Sample records for gas flaring coal

  1. Recovering Flare Gas Energy - A Different Approach

    E-Print Network [OSTI]

    Brenner, W.

    depend on a compressor to pull suction on the pressurized flare line and pump the gas into a plant-wide fuer gas system. Because SunOlin shares its flare system with an adjacent oil refinery, any change to the flare system operation could have far... design and operating scheme incorporating the results of the HAZOP study. The major features of our flare gas recovery system, then, are as follows: A 30" main flare gas header originating in the adjacent oil refinery is routed through the Sun...

  2. Sauget Plant Flare Gas Reduction Project

    E-Print Network [OSTI]

    Ratkowski, D. P.

    2007-01-01T23:59:59.000Z

    Empirical analysis of stack gas heating value allowed the Afton Chemical Corporation Sauget Plant to reduce natural gas flow to its process flares by about 50% while maintaining the EPA-required minimum heating value of the gas streams....

  3. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYear Jan Feb Mar AprVented and Flared

  4. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.GasYear Jan Feb Mar AprVented and FlaredVented

  5. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    MEIYU SHEN; ROYCE ABBOTT; T.D. WHEELOCK

    1998-09-30T23:59:59.000Z

    The agglomeration of ultrafine-size coal particles in an aqueous suspension by means of microscopic gas bubbles was demonstrated in numerous experiments with a scale model mixing system. Coal samples from both the Pittsburgh No. 8 Seam and the Upper Freeport Seam were used for these experiments. A small amount of i-octane was added to facilitate the process. Microscopic gas bubbles were generated by saturating the water used for suspending coal particles with gas under pressure and then reducing the pressure. Microagglomerates were produced which appeared to consist of gas bubbles encapsulated in coal particles. Since dilute particle suspensions were employed, it was possible to monitor the progress of agglomeration by observing changes in turbidity. By such means it became apparent that the rate of agglomeration depends on the concentration of microscopic gas bubbles and to a lesser extent on the concentration of i-octane. Similar results were obtained with both Pittsburgh No. 8 coal and Upper Freeport coal.

  6. Natural Gas Vented and Flared

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough2,869,9601. Natural5,1958 20098

  7. Flare Gas Recovery in Shell Canada Refineries

    E-Print Network [OSTI]

    Allen, G. D.; Wey, R. E.; Chan, H. H.

    1983-01-01T23:59:59.000Z

    the flow properties for compressor selection? What controls should be incorporated? How much operator and maintenance effort will be required for safe, efficient operation? What kind of process and hardware problems should be watched for? When...? This paper will touch on all these issues. SYSTEM CONFIGURATION A schematic of a typical refinery flare gas recovery facility is shown in Figure I. The facilities include the following pieces of equipment: - compressor suction drum - compressor set...

  8. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14T23:59:59.000Z

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  9. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15T23:59:59.000Z

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  10. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31T23:59:59.000Z

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the strength of natural gas. The cost of producing oil is to a large extent the cost of electric power used to extract and deliver the oil. Researchers have identified stranded and flared gas in California that could generate 400 megawatts of power, and believe that there is at least an additional 2,000 megawatts that have not been identified. Since California accounts for about 14.5% of the total domestic oil production, it is reasonable to assume that about 16,500 megawatts could be generated throughout the United States. This power could restore the cost-effectiveness of thousands of oil wells, increasing oil production by millions of barrels a year, while reducing emissions and greenhouse gas emissions by burning the gas in clean distributed generators rather than flaring or venting the stranded gases. Most turbines and engines are designed for standardized, high-quality gas. However, emerging technologies such as microturbines have increased the options for a broader range of fuels. By demonstrating practical means to consume the four gas streams, the project showed that any gases whose properties are between the extreme conditions also could be utilized. The economics of doing so depends on factors such as the value of additional oil recovered, the price of electricity produced, and the alternate costs to dispose of stranded gas.

  11. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01T23:59:59.000Z

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  12. Associated Shale Gas- From Flares to Rig Power 

    E-Print Network [OSTI]

    Wallace, Elizabeth Michelle

    2014-10-16T23:59:59.000Z

    /D, resulting in the flaring of approximately 266 MMcf/D. The Bakken area is one of the most produced shale oil and condensate formations in the US. Reported volumes for this formation suggest that the amount of associated gas flared is enough to power drilling...

  13. Assessment of coal bed gas prospects

    SciTech Connect (OSTI)

    Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1996-12-31T23:59:59.000Z

    Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

  14. Interaction of coal-derived synthesis gas impurities with solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal-derived synthesis gas impurities with solid oxide fuel cell metallic components. Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic...

  15. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01T23:59:59.000Z

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  16. Coal seam natural gas producing areas (Louisiana)

    Broader source: Energy.gov [DOE]

    In order to prevent waste and to avoid the drilling of unnecessary wells and to encourage the development of coal seam natural gas producing areas in Louisiana, the commissioner of conservation is...

  17. Illinois Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 TableTotal Consumption (MillionTotalVented and Flared

  18. Natural Gas Vented and Flared (Summary)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYear Janthrough2,869,9601. Natural5,1958 200988 2009

  19. Advanced Coal-Fueled Gas Turbine Program

    SciTech Connect (OSTI)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01T23:59:59.000Z

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  20. Demonstration of a Carbonate Fuel Cell on Coal Derived Gas

    E-Print Network [OSTI]

    Rastler, D. M.; Keeler, C. G.; Chi, C. V.

    Several studies indicate that carbonate fuel cell systems have the potential to offer efficient, cost competitive, and environmentally preferred power plants operating on natural gas or coal derived gas (“syn-gas”). To date, however, no fuel cell...

  1. Degradation Mechanisms of SOFC Anodes in Coal Gas Containing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phosphorus. Abstract: The interaction of phosphorus in synthetic coal gas with the nickel-based anode of solid oxide fuel cells has been investigated. Tests with both...

  2. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

  3. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01T23:59:59.000Z

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  4. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01T23:59:59.000Z

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  5. Testing for market integration crude oil, coal, and natural gas

    SciTech Connect (OSTI)

    Bachmeier, L.J.; Griffin, J.M. [Texas A& amp; M Univ, College Station, TX (United States)

    2006-07-01T23:59:59.000Z

    Prompted by the contemporaneous spike in coal, oil, and natural gas prices, this paper evaluates the degree of market integration both within and between crude oil, coal, and natural gas markets. Our approach yields parameters that can be readily tested against a priori conjectures. Using daily price data for five very different crude oils, we conclude that the world oil market is a single, highly integrated economic market. On the other hand, coal prices at five trading locations across the United States are cointegrated, but the degree of market integration is much weaker, particularly between Western and Eastern coals. Finally, we show that crude oil, coal, and natural gas markets are only very weakly integrated. Our results indicate that there is not a primary energy market. Despite current price peaks, it is not useful to think of a primary energy market, except in a very long run context.

  6. Coal liquefaction and gas conversion: Proceedings. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  7. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1990-01-01T23:59:59.000Z

    Measurement of sorption capacity of coals by microbalance in a high pressure environment requires that corrections be made for the buoyancy of the gas that is displaced by the solid coal. As the pressure increases, the gas density increases, requiring that a correction factor be applied to the weight of the sample as measured by microbalance. A brief report summarizing this correction is attached as Appendix A.

  8. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05T23:59:59.000Z

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  9. Comparative Assessment of Coal-and Natural Gas-fired Power Plants under a

    E-Print Network [OSTI]

    Comparative Assessment of Coal- and Natural Gas-fired Power Plants under a CO2 Emission Performance standard (EPS) for pulverized coal (PC) and natural gas combined cycle (NGCC) power plants; · Evaluate · Coal-fired Power Plant: Supercritical pulverized coal (SC PC) Illinois #6 Coal Capacity Factor 75

  10. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01T23:59:59.000Z

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  11. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11T23:59:59.000Z

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  12. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

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  13. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

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  14. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar Apr May Jun Jul9 20102009Vented and Flared

  15. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar Apr May Jun Jul9 20102009Vented and FlaredVented

  16. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar Apr May JunFeet)TotalVented and Flared

  17. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear Jan Feb Mar Apr May JunFeet)TotalVented and FlaredVented

  18. Associated Shale Gas- From Flares to Rig Power

    E-Print Network [OSTI]

    Wallace, Elizabeth Michelle

    2014-10-16T23:59:59.000Z

    , compressed natural gas (CNG), or liquefied natural gas (LNG) (Soares 2008). Another option that can be considered to use natural gas and meet power load requirements is to convert diesel generators to a dual-fuel engines. Using both diesel and natural gas...-scale gas process could provide the solution to variable gas quality from different locations for use in power sources using natural gas. This micro-scale process is comparable to full scale LNG and CNG processing, first separating the liquids...

  19. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The goal of this task is to accurately measure the elongation and shrinkage exhibited by coal as it sorbs and desorbs methane gas at elevated pressure. Our research group has discussed several possible methods to measure this strain, including: optical microscopy, laser interferometry, conventional strain gauges, and LVDT strain gauges. There are advantages and disadvantages of each method. We had planned to use optical microscopy but, on further investigation, this approach will be less satisfactory than the strain gauge method. Accordingly, we have switched our focws to the use of strain gauges. Conventional strain gauges also involve potential problems which must be overcome, including: (1) Contrast in strength between the coal and the strain gauge must be minimized, (2) The proper glue that is neither too strong or too weak must be used to affix the strain gauge to the coal or the strain in the coal will not be accurately transmitted to the gauge, and (3) We must be aware that the total strain in the coal may not be homogeneously distributed through the specimen (due either either to boundary effects or contrast in composition of the coal layers). A high pressure chamber for sorption-strain experiments is currently being tested an modified and tested. The chamber will accommodate several small blocks of coal simultaneously. This will optimize efficiency, owing to the long times required to reequilibrate the coal blocks to changes in methane pressure.

  20. Reduced Nitrogen and Natural Gas Consumption at Deepwell Flare

    E-Print Network [OSTI]

    Williams, C.

    2004-01-01T23:59:59.000Z

    Facing both an economic downturn and the liklihood of steep natural gas price increases, company plants were challenged to identify and quickly implement energy saving projects that would reduce natural gas usage. Unit operating personnel...

  1. Reduced Nitrogen and Natural Gas Consumption at Deepwell Flare 

    E-Print Network [OSTI]

    Williams, C.

    2004-01-01T23:59:59.000Z

    Facing both an economic downturn and the liklihood of steep natural gas price increases, company plants were challenged to identify and quickly implement energy saving projects that would reduce natural gas usage. Unit operating personnel...

  2. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

    1983-01-01T23:59:59.000Z

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  3. California Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321 2,590FuelDecade Year-0 Year-1 Year-2 Year-3

  4. California Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321 2,590FuelDecade Year-0 Year-1 Year-2

  5. Colorado Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321Spain (MillionFeet)2008Year Jan FebDecade

  6. Colorado Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,128 2,469 2,321Spain (MillionFeet)2008Year Jan

  7. Alabama Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at Commercial andSeptember 25,9,1996Feet)4.32 4.46Feet)Decade

  8. Alabama Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at Commercial andSeptember 25,9,1996Feet)4.32

  9. Alaska Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1 Year-2 Year-3 Year-4Year JanDecade

  10. Alaska Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1 Year-2 Year-3 Year-4Year

  11. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1Year Jan FebRepressuringYear

  12. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1Year Jan FebRepressuringYearVented

  13. Arkansas Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1Year%Underground Storage

  14. Arkansas Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at CommercialDecade Year-0 Year-1Year%Underground StorageYear Jan Feb

  15. Indiana Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 TableTotal2009 2010 2011 2012 2013Vehicle Fuel

  16. Indiana Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 TableTotal2009 2010 2011 2012 2013Vehicle FuelYear Jan

  17. Nebraska Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYearWithdrawals (Million CubicTotalDecadeYear

  18. Nebraska Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYearWithdrawals (Million CubicTotalDecadeYearYear Jan

  19. Nevada Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYearWithdrawalsYear Jan Feb Mar Apr May Jun JulDecade

  20. Nevada Natural Gas Vented and Flared (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803andYearWithdrawalsYear Jan Feb Mar Apr May Jun

  1. Optimal transition from coal to gas and renewable power under capacity constraints and adjustment costs

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Optimal transition from coal to gas and renewable power under capacity constraints and adjustment existing coal power plants to gas and renewable power under a carbon budget. It solves a model of polluting, exhaustible resources with capacity constraints and adjustment costs (to build coal, gas, and renewable power

  2. Demonstration of a Carbonate Fuel Cell on Coal Derived Gas 

    E-Print Network [OSTI]

    Rastler, D. M.; Keeler, C. G.; Chi, C. V.

    1993-01-01T23:59:59.000Z

    system has run on actual syn-gas. Consequently, the Electric Power Research Institute (“EPRI”) has sponsored a 20 kW carbonate fuel cell pilot plant that will begin operating in March at Destec Energy’s coal gasification plant in Plaquemine, Louisiana...

  3. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  4. Innovative coal gas cleaning at Sparrows Point Coal Chemical Plant, Maryland for Bethlehem Steel Corporation

    SciTech Connect (OSTI)

    Antrobus, K.; Platts, M. (Davy/Still Otto, Pittsburgh, PA (US)); Harbold, L. (Bethlehem Steel Corp., PA (USA)); Kornosky, R. (Office of Clean Coal Technology, US DOE, Pittsburgh, PA (US))

    1990-01-01T23:59:59.000Z

    In response to the Clean Coal II solicitation, Bethlehem Steel Corporation (BSC) submitted a proposal to the DOE in May 1988. The proposal submitted by BSC describes a Unique integration of commercial technologies developed by Davy/Still Otto to clean coke oven gas being produced at its Sparrows Point, Maryland steel plant. This innovative coke oven gas cleaning system combines secondary gas cooling with hydrogen sulfide and ammonia removal, hydrogen sulfide and ammonia recovery, ammonia destruction and sulfur recovery to produce a cleaner fuel gas for plant use. The primary environmental benefit associated with employing this innovative coke oven gas cleaning system is realized when the fuel gas is burned within the steel plant. Emissions of sulfur dioxide are reduced by more than 60 percent. The removal, recovery and destruction of ammonia eliminates the disposal problems associated with an unmarketable ammonium sulfate by-product. Significant reduction in benzene and hydrogen cyanide emissions are also obtained.

  5. Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

    SciTech Connect (OSTI)

    Seaman, John

    2013-01-14T23:59:59.000Z

    The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal’s Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

  6. Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION MEANS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION to the surface is especially significant in the context of coal mines. This is because mine gas can migrate of the scheduled closure of all coal mining operations in France, INERIS has drawn up, at the request of national

  7. Unconventional gas sources. Executive summary. [Coal seams, Devonian shale, geopressured brines, tight gas reservoirs

    SciTech Connect (OSTI)

    Not Available

    1980-12-01T23:59:59.000Z

    The long lead time required for conversion from oil or gas to coal and for development of a synthetic fuel industry dictates that oil and gas must continue to supply the United States with the majority of its energy requirements over the near term. In the interim period, the nation must seek a resource that can be developed quickly, incrementally, and with as few environmental concerns as possible. One option which could potentially fit these requirements is to explore for, drill, and produce unconventional gas: Devonian Shale gas, coal seam gas, gas dissolved in geopressured brines, and gas from tight reservoirs. This report addresses the significance of these sources and the economic and technical conditions under which they could be developed.

  8. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  9. Advanced Coal-Fueled Gas Turbine Program. Final report

    SciTech Connect (OSTI)

    Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

    1989-02-01T23:59:59.000Z

    The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

  10. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

    1988-01-01T23:59:59.000Z

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  11. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01T23:59:59.000Z

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  12. Ni/YSZ Anode Interactions with Impurities in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

    2009-10-16T23:59:59.000Z

    Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

  13. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    None

    2005-09-29T23:59:59.000Z

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  14. Rock, Mineral, Coal, Oil, and Gas Resources on State Lands (Montana)

    Broader source: Energy.gov [DOE]

    This chapter authorizes and regulates prospecting permits and mining leases for the exploration and development of rock, mineral, oil, coal, and gas resources on state lands.

  15. The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1

    E-Print Network [OSTI]

    1 The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1 , James Katzer1 1 M coal can make to the growing world energy demand during a period of increasing concern about global pursue in the short-term so that we can utilize coal in the longer-term and reduce its associated CO2

  16. CO2 gas production understanding above a partly flooded coal post-mining area

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    - The Westphalian deposit is constituted by numerous exploited coal seams of different thicknesses. These seamsCO2 gas production understanding above a partly flooded coal post-mining area Candice Lagnya, a former coal mining area. To understand the origin of this production, a borehole of 90 meters deep

  17. Federal Offshore--Gulf of Mexico Natural Gas Vented and Flared (Million

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 Table A1.Gas Proved Reserves, WetGasCubic Feet)

  18. Flare System Optimization

    E-Print Network [OSTI]

    Aegerter, R.

    Flare losses are typically the largest source of variable losses in a refinery or chemical plant. Since most plant flare systems are complex, there can be many opportunities to reduce costs. Losses to the flare can include process gases, fuel gas...

  19. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  20. An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters

    E-Print Network [OSTI]

    Nebeker, C. J.

    1982-01-01T23:59:59.000Z

    As the price gap between oil and natural gas and coal continues to widen, Monsanto has carefully searched out and examined opportunities to convert fuel use to coal. Preliminary studies indicate that the low-btu gas produced by fixed-bed, air blown...

  1. Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright 2008 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright © 2008 Inderscience using neural networks', Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, pp.65­80. Biographical

  2. Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright 2014 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright © 2014 Inderscience fields in Saudi Arabia', Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, pp.115­131. Biographical

  3. 104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright 2011 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright © 2011 Inderscience, Gas and Coal Technology, Vol. 4, No. 2, pp.104­133. Biographical notes: Amirmasoud Kalantari

  4. 2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright 2009 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright © 2009 Inderscience, Gas, and Coal Technology, Vol. 2, No. 1, pp.2­23. Biographical notes: Shahab D. Mohaghegh is currently

  5. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30T23:59:59.000Z

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  6. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #844: Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

  7. Hot coal gas desulfurization with manganese-based sorbents

    SciTech Connect (OSTI)

    Hepworth, M.T.; Ben-Slimane, R.

    1995-11-01T23:59:59.000Z

    The primary major deposit of manganese in the US which can be readily mined by an in situ process is located in the Emily district of Minnesota. The US Bureau of Mines Research Centers at both the Twin Cities and Salt Lake City have developed a process for extracting and refining manganese in the form of a high-purity carbonate product. This product has been formulated into pellets by a multi-step process of drying, calcination, and induration to produce relatively high-strength formulations which are capable of being used for hot fuel gas desulfurization. These pellets, which have been developed at the University of Minnesota under joint sponsorship of the US Department of Energy and the US Bureau of Mines, appear superior to other, more expensive, formulations of zinc titanate and zinc ferrite which have previously been studied for multi-cycle loading (desulfurization) and regeneration (evolution of high-strength SO{sub 2} and restoration of pellet reactivity). Although these other formulations have been under development for the past twelve years, their prices still exceed $7 per pound. If manganese pellets perform as predicted in fixed bed testing, and if a significant number of utilities which burn high-sulfur coals incorporate combined-cycle gasification with hot coal gas desulfurization as a viable means of increasing conversion efficiencies, then the potential market for manganese pellets may be as high as 200,000 tons per year at a price not less than $3 per pound. This paper discusses the role of manganese pellets in the desulfurization process with respect to the integrated gasification combined-cycle (IGCC) for power generation.

  8. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  9. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15T23:59:59.000Z

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  10. Assessment of the Flue Gas Recycle Strategies on Oxy-Coal Power Plants using an Exergy-based Methodology

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Assessment of the Flue Gas Recycle Strategies on Oxy- Coal Power Plants using an Exergy to be competitive with post-combustion for carbon capture on coal-fired power plants. In order to achieve is produced from coal (IEA 2012b), the development of CO2 capture technology on coal-fired power plants

  11. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G. (Bolingbrook, IL); Sandstrom, William A. (Chicago, IL); Tarman, Paul B. (Elmhurst, IL)

    1982-01-01T23:59:59.000Z

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  12. An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters 

    E-Print Network [OSTI]

    Nebeker, C. J.

    1982-01-01T23:59:59.000Z

    of these factors, the difference between coal and natural gas prices and the project life are difficult to predict. The resulting uncertainty has caused Monsanto to pursue coal gasification for process heaters with cautious optimism, on a site by site basis....

  13. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers 

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01T23:59:59.000Z

    Chemical technology has been used successfully to solve many of the operational and emissions problems that result from burning coal. This paper describes the use of blended chemical flue gas conditioners to significantly reduce particulate...

  14. The competition between coal and natural gas : the importance of sunk costs

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1996-01-01T23:59:59.000Z

    This paper explores the seeming paradox between the predominant choice of natural gas for capacity additions to generate electricity in the United States and the continuing large share of coal in meeting incremental ...

  15. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05T23:59:59.000Z

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  16. Should we transport coal, gas, or electricity: cost, efficiency, and environmental implications

    SciTech Connect (OSTI)

    Joule A. Bergerson; Lester B. Lave [Carnegie Mellon University, Pittsburgh, PA (US)

    2005-08-15T23:59:59.000Z

    The authors examine the life cycle costs, environmental discharges, and deaths of moving coal via rail, coal to synthetic natural gas via pipeline, and electricity via wire from the Powder River Basin (PRB) in Wyoming to Texas. Which method has least social cost depends on how much additional investment in rail line, transmission, or pipeline infrastructure is required, as well as how much and how far energy is transported. If the existing rail lines have unused capacity, coal by rail is the cheapest method (up to 200 miles of additional track could be added). If no infrastructure exists, greater distances and larger amounts of energy favor coal by rail and gasified coal by pipeline over electricity transmission. For 1,000 miles and 9 gigawatts of power, a gas pipeline is cheapest, has less environmental discharges, uses less land, and is least obtrusive. 28 refs., 4 figs., 3 tabs.

  17. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1990--June 1991

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; Wen, C.S.

    1991-07-01T23:59:59.000Z

    Advances in coal-fueled gas turbine technology over the past few years, together with recent DOE-METC sponsored studies, have served to provide new optimism that the problems demonstrated in the past can be economically resolved and that the coal-fueled gas turbine can ultimately be the preferred system in appropriate market application sectors. The objective of the Solar/METC program is to prove the technical, economic, and environmental feasibility of a coal-fired gas turbine for cogeneration applications through tests of a Centaur Type H engine system operated on coal fuel throughout the engine design operating range. The five-year program consists of three phases, namely: (1) system description; (2) component development; (3) prototype system verification. A successful conclusion to the program will initiate a continuation of the commercialization plan through extended field demonstration runs.

  18. Coal-fired gas turbine for locomotive propulsion

    SciTech Connect (OSTI)

    Green, L. Jr.

