National Library of Energy BETA

Sample records for gas emission factors

  1. Effect of Environmental Factors on Sulfur Gas Emissions from Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy

    2011-08-20

    Problem drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. The U.S. Consumer Product Safety Commission's (CPSC) investigation of problem drywall incorporates three parallel tracks: (1) evaluating the relationship between the drywall and reported health symptoms; (2) evaluating the relationship between the drywall and electrical and fire safety issues in affected homes; and (3) tracing the origin and the distribution of the drywall. To assess the potential impact on human health and to support testing for electrical and fire safety, the CPSC has initiated a series of laboratory tests that provide elemental characterization of drywall, characterization of chemical emissions, and in-home air sampling. The chemical emission testing was conducted at Lawrence Berkeley National Laboratory (LBNL). The LBNL study consisted of two phases. In Phase 1 of this study, LBNL tested thirty drywall samples provided by CPSC and reported standard emission factors for volatile organic compounds (VOCs), aldehydes, reactive sulfur gases (RSGs) and volatile sulfur compounds (VSCs). The standard emission factors were determined using small (10.75 liter) dynamic test chambers housed in a constant temperature environmental chamber. The tests were all run at 25 C, 50% relative humidity (RH) and with an area-specific ventilation rate of {approx}1.5 cubic meters per square meter of emitting surface per hour [m{sup 3}/m{sup 2}/h]. The thirty samples that were tested in Phase 1 included seventeen that were manufactured in China in 2005, 2006 and 2009, and thirteen that were manufactured in North America in 2009. The measured emission factors for VOCs and aldehydes were generally low and did not differ significantly between the Chinese and North American drywall. Eight of the samples tested had elevated emissions of volatile sulfur-containing compounds with total RSG emission factors between 32 and 258 micrograms per square meter per hour [{micro}g/m{sup 2}/h]. The dominant sulfur containing compounds in the RSG emission stream were hydrogen sulfide with emission factors between 17-201 {micro}g/m{sup 2}/h, and sulfur dioxide with emission factors between 8-64 {micro}g/m{sup 2}/h. The four highest emitting samples also had a unique signature of VSC emissions including > 40 higher molecular weight sulfur-containing compounds although the emission rate for the VSCs was several orders of magnitude lower than that of the RSGs. All of the high emitting drywall samples were manufactured in China in 2005-2006. Results from Phase 1 provided baseline emission factors for drywall samples manufactured in China and in North America but the results exclude variations in environmental conditions that may exist in homes or other built structures, including various combinations of temperature, RH, ventilation rate and the influence of coatings such as texture and paints. The objective of Phase 2 was to quantify the effect of temperature and RH on the RSG emission factors for uncoated drywall, and to measure the effect of plaster and paint coatings on RSG emission factors from drywall. Additional experiments were also performed to assess the influence of ventilation rate on measured emission factors for drywall.

  2. Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors (Transportation Energy Futures Series)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DEMAND Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors TRANSPORTATION ENERGY FUTURES SERIES: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors A Study Sponsored by U.S. Department of Energy Office of Energy Efficiency and Renewable Energy March 2013 Prepared by CAMBRIDGE SYSTEMATICS Cambridge, MA 02140 under subcontract DGJ-1-11857-01 Technical monitoring performed by NATIONAL

  3. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  4. Emission factors for domestic use of L.P. gas in the metropolitan area of Mexico City

    SciTech Connect (OSTI)

    Molina, M.M.; Schifter, I.; Ontiveros, L.E.; Salinas, A.; Moreno, S.; Melgarejo, L.A.; Molina, R.; Krueger, B.

    1998-12-31

    One of the main problems found in air pollution in the Metropolitan Area of Mexico City (MAMC) is the presence of high concentrations of ozone at ground level in the atmosphere. The official Mexican standard for ozone concentration in the air (0.11 ppm, one hour, once every 3 years) has been exceeded more than 300 days per year. Ozone is formed due to the emissions of nitrogen oxides and hydrocarbons originated from either combustion processes or vapors emanating from fuel handling operations. The results of an evaluation of several domestic devices like stoves and water heaters with L.P. gas as fuel are presented. A method for the evaluation of hydrocarbon emission was developed. A prototype of domestic installation was constructed. The prototype includes L.P. gas tank, domestic stove, water heater, piping and instrumentation. Several combinations of stoves and water heaters were evaluated. The sampling and analysis of hydrocarbons were performed using laboratory equipment originally designed for the evaluation of combustion and evaporative emissions in automobiles: a SHED camera (sealed room equipped with an hydrocarbon analyzer) was used to measure leaks in the prototype of domestic installation and a Constant Volume Sampler (CVS) for the measurement of incomplete combustion emissions. Emission factors were developed for each domestic installation.

  5. State-level Greenhouse Gas Emission Factors for Electricity Generation, Updated

    Reports and Publications (EIA)

    2001-01-01

    To assist reporters in estimating emissions and emission reductions, The Energy Information Administration (EIA) has made available in the instructions to Forms EIA-1605 and EIA-1605EZ emission coefficients for most commonly used fossil fuels and electricity. These coefficients were based on 1992 emissions and generation data. In 1999, updated coefficients were prepared based on the most recent data (1998) then available; however, the updated coefficients were not included in the instructions for the 1999 data year. This year, they have been updated again, but based on three years worth of data (1997, 1998, and 1999) rather than a single year.

  6. Transportation Energy Futures Series: Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-01

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  7. Transportation Energy Futures Series. Effects of the Built Environment on Transportation. Energy Use, Greenhouse Gas Emissions, and Other Factors

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; Dunphy, R. T.; Vimmerstedt, L.

    2013-03-15

    Planning initiatives in many regions and communities aim to reduce transportation energy use, decrease emissions, and achieve related environmental benefits by changing land use. This report reviews and summarizes findings from existing literature on the relationship between the built environment and transportation energy use and greenhouse gas emissions, identifying results trends as well as potential future actions. The indirect influence of federal transportation and housing policies, as well as the direct impact of municipal regulation on land use are examined for their effect on transportation patterns and energy use. Special attention is given to the 'four D' factors of density, diversity, design and accessibility. The report concludes that policy-driven changes to the built environment could reduce transportation energy and GHG emissions from less than 1% to as much as 10% by 2050, the equivalent of 16%-18% of present-day urban light-duty-vehicle travel. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  8. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England

    2004-10-20

    In 1997, the United States Environmental Protection Agency (EPA) promulgated new National Ambient Air Quality Standards (NAAQS) for particulate matter, including for the first time particles with aerodynamic diameter smaller than 2.5 micrometers ({micro}m) referred to as PM2.5. PM2.5 in the atmosphere also contributes to reduced atmospheric visibility, which is the subject of existing rules for siting emission sources near Class 1 areas and new Regional Haze rules. There are few existing data regarding emissions and characteristics of fine aerosols from oil, gas and power generation industry combustion sources, and the information that is available is generally outdated and incomplete. Traditional stationary source air emission sampling methods tend to underestimate or overestimate the contribution of the source to ambient aerosols because they do not properly account for primary aerosol formation, which occurs after the gases leave the stack. Primary aerosol includes both filterable particles that are solid or liquid aerosols at stack temperature plus those that form as the stack gases cool through mixing and dilution processes in the plume downwind of the source. These deficiencies in the current methods can have significant impacts on regulatory decision-making. PM2.5 measurement issues were extensively reviewed by the American Petroleum Institute (API) (England et al., 1998), and it was concluded that dilution sampling techniques are more appropriate for obtaining a representative particulate matter sample from combustion systems for determining PM2.5 emission rate and chemical speciation. Dilution sampling is intended to collect aerosols including those that condense and/or react to form solid or liquid aerosols as the exhaust plume mixes and cools to near-ambient temperature immediately after the stack discharge. These techniques have been widely used in recent research studies. For example, Hildemann et al. (1994) and McDonald et al. (1998) used filtered ambient air to dilute the stack gas sample followed by 80-90 seconds residence time to allow aerosol formation and growth to stabilize prior to sample collection and analysis. More accurate and complete emissions data generated using the methods developed in this program will enable more accurate source-receptor and source apportionment analysis for PM2.5 National Ambient Air Quality Standards (NAAQS) implementation and streamline the environmental assessment of oil, gas and power production facilities. The overall goals of this program were to: (1) Develop improved dilution sampling technology and test methods for PM2.5 mass emissions and speciation measurements, and compare results obtained with dilution and traditional stationary source sampling methods. (2) Develop emission factors and speciation profiles for emissions of fine particulate matter, especially organic aerosols, for use in source-receptor and source apportionment analyses. (3) Identify and characterize PM2.5 precursor compound emissions that can be used in source-receptor and source apportionment analyses.

  9. An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

    SciTech Connect (OSTI)

    Townsend, Aaron K.; Webber, Michael E.

    2012-07-15

    This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.

  10. DEVELOPMENT OF FINE PARTICULATE EMISSION FACTORS AND SPECIATION PROFILES FOR OIL AND GAS-FIRED COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Glenn C. England; Stephanie Wien; Mingchih O. Chang

    2002-08-01

    This report provides results from the first year of this three-year project to develop dilution measurement technology for characterizing PM2.5 (particles with aerodynamic diameter smaller than 2.5 micrometers) and precursor emissions from stationary combustion sources used in oil, gas and power generation operations. Detailed emission rate and chemical speciation test results for a refinery gas-fired process heater and plans for cogeneration gas turbine tests and pilot-scale tests are presented. Tests were performed using a research dilution sampling apparatus and traditional EPA methods to compare PM2.5 mass and chemical speciation. Test plans are presented for a gas turbine facility that will be tested in the fourth quarter of 2002. A preliminary approach for pilot-scale tests is presented that will help define design constraints for a new dilution sampler design that is smaller, lighter, and less costly to use.

