National Library of Energy BETA

Sample records for gas flaring coal

  1. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Virginia Natural Gas Vented and Flared (Million ... Referring Pages: Natural Gas Vented and Flared Virginia Natural Gas Gross Withdrawals and ...

  2. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Date: 12312015 Next Release Date: 01292016 Referring Pages: Natural Gas Vented and Flared Arizona Natural Gas Gross Withdrawals and Production Natural Gas Vented and Flared...

  3. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Release Date: 03312016 Next Release Date: 04292016 Referring Pages: Natural Gas Vented and Flared Virginia Natural Gas Gross Withdrawals and Production Natural Gas Vented and ...

  4. Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vented and Flared (Million Cubic Feet) Virginia Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...

  5. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the

  6. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  7. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  8. Federal Offshore--Gulf of Mexico Natural Gas Vented and Flared...

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Federal Offshore--Gulf of Mexico Natural Gas Vented ... Referring Pages: Natural Gas Vented and Flared Federal Offshore Gulf of Mexico Natural Gas ...

  9. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  10. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Kentucky Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 6 15 0 1970's 0 0 0 0 0 0 0 0 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016

  11. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Ohio Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 0 0 0 330 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages:

  12. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Oklahoma Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 126,629 129,408 130,766 1970's 129,629 39,799 38,797 36,411 34,199 31,802 30,197 29,186 27,489 26,605 1980's 25,555 2000's 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release

  13. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 0 0 0 98 96 99 75 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring

  14. Arizona Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Arizona Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 347 367 277 26 47 32 101 1980's 143 106 162 108 182 124 122 125 123 95 1990's 22 56 23 21 8 0 0 1 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date:

  15. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Florida Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1970's 355 284 837 607 1980's 677 428 435 198 34 13 54 30 166 450 1990's 286 482 245 205 220 28 - 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016

  16. Illinois Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Illinois Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 126 102 93 1970's 122 3,997 1,806 0 0 0 0 0 0 0 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date:

  17. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Tennessee Natural Gas Vented and Flared (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 0 0 0 1970's 0 408 180 165 376 585 339 156 117 126 1980's 0 0 0 0 0 0 0 0 0 0 1990's 0 0 0 0 0 0 0 0 0 2000's 0 0 0 0 0 2010's 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016

  18. Oxygen permeation and coal-gas-assisted hydrogen production using...

    Office of Scientific and Technical Information (OSTI)

    Oxygen permeation and coal-gas-assisted hydrogen production using oxygen transport membranes Citation Details In-Document Search Title: Oxygen permeation and coal-gas-assisted ...

  19. DOE - Fossil Energy: The Cleanest Coal Technology - A Real Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5-Cleanest Coal Technology An Energy Lesson Cleaning Up Coal The Cleanest Coal Technology - a Real Gas Don't think of coal as a solid black rock. Think of it as a mass of atoms. ...

  20. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C.; Zboray, James A.

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  1. Levelized Costs for Nuclear, Gas and Coal for Electricity, under...

    Office of Scientific and Technical Information (OSTI)

    Conference: Levelized Costs for Nuclear, Gas and Coal for Electricity, under the Mexican Scenario Citation Details In-Document Search Title: Levelized Costs for Nuclear, Gas and ...

  2. Conventional Energy (Oil, Gas, and Coal) Forum & Associated Vertical...

    Office of Environmental Management (EM)

    CONVENTIONAL ENERGY (OIL, GAS & COAL) FORUM & ASSOCIATED VERTICAL BUSINESS DEVELOPMENT ... South, Las Vegas, NV 89119 The dynamic world of conventional energy (focusing on oil, gas ...

  3. Natural gas from coal, courtesy of microbes | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to view larger. Natural gas from coal, courtesy of microbes November 20, 2015 Tweet EmailPrint The key to extracting usable energy from deep coal seams and depleted oil reservoirs ...

  4. Production of Substitute Natural Gas from Coal

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-01-31

    The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

  5. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0

  6. Illinois Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  7. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  8. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  9. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  10. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1996 - - - - - - - - - - - - 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0 2005 0 0 0 0 0 0 0 0 0 0 0 0 2006 0 0 0 0 0 0 0 0 0 0 0 0 2007 0 0 0 0 0 0 0 0 0 0 0 0 2008 0 0 0 0 0 0 0 0 0 0 0 0 2009 0 0 0 0 0 0 0 0 0 0 0 0

  11. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Vented and Flared (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1991 0 0 0 0 0 0 0 0 0 0 0 0 1992 0 0 0 0 0 0 0 0 0 0 0 0 1993 0 0 0 0 0 0 0 0 0 0 0 0 1994 0 0 0 0 0 0 0 0 0 0 0 0 1995 0 0 0 0 0 0 0 0 0 0 0 0 1996 0 0 0 0 0 0 0 0 0 0 0 0 1997 0 0 0 0 0 0 0 0 0 0 0 0 1998 0 0 0 0 0 0 0 0 0 0 0 0 1999 0 0 0 0 0 0 0 0 0 0 0 0 2000 0 0 0 0 0 0 0 0 0 0 0 0 2001 0 0 0 0 0 0 0 0 0 0 0 0 2002 0 0 0 0 0 0 0 0 0 0 0 0 2003 0 0 0 0 0 0 0 0 0 0 0 0 2004 0 0 0 0 0 0 0 0 0 0 0 0

  12. Natural gas beats coal in power generation

    U.S. Energy Information Administration (EIA) Indexed Site

    is expected to exceed the output from coal-fired power plants this year and in 2017. In ... have made coal a less competitive generating fuel for many U.S. power plant operators.

  13. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  14. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  15. Testing for market integration crude oil, coal, and natural gas

    SciTech Connect (OSTI)

    Bachmeier, L.J.; Griffin, J.M.

    2006-07-01

    Prompted by the contemporaneous spike in coal, oil, and natural gas prices, this paper evaluates the degree of market integration both within and between crude oil, coal, and natural gas markets. Our approach yields parameters that can be readily tested against a priori conjectures. Using daily price data for five very different crude oils, we conclude that the world oil market is a single, highly integrated economic market. On the other hand, coal prices at five trading locations across the United States are cointegrated, but the degree of market integration is much weaker, particularly between Western and Eastern coals. Finally, we show that crude oil, coal, and natural gas markets are only very weakly integrated. Our results indicate that there is not a primary energy market. Despite current price peaks, it is not useful to think of a primary energy market, except in a very long run context.

  16. Recovery Act: ArcelorMittal USA Blast Furnace Gas Flare Capture

    SciTech Connect (OSTI)

    Seaman, John

    2013-01-14

    The U.S. Department of Energy (DOE) awarded a financial assistance grant under the American Recovery and Reinvestment Act of 2009 (Recovery Act) to ArcelorMittal USA, Inc. (ArcelorMittal) for a project to construct and operate a blast furnace gas recovery boiler and supporting infrastructure at ArcelorMittal’s Indiana Harbor Steel Mill in East Chicago, Indiana. Blast furnace gas (BFG) is a by-product of blast furnaces that is generated when iron ore is reduced with coke to create metallic iron. BFG has a very low heating value, about 1/10th the heating value of natural gas. BFG is commonly used as a boiler fuel; however, before installation of the gas recovery boiler, ArcelorMittal flared 22 percent of the blast furnace gas produced at the No. 7 Blast Furnace at Indiana Harbor. The project uses the previously flared BFG to power a new high efficiency boiler which produces 350,000 pounds of steam per hour. The steam produced is used to drive existing turbines to generate electricity and for other requirements at the facility. The goals of the project included job creation and preservation, reduced energy consumption, reduced energy costs, environmental improvement, and sustainability.

  17. South Dakota Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Feet) Vehicle Fuel Price (Dollars per Thousand Cubic Feet) South Dakota Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 4.13 4.08 4.19 3.17 3.89 3.76 3.48 4.95 4.83 2000's 4.48 -- 4.14 -- -- -- -- -- -- -- 2010's -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date:

  18. Coal liquefaction and gas conversion: Proceedings. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  19. Ohio Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 12 11 12 12 12 12 12 12 12 12 12 12 2011 8 7 8 7 8 7 8 8 7 8 7 8 2012 8 7 8 7 8 7 8 8 7 8 7 8 2013 25 23 25 25 25 25 25 25 25 25 25 25 2014 30 27 30 29 30 29 30 30 29 30 29 30 2015 8 8 8 8 8 27 30 30 29 30 29 30 2016 33 30 33 32 47 46

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Ohio Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9

  20. Oklahoma Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 21 19 21 20 21 20 21 21 20 21 20 21 2011 22 20 22 21 22 21 22 22 21 22 21 22 2012 22 20 22 21 22 21 22 22 21 22 21 22 2013 29 27 29 28 29 28 29 29 28 29 28 29 2014 34 31 34 33 34 33 34 34 33 34 33 34 2015 24 22 24 24 24 32 34 34 33 34 33 34 2016 38 35 38 37 44 43

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Oklahoma Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  1. Oregon Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 16 14 16 15 16 15 16 16 15 16 15 16 2011 12 11 12 12 12 12 12 12 12 12 12 12 2012 12 11 12 12 12 12 12 12 12 12 12 12 2013 13 12 13 13 13 13 13 13 13 13 13 13 2014 15 14 15 15 15 15 15 15 15 15 15 15 2015 14 12 14 13 14 14 15 15 15 15 15 15 2016 17 15 17 17 16 15

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Oregon Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  2. Pennsylvania Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 25 23 25 24 25 24 25 25 24 25 24 25 2011 25 23 25 24 25 24 25 25 24 25 24 25 2012 25 24 25 24 25 24 25 25 24 25 24 25 2013 26 24 26 26 26 26 26 26 26 26 26 26 2014 31 28 31 30 31 30 31 31 30 31 30 31 2015 28 26 28 27 28 29 31 31 30 31 30 31 2016 35 31 35 33 37 36 Feet)

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Pennsylvania Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3

  3. Tennessee Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 1 1 1 1 1 1 1 1 1 1 1 1 2011 1 1 1 1 1 1 1 1 1 1 1 1 2012 1 1 1 1 1 1 1 1 1 1 1 1 2013 7 7 7 7 7 7 7 7 7 7 7 7 2014 9 8 9 8 9 8 9 9 8 9 8 9 2015 2 1 2 2 2 8 9 9 8 9 8 9 2016 10 9 10 9 21 20

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Tennessee Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 4.29 4.11 4.35 4.63 5.69 5.08 5.49

  4. Texas Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 198 179 198 192 198 192 198 198 192 198 192 198 2011 187 169 187 181 187 181 187 187 181 187 181 187 2012 187 175 187 181 187 181 187 187 181 187 181 187 2013 255 230 255 247 255 247 255 255 247 255 247 255 2014 300 271 300 290 300 290 300 300 290 300 290 300 2015 210 190 210 203 210 276 300 300 290 300 290 300 2016 333 301 333 322 393 380

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Texas Natural Gas Vehicle Fuel Price

  5. Utah Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 17 16 17 17 17 17 17 17 17 17 17 17 2011 25 22 25 24 25 24 25 25 24 25 24 25 2012 24 23 24 24 24 24 24 24 24 24 24 24 2013 19 17 19 18 19 18 19 19 18 19 18 19 2014 22 20 22 22 22 22 22 22 22 22 22 22 2015 28 25 28 27 28 21 22 22 22 22 22 22 2016 25 22 25 24 24 23

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Utah Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  6. West Virginia Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 1 1 1 1 1 1 1 1 1 1 1 1 2014 1 1 1 1 1 1 1 1 1 1 1 1 2015 0 0 0 0 0 1 1 1 1 1 1 1 2016 1 1 1 1 1 1 Feet)

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) West Virginia Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.90 2.90 3.82 2.08 2.20

  7. Colorado Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 21 19 21 20 21 20 21 21 20 21 20 21 2011 24 22 24 23 24 23 24 24 23 24 23 24 2012 24 22 24 23 24 23 24 24 23 24 23 24 2013 23 21 23 22 23 22 23 23 22 23 22 23 2014 27 24 27 26 27 26 27 27 26 27 26 27 2015 27 24 27 26 27 25 27 27 26 27 26 27 2016 30 27 30 29 31 30

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Colorado Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  8. Florida Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 5 5 5 5 5 5 5 5 5 5 5 5 2011 7 6 7 7 7 7 7 7 7 7 7 7 2012 7 7 7 7 7 7 7 7 7 7 7 7 2013 15 13 15 14 15 14 15 15 14 15 14 15 2014 18 16 18 17 18 17 18 18 17 18 17 18 2015 8 7 8 8 8 16 18 18 17 18 17 18 2016 19 18 19 19 27 26

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Florida Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 2.75