    1987-01-01T23:59:59.000Z

    Substitution of a deeply-cleaned coal-water slurry fuel for bulk solid coal in an atmospheric fluidized-bed combustor permits a sequence of evolutionary steps which can convert the conventional AFBC into a pressurized, combustion-stirred, fluidized-bed heat exchanger compact enough to propel a standard locomotive by use of a closed Brayton power cycle.

  19. Coal-bed methane - An unconventional but viable source of natural gas

    SciTech Connect (OSTI)

    Hallinger, D.E. (Southern California Gas Co., Los Angeles (United States))

    1991-02-01T23:59:59.000Z

    As of December 31, 1988, the potential Gas Committee, a group of industry experts, estimates that the remaining undiscovered potential supplies of natural gas amounted to 795.6 trillion cubic feet (TCF) in the United States, including the offshore areas. Besides the conventional sources, the sandstone and carbonate reservoirs that geologists have been looking for since Drake, there are a number of unconventional sources of natural gas. One of these, coal-bed methane (CBM) is being actively developed today and promises to provide significant additions to the proved reserves of this nation in the next ten years. The potential supplies of CBM are variously estimates to be between 400 to 1,000 tcf, or equal to the remaining undiscovered conventional supplies of natural gas. If these estimates are real, they will have a profound effect on forecasts of future prices and availability of natural gas. How valid are these estimates At what rate will this new source of natural gas come on stream The answers to these questions are dependent in part upon the uniqueness of the coal reservoir. Coal can contain more natural gas than a comparable size conventional reservoir. A coal reservoir exhibits positive production decline instead of the negative decline of conventional reservoirs. There are legal and economic considerations that will affect the development of this relatively new and exciting source of natural gas. All of these questions are discussed by the author.

  20. Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”

    SciTech Connect (OSTI)

    Granite, E.J.; Presto, A.A.

    2008-09-01T23:59:59.000Z

    A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

  1. Geologic assessment of natural gas from coal seams in the Warrior Basin, Alabama. Topical report, September 1985-September 1986

    SciTech Connect (OSTI)

    McFall, K.S.; Wicks, D.E.; Kuuskraa, V.A.

    1986-11-01T23:59:59.000Z

    This study provides a detailed geologic assessment of the coal deposits in the Warrior Basin area that have high potential for natural gas from coal seams. The estimate of the natural gas in place in the four major coal groups is 19.8 trillion cubic feet. Although the bulk of the gas in place is in the deeper areally extensive Black Creek and Mary Lee coal groups, the more shallow Pratt coal group also shows good potential for coal seam gas. The most concentrated areas of methane in place are in the eastern portion of the Warrior Basin. These areas coincide with thick accumulations of high rank coals and their associated higher gas contents. These areas also appear to have been structurally altered, leading to enhanced permeability to gas and water. Thus, the eastern portions of the basin appear more favorable for coalbed methane production due to high gas contents, attractive coal thicknesses, closely-spaced coal cleats and joints, and moderate depths to the coal horizons.

  2. Permeability changes in coal resulting from gas desorption. Quarterly report, August 16, 1989--November 15, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-12-31T23:59:59.000Z

    The goal of this task is to accurately measure the elongation and shrinkage exhibited by coal as it sorbs and desorbs methane gas at elevated pressure. Our research group has discussed several possible methods to measure this strain, including: optical microscopy, laser interferometry, conventional strain gauges, and LVDT strain gauges. There are advantages and disadvantages of each method. We had planned to use optical microscopy but, on further investigation, this approach will be less satisfactory than the strain gauge method. Accordingly, we have switched our focws to the use of strain gauges. Conventional strain gauges also involve potential problems which must be overcome, including: (1) Contrast in strength between the coal and the strain gauge must be minimized, (2) The proper glue that is neither too strong or too weak must be used to affix the strain gauge to the coal or the strain in the coal will not be accurately transmitted to the gauge, and (3) We must be aware that the total strain in the coal may not be homogeneously distributed through the specimen (due either either to boundary effects or contrast in composition of the coal layers). A high pressure chamber for sorption-strain experiments is currently being tested an modified and tested. The chamber will accommodate several small blocks of coal simultaneously. This will optimize efficiency, owing to the long times required to reequilibrate the coal blocks to changes in methane pressure.

  3. Forecasting long-term gas production of dewatered coal seams and fractured gas shales

    SciTech Connect (OSTI)

    Spivey, J.P.; Semmelbeck, M.E.

    1995-12-31T23:59:59.000Z

    Production decline curves are routinely used by engineers to predict the future performance of oil and gas wells. Because the results of decline curve predictions are used for calculating asset value and estimating future revenue, they are one of the most important tools reservoir engineers use. There are numerous variations on the basic exponential or hyperbolic decline analysis method. Fetkovitch and other have extended the decline curve analysis method to handle gas wells properly and to be able to estimate reservoir properties from the analysis of these data. However, there has been considerable drilling activity in the last 10 years into unconventional reservoirs whose wells do not follow the traditional production decline characteristic shapes. Among these problem reservoirs are coalbed methane and fractured shale reservoirs. A procedure is presented which allows forecasting long range performance of dewatered coal and fractured gas shale reservoirs having nonlinear adsorption isotherms, using constant pressure solutions to the flow equation for slightly compressible liquids. A correlation is presented to show the range of applicability of this procedure.

  4. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S. [Southern Illinois Univ., Carbondale, IL (United States); Gupta, R.P. [Research Triangle Inst., Durham, NC (United States)

    1992-09-01T23:59:59.000Z

    There is a primary need to increase the utilization of Illinois coal resources by developing new methods of converting the coal into electricity by highly efficient and environmentally acceptable systems. New coal gasification processes are now being developed that can generate electricity with high thermal efficiency in either an integrated gasification combined cycle (IGCC) system or a molten carbonate fuel cell (MCFC). Both of-these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as-sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCI) in the coal gas. This project investigates the effect of HCI, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by HCI, both in adsorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences Of utilizing high-chlorine Illinois coal in these processes.

  5. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    SciTech Connect (OSTI)

    Milbrandt, A.; Mann, M.

    2009-02-01T23:59:59.000Z

    This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

  6. Preliminary evaluation of coal and coalbed gas resource potential of western Clay County, Mississippi

    SciTech Connect (OSTI)

    Henderson, K.S.; Gazzier, C.A.

    1989-01-01T23:59:59.000Z

    After reviewing all previously published data it appeared that if the Mississippi portion of the Black Warrior Basin contained potentially economic seams of coal the thicker downdip section was a more likely place to look. The generosity of several exploration companies in providing an extensive suite of logs that could be correlated with samples contained in the Bureau of Geology Sample Library allowed the authors to correlate and identify these upper Pottsville coal groups previously unknown in Mississippi. The purpose of this study was to identify the potential for coal resources in western Clay County, Mississippi, and to correlate laterally any coal seams identified in order to develop a gross volumetric estimate of in-place resources. It became apparent that many of the shallow coal seams (1,800 feet-3,700 feet) had appreciable quantities of gas, for they exhibited excellent gas shows when drilled. Efforts to determine rank for these coals were made by vitrinite reflectance and thus a preliminary estimate was also made for the potential coalbed methane reserves. 73 refs., 8 figs., 3 tabs.

  7. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01T23:59:59.000Z

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  8. Uncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal

    E-Print Network [OSTI]

    Jaramillo, Paulina

    and transport, to compare its environmental impact with other fuels. Until recent years, LCA studies environmental impacts between two competing fuels/products are small. This study builds upon an existingUncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal Aranya Venkatesh

  9. Investigation of mercury transformation by HBr addition in a slipstream facility with real flue gas atmospheres of bituminous coal and Powder River Basin Coal

    SciTech Connect (OSTI)

    Yan Cao; Quanhai Wang; Chien-wei Chen; Bobby Chen; Martin Cohron; Yi-chuan Tseng; Cheng-chung Chiu; Paul Chu; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

    2007-09-15T23:59:59.000Z

    An investigation of speciated mercury transformation with the addition of hydrogen bromide (HBr) at elevated temperatures was conducted in a slipstream reactor with real flue gas atmospheres. Test results indicated that adding HBr into the flue gas at several parts per million strongly impacted the mercury oxidation and adsorption, which were dependent upon temperature ranges. Higher temperatures (in the range of 300-350 C) promoted mercury oxidation by HBr addition but did not promote mercury adsorption. Lower temperatures (in a range of 150-200 C) enhanced mercury adsorption on the fly ash by adding HBr. Test results also verified effects of flue gas atmospheres on the mercury oxidation by the addition of HBr, which included concentrations of chlorine and sulfur in the flue gas. Chlorine species seemed to be involved in the competition with bromine species in the mercury oxidation process. With the addition of HBr at 3 ppm at a temperature of about 330 C, the additional mercury oxidation could be reached by about 55% in a flue gas atmosphere by burning PRB coal in the flue gas and by about 20% in a flue gas by burning bituminous coal. These are both greater than the maximum gaseous HgBr2 percentage in the flue gas (35% for PRB coal and 5% for bituminous coal) by thermodynamic equilibrium analysis predictions under the same conditions. This disagreement may indicate a greater complexity of mercury oxidation mechanisms by the addition of HBr. It is possible that bromine species promote activated chlorine species generation in the flue gas, where the kinetics of elemental mercury oxidation were enhanced. However, SO{sub 2} in the flue gas may involve the consumption of the available activated chlorine species. Thus, the higher mercury oxidation rate by adding bromine under the flue gas by burning PRB coal may be associated with its lower SO{sub 2} concentration in the flue gas. 39 refs., 8 figs., 4 tabs.

  10. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07T23:59:59.000Z

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  11. Office of Oil, Gas, and Coal Supply Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    of Energy Washington, DC 20585 April 2014 U.S. Energy Information Administration | Natural Gas Monthly ii This report was prepared by the U.S. Energy Information...

  12. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01T23:59:59.000Z

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  13. A parametric study of the effects of coal seam properties on gas drainage efficiency

    SciTech Connect (OSTI)

    Remner, D.J.; Ertekin, T.; Sung, W.; King, G.R.

    1986-11-01T23:59:59.000Z

    A parametric study is conducted to investigate the effects of reservoir properties on gas drainage efficiency. It is found that when a coal seam is opened to production, the gas desorption and production rates increase to a maximum value and then decline. The magnitude of the early desorption peak was found to be a function of (1) the ability of the micropore matrix to supply gas to the macropore system, and (2) the coal seam's conductivity to water. The desorbing gas was observed to create a localized, high-gas-saturation bank in the area enclosed by the pressure transient. The gas bank provided an internal pressure maintenance to the reservoir, while it decreased the relative permeability to brine. This created a competing effect with respect to water production. Because water removal strongly influences the pressure decline and, consequently, the desorption rate, a unique production mechanism was observed. The study explored the interference effects on gas and water flow in multiple-well systems. It was found that the pressure drawdown caused by the multiple wells enhanced the desorption of gas into the macropore system and caused a positive interference effect on the gas flow rate. The water rate, however, encountered the more conventional negative interference effect.

  14. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  15. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1989-11-19T23:59:59.000Z

    Sampling Procedure: This project requires a carefully coordinated sample preparation procedure that will ensure that specimens of the proper size and physical characteristics are available for the various measurement methods used. Coherent blocks of coal will be collected in the field, with subsamples being removed in the lab by 1 inch-diameter core drill. At least 5 separate cores will be drilled from each block. Coal blocks sampled in the field will be approximately 10 inches (times) 10 inches {times} 6 inches. Distinctive compositional lithologies should be selected for sampling. For example, a section of the seam containing particularly thick vitrain or durain bands might be selected; or the block might include a mineral matter rich layer. If necessary, several blocks should be selected to represent a range in compositions. Sampling procedure must include a method for retaining moisture. The sample must not be allowed to dry out. Exposure to atmospheric oxygen should be limited as much as possible. The samples must carefully packed for shipment so as to preserve their integrity.

  16. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01T23:59:59.000Z

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  17. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01T23:59:59.000Z

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  18. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01T23:59:59.000Z

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  19. Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic components

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Edwards, Danny J.; Chou, Y. S.; Cramer, Carolyn N.

    2010-05-28T23:59:59.000Z

    Chromium-containing iron-based alloys Crofer22 APU and SS 441 and nickel-based alloy Inconel600, all commonly used in a solid oxide fuel cell (SOFC) stack as interconnect materials, heat exchanger and gas feeding pipes, were exposed at 700-850oC to a synthetic coal gas containing ?2 ppm phosphine, arsine, sulfur and antimony. Samples were characterized by SEM/EDS and XRD to monitor the secondary phase formation. Exposure of ferritic stainless steels to P led to the formation of surface Cr-Mn-P-O and Fe-P-O compounds and increased temperatures accelerated the rate of interactions. Fewer interactions were observed after exposures to As and Sb. No sulfur containing compounds were found. Nickel-based alloy exhibited much stronger interactions with As and P in comparison with ferritic steels and the arsenic interactions were particularly strong. The difference between the iron- and nickel-based alloys is explained by the different chemistry and morphology of the scales grown on the alloy surfaces in coal gas. While P and As interactions with the metallic parts in the SOFC are likely to mitigate the nickel/zirconia anode poisoning, the other degradation mechanisms should be taken into consideration to avoid potential stack failures. Manganese spinels were found to be effective as phosphorus getters and could be used in coal gas cleanup.

  20. Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel

    E-Print Network [OSTI]

    Columbia University

    Energy's patented technology produces a clean-burning by-product from the widest variety of processed-efficient technology represented by the coal-substitute technology. The same technology will be deployed by DIGGDigital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital

  1. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  2. Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques

    SciTech Connect (OSTI)

    Mastalerz, Maria [Indiana Geological Survey; He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Rupp, John A [ORNL

    2012-01-01T23:59:59.000Z

    Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

  3. Novel carbons from Illinois coal for natural gas storage. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Sun, J.; Lizzio, A.A. [Illinois State Geological Survey, Champaign, IL (United States); Fatemi, M. [Amoco Research Center, Naperville, IL (United States)

    1994-12-31T23:59:59.000Z

    The goal of this project is to develop a technology for producing microengineered adsorbent carbons from Illinois coal and to evaluate the potential application of these novel materials for storing natural gas for use in emerging low pressure, natural gas vehicles (NGV). Potentially, about two million tons of adsorbent could be consumed in natural gas vehicles by year 2000. If successful, the results obtained in this project could lead to the use of Illinois coal in a growing and profitable market that could exceed 6 million tons per year. During this reporting period, a pyrolysis-gasification reactor system was designed and assembled. Four carbon samples were produced from a {minus}20+100 mesh size fraction of an Illinois Basin Coal (IBC-106) using a three-step process. The three steps were: coal oxidation in air at 250 C, oxicoal (oxidized coal) devolatilization in nitrogen at 425 C and char gasification in 50% steam-50% nitrogen at 860 C. These initial tests were designed to evaluate the effects of pre-oxidation on the surface properties of carbon products, and to determine optimum reaction time and process conditions to produce an activated carbon with high surface area. Nitrogen-BET surface areas of the carbon products ranged from 700--800 m{sup 2}/g. Work is in progress to further optimize reaction conditions in order to produce carbons with higher surface areas. A few screening tests were made with a pressurized thermogravimetric (PTGA) to evaluate the suitability of this instrument for obtaining methane adsorption isotherms at ambient temperature and pressures ranging from one to 30 atmospheres. The preliminary results indicate that PTGA can be used for both the adsorption kinetic and equilibrium studies.

  4. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  5. Int. J. Oil, Gas and Coal Technology, Vol. 5, No. 1, 2012 1 Copyright 2012 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    production from shale formations. Examples of three case studies in Lower Huron and New Albany shale Reservoir Modelling of Oil and Gas Producing Shale Reservoirs; Case Studies, Int. J. Oil, Gas, and Coal Enterprises Ltd. Top-Down, Intelligent Reservoir Modeling of Oil and Gas Producing Shale Reservoirs; Case

  6. Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity Generation

    E-Print Network [OSTI]

    Jaramillo, Paulina

    1 Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity from the LNG life-cycle. Notice that local distribution of natural gas falls outside our analysis boundary. Figure 1S: Domestic Natural Gas Life-cycle. Figure 2S: LNG Life-cycle. Processing Transmission

  7. Permeability changes in coal resulting from gas desorption. Second quarterly report, November 15, 1989--February 15, 1990

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1990-12-31T23:59:59.000Z

    Measurement of sorption capacity of coals by microbalance in a high pressure environment requires that corrections be made for the buoyancy of the gas that is displaced by the solid coal. As the pressure increases, the gas density increases, requiring that a correction factor be applied to the weight of the sample as measured by microbalance. A brief report summarizing this correction is attached as Appendix A.

  8. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01T23:59:59.000Z

    FLUE GAS CONDITIONING TO REDUCE PARTICULATE EMISSIONS IN INDUSTRIAL COAL-FIRED BOILERS Barry Miller and Ed Keon Apollo Technologies, Inc. Whippany, New Jersey ABSTRACT Chemical technology has been used successfully to solve many... inspection of the ESP, careful observation of ESP controls to determine spark rate and voltage drop during sparking, in-situ resistivity mea surements, rapper on-off observations, and a re view of records to investigate the relationship of boiler...

  9. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Levine, J.R.

    1991-01-01T23:59:59.000Z

    A high pressure chamber with a microbalance inside was designed and constructed for the purpose of measuring weight changes due to gas sorption at increasing pressure steps from 0 to 1000 psig. The raw weight changes recorded during the experiments had to be corrected for buoyancy and sample swelling. As the pressure in the balance chamber increases, the buoyancy forces tend to increase. The data were corrected and examined on the basis of five different sets of assumptions. At high pressures gas volumes measured have to be corrected for compressibility. The experimental data was analysed using five cases. The different cases were developed with certain assumptions. The five cases and the equations involved in each of them are discussed here.

  10. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G. [Oak Ridge National Lab., TN (United States); Andres, R.J. [University of Alaska, Fairbanks, AK (United States). Inst. of Northern Engineering

    1995-12-01T23:59:59.000Z

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  11. Help for declining natural gas production seen in the unconventional sources of natural gas. [Eastern shales, tight sands, coal beds, geopressured zones

    SciTech Connect (OSTI)

    Staats, E.B.

    1980-01-10T23:59:59.000Z

    Oil imports could be reduced and domestic gas production increased if additional gas production is obtained from four unconventional resources-eastern Devonian shales, tight sands, coal beds, and geopressured zones. Gas produced from these resources can help maintain overall production levels as supplies from conventional gas sources gradually decline. The eastern shales and western sands are the chief potential contributors in the near term. Further demonstrations of coal bed methane's recovery feasibility could improve the prospects for its production while future geopressured methane production remains speculative at this time.

  12. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30T23:59:59.000Z

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  13. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01T23:59:59.000Z

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  14. Hot Coal Gas Desulfurization With Manganese-Based Sorbents

    SciTech Connect (OSTI)

    Berns, J.J.; Hepworth, M.T. [Dept. of Civil Engineering, Univ. of Minnesota, Minneapolis, MN (United States)

    1996-12-31T23:59:59.000Z

    The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina. They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000 ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2 mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100 ppmv H{sub 2}S and loading temperatures of 5000 {degrees}C and an empty-bed space velocity of 4, 000 per hour, breakthrough occurred an effective loading of sulfur of 27 to 29% over 5 loading and regeneration cycles. At 90% of this saturation condition, the observed level of H{sub 2}S was below 10 ppmv. For regeneration, a temperature of 9000 {degrees}C is required to dissociate the sulfide into sulfur dioxide using air at atmospheric pressure. The mean sulfur dioxide concentration which is achieved during regeneration is 8% with empty-bed space velocities of 700/hr. TGA tests on individual pellets indicate that bentonite is not desirable as a bonding material and that Mn/Ti ratios higher than 7:1 produce relatively non-porous pellets. Whereas the reactivity is rapid below 12% conversion, the kinetics of conversion decreased significantly above this level. This observation may be the result of plugging of the pellet pores with sulfided product creating inaccessible pore volumes or alternately an increase in diffusional resistance by formation of MnS.

  15. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31T23:59:59.000Z

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  16. Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

    SciTech Connect (OSTI)

    Hepworth, M.T.; Slimane, R.B.

    1994-11-01T23:59:59.000Z

    The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

  17. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01T23:59:59.000Z

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  18. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews [Carnegie Mellon University, Pittsburgh, PA (United States). Civil and Environmental Engineering Department

    2007-09-15T23:59:59.000Z

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  19. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01T23:59:59.000Z

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  20. Is FLARE for Solar flare?

    E-Print Network [OSTI]

    D. Fargion

    2005-12-07T23:59:59.000Z

    The Fermi Lab Liquid ARgon experiment, FLARE, a huge neutrino argon-liquid project detector of 50 kt mass, might in a near future enlarge the neutrino telescope accuracy revealing in detail solar, supernova, atmospheric as well as largest solar flares neutrino. Indeed the solar energetic (E_p > 100 MeVs) flare particles (protons, alpha) while scattering among themselves or hitting the solar atmosphere must produce on sun prompt charged pions, whose decay (as well as their sequent muon decays) into secondaries is source of a copious solar neutrino "flare" (at tens or hundreds MeV energy). These brief (minutes) neutrino "burst" at largest flare peak may overcome by three to five order of magnitude the steady atmospheric neutrino noise on the Earth, possibly leading to their emergence and detection above the thresholds. The largest prompt "burst" solar neutrino flare may be detected in future FLARE neutrino detectors both in electron and positron and possibly in its muon pair neutrino component. Our estimate for the recent and exceptional October - November 2003 solar flares and last January 20th 2005 exceptional flare might lead to a few events for future FLARE or near unity for present Super-KamiokandeII. The neutrino spectra may reflect the neutrino flavor oscillations and mixing in flight. In neutrino detectors a surprising (correlated) muon appearance may occur while a rarer tau appearance may even marginally take place. A comparison of the solar neutrino flare signal with other neutrino foreground is estimated: it offer the first opportunity for an independent road map to disentangle the neutrino flavor puzzles, as well a prompt alarm system for dangerous solar flare eruptions.

  1. College Of Wooster 2012 Greenhouse Gas Emissions From Coal and Natural Gas Combustion Default Values From EPA Greenhouse Gas Rule

    E-Print Network [OSTI]

    Wilson, Mark A.