  11. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    ‹ Environment Emissions of Greenhouse Gases in the U. S. Release Date: March 31, 2011 | Next Release Date: Report Discontinued | Report Number: DOE/EIA-0573(2009) Greenhouse Gas Emissions Overview Diagram Notes [a] CO2 emissions related to petroleum consumption (includes 64 MMTCO2 of non-fuel-related emissions). [b] CO2 emissions related to coal consumption (includes 0.3 MMTCO2 of non-fuel-related emissions). [c] CO2 emissions related to natural gas consumption (includes 13 MMTCO2 of

  12. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    1. Greenhouse Gas Emissions Overview 1.1 Total emissions Total U.S. anthropogenic (human-caused) greenhouse gas emissions in 2009 were 5.8 percent below the 2008 total (Table 1). The decline in total emissions-from 6,983 million metric tons carbon dioxide equivalent (MMTCO2e) in 2008 to 6,576 MMTCO2e in 2009-was the largest since emissions have been tracked over the 1990-2009 time frame. It was largely the result of a 419-MMTCO2e drop in carbon dioxide (CO2) emissions (7.1 percent). There was a

  13. EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors

  14. IPCC Emission Factor Database | Open Energy Information

    Open Energy Info (EERE)

    Emission Factor Database Jump to: navigation, search Tool Summary LAUNCH TOOL Name: IPCC Emission Factor Database AgencyCompany Organization: World Meteorological Organization,...

  15. EIA - Greenhouse Gas Emissions - Methane Emissions

    Gasoline and Diesel Fuel Update (EIA)

    3. Methane Emissions 3.1. Total emissions The major sources of U.S. methane emissions are energy production, distribution, and use; agriculture; and waste management (Figure 17). U.S. methane emissions in 2009 totaled 731 MMTCO2e, 0.9 percent higher than the 2008 total of 724 MMTCO2e (Table 17). Methane emissions declined steadily from 1990 to 2001, as emissions from coal mining and landfills fell, then rose from 2002 to 2009 as a result of moderate increases in emissions related to energy,

  16. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission Factors and

    Gasoline and Diesel Fuel Update (EIA)

    Global Warming Emission Factors Voluntary Reporting of Greenhouse Gases Program Emission Factors and Global Warming Potentials The greenhouse gas emission factors and global warming potentials (GWPs) presented on this page should be used for preparing emission inventories and calculating emission reductions submitted to U.S. Energy Information Administration (EIA) on Form EIA-1605(b). Fuel and Energy Emission Factors: Instructions | HTML | Tables Electricity Emission Factors: Instructions |

  17. Emission Factors (EMFAC) | Open Energy Information

    Open Energy Info (EERE)

    The EMission FACtors (EMFAC) model is used to calculate emission rates from all motor vehicles, such as passenger cars to heavy-duty trucks, operating on highways, freeways...

  18. Alternative Fuels Data Center: Natural Gas Vehicle Emissions

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Natural Gas Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Natural Gas Vehicle Emissions on Digg Find More places to share Alternative Fuels Data

  19. Ethiopia-National Greenhouse Gas Emissions Baseline Scenarios...

    Open Energy Info (EERE)

    National Greenhouse Gas Emissions Baseline Scenarios: Learning from Experiences in Developing Countries Jump to: navigation, search Name Ethiopia-National Greenhouse Gas Emissions...

  20. EIA Energy Efficiency-Energy Related Greenhouse Gas Emissions...

    U.S. Energy Information Administration (EIA) Indexed Site

    Related Greenhouse Gas Emissions Links Energy Related Greenhouse Gas Emissions Links Posted Date: May 2007 Page Last Modified: September 2010 EIA Links Disclaimer: These pages...

  1. Displacing Natural Gas Consumption and Lowering Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion System for Refinery and Chemical Plant Process Heaters ADVANCED MANUFACTURING OFFICE Displacing Natural Gas Consumption and Lowering Emissions By enabling process heaters to utilize opportunity gaseous fuels with a fuel-flexible combustion system, this technol- ogy lowers carbon and nitrogen oxide (NO x ) emissions and reduces energy costs for industry. Introduction The refning and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion

  2. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  3. EIA - Greenhouse Gas Emissions Overview

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    grasslands 34 Net carbon dioxide sequestration in U.S. urban trees, yard trimmings, and food scraps 35 Emissions of carbon dioxide from biofuelbioenergy use by sector and fuel

  4. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Natural Gas System; Sankey Diagram Methodology Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology As natural gas travels through ...

  5. SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 | Department

    Energy Savers [EERE]

    of Energy SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 SUMMARY GREENHOUSE GAS EMISSIONS DATA WORKSHEET JANUARY 2015 File SUMMARY_GREENHOUSE_GAS_EMISSIONS_DATA_WORKSHEET_JANUARY_2015.xlsx More Documents & Publications Attachment C - Summary GHG Emissions Data FINAL Attachment C Summary GHG Emissions Data FINAL Full Service Leased Space Data Report

  6. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    1997-10-01

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  7. Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Trucks Wisconsin Reduces Emissions With Natural Gas Trucks to someone by E-mail Share Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Facebook Tweet about Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Twitter Bookmark Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Google Bookmark Alternative Fuels Data Center: Wisconsin Reduces Emissions With Natural Gas Trucks on Delicious

  8. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    Contacts This report, Emissions of Greenhouse Gases in the United States 2009, was prepared under the general direction of John Conti, Assistant Administrator for Energy Analysis, and Paul Holtberg, Team Leader, Analysis Integration Team. General questions concerning the content of this report may be directed to the Office of Communications at 202/586-8800. Technical information concerning the content of the report may be obtained from Perry Lindstrom at 202/586-0934 (email,

  9. Module: Emission Factors for Deforestation | Open Energy Information

    Open Energy Info (EERE)

    www.leafasia.orgtoolstechnical-guidance-series-emission-factors-defo Cost: Free Language: English Module: Emission Factors for Deforestation Screenshot Logo: Module: Emission...

  10. Destruction of acid gas emissions

    DOE Patents [OSTI]

    Mathur, Mahendra P. (Pittsburgh, PA); Fu, Yuan C. (Muroran, JP); Ekmann, James M. (Pittsburgh, PA); Boyle, John M. (Pittsburgh, PA)

    1991-01-01

    A method of destroying NO.sub.x and SO.sub.2 in a combustion gas in disclosed. The method includes generating active species by treating stable moleucles in a high temperature plasma. Ammonia, methane, steam, hydrogen, nitrogen or a combination of these gases can be selected as the stable molecules. The gases are subjected to plasma conditions sufficient to create free radicals, ions or excited atoms such as N, NH, NH.sub.2, OH.sup.-, CH and/or CH.sub.2. These active species are injected into a combustion gas at a location of sufficiently high temperature to maintain the species in active state and permit them to react with NO.sub.x and SO.sub.2. Typically the injection is made into the immediate post-combustion gases at temperatures of 475.degree.-950.degree. C.

  11. Greenhouse Gas Emissions and Fuel Use

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gas Emissions and Fuel Use within the Natural Gas Supply Chain - Sankey Diagram Methodology James Bradbury, Zachary Clement, and Adrian Down Office of Energy Policy and Systems Analysis U.S. Department of Energy July, 2015 2 Acknowledgements The authors are grateful for excellent technical reviews and other contributions provided by several individuals. Within the Department of Energy, input was provided by Judi Greenwald, Elke Hodson and Diana Bauer. External reviewers included the

  12. Greenhouse Gas Emissions Reduction Benefits of Workplace Charging |

    Office of Environmental Management (EM)

    Department of Energy Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Greenhouse Gas Emissions Reduction Benefits of Workplace Charging Reducing greenhouse gas emissions (GHG) from employees' commutes, also known as Scope 3 emissions, is a top priority for many organizations interested in minimizing their carbon footprint. Scope 3 emissions are indirect GHG emissions from sources not owned or directly controlled by the organization but are related to their activities,

  13. Greenhouse Gas Emission Trends and Projections in Europe 2009...

    Open Energy Info (EERE)

    Liechtenstein, Poland and Turkey provided updated information on emission projections and national programmes in 2009." References "Greenhouse Gas Emission Trends and...

  14. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation Potential in Agriculture) Jump to: navigation, search Logo: Monitoring and Assessment of Greenhouse Gas...

  15. Secretary of Energy Memorandum on DOE Greenhouse Gas Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    including strategies for: reducing greenhouse gas emissions; using water more efficiently; promoting pollution prevention and eliminating waste; constructing high performance ...

  16. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myth versus facts about biofuels and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Microsoft Word - 47C468D4-69BA-281F40.doc Biofuels & Greenhouse Gas Emissions: Myths versus Facts

  17. Biofuels & Greenhouse Gas Emissions: Myths versus Facts | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy myths versus facts of ethanol and greenhouse gas emissions. PDF icon Biofuels & Greenhouse Gas Emissions: Myths versus Facts More Documents & Publications Biofuels & Greenhouse Gas Emissions: Myths versus Facts Microsoft Word - 47C468D4-69BA-281F40.doc

  18. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  19. Application of microturbines to control emissions from associated gas

    DOE Patents [OSTI]

    Schmidt, Darren D.