  9. Maryland Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 17 16 17 17 17 17 17 17 17 17 17 17 2011 19 17 19 18 19 18 19 19 18 19 18 19 2012 19 17 19 18 19 18 19 19 18 19 18 19 2013 17 15 17 17 17 17 17 17 17 17 17 17 2014 20 18 20 19 20 19 20 20 19 20 19 20 2015 21 19 21 20 21 19 20 20 19 20 19 20 2016 22 20 22 22 22 22

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Maryland Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  10. Michigan Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 22 20 22 21 22 21 22 22 21 22 21 22 2011 28 25 28 27 28 27 28 28 27 28 27 28 2012 28 26 28 27 28 27 28 28 27 28 27 28 2013 29 26 29 28 29 28 29 29 28 29 28 29 2014 34 31 34 33 34 33 34 34 33 34 33 34 2015 32 29 32 31 32 32 34 34 33 34 33 34 2016 38 35 38 37 42 4

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Michigan Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  11. Mississippi Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 2 2 2 2 2 2 2 2 2 2 2 2 2014 2 2 2 2 2 2 2 2 2 2 2 2 2015 0 0 0 0 0 2 2 2 2 2 2 2 2016 2 2 2 2 7 7 Feet)

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Mississippi Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.82 1.63 2.51 2.76 2.79 2.91

  12. Missouri Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 1 1 1 1 1 1 1 1 1 1 1 1 2011 1 0 1 0 1 0 1 1 0 1 0 1 2012 1 0 1 0 1 0 1 1 0 1 0 1 2013 4 3 4 3 4 3 4 4 3 4 3 4 2014 4 4 4 4 4 4 4 4 4 4 4 4 2015 1 1 1 1 1 4 4 4 4 4 4 4 2016 5 4 5 4 10 10

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Missouri Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 4.37 2.74 3.19 3.79 3.38 3.04 2000's

  13. Montana Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Montana Natural Gas Vehicle Fuel Consumption (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 0 0 0 0 0 0 0 0 0 0 0 0 2014 0 0 0 0 0 0 0 0 0 0 0 0 2015 0 0 0 0 0 0 0 0 0 0 0 0 2016 0 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring

  14. Nebraska Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 3 2 3 2 3 2 3 3 2 3 2 3 2011 3 3 3 3 3 3 3 3 3 3 3 3 2012 3 3 3 3 3 3 3 3 3 3 3 3 2013 4 4 4 4 4 4 4 4 4 4 4 4 2014 5 4 5 5 5 5 5 5 5 5 5 5 2015 3 3 3 3 3 4 5 5 5 5 5 5 2016 5 5 5 5 5 5

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Nebraska Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 4.67 2010's 15.10 15.29 - = No Data

  15. Nevada Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 71 64 71 69 71 69 71 71 69 71 69 71 2011 50 45 50 49 50 49 50 50 49 50 49 50 2012 50 47 50 48 50 48 50 50 48 50 48 50 2013 51 46 51 49 51 49 51 51 49 51 49 51 2014 60 54 60 58 60 58 60 60 58 60 58 60 2015 56 51 56 54 56 55 60 60 58 60 58 60 2016 66 60 66 64 92 89

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Nevada Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5

  16. New Mexico Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 25 23 25 25 25 25 25 25 25 25 25 25 2011 21 19 21 21 21 21 21 21 21 21 21 21 2012 21 20 21 21 21 21 21 21 21 21 21 21 2013 13 12 13 13 13 13 13 13 13 13 13 13 2014 16 14 16 15 16 15 16 16 15 16 15 16 2015 24 22 24 23 24 14 16 16 15 16 15 16 2016 17 16 17 17 15 14

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) New Mexico Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4

  17. New York Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 305 275 305 295 305 295 305 305 295 305 295 305 2011 328 297 328 318 328 318 328 328 318 328 318 328 2012 326 305 326 316 326 316 326 326 316 326 316 326 2013 282 254 282 273 282 273 282 282 273 282 273 282 2014 331 299 331 320 331 320 331 331 320 331 320 331 2015 367 332 367 355 367 305 331 331 320 331 320 331 2016 367 332 367 356 347 33

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) New York Natural Gas Vehicle Fuel Price

  18. North Dakota Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Vehicle Fuel Consumption (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 0 0 0 0 0 0 0 0 0 0 0 0 2014 0 0 0 0 0 0 0 0 0 0 0 0 2015 0 0 0 0 0 0 0 0 0 0 0 0 2016 0 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 8/31/2016 Next Release Date: 9/30/2016 Referring Pages: Natural Gas

  19. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  20. Wyoming Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 1 1 1 1 1 1 1 1 1 1 1 1 2011 2 1 2 2 2 2 2 2 2 2 2 2 2012 2 2 2 2 2 2 2 2 2 2 2 2 2013 2 2 2 2 2 2 2 2 2 2 2 2 2014 2 2 2 2 2 2 2 2 2 2 2 2 2015 2 2 2 2 2 2 2 2 2 2 2 2 2016 2 2 2 2 2 2

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Wyoming Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 5.66 5.74 5.66 4.62 5.34 5.24 5.56 6.30

  1. Indiana Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 4 4 4 4 4 4 4 4 4 4 4 4 2011 1 1 1 1 1 1 1 1 1 1 1 1 2012 1 1 1 1 1 1 1 1 1 1 1 1 2013 2 2 2 2 2 2 2 2 2 2 2 2 2014 2 2 2 2 2 2 2 2 2 2 2 2 2015 2 1 2 2 2 2 2 2 2 2 2 2 2016 2 2 2 2 8 7

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Indiana Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 2.69 4.71 4.25 5.23 5.11 7.13 7.20 5.53

  2. Kentucky Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0 0 0 0 0 0 0 2011 0 0 0 0 0 0 0 0 0 0 0 0 2012 0 0 0 0 0 0 0 0 0 0 0 0 2013 2 2 2 2 2 2 2 2 2 2 2 2 2014 2 2 2 2 2 2 2 2 2 2 2 2 2015 0 0 0 0 0 2 2 2 2 2 2 2 2016 3 2 3 3 4 4

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Kentucky Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 3.78 5.30 4.62 5.10 5.54 6.68 6.75 6.68

  3. Louisiana Natural Gas Vented and Flared (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 1 1 1 1 1 1 1 1 1 1 1 1 2011 1 1 1 1 1 1 1 1 1 1 1 1 2012 1 1 1 1 1 1 1 1 1 1 1 1 2013 4 4 4 4 4 4 4 4 4 4 4 4 2014 5 4 5 4 5 4 5 5 4 5 4 5 2015 1 1 1 1 1 4 5 5 4 5 4 5 2016 5 5 5 5 5 5

    Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Louisiana Natural Gas Vehicle Fuel Price (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 3.24 3.56 4.30 3.47 2.36 2.99 3.53 5.57

  4. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Levine, J.R.; Johnson, P.W.

    1992-11-30

    This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

  5. Permeability changes in coal resulting from gas desorption. Final report

    SciTech Connect (OSTI)

    Levine, J.R.; Johnson, P.W.

    1992-11-30

    This report documents studies on the effects of gas sorption on coal, with the intent of eventually evaluating how sorption and strain affect permeability. These studies were, carried out at the University of Alabama during the period from 1989 through 1992. Two major experimental methods were developed and used. In the strain experiments, electronic strain gauges were attached to polished blocks of coal in order to measure linear and volumetric swelling due to gas sorption. The effects of bedding plane orientation, of gas type, and of coal type were investigated. In the gravimetric experiment the weight of small samples of coal was measured during exposure to high pressure gases. Sample measurements were corrected for buoyancy effects and for sample swelling, and the results were plotted in the form of Langmuir isotherms. Experiments were conducted to determine the effect of grain size, coal type, moisture, and of sorbant gas. The advantage of this method is that it can be applied to very small samples, and it enabled comparison liptinite versus vitrinite concentrates, and kerogen rich versus kerogen depleted oil shales. Also included is a detailed discussion of the makeup of coal and its effect on gas sorption behavior.

  6. Gas turbine fuel from low-rank coal

    SciTech Connect (OSTI)

    Maas, D.J.; Smith, F.J.

    1986-06-01

    Five low-rank coals from the western United States were cleaned in a bench-scale heavy media separation procedures followed by acid leaching and hydrothermal processing. The objective of these cleaning steps was to determine the amenability of preparing gas turbine quality fuel from low-rank coal. The best candidate for scale-up was determined to be a Wyoming subbituminous coal from the eagle Butte mine. Two hundred thirty kilograms of cleaned and micronized coal/water fuel were prepared in pilot-scale equipment to determine process parameters and fuel characteristics. After establishing operating conditions, two thousand kilograms of cleaned and micronized coal/water and powdered coal fuel were produced for testing in a pilot-scale gas turbine combustor. An economic analysis was completed for a commercial-scale plant designed to produce clean gas turbine fuel from low-rank coal using the most promising process steps identified form the bench- and pilot-scale studies. 21 refs., 12 figs., 20 tabs.

  7. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  8. Conversion of Coal Mine Gas to ...

    Office of Scientific and Technical Information (OSTI)

    ... BECOME TOO GREAT WATER KNOCKOUT FIELD COMPRESSOR ... FROM GOV AT MARKETING ENGINEERING Dia (in) SHELTER FOR LNG ... Mines 2008) o >1,000' deep o >12' seam o Annual coal ...

  9. State of Illinois 1982 annual coal, oil and gas report

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    This data compilation contains statistics from the coal industry and petroleum industry of Illinois. Data are given on the production, accidents, explosives, and mechanization of coal mines. Metal mines are only briefly described. The report from the Division of Oil and Gas contains data on oil well completions, oil wells plugged, water input wells, and salt water and waste disposal wells. The results of hearings in the division are included. The Land Reclamation Division reports data on permits and acreage affected by surface mining of coal, limestone, shale, clay, sand, and gravel. 2 figures, 76 tables.

  10. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R.; Gregg, David W.

    1983-01-01

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  11. Saga of coal bed methane, Ignacio Blanco gas field, Colorado

    SciTech Connect (OSTI)

    Boyce, B.C.; Harr, C.L.; Burch, L.C. )

    1989-09-01

    Prior to the 1977 discovery of the Cedar Hill Basal Fruitland pool (the first officially designated coal-bed methane field in the western US) 28.5 bcf of gas had been produced from Fruitland Formation coal seams in the Ignacio Blanco Fruitland-Pictured Cliffs field, Northern San Juan basin, Colorado. The discovery well for the field, Southern Ute D-1, was drilled and completed in 1951 on the Ignacio anticline, La Plata County, Colorado. Initial completion was attempted in the Pictured Cliffs Sandstone. The well was plugged back after making water from the Pictured Cliffs and was completed in the lower coal-bearing section of the Fruitland Formation. The well produced 487,333 mcf of gas in nine years and was abandoned in 1959 due to water encroachment. Additionally, 52 similarly completed Ignacio anticline Fruitland wells were abandoned by the early 1970s due to the nemesis of If it's starting to kick water, you're through. Under today's coal-bed methane technology and economics, Amoco has twinned 12 of the abandoned wells, drilled five additional wells, and is successfully dewatering and producing adsorbed methane from previously depleted coal sections of the Ignacio structure. Field-wide drilling activity in 1988 exceeded all previous annual levels, with coal-seam degasification projects leading the resurgence. Drilling and completion forecasts for 1989 surpass 1988 levels by 50%.

  12. RCW 79.14 Mineral, Coal, Oil and Gas Leases | Open Energy Information

    Open Energy Info (EERE)

    79.14 Mineral, Coal, Oil and Gas Leases Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: RCW 79.14 Mineral, Coal, Oil and Gas...

  13. Petroleum Data, Natural Gas Data, Coal Data, Macroeconomic Data, Petroleum Import Data

    SciTech Connect (OSTI)

    2009-01-18

    Supplemental tables to the Annual Energy Outlook (AEO) 2006 for petroleum, natural gas, coal, macroeconomic, and import data

  14. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  15. Office of Oil, Gas, and Coal Supply Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    Office of Oil, Gas, and Coal Supply Statistics www.eia.gov Natural Gas Monthly August 2016 U.S. Department of Energy Washington, DC 20585 August 2016 U.S. Energy Information Administration | Natural Gas Monthly ii This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States

  16. Displacing oil and gas with coal: Constraints and opportunities

    SciTech Connect (OSTI)

    Langley, V.E.