    56410 CO2 = 1 X 10 -3 X Fuel X HHV X EF Where CO2 = Annual CO2 mass emissions for the specific fuel type high heat value. EF =Fuel default CO2 Emission Factor from Table C-1Page 56410 CO2 Coal CO2 = 1 X 10 -3 Default CO2 Emission Factor For Bituminous Coal = 93.40 kg/mmbtu Default CH4 Emission Factor

  2. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  3. Impact of mine closure and access facilities on gas emissions from old mine workings to surface: examples of French iron and coal

    E-Print Network [OSTI]

    Boyer, Edmond

    : examples of French iron and coal Lorraine basins C. Lagny, R. Salmon, Z. Pokryszka and S. Lafortune (INERIS of mine shafts located in the iron Lorraine basin, in the Lorraine and in North-East coal basins are quite in mine workings but gas entrance and exit are allowed. Coal shafts are secured and can be equipped

  4. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31T23:59:59.000Z

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  5. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31T23:59:59.000Z

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  6. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect (OSTI)

    Kloosterman, Jeff

    2012-12-31T23:59:59.000Z

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  7. Reducing Emissions in Plant Flaring Operations

    E-Print Network [OSTI]

    Duck, B.

    2011-01-01T23:59:59.000Z

    -05-10 Proceedings of the 2011 Industrial Energy Technology Conference New Orleans, Louisiana, May 17-19, 2011 over 12 inches per hour. The pilot system incorporates a windshield, strainer and a true premix burner capable of firing in 0% oxygen environments... of the knockout drum since all the flare gases are available at this single point. Compressors take suction from the flare gas header and compress and cool it for reuse in the refinery fuel gas system. As flare gas flows through the flare header...

  8. Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass

    SciTech Connect (OSTI)

    Anuar, S.H.; Keener, H.M.

    1995-12-31T23:59:59.000Z

    The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

  9. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    None

    1998-09-01T23:59:59.000Z

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

  10. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    None

    1998-06-01T23:59:59.000Z

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

  11. Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

    2009-09-15T23:59:59.000Z

    HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

  12. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1990-10-20T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. Progress is discussed.

  13. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1990-07-19T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is on hold'' because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  14. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1989-09-27T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  15. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1988-12-22T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

  16. Combustion of ultrafine coal/water mixtures and their application in gas turbines: Final report

    SciTech Connect (OSTI)

    Toqan, M.A.; Srinivasachar, S.; Staudt, J.; Varela, F.; Beer, J.M.

    1987-10-01T23:59:59.000Z

    The feasibility of using coal-water fuels (CWF) in gas turbine combustors has been demonstrated in recent pilot plant experiments. The demands of burning coal-water fuels with high flame stability, complete combustion, low NO/sub x/ emission and a resulting fly ash particle size that will not erode turbine blades represent a significant challenge to combustion scientists and engineers. The satisfactory solution of these problems requires that the variation of the structure of CWF flames, i.e., the fields of flow, temperature and chemical species concentration in the flame, with operating conditions is known. Detailed in-flame measurements are difficult at elevated pressures and it has been proposed to carry out such experiments at atmospheric pressure and interpret the data by means of models for gas turbine combustor conditions. The research was carried out in five sequential tasks: cold flow studies; studies of conventional fine-grind CWF; combustion studies with ultrafine CWF fuel; reduction of NO/sub x/ emission by staged combustion; and data interpretation-ignition and radiation aspects. 37 refs., 61 figs., 9 tabs.

  17. advanced coal-fired gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coal-fired unit at Hawthorn Station. Ultimately, KCPL decided to replace the destroyed steam generator with another coal-fired unit, and repower the existing turbinegenerator...

  18. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01T23:59:59.000Z

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  19. Reducing Safety Flaring through Advanced Control 

    E-Print Network [OSTI]

    Hokanson, D.; Lehman, K.; Matsumoto, S.; Takai, N.; Takase, F.

    2010-01-01T23:59:59.000Z

    An advanced process control application, using DMCplus® (Aspen Technology, Inc.), was developed to substantially reduce fuel gas losses to the flare at a large integrated refining / petrochemical complex. Fluctuations in internal fuel gas system...

  20. Reducing Safety Flaring through Advanced Control

    E-Print Network [OSTI]

    Hokanson, D.; Lehman, K.; Matsumoto, S.; Takai, N.; Takase, F.

    2010-01-01T23:59:59.000Z

    An advanced process control application, using DMCplus® (Aspen Technology, Inc.), was developed to substantially reduce fuel gas losses to the flare at a large integrated refining / petrochemical complex. Fluctuations in internal fuel gas system...

  1. Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.

    SciTech Connect (OSTI)

    Parkinson, W. J. (William Jerry),

    2003-01-01T23:59:59.000Z

    In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

  2. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1997-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  3. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  4. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  5. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1999-01-01T23:59:59.000Z

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  6. Secondary atomization of coal-water fuels for gas turbine applications: Final report

    SciTech Connect (OSTI)

    Yu, T.U.; Kang, S.W.; Beer, J.M.

    1988-12-01T23:59:59.000Z

    The main research objective was to determine the effectiveness of the CWF treatments on atomization quality when applied to an ultrafine coal-water fuel (solids loading reduced to 50%) and to gas turbine operating conditions (atomization at elevated pressures). Three fuel treatment techniques were studied: (1) heating of CWF under pressure to produce steam as the pressure drops during passage of the CWF through the atomizer nozzle, (2) absorption of CO/sub 2/ gas in the CWF to produce a similar effect, and (3) a combination of the two treatments above. These techniques were expected to produce secondary atomization, that is, disruptive shattering of CWF droplets subsequent to their leaving the atomizing nozzle, and to lead to better burnout and finer fly ash size distribution. A parallel objective was to present quantitative information on the spray characteristics (mean droplet size, radial distribution of droplet size, and spray shape) of CWF with and without fuel treatment, applicable to the design of CWF-burning gas turbine combustors. The experiments included laser diffraction droplet size measurements and high-speed photographic studies in the MIT Spray Test Facility to determine mean droplet size (mass median diameter), droplet size distribution, and spray shape and angle. Three systems of atomized sprays were studied: (1) water sprays heated to a range of temperatures at atmospheric pressure; (2) CWF sprays heated at atmospheric pressure to different temperatures; and (3) sprays at elevated pressure. 31 refs., 47 figs., 1 tab.

  7. The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

  8. Enhancing the use of coals by gas reburning-sorbent injection: Volume 3 -- Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x} and SO{sub 2} from a wall fired unit at Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the as found baseline of 0.98 lb/MBtu and to reduce emissions of SO{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an SO{sub 2} limit of 1.8 lb/MBtu, the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with SO{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The system was designed to inject sorbent at a rate corresponding to a calcium (sorbent) to sulfur (coal) molar ratio of 2.0. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  9. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    None

    1982-01-01T23:59:59.000Z

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  10. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30T23:59:59.000Z

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  11. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah (Sarah Omer)

    2010-01-01T23:59:59.000Z

    Post-combustion capture retrofits are expected to a near-term option for mitigating CO 2 emissions from existing coal-fired power plants. Much of the literature proposes using power from the existing coal plant and thermal ...

  12. Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures

    E-Print Network [OSTI]

    Couling, David Joseph

    2012-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

  13. BioCoComb -- Gasification of biomass and co-combustion of the gas in a pulverized-coal-boiler

    SciTech Connect (OSTI)

    Anderl, H.; Zotter, T.; Mory, A.

    1999-07-01T23:59:59.000Z

    In a demonstration project supported by an European Community Thermie Fund a biomass gasifier for bark, wood chips, saw dust, etc. has been installed by Austrian Energy and Environment at the 137 MW{sub el} pulverized-coal fired power station in Zeltweg, Austria. The project title BioCoComb is an abbreviation for Preparation of Biofuel for Co-Combustion, where co-combustion means combustion together with coal in existing power plants. According to the thermal capacity of 10 MW the produced gas substitutes approx. 3% of the coal fired in the boiler. Only the coarse fraction of the biomass has to pass a shredder and is then fed together with the fine fraction without any further pretreatment into the gasifier. In the gasification process the biomass will combust in a substoichiometric atmosphere, create the necessary temperature of 820 C and partly gasify due to the lack of oxygen in the combustion chamber (autothermal operation). The gasifier uses circulating fluidized bed technology, which guarantees even relatively low temperatures in all parts of the gasifier to prevent slagging. The intense motion of the bed material also favors attrition of the biomass particles. Via a hot gas duct the produced low calorific value (LCV) gas is directly led into the furnace of the existing pulverized coal fired boiler for combustion. The gas also contains fine wood char particles, that can pass the retention cyclone and burn out in the furnace of the coal boiler. The main advantages of the BioCoComb concept are: low gas quality sufficient for co-firing; no gas cleaning or cooling; no predrying of the biomass; relatively low temperatures in the gasifier to prevent slagging; favorable effects on power plant emissions (CO{sub 2}, NO{sub x}); no severe modifications of the existing coal fired boiler; and high flexibility in arranging and integrating the main components into existing plants. The plant started its trial run in November 1997 and has been in successful commercial operation since January 1998.

  14. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-12-31T23:59:59.000Z

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  15. Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application

    SciTech Connect (OSTI)

    Ashok K. Anand

    2005-12-16T23:59:59.000Z

    This study identifies vital gas turbine (GT) parameters and quantifies their influence in meeting the DOE Turbine Program overall Integrated Gasification Combined Cycle (IGCC) plant goals of 50% net HHV efficiency, $1000/kW capital cost, and low emissions. The project analytically evaluates GE advanced F class air cooled technology level gas turbine conceptual cycle designs and determines their influence on IGCC plant level performance including impact of Carbon capture. This report summarizes the work accomplished in each of the following six Tasks. Task 1.0--Overall IGCC Plant Level Requirements Identification: Plant level requirements were identified, and compared with DOE's IGCC Goal of achieving 50% Net HHV Efficiency and $1000/KW by the Year 2008, through use of a Six Sigma Quality Functional Deployment (QFD) Tool. This analysis resulted in 7 GT System Level Parameters as the most significant. Task 2.0--Requirements Prioritization/Flow-Down to GT Subsystem Level: GT requirements were identified, analyzed and prioritized relative to achieving plant level goals, and compared with the flow down of power island goals through use of a Six Sigma QFD Tool. This analysis resulted in 11 GT Cycle Design Parameters being selected as the most significant. Task 3.0--IGCC Conceptual System Analysis: A Baseline IGCC Plant configuration was chosen, and an IGCC simulation analysis model was constructed, validated against published performance data and then optimized by including air extraction heat recovery and GE steam turbine model. Baseline IGCC based on GE 207FA+e gas turbine combined cycle has net HHV efficiency of 40.5% and net output nominally of 526 Megawatts at NOx emission level of 15 ppmvd{at}15% corrected O2. 18 advanced F technology GT cycle design options were developed to provide performance targets with increased output and/or efficiency with low NOx emissions. Task 4.0--Gas Turbine Cycle Options vs. Requirements Evaluation: Influence coefficients on 4 key IGCC plant level parameters (IGCC Net Efficiency, IGCC Net Output, GT Output, NOx Emissions) of 11 GT identified cycle parameters were determined. Results indicate that IGCC net efficiency HHV gains up to 2.8 pts (40.5% to 43.3%) and IGCC net output gains up to 35% are possible due to improvements in GT technology alone with single digit NOx emission levels. Task 5.0--Recommendations for GT Technical Improvements: A trade off analysis was conducted utilizing the performance results of 18 gas turbine (GT) conceptual designs, and three most promising GT candidates are recommended. A roadmap for turbine technology development is proposed for future coal based IGCC power plants. Task 6.0--Determine Carbon Capture Impact on IGCC Plant Level Performance: A gas turbine performance model for high Hydrogen fuel gas turbine was created and integrated to an IGCC system performance model, which also included newly created models for moisturized syngas, gas shift and CO2 removal subsystems. This performance model was analyzed for two gas turbine technology based subsystems each with two Carbon removal design options of 85% and 88% respectively. The results show larger IGCC performance penalty for gas turbine designs with higher firing temperature and higher Carbon removal.

  16. Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V. [U.S. DOE; Ksepko, Ewelina; Tian, Hanging [URS

    2013-01-01T23:59:59.000Z

    The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

  17. Pennsylvania Farmland and Forest Land Assessment Act of 1974- Utilization of Land or Conveyance of Rights for Exploration or Extraction of Gas, Oil or Coal Bed Methane

    Broader source: Energy.gov [DOE]

    This act prescribes the procedure utilization of land or conveyance of rights for exploration or extraction of gas, oil or coal bed methane in agricultural and forest reserve areas.

  18. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  19. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30T23:59:59.000Z

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this report describes the development efforts which expand this sorbent development effort to include Se, Cd, and P as well as Hg and As. Additional research has focused on improving removal performance with the goal of achieving effluent concentrations that are suitable for chemical production applications. By contrast, sorbent development for CO{sub 2} capture has focused on regenerable sorbents that capture the CO{sub 2} byproduct at higher CO{sub 2} pressures. Previous research on CO{sub 2} sorbents has demonstrated that the most challenging aspect of developing CO{sub 2} sorbents is regeneration. The research documented in this report investigates options to improve regeneration of the CO{sub 2} capture sorbents. This research includes effort on addressing existing regeneration limitations for sorbents previously developed and new approaches that focus initially on the regeneration performance of the sorbent.

  20. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan: Preprint

    SciTech Connect (OSTI)

    Tegen, S.

    2005-08-01T23:59:59.000Z

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power, and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  1. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan

    SciTech Connect (OSTI)

    Tegen, S.

    2006-05-01T23:59:59.000Z

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  2. Enhancing the use of coals by gas reburning-sorbent injection. Volume 3, Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company

    SciTech Connect (OSTI)

    NONE

    1994-10-01T23:59:59.000Z

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x}, and SO{sub 2} from a wall fired unit. A GR-SI system was designed for Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The unit is rated at 117 MW(e) (net) and is front wall fired with a pulverized bituminous coal blend. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the ``as found`` baseline of 0.98 lb/MBtu (420 mg/MJ), and to reduce emissions of S0{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an S0{sub 2} limit Of 1.8 lb/MBtu (770 mg/MJ), the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. The design natural gas input corresponds to 18% of the total heat input. Burnout (overfire) air is injected at a higher elevation to burn out fuel combustible matter at a normal excess air level of 18%. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with S0{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  3. Reduction of Hydrocarbon Losses to Flare Systems

    E-Print Network [OSTI]

    Page, J.

    1979-01-01T23:59:59.000Z

    merit consideration because the losses and associated economic penalties are assumed to be small. Flare gas flow is not easily measured and as a result, most plants are unaware of how much product they are actually losing during normal operation...

  4. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  5. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect (OSTI)

    Barton, Tom

    2013-06-30T23:59:59.000Z

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  6. Trace element chemistry of coal bed natural gas produced water in the Powder River Basin, Wyoming

    SciTech Connect (OSTI)

    Richard E. Jackson; K.J. Reddy [University of Wyoming, Laramie, WY (United States). Department of Renewable Resources

    2007-09-15T23:59:59.000Z

    Coal bed natural gas (CBNG) produced water is usually disposed into nearby constructed disposal ponds. Geochemistry of produced water, particularly trace elements interacting with a semiarid environment, is not clearly understood. The objective of this study was to collect produced water samples at outfalls and corresponding disposal ponds and monitor pH, iron (Fe), aluminum (Al), chromium (Cr), manganese (Mn), lead (Pb), copper (Cu), zinc (Zn), arsenic (As), boron (B), selenium (Se), molybdenum (Mo), cadmium (Cd), and barium (Ba). Outfalls and corresponding disposal ponds were sampled from five different watersheds including Cheyenne River (CHR), Belle Fourche River (BFR), Little Powder River (LPR), Powder River (PR), and Tongue River (TR) within the Powder River Basin (PRB), Wyoming from 2003 to 2005. Paired tests were conducted between CBNG outfalls and corresponding disposal ponds for each watershed. Results suggest that produced water from CBNG outfalls is chemically different from the produced water from corresponding disposal ponds. Most trace metal concentrations in the produced water increased from outfall to disposal pond except for Ba. In disposal ponds, Ba, As, and B concentrations increased from 2003 to 2005. Geochemical modeling predicted precipitation and dissolution reactions as controlling processes for Al, Cu, and Ba concentrations in CBNG produced water. Adsorption and desorption reactions appear to control As, Mo, and B concentrations in CBNG water in disposal ponds. Overall, results of this study will be important to determine beneficial uses (e.g., irrigation, livestock/wildlife water, and aquatic life) for CBNG produced water in the PRB, Wyoming. 18 refs., 4 figs., 3 tabs.

  7. Hard truths: facing the hard truths about energy. Topic Paper No. 18: Coal to liquids and gas

    SciTech Connect (OSTI)

    NONE

    2007-07-18T23:59:59.000Z

    The report presents the issues associated with and the potential of coal to liquids (CTL) and coal to gas (CTG) technologies. The other important outcome from this report is to view and understand the inputs and assumptions from various publications and the range of production estimates from CTG and CTL technology. The examination of the publications demonstrates a large uncertainty for CTL, due to various assumptions from petroleum price to technological abilities. Key assumptions are left unexamined, such as product transportation, labor, equipment availability, and environmental risk. Overall, the published CTL production estimates are small in the total global petroleum market perspective; even in the most optimistic scenario the volume from CTL amounts to only 20% of the U.S. petroleum market in the Southern States Energy Board (SSEB) report. The National Coal Council (NCC) saw a 10% market share, whereas the various Energy Information Administration (EIA) scenarios saw 0% to 6% of the U.S market share. The NCC and SSEB both mentioned the added benefit of using the CO{sub 2} for enhanced oil recovery (EOR). It begins by introducing the process, giving a detailed technological understanding, and then outlining each issue with each report from coal availability to oil price assumptions. The incremental gains from CTL and other technology areas, such as oil shale, could have a significant impact on U.S. energy cost and foreign dependency. The use of coal allows the added benefit of relying on a resource that is domestically more plentiful than petroleum, but this reliance must be carefully balanced with the economics of developing the resource, since CTL facilities can cost more than $1 billion per 10,000 days of production, which implicates the competitiveness of the U.S. economy within the global economy. 33 refs.

  8. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah O.

    Adding post-combustion capture technology to existing coal-fired power plants is being considered as a near-term option for mitigating CO[subscript 2] emissions. To supply the thermal energy needed for CO[subscript 2] ...

  9. A parametric study of the effects of coal seam properties on gas drainage efficiency

    SciTech Connect (OSTI)

    Remmer, O.J.; Ertekin, T.; King, G.R.

    1984-09-01T23:59:59.000Z

    A mathematical model which simulates the flow of methane and water through a coal seam was developed. Partial differential equations governing the flow of methane and brine were derived from mass balances applied to an elemental volume of the reservoir. A two-dimensional cartesian coordinate system was superimposed on the coal seam and was utilized to transform the continuous flow equations to discrete form by application of finite differences.

  10. Desulfurization of a coal model compound by in situ hydrogen generation through water-gas shift

    E-Print Network [OSTI]

    Kumar, Meyyappan

    1982-01-01T23:59:59.000Z

    Statistiacl Analysis Results for Temperature Profile T3 110 10 Statistical Analysis Results for Temperature Profile T4 CHAPTER I INTRODIJCTION The ever developing problem of an energy crisis has led to the search for alternative energy sources. Some... in industry to produce clean burning low sulfur fuel. As there is a growing need for alternative energy sources, coal liquefaction is likely to be commercialized within the next decade. Since coal contains a high percentage of sulfur compounds, there is a...

  11. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way; Robert L. McCormick

    2001-06-01T23:59:59.000Z

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({approx}10 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H{sub 2} separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 40} alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

  12. Simultaneous removal of H{sub 2}S and NH{sub 3} from coal gas. Final report

    SciTech Connect (OSTI)

    Gangwal, S.K.; Portzer, J.W.

    1998-05-01T23:59:59.000Z

    Hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) are the primary sulfur and nitrogen contaminants released when coal is gasified. Before coal gas can be utilized in an integrated gasification combined cycle (IGCC) plant to produce electricity, these contaminants need to be removed. The objective of this research was to develop sorbent-catalysts with the ability to simultaneously remove H{sub 2}S and NH{sub 3} from coal gas. Microreactor tests with HART-49, a zinc-based sorbent-catalyst with Ni, Co, and Mo as catalyst additives, showed that this material had the potential to remove 90% NH{sub 3} and reduce H{sub 2}S to <20 ppmv at 1 atm and 550 to 700 C. HART-49 was prepared in attrition-resistant fluidizable form (HART-56) using up to 75 wt% binder. Bench-scale fluidized-bed multicycle tests were conducted with the attrition-resistant sorbent-catalyst, HART-56, at 20 atm and 550 C. The H{sub 2}S and NH{sub 3} removal performance over the first two cycles was good in the presence of 5% steam but deteriorated thereafter when steam level was increased to 15%. The results point to a complex mechanism for simultaneous H{sub 2}S and NH{sub 3} removal, potentially involving both chemisorption and catalytic decomposition of NH{sub 3}. Further research and development is needed to develop a sorbent-catalyst for simultaneous H{sub 2}S and NH{sub 3} removal at IGCC hot-gas cleanup conditions.

  13. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  14. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 23, April 1--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-15T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x} and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. Specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. In phase AIII at Hennepin - Testing, Data Collection, Reporting and Disposition - Gas Reburning runs were made that indicate as high as 77% reduction in NO{sub x} emission using about 18% gas. Gas Reburning - Sorbent Injection test results indicated as high as 62% reduction in S0{sub 2}. A year of long term testing was completed in October, 1992.

  15. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Not Available

    1990-07-01T23:59:59.000Z

    CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

  16. The dark connection between the Canis Major dwarf, the Monoceros ring, the gas flaring, the rotation curve and the EGRET excess of diffuse Galactic Gamma Rays

    E-Print Network [OSTI]

    W. de Boer; I. Gebauer; M. Weber; C. Sander; V. Zhukov; D. Kazakov

    2007-10-26T23:59:59.000Z

    The excess of diffuse galactic gamma rays above 1 GeV, as observed by the EGRET telescope on the NASA Compton Gamma Ray Observatory, shows all the key features from Dark Matter (DM) annihilation: (i) the energy spectrum of the excess is the same in all sky directions and is consistent with the gamma rays expected for the annihilation of WIMPs with a mass between 50-100 GeV; (ii) the intensity distribution of the excess in the sky is used to determine the halo profile, which was found to correspond to the usual profile from N-body simulations with additional substructure in the form of two doughnut-shaped structures at radii of 4 and 13 kpc; (iii) recent N-body simulations of the tidal disruption of the Canis Major dwarf galaxy show that it is a perfect progenitor of the ringlike Monoceros tidal stream of stars at 13 kpc with ring parameters in agreement with the EGRET data; (iiii) the mass of the outer ring is so large, that its gravitational effects influence both the gas flaring and the rotation curve of the Milky Way. Both effects are clearly observed in agreement with the DMA interpretation of the EGRET excess.

  17. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01T23:59:59.000Z

    Hydrogen Requirement for Coal Slurry Reactor, G. Gas-LiquidFlow of Gas-Liquid and Gas-Coal Slurry Mixtures in Verticalper unit volume of melt coal slurry can be expressed in

  18. Gas Permeability of Fractured Sandstone/Coal Samples under Variable Confining Pressure

    E-Print Network [OSTI]

    Liu, Weiqun; Li, Yushou; Wang, Bo

    2010-01-01T23:59:59.000Z

    argillite under con?nement: gas and water testing. Phys.Gascoyne, M. , Wuschke, D.M. : Gas migration through water-fractured rock: results of a gas injection test. J.