    2013-04-16

    A system for controlling the emission of associated gas produced from a reservoir. In an embodiment, the system comprises a gas compressor including a gas inlet in fluid communication with an associated gas source and a gas outlet. The gas compressor adjusts the pressure of the associated gas to produce a pressure-regulated associated gas. In addition, the system comprises a gas cleaner including a gas inlet in fluid communication with the outlet of the gas compressor, a fuel gas outlet, and a waste product outlet. The gas cleaner separates at least a portion of the sulfur and the water from the associated gas to produce a fuel gas. Further, the system comprises a gas turbine including a fuel gas inlet in fluid communication with the fuel gas outlet of the gas cleaner and an air inlet. Still further, the system comprises a choke in fluid communication with the air inlet.

  20. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and

    Energy Savers [EERE]

    Climate Change in NEPA Reviews | Department of Energy Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews On December 18, 2014, CEQ released revised draft guidance for public comment that describes how Federal departments and agencies should consider the effects of greenhouse gas emissions and climate change in their National Environmental Policy

  1. Monitoring and Assessment of Greenhouse Gas Emissions and Mitigation...

    Open Energy Info (EERE)

    the MAGHG project is to support developing countries assess and report their greenhouse gas (GHG) emissions from agriculture, including assessment of mitigation options for...

  2. Verifying Greenhouse Gas Emissions: Methods to Support International...

    Open Energy Info (EERE)

    Climate Agreements Jump to: navigation, search Tool Summary Name: Verifying Greenhouse Gas Emissions: Methods to Support International Climate Agreements AgencyCompany...

  3. #AskBerkeleyLab: Jeff Greenblatt Talks Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Greenblatt, Jeff

    2015-02-02

    We received questions from our social media audience around California's goal to dramatically reduce its greenhouse gas emissions by 2030. Berkeley Lab scientist Jeff Greenblatt answers them here.

  4. Revised Draft Guidance on Consideration of Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Climate Change in NEPA Reviews Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and Climate Change in NEPA Reviews On December 18, 2014, CEQ released ...

  5. Greenhouse Gas Emissions from Aviation and Marine Transportation...

    Open Energy Info (EERE)

    and Policies Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Greenhouse Gas Emissions from Aviation and Marine Transportation: Mitigation Potentials and Policies...

  6. The Greenhouse Gas Protocol Initiative: GHG Emissions from Purchased...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (carbon dioxide, methane, nitrous oxide, and carbon dioxide equivalent) for each facility as well as total...

  7. The Greenhouse Gas Protocol Initiative: GHG Emissions from Transport...

    Open Energy Info (EERE)

    Outputs include: The tool outputs greenhouse gas emissions (including carbon dioxide, methane, nitrous oxide, carbon dioxide equivalent, and biogenic carbon dioxide) for each...

  8. PPPL Celebrates Earth Day with Reduction in Greenhouse Gas Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PPPL Celebrates Earth Day with Reduction in Greenhouse Gas Emissions By Patti Wieser April 25, 2011 Tweet Widget Google Plus One Share on Facebook PPPL's Tim Stevenson takes...

  9. EIA - Greenhouse Gas Emissions - Table-Figure Notes and Sources

    Gasoline and Diesel Fuel Update (EIA)

    A1. Notes and Sources Tables Chapter 1: Greenhouse gas emissions overview Table 1. U.S. emissions of greenhouse gases, based on global warming potential, 1990-2009: Sources: Emissions: EIA estimates. Data in this table are revised from the data contained in the previous EIA report, Emissions of Greenhouse Gases in the United States 2008, DOE/EIA-0573(2008) (Washington, DC, December 2009). Global warming potentials: Intergovernmental Panel on Climate Change, Climate Change 2007: The Physical

  10. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology

    Broader source: Energy.gov [DOE]

    As natural gas travels through infrastructure, from well-head to customer meter, small portions are routinely used as fuel, vented, flared, or inadvertently leaked to the atmosphere. This paper describes the analytical and methodological basis for three diagrams that illustrate the natural gas losses and greenhouse gas emissions that result from these processes. The paper examines these emissions in some detail, focusing in particular on the production, processing, transmission and storage, and distribution segments of natural gas infrastructure.

  11. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis...

    Office of Environmental Management (EM)

    Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumbenergyuselossemissionslg.gif How...

  12. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions

    Energy Savers [EERE]

    through Deployment of Advanced Technology | Department of Energy Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas Emissions through Deployment of Advanced Technology September 22, 2005 - 10:45am Addthis WASHINGTON, DC - The Department of Energy today released for public review and comment a plan for accelerating the development and reducing the cost of new and advanced

  13. Development of the Electricity Carbon Emission Factors for Russia...

    Open Energy Info (EERE)

    Russia Jump to: navigation, search Name Development of the Electricity Carbon Emission Factors for Russia AgencyCompany Organization European Bank for Reconstruction and...

  14. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  15. EIA - Greenhouse Gas Emissions - High-GWP gases

    Gasoline and Diesel Fuel Update (EIA)

    5. High-GWP gases 5.1. Total emissions Greenhouse gases with high global warming potential (high-GWP gases) are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride (SF6), which together represented 3 percent of U.S. greenhouse gas emissions in 2009. Emissions estimates for the high-GWP gases are provided to EIA by the EPA's Office of Air and Radiation. The estimates for emissions of HFCs not related to industrial processes or electric transmission are derived from the EPA

  16. Mitigating Greenhouse Gas Emissions: Voluntary Reporting 1996

    Reports and Publications (EIA)

    1997-01-01

    Presents information on voluntary actions to reduce greenhouse gases or remove such gases from the atmosphere in 1995. It provides an overview of participation in the Voluntary Reporting Program, a perspective on the composition of activities reported, and a review of some key issues in interpreting and evaluating achievements associated with reported emissions mitigation initiatives.

  17. FETC Programs for Reducing Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Ruether, J.A.

    1998-02-01

    Mark Twain once quipped that everyone talks about the weather but no one does anything about it. With interest in global climate change on the rise, researchers in the fossil-energy sector are feeling the heat to provide new technology to permit continued use of fossil fuels but with reduced emissions of so-called `greenhouse gases.` Three important greenhouse gases, carbon dioxide, methane, and nitrous oxide, are released to the atmosphere in the course of recovering and combusting fossil fuels. Their importance for trapping radiation, called forcing, is in the order given. In this report, we briefly review how greenhouse gases cause forcing and why this has a warming effect on the Earth`s atmosphere. Then we discuss programs underway at FETC that are aimed at reducing emissions of methane and carbon dioxide.

  18. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  19. Greenhouse gas emissions from landfill leachate treatment plants: A

    Office of Scientific and Technical Information (OSTI)

    comparison of young and aged landfill (Journal Article) | SciTech Connect Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill Citation Details In-Document Search Title: Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill Highlights: * Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup -1}. * Fresh leachate owned extremely low ORP and high organic

  20. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  1. Sensitivity of Multi-gas Climate Policy to Emission Metrics

    SciTech Connect (OSTI)

    Smith, Steven J.; Karas, Joseph F.; Edmonds, James A.; Eom, Jiyong; Mizrahi, Andrew H.

    2013-04-01

    Multi-gas greenhouse emission targets require that different emissions be combined into an aggregate total. The Global Warming Potential (GWP) index is currently used for this purpose, despite various criticisms of the underlying concept. It is not possible to uniquely define a single metric that perfectly captures the different impacts of emissions of substances with widely disparate atmospheric lifetimes, which leads to a wide range of possible index values. We examine the sensitivity of emissions and climate outcomes to the value of the index used to aggregate methane emissions using a technologically detailed integrated assessment model. We find that the sensitivity to index value is of order 4-14% in terms of methane emissions and 2% in terms of total radiative forcing, using index values between 4 and 70 for methane, with larger regional differences in some cases. The sensitivity to index value is much higher in economic terms, with total 2-gas mitigation cost decreasing 4-5% for a lower index and increasing 10-13% for a larger index, with even larger changes if the emissions reduction targets are small. The sensitivity to index value also depends on the assumed maximum amount of mitigation available in each sector. Evaluation of the maximum mitigation potential for major sources of non-CO2 greenhouse gases would greatly aid analysis

  2. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  3. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    SciTech Connect (OSTI)

    Mark Scotto

    2010-05-30

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NO{sub x} emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of high-flammable content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NO{sub x} emissions. The actual NO{sub x} reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammable content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NO{sub x} reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NO{sub x} emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NO{sub x} emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  4. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    SciTech Connect (OSTI)

    Mark V. Scotto; Mark A. Perna

    2010-05-30

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NOx emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of highflammables content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NOx emissions. The actual NOx reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammables content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NOx reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NOx emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NOx emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  5. Estonian greenhouse gas emissions inventory report

    SciTech Connect (OSTI)

    Punning, J.M.; Ilomets, M.; Karindi, A.; Mandre, M.; Reisner, V.; Martins, A.; Pesur, A.; Roostalu, H.; Tullus, H.

    1996-07-01

    It is widely accepted that the increase of greenhouse gas concentrations in the atmosphere due to human activities would result in warming of the Earth`s surface. To examine this effect and better understand how the GHG increase in the atmosphere might change the climate in the future, how ecosystems and societies in different regions of the World should adapt to these changes, what must policymakers do for the mitigation of that effect, the worldwide project within the Framework Convention on Climate Change was generated by the initiative of United Nations. Estonia is one of more than 150 countries, which signed the Framework Convention on Climate Change at the United Nations Conference on Environment and Development held in Rio de Janeiro in June 1992. In 1994 a new project, Estonian Country Study was initiated within the US Country Studies Program. The project will help to compile the GHG inventory for Estonia, find contemporary trends to investigate the impact of climate change on the Estonian ecosystems and economy and to formulate national strategies for Estonia addressing to global climate change.

  6. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  7. Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Title Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands...