    1982-01-01

    It is obvious that a major result of the oil supply interruptions of the 1970s was to dramatically increase the competitiveness of coal as an industrial and utility fuel. In fact, between 1973 and 1981, coal's share of the energy feed to the electric utility industry did increase from 43 to 52 percent. However, given the actual market place incentives, this increase is not a remarkable improvement, and reflects the fact that disappointingly few existing units have been converted from oil to coal. In the wake of the 1973 embargo, the passage of the Energy Supply and Coordination Act of 1974 (''ENSECA'') and the Power Plant and Industrial Fuel Use Act (''FUA'') provided the Executive Branch with the power to mandate the conversion of oil and gas units to coal. However, ENSECA lacked strong enforcement provisions and there resulted few conversions other than those which were made voluntarily on purely economic grounds. As a result, in 1978, Congress enacted the Fuel Use Act which placed the burden of proof upon owners to demonstrate that a specified coal convertible unit could not be converted.

  17. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W.

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  18. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  19. Ni/YSZ Anode Interactions with Impurities in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

    2009-10-16

    Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

  20. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W.

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  1. Combustion research related to utilization of coal as a gas turbine fuel

    SciTech Connect (OSTI)

    Davis-Waltermine, D.M.; Anderson, R.J.

    1984-06-01

    A nominal 293 kw (1 MBtu/hr) atmospheric pressure, refractory-lined combustor has been used to investigate the effects of a number of combustor and fuel dependent variables on combustion efficiency and flue gas characteristics for minimally cleaned, coal-derived gas (MCG) and coal water mixtures. The variables which have been evaluated include: percent excess air, air distribution, combustion air preheat temperature, swirl number, fuel feedrate, coal particle size, coal loading in slurry, and slurry viscosity. Characterization of the flue gas included major/minor gas species, alkali levels, and particulate loading, size, and composition. These atmospheric pressure combustion studies accompanied by data from planned pressurized studies on coal-water slurries and hot, minimally cleaned, coal-derived gas will aid in the determination of the potential of these fuels for use in gas turbines.

  2. Analysis of safety precautions for coal and gas outburst-hazardous strata

    SciTech Connect (OSTI)

    Hudecek, V.

    2008-09-15

    The author analyses coal and gas outbursts and generalizes the available data on the approaches to solving the problematics of these gas-dynamic events in the framework of Czech Republic Grant 'Estimate of the Safety Precautions for Coal and Gas Outburst Hazardous Strata'.

  3. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    2005-09-29

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  4. Method for increasing the calorific value of gas produced by the in situ combustion of coal

    DOE Patents [OSTI]

    Shuck, Lowell Z.

    1978-01-01

    The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

  5. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or

  6. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan

    SciTech Connect (OSTI)

    Tegen, S.

    2006-05-01

    Report comparing the impacts to states from equivalent new electrical generation from wind, natural gas, and coal.

  7. The Clean Coal Technology Program 100 MWe demonstration of gas suspension absorption for flue gas desulfurization

    SciTech Connect (OSTI)

    Hsu, F.E.; Hedenhag, J.G.; Marchant, S.K.; Pukanic, G.W.; Norwood, V.M.; Burnett, T.A.

    1997-12-31

    AirPol Inc., with the cooperation of the Tennessee Valley Authority (TVA) under a Cooperative Agreement with the United States Department of Energy, installed and tested a 10 MWe Gas Suspension Absorption (GSA) Demonstration system at TVA`s Shawnee Fossil Plant near Paducah, Kentucky. This low-cost retrofit project demonstrated that the GSA system can remove more than 90% of the sulfur dioxide from high-sulfur coal-fired flue gas, while achieving a relatively high utilization of reagent lime. This paper presents a detailed technical description of the Clean Coal Technology demonstration project. Test results and data analysis from the preliminary testing, factorial tests, air toxics texts, 28-day continuous demonstration run of GSA/electrostatic precipitator (ESP), and 14-day continuous demonstration run of GSA/pulse jet baghouse (PJBH) are also discussed within this paper.

  8. Secured electrical supply at least cost: Coal, gas, nuclear, hydro

    SciTech Connect (OSTI)

    Gavor, J.; Stary, O.; Vasicek, J.

    1995-12-01

    Electric power sector in East Central European countries finds in a difficult period. In the situation of demand stagnation, enormous investments must be realized in a very short time. Today`s decisions in the development strategy will influence the long term future of the industry. The optimal structure of the sources is one of the most important problem to be solved. Paper describes the current structure of the sources in electric power sector in the Czech Republic. The importance of coal, oil and gas, nuclear and hydro in electric power generation is compared. Taking into account the different position in the load coverage, economy of individual sources is evaluated and basic results of discounted cash flow calculations are presented. Information on specific investment programs and projects are included and further trends are estimated.

  9. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G.; Sandstrom, William A.; Tarman, Paul B.

    1982-01-01

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  10. A novel configuration for coproducing transportation fuels and power from coal and natural gas

    SciTech Connect (OSTI)

    Gray, D.; Tomlinson, G.

    1998-07-01

    The US Department of Energy and Mitretek Systems have evolved and evaluated a concept that combines the use of gas and coal for the highly efficient production of electric power and high quality transportation fuels. In its simplest form, this coproduction cofeed (CoCo) concept consists of diverting coal-derived synthesis gas from the combined cycle power block of an Integrated Coal Gasification Combined Cycle (IGCC) unit to a slurry-phase Fischer-Tropsch (F-T) synthesis reactor. The unreacted synthesis gas from the F-T reactor, and imported natural gas are then combusted in the downstream combined cycle power generation unit. Combining processes in this manner accomplishes the equivalent of natural gas to liquid synthesis while eliminating the conversion losses associated with the production of synthesis gas from natural gas. The paper discusses the benefits of coproduction.

  11. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

    Office of Energy Efficiency and Renewable Energy (EERE)

    From 2002 to 2012, most states have reduced their reliance on coal for electricity generation. The figure below shows the percent change in electricity generated by coal and natural gas for each...

  12. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  13. Should we transport coal, gas, or electricity: cost, efficiency, and environmental implications

    SciTech Connect (OSTI)

    Joule A. Bergerson; Lester B. Lave

    2005-08-15

    The authors examine the life cycle costs, environmental discharges, and deaths of moving coal via rail, coal to synthetic natural gas via pipeline, and electricity via wire from the Powder River Basin (PRB) in Wyoming to Texas. Which method has least social cost depends on how much additional investment in rail line, transmission, or pipeline infrastructure is required, as well as how much and how far energy is transported. If the existing rail lines have unused capacity, coal by rail is the cheapest method (up to 200 miles of additional track could be added). If no infrastructure exists, greater distances and larger amounts of energy favor coal by rail and gasified coal by pipeline over electricity transmission. For 1,000 miles and 9 gigawatts of power, a gas pipeline is cheapest, has less environmental discharges, uses less land, and is least obtrusive. 28 refs., 4 figs., 3 tabs.

  14. Reducing GHG emissions by co-utilization of coal with natural gas or biomass

    SciTech Connect (OSTI)

    Smith, I.M.

    2004-07-01

    Energy reserves price and security of supply issues are discussed in the context of the prospects for coal and policies to reduce greenhouse gas (GHG) emissions. Coal is projected to remain a major source of energy, with most of the demand growth in developing countries. Currently available power-generating technologies, deploying coal with natural gas or biomass, are examined. Examples of successful, partial substitution of coal by other fuels in power stations are highlighted, including the GHG emissions reductions achieved as well as the costs where available. Among various options, hybrid gasification and parallel cofiring of coal with biomass and natural gas appear to have the greatest potential to reduce GHG emissions. Much may also be achieved by cofiring, reburning, and repowering with gas turbines. The best method differs between different power systems. Co-utilization of biomass with coal is a least-cost option to reduce GHG emissions where the fuel prices are comparable, usually due to subsidies or taxes. The role of biomass is likely to increase due to greater use of subsidies, carbon taxes, and emissions trading within the context of the Kyoto Protocol. This should provide opportunities for clean coal technology transfer and diffusion, including biomass co-utilization. 32 refs., 1 fig., 3 tabs.

  15. Combustion characteristics of pulverized coal and air/gas premixed flame in a double swirl combustor

    SciTech Connect (OSTI)

    Kamal, M.M.

    2009-07-01

    An experimental work was performed to investigate the co-firing of pulverized coal and premixed gas/air streams in a double swirl combustor. The results showed that the NOx emissions are affected by the relative rates of thermal NOx formation and destruction via the pyrolysis of the fuel-N species in high temperature fuel-rich zones. Various burner designs were tested in order to vary the temperature history and the residence time across both coal and gas flames inside the furnace. It was found that by injecting the coal with a gas/air mixture as a combined central jet surrounded by a swirled air stream, a double flame envelope develops with high temperature fuel-rich conditions in between the two reaction zones such that the pyrolysis reactions to N{sub 2} are accelerated. A further reduction in the minimum NOx emissions, as well as in the minimum CO concentrations, was reported for the case where the coal particles are fed with the gas/air mixture in the region between the two swirled air streams. On the other hand, allocating the gas/air mixture around the swirled air-coal combustion zone provides an earlier contact with air and retards the NOx reduction mechanism in such a way that the elevated temperatures around the coal particles allow higher overall NOx emissions. The downstream impingement of opposing air jets was found more efficient than the impinging of particle non-laden premixed flames for effective NOx reduction. In both cases, there is an upstream flow from the stagnation region to the coal primary combustion region, but with the case of air impingement, the hot fuel-rich zone develops earlier. The optimum configuration was found by impinging all jets of air and coal-gas/air mixtures that pronounced minimum NOx and CO concentrations of 310 and 480ppm, respectively.

  16. Development of biological coal gasification (MicGAS) process

    SciTech Connect (OSTI)

    Walia, D.S.; Srivastava, K.C.; Barik, S.

    1992-01-01

    Biomethanation of coal is a phenomenon carried out in concert by a mixed population (consortium) of at least three different groups of anaerobic bacteria and can be considered analogous to that of anaerobic digestion of municipal waste. The exception, however, is that unlike municipal waste; coal is a much complex and difficult substrate to degrade. This project was focused on studying the types of microorganisms involved in coal degradation, rates of methane production, developing a cost-effective synthetic culture medium for these microbial consortia and determining the rate of methane production in bench scale bioreactors.

  17. Development of biological coal gasification (MicGAS) process

    SciTech Connect (OSTI)

    Walia, D.S.; Srivastava, K.C.; Barik, S.

    1992-11-01

    Biomethanation of coal is a phenomenon carried out in concert by a mixed population (consortium) of at least three different groups of anaerobic bacteria and can be considered analogous to that of anaerobic digestion of municipal waste. The exception, however, is that unlike municipal waste; coal is a much complex and difficult substrate to degrade. This project was focused on studying the types of microorganisms involved in coal degradation, rates of methane production, developing a cost-effective synthetic culture medium for these microbial consortia and determining the rate of methane production in bench scale bioreactors.

  18. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  19. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown – Dataset

    Office of Energy Efficiency and Renewable Energy (EERE)

    Excel file with dataset for Fact #844: Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

  20. Environmental trends in Asia are accelerating the introduction of clean coal technologies and natural gas

    SciTech Connect (OSTI)

    Johnson, C.J.

    1997-09-01

    This paper examines the changing energy mix for Asia to 2020, and impacts of increased coal consumption on Asia`s share of world SO{sub 2} and CO{sub 2} emissions. Stricter SO{sub 2} emissions laws are summarized for eight Asian economies along with implications for fuel and technology choices. The paper compares the economics of different technologies for coal and natural gas in 1997 and in 2007. Trends toward introducing clean coal technologies and the use of natural gas will accelerate in response to tighter environmental standards by 2000. The most important coal conversion technology for Asia, particularly China, in the long term is likely to be integrated gasification combined-cycle (IGCC), but only under the assumption of multiple products.

  1. Economic comparison of clean coal generating technologies with natural gas-combined cycle systems

    SciTech Connect (OSTI)

    Sebesta, J.J.; Hoskins, W.W. )

    1990-01-01

    This paper reports that there are four combustion technologies upon which U.S. electric utilities are expected to rely for the majority of their future power generating needs. These technologies are pulverized coal- fired combustion (PC); coal-fired fluidized bed combustion (AFBC); coal gasification, combined cycle systems (CGCC); and natural gas-fired combined cycle systems (NGCC). The engineering and economic parameters which affect the choice of a technology include capital costs, operating and maintenance costs, fuel costs, construction schedule, process risk, environmental and site impacts, fuel efficiency and flexibility, plant availability, capacity factors, timing of startup, and the importance of utility economic and financial factors.

  2. A new laboratory technique to estimate gas diffusion characteristics of coal

    SciTech Connect (OSTI)

    Harpalani, S.; Ouyang, S.