  19. Coal systems analysis

    SciTech Connect (OSTI)

    Warwick, P.D. (ed.)

    2005-07-01T23:59:59.000Z

    This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.

  20. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30T23:59:59.000Z

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  1. Firing microfine coal with a low NOx, RSFC burner in an industrial boiler designed for oil and gas

    SciTech Connect (OSTI)

    Thornhock, D.E.; Patel, R.; Borio, R.W. [Combustion Engineering, Inc., Windsor, CT (United States). ABB Power Plant Labs.; Miller, B.G.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center

    1996-12-31T23:59:59.000Z

    ABB Power Plant Laboratories (ABB-PPL) working under a US Department of Energy-Pittsburgh Energy Technology Center (DOE-PETC) contract has carried out tests with the Radially Stratified Flame Core (RSFC) burner which was licensed from the Massachusetts Institute of Technology who developed and patented the RSFC burner. Tests were carried out in a small industrial boiler, designed for oil and natural gas, located at the Energy and Fuels Research Center of Penn State University who was working as a subcontractor to ABB-PPL. The paper presents results from the long-term testing task in the DOE-PETC program with particular attention being paid to the challenges faced in maintaining high combustion efficiencies while achieving low NOx in a small industrial boiler designed for firing oil or natural gas. The paper will also address the issue of ash management when firing coal in a boiler designed for fuels having essentially no ash.

  2. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 11, April 1--June 30, 1990

    SciTech Connect (OSTI)

    Not Available

    1990-07-19T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is ``on hold`` because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  3. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27T23:59:59.000Z

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  4. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 5, October 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-01-01T23:59:59.000Z

    Two base case flow sheets have now been prepared. In the first, which was originally presented in TPR4, a Texaco gasifier is used. Natural gas is also burned in sufficient quantity to increase the hydrogen to carbon monoxide ratio of the synthesis gas to the required value of 1. 1 for alcohol synthesis. Acid gas clean up and sulfur removal are accomplished using the Rectisol process followed by the Claus and Beavon processes. About 10% of the synthesis gas is sent to a power generation unit in order to produce electric power, with the remaining 90% used for alcohol synthesis. For this process, the estimated installed cost is $474.2 mm. The estimated annual operating costs are $64.5 MM. At a price of alcohol fuels in the vicinity of $1. 00/gal, the pay back period for construction of this plant is about four years. The details of this case, called Base Case 1, are presented in Appendix 1. The second base case, called Base Case 2, also has a detailed description and explanation in Appendix 1. In Base Case 2, a Lurgi Gasifier is used. The motivation for using a Lurgi Gasifier is that it runs at a lower temperature and pressure and, therefore, produces by-products such as coal liquids which can be sold. Based upon the economics of joint production, discussed in Technical Progress Report 4, this is a necessity. Since synthesis gas from natural gas is always less expensive to produce than from coal, then alcohol fuels will always be less expensive to produce from natural gas than from coal. Therefore, the only way to make coal- derived alcohol fuels economically competitive is to decrease the cost of production of coal-derived synthesis gas. one method for accomplishing this is to sell the by-products from the gasification step. The details of this strategy are discussed in Appendix 3.

  5. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30T23:59:59.000Z

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

  6. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2003-01-01T23:59:59.000Z

    For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

  7. Illinois Natural Gas Withdrawals from Gas Wells (Million Cubic Feet)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40CoalLease(Billion2,12803 TableTotal Consumption (MillionTotalVented and FlaredGas

  8. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

    1991-01-01T23:59:59.000Z

    The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro's estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

  9. Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

  10. Using Auxiliary Gas Power for CCS Energy Needs in Retrofitted Coal Power Plants

    E-Print Network [OSTI]

    with back pressure steam turbine. The capital cost of the MEA unit is estimated using the Aspen Icarus integration of its supercritical steam cycle with the stripper reboiler to supply the energy needed gas plant technologies. The three technologies assessed are the gas turbine (GT) with heat recovery

  11. Opportunities in underground coal gasification

    SciTech Connect (OSTI)

    Bloomstran, M.A.; Davis, B.E.

    1984-06-01T23:59:59.000Z

    A review is presented of the results obtained on DOE-sponsored field tests of underground coal gasification in steeply-dipping beds at Rawlins, Wyoming. The coal gas composition, process parameters, and process economics are described. Steeply-dipping coal resources, which are not economically mineable using conventional coal mining methods, are identified and potential markets for underground coal gasification products are discussed. It is concluded that in-situ gasification in steeply-dipping deposits should be considered for commercialization.

  12. Development of Biological Coal Gasification (MicGAS Process). Topical report, July 1991--February 1993

    SciTech Connect (OSTI)

    Srivastava, K.C.

    1993-06-01T23:59:59.000Z

    Laboratory and bench scale reactor research carried out during the report period confirms the feasibility of biomethanation of Texas lignite (TxL) and some other low-rank coals to methane by specifically developed unique anaerobic microbial consortia. The data obtained demonstrates specificity of a particular microbial consortium to a given lignite. Development of a suitable microbial consortium is the key to the success of the process. The Mic-1 consortium was developed to tolerate higher coal loadings of 1 and 5% TxL in comparison to initial loadings of 0.01% and 0.1% TxL. Moreover, the reaction period was reduced from 60 days to 14 to 21 days. The cost of the culture medium for bioconversion was reduced by studying the effect of different growth factors on the biomethanation capability of Mic-1 consortium. Four different bench scale bioreactor configurations, namely Rotating Biological Contactor (RBC), Upflow Fluidized Bed Reactor (UFBR), Trickle Bed Reactor (TBR), and Continuously Stirred Tank Reactor (CSTR) were evaluated for scale up studies. Preliminary results indicated highest biomethanation of TxL by the Mic-1 consortium in the CSTR, and lowest in the trickle bed reactor. However, highest methane production and process efficiency were obtained in the RBC.

  13. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01T23:59:59.000Z

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  14. Simulated coal-gas fueled carbonate fuel cell power plant system verification. Final report, September 1990--June 1995

    SciTech Connect (OSTI)

    NONE

    1995-03-01T23:59:59.000Z

    This report summarizes work performed under U.S. Department of Energy, Morgantown Energy Technology Center (DOE/METC) Contract DE-AC-90MC27168 for September 1990 through March 1995. Energy Research Corporation (ERC), with support from DOE, EPRI, and utilities, has been developing a carbonate fuel cell technology. ERC`s design is a unique direct fuel cell (DFC) which does not need an external fuel reformer. An alliance was formed with a representative group of utilities and, with their input, a commercial entry product was chosen. The first 2 MW demonstration unit was planned and construction begun at Santa Clara, CA. A conceptual design of a 10OMW-Class dual fuel power plant was developed; economics of natural gas versus coal gas use were analyzed. A facility was set up to manufacture 2 MW/yr of carbonate fuel cell stacks. A 100kW-Class subscale power plant was built and several stacks were tested. This power plant has achieved an efficiency of {approximately}50% (LHV) from pipeline natural gas to direct current electricity conversion. Over 6,000 hours of operation including 5,000 cumulative hours of stack operation were demonstrated. One stack was operated on natural gas at 130 kW, which is the highest carbonate fuel cell power produced to date, at 74% fuel utilization, with excellent performance distribution across the stack. In parallel, carbonate fuel cell performance has been improved, component materials have been proven stable with lifetimes projected to 40,000 hours. Matrix strength, electrolyte distribution, and cell decay rate have been improved. Major progress has been achieved in lowering stack cost.

  15. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    SciTech Connect (OSTI)

    Hsu, F.E.

    1995-08-01T23:59:59.000Z

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  16. System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines

    SciTech Connect (OSTI)

    Shahrokh Etemad; Lance Smith; Kevin Burns

    2004-12-01T23:59:59.000Z

    Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

  17. A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction

    E-Print Network [OSTI]

    Liu, Hui-Hai; Rutqvist, Jonny

    2010-01-01T23:59:59.000Z

    L. : Adsorption-induced coal swelling and stress:acid gas sequestration into coal seams. J Geophys. Res. (fracturing on permeability of coal. Min. Sci. Technol. 3,

  18. A new coal-permeability model: Internal swelling stress and fracture-matrix interaction

    E-Print Network [OSTI]

    Liu, H.H.

    2010-01-01T23:59:59.000Z

    of carbon dioxide in coal with enhanced coalbed methaneL. Adsorption-induced coal swelling and stress: Implicationsand acid gas sequestration into coal seams. J Geophys Res. (

  19. A new coal-permeability model: Internal swelling stress and fracture-matrix interaction

    E-Print Network [OSTI]

    Liu, H.H.

    2010-01-01T23:59:59.000Z

    gas sequestration into coal seams. J Geophys Res. (2007)Reservoir engineering in coal seams: Part 1 – the physicaland movement in coal seams. SPE Reservoir engineering.

  20. Coal - U.S. Energy Information Administration (EIA)

    U.S. Energy Information Administration (EIA) Indexed Site

    Scheduled 2015 capacity additions mostly wind and natural gas; retirements mostly coal natural gaselectricityrenewablenucleargeneration capacitywindsolarretirementscapacity...

  1. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2001-09-01T23:59:59.000Z

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

  2. Robust Low-Cost Water-Gas Shift Membrane Reactor for High-Purity Hydrogen Production form Coal-Derived Syngas

    SciTech Connect (OSTI)

    James Torkelson; Neng Ye; Zhijiang Li; Decio Coutinho; Mark Fokema

    2008-05-31T23:59:59.000Z

    This report details work performed in an effort to develop a low-cost, robust water gas shift membrane reactor to convert coal-derived syngas into high purity hydrogen. A sulfur- and halide-tolerant water gas shift catalyst and a sulfur-tolerant dense metallic hydrogen-permeable membrane were developed. The materials were integrated into a water gas shift membrane reactor in order to demonstrate the production of >99.97% pure hydrogen from a simulated coal-derived syngas stream containing 2000 ppm hydrogen sulfide. The objectives of the program were to (1) develop a contaminant-tolerant water gas shift catalyst that is able to achieve equilibrium carbon monoxide conversion at high space velocity and low steam to carbon monoxide ratio, (2) develop a contaminant-tolerant hydrogen-permeable membrane with a higher permeability than palladium, (3) demonstrate 1 L/h purified hydrogen production from coal-derived syngas in an integrated catalytic membrane reactor, and (4) conduct a cost analysis of the developed technology.

  3. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31T23:59:59.000Z

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

  4. Natural Gas Vented and Flared

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office of(Millionthrough 1996)200971 andEIA1-2015

  5. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    SciTech Connect (OSTI)

    Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

    2008-07-02T23:59:59.000Z

    Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

  6. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 8, 1 July, 1993--30 September, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    Task 1, the preparation of catalyst materials, is proceeding actively. At WVU, catalysts based on Mo are being prepared using a variety of approaches to alter the oxidation state and environment of the Mo. At UCC and P, copper-based zinc chromite spinel catalysts will be prepared and tested. The modeling of the alcohol-synthesis reaction in a membrane reactor is proceeding actively. Under standard conditions, pressure drop in the membrane reactor has been shown to be negligible. In Task 2, base case designs had previously been completed with a Texaco gasifier. Now, similar designs have been completed using the Shell gasifier. A comparison of the payback periods or production cost of these plants shows significant differences among the base cases. However, a natural gas only design, prepared for comparison purposes, gives a lower payback period or production cost. Since the alcohol synthesis portion of the above processes is the same, the best way to make coal-derived higher alcohols more attractive economically than natural gas-derived higher alcohols is by making coal-derived syngas less expensive than natural gas-derived syngas. The maximum economically feasible capacity for a higher alcohol plant from coal-derived syngas appears to be 32 MM bbl/yr. This is based on consideration of regional coal supply in the eastern US, coal transportation, and regional product demand. The benefits of economics of scale are illustrated for the base case designs. A value for higher alcohol blends has been determined by appropriate combination of RVP, octane number, and oxygen content, using MTBE as a reference. This analysis suggests that the high RVP of methanol in combination with its higher water solubility make higher alcohols more valuable than methanol.

  7. Cooperative research on the combustion characteristics of cofired desulfurized Illinois coal and char with natural gas. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Buckius, R.O.; Wu, Cheng-Kang; Krier, H.; Peters, J.E. [Illinois Univ., Urbana-Champaign, IL (United States)

    1992-12-31T23:59:59.000Z

    The DTFF is extended to larger sample collecting capability and higher temperatures, resulting in the establishment of the Ash Characterization Facility and the High Temperature Drop Tube Furnace. The Ash Characterization Facility enables continuous coal injection and sampling under controlled conditions. Several hundred milligrams of char or ash can be collected in one-half hour. The High Temperature Drop Tube Furnace uses a plasma torch to preheat the gas to over 2000 K and inject it into a ceramic tube which enters a furnace designed for 1700{degrees}C (1973 K) operation, so that temperatures and heating rates encountered by pulverized coal particles in the flames of large boilers or in the advanced slagging cyclone combustors can be simulated. An aerodynamic coal feeder works well in supplying coal continuously to the drop tube. A watercooled, Helium-quench sampling probe collects the solid samples. A scanning electron microscope is used to study the morphology of ash and char particles. A sulfur determinator, a gas chromatograph provide analytical means in the laboratory, and the Illinois State Geological Survey performs other necessary analyses of the samples. Tests on cofiring coal with I to 4% methane show that sulfur retention in ash was related to temperature and residence time. The addition of methane caused changes in gas temperature profile in the tube and also changes in chemical composition of the gases. The overall effect on sulfur retention is seen to be a result of several complex interacting factors. Further detailed studies are necessary to clarify the contribution of each factor and to provide clues to the mechanism of the process.

  8. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15T23:59:59.000Z

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  9. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05T23:59:59.000Z

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  10. Supersonic coal water slurry fuel atomizer

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

    1991-01-01T23:59:59.000Z

    A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

  11. Proceedings, twenty-five annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

  12. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01T23:59:59.000Z

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  13. Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +

    E-Print Network [OSTI]

    Zevenhoven, Ron

    pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system scrubber (pH ~ 6) 60 - 70 7 Re-heater 350 - 400 8 SCR DeNOx 300 - 400 9 Active coke bed 100 - 150 Figure 10

  14. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1982-01-01T23:59:59.000Z

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  15. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenter (LMI-EFRC)MaRIETechnologiesMesdiCenter for Gas

  16. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, natural gas, 1990 - 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14Total DeliveredPrincipal shale gas: Total

  17. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, natural gas, 1990 - 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocks Nov-14Total DeliveredPrincipal shale gas: TotalArkansas"

  18. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogen and Fuel CellFew-LayerGas Streamsof the

  19. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30T23:59:59.000Z

    The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  20. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has...

  1. Quality Guidelines for Energy System Studies: Detailed Coal Specificat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Baseline for Fossil Energy Plants, Volume 1: Bituminous Coal and Natural Gas to Electricity, Revision 2 CO2 Capture Ready Coal Power Plants Assessment of Hydrogen Production...

  2. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high-temperature furnace (HITAF): Volume 3. Final report

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    Testing of an atmospheric circulating bed pyrolyzer was done at Southern Illinois University. A variety of experiments have been conducted in a laboratory scale pyrolyzer with coal input flow rates from 2 to 6 lb/h. three feed coal particle sizes, corresponding to a nominal -40 mesh, -30 mesh and -18 mesh were used. The limestone used in the tests was a Genstar limestone. Parameters investigated in the tests include the influence of superficial velocity, temperature and coal-air mass ratios. Char particle size distributions under various test conditions have been measured and the char composition determined. Fuel gas composition, yields and heating values have been investigated. Char morphology has been studied using scanning electron microscopy. Char reactivity for selected samples has been measures, and the influence of feed coal size, bed temperature and superficial velocity has been determined. Material balance calculations have been performed and found to be in very good agreement. Energy audit calculations for the process have been made to investigate the flow of energy and to estimate the losses during the process. Full details of the data, results obtained and conclusions drawn are presented.

  3. Synthetic fuel production by indirect coal liquefaction

    E-Print Network [OSTI]

    and dimethyl ether) by indirect coal liquefaction (ICL). Gasification of coal pro- duces a synthesis gas by coal gasification. The principal con- stituents of ``syngas'' are carbon monoxide and hydrogen, which modern coal gasification facilities in operation to make hydrogen for ammonia production. Also

  4. Computer Aided Design of Advanced Turbine Airfoil Alloys for Industrial Gas Turbines in Coal Fired Environments

    SciTech Connect (OSTI)

    G.E. Fuchs

    2007-12-31T23:59:59.000Z

    Recent initiatives for fuel flexibility, increased efficiency and decreased emissions in power generating industrial gas turbines (IGT's), have highlighted the need for the development of techniques to produce large single crystal or columnar grained, directionally solidified Ni-base superalloy turbine blades and vanes. In order to address the technical difficulties of producing large single crystal components, a program has been initiated to, using computational materials science, better understand how alloy composition in potential IGT alloys and solidification conditions during processing, effect castability, defect formation and environmental resistance. This program will help to identify potential routes for the development of high strength, corrosion resistant airfoil/vane alloys, which would be a benefit to all IGT's, including small IGT's and even aerospace gas turbines. During the first year, collaboration with Siemens Power Corporation (SPC), Rolls-Royce, Howmet and Solar Turbines has identified and evaluated about 50 alloy compositions that are of interest for this potential application. In addition, alloy modifications to an existing alloy (CMSX-4) were also evaluated. Collaborating with SPC and using computational software at SPC to evaluate about 50 alloy compositions identified 5 candidate alloys for experimental evaluation. The results obtained from the experimentally determined phase transformation temperatures did not compare well to the calculated values in many cases. The effects of small additions of boundary strengtheners (i.e., C, B and N) to CMSX-4 were also examined. The calculated phase transformation temperatures were somewhat closer to the experimentally determined values than for the 5 candidate alloys, discussed above. The calculated partitioning coefficients were similar for all of the CMSX-4 alloys, similar to the experimentally determined segregation behavior. In general, it appears that computational materials science has become a useful tool to help reduce the number of iterations necessary to perform laboratory experiments or alloy development. However, we clearly are not able to rely solely on computational techniques in the development of high temperature materials for IGT applications. A significant amount of experimentation will continue to be required.

  5. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    produced. Primary energy associated with coal products wasUse EJ China Residential Energy Use Gas Coal Oil Biomass GasUse EJ China Residential Energy Use Gas Coal Oil Gas Biomass

  6. Soot and SO[subscript 2] contribution to the supersites in the MILAGRO campaign from elevated flares in the Tula Refinery

    E-Print Network [OSTI]

    Molina, Luisa Tan

    This work presents a simulation of the plume trajectory emitted by flaring activities of the Miguel Hidalgo Refinery in Mexico. The flame of a representative sour gas flare is modeled with a CFD combustion code in order ...

  7. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01T23:59:59.000Z

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  8. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  9. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  10. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01T23:59:59.000Z

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  11. Effect of cavitation on the properties of coal-tar pitch as studied by gas-liquid chromatography

    SciTech Connect (OSTI)

    M.I. Baikenov; T.B. Omarbekov; S.K. Amerkhanova (and others) [Buketov State University, Karaganda (Kazakhstan)

    2008-02-15T23:59:59.000Z

    The applicability of the cavitation-wave effect to coal-tar pitch processing is considered. The results of the GLC analysis of the test material before and after rotor-pulsation cavitation treatment are given. The organic matter of coal-tar pitch was found to degrade upon cavitation; as a result of this, the yields of light and medium fractions considerably increased. 5 refs., 2 figs., 4 tabs.

  12. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01T23:59:59.000Z

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  13. Comprehensive report to Congress: Clean Coal Technology program: Evaluation of gas reburning and low-NO sub x burners on a wall-fired boiler

    SciTech Connect (OSTI)

    Not Available

    1990-09-01T23:59:59.000Z

    This report briefly describes the Gas Reburning and Low-NO{sub x} Burners technology which is a low-cost technology that can be applied in both retrofit and new applications. This demonstration will be conducted on a utility boiler in Colorado at Cherokee Station {number sign}3; however, the technology is applicable to industrial boilers and other combustion systems. Although this technology is primarily a NO{sub x} reduction technology, some reductions in other emissions will take place. Since 15--20% of the coal is replaced with natural gas, SO{sub 2} and particulate emissions are reduced commensurately. Also the lower carbon-to-hydrogen ratio of natural gas compared to coal reduces CO{sub 2} emissions. The formation of NO{sub x} is controlled by several factors: (1) the amount of nitrogen that is chemically bound in the fuel; (2) the flame temperature; (3) the residence time that combustion products remain at very high temperatures; and (4) the amount of excess oxygen available, especially at the hottest parts of the flame. Decreasing any of these parameters, tends to reduce NO{sub x} formation. 6 figs., 1 tab.

  14. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2012-09-30T23:59:59.000Z

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120�, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230�, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky Center for Applied Energy Research (UK-CAER) led by Dr. Burt Davis. We first conducted a detailed thermodynamic analysis. The three primary mechanisms whereby the contaminants may deactivate the catalyst are condensation, deposition, and reaction. AsH{sub 3}, PH{sub 3}, H{sub 2}S, HCl, NH{sub 3} and HCN were found to have a major impact on the Fe-FT catalyst by producing reaction products, while NaCl, KCl and PH{sub 3} produce trace amounts of deposition products. The impact of the contaminants on the activity, selectivity, and deactivation rates (lifetime) of the catalysts was determined in bench-scale tests. Most of the contaminants appeared to adsorb onto (or react with) the HT- and LT-WGS catalysts were they were co-fed with the syngas: � 4.5 ppmv AsH{sub 3} or 1 ppmv PH{sub 3} in the syngas impacted the selectivity and CO conversion of both catalysts; � H{sub 2}S slowly degraded both WGS catalysts; - A binary mixture of H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv) impacted the activity of the LT-WGS catalyst, but not the HT-WGS catalyst � Moderate levels of NH{sub 3} (100 ppmv) or HCN (10 ppmv) had no impact � NaCl or KCl had essentially no effect on the HT-WGS catalyst, but the activity of the LT-WGS catalyst decreased very slowly Long-term experiments on the Co-FT catalyst at 260 and 270 °C showed that all of the contaminants impacted it to some extent with the exception of NaCl and HF. Irrespective of its source (e.g., NH{sub 3}, KNO{sub 3}, or HNO{sub 3}), ammonia suppressed the activity of the Co-FT catalyst to a moderate degree. There was essentially no impact the Fe-FT catalyst when up to 100 ppmw halide compounds (NaCl and KCl), or up to 40 ppmw alkali bicarbonates (NaHCO{sub 3} and KHCO{sub 3}). After testing, BET analysis showed that the surface areas, and pore volumes and diameters of both WGS catalysts decreased during both single and binary H2S and NH3 tests, which was attributed to sintering and pore filling by the impurities. The HT-WGS catalyst was evaluated with XRD after testing in syngas that contained 1 ppmv PH{sub 3}, or 2 ppmv H{sub 2}S, or both H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv). The peaks became sharper during testing, which was indicative of crystal growth and sintering, but no new phases were detected. After LT-WGS tests (3-33 ppmv NH{sub 3} and/or 0-88 ppmv H{sub 2}S) there were a few new phases that appeared, including sulfides. The fresh Fe-FT catalyst was nanocrystalline and amorphous. ICP-AA spectroscopy and other methods (e.g., chromatography) were used to analyze for

  15. REMEDIAT1NG AT MANUFACTURED GAS

    E-Print Network [OSTI]

    Peters, Catherine A.