  8. Emission Testing of Washington Metropolitan Area Transit Authority (WMATA) Natural Gas and Diesel Transit Buses

    SciTech Connect (OSTI)

    Melendez, M.; Taylor, J.; Wayne, W. S.; Smith, D.; Zuboy, J.

    2005-12-01

    An evaluation of emissions of natural gas and diesel buses operated by the Washington Metro Area Transit Authority.

  9. U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Manufacturing Energy Use and Greenhouse Gas Emissions Analysis U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis thumb_energyuse_loss_emissions_lg.gif How effectively is energy used in U.S. manufacturing? How much greenhouse gas (GHG) is emitted from combustion in manufacturing operations? The U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis from the Oak Ridge National Laboratory traces energy from supply (fuel, electricity, and

  10. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    D. Straub; D. Ferguson; K. Casleton; G. Richards

    2006-03-01

    U.S. natural gas composition is expected to be more variable in the future. Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Unconventional gas supplies, like coal-bed methane, are also expected to grow. As a result of these anticipated changes, the composition of fuel sources may vary significantly from existing domestic natural gas supplies. To allow the greatest use of gas supplies, end-use equipment should be able to accommodate the widest possible gas composition. For this reason, the effect of gas composition on combustion behavior is of interest. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 589K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx emissions. These results vary from data reported in the literature for some engine applications and potential reasons for these differences are discussed.

  11. PHYSICAL CONDITIONS IN THE X-RAY EMISSION-LINE GAS IN NGC1068

    SciTech Connect (OSTI)

    Kraemer, S. B. [Institute for Astrophysics and Computational Sciences, Department of Physics, The Catholic University of America, Washington, DC 20064 (United States); Sharma, N.; Turner, T. J.; George, Ian M. [Department of Physics, University of Maryland Baltimore County, Baltimore, MD 21250 (United States); Crenshaw, D. Michael, E-mail: kraemer@yancey.gsfc.nasa.gov [Department of Physics and Astronomy, Georgia State University, Astronomy Offices, One Park Place South SE, Suite 700, Atlanta, GA 30303 (United States)

    2015-01-01

    We present a detailed, photoionization modeling analysis of XMM-Newton/Reflection Grating Spectrometer observations of the Seyfert 2 galaxy NGC1068. The spectrum, previously analyzed by Kinkhabwala et al., reveals a myriad of soft X-ray emission lines, including those from H- and He-like carbon, nitrogen, oxygen, and neon, and M- and L-shell iron. As noted in the earlier analysis, based on the narrowness of the radiative recombination continua, the electron temperatures in the emission-line gas are consistent with photoionization, rather than collisional ionization. The strengths of the carbon and nitrogen emission lines, relative to those of oxygen, suggest unusual elemental abundances, which we attribute to the star formation history of the host galaxy. Overall, the emission lines are blueshifted with respect to systemic, with radial velocities ?160kms{sup 1}, similar to that of [O III] ?5007, and thus consistent with the kinematics and orientation of the optical emission-line gas and, hence, likely part of an active galactic nucleus driven outflow. We were able to achieve an acceptable fit to most of the strong emission lines with a two-component photoionization model, generated with CLOUDY. The two components have ionization parameters and column densities of logU = 0.05 and 1.22 and logN {sub H} = 20.85 and 21.2 and covering factors of 0.35 and 0.84, respectively. The total mass of the X-ray gas is roughly an order of magnitude greater than the mass of ionized gas determined from optical and near-IR spectroscopy, which indicates that it may be the dominant component of the narrow-line region. Furthermore, we suggest that the medium that produces the scattered/polarized optical emission in NGC1068 possesses similar physical characteristics to those of the more highly ionized of the X-ray model components.

  12. GHG emission factors developed for the recycling and composting of municipal waste in South African municipalities

    SciTech Connect (OSTI)

    Friedrich, Elena Trois, Cristina

    2013-11-15

    Highlights: GHG emission factors for local recycling of municipal waste are presented. GHG emission factors for two composting technologies for garden waste are included. Local GHG emission factors were compared to international ones and discussed. Uncertainties and limitations are presented and areas for new research highlighted. - Abstract: GHG (greenhouse gas) emission factors for waste management are increasingly used, but such factors are very scarce for developing countries. This paper shows how such factors have been developed for the recycling of glass, metals (Al and Fe), plastics and paper from municipal solid waste, as well as for the composting of garden refuse in South Africa. The emission factors developed for the different recyclables in the country show savings varying from ?290 kg CO{sub 2} e (glass) to ?19 111 kg CO{sub 2} e (metals Al) per tonne of recyclable. They also show that there is variability, with energy intensive materials like metals having higher GHG savings in South Africa as compared to other countries. This underlines the interrelation of the waste management system of a country/region with other systems, in particular with energy generation, which in South Africa, is heavily reliant on coal. This study also shows that composting of garden waste is a net GHG emitter, releasing 172 and 186 kg CO{sub 2} e per tonne of wet garden waste for aerated dome composting and turned windrow composting, respectively. The paper concludes that these emission factors are facilitating GHG emissions modelling for waste management in South Africa and enabling local municipalities to identify best practice in this regard.

  13. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  14. Analysis on storage off-gas emissions from woody, herbaceous, and torrefied biomass

    SciTech Connect (OSTI)

    Tumuluru, Jaya Shankar; Lim, C. Jim; Bi, Xiaotao T.; Kuang, Xingya; Melin, Staffan; Yazdanpanah, Fahimeh; Sokhansanj, Shahab

    2015-03-02

    Wood chips, torrefied wood chips, ground switchgrass, and wood pellets were tested for off-gas emissions during storage. Storage canisters with gas-collection ports were used to conduct experiments at room temperature of 20 C and in a laboratory oven set at 40 C. Commercially-produced wood pellets yielded the highest carbon monoxide (CO) emissions at both 20 and 40 C (1600 and 13,000 ppmv), whereas torrefied wood chips emitted the lowest of about <200 and <2000 ppmv. Carbon dioxide (CO?) emissions from wood pellets were 3000 ppmv and 42,000 ppmv, whereas torrefied wood chips registered at about 2000 and 25,000 ppmv, at 20 and 40 C at the end of 11 days of storage. CO emission factors (milligrams per kilogram of biomass) calculated were lowest for ground switchgrass and torrefied wood chips (2.68 and 4.86 mg/kg) whereas wood pellets had the highest CO of about 10.60 mg/kg, respectively, at 40 C after 11 days of storage. In the case of CO?, wood pellets recorded the lowest value of 55.46 mg/kg, whereas switchgrass recorded the highest value of 318.72 mg/kg. This study concludes that CO emission factor is highest for wood pellets, CO? is highest for switchgrass and CH? is negligible for all feedstocks except for wood pellets, which is about 0.374 mg/kg at the end of 11-day storage at 40 C.

  15. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  16. NREL Develops More Precise Look at Cradle-to-Grave Greenhouse Gas Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Energy Technologies - News Releases | NREL NREL Develops More Precise Look at Cradle-to-Grave Greenhouse Gas Emissions for Energy Technologies May 4, 2012 A new approach to assessing greenhouse-gas emissions from coal, wind, solar and other energy technologies paints a much more precise picture of cradle-to-grave emissions and should help sharpen decisions on what new energy projects to build. The method - a harmonization of widely variant estimates of greenhouse gas emissions by the

  17. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Across the Continental United States | Department of Energy Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Data analysis from this study will provide insight into real-world performance of current emissions reduction devices, under various operating conditions, and with respect to greenhouse gas emissions. PDF icon p-03_carder.pdf

  18. Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 8: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 Fact #608: February 1, 2010 Changes in Greenhouse Gas Emissions since 1990 In October of 2009, the United Nations (UN) released greenhouse gas inventory data for 1990 to 2007 for all countries that submitted data in accordance with the UN Framework Convention on Climate Change (UNFCCC). Between 1990 and 2007, total aggregate greenhouse gas (GHG) emissions for all reporting countries declined by 3.9%

  19. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Environmental Management (EM)

    Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12-13, 2014 Advanced Materials Manufacturing and Innovative Technologies for Natural Gas Pipeline Systems and Components Panel > November 12, 2014 > Pittsburgh, PA > By Daniel Ersoy, GTI Nat. Gas Infrastructure R&D /Methane Emissions Mitigation Workshop, Nov. 2014, Pittsburgh, PA 2 Nat. Gas Infrastructure R&D /Methane Emissions Mitigation Workshop, Nov. 2014, Pittsburgh, PA 2 GTI Company Overview

  20. Volcanic gas emissions and their effect on ambient air character

    SciTech Connect (OSTI)

    Sutton, A.J.; Elias, T.

    1994-01-01

    This bibliography was assembled to service an agreement between Department of Energy and the USGS to provide a body of references and useful annotations for understanding background gas emissions from Kilauea volcano. The current East Rift Zone (ERZ) eruption of Kilauea releases as much as 500,000 metric tonnes of SO{sub 2} annually, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl, and HF. Primary degassing locations on Kilauea are located in the summit caldera and along the middle ERZ. The effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Because of this complexity, we organized the bibliography into three main sections: (1) characterizing gases as they leave the edifice; (2) characterizing gases and chemical reaction products away from degassing sources; and (3) Hawaii Island meteorology.

  1. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  2. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Not Available

    1997-10-01

    This report serves as the technology basis of a needed national climate change technology strategy, with the confidence that a strong technology R&D program will deliver a portfolio of technologies with the potential to provide very substantial greenhouse gas emission reductions along with continued economic growth. Much more is needed to define such a strategy, including identification of complementary deployment policies and analysis to support the seeping and prioritization of R&D programs. A national strategy must be based upon governmental, industrial, and academic partnerships.