    1999-07-01

    This paper describes a new experimental technique developed to measure the diffusion coefficient (D) for a coal-methane system using the transient flow mechanism, and examine its dependency on factors that change with continued flow-pressure and gas concentration. Although developed primarily for coalbed methane reservoirs and coal in the gob regions, it also has application in situations where a second gas is injected in coal since it utilizes the principle of counter-diffusion. The results show that there is a continuous decrease in the value of D with decreasing mean concentration of methane in coal. The logarithm of D varies directly with the pressure. Two effects may be responsible for this decrease. The first is a possible change in the flow mechanism with decreasing methane concentration due to the existence of varying pore sizes in coal. The other is the volumetric strain of solid coal matrix induced by desorption of gas, the so called shrinkage effect. This matrix shrinkage may be resulting in reduced pore sizes, and consequently, a decrease in the value of D.

  3. Coal

    Broader source: Energy.gov [DOE]

    Coal is the largest domestically produced source of energy in America and is used to generate a significant amount of our nation’s electricity.

  4. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect (OSTI)

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  5. New mineral occurrences and mineralization processes: Wuda coal-fire gas vents of Inner Mongolia

    SciTech Connect (OSTI)

    Stracher, G.B.; Prakash, A.; Schroeder, P.; McCormack, J.; Zhang, X.M.; Van Dijk, P.; Blake, D.

    2005-12-01

    Five unique mineral assemblages that include the sulfates millosevichite, alunogen, anhydrite, tschermigite, coquimbite, voltaite, and godovikovite, as well as the halide salammoniac and an unidentified phase, according to X-ray diffraction and EDS data, were found as encrustations on quartzofeldspathic sand and sandstone adjacent to coal-fire gas vents associated with underground coal fires in the Wuda coalfield of Inner Mongolia. The mineral assemblage of alunogen, coquimbite, voltaite, and the unidentified phase collected front the same gas vent, is documented for the first time. Observations suggest that the sulfates millosevichite, alunogen, coquimbite, voltaite, godovikovite, and the unidentified phase, crystallized in response to a complex sequence of processes that include condensation, hydrothermal alteration, crystallization from solution, fluctuating vent temperatures, boiling, and dehydration reactions, whereas the halide salammoniac crystallized during the sublimation of coal-fire gas. Tschermigite and anhydrite formed by the reaction of coal-fire gas with quartzofelds pathic rock or by hydrothermal alteration of this rock and crystallization from an acid-rich aqueous solution. These minerals have potentially important environmental significance and may be vectors for the transmission of toxins. Coal fires also provide insight for the recognition in the geologic record of preserved mineral assemblages that are diagnostic of ancient fires.

  6. Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    Alptekin, G.O.; Copeland, R.; Dubovik, M.; Gershanovich, Y.

    2002-09-20

    Gasification technologies convert coal and other heavy feedstocks into synthesis gas feed streams that can be used in the production of a wide variety of chemicals, ranging from hydrogen through methanol, ammonia, acetic anhydride, dimethyl ether (DME), methyl tertiary butyl ether (MTBE), high molecular weight liquid hydrocarbons and waxes. Syngas can also be burned directly as a fuel in advanced power cycles to generate electricity with very high efficiency. However, the coal-derived synthesis gas contains a myriad of trace contaminants that may poison the catalysts that are used in the downstream manufacturing processes and may also be regulated in power plant emissions. Particularly, the catalysts used in the conversion of synthesis gas to methanol and other liquid fuels (Fischer-Tropsch liquids) have been found to be very sensitive to the low levels of poisons, especially arsenic, that are present in the synthesis gas from coal. TDA Research, Inc. (TDA) is developing an expendable high capacity, low-cost chemical absorbent to remove arsenic from coal-derived syngas. Unlike most of the commercially available sorbents that physically adsorb arsenic, TDA's sorbent operates at elevated temperatures and removes the arsenic through chemical reaction. The arsenic content in the coal gas stream is reduced to ppb levels with the sorbent by capturing and stabilizing the arsenic gas (As4) and arsenic hydrides (referred to as arsine, AsH3) in the solid state. To demonstrate the concept of high temperature arsenic removal from coal-derived syngas, we carried out bench-scale experiments to test the absorption capacity of a variety of sorbent formulations under representative conditions. Using on-line analysis techniques, we monitored the pre- and post-breakthrough arsine concentrations over different sorbent samples. Some of these samples exhibited pre-breakthrough arsine absorption capacity over 40% wt. (capacity is defined as lb of arsenic absorbed/lb of sorbent), while

  7. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    SciTech Connect (OSTI)

    Milbrandt, A.; Mann, M.

    2009-02-01

    This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

  8. Study on systems based on coal and natural gas for producing dimethyl ether

    SciTech Connect (OSTI)

    Zhou, L.; Hu, S.Y.; Chen, D.J.; Li, Y.R.; Zhu, B.; Jin, Y.

    2009-04-15

    China is a coal-dependent country and will remain so for a long time. Dimethyl ether (DME), a potential substitute for liquid fuel, is a kind of clean diesel motor fuel. The production of DME from coal is meaningful and is studied in this article. Considering the C/H ratios of coal and natural gas (NG), the cofeed (coal and NG) system (CFS), which does not contain the water gas shift process, is studied. It can reduce CO{sub 2} emission and increase the conversion rate of carbon, producing more DME. The CFS is simulated and compared with the coal-based and NG-based systems with different recycling ratios. The part of the exhaust gas that is not recycled is burned, producing electricity. On the basis of the simulation results, the thermal efficiency, economic index, and CO{sub 2} emission ratio are calculated separately. The CFS with a 100% recycling ratio has the best comprehensive evaluation index, while the energy, economy, and environment were considered at the same time.

  9. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  10. Advanced coal-fueled industrial cogeneration gas turbine system

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  11. Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in COAL IGCC Powerplants

    SciTech Connect (OSTI)

    Kenneth A. Yackly

    2004-09-30

    The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, has been re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for Coal IGCC powerplants. The new program has been re-titled as ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants'' to better match the new scope. This technical progress report summarizes the work accomplished in the reporting period April 1, 2004 to August 31, 2004 on the revised Re-Directed and De-Scoped program activity. The program Tasks are: Task 1--IGCC Environmental Impact on high Temperature Materials: This first materials task has been refocused to address Coal IGCC environmental impacts on high temperature materials use in gas turbines and remains in the program. This task will screen material performance and quantify the effects of high temperature erosion and corrosion of hot gas path materials in Coal IGCC applications. The materials of interest will include those in current service as well as advanced, high-performance alloys and coatings. Task 2--Material In-Service Health Monitoring: This second task develops and demonstrates new sensor technologies to determine the in-service health of advanced technology Coal IGCC powerplants, and remains in the program with a reduced scope. Its focus is now on only two critical sensor need areas for advanced Coal IGCC gas turbines: (1) Fuel Quality Sensor for detection of fuel impurities that could lead to rapid component degradation, and a Fuel Heating Value Sensor to rapidly determine the fuel heating value for more precise control of the gas turbine, and (2) Infra-Red Pyrometer to continuously measure the temperature of gas turbine buckets, nozzles, and combustor hardware.

  12. Gas turbines for coal-fired turbocharged PFBC boiler power plants

    SciTech Connect (OSTI)

    Wenglarz, R.; Drenker, S.

    1984-11-01

    A coal-fired turbocharged boiler using fluidized bed combustion at high pressure would be more compact than a pulverized coal fired boiler. The smaller boiler size could permit the utility industry to adopt efficient modular construction methods now widely used in other industries. A commercial turbocharger of the capacity needed to run a 250 MW /SUB e/ power plant does not exist; commercial gas turbines of the correct capacity exist, but they are not matched to this cycle's gas temperature of less than 538/sup 0/C (1000/sup 0/F). In order to avoid impeding the development of the technology, it will probably be desirable to use existing machines to the maximum extent possible. This paper explores the advantages and disadvantages of applying either standard gas turbines or modified standard gas turbines to the turbocharged boiler.

  13. Gas-chromatographic determination of the main components of hard-coal tar and its fractions

    SciTech Connect (OSTI)

    Nabivach, V.M.

    1983-01-01

    An investigation was carried out into the composition of bituminous coal tars from several coking plants in the Ukraine using gas-liquid chromatography. It was shown that analytical data can be used for operational quality control of the fractions produced.

  14. Characterization and control of exhaust gas from diesel engine firing coal-water mixture

    SciTech Connect (OSTI)

    Samuel, E.A.; Gal, E.; Mengel, M.; Arnold, M.

    1990-03-01

    Exhaust from the GE-TS single cylinder diesel engine, fitted with hardened metal, and diamond-tipped metal fuel injection nozzles, and firing coal-water mixture (CWM) has been characterized with respect to gas composition, particulate size distribution, and particulate filtration characteristics. The measured flue gas compositions are roughly in keeping with results from combustion calculations. The time variations of the hydrocarbon, CO, and NO[sub x] concentrations are also understood in terms of known reaction mechanisms.

  15. Characterization and control of exhaust gas from diesel engine firing coal-water mixture

    SciTech Connect (OSTI)

    Samuel, E.A.; Gal, E.; Mengel, M.; Arnold, M.

    1990-03-01

    Exhaust from the GE-TS single cylinder diesel engine, fitted with hardened metal, and diamond-tipped metal fuel injection nozzles, and firing coal-water mixture (CWM) has been characterized with respect to gas composition, particulate size distribution, and particulate filtration characteristics. The measured flue gas compositions are roughly in keeping with results from combustion calculations. The time variations of the hydrocarbon, CO, and NO{sub x} concentrations are also understood in terms of known reaction mechanisms.

  16. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  17. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct

  18. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  19. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  20. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  1. Adsorptive removal of catalyst poisons from coal gas for methanol synthesis

    SciTech Connect (OSTI)

    Bhatt, B.L.; Golden, T.C.; Hsiung, T.H. (Air Products and Chemicals, Inc., Allentown, PA (United States))

    1991-12-01

    As an integral part of the liquid-phase methanol (LPMEOH) process development program, the present study evaluated adsorptive schemes to remove traces of catalyst poisons such as iron carbonyl, carbonyl sulfide, and hydrogen sulfide from coal gas on a pilot scale. Tests were conducted with coal gas from the Cool Water gasification plant at Daggett, California. Iron carbonyl, carbonyl sulfide, and hydrogen sulfide were effectively removed from the coal gas. The adsorption capacities of Linde H-Y zeolite and Calgon BPL carbon for Fe(CO){sub 5} compared well with previous bench-scale results at similar CO{sub 2} partial pressure. Adsorption of COS by Calgon FCA carbon appeared to be chemical and nonregenerable by thermal treatment in nitrogen. A Cu/Zn catalyst removed H{sub 2}S very effectively. With the adsorption system on-line, a methanol catalyst showed stable activity during 120 h operation, demonstrating the feasibility of adsorptive removal of trace catalyst poisons from the synthesis gas. Mass transfer coefficients were estimated for Fe(CO){sub 5} and COS removal which can be directly used for design and scale up.

  2. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  3. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  4. High temperature alkali corrosion of ceramics in coal gas: Final report

    SciTech Connect (OSTI)

    Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

    1994-12-31

    There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.

  5. Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques

    SciTech Connect (OSTI)

    Mastalerz, Maria; He, Lilin; Melnichenko, Yuri B; Rupp, John A

    2012-01-01

    Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

  6. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  7. Core-in-shell sorbent for hot coal gas desulfurization

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Akiti, Jr., Tetteh T.

    2004-02-10

    A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical characteristics to withstand the conditions of use.

