperature conditions. Here, we discuss molecular properties of closely spaced gas voids (formed as a result of core recovery) and gas hydrates from an area of relatively low gas flux at the flanks of the southern Hydrate Ridge Offshore Oregon (ODP Sites 1244, 1245 and 1247).

  17. Sources of biogenic methane to form marine gas hydrates: In situ production or upward migration?

    SciTech Connect (OSTI)

    Paull, C.K.; Ussler, W. III; Borowski, W.S.

    1993-09-01

    Potential sources of biogenic methane in the Carolina Continental Rise -- Blake Ridge sediments have been examined. Two models were used to estimate the potential for biogenic methane production: (1) construction of sedimentary organic carbon budgets, and (2) depth extrapolation of modern microbial production rates. While closed-system estimates predict some gas hydrate formation, it is unlikely that >3% of the sediment volume could be filled by hydrate from methane produced in situ. Formation of greater amounts requires migration of methane from the underlying continental rise sediment prism. Methane may be recycled from below the base of the gas hydrate stability zone by gas hydrate decomposition, upward migration of the methane gas, and recrystallization of gas hydrate within the overlying stability zone. Methane bubbles may also form in the sediment column below the depth of gas hydrate stability because the methane saturation concentration of the pore fluids decreases with increasing depth. Upward migration of methane bubbles from these deeper sediments can add methane to the hydrate stability zone. From these models it appears that recycling and upward migration of methane is essential in forming significant gas hydrate concentrations. In addition, the depth distribution profiles of methane hydrate will differ if the majority of the methane has migrated upward rather than having been produced in situ.

  18. Methane Hydrate Field Studies | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy AEnergy Managing Swimming PoolCommercial IndustrialDepartment of68 of the

  19. Kinetic inhibition of natural gas hydrates in offshore drilling, production, and processing operations. Annual report, January 1--December 31, 1992

    SciTech Connect (OSTI)

    1992-12-31

    Natural gas hydrates are solid crystalline compounds which form when molecules smaller than n-butane contact molecules of water at elevated pressures and reduced temperatures, both above and below the ice point. Because these crystalline compounds plug flow channels, they are undesirable. In this project the authors proposed an alternate approach of controlling hydrate formation by preventing hydrate growth into a sizeable mass which could block a flow channel. The authors call this new technique kinetic inhibition, because while it allows the system to exist in the hydrate domain, it prevents the kinetic agglomeration of small hydrate crystals to the point of pluggage of a flow channel. In order to investigate the kinetic means of inhibiting hydrate formation, they held two consortium meetings, on June 1, 1990 and on August 31, 1990. At subsequent meetings, the authors determined the following four stages of the project, necessary to reach the goal of determining a new hydrate field inhibitor: (1) a rapid screening method was to be determined for testing the hydrate kinetic formation period of many surfactants and polymer candidates (both individually and combined), the present report presents the success of two screening apparatuses: a multi-reactor apparatus which is capable of rapid, high volume screening, and the backup screening method--a viscometer for testing with gas at high pressure; (2) the construction of two high, constant pressure cells were to experimentally confirm the success of the chemicals in the rapid screening apparatus; (3) in the third phase of the work, Exxon volunteered to evaluate the performance of the best chemicals from the previous two stages in their 4 inch I.D. Multiphase flow loop in Houston; (4) in the final phase of the work, the intention was to take the successful kinetic inhibition chemicals from the previous three stages and then test them in the field in gathering lines and wells from member companies.

  20. A multi-phase, micro-dispersion reactor for the continuous production of methane gas hydrate

    SciTech Connect (OSTI)

    Taboada Serrano, Patricia L [ORNL; Ulrich, Shannon M [ORNL; Szymcek, Phillip [ORNL; McCallum, Scott [Oak Ridge Associated Universities (ORAU); Phelps, Tommy Joe [ORNL; Palumbo, Anthony Vito [ORNL; Tsouris, Costas [ORNL

    2009-01-01

    A continuous-jet hydrate reactor originally developed to generate a CO2 hydrate stream has been modified to continuously produce CH4 hydrate. The reactor has been tested in the Seafloor Process Simulator (SPS), a 72-L pressure vessel available at Oak Ridge National Laboratory. During experiments, the reactor was submerged in water inside the SPS and received water from the surrounding through a submersible pump and CH4 externally through a gas booster pump. Thermodynamic conditions in the hydrate stability regime were employed in the experiments. The reactor produced a continuous stream of CH4 hydrate, and based on pressure values and amount of gas injected, the conversion of gas to hydrate was estimated. A conversion of up to 70% was achieved using this reactor.

  1. International Conference on Gas Hydrates May 19-23, 2002, Yokohama

    E-Print Network [OSTI]

    Gudmundsson, Jon Steinar

    and Technology, 7491 Trondheim, Norway The rate of hydrate formation is an important parameter in the production of hydrates for transport and storage of natural gas and in cold flow technology. In a continuous stirred tank processes rather than growth kinetics. A bubble-to-crystal model has been developed for the transport of gas

  2. Occurrence of gas hydrate in Oligocene Frio sand: Alaminos Canyon Block 818: Northern Gulf of Mexico

    SciTech Connect (OSTI)

    Boswell, R.D.; Shelander, D.; Lee, M.; Latham, T.; Collett, T.; Guerin, G.; Moridis, G.; Reagan, M.; Goldberg, D.

    2009-07-15

    A unique set of high-quality downhole shallow subsurface well log data combined with industry standard 3D seismic data from the Alaminos Canyon area has enabled the first detailed description of a concentrated gas hydrate accumulation within sand in the Gulf of Mexico. The gas hydrate occurs within very fine grained, immature volcaniclastic sands of the Oligocene Frio sand. Analysis of well data acquired from the Alaminos Canyon Block 818 No.1 ('Tigershark') well shows a total gas hydrate occurrence 13 m thick, with inferred gas hydrate saturation as high as 80% of sediment pore space. Average porosity in the reservoir is estimated from log data at approximately 42%. Permeability in the absence of gas hydrates, as revealed from the analysis of core samples retrieved from the well, ranges from 600 to 1500 millidarcies. The 3-D seismic data reveals a strong reflector consistent with significant increase in acoustic velocities that correlates with the top of the gas-hydrate-bearing sand. This reflector extends across an area of approximately 0.8 km{sup 2} and delineates the minimal probable extent of the gas hydrate accumulation. The base of the inferred gas-hydrate zone also correlates well with a very strong seismic reflector that indicates transition into units of significantly reduced acoustic velocity. Seismic inversion analyses indicate uniformly high gas-hydrate saturations throughout the region where the Frio sand exists within the gas hydrate stability zone. Numerical modeling of the potential production of natural gas from the interpreted accumulation indicates serious challenges for depressurization-based production in settings with strong potential pressure support from extensive underlying aquifers.

  3. Development of Alaskan gas hydrate resources: Annual report, October 1986--September 1987

    SciTech Connect (OSTI)

    Sharma, G.D.; Kamath, V.A.; Godbole, S.P.; Patil, S.L.; Paranjpe, S.G.; Mutalik, P.N.; Nadem, N.

    1987-10-01

    Solid ice-like mixtures of natural gas and water in the form of natural gas hydrated have been found immobilized in the rocks beneath the permafrost in Arctic basins and in muds under the deep water along the American continental margins, in the North Sea and several other locations around the world. It is estimated that the arctic areas of the United States may contain as much as 500 trillion SCF of natural gas in the form of gas hydrates (Lewin and Associates, 1983). While the US Arctic gas hydrate resources may have enormous potential and represent long term future source of natural gas, the recovery of this resource from reservoir frozen with gas hydrates has not been commercialized yet. Continuing study and research is essential to develop technologies which will enable a detailed characterization and assessment of this alternative natural gas resource, so that development of cost effective extraction technology.

  4. Investigation of gas hydrate-bearing sandstone reservoirs at the "Mount Elbert" stratigraphic test well, Milne Point, Alaska

    SciTech Connect (OSTI)

    Boswell, R.M.; Hunter, R.; Collett, T.; Digert, S. Inc., Anchorage, AK); Hancock, S.; Weeks, M. Inc., Anchorage, AK); Mt. Elbert Science Team

    2008-01-01

    In February 2007, the U.S. Department of Energy, BP Exploration (Alaska), Inc., and the U.S. Geological Survey conducted an extensive data collection effort at the "Mount Elbert #1" gas hydrates stratigraphic test well on the Alaska North Slope (ANS). The 22-day field program acquired significant gas hydrate-bearing reservoir data, including a full suite of open-hole well logs, over 500 feet of continuous core, and open-hole formation pressure response tests. Hole conditions, and therefore log data quality, were excellent due largely to the use of chilled oil-based drilling fluids. The logging program confirmed the existence of approximately 30 m of gashydrate saturated, fine-grained sand reservoir. Gas hydrate saturations were observed to range from 60% to 75% largely as a function of reservoir quality. Continuous wire-line coring operations (the first conducted on the ANS) achieved 85% recovery through 153 meters of section, providing more than 250 subsamples for analysis. The "Mount Elbert" data collection program culminated with open-hole tests of reservoir flow and pressure responses, as well as gas and water sample collection, using Schlumberger's Modular Formation Dynamics Tester (MDT) wireline tool. Four such tests, ranging from six to twelve hours duration, were conducted. This field program demonstrated the ability to safely and efficiently conduct a research-level openhole data acquisition program in shallow, sub-permafrost sediments. The program also demonstrated the soundness of the program's pre-drill gas hydrate characterization methods and increased confidence in gas hydrate resource assessment methodologies for the ANS.

  5. Modelling of Gas Clathrate Hydrate Equilibria using the Electrolyte Non-Random Two-Liquid (eNRTL) Model

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    )-liquid ( wL )-gas (G)-phase equilibria of selected ternary {water + salt + gas} and quaternary {water + salt1 + salt2 + gas} systems (salt = NaCl, KCl, CaCl2; gas = CH4, CO2) comprising a gas clathrate hydrate phase.g. pipeline blockages by hydrates in drilling applications or gas pipelines) [6]. Species being capable

  6. Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions

    E-Print Network [OSTI]

    Zhang, Youxue

    Methane escape from gas hydrate systems in marine environment, and methane-driven oceanic eruptions quantities of CH4 are stored in marine sediment in the form of methane hydrate, bubbles, and dissolved CH4 in pore water. Here I discuss the various pathways for methane to enter the ocean and atmosphere

  7. Method for the photocatalytic conversion of gas hydrates

    DOE Patents [OSTI]

    Taylor, Charles E. (Pittsburg, PA); Noceti, Richard P. (Pittsburg, PA); Bockrath, Bradley C. (Bethel Park, PA)

    2001-01-01

    A method for converting methane hydrates to methanol, as well as hydrogen, through exposure to light. The process includes conversion of methane hydrates by light where a radical initiator has been added, and may be modified to include the conversion of methane hydrates with light where a photocatalyst doped by a suitable metal and an electron transfer agent to produce methanol and hydrogen. The present invention operates at temperatures below 0.degree. C., and allows for the direct conversion of methane contained within the hydrate in situ.

  8. Oil & Natural Gas Technology Temporal Characterization of Hydrates...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    controlled by both deep and near- surface structure. Results have been integrated with seismic data from the area and show correspondence in space of hydrate and structures,...

  9. Hydrate Formation and Dissociation in Simulated and Field Samples

    E-Print Network [OSTI]

    Pennycook, Steve

    -Resolved 3-D temperature monitoring #12;Distributed Sensing System (DSS) The Luna® Distributed Sensing System-Situ Diffraction ­ XRD ­ Neutron · Hydrate synthesis capabilities · Seafloor Processing Simulator ­ housed and temperatures where hydrates are stable ­ Luna Distributed Sensing System (DSS) for observation of hydrate

  10. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    SciTech Connect (OSTI)

    Reagan, M.; Moridis, G.; Elliott, S.; Maltrud, M.

    2011-06-01

    Vast quantities of methane are trapped in oceanic hydrate deposits, and there is concern that a rise in the ocean temperature will induce dissociation of these hydrate accumulations, potentially releasing large amounts of carbon into the atmosphere. Because methane is a powerful greenhouse gas, such a release could have dramatic climatic consequences. The recent discovery of active methane gas venting along the landward limit of the gas hydrate stability zone (GHSZ) on the shallow continental slope (150 m - 400 m) west of Svalbard suggests that this process may already have begun, but the source of the methane has not yet been determined. This study performs 2-D simulations of hydrate dissociation in conditions representative of the Arctic Ocean margin to assess whether such hydrates could contribute to the observed gas release. The results show that shallow, low-saturation hydrate deposits, if subjected to recently observed or future predicted temperature changes at the seafloor, can release quantities of methane at the magnitudes similar to what has been observed, and that the releases will be localized near the landward limit of the GHSZ. Both gradual and rapid warming is simulated, along with a parametric sensitivity analysis, and localized gas release is observed for most of the cases. These results resemble the recently published observations and strongly suggest that hydrate dissociation and methane release as a result of climate change may be a real phenomenon, that it could occur on decadal timescales, and that it already may be occurring.

  11. Depressurization-induced gas production from Class 1 and Class 2 hydrate deposits

    E-Print Network [OSTI]

    Moridis, George J.; Kowalsky, Michael

    2006-01-01

    Induced Gas Production From Class 1 Hydrate Deposits, SPEso in Stage IV. 3. In Class 1W deposits, up to 65% of the4. Production from Class 1G deposits is continuous, free of

  12. First results from a marine controlled-source electromagnetic survey to detect gas hydrates offshore Oregon

    E-Print Network [OSTI]

    Constable, Steve

    offshore Oregon K. A. Weitemeyer, S. C. Constable, K. W. Key, and J. P. Behrens Scripps Institution from a marine controlled-source electromagnetic survey to detect gas hydrates offshore Oregon, Geophys

  13. Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

    E-Print Network [OSTI]

    Moridis, George J.; Sloan, E. Dendy

    2006-01-01

    bound gas in marine sediments: how much is really out there?methane hydrate in ocean sediment. Energy & Fuels 2005: 19:Accumulations in Oceanic Sediments George J. Moridis 1 and

  14. Molecular dynamics simulations of methane hydrate using polarizable force fields

    SciTech Connect (OSTI)

    Jiang, H.N.; Jordan, K.D.; Taylor, C.E.

    2007-03-01

    Molecular dynamics simulations of methane hydrate have been carried out using the AMOEBA and COS/G2 polarizable force fields. Properties examined include the temperature dependence of the lattice constant, the OC and OO radial distribution functions and the vibrational spectra. Both the AMOEBA and COS/G2 models are found to successfully account for the available experimental data, with overall slightly better agreement with experiment being found for the AMOEBA model. Several properties calculated using the AMOEBA and COS/G2 models differ appreciable from the corresponding results obtained previously using the polarizable TIP4P-FQ model. This appears to be due to the inadequacy of the treatment of polarization, especially, the restriction of polarization to in-plane only, in the TIP4P-FQ model.

  15. Methane hydrate distribution from prolonged and repeated formation in natural and compacted sand samples: X-ray CT observations

    E-Print Network [OSTI]

    Rees, E.V.L.

    2012-01-01

    Deep Ocean Field Test of Methane Hydrate Formation from aW.J. , and Mason, D.H. , Methane Hydrate Formation inNatural and Laboratory--Formed Methane Gas Hydrate. American

  16. Methane Hydrate Field Program: Development of a Scientific Plan for a Methane Hydrate-Focused Marine Drilling, Logging and Coring Program

    SciTech Connect (OSTI)

    Collett, Tim; Bahk, Jang-Jun; Frye, Matt; Goldberg, Dave; Husebo, Jarle; Koh, Carolyn; Malone, Mitch; Shipp, Craig; Torres, Marta; Myers, Greg; Divins, David; Morell, Margo

    2013-11-30

    This topical report represents a pathway toward better understanding of the impact of marine methane hydrates on safety and seafloor stability and future collection of data that can be used by scientists, engineers, managers and planners to study climate change and to assess the feasibility of marine methane hydrate as a potential future energy resource. Our understanding of the occurrence, distribution and characteristics of marine methane hydrates is incomplete; therefore, research must continue to expand if methane hydrates are to be used as a future energy source. Exploring basins with methane hydrates has been occurring for over 30 years, but these e?orts have been episodic in nature. To further our understanding, these e?orts must be more regular and employ new techniques to capture more data. This plan identifies incomplete areas of methane hydrate research and o?ers solutions by systematically reviewing known methane hydrate “Science Challenges” and linking them with “Technical Challenges” and potential field program locations.

  17. GAS METHANE HYDRATES-RESEARCH STATUS, ANNOTATED BIBLIOGRAPHY, AND ENERGY IMPLICATIONS

    SciTech Connect (OSTI)

    James Sorensen; Jaroslav Solc; Bethany Bolles

    2000-07-01

    The objective of this task as originally conceived was to compile an assessment of methane hydrate deposits in Alaska from available sources and to make a very preliminary evaluation of the technical and economic feasibility of producing methane from these deposits for remote power generation. Gas hydrates have recently become a target of increased scientific investigation both from the standpoint of their resource potential to the natural gas and oil industries and of their positive and negative implications for the global environment After we performed an extensive literature review and consulted with representatives of the U.S. Geological Survey (USGS), Canadian Geological Survey, and several oil companies, it became evident that, at the current stage of gas hydrate research, the available information on methane hydrates in Alaska does not provide sufficient grounds for reaching conclusions concerning their use for energy production. Hence, the original goals of this task could not be met, and the focus was changed to the compilation and review of published documents to serve as a baseline for possible future research at the Energy & Environmental Research Center (EERC). An extensive annotated bibliography of gas hydrate publications has been completed. The EERC will reassess its future research opportunities on methane hydrates to determine where significant initial contributions could be made within the scope of limited available resources.

  18. Gas Production From a Cold, Stratigraphically Bounded Hydrate Deposit at the Mount Elbert Site, North Slope, Alaska

    SciTech Connect (OSTI)

    Moridis, G.J.; Silpngarmlert, S.; Reagan, M. T.; Collett, T.S.; Zhang, K.

    2009-09-01

    As part of an effort to identify suitable targets for a planned long-term field test, we investigate by means of numerical simulation the gas production potential from unit D, a stratigraphically bounded (Class 3) permafrost-associated hydrate occurrence penetrated in the ount Elbert well on North Slope, Alaska. This shallow, low-pressure deposit has high porosities, high intrinsic permeabilities and high hydrate saturations. It has a low temperature because of its proximity to the overlying permafrost. The simulation results indicate that vertical ells operating at a constant bottomhole pressure would produce at very low rates for a very long period. Horizontal wells increase gas production by almost two orders of magnitude, but production remains low. Sensitivity analysis indicates that the initial deposit temperature is y the far the most important factor determining production performance (and the most effective criterion for target selection) because it controls the sensible heat available to fuel dissociation.

  19. Massive dissociation of gas hydrate during a Jurassic

    E-Print Network [OSTI]

    Hesselbo, Stephen P.

    the upper oceanic, biospheric and atmospheric carbon reservoirs, and that this occurred despite the enhanced hydrate during a Jurassic oceanic anoxic event Stephen P. Hesselbo*, Darren R. Gro¨cke*, Hugh C. Jenkyns*, Christian J. Bjerrum, Paul Farrimond, Helen S. Morgans Bell* & Owen R. Green* * Department of Earth Sciences

  20. International Conference on Gas Hydrates May 19-23, 2002, Yokohama

    E-Print Network [OSTI]

    Gudmundsson, Jon Steinar

    at high pressure and low temperature. The pressure and temperature conditions for hydrate formation University of Science and Technology, 7491 Trondheim, Norway Cost-effective exploitation of deepwater oil and gas reservoirs, requires trouble free flow of oil, gas and water mixtures from subsea wellheads

  1. Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments [Part 2 of 2

    SciTech Connect (OSTI)

    Bryant, Steven; Juanes, Ruben

    2011-12-31

    In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between intervals containing large hydrate saturations. Large volumes (of order one pore volume) of gaseous and aqueous phases must be transported into the gas hydrate stability zone. The driver for this transport is the pressure sink induced by a reduction in occupied pore volume that accompanies the formation of hydrate from gas and water. Pore-scale imbibition models and bed-scale multiphase flow models indicate that the rate-limiting step in converting gas to hydrate is the supply of water to the hydrate stability zone. Moreover, the water supply rate is controlled by capillarity-driven flux for conditions typical of the Alaska North Slope. A meter-scale laboratory experiment confirms that significant volumes of fluid phases move into the hydrate stability zone and that capillarity is essential for the water flux. The model shows that without capillarity-driven flux, large saturations of hydrate cannot form. The observations of thick zones of large saturation at Mallik and Mt Elbert thus suggest that the primary control on these systems is the rate of transport of gaseous and aqueous phases, driven by the pressure sink at the base of the gas hydrate stability zone. A key finding of our project is the elucidation of ?capillary fracturing? as a dominant gas transport mechanism in low-permeability media. We initially investigate this phenomenon by means of grain-scale simulations in which we extended a discrete element mechanics code (PFC, by Itasca) to incorporate the dynamics of first singlephase and then multiphase flow. A reductionist model on a square lattice allows us to determine some of the fundamental dependencies of the mode of gas invasion (capillary fingering, viscous fingering, and fracturing) on the parameters of the system. We then show that the morphology of the gas-invaded region exerts a fundamental control on the fabric of methane hydrate formation, and on the overpressures caused by methane hydrate dissociation. We demonstrate the existence of the different invasion regimes by means of controlled laboratory experiments in a radial cell. We collapse the behavior in the form of a phase dia

  2. Mechanisms Leading to Co-Existence of Gas Hydrate in Ocean Sediments [Part 1 of 2

    SciTech Connect (OSTI)

    Bryant, Steven; Juanes, Ruben

    2011-12-31

    In this project we have sought to explain the co-existence of gas and hydrate phases in sediments within the gas hydrate stability zone. We have focused on the gas/brine interface at the scale of individual grains in the sediment. The capillary forces associated with a gas/brine interface play a dominant role in many processes that occur in the pores of sediments and sedimentary rocks. The mechanical forces associated with the same interface can lead to fracture initiation and propagation in hydrate-bearing sediments. Thus the unifying theme of the research reported here is that pore scale phenomena are key to understanding large scale phenomena in hydrate-bearing sediments whenever a free gas phase is present. Our analysis of pore-scale phenomena in this project has delineated three regimes that govern processes in which the gas phase pressure is increasing: fracturing, capillary fingering and viscous fingering. These regimes are characterized by different morphology of the region invaded by the gas. On the other hand when the gas phase pressure is decreasing, the corresponding regimes are capillary fingering and compaction. In this project, we studied all these regimes except compaction. Many processes of interest in hydrate-bearing sediments can be better understood when placed in the context of the appropriate regime. For example, hydrate formation in sub-permafrost sediments falls in the capillary fingering regime, whereas gas invasion into ocean sediments is likely to fall into the fracturing regime. Our research provides insight into the mechanisms by which gas reservoirs are converted to hydrate as the base of the gas hydrate stability zone descends through the reservoir. If the reservoir was no longer being charged, then variation in grain size distribution within the reservoir explain hydrate saturation profiles such as that at Mt. Elbert, where sand-rich intervals containing little hydrate are interspersed between intervals containing large hydrate saturations. Large volumes (of order one pore volume) of gaseous and aqueous phases must be transported into the gas hydrate stability zone. The driver for this transport is the pressure sink induced by a reduction in occupied pore volume that accompanies the formation of hydrate from gas and water. Pore-scale imbibition models and bed-scale multiphase flow models indicate that the rate-limiting step in converting gas to hydrate is the supply of water to the hydrate stability zone. Moreover, the water supply rate is controlled by capillarity-driven flux for conditions typical of the Alaska North Slope. A meter-scale laboratory experiment confirms that significant volumes of fluid phases move into the hydrate stability zone and that capillarity is essential for the water flux. The model shows that without capillarity-driven flux, large saturations of hydrate cannot form. The observations of thick zones of large saturation at Mallik and Mt Elbert thus suggest that the primary control on these systems is the rate of transport of gaseous and aqueous phases, driven by the pressure sink at the base of the gas hydrate stability zone. A key finding of our project is the elucidation of ?capillary fracturing? as a dominant gas transport mechanism in low-permeability media. We initially investigate this phenomenon by means of grain-scale simulations in which we extended a discrete element mechanics code (PFC, by Itasca) to incorporate the dynamics of first single-phase and then multiphase flow. A reductionist model on a square lattice allows us to determine some of the fundamental dependencies of the mode of gas invasion (capillary fingering, viscous fingering, and fracturing) on the parameters of the system. We then show that the morphology of the gas-invaded region exerts a fundamental control on the fabric of methane hydrate formation, and on the overpressures caused by methane hydrate dissociation. We demonstrate the existence of the different invasion regimes by means of controlled laboratory experiments in a radial cell. We collapse the behavior in the form of a phase di

  3. Geological evolution and analysis of confirmed or suspected gas hydrate localities: Volume 9, Formation and stability of gas hydrates of the Middle America Trench

    SciTech Connect (OSTI)

    Finley, P.; Krason, J.

    1986-12-01

    This report presents a geological description of the Pacific margin of Mexico and Central America, including regional and local structural settings, geomorphology, geological history, stratigraphy, and physical properties. It provides the necessary regional and geological background for more in-depth research of the area. Detailed discussion of bottom simulating acoustic reflectors, sediment acoustic properties, and distribution of hydrates within the sediments are also included in this report. The formation and stabilization of gas hydrates in sediments are considered in terms of phase relations, nucleation, and crystallization constraints, gas solubility, pore fluid chemistry, inorganic diagenesis, and sediment organic content. Together with a depositional analysis of the area, this report is a better understanding of the thermal evolution of the locality. It should lead to an assessment of the potential for both biogenic and thermogenic hydrocarbon generation. 150 refs., 84 figs., 17 tabs.

  4. Modeling of Oceanic Gas Hydrate Instability and Methane Release in Response to Climate Change

    SciTech Connect (OSTI)

    Reagan, Matthew; Reagan, Matthew T.; Moridis, George J.

    2008-04-15

    Paleooceanographic evidence has been used to postulate that methane from oceanic hydrates may have had a significant role in regulating global climate, implicating global oceanic deposits of methane gas hydrate as the main culprit in instances of rapid climate change that have occurred in the past. However, the behavior of contemporary oceanic methane hydrate deposits subjected to rapid temperature changes, like those predicted under future climate change scenarios, is poorly understood. To determine the fate of the carbon stored in these hydrates, we performed simulations of oceanic gas hydrate accumulations subjected to temperature changes at the seafloor and assessed the potential for methane release into the ocean. Our modeling analysis considered the properties of benthic sediments, the saturation and distribution of the hydrates, the ocean depth, the initial seafloor temperature, and for the first time, estimated the effect of benthic biogeochemical activity. The results show that shallow deposits--such as those found in arctic regions or in the Gulf of Mexico--can undergo rapid dissociation and produce significant methane fluxes of 2 to 13 mol/yr/m{sup 2} over a period of decades, and release up to 1,100 mol of methane per m{sup 2} of seafloor in a century. These fluxes may exceed the ability of the seafloor environment (via anaerobic oxidation of methane) to consume the released methane or sequester the carbon. These results will provide a source term to regional or global climate models in order to assess the coupling of gas hydrate deposits to changes in the global climate.

  5. Seismic technology will be of key importance for evaluat-ing gas-hydrate resources, particularly across the Gulf of

    E-Print Network [OSTI]

    Texas at Austin, University of

    Seismic technology will be of key importance for evaluat- ing gas-hydrate resources, particularly across the Gulf of Mexico (GoM) where many seismic surveys have been acquired and will continue to be acquired. To apply seismic technology to gas-hydrate studies in the gulf in an optimal manner

  6. Ground movements associated with gas hydrate production. Progress report, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    An obvious consequence of hydrate dissociation is the compression of reservoir matrix causing displacements in the surrounding area. The reservoir compression is a time-dependent process which depends on the production rate. The ground movements cause additional stresses in the overburden which may result in rock mass fracture and failure. Rock failure may cause rubble formation or bulking in the fracture zone. This in turn can cause an increase in permeability for gas flow which may offset the reduction in permeability caused by closure of existing fractures during reservoir compression. The mechanics of ground movements during hydrate production can be more closely simulated by considering similarities with ground movements associated with subsidence in permafrost regions. The purpose of this research work is to investigate the potential strata movements associated with hydrate production by considering similarities with ground movements in permafrost regions. The work primarily involves numerical modeling of subsidence caused by hydrate dissociation. The investigation is based on the theories of continuum mechanics, thermomechanical behavior of frozen geo-materials, principles of rock mechanics and geomechanics. It is expected that some phases of the investigation will involve the use of finite element method, which is a powerful computer-based method which has been widely used in many areas of science and engineering. Parametric studies will be performed to predict expected strata movements and surface subsidence for different reservoir conditions and properties of geological materials. The results from this investigation will be useful in predicting the magnitude of the subsidence problem associated with gas hydrate production. The analogy of subsidence in permafrost regions may provide lower bounds for subsidence expected in hydrate reservoirs. Furthermore, it is anticipated that the results will provide insight into planning of hydrate recovery operations.

  7. Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

    E-Print Network [OSTI]

    2010-01-01

    and stable isotope compositions of natural gas hydrates: acarbon isotopic composition of methane from natural gases of

  8. New Natural Gas Storage and Transportation Capabilities Utilizing Rapid Methane Hydrate Formation Techniques

    SciTech Connect (OSTI)

    Brown, T.D.; Taylor, C.E.; Bernardo, M.

    2010-01-01

    Natural gas (methane as the major component) is a vital fossil fuel for the United States and around the world. One of the problems with some of this natural gas is that it is in remote areas where there is little or no local use for the gas. Nearly 50 percent worldwide natural gas reserves of ~6,254.4 trillion ft3 (tcf) is considered as stranded gas, with 36 percent or ~86 tcf of the U.S natural gas reserves totaling ~239 tcf, as stranded gas [1] [2]. The worldwide total does not include the new estimates by U.S. Geological Survey of 1,669 tcf of natural gas north of the Arctic Circle, [3] and the U.S. ~200,000 tcf of natural gas or methane hydrates, most of which are stranded gas reserves. Domestically and globally there is a need for newer and more economic storage, transportation and processing capabilities to deliver the natural gas to markets. In order to bring this resource to market, one of several expensive methods must be used: 1. Construction and operation of a natural gas pipeline 2. Construction of a storage and compression facility to compress the natural gas (CNG) at 3,000 to 3,600 psi, increasing its energy density to a point where it is more economical to ship, or 3. Construction of a cryogenic liquefaction facility to produce LNG, (requiring cryogenic temperatures at <-161 °C) and construction of a cryogenic receiving port. Each of these options for the transport requires large capital investment along with elaborate safety systems. The Department of Energy's Office of Research and Development Laboratories at the National Energy Technology Laboratory (NETL) is investigating new and novel approaches for rapid and continuous formation and production of synthetic NGHs. These synthetic hydrates can store up to 164 times their volume in gas while being maintained at 1 atmosphere and between -10 to -20°C for several weeks. Owing to these properties, new process for the economic storage and transportation of these synthetic hydrates could be envisioned for stranded gas reserves. The recent experiments and their results from the testing within NETL's 15-Liter Hydrate Cell Facility exhibit promising results. Introduction of water at the desired temperature and pressure through an NETL designed nozzle into a temperature controlled methane environment within the 15-Liter Hydrate Cell allowed for instantaneous formation of methane hydrates. The instantaneous and continuous hydrate formation process was repeated over several days while varying the flow rate of water, its' temperature, and the overall temperature of the methane environment. These results clearly indicated that hydrates formed immediately after the methane and water left the nozzle at temperatures above the freezing point of water throughout the range of operating conditions. [1] Oil and Gas Journal Vol. 160.48, Dec 22, 2008. [2] http://www.eia.doe.gov/oiaf/servicerpt/natgas/chapter3.html and http://www.eia.doe.gov/oiaf/servicerpt/natgas/pdf/tbl7.pdf [3] U.S. Geological Survey, “Circum-Arctic Resource Appraisal: Estimates of Undiscovered Oil and Gas North of the Arctic Circle,” May 2008.

  9. CO{sub 2} HYDRATE PROCESS FOR GAS SEPARATION

    SciTech Connect (OSTI)

    G. Deppe; R. Currier; D. Spencer

    2004-01-01

    Modifications were implemented to the hydrogen flow test rig per safety review comments, and the apparatus was tested for leaks. Tests were then done using Helium/CO{sub 2} mixtures to re-verify performance prior to hydrogen testing. It was discovered that hydrate formation was more difficult to initiate, and new initiation methods were developed to improve the tests. Delivery of ETM hardware continued and buildup of the ETM system continued, the ETM is now mechanically complete. The STU (pilot plant) site selection process was resumed because Tennessee Eastman declined to participate in the program. Two potential sites were visited: The Global Energy/Conoco-Phillips Wabash River Plant, and the Tampa Electric Polk Power Plant.

  10. ORIGINAL RESEARCH PAPER Geothermal modeling of the gas hydrate stability zone

    E-Print Network [OSTI]

    / Published online: 12 June 2010 Ó Springer Science+Business Media B.V. 2010 Abstract A wide-spread bottom-hydrates are ice-like solids belonging to the class of clathrate compounds in which gas molecules (mainly methaneL 4B2, Canada e-mail: mriedel@nrcan.gc.ca A. V. Sathe Oil and Natural Gas Corporation Ltd., KDM Inst

  11. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluationof Technology and Potential

    SciTech Connect (OSTI)

    Reagan, Matthew; Moridis, George J.; Collett, Timothy; Boswell, Ray; Kurihara, M.; Reagan, Matthew T.; Koh, Carolyn; Sloan, E. Dendy

    2008-02-12

    Gas hydrates are a vast energy resource with global distribution in the permafrost and in the oceans. Even if conservative estimates are considered and only a small fraction is recoverable, the sheer size of the resource is so large that it demands evaluation as a potential energy source. In this review paper, we discuss the distribution of natural gas hydrate accumulations, the status of the primary international R&D programs, and the remaining science and technological challenges facing commercialization of production. After a brief examination of gas hydrate accumulations that are well characterized and appear to be models for future development and gas production, we analyze the role of numerical simulation in the assessment of the hydrate production potential, identify the data needs for reliable predictions, evaluate the status of knowledge with regard to these needs, discuss knowledge gaps and their impact, and reach the conclusion that the numerical simulation capabilities are quite advanced and that the related gaps are either not significant or are being addressed. We review the current body of literature relevant to potential productivity from different types of gas hydrate deposits, and determine that there are consistent indications of a large production potential at high rates over long periods from a wide variety of hydrate deposits. Finally, we identify (a) features, conditions, geology and techniques that are desirable in potential production targets, (b) methods to maximize production, and (c) some of the conditions and characteristics that render certain gas hydrate deposits undesirable for production.