  3. Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

    SciTech Connect (OSTI)

    Yang Na; Zhang Hua; Chen Miao; Shao Liming; He Pinjing

    2012-12-15

    Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25-207 kg CO{sub 2}-eq t{sup -1} rw. Within all process stages, the emission of fossil CO{sub 2} from the combustion of MSW was the main contributor (111-254 kg CO{sub 2}-eq t{sup -1} rw), while the substitution of electricity reduced the GHG emissions by 150-247 kg CO{sub 2}-eq t{sup -1} rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.

  4. Comparative emissions from natural gas and diesel buses

    SciTech Connect (OSTI)

    Clark, N.N.; Gadapati, C.J.; Lyons, D.W.; Wang, W.; Gautam, M.; Bata, R.M.; Kelly, K.; White, C.L.

    1995-12-31

    Data has been gathered using the West Virginia University Heavy Duty Transportable Emissions Laboratories from buses operating on diesel and a variety of alternate fuels in the field. Emissions data are acquired from buses using the Central Business District cycle reported in SAE Standard J1376; this cycle has 14 ramps with 20 mph (32.2 km/h) peaks, separated by idle periods. During the three years of testing, a significant fraction of emissions data was acquired from buses with Cummins L-10 engines designed to operate on either CNG or diesel. The CNG lean burn engines were spark ignited and throttled. Early CNG engines, which were pre-certification demonstration models, have provided the bulk of the data, but data from 9 buses with more advanced technology were also available. It has been found that carbon monoxide (CO) levels from early Cummins L-10 CNG powered buses varied greatly from bus to bus, with the higher values ascribed to either faulty catalytic converters or a rich idle situation, while the later model CNG L-10 engines offered CO levels considerably lower than those typical of diesel engines. The NO{sub x} emissions were on par with those from diesel L-10 buses. Those natural gas buses with engines adjusted correctly for air-fuel ratio, returned very low emissions data. CNG bus hydrocarbon emissions are not readily compared with diesel engine levels since only the non-methane organic gases (NMOG) are of interest. Data show that NMOG levels are low for the CNG buses. Significant reduction was observed in the particulate matter emitted by the CNG powered buses compared to the diesel buses, in most cases the quantity captured was vanishingly small. Major conclusions are that engine maintenance is crucial if emissions are to remain at design levels and that the later generation CNG engines show marked improvement over the earlier models. One may project for the long term that closed loop stoichiometry control is desirable even in lean burn applications.

  5. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  6. Scaling law for direct current field emission-driven microscale gas breakdown

    SciTech Connect (OSTI)

    Venkattraman, A.; Alexeenko, A. A.

    2012-12-15

    The effects of field emission on direct current breakdown in microscale gaps filled with an ambient neutral gas are studied numerically and analytically. Fundamental numerical experiments using the particle-in-cell/Monte Carlo collisions method are used to systematically quantify microscale ionization and space-charge enhancement of field emission. The numerical experiments are then used to validate a scaling law for the modified Paschen curve that bridges field emission-driven breakdown with the macroscale Paschen law. Analytical expressions are derived for the increase in cathode electric field, total steady state current density, and the ion-enhancement coefficient including a new breakdown criterion. It also includes the effect of all key parameters such as pressure, operating gas, and field-enhancement factor providing a better predictive capability than existing microscale breakdown models. The field-enhancement factor is shown to be the most sensitive parameter with its increase leading to a significant drop in the threshold breakdown electric field and also to a gradual merging with the Paschen law. The proposed scaling law is also shown to agree well with two independent sets of experimental data for microscale breakdown in air. The ability to accurately describe not just the breakdown voltage but the entire pre-breakdown process for given operating conditions makes the proposed model a suitable candidate for the design and analysis of electrostatic microscale devices.

  7. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  8. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  9. Analysis on storage off-gas emissions from woody, herbaceous, and torrefied biomass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tumuluru, Jaya Shankar; Lim, C. Jim; Bi, Xiaotao T.; Kuang, Xingya; Melin, Staffan; Yazdanpanah, Fahimeh; Sokhansanj, Shahab

    2015-03-02

    Wood chips, torrefied wood chips, ground switchgrass, and wood pellets were tested for off-gas emissions during storage. Storage canisters with gas-collection ports were used to conduct experiments at room temperature of 20 °C and in a laboratory oven set at 40 °C. Commercially-produced wood pellets yielded the highest carbon monoxide (CO) emissions at both 20 and 40 °C (1600 and 13,000 ppmv), whereas torrefied wood chips emitted the lowest of about <200 and <2000 ppmv. Carbon dioxide (CO₂) emissions from wood pellets were 3000 ppmv and 42,000 ppmv, whereas torrefied wood chips registered at about 2000 and 25,000 ppmv, atmore » 20 and 40 °C at the end of 11 days of storage. CO emission factors (milligrams per kilogram of biomass) calculated were lowest for ground switchgrass and torrefied wood chips (2.68 and 4.86 mg/kg) whereas wood pellets had the highest CO of about 10.60 mg/kg, respectively, at 40 °C after 11 days of storage. In the case of CO₂, wood pellets recorded the lowest value of 55.46 mg/kg, whereas switchgrass recorded the highest value of 318.72 mg/kg. This study concludes that CO emission factor is highest for wood pellets, CO₂ is highest for switchgrass and CH₄ is negligible for all feedstocks except for wood pellets, which is about 0.374 mg/kg at the end of 11-day storage at 40 °C.« less

  10. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental...

  11. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels ... More Documents & Publications Well-to-Wheels Analysis of Energy Use and Greenhouse Gas ...

  12. A Path to Reduce Methane Emissions from Gas Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Path to Reduce Methane Emissions from Gas Systems A Path to Reduce Methane Emissions from Gas Systems July 29, 2014 - 3:33pm Addthis A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy

  13. Combustor for a low-emissions gas turbine engine

    DOE Patents [OSTI]

    Glezer, Boris (Del Mar, CA); Greenwood, Stuart A. (San Diego, CA); Dutta, Partha (San Diego, CA); Moon, Hee-Koo (San Diego, CA)

    2000-01-01

    Many government entities regulated emission from gas turbine engines including CO. CO production is generally reduced when CO reacts with excess oxygen at elevated temperatures to form CO2. Many manufactures use film cooling of a combustor liner adjacent to a combustion zone to increase durability of the combustion liner. Film cooling quenches reactions of CO with excess oxygen to form CO2. Cooling the combustor liner on a cold side (backside) away from the combustion zone reduces quenching. Furthermore, placing a plurality of concavities on the cold side enhances the cooling of the combustor liner. Concavities result in very little pressure reduction such that air used to cool the combustor liner may also be used in the combustion zone. An expandable combustor housing maintains a predetermined distance between the combustor housing and combustor liner.

  14. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  15. Nitrogen enriched combustion of a natural gas internal combustion engine to reduce NO.sub.x emissions

    DOE Patents [OSTI]

    Biruduganti, Munidhar S. (Naperville, IL); Gupta, Sreenath Borra (Naperville, IL); Sekar, R. Raj (Naperville, IL); McConnell, Steven S. (Shorewood, IL)

    2008-11-25

    A method and system for reducing nitrous oxide emissions from an internal combustion engine. An input gas stream of natural gas includes a nitrogen gas enrichment which reduces nitrous oxide emissions. In addition ignition timing for gas combustion is advanced to improve FCE while maintaining lower nitrous oxide emissions.

  16. Controlling Methane Emissions in the Natural Gas Sector: A Review of

    Office of Environmental Management (EM)

    Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution | Department of Energy Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Processing, Transmission, and Distribution This paper

  17. The Greenhouse Gas Protocol Initiative: Allocation of Emissions...

    Open Energy Info (EERE)

    for allocation of GHG emissions from a combined heat and power (CHP) plant is a free Excel spreadsheet calculator designed to determine the GHG emissions attributable to the...

  18. Regulated Emissions from Diesel and Compressed Natural Gas Transit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Heavy Duty Vehicle In-Use Emission Performance Comparison of Clean Diesel Buses to CNG Buses

  19. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Environmental Management (EM)

    November 12-13, 2014 DOE's Natural Gas Modernization Initiative Christopher Freitas, Program Manager, Natural Gas Midstream Infrastructure R&D, Office of Oil and Natural Gas, U.S. Dept. of Energy 3 Summary It is critical to minimize leakage Reducing natural gas leakage has multiple wins We know enough to act Natural Gas Modernization Initiative: DOE is working to drive innovation, better characterize emissions, address market barriers, and catalyze action 4 Interagency Methane Strategy

  20. Electricity price impacts of alternative Greenhouse gas emission cap-and-trade programs

    SciTech Connect (OSTI)

    Edelston, Bruce; Armstrong, Dave; Kirsch, Laurence D.; Morey, Mathew J.