  8. Coal pump

    DOE Patents [OSTI]

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  9. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an

  10. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The

  11. Office of Oil, Gas, and Coal Supply Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    3 U.S. Department of Energy Washington, DC 20585 2013 U.S. Energy Information Administration | Natural Gas Monthly ii This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States Government. The views in this report therefore should not be construed as representing those of the

  12. Office of Oil, Gas, and Coal Supply Statistics

    U.S. Energy Information Administration (EIA) Indexed Site

    4 U.S. Department of Energy Washington, DC 20585 2014 U.S. Energy Information Administration | Natural Gas Monthly ii This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States Government. The views in this report therefore should not be construed as representing those of the

  13. PRELIMINARY CHARACTERIZATION OF CO2 SEPARATION AND STORAGE PROPERTIES OF COAL GAS RESERVOIRS

    SciTech Connect (OSTI)

    John Kemeny; Satya Harpalani

    2004-03-01

    An attractive alternative of sequestering CO{sub 2} is to inject it into coalbed methane reservoirs, particularly since it has been shown to enhance the production of methane during near depletion stages. The basis for enhanced coalbed methane recovery and simultaneous sequestration of carbon dioxide in deep coals is the preferential sorption property of coal, with its affinity for carbon dioxide being significantly higher than that for methane. Yet, the sorption behavior of coal under competitive sorptive environment is not fully understood. Hence, the original objective of this research study was to carry out a laboratory study to investigate the effect of studying the sorption behavior of coal in the presence of multiple gases, primarily methane, CO{sub 2} and nitrogen, in order to understand the mechanisms involved in displacement of methane and its movement in coal. This had to be modified slightly since the PVT property of gas mixtures is still not well understood, and any laboratory work in the area of sorption of gases requires a definite equation of state to calculate the volumes of different gases in free and adsorbed forms. This research study started with establishing gas adsorption isotherms for pure methane and CO{sub 2}. The standard gas expansion technique based on volumetric analysis was used for the experimental work with the additional feature of incorporating a gas chromatograph for analysis of gas composition. The results were analyzed first using the Langmuir theory. As expected, the Langmuir analysis indicated that CO{sub 2} is more than three times as sorptive as methane. This was followed by carrying out a partial desorption isotherm for methane, and then injecting CO{sub 2} to displace methane. The results indicated that CO{sub 2} injection at low pressure displaced all of the sorbed methane, even when the total pressure continued to be high. However, the displacement appeared to be occurring due to a combination of the preferential

  14. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis

  15. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  16. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  17. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2007-09-15

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  18. Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995

    SciTech Connect (OSTI)

    1998-12-31

    ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

  19. Gas cofiring in coal-fired stokers for emissions reduction and performance improvement

    SciTech Connect (OSTI)

    Mason, H.B.; Drennan, S.; Chan, I.; Kinney, W.L.; Borland, D.

    1996-12-31

    Adding gas burners above the grate of a coal-fired stoker can be an economical method of reducing gaseous and particulate emissions and improving efficiency and operational flexibility. With this cofiring configuration, the improved heat distribution and mixing with the stoker combustion products can give reduced opacity, reduced emissions of particulate, NO{sub x} and SO{sub 2}, improved carbon burnout and lower overall ash, reduced excess air, faster load response, cleaner and quicker lightoffs, improved turndown at both lower and upper capacity limits, and improved performance with problematic coals. To develop and validate the cofiring technology, three cofire field experiments have been conducted. A 165,000 lb/hr spreader stoker and mass feed chain grate stokers rated at 40,000 and 75,000 lb/hr have been retrofit with gas burners and tested in the field. The two larger units used dual, opposed burners, while the smaller unit was retrofit with a single burner. With the spreader stoker, the primary benefits of gas cofire was reduction in opacity episodes with coal quality variability and recovery of lost derate. With the larger chain grate unit, the primary benefit was reduction of NO{sub x} and SO{sub 2} to within Title V limits and elimination of opacity episodes during startup and load swings. With the smaller chain grate, the primary benefit was ability to operate at low loads without unacceptable opacity excursions which had previously required a backup boiler. In all cases, the economics justified the capital burner system retrofit cost and incremental fuel costs.

  20. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-10-01

    New coal gasification processes are now being developed which can generate electricity with high thermal efficiency either in an integrated gasification combined cycle (IGCC) or in a fuel cell (MCFC). Both of these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCl) in the coal-gas. This project investigates the effect of HCl, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by the HCI, both in absorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences of utilizing high-chlorine Illinois coal in these processes. The work activity during the third quarter of this project involved the performance of the second block-set of experiments in the bench-scale fluidized-bed reactor. These experiments were designed to study the effect of HCl in the desulfurization of a low-Btu fuel gas. Nine single-cycle experiments were performed, at operating temperature of 538, 650, and 750{degrees}C, with HCl concentrations of 0, 200, and 800 ppMv. The presence of HCl in the coal gas significantly enhanced the desulfurization efficacy of the sorbent. A 10-cycle sulfidation-regeneration sequence is currently being performed at 650{degrees}C with 800 ppMv HCl in the simulated fuel gas to determine any adverse effects on the sorbent structure or its desulfurization capability.

  1. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation's urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  2. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no

  3. Tunable Diode Laser Sensors to Monitor Temperature and Gas Composition in High-Temperature Coal Gasifiers

    SciTech Connect (OSTI)

    Hanson, Ronald; Whitty, Kevin

    2014-12-01

    The integrated gasification combined cycle (IGCC) when combined with carbon capture and storage can be one of the cleanest methods of extracting energy from coal. Control of coal and biomass gasification processes to accommodate the changing character of input-fuel streams is required for practical implementation of integrated gasification combined-cycle (IGCC) technologies. Therefore a fast time-response sensor is needed for real-time monitoring of the composition and ideally the heating value of the synthesis gas (here called syngas) as it exits the gasifier. The goal of this project was the design, construction, and demonstration an in situ laserabsorption sensor to monitor multiple species in the syngas output from practical-scale coal gasifiers. This project investigated the hypothesis of using laser absorption sensing in particulateladen syngas. Absorption transitions were selected with design rules to optimize signal strength while minimizing interference from other species. Successful in situ measurements in the dusty, high-pressure syngas flow were enabled by Stanford’s normalized and scanned wavelength modulation strategy. A prototype sensor for CO, CH4, CO2, and H2O was refined with experiments conducted in the laboratory at Stanford University, a pilot-scale at the University of Utah, and an engineering-scale gasifier at DoE’s National Center for Carbon Capture with the demonstration of a prototype sensor with technical readiness level 6 in the 2014 measurement campaign.

  4. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect (OSTI)

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  5. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  6. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-09-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to

  7. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-06-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were

  8. A Perspective of petroleum, natural gas, and coal bed methane on the energy security of India

    SciTech Connect (OSTI)

    Ghose, M.K.; Paul, B.

    2008-07-01

    The global energy requirement has grown at a phenomenal rate and the consumption of primary energy sources has been a very high positive growth. This article focuses on the consumption of different primary energy sources and it identifies that coal will continue to remain as the prime energy in the foreseeable future. It examines energy requirement perspectives for India and demands of petroleum, natural gas, and coal bed methane in the foreseeable future. It discusses the state of present day petroleum and petrochemical industries in the country and the latest advances in them to take over in the next few years. The regional pattern of consumption of primary energy sources shows that oil remains as the largest single source of primary energy in most parts of the world. However, gas dominates as the prime source in some parts of the world. Economic development and poverty alleviation depend on securing affordable energy sources and for the country's energy security; it is necessary to adopt the latest technological advances in petroleum and petrochemical industries by supportive government policies. But such energy is very much concerned with environmental degradation and must be driven by contemporary managerial acumen addressing environmental and social challenges effectively. Environmental laws for the abatement of environmental degradation are discussed in this paper. The paper concludes that energy security leading to energy independence is certainly possible and can be achieved through a planned manner.

  9. Enhancing the use of coals by gas reburning-sorbent injection

    SciTech Connect (OSTI)

    Not Available

    1988-12-22

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on three coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices; tangential, wall, and cyclone fired. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace, at the superheater exit or into the ducting following the air heater. The sorbents trap SO{sub x} as solid sulfates and sulfites, which are collected in the particulate control device.

  10. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  11. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2003-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objective of this research is to support the near- and long-term DOE efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 60-{micro}m C-500-04 alumina catalyst particles and a PFA differential fixed-bed micro reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into elemental sulfur were carried out for the space time range of 0.01-0.047 seconds at 125-155 C to evaluate effects of reaction temperatures, moisture concentrations, reaction pressures on conversion of hydrogen sulfide into elemental sulfur. Simulated coal gas mixtures consist of 61-89 v% hydrogen, 2,300-9,200-ppmv hydrogen sulfide, 1,600-4,900 ppmv sulfur dioxide, and 2.6-13.7 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 100-110 cm{sup 3}/min at room temperature and atmospheric pressure (SCCM). The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 28-127 psia. The following results were obtained based on experimental data generated from the differential reactor system, and their interpretations, (1) Concentration of moisture and concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction

  12. Conversion of Coal Mine Gas to LNG (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    obtaining rights to coal mine methane with a number of coal companies, explored marketing potential with a wide variety of customers in many sections of the United States, ...

  13. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping )

    1996-01-01

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH[sub 4] content ofthe gases there is 83 -90%, with [delta][sup 13]C[sub 1] -35.5 [approximately] -39.9[per thousand], and [delta][sup 13]C[sub 2] -24.0 [approximately] -26.8[per thousand]. The [delta][sup 13]C of condensate oils associated with the gases ranges from -25.4[per thousand] to -26.8[per thousand]. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The [delta][sup 13]C[sub 1] of the gases there is -37.9 [approximately] -37. l[per thousand], with the [delta][sup 13]C of condensate oil accompanying them - 25.1 [approximately] -26.6[per thousand]. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH[sub 4] content of the gases there varies from 60 to 90%, with [delta][sup 13]C[sub 1] from - 38.7 to -43.7[per thousand] and [delta] [sup 13]C[sub 2] from -25.9[per thousand] to -29.9[per thousand]. The [delta] [sup 13]C of light oils and condensate oils accompanying the gases changes from 24.3[per thousand] to 27.8[per thousand].

  14. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping

    1996-12-31

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH{sub 4} content ofthe gases there is 83 -90%, with {delta}{sup 13}C{sub 1} -35.5 {approximately} -39.9{per_thousand}, and {delta}{sup 13}C{sub 2} -24.0 {approximately} -26.8{per_thousand}. The {delta}{sup 13}C of condensate oils associated with the gases ranges from -25.4{per_thousand} to -26.8{per_thousand}. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The {delta}{sup 13}C{sub 1} of the gases there is -37.9 {approximately} -37. l{per_thousand}, with the {delta}{sup 13}C of condensate oil accompanying them - 25.1 {approximately} -26.6{per_thousand}. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH{sub 4} content of the gases there varies from 60 to 90%, with {delta}{sup 13}C{sub 1} from - 38.7 to -43.7{per_thousand} and {delta} {sup 13}C{sub 2} from -25.9{per_thousand} to -29.9{per_thousand}. The {delta} {sup 13}C of light oils and condensate oils accompanying the gases changes from 24.3{per_thousand} to 27.8{per_thousand}.

  15. The Coal-Seq III Consortium. Advancing the Science of CO2 Sequestration in Coal Seam and Gas Shale Reservoirs

    SciTech Connect (OSTI)

    Koperna, George

    2014-03-14

    The Coal-Seq consortium is a government-industry collaborative that was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO2 sequestration in deep, unmineable coal seams. The consortium’s objective aimed to advancing industry’s understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. Research from this collaborative effort was utilized to produce modules to enhance reservoir simulation and modeling capabilities to assess the technical and economic potential for CO2 storage and enhanced coalbed methane recovery in coal basins. Coal-Seq Phase 3 expands upon the learnings garnered from Phase 1 & 2, which has led to further investigation into refined model development related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins the extension of the work to gas shale reservoirs, and continued global technology exchange. The first research objective assesses changes in coal and shale properties with exposure to CO2 under field replicated conditions. Results indicate that no significant weakening occurs when coal and shale were exposed to CO2, therefore, there was no need to account for mechanical weakening of coal due to the injection of CO2 for modeling. The second major research objective evaluates cleat, Cp, and matrix, Cm, swelling/shrinkage compressibility under field replicated conditions. The experimental studies found that both Cp and Cm vary due to changes in reservoir pressure during injection and depletion under field replicated conditions. Using laboratory data from this study, a compressibility model was developed to predict the pore-volume compressibility, Cp, and the matrix compressibility, Cm, of coal and shale, which was applied to

  16. KINETICS OF Mn-BASED SORBENTS FOR HOT COAL GAS DESULFURIZATION

    SciTech Connect (OSTI)

    K.A. SADECKI; M.T. HEPWORTH

    1997-06-15

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H2S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In previous reports, the sulfidation and regeneration results from cyclic testing done at 550 and 600 °C were presented. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H2S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent at 600 °C. Regeneration tests determined that loaded pellets can be essentially completely regenerated in air/steam mixture at 750 °C with minimal sulfate formation. In this report, the performance of the leading formulation (designated C6-2) was investigated for high temperature removal of H2S from simulated coal-derived fuel gas under varying sorbent induration temperature, reaction temperature, and superficial gas velocity. Sulfidation experiments were performed in an ambient pressure fixed-bed reactor between 500 °C and 600 °C. Four tests were conducted with each test consisting of four cycles of sulfidation and regeneration. Results showed that the induration temperature of the sorbent and the reaction temperature greatly affected the H2S removal capacity of the sorbent while the superficial gas velocity between 1090 and 1635 cm/min had minimal affect on the sorbent's breakthrough capacity. Sorbent also showed 30 to 53% loss of its strength over four cycles of sulfidation and regeneration. The former being sorbent indurated at 1115 °C and the prior being sorbent indurated at 1100 °C.