  12. Insights into the structure of mixed CO2/CH4 in gas hydrates

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Chakoumakos, Bryan C; Keffer, David J.; Huq, Ashfia; Phelps, Tommy Joe

    2015-01-01

    The exchange of CO2 for CH4 in natural gas hydrates is an attractive approach to methane for energy production while simultaneously sequestering CO2. In addition to the energy and environmental implications, the solid solution of clathrate hydrate (CH4)1-x(CO2)x 5.75H2O provides a model system to study how the distinct bonding and shapes of CH4 and CO2 influence the structure and properties of the compound. High-resolution neutron diffraction was used to examine mixed CO2/CH4 gas hydrates. CO2-rich hydrates had smaller lattice parameters, which were attributed to the higher affinity of the CO2 molecule interacting with H2O molecules that form the surrounding cages, and resulted in a reduction in the unit cell volume. Experimental nuclear scattering densities illustrate how the cage occupants and energy landscape change with composition. These results provide important insights on the impact and mechanisms for exchanging CH4 and CO2.

  13. Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration and Production Activities

    SciTech Connect (OSTI)

    Bent, Jimmy

    2014-05-31

    In 2000 Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deep water portion of the Gulf of Mexico (GOM). Chevron is an active explorer and operator in the Gulf of Mexico and is aware that natural gas hydrates need to be understood to operate safely in deep water. In August 2000 Chevron worked closely with the National Energy Technology Laboratory (NETL) of the United States Department of Energy (DOE) and held a workshop in Houston, Texas to define issues concerning the characterization of natural gas hydrate deposits. Specifically, the workshop was meant to clearly show where research, the development of new technologies, and new information sources would be of benefit to the DOE and to the oil and gas industry in defining issues and solving gas hydrate problems in deep water.

  14. Temporal changes in gas hydrate mound topography and ecology: deep-sea time-lapse camera observations 

    E-Print Network [OSTI]

    Vardaro, Michael Fredric

    2004-09-30

    A deep-sea time-lapse camera and several temperature probes were deployed on the Gulf of Mexico continental shelf at a biological community associated with a gas hydrate outcropping to study topographic and hydrologic changes over time...

  15. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    occurrence while drilling a well (Takahashi et al, 2001;logging while drilling (16 wells), wireline logging (2that has led the drilling of 36 wells in gas hydrate-bearing

  16. DOE THREE-DIMENSIONAL STRUCTURE AND PHYSICAL PROPERTIES OF A METHANE HYDRATE DEPOSIT AND GAS RESERVOIR, BLAKE RIDGE

    SciTech Connect (OSTI)

    W. Steven Holbrook

    2004-11-11

    This report contains a summary of work conducted and results produced under the auspices of award DE-FC26-00NT40921, ''DOE Three-Dimensional Structure and Physical Properties of a Methane Hydrate Deposit and Gas Reservoir, Blake Ridge.'' This award supported acquisition, processing, and interpretation of two- and three-dimensional seismic reflection data over a large methane hydrate reservoir on the Blake Ridge, offshore South Carolina. The work supported by this project has led to important new conclusions regarding (1) the use of seismic reflection data to directly detect methane hydrate, (2) the migration and possible escape of free gas through the hydrate stability zone, and (3) the mechanical controls on the maximum thickness of the free gas zone and gas escape.

  17. Status of DOE Research Efforts in Gas Hydrates | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    confirmed the ability to safely conduct scientific data acquisition within an operating oil field with minimal impact to operations, and increased the confidence in the broader...

  18. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    Project: Overview of Leg II LWD results. Paper OTC-20560,the GOM Hydrate JIP Leg II LWD Drilling, Proceedings, 6 thIndustry Project Leg II: LWD logging program design, data

  19. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    P.D. , Messoyakh Gas Field - Russia: West Siberian Basin,Russia – The Messoyakha Field. The Messoyakha Field, a gas

  20. Contribution of oceanic gas hydrate dissociation to the formation of Arctic Ocean methane plumes

    E-Print Network [OSTI]

    Reagan, M.

    2012-01-01

    Potential distribution of methane hydrate in the world'sisotopic evidence for methane hydrate instability duringHendy, L.L. , and R.J. Behl, Methane hydrates in quaternary

  1. Methane Recovery from Hydrate-bearing Sediments

    SciTech Connect (OSTI)

    J. Carlos Santamarina; Costas Tsouris

    2011-04-30

    Gas hydrates are crystalline compounds made of gas and water molecules. Methane hydrates are found in marine sediments and permafrost regions; extensive amounts of methane are trapped in the form of hydrates. Methane hydrate can be an energy resource, contribute to global warming, or cause seafloor instability. This study placed emphasis on gas recovery from hydrate bearing sediments and related phenomena. The unique behavior of hydrate-bearing sediments required the development of special research tools, including new numerical algorithms (tube- and pore-network models) and experimental devices (high pressure chambers and micromodels). Therefore, the research methodology combined experimental studies, particle-scale numerical simulations, and macro-scale analyses of coupled processes. Research conducted as part of this project started with hydrate formation in sediment pores and extended to production methods and emergent phenomena. In particular, the scope of the work addressed: (1) hydrate formation and growth in pores, the assessment of formation rate, tensile/adhesive strength and their impact on sediment-scale properties, including volume change during hydrate formation and dissociation; (2) the effect of physical properties such as gas solubility, salinity, pore size, and mixed gas conditions on hydrate formation and dissociation, and it implications such as oscillatory transient hydrate formation, dissolution within the hydrate stability field, initial hydrate lens formation, and phase boundary changes in real field situations; (3) fluid conductivity in relation to pore size distribution and spatial correlation and the emergence of phenomena such as flow focusing; (4) mixed fluid flow, with special emphasis on differences between invading gas and nucleating gas, implications on relative gas conductivity for reservoir simulations, and gas recovery efficiency; (5) identification of advantages and limitations in different gas production strategies with emphasis; (6) detailed study of CH4-CO2 exchange as a unique alternative to recover CH4 gas while sequestering CO2; (7) the relevance of fines in otherwise clean sand sediments on gas recovery and related phenomena such as fines migration and clogging, vuggy structure formation, and gas-driven fracture formation during gas production by depressurization.

  2. Comparison of kinetic and equilibrium reaction models in simulating gas hydrate behavior in porous media

    E-Print Network [OSTI]

    Kowalsky, Michael B.; Moridis, George J.

    2006-01-01

    hydrocarbons residing in hydrate deposits is estimated to substantially exceed all known conventional

  3. Geomechanical response of permafrost-associated hydrate deposits to depressurization-induced gas production

    E-Print Network [OSTI]

    Rutqvist, J.

    2009-01-01

    hydrocarbons) trapped in hydrates is enormous, and easily exceeds the equivalent of all the known conventional

  4. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    time frame. The unconventional oil and gas hydrocarbonsare currently no unconventional developments, oil or gas, in

  5. Hydrate-phobic surfaces

    E-Print Network [OSTI]

    Smith, Jonathan David, S.M. Massachusetts Institute of Technology

    2011-01-01

    Clathrate hydrate formation and subsequent plugging of deep-sea oil and gas pipelines represent a significant bottleneck for ultra deep-sea production. Current methods for hydrate mitigation focus on injecting thermodynamic ...

  6. Benchmarking the performance of density functional theory and point charge force fields in their description of sI methane hydrate against diffusion Monte Carlo

    SciTech Connect (OSTI)

    Cox, Stephen J.; Michaelides, Angelos; Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ ; Towler, Michael D.; Theory of Condensed Matter Group, Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE ; Alfč, Dario; Department of Earth Sciences, University College London Gower Street, London WC1E 6BT

    2014-05-07

    High quality reference data from diffusion Monte Carlo calculations are presented for bulk sI methane hydrate, a complex crystal exhibiting both hydrogen-bond and dispersion dominated interactions. The performance of some commonly used exchange-correlation functionals and all-atom point charge force fields is evaluated. Our results show that none of the exchange-correlation functionals tested are sufficient to describe both the energetics and the structure of methane hydrate accurately, while the point charge force fields perform badly in their description of the cohesive energy but fair well for the dissociation energetics. By comparing to ice I{sub h}, we show that a good prediction of the volume and cohesive energies for the hydrate relies primarily on an accurate description of the hydrogen bonded water framework, but that to correctly predict stability of the hydrate with respect to dissociation to ice I{sub h} and methane gas, accuracy in the water-methane interaction is also required. Our results highlight the difficulty that density functional theory faces in describing both the hydrogen bonded water framework and the dispersion bound methane.

  7. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    Annual Conference on Unconventional Gas, Calgary, Alberta,most conventional and unconventional gas wells due a numbermarket prices. Unconventional gas projects can generally

  8. RESULTS FROM THE (1) DATA COLLECTION WORKSHOP, (2) MODELING WORKSHOP AND (3) DRILLING AND CORING METHODS WORKSHOP AS PART OF THE JOINT INDUSTRY PARTICIPATION (JIP) PROJECT TO CHARACTERIZE NATURAL GAS HYDRATES IN THE DEEPWATER GULF OF MEXICO

    SciTech Connect (OSTI)

    Stephen A. Holditch; Emrys Jones

    2002-09-01

    In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deepwater Gulf of Mexico. These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. As part of the project, three workshops were held. The first was a data collection workshop, held in Houston during March 14-15, 2002. The purpose of this workshop was to find out what data exist on gas hydrates and to begin making that data available to the JIP. The second and third workshop, on Geoscience and Reservoir Modeling, and Drilling and Coring Methods, respectively, were held simultaneously in Houston during May 9-10, 2002. The Modeling Workshop was conducted to find out what data the various engineers, scientists and geoscientists want the JIP to collect in both the field and the laboratory. The Drilling and Coring workshop was to begin making plans on how we can collect the data required by the project's principal investigators.

  9. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Thomas E. Williams; Keith Millheim; Bill Liddell

    2005-03-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Oil-field engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in Arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrates agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is a cost-shared partnership between Maurer Technology, Anadarko Petroleum, Noble Corporation, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to help identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. As part of the project work scope, team members drilled and cored the HOT ICE No. 1 on Anadarko leases beginning in January 2003 and completed in March 2004. Due to scheduling constraints imposed by the Arctic drilling season, operations at the site were suspended between April 21, 2003 and January 30, 2004. An on-site core analysis laboratory was designed, constructed and used for determining physical characteristics of frozen core immediately after it was retrieved from the well. The well was drilled from a new and innovative Anadarko Arctic Platform that has a greatly reduced footprint and environmental impact. Final efforts of the project were to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists for future hydrate operations. Unfortunately, no gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in the project reports.

  10. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    of United States oil and gas resources on CD-ROM: U.S.of United States Oil and Gas Resources conducted by the U.S.assess conventional oil and gas resources. In order to use

  11. Evaluation of a deposit in the vicinity of the PBU L-106 Site, North Slope, Alaska, for a potential long-term test of gas production from hydrates

    SciTech Connect (OSTI)

    Moridis, G.J.; Reagan, M.T.; Boyle, K.L.; Zhang, K.

    2010-05-01

    As part of the effort to investigate the technical feasibility of gas production from hydrate deposits, a long-term field test (lasting 18-24 months) is under consideration in a project led by the U.S. Department of Energy. We evaluate a candidate deposit involving the C-Unit in the vicinity of the PBU-L106 site in North Slope, Alaska. This deposit is stratigraphically bounded by impermeable shale top and bottom boundaries (Class 3), and is characterized by high intrinsic permeabilities, high porosity, high hydrate saturation, and a hydrostatic pressure distribution. The C-unit deposit is composed of two hydrate-bearing strata separated by a 30-ft-thick shale interlayer, and its temperatrure across its boundaries ranges between 5 and 6.5 C. We investigate by means of numerical simulation involving very fine grids the production potential of these two deposits using both vertical and horizontal wells. We also explore the sensitivity of production to key parameters such as the hydrate saturation, the formation permeability, and the permeability of the bounding shale layers. Finally, we compare the production performance of the C-Unit at the PBU-L106 site to that of the D-Unit accumulation at the Mount Elbert site, a thinner, single-layer Class 3 deposit on the North Slope of Alaska that is shallower, less-pressurized and colder (2.3-2.6 C). The results indicate that production from horizontal wells may be orders of magnitude larger than that from vertical ones. Additionally, production increases with the formation permeability, and with a decreasing permeability of the boundaries. The effect of the hydrate saturation on production is complex and depends on the time frame of production. Because of higher production, the PBU-L106 deposit appears to have an advantage as a candidate for the long-term test.

  12. U N C L A S S I F I E D Gas Hydrate Experimental Capabilities at the Los Alamos

    E-Print Network [OSTI]

    Downs, Robert T.

    U N C L A S S I F I E D Gas Hydrate Experimental Capabilities at the Los Alamos Neutron Scattering, and Robert T. Downs2 1LANSCE-LC, Los Alamos National Laboratory, 2Dept of Geosciences, University of Arizona of Energy's Office of Basic Energy Sciences. Los Alamos National Laboratory is operated by the University

  13. Gas Hydrate Equilibrium Measurements for Multi-Component Gas Mixtures and Effect of Ionic Liquid Inhibitors 

    E-Print Network [OSTI]

    Othman, Enas Azhar

    2014-04-07

    -component gas mixtures whose compositions are typical of Qatari natural gases with initiatives aimed at helping producers minimize costs, optimize operations, and prevent interruption of gas flow in offshore drilling and production. In addition, it presents...

  14. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    National assessment of United States oil and gas resourcesNational Assessment of United States Oil and Gas Resourcesassessment methodologies that have been developed to assess conventional oil and

  15. Geomechanical Performance of Hydrate-Bearing Sediment in Offshore Environments

    SciTech Connect (OSTI)

    Stephen Holditch; Tad Patzek; Jonny Rutqvist; George Moridis; Richard Plumb

    2008-03-31

    The objective of this multi-year, multi-institutional research project was to develop the knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate-bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus was on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. We have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. We also investigated the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. The objective of the UC Berkeley work was to develop a grain-scale model of hydrate-bearing sediments. Hydrate dissociation alters the strength of HBS. In particular, transformation of hydrate clusters into gas and liquid water weakens the skeleton and, simultaneously, reduces the effective stress by increasing the pore pressure. The large-scale objective of the study is evaluation of geomechanical stability of offshore oil and gas production infrastructure. At Lawrence Berkeley National Laboratory (LBNL), we have developed the numerical model TOUGH + Hydrate + FLAC3D to evaluate how the formation and disassociation of hydrates in seafloor sediments affects seafloor stability. Several technical papers were published using results from this model. LBNL also developed laboratory equipment and methods to produce realistic laboratory samples of sediments containing gas hydrates so that mechanical properties could be measured in the laboratory. These properties are required to run TOUGH + Hydrate + FLAC3D to evaluate seafloor stability issues. At Texas A&M University we performed a detailed literature review to determine what gas hydrate formation properties had been measured and reported in the literature. We then used TOUGH + Hydrate to simulate the observed gas production and reservoir pressure field data at Messoyakha. We simulated various scenarios that help to explain the field behavior. We have evaluated the effect of reservoir parameters on gas recovery from hydrates. Our work should be beneficial to others who are investigating how to produce gas from a hydrate capped gas reservoir. The results also can be used to better evaluate the process of producing gas from offshore hydrates. The Schlumberger PETREL model is used in industry to the description of geologic horizons and the special distribution of properties. An interface between FLAC3D and Petrel was built by Schlumberger to allow for efficient data entry into TOUGH + Hydrate + FLAC3D.

  16. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    life of the field when the subsea tree, blow out preventer,for both fields assumed a subsea development in 5000 ft of

  17. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    gas releases during drilling, and well integrity issuesNext, drilling of exploration wells and conducting wellal. , 2006a), as well as the 1998 and 2005 drilling programs

  18. Ground movements associated with gas hydrate production. Progress report, October 1--December 31, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks; mechanics of subsidence in permafrost regions, modeling of subsidence, and parametric studies.

  19. Electrical Resistivity Investigation of Gas Hydrate Distribution in Mississippi Canyon Block 118, Gulf of Mexico

    SciTech Connect (OSTI)

    Dunbar, John

    2012-12-31

    Electrical methods offer a geophysical approach for determining the sub-bottom distribution of hydrate in deep marine environments. Methane hydrate is essentially non-conductive. Hence, sediments containing hydrate are more resistive than sediments without hydrates. To date, the controlled source electromagnetic (CSEM) method has been used in marine hydrates studies. This project evaluated an alternative electrical method, direct current resistivity (DCR), for detecting marine hydrates. DCR involves the injection of direct current between two source electrodes and the simultaneous measurement of the electric potential (voltage) between multiple receiver electrodes. The DCR method provides subsurface information comparable to that produced by the CSEM method, but with less sophisticated instrumentation. Because the receivers are simple electrodes, large numbers can be deployed to achieve higher spatial resolution. In this project a prototype seafloor DCR system was developed and used to conduct a reconnaissance survey at a site of known hydrate occurrence in Mississippi Canyon Block 118. The resulting images of sub-bottom resistivities indicate that high-concentration hydrates at the site occur only in the upper 50 m, where deep-seated faults intersect the seafloor. Overall, there was evidence for much less hydrate at the site than previously thought based on available seismic and CSEM data alone.

  20. Microsoft Word - NETL-TRS-6-2015 Detection of Hydrates on Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hydrate nucleation elsewhere in the system. By accurately controlling the pressure, temperature, and aqueous-phase hydrocarbon concentration, the thermodynamic state of the...

  1. Salt Tectonics and Its Effect on Sediment Structure and Gas Hydrate Occurrence in the Northwestern Gulf of Mexico from 2-D Multichannel Seismic Data 

    E-Print Network [OSTI]

    Lewis, Dan'L 1986-

    2012-10-04

    This study was undertaken to investigate mobile salt and its effect on fault structures and gas hydrate occurrence in the northwestern Gulf of Mexico. Industry 2-D multichannel seismic data were used to investigate the effects of the salt within...

  2. Petrographic, Mineralogic, and Geochemical Studies of Hydrocarbon-derived Authigenic Carbonate Rock from Gas Venting, Seepage, Free Gas, and Gas Hydrate Sites in the Gulf of Mexico and offshore India 

    E-Print Network [OSTI]

    Jung, Woodong

    2012-02-14

    . ACR collected from the seafloor in the Gulf of Mexico (GOM) and ACR recovered from drilled cores in the Krishna-Godawari (KG) basin offshore India were used. All study sites are associated with hydrocarbon gas venting, seepage, free gas, or gas hydrate...

  3. Gas Hydrate: A Realistic Future Source of Gas Supply? | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping intoandMinimal Cost2-95)LETTEREnergy

  4. Ground movements associated with gas hydrate production. Progress report, July 1--September 30, 1992

    SciTech Connect (OSTI)

    Siriwardane, H.J.

    1992-12-31

    The grantee will evaluate the influence of hydrate production on ground subsidence near the wellbore and the surface. The objective of this research will be achieved by using computer simulations of what is expected in a hydrate reservoir during the production stage as reported by hydrate production models and available data. The model will be based on theories of continuum mechanics, thermomechanics of hydrate production, principles of rock mechanics and geomechanics, and special features of geomaterials under cold temperatures such as those found in permafrost regions. The research work involved in the proposed investigation will be divided into three major tasks: (1) Mechanics of subsidence in permafrost regions; (2) modeling of subsidence; and (3) parametric studies. Progress reports are presented for tasks 1 and 2.

  5. International Conference on Gas Hydrates May 19-23, 2002, Yokohama

    E-Print Network [OSTI]

    Gudmundsson, Jon Steinar

    % of the natural gas fields yet to be developed in the world are medium-to-small-scale and about one, but the resources are too small to justify large investments for a pipeline or a large enough LNG (liquefied natural to markets. The feasibility of LNG technology is highly dependent on scale, making development less than 4

  6. Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling

    SciTech Connect (OSTI)

    Kneafsey, Timothy J.; Lu, Hailong; Winters, William; Boswell, Ray; Hunter, Robert; Collett, Timothy S.

    2009-09-01

    Collecting and preserving undamaged core samples containing gas hydrates from depth is difficult because of the pressure and temperature changes encountered upon retrieval. Hydrate-bearing core samples were collected at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well in February 2007. Coring was performed while using a custom oil-based drilling mud, and the cores were retrieved by a wireline. The samples were characterized and subsampled at the surface under ambient winter arctic conditions. Samples thought to be hydrate bearing were preserved either by immersion in liquid nitrogen (LN), or by storage under methane pressure at ambient arctic conditions, and later depressurized and immersed in LN. Eleven core samples from hydrate-bearing zones were scanned using x-ray computed tomography to examine core structure and homogeneity. Features observed include radial fractures, spalling-type fractures, and reduced density near the periphery. These features were induced during sample collection, handling, and preservation. Isotopic analysis of the methane from hydrate in an initially LN-preserved core and a pressure-preserved core indicate that secondary hydrate formation occurred throughout the pressurized core, whereas none occurred in the LN-preserved core, however no hydrate was found near the periphery of the LN-preserved core. To replicate some aspects of the preservation methods, natural and laboratory-made saturated porous media samples were frozen in a variety of ways, with radial fractures observed in some LN-frozen sands, and needle-like ice crystals forming in slowly frozen clay-rich sediments. Suggestions for hydrate-bearing core preservation are presented.

  7. Examination of core samples from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Effects of retrieval and preservation

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Liu, T.J. H.; Winters, W.; Boswell, R.; Hunter, R.; Collett, T.S.

    2011-06-01

    Collecting and preserving undamaged core samples containing gas hydrates from depth is difficult because of the pressure and temperature changes encountered upon retrieval. Hydrate-bearing core samples were collected at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well in February 2007. Coring was performed while using a custom oil-based drilling mud, and the cores were retrieved by a wireline. The samples were characterized and subsampled at the surface under ambient winter arctic conditions. Samples thought to be hydrate bearing were preserved either by immersion in liquid nitrogen (LN), or by storage under methane pressure at ambient arctic conditions, and later depressurized and immersed in LN. Eleven core samples from hydrate-bearing zones were scanned using x-ray computed tomography to examine core structure and homogeneity. Features observed include radial fractures, spalling-type fractures, and reduced density near the periphery. These features were induced during sample collection, handling, and preservation. Isotopic analysis of the methane from hydrate in an initially LN-preserved core and a pressure-preserved core indicate that secondary hydrate formation occurred throughout the pressurized core, whereas none occurred in the LN-preserved core, however no hydrate was found near the periphery of the LN-preserved core. To replicate some aspects of the preservation methods, natural and laboratory-made saturated porous media samples were frozen in a variety of ways, with radial fractures observed in some LN-frozen sands, and needle-like ice crystals forming in slowly frozen clay-rich sediments. Suggestions for hydrate-bearing core preservation are presented.

  8. Characterization of Field-Aged Exhaust Gas Recirculation Cooler...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Field-Aged Exhaust Gas Recirculation Cooler Deposits Characterization of Field-Aged Exhaust Gas Recirculation Cooler Deposits Characterized field-aged exhaust gas recirculation...

  9. Presentations from the March 27th - 28th Methane Hydrates Advisory...

    Office of Environmental Management (EM)

    the March 27th - 28th Methane Hydrates Advisory Committee Meeting Presentations from the March 27th - 28th Methane Hydrates Advisory Committee Meeting International Gas Hydrate...

  10. ,"Natural Gas Plant Field Production: Natural Gas Liquids "

    U.S. Energy Information Administration (EIA) Indexed Site

    Field Production: Natural Gas Liquids " ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data...

  11. Comparison of Kinetic and Equilibrium Reaction Models in Simulating the Behavior of Gas Hydrates in Porous Media

    E-Print Network [OSTI]

    Kowalsky, Michael B.; Moridis, George J.

    2006-01-01

    hydrocarbons residing in hydrate deposits is estimated to substantially exceed all known conventional

  12. Sulfur geochemistry of thermogenic gas hydrate and associated sediment from the Texas-Louisiana continental slope 

    E-Print Network [OSTI]

    Gledhill, Dwight Kuehl

    2001-01-01

    content were measured using a new wet chemical technique. The []ł?S relative to Vienna Canyon Diablo troilite was determined for TRS and hydrate H?S. Extensive (>95%) reduction of pore-fluid sulfate occurred, resulting in exceptionally high []H?S...

  13. Application of Crunch-Flow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites

    SciTech Connect (OSTI)

    Torres, Marta

    2014-01-31

    In November 2012, Oregon State University initiated the project entitled: Application of Crunch-Flow routines to constrain present and past carbon fluxes at gas-hydrate bearing sites. Within this project we developed Crunch-Flow based modeling modules that include important biogeochemical processes that need to be considered in gas hydrate environments. Our modules were applied to quantify carbon cycling in present and past systems, using data collected during several DOE-supported drilling expeditions, which include the Cascadia margin in US, Ulleung Basin in South Korea, and several sites drilled offshore India on the Bay of Bengal and Andaman Sea. Specifically, we completed modeling efforts that: 1) Reproduce the compositional and isotopic profiles observed at the eight drilled sites in the Ulleung Basin that constrain and contrast the carbon cycling pathways at chimney (high methane flux) and non-chimney sites (low methane, advective systems); 2) Simulate the Ba record in the sediments to quantify the past dynamics of methane flux in the southern Hydrate Ridge, Cascadia margin; and 3) Provide quantitative estimates of the thickness of individual mass transport deposits (MTDs), time elapsed after the MTD event, rate of sulfate reduction in the MTD, and time required to reach a new steady state at several sites drilled in the Krishna-Godavari (K-G) Basin off India. In addition we developed a hybrid model scheme by coupling a home-made MATLAB code with CrunchFlow to address the methane transport and chloride enrichment at the Ulleung Basins chimney sites, and contributed the modeling component to a study focusing on pore-scale controls on gas hydrate distribution in sediments from the Andaman Sea. These efforts resulted in two manuscripts currently under review, and contributed the modeling component of another pare, also under review. Lessons learned from these efforts are the basis of a mini-workshop to be held at Oregon State University (Feb 2014) to instruct graduate students (OSU and UW) as well as DOE staff from the NETL lab in Albany on the use of Crunch Flow for geochemical applications.

  14. Study on small-strain behaviours of methane hydrate sandy sediments using discrete element method

    SciTech Connect (OSTI)

    Yu Yanxin; Cheng Yipik; Xu Xiaomin; Soga, Kenichi

    2013-06-18

    Methane hydrate bearing soil has attracted increasing interest as a potential energy resource where methane gas can be extracted from dissociating hydrate-bearing sediments. Seismic testing techniques have been applied extensively and in various ways, to detect the presence of hydrates, due to the fact that hydrates increase the stiffness of hydrate-bearing sediments. With the recognition of the limitations of laboratory and field tests, wave propagation modelling using Discrete Element Method (DEM) was conducted in this study in order to provide some particle-scale insights on the hydrate-bearing sandy sediment models with pore-filling and cementation hydrate distributions. The relationship between shear wave velocity and hydrate saturation was established by both DEM simulations and analytical solutions. Obvious differences were observed in the dependence of wave velocity on hydrate saturation for these two cases. From the shear wave velocity measurement and particle-scale analysis, it was found that the small-strain mechanical properties of hydrate-bearing sandy sediments are governed by both the hydrate distribution patterns and hydrate saturation.

  15. Gas production potential of disperse low-saturation hydrate accumulations in oceanic sediments

    E-Print Network [OSTI]

    Moridis, George J.; Sloan, E. Dendy

    2006-01-01

    to economically Page viable gas production. The overallare not promising targets for gas production. AcknowledgmentEnergy, Office of Natural Gas and Petroleum Technology,

  16. Molecular computations for reactions and phase transitions: applications to protein stabilization, hydrates and catalysis

    E-Print Network [OSTI]

    Anderson, Brian J.

    In this work we have made significant contributions in three different areas of interest: therapeutic protein stabilization, thermodynamics of natural gas clathrate-hydrates, and zeolite catalysis. In all three fields, ...

  17. Microsoft Word - NETL-TRS-6-2015 Detection of Hydrates on Gas Bubbles during a Subsea Oil Gas Leak.20150722.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OFDetection of Hydrates on Gas Bubbles during a Subsea

  18. Hydrate-phobic surfaces: fundamental studies in clathrate hydrate adhesion reduction

    E-Print Network [OSTI]

    Smith, J. David

    Clathrate hydrate formation and subsequent plugging of deep-sea oil and gas pipelines represent a significant bottleneck for deep-sea oil and gas operations. Current methods for hydrate mitigation are expensive and energy ...

  19. The Use of Horizontal Wells in Gas Production from Hydrate Accumulations

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    saturation V G Cumulative volume of free gas in reservoir [reservoir (m) t Time (s) T Temperature [ o C] Aqueous phase saturation

  20. Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase hydration

    E-Print Network [OSTI]

    Sanov, Andrei

    Nonexistent electron affinity of OCS and the stabilization of carbonyl sulfide anions by gas phase2,7,8,26 studies, much less is known about the anions of carbonyl sulfide.9,22,28 In several

  1. Modeling pure methane hydrate dissociation using a numerical simulator from a novel combination of X-ray computed tomography and macroscopic data

    E-Print Network [OSTI]

    Gupta, A.

    2010-01-01

    of predicted and measured methane gas production data within the heterogeneous porous methane hydrate sample.Global Distribution of Methane Hydrate in Ocean Hydrate.

  2. Physical property changes in hydrate-bearingsediment due to depressurization and subsequent repressurization

    SciTech Connect (OSTI)

    Kneafsey, Timothy; Waite, W.F.; Kneafsey, T.J.; Winters, W.J.; Mason, D.H.

    2008-06-01

    Physical property measurements of sediment cores containing natural gas hydrate are typically performed on material exposed at least briefly to non-in situ conditions during recovery. To examine effects of a brief excursion from the gas-hydrate stability field, as can occur when pressure cores are transferred to pressurized storage vessels, we measured physical properties on laboratory-formed sand packs containing methane hydrate and methane pore gas. After depressurizing samples to atmospheric pressure, we repressurized them into the methane-hydrate stability field and remeasured their physical properties. Thermal conductivity, shear strength, acoustic compressional and shear wave amplitudes and speeds are compared between the original and depressurized/repressurized samples. X-ray computed tomography (CT) images track how the gas-hydrate distribution changes in the hydrate-cemented sands due to the depressurization/repressurization process. Because depressurization-induced property changes can be substantial and are not easily predicted, particularly in water-saturated, hydrate-bearing sediment, maintaining pressure and temperature conditions throughout the core recovery and measurement process is critical for using laboratory measurements to estimate in situ properties.

  3. Coupled flow and geomechanical analysis for gas production in the Prudhoe Bay Unit L-106 well Unit C gas hydrate deposit in Alaska

    E-Print Network [OSTI]

    Kim, J.

    2014-01-01

    Compression. Int. J. Offshore Polar Eng. , (20): 61 – 67.Compression. Int. J. Offshore Polar Eng. , (20): 256 – 264.Hydrate Bearing Sediments. Offshore Tech. Conf. (OTC 20721),

  4. DOE Leads National Research Program in Gas Hydrates | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle10nominate anDepartment ofTraining| WASHINGTON, DCtoday

  5. U.S. and Japan Complete Successful Field Trial of Methane Hydrate...

    Broader source: Energy.gov (indexed) [DOE]

    a larger scale in the U.S. Gulf Coast. "The Energy Department's long term investments in shale gas research during the 70s and 80s helped pave the way for today's boom in domestic...

  6. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    E-Print Network [OSTI]

    Kneafsey, T.J.

    2012-01-01

    T. and Narita, H. , 2006. Methane hydrate crystal growth ina porous medium filled with methane-saturated liquid water.Kneafsey, T.J. et al. , 2007. Methane hydrate formation and

  7. DOE Gas Hydrate R&D: Shale Gas DĂ©jĂ  Vu? | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i pStateDOE Federal Aviation Professional Awards More14Lynchburg,Points of

  8. Top 100 Oil and Gas Fields of 2009

    Gasoline and Diesel Fuel Update (EIA)

    Top 100 Oil and Gas Fields of 2009 Introduction This supplement to the Energy Information Administration's summary of U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved...