    , comhusti- hle gas manufactured Pfrom coke, coal, and oil 1 served as the major gas- eous fuel for urban for the three primary gas production meth- ods: coal carbonization, carbureted water gas production, and oil gas, and metals. Tar resid- uals were produced from the vola- tiIe component of bituminous coals in coal

  16. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 27, April 1, 1994--June 30, 1994

    SciTech Connect (OSTI)

    Not Available

    1994-07-15T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal-fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone-fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions through a combination of two technologies, gas reburning and sorbent injection.

  17. FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS

    SciTech Connect (OSTI)

    Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

    2004-01-29T23:59:59.000Z

    With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

  18. Parameterization of solar flare dose 

    E-Print Network [OSTI]

    Lamarche, Anne Helene

    1995-01-01T23:59:59.000Z

    A critical aspect of missions to the Moon or Mars is the safety and health of the crew. Radiation in space is a hazard for astronauts, especially high-energy radiation following certain types of solar flares. A solar flare ...

  19. Clean Coal Technology: Reduction of NO{sub x} and SO{sub 2} using gas reburning, sorbent injection, and integrated technologies. Topical report No. 3, Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (also referred to as the CCT Program), is a unique government/industry cost-shared effort to develop these advanced coal-based technologies. The CCT Program provides numerous options for addressing a wide range of energy and environmental issues, including acid rain, global climate change, improved energy efficiency, energy security, and environmental qualitiy. It is intended to demonstrate a new generation of full-scale, ``showcase`` facilities built through the United States. Gas Reburning, Sorbent Injection and Integrated Technologies -- the subject of this Topical Report -- are one such set of promising innovative developments. In addition to discussing the technologies involved, this report will describe two specific projects, results to date, and the commercial promise of these processes. The objectives of Gas Reburning and Sorbent Injection were to have a 60% reduction in NO{sub x} emissions and a 50% reduction in SO{sub 2} emissions. These objectives have been achieved at the tangentially-fired boiler at the Hennepin site of Illinois Power and at the cyclone-fired boiler operated by City Water, Light and Power in Springfield, Illinois. The other project, Gas Reburning and Low NO{sub x} Burners had the goal of a 70% NO{sub x} reduction from the wall-fired boiler operated by Public Service of Colorado at Denver. In early preliminary testing, this goal was also achieved. Energy and Environmental Research (EER) is now ready to design and install Gas Rebunting and Sorbent Injection systems, and Gas Reburning-Low NO{sub x}, Burner systems for any utility or industrial application. These technologies are offered with performance and emission control guarantees.

  20. Solar Flares and particle acceleration

    E-Print Network [OSTI]

    of Glasgow, UK STFC Summer School, Armagh, 2012 #12;Solar flares: basics X-raysradiowavesParticles1AU Figure energy ~2 1032 ergs #12;"Standard" model of a solar flare/CME Solar corona T ~ 106 K => 0.1 keV per MeV Proton energies >100 MeV Large solar flare releases about 1032 ergs (about half energy

  1. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31T23:59:59.000Z

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of the CO{sub 2} in the original process as converted to methane. The process could under another option avoid emissions following the conversion to SNG through an adjunct algae conversion process. The algae would then be converted to fuels or other products. An additional application of the algae process at the end use natural gas fired plant could further reduce emissions. The APS team fully recognizes the competition facing the process from natural gas and imported liquid natural gas. While we expect those resources to set the price for methane in the near-term, the team's work to date indicates that the AHP process can be commercially competitive, with the added benefit of assuring long-term energy supplies from North American resources. Conversion of coal to a more readily transportable fuel that can be employed near load centers with an overall reduction of greenhouses gases is edging closer to reality.

  2. CORROSION OF IRON-BASE ALLOYS BY COAL CHAR AT 871 AND 982 C

    E-Print Network [OSTI]

    Gordon, Bruce Abbott

    2011-01-01T23:59:59.000Z

    Coal Processing . Corrosion . Preliminary Screening2. A. B. C. Gas Phase Corrosion Equilibrium Thermodynamicsof Gas Phase Corrosion Thermodynamic Stability Diagrams

  3. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report no. 8-A, June 1--August 31, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-09-27T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

  4. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report no. 6, September 1, 1988--November 30, 1988

    SciTech Connect (OSTI)

    Not Available

    1988-12-22T23:59:59.000Z

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

  5. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01T23:59:59.000Z

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  6. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  7. Co-combustion of refuse derived fuel and coal in a cyclone furnace at the Baltimore Gas and Electric Company, C. P. Crane Station

    SciTech Connect (OSTI)

    Not Available

    1982-03-01T23:59:59.000Z

    A co-combustion demonstration burn of coal and fluff refuse-derived fuel (RDF) was conducted by Teledyne National and Baltimore Gas and Electric Company. This utility has two B and W cyclone furnaces capable of generating 400 MW. The facility is under a prohibition order to convert from No. 6 oil to coal; as a result, it was desirable to demonstrate that RDF, which has a low sulfur content, can be burned in combination with coals containing up to 2% sulfur, thus reducing overall sulfur emissions without deleterious effects. Each furnace consists of four cyclones capable of generating 1,360,000 pounds per hour steam. The tertiary air inlet of one of the cyclones was modified with an adapter to permit fluff RDF to be pneumatically blown into the cyclone. At the same time, coal was fed into the cyclone furnace through the normal coal feeding duct, where it entered the burning chamber tangentially and mixed with the RDF during the burning process. Secondary shredded fluff RDF was prepared by the Baltimore County Resource Recovery Facility. The RDF was discharged into a receiving station consisting of a belt conveyor discharging into a lump breaker, which in turn, fed the RDF into a pneumatic line through an air-lock feeder. A total of 2316 tons were burned at an average rate of 5.6 tons per hour. The average heat replacement by RDF for the cyclone was 25%, based on Btu input for a period of forty days. The range of RDF burned was from 3 to 10 tons per hour, or 7 to 63% heat replacement. The average analysis of the RDF (39 samples) for moisture, ash, heat (HHV) and sulfur content were 18.9%, 13.4%, 6296 Btu/lb and 0.26% respectively. RDF used in the test was secondary shredded through 1-1/2 inch grates producing the particle size distribution of from 2 inches to .187 inches. Findings to date after inspection of the boiler and superheater indicate satisfactory results with no deleterious effects from the RDF.

  8. Gamma-ray burst flares: X-ray flaring. II

    SciTech Connect (OSTI)

    Swenson, C. A.; Roming, P. W. A., E-mail: cswenson@astro.psu.edu [Pennsylvania State University, 525 Davey Lab, University Park, PA 16802 (United States)

    2014-06-10T23:59:59.000Z

    We present a catalog of 498 flaring periods found in gamma-ray burst (GRB) light curves taken from the online Swift X-Ray Telescope GRB Catalogue. We analyzed 680 individual light curves using a flare detection method developed and used on our UV/optical GRB Flare Catalog. This method makes use of the Bayesian Information Criterion to analyze the residuals of fitted GRB light curves and statistically determines the optimal fit to the light curve residuals in an attempt to identify any additional features. These features, which we classify as flares, are identified by iteratively adding additional 'breaks' to the light curve. We find evidence of flaring in 326 of the analyzed light curves. For those light curves with flares, we find an average number of ?1.5 flares per GRB. As with the UV/optical, flaring in our sample is generally confined to the first 1000 s of the afterglow, but can be detected to beyond 10{sup 5} s. Only ?50% of the detected flares follow the 'classical' definition of ?t/t ? 0.5, with many of the largest flares exceeding this value.

  9. Imminence of peak in US coal production and overestimation of reserves

    E-Print Network [OSTI]

    Khare, Sanjay V.

    1 Imminence of peak in US coal production and overestimation of reserves Nathan G. F. Reaver, coal reserves, coal production forecast, peak coal, USA energy, non- linear fitting #12;3 1 fuels, coal, oil, and natural gas, it is coal that is the most carbon intensive (W. Moomaw, 2011). Due

  10. Energy and environmental research emphasizing low-rank coal: Task 3.4 -- Hot-gas cleaning. Topical report (includes semiannual report for January--June 1995)

    SciTech Connect (OSTI)

    Weber, G.F.; Swanson, M.L.

    1995-06-01T23:59:59.000Z

    This report summarizes the accomplishments of three subtasks completed in support of the current and future hot-gas cleanup activities at the Energy and Environmental Research Center (EERC). The overall objective of the EERC hot-gas cleanup task is to develop reliable methods to remove particulate matter from high-temperature, high-pressure gas streams produced from coal combustion and/or gasification. Near-term task objectives include (1) design, fabrication, and assembly of a high-temperature, high-pressure bench-scale filter vessel; (2) design, fabrication, and assembly of a high-temperature, high-pressure sampling train; and (3) the preliminary design of a pilot-scale high-temperature, high-pressure filter vessel and support systems. Bench-scale hot-gas filter research will be performed with the pressurized fluid-bed reactor (PFBR) or the continuous fluid-bed reactor (CFBR) and a hot-gas filter vessel. The objectives of future work with the bench-scale system will be to determine particulate and vapor-phase alkali degradation of candidate ceramic filter structures as well as filter performance relative to particulate collection efficiency, differential pressure, and filter cleanability. Construction of the high-temperature, high-pressure sampling system was intended to support bench- and pilot-scale activities with respect to conventional particulate sampling (total mass and particle-size distribution) and hazardous air pollutant (HAP) sampling. Finally, pilot-scale tests will be performed to evaluate filter performance and determine alkali corrosion of ceramic materials with a hot-gas filter vessel attached to the EERC Transport Reactor Development Unit (TRDU).

  11. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  12. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  13. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  14. The Caterpillar Coal Gasification Facility

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    ' in 1981 and won the 'energy conservation award' for 1983. The decision to install and operate a coal gasification plant was based on severe natural gas curtailments at York with continuing supply interruptions. This paper will present a detailed...

  15. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 5, Appendix D: Cost support information: Final report

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

    1991-01-01T23:59:59.000Z

    The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro`s estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

  16. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

    2006-07-01T23:59:59.000Z

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  17. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01T23:59:59.000Z

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  18. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25T23:59:59.000Z

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  19. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01T23:59:59.000Z

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  20. Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 2, Appendices

    SciTech Connect (OSTI)

    Underkoffler, V.S.

    1986-12-01T23:59:59.000Z

    The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Data from sidestream testing are presented. 18 refs.

  1. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01T23:59:59.000Z

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  2. Permeability changes in coal resulting from gas desorption. First quarterly report, August 16, 1989--November 15, 1989

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1989-11-19T23:59:59.000Z

    Sampling Procedure: This project requires a carefully coordinated sample preparation procedure that will ensure that specimens of the proper size and physical characteristics are available for the various measurement methods used. Coherent blocks of coal will be collected in the field, with subsamples being removed in the lab by 1 inch-diameter core drill. At least 5 separate cores will be drilled from each block. Coal blocks sampled in the field will be approximately 10 inches (times) 10 inches {times} 6 inches. Distinctive compositional lithologies should be selected for sampling. For example, a section of the seam containing particularly thick vitrain or durain bands might be selected; or the block might include a mineral matter rich layer. If necessary, several blocks should be selected to represent a range in compositions. Sampling procedure must include a method for retaining moisture. The sample must not be allowed to dry out. Exposure to atmospheric oxygen should be limited as much as possible. The samples must carefully packed for shipment so as to preserve their integrity.

  3. Abstract-Coal and hydro will be the main sources of electric energy in Chile for the near future, given that natural gas

    E-Print Network [OSTI]

    Dixon, Juan

    Abstract- Coal and hydro will be the main sources of electric energy in Chile for the near future and the environmental dilemma faced by the country, where both coal and hydro produce some kind of impact. The role

  4. Parameterization of solar flare dose

    E-Print Network [OSTI]

    Lamarche, Anne Helene

    1995-01-01T23:59:59.000Z

    A critical aspect of missions to the Moon or Mars is the safety and health of the crew. Radiation in space is a hazard for astronauts, especially high-energy radiation following certain types of solar flares. A solar flare event can be very...

  5. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA); McDermott, Wayne T. (Allentown, PA); Givens, Edwin N. (Bethlehem, PA)

    1985-01-01T23:59:59.000Z

    A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

  6. Smokeless Control of Flare Steam Flow Rate

    E-Print Network [OSTI]

    Agar, J.; Balls, B. W.

    1979-01-01T23:59:59.000Z

    the First Industrial Energy Technology Conference Houston, TX, April 22-25, 1979 FLARE GAS FLOW RATE MEASUREMENT "Accurate measurement of the very low flow rates which are normally present is very difficult" 0, p 15-8). "It is generally considered too...-04-91 Proceedings from the First Industrial Energy Technology Conference Houston, TX, April 22-25, 1979 to calibration conditions. Turndown is 40:1 and pressure loss is negligible. APPLICATION FLOW RATE The mass flow meter described has been applied to a wide...

  7. Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams

    SciTech Connect (OSTI)

    Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

    1980-07-01T23:59:59.000Z

    Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

  8. Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 1

    SciTech Connect (OSTI)

    Underkoffler, V.S.

    1986-12-01T23:59:59.000Z

    The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Optimum operating parameters for zinc ferrite such as temperatures, gas compositions, and space velocities are discussed. From the test results, salient features of zinc ferrite were derived and discussed in regard to system implications, issues raised, and technical requirements. 47 refs., 53 figs., 41 tabs.

  9. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  10. Combined cycle power plant incorporating coal gasification

    DOE Patents [OSTI]

    Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

    1981-01-01T23:59:59.000Z

    A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

  11. Assessment of undiscovered carboniferous coal-bed gas resources of the Appalachian Basin and Black Warrior Basin Provinces, 2002

    SciTech Connect (OSTI)

    Milici, R.C.; Hatch, J.R.

    2004-09-15T23:59:59.000Z

    Coalbed methane (CBM) occurs in coal beds of Mississippian and Pennsylvanian (Carboniferous) age in the Appalachian basin, which extends almost continuously from New York to Alabama. In general, the basin includes three structural subbasins: the Dunkard basin in Pennsylvania, Ohio, and northern West Virginia; the Pocahontas basin in southern West Virginia, eastern Kentucky, and southwestern Virginia; and the Black Warrior basin in Alabama and Mississippi. For assessment purposes, the Appalachian basin was divided into two assessment provinces: the Appalachian Basin Province from New York to Alabama, and the Black Warrior Basin Province in Alabama and Mississippi. By far, most of the coalbed methane produced in the entire Appalachian basin has come from the Black Warrior Basin Province. 8 refs., 1 fig., 1 tab.

  12. A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction

    E-Print Network [OSTI]

    Liu, Hui-Hai; Rutqvist, Jonny

    2010-01-01T23:59:59.000Z

    gas sequestration into coal seams. J Geophys. Res. (2007).Reservoir engineering in coal seams: part 1—the physicalstorage and movement in coal seams. SPE Reserv. Eng. , 2(1),

  13. Comparative Life-Cycle Air Emissions of Coal, Domestic Natural

    E-Print Network [OSTI]

    Jaramillo, Paulina

    come domestically from the production of synthetic natural gas (SNG) via coal gasification- methanation gasification technologies that use coal to produce SNG. This National Gasification Strategy callsComparative Life-Cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity

  14. Flotation and flocculation chemistry of coal and oxidized coals

    SciTech Connect (OSTI)

    Somasundaran, P.

    1990-01-01T23:59:59.000Z

    The objective of this research project is to understand the fundamentals involved in the flotation and flocculation of coal and oxidized coals and elucidate mechanisms by which surface interactions between coal and various reagents enhance coal beneficiation. An understanding of the nature of the heterogeneity of coal surfaces arising from the intrinsic distribution of chemical moieties is fundamental to the elucidation of mechanism of coal surface modification and its role in interfacial processes such as flotation, flocculation and agglomeration. A new approach for determining the distribution in surface properties of coal particles was developed in this study and various techniques capable of providing such information were identified. Distributions in surface energy, contact angle and wettability were obtained using novel techniques such as centrifugal immersion and film flotation. Changes in these distributions upon oxidation and surface modifications were monitored and discussed. An approach to the modelling of coal surface site distributions based on thermodynamic information obtained from gas adsorption and immersion calorimetry is proposed. Polyacrylamide and dodecane was used to alter the coal surface. Methanol adsorption was also studied. 62 figs.

  15. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Quarterly progress report No. 7, July--September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluating the economic and technical feasibility of the concept, and preparing an R&D plan to develop the concept further. Foster Wheeler Development Corporation (FWDC) is leading a team of companies involved in this effort. The power generating system being developed in this project will be an improvement over current coal-fired systems. Goals have been specified that relate to the efficiency, emissions, costs, and general operation of the system. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800{degrees}F in furnaces fired with coal-derived fuels and then directly heated in a natural-gas-fired combustor to about 2400{degrees}F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuel gas is relatively clean, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need to be a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown in Figure 1.

  16. Using Airborne Geophysics to Improve the Management of Produced Water from Coal Bed Natural Gas Extraction in the Powder River Basin

    SciTech Connect (OSTI)

    Sams, J.I.; Lipinski, B.A.; Hammack, R.W.; Veloski, G.A.; Ackman, T.E.; Harbert, W.P. (Univ. of Pittsburgh)

    2005-05-01T23:59:59.000Z

    The Powder River Basin (PRB) of Wyoming and Montana has seen a boom in drilling for coalbed natural gas (CBNG), the natural gas contained in coal seams. Large quantities of water are coproduced during the extraction process. The water is currently managed by land application (irrigation), returned to shallow groundwater aquifers via infiltration basins, directly discharged to ephemeral or perennial streams, or injected into the deep subsurface via injection wells. At present, there are over 28,000 CBNG wells permitted or drilled in the PRB and it is estimated that another 50,000 to 100,000 new wells will be drilled in the future. Produced water management is a major challenge to the oil and gas industry as well as federal and state regulators. The purpose of this study was to evaluate the use of airborne electromagnetic (AEM) methods for the large-scale mapping of vadose zone properties. The base maps derived from the AEM data show the location of conductive anomalies within the vadose zone. These conductive anomalies have been identified as conditions related to soil properties, geologic features, saturated areas, and seepage zones. In the PRB, the data can be used to identify suitable locations for constructing impoundments in areas that avoid highly conductive soils where infiltrating water may leach salts through the vadose zone and into shallow aquifers. Hydrologic changes within the vadose zone were evaluated by completing an AEM survey in 2003 and 2004 over two coincident spatial areas. The data were analyzed to determine statistical relationships between the data sets, in particular data outliers which may represent areas of significant change between each year. Some outliers plot near areas of CBNG development. Ultimately, it is hoped that the information from these surveys will identify cost effective treatment or disposal options for produced water that address both production and environmental issues.

  17. Analysis of coal and coal bed methane resources of Warrior basin, Alabama

    SciTech Connect (OSTI)

    Wicks, D.E.; McFall, K.S.; Malone, P.

    1987-09-01T23:59:59.000Z

    The Warrior basin in Alabama is the most active area in the US producing natural gas from coal beds. As of 1986, 300 coal-bed methane wells were producing from eight degasification fields, mainly from the Pennsylvanian coal seams along the eastern margin of the basin. Despite difficult market conditions, drilling and expansion are continuing. A detailed geologic analysis of Warrior basin coal-bed methane targets the areas of the basin that show the most promise for future gas production. The geologic analysis is based on extensive well and core data and basin-wide correlations of the Pennsylvanian coal groups. Four detailed cross sections were constructed, correlating the target coal groups in the basin, namely the Cobb, Pratt, Mary Lee, and Black Creek. They estimate that the Warrior basin contains nearly 20 tcf of in-place coal-bed methane, mainly in three of the target coal groups - the Pratt, Mary Lee, and Black Creek coals, with 4, 7, and 8 tcf, respectively. The east-central area of the basin contains the greatest volume of natural gas resource due to its concentration of thicker, higher ranked coals with high gas content. The geologic analysis also provided the underlying framework for the subsequent engineering analysis of economically recoverable gas reserves. For example, analysis of structure and tectonics showed the east-central area to be promising for gas recovery due to its proximity to the Appalachian structural front and consequent structural deformation and permeability enhancement.

  18. Chlorine in coal and boiler corrosion

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Liu, L. [Western Kentucky Univ., Bowling Green, KY (United States); Huggins, F.E.; Huffman, G.P. [Univ. of Kentucky, Lexington, KY (United States); Ho, K.K. [Illinois Clean Coal Inst., Carbondale, IL (United States)

    1994-12-31T23:59:59.000Z

    Corrosion of superheaters in the United Kingdom has been attributed to the high level of chlorine (Cl) in British coals. On the other hand, similar high-Cl Illinois coals have not caused boiler corrosion. This suggests that the extent of boiler corrosion due to Cl may not be directly related to the amount of Cl in the coal but to how the Cl occurs in the coal or to other factors. In this study, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the thermal evolution characteristics and the forms of Cl in four Illinois and four British coals. The TGA-FTIR results indicate that under oxidizing conditions, both British and Illinois coals release hydrogen chloride (HCl) gas. Maximum evolution of HCl gas from Illinois coals occurs near 425 C, whereas, the temperature of maximum HCl release from British coals occurs between 210 and 280 C. The XANES results indicate that Cl in coal exists in ionic forms including a solid salt form. The HCl evolution profiles of the Illinois and British coals suggests that the way in which Cl ions are associated in Illinois coals is of different from the way they are associated in British coals.

  19. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Major Demonstrations Major Demonstrations Since 1985, we have helped fund commercial-scale clean coal technology demonstration projects. ICCS | CCPI | PPII | CCTDP | FutureGen...

  20. Sectoral trends in global energy use and greenhouse gas emissions

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    all fuels including electricity and syngas will be used forGas Electricity Biomass Syngas Space Heating Coal Oil Gas

  1. Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

    SciTech Connect (OSTI)

    Shiquan Tao

    2006-12-31T23:59:59.000Z

    The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

  2. New Clean Coal Cycle Optimized Using Pinch Technology 

    E-Print Network [OSTI]

    Rossiter, A. P.; O'Donnell, J. J.