  17. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1999-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  18. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1997-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  19. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  20. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  1. Chemicals from coal

    SciTech Connect (OSTI)

    Harold A. Wittcoff; Bryan G. Reuben; Jeffrey S. Plotkin

    2004-12-01

    This chapter contains sections titled: Chemicals from Coke Oven Distillate; The Fischer-Tropsch Reaction; Coal Hydrogenation; Substitute Natural Gas (SNG); Synthesis Gas Technology; Calcium Carbide; Coal and the Environment; and Notes and References

  2. Corrosion and degradation of test materials in the BI-GAS coal-gasification pilot plant

    SciTech Connect (OSTI)

    Yurkewycz, R.; Firestone, R.F.

    1982-02-01

    Corrosion monitoring of test materials was conducted in the BI-GAS coal gasification pilot plant from 1976 through 1981. Montana Rosebud subbituminous coal was processed at pressures of 750 psia (5175 kPa). Metals were exposed at low to moderate temperatures (700/sup 0/F (371/sup 0/C)) in the coal preparation area, gasifier slag quench, and the product gas scrubbing system. Refractories and metals were evaluated in the gasifier high temperature (1372/sup 0/F (744/sup 0/C)-1915/sup 0/F (1046/sup 0/C)) test sites at the top of stage II. In the moderate temperature aqueous environments, alloys 26-1, Types 329, 304, 316, 405, and IN-825 were superior in performance to Monel 400, carbon steel A515, and 2-1/4Cr-1Mo. Stress corrosion cracking was not observed in welded U-bend samples (A515, 304, 316, 329, 26-1). First-exposure gasifier corrosion test results generally indicated that uncoated alloys with 23.0 to 26.2 wt % Cr and less than 30 wt % Ni exhibited the best performance. Alloy Types 446 and 310 experienced the least corrosion attack with linear corrosion rates less than 20 mpy (0.51 mm/y); marginal performing alloys were Type 314, 22-13-5, and RA-333. During the second exposure, all uncoated alloys incurred acceptable corrosion losses. Alloys with Co, Cr, and Ni (N155, 556) in approximately equal proportions, at concentrations of approx. 20 wt %, ranked higher in performance than alloys such as Type 310, IN-800, Cru-25, and RA-333. Gasifier exposure of pack-aluminized alloys IN-800(A1) and Type 310(A1)showed that the coating provided corrosion protection. Cracks in the bulk coating were filled with Fe-Al rich oxides. The refractories were changed very little by exposure with two exceptions: tar was removed from a tar-impregnated brick, and a lightweight insulating castable deteriorated greatly.

  3. Philadelphia gas works medium-Btu coal gasification project: capital and operating cost estimate, financial/legal analysis, project implementation

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    This volume of the final report is a compilation of the estimated capital and operating costs for the project. Using the definitive design as a basis, capital and operating costs were developed by obtaining quotations for equipment delivered to the site. Tables 1.1 and 1.2 provide a summary of the capital and operating costs estimated for the PGW Coal Gasification Project. In the course of its Phase I Feasibility Study of a medium-Btu coal-gas facility, Philadelphia Gas Works (PGW) identified the financing mechanism as having great impact on gas cost. Consequently, PGW formed a Financial/Legal Task Force composed of legal, financial, and project analysis specialists to study various ownership/management options. In seeking an acceptable ownership, management, and financing arrangement, certain ownership forms were initially identified and classified. Several public ownership, private ownership, and third party ownership options for the coal-gas plant are presented. The ownership and financing forms classified as base alternatives involved tax-exempt and taxable financing arrangements and are discussed in Section 3. Project implementation would be initiated by effectively planning the methodology by which commercial operation will be realized. Areas covered in this report are sale of gas to customers, arrangements for feedstock supply and by-product disposal, a schedule of major events leading to commercialization, and a plan for managing the implementation.

  4. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  5. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    1982-01-01

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  6. Clean coal technology III 10 MW demonstration of gas suspension absorption. Final public design report

    SciTech Connect (OSTI)

    1995-06-01

    This report provides the nonproprietary design information for the ``10 MW Demonstration of Gas Suspension Absorption (GSA)`` Demonstration Project at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emission Research (CER). The 10 MW Demonstration of GSA program is designed to demonstrate the performance of the GSA system in treating the flue gas from a boiler burning high sulfur coal. This project involves design, manufacturing, construction and testing of a retrofitted GSA system. This report presents a nonproprietary description of the technology and overall process performance requirements, plant location and plant facilities. The process, mechanical, structural and electrical design of the GSA system as well as project cost information are included. It also includes a description the modification or alterations made during the course of construction and start-up. Plant start-up provisions, environmental considerations and control, monitoring and safety considerations are also addressed for the process. This report, initially drafted in 1993, covers design information available prior to startup of the demonstration project. It does not reflect the results obtained in that project, which is now complete.

  7. Coal feed lock

    DOE Patents [OSTI]

    Pinkel, I. Irving

    1978-01-01

    A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

  8. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  9. Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application

    SciTech Connect (OSTI)

    Ashok K. Anand

    2005-12-16

    IGCC plant level parameters (IGCC Net Efficiency, IGCC Net Output, GT Output, NOx Emissions) of 11 GT identified cycle parameters were determined. Results indicate that IGCC net efficiency HHV gains up to 2.8 pts (40.5% to 43.3%) and IGCC net output gains up to 35% are possible due to improvements in GT technology alone with single digit NOx emission levels. Task 5.0--Recommendations for GT Technical Improvements: A trade off analysis was conducted utilizing the performance results of 18 gas turbine (GT) conceptual designs, and three most promising GT candidates are recommended. A roadmap for turbine technology development is proposed for future coal based IGCC power plants. Task 6.0--Determine Carbon Capture Impact on IGCC Plant Level Performance: A gas turbine performance model for high Hydrogen fuel gas turbine was created and integrated to an IGCC system performance model, which also included newly created models for moisturized syngas, gas shift and CO2 removal subsystems. This performance model was analyzed for two gas turbine technology based subsystems each with two Carbon removal design options of 85% and 88% respectively. The results show larger IGCC performance penalty for gas turbine designs with higher firing temperature and higher Carbon removal.

  10. Development of a dry-feed system for a coal-fired gas turbine

    SciTech Connect (OSTI)

    Rothrock, J.W. Jr.; Smith, C.F.

    1993-11-01

    The objective of the reported of the reported work is to develop a dry coal feed system that provides smooth, controllable flow of coal solids into the high pressure combustor of the engine and all test rigs. The system must start quickly and easily, run continuously with automatic transfer of coal from low pressure hoppers to the high pressure delivery system, and offer at least a 3:1 smooth turn-down ratio. cost of the equipment must be minimized to maintain the economic attractiveness of the whole system. Before the current contract started some work was done with dry powder coal. For safety and convenience reasons, coal water slurry was selected as the fuel for all work on the program. Much of the experimental work, including running the Allison 501-KM engine was done with coal slurry. Recent economic analysis led to a change to powdered coal.

  11. Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Ksepko, Ewelina; Tian, Hanging

    2013-01-01

    The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

  12. JV Task 5 - Evaluation of Residual Oil Fly Ash As A Mercury Sorbent For Coal Combustion Flue Gas

    SciTech Connect (OSTI)

    Robert Patton

    2006-12-31

    The mercury adsorption capacity of a residual oil fly ash (ROFA) sample collected form Florida Power and Light Company's Port Everglades Power Plant was evaluated using a bituminous coal combustion flue gas simulator and fixed-bed testing protocol. A size-segregated (>38 {micro}g) fraction of ROFA was ground to a fine powder and brominated to potentially enhance mercury capture. The ROFA and brominated-ROFA were ineffective in capturing or oxidizing the Hg{sup 0} present in a simulated bituminous coal combustion flue gas. In contrast, a commercially available DARCO{reg_sign} FGD initially adsorbed Hg{sup 0} for about an hour and then catalyzed Hg{sup 0} oxidation to produce Hg{sup 2+}. Apparently, the unburned carbon in ROFA needs to be more rigorously activated in order for it to effectively capture and/or oxidize Hg{sup 0}.

  13. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    C. Jean Bustard; Kenneth E. Baldrey; Richard Schlager

    2000-04-01

    The U.S. Department of Energy and ADA Environmental Solutions has begun a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the flyash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. Preliminary testing has identified a class of common deliquescent salts that effectively control flyash resistivity on a variety of coals. A method to evaluate cohesive properties of flyash in the laboratory has been selected and construction of an electrostatic tensiometer test fixture is underway. Preliminary selection of a variety of chemicals that will be screened for effect on flyash cohesion has been completed.

  14. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this

  15. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan

    SciTech Connect (OSTI)

    Tegen, S.

    2006-05-01

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  16. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.'' This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft[sup 2] cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  17. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, ``Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.`` This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft{sup 2} cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  18. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate

  19. Optical Thin Films for Gas Sensing in Advanced Coal Fired Power Plants

    SciTech Connect (OSTI)

    Ohodnicki, Paul; Brown, Thomas; Baltrus John; Chorpening, Benjamin

    2012-08-09

    Even for existing coal based plants, the opportunity for sensors and controls to improve efficiency is great. A wide range of gas species are of interest for relevant applications. Functional sensor layers for embedded sensing must be compatible with extreme conditions (temperature, pressure, corrosive). Au incorporated metal oxides have been looked at by a number of other authors previously for gas sensing, but have often focused on temperatures below 500{degree}C. Au nanoparticle incorporated metal oxide thin films have shown enhanced gas sensing response. In prior work, we have demonstrated that material systems such as Au nanoparticle incorporated TiO{sub 2} films exhibit a potentially useful optical response to changing gas atmospheres at temperatures up to ~800-850{degree}C. Current work is focused on sputter-deposited Au/TiO{sub 2} films. Au and Ti are multi-layered sputter deposited, followed by a 950{degree}C oxidation step. Increasing Au layer thickness yields larger particles. Interband electronic transitions significantly modify the optical constants of Au as compared to the damped free electron theory. A high temperature oxidation (20%O{sub 2}/N{sub 2}) treatment was performed at 700{degree}C followed by a reduction (4%H{sub 2}/N{sub 2}) treatment to illustrate the shift in both absorption and scattering with exposure to reducing gases. Shift of localized surface plasmon resonance (LSPR) absorption peak in changing gas atmospheres is well documented, but shift in the peak associated with diffuse scattering is a new observation. Increasing Au layer-thickness results in an increase in LSPR absorption and a shift to longer wavelengths. Diffuse scattering associated with the LSPR resonance of Au shows a similar trend with increasing Au thickness. To model the temperature dependence of LSPR, the modification to the plasmon frequency, the damping frequency, and the dielectric constant of the oxide matrix must be accounted for. Thermal expansion of Au causes

  20. Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2008-10-15

    Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

  1. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  2. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    SciTech Connect (OSTI)

    Alptekin, Gokhan

    2013-02-15

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H2S, NH3, HCN, AsH3, PH3, HCl, NaCl, KCl, AS3, NH4NO3, NH4OH, KNO3, HBr, HF, and HNO3) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts.

  3. SUBTASK 3.12 – GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL

    SciTech Connect (OSTI)

    Stanislowski, Joshua; Curran, Tyler; Henderson, Ann

    2014-06-30

    The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three scenarios. The first scenario used traditional techniques for cleaning the syngas prior to Fischer–Tropsch (FT) synthesis, including gas sweetening with a physical solvent. In the second scenario, the CO2 was not removed from the gas stream prior to FT synthesis. In the third scenario, only warm-gas cleanup techniques were used, such that the feed gas to the FT unit contained both moisture and CO2. The results of the testing showed that the liquid fuels production from the FT catalyst was significantly hindered by the presence of moisture and CO2 in the syngas. Further testing would be needed to determine if this thermally efficient process is feasible with other FT catalysts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Illinois Clean Coal Institute.