  9. Heat Flow and Gas Hydrates on the Continental Margin of India: Building on Results from NGHP Expedition 01

    SciTech Connect (OSTI)

    Trehu, Anne; Kannberg, Peter

    2011-06-30

    The Indian National Gas Hydrate Program (NGHP) Expedition 01 presented the unique opportunity to constrain regional heat flow derived from seismic observations by using drilling data in three regions on the continental margin of India. The seismic bottom simulating reflection (BSR) is a well-documented feature in hydrate bearing sediments, and can serve as a proxy for apparent heat flow if data are available to estimate acoustic velocity and density in water and sediments, thermal conductivity, and seafloor temperature. Direct observations of temperature at depth and physical properties of the sediment obtained from drilling can be used to calibrate the seismic observations, decreasing the uncertainty of the seismically-derived estimates. Anomalies in apparent heat flow can result from a variety of sources, including sedimentation, erosion, topographic refraction and fluid flow. We constructed apparent heat flow maps for portions of the Krishna-Godavari (K-G) basin, the Mahanadi basin, and the Andaman basin and modeled anomalies using 1-D conductive thermal models. Apparent heat flow values in the Krishna-Godavari (K-G) basin and Mahanadi basin are generally 0.035 to 0.055 watts per square meter (W/m2). The borehole data show an increase in apparent heat flow as water depth increases from 900 to 1500 m. In the SW part of the seismic grid, 1D modeling of the effect of sedimentation on heat flow shows that ~50% of the observed increase in apparent heat flow with increasing water depth can be attributed to trapping of sediments behind a "toe-thrust" ridge that is forming along the seaward edge of a thick, rapidly accumulating deltaic sediment pile. The remainder of the anomaly can be explained either by a decrease in thermal conductivity of the sediments filling the slope basin or by lateral advection of heat through fluid flow along stratigraphic horizons within the basin and through flexural faults in the crest of the anticline. Such flow probably plays a role in bringing methane into the ridge formed by the toe-thrust. Because of the small anomaly due to this process and the uncertainty in thermal conductivity, we did not model this process explicitly. In the NE part of the K-G basin seismic grid, a number of local heat flow lows and highs are observed, which can be attributed to topographic refraction and to local fluid flow along faults, respectively. No regional anomaly can be resolved. Because of lack of continuity between the K-G basin sites within the seismic grid and those ~70 km to the NE in water depths of 1200 to 1500 m, we do not speculate on the reason for higher heat flow at these depths. The Mahanadi basin results, while limited in geographic extent, are similar to those for the KG basin. The Andaman basin exhibits much lower apparent heat flow values, ranging from 0.015 to 0.025 W/m2. Heat flow here also appears to increase with increasing water depth. The very low heat flow here is among the lowest heat flow observed anywhere and gives rise to a very thick hydrate stability zone in the sediments. Through 1D models of sedimentation (with extremely high sedimentation rates as a proxy for tectonic thickening), we concluded that the very low heat flow can probably be attributed to the combined effects of high sedimentation rate, low thermal conductivity, tectonic thickening of sediments and the cooling effect of a subducting plate in a subduction zone forearc. Like for the K-G basin, much of the local variability can be attributed to topography. The regional increase in heat flow with water depth remains unexplained because the seismic grid available to us did not extend far enough to define the local tectonic setting of the slope basin controlling this observational pattern. The results are compared to results from other margins, both active and passive. While an increase in apparent heat flow with increasing water depth is widely observed, it is likely a result of different processes in different places. The very low heat flow due to sedimentation and tectonics in the Andaman basin is at the low end of glob

  10. Heat Flow and Gas Hydrates on the Continental Margin of India: Building on Results from NGHP Expedition 01

    SciTech Connect (OSTI)

    Anne Trehu; Peter Kannberg

    2011-06-30

    The Indian National Gas Hydrate Program (NGHP) Expedition 01 presented the unique opportunity to constrain regional heat flow derived from seismic observations by using drilling data in three regions on the continental margin of India. The seismic bottom simulating reflection (BSR) is a well-documented feature in hydrate bearing sediments, and can serve as a proxy for apparent heat flow if data are available to estimate acoustic velocity and density in water and sediments, thermal conductivity, and seafloor temperature. Direct observations of temperature at depth and physical properties of the sediment obtained from drilling can be used to calibrate the seismic observations, decreasing the uncertainty of the seismically-derived estimates. Anomalies in apparent heat flow can result from a variety of sources, including sedimentation, erosion, topographic refraction and fluid flow. We constructed apparent heat flow maps for portions of the Krishna-Godavari (K-G) basin, the Mahanadi basin, and the Andaman basin and modeled anomalies using 1-D conductive thermal models. Apparent heat flow values in the Krishna-Godavari (K-G) basin and Mahanadi basin are generally 0.035 to 0.055 watts per square meter (W/m{sup 2}). The borehole data show an increase in apparent heat flow as water depth increases from 900 to 1500 m. In the SW part of the seismic grid, 1D modeling of the effect of sedimentation on heat flow shows that {approx}50% of the observed increase in apparent heat flow with increasing water depth can be attributed to trapping of sediments behind a 'toe-thrust' ridge that is forming along the seaward edge of a thick, rapidly accumulating deltaic sediment pile. The remainder of the anomaly can be explained either by a decrease in thermal conductivity of the sediments filling the slope basin or by lateral advection of heat through fluid flow along stratigraphic horizons within the basin and through flexural faults in the crest of the anticline. Such flow probably plays a role in bringing methane into the ridge formed by the toe-thrust. Because of the small anomaly due to this process and the uncertainty in thermal conductivity, we did not model this process explicitly. In the NE part of the K-G basin seismic grid, a number of local heat flow lows and highs are observed, which can be attributed to topographic refraction and to local fluid flow along faults, respectively. No regional anomaly can be resolved. Because of lack of continuity between the K-G basin sites within the seismic grid and those {approx}70 km to the NE in water depths of 1200 to 1500 m, we do not speculate on the reason for higher heat flow at these depths. The Mahanadi basin results, while limited in geographic extent, are similar to those for the K-G basin. The Andaman basin exhibits much lower apparent heat flow values, ranging from 0.015 to 0.025 W/m{sup 2}. Heat flow here also appears to increase with increasing water depth. The very low heat flow here is among the lowest heat flow observed anywhere and gives rise to a very thick hydrate stability zone in the sediments. Through 1D models of sedimentation (with extremely high sedimentation rates as a proxy for tectonic thickening), we concluded that the very low heat flow can probably be attributed to the combined effects of high sedimentation rate, low thermal conductivity, tectonic thickening of sediments and the cooling effect of a subducting plate in a subduction zone forearc. Like for the K-G basin, much of the local variability can be attributed to topography. The regional increase in heat flow with water depth remains unexplained because the seismic grid available to us did not extend far enough to define the local tectonic setting of the slope basin controlling this observational pattern. The results are compared to results from other margins, both active and passive. While an increase in apparent heat flow with increasing water depth is widely observed, it is likely a result of different processes in different places. The very low heat flow due to sedimentation and tectonics in the Andaman basi

  11. U.S. and Japan Complete Successful Field Trial of Methane Hydrate

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment| Department of Energy Office ofProduction Technologies | Department

  12. Coupled flow and geomechanical analysis for gas production in the Prudhoe Bay Unit L-106 well Unit C gas hydrate deposit in Alaska

    E-Print Network [OSTI]

    Kim, J.

    2014-01-01

    way Coupled Fluid Flow and Geomechanics in Hydrate Deposits.for Coupled Flow and Geomechanics. Soc. Pet. Eng. J. 16(2):for coupled flow and geomechanics: Drained and undrained

  13. CONTENTS Concentrated Gas Hydrate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from the CloudGEGR-N Goods PO 1 of 8 GE4, Volume

  14. Oil and gas field code master list, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-16

    This document contains data collected through October 1993 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service.

  15. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Donn McGuire; Steve Runyon; Richard Sigal; Bill Liddell; Thomas Williams; George Moridis

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project is in the final stages of a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. Hot Ice No. 1 was planned to test the Ugnu and West Sak sequences for gas hydrates and a concomitant free gas accumulation on Anadarko's 100% working interest acreage in section 30 of Township 9N, Range 8E of the Harrison Bay quadrangle of the North Slope of Alaska. The Ugnu and West Sak intervals are favorably positioned in the hydrate-stability zone over an area extending from Anadarko's acreage westward to the vicinity of the aforementioned gas-hydrate occurrences. This suggests that a large, north-to-south trending gas-hydrate accumulation may exist in that area. The presence of gas shows in the Ugnu and West Sak reservoirs in wells situated eastward and down dip of the Hot Ice location indicate that a free-gas accumulation may be trapped by gas hydrates. The Hot Ice No. 1 well was designed to core from the surface to the base of the West Sak interval using the revolutionary and new Arctic Drilling Platform in search of gas hydrate and free gas accumulations at depths of approximately 1200 to 2500 ft MD. A secondary objective was the gas-charged sands of the uppermost Campanian interval at approximately 3000 ft. Summary results of geophysical analysis of the well are presented in this report.

  16. METHANE HYDRATE STUDIES: DELINEATING PROPERTIES OF HOST SEDIMENTS TO ESTABLISH REPRODUCIBLE DECOMPOSITION KINETICS.

    SciTech Connect (OSTI)

    Mahajan, Devinder; Jones, Keith W.; Feng, Huan; Winters, William J.

    2004-12-01

    The use of methane hydrate as an energy source requires development of a reliable method for its extraction from its highly dispersed locations in oceanic margin sediments and permafrost. The high pressure (up to 70 MPa) and low temperature (272 K to 278 K) conditions under which hydrates are stable in the marine environment can be mimicked in a laboratory setting and several kinetic studies of pure methane hydrate decomposition have been reported. However, the effect of host sediments on methane hydrate occurrence and decomposition are required to develop reliable hydrate models. In this paper, we describe methods to measure sediment properties as they relate to pore-space methane gas hydrate. Traditional geotechnical techniques are compared to the micrometer level by use of the synchrotron Computed Microtomography (CMT) technique. CMT was used to measure the porosity at the micrometer level and to show pore-space pathways through field samples. Porosities for three sediment samples: one from a site on Georges Bank and two from the known Blake Ridge methane hydrate site, from different depths below the mud line were measured by traditional drying and by the new CMT techniques and found to be in good agreement. The integration of the two analytical approaches is necessary to enable better understanding of methane hydrate interactions with the surrounding sediment particles.

  17. Complex admixtures of clathrate hydrates in a water desalination method

    DOE Patents [OSTI]

    Simmons, Blake A. (San Francisco, CA); Bradshaw, Robert W. (Livermore, CA); Dedrick, Daniel E. (Berkeley, CA); Anderson, David W. (Riverbank, CA)

    2009-07-14

    Disclosed is a method that achieves water desalination by utilizing and optimizing clathrate hydrate phenomena. Clathrate hydrates are crystalline compounds of gas and water that desalinate water by excluding salt molecules during crystallization. Contacting a hydrate forming gaseous species with water will spontaneously form hydrates at specific temperatures and pressures through the extraction of water molecules from the bulk phase followed by crystallite nucleation. Subsequent dissociation of pure hydrates yields fresh water and, if operated correctly, allows the hydrate-forming gas to be efficiently recycled into the process stream.

  18. Gas storage and separation by electric field swing adsorption

    DOE Patents [OSTI]

    Currier, Robert P; Obrey, Stephen J; Devlin, David J; Sansinena, Jose Maria

    2013-05-28

    Gases are stored, separated, and/or concentrated. An electric field is applied across a porous dielectric adsorbent material. A gas component from a gas mixture may be selectively separated inside the energized dielectric. Gas is stored in the energized dielectric for as long as the dielectric is energized. The energized dielectric selectively separates, or concentrates, a gas component of the gas mixture. When the potential is removed, gas from inside the dielectric is released.

  19. Overview on Hydrate Coring, Handling and Analysis

    SciTech Connect (OSTI)

    Jon Burger; Deepak Gupta; Patrick Jacobs; John Shillinglaw

    2003-06-30

    Gas hydrates are crystalline, ice-like compounds of gas and water molecules that are formed under certain thermodynamic conditions. Hydrate deposits occur naturally within ocean sediments just below the sea floor at temperatures and pressures existing below about 500 meters water depth. Gas hydrate is also stable in conjunction with the permafrost in the Arctic. Most marine gas hydrate is formed of microbially generated gas. It binds huge amounts of methane into the sediments. Worldwide, gas hydrate is estimated to hold about 1016 kg of organic carbon in the form of methane (Kvenvolden et al., 1993). Gas hydrate is one of the fossil fuel resources that is yet untapped, but may play a major role in meeting the energy challenge of this century. In June 2002, Westport Technology Center was requested by the Department of Energy (DOE) to prepare a ''Best Practices Manual on Gas Hydrate Coring, Handling and Analysis'' under Award No. DE-FC26-02NT41327. The scope of the task was specifically targeted for coring sediments with hydrates in Alaska, the Gulf of Mexico (GOM) and from the present Ocean Drilling Program (ODP) drillship. The specific subjects under this scope were defined in 3 stages as follows: Stage 1: Collect information on coring sediments with hydrates, core handling, core preservation, sample transportation, analysis of the core, and long term preservation. Stage 2: Provide copies of the first draft to a list of experts and stakeholders designated by DOE. Stage 3: Produce a second draft of the manual with benefit of input from external review for delivery. The manual provides an overview of existing information available in the published literature and reports on coring, analysis, preservation and transport of gas hydrates for laboratory analysis as of June 2003. The manual was delivered as draft version 3 to the DOE Project Manager for distribution in July 2003. This Final Report is provided for records purposes.

  20. Oil and Gas Field Code Master List 1990

    SciTech Connect (OSTI)

    Not Available

    1991-01-04

    This is the ninth annual edition of the Energy Information Administration's (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1990 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. There are 54,963 field records in this year's Oil and Gas Field Code Master List (FCML). This amounts to 467 more than in last year's report. As it is maintained by EIA, the Master List includes: Field records for each state and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides;field records for each alias field name; fields crossing state boundaries that may be assigned different names by the respective state naming authorities.

  1. ,"New Mexico Dry Natural Gas Reserves New Field Discoveries ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)",1,"Annual",2013...

  2. ,"Texas Dry Natural Gas Reserves New Field Discoveries (Billion...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Texas Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)",1,"Annual",2013...

  3. ,"Texas Dry Natural Gas New Reservoir Discoveries in Old Fields...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Texas Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion Cubic...

  4. Characterization of Field-Aged Exhaust Gas Recirculation Cooler Deposits

    Broader source: Energy.gov [DOE]

    Characterized field-aged exhaust gas recirculation coolers from 7 engine manufacturers, discussed differences and commonalities, and provided understanding of cooler fouling and prevention.

  5. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    Assessment of U.S. Oil and Gas Resources (on CD-ROM) (limited conventional oil and gas resources (Boswell, 2007).for conventional oil and gas resources (Collett, 2004)

  6. Assessing the Potential of Using Hydrate Technology to Capture, Store and Transport Gas for the Caribbean Region 

    E-Print Network [OSTI]

    Rajnauth, Jerome Joel

    2012-02-14

    Monetizing gas has now become a high priority issue for many countries. Natural gas is a much cleaner fuel than oil and coal especially for electricity generation. Approximately 40 percent of the world's natural gas reserves remain unusable because...

  7. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    conventional oil and gas reserves, the assessment of the1995 National Assessment of U.S. Oil and Gas Resources (on

  8. X-ray CT Observations of Methane Hydrate Distribution Changes over Time in a Natural Sediment Core from the BPX-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well

    E-Print Network [OSTI]

    Kneafsey, T.J.

    2012-01-01

    temperature to 4°C with the pore pressure of the system atby increasing the pore pressure to 4.8MPa and the confiningto a drop in pore pressure of 0.07MPa. Additional hydrate

  9. Multiple stage multiple filter hydrate store

    DOE Patents [OSTI]

    Bjorkman, Jr., Harry K. (Birmingham, MI)

    1983-05-31

    An improved hydrate store for a metal halogen battery system is disclosed which employs a multiple stage, multiple filter means or separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means.

  10. Multiple stage multiple filter hydrate store

    DOE Patents [OSTI]

    Bjorkman, H.K. Jr.

    1983-05-31

    An improved hydrate store for a metal halogen battery system is disclosed which employs a multiple stage, multiple filter means for separating the halogen hydrate from the liquid used in forming the hydrate. The filter means is constructed in the form of three separate sections which combine to substantially cover the interior surface of the store container. Exit conduit means is provided in association with the filter means for transmitting liquid passing through the filter means to a hydrate former subsystem. The hydrate former subsystem combines the halogen gas generated during the charging of the battery system with the liquid to form the hydrate in association with the store. Relief valve means is interposed in the exit conduit means for controlling the operation of the separate sections of the filter means, such that the liquid flow through the exit conduit means from each of the separate sections is controlled in a predetermined sequence. The three separate sections of the filter means operate in three discrete stages to provide a substantially uniform liquid flow to the hydrate former subsystem during the charging of the battery system. The separation of the liquid from the hydrate causes an increase in the density of the hydrate by concentrating the hydrate along the filter means. 7 figs.

  11. Multi-property characterization chamber for geophysical-hydrological investigations of hydrate bearing sediments

    SciTech Connect (OSTI)

    Seol, Yongkoo Choi, Jeong-Hoon; Dai, Sheng

    2014-08-01

    With the increase in the interest of producing natural gas from methane hydrates as well as potential risks of massive hydrate dissociation in the context of global warming, studies have recently shifted from pure hydrate crystals to hydrates in sediments. Such a research focus shift requires a series of innovative laboratory devices that are capable of investigating various properties of hydrate-bearing sediments (HBS). This study introduces a newly developed high pressure testing chamber, i.e., multi-property characterization chamber (MPCC), that allows simultaneous investigation of a series of fundamental properties of HBS, including small-strain stiffness (i.e., P- and S-waves), shear strength, large-strain deformation, stress-volume responses, and permeability. The peripheral coolant circulation system of the MPCC permits stable and accurate temperature control, while the core holder body, made of aluminum, enables X-ray computer tomography scanning to be easily employed for structural and morphological characterization of specimens. Samples of hydrate-bearing sediments are held within a rubber sleeve inside the chamber. The thick sleeve is more durable and versatile than thin membranes while also being much softer than oedometer-type chambers that are incapable of enabling flow tests. Bias introduced by the rubber sleeve during large deformation tests are also calibrated both theoretically and experimentally. This system provides insight into full characterization of hydrate-bearing sediments in the laboratory, as well as pressure core technology in the field.

  12. Towards bio-silicon interfaces: Formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan deposited in high vacuum from the gas-phase

    SciTech Connect (OSTI)

    Retamal, María J. Cisternas, Marcelo A.; Seifert, Birger; Volkmann, Ulrich G.; Gutierrez-Maldonado, Sebastian E.; Perez-Acle, Tomas; Busch, Mark; Huber, Patrick

    2014-09-14

    The recent combination of nanoscale developments with biological molecules for biotechnological research has opened a wide field related to the area of biosensors. In the last years, device manufacturing for medical applications adapted the so-called bottom-up approach, from nanostructures to larger devices. Preparation and characterization of artificial biological membranes is a necessary step for the formation of nano-devices or sensors. In this paper, we describe the formation and characterization of a phospholipid bilayer (dipalmitoylphosphatidylcholine, DPPC) on a mattress of a polysaccharide (Chitosan) that keeps the membrane hydrated. The deposition of Chitosan (?25 Ĺ) and DPPC (?60 Ĺ) was performed from the gas phase in high vacuum onto a substrate of Si(100) covered with its native oxide layer. The layer thickness was controlled in situ using Very High Resolution Ellipsometry (VHRE). Raman spectroscopy studies show that neither Chitosan nor DPPC molecules decompose during evaporation. With VHRE and Atomic Force Microscopy we have been able to detect phase transitions in the membrane. The presence of the Chitosan interlayer as a water reservoir is essential for both DPPC bilayer formation and stability, favoring the appearance of phase transitions. Our experiments show that the proposed sample preparation from the gas phase is reproducible and provides a natural environment for the DPPC bilayer. In future work, different Chitosan thicknesses should be studied to achieve a complete and homogeneous interlayer.

  13. Sequestration of CO2 in the Altmark natural gas field, Germany: Mobility control to extend enhanced gas recovery

    E-Print Network [OSTI]

    Rebscher, D.; May, F.; Oldenburg, C.M.

    2006-01-01

    OF CO 2 IN THE ALTMARK NATURAL GAS FIELD, GERMANY: MOBILITYin the depleted Altmark natural gas reservoir, Germany. Ourdioxide or nitrogen in natural gas (methane) reservoirs,

  14. Oil and Gas field code master list 1995

    SciTech Connect (OSTI)

    1995-12-01

    This is the fourteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1995 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the US. The Field Code Index, a listing of all field names and the States in which they occur, ordered by field code, has been removed from this year`s publications to reduce printing and postage costs. Complete copies (including the Field Code Index) will be available on the EIA CD-ROM and the EIA World-Wide Web Site. Future editions of the complete Master List will be available on CD-ROM and other electronic media. There are 57,400 field records in this year`s Oil and Gas Field Code Master List. As it is maintained by EIA, the Master List includes the following: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (see definition of alias below); and fields crossing State boundaries that may be assigned different names by the respective State naming authorities. Taking into consideration the double-counting of fields under such circumstances, EIA identifies 46,312 distinct fields in the US as of October 1995. This count includes fields that no longer produce oil or gas, and 383 fields used in whole or in part for oil or gas Storage. 11 figs., 6 tabs.

  15. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    at producing gas from this unconventional source be aunconventional energy resources clearly shows that the evolution of gasand gas reservoirs, or even to the large (and rapidly increasing) data-base of information on unconventional

  16. Toward Production From Gas Hydrates: Current Status, Assessment of Resources, and Simulation-Based Evaluation of Technology and Potential

    E-Print Network [OSTI]

    Moridis, George J.

    2008-01-01

    oil and gas reservoirs, or even to the large (and rapidly increasing) data-base of information on unconventional

  17. Detection and Production of Methane Hydrate

    SciTech Connect (OSTI)

    George Hirasaki; Walter Chapman; Gerald Dickens; Colin Zelt; Brandon Dugan; Kishore Mohanty; Priyank Jaiswal

    2011-12-31

    This project seeks to understand regional differences in gas hydrate systems from the perspective of as an energy resource, geohazard, and long-term climate influence. Specifically, the effort will: (1) collect data and conceptual models that targets causes of gas hydrate variance, (2) construct numerical models that explain and predict regional-scale gas hydrate differences in 2-dimensions with minimal 'free parameters', (3) simulate hydrocarbon production from various gas hydrate systems to establish promising resource characteristics, (4) perturb different gas hydrate systems to assess potential impacts of hot fluids on seafloor stability and well stability, and (5) develop geophysical approaches that enable remote quantification of gas hydrate heterogeneities so that they can be characterized with minimal costly drilling. Our integrated program takes advantage of the fact that we have a close working team comprised of experts in distinct disciplines. The expected outcomes of this project are improved exploration and production technology for production of natural gas from methane hydrates and improved safety through understanding of seafloor and well bore stability in the presence of hydrates. The scope of this project was to more fully characterize, understand, and appreciate fundamental differences in the amount and distribution of gas hydrate and how this would affect the production potential of a hydrate accumulation in the marine environment. The effort combines existing information from locations in the ocean that are dominated by low permeability sediments with small amounts of high permeability sediments, one permafrost location where extensive hydrates exist in reservoir quality rocks and other locations deemed by mutual agreement of DOE and Rice to be appropriate. The initial ocean locations were Blake Ridge, Hydrate Ridge, Peru Margin and GOM. The permafrost location was Mallik. Although the ultimate goal of the project was to understand processes that control production potential of hydrates in marine settings, Mallik was included because of the extensive data collected in a producible hydrate accumulation. To date, such a location had not been studied in the oceanic environment. The project worked closely with ongoing projects (e.g. GOM JIP and offshore India) that are actively investigating potentially economic hydrate accumulations in marine settings. The overall approach was fivefold: (1) collect key data concerning hydrocarbon fluxes which is currently missing at all locations to be included in the study, (2) use this and existing data to build numerical models that can explain gas hydrate variance at all four locations, (3) simulate how natural gas could be produced from each location with different production strategies, (4) collect new sediment property data at these locations that are required for constraining fluxes, production simulations and assessing sediment stability, and (5) develop a method for remotely quantifying heterogeneities in gas hydrate and free gas distributions. While we generally restricted our efforts to the locations where key parameters can be measured or constrained, our ultimate aim was to make our efforts universally applicable to any hydrate accumulation.

  18. Oil and gas field code master list 1994

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    This is the thirteenth annual edition of the Energy Information Administration`s (EIA) Oil and Gas Field Code Master List. It reflects data collected through October 1994 and provides standardized field name spellings and codes for all identified oil and/or gas fields in the United States. The master field name spellings and codes are to be used by respondents when filing the following Department of Energy (DOE) forms: Form EIA-23, {open_quotes}Annual Survey of Domestic Oil and Gas Reserves,{close_quotes} filed by oil and gas well operators (field codes are required from larger operators only); Forms FERC 8 and EIA-191, {open_quotes}Underground Gas Storage Report,{close_quotes} filed by natural gas producers and distributors who operate underground natural gas storage facilities. Other Federal and State government agencies, as well as industry, use the EIA Oil and Gas Field Code Master List as the standard for field identification. A machine-readable version of the Oil and Gas Field Code Master List is available from the National Technical Information Service, 5285 Port Royal Road, Springfield, Virginia 22161, (703) 487-4650. In order for the Master List to be useful, it must be accurate and remain current. To accomplish this, EIA constantly reviews and revises this list. The EIA welcomes all comments, corrections, and additions to the Master List. All such information should be given to the EIA Field Code Coordinator at (214) 953-1858. EIA gratefully acknowledges the assistance provides by numerous State organizations and trade associations in verifying the existence of fields and their official nomenclature.

  19. Oil and gas field code master list 1997

    SciTech Connect (OSTI)

    1998-02-01

    The Oil and Gas Field Code Master List 1997 is the sixteenth annual listing of all identified oil and gas fields in the US. It is updated with field information collected through October 1997. The purpose of this publication is to provide unique, standardized codes for identification of domestic fields. Use of these field codes fosters consistency of field identification by government and industry. As a result of their widespread adoption they have in effect become a national standard. The use of field names and codes listed in this publication is required on survey forms and other reports regarding field-specific data collected by EIA. There are 58,366 field records in this year`s FCML, 437 more than last year. The FCML includes: field records for each State and county in which a field resides; field records for each offshore area block in the Gulf of Mexico in which a field resides; field records for each alias field name (definition of alias is listed); fields crossing State boundaries that may be assigned different names by the respective State naming authorities. This report also contains an Invalid Field Record List of 4 records that have been removed from the FCML since last year`s report. These records were found to be either technically incorrect or to represent field names which were never recognized by State naming authorities.

  20. Natural Gas Plant Field Production: Natural Gas Liquids

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets See(STEO),7F e28 3.24 3.23200950

  1. Trip report for field visit to Fayetteville Shale gas wells.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2007-09-30

    This report describes a visit to several gas well sites in the Fayetteville Shale on August 9, 2007. I met with George Sheffer, Desoto Field Manager for SEECO, Inc. (a large gas producer in Arkansas). We talked in his Conway, Arkansas, office for an hour and a half about the processes and technologies that SEECO uses. We then drove into the field to some of SEECO's properties to see first-hand what the well sites looked like. In 2006, the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) made several funding awards under a program called Low Impact Natural Gas and Oil (LINGO). One of the projects that received an award is 'Probabilistic Risk-Based Decision Support for Oil and Gas Exploration and Production Facilities in Sensitive Ecosystems'. The University of Arkansas at Fayetteville has the lead on the project, and Argonne National Laboratory is a partner. The goal of the project is to develop a Web-based decision support tool that will be used by mid- and small-sized oil and gas companies as well as environmental regulators and other stakeholders to proactively minimize adverse ecosystem impacts associated with the recovery of gas reserves in sensitive areas. The project focuses on a large new natural gas field called the Fayetteville Shale. Part of the project involves learning how the natural gas operators do business in the area and the technologies they employ. The field trip on August 9 provided an opportunity to do that.

  2. Gas characterization system 241-AN-105 field acceptance test procedure

    SciTech Connect (OSTI)

    Schneider, T.C.

    1996-03-01

    This document details the field Acceptance Testing of a gas characterization system being installed on waste tank 241-AN-105. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  3. Gas characterization system 241-AW-101 field acceptance test procedure

    SciTech Connect (OSTI)

    Schneider, T.C.

    1996-03-01

    This document details the field Acceptance Testing of a gas characterization system being installed on waste tank 241-AW-101. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  4. Working Gas Capacity of Depleted Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan3Additions (Million2.8 2.6 2.7 2.7 2.9 3.0 1993-201496,092

  5. Natural Gas Depleted Fields Storage Capacity

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in Nevada (Millionthroughthrough

  6. Natural Gas Liquids New Field Discoveries

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in NevadaYear-Month802 827 788 811 831 84035

  7. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD: Pt.Campaign govCampaignsPrecision Gas Sampling (PGS)

  8. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD: Pt.Campaign govCampaignsPrecision Gas Sampling

  9. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD: Pt.Campaign govCampaignsPrecision Gas

  10. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design togovCampaignsMASRAD: Pt.Campaign govCampaignsPrecision GasCampaign

  11. Power Plays: Geothermal Energy In Oil and Gas Fields

    Broader source: Energy.gov [DOE]

    The SMU Geothermal Lab is hosting their 7th international energy conference and workshop Power Plays: Geothermal Energy in Oil and Gas Fields May 18-20, 2015 on the SMU Campus in Dallas, Texas. The two-day conference brings together leaders from the geothermal, oil and gas communities along with experts in finance, law, technology, and government agencies to discuss generating electricity from oil and gas well fluids, using the flare gas for waste heat applications, and desalinization of the water for project development in Europe, China, Indonesia, Mexico, Peru and the US. Other relevant topics include seismicity, thermal maturation, and improved drilling operations.

  12. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Frank R. Rack; Tim Francis; Peter Schultheiss; Philip E. Long; Barry M. Freifeld

    2005-04-01

    The primary activities accomplished during this quarter were continued efforts to develop plans for Phase 2 of this cooperative agreement based on the evolving operational planning for IODP Expedition 311, which will use the JOIDES Resolution to study marine methane hydrates along the Cascadia margin, offshore Vancouver Island. IODP Expedition 311 has been designed to further constrain the models for the formation of marine gas hydrate in subduction zone accretionary prisms. The objectives include characterizing the deep origin of the methane, its upward transport, its incorporation in gas hydrate, and its subsequent loss to the seafloor. The main attention of this expedition is on the widespread seafloor-parallel layer of dispersed gas hydrate located just above the base of the predicted stability field. In a gas hydrate formation model, methane is carried upward through regional sediment or small-scale fracture permeability, driven by the tectonic consolidation of the accretionary prism. The upward moving methane is incorporated into the gas hydrate clathrate as it enters the methane hydrate stability zone. Also important is the focusing of a portion of the upward methane flux into localized plumes or channels to form concentrations of near-seafloor gas hydrate. The amount of gas hydrate in local concentrations near the seafloor is especially important for understanding the response of marine gas hydrate to climate change. The expedition includes coring and downhole measurements at five sites across the Northern Cascadia accretionary prism. The sites will track the history of methane in an accretionary prism from (1) its production by mainly microbiological processes over a thick sediment vertical extent, (2) its upward transport through regional or locally focused fluid flow, (3) its incorporation in the regional hydrate layer above the BSR or in local concentrations at or near the seafloor, (4) methane loss from the hydrate by upward diffusion, and (5) methane oxidation and incorporation in seafloor carbonate, or expulsion to the ocean. This expedition builds on the previous Cascadia gas hydrate drilling of ODP Leg 146 and on more recent ODP Leg 204 off Oregon. Important experiments being considered for DOE/NETL funding as part of the JOI cooperative agreement include, (1) Logging-While-Drilling/Measurements-While-Drilling (LWD/MWD), (2) Pressure Core Sampling (PCS/HYACINTH) of gas hydrate, and fluid recovery under in situ conditions, (3) X-ray CT logging of whole cores under in situ conditions, and (4) Infrared thermal imaging of whole round cores to map temperature variations resulting from the presence of hydrate. Preliminary budget estimates have been made for each of these tasks and discussions are ongoing with DOE/NETL program managers to develop a final plan that can be implemented within the constraints of the available funding and logistical considerations.

  13. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Ali Kadaster; Bill Liddell; Tommy Thompson; Thomas Williams; Michael Niedermayr

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and implemented for determining physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. Final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models and to research teams for developing future gas-hydrate projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and has been documented by the project team. This Topical Report documents drilling and coring operations and other daily activities.

  14. HOT GAS HALOS IN EARLY-TYPE FIELD GALAXIES

    SciTech Connect (OSTI)

    Mulchaey, John S. [Observatories of the Carnegie Institution of Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Jeltema, Tesla E., E-mail: mulchaey@obs.carnegiescience.ed, E-mail: tesla@ucolick.or [UCO/Lick Observatories, 1156 High Street, Santa Cruz, CA 95064 (United States)

    2010-05-20

    We use Chandra and XMM-Newton to study the hot gas content in a sample of field early-type galaxies. We find that the L {sub X}-L {sub K} relationship is steeper for field galaxies than for comparable galaxies in groups and clusters. The low hot gas content of field galaxies with L {sub K} {approx_lt} L {sub *} suggests that internal processes such as supernovae-driven winds or active galactic nucleus feedback expel hot gas from low-mass galaxies. Such mechanisms may be less effective in groups and clusters where the presence of an intragroup or intracluster medium can confine outflowing material. In addition, galaxies in groups and clusters may be able to accrete gas from the ambient medium. While there is a population of L {sub K} {approx_lt} L {sub *} galaxies in groups and clusters that retain hot gas halos, some galaxies in these rich environments, including brighter galaxies, are largely devoid of hot gas. In these cases, the hot gas halos have likely been removed via ram pressure stripping. This suggests a very complex interplay between the intragroup/intracluster medium and hot gas halos of galaxies in rich environments, with the ambient medium helping to confine or even enhance the halos in some cases and acting to remove gas in others. In contrast, the hot gas content of more isolated galaxies is largely a function of the mass of the galaxy, with more massive galaxies able to maintain their halos, while in lower mass systems the hot gas escapes in outflowing winds.

  15. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Steve Runyon; Mike Globe; Kent Newsham; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. This gas-hydrate project was a cost-shared partnership between Maurer Technology, Noble Corporation, Anadarko Petroleum, and the U.S. Department of Energy's Methane Hydrate R&D program. The purpose of the project is to build on previous and ongoing R&D in the area of onshore hydrate deposition to identify, quantify and predict production potential for hydrates located on the North Slope of Alaska. The work scope included drilling and coring a well (Hot Ice No. 1) on Anadarko leases beginning in FY 2003 and completed in 2004. During the first drilling season, operations were conducted at the site between January 28, 2003 to April 30, 2003. The well was spudded and drilled to a depth of 1403 ft. Due to the onset of warmer weather, work was then suspended for the season. Operations at the site were continued after the tundra was re-opened the following season. Between January 12, 2004 and March 19, 2004, the well was drilled and cored to a final depth of 2300 ft. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists planning hydrate exploration and development projects. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this and other project reports. This Topical Report contains details describing logging operations.

  16. Ice method for production of hydrogen clathrate hydrates

    DOE Patents [OSTI]

    Lokshin, Konstantin (Santa Fe, NM); Zhao, Yusheng (Los Alamos, NM)

    2008-05-13

    The present invention includes a method for hydrogen clathrate hydrate synthesis. First, ice and hydrogen gas are supplied to a containment volume at a first temperature and a first pressure. Next, the containment volume is pressurized with hydrogen gas to a second higher pressure, where hydrogen clathrate hydrates are formed in the process.

  17. Largest US oil and gas fields, August 1993

    SciTech Connect (OSTI)

    Not Available

    1993-08-06

    The Largest US Oil and Gas Fields is a technical report and part of an Energy Information Administration (EIA) series presenting distributions of US crude oil and natural gas resources, developed using field-level data collected by EIA`s annual survey of oil and gas proved reserves. The series` objective is to provide useful information beyond that routinely presented in the EIA annual report on crude oil and natural gas reserves. These special reports also will provide oil and gas resource analysts with a fuller understanding of the nature of US crude oil and natural gas occurrence, both at the macro level and with respect to the specific subjects addressed. The series` approach is to integrate EIA`s crude oil and natural gas survey data with related data obtained from other authoritative sources, and then to present illustrations and analyses of interest to a broad spectrum of energy information users ranging from the general public to oil and gas industry personnel.

  18. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle D. (Golden, CO)

    1995-01-01

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

  19. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    E-Print Network [OSTI]

    Kwon, T.H.

    2012-01-01

    composed of methane and ethane”; The 6th InternationalGupta et al. (2008) 24 Ethane hydrate (h ? l + g) Nakagawamol gas. 12 On the contrary, ethane (C 2 H 6 ) hydrate (sI

  20. Designing Durable Vapor-Deposited Surfaces for Reduced Hydrate Adhesion

    E-Print Network [OSTI]

    Sojoudi, Hossein

    The formation and accumulation of clathrate hydrates inside oil and gas pipelines cause severe problems in deep-sea oil/gas operations. In the present work, durable and mechanically robust bilayer poly-divinyl benzene/po ...

  1. Method for production of hydrocarbons from hydrates

    DOE Patents [OSTI]

    McGuire, Patrick L. (Los Alamos, NM)

    1984-01-01

    A method of recovering natural gas entrapped in frozen subsurface gas hydrate formations in arctic regions. A hot supersaturated solution of CaCl.sub.2 or CaBr.sub.2, or a mixture thereof, is pumped under pressure down a wellbore and into a subsurface hydrate formation so as to hydrostatically fracture the formation. The CaCl.sub.2 /CaBr.sub.2 solution dissolves the solid hydrates and thereby releases the gas entrapped therein. Additionally, the solution contains a polymeric viscosifier, which operates to maintain in suspension finely divided crystalline CaCl.sub.2 /CaBr.sub.2 that precipitates from the supersaturated solution as it is cooled during injection into the formation.