    1990-01-01T23:59:59.000Z

    transport reaction technology, developed originally for Fluid Catalytic Cracking plants, is used in the coal conversion steps; and pulverized limestone is circulated with the coal to capture the sulfur that is released during this process. Both gas turbines...

  3. Hydroliquefaction of coal

    DOE Patents [OSTI]

    Sze, Morgan C. (Upper Montclair, NJ); Schindler, Harvey D. (Fairlawn, NJ)

    1982-01-01T23:59:59.000Z

    Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

  4. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01T23:59:59.000Z

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  5. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology, (United States) Illinois Coal Association (United States))

    1992-01-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  6. Permeability changes in coal resulting from gas desorption. Eighth quarterly report, July 1, 1991--September 30, 1991

    SciTech Connect (OSTI)

    Levine, J.R.

    1991-12-31T23:59:59.000Z

    A high pressure chamber with a microbalance inside was designed and constructed for the purpose of measuring weight changes due to gas sorption at increasing pressure steps from 0 to 1000 psig. The raw weight changes recorded during the experiments had to be corrected for buoyancy and sample swelling. As the pressure in the balance chamber increases, the buoyancy forces tend to increase. The data were corrected and examined on the basis of five different sets of assumptions. At high pressures gas volumes measured have to be corrected for compressibility. The experimental data was analysed using five cases. The different cases were developed with certain assumptions. The five cases and the equations involved in each of them are discussed here.

  7. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11T23:59:59.000Z

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  8. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J. (Energy Systems)

    2011-04-01T23:59:59.000Z

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  9. Laboratory scale studies of Pd/y-Al2O3 sorbents for the removal of trace contaminents from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

    2010-12-31T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150-540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/{gamma}-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  10. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1996-01-01T23:59:59.000Z

    Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence a small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

  11. Conventional Energy (Oil, Gas, and Coal) Forum & Associated Vertical Business Development Best Practices in Indian Country

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T, Inc.'sEnergyTexas1.SpaceFluorControls andCONVENTIONAL ENERGY (OIL, GAS &

  12. X-ray Computed Tomography of coal: Final report

    SciTech Connect (OSTI)

    Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

    1986-12-01T23:59:59.000Z

    X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

  13. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    gas emissions from conven- tional power sources like coal.total emissions from coal- or natural gas-fired power plantsemissions, the lifecycle for natural gas power production is more complicated than that of coal.

  14. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30T23:59:59.000Z

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?˘ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?˘ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?˘ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?˘ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  15. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  16. Comparison of coal tars generated by pyrolysis of Hanna coal and UCG (underground coal gasification) Hanna IVB coal tars

    SciTech Connect (OSTI)

    Barbour, F.A.; Cummings, R.E.

    1986-04-01T23:59:59.000Z

    The compositions of coal tars produced by laboratory and pilot scale apparatus have been compared to those produced during underground coal gasification (UCG) experiments at Hanna, Wyoming. Four coal tars were generated by pyrolysis using the block reactor and the laboratory reference retort, and a fifth coal tar was composited from products produced by UCG. Coal tars were separated into chemically defined fractions and were characterized by gas chromatography. Specific compounds were not identified, but rather fingerprinting or compound-type profiling was used for identifying similarities and differences in the product tars. This permitted the evaluation of the different methods of tar production with respect to one another. The UCG coal tars appeared to have undergone more secondary cracking than the pyrolytic products. The coal tar products from the laboratory reference retort appear to be more indicative of the coal's chemical structure. Products from the block reactor contained lesser amounts of the lighter boiling material. In addition there is organic sulfur contamination as indicated by the large amount of sulfur present in the product tar from the block reactor. 11 refs., 16 figs., 11 tabs.

  17. Natural Gas Vented and Flared (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office of(Millionthrough 1996)200971 andEIA1-2015NA NA NA NA

  18. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems, Volume 4

    SciTech Connect (OSTI)

    Not Available

    1991-02-01T23:59:59.000Z

    This appendix is a compilation of work done to predict overall cycle performance from gasifier to generator terminals. A spreadsheet has been generated for each case to show flows within a cycle. The spreadsheet shows gaseous or solid composition of flow, temperature of flow, quantity of flow, and heat heat content of flow. Prediction of steam and gas turbine performance was obtained by the computer program GTPro. Outputs of all runs for each combined cycle reviewed has been added to this appendix. A process schematic displaying all flows predicted through GTPro and the spreadsheet is also added to this appendix. The numbered bubbles on the schematic correspond to columns on the top headings of the spreadsheet.

  19. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard

    2003-12-01T23:59:59.000Z

    ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

  20. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  1. DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2005-01-30T23:59:59.000Z

    For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

  2. Gas/slurry flow in coal-liquefaction processes (fluid dynamics in a three-phase-flow column). Final technical progress report, 1 October 1979-31 March 1982

    SciTech Connect (OSTI)

    Ying, D.H.S.; Sivasubramanian, R.; Moujaes, S.F.; Givens, E.N.

    1982-04-01T23:59:59.000Z

    A commercial coal liquefaction plant will employ vertical tubular reactors feeding slurry and gas concurrently upward through these vessels. In the SRC-I plant design the reactor is essentially an empty vessel with only a distributor plate located near the inlet. Because the commercial plant represents a considerable scale-up over Wilsonville or any pilot plant, this program addressed the need for additional data on behavior of three phase systems in large vessels. Parameters that were investigated in this program were studied at conditions that relate directly to projected plant operating conditions. The fluid dynamic behavior of the three-phase upflow system was studied by measuring gas and slurry holdup, liquid dispersion, solids suspension and solids accumulation. The dependent parameters are gas and liquid velocities, solid particle size, solids concentration, liquid viscosity, liquid surface tension and inlet distributor. Within the range of liquid superficial velocity from 0.0 to 0.5 ft/sec, gas holdup is found to be independent of liquid flow which agrees with other investigators. The results also confirm our previous finding that gas holdup is independent of column diameter when the column diameter is 5 inches or larger. The gas holdup depends strongly on gas flow rate; gas holdup increases with increasing gas velocity. The effect of solids particles on gas holdup depends on the gas flow rate. Increasing liquid viscosity and surface tension reduce gas holdup which agrees with other investigators. Because of the complexity of the system, we could not find a single correlation to best fit all the data. The degree of liquid backmixing markedly affects chemical changes occurring in the dissolver, such as sulfur removal, and oil and distillate formation.

  3. Environmental data energy technology characterizations: coal

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    This document describes the activities leading to the conversion of coal to electricity. Specifically, the activities consist of coal mining and beneficiation, coal transport, electric power generation, and power transmission. To enhance the usefulness of the material presented, resource requirements, energy products, and residuals for each activity area are normalized in terms of 10/sup 12/ Btus of energy produced. Thus, the total effect of producing electricity from coal can be determined by combining the residuals associated with the appropriate activity areas. Emissions from the coal cycle are highly dependent upon the type of coal consumed as well as the control technology assigned to the activity area. Each area is assumed to be equipped with currently available control technologies that meet environmental regulations. The conventional boiler, for example, has an electrostatic precipitator and a flue gas desulfurization scrubber. While this results in the removal of most of the particulate matter and sulfur dioxide in the flue gas stream, it creates other new environmental residuals -- solid waste, sludge, and ash. There are many different types of mined coal. For informational purposes, two types from two major producing regions, the East and the West, are characterized here. The eastern coal is typical of the Northern Appalachian coal district with a high sulfur and heat content. The western coal, from the Powder River Basin, has much less sulfur, but also has a substantially lower heating value.

  4. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 5, October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1994-05-01T23:59:59.000Z

    An announced objective of the Department of Energy in funding this work, and other current research in coal liquefaction, is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel. A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline-burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number. Experimental coal liquefaction studies conducted in a batch microreactor in the authors laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly such results may be approached in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

  5. abandoned surface coal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage, Conversion and Utilization Websites Summary: is oxygen-blown (O2-blown) gasification to generate synthesis gas from coal. This technology is used is a strong...

  6. advanced coal fired: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a possible co-firing fuel with coal. Cofiring of DB offers a technique of utilizing dairy manure for powersteam generation, reducing greenhouse gas concerns, and increasing...

  7. african coal sources: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage, Conversion and Utilization Websites Summary: is oxygen-blown (O2-blown) gasification to generate synthesis gas from coal. This technology is used is a strong...

  8. Utilization of coal mine ventilation exhaust as combustion air in gas-fired turbines for electric and/or mechanical power generation. Semi-annual topical report, June 1995--August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Methane emitted during underground coal mining operations is a hazard that is dealt with by diluting the methane with fresh air and exhausting the contaminated air to the atmosphere. Unfortunately this waste stream may contain more than 60% of the methane resource from the coal, and in the atmosphere the methane acts as a greenhouse gas with an effect about 24.5 times greater than CO{sub 2}. Though the waste stream is too dilute for normal recovery processes, it can be used as combustion air for a turbine-generator, thereby reducing the turbine fuel requirements while reducing emissions. Preliminary analysis indicates that such a system, built using standard equipment, is economically and environmentally attractive, and has potential for worldwide application.

  9. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15T23:59:59.000Z

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  10. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01T23:59:59.000Z

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  11. Division of Oil, Gas, and Mining Permitting

    E-Print Network [OSTI]

    Utah, University of

    " or "Gas" does not include any gaseous or liquid substance processed from coal, oil shale, or tar sands

  12. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  13. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    coal mining, petroleum extraction and refining, coking, andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking and

  14. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis G. Smirniotis

    2007-06-30T23:59:59.000Z

    In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

  15. Mechanical properties of reconstituted Australian black coal

    SciTech Connect (OSTI)

    Jasinge, D.; Ranjith, P.G.; Choi, S.K.; Kodikara, J.; Arthur, M.; Li, H. [Monash University, Clayton, Vic. (Australia). Dept. of Civil Engineering

    2009-07-15T23:59:59.000Z

    Coal is usually highly heterogeneous. Great variation in properties can exist among samples obtained even at close proximity within the same seam or within the same core sample. This makes it difficult to establish a correlation between uniaxial compressive strength (UCS) and point load index for coal. To overcome this problem, a method for making reconstituted samples for laboratory tests was developed. Samples were made by compacting particles of crushed coal mixed with cement and water. These samples were allowed to cure for four days. UCS and point load tests were performed to measure the geomechanical properties of the reconstituted coal. After four days curing, the average UCS was found to be approximately 4 MPa. This technical note outlines some experimental results and correlations that were developed to predict the mechanical properties of the reconstituted black coal samples. By reconstituting the samples from crushed coal, it is hoped that the samples will retain the important mechanical and physicochemical properties of coal, including the swelling, fluid transport, and gas sorption properties of coal. The aim is to be able to produce samples that are homogeneous with properties that are highly reproducible, and the reconstituted coal samples can be used for a number of research areas related to coal, including the long-term safe storage of CO{sub 2} in coal seams.

  16. 1 | P a g e 2012 International Pittsburgh Coal Conference

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    1 | P a g e 2012 International Pittsburgh Coal Conference Pittsburgh, PA, USA October 15 - 18, 2012-mineable Coal Seam Qin He, Shahab D. Mohaghegh, Vida Gholami Department of Petroleum and Natural Gas Engineering, West Virginia University, Morgantown, WV26505, U.S.A. Abstract Studies have shown that, coal seam

  17. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  18. Toward zero emissions from coal in China Robert H. Williams

    E-Print Network [OSTI]

    is oxygen-blown (O2­blown) gasification to generate synthesis gas from coal. This technology is used is a strong candidate for becoming the "third" clean energy carrier for China. Evolving a coal-based energyToward zero emissions from coal in China Robert H. Williams Princeton Environmental Institute, Room

  19. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31T23:59:59.000Z

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  20. Outlook and Challenges for Chinese Coal

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20T23:59:59.000Z

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

  1. Nine clean coal projects chosen by DOE

    SciTech Connect (OSTI)

    Not Available

    1986-09-01T23:59:59.000Z

    On July 25, 1986 the US Department of Energy announced the nine projects selected as DOE's top choices in their Clean Coal Technology Program. The projects are: pressurized fluidized bed combustion combined cycle utility retrofit; extended tests of limestone injection multi-stage burner plus sorbent duct injection; slagging combustor with sorbent injection into combustor; gas reburning and sorbent injection retrofit into 3 utility boilers; steeply dipping bed underground coal gasification integrated with indirect liquefaction; integrated coal gasification steam injection gas turbine demonstration plants (2) with hot gas cleanup; coal-oil coprocessing liquefaction; fluidized bed gasification with hot gas cleanup integrated combined cycle demonstration plant; and direct iron ore reduction to replace coke oven/blast furnace for steelmaking. A table lists the 14 runner-up projects any of which could be selected if cooperative agreements are not reached with any of the nine companies selected. Brief descriptions are given of the nine selected projects.

  2. Industrial Utilization of Coal-Oil Mixtures

    E-Print Network [OSTI]

    Dunn, J. E.; Hawkins, G. T.

    1982-01-01T23:59:59.000Z

    Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

  3. Transition Region Emission and Energy Input to Thermal Plasma During the Impulsive Phase of Solar Flares

    E-Print Network [OSTI]

    J. C. Raymond; G. Holman; A. Ciaravella; A. Panasyuk; Y. -K. Ko; J. Kohl

    2007-01-12T23:59:59.000Z

    The energy released in a solar flare is partitioned between thermal and non-thermal particle energy and lost to thermal conduction and radiation over a broad range of wavelengths. It is difficult to determine the conductive losses and the energy radiated at transition region temperatures during the impulsive phases of flares. We use UVCS measurements of O VI photons produced by 5 flares and subsequently scattered by O VI ions in the corona to determine the 5.0 thermal energy and the conductive losses deduced from RHESSI and GOES X-ray data using areas from RHESSI images to estimate the loop volumes, cross-sectional areas and scale lengths. The transition region luminosities during the impulsive phase exceed the X-ray luminosities for the first few minutes, but they are smaller than the rates of increase of thermal energy unless the filling factor of the X-ray emitting gas is ~ 0.01. The estimated conductive losses from the hot gas are too large to be balanced by radiative losses or heating of evaporated plasma, and we conclude that the area of the flare magnetic flux tubes is much smaller than the effective area measured by RHESSI during this phase of the flares. For the 2002 July 23 flare, the energy deposited by non-thermal particles exceeds the X-ray and UV energy losses and the rate of increase of the thermal energy.

  4. High-pressure gasification of Montana subbituminous coal

    SciTech Connect (OSTI)

    Goyal, A.; Bryan, B.; Rehmat, A.

    1991-01-01T23:59:59.000Z

    A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

  5. Method of operating a two-stage coal gasifier

    DOE Patents [OSTI]

    Tanca, Michael C. (Tariffville, CT)

    1982-01-01T23:59:59.000Z

    A method of operating an entrained flow coal gasifier (10) via a two-stage gasification process. A portion of the coal (18) to be gasified is combusted in a combustion zone (30) with near stoichiometric air to generate combustion products. The combustion products are conveyed from the combustion zone into a reduction zone (32) wherein additional coal is injected into the combustion products to react with the combustion products to form a combustible gas. The additional coal is injected into the reduction zone as a mixture (60) consisting of coal and steam, preferably with a coal-to-steam weight ratio of approximately ten to one.

  6. Process for electrochemically gasifying coal using electromagnetism

    DOE Patents [OSTI]

    Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

    1987-01-01T23:59:59.000Z

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  7. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01T23:59:59.000Z

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  8. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

  9. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25T23:59:59.000Z

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  10. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  11. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 3, Appendix B: NO{sub x} and alkali vapor control strategies: Final report

    SciTech Connect (OSTI)

    Not Available

    1990-07-01T23:59:59.000Z

    CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

  12. Carbon Dioxide Sequestration in Geologic Coal Formations

    SciTech Connect (OSTI)

    None

    2001-09-30T23:59:59.000Z

    BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

  13. Materials performance in coal gasification pilot plants

    SciTech Connect (OSTI)

    Judkins, R.R.; Bradley, R.A.

    1987-10-15T23:59:59.000Z

    This paper presents the results of several materials testing projects which were conducted in operating coal gasification pilot plants in the United States. These projects were designed to test potential materials of construction for commercial plants under actual operating conditions. Pilot plants included in the overall test program included the Hygas, Conoco Coal, Synthane, Bi-Gas, Peatgas (Hygas operating with peat), Battelle, U-Gas, Westinghouse (now KRW), General Electric (Gegas), and Mountain Fuel Resources plants. Test results for a large variety of alloys are discussed and conclusions regarding applicability of these materials in coal gasification environments are presented. 14 refs., 2 tabs.

  14. Pumping carbon out of underground coal deposits

    SciTech Connect (OSTI)

    Steinberg, M.

    1999-07-01T23:59:59.000Z

    Thin steam and deep coal deposits are difficult and costly to mine. Underground coal gasification (UCG) with air or oxygen was thought to alleviate this problem. Experimental field tests were conducted in Wyoming and Illinois. Problems were encountered concerning a clear path for the team gasification to take place and removal of gas. The high endothermic heat of reaction requiring large quantities of steam and oxygen makes the process expensive. Safety problems due to incomplete reaction is also of concern. A new approach is proposed which can remedy most of these drawbacks for extracting energy from underground coal deposits. It is proposed to hydrogasify the coal underground with a heated hydrogen gas stream under pressure to produce a methane-rich gas effluent stream. The hydrogasification of coal is essentially exothermic so that no steam or oxygen is required. The gases formed are always in a reducing atmosphere making the process safe. The hydrogen is obtained by thermally decomposing the effluent methane above ground to elemental carbon and hydrogen. The hydrogen is returned underground for further hydrogasification of the coal seam. The small amount of oxygen and sulfur in the coal can be processed out above ground by removal as water and H{sub 2}S. Any CO can be removed by a methanation step returning the methane to process. The ash remains in the ground and the elemental carbon produced is the purest form of coal. The particulate carbon can be slurried with water to produce a fuel stream that can be fed to a turbine for efficient combined cycle power plants with lower CO{sub 2} emissions. Coal cannot be used for combined cycle because of its ash and sulfur content destroys the gas turbine. Depending on its composition of coal seam some excess hydrogen is also produced. Hydrogen is, thus, used to pump pure carbon out of the ground.

  15. Present coal potential of Turkey and coal usage in electricity generation

    SciTech Connect (OSTI)

    Yilmaz, A.O. [Karadeniz Technical University, Trabzon (Turkey). Mining Engineering Department

    2009-07-01T23:59:59.000Z

    Total coal reserve (hard coal + lignite) in the world is 984 billion tons. While hard coal constitutes 52% of the total reserve, lignite constitutes 48% of it. Turkey has only 0.1% of world hard coal reserve and 1.5% of world lignite reserves. Turkey has 9th order in lignite reserve, 8th order in lignite production, and 12th order in total coal (hard coal and lignite) consumption. While hard coal production meets only 13% of its consumption, lignite production meets lignite consumption in Turkey. Sixty-five percent of produced hard coal and 78% of produced lignite are used for electricity generation. Lignites are generally used for electricity generation due to their low quality. As of 2003, total installed capacity of Turkey was 35,587 MW, 19% (6,774 MW) of which is produced from coal-based thermal power plants. Recently, use of natural gas in electricity generation has increased. While the share of coal in electricity generation was about 50% for 1986, it is replaced by natural gas today.

  16. Magnetic reconnection configurations and particle acceleration in solar flares

    E-Print Network [OSTI]

    Chen, P. F.

    types of solar flares. Upper panel: two-ribbon flares; Lower panel: compact flares. The color shows space under different magnetic configurations. Key words: solar flares, magnetic reconnection, particleMagnetic reconnection configurations and particle acceleration in solar flares P. F. Chen, W. J

  17. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

    2012-01-01T23:59:59.000Z

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?˘ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?˘ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?˘ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?˘ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?˘ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?˘ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

  18. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01T23:59:59.000Z

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  19. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30T23:59:59.000Z

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

  20. High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 14, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Wiser, W.H.; Oblad, A.G.

    1996-04-01T23:59:59.000Z

    The objective of this project is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous- flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal. A continuous system has been constructed and operated, with a one-half inch inside diameter (ID) tube as the reaction vessel. As the work in this project proceeded toward its conclusion, an unexpected benefit was discovered. As the residence times were decreased to values of 10 seconds or less, ratios of liquids/HC gases of 20/1 or higher were achieved. But very importantly, it was discovered that the chemical reactions which produce the primary liquids can be carried to high conversions at pressures much lower than reported, and indeed required, in the processes at longer times.

  1. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  2. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  3. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  4. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  5. EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

  6. Monitoring of FR Cnc Flaring Activity

    E-Print Network [OSTI]

    A. Golovin; M. Andreev; E. Pavlenko; Yu. Kuznyetsova; V. Krushevska; A. Sergeev

    2007-12-10T23:59:59.000Z

    Being excited by the detection of the first ever-observed optical flare in FR Cnc, we decided to continue photometrical monitoring of this object. The observations were carried out at Crimean Astrophysical Observatory (Crimea, Ukraine; CrAO - hereafter) and at the Terskol Observatory (Russia, Northern Caucasus). The obtained lightcurves are presented and discussed. No distinguishable flares were detected that could imply that flares on FR Cnc are very rare event.

  7. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  8. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  9. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  10. alberta flare research: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O. Terry 5 FLARE: Fast Layout for Augmented Reality Applications Microsoft Research Energy Storage, Conversion and Utilization Websites Summary: FLARE: Fast Layout for Augmented...

  11. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  12. 4th Annual Clean Coal

    E-Print Network [OSTI]

    Ferriter John P

    Proceedings he emphasis of the Fourth Clean Coal Technology Conference wm the marketability of clean coal projects both domestically and abroad. The success rate of clean coal projects in the U.S. for coalfired electricity generation is a beacon to foreign governments that are working toward effectively using advanced NO, and SO2 technology to substantially reduce flue-gas emissions for a cleaner environment. There is a continuing dialogue between U.S. Government, North American private industry, and the electricity producing governmental ministries and the private sector abroad. The international community was well represented at this conference. The Administration is determined to move promising, near-term technologies from the public to the private sector a ~ well a8 into the international marketplace.

  13. Experimental Characterization and Molecular Study of Natural Gas Mixtures

    E-Print Network [OSTI]

    Cristancho Blanco, Diego Edison

    2011-08-08T23:59:59.000Z

    ) 5, advanced gas turbine 5 and coal-based zero emissions power plant 6 are some of the technological advances recently reported. It is important to note that these technologies are adaptable to natural gas feedstock. However, until clean coal...

  14. Underground coal gasification product quality parameters

    SciTech Connect (OSTI)

    Bruggink, P.R.; Davis, B.E.