  4. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2002-05-01

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

  5. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect (OSTI)

    Barton, Tom

    2013-06-30

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  6. Hot coal gas desulfurization with manganese-based sorbents. Annual report, September 1992--September 1993

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1993-12-01

    The focus of work being performed on Hot Coal Gas Desulfurization at the Morgantown Energy Technology Center is primarily in the use of zinc ferrite and zinc titanate sorbents; however, prior studies at the US Steel Fundamental Research Laboratories in Monroeville, PA, by E. T. Turkdogan indicated that an alternate sorbent, manganese dioxide-containing ore in mixture with alumina (75 wt % ore + 25 wt % Al{sub 2}O{sub 3}) may be a viable alternative to zinc-based sorbents. Manganese, for example, has a lower vapor pressure in the elemental state than zinc hence it is not as likely to undergo depletion from the sorbent surface upon loading and regeneration cycles. Also manganese oxide is less readily reduced to the elemental state than iron hence the range of reduction potentials for oxygen is somewhat greater than for zinc ferrite. In addition, thermodynamic analysis of the manganese-oxygen-sulfur system shows it to be less amenable to sulfation than zinc ferrite. Potential also exists for utilization of manganese at higher temperatures than zinc ferrite or zinc titanate. This Annual Topical Report documents progress in pelletizing and testing via thermo-gravimetric analysis of individual pellet formulations of manganese ore/ alumina combinations and also manganese carbonate/alumina with two binders, dextrin and bentonite. It includes the prior Quarterly Technical Reports which indicate that the manganese carbonate material, being of higher purity than the manganese ore, has a higher degree of sulfur capacity and more rapid absorption kinetics. A 2-inch fixed-bed reactor has been fabricated and is now ready for subjecting pellets to cyclic loading and regeneration.

  7. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    6-2016 Colorado NA NA NA NA NA NA 1996-2016 Federal Offshore Gulf of Mexico NA NA NA NA NA NA 1997-2016 Kansas NA NA NA NA NA NA 1996-2016 Louisiana NA NA NA NA NA NA 1991-2016 Montana NA NA NA NA NA NA 1996-2016 New Mexico NA NA NA NA NA NA 1996-2016 North Dakota NA NA NA NA NA NA 1996-2016 Ohio NA NA NA NA NA NA 1991-2016 Oklahoma NA NA NA NA NA NA 1996-2016 Pennsylvania NA NA NA NA NA NA 1991-2016 Texas NA NA NA NA NA NA 1991-2016 Utah NA NA NA NA NA NA 1994-2016 West Virginia NA NA NA NA NA

  8. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    165,360 165,928 209,439 212,848 260,394 288,743 1936-2014 Alaska 6,481 10,173 10,966 11,769 7,219 6,554 1967-2014 Alaska Onshore 5,271 8,034 9,276 9,244 5,670 5,779 1992-2014 Alaska State Offshore 1,210 2,139 1,690 2,525 1,549 776 1992-2014 Arkansas 141 425 494 0 NA NA 1967-2014 California 2,501 2,790 2,424 0 NA NA 1967-2014 California Onshore 2,501 2,790 2,424 NA NA NA 1992-2014 California State Offshore 0 0 0 NA NA NA 2003-2014 Federal Offshore California NA NA 2003-2014 Colorado 1,411 1,242

  9. Natural Gas Vented and Flared

    U.S. Energy Information Administration (EIA) Indexed Site

    NA NA NA NA NA NA 1991-2015 Montana NA NA NA NA NA NA 1996-2015 New Mexico NA NA NA NA NA NA 1996-2015 North Dakota NA NA NA NA NA NA 1996-2015 Ohio NA NA NA NA NA NA 1991-2015 ...

  10. Particle and gas emissions from a simulated coal-burning household fire pit

    SciTech Connect (OSTI)

    Linwei Tian; Donald Lucas; Susan L. Fischer; S. C. Lee; S. Katharine Hammond; Catherine P. Koshland

    2008-04-01

    An open fire was assembled with firebricks to simulate the household fire pit used in rural China, and 15 different coals from this area were burned to measure the gaseous and particulate emissions. Particle size distribution was studied with a microorifice uniform-deposit impactor (MOUDI). Over 90% of the particulate mass was attributed to sub-micrometer particles. The carbon balance method was used to calculate the emission factors. Emission factors for four pollutants (particulate matter, CO{sub 2}, total hydrocarbons, and NOx) were 2-4 times higher for bituminous coals than for anthracites. In past inventories of carbonaceous emissions used for climate modeling, these two types of coal were not treated separately. The dramatic emission factor difference between the two types of coal warrants attention in the future development of emission inventories. 25 refs., 8 figs., 1 tab.

  11. JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas

    SciTech Connect (OSTI)

    Ye Zhuang; Christopher Martin; John Pavlish

    2009-03-31

    This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

  12. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2001-07-31

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H2 separation. These membranes consist of a thin ({approx}1 mm) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H2 separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 4}0 alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

  13. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    1996-02-01

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  14. Cost-Benefit Analysis of Flexibility Retrofits for Coal and Gas Fueled Power Plants: August 2012 - December 2013

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cost Study Manual Cost Study Manual Update 6/29/12. Memo regarding Cost Study Manual (60.85 KB) Cost Study Manual (334.89 KB) More Documents & Publications Contractor Human Resources Management QER - Comment of Energy Innovation 7 QER - Comment of Energy Innovation 6

    Cost-Benefit Analysis of Flexibility Retrofits for Coal and Gas-Fueled Power Plants August 2012 - December 2013 S. Venkataraman, G. Jordan, and M. O'Connor GE Energy Schenectady, New York N. Kumar and S. Lefton Intertek AIM

  15. Dry piston coal feeder

    DOE Patents [OSTI]

    Hathaway, Thomas J.; Bell, Jr., Harold S.

    1979-01-01

    This invention provides a solids feeder for feeding dry coal to a pressurized gasifier at elevated temperatures substantially without losing gas from the gasifier by providing a lock having a double-acting piston that feeds the coals into the gasifier, traps the gas from escaping, and expels the trapped gas back into the gasifier.

  16. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature

  17. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  18. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  19. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2003-01-01

    For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating

  20. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, p

  1. Method for fluorinating coal

    DOE Patents [OSTI]

    Huston, John L.; Scott, Robert G.; Studier, Martin H.

    1978-01-01

    Coal is fluorinated by contact with fluorine gas at low pressure. After pial fluorination, when the reaction rate has slowed, the pressure is slowly increased until fluorination is complete, forming a solid fluorinated coal of approximate composition CF.sub.1.55 H.sub.0.15. The fluorinated coal and a solid distillate resulting from vacuum pyrolysis of the fluorinated coal are useful as an internal standard for mass spectrometric unit mass assignments from about 100 to over 1500.

  2. Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992

    SciTech Connect (OSTI)

    LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

    1992-06-01

    This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

  3. Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings

    SciTech Connect (OSTI)

    Jianping Jing; Zhengqi Li; Guangkui Liu; Zhichao Chen; Chunlong Liu

    2009-07-15

    Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase, and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.

  4. Solvent-refined-coal (SRC) process. Determination of trace hydrocarbon, sulfur, and nitrogen compounds in SRC-II process development Unit P-99 gas streams. [Impure hydrogen in recycle gas and low pressure gas processing

    SciTech Connect (OSTI)

    Gray, J.A.; Galli, R.D.; McCracken, J.H.

    1982-02-01

    A knowledge of the identity and concentration of trace hydrocarbon, sulfur, and nitrogen compounds in the various gas streams of the SRC-II Coal Liquefaction Process is needed in order to design the recycle gas purification and low pressure gas processing systems in large-scale plants. This report discusses the results of an experimental study to identify and quantify trace compounds in the various high and low pressure gas streams of SRC-II Process Development Unit P-99. A capillary column trace hydrocarbon analysis has been developed which can quantify 41 hydrocarbons from methane to xylenes in SRC-II gas streams. With more work a number of other hydrocarbons could be quantified. A fixed gas analysis was also developed which can be integrated with the hydrocarbon analysis to yield a complete stream analysis. A gas chromatographic procedure using a flame photometric detector was developed for trace sulfur compounds, and six sulfur compounds were identified and quantified. A chemiluminescence method was developed for determination of NO and NO/sub 2/ down to 10 ppB in concentration. A gas chromatographic procedure using an electron capture detector was developed for HCN analysis down to 5 ppM. Drager tube analyses gave semiquantitative data on HCl and NH/sub 3/ content of the gas streams.

  5. Coal market momentum converts skeptics

    SciTech Connect (OSTI)

    Fiscor, S.

    2006-01-15

    Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

  6. Integrated coal liquefaction process

    DOE Patents [OSTI]

    Effron, Edward

    1978-01-01

    In a process for the liquefaction of coal in which coal liquids containing phenols and other oxygenated compounds are produced during the liquefaction step and later hydrogenated, oxygenated compounds are removed from at least part of the coal liquids in the naphtha and gas oil boiling range prior to the hydrogenation step and employed as a feed stream for the manufacture of a synthesis gas or for other purposes.

  7. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

    1991-01-01

    The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro's estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

  8. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  9. Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

  10. Gamma-ray burst flares: X-ray flaring. II

    SciTech Connect (OSTI)

    Swenson, C. A.; Roming, P. W. A., E-mail: cswenson@astro.psu.edu [Pennsylvania State University, 525 Davey Lab, University Park, PA 16802 (United States)

    2014-06-10

    We present a catalog of 498 flaring periods found in gamma-ray burst (GRB) light curves taken from the online Swift X-Ray Telescope GRB Catalogue. We analyzed 680 individual light curves using a flare detection method developed and used on our UV/optical GRB Flare Catalog. This method makes use of the Bayesian Information Criterion to analyze the residuals of fitted GRB light curves and statistically determines the optimal fit to the light curve residuals in an attempt to identify any additional features. These features, which we classify as flares, are identified by iteratively adding additional 'breaks' to the light curve. We find evidence of flaring in 326 of the analyzed light curves. For those light curves with flares, we find an average number of ?1.5 flares per GRB. As with the UV/optical, flaring in our sample is generally confined to the first 1000 s of the afterglow, but can be detected to beyond 10{sup 5} s. Only ?50% of the detected flares follow the 'classical' definition of ?t/t ? 0.5, with many of the largest flares exceeding this value.

  11. Kinetics of MN based sorbents for hot coal gas. Quarterly report, September--December 1996

    SciTech Connect (OSTI)

    1996-12-31

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases prior to its use in combined cycle turbines. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H{sub 2}S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In a previous report, the sulfidation results were presented. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H{sub 2}S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent. In this report, the regeneration results will be presented. Regeneration tests determined that loaded pellets can be fully regenerated in air/steam mixture at 750{degrees}C with minimal sulfate formation. 16 refs., 9 figs., 5 tabs.

  12. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  13. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    SciTech Connect (OSTI)

    Hsu, F.E.

    1995-08-01

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  14. NEMS Modeling of Coal Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquid Fuels Market Module Model inputs for coal plants 3 * Existing coal plants - plant specific ... FF - Cost to convert to natural gas-fired steam plant - Cost to implement heat ...

  15. System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines

    SciTech Connect (OSTI)

    Shahrokh Etemad; Lance Smith; Kevin Burns

    2004-12-01

    Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

  16. Underground gasification of coal

    DOE Patents [OSTI]

    Pasini, III, Joseph; Overbey, Jr., William K.; Komar, Charles A.

    1976-01-20

    There is disclosed a method for the gasification of coal in situ which comprises drilling at least one well or borehole from the earth's surface so that the well or borehole enters the coalbed or seam horizontally and intersects the coalbed in a direction normal to its major natural fracture system, initiating burning of the coal with the introduction of a combustion-supporting gas such as air to convert the coal in situ to a heating gas of relatively high calorific value and recovering the gas. In a further embodiment the recovered gas may be used to drive one or more generators for the production of electricity.

  17. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  18. Robust Low-Cost Water-Gas Shift Membrane Reactor for High-Purity Hydrogen Production form Coal-Derived Syngas

    SciTech Connect (OSTI)

    James Torkelson; Neng Ye; Zhijiang Li; Decio Coutinho; Mark Fokema

    2008-05-31

    This report details work performed in an effort to develop a low-cost, robust water gas shift membrane reactor to convert coal-derived syngas into high purity hydrogen. A sulfur- and halide-tolerant water gas shift catalyst and a sulfur-tolerant dense metallic hydrogen-permeable membrane were developed. The materials were integrated into a water gas shift membrane reactor in order to demonstrate the production of >99.97% pure hydrogen from a simulated coal-derived syngas stream containing 2000 ppm hydrogen sulfide. The objectives of the program were to (1) develop a contaminant-tolerant water gas shift catalyst that is able to achieve equilibrium carbon monoxide conversion at high space velocity and low steam to carbon monoxide ratio, (2) develop a contaminant-tolerant hydrogen-permeable membrane with a higher permeability than palladium, (3) demonstrate 1 L/h purified hydrogen production from coal-derived syngas in an integrated catalytic membrane reactor, and (4) conduct a cost analysis of the developed technology.