    2009-07-15

    Limits on greenhouse gas emissions would raise the prices of the goods and services that require such emissions for their production, including electricity. Looking at a variety of emission limit cases and scenarios for selling or allocating allowances to load-serving entities, the authors estimate how the burden of greenhouse gas limits are likely to be distributed among electricity consumers in different states. (author)

  1. Land-use change and greenhouse gas emissions from corn and cellulosic

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ethanol | Argonne National Laboratory Land-use change and greenhouse gas emissions from corn and cellulosic ethanol July 16, 2013 Tweet EmailPrint The greenhouse gas (GHG) emissions that may accompany land-use change (LUC) from increased biofuel feedstock production are a source of debate in the discussion of drawbacks and advantages of biofuels. Estimates of LUC GHG emissions focus mainly on corn ethanol and vary widely. Increasing the understanding of LUC GHG impacts associated with both

  2. JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Priorities - News Releases | NREL JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates New Priorities Study findings published in Policy Forum of Journal Science February 18, 2014 A new study published in the journal Science says that the total impact of switching to natural gas depends heavily on leakage of methane (CH4) during the natural gas life cycle, and suggests that more can be done to reduce methane emissions and to improve measurement tools which help

  3. NREL: News - Prototype Low-Emissions Natural Gas Engine Saves Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Prototype Low-Emissions Natural Gas Engine Saves Fuel Golden, Colo., April 25, 2002 Using a unique fuel system design, researchers have developed a prototype natural gas engine that significantly improves fuel efficiency without increasing emissions. A recent report from the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) highlights the promise of the prototype medium-duty natural gas engine equipped with fuel-injected pre-chamber (FIPC) technology. Go to

  4. The quantum mechanics of ion-enhanced field emission and how it influences microscale gas breakdown

    SciTech Connect (OSTI)

    Li, Yingjie; Go, David B.

    2014-09-14

    The presence of a positive gas ion can enhance cold electron field emission by deforming the potential barrier and increasing the tunneling probability of electronsa process known as ion-enhanced field emission. In microscale gas discharges, ion-enhanced field emission produces additional emission from the cathode and effectively reduces the voltage required to breakdown a gaseous medium at the microscale (<10 ?m). In this work, we enhance classic field emission theory by determining the impact of a gaseous ion on electron tunneling and compute the effect of ion-enhanced field emission on the breakdown voltage. We reveal that the current density for ion-enhanced field emission retains the same scaling as vacuum cold field emission and that this leads to deviations from traditional breakdown theory at microscale dimensions.

  5. Greenhouse gas emissions from forest, land use and biomass burning in Tanzania

    SciTech Connect (OSTI)

    Matitu, M.R.

    1994-12-31

    Carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) gases are the main contributors to the greenhouse effect that consequently results in global warming. This paper examines the sources and sinks of these gases from/to forest, land use and biomass burning and their likely contribution to climate change using IPCC/OECD methodology. Emissions have been calculated in mass units of carbon and nitrogen Emissions and uptake have been summed for each gas and the emissions converted to full molecular weights. Mismanagement of forests and land misuse have contributed much to greenhouse gas emissions in Tanzania. For example, cultivation methods, forest clearing, burning of savannah grass and indiscriminate logging (non-sustainable logging) have contributed significantly to greenhouse gas emissions. These categories contribute more than 90% of total CO{sub 2} emissions. However, the study shows that shifting cultivation, savannah burning and forest clearing for conversion to permanent crop land and pasture are the main contributors.

  6. Co-benefits of mitigating global greenhouse gas emissions for future air

    Office of Scientific and Technical Information (OSTI)

    quality and human health (Journal Article) | SciTech Connect Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health Citation Details In-Document Search Title: Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted

  7. Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Vehicles | Department of Energy Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Well-to-Wheels Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Presented at the U.S. Department of EnergyLight Duty Vehicle Workshop in Washington, D.C. on July 26, 2010. PDF icon wtw_analysis_phevs.pdf More Documents & Publications Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles System

  8. Near-Zero Emissions Oxy-Combustion Flue Gas Purification

    SciTech Connect (OSTI)

    Minish Shah; Nich Degenstein; Monica Zanfir; Rahul Solunke; Ravi Kumar; Jennifer Bugayong; Ken Burgers

    2012-06-30

    The objectives of this project were to carry out an experimental program to enable development and design of near zero emissions (NZE) CO{sub 2} processing unit (CPU) for oxy-combustion plants burning high and low sulfur coals and to perform commercial viability assessment. The NZE CPU was proposed to produce high purity CO{sub 2} from the oxycombustion flue gas, to achieve > 95% CO{sub 2} capture rate and to achieve near zero atmospheric emissions of criteria pollutants. Two SOx/NOx removal technologies were proposed depending on the SOx levels in the flue gas. The activated carbon process was proposed for power plants burning low sulfur coal and the sulfuric acid process was proposed for power plants burning high sulfur coal. For plants burning high sulfur coal, the sulfuric acid process would convert SOx and NOx in to commercial grade sulfuric and nitric acid by-products, thus reducing operating costs associated with SOx/NOx removal. For plants burning low sulfur coal, investment in separate FGD and SCR equipment for producing high purity CO{sub 2} would not be needed. To achieve high CO{sub 2} capture rates, a hybrid process that combines cold box and VPSA (vacuum pressure swing adsorption) was proposed. In the proposed hybrid process, up to 90% of CO{sub 2} in the cold box vent stream would be recovered by CO{sub 2} VPSA and then it would be recycled and mixed with the flue gas stream upstream of the compressor. The overall recovery from the process will be > 95%. The activated carbon process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx, thus exceeding the performance targets of >99% and >95%, respectively. The process was also found to be suitable for power plants burning both low and high sulfur coals. Sulfuric acid process did not meet the performance expectations. Although it could achieve high SOx (>99%) and NOx (>90%) removal efficiencies, it could not produce by-product sulfuric and nitric acids that meet the commercial product specifications. The sulfuric acid will have to be disposed of by neutralization, thus lowering the value of the technology to same level as that of the activated carbon process. Therefore, it was decided to discontinue any further efforts on sulfuric acid process. Because of encouraging results on the activated carbon process, it was decided to add a new subtask on testing this process in a dual bed continuous unit. A 40 days long continuous operation test confirmed the excellent SOx/NOx removal efficiencies achieved in the batch operation. This test also indicated the need for further efforts on optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level. The VPSA process was tested in a pilot unit. It achieved CO{sub 2} recovery of > 95% and CO{sub 2} purity of >80% (by vol.) from simulated cold box feed streams. The overall CO{sub 2} recovery from the cold box VPSA hybrid process was projected to be >99% for plants with low air ingress (2%) and >97% for plants with high air ingress (10%). Economic analysis was performed to assess value of the NZE CPU. The advantage of NZE CPU over conventional CPU is only apparent when CO{sub 2} capture and avoided costs are compared. For greenfield plants, cost of avoided CO{sub 2} and cost of captured CO{sub 2} are generally about 11-14% lower using the NZE CPU compared to using a conventional CPU. For older plants with high air intrusion, the cost of avoided CO{sub 2} and capture CO{sub 2} are about 18-24% lower using the NZE CPU. Lower capture costs for NZE CPU are due to lower capital investment in FGD/SCR and higher CO{sub 2} capture efficiency. In summary, as a result of this project, we now have developed one technology option for NZE CPU based on the activated carbon process and coldbox-VPSA hybrid process. This technology is projected to work for both low and high sulfur coal plants. The NZE CPU technology is projected to achieve near zero stack emissions

  9. Emission Testing of Washington Metropolitan Area Transit Authority (WMATA) Natural Gas and Diesel Transit Buses

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emission Testing of Washington Metropolitan Area Transit Authority (WMATA) Natural Gas and Diesel Transit Buses M. Melendez, J. Taylor, and J. Zuboy National Renewable Energy Laboratory W.S. Wayne West Virginia University D. Smith U.S. Department of Energy Technical Report NREL/TP-540-36355 December 2005 Emission Testing of Washington Metropolitan Area Transit Authority (WMATA) Natural Gas and Diesel Transit Buses M. Melendez, J. Taylor, and J. Zuboy National Renewable Energy Laboratory W.S.

  10. Life Cycle Greenhouse Gas Emissions from Solar Photovoltaics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-11-01

    The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that helps to clarify inconsistent and conflicting life cycle GHG emission estimates in the published literature and provide more precise estimates of life cycle GHG emissions from PV systems.

  11. Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2009 … Main Text

    National Nuclear Security Administration (NNSA)

    Emissions from Metallurgical Coke Production (Thousand Metric Tons) .............................................................................................................. 4-40 Table 4-56: Production and Consumption Data for the Calculation of CO 2 Emissions from Metallurgical Coke Production (million ft 3 ) ............................................................................................................................................ 4-41 Table 4-57: CO 2 Emission Factors

  12. Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions May 2005 Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems - A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions Norman Brinkman, General Motors Corporation Michael Wang, Argonne National Laboratory Trudy Weber, General Motors Corporation Thomas Darlington, Air Improvement Resource, Inc. May

  13. Technologies to characterize natural gas emissions tested in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... responsible exploration and production of petroleum and natural gas that will ultimately provide benefit to the environment. The majority of these research projects have been ...

  14. The Greenhouse Gas Protocol Initiative: GHG Emissions from Stationary...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Stationary Combustion Guidance1 The Greenhouse Gas Protocol tool for...

  15. The Greenhouse Gas Protocol Initiative: GHG Emissions from Refrigerati...

    Open Energy Info (EERE)

    Interface: Spreadsheet Website: www.ghgprotocol.orgcalculation-toolsall-tools Cost: Free References: Refrigerant Guide1 The Greenhouse Gas Protocol tool for refrigeration is...

  16. Evaluation of Gas, Oil and Wood Pellet Fueled Residential Heating System Emissions Characteristics

    SciTech Connect (OSTI)

    McDonald, R.