    1981-01-01T23:59:59.000Z

    A simplified model is described which will indicate the economic value of the raw product gas from an experimental underground coal gasification test on a real-time basis in order to aid in the optimization of the process during the course of the test. The model relates the properties of the product gas and the injection gas to the cost of producing each of five potential commercial products. This model was utilized to evaluate data during the Gulf-DOE underground coal gasification test at Rawlins, Wyoming in the fall of 1981. 6 refs.

  15. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  16. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15T23:59:59.000Z

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  17. Gasifier feed - Tailor-made from Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technology, (United States)]|[Illinois Coal Association (United States)

    1992-08-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  18. Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (S. Somerville, NJ)

    1989-01-01T23:59:59.000Z

    A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

  19. CO2 SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

    2004-07-01T23:59:59.000Z

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The main tasks for this reporting period were to correlate well logs and refine coal property maps, evaluate methane content and gas composition of Wilcox Group coals, and initiate discussions concerning collection of additional, essential data with Anadarko. To assess the volume of CO{sub 2} that may be sequestered and volume of methane that can be produced in the vicinity of the proposed Sam Seymour sequestration site, we used approximately 200 additional wells logs from Anadarko Petroleum Corp. to correlate and map coal properties of the 3 coal-bearing intervals of Wilcox group. Among the maps we are making are maps of the number of coal beds, number of coal beds greater than 5 ft thick, and cumulative coal thickness for each coal interval. This stratigraphic analysis validates the presence of abundant coal for CO{sub 2} sequestration in the Wilcox Group in the vicinity of Sam Seymour power plant. A typical wellbore in this region may penetrate 20 to 40 coal beds with cumulative coal thickness between 80 and 110 ft. Gas desorption analyses of approximately 75 coal samples from the 3 Wilcox coal intervals indicate that average methane content of Wilcox coals in this area ranges between 216 and 276 scf/t, basinward of the freshwater boundary indicated on a regional hydrologic map. Vitrinite reflectance data indicate that Wilcox coals are thermally immature for gas generation in this area. Minor amounts of biogenic gas may be present, basinward of the freshwater line, but we infer that most of the Wilcox coalbed gas in the deep coal beds is migrated thermogenic gas. Analysis based on limited data suggest that sites for CO{sub 2} sequestration and enhanced coalbed gas recovery should be located basinward of the Wilcox freshwater contour, where methane content is high and the freshwater aquifer can be avoided.

  20. Case Study of Optimal Byproduct Gas Distribution in Integrated Steel Mill Using Multi-Period Optimization

    E-Print Network [OSTI]

    Makinen, K.; Kymalainen, T.; Junttila, J.

    2012-01-01T23:59:59.000Z

    byproduct gases at varying rates. The differences between gas generation and consumption rates are compensated with gas holders. However, under certain circumstances the imbalances can lead to the flaring of excessive gas or require the purchase...

  1. Coal gasification 2006: roadmap to commercialization

    SciTech Connect (OSTI)

    NONE

    2006-05-15T23:59:59.000Z

    Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

  2. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15T23:59:59.000Z

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  3. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15T23:59:59.000Z

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  4. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > The EnergyCenterDioxide CaptureSee the Foundry'sMcGuireNETLCareersCoal

  5. Repowering with clean coal technologies

    SciTech Connect (OSTI)

    Freier, M.D. [USDOE Morgantown Energy Technology Center, WV (United States); Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N. [Parsons Power Group, Inc., Reading, PA (United States)

    1996-02-01T23:59:59.000Z

    Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

  6. Apparatus and method for solar coal gasification

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1980-01-01T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  7. Earth Planets Space, , , Flares and the Chromosphere

    E-Print Network [OSTI]

    Hudson, Hugh

    The radiative energy of a solar flare appears mainly in the optical and UV continuum, which form in the lowerSSL, UC Berkeley, CA USA 94720-7450 2University of Glasgow, UK (Received xxxx xx, 2003; Revised xxxx produces in the photospheric magnetic field. Key words: Solar flares, Solar chromosphere, Solar corona

  8. OVERVIEW OF SOLAR FLARES The Yohkoh Perspective

    E-Print Network [OSTI]

    Hudson, Hugh

    that solar flares begin with high-energy processes. The key elements are accelerated particlesChapter 8 OVERVIEW OF SOLAR FLARES The Yohkoh Perspective Hugh Hudson Space Sciences Laboratory, UC of Glasgow, Glasgow G12 8QQ, Scotland, U.K. lyndsay@astro.gla.ac.uk Josef I. Khan Dept. of Physics

  9. OVERVIEW OF SOLAR FLARES The Yohkoh Perspective

    E-Print Network [OSTI]

    California at Berkeley, University of

    observations from space from the 1960s, revealed that solar flares begin with high-energy processes. The keyChapter 8 OVERVIEW OF SOLAR FLARES The Yohkoh Perspective Hugh Hudson Space Sciences Laboratory, UC of Glasgow, Glasgow G12 8QQ, Scotland, U.K. lyndsay@astro.gla.ac.uk Josef I. Khan Dept. of Physics

  10. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01T23:59:59.000Z

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  11. Coal-Fired Fluidized Bed Combustion Cogeneration

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    COAL-FIRED FLUIDIZED BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed... combustion, has encouraged many steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However...

  12. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2000-09-01T23:59:59.000Z

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  13. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01T23:59:59.000Z

    Commission (NDRC), 2007. Natural Gas Use Policy [??? ????].Commission (NDRC), 2007. Natural Gas Use Policy [??? ????].coal, crude oil, and natural gas. Hydropower, nuclear, and

  14. Arco's research and development efforts in underground coal gasification

    SciTech Connect (OSTI)

    Bell, G.J.; Brandenburg, C.F.; Bailey, D.W.

    1983-01-01T23:59:59.000Z

    Arco's Rocky Hill No. 1 field test provided invaluable experience in gasifying the deep, thick coal resources in Wyoming. Reverse combustion successfully linked the wells and allowed conversion of the highly permeable, very wet coal to a high-quality gas. The test also produced data on overburden subsidence and groundwater effects. Unresolved issues include such items as site selection, ground water protection, surface treatment of product gas, and the interaction of simultaneously operating gas production modules.

  15. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  16. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 1, Final report

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01T23:59:59.000Z

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  17. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect (OSTI)

    Not Available

    1990-08-01T23:59:59.000Z

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  18. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    is produced via coal gasification, then, depending on thenot be amenable to coal gasification and, thus, Eastern coalto represent a coal-to- hydrogen gasification process that

  19. Coal properties and system operating parameters for underground coal gasification

    SciTech Connect (OSTI)

    Yang, L. [China University of Mining & Technology, Xuzhou (China)

    2008-07-01T23:59:59.000Z

    Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

  20. Process for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  1. Investigation of coal tar mobility at a former MGP site

    SciTech Connect (OSTI)

    Moo-Young, H.K.; Mo, X.H.; Waterman, R.; Coleman, A.; Saroff, S. [California State University Los Angeles, Los Angeles, CA (United States)

    2009-11-15T23:59:59.000Z

    The presence of coal tar in the subsurface of former manufactured gas plant sites poses an environmental hazard and a potential threat to public health. Coal tar can release various chemical compounds that are transported into the groundwater. Before any efforts can be made to remove coal tar from contaminated subsurface soils, it is recommended to characterize coal tar properties and composition and to delineate the residual saturation point between mobile and immobile coal tar. This paper presents a new innovative field device, the Res-SAT field tool, and laboratory procedures that can be used to determine the saturation-capillary pressure relationship for a soil-water coal-tar system and the critical pressure for coal tar mobility.

  2. Western Europe's future gas supplies

    SciTech Connect (OSTI)

    Kardaun, G.

    1983-05-01T23:59:59.000Z

    Decline in indigenous natural gas production by 2000 will be compensated by imported natural gas and LNG and gas from unconventional sources. Coal gas will furnish about 10 percent of the demand, more natural gas imports will come from North Africa and the USSR and additional LNG will come from West Africa, the Middle East and the Western Hemisphere.

  3. Rails Beyond Coal The Impacts of "New Energy" & the Dawning of the Domestic Intermodal Age

    E-Print Network [OSTI]

    Bustamante, Fabián E.

    (~13% share · capture from coal) · » Despite recent increases in prices, natural gas share capture Themes or "Givens' · Green is here to stay · Oil Prices will remain high (price points at $65, $45, $25 elsewhere.... #12;Gas displaces Coal (PLG) · » Natural gas now supplying approx. 30% of thermal fuel demand

  4. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  5. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08T23:59:59.000Z

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  6. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26T23:59:59.000Z

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  7. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  8. coal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Commercial Technologies for Coal Storage and Feed Preparation AlternativesSupplements to Coal - Feedstock Flexibility DOE Supported R&D for CoalBiomass Feed and Gasification...

  9. Process for clean-burning fuel from low-rank coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Sethi, Vijay (Laramie, WY); Brecher, Lee E. (Laramie, WY)

    1994-01-01T23:59:59.000Z

    A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

  10. Program for large-scale underground-coal-gasification tests

    SciTech Connect (OSTI)

    Hammesfahr, F.W.; Winter, P.L.

    1982-11-01T23:59:59.000Z

    The continuing development of underground coal gasification technology requires extended multi-module field programs in which the output gas is linked to surface usage. This effort was to appraise whether existing surface facilities in the utility, petroleum refinery, or natural gas industries could be used to reduce the cost of such an extended multi-module test and whether regional demand in areas having underground coal gasification coal resources could support the manufacture of transportation fuels from underground coal gasification gases. To limit the effort to a reasonable level but yet to permit a fair test of the concept, effort was focused on five states, Illinois, New Mexico, Texas, Washington, and Wyoming, which have good underground coal gasification reserves. Studies of plant distribution located 25 potential sites within 3 miles of the underground coal gasification amenable reserves in the five states. Distribution was 44% to utilities, 44% to refineries, and 12% to gas processing facilities. The concept that existing surface facilities, currently or potentially gas-capable, might contribute to the development of underground coal gasification technology by providing a low cost industrial application for the gas produced in a multi-module test appears valid. To further test the concept, three industries were reviewed in depth. These were the electric utility, natural gas, and petroleum industries. When looking at a fuel substitution of the type proposed, each industry had its special perspective. These are discussed in detail in the report.

  11. Healy clean coal project

    SciTech Connect (OSTI)

    Not Available

    1992-08-01T23:59:59.000Z

    The objective of the Healy Clean Coal Project is to demonstrate the integration of an advanced combustor and a heat recovery system with both high and low temperature emission control processes. Resulting emission levels of SO[sub 2], NO[sub x], and particulates are expected to be significantly better than the federal New source Performance standards. During this past quarter, engineering and design continued on the boiler, combustion flue gas desulfurization (FGD), and turbine/generator systems. Balance of plant equipment procurement specifications continue to be prepared. Construction activities commenced as the access road construction got under way. Temporary ash pond construction and drilling of the supply well will be completed during the next quarter.

  12. Economic assessment of coal-burning locomotives: Topical report

    SciTech Connect (OSTI)

    Not Available

    1986-02-01T23:59:59.000Z

    The General Electric Company embarked upon a study to evaluate various alternatives for the design and manufacture a coal fired locomotive considering various prime movers, but retaining the electric drive transmission. The initial study was supported by the Burlington-Northern and Norfolk-Southern railroads, and included the following alternatives: coal fired diesel locomotive; direct fired gas turbine locomotives; direct fired gas turbine locomotive with steam injection; raw coal gasifier gas turbine locomotive; and raw coal fluid bed steam turbine locomotive. All alternatives use the electric drive transmission and were selected for final evaluation. The first three would use a coal water slurry as a fuel, which must be produced by new processing plants. Therefore, use of a slurry would require a significant plant capital investment. The last two would use classified run-of-the-mine (ROM) coal with much less capital expenditure. Coal fueling stations would be required but are significantly lower in capital cost than a coal slurry plant. For any coal fired locomotive to be commercially viable, it must pass the following criteria: be technically feasible and environmentally acceptable; meet railroads' financial expectations; and offer an attractive return to the locomotive manufacturer. These three criteria are reviewed in the report.

  13. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  14. ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES

    E-Print Network [OSTI]

    Onu, Christopher O.

    2013-01-01T23:59:59.000Z

    The Synthoil process employs a fixed bed of cobalt molybdateoil, and gas through the fixed bed. The H-Coal process has

  15. CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS

    SciTech Connect (OSTI)

    Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

    2009-11-30T23:59:59.000Z

    This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

  16. Hanna, Wyoming underground coal gasification field test series

    SciTech Connect (OSTI)

    Bartke, T.C.; Gunn, R.D.

    1983-01-01T23:59:59.000Z

    The six in situ coal gasification field tests conducted by LETC near Hanna, WY, demonstrated typical gasification rates of 100 tons/day for continuous operation of about 30 days. Featuring high coal recovery and high product-gas calorific values, the underground process proved to be simple, reliable, and potentially controllable.

  17. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

    1995-01-01T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  18. Transforming coal for sustainability: a strategy for China

    E-Print Network [OSTI]

    energy, and ``modernized'' coal. By aggressively pursu- ing the advanced technology strategy now refers to the use of gasification technology to produce synthetic gas for power, clean fuelsTransforming coal for sustainability: a strategy for China Report by the Task Force on Energy

  19. Sixth annual coal preparation, utilization, and environmental control contractors conference

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    A conference was held on coal preparation, utilization and environmental control. Topics included: combustion of fuel slurries; combustor performance; desulfurization chemically and by biodegradation; coal cleaning; pollution control of sulfur oxides and nitrogen oxides; particulate control; and flue gas desulfurization. Individual projects are processed separately for the databases. (CBS).

  20. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04T23:59:59.000Z

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  1. Achieve smokeless flaring -- Air or steam assist?

    SciTech Connect (OSTI)

    Chaudhuri, M.; Diefenderfer, J.J.

    1995-06-01T23:59:59.000Z

    Because of the technological advances made during the past several years, flare system design has become more important with respect to the economics of plant operation. There are many options available to the engineer during the initial design phase of a flare system for a chemical process industries (CPI) plant. An earlier CEP article covered the basics of flare design and how to choose and size the right equipment, such as stack height and diameter, tip design, pilots and pilots flame detectors, seals, and so on. One of the most important factors is how to achieve smokeless operation, which is accomplished by either steam-assisted or air-assisted elevated flare stack assemblies. This article compares the two approaches and outlines the advantages and disadvantages of each with respect to economics, practicality, and operability. Table 1 summarizes the data for a typical plant in the U.S. Gulf Coast area that will be used as the basis for comparing costs.

  2. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08T23:59:59.000Z

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  3. Coal Severance Tax (North Dakota)

    Broader source: Energy.gov [DOE]

    The Coal Severance Tax is imposed on all coal severed for sale or industrial purposes, except coal used for heating buildings in the state, coal used by the state or any political subdivision of...

  4. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    Hydrogen (Natural Gas, pipeline) Hydrogen (Natural Gas,liquid H2 truck) Hydrogen (Coal, pipeline) Electricity (production? Hydrogen Production Mix Natural Gas, pipeline,

  5. TOXIC SUBSTANCES FROM COAL COMBUSTION

    SciTech Connect (OSTI)

    A KOLKER; AF SAROFIM; CL SENIOR; FE HUGGINS; GP HUFFMAN; I OLMEZ; J LIGHTY; JOL WENDT; JOSEPH J HELBLE; MR AMES; N YAP; R FINKELMAN; T PANAGIOTOU; W SEAMES

    1998-12-08T23:59:59.000Z

    The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), Physical Sciences Inc. (PSI) has teamed with researchers from USGS, MIT, the University of Arizona (UA), the University of Kentucky (UK), the University of Connecticut (UC), the University of Utah (UU) and the University of North Dakota Energy and Environmental Research Center (EERC) to develop a broadly applicable emissions model useful to regulators and utility planners. The new Toxics Partitioning Engineering Model (ToPEM) will be applicable to all combustion conditions including new fuels and coal blends, low-NO combustion systems, and new power generation x plants. Development of ToPEM will be based on PSI's existing Engineering Model for Ash Formation (EMAF). This report covers the reporting period from 1 July 1998 through 30 September 1998. During this period distribution of all three Phase II coals was completed. Standard analyses for the whole coal samples were also completed. Mössbauer analysis of all project coals and fractions received to date has been completed in order to obtain details of the iron mineralogy. The analyses of arsenic XAFS data for two of the project coals and for some high arsenic coals have been completed. Duplicate splits of the Ohio 5,6,7 and North Dakota lignite samples were taken through all four steps of the selective leaching procedure. Leaching analysis of the Wyodak coal has recently commenced. Preparation of polished coal/epoxy pellets for probe/SEM studies is underway. Some exploratory mercury LIII XAFS work was carried out during August at the Advanced Photon Source (APS), the new synchrotron facility at Argonne National Laboratory, Chicago, IL. Further analysis of small-scale combustion experiments conducted at PSI in Phase I was completed this quarter. The results of these experiments for the first time suggest almost complete vaporization of certain trace elements (Se, Zn) from coal combustion in the flame zone, in accordance with theoretical equilibrium predictions. Other elements (As, Sb, Cr) appeared considerably less volatile and may react with constituents in the bulk ash at combustion temperatures. The combustion section of the University of Arizona's Downflow Combustor was completely rebuilt. The University of Utah worked on setting up EPA Method 26A to give the capability to measure chlorine in flue gas. The chlorine kinetic calculations performed as part of the Phase I program were found to have an error in the initial conditions. Therefore, the calculations were re-done this quarter with the correct starting conditions. Development of a quasi-empirical emissions model based on reported emissions of particulate matter from field measurements was continued this quarter. As a first step in developing the ToPEM, we developed a sub-model that calculates the evaporation of major elements (Na, K, Fe, Si, Al, Ca and Mg) from both inherent and extraneous minerals of coal. During this quarter, this sub-model was included into EMAF, which formed the ToPEM. Experimental data from the Phase I program were used to test and modify the sub-model and the ToPEM.

  6. VIRGINIA CENTER FOR COAL & ENERGY RESEARCH WINTER 1998-99 / VOL. XVIII, NO. 1 Global Warming

    E-Print Network [OSTI]

    VIRGINIA CENTER FOR COAL & ENERGY RESEARCH WINTER 1998-99 / VOL. XVIII, NO. 1 Global Warming Our the opinion. Can the VCCER with its mandated interests in coal and energy be any different? Well, we do try QUARTERLY COAL PRODUCTION STATISTICS 5 GAS PRODUCTION STATISTICS 6 1840 1860 1880 1900 1920 1940 1960 1980

  7. Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow Conditkms

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    . `E 22673 7ype-Curve ., Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow the presenceof water in the coal seam and its co- production with gas. The developed type curves are capable dynamics of methane in coal seams. A previously developed numerical model has been instrumental

  8. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Plant - without coking (lb/hr) Feed Coal* Hydrogen YieldsCoking Summary Cost Estimates for Solvent Refining of Five U.S. CoalsCoal Handling and Preparation Preheaters and Dissolvers Mineral Separation (Filters) Solvent Recovery Gas Recovery Mineral Residue Processing and Storage Coking

  9. Comprehensive Report to Congress Clean Coal Technology Program: Clean power from integrated coal/ore reduction

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report describes a clean coal program in which an iron making technology is paired with combined cycle power generation to produce 3300 tons per day of hot metal and 195 MWe of electricity. The COREX technology consists of a metal-pyrolyzer connected to a reduction shaft, in which the reducing gas comes directly from coal pyrolysis. The offgas is utilized to fuel a combined cycle power plant.

  10. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

    1992-01-01T23:59:59.000Z

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  11. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15T23:59:59.000Z

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  12. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Ursla Levy; John Sale; Nenad Sarunac

    2006-01-01T23:59:59.000Z

    This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energy extracted from boiler flue gas.

  13. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R. (Lexington, MA)

    1987-01-01T23:59:59.000Z

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  14. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  15. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07T23:59:59.000Z

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  16. Summary: U.S. Crude Oil, Natural Gas, and Natural Gas Liquids...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Summary: U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves 2009 November 2010 U.S. Energy Information Administration Office of Oil, Gas, and Coal Supply...

  17. Chlorine in coal and its relationship with boiler corrosion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-09-01T23:59:59.000Z

    Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties. In this quarter, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the forms and the evolution characteristics of chlorine in coals. The TGA-FTIR results indicate that under oxidation condition, both British and Illinois coals release hydrogen chloride gas. Illinois coals release the gas at high temperature with maximum evolution temperature ranged between 210 and 280 C. The XANES results indicate that chlorine in coal exists in ionic forms including a solid salt form. The solid NaCl salt form, however, is observed only in some of the British coals and none of the Illinois coals. These results combined with TGA-FTIR results suggest that the chlorine ions in Illinois coals are different from the chlorine ions in British coals.

  18. Environmental Permitting of a Low-BTU Coal Gasification Facility

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  19. Environmental Permitting of a Low-BTU Coal Gasification Facility 

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  20. Application of Multivariable Control to Oil and Coal Fired Boilers

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01T23:59:59.000Z

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, hydrocarbon, opacity...

  1. Global Installed Capacity of Coal Fired Power Generation to Reach...

    Open Energy Info (EERE)

    Global Installed Capacity of Coal Fired Power Generation to Reach 2,057.6 GW by 2019 Home > Groups > Increase Natural Gas Energy Efficiency John55364's picture Submitted by...

  2. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  3. International perspectives on coal preparation

    SciTech Connect (OSTI)

    NONE

    1997-12-31T23:59:59.000Z

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  4. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15T23:59:59.000Z

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  5. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01T23:59:59.000Z

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  6. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29T23:59:59.000Z

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  7. Development of an advanced high efficiency coal combustor for boiler retrofit

    SciTech Connect (OSTI)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01T23:59:59.000Z

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  8. Development of an advanced high efficiency coal combustor for boiler retrofit. Summary report

    SciTech Connect (OSTI)

    LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

    1990-04-01T23:59:59.000Z

    The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

  9. Coal demonstration plants. Quarterly report, July-September 1979

    SciTech Connect (OSTI)

    None

    1980-07-01T23:59:59.000Z

    The status of two coal liquefaction demonstration plants and of four coal gasification demonstration plants is reviewed under the following headings: company involved, contract number, funding, process name, process description, flowsheet, schedule, history and progress during the July-September quarter, 1979. Supporting projects in coal feeding systems, valves, grinding equipment, instrumentation, process control and water treatment are discussed in a similar way. Conceptual design work on commercial plants for coal to methanol and for a HYGAS high BTU gas plant were continued. (LTN)

  10. Investigation of plasma-aided bituminous coal gasification

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (United States)

    2009-04-15T23:59:59.000Z

    This paper presents thermodynamic and kinetic modeling of plasma-aided bituminous coal gasification. Distributions of concentrations, temperatures, and velocities of the gasification products along the gasifier are calculated. Carbon gasification degree, specific power consumptions, and heat engineering characteristics of synthesis gas at the outlet of the gasifier are determined at plasma air/steam and oxygen/steam gasification of Powder River Basin bituminous coal. Numerical simulation showed that the plasma oxygen/steam gasification of coal is a more preferable process in comparison with the plasma air/steam coal gasification. On the numerical experiments, a plasma vortex fuel reformer is designed.