  19. PRECURSOR FLARES IN OJ 287

    SciTech Connect (OSTI)

    Pihajoki, P.; Berdyugin, A.; Lindfors, E.; Reinthal, R.; Sillanpaeae, A.; Takalo, L.; Valtonen, M.; Nilsson, K.; Zola, S.; Koziel-Wierzbowska, D.; Liakos, A.; Drozdz, M.; Winiarski, M.; Ogloza, W.; Provencal, J.; Santangelo, M. M. M.; Salo, H.; Chandra, S.; Ganesh, S.; Baliyan, K. S.; and others

    2013-02-10

    We have studied three most recent precursor flares in the light curve of the blazar OJ 287 while invoking the presence of a precessing binary black hole in the system to explain the nature of these flares. Precursor flare timings from the historical light curves are compared with theoretical predictions from our model that incorporate effects of an accretion disk and post-Newtonian description for the binary black hole orbit. We find that the precursor flares coincide with the secondary black hole descending toward the accretion disk of the primary black hole from the observed side, with a mean z-component of approximately z{sub c} = 4000 AU. We use this model of precursor flares to predict that precursor flare of similar nature should happen around 2020.96 before the next major outburst in 2022.

  20. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  1. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants

  2. Solar at the cost of coal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    cost of coal 1 Domestic shale gas 2 US shale gas enables solar g SunShot: towards 1 Watt SunShot: towards 1 Watt Silicon PV can reach coal parity p y *LCOE calculated ...

  3. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  4. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  5. ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components"

    U.S. Energy Information Administration (EIA) Indexed Site

    Relative Standard Errors for Table 7.1;" " Unit: Percents." ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,"Selected Wood and Other Biomass Components" ,,,,,,"Coal Components",,,"Coke",,,"Electricity Components",,,,,,,,,,,,,,"Natural Gas Components",,,"Steam Components" " "," ",,,,,,,,,,,,,"Total",,,,,,,,,,,,,,,,,,,,,,,"Wood Residues",,,," " " "," ","

  6. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  7. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  8. Supersonic coal water slurry fuel atomizer

    DOE Patents [OSTI]

    Becker, Frederick E.; Smolensky, Leo A.; Balsavich, John

    1991-01-01

    A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

  9. Methane modeling: predicting the inflow of methane gas into coal mines. Quarterly technical progress report, April 1, 1982-June 30, 1982

    SciTech Connect (OSTI)

    Boyer, C.M. II; Hoysan, P.M.; Pavone, A.M.; Richmond, O.; Schwerer, F.C.; Smelser, R.E.

    1982-01-01

    Work on Phase I of the Contract program is essentially complete and was reported in the Phase I Technical Report which has been reviewed and accepted by the Contract Technical Project Officer. Phase I work included a survey of relevant technical literature and development, demonstration and documentation of a computer model, MINE1D, for flow of methane and water in coal strata for geometries corresponding to an advancing mine face and to a mine pillar. The Phase I models are one-dimensional in the space variable but describe time-dependent (nonsteady) phenomena and include gas sorption phenomena. Some revisions have been made to input/output sections of MINE1D and the documentation has been expanded. These modifications will be reported in the next Quarterly Technical Report. Preliminary test scenarios have been formulated and reviewed with the Contract Technical Project Officer for measurement of emissions during room-and-pillar and longwall mining operations. These preliminary scenarios are described in this report. A mathematical model has been developed to describe the increased stresses on the coal seam near mine openings. The model is based on an approximate elastic/plastic treatment of the coal seam and an elastic treatment of surrounding strata. In this model, elastic compaction of the coal seam decreases porosity and permeability, whereas plastic deformation increases the porosity of the natural fracture network and thereby increases the permeability. The model takes into account the effect of changes in pore fluid pressure (in the natural fracture network of the coal seam) on the deformation of the coal seam. This model is described in this report, and will be programmed for inclusion in revised versions of MINE1D and for use in the two-dimensional computer models now under development. 8 figures.

  10. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30

    , pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  11. Microbial solubilization of coals

    SciTech Connect (OSTI)

    Campbell, J.A.; Fredrickson, J.K.; Stewart, D.L.; Thomas, B.L.; McCulloch, M.; Wilson, B.W.; Bean, R.M.

    1988-11-01

    Microbial solubilization of coal may serve as a first step in a process to convert low-rank coals or coal-derived products to other fuels or products. For solubilization of coal to be an economically viable technology, a mechanistic understanding of the process is essential. Leonardite, a highly oxidized, low-rank coal, has been solubilized by the intact microorganism, cell-free filtrate, and cell-free enzyme of /ital Coriolus versicolor/. A spectrophotometric conversion assay was developed to quantify the amount of biosolubilized coal. In addition, a bituminous coal, Illinois No. 6, was solubilized by a species of /ital Penicillium/, but only after the coal had been preoxidized in air. Model compounds containing coal-related functionalities have been incubated with the leonardite-degrading fungus, its cell-free filtrate, and purified enzyme. The amount of degradation was determined by gas chromatography and the degradation products were identified by gas chromatography/mass spectrometry. We have also separated the cell-free filtrate of /ital C. versicolor/ into a <10,000 MW and >10,000 MW fraction by ultrafiltration techniques. Most of the coal biosolubilization activity is contained in the <10,000 MW fraction while the model compound degradation occurs in the >10,000 MW fraction. The >10,000 MW fraction appears to contain an enzyme with laccase-like activity. 10 refs., 8 figs., 5 tabs.

  12. Weekly Coal Production by State

    U.S. Energy Information Administration (EIA) Indexed Site

    Greenhouse gas data, voluntary report- ing, electric power plant emissions. Highlights ... Stocks Imports, exports & distribution Coal-fired electric power plants Transportation ...

  13. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has Declined while ...

  14. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generated from Coal has Declined while Generation from Natural Gas has Grown - Dataset Fact 844: October 27, 2014 Electricity Generated from Coal has Declined while ...

  15. Computer Aided Design of Advanced Turbine Airfoil Alloys for Industrial Gas Turbines in Coal Fired Environments

    SciTech Connect (OSTI)

    G.E. Fuchs

    2007-12-31

    Recent initiatives for fuel flexibility, increased efficiency and decreased emissions in power generating industrial gas turbines (IGT's), have highlighted the need for the development of techniques to produce large single crystal or columnar grained, directionally solidified Ni-base superalloy turbine blades and vanes. In order to address the technical difficulties of producing large single crystal components, a program has been initiated to, using computational materials science, better understand how alloy composition in potential IGT alloys and solidification conditions during processing, effect castability, defect formation and environmental resistance. This program will help to identify potential routes for the development of high strength, corrosion resistant airfoil/vane alloys, which would be a benefit to all IGT's, including small IGT's and even aerospace gas turbines. During the first year, collaboration with Siemens Power Corporation (SPC), Rolls-Royce, Howmet and Solar Turbines has identified and evaluated about 50 alloy compositions that are of interest for this potential application. In addition, alloy modifications to an existing alloy (CMSX-4) were also evaluated. Collaborating with SPC and using computational software at SPC to evaluate about 50 alloy compositions identified 5 candidate alloys for experimental evaluation. The results obtained from the experimentally determined phase transformation temperatures did not compare well to the calculated values in many cases. The effects of small additions of boundary strengtheners (i.e., C, B and N) to CMSX-4 were also examined. The calculated phase transformation temperatures were somewhat closer to the experimentally determined values than for the 5 candidate alloys, discussed above. The calculated partitioning coefficients were similar for all of the CMSX-4 alloys, similar to the experimentally determined segregation behavior. In general, it appears that computational materials science has become a

  16. Enclosed ground-flare incinerator

    DOE Patents [OSTI]

    Wiseman, Thomas R.

    2000-01-01

    An improved ground flare is provided comprising a stack, two or more burner assemblies, and a servicing port so that some of the burner assemblies can be serviced while others remain in operation. The burner assemblies comprise a burner conduit and nozzles which are individually fitted to the stack's burner chamber and are each removably supported in the chamber. Each burner conduit is sealed to and sandwiched between a waste gas inlet port and a matching a closure port on the other side of the stack. The closure port can be opened for physically releasing the burner conduit and supplying sufficient axial movement room for extracting the conduit from the socket, thereby releasing the conduit for hand removal through a servicing port. Preferably, the lower end of the stack is formed of one or more axially displaced lower tubular shells which are concentrically spaced for forming annular inlets for admitting combustion air. An upper tubular exhaust stack, similarly formed, admits additional combustion air for increasing the efficiency of combustion, increasing the flow of exhausted for improved atmospheric dispersion and for cooling the upper stack.

  17. STEO November 2012 - coal supplies

    U.S. Energy Information Administration (EIA) Indexed Site

    Despite drop in domestic coal production, U.S. coal exports to reach record high in 2012. While U.S. coal production is down 7 percent this year due in part to utilities switching to low-priced natural gas to generate electricity, American coal is still finding plenty of buyers in overseas markets. U.S. coal exports are expected to hit a record 125 million tons in 2012, the U.S. Energy Information Administration says in its new monthly short-term energy outlook. Coal exports are expected to

  18. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    Smith, P.; Deo, M.; Eddings, E.; Sarofim, A.; Gueishen, K.; Hradisky, M.; Kelly, K.; Mandalaparty, P.; Zhang, H.

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  19. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  20. Effect of cavitation on the properties of coal-tar pitch as studied by gas-liquid chromatography

    SciTech Connect (OSTI)

    M.I. Baikenov; T.B. Omarbekov; S.K. Amerkhanova

    2008-02-15

    The applicability of the cavitation-wave effect to coal-tar pitch processing is considered. The results of the GLC analysis of the test material before and after rotor-pulsation cavitation treatment are given. The organic matter of coal-tar pitch was found to degrade upon cavitation; as a result of this, the yields of light and medium fractions considerably increased. 5 refs., 2 figs., 4 tabs.

  1. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin; Mongia, Hukam C.; Tramm, Peter C.

    1988-01-01

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  2. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  3. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M.

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  4. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C.

    1983-01-01

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  5. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels | Prices | States | International | Country Analysis...

  6. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Independence Avenue, SW Washington, DC 20585 . Home | Petroleum | Gasoline | Diesel | Propane | Natural Gas | Electricity | Coal | Nuclear Renewables | Alternative Fuels |...

  7. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal and Coal-Biomass to Liquids FAQs faq-header-big.jpg BASICS Q: How are gasoline and diesel fuel made from coal? A: Gasoline and diesel fuels can be produced from coal in two distinct processes: Indirect Liquefaction and Direct Liquefaction. In Indirect Liquefaction, coal is first gasified to produce synthesis gas (syngas for short), which is a mixture containing primarily hydrogen (H2) and carbon monoxide (CO) gases. The Fischer-Tropsch (FT) synthesis is a commercial process that can be used

  8. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of

  9. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-12-31

    In this project, simulated gasifier-product streams were contacted with the zinc titanate desulfurization sorbent in a bench-scale atmospheric fluidized-bed reactor at temperatures ranging from 538 to 750 {degree}C (1000 to 1382 {degree}F). The first set of experiments involved treating a medium-Btu fuel gas (simulating that of a ``Texaco`` oxygen-blown, entrained-bed gasifier) containing 1.4 percent H{sub 2}S and HCl concentrations of 0, 200, and 1500 ppmv. The second experimental set evaluated hot-gas desulfurization of a low-Btu fuel gas (simulating the product of the ``U-Gas`` air-blown gasifier), with HCl concentrations of 0, 200, and 800 ppmv. These operating conditions were typical of the gas-treatment requirements of gasifiers fueled by Illinois basin coals containing up to 0.6 percent chlorine. The results of the experiments at 538 and 650 {degree}C at all the HCl concentrations revealed no deleterious effects on the capability of the sorbent to remove H{sub 2}S from the fuel gas mixtures. In most cases, the presence of the HCl significantly enhanced the desulfurization reaction rate. Some zinc loss, however, was encountered in certain situations at 750 {degree}C when low-steam operating conditions were present. Also of interest, a portion of the incoming HCl was removed from the gas stream and was retained permanently by the sorbent. This behavior was examined in more detail in a limited set of experiments aimed at identifying ways to modify the sorbents composition so that the sorbent could act as a simultaneous desulfurization and dechlorination agent in the hot-gas cleanup process.

  10. Pretreatment of coal during transport

    DOE Patents [OSTI]

    Johnson, Glenn E.; Neilson, Harry B.; Forney, Albert J.; Haynes, William P.

    1977-04-19

    Many available coals are "caking coals" which possess the undesirable characteristic of fusing into a solid mass when heated through their plastic temperature range (about 400.degree. C.) which temperature range is involved in many common treatment processes such as gasification, hydrogenation, carbonization and the like. Unless the caking properties are first destroyed, the coal cannot be satisfactorily used in such processes. A process is disclosed herein for decaking finely divided coal during its transport to the treating zone by propelling the coal entrained in an oyxgen-containing gas through a heated transport pipe whereby the separate transport and decaking steps of the prior art are combined into a single step.