  2. METHANE HYDRATE PRODUCTION FROM ALASKAN PERMAFROST

    SciTech Connect (OSTI)

    Richard Sigal; Kent Newsham; Thomas Williams; Barry Freifeld; Timothy Kneafsey; Carl Sondergeld; Shandra Rai; Jonathan Kwan; Stephen Kirby; Robert Kleinberg; Doug Griffin

    2005-02-01

    Natural-gas hydrates have been encountered beneath the permafrost and considered a nuisance by the oil and gas industry for years. Engineers working in Russia, Canada and the USA have documented numerous drilling problems, including kicks and uncontrolled gas releases, in arctic regions. Information has been generated in laboratory studies pertaining to the extent, volume, chemistry and phase behavior of gas hydrates. Scientists studying hydrate potential agree that the potential is great--on the North Slope of Alaska alone, it has been estimated at 590 TCF. However, little information has been obtained on physical samples taken from actual rock containing hydrates. The work scope drilled and cored a well The Hot Ice No. 1 on Anadarko leases beginning in FY 2003 and completed in 2004. An on-site core analysis laboratory was built and utilized for determining the physical characteristics of the hydrates and surrounding rock. The well was drilled from a new Anadarko Arctic Platform that has a minimal footprint and environmental impact. The final efforts of the project are to correlate geology, geophysics, logs, and drilling and production data and provide this information to scientists developing reservoir models. No gas hydrates were encountered in this well; however, a wealth of information was generated and is contained in this report. The Hot Ice No. 1 well was drilled from the surface to a measured depth of 2300 ft. There was almost 100% core recovery from the bottom of surface casing at 107 ft to total depth. Based on the best estimate of the bottom of the methane hydrate stability zone (which used new data obtained from Hot Ice No. 1 and new analysis of data from adjacent wells), core was recovered over its complete range. Approximately 580 ft of porous, mostly frozen, sandstone and 155 of conglomerate were recovered in the Ugnu Formation and approximately 215 ft of porous sandstone were recovered in the West Sak Formation. There were gas shows in the bottom part of the Ugnu and throughout the West Sak. No hydrate-bearing zones were identified either in recovered core or on well logs. The base of the permafrost was found at about 1260 ft. With the exception of the deepest sands in the West Sak and some anomalous thin, tight zones, all sands recovered (after thawing) are unconsolidated with high porosity and high permeability. At 800 psi, Ugnu sands have an average porosity of 39.3% and geometrical mean permeability of 3.7 Darcys. Average grain density is 2.64 g/cc. West Sak sands have an average porosity of 35.5%, geometrical mean permeability of 0.3 Darcys, and average grain density of 2.70 g/cc. There were several 1-2 ft intervals of carbonate-cemented sandstone recovered from the West Sak. These intervals have porosities of only a few percent and very low permeability. On a well log they appear as resistive with a high sonic velocity. In shallow sections of other wells these usually are the only logs available. Given the presence of gas in Hot Ice No. 1, if only resistivity and sonic logs and a mud log had been available, tight sand zones may have been interpreted as containing hydrates. Although this finding does not imply that all previously mapped hydrate zones are merely tight sands, it does add a note of caution to the practice of interpreting the presence of hydrates from old well information. The methane hydrate stability zone below the Hot Ice No. 1 location includes thick sections of sandstone and conglomerate which would make excellent reservoir rocks for hydrates and below the permafrost zone shallow gas. The Ugnu formation comprises a more sand-rich section than does the West Sak formation, and the Ugnu sands when cleaned and dried are slightly more porous and significantly more permeable than the West Sak.

  3. Thermodynamics of Modified Chaplygin Gas and Tachyonic Field

    E-Print Network [OSTI]

    Samarpita Bhattacharya; Ujjal Debnath

    2010-12-26

    Here we generalize the results of the work of ref. [10] in modified Chaplygin gas model and tachyonic field model. Here we have studied the thermodynamical behaviour and the equation of state in terms of volume and temperature for both models. We have used the solution and the corresponding equation of state of our previous work [12] for tachyonic field model. We have also studied the thermodynamical stability using thermal equation of state for the tachyonic field model and have shown that there is no critical points during thermodynamical expansion. The determination of $T_{*}$ due to expansion for the tachyonic field have been discussed by assuming some initial conditions. Here, the thermal quantities have been investigated using some reduced parameters.

  4. Gas insulated transmission line with insulators having field controlling recesses

    DOE Patents [OSTI]

    Cookson, Alan H. (Pittsburgh, PA); Pederson, Bjorn O. (Chelmsford, MA)

    1984-01-01

    A gas insulated transmission line having a novel insulator for supporting an inner conductor concentrically within an outer sheath. The insulator has a recess contiguous with the periphery of one of the outer and inner conductors. The recess is disposed to a depth equal to an optimum gap for the dielectric insulating fluid used for the high voltage insulation or alternately disposed to a large depth so as to reduce the field at the critical conductor/insulator interface.

  5. Phase I (CATTS Theory), Phase II (Milne Point), Phase III (Hydrate Ridge)

    SciTech Connect (OSTI)

    None

    2009-10-31

    This study introduces a new type of â??cumulative seismic attributeâ?ť (CATT) which quantifies gas hydrates resources in Hydrate Ridge offshore Oregon. CATT is base on case-specific transforms that portray hydrated reservoir properties. In this study we used a theoretical rock physics model to correct measured velocity log data.

  6. STRUCTURE OF A CARBONATE/HYDRATE MOUND IN THE NORTHERN GULF OF MEXICO

    E-Print Network [OSTI]

    Gerstoft, Peter

    STRUCTURE OF A CARBONATE/HYDRATE MOUND IN THE NORTHERN GULF OF MEXICO T. McGee1* , J. R. Woolsey1 and hydrate outcrops imply that the faults act as migration conduits for hydrocarbons from a deep, hot the mound. Keywords: carbonate/hydrate mound, seismic structures, gas migration, seafloor observatory

  7. Micromechanics of Hydrate Dissociation in Marine Sediments by Grain-Scale Simulations

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    SPE 114223 Micromechanics of Hydrate Dissociation in Marine Sediments by Grain-Scale Simulations dissociation on the strength of hydrate-bearing sediments. Dissociation of gas-hydrates in marine sediments pressure increase, this process reduces the stiffness of the sediments, which may fracture or be flu

  8. Field testing the Raman gas composition sensor for gas turbine operation

    SciTech Connect (OSTI)

    Buric, M.; Chorpening, B.; Mullem, J.; Ranalli, J.; Woodruff, S.

    2012-01-01

    A gas composition sensor based on Raman spectroscopy using reflective metal lined capillary waveguides is tested under field conditions for feed-forward applications in gas turbine control. The capillary waveguide enables effective use of low powered lasers and rapid composition determination, for computation of required parameters to pre-adjust burner control based on incoming fuel. Tests on high pressure fuel streams show sub-second time response and better than one percent accuracy on natural gas fuel mixtures. Fuel composition and Wobbe constant values are provided at one second intervals or faster. The sensor, designed and constructed at NETL, is packaged for Class I Division 2 operations typical of gas turbine environments, and samples gas at up to 800 psig. Simultaneous determination of the hydrocarbons methane, ethane, and propane plus CO, CO2, H2O, H2, N2, and O2 are realized. The capillary waveguide permits use of miniature spectrometers and laser power of less than 100 mW. The capillary dimensions of 1 m length and 300 μm ID also enable a full sample exchange in 0.4 s or less at 5 psig pressure differential, which allows a fast response to changes in sample composition. Sensor operation under field operation conditions will be reported.

  9. Effect of bubble size and density on methane conversion to hydrate

    SciTech Connect (OSTI)

    Leske, J.; Taylor, C.E.; Ladner, E.P.

    2007-03-01

    Research is underway at NETL to understand the physical properties of methane hydrates. One area of investigation is the storage of methane as methane hydrates. An economical and efficient means of storing methane in hydrates opens many commercial opportunities such as transport of stranded gas, off-peak storage of line gas, etc.We have observed during our investigations that the ability to convert methane to methane hydrate is enhanced by foaming of the methane–water solution using a surfactant. The density of the foam, along with the bubble size, is important in the conversion of methane to methane hydrate.

  10. Field test comparison of natural gas engine exhaust valves

    SciTech Connect (OSTI)

    Bicknell, W.B.; Hay, S.C.; Shade, W.N.; Statler, G.R.

    1996-12-31

    As part of a product improvement program, an extensive spark-ignited, turbocharged, natural gas engine exhaust valve test program was conducted using laboratory and field engines. Program objectives were to identify a valve and seat insert combination that increased mean time between overhauls (MTBO) while reducing the risk of premature valve cracking and failure. Following a thorough design review, a large number of valve and seat insert configurations were tested in a popular 900 RPM, 166 BHP (0.123 Mw) per cylinder industrial gas engine series. Material, head geometry, seat angle and other parameters were compared. Careful in-place measurements and post-test inspections compared various configurations and identified optimal exhaust valving for deployment in new units and upgrades of existing engines.

  11. Effect of under-inhibition with methanol and ethylene glycol on the hydrate control process

    SciTech Connect (OSTI)

    Yousif, M.H.

    1996-12-31

    Hydrate control can be achieved by chemical injection. Currently, methanol and ethylene glycol are the most widely used inhibitors in offshore hydrate control operations. To achieve effective hydrate inhibition, a sufficient amount of inhibitor must be injected to shift the thermodynamic equilibrium condition for hydrate formation outside the pipeline operating pressure and temperature. Recently published field experiments showed that hydrate blockages form more readily in under-inhibited systems than in systems completely without inhibitor. A laboratory study is conducted to determine the effect of low concentration (1--5wt%) methanol and ethylene glycol on the hydrate formation process. The results show that, although these chemicals are effective hydrate inhibitors when added in sufficient quantities, they actually enhance the rate of hydrate formation when added at low concentrations to the water. Furthermore, the presence of these chemicals seems to affect the size of the forming hydrate particles.

  12. Field Demonstration of High-Efficiency Gas Heaters

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRD Report to CongressApril 6, 2012Certification |Field

  13. Michigan Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal ConsumptionperYearFeet) New Field

  14. U.S. Natural Gas Plant Field Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: April 15,Gas9,7WithdrawalsCubicCanadaDecadePoint2009

  15. Application of Phase-field Method in Predicting Gas Bubble Microstructure Evolution in Nuclear Fuels

    SciTech Connect (OSTI)

    Hu, Shenyang Y.; Li, Yulan; Sun, Xin; Gao, Fei; Devanathan, Ramaswami; Henager, Charles H.; Khaleel, Mohammad A.

    2010-04-30

    Fission product accumulation and gas bubble microstructure evolution in nuclear fuels strongly affect thermo-mechanical properties such as thermal conductivity, gas release, volumetric swelling and cracking, and hence the fuel performance. In this paper, a general phase-field model is developed to predict gas bubble formation and evolution. Important materials processes and thermodynamic properties including the generation of gas atoms and vacancies, sinks for vacancies and gas atoms, the elastic interaction among defects, gas re-solution, and inhomogeneity of elasticity and diffusivity are accounted for in the model. The simulations demonstrate the potential application of the phase-field method in investigating 1) heterogeneous nucleation of gas bubbles at defects; 2) effect of elastic interaction, inhomogeneity of material properties, and gas re-solution on gas bubble microstructures; and 3) effective properties from the output of phase-field simulations such as distribution of defects, gas bubbles, and stress fields.

  16. Investigating the Metastability of Clathrate Hydrates for Energy Storage

    SciTech Connect (OSTI)

    Koh, Carolyn Ann

    2014-11-18

    Important breakthrough discoveries have been achieved from the DOE award on the key processes controlling the synthesis and structure-property relations of clathrate hydrates, which are critical to the development of clathrate hydrates as energy storage materials. Key achievements include: (i) the discovery of key clathrate hydrate building blocks (stable and metastable) leading to clathrate hydrate nucleation and growth; (ii) development of a rapid clathrate hydrate synthesis route via a seeding mechanism; (iii) synthesis-structure relations of H2 + CH4/CO2 binary hydrates to control thermodynamic requirements for energy storage and sequestration applications; (iv) discovery of a new metastable phase present during clathrate hydrate structural transitions. The success of our research to-date is demonstrated by the significant papers we have published in high impact journals, including Science, Angewandte Chemie, J. Am. Chem. Soc. Intellectual Merits of Project Accomplishments: The intellectual merits of the project accomplishments are significant and transformative, in which the fundamental coupled computational and experimental program has provided new and critical understanding on the key processes controlling the nucleation, growth, and thermodynamics of clathrate hydrates containing hydrogen, methane, carbon dioxide, and other guest molecules for energy storage. Key examples of the intellectual merits of the accomplishments include: the first discovery of the nucleation pathways and dominant stable and metastable structures leading to clathrate hydrate formation; the discovery and experimental confirmation of new metastable clathrate hydrate structures; the development of new synthesis methods for controlling clathrate hydrate formation and enclathration of molecular hydrogen. Broader Impacts of Project Accomplishments: The molecular investigations performed in this project on the synthesis (nucleation & growth)-structure-stability relations of clathrate hydrate systems are pivotal in the fundamental understanding of crystalline clathrate hydrates and the discovery of new clathrate hydrate properties and novel materials for a broad spectrum of energy applications, including: energy storage (hydrogen, natural gas); carbon dioxide sequestration; controlling hydrate formation in oil/gas transportation in subsea pipelines. The Project has also enabled the training of undergraduate, graduate and postdoctoral students in computational methods, molecular spectroscopy and diffraction, and measurement methods at extreme conditions of high pressure and low temperature.

  17. Examination of Hydrate Formation Methods: Trying to Create Representative Samples

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Rees, E.V.L.; Nakagawa, S.; Kwon, T.-H.

    2011-04-01

    Forming representative gas hydrate-bearing laboratory samples is important so that the properties of these materials may be measured, while controlling the composition and other variables. Natural samples are rare, and have often experienced pressure and temperature changes that may affect the property to be measured [Waite et al., 2008]. Forming methane hydrate samples in the laboratory has been done a number of ways, each having advantages and disadvantages. The ice-to-hydrate method [Stern et al., 1996], contacts melting ice with methane at the appropriate pressure to form hydrate. The hydrate can then be crushed and mixed with mineral grains under controlled conditions, and then compacted to create laboratory samples of methane hydrate in a mineral medium. The hydrate in these samples will be part of the load-bearing frame of the medium. In the excess gas method [Handa and Stupin, 1992], water is distributed throughout a mineral medium (e.g. packed moist sand, drained sand, moistened silica gel, other porous media) and the mixture is brought to hydrate-stable conditions (chilled and pressurized with gas), allowing hydrate to form. This method typically produces grain-cementing hydrate from pendular water in sand [Waite et al., 2004]. In the dissolved gas method [Tohidi et al., 2002], water with sufficient dissolved guest molecules is brought to hydrate-stable conditions where hydrate forms. In the laboratory, this is can be done by pre-dissolving the gas of interest in water and then introducing it to the sample under the appropriate conditions. With this method, it is easier to form hydrate from more soluble gases such as carbon dioxide. It is thought that this method more closely simulates the way most natural gas hydrate has formed. Laboratory implementation, however, is difficult, and sample formation is prohibitively time consuming [Minagawa et al., 2005; Spangenberg and Kulenkampff, 2005]. In another version of this technique, a specified quantity of gas is placed in a sample, then the sample is flooded with water and cooled [Priest et al., 2009]. We have performed a number of tests in which hydrate was formed and the uniformity of the hydrate formation was examined. These tests have primarily used a variety of modifications of the excess gas method to make the hydrate, although we have also used a version of the excess water technique. Early on, we found difficulties in creating uniform samples with a particular sand/ initial water saturation combination (F-110 Sand, {approx} 35% initial water saturation). In many of our tests we selected this combination intentionally to determine whether we could use a method to make the samples uniform. The following methods were examined: Excess gas, Freeze/thaw/form, Freeze/pressurize/thaw, Excess gas followed by water saturation, Excess water, Sand and kaolinite, Use of a nucleation enhancer (SnoMax), and Use of salt in the water. Below, each method, the underlying hypothesis, and our results are briefly presented, followed by a brief conclusion. Many of the hypotheses investigated are not our own, but were presented to us. Much of the data presented is from x-ray CT scanning our samples. The x-ray CT scanner provides a three-dimensional density map of our samples. From this map and the physics that is occurring in our samples, we are able to gain an understanding of the spatial nature of the processes that occur, and attribute them to the locations where they occur.

  18. Seismic-Scale Rock Physics of Methane Hydrate

    SciTech Connect (OSTI)

    Amos Nur

    2009-01-08

    We quantify natural methane hydrate reservoirs by generating synthetic seismic traces and comparing them to real seismic data: if the synthetic matches the observed data, then the reservoir properties and conditions used in synthetic modeling might be the same as the actual, in-situ reservoir conditions. This approach is model-based: it uses rock physics equations that link the porosity and mineralogy of the host sediment, pressure, and hydrate saturation, and the resulting elastic-wave velocity and density. One result of such seismic forward modeling is a catalogue of seismic reflections of methane hydrate which can serve as a field guide to hydrate identification from real seismic data. We verify this approach using field data from known hydrate deposits.

  19. Understanding Sectoral Labor Market Dynamics: An Equilibrium Analysis of the Oil and Gas Field Services

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    Understanding Sectoral Labor Market Dynamics: An Equilibrium Analysis of the Oil and Gas Field examines the response of employment and wages in the US oil and gas ...eld services industry to changes the dynamic response of wages and employment in the U.S. Oil and Gas Field Services (OGFS) industry to changes

  20. A Multistage Stochastic Programming Approach for the Planning of Offshore Oil or Gas Field Infrastructure

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 A Multistage Stochastic Programming Approach for the Planning of Offshore Oil or Gas Field, Houston, TX 77098 Abstract The planning of offshore oil or gas field infrastructure under uncertainty is addressed in this paper. The main uncertainties considered are in the initial maximum oil or gas flowrate

  1. Optimization of Oil Field Production Under Gas Coning Conditions Using the

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimization of Oil Field Production Under Gas Coning Conditions Using the Optimal Closed such that the gas-oil ratio (GOR) depends on the wells production rate, oil production is maximized if the marginal of individual well rates. Usually, wells produce oil, gas and water. The gas-oil ratio (GOR) becomes

  2. OPTIMAL DEVELOPMENT PLANNING OF OFFSHORE OIL AND GAS FIELD

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    development planning. Keywords Multiperiod Optimization, Planning, Offshore Oil and Gas, MINLP, MILP, FPSO

  3. Experimental and simulation studies of water-alternating-enriched gas injection for San Francisco Field, Colombia 

    E-Print Network [OSTI]

    Soto Tavera, Claudia Patricia

    2003-01-01

    This thesis presents a complete investigation involving experimental and compositional reservoir simulation studies into enriched gas injection as a method to enhance oil recovery from the San Francisco field in Colombia. In enriched gas floods...

  4. Carbon dioxide hydrate particles for ocean carbon sequestration

    E-Print Network [OSTI]

    Chow, Aaron C.

    This paper presents strategies for producing negatively buoyant CO[subscript 2] hydrate composite particles for ocean carbon sequestration. Our study is based on recent field observations showing that a continuous-jet ...

  5. Metal halogen battery system with multiple outlet nozzle for hydrate

    DOE Patents [OSTI]

    Bjorkman, Jr., Harry K. (Birmingham, MI)

    1983-06-21

    A metal halogen battery system, including at least one cell having a positive electrode and a negative electrode contacted by aqueous electrolyte containing the material of said metal and halogen, store means whereby halogen hydrate is formed and stored as part of an aqueous material, means for circulating electrolyte through the cell and to the store means, and conduit means for transmitting halogen gas formed in the cell to a hydrate former whereby the hydrate is formed in association with the store means, said store means being constructed in the form of a container which includes a filter means, said filter means being inoperative to separate the hydrate formed from the electrolyte, said system having, a hydrate former pump means associated with the store means and being operative to intermix halogen gas with aqueous electrolyte to form halogen hydrate, said hydrate former means including, multiple outlet nozzle means connected with the outlet side of said pump means and being operative to minimize plugging, said nozzle means being comprised of at least one divider means which is generally perpendicular to the rotational axes of gears within the pump means, said divider means acting to divide the flow from the pump means into multiple outlet flow paths.

  6. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, E.D. Jr.

    1995-07-11

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  7. Method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle D. (Golden, CO)

    1995-01-01

    Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

  8. Four Critical Needs to Change the Hydrate Energy Paradigm from Assessment to Production: The 2007 Report to Congress by the U.S. Federal methane Hydrate Advisory Committee

    SciTech Connect (OSTI)

    Mahajan,D.; Sloan, D.; Brewer, P.; Dutta, N.; Johnson, A.; Jones, E.; Juenger, K.; Kastner, M.; Masutani, S.; Swenson, R.; Whelan, J.; Wilson, s.; Woolsey, R.

    2009-03-11

    This work summarizes a two-year study by the U.S. Federal Methane Hydrate Advisory Committee recommending the future needs for federally-supported hydrate research. The Report was submitted to the US Congress on August 14, 2007 and includes four recommendations regarding (a) permafrost hydrate production testing, (b) marine hydrate viability assessment (c) climate effect of hydrates, and (d) international cooperation. A secure supply of natural gas is a vital goal of the U.S. national energy policy because natural gas is the cleanest and most widely used of all fossil fuels. The inherent cleanliness of natural gas, with the lowest CO2 emission per unit of heat energy of any fossil fuel, means substituting gas for coal and fuel oil will reduce emissions that can exacerbate the greenhouse effect. Both a fuel and a feedstock, a secure and reasonably priced supply of natural gas is important to industry, electric power generators, large and small commercial enterprises, and homeowners. Because each volume of solid gas hydrate contains as much as 164 standard volumes of methane, hydrates can be viewed as a concentrated form of natural gas equivalent to compressed gas but less concentrated than liquefied natural gas (LNG). Natural hydrate accumulations worldwide are estimated to contain 700,000 TCF of natural gas, of which 200,000 TCF are located within the United States. Compared with the current national annual consumption of 22 TCF, this estimate of in-place gas in enormous. Clearly, if only a fraction of the hydrated methane is recoverable, hydrates could constitute a substantial component of the future energy portfolio of the Nation (Figure 1). However, recovery poses a major technical and commercial challenge. Such numbers have sparked interest in natural gas hydrates as a potential, long-term source of energy, as well as concerns about any potential impact the release of methane from hydrates might have on the environment. Energy-hungry countries such as India and Japan are outspending the United States on hydrate science and engineering R&D by a factor of 10, and may bring this resource to market as much as a decade before the United States.

  9. Calculation of CO2 column heights in depleted gas fields from known pre-production gas column heights

    E-Print Network [OSTI]

    Wilkinson, Mark

    Calculation of CO2 column heights in depleted gas fields from known pre-production gas column that the CO2 is in a dense phase (either liquid or supercritical). Accurate assessment of the storage capacity also requires an estimation of the amount of CO2 that can be safely stored beneath the reservoir seal

  10. Hydrate-phobic Surfaces: Fundamental studies in clathrate hydrate adhesion reduction By J. David Smith, Adam J. Meuler, Harrison Bralower, Rama Venkatesan, Siva

    E-Print Network [OSTI]

    of blockages in deep-sea oil and gas operations. 1. Introduction The most recent world energy outlook predicts to greater depths. Current methods for hydrate mitigation are energy intensive and environmentally unfriendly of hydrate adhesion on smooth substrates with varying solid surface energies reveal a linear trend between

  11. EVALUATION OF MECHANICAL RELIABILITY OF SILICON NITRIDE VANES AFTER FIELD TESTS IN AN INDUSTRIAL GAS TURBINE

    E-Print Network [OSTI]

    Pennycook, Steve

    GAS TURBINE H.-T. Lin and M. K. Ferber Metals and Ceramics Division Oak Ridge National Laboratory Oak field tests in an industrial gas turbine. Two commercially available silicon nitride vanes (i.e., AS800- temperature structural components in advanced gas turbines [1-5]. These materials offer the advantages of (1

  12. Water alternating enriched gas injection to enhance oil production and recovery from San Francisco Field, Colombia 

    E-Print Network [OSTI]

    Rueda Silva, Carlos Fernando

    2003-01-01

    The main objectives of this study are to determine the most suitable type of gas for a water-alternating-gas (WAG) injection scheme, the WAG cycle time, and gas injection rate to increase oil production rate and recovery from the San Francisco field...

  13. Coiled tubing helps gas production

    SciTech Connect (OSTI)

    Matheny, S.L. Jr.

    1980-08-11

    To boost production from its gas fields in Lake Erie, Consumers' Gas Co., Toronto, used a giant reel holding a 33,000-ft coil of 1-in. polypropylene-coated steel tubing to lay about 44 miles of control lines that now service 20 wells 17 miles offshore. As the forward motion of the boat unwound the tubing, the reel rig's hydraulic motor served as a brake to maintain the proper tension. This innovative method of laying the lines eliminated more than 80% of the pipe joints, correspondingly reduced the installation labor time, and improved the system's reliability. The two hydraulic-control lines that were laid actuate the gas-gathering line valves, while a hydrate-control line injects each well with methyl alcohol to inhibit hydrate formation.

  14. Oil and Gas Field Code Master List - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural GasEIARegionalMethodologyNorth093 *Oil and Gas

  15. Solubility trapping in formation water as dominant CO2 sink in natural gas fields

    E-Print Network [OSTI]

    Haszeldine, Stuart

    LETTERS Solubility trapping in formation water as dominant CO2 sink in natural gas fields Stuart M, dissolu- tion in formation water at a pH of 5­5.8 is the sole major sink for CO2. In two fields dissolved in water. Noble gas and CO2 carbon isotopes are powerful tracers of crustal fluid processes

  16. Methane Hydrates R&D Program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on dark matter ByMentor-ProtegeFromGas Hydrates R&D Program Gas

  17. MRI of the lung gas-space at very low-field using hyperpolarized noble gases

    E-Print Network [OSTI]

    MRI of the lung gas-space at very low-field using hyperpolarized noble gases Arvind K. Venkatesha such as in the lungs. In HP gas MRI the signal-to-noise ratio (SNR) depends only weakly on the static magnetic field (B of the lungs in humans and in rats, obtained at a field of only 15 millitesla (150 Gauss). © 2003 Elsevier Inc

  18. Predicting Well Stimulation Results in a Gas Storage Field in the Absence of Reservoir Data, Using Neural Networks

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    SPE 31159 Predicting Well Stimulation Results in a Gas Storage Field in the Absence of Reservoir of this methodology to a gas storage field is presented in this paper. The developed neural network can predict for future stimulation treatment in the aforementioned field. INTRODUCTION Gas storage fields have numerous

  19. Thermal dissociation behavior and dissociation enthalpies of methane-carbon dioxide mixed hydrates

    SciTech Connect (OSTI)

    Kwon, T.H.; Kneafsey, T.J.; Rees, E.V.L.

    2011-02-15

    Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO{sub 2}) and/or production of methane (CH{sub 4}) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH{sub 4} and CO{sub 2} hydrate (CH{sub 4}-CO{sub 2} mixed hydrates), as well as thermophysical property changes during gas exchange. This study explores the thermal dissociation behavior and dissociation enthalpies of CH{sub 4}-CO{sub 2} mixed hydrates. We prepared CH{sub 4}-CO{sub 2} mixed hydrate samples from two different, well-defined gas mixtures. During thermal dissociation of a CH{sub 4}-CO{sub 2} mixed hydrate sample, gas samples from the head space were periodically collected and analyzed using gas chromatography. The changes in CH{sub 4}-CO{sub 2} compositions in both the vapor phase and hydrate phase during dissociation were estimated based on the gas chromatography measurements. It was found that the CO{sub 2} concentration in the vapor phase became richer during dissociation because the initial hydrate composition contained relatively more CO{sub 2} than the vapor phase. The composition change in the vapor phase during hydrate dissociation affected the dissociation pressure and temperature; the richer CO{sub 2} in the vapor phase led to a lower dissociation pressure. Furthermore, the increase in CO{sub 2} concentration in the vapor phase enriched the hydrate in CO{sub 2}. The dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate was computed by fitting the Clausius-Clapeyron equation to the pressure-temperature (PT) trace of a dissociation test. It was observed that the dissociation enthalpy of the CH{sub 4}-CO{sub 2} mixed hydrate lays between the limiting values of pure CH{sub 4} hydrate and CO{sub 2} hydrate, increasing with the CO{sub 2} fraction in the hydrate phase.

  20. TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media

    E-Print Network [OSTI]

    Moridis, George

    2008-01-01

    Hydrate saturation distribution in the reservoir at t = 2phase saturation distribution in the reservoir at t = 2 days12.23. Gas saturation distribution in the reservoir at t = 2

  1. TOUGH+Hydrate v1.0 User's Manual: A Code for the Simulation of System Behavior in Hydrate-Bearing Geologic Media

    SciTech Connect (OSTI)

    Moridis, George; Moridis, George J.; Kowalsky, Michael B.; Pruess, Karsten

    2008-03-01

    TOUGH+HYDRATE v1.0 is a new code for the simulation of the behavior of hydrate-bearing geologic systems. By solving the coupled equations of mass and heat balance, TOUGH+HYDRATE can model the non-isothermal gas release, phase behavior and flow of fluids and heat under conditions typical of common natural CH{sub 4}-hydrate deposits (i.e., in the permafrost and in deep ocean sediments) in complex geological media at any scale (from laboratory to reservoir) at which Darcy's law is valid. TOUGH+HYDRATE v1.0 includes both an equilibrium and a kinetic model of hydrate formation and dissociation. The model accounts for heat and up to four mass components, i.e., water, CH{sub 4}, hydrate, and water-soluble inhibitors such as salts or alcohols. These are partitioned among four possible phases (gas phase, liquid phase, ice phase and hydrate phase). Hydrate dissociation or formation, phase changes and the corresponding thermal effects are fully described, as are the effects of inhibitors. The model can describe all possible hydrate dissociation mechanisms, i.e., depressurization, thermal stimulation, salting-out effects and inhibitor-induced effects. TOUGH+HYDRATE is the first member of TOUGH+, the successor to the TOUGH2 [Pruess et al., 1991] family of codes for multi-component, multiphase fluid and heat flow developed at the Lawrence Berkeley National Laboratory. It is written in standard FORTRAN 95, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available.

  2. Electromagnetic fields and transport coefficients in a hot pion gas

    E-Print Network [OSTI]

    A. Gomez Nicola; D. Fernandez-Fraile

    2006-08-24

    We present recent results on finite temperature electromagnetic form factors and the electrical conductivity in a pion gas. The standard Chiral Perturbation Theory power counting needs to be modified for transport coefficients. We pay special attention to unitarity and to possible applications for dilepton and photon production.

  3. An evaluation of gas field rules in light of current conditions and production practices in the Panhandle non-associated gas fields

    SciTech Connect (OSTI)

    Brady, C.L.; O`Rear, C.H.

    1996-09-01

    During the early years of development in the Panhandle fields the Rule of Capture was king. Under the Rule of Capture each property owner has the right to drill as many wells as desired at any location. Adjacent property owners protect their rights by doing the same. Courts adopted the Rule of Capture to protect mineral owners from liability due to migration of oil and gas across property boundary lines. This general practice {open_quotes}to go and do likewise{close_quotes} generally leads to enormous economic and natural resource waste. Established to offset the waste created under the Rule of Capture is the doctrine of Correlative Rights. Correlative Rights is the fight of each mineral owner to obtain oil and gas from a common source of supply under lawful operations conducted from his property. However, each mineral owner has a duty to every other mineral owner not to extract oil and gas in a manner injurious to the common source of supply. This paper will examine the historical context of these common law principles with regard to the Panhandle non-associated gas fields. Discovered in 1917, the Panhandle fields are ideal to evaluate the merit of statutes and regulations enacted in response to production practices. As in many Texas fields, proration in the Panhandle fields is the primary mechanism to protect correlative rights and prevent waste. Signed and made effective May 1989, the current field rules pre-date much of the enhanced recovery techniques that use well-head vacuum compression. This paper reviews the gas rules in the 1989 Texas Railroad Commission order in light of current reservoir conditions and production practices.

  4. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Frank R. Rack

    2006-09-20

    Cooperative Agreement DE-FC26-01NT41329 between Joint Oceanographic Institutions and DOE-NETL was divided into two phases based on successive proposals and negotiated statements of work pertaining to activities to sample and characterize methane hydrates on ODP Leg 204 (Phase 1) and on IODP Expedition 311 (Phase 2). The Phase 1 Final Report was submitted to DOE-NETL in April 2004. This report is the Phase 2 Final Report to DOE-NETL. The primary objectives of Phase 2 were to sample and characterize methane hydrates using the systems and capabilities of the D/V JOIDES Resolution during IODP Expedition 311, to enable scientists the opportunity to establish the mass and distribution of naturally occurring gas and gas hydrate at all relevant spatial and temporal scales, and to contribute to the DOE methane hydrate research and development effort. The goal of the work was to provide expanded measurement capabilities on the JOIDES Resolution for a dedicated hydrate cruise to the Cascadia continental margin off Vancouver Island, British Columbia, Canada (IODP Expedition 311) so that hydrate deposits in this region would be well characterized and technology development continued for hydrate research. IODP Expedition 311 shipboard activities on the JOIDES Resolution began on August 28 and were concluded on October 28, 2005. The statement of work for this project included three primary tasks: (1) research management oversight, provided by JOI; (2) mobilization, deployment and demobilization of pressure coring and core logging systems, through a subcontract with Geotek Ltd.; and, (3) mobilization, deployment and demobilization of a refrigerated container van that will be used for degassing of the Pressure Core Sampler and density logging of these pressure cores, through a subcontract with the Texas A&M Research Foundation (TAMRF). Additional small tasks that arose during the course of the research were included under these three primary tasks in consultation with the DOE-NETL Program Manager. All tasks outlined in the original statement of work were accomplished except for the deployment and use of the X-ray CT system under Subtask 2-2. This reduction in scope provided resources that were applied to other activities to support the overall project. Post-expedition analysis of results and report writing will continue beyond this reporting period, however, all field deployments associated with this project have been successfully concluded as of this writing.

  5. Natural gas pipelines after field price decontrol : a study of risk, return and regulation

    E-Print Network [OSTI]

    Carpenter, Paul R.

    1984-01-01

    This is a study of a regulated industry undergoing rapid change. For the first time in its history, following the partial decontrol of field prices in 1978, natural gas is being priced at a level which places it in direct ...