    2009-12-01

    This study has measured the emissions from a wide range of heating equipment burning different fuels including several liquid fuel options, utility supplied natural gas and wood pellet resources. The major effort was placed on generating a database for the mass emission rate of fine particulates (PM 2.5) for the various fuel types studied. The fine particulates or PM 2.5 (less than 2.5 microns in size) were measured using a dilution tunnel technique following the method described in US EPA CTM-039. The PM 2.5 emission results are expressed in several units for the benefit of scientists, engineers and administrators. The measurements of gaseous emissions of O{sub 2}, CO{sub 2}, CO, NO{sub x} and SO{sub 2} were made using a combustion analyzer based on electrochemical cells These measurements are presented for each of the residential heating systems tested. This analyzer also provides a steady state efficiency based on stack gas and temperature measurements and these values are included in the report. The gaseous results are within the ranges expected from prior emission studies with the enhancement of expanding these measurements to fuels not available to earlier researchers. Based on measured excess air levels and ultimate analysis of the fuel's chemical composition the gaseous emission results are as expected and fall within the range provided for emission factors contained in the US-EPA AP 42, Emission Factors Volume I, Fifth Edition. Since there were no unexpected findings in these gaseous measurements, the bulk of the report is centered on the emissions of fine particulates, or PM 2.5. The fine particulate (PM 2.5) results for the liquid fuel fired heating systems indicate a very strong linear relationship between the fine particulate emissions and the sulfur content of the liquid fuels being studied. This is illustrated by the plot contained in the first figure on the next page which clearly illustrates the linear relationship between the measured mass of fine particulate per unit of energy, expressed as milligrams per Mega-Joule (mg/MJ) versus the different sulfur contents of four different heating fuels. These were tested in a conventional cast iron boiler equipped with a flame retention head burner. The fuels included a typical ASTM No. 2 fuel oil with sulfur below 0.5 percent (1520 average ppm S), an ASTM No. 2 fuel oil with very high sulfur content (5780 ppm S), low sulfur heating oil (322 ppm S) and an ultra low sulfur diesel fuel (11 ppm S). Three additional oil-fired heating system types were also tested with normal heating fuel, low sulfur and ultralow sulfur fuel. They included an oil-fired warm air furnace of conventional design, a high efficiency condensing warm air furnace, a condensing hydronic boiler and the conventional hydronic boiler as discussed above. The linearity in the results was observed with all of the different oil-fired equipment types (as shown in the second figure on the next page). A linear regression of the data resulted in an Rsquared value of 0.99 indicating that a very good linear relationship exits. This means that as sulfur decreases the PM 2.5 emissions are reduced in a linear manner within the sulfur content range tested. At the ultra low sulfur level (15 ppm S) the amount of PM 2.5 had been reduced dramatically to an average of 0.043 mg/MJ. Three different gas-fired heating systems were tested. These included a conventional in-shot induced draft warm air furnace, an atmospheric fired hydronic boiler and a high efficiency hydronic boiler. The particulate (PM 2.5) measured ranged from 0.011 to 0.036 mg/MJ. depending on the raw material source used in their manufacture. All three stoves tested were fueled with premium (low ash) wood pellets obtained in a single batch to provide for uniformity in the test fuel. Unlike the oil and gas fired systems, the wood pellet stoves had measurable amounts of particulates sized above the 2.5-micron size that defines fine particulates (less than 2.5 microns). The fine particulate emissions rates ranged from 22 to 30 mg/ MJ with an average value

  17. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  18. Greenhouse Gas emissions from California Geothermal Power Plants

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sullivan, John

    2014-03-14

    The information given in this file represents GHG emissions and corresponding emission rates for California flash and dry steam geothermal power plants. This stage of the life cycle is the fuel use component of the fuel cycle and arises during plant operation. Despite that no fossil fuels are being consumed during operation of these plants, GHG emissions nevertheless arise from GHGs present in the geofluids and dry steam that get released to the atmosphere upon passing through the system. Data for the years of 2008 to 2012 are analyzed.

  19. Greenhouse Gas emissions from California Geothermal Power Plants

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sullivan, John

    The information given in this file represents GHG emissions and corresponding emission rates for California flash and dry steam geothermal power plants. This stage of the life cycle is the fuel use component of the fuel cycle and arises during plant operation. Despite that no fossil fuels are being consumed during operation of these plants, GHG emissions nevertheless arise from GHGs present in the geofluids and dry steam that get released to the atmosphere upon passing through the system. Data for the years of 2008 to 2012 are analyzed.

  20. RADIO SYNCHROTRON EMISSION FROM A BOW SHOCK AROUND THE GAS CLOUD G2 HEADING TOWARD THE GALACTIC CENTER

    SciTech Connect (OSTI)

    Narayan, Ramesh; Sironi, Lorenzo; Oezel, Feryal

    2012-10-01

    A dense ionized cloud of gas has been recently discovered to be moving directly toward the supermassive black hole, Sgr A*, at the Galactic center. In 2013 June, at the pericenter of its highly eccentric orbit, the cloud will be approximately 3100 Schwarzschild radii from the black hole and will move supersonically through the ambient hot gas with a velocity of v{sub p} Almost-Equal-To 5400 km s{sup -1}. A bow shock is likely to form in front of the cloud and could accelerate electrons to relativistic energies. We estimate via particle-in-cell simulations the energy distribution of the accelerated electrons and show that the non-thermal synchrotron emission from these electrons might exceed the quiescent radio emission from Sgr A* by a factor of several. The enhanced radio emission should be detectable at GHz and higher frequencies around the time of pericentric passage and in the following months. The bow shock emission is expected to be displaced from the quiescent radio emission of Sgr A* by {approx}33 mas. Interferometric observations could resolve potential changes in the radio image of Sgr A* at wavelengths {approx}< 6 cm.

  1. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    SciTech Connect (OSTI)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.; Oshinuga, A.; Miyasato, M.; Lucht, E.; van der Merwe, D.; Schaberg, P.

    2010-05-01

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimes almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.

  2. Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Gasoline Vehicles | Department of Energy Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Long-Term Changes in Gas- and Particle-Phase Emissions from On-Road Diesel and Gasoline Vehicles Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon

  3. DOE Strengthens Public Registry to Track Greenhouse Gas Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Under this program, U.S. companies will submit detailed, annual reports on their emissions and reductions of greenhouse gases, and these reports will become part of the public ...

  4. Regulated Emissions from Diesel and Compressed Natural Gas Transit Buses

    Broader source: Energy.gov [DOE]

    Poster presentaiton at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT).

  5. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Environmental Management (EM)

    Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop November 12-13, 2014, Sheraton Pittsburgh Airport Hotel, Coraopolis, PA 15108 FINAL AGENDA Day 1 (Wednesday, November 12) 12:00-1:00 pm REGISTRATION 1:00-1:30 pm Welcome and Overviews Mark Johnson, Director, Advanced Manufacturing Office (AMO), DOE Office of Energy Efficiency and Renewable Energy Christopher J. Freitas, Senior Program Manager, Natural Gas Infrastructure, Office of Oil and Natural Gas, DOE Office of

  6. GHG emission factors developed for the collection, transport and landfilling of municipal waste in South African municipalities

    SciTech Connect (OSTI)

    Friedrich, Elena; Trois, Cristina

    2013-04-15

    Highlights: ? An average GHG emission factor for the collection and transport of municipal solid waste in South Africa is calculated. ? A range of GHG emission factors for different types of landfills (including dumps) in South Africa are calculated. ? These factors are compared internationally and their implications for South Africa and developing countries are discussed . ? Areas for new research are highlighted. - Abstract: Greenhouse gas (GHG) emission factors are used with increased frequency for the accounting and reporting of GHG from waste management. However, these factors have been calculated for developed countries of the Northern Hemisphere and are lacking for developing countries. This paper shows how such factors have been developed for the collection, transport and landfilling of municipal waste in South Africa. As such it presents a model on how international results and methodology can be adapted and used to calculate country-specific GHG emission factors from waste. For the collection and transport of municipal waste in South Africa, the average diesel consumption is around 5 dm{sup 3} (litres) per tonne of wet waste and the associated GHG emissions are about 15 kg CO{sub 2} equivalents (CO{sub 2} e). Depending on the type of landfill, the GHG emissions from the landfilling of waste have been calculated to range from ?145 to 1016 kg CO{sub 2} e per tonne of wet waste, when taking into account carbon storage, and from 441 to 2532 kg CO{sub 2} e per tonne of wet waste, when carbon storage is left out. The highest emission factor per unit of wet waste is for landfill sites without landfill gas collection and these are the dominant waste disposal facilities in South Africa. However, cash strapped municipalities in Africa and the developing world will not be able to significantly upgrade these sites and reduce their GHG burdens if there is no equivalent replacement of the Clean Development Mechanism (CDM) resulting from the Kyoto agreement. Other low cost avenues need to be investigated to suit local conditions, in particular landfill covers which enhance methane oxidation.

  7. Greenhouse gas emissions in Sub-Saharan Africa

    SciTech Connect (OSTI)

    Graham, R.L.; Perlack, R.D.; Prasad, A.M.G.; Ranney, J.W.; Waddle, D.B.

    1990-11-01

    Current and future carbon emissions from land-use change and energy consumption were analyzed for Sub-Saharan Africa. The energy sector analysis was based on UN energy data tapes while the land-use analysis was based on a spatially-explicit land-use model developed specifically for this project. The impacts of different energy and land-use strategies on future carbon emissions were considered. (A review of anthropogenic emissions of methane, nitrous oxides, and chlorofluorocarbons in Sub-Saharan Africa indicated that they were probably minor in both a global and a regional context. The study therefore was focused on emissions of carbon dioxide.) The land-use model predicts carbon emissions from land use change and the amount of carbon stored in vegetation (carbon inventory) on a yearly basis between 1985 and 2001. Emissions and inventory are modeled at 9000 regularly-spaced point locations in Sub-Saharan Africa using location-specific information on vegetation type, soils, climate and deforestation. Vegetation, soils, and climate information were derived from continental-scale maps while relative deforestation rates(% of forest land lost each year) were developed from country-specific forest and deforestation statistics (FAO Tropical Forest Resources Assessment for Africa, 1980). The carbon emissions under different land use strategies in Sub-Saharan Africa were analyzed by modifying deforestation rates and altering the amount of carbon stored under different land uses. The considered strategies were: preservation of existing forests, implementation of agroforestry, and establishment of industrial tree plantations. 82 refs., 16 figs., 25 tabs.