  11. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    associated with coal generation occur at the smokestack. Theassociated with coal-fired electricity generation by up toCoal, Domestic Natural Gas, LNG, and SNG for Electricity Generation,

  12. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01T23:59:59.000Z

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  13. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  14. Weekly Natural Gas Storage Report - EIA

    U.S. Energy Information Administration (EIA) Indexed Site

    Careers Feedback Contact Us Sources & Uses Petroleum Coal Natural Gas Renewable Nuclear Electricity Consumption Total Energy Topics Analysis & Projections Environment Markets &...

  15. Slurry Phase Iron Catalysts for Indirect Coal Liquefaction

    SciTech Connect (OSTI)

    Abhaya K. Datye

    1998-09-10T23:59:59.000Z

    This report describes research conducted to support the DOE program in indirect coal liquefaction. Specifically, we have studied the attrition behavior of Iron Fischer-Tropsch catalysts, their interaction with the silica binder and the evolution of iron phases in a synthesis gas conversion process. The results provide significant insight into factors that should be considered in the design of catalysts for the conversion of coal-derived synthesis gas into liquid fuels.

  16. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31T23:59:59.000Z

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  17. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31T23:59:59.000Z

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  18. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29T23:59:59.000Z

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  19. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology (United States) Illinois Coal Association (United States))

    1992-01-01T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. This project will bring the expertise of four organizations together to perform the various tasks. The Illinois Coal Association will help direct the project to be the most beneficial to the Illinois coal industry. DESTEC Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technology will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handlability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals. As reported earlier, a variety of possible samples of coal have been analyzed and the gasification performance evaluation reported. Additionally, commercial sized samples of -28 mesh {times} 100 mesh coal -100 {times} 0 coal were subjected to pumpability testing. Neither the coarse product nor the fine product by themselves proved to be good candidates for trouble free pumping, but the mix of the two proved to be a very acceptable product

  20. Coal reburning for cyclone boiler NO sub x control demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-01-01T23:59:59.000Z

    Babcock Wilcox engineering studies followed by pilot-scale testing has developed/confirmed the potential of utilizing gas, oil or coal reburning as a viable NO{sub x} reduction technology. To date, two US sponsored programs promote natural gas/oil as a reburning fuel because it was believed that gas/oil will provide significantly higher combustion efficiency than using coal at the reburn zone. Although B W has shown that gas/oil reburning will play a role in reducing NO{sub x} emissions from cyclone boilers, B W coal reburning research has also shown that coal as a reburning fuel performs nearly as well as gas/oil without deleterious effects on combustion efficiency. This means that boilers using reburning for NO, control can maintain 100% coal usage instead of switching to 20% gas/oil for reburning. As a result of the B W performed coal reburning research, the technology has advanced to the point which it is now ready for demonstration on a commercial scale.

  1. Coal-bed methane - New energy for today and the future

    SciTech Connect (OSTI)

    Murray, D.K. (Keith Murray and Associates, Inc., Golden, CO (USA)); Schwochow, S.D. (Colorado School of Mines, Golden (USA))

    1990-05-01T23:59:59.000Z

    Coal is one of the richest known sources of hydrocarbons. This heterogeneous material has the unique characteristic of being both a source and a reservoir of natural gas. By virtue of their maturation to high rank some coals have the capacity to generate more than 8,000 ft{sup 3} of methane per ton of coal. Although most of this gas eventually has been lost over 400 trillion ft{sup 3} remains in place in US coal basins. The Potential Gas Committee has estimated that at least 90 trillion ft{sup 3} likely are recoverable. Coal-bed methane exploration requires application of both coal geology and petroleum geology as well as nonconventional approaches to reservoir engineering. With advanced technologies developed largely through cooperative efforts of the Gas Research Institute and industry, researchers and explorationists are better understanding the geological and engineering peculiarities of coal reservoirs. Commercial coal-bed methane development occurs basically in two diverse geologic settings: (1) thin, shallow coals of Pennsylvanian age in the Black Warrior and Appalachian basins and (2) thicker, deeper coals of Cretaceous age in the Rocky Mountains, principally the San Juan, Piceance, Raton, and Green River basins. Recent exploration has targeted shallow, anomalously thick but lower-rank, low-gas-content Tertiary coals in Wyoming. Coal basins in Washington, British Columbia, and Alberta also show potential. Methane in coal beds is an immense, virtually untapped source of environmentally acceptable, pipeline-quality energy. In light of increasing demand for natural gas, coal-bed methane is becoming an economically viable, low-risk exploratory and development objective.

  2. Comparative assessment of health and safety impacts of coal use

    SciTech Connect (OSTI)

    Not Available

    1980-03-01T23:59:59.000Z

    Increasing the use of coal to replace oil and gas consumption is considered beneficial for economic and political reasons. The evaluation of this report, however, is that the shift to coal can involve significant health, safety, and environmental impacts compared to those from oil and natural gas systems, which are considerably less adverse than those of any coal energy system in use today. An evaluation and comparison of the potential impacts from the various alternative coal technologies would be useful to both governmental and industrial policy planners and would provide them with information relevant to a decision on assistance, incentives, and prioritization among the energy technologies. It is, therefore, the main objective of this report to review the key health, safety, and environmental impacts of some promising coal energy technologies and to compare them.

  3. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01T23:59:59.000Z

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  4. Pressurized pyrolysis and gasification of Chinese typical coal samples

    SciTech Connect (OSTI)

    Hanping Chen; Zhiwu Luo; Haiping Yang; Fudong Ju; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2008-03-15T23:59:59.000Z

    This paper aims to understand the pyrolysis and gasification behavior of different Chinese coal samples at different pressures. First, the pyrolysis of four typical Chinese coals samples (Xiaolongtan brown coal, Shenfu bituminous coal, Pingzhai anthracite coal, and Heshan lean coal) were carried out using a pressurized thermogravimetric analyzer at ambient pressure and 3 MPa, respectively. The surface structure and elemental component of the resultant char were measured with an automated gas adsorption apparatus and element analyzer. It was observed that higher pressure suppressed the primary pyrolysis, while the secondary pyrolysis of coal particles was promoted. With respect to the resultant solid char, the carbon content increased while H content decreased; however, the pore structure varied greatly with increasing pressure for different coal samples. For Xiaolongtan brown coal (XLT) char, it decreased greatly, while it increased obviously for the other three char types. Then, the isothermal gasification behavior of solid char particles was investigated using an ambient thermal analyzer with CO{sub 2} as the gasifying agent at 1000{sup o}C. The gasification reactivity of solid char was decreased greatly with increasing pyrolysis pressure. However, the extent of change displayed a vital relation with the characteristics of the original coal sample. 26 refs., 5 figs., 5 tabs.

  5. acute gout flare: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ones (X9) are selected as representative of the flaring Sun. The emission measure distribution vs. temperature, EM(T), of the flaring regions is derived from YohkohSXT...

  6. anterior chamber flare: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ones (X9) are selected as representative of the flaring Sun. The emission measure distribution vs. temperature, EM(T), of the flaring regions is derived from YohkohSXT...

  7. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    anthracite, lignite and brown coal. While bituminous coal isproduction of lignite and brown coal, which also increasedtonnes. Whereas lignite and brown coal accounted for 4% of

  8. Technology Adoption and Regulatory Regimes: Gas Turbines Electricity Generators from 1980 to 2001

    E-Print Network [OSTI]

    Ishii, Jun

    2004-01-01T23:59:59.000Z

    Clean Air Amendments helped lower the cost of natural gas turbines vis-a-vis coal based technologies.

  9. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

    2010-01-01T23:59:59.000Z

    the subsurface geology and the gas bubble (with oil) plumesgeology and gas-phase (methane) seepage for the Coal Oilwith offshore oil production. Geology 27:1047–1050 Shindell

  10. Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J. [U.S. DOE; Stanko, Dennis C. [U.S. DOE

    2013-01-01T23:59:59.000Z

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  11. Geosphere in underground coal gasification

    SciTech Connect (OSTI)

    Daly, D.J.; Groenewold, G.H.; Schmit, C.R.; Evans, J.M.

    1988-07-01T23:59:59.000Z

    The feasibility of underground coal gasification (UCG), the in-situ conversion of coal to natural gas, has been demonstrated through 28 tests in the US alone, mainly in low-rank coals, since the early 1970s. Further, UCG is currently entering the commercial phase in the US with a planned facility in Wyoming for the production of ammonia-urea from UCG-generated natural gas. Although the UCG process both affects and is affected by the natural setting, the majority of the test efforts have historically been focused on characterizing those aspects of the natural setting with the potential to affect the burn. With the advent of environmental legislation, this focus broadened to include the potential impacts of the process on the environment (e.g., subsidence, degradation of ground water quality). Experience to date has resulted in the growing recognition that consideration of the geosphere is fundamental to the design of efficient, economical, and environmentally acceptable UCG facilities. The ongoing RM-1 test program near Hanna, Wyoming, sponsored by the US Department of Energy and an industry consortium led by the Gas Research Institute, reflects this growing awareness through a multidisciplinary research effort, involving geoscientists and engineers, which includes (1) detailed geological site characterization, (2) geotechnical, hydrogeological, and geochemical characterization and predictive modeling, and (3) a strategy for ground water protection. Continued progress toward commercialization of the UCG process requires the integration of geological and process-test information in order to identify and address the potentially adverse environmental ramifications of the process, while identifying and using site characteristics that have the potential to benefit the process and minimize adverse impacts.

  12. Investigation into the effects of trace coal syn gas species on the performance of solid oxide fuel cell anodes, PhD. thesis, Russ College of Engineering and Technology of Ohio University

    SciTech Connect (OSTI)

    Trembly, J.P.

    2007-06-01T23:59:59.000Z

    Coal is the United States’ most widely used fossil fuel for the production of electric power. Coal’s availability and cost dictates that it will be used for many years to come in the United States for power production. As a result of the environmental impact of burning coal for power production more efficient and environmentally benign power production processes using coal are sought. Solid oxide fuel cells (SOFCs) combined with gasification technologies represent a potential methodology to produce electric power using coal in a much more efficient and cleaner manner. It has been shown in the past that trace species contained in coal, such as sulfur, severely degrade the performance of solid oxide fuel cells rendering them useless. Coal derived syngas cleanup technologies have been developed that efficiently remove sulfur to levels that do not cause any performance losses in solid oxide fuel cells. The ability of these systems to clean other trace species contained in syngas is not known nor is the effect of these trace species on the performance of solid oxide fuel cells. This works presents the thermodynamic and diffusion transport simulations that were combined with experimental testing to evaluate the effects of the trace species on the performance of solid oxide fuel cells. The results show that some trace species contained in coal will interact with the SOFC anode. In addition to the transport and thermodynamic simulations that were completed experimental tests were completed investigating the effect of HCl and AsH3 on the performance of SOFCs.

  13. Investigation of plasma velocity field solar flare footpoints

    E-Print Network [OSTI]

    Mrozek, Tomasz

    of Wroclaw NCN Grant 2011/01/M/ST9/06096 #12;The Solar Flare - observations #12;chromosphere corona photosphere The Solar Flare - cartoon - conversion of magnetic energy into other forms - transport of energyInvestigation of plasma velocity field in solar flare footpoints from RHESSI observations T. Mrozek

  14. Dimethyl ether (DME) from coal as a household cooking fuel in China

    E-Print Network [OSTI]

    be made from any carbonaceous feedstock, including natural gas, coal, or biomass, using establishedDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

  15. Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California

    E-Print Network [OSTI]

    Luyendyk, Bruce

    geology and gas-phase (methane) seepage for the Coal Oil Point (COP) seep field, one of the worldORIGINAL Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field's largest and best-studied marine oil and gas seep fields, located over a producing hydrocarbon reservoir

  16. Measurement of Oil and Gas Emissions from a Marine Seep

    E-Print Network [OSTI]

    Leifer, Ira; Boles, J R; Luyendyk, B P

    2007-01-01T23:59:59.000Z

    hydrocarbon seeps near Coal Oil Point, California, Marineet al. , 2007, Measurement of Oil and Gas Emissions from aand P.G. Mikolaj, Natural oil seepage at Coal Oil Point,

  17. STATISTICS OF FLARES SWEEPING ACROSS SUNSPOTS

    SciTech Connect (OSTI)

    Li Leping; Zhang Jun, E-mail: lepingli@ourstar.bao.ac.c, E-mail: zjun@ourstar.bao.ac.c [Key Laboratory of Solar Activity, National Astronomical Observatories, Chinese Academy of Sciences, Beijing 100012 (China)

    2009-11-20T23:59:59.000Z

    Flare ribbons are always dynamic and sometimes sweep across sunspots. After examining 588 (513 M-class and 75 X-class) flare events observed by the TRACE satellite and the Hinode/Solar Optical Telescope from 1998 May to 2009 May, we choose the event displaying one of the flare ribbons that completely sweeps across the umbra of a main sunspot of the corresponding active region, and finally obtain 20 (7 X-class and 13 M-class) events as our sample. In each event, we define the main sunspot completely swept across by the flare ribbon as the A-sunspot and its nearby opposite polarity sunspot as the B-sunspot. Observations show that the A-sunspot is a following polarity sunspot in 18 events and displays flux emergence in 13 cases. All of the B-sunspots are relatively simple, exhibiting either one main sunspot or one main sunspot and several small neighboring sunspots (pores). In two days prior to the flare occurrence, the A-sunspot rotates in all the cases, while the B-sunspot rotates in 19 events. The total rotating angle of the A-sunspot and B-sunspot rotates is 193{sup 0} on average, and the rotating directions are the same in 12 events. In all cases; the A-sunspot and B-sunspot manifest shear motions with an average shearing angle of 28.{sup 0}5, and in 14 cases, the shearing direction is opposite to the rotating direction of the A-sunspot. We suggest that the emergence, the rotation, and the shear motions of the A-sunspot and B-sunspot result in the phenomenon that flare ribbons sweep across sunspots completely.

  18. Corresponding author: Tel. (617) 253-3901, Fax. (617) 253-9845, Email: jrm1@mit.edu THE FUTURE OF COAL CONSUMPTION IN A CARBON CONSTRAINED WORLD

    E-Print Network [OSTI]

    , and the dispatch between coal and natural gas generation technologies. In this paper, we develop plausible, yet of penalties or restrictions on carbon dioxide emissions, coal use for electricity generation is expected coal and natural gas generation technologies. This analysis emphasizes the time frame to 2050

  19. Blazar Flaring Rates Measured with GLAST

    E-Print Network [OSTI]

    C. D. Dermer; B. L. Dingus

    2003-12-22T23:59:59.000Z

    We derive the minimum observing time scales to detect a blazar at a given flux level with the LAT on GLAST in the scanning and pointing modes. Based upon Phase 1 observations with EGRET, we predict the GLAST detection rate of blazar flares at different flux levels. With some uncertainty given the poor statistics of bright blazars, we predict that a blazar flare with integral flux >~ 200e-8 ph(> 100 MeV) cm^{-2} s^{-1}, which are the best candidates for Target of Opportunity pointings and extensive temporal and spectral studies, should occur every few days.

  20. Blazar Flaring Rates Measured with GLAST

    E-Print Network [OSTI]

    Dermer, C D

    2004-01-01T23:59:59.000Z

    We derive the minimum observing time scales to detect a blazar at a given flux level with the LAT on GLAST in the scanning and pointing modes. Based upon Phase 1 observations with EGRET, we predict the GLAST detection rate of blazar flares at different flux levels. With some uncertainty given the poor statistics of bright blazars, we predict that a blazar flare with integral flux >~ 200e-8 ph(> 100 MeV) cm^{-2} s^{-1}, which are the best candidates for Target of Opportunity pointings and extensive temporal and spectral studies, should occur every few days.

  1. Water pollution control for underground coal gasification

    SciTech Connect (OSTI)

    Humenick, M.J.

    1984-06-01T23:59:59.000Z

    Water pollution arising from underground gasification of coal is one of the important considerations in the eventual commercialization of the process. Because many coal seams which are amenable to in situ gasification are also ground-water aquifers, contaminants may be released to these ground waters during and after gasification. Also, when product gas is processed above ground for use, wastewater streams are generated which are too polluted to be discharged. The purpose of this paper is to characterize the nature of the groundwater and above-ground pollutants, discuss the potential long and short-term effects on ground water, propose control and restoration strategies, and to identify potential wastewater treatment schemes.

  2. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15T23:59:59.000Z

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  3. Coal surface structure and thermodynamics. Final report

    SciTech Connect (OSTI)

    Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

    1994-05-01T23:59:59.000Z

    Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

  4. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    ~ - - - - - ' Gri~ing Feed Coal Slurry Feed Pump Filterused to heat a coal-solvent slurry up to the tempera- turePULVERIZED COAL DISSOLVER PRODUCT SLURRY L-. 5 TJ'OON , ~ (

  5. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

  6. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal-to-hydrogen plant capital costs .Capital cost of pulverized coal plant ($/kW) Capital cost ofIGCC coal plant ($/kW) Capital cost of repowering PC plant

  7. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Clean Coal Produced, * T/D (Dry Basis) Installed Plant Cost,Plant Cost, MM$ Net Operating Cost, $/T (Clean Coal Basis)Cost increments fora 25246 ton coal per day SRC plant are

  8. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    5 Figure 1: Map of U.S. coal plants and generating1: Map of U.S. coal plants and generating units (GED, 2006a)of an electric generating coal power plant that would be

  9. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    Council (NCC), 2006, “Coal: America’s Energy Future”, VolumeAssessments to Inform Energy Policy, “Coal: Research andOF RAIL TRANSPORTATION OF COAL The Federal Energy Regulatory

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    OF RAIL TRANSPORTATION OF COAL The Federal Energy RegulatoryPlants Due to Coal Shortages”, Federal Energy RegulatoryCouncil (NCC), 2006, “Coal: America’s Energy Future”, Volume

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    of total electricity generation is because coal plants haveplants come to play an important role in the electricity generationplants will be built in the years around 2020, thereby increasing coal’s share of electricity generation

  12. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01T23:59:59.000Z

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  13. Structure, constitution and utilization of low rank Indian coal

    SciTech Connect (OSTI)

    Iyengar, M.S.; Iyengar, V.A. [M.S. Iyengar and Associates, New Delhi (India)

    1996-12-31T23:59:59.000Z

    This paper briefly reviews the work done on lignite and sub-bituminous coals. Surface area and moisture adsorption dependency on functional group is described. The role of hydrogen bonding in the briquetting of lignite and of alkyl groups in inducing caking properties are discussed. The dualistic behavior of abnormal coals as both a low and high rank coal is also discussed in relation to the nature of their sulphur groups. On the utilization side, processes are described for: (1) Utilization of non-caking coal in the reduction of iron ore. Coal is first briquetted using a lime-tar binder. It is then carbonized for reducing iron ore. The bar is recovered and recycled. (2) Production of carbon black from low rank coals. In this process, coal is carbonized at high temperature in a fluidized bed. Carbon black, for tire industry, is obtained with char as by-product. (3) Utilization of flue gases of industry is also discussed. In this new approach, the flue gas is reduced to synthesis gas by additional fuel and the inevitable surplus heat. The viability of the process is illustrated by details of a recent study in a cement plant. In addition to the above, the implication of recycling flue gas in automobile engines to make them more environment friendly and cost effective, is also discussed.

  14. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01T23:59:59.000Z

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  15. Fixed-bed gasification research using US coals. Volume 2. Gasification of Jetson bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-03-31T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report describes the gasification testing of Jetson bituminous coal. This Western Kentucky coal was gasified during an initial 8-day and subsequent 5-day period. Material flows and compositions are reported along with material and energy balances. Operational experience is also described. 4 refs., 24 figs., 17 tabs.

  16. Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

  17. Fixed-bed gasification research using US coals. Volume 7. Gasification of Piney Tipple bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the seventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Piney Tipple bituminous coal. The period of the gasification test was July 18-24, 1983. 6 refs., 20 figs., 17 tabs.

  18. CO2 Sequestration Potential of Texas Low-Rank Coals

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

    2004-04-01T23:59:59.000Z

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The primary objectives for this reporting period were to construct a coal geological model for reservoir analysis and to continue acquisition of data pertinent to coal characterization that would help in determining the feasibility of carbon dioxide sequestration. Structural analysis and detailed correlation of coal zones are important for reservoir analysis and modeling. Evaluation of existing well logs indicates local structural complexity that complicates interpretations of continuity of the Wilcox Group coal zones. Therefore, we have begun searching for published structural maps for the areas of potential injection CO{sub 2}, near the coal-fired power plants. Preliminary evaluations of data received from Anadarko Petroleum Corporation suggest that coal properties and gas content and chemical composition vary greatly among coal seams. We are assessing the stratigraphic and geographic distributions and the weight of coal samples that Anadarko has provided to select samples for further laboratory analysis. Our goal is to perform additional isotherm analyses with various pure and/or mixed gases to enhance our characterization model. Additionally, we are evaluating opportunities for field determination of permeability with Anadarko, utilizing one of their wells.

  19. Sibley station low-sulfur coal conversion program

    SciTech Connect (OSTI)

    Rupinskas, R.L. [Sargent & Lundy LLC, Chicago, IL (United States); Rembold, D.F. [Missouri Public Service, Kansas City, MO (United States)

    1995-03-01T23:59:59.000Z

    After embarking on an upgrade project in 1986 that was designed to allow efficient and reliable operation of its coal-fired Sibley station through 2010, Missouri Public Service (MPS) faced the uncertainty of impending acid-rain legislation. To protect its investment in the Sibley Rebuild Program, the utility evaluated compliance options based on the emerging legislation and concluded that switching to low-sulfur coal offered the least-cost compliance approach. Compared to installing a scrubber, switching to a low-sulfur coal was also more straightforward, although not without challenges and complications. This paper reviews the Sibley low-sulfur coal conversion program. At Sibley, fuel switching was chosen only after numerous internal and external studies; it withstood late challenges from natural gas and allowance trading. Switching demanded additional equipment to blend Power River Basin coals and other coals, and demanded additional and upgraded protective equipment in the areas of fire protection, dust collection, and explosion prevention. In the year since the coal conversion project was completed the facility has operated reliably, the economic benefits of the lower cost Powder River Basin coals have been realized, and the station has also met the requirements of both phases of the acid rain legislation. Fuel switching at Sibley required a team approach and careful analysis. The coal conversion project also required attention and dedication by team members in order to minimize fuel costs while maintaining optimum plant efficiency and availability.

  20. Coal Mining Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.