  6. SHEAR WAVE TIME-LAPSE SEISMIC MONITORING OF A TIGHT GAS SANDSTONE RESERVOIR, RULISON FIELD, COLORADO

    E-Print Network [OSTI]

    SHEAR WAVE TIME-LAPSE SEISMIC MONITORING OF A TIGHT GAS SANDSTONE RESERVOIR, RULISON FIELD focused specifically on the use of time-lapse (4D) poststack migrated shear-wave seismic data of shear wave data as a tool for monitoring 4D changes. The basin centered tight gas sandstone reservoir

  7. Wax and hydrate control with electrical power

    SciTech Connect (OSTI)

    1997-08-01

    Electrical heating of subsea flowlines is an effective way to prevent wax and hydrate information, especially for long transportation distances and in low-temperature deep water. Systems are available for use in conjunction with bundles, pipe-in-pipe, and wet-thermal-insulation systems. These systems provide environmentally friendly fluid-temperature control without chemicals or flaring for pipeline depressurizing. Enhanced production is achieved because no time is lost by unnecessary depressurizing, pigging, heating-medium circulation, or removal of hydrate and wax blockages. The seabed temperature at 100-m and greater water depths may range from 7 to {minus}1.5 C, causing a rapid cooling of the hot well streams being transported in subsea flowlines. Under these supercooling conditions, vulnerable crude oils and multiphase compositions will deposit wax and asphalts; also the gas/water phase may freeze solid with hydrate particles. The paper discusses thermal-insulated flowlines, heat-loss compensation with electrical power, electrical power consumption and operation, and subsea electrical-power distribution system.

  8. Total Number of Existing Underground Natural Gas Storage Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan3 November18.5 385.5Dry Production (MillionTop 100 Operators:

  9. Natural Gas Liquids New Reservoir Discoveries in Old Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in NevadaYear-Month802 827 788 811 831

  10. New Field Discoveries of Dry Natural Gas Reserves

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in155DecadeFeet)VehicleYear8 0.8 0.9

  11. New Field Discoveries of Natural Gas, Wet After Lease Separation

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996) in155DecadeFeet)VehicleYear8 0.8 0.91,423

  12. Nonassociated Natural Gas New Field Discoveries, Wet After Lease Separation

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996)Price780Year JanYearFeet)19,981

  13. Nonassociated Natural Gas New Reservoir Discoveries in Old Fields, Wet

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996)Price780Year JanYearFeet)19,981After Lease

  14. Number of Existing Natural Gas Aquifers Storage Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb MarthroughFeet)Feet) YearThousand81Nuclear > U.S.43

  15. Number of Existing Natural Gas Depleted Fields Storage

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb MarthroughFeet)Feet) YearThousand81Nuclear >

  16. Number of Existing Natural Gas Salt Caverns Storage Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb MarthroughFeet)Feet) YearThousand81Nuclear >35 37

  17. Top 100 U.S. Oil and Gas Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved Reserves (BillionProduction(MillionGrossJarrett WhistanceTop

  18. Arkansas Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570MonthThousand8 0.8

  19. California Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per ThousandLease0YearExtensions

  20. Colorado Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948CaliforniaFeet)Extensions (Billion Cubic

  1. Dry Natural Gas New Reservoir Discoveries in Old Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun Jul AugAdditions1-- -- -- --WO R K1,594

  2. Dry Natural Gas New Reservoir Discoveries in Old Fields (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun Jul AugAdditions1-- -- -- --WO R K1,5942,598

  3. Dry Natural Gas Proved Reserves New Field Discoveries (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun Jul AugAdditions1-- -- -- --WO R5,0981,372 850

  4. Kentucky Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013 2014 View Historyto7EstimatedFeet) New

  5. Louisiana Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013(Million Barrels) NaturalFeet) New

  6. Mississippi Dry Natural Gas New Reservoir Discoveries in Old Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal19 1522 35 42 44 46 287 5 7 12252

  7. Mississippi Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal19 1522 35 42 44 46 287Feet) New

  8. Field Demonstration of High Efficiency Gas Heaters | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment ofOffice ofofWindUpcoming events September 3,President Barackbuildings

  9. Top 100 U.S. Oil and Gas Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight Paths30,2,8, 2015 |8Supplement from:

  10. U.S. Natural Gas Plant Field Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices Global CrudeWhat's NewBarrels,9,470 9,552

  11. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Bohrmann, Gerhard; Trehu, Anne; Storms, Michael; Schroeder, Derryl

    2002-09-30

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the deployment of tools and measurement systems on ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September, 2002. During Leg 204, we cored and logged 9 sites on the Oregon continental margin to determine the distribution and concentration of gas hydrates in an accretionary ridge and adjacent slope basin, investigate the mechanisms that transport methane and other gases into the gas hydrate stability zone (GHSZ), and obtain constraints on physical properties of hydrates in situ. A 3D seismic survey conducted in 2000 provided images of potential subsurface fluid conduits and indicated the position of the GHSZ throughout the survey region. After coring the first site, we acquired Logging-While-Drilling (LWD) data at all but one site to provide an overview of downhole physical properties. The LWD data confirmed the general position of key seismic stratigraphic horizons and yielded an initial estimate of hydrate concentration through the proxy of in situ electrical resistivity. These records proved to be of great value in planning subsequent coring. The second new hydrate proxy to be tested was infrared thermal imaging of cores on the catwalk as rapidly as possible after retrieval. The thermal images were used to identify hydrate samples and to map estimate the distribution and texture of hydrate within the cores. Geochemical analyses of interstitial waters and of headspace and void gases provide additional information on the distribution and concentration of hydrate within the stability zone, the origin and pathway of fluids into and through the GHSZ, and the rates at which the process of gas hydrate formation is occurring. Bio- and lithostratigraphic description of cores, measurement of physical properties, and in situ pressure core sampling and thermal measurements complement the data set, providing ground-truth tests of inferred physical and sedimentological properties. Among the most interesting preliminary results are: (1) the discovery that gas hydrates are distributed through a broad depth range within the GHSZ and that different physical and chemical proxies for hydrate distribution and concentration give generally consistent results; (2) evidence for the importance of sediment properties for controlling the migration of fluids in the accretionary complex; (3) geochemical indications that the gas hydrate system at Hydrate Ridge contains significant concentrations of higher order hydrocarbons and that fractionation and mixing signals will provide important constraints on gas hydrate dynamics; and (4) the discovery of very high chlorinity values that extend for at least 10 mbsf near the summit, indicating that hydrate formation here must be very rapid.

  12. MethaneHydrateRD_FC.indd

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof Methane Hydrate Program Annual Report to Congress

  13. Production of hydrocarbons from hydrates. [DOE patent application

    DOE Patents [OSTI]

    McGuire, P.L.

    1981-09-08

    An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

  14. SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN Sea Floor Methane Hydrates at Hydrate Ridge, Cascadia Margin

    E-Print Network [OSTI]

    Goldfinger, Chris

    SUESS ET AL.: SEA FLOOR METHANE HYDRATES AT HYDRATE RIDGE, CASCADIA MARGIN 1 Sea Floor Methane are exposed at the sea floor. A methane-oxidizing bacterial consortium populates the exposures of hydrate; colonies of vent macro-fauna are abundant as well. Discharge of methane from destabilized hydrate

  15. Dynamics of Protein Hydration Water

    E-Print Network [OSTI]

    M. Wolf; S. Emmert; R. Gulich; P. Lunkenheimer; A. Loidl

    2014-12-08

    We present the frequency- and temperature-dependent dielectric properties of lysozyme solutions in a broad concentration regime, measured at subzero temperatures and compare the results with measurements above the freezing point of water and on hydrated lysozyme powder. Our experiments allow examining the dynamics of unfreezable hydration water in a broad temperature range including the so-called No Man's Land (160 - 235 K). The obtained results prove the bimodality of the hydration shell dynamics and are discussed in the context of the highly-debated fragile-to-strong transition of water.

  16. Oklahoma Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear JanNew FieldDecade Year-0Year Jan FebFeet) New

  17. Flexible gas insulated transmission line having regions of reduced electric field

    DOE Patents [OSTI]

    Cookson, Alan H. (Pittsburgh, PA); Fischer, William H. (Wilkins Township, Allegheny County, PA); Yoon, Kue H. (Pittsburgh, PA); Meyer, Jeffry R. (Penn Hills Township, Allegheny County, PA)

    1983-01-01

    A gas insulated transmission line having radially flexible field control means for reducing the electric field along the periphery of the inner conductor at predetermined locations wherein the support insulators are located. The radially flexible field control means of the invention includes several structural variations of the inner conductor, wherein careful controlling of the length to depth of surface depressions produces regions of reduced electric field. Several embodiments of the invention dispose a flexible connector at the predetermined location along the inner conductor where the surface depressions that control the reduced electric field are located.

  18. Field-free alignment in repetitively kicked nitrogen gas

    SciTech Connect (OSTI)

    Cryan, James P. [PULSE Institute for Ultrafast Energy Science, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Department of Physics, Stanford University, Stanford, California 94305 (United States); Bucksbaum, Philip H. [PULSE Institute for Ultrafast Energy Science, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Department of Physics, Stanford University, Stanford, California 94305 (United States); Department of Applied Physics, Stanford University, Stanford, California 94305 (United States); Coffee, Ryan N. [PULSE Institute for Ultrafast Energy Science, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States)

    2009-12-15

    We demonstrate a high level of laser-induced transient alignment in room temperature and density N{sub 2} with a technique that avoids laser field ionization. Our measured alignment shows an improvement over previous one-pulse or two-pulse experimental alignment results and approaches the theoretical maximum value. We employ eight equally spaced ultrafast laser pulses with a separation that takes advantage of the periodic revivals for the ensemble of quantum rotors. Each successive pulse increases the transient alignment [(t)] and also moves the rotational population away from thermal equilibrium. These measurements are combined with simulations to determine the value of , the J-state distributions, and the functional dependencies of the alignment features.

  19. Response of oceanic hydrate-bearing sediments to thermalstresses

    SciTech Connect (OSTI)

    Moridis, G.J.; Kowalsky, M.B.

    2006-05-01

    In this study, we evaluate the response of oceanicsubsurface systems to thermal stresses caused by the flow of warm fluidsthrough noninsulated well systems crossing hydrate-bearing sediments.Heat transport from warm fluids, originating from deeper reservoirs underproduction, into the geologic media can cause dissociation of the gashydrates. The objective of this study is to determine whether gasevolution from hydrate dissociation can lead to excessive pressurebuildup, and possibly to fracturing of hydrate-bearing formations andtheir confining layers, with potentially adverse consequences on thestability of the suboceanic subsurface. This study also aims to determinewhether the loss of the hydrate--known to have a strong cementing effecton the porous media--in the vicinity of the well, coupled with thesignificant pressure increases, can undermine the structural stability ofthe well assembly.Scoping 1D simulations indicated that the formationintrinsic permeability, the pore compressibility, the temperature of theproduced fluids andthe initial hydrate saturation are the most importantfactors affecting the system response, while the thermal conductivity andporosity (above a certain level) appear to have a secondary effect.Large-scale simulations of realistic systems were also conducted,involving complex well designs and multilayered geologic media withnonuniform distribution of properties and initial hydrate saturationsthat are typical of those expected in natural oceanic systems. Theresults of the 2D study indicate that although the dissociation radiusremains rather limited even after long-term production, low intrinsicpermeability and/or high hydrate saturation can lead to the evolution ofhigh pressures that can threaten the formation and its boundaries withfracturing. Although lower maximum pressures are observed in the absenceof bottom confining layers and in deeper (and thus warmer and morepressurized) systems, the reduction is limited. Wellbore designs withgravel packs that allow gas venting and pressure relief result insubstantially lower pressures.

  20. Combining Multicomponent Seismic Attributes, New Rock Physics Models, and In Situ Data to Estimate Gas-Hydrate Concentrations in Deep-Water, Near-Seafloor Strata of the Gulf of Mexico

    SciTech Connect (OSTI)

    Bureau of Economic Geology

    2009-04-30

    The Bureau of Economic Geology was contracted to develop technologies that demonstrate the value of multicomponent seismic technology for evaluating deep-water hydrates across the Green Canyon area of the Gulf of Mexico. This report describes the methodologies that were developed to create compressional (P-P) and converted-shear (P-SV) images of near-seafloor geology from four-component ocean-bottom-cable (4C OBC) seismic data and the procedures used to integrate P-P and P-SV seismic attributes with borehole calibration data to estimate hydrate concentration across two study areas spanning 16 and 25 lease blocks (or 144 and 225 square miles), respectively. Approximately 200 km of two-dimensional 4C OBC profiles were processed and analyzed over the course of the 3-year project. The strategies we developed to image near-seafloor geology with 4C OBC data are unique, and the paper describing our methodology was peer-recognized with a Best Paper Award by the Society of Exploration Geophysicists in the first year of the project (2006). Among the valuable research findings demonstrated in this report, the demonstrated ability to image deep-water near-seafloor geology with sub-meter resolution using a standard-frequency (10-200 Hz) air gun array on the sea surface and 4C sensors on the seafloor has been the accomplishment that has received the most accolades from professional peers. Our study found that hydrate is pervasive across the two study areas that were analyzed but exists at low concentrations. Although our joint inversion technique showed that in some limited areas, and in some geologic units across those small areas, hydrates occupied up to 40-percent of the sediment pore space, we found that when hydrate was present, hydrate concentration tended to occupy only 10-percent to 20-percent of the pore volume. We also found that hydrate concentration tended to be greater near the base of the hydrate stability zone than it was within the central part of the stability zone.

  1. Gravity Control by means of Electromagnetic Field through Gas or Plasma at Ultra-Low Pressure

    E-Print Network [OSTI]

    Fran De Aquino

    2013-12-02

    It is shown that the gravity acceleration just above a chamber filled with gas or plasma at ultra-low pressure can be strongly reduced by applying an Extra Low-Frequency (ELF) electromagnetic field across the gas or the plasma. This Gravitational Shielding Effect is related to recent discovery of quantum correlation between gravitational mass and inertial mass. According to the theory samples hung above the gas or the plasma should exhibit a weight decrease when the frequency of the electromagnetic field is decreased or when the intensity of the electromagnetic field is increased. This Gravitational Shielding Effect is unprecedented in the literature and can not be understood in the framework of the General Relativity. From the technical point of view, there are several applications for this discovery; possibly it will change the paradigms of energy generation, transportation and telecommunications.

  2. Variability of the methane trapping in martian subsurface clathrate hydrates

    E-Print Network [OSTI]

    Caroline Thomas; Olivier Mousis; Sylvain Picaud; Vincent Ballenegger

    2008-10-23

    Recent observations have evidenced traces of methane CH4 heterogeneously distributed in the martian atmosphere. However, because the lifetime of CH4 in the atmosphere of Mars is estimated to be around 300-600 years on the basis of photochemistry, its release from a subsurface reservoir or an active primary source of methane have been invoked in the recent literature. Among the existing scenarios, it has been proposed that clathrate hydrates located in the near subsurface of Mars could be at the origin of the small quantities of the detected CH4. Here, we accurately determine the composition of these clathrate hydrates, as a function of temperature and gas phase composition, by using a hybrid statistical thermodynamic model based on experimental data. Compared to other recent works, our model allows us to calculate the composition of clathrate hydrates formed from a more plausible composition of the martian atmosphere by considering its main compounds, i.e. carbon dioxyde, nitrogen and argon, together with methane. Besides, because there is no low temperature restriction in our model, we are able to determine the composition of clathrate hydrates formed at temperatures corresponding to the extreme ones measured in the polar caps. Our results show that methane enriched clathrate hydrates could be stable in the subsurface of Mars only if a primitive CH4-rich atmosphere has existed or if a subsurface source of CH4 has been (or is still) present.

  3. UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Environmental assessment of deep-water sponge fields in relation to oil and gas

    E-Print Network [OSTI]

    Henderson, Gideon

    UK Oil and Gas Collaborative Doctoral Training Centre (2014 start) Project Title: Environmental assessment of deep-water sponge fields in relation to oil and gas activity: a west of Shetland case study industry and government identified sponge grounds in areas of interest to the oil and gas sector

  4. Variations in dissolved gas compositions of reservoir fluids from the Coso geothermal field

    SciTech Connect (OSTI)

    Williams, Alan E.; Copp, John F.

    1991-01-01

    Gas concentrations and ratios in 110 analyses of geothermal fluids from 47 wells in the Coso geothermal system illustrate the complexity of this two-phase reservoir in its natural state. Two geographically distinct regions of single-phase (liquid) reservoir are present and possess distinctive gas and liquid compositions. Relationships in soluble and insoluble gases preclude derivation of these waters from a common parent by boiling or condensation alone. These two regions may represent two limbs of fluid migration away from an area of two-phase upwelling. During migration, the upwelling fluids mix with chemically evolved waters of moderately dissimilar composition. CO{sub 2} rich fluids found in the limb in the southeastern portion of the Coso field are chemically distinct from liquids in the northern limb of the field. Steam-rich portions of the reservoir also indicate distinctive gas compositions. Steam sampled from wells in the central and southwestern Coso reservoir is unusually enriched in both H{sub 2}S and H{sub 2}. Such a large enrichment in both a soluble and insoluble gas cannot be produced by boiling of any liquid yet observed in single-phase portions of the field. In accord with an upflow-lateral mixing model for the Coso field, at least three end-member thermal fluids having distinct gas and liquid compositions appear to have interacted (through mixing, boiling and steam migration) to produce the observed natural state of the reservoir.

  5. Two-dimensional electron gas in a linearly varying magnetic field: Quantization of the electron and current density

    E-Print Network [OSTI]

    MacKinnon, Angus

    Two-dimensional electron gas in a linearly varying magnetic field: Quantization of the electron of electron and current densities. We investigate the case where the magnetic field varies linearly properties of a noninteracting electron gas in a linearly varying magnetic field, we consider the following

  6. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeabilitymore »measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction « less

  7. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    with Logging While Drilling (LWD) 7.3.3 Comparison with MTlogging while drilling (LWD) data from Ocean Drillingat depth as compared xvii to the LWD. An overlay of the CSEM

  8. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    with Logging While Drilling (LWD) 7.3.3 Comparison with MTlogging while drilling (LWD) data from Ocean Drillingat depth as compared xvii to the LWD. An overlay of the CSEM

  9. Marine Electromagnetic Methods for Gas Hydrate Characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen A

    2008-01-01

    possible by funding from Exxon Mobil and GERD, Japan. I wishvery limited funding from Exxon Mobil and from GERD, Japan

  10. Marine electromagnetic methods for gas hydrate characterization

    E-Print Network [OSTI]

    Weitemeyer, Karen Andrea

    2008-01-01

    possible by funding from Exxon Mobil and GERD, Japan. I wishvery limited funding from Exxon Mobil and from GERD, Japan

  11. ,"Natural Gas Plant Field Production: Natural Gas Liquids "

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterMonthly","10/2015" ,"ReleaseVolumeVolume (MMcf)" ,"Click worksheet name orVolumeField Production:

  12. Dry gas zone, Elk Hills Field, Kern County, California: General reservoir study: Engineering data, effective August 1, 1988

    SciTech Connect (OSTI)

    Not Available

    1989-01-10

    This reservoir study of the dry gas zone of Elk Hills Field is a data compilation with information relating to well: completion; production; pressure; and back pressure. (JF)

  13. Exemptions from OSHA`s PSM rule oil and gas field production

    SciTech Connect (OSTI)

    West, H.H. [Shawnee Engineers, Houston, TX (United States); Landes, S. [SH Landes, Houston, TX (United States)

    1995-12-31

    The OSHA Process Safety Management (PSM) regulation, OSHA 1910.119, contains a number of exemptions which are specifically directed to the low hazard situations typically found in the field production facilities of the oil and gas industry. Each relevant PSM exemption is discussed with particular regard to the requirements of hydrocarbon production facilities.

  14. 3-DIMENSIONAL GEOMECHANICAL MODELING OF A TIGHT GAS RESERVOIR, RULISON FIELD, PICEANCE BASIN, COLORADO

    E-Print Network [OSTI]

    3-DIMENSIONAL GEOMECHANICAL MODELING OF A TIGHT GAS RESERVOIR, RULISON FIELD, PICEANCE BASIN, COLORADO by Kurtis R. Wikel #12;ii #12;iii ABSTRACT An integrated 3-dimensional geomechanical model have used the predictive geomechanical model to compare production and effective stress change

  15. Equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride

    SciTech Connect (OSTI)

    Majumdar, A.; Mahmoodaghdam, E.; Bishnoi, P.R.

    2000-02-01

    Natural gas components such as hydrogen sulfide, carbon dioxide, and ethane form gas hydrates of structure I under suitable temperature and pressure conditions. Information on such conditions is vital to the oil and gas industry in order to design and operate processing equipment and pipelines so that hydrate formation is avoided. Incipient equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride were experimentally obtained in the temperature range 264--290 K and the pressure range 0.23--3.18 MPa. A variable-volume sapphire cell was used for the measurements.

  16. Scaling law for direct current field emission-driven microscale gas breakdown

    SciTech Connect (OSTI)

    Venkattraman, A.; Alexeenko, A. A.

    2012-12-15

    The effects of field emission on direct current breakdown in microscale gaps filled with an ambient neutral gas are studied numerically and analytically. Fundamental numerical experiments using the particle-in-cell/Monte Carlo collisions method are used to systematically quantify microscale ionization and space-charge enhancement of field emission. The numerical experiments are then used to validate a scaling law for the modified Paschen curve that bridges field emission-driven breakdown with the macroscale Paschen law. Analytical expressions are derived for the increase in cathode electric field, total steady state current density, and the ion-enhancement coefficient including a new breakdown criterion. It also includes the effect of all key parameters such as pressure, operating gas, and field-enhancement factor providing a better predictive capability than existing microscale breakdown models. The field-enhancement factor is shown to be the most sensitive parameter with its increase leading to a significant drop in the threshold breakdown electric field and also to a gradual merging with the Paschen law. The proposed scaling law is also shown to agree well with two independent sets of experimental data for microscale breakdown in air. The ability to accurately describe not just the breakdown voltage but the entire pre-breakdown process for given operating conditions makes the proposed model a suitable candidate for the design and analysis of electrostatic microscale devices.

  17. HYDRATE RESEARCH ACTIVITIES THAT BOTH SUPPORT AND DERIVE FROM THE MONITORING STATION/SEA-FLOOR OBSERVATORY, MISSISSIPPI CANYON 118, NORTHERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Lutken, Carol

    2013-07-31

    A permanent observatory has been installed on the seafloor at Federal Lease Block, Mississippi Canyon 118 (MC118), northern Gulf of Mexico. Researched and designed by the Gulf of Mexico Hydrates Research Consortium (GOM-HRC) with the geological, geophysical, geochemical and biological characterization of in situ gas hydrates systems as the research goal, the site has been designated by the Bureau of Ocean Energy Management as a permanent Research Reserve where studies of hydrates and related ocean systems may take place continuously and cooperatively into the foreseeable future. The predominant seafloor feature at MC118 is a carbonate-hydrate complex, officially named Woolsey Mound for the founder of both the GOM-HRC and the concept of the permanent seafloor hydrates research facility, the late James Robert “Bob” Woolsey. As primary investigator of the overall project until his death in mid-2008, Woolsey provided key scientific input and served as chief administrator for the Monitoring Station/ Seafloor Observatory (MS-SFO). This final technical report presents highlights of research and accomplishments to date. Although not all projects reached the status originally envisioned, they are all either complete or positioned for completion at the earliest opportunity. All Department of Energy funds have been exhausted in this effort but, in addition, leveraged to great advantage with additional federal input to the project and matched efforts and resources. This report contains final reports on all subcontracts issued by the University of Mississippi, Administrators of the project, Hydrate research activities that both support and derive from the monitoring station/sea-floor Observatory, Mississippi Canyon 118, northern Gulf of Mexico, as well as status reports on the major components of the project. All subcontractors have fulfilled their primary obligations. Without continued funds designated for further project development, the Monitoring Station/Seafloor Observatory is in danger of lapsing into disuse. However, for the present, interest in the site on the continental slope is healthy and The Center for Marine Resources and Environmental Technology continues to coordinate all activity at the MS/SFO as arranged through the BOEM in 2005. Field and laboratory research projects and findings are reviewed, new technologies and tests described. Many new sensors, systems and two custom ROVs have been developed specifically for this project. Characteristics of marine gas hydrates are dramatically more refined than when the project was initiated and include appear in sections entitled Accomplishments, Products and Publications.

  18. Hydration water dynamics and instigation of protein structuralrelaxation

    SciTech Connect (OSTI)

    Russo, Daniela; Hura, Greg; Head-Gordon, Teresa

    2003-09-01

    Until a critical hydration level is reached, proteins do not function. This critical level of hydration is analogous to a similar lack of protein function observed for temperatures below a dynamical temperature range of 180-220K that also is connected to the dynamics of protein surface water. Restoration of some enzymatic activity is observed in partially hydrated protein powders, sometimes corresponding to less than a single hydration layer on the protein surface, which indicates that the dynamical and structural properties of the surface water is intimately connected to protein stability and function. Many elegant studies using both experiment and simulation have contributed important information about protein hydration structure and timescales. The molecular mechanism of the solvent motion that is required to instigate the protein structural relaxation above a critical hydration level or transition temperature has yet to be determined. In this work we use experimental quasi-elastic neutron scattering (QENS) and molecular dynamics simulation to investigate hydration water dynamics near a greatly simplified protein system. We consider the hydration water dynamics near the completely deuterated N-acetyl-leucine-methylamide (NALMA) solute, a hydrophobic amino acid side chain attached to a polar blocked polypeptide backbone, as a function of concentration between 0.5M-2.0M under ambient conditions. We note that roughly 50-60% of a folded protein's surface is equally distributed between hydrophobic and hydrophilic domains, domains whose lengths are on the order of a few water diameters, that justify our study of hydration dynamics of this simple model protein system. The QENS experiment was performed at the NIST Center for Neutron Research, using the disk chopper time of flight spectrometer (DCS). In order to separate the translational and rotational components in the spectra, two sets of experiments were carried out using different incident neutron wavelengths of 7.5{angstrom} and 5.5{angstrom} to give two different time resolutions. All the spectra have been measure at room temperature. The spectra were corrected for the sample holder contribution and normalized using the vanadium standard. The resulting data were analyzed with DAVE programs (http://www.ncnr.nist.gov/dave/). The AMBER force field and SPCE water model were used for modeling the NALMA solute and water, respectively. For the analysis of the water dynamics in the NALMA aqueous solutions, we performed simulations of a dispersed solute configuration consistent with our previous structural analysis, where we had primarily focused on the structural organization of these peptide solutions and their connection to protein folding. Further details of the QENS experiment and molecular dynamics simulations are reported elsewhere.

  19. Kinetics of Methane Hydrate Decomposition Studied via in Situ Low Temperature X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Everett, Susan M; Rawn, Claudia J; Keffer, David J.; Mull, Derek L; Payzant, E Andrew; Phelps, Tommy Joe

    2013-01-01

    Gas hydrates are known to have a slowed decomposition rate at ambient pressure and temperatures below the melting point of ice termed self-preservation or anomalous preservation. As hydrate exothermically decomposes, gas is released and water of the clathrate cages transforms into ice. Two regions of slowed decomposition for methane hydrate, 180 200 K and 230 260 K, were observed, and the kinetics were studied by in situ low temperature x-ray powder diffraction. The kinetic constants for ice formation from methane hydrate were determined by the Avrami model within each region and activation energies, Ea, were determined by the Arrhenius plot. Ea determined from the data for 180 200 K was 42 kJ/mol and for 230 260 K was 22 kJ/mol. The higher Ea in the colder temperature range was attributed to a difference in the microstructure of ice between the two regions.

  20. Solubility of Hematite Revisited: Effects of Hydration

    E-Print Network [OSTI]

    Burgos, William

    immediately after synthesis, but [Fe(III)diss] increased with hydration time to be consistent with the predicted solubility of goethite or hydrous ferric oxide (HFO), hydrated analogues of hematite. X an equilibrium with goethite or HFO. This is the first experimental confirmation that the interfacial hydration

  1. Multipole Electrostatics in Hydration Free Energy Calculations

    E-Print Network [OSTI]

    Ponder, Jay

    Multipole Electrostatics in Hydration Free Energy Calculations YUE SHI,1 CHUANJIE WU,2 JAY W: Hydration free energy (HFE) is generally used for evaluating molecular solubility, which is an important interactions. The effect of long-range correction to van der Waals interaction on the hydration free energies

  2. Natural gas cofiring in a refuse derived fuel incinerator: Results of a field evaluation. Topical report

    SciTech Connect (OSTI)

    Beshai, R.Z.; Hong, C.C.

    1993-10-01

    An evaluation of emissions reduction and improved operation of a municipal solid waste incinerator through natural gas cofiring is presented. A natural gas cofiring system was retrofitted on a refuse derived fuel combustor of the Columbis Solid Waste Reduction Facility in Columbus, Ohio. The field evaluation, conducted between July 6 and August 5, 1992, showed significant improvements in emissions and boiler operations. Carbon monoxide emissions were reduced from the baseline operations range of 530 to 1,950 parts per million to less than 50 ppm. Emissions of carbon dioxide, sulfur dioxide, hydrocarbons, and polychlorinated dibenzo-p-dioxins and furans were also reduced.

  3. Florida Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun20032,485,331Gas2001Year JanNew Field

  4. Wyoming Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural Gas Reserves Adjustments (Billion Cubic Feet)New Field

  5. Ion Species and Charge States of Vacuum Arc Plasma with Gas Feed and Longitudinal Magnetic Field

    SciTech Connect (OSTI)

    Oks, Efim; Anders, Andre

    2010-06-23

    The evolution of copper ion species and charge state distributions is measured for a long vacuum arc discharge plasma operated in the presence of a longitudinal magnetic field of several 10 mT and working gas (Ar). It was found that changing the cathode-anode distance within 20 cm as well as increasing the gas pressure did not affect the arc burning voltage and power dissipation by much. In contrast, burning voltage and power dissipation were greatly increased as the magnetic field was increased. The longer the discharge gap the greater was the fraction of gaseous ions and the lower the fraction of metal ions, while the mean ion charge state was reduced. It is argued that the results are affected by charge exchange collisions and electron impact ionization.

  6. Power spectrum in the Chaplygin gas model: tachyonic, fluid and scalar field representations

    E-Print Network [OSTI]

    C. E. M. Batista; J. C. Fabris; M. Morita

    2009-04-24

    The Chaplygin gas model, characterized by an equation of state of the type $p = - \\frac{A}{\\rho}$ emerges naturally from the Nambu-Goto action of string theory. This fluid representation can be recast under the form of a tachyonic field given by a Born-Infeld type Lagrangian. At the same time, the Chaplygin gas equation of state can be obtained from a self-interacting scalar field. We show that, from the point of view of the supernova type Ia data, the three representations (fluid, tachyonic, scalar field) lead to the same results. However, concerning the matter power spectra, while the fluid and tachyonic descriptions lead to exactly the same results, the self-interacting scalar field representation implies different statistical estimations for the parameters. In particular, the estimation for the dark matter density parameter in the fluid representation favors a universe dominated almost completely by dark matter, while in the self-interacting scalar field representation the prediction is very closed to that obtained in the $\\Lambda$CDM model.

  7. Application of the Split Hopkinson Resonant Bar Test for Seismic Property Characterization of Hydrate-bearing Sand Undergoing Water Saturation

    E-Print Network [OSTI]

    Nakagawa, S.

    2012-01-01

    exploration, it is essential to understand the seismicSEISMIC SIGNATURES OF METHANE HYDRATE FORMATION WITHIN PARTIALLY SATURATED SEDIMENT For assuring seafloor stability during off-shore oil and gas exploration

  8. X-ray computed-tomography observations of water flow through anisotropic methane hydrate-bearing sand

    E-Print Network [OSTI]

    Seol, Yongkoo

    2010-01-01

    of gas hydrate-bearing sand. J. Geophys. Res. 110 (B01311).in a partially saturated sand, The 229th ACS NationalScale Partially Saturated Sand Sample, Journal of Petroleum

  9. favorable equilibrium with the atmospheric reservoir. Formation of a hydrate is but one

    E-Print Network [OSTI]

    Cohen, Ronald C.

    to a set of valves and fittings, which permitted loading of the cylinder with liquid CO2 from standard gas. Maier-Reimer, Geophys. Res. Lett. 24, 405 (1997). 8. E. D. Sloan Jr., Clathrate Hydrates of Natural pounds per square inch (psi) was observed, with the piston set at maximum accumulator capacity. The gas

  10. Hadron resonance gas and mean-field nuclear matter for baryon number fluctuations

    E-Print Network [OSTI]

    Kenji Fukushima

    2014-09-09

    We give an estimate for the skewness and the kurtosis of the baryon number distribution in two representative models; i.e., models of a hadron resonance gas and relativistic mean-field nuclear matter. We emphasize formal similarity between these two descriptions. The hadron resonance gas leads to a deviation from the Skellam distribution if quantum statistical correlation is taken into account at high baryon density, but this effect is not strong enough to explain fluctuation data seen in the beam-energy scan at RHIC/STAR. In the calculation of mean-field nuclear matter the density correlation with the vector \\omega-field rather than the effective mass with the scalar \\sigma-field renders the kurtosis suppressed at higher baryon density so as to account for the experimentally observed behavior of the kurtosis. We finally discuss the difference between the baryon number and the proton number fluctuations from correlation effects in isospin space. Our numerical results suggest that such effects are only minor even in the case of complete randomization of isospin.

  11. Hadron resonance gas and mean-field nuclear matter for baryon number fluctuations

    E-Print Network [OSTI]

    Kenji Fukushima

    2015-08-30

    I give an estimate for the skewness and the kurtosis of the baryon number distribution in two representative models; i.e., models of a hadron resonance gas and relativistic mean-field nuclear matter. I emphasize formal similarity between these two descriptions. The hadron resonance gas leads to a deviation from the Skellam distribution if quantum statistical correlation is taken into account at high baryon density, but this effect is not strong enough to explain fluctuation data seen in the beam-energy scan at RHIC/STAR. In the calculation of mean-field nuclear matter the density correlation with the vector $\\omega$-field rather than the effective mass with the scalar $\\sigma$-field renders the kurtosis suppressed at higher baryon density so as to account for the experimentally observed behavior of the kurtosis. We finally discuss the difference between the baryon number and the proton number fluctuations from correlation effects in isospin space. The numerical results suggest that such effects are only minor even in the case of complete randomization of isospin.

  12. Influence of spatially varying pseudo-magnetic field on a 2D electron gas in graphene

    E-Print Network [OSTI]

    L. G. da Silva Leite; D. Cogollo; C. Filgueiras; Edilberto O. Silva

    2015-01-28

    The effect of a varying pseudo-magnetic field, which falls as $1/x^2$, on a two dimensional electron gas in graphene is investigated. By considering the second order Dirac equation, we show that its correct general solution is that which might present singular wavefunctions since such field induced by elastic deformations diverges as $x\\rightarrow0$. We show that only this consideration yields the known relativistic Landau levels when we remove such elastic field. We have observed that the zero Landau level fails to develop for certain values of it. We then speculate about the consequences of these facts to the quantum Hall effect on graphene. We also analyze the changes in the relativistic cyclotron frequency. We hope our work being probed in these contexts, since graphene has great potential for electronic applications.

  13. CFD Simulation of 3D Flow field in a Gas Centrifuge

    SciTech Connect (OSTI)

    Dongjun Jiang; Shi Zeng

    2006-07-01

    A CFD method was used to study the whole flow field in a gas centrifuge. In this paper, the VSM (Vector Splitting Method) of the FVM (Finite Volume Method) was used to solve the 3D Navier-Stokes equations. An implicit second-order upwind scheme was adopted. The numerical simulation was successfully performed on a parallel cluster computer and a convergence result was obtained. The simulation shows that: in the withdrawal chamber, a strong detached shock wave is formed in front of the scoop; as the radial position increases, the shock becomes stronger and the distance to scoop front surface is smaller. An oblique shock forms in the clearance between the scoop and the centrifuge wall; behind the shock-wave, the radially-inward motion of gas is induced because of the imbalance of the pressure gradient and the centrifugal force. In the separation chamber, a countercurrent is introduced. This indicates that CFD method can be used to study the complex three-dimensional flow field of gas centrifuges. (authors)

  14. IN-SITU SAMPLING AND CHARACTERIZATION OF NATURALLY OCCURRING MARINE METHANE HYDRATE USING THE D/V JOIDES RESOLUTION

    SciTech Connect (OSTI)

    Rack, Frank R.; Dickens, Gerald; Ford, Kathryn; Schroeder, Derryl; Storms, Michael

    2002-08-01

    The primary accomplishment of the JOI Cooperative Agreement with DOE/NETL in this quarter was the preparation of tools and measurement systems for deployment, testing and use on ODP Leg 204, which will study hydrate deposits on Hydrate Ridge, offshore Oregon. Additional accomplishments were related to the postcruise evaluation of tools and measurements systems used on ODP Leg 201 along the Peru margin from January through March, 2002. The operational results from the use of the Pressure Core Sampler (PCS) tool and the PCS Gas Manifold on ODP Leg 201 are evaluated in this progress report in order to prepare for the upcoming deployments on ODP Leg 204 in July, 2002. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane gas hydrates. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, was also deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at three shallow-water sites located offshore Peru. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The testing of these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively during ODP Leg 201. The data obtained from the successful deployments of these tools is still being evaluated by the scientists and engineers involved in this testing; however, preliminary results are presented in this report. An infrared-thermal imaging system (IR-TIS) was deployed for the first time on ODP Leg 201. This system was used to identify methane hydrate intervals in the recovered cores. Initial discussions of these experiments are provided in this report. This report is an overview of the field measurements made on recovered sediment cores and the downhole measurements made during ODP Leg 201. These results are currently being used to incorporate the ''lessons learned'' from these deployments to prepare for a dedicated ODP leg to study the characteristics of naturally-occurring hydrates in the subsurface environment of Hydrate Ridge, offshore Oregon during ODP Leg 204, which will take place from July through September, 2002.

  15. Use of oil-emulsion mud in the Sivells Bend Field: Gas and gas condensate operations for the independent producer. 

    E-Print Network [OSTI]

    Echols, Walter Harlan

    1954-01-01

    ago: A company was buying casing head gas for gasoline extraction and selling high pressure residue gas for gas lift purposes. The purchaser of the residue gas was billed for what appeared to be an excessive amount of gas over a period of sevex'al... of processing contracts. The early processing contraots used ln gas condensate operations wexe patterned after the old NGAA Caslnghead Gasoline Contract, whexeln the producer's portion of the liquids amounted to 20 to 3g 1/3 percent of the tested liquid...

  16. Additives and method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.

    1997-06-17

    Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

  17. Additives and method for controlling clathrate hydrates in fluid systems

    DOE Patents [OSTI]

    Sloan, Jr., Earle Dendy (Golden, CO); Christiansen, Richard Lee (Littleton, CO); Lederhos, Joseph P. (Wheatridge, CO); Long, Jin Ping (Dallas, TX); Panchalingam, Vaithilingam (Lakewood, CO); Du, Yahe (Golden, CO); Sum, Amadeu Kun Wan (Golden, CO)

    1997-01-01

    Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

  18. Semi-flexible gas-insulated transmission line using electric field stress shields

    DOE Patents [OSTI]

    Cookson, Alan H. (Churchill Borough, PA); Dale, Steinar J. (Monroeville, PA); Bolin, Philip C. (Wilkins Township, Allegheny County, PA)

    1982-12-28

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by use of main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. The flexing elements and the stress shields may also be utilized in connection with a plug and socket arrangement for providing electrical connection between main conductor sections.

  19. Semi-flexible gas-insulated transmission line using electric field stress shields

    DOE Patents [OSTI]

    Cookson, A.H.; Dale, S.J.; Bolin, P.C.

    1982-12-28

    A gas-insulated transmission line includes an outer sheath, an inner conductor, an insulating gas electrically insulating the inner conductor from the outer sheath, and insulating supports insulatably supporting the inner conductor within the outer sheath. The inner conductor is provided with flexibility by use of main conductor sections which are joined together through a conductor hub section and flexible flexing elements. Stress shields are provided to control the electric field at the locations of the conductor hub sections where the insulating supports are contacting the inner conductor. The flexing elements and the stress shields may also be utilized in connection with a plug and socket arrangement for providing electrical connection between main conductor sections. 10 figs.

  20. Geomechanical Performance of Hydrate-Bearing Sediments in Offshore Environments

    SciTech Connect (OSTI)

    Stephen A. Holditch

    2006-12-31

    The main objective of this study is to develop the necessary knowledge base and quantitative predictive capability for the description of geomechanical performance of hydrate bearing sediments (hereafter referred to as HBS) in oceanic environments. The focus is on the determination of the envelope of hydrate stability under conditions typical of those related to the construction and operation of offshore platforms. To achieve this objective, we have developed a robust numerical simulator of hydrate behavior in geologic media by coupling a reservoir model with a commercial geomechanical code. To be sure our geomechanical modeling is realistic, we are also investigating the geomechanical behavior of oceanic HBS using pore-scale models (conceptual and mathematical) of fluid flow, stress analysis, and damage propagation. In Phase II of the project, we will review all published core data and generate additional core data to verify the models. To generate data for our models, we are using data from the literature and we will be conducting laboratory studies in 2007 that generate data to (1) evaluate the conceptual pore-scale models, (2) calibrate the mathematical models, (3) determine dominant relations and critical parameters defining the geomechanical behavior of HBS, and (4) establish relationships between the geomechanical status of HBS and the corresponding geophysical signature. The milestones for Phase I of this project are given as follows: Literature survey on typical sediments containing gas hydrates in the ocean (TAMU); Recommendations on how to create typical sediments in the laboratory (TAMU); Demonstrate that typical sediments can be created in a repeatable manner in the laboratory and gas hydrates can be created in the pore space (TAMU); Develop a conceptual pore-scale model based on available data and reports (UCB); Test the developed pore-scale concepts on simple configurations and verify the results against known measurements and observations (UCB); Complete the FLAC3D routines that will be linked with the reservoir model (LBNL); Complete the TOUGH+/HYDRATE modifications and extensions (LBNL); Complete the TOUGH+/FLAC3D interaction interface (LBNL); Integrate and test the coupled geomechanical numerical model TFxH/FLAC3D (LBNL); and Demonstrate that Petrel can be used to develop an earth model for providing data to the TOUGH+/FLAC3D (SLB).

  1. ADVANCED FRACTURING TECHNOLOGY FOR TIGHT GAS: AN EAST TEXAS FIELD DEMONSTRATION

    SciTech Connect (OSTI)

    Mukul M. Sharma

    2005-03-01

    The primary objective of this research was to improve completion and fracturing practices in gas reservoirs in marginal plays in the continental United States. The Bossier Play in East Texas, a very active tight gas play, was chosen as the site to develop and test the new strategies for completion and fracturing. Figure 1 provides a general location map for the Dowdy Ranch Field, where the wells involved in this study are located. The Bossier and other tight gas formations in the continental Unites States are marginal plays in that they become uneconomical at gas prices below $2.00 MCF. It was, therefore, imperative that completion and fracturing practices be optimized so that these gas wells remain economically attractive. The economic viability of this play is strongly dependent on the cost and effectiveness of the hydraulic fracturing used in its well completions. Water-fracs consisting of proppant pumped with un-gelled fluid is the type of stimulation used in many low permeability reservoirs in East Texas and throughout the United States. The use of low viscosity Newtonian fluids allows the creation of long narrow fractures in the reservoir, without the excessive height growth that is often seen with cross-linked fluids. These low viscosity fluids have poor proppant transport properties. Pressure transient tests run on several wells that have been water-fractured indicate a long effective fracture length with very low fracture conductivity even when large amounts of proppant are placed in the formation. A modification to the water-frac stimulation design was needed to transport proppant farther out into the fracture. This requires suspending the proppant until the fracture closes without generating excessive fracture height. A review of fracture diagnostic data collected from various wells in different areas (for conventional gel and water-fracs) suggests that effective propped lengths for the fracture treatments are sometimes significantly shorter than those predicted by fracture models. There was no accepted optimal method for conducting hydraulic fracturing in the Bossier. Each operator used a different approach. Anadarko, the most active operator in the play, had tested at least four different kinds of fracture treatments. The ability to arrive at an optimal fracturing program was constrained by the lack of adequate fracture models to simulate the fracturing treatment, and an inability to completely understand the results obtained in previous fracturing programs. This research aimed at a combined theoretical, experimental and field-testing program to improve fracturing practices in the Bossier and other tight gas plays.

  2. Gas field ion source current stability for trimer and single atom terminated W(111) tips

    SciTech Connect (OSTI)

    Urban, Radovan; Wolkow, Robert A. [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2G7 (Canada); National Institute for Nanotechnology, National Research Council of Canada, Edmonton, Alberta T6G 2M9 (Canada); Pitters, Jason L. [National Institute for Nanotechnology, National Research Council of Canada, Edmonton, Alberta T6G 2M9 (Canada)

    2012-06-25

    Tungsten W(111) oriented trimer-terminated tips as well as single atom tips, fabricated by a gas and field assisted etching and evaporation process, were investigated with a view to scanning ion microscopy and ion beam writing applications. In particular, ion current stability was studied for helium and neon imaging gases. Large ion current fluctuations from individual atomic sites were observed when a trimer-terminated tip was used for the creation of neon ion beam. However, neon ion current was stable when a single atom tip was employed. No such current oscillations were observed for either a trimer or a single atom tip when imaged with helium.

  3. U.S. Natural Gas Plant Liquids, Reserves New Field Discoveries (Million

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData2009 2010Year Jan FebBarrels) New Field

  4. Alabama Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade Year-0Cubic(Million CubicWorkingNew Field Discoveries

  5. Alaska Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570 2,304 1,670Same0New Field Discoveries

  6. Montana Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal19FuelYear5) Model37 64New Field

  7. Characterization of the reactive flow field dynamics in a gas turbine injector using high frequency PIV

    E-Print Network [OSTI]

    Barbosa, Séverine; Ducruix, Sébastien

    2008-01-01

    The present work details the analysis of the aerodynamics of an experimental swirl stabilized burner representative of gas turbine combustors. This analysis is carried out using High Frequency PIV (HFPIV) measurements in a reactive situation. While this information is usually available at a rather low rate, temporally resolved PIV measurements are necessary to better understand highly turbulent swirled flows, which are unsteady by nature. Thanks to recent technical improvements, a PIV system working at 12 kHz has been developed to study this experimental combustor flow field. Statistical quantities of the burner are first obtained and analyzed, and the measurement quality is checked, then a temporal analysis of the velocity field is carried out, indicating that large coherent structures periodically appear in the combustion chamber. The frequency of these structures is very close to the quarter wave mode of the chamber, giving a possible explanation for combustion instability coupling.

  8. Enhanced Generic Phase-field Model of Irradiation Materials: Fission Gas Bubble Growth Kinetics in Polycrystalline UO2

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2012-05-30

    Experiments show that inter-granular and intra-granular gas bubbles have different growth kinetics which results in heterogeneous gas bubble microstructures in irradiated nuclear fuels. A science-based model predicting the heterogeneous microstructure evolution kinetics is desired, which enables one to study the effect of thermodynamic and kinetic properties of the system on gas bubble microstructure evolution kinetics and morphology, improve the understanding of the formation mechanisms of heterogeneous gas bubble microstructure, and provide the microstructure to macroscale approaches to study their impact on thermo-mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking. In our previous report 'Mesoscale Benchmark Demonstration, Problem 1: Mesoscale Simulations of Intra-granular Fission Gas Bubbles in UO2 under Post-irradiation Thermal Annealing', we developed a phase-field model to simulate the intra-granular gas bubble evolution in a single crystal during post-irradiation thermal annealing. In this work, we enhanced the model by incorporating thermodynamic and kinetic properties at grain boundaries, which can be obtained from atomistic simulations, to simulate fission gas bubble growth kinetics in polycrystalline UO2 fuels. The model takes into account of gas atom and vacancy diffusion, vacancy trapping and emission at defects, gas atom absorption and resolution at gas bubbles, internal pressure in gas bubbles, elastic interaction between defects and gas bubbles, and the difference of thermodynamic and kinetic properties in matrix and grain boundaries. We applied the model to simulate gas atom segregation at grain boundaries and the effect of interfacial energy and gas mobility on gas bubble morphology and growth kinetics in a bi-crystal UO2 during post-irradiation thermal annealing. The preliminary results demonstrate that the model can produce the equilibrium thermodynamic properties and the morphology of gas bubbles at grain boundaries for given grain boundary properties. More validation of the model capability in polycrystalline is underway.

  9. Technology Solutions Case Study: Improving the Field Performance of Natural Gas Furnaces

    SciTech Connect (OSTI)

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  10. Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    Rothgeb, S.; Brand, L.

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  11. A simple correlation to predict the hydrate quadruple point temperature for LPG mixtures

    SciTech Connect (OSTI)

    Yousif, M.H.

    1997-12-31

    A simple correlation to predict the hydrate upper quadruple point temperature, T{sub Q2B} for liquefied petroleum gas (LPG) mixtures was developed. It was developed for use as a part of a modeling and control system for a LPG pipeline in Russia. For performance reasons, a simple hydrate prediction correlation was required that could be incorporated into the real-time and predictive pipeline simulation models. The operating company required both real time and predictive simulation tools be developed to assist in preventing hydrate blockages while minimizing the use of methanol. In this particular pipeline, LPG fluid moves through the pipeline as a single phase liquid above its bubble point pressure. Because of the very low flow rates, the trace amount of water present in the LPG drops out and creates water pools at low points in the pipeline. The pipeline pressure and seasonal temperatures are conducive for hydrate formation in these pools. Methanol and monoethylene glycol (MEG) are injected in the pipeline to help prevent hydrate formation. The newly developed correlation predicts the hydrate quadruple point temperature using only the composition and the molecular weight of the LPG mixture while retaining an accuracy comparable to the statistical thermodynamic models throughout the range of normal operating conditions.

  12. Control of NO/sub x/ emissions in gas engines using pre-stratified charge - Applications and field experience

    SciTech Connect (OSTI)

    Tice, J.K.; Nalim, M.R.

    1988-01-01

    Since 1983, development of the Pre-Stratified Charge (PSC) means of NO/sub x/ control has focused upon gas fueled industrial engines following a decade of development in automobile-type liquid fueled engines. The early test results indicated exceptional potential and wre previously reported. In the two years following the initial tests of PSC on in-field gas engines, over 140 units have been installed in a wide range of applications including compression, generation, and pumping service. Importantly, the applications have demonstrated PSC effectiveness and longevity where other means of emissions control are either not applicable or ineffective. These include higher digester gas, landfill gas, and sour natural gas (containing substantial H/sub 2/S). This work is concerned with the Field experience in general, but with emphasis on particular applications and specific results.

  13. Geological characterization and 3D visualizations of the gas storage reservoir at Hillsboro field, Montgomery County, IL

    SciTech Connect (OSTI)

    Udegbunam, E.O.; Huff, B.G. [Illinois State Geological Survey, Champaign, IL (United States)

    1994-12-31

    Geological characterizations, modeling and 3-D computer-generated visualizations of the Ordovician St. Peter Sandstone at the Hillsboro Gas Storage field in Montgomery County, Illinois, are discussed. Petrophysical analyses reveal four distinct hydraulic flow units in six cored wells. Furthermore, four lithologies, identified by thin section petrography, are associated with the various hydraulic units. Fieldwide visualizations of 3-D distributions of petrophysically-derived attributes reservoir quality index (RQI) and flow zone indicator (FZI) -- show considerable vertical variability but lateral continuity. This finding explains why it is easier to expand the gas bubble laterally than vertically. Advantages of the 3-D reservoir description of Hillsboro Gas Storage field include (1) improved definition of the spatial porosity distribution which leads to better estimation of reservoir volumetrics; (2) improved definition of reservoir hydraulic flow zones; and (3) development of realistic reservoir model(s) for the simulation and management of the gas storage field.

  14. A Mathematical Model for Predicting the Life of PEM Fuel Cell Membranes Subjected to Hydration Cycling

    E-Print Network [OSTI]

    Burlatsky, S F; O'Neill, J; Atrazhev, V V; Varyukhin, A N; Dmitriev, D V; Erikhman, N S

    2013-01-01

    Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic swelling/shrinking of the unconstrained membrane. In a constrained membrane, it causes cyclic stress resulting in mechanical failure in the area adjacent to the gas inlet. A mathematical modeling framework for prediction of the lifetime of a PEM FC membrane subjected to hydration cycling is developed in this paper. The model predicts membrane lifetime as a function of RH cycling amplitude and membrane mechanical properties. The modeling framework consists of three model components: a fuel cell RH distribution model, a hydration/dehydration induced stress model that predicts stress distribution in the membrane, and a damage accrual model that predicts membrane life-time. Short descriptions of the model components along with overall framework are presented in the paper. The model was used...

  15. Field testing of a probe to measure fouling in an industrial flue gas stream

    SciTech Connect (OSTI)

    Sohal, M.S.

    1990-11-01

    The US Department of Energy, Office of Industrial Technology sponsors work in the area of measuring and mitigating fouling in heat exchangers. This report describes the design and fabrication of a gas-side fouling measuring device, and its testing in an industrial environment. The report gives details of the probe fabrication, material used, controllers, other instrumentation required for various measurements, and computer system needed for recording the data. The calibration constants for measuring the heat flux with the heat fluxmeter were determined. The report also describes the field test location, the tests performed, the data collected, and the data analysis. The conclusions of the tests performed were summarized. Although fouling deposits on the probe were minimal, the tests proved that the probe is capable of measuring the fouling in a harsh industrial environment. 17 refs., 19 figs., 5 tabs.

  16. CO2-SO2 clathrate hydrate formation on early Mars1 Eric Chassefirea,b

    E-Print Network [OSTI]

    Boyer, Edmond

    and maintained a global average surface temperature ~230 K. Because35 clathrates trap SO2 more favorably than CO2 as a possible greenhouse gas which worked together55 with CO2 to raise the surface temperature of early Mars1 CO2-SO2 clathrate hydrate formation on early Mars1 2 Eric Chassefičrea,b , Emmanuel Dartoisc

  17. Department of Energy Advance Methane Hydrates Science and Technology Projects

    Broader source: Energy.gov [DOE]

    Descriptions for Energy Department Methane Hydrates Science and Technology Projects, August 31, 2012

  18. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Schroeder, Derryl; Storms, Michael

    2001-03-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were the deployment of tools and measurement systems for testing on ODP Leg 201, which is intended to study hydrate deposits on the Peru margin as part of other scientific investigations. Additional accomplishments were related to the continuing evolution of tools and measurements systems in preparation for deployment on ODP Leg 204, Hydrate Ridge, offshore Oregon in July 2002. The design for PCS Gas Manifold was finalized and parts were procured to assemble the gas manifold and deploy this system with the Pressure Core Sampler (PCS) tool on ODP Leg 201. The PCS was deployed 17 times during ODP Leg 201 and successfully retrieved cores from a broad range of lithologies and sediment depths along the Peru margin. Eleven deployments were entirely successful, collecting between 0.5 and 1.0 meters of sediment at greater than 75% of hydrostatic pressure. The PCS gas manifold was used in conjunction with the Pressure Core Sampler (PCS) throughout ODP Leg 201 to measure the total volume and composition of gases recovered in sediment cores associated with methane hydrates. The results of these deployments will be the subject of a future progress report. The FUGRO Pressure Corer (FPC), one of the HYACE/HYACINTH pressure coring tools, and two FUGRO engineers were deployed on the D/V JOIDES Resolution during ODP Legs 201 to field-test this coring system at sites located offshore Peru. The HYACINTH project is a European Union (EU) funded effort to develop tools to characterize methane hydrate and measure physical properties under in-situ conditions. The field-testing of these tools provides a corollary benefit to DOE/NETL at no cost to this project. The opportunity to test these tools on the D/V JOIDES Resolution was negotiated as part of a cooperative agreement between JOI/ODP and the HYACINTH partners. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were deployed onboard the R/V JOIDES Resolution and used extensively during ODP Leg 201. Preliminary results indicate successful deployments of these tools. An infrared-thermal imaging system (IR-TIS) was delivered to JOI/ODP for testing and use on ODP Leg 201 to identify methane hydrate intervals in the recovered cores. The results of these experiments will be the subject of a future progress report. This report presents an overview of the primary methods used for deploying the ODP memory tools and PCS on ODP Leg 201 and the preliminary operational results of this leg. Discussions regarding the laboratory analysis of the recovered cores and downhole measurements made during these deployments will be covered in a future progress report.

  19. Permeability of laboratory-formed methane-hydrate-bearing sand: Measurements and observations using x-ray computed tomography

    SciTech Connect (OSTI)

    Kneafsey, T. J.; Seol, Y.; Gupta, A.; Tomutsa, L.

    2010-09-15

    Methane hydrate was formed in two moist sands and a sand/silt mixture under a confining stress in an X-ray-transparent pressure vessel. Three initial water saturations were used to form three different methane-hydrate saturations in each medium. X-ray computed tomography (CT) was used to observe location-specific density changes caused by hydrate formation and flowing water. Gas-permeability measurements in each test for the dry, moist, frozen, and hydrate-bearing states are presented. As expected, the effective permeabilities (intrinsic permeability of the medium multiplied by the relative permeability) of the moist sands decreased with increasing moisture content. In a series of tests on a single sample, the effective permeability typically decreased as the pore space became more filled, in the order of dry, moist, frozen, and hydrate-bearing. In each test, water was flowed through the hydrate-bearing medium and we observed the location-specific changes in water saturation using CT scanning. We compared our data to a number of models, and our relative permeability data compare most favorably with models in which hydrate occupies the pore bodies rather than the pore throats. Inverse modeling (using the data collected from the tests) will be performed to extend the relative permeability measurements.

  20. A critical review of methods used in the estimation of natural gas reserves: Natural gas reserves in the state of Texas. Some educational prerequisites in the field of petroleum economics and evaluation. 

    E-Print Network [OSTI]

    Crichton, John Alston

    1953-01-01

    A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES NATURAL GAS RESERVES IN THE SI'AT. S OF TEXAS SOME EDUCATIONAL PREREQUISITES IN THE FIELD OF PETROLEUM ECONOMICS AND EVAI UATION Sy John Alston Crichton... ENGINEERING TABLE of CONTENTS ~Pa e A CRITICAL REVIEW OF METHODS USED IN THE ESTIMATION OF NATURAL GAS RESERVES Abstract Introdu=tion History of the Estimation of Gas Reserves Present Methods of Estimating Gas Reserves Meth& ds of Estimating Non...

  1. EA-2012: Strategic Test Well (s) Planning and Drilling for Long-Term Methane Hydrate Production Testing in Alaska

    Broader source: Energy.gov [DOE]

    DOE is preparing an EA that evaluates the potential environmental impacts of providing financial support for planning, analysis, and engineering services to support a proposed project of Petrotechnical Resources of Alaska with Japan Oil, Gas and Metals National Corporation to perform gas hydrate drilling and testing on the North Slope of Alaska.

  2. Integral Field Unit Observations of NGC 4302: Kinematics of the Diffuse Ionized Gas Halo

    E-Print Network [OSTI]

    George H. Heald; Richard J. Rand; Robert A. Benjamin; Matthew A. Bershady

    2007-03-13

    We present moderate resolution spectroscopy of extraplanar diffuse ionized gas (EDIG) emission in the edge-on spiral galaxy NGC 4302. The spectra were obtained with the SparsePak integral field unit (IFU) at the WIYN Observatory. The spectra are used to construct position-velocity (PV) diagrams at several ranges of heights above the midplane. Azimuthal velocities are directly extracted from the PV diagrams using the envelope tracing method, and indicate an extremely steep dropoff in rotational velocity with increasing height, with magnitude ~30 km/s/kpc. We find evidence for a radial variation in the velocity gradient on the receding side. We have also performed artificial observations of galaxy models in an attempt to match the PV diagrams. The results of a statistical analysis also favor a gradient of ~30 km/s/kpc. We compare these results with an entirely ballistic model of disk-halo flow, and find a strong dichotomy between the observed kinematics and those predicted by the model. The disagreement is worse than we have found for other galaxies in previous studies. The conclusions of this paper are compared to results from two other galaxies, NGC 5775 and NGC 891. We find that the vertical gradient in rotation speed, per unit EDIG scale height, for all three galaxies is consistent with a constant magnitude (within the errors) of approximately 15-25 km/s/scaleheight, independent of radius. This relationship is also true within the galaxy NGC 4302. We also discuss how the gradient depends on the distribution and morphology of the EDIG and the star formation rates of the galaxies, and consequences for the origin of the gas.

  3. A realistic molecular model of cement hydrates

    E-Print Network [OSTI]

    Ulm, Franz-Josef

    Despite decades of studies of calcium-silicate-hydrate (C-S-H), the structurally complex binder phase of concrete, the interplay between chemical composition and density remains essentially unexplored. Together these ...

  4. Weakening of ice by magnesium perchlorate hydrate

    E-Print Network [OSTI]

    Lenferink, Hendrik J., 1985-

    2012-01-01

    I show that perchlorate hydrates, which have been indirectly detected at high Martian circumpolar latitudes by the Phoenix Mars Lander, have a dramatic effect upon the rheological behavior of polycrystalline water ice under ...

  5. Nanomechanical properties of hydrated organic thin films

    E-Print Network [OSTI]

    Choi, Jae Hyeok

    2007-01-01

    Hydrated organic thin films are biological or synthetic molecularly thin coatings which impart a particular functionality to an underlying substrate and which have discrete water molecules associated with them. Such films ...

  6. Methane Hydrate Advisory Committee (MHAC) Meeting

    Broader source: Energy.gov (indexed) [DOE]

    to establish the resource potential of methane hydrates via a sustained, long-term production test in the Arctic. DFO Gant reminded the Committee that on May 1, the MHAC members...

  7. FIELD DEMONSTRATION OF A MEMBRANE PROCESS TO RECOVER HEAVY HYDROCARBONS AND TO REMOVE WATER FROM NATURAL GAS

    SciTech Connect (OSTI)

    R. Baker; T. Hofmann; J. Kaschemekat; K.A. Lokhandwala; Membrane Group; Module Group; Systems Group

    2001-01-11

    The objective of this project is to design, construct and field demonstrate a 3-MMscfd membrane system to recover natural gas liquids (NGL) and remove water from raw natural gas. An extended field test to demonstrate system performance under real-world conditions is required to convince industry users of the efficiency and reliability of the process. The system will be designed and fabricated by Membrane Technology and Research, Inc. (MTR) and then installed and operated at British Petroleum (BP)-Amoco's Pascagoula, MS plant. The Gas Research Institute will partially support the field demonstration and BP-Amoco will help install the unit and provide onsite operators and utilities. The gas processed by the membrane system will meet pipeline specifications for dewpoint and Btu value and can be delivered without further treatment to the pipeline. Based on data from prior membrane module tests, the process is likely to be significantly less expensive than glycol dehydration followed by propane refrigeration, the principal competitive technology. At the end of this demonstration project the process will be ready for commercialization. The route to commercialization will be developed during this project and may involve collaboration with other companies already servicing the natural gas processing industry.

  8. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank; Storms, Michael; Schroeder, Derryl; Dugan, Brandon; Schultheiss, Peter

    2002-12-31

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were (1) the preliminary postcruise evaluation of the tools and measurement systems that were used during ODP Leg 204 to study hydrate deposits on Hydrate Ridge, offshore Oregon from July through September 2002; and (2) the preliminary study of the hydrate-bearing core samples preserved in pressure vessels and in liquid nitrogen cryofreezers, which are now stored at the ODP Gulf Coast Repository in College Station, TX. During ODP Leg 204, several newly modified downhole tools were deployed to better characterize the subsurface lithologies and environments hosting microbial populations and gas hydrates. A preliminary review of the use of these tools is provided herein. The DVTP, DVTP-P, APC-methane, and APC-Temperature tools (ODP memory tools) were used extensively and successfully during ODP Leg 204 aboard the D/V JOIDES Resolution. These systems provided a strong operational capability for characterizing the in situ properties of methane hydrates in subsurface environments on Hydrate Ridge during ODP Leg 204. Pressure was also measured during a trial run of the Fugro piezoprobe, which operates on similar principles as the DVTP-P. The final report describing the deployments of the Fugro Piezoprobe is provided in Appendix A of this report. A preliminary analysis and comparison between the piezoprobe and DVTP-P tools is provided in Appendix B of this report. Finally, a series of additional holes were cored at the crest of Hydrate Ridge (Site 1249) specifically geared toward the rapid recovery and preservation of hydrate samples as part of a hydrate geriatric study partially funded by the Department of Energy (DOE). In addition, the preliminary results from gamma density non-invasive imaging of the cores preserved in pressure vessels are provided in Appendix C of this report. An initial visual inspection of the samples stored in liquid nitrogen is provided in Appendix D of this report.

  9. Optimizing the efficiency of cylindrical cyclone gas/liquid separators for field applications 

    E-Print Network [OSTI]

    Adebare, Adedeji

    2006-10-30

    Problems associated with the use of compact cylindrical cyclone gas/liquid (CCGL) separators can be attributed to two physical phenomena: gas carry-under and liquid carryover (LCO). Inadequate understanding of the complex ...

  10. SHEAR-WAVE SOURCED 3-D VSP IMAGING OF TIGHT-GAS SANDSTONES IN RULISON FIELD, COLORADO

    E-Print Network [OSTI]

    1 #12;SHEAR-WAVE SOURCED 3-D VSP IMAGING OF TIGHT-GAS SANDSTONES IN RULISON FIELD, COLORADO heavily on understanding the distribution of sandstone bodies in the subsurface. Shear-wave sourced 3-D was applied to the shear- wave reflection data. A geologically-constrained migration-velocity model

  11. Monitoring protocol for Gas Research Institute natural gas vehicle field test projects. Topical report, March-October 1991

    SciTech Connect (OSTI)

    Londos, T.C.; Agan, D.D.

    1991-10-01

    In order to ensure the consistency and comparability of natural gas vehicle (NGV) operation and performance data, a data collection protocol was developed. Recommendations were also made for emission testing of NGVs. The protocol utilizes an online database management and reporting system for timely dissemination of data to interested parties within industry and government. Further evaluation and testing of the protocol will be completed before final documentation of the protocol.

  12. FIELD DEMONSTRATION OF A MEMBRANE PROCESS TO RECOVER HEAVY HYDROCARBONS AND TO REMOVE WATER FROM NATURAL GAS

    SciTech Connect (OSTI)

    Unknown

    2002-04-10

    The objective of this project is to design, construct and field demonstrate a 3-MMscfd membrane system to recover natural gas liquids (NGL) and remove water from raw natural gas. The gas processed by the membrane system will meet pipeline specifications for dew point and Btu value, and the process is likely to be significantly less expensive than glycol dehydration followed by propane refrigeration, the principal competitive technology. The BP-Amoco gas processing plant in Pascagoula, MS was finalized as the location for the field demonstration. Detailed drawings of the MTR membrane skid (already constructed) were submitted to the plant in February, 2000. However, problems in reaching an agreement on the specifications of the system compressor delayed the project significantly, so MTR requested (and was subsequently granted) a no-cost extension to the project. Following resolution of the compressor issues, the goal is to order the compressor during the first quarter of 2002, and to start field tests in mid-2002. Information from potential users of the membrane separation process in the natural gas processing industry suggests that applications such as fuel gas conditioning and wellhead gas processing are the most promising initial targets. Therefore, most of our commercialization effort is focused on promoting these applications. Requests for stream evaluations and for design and price quotations have been received through MTR's web site, from direct contact with potential users, and through announcements in industry publications. To date, about 90 commercial quotes have been supplied, and orders totaling about $1.13 million for equipment or rental of membrane units have been received.

  13. Digital field-bus mode SCADA is key to offshore efficiency. [Automation of offshore gas production platforms

    SciTech Connect (OSTI)

    Cuthbert, P. )

    1994-02-01

    An all-digital SCADA network has been installed in one of the North Sea's largest natural gas fields, controlling the delivery of gas from Shell UK Exploration and Production's souther-area fields to a British Gas Terminal at Bacton, UK. The innovative use of digital technology -- based on the industry-standard HART field protocol -- to complete a digital communications link stretching from the onshore SCADA host right out to the process variable transmitters on the platforms, is playing a key role in the automation of the monitoring and control system by allowing Shell UK Expro to run the majority of the platforms unmanned. The SCADA system is part of a major refit being carried out by Shell Expro on its Leman field. The refit is part of the company's long-term strategy to extend the lifetime of this established field, which started operations in the late 1960s. In order to meet this goal, the prime requirements are to reduce operational costs and risk exposure, and the key element in this area was to reduce the need for resident staff and all of their associated support and equipment costs, through the deployment of automation. The system will achieve the project's cost-cutting aims, but also break new ground in control and monitoring technology for the gas industry, through the use of a smart transmitter scheme as a digital field communications within the wide-area network, using the protocol's all-digital capability in preference to the commonly used 4-20mA-compatible mode, will allow real-time monitoring and control, plus maintenance and diagnostics, to take place remotely. This paper describes the design of this system.

  14. Abstract The concurrent goals of cement hydration are to percolate (bridge) the original

    E-Print Network [OSTI]

    Bentz, Dale P.

    Abstract The concurrent goals of cement hydration are to percolate (bridge) the original cement. The initial volume, particle size distribution, and flocculation/dispersion state of the cement particles have and the alkali content of the cement pastes. Finally, it is proposed that future efforts in this field

  15. Proceedings of the natural gas research and development contractors review meeting

    SciTech Connect (OSTI)

    Malone, R.D.; Shoemaker, H.D.; Byrer, C.W.

    1990-11-01

    The purpose of this meeting was to present results of the research in the DOE-sponsored Natural Gas Program, and simultaneously to provide a forum for real-time technology transfer, to the active research community, to the interested public, and to the natural gas industry, who are the primary users of this technology. The current research focus is to expand the base of near-term and mid-term economic gas resources through research activities in Eastern Tight Gas, Western Tight Gas, Secondary Gas Recovery (increased recovery of gas from mature fields); to enhance utilization, particularly of remote gas resources through research in Natural Gas to Liquids Conversion; and to develop additional, long term, potential gas resources through research in Gas Hydrates and Deep Gas. With the increased national emphasis on the use of natural gas, this forum has been expanded to include summaries of DOE-sponsored research in energy-related programs and perspectives on the importance of gas to future world energy. Thirty-two papers and fourteen poster presentations were given in seven formal, and one informal, sessions: Three general sessions (4 papers); Western Tight Gas (6 papers); Eastern Tight Gas (8 papers); Conventional/Speculative Resources (8 papers); and Gas to Liquids (6 papers). Individual reports are processed separately on the data bases.

  16. Phase-field simulations of gas density within bubbles under irradiatio...

    Office of Scientific and Technical Information (OSTI)

    DEFECTS; DISTRIBUTION; FREE ENERGY; IRRADIATION; MINIMIZATION; NUCLEATION; THERMODYNAMICS Fission gas; Modeling and Simulation Word Cloud More Like This Full Text Journal...

  17. Preliminary relative permeability estimates of methane hydrate-bearing sand

    E-Print Network [OSTI]

    Seol, Yongkoo; Kneafsey, Timothy J.; Tomutsa, Liviu; Moridis, George J.

    2006-01-01

    through methane hydrate-bearing sand. X-ray CT was usedin partially saturated sand, 229th ACS National Meeting, SanOF METHANE HYDRATE- BEARING SAND Yongkoo Seol, Timothy J.

  18. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

    2003-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  19. Fuel cell membrane hydration and fluid metering

    DOE Patents [OSTI]

    Jones, Daniel O. (Glenville, NY); Walsh, Michael M. (Fairfield, CT)

    1999-01-01

    A hydration system includes fuel cell fluid flow plate(s) and injection port(s). Each plate has flow channel(s) with respective inlet(s) for receiving respective portion(s) of a given stream of reactant fluid for a fuel cell. Each injection port injects a portion of liquid water directly into its respective flow channel in order to mix its respective portion of liquid water with the corresponding portion of the stream. This serves to hydrate at least corresponding part(s) of a given membrane of the corresponding fuel cell(s). The hydration system may be augmented by a metering system including flow regulator(s). Each flow regulator meters an injecting at inlet(s) of each plate of respective portions of liquid into respective portion(s) of a given stream of fluid by corresponding injection port(s).

  20. Curvature Dependence of Hydrophobic Hydration Dynamics

    E-Print Network [OSTI]

    R. Gregor Weiß; Matthias Heyden; Joachim Dzubiella

    2015-04-08

    We investigate the curvature-dependence of water dynamics in the vicinity of hydrophobic spherical solutes using molecular dynamics simulations. For both, the lateral and perpendicular diffusivity as well as for H-bond kinetics of water in the first hydration shell, we find a non-monotonic solute-size dependence, exhibiting extrema close to the well-known structural crossover length scale for hydrophobic hydration. Additionally, we find an apparently anomalous diffusion for water moving parallel to the surface of small solutes, which, however, can be explained by topology effects. The intimate connection between solute curvature, water structure and dynamics has implications for our understanding of hydration dynamics at heterogeneous biomolecular surfaces.

  1. Liquid-gas phase transition in hot asymmetric nuclear matter with density-dependent relativistic mean-field models

    E-Print Network [OSTI]

    Guang-Hua Zhang; Wei-Zhou Jiang

    2013-02-14

    The liquid-gas phase transition in hot asymmetric nuclear matter is studied within density-dependent relativistic mean-field models where the density dependence is introduced according to the Brown-Rho scaling and constrained by available data at low densities and empirical properties of nuclear matter. The critical temperature of the liquid-gas phase transition is obtained to be 15.7 MeV in symmetric nuclear matter falling on the lower edge of the small experimental error bars. In hot asymmetric matter, the boundary of the phase-coexistence region is found to be sensitive to the density dependence of the symmetry energy. The critical pressure and the area of phase-coexistence region increases clearly with the softening of the symmetry energy. The critical temperature of hot asymmetric matter separating the gas phase from the LG coexistence phase is found to be higher for the softer symmetry energy.

  2. Dehydration of plutonium or neptunium trichloride hydrate

    DOE Patents [OSTI]

    Foropoulos, J. Jr.; Avens, L.R.; Trujillo, E.A.

    1992-03-24

    A process is described for preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride.

  3. Dehydration of plutonium or neptunium trichloride hydrate

    DOE Patents [OSTI]

    Foropoulos, Jr., Jerry (Los Alamos, NM); Avens, Larry R. (Los Alamos, NM); Trujillo, Eddie A. (Espanola, NM)

    1992-01-01

    A process of preparing anhydrous actinide metal trichlorides of plutonium or neptunium by reacting an aqueous solution of an actinide metal trichloride selected from the group consisting of plutonium trichloride or neptunium trichloride with a reducing agent capable of converting the actinide metal from an oxidation state of +4 to +3 in a resultant solution, evaporating essentially all the solvent from the resultant solution to yield an actinide trichloride hydrate material, dehydrating the actinide trichloride hydrate material by heating the material in admixture with excess thionyl chloride, and recovering anhydrous actinide trichloride is provided.

  4. Characterization of gas condensate reservoirs using pressure transient and production data - Santa Barbara Field, Monagas, Venezuela 

    E-Print Network [OSTI]

    Medina Tarrazzi, Trina Mercedes

    2003-01-01

    This thesis presents a field case history of the integrated analysis and interpretation developed using all of the available petrophysical, production, and well test data from the condensate zone of Block A, Santa Barbara Field (Monagas, Venezuela...

  5. Dynamic behavior of hydration water in calcium-silicate-hydrate gel: A quasielastic neutron scattering spectroscopy investigation

    E-Print Network [OSTI]

    Li, Hua

    The translational dynamics of hydration water confined in calcium-silicate-hydrate (C-S-H) gel was studied by quasielastic neutron scattering spectroscopy in the temperature range from 280 to 230 K. The stretch exponent ...

  6. MODELING OF HYDRATION KINETICS AND SHRINKAGE OF PORTLAND CEMENT PASTE

    E-Print Network [OSTI]

    Meyer, Christian

    MODELING OF HYDRATION KINETICS AND SHRINKAGE OF PORTLAND CEMENT PASTE Feng Lin Submitted in partial and Sciences COLUMBIA UNIVERSITY 2006 #12;MODELING OF HYDRATION KINETICS AND SHRINKAGE OF PORTLAND CEMENT PASTE;ABSTRACT MODELING OF HYDRATION KINETICS AND SHRINKAGE OF PORTLAND CEMENT PASTE Feng Lin A mathematical

  7. Dry Gas Zone, Elk Hills Field, Kern County, California: General reservoir study: Geologic text and tables: Final report

    SciTech Connect (OSTI)

    Not Available

    1988-06-29

    The Dry Gas Zone was defined by US Naval Petroleum Reserve No. 1 Engineering Committee (1957) as ''/hor ellipsis/all sands bearing dry gas above the top of the Lower Scalez marker bed. The term is used to include the stratigraphic interval between the Scalez Sand Zone and the Tulare Formation - the Mya Sand Zone. The reservoirs in this upper zone are thin, lenticular, loosely cemented sandstones with relatively high permeabilities.'' Other than the limited Tulare production in the western part of the field, the Dry Gas Zone is the shallowest productive zone in the Elk Hills Reserve and is not included in the Shallow Oil Zone. It is Pliocene in age and makes up approximately eighty percent of the San Joaquin Formation as is summarized in Exhibit TL-1. The lithologic character of the zone is one of interbedded shales and siltstones with intermittent beds of various thickness sands. The stratigraphic thickness of the Dry Gas Zone ranges from 950 to 1150 feet with a general thickening along the flanks and thinning over the crests of the anticlines. The productive part of the Dry Gas Zone covers portions of 30 sections in an area roughly 10 miles long by 4 miles wide. 4 refs.

  8. Ion Species and Charge States of Vacuum Arc Plasma with Gas Feed and Longitudinal Magnetic Field

    E-Print Network [OSTI]

    Oks, Efim

    2010-01-01

    in cathodic vacuum arc plasmas,” J. Appl. Phys. , vol. 102,models of the cathodic arc plasma and its interaction withand Charge States of Vacuum Arc Plasma with Gas Feed and

  9. field

    National Nuclear Security Administration (NNSA)

    09%2A en Ten-Year Site Plans (TYSP) http:www.nnsa.energy.govaboutusouroperationsinfopsinfopstysp

    field field-type-text field-field-page-name">
  10. CO2 hydrate dissociation at low temperatures - formation and annealing of ice Ic

    E-Print Network [OSTI]

    Falenty, Andrzej; Kuhs, Werner F

    2015-01-01

    Dissociation of gas hydrates below 240 K leads to the formation of a metastable form of water ice, so called cubic ice (Ic). Through its defective nature and small particle size the surface film composed of such material is incapable of creating any significant diffusion barrier. Above 160 K, cubic ice gradually transforms to the stable hexagonal (Ih) form on laboratory time scales. The annealing, coupled with a parallel decomposition of gas hydrates, accelerates as temperature rises but already above 190 K the first process prevails, transforming cubic stacking sequences in-to ordinary Ih ice within a few minutes. Remaining stacking faults are removed through very slow isothermal annealing or after heating up above 240 K. The role of the proportion of cubic stacking on the decomposition rate is discussed. A better understanding of the dissociation kinetics at low temperatures is particularly im-portant for the critical evaluation of existing hypotheses that consider clathrates as a potential medium that acti...

  11. Alabama Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade Year-0Cubic(Million CubicWorking Gas1) Part

  12. Florida Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun20032,485,331Gas2001

  13. Louisiana Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013(Million Barrels) Natural Gas8 0 0 0

  14. Tracer Gas as a Practical Field Diagnostic Tool for Assessing Duct System Leaks 

    E-Print Network [OSTI]

    Cummings, J. B.

    1989-01-01

    diagnostic tools for detecting and locating leaks in the air distribution system. The tracer gas tests described are a good complement to these tools in the detection, location, and measurement of duct leakage. Testing for house infiltration once with the air...

  15. Methane Hydrate Advisory Committee Meeting

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safetyof EnergyPresentation:DaisStatesEMCHIEFMeltingMethane

  16. A Long Term Field Emissions Study of Natural Gas Fueled Refuse Haulers in New York City

    SciTech Connect (OSTI)

    Nigel N. Clark; Byron l. Rapp; Mridul Gautam; Wenguang Wang; Donald W. Lyons

    1998-10-19

    New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these was for street collection and transporting the refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines. Five trucks were equipped with electronically controlled Detroit Diesel Series 50 lean burn engines, while another five were powered by Caterpillar stoichiometric burn 3306 natural gas engines, The Ca terpillar engines employed an exhaust oxygen sensor feedback and three way catalysts. Since the refuse haulers had automatic Allison transmissions, and since they were employed in stop-and-go city service, initial emissions measurements were made using the Central Business Cycle (SAE Jl376) for buses at 42,000 pound test weight. Some additional measurements were made using an ad hoc cycle that has been designed to be more representative of the real refuse hauler use that included several compaction cycles. The Cummins powered natural gas vehicles showed oxides of nitrogen and carbon monoxide emission variations typically associated with variable fuel mixer performance. In the first Year of testing, the stoichiometric Caterpillar engines yielded low emission levels, but in later years two of these refuse haulers had high carbon monoxide attributed to failure of the feedback system. For example, carbon monoxide on these two vehicles rose from 1.4 g/mile and 10 g/mile in 1995 to 144.9 g/mile and 57.8 g/mile in 1996. These stoichiometric engines were also less fuel efficient than their lean burn counterparts. The Detroit Diesel Series 50 powered refuse haulers produced high levels of oxides of nitrogen. However, it was found that changing the shifting patterns of the transmission lowered the oxides of nitrogen. All three engine types showed the potential for low emissions operation and the particulate matter reduction advantage offered by natural gas was evident from the results.

  17. Increasing Well Productivity in Gas Condensate Wells in Qatar's North Field 

    E-Print Network [OSTI]

    Miller, Nathan

    2010-07-14

    2.1.4. Method for Reduction of Non Darcy Flow Study ......... 17 2.2. PVT Analysis .......................................................................... 17 2.3. Reservoir Description... to study Non Darcy flow in both a multilateral well and a vertical well. A Non Darcy flow sensitivity test is run to see the impact Non Darcy flow has on near wellbore condensate blockage, and therefore, gas well productivity. 2.2. PVT...

  18. Geometrical Field Representation of Solid, Fluid, and Gas as Continuum in Rational Mechanics

    E-Print Network [OSTI]

    Jianhua Xiao

    2009-11-07

    Based on the points-set transformation concept about the motion transformation in continuum, the macro classical strain is expressed by the additive addition of the intrinsic stretching of material element and its intrinsic local rotation. For zero classical strain (no macro deformation observed on its configuration surface, suitable container is required for liquid and gas to make up macro invariant configuration), the results show that: (1) For solid, the local rotation angular is zero. The material element has no intrinsic stretching. (2) For liquid, the local rotation will not change the basic gauge tensor. The material element has intrinsic plane stretching on the rotation plane. (3) For gas state, the intrinsic local rotation will amplify the basic gauge tensor. The material element has intrinsic stretching along the rotation direction. Hence, under the condition of no macro classical strain be observed, the material element has three different physical states: solid (no intrinsic stretching), fluid (plane intrinsic stretching), and gas (directional intrinsic stretching). Furthermore, for the three states, the free conditions are defined by zero intrinsic stretching. Referring to this free condition, the constitutive equations for the materials at multiple states are established.

  19. The thermodynamics for a hadronic gas of fireballs with internal color structures and chiral fields

    E-Print Network [OSTI]

    Ismail Zakout; Carsten Greiner

    2008-08-11

    The thermodynamical partition function for a gas of color-singlet bags consisting of fundamental and adjoint particles in both $U(N_c)$ and $SU(N_c)$ group representations is reviewed in detail. The constituent particle species are assumed to satisfy various thermodynamical statistics. The gas of bags is probed to study the phase transition for a nuclear matter in the extreme conditions. These bags are interpreted as the Hagedorn states and they are the highly excited hadronic states which are produced below the phase transition point to the quark-gluon plasma. The hadronic density of states has the Gross-Witten critical point and exhibits a third order phase transition from a hadronic phase dominated by the discrete low-lying hadronic mass spectrum particles to another hadronic phase dominated by the continuous Hagedorn states. The Hagedorn threshold production is found just above the highest known experimental discrete low-lying hadronic mass spectrum. The subsequent Hagedorn phase undergoes a first order deconfinement phase transition to an explosive quark-gluon plasma. The role of the chiral phase transition in the phases of the discrete low-lying mass spectrum and the continuous Hagedorn mass spectrum is also considered. It is found crucial in the phase transition diagram. Alternate scenarios are briefly discussed for the Hagedorn gas undergoes a higher order phase transition through multi-processes of internal color-flavor structure modification.

  20. SUPPORT OF GULF OF MEXICO HYDRATE RESEARCH CONSORTIUM: ACTIVITIES TO SUPPORT ESTABLISHMENT OF A SEA FLOOR MONITORING STATION PROJECT

    SciTech Connect (OSTI)

    Paul Higley; J. Robert Woolsey; Ralph Goodman; Vernon Asper; Boris Mizaikoff; Angela Davis

    2005-08-01

    A Consortium, designed to assemble leaders in gas hydrates research, has been established at the University of Mississippi's Center for Marine Resources and Environmental Technology, CMRET. The primary objective of the group is to design and emplace a remote monitoring station on the sea floor in the northern Gulf of Mexico by the year 2005, in an area where gas hydrates are known to be present at, or just below, the sea floor. This mission necessitates assembling a station that will monitor physical and chemical parameters of the sea water and sea floor sediments on a more-or-less continuous basis over an extended period of time. Development of the station allows for the possibility of expanding its capabilities to include biological monitoring, as a means of assessing environmental health. Establishment of the Consortium has succeeded in fulfilling the critical need to coordinate activities, avoid redundancies and communicate effectively among researchers in this relatively new research arena. Complementary expertise, both scientific and technical, has been assembled to innovate research methods and construct necessary instrumentation. A year into the life of this cooperative agreement, we note the following achievements: (1) Progress on the vertical line array (VLA) of sensors: (A) Software and hardware upgrades to the data logger for the prototype vertical line array, including enhanced programmable gains, increased sampling rates, improved surface communications, (B) Cabling upgrade to allow installation of positioning sensors, (C) Adaptation of SDI's Angulate program to use acoustic slant ranges and DGPS data to compute and map the bottom location of the vertical array, (D) Progress in T''0'' delay and timing issues for improved control in data recording, (E) Successful deployment and recovery of the VLA twice during an October, 2003 cruise, once in 830m water, once in 1305m water, (F) Data collection and recovery from the DATS data logger, (G) Sufficient energy supply and normal functioning of the pressure compensated battery even following recharge after the first deployment, (H) Survival of the acoustic modem following both deployments though it was found to have developed a slow leak through the transducer following the second deployment due, presumably, to deployment in excess of 300m beyond its rating. (2) Progress on the Sea Floor Probe: (A) The Sea Floor Probe and its delivery system, the Multipurpose sled have been completed, (B) The probe has been modified to penetrate the <1m blanket of hemipelagic ooze at the water/sea floor interface to provide the necessary coupling of the accelerometer with the denser underlying sediments, (C) The MPS has been adapted to serve as an energy source for both p- and s-wave studies at the station as well as to deploy the horizontal line arrays and the SFP. (3) Progress on the Electromagnetic Bubble Detector and Counter: (A) Components for the prototype have been assembled, including a dedicated microcomputer to control power, readout and logging of the data, all at an acceptable speed, (B) The prototype has been constructed and preliminary data collected, (C) The construction of the field system is underway. (4) Progress on the Acoustic Systems for Monitoring Gas Hydrates: (A) Video recordings of bubbles emitted from a seep in Mississippi Canyon have been made from a submersible dive and the bubbles analyzed with respect to their size, number, and rise rate. These measurements have been used to determine the parameters to build the system capable of measuring gas escaping at the site of the monitoring station, (B) Laboratory tests performed using the project prototype have produced a conductivity data set that is being used to refine parameters of the field model. (5) Progress on the Mid-Infrared Sensor for Continuous Methane Monitoring: (A) Preliminary designs of mounting pieces for electrical components of ''sphereIR'' have been completed using AutoCAD software, (B) The preliminary design of an electronics baseplate has been completed and aided in the optimization of

  1. Hydrodynamic flow in lower Cretaceous Muddy sandstone, Gas Draw Field, Powder River Basin, Wyoming 

    E-Print Network [OSTI]

    Lin, Joseph Tien-Chin

    1978-01-01

    potentiometric gradient of 32 ft/mi across the field yields a hydrodynamic oil column of 210 ft, whereas capillary-pressure differ- ences due to permeability changes can account for only 38 ft of oil column. The observed oil column over most of the field has a... height somewhat greater than 250 ft. The agreement between total calculated oil column of about 248 ft and the observed oil column demonstrates that the positive hydrodynamic gradient across the reservoir and the decrease in permeability updip...

  2. Methane Hydrate Program Annual Report to Congress

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy May 28 WebinarProtectMessageFY 2010 Methane Hydrate

  3. Field monitoring and evaluation of a residential gas-engine-driven heat pump: Volume 2, Heating season

    SciTech Connect (OSTI)

    Miller, J.D.

    1995-11-01

    The Federal Government is the largest single energy consumer in the United States; consumption approaches 1.5 quads/year of energy (1 quad = 10{sup 15} Btu) at a cost valued at nearly $10 billion annually. The US Department of Energy (DOE) Federal Energy Management Program (FEMP) supports efforts to reduce energy use and associated expenses in the Federal sector. One such effort, the New Technology Demonstration Program (NTDP), seeks to evaluate new energy-saving US technologies and secure their more timely adoption by the US Government. Pacific Northwest Laboratory (PNL) is one of four DOE national multiprogram laboratories that participate in the NTDP by providing technical expertise and equipment to evaluate new, energy-saving technologies being studied and evaluated under that program. This two-volume report describes a field evaluation that PNL conducted for DOE/FEMP and the US Department of Defense (DoD) Strategic Environmental Research and Development Program (SERDP) to examine the performance of a candidate energy-saving technology -- a gas-engine-driven heat pump. The unit was installed at a single residence at Fort Sam Houston, a US Army base in San Antonio, Texas, and the performance was monitored under the NTDP. Participating in this effort under a Cooperative Research and Development Agreement (CRADA) were York International, the heat pump manufacturer; Gas Research Institute (GRI), the technology developer; City Public Service of San Antonio, the local utility; American Gas Cooling Center (AGCC); Fort Sam Houston; and PNL.

  4. DEVELOPMENT AND FIELD IMPLEMENTATION OF AN IMPROVED METHOD FOR HEADSPACE GAS SAMPLING OF TRANSURANIC WASTE DRUMS

    SciTech Connect (OSTI)

    Polley, M.; Ankrom, J.; Wickland, T.; Warren, J.

    2003-02-27

    A fast, safe, and cost-effective method for obtaining headspace gas samples has been developed and implemented at Los Alamos National Laboratory (LANL). A sample port is installed directly into a drum lid using a pneumatic driver, allowing sampling with a side-port needle. Testing has shown that the sample port can be installed with no release of radioactive material. Use of this system at LANL has significantly reduced the time required for sampling, and eliminates the need for many safety precautions previously used. The system has significantly improved productivity and lowered radiation exposure and cost.

  5. New Reservoir Discoveries in Old Fields of Natural Gas, Wet After Lease

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Marthrough 1996)Price780 922

  6. U.S. Natural Gas Plant Liquids, New Reservoir Discoveries in Old Fields

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0Proved ReservesData2009 2010Year Jan Feb Mar2009 2010(Million

  7. Alaska Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570 2,304 1,670Same0 1 2Cubic3,566

  8. Arkansas Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570MonthThousand8 0.8 0.8 0.622 28 21

  9. Associated-Dissolved Natural Gas New Field Discoveries, Wet After Lease

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per Thousand CubicSeparation, 263 102 611

  10. Associated-Dissolved Natural Gas New Reservoir Discoveries in Old Fields,

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per Thousand CubicSeparation, 263 102

  11. California Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724per ThousandLease0Year Jan,835 2,939

  12. Colorado Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948CaliforniaFeet) (Million,914 1,886Cubic

  13. Kansas Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr MayYearYearDecade Year-0163 258 228 183 189 21164

  14. Kansas Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr MayYearYearDecade Year-0163 258 228Extensions

  15. Kentucky Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012 2013 2014 View Historyto7 2005-2014

  16. Michigan Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal ConsumptionperYear Jan

  17. Montana Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr 2012DecadeTotal19FuelYear5) Model37 64 25 11 16

  18. Wyoming Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural Gas Production3,1,50022,3,,0,,6,1,6,1,50022,3,,,,6,1,8,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Separation 362855

  19. Hydration of ions in two dimensional water

    E-Print Network [OSTI]

    S. Dutta; Yongjin Lee; Y. S. Jho

    2015-11-11

    We present a 2D lattice model of water to study the effects of ion hydration on the properties of water. We map the water molecules as lattice particles consisting of a single Oxygen at the center of a site and two Hydrogen atoms on each side. The internal state of the system, such as the dipole moment at a site, is defined with respect to the location of the Hydrogen atoms at the site depending on their role in Hydrogen bonds (H-bonds) being a donor or an acceptor. We study the influence of the charge and the radius of the ion on the insertion energy and on the H-bonds in the first and second hydration layers around the ion and in the bulk. In particular we analyze how the competing interactions of the short-ranged H-bonds and the long-ranged electrostatics influence the hydration properties. The role of the ion both as a source of the electrostatic interactions as well as a defect is also discussed. Our model also shows the well known fact that the polarizability of the water molecules destroys the hydrogen bond network and increases the dipole moment of the molecules near the ion.

  20. Hydration of ions in two dimensional water

    E-Print Network [OSTI]

    Dutta, S; Jho, Y S

    2015-01-01

    We present a 2D lattice model of water to study the effects of ion hydration on the properties of water. We map the water molecules as lattice particles consisting of a single Oxygen at the center of a site and two Hydrogen atoms on each side. The internal state of the system, such as the dipole moment at a site, is defined with respect to the location of the Hydrogen atoms at the site depending on their role in Hydrogen bonds (H-bonds) being a donor or an acceptor. We study the influence of the charge and the radius of the ion on the insertion energy and on the H-bonds in the first and second hydration layers around the ion and in the bulk. In particular we analyze how the competing interactions of the short-ranged H-bonds and the long-ranged electrostatics influence the hydration properties. The role of the ion both as a source of the electrostatic interactions as well as a defect is also discussed. Our model also shows the well known fact that the polarizability of the water molecules destroys the hydrogen...

  1. A Mathematical Model for Predicting the Life of PEM Fuel Cell Membranes Subjected to Hydration Cycling

    E-Print Network [OSTI]

    S. F. Burlatsky; M. Gummalla; J. O'Neill; V. V. Atrazhev; A. N. Varyukhin; D. V. Dmitriev; N. S. Erikhman

    2013-06-19

    Under typical PEM fuel cell operating conditions, part of membrane electrode assembly is subjected to humidity cycling due to variation of inlet gas RH and/or flow rate. Cyclic membrane hydration/dehydration would cause cyclic swelling/shrinking of the unconstrained membrane. In a constrained membrane, it causes cyclic stress resulting in mechanical failure in the area adjacent to the gas inlet. A mathematical modeling framework for prediction of the lifetime of a PEM FC membrane subjected to hydration cycling is developed in this paper. The model predicts membrane lifetime as a function of RH cycling amplitude and membrane mechanical properties. The modeling framework consists of three model components: a fuel cell RH distribution model, a hydration/dehydration induced stress model that predicts stress distribution in the membrane, and a damage accrual model that predicts membrane life-time. Short descriptions of the model components along with overall framework are presented in the paper. The model was used for lifetime prediction of a GORE-SELECT membrane.

  2. MULTI-KEV X-RAY YIELDS FROM HIGH-Z GAS TARGETS FIELDED AT OMEGA

    SciTech Connect (OSTI)

    Kane, J O; Fournier, K B; May, M J; Colvin, J D; Thomas, C A; Marrs, R E; Compton, S M; Moody, J D; Bond, E J; Davis, J F

    2010-11-04

    The authors report on modeling of x-ray yield from gas-filled targets shot at the OMEGA laser facility. The OMEGA targets were 1.8 mm long, 1.95 mm in diameter Be cans filled with either a 50:50 Ar:Xe mixture, pure Ar, pure Kr or pure Xe at {approx} 1 atm. The OMEGA experiments heated the gas with 20 kJ of 3{omega} ({approx} 350 nm) laser energy delivered in a 1 ns square pulse. the emitted x-ray flux was monitored with the x-ray diode based DANTE instruments in the sub-keV range. Two-dimensional x-ray images (for energies 3-5 keV) of the targets were recorded with gated x-ray detectors. The x-ray spectra were recorded with the HENWAY crystal spectrometer at OMEGA. Predictions are 2D r-z cylindrical with DCA NLTE atomic physics. Models generally: (1) underpredict the Xe L-shell yields; (2) overpredict the Ar K-shell yields; (3) correctly predict the Xe thermal yields; and (4) greatly underpredict the Ar thermal yields. However, there are spreads within the data, e.g. the DMX Ar K-shell yields are correctly predicted. The predicted thermal yields show strong angular dependence.

  3. An Integrated Study Method For Exploration Of Gas Hydrate Reservoirs...

    Open Energy Info (EERE)

    and geochemistry. First, geological analysis is made using data of material sources, structures, sediments, and geothermal regimes to determine the hydrocarbon-formation conditions...

  4. Marine Electromagnetic Methods for Gas Hydrate Characterization, Gulf of Mexico

    E-Print Network [OSTI]

    Key, Kerry

    , October 7th ­ 26th 2008 Sponsors: CGG-Veritas, Chevron, emgs , ExxonMobil, Fugro, Shell, Statoil, Western to collect data, and data quality was excellent on all the rest. We also carried out a multibeam survey over

  5. Strategies for gas production from oceanic Class 3 hydrate accumulations

    E-Print Network [OSTI]

    Moridis, George J.; Reagan, Matthew T.

    2007-01-01

    where the local geothermal gradient may vary significantly,of the onshore geothermal gradient. Geological System

  6. FROZEN HEAT A GLOBAL OUTLOOK ON METHANE GAS HYDRATES EXECUTIVE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    energy demands, uncertainty about supplies, and the urgent need to reduce emissions of greenhouse gases mean that the world faces an uncertain energy future. Many countries have...

  7. CONTENTS Preliminary Results of China's Third Gas Hydrate Drilling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B LReports from the CloudGEGR-N Goods PO 1 of 8 GE4,Preliminary

  8. gas-hydrate-global-assessment | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAboutXu Named| Princetondefault Sign InEnhancedFuel Oil Usage

  9. Rapid Gas Hydrate Formation Process - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on GlobalRachel2 RadiometerRafaelAnalysis (Conference)

  10. Oil and Gas Science and Technology, 2009, 64(5), 629-636, doi: 10.2516/ogst/2009042 DDDiiissscccuuussssssiiiooonnn ooofff aaagggggglllooommmeeerrraaatttiiiooonnn mmmeeeccchhhaaannniiisssmmmsss bbbeeetttwwweeeeeennn hhhyyydddrrraaattteee

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oil and Gas Science and Technology, 2009, 64(5), 629-636, doi: 10.2516/ogst/2009042 1. KKeeyywwoorrddss:: gas hydrate formation ; water/oil emulsions ; hydrate slurry ; agglomeration ; Population@emse.fr hal-00480033,version1-3May2010 Author manuscript, published in "Oil & Gas Science and Technology 64, 5

  11. Formation of gas-phase peroxides in a rural atmosphere: An interpretation of the recent SOS/SERON field results

    SciTech Connect (OSTI)

    Lee, J.H.; Tang, I.N. [Brookhaven National Lab., Upton, NY (United States); Weinstein-Lloyd, J.B. [State Univ. of New York, Old Westbury, NY (United States). Chemistry/Physics Dept.

    1993-09-01

    Hydrogen perioxide (H{sub 2}O{sub 2}) and certain organic peroxides such as hydroxymethyl-hydroperoxide (HMHP), are gas-phase oxidants present in the atmosphere at ppbv concentration levels. These oxidants play an important role in atmospheric chemistry. In addition, precipitation containing H{sub 2}O{sub 2} is toxic to trees, and it has also been suggested that organic peroxides formed presumably by ozone reactions with biogenic alkenes are responsible for leaf disorders. Recently, we have developed a nonenzymatic method or aqueous-phase H{sub 2}O{sub 2} measurement, using Fenton reagent and fluorescent hydroxy- benzoic acid. The new method, in conjunction with the well-known method of p-hydroxyphenylacetic acid and horseradish peroxidase for total peroxides, and together with an improved gas scrubber to mitigate sampling line problems, has been successfully deployed in recent SOS/SERON field measurements in rural Georgia. For the first time, continuously measured and speciated gas-phase peroxide data have become available, making it possible to examine some aspects of the ozone chemistry leading to the formation of these oxidants. It is observed that daily H{sub 2}O{sub 2} maximum frequently occurs at a different time than does HMHP, and that H{sub 2}O{sub 2} concentration, but not HMHP, tends to correlate with solar fluxes measured at the same location. These findings seem to indicate that the formation mechanisms for H{sub 2}O{sub 2} and organic peroxides are basically different. It is likely that H{sub 2}O{sub 2} is formed from radical-radical recombination, while HMHP is formed by ozone-alkene reactions. Since the gas-phase ozone-alkene reactions are usually too slow to account for the diurnal concentration variations observed for HMHP, heterogeneous processes involving ozone and alkenes are also a possibility.

  12. Van't Hoff law for temperature dependent Langmuir constants in clathrate hydrate nanocavities

    E-Print Network [OSTI]

    Lakhlifi, Azzedine

    2015-01-01

    This work gives a van't Hoff law expression of Langmuir constants of different species for determining their occupancy in the nanocavities of clathrate hydrates. The van't Hoff law's parameters are derived from a fit with Langmuir constants calculated using a pairwise site-site interaction potential to model the anisotropic potential environment in the cavities, as a function of temperature. The parameters can be used for calculating clathrates compositions. Results are given for nineteen gas species trapped in the small and large cavities of structure types I and II [1]. The accuracy of this approach is based on a comparison with available experimental data for ethane and cyclo- propane clathrate hydrates. The numerical method applied in this work, was recently validated from a comparison with the spherical cell method based on analytical considerations [1

  13. Depositional environment and reservoir morphology of the Upper Wilcox sandstones, Katy gas field, Waller County, Texas 

    E-Print Network [OSTI]

    DePaul, Gilbert John

    1979-01-01

    and structural characteristics of the field. The Upper Wilcox is divided into the following units, in ascending order, "First Lower Massive" sandstones and "D", "C", "B", "A", "Second Wilcox" and "First Wilcox" interbedded sandstones and shales. The reservoir... and are generally abruptly overla1n by sandstones with sharp or erosional bases. The sandstones change laterally to thin sandstones interlaminated with thick shales. The thick sandstones are submarine, constructional- channel deposits with associated thin...

  14. Adaptive Management and Planning Models for Cultural Resources in Oil and Gas Fields in New Mexico and Wyoming

    SciTech Connect (OSTI)

    Eckerle, William; Hall, Stephen

    2005-12-30

    In 2002, Gnomon, Inc., entered into a cooperative agreement with the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) for a project entitled, Adaptive Management and Planning Models for Cultural Resources in Oil and Gas Fields in New Mexico and Wyoming (DE-FC26-02NT15445). This project, funded through DOE’s Preferred Upstream Management Practices grant program, examined cultural resource management practices in two major oil- and gas-producing areas, southeastern New Mexico and the Powder River Basin of Wyoming (Figure 1). The purpose of this project was to examine how cultural resources have been investigated and managed and to identify more effective management practices. The project also was designed to build information technology and modeling tools to meet both current and future management needs. The goals of the project were described in the original proposal as follows: Goal 1. Create seamless information systems for the project areas. Goal 2. Examine what we have learned from archaeological work in the southeastern New Mexico oil fields and whether there are better ways to gain additional knowledge more rapidly or at a lower cost. Goal 3. Provide useful sensitivity models for planning, management, and as guidelines for field investigations. Goal 4. Integrate management, investigation, and decision- making in a real-time electronic system. Gnomon, Inc., in partnership with the Wyoming State Historic Preservation Office (WYSHPO) and Western GeoArch Research, carried out the Wyoming portion of the project. SRI Foundation, in partnership with the New Mexico Historic Preservation Division (NMHPD), Statistical Research, Inc., and Red Rock Geological Enterprises, completed the New Mexico component of the project. Both the New Mexico and Wyoming summaries concluded with recommendations how cultural resource management (CRM) processes might be modified based on the findings of this research.

  15. Evaluation of water production in tight gas sands in the Cotton Valley formation in the Caspiana, Elm Grove and Frierson fields 

    E-Print Network [OSTI]

    Ozobeme, Charles Chinedu

    2007-04-25

    in the Elm Grove and Caspiana fields. 3 Fig. 1.2: Distribution of Cotton Valley Reservoirs across East Texas and North Louisiana. (Source - Collins 2 ) CV Lime Producing Trend. CV Blanket Sands . Good porosity and permeability..., no fracturing required. CV Massive Sands . Low permeability and porosity, require fracturing. CV Sand Fields. CV Lime Fields. 4 1.2 The Cotton Valley Formation in Northwest Louisiana The Cotton Valley formation is a tight gas sand play...

  16. Methane Hydrate Dissociation by Depressurization in a Mount Elbert Sandstone Sample: Experimental Observations and Numerical Simulations

    E-Print Network [OSTI]

    Kneafsey, T.

    2012-01-01

    S.S.H. , 1987. Kinetics of Methane Hydrate Decomposition,T. J. , et al. (2007), Methane Hydrate Formation andCharting the future of methane hydrate research in the

  17. ,"Underground Natural Gas Storage - Storage Fields Other than Salt Caverns"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEtGeorgia:Illinois:WizardYatescloudDataAge Refining AirA1.AllStorage Fields

  18. An Intelligent Portfolio Management Approach to Gas Storage Field Deliverability Maintenance and

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    = - = + - - = - - = scscsc sc sc scscsc scsc sc t ggqN q qN b ggqN qq q a 2 2 2 6 6 2 1 10 log 3.23 0.869 1.632 10 t i i w kh · Flowing Pr 1 · Rate 1 · Time Extended · Field Pr Extend · Flowing Pr Extend · Rate Extend · n Value · C Analysis #12;2 2 ( 0 )n AOF C p= - ( 250,000)n PDRate C= × 2 2 ( ) g n wf q C p p = - 2 R wf t sc sca q bq

  19. Creation and recovery of a W(111) single atom gas field ion source

    SciTech Connect (OSTI)

    Pitters, Jason L. [National Institute for Nanotechnology, National Research Council of Canada, Edmonton, Alberta T6G 2M9 (Canada); Urban, Radovan [Department of Physics, University of Alberta, Edmonton, Alberta T6G 2G7 (Canada); Wolkow, Robert A. [National Institute for Nanotechnology, National Research Council of Canada, Edmonton, Alberta T6G 2M9 (Canada); Department of Physics, University of Alberta, Edmonton, Alberta T6G 2G7 (Canada)

    2012-04-21

    Tungsten single atom tips have been prepared from a single crystal W(111) oriented wire using the chemical assisted field evaporation and etching method. Etching to a single atom tip occurs through a symmetric structure and leads to a predictable last atom unlike etching with polycrystalline tips. The single atom tip formation procedure is shown in an atom by atom removal process. Rebuilds of single atom tips occur on the same crystalline axis as the original tip such that ion emission emanates along a fixed direction for all tip rebuilds. This preparation method could be utilized and developed to prepare single atom tips for ion source development.

  20. New York Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear Jan Feb Mar Apr May Jun JulFeet) New Field

  1. Ohio Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear JanNew Field Discoveries (Billion Cubic Feet) Ohio Dry

  2. Oklahoma Dry Natural Gas New Reservoir Discoveries in Old Fields (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYear JanNew FieldDecade Year-0 Year-1VentedMonth799338Cubic

  3. Texas Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome6,672 7,2060Year0 0New Field

  4. U.S. Dry Natural Gas Reserves New Field Discoveries (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of the NationalSales (Million Barrels)New Field Discoveries

  5. U.S. Natural Gas Underground Storage Depleted Fields Capacity (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubic Feet) Depleted Fields Capacity (Million Cubic

  6. U.S. Natural Gas, Wet After Lease Separation Reserves New Field Discoveries

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubic Feet) Depleted Fields(Billion Cubic Feet)

  7. West Virginia Dry Natural Gas Reserves New Field Discoveries (Billion Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal,Demand Module of theCubicEstimation10,428 (Million20 21Feet) New Field

  8. Dry Gas Zone, Elk Hills field, Kern County, California: General reservoir study: Engineering text and exhibits: (Final report)

    SciTech Connect (OSTI)

    Not Available

    1988-08-01

    The Dry Gas Zone in the Elk Hills field is comprised of fourteen separate productive horizons deposited in the MYA Group of the San Joaquin Formation of Pliocene Age. Eighty-six separate Reservoir Units have been identified within the interval over an area roughly ten miles long and four miles wide. One basal Tulare sand, the Tulare B, was also included in the geologic study. Five earlier studies have been made of the Dry Gas Zone; each is referenced in the Appendix of this report. Most of these studies were geologic in nature, and none provided in-depth reservoir analyses. This report is made up of ten (10) separate volumes which include: engineering text and exhibits (white dot); engineering data (black dot); geologic text and tables (green dot); structure and isochore maps (light blue dot); structural cross sections (dark blue dot); stratigraphic cross sections (brown dot); geologic data sheets -book 1 (yellow dot); geologic data sheets - book 2 (orange dot); geologic data sheets - book 3 (red dot); and geologic data sheets - book 4 (pink or coral dot). Basic production, injection, pressure, and other assorted technical data were provided by the US Department of Energy engineering staff at Elk Hills. These data were accepted as furnished with no attempt being made at independent verification.

  9. Methane Hydrate Dissociation by Depressurization in a Mount Elbert Sandstone Sample: Experimental Observations and Numerical Simulations

    E-Print Network [OSTI]

    Kneafsey, T.

    2012-01-01

    in a Mount Elbert Sandstone Sample: Experimentalsample of hydrate-bearing sandstone from the Mount Elbertsample of hydrate-bearing sandstone from the Mount Elbert

  10. Fundamental measure theory of hydrated hydrocarbons

    E-Print Network [OSTI]

    Victor F. Sokolov; Gennady N. Chuev

    2006-04-13

    To calculate the solvation of hydrophobic solutes we have developed the method based on the fundamental measure treatment of the density functional theory. This method allows us to carry out calculations of density profiles and the solvation energy for various hydrophobic molecules with a high accuracy. We have applied the method to the hydration of various hydrocarbons (linear, branched and cyclic). The calculations of the entropic and the enthalpic parts are also carried out. We have examined a question about temperature dependence of the entropy convergence. Finally, we have calculated the mean force potential between two large hydrophobic nanoparticles immersed in water.

  11. Inter-cage dynamics in structure I, II, and H fluoromethane hydrates as studied by NMR and molecular dynamics simulations

    SciTech Connect (OSTI)

    Trueba, Alondra Torres; Kroon, Maaike C.; Peters, Cor J.; Moudrakovski, Igor L.; Ratcliffe, Christopher I.; Ripmeester, John A.; Alavi, Saman

    2014-06-07

    Prospective industrial applications of clathrate hydrates as materials for gas separation require further knowledge of cavity distortion, cavity selectivity, and defects induction by guest-host interactions. The results presented in this contribution show that under certain temperature conditions the guest combination of CH{sub 3}F and a large polar molecule induces defects on the clathrate hydrate framework that allow intercage guest dynamics. {sup 13}C NMR chemical shifts of a CH{sub 3}F/CH{sub 4}/TBME sH hydrate and a temperature analysis of the {sup 2}H NMR powder lineshapes of a CD{sub 3}F/THF sII and CD{sub 3}F/TBME sH hydrate, displayed evidence that the populations of CH{sub 4} and CH{sub 3}F in the D and D{sup ?} cages were in a state of rapid exchange. A hydrogen bonding analysis using molecular dynamics simulations on the TBME/CH{sub 3}F and TBME/CH{sub 4} sH hydrates showed that the presence of CH{sub 3}F enhances the hydrogen bonding probability of the TBME molecule with the water molecules of the cavity. Similar results were obtained for THF/CH{sub 3}F and THF/CH{sub 4} sII hydrates. The enhanced hydrogen bond formation leads to the formation of defects in the water hydrogen bonding lattice and this can enhance the migration of CH{sub 3}F molecules between adjacent small cages.

  12. Secondary natural gas recovery: Targeted applications for infield reserve growth in midcontinent reservoirs, Boonsville Field, Fort Worth Basin, Texas. Topical report, May 1993--June 1995

    SciTech Connect (OSTI)

    Hardage, B.A.; Carr, D.L.; Finley, R.J.; Tyler, N.; Lancaster, D.E.; Elphick, R.Y.; Ballard, J.R.

    1995-07-01

    The objectives of this project are to define undrained or incompletely drained reservoir compartments controlled primarily by depositional heterogeneity in a low-accommodation, cratonic Midcontinent depositional setting, and, afterwards, to develop and transfer to producers strategies for infield reserve growth of natural gas. Integrated geologic, geophysical, reservoir engineering, and petrophysical evaluations are described in complex difficult-to-characterize fluvial and deltaic reservoirs in Boonsville (Bend Conglomerate Gas) field, a large, mature gas field located in the Fort Worth Basin of North Texas. The purpose of this project is to demonstrate approaches to overcoming the reservoir complexity, targeting the gas resource, and doing so using state-of-the-art technologies being applied by a large cross section of Midcontinent operators.

  13. RHEOLOGICAL STUDY OF AN HYDRATE SLURRY FOR AIR CONDITIONNING APPLICATION

    E-Print Network [OSTI]

    Boyer, Edmond

    Saint-Etienne France ABSTRACT Under atmospheric pressure condition and temperatures between 0°C and +12 behaviour. The experimental device is made up of a brushed surface heat exchanger in which the hydrates flow rates and pressure drops measurements. We obtain flow curves of hydrates slurries depending

  14. field

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4) August 20123/%2A en46Afed feed families |fff |

  15. Towards bio-silicon interfaces: Formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan

    E-Print Network [OSTI]

    . 133, 164505 (2010); 10.1063/1.3495973 Phase separation in three-component lipid membranes: From MonteTowards bio-silicon interfaces: Formation of an ultra-thin self-hydrated artificial membrane composed of dipalmitoylphosphatidylcholine (DPPC) and chitosan deposited in high vacuum from the gas

  16. Probabilistic approach to the length-scale dependence of the effect of water hydrogen bonding on hydrophobic hydration

    E-Print Network [OSTI]

    Yuri S. Djikaev; Eli Ruckenstein

    2013-03-18

    We present a probabilistic approach to water-water hydrogen bonding that allows one to obtain an analytic expression for the number of bonds per water molecule as a function of both its distance to a hydrophobic particle and hydrophobe radius. This approach can be used in the density functional theory (DFT) and computer simulations to examine particle size effects on the hydration of particles and on their solvent-mediated interaction. For example, it allows one to explicitly identify a water hydrogen bond contribution to the external potential whereto a water molecule is subjected near a hydrophobe. The DFT implementation of the model predicts the hydration free energy per unit area of a spherical hydrophobe to be sharply sensitive to the hydropobe radius for small radii and weakly sensitive thereto for large ones; this corroborates the vision of the hydration of small and large length-scale particles as occurring via different mechanisms. On the other hand, the model predicts that the hydration of even apolar particles of small enough radii may become thermodynamically favorable owing to the interplay of the energies of pairwise (dispersion) water-water and water-hydrophobe interactions. This sheds light on previous counterintuitive observations (both theoretical and simulational) that two inert gas molecules would prefer to form a solvent-separated pair rather than a contact one.

  17. Seventy-seventh annual convention Gas Processors Association: Proceedings

    SciTech Connect (OSTI)

    NONE

    1998-12-31

    The 42 papers in these proceedings discuss the following topics: gas hydrates; gas transport; emission abatement; acid gas disposal; control of processing plants; NGL and LPG recovery; marketing; underground storage; NGL fractionation; and plant optimization. Papers have been processed separately for inclusion on the data base.

  18. A comparison of microseismicity induced by gel-proppant-and water-injected hydraulic fractures, Carthage Cotton Valley gas field, East Texas

    E-Print Network [OSTI]

    A comparison of microseismicity induced by gel-proppant- and water-injected hydraulic fractures induced during a series of hydraulic fracture completions within the Cotton Valley formation of East Texas a series of hydraulic fracture imaging tests in the Carthage Cotton Valley gas field of East Texas (Walker

  19. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  20. Field data on testing of natural gas vehicle (NGV) containers using proposed ASTM standard test method for examination of gas-filled filament-wound pressure vessels using acoustic emission (ASTM-E070403-95/1)

    SciTech Connect (OSTI)

    Fultineer, R.D. Jr.; Mitchell, J.R.

    1999-07-01

    There are many composite wrapped pressure vessels in service. These containers are most widely used for gas storage in natural gas vehicles (NGV). A standard has been developed for the testing of these vessels by the subcommittee ASTM E07.04.03 Acoustic Emission (AE) applications. The AE test method is supported by both field test data and laboratory destructive testing. The test method describes a global volumetric testing technique which is offered as an alternative to the current practice of visual inspection.

  1. DPF -"Hydrated EGR" Fuel Saver System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications GreenPower Trap Water-Muffler System GreenPowerTM Trap-Muffler System Diesel NOx-PM Reduction with Fuel Economy Increase by IMET-OBC-DPF + Hydrated-EGR System for...

  2. Geotechnical characterization of sediments from Hydrate Ridge, Cascadia Continental Margin

    E-Print Network [OSTI]

    Tan, Brian B. (Brian Bautista), 1979-

    2004-01-01

    Eight whole core sediment samples were obtained from ODP Site 1244, Hydrate Ridge, Cascadia Continental Margin with the goal of understanding the stress history, consolidation behavior and strength characteristics of the ...

  3. Hydration water dynamics and instigation of protein structural relaxation

    E-Print Network [OSTI]

    Russo, Daniela; Hura, Greg; Head-Gordon, Teresa

    2008-01-01

    the dipole vector of the water molecule at times t and 0.the rotational dynamics of water molecules that maintained aHydration Water Dynamics and Instigation of Protein

  4. In-Situ Sampling and Characterization of Naturally Occurring Marine Methane Hydrate Using the D/V JOIDES Resolution

    SciTech Connect (OSTI)

    Rack, Frank

    2003-06-30

    The primary accomplishments of the JOI Cooperative Agreement with DOE/NETL in this quarter were that: (1) Frank Rack, Anne Trehu, and Tim Collett presented preliminary results and operational outcomes of ODP Leg 204 at the American Association of Petroleum Geologists annual meeting in Salt Lake City, UT; (2) several Leg 204 scientists participated in special hydrate sessions at the international EGS/AGU/EUG meeting in Nice, France and presented initial science results from the cruise, which included outcomes arising from this cooperative agreement; and, (3) postcruise evaluation of the data, tools and measurement systems that were used during ODP Leg 204 continued in the preparation of deliverables under this agreement. At the EGS/EUG/AGU meeting in Nice, France in April, Leg 204 Co-chiefs Anne Trehu and Gerhard Bohrmann, as well as ODP scientists Charlie Paull, Erwin Suess, and Jim Kennett, participated in a press conference on hydrates. The well-attended press conference entitled ''Gas Hydrates: Free methane found and controversy over the 'hydrate gun''' led to stories in Nature on-line and BBC radio, among others. There were six (6) oral and fifteen (15) poster presentations on ODP Leg 204 hydrate science at the EGS/AGU/EUG Meeting in Nice, France on April 6-11, 2003. This was a very strong showing at a meeting just over six month following the completion of the drilling cruise and highlighted many of the results of the leg, including the results obtained with instruments and equipment funded under this cooperative agreement. At the AAPG annual meeting in Salt Lake City, UT on May 11-14, 2003, Anne Trehu gave an oral presentation about the scientific results of Leg 204, and Frank Rack presented a poster outlining the operational and technical accomplishments. Work continued on analyzing data collected during ODP Leg 204 and preparing reports on the outcomes of Phase 1 projects as well as developing plans for Phase 2.

  5. Phase-field simulations of intragranular fission gas bubble evolution in UO2 under post-irradiation thermal annealing

    SciTech Connect (OSTI)

    Li, Yulan; Hu, Shenyang Y.; Montgomery, Robert O.; Gao, Fei; Sun, Xin

    2013-05-15

    Fission gas bubble is one of evolving microstructures, which affect thermal mechanical properties such as thermo-conductivity, gas release, volume swelling, and cracking, in operating nuclear fuels. Therefore, fundamental understanding of gas bubble evolution kinetics is essential to predict the thermodynamic property and performance changes of fuels. In this work, a generic phasefield model was developed to describe the evolution kinetics of intra-granular fission gas bubbles in UO2 fuels under post-irradiation thermal annealing conditions. Free energy functional and model parameters are evaluated from atomistic simulations and experiments. Critical nuclei size of the gas bubble and gas bubble evolution were simulated. A linear relationship between logarithmic bubble number density and logarithmic mean bubble diameter is predicted which is in a good agreement with experimental data.

  6. For the first 15 years of my life, I lived in the shadow of the oil and gas fields of South Louisiana and became accustomed to the oil indus-

    E-Print Network [OSTI]

    Stephens, Jacqueline

    For the first 15 years of my life, I lived in the shadow of the oil and gas fields of South jobs and how they worked together to drill and explore for oil and gas. It was no wonder then that I in building the oil and gas assets in Enerfin Resources over a 20 year period to over $250 million. After

  7. The structure of the hydrated electron in bulk and at interfaces: Does the hydrated electron occupy a cavity?

    E-Print Network [OSTI]

    Casey, Jennifer Ryan

    2014-01-01

    Cavity and Non-cavity Hydrated Elec- tron at the Air/Waterrelaxation dynamics at water/air interfaces. J. Chem.Electronic states at the water/air interface. J. Phys. Chem.

  8. The U.S. DOE Methane Hydrate R&D Program DOE Sponsored Student Researchers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. Jeffrey GriffinHydratesTri-PartyU.S. DOE Methane

  9. Polarization and Charge Transfer in the Hydration of Chloride Ions

    E-Print Network [OSTI]

    Zhen Zhao; David M. Rogers; Thomas L. Beck

    2009-12-14

    A theoretical study of the structural and electronic properties of the chloride ion and water molecules in the first hydration shell is presented. The calculations are performed on an ensemble of configurations obtained from molecular dynamics simulations of a single chloride ion in bulk water. The simulations utilize the polarizable AMOEBA force field for trajectory generation, and MP2-level calculations are performed to examine the electronic structure properties of the ions and surrounding waters in the external field of more distant waters. The ChelpG method is employed to explore the effective charges and dipoles on the chloride ions and first-shell waters. The Quantum Theory of Atoms in Molecules (QTAIM) is further utilized to examine charge transfer from the anion to surrounding water molecules. From the QTAIM analysis, 0.2 elementary charges are transferred from the ion to the first-shell water molecules. The default AMOEBA model overestimates the average dipole moment magnitude of the ion compared with the estimated quantum mechanical value. The average magnitude of the dipole moment of the water molecules in the first shell treated at the MP2 level, with the more distant waters handled with an AMOEBA effective charge model, is 2.67 D. This value is close to the AMOEBA result for first-shell waters (2.72 D) and is slightly reduced from the bulk AMOEBA value (2.78 D). The magnitude of the dipole moment of the water molecules in the first solvation shell is most strongly affected by the local water-water interactions and hydrogen bonds with the second solvation shell, rather than by interactions with the ion.

  10. Field Laboratory in the Osage Reservation -- Determination of the Status of Oil and Gas Operations: Task 1. Development of Survey Procedures and Protocols

    SciTech Connect (OSTI)

    Carroll, Herbert B.; Johnson, William I.

    1999-04-27

    Procedures and protocols were developed for the determination of the status of oil, gas, and other mineral operations on the Osage Mineral Reservation Estate. The strategy for surveying Osage County, Oklahoma, was developed and then tested in the field. Two Osage Tribal Council members and two Native American college students (who are members of the Osage Tribe) were trained in the field as a test of the procedures and protocols developed in Task 1. Active and inactive surface mining operations, industrial sites, and hydrocarbon-producing fields were located on maps of the county, which was divided into four more or less equal areas for future investigation. Field testing of the procedures, protocols, and training was successful. No significant damage was found at petroleum production operations in a relatively new production operation and in a mature waterflood operation.

  11. UONPR No. 1, Elk Hills, 26R Reservoir, Elk Hills oil and gas field, Kern County, California: Management Review: Surface operations and measurements of production and injection volumes

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    Evans, Carey and Crozier was given the task to conduct a Management Review of the Surface Operations of the 26R Reservoir in UONPR No. 1, Elk Hills field, Kern County, California. The MER strategy for this reservoir is to maintain pressure, and toward this end, gas injection volumes are scheduled to amount to 110% of calculated withdrawals. In spite of this, however, reservoir pressure continues to decline. The purpose of this study was, therefore, to determine if, and to what extent, field operating practices and accounting procedures may be contributing to this dilemma and to make appropriate recommendations pertaining to correcting any deficiencies which may have been found.

  12. Fluid pressure arrival time tomography: Estimation and assessment in the presence of inequality constraints, with an application to a producing gas field at Krechba, Algeria

    SciTech Connect (OSTI)

    Rucci, A.; Vasco, D.W.; Novali, F.

    2010-04-01

    Deformation in the overburden proves useful in deducing spatial and temporal changes in the volume of a producing reservoir. Based upon these changes we estimate diffusive travel times associated with the transient flow due to production, and then, as the solution of a linear inverse problem, the effective permeability of the reservoir. An advantage an approach based upon travel times, as opposed to one based upon the amplitude of surface deformation, is that it is much less sensitive to the exact geomechanical properties of the reservoir and overburden. Inequalities constrain the inversion, under the assumption that the fluid production only results in pore volume decreases within the reservoir. We apply the formulation to satellite-based estimates of deformation in the material overlying a thin gas production zone at the Krechba field in Algeria. The peak displacement after three years of gas production is approximately 0.5 cm, overlying the eastern margin of the anticlinal structure defining the gas field. Using data from 15 irregularly-spaced images of range change, we calculate the diffusive travel times associated with the startup of a gas production well. The inequality constraints are incorporated into the estimates of model parameter resolution and covariance, improving the resolution by roughly 30 to 40%.

  13. A Methodology for the Assessment of Unconventional (Continuous) Resources with an Application to the Greater Natural Buttes Gas Field, Utah

    SciTech Connect (OSTI)

    Olea, Ricardo A.; Cook, Troy A.; Coleman, James L.

    2010-12-15

    The Greater Natural Buttes tight natural gas field is an unconventional (continuous) accumulation in the Uinta Basin, Utah, that began production in the early 1950s from the Upper Cretaceous Mesaverde Group. Three years later, production was extended to the Eocene Wasatch Formation. With the exclusion of 1100 non-productive ('dry') wells, we estimate that the final recovery from the 2500 producing wells existing in 2007 will be about 1.7 trillion standard cubic feet (TSCF) (48.2 billion cubic meters (BCM)). The use of estimated ultimate recovery (EUR) per well is common in assessments of unconventional resources, and it is one of the main sources of information to forecast undiscovered resources. Each calculated recovery value has an associated drainage area that generally varies from well to well and that can be mathematically subdivided into elemental subareas of constant size and shape called cells. Recovery per 5-acre cells at Greater Natural Buttes shows spatial correlation; hence, statistical approaches that ignore this correlation when inferring EUR values for untested cells do not take full advantage of all the information contained in the data. More critically, resulting models do not match the style of spatial EUR fluctuations observed in nature. This study takes a new approach by applying spatial statistics to model geographical variation of cell EUR taking into account spatial correlation and the influence of fractures. We applied sequential indicator simulation to model non-productive cells, while spatial mapping of cell EUR was obtained by applying sequential Gaussian simulation to provide multiple versions of reality (realizations) having equal chances of being the correct model. For each realization, summation of EUR in cells not drained by the existing wells allowed preparation of a stochastic prediction of undiscovered resources, which range between 2.6 and 3.4 TSCF (73.6 and 96.3 BCM) with a mean of 2.9 TSCF (82.1 BCM) for Greater Natural Buttes. A second approach illustrates the application of multiple-point simulation to assess a hypothetical frontier area for which there is no production information but which is regarded as being similar to Greater Natural Buttes.

  14. A method for measuring methane oxidation rates using low levels of 14C-labeled methane and accelerator mass spectrometry

    E-Print Network [OSTI]

    2011-01-01

    the anaerobic oxidation of methane. Environ. Microbiol. 10(Field observations of methane concentra- tions and oxidationAnaerobic oxidation of methane above gas hydrates at Hydrate

  15. MethaneHydrateRD_FC.indd

    Office of Environmental Management (EM)

    gas is an important energy resource for the United States, providing nearly one-quarter of total energy use. The Department of Energy's Office of Fossil Energy (FE) has played a...

  16. Laboratory measurements on core-scale sediment/hydrate samples to predice reservoir behavior

    E-Print Network [OSTI]

    Kneafsey, Timothy J.; Seol, Yongkoo; Moridis, George J.; Tomutsa, Liviu; Freifeld, Barry M.

    2008-01-01

    examination of field and laboratory samples using a varietyLawrence Berkeley National Laboratory Report LBNL-40400.containing natural and laboratory-formed methane gas

  17. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    M. F. , Northern California oil and gas field production.California, Division of Oil, Gas and Geothermal Resources;Beaumont EA, eds. , Atlas of Oil and Gas Fields, Structural

  18. Dynamics of biopolymers and their hydration water studied by neutron and X-ray scattering

    E-Print Network [OSTI]

    Chu, Xiang-qiang

    2010-01-01

    Protein functions are intimately related to their dynamics. Moreover, protein hydration water is believed to have significant influence on the dynamics of proteins. One of the evidence is that both protein and its hydration ...

  19. Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

    E-Print Network [OSTI]

    Suo, Zhigang

    Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt 2014; published online 14 October 2014) Polyacrylamide hydrogels containing salt as electrolyte have of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced

  20. Promotion of n-Butane isomerization activity by hydration of sulfated zirconia

    SciTech Connect (OSTI)

    Gonzalez, M.R.; Kobe, J.M.; Fogash, K.B.; Dumesic, J.A.

    1996-05-01

    The effects of sulfated zirconia catalyst hydration on the activity for n-butane isomerization is reported. The catalytic activity of of a partially hydrated catalyst is enhanced. 66 refs., 11 figs.

  1. Hydration kinetics modeling of Portland cement considering the effects of curing temperature and applied pressure

    E-Print Network [OSTI]

    Meyer, Christian

    pressure. However, elevated temperatures and high pressures are frequently encountered in oil wells whereHydration kinetics modeling of Portland cement considering the effects of curing temperature 2006 Accepted 28 January 2009 Keywords: Hydration Kinetics Portland cement Modeling Thermodynamics

  2. Protein structure and hydration probed by SANS and osmotic stress

    SciTech Connect (OSTI)

    Rau, Dr. Donald [National Institutes of Health

    2008-01-01

    Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

  3. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  4. High-surface-area hydrated lime for SO2 control

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Moran, D.L. (Illinois State Geological Survey, Champaign, IL (United States). Minerals Engineering Section)

    1993-03-01

    Since 1986, the Illinois State Geological Survey (ISGS), has been developing a process to produce high-surface-area hydrated lime (HSAHL) with more activity for adsorbing SO2 than commercially available hydrated lime. HSAHL prepared by the ISGS method as considerably higher surface area and porosity, and smaller mean particle diameter and crystallite size than commercial hydrated lime. The process has been optimized in a batch, bench-scale reactor and has been scaled-up to a 20--100 lb/hr process optimization unit (POU). Experiments have been conducted to optimize the ISGS hydration process and identify key parameters influencing hydrate properties for SO2 capture (surface area, porosity, particle size, and crystallite size). The known how is available to tailor properties of hydrated limes for specific SO2 removal applications. Pilot-scale tests conducted with the HSAHL under conditions typical of burning high-sulfur coals have achieved up to 90% SO2 capture in various DSI systems. The removal results are enough to bring most high-sulfur coals into compliance with acid rain legislation goals for the year 2000. The focus of the POU program is to generate critical engineering data necessary for the private sector to scale-up the process to a commercial level and provide estimates of the optimal cost of construction and operation of a commercial plant. ISGS is currently participating in a clean coal technology program (CCT-1) by providing 50 tons of HSAHL for a demonstration test at Illinois Power's Hennepin station in January 1993.

  5. An evaluation of the deep reservoir conditions of the Bacon-Manito geothermal field, Philippines using well gas chemistry

    SciTech Connect (OSTI)

    D'Amore, Franco; Maniquis-Buenviaje, Marinela; Solis, Ramonito P.

    1993-01-28

    Gas chemistry from 28 wells complement water chemistry and physical data in developing a reservoir model for the Bacon-Manito geothermal project (BMGP), Philippines. Reservoir temperature, THSH, and steam fraction, y, are calculated or extrapolated from the grid defined by the Fischer-Tropsch (FT) and H2-H2S (HSH) gas equilibria reactions. A correction is made for H2 that is lost due to preferential partitioning into the vapor phase and the reequilibration of H2S after steam loss.

  6. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    the purpose of reservoir characterization. Well testing andhave been used for reservoir characterization. Significant

  7. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    et al. , Initial seismic interpretation indicated a range ofmethod for interpretation of cross-well seismic data fromanalysis and interpretation of available 3-D and 2-D seismic

  8. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    to the sediments, and subsidence. The problem is at itsof pressure depletion on subsidence and stress is shown inand vertical displacement (subsidence) are approximately

  9. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    et al. , Initial seismic interpretation indicated a range ofmethod for interpretation of cross-well seismic data fromand interpretation of available 3-D and 2-D seismic data

  10. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    the value of the product (oil), heavy oil developments canin the wellbore (common in heavy oil operations). Casingused effectively in heavy oil applications. Steam applied in

  11. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    with freeze-depressed drilling fluids chilled to below 32 odrilling techniques, which allows maximum cooling of the coring fluid

  12. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    throughout the world. Deepwater drilling technology andall deepwater wells) to support the loads from the drillingdrilling through the clay-dominated sediments that typify the shallow sub-seafloor in the deepwater

  13. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    in the wellbore (common in heavy oil operations). Casingused effectively in heavy oil applications. Steam applied insome limited success. Heavy oil wells are typically quite

  14. Monitoring the hydration of cement using highly nonlinear solitary waves Xianglei Ni a

    E-Print Network [OSTI]

    Daraio, Chiara

    Monitoring the hydration of cement using highly nonlinear solitary waves Xianglei Ni Available online 22 May 2012 Keywords: Highly nonlinear solitary waves Cement Hydration Nondestructive on the propagation of highly nonlinear solitary waves (HNSWs) to monitor the hydration of cement. HNSWs

  15. A Comparison Study of Portland Cement Hydration Kinetics as Measured by Chemical Shrinkage and Isothermal Calorimetry

    E-Print Network [OSTI]

    Bentz, Dale P.

    1 A Comparison Study of Portland Cement Hydration Kinetics as Measured by Chemical Shrinkage methods of evaluating cement hydration kinetics, namely chemical shrinkage and isothermal calorimetry tests, are used to investigate the early stage hydration of different classes of oilwell cement

  16. Aalborg Universitet Modelling and Validation of Water Hydration of PEM Fuel Cell Membrane in Dynamic

    E-Print Network [OSTI]

    Liso, Vincenzo

    Aalborg Universitet Modelling and Validation of Water Hydration of PEM Fuel Cell Membrane of Water Hydration of PEM Fuel Cell Membrane in Dynamic Operations. In ECS Transactions. (Vol. 68). ECS from vbn.aau.dk on: november 29, 2015 #12;Modelling and Validation of Water Hydration of PEM Fuel Cell

  17. Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide

    E-Print Network [OSTI]

    Zeebe, Richard E.

    Kinetic fractionation of carbon and oxygen isotopes during hydration of carbon dioxide Richard E the inorganic hydration of carbon dioxide (CO2) in aqueous solution cause reduced stable carbon and oxygen of the carbon and oxygen kinetic isotope fractionation (KIF) during hydration of CO2. Here I use transition

  18. Review of disaster management implementation for the community safety in the vicinity of oil and gas field

    SciTech Connect (OSTI)

    Musa, R. Abdullah; Heni, Siti; Harjanto, Meddy

    2015-04-24

    Sukowati site which is operated by Production Sharing Contract (PSC) Joint Operating Body Pertamina Petrochina East Java (JOB P-PEJ) located at Bojonegoro regency East Java Province. This site is close to densely populated settlements with approximately 6,010 people within a radius less than 600 m. The fluid produced have a dangerous potential to the above mention community, due to accompanying of hydrogen sulphide gas (H2S) with a concentration about 0.6% – 2% from the total gas produced. In 2006, there was incident of gas leak from drilling development well of Sukowati # 5. The incident made the surrounding community panic due to lack of preparedness and awareness. Learning from the incident, the company together with the government and local communities initiated to make improvements through the disaster management system approach. The efforts are carried out in accordance with the 4 (four) periods in a continuous cycle consist of (1) mitigation; (2) preparation; (3) response and (4) recovery. Emergency response drills conducted regularly at least once a year, its main purpose is to find out the results of the implementation of the existing disaster management. The results of the drills showed an increase in public awareness and responsiveness to emergency situations caused by the operational failures of oil and gas exploration and production activities near their settlement.

  19. Advanced Gas Storage Concepts: Technologies for the Future

    SciTech Connect (OSTI)

    Freeway, Katy; Rogers, R.E.; DeVries, Kerry L.; Nieland, Joel D.; Ratigan, Joe L.; Mellegard, Kirby D.

    2000-02-01

    This full text product includes: 1) A final technical report titled Advanced Underground Gas Storage Concepts, Refrigerated-Mined Cavern Storage and presentations from two technology transfer workshops held in 1998 in Houston, Texas, and Pittsburgh, Pennsylvania (both on the topic of Chilled Gas Storage in Mined Caverns); 2) A final technical report titled Natural Gas Hydrates Storage Project, Final Report 1 October 1997 - 31 May 1999; 3) A final technical report titled Natural Gas Hydrates Storage Project Phase II: Conceptual Design and Economic Study, Final Report 9 June - 10 October 1999; 4) A final technical report titled Commerical Potential of Natural Gas Storage in Lined Rock Caverns (LRC) and presentations from a DOE-sponsored workshop on Alternative Gas Storage Technologies, held Feb 17, 2000 in Pittsburgh, PA; and 5) Phase I and Phase II topical reports titled Feasibility Study for Lowering the Minimum Gas Pressure in Solution-Mined Caverns Based on Geomechanical Analyses of Creep-Induced Damage and Healing.

  20. Time-dependent water dynamics in hydrated uranyl fluoride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Miskowiec, Andrew J.; Anderson, Brian B.; Herwig, Kenneth W.; Huq, Ashfia; Mamontov, Eugene; Rondinone, Adam; Trowbridge, Lee D.

    2015-09-15

    In this study, uranyl fluoride is a three-layer, hexagonal structure with significant stacking disorder in the c-direction. It supports a range of unsolved ‘thermodynamic’ hydrates with 0–2.5 water molecules per uranium atom, and perhaps more. However, the relationship between water, hydrate crystal structures, and thermodynamic results, collectively representing the chemical pathway through these hydrate structures, has not been sufficiently elucidated. We used high-resolution quasielastic neutron scattering to study the dynamics of water in partially hydrated uranyl fluoride powder over the course of 4 weeks under closed conditions. The spectra are composed of two quasielastic components: one is associated with translationalmore »diffusive motion of water that is approximately five to six times slower than bulk water, and the other is a slow (on the order of 2–300 ps), spatially bounded water motion. The translational component represents water diffusing between the weakly bonded layers in the crystal, while the bounded component may represent water trapped in subnanometre ‘pockets’ formed by the space between uranium-centred polymerisation units. Complementary neutron diffraction measurements do not show any significant structural changes, suggesting that a chemical conversion of the material does not occur in the thermodynamically isolated system on this timescale.« less