  8. Fuel-cycle greenhouse gas emissions impacts of alternative transportation fuels and advanced vehicle technologies.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-12-16

    At an international conference on global warming, held in Kyoto, Japan, in December 1997, the United States committed to reduce its greenhouse gas (GHG) emissions by 7% over its 1990 level by the year 2012. To help achieve that goal, transportation GHG emissions need to be reduced. Using Argonne's fuel-cycle model, I estimated GHG emissions reduction potentials of various near- and long-term transportation technologies. The estimated per-mile GHG emissions results show that alternative transportation fuels and advanced vehicle technologies can help significantly reduce transportation GHG emissions. Of the near-term technologies evaluated in this study, electric vehicles; hybrid electric vehicles; compression-ignition, direct-injection vehicles; and E85 flexible fuel vehicles can reduce fuel-cycle GHG emissions by more than 25%, on the fuel-cycle basis. Electric vehicles powered by electricity generated primarily from nuclear and renewable sources can reduce GHG emissions by 80%. Other alternative fuels, such as compressed natural gas and liquefied petroleum gas, offer limited, but positive, GHG emission reduction benefits. Among the long-term technologies evaluated in this study, conventional spark ignition and compression ignition engines powered by alternative fuels and gasoline- and diesel-powered advanced vehicles can reduce GHG emissions by 10% to 30%. Ethanol dedicated vehicles, electric vehicles, hybrid electric vehicles, and fuel-cell vehicles can reduce GHG emissions by over 40%. Spark ignition engines and fuel-cell vehicles powered by cellulosic ethanol and solar hydrogen (for fuel-cell vehicles only) can reduce GHG emissions by over 80%. In conclusion, both near- and long-term alternative fuels and advanced transportation technologies can play a role in reducing the United States GHG emissions.

  9. Trace Gas Emissions Data from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, and models and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. Collections under the broad heading of Trace Gas Emissions are organized as Fossil-Fuel CO2 Emissions, Land-Use CO2 Emissions, Soil CO2 Emissions, and Methane.

  10. Life Cycle Greenhouse Gas Emissions from Electricity Generation Fact Sheet

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  11. Life Cycle Greenhouse Gas Emissions from Electricity Generation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-01-01

    Analysts at NREL have developed and applied a systematic approach to review the LCA literature, identify primary sources of variability and, where possible, reduce variability in GHG emissions estimates through a procedure called 'harmonization.' Harmonization of the literature provides increased precision and helps clarify the impacts of specific electricity generation choices, producing more robust results.

  12. An approach for verifying biogenic greenhouse gas emissions inventories with atmospheric CO 2 concentration data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ogle, Stephen; Davis, Kenneth J.; Lauvaux, Thomas; Schuh, Andrew E.; Cooley, Dan; West, Tristram O.; Heath, L.; Miles, Natasha; Richardson, S. J.; Breidt, F. Jay; et al

    2015-03-10

    Verifying national greenhouse gas (GHG) emissions inventories is a critical step to ensure that reported emissions data to the United Nations Framework Convention on Climate Change (UNFCCC) are accurate and representative of a country’s contribution to GHG concentrations in the atmosphere. Verification could include a variety of evidence, but arguably the most convincing verification would be confirmation of a change in GHG concentrations in the atmosphere that is consistent with reported emissions to the UNFCCC. We report here on a case study evaluating this option based on a prototype atmospheric CO2 measurement network deployed in the Mid-Continent Region of themore » conterminous United States. We found that the atmospheric CO2 measurement data did verify the accuracy of the emissions inventory within the confidence limits of the emissions estimates, suggesting that this technology could be further developed and deployed more widely in the future for verifying reported emissions.« less

  13. NATURAL GAS VARIABILITY IN CALIFORNIA: ENVIRONMENTAL IMPACTS AND DEVICE PERFORMANCE EXPERIMENTAL EVALUATION OF POLLUTANT EMISSIONS FROM RESIDENTIAL APPLIANCES

    SciTech Connect (OSTI)

    Singer, Brett C.; Apte, Michael G.; Black, Douglas R.; Hotchi, Toshifumi; Lucas, Donald; Lunden, Melissa M.; Mirer, Anna G.; Spears, Michael; Sullivan, Douglas P.

    2009-12-01

    The effect of liquefied natural gas on pollutant emissions was evaluated experimentally with used and new appliances in the laboratory and with appliances installed in residences, targeting information gaps from previous studies. Burner selection targeted available technologies that are projected to comprise the majority of installed appliances over the next decade. Experiments were conducted on 13 cooktop sets, 12 ovens, 5 broiler burners, 5 storage water heaters, 4 forced air furnaces, 1 wall furnace, and 6 tankless water heaters. Air-free concentrations and fuel-based emission factors were determined for carbon monoxide, nitrogen oxides, nitrogen dioxide, and the number of (predominantly ultrafine) particles over complete burns?including transient effects (device warm-up and intermittent firing of burners) following ignition--and during more stable end-of-burn conditions. Formaldehyde was measured over multi-burn cycles. The baseline fuel was Northern California line gas with Wobbe number (a measure of fuel energy delivery rate) of 1320-1340; test fuels had Wobbe numbers of roughly 1390 and 1420, and in some cases 1360. No ignition or operational problems were observed during test fuel use. Baseline emissions varied widely across and within burner groups and with burner operational mode. Statistically significant emissions changes were observed for some pollutants on some burners.

  14. Meeting State Carbon Emission Requirements through Industrial Energy Efficiency: The Southern California Gas Company’s Industrial End User Program

    Broader source: Energy.gov [DOE]

    This case study describes the Southern California Gas Company’s Industrial End User program, which helps large industrial customers increase energy efficiency and reduce energy use and greenhouse gas emissions.

  15. California Greenhouse Gas Emissions Standards for Light-Duty Vehicles (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01

    In July 2002, California Assembly Bill 1493 (A.B. 1493) was signed into law. The law requires that the California Air Resources Board (CARB) develop and adopt, by January 1, 2005, greenhouse gas emission standards for light-duty vehicles that provide the maximum feasible reduction in emissions. In estimating the feasibility of the standard, CARB is required to consider cost-effectiveness, technological capability, economic impacts, and flexibility for manufacturers in meeting the standard.

  16. Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of

    Broader source: Energy.gov (indexed) [DOE]

    Plug-In Hybrid Electric Vehicles | Department of Energy This report examines energy use and emissions from primary energy source through vehicle operation to help researchers understand the impact of the upstream mix of electricity generation technologies for recharging plug-in hybrid electric vehicles (PHEVs), as well as the powertrain technology and fuel sources for PHEVs. PDF icon Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles More

  17. Reducing GHG emissions by co-utilization of coal with natural gas or biomass

    SciTech Connect (OSTI)

    Smith, I.M.

    2004-07-01

    Energy reserves price and security of supply issues are discussed in the context of the prospects for coal and policies to reduce greenhouse gas (GHG) emissions. Coal is projected to remain a major source of energy, with most of the demand growth in developing countries. Currently available power-generating technologies, deploying coal with natural gas or biomass, are examined. Examples of successful, partial substitution of coal by other fuels in power stations are highlighted, including the GHG emissions reductions achieved as well as the costs where available. Among various options, hybrid gasification and parallel cofiring of coal with biomass and natural gas appear to have the greatest potential to reduce GHG emissions. Much may also be achieved by cofiring, reburning, and repowering with gas turbines. The best method differs between different power systems. Co-utilization of biomass with coal is a least-cost option to reduce GHG emissions where the fuel prices are comparable, usually due to subsidies or taxes. The role of biomass is likely to increase due to greater use of subsidies, carbon taxes, and emissions trading within the context of the Kyoto Protocol. This should provide opportunities for clean coal technology transfer and diffusion, including biomass co-utilization. 32 refs., 1 fig., 3 tabs.

  18. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop The Advanced Manufacturing Office (AMO) at the U.S. Department of Energy (DOE)'s Office of Energy Efficiency and Renewable Energy and the Office of Fossil Energy (FE) hosted a workshop, November 12-13, 2014, in Coraopolis, Pennsylvania, as a follow-up to the President's Climate Action Plan and the DOE meeting series on

  19. Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Implications for U.S. Petroleum Fuels | Argonne National Laboratory Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Title Well-to-Wheels Greenhouse Gas Emissions of Canadian Oil Sands Products: Implications for U.S. Petroleum Fuels Publication Type Journal Article Year of Publication 2015 Authors Cai, H, Brandt, AR, Yeh, S, Englander, JG, Han, J, Elgowainy, A, M.Q., W Journal Environmental Science & Technology Volume 49 Start

  20. CIRCUMBINARY GAS ACCRETION ONTO A CENTRAL BINARY: INFRARED MOLECULAR HYDROGEN EMISSION FROM GG Tau A

    SciTech Connect (OSTI)

    Beck, Tracy L.; Lubow, S. H.; Bary, Jeffrey S.; Dutrey, Anne; Guilloteau, Stephane; Pietu, Vincent; Simon, M. E-mail: lubow@stsci.edu E-mail: Anne.Dutrey@obs.u-bordeaux1.fr E-mail: pietu@iram.fr

    2012-07-20

    We present high spatial resolution maps of ro-vibrational molecular hydrogen emission from the environment of the GG Tau A binary component in the GG Tau quadruple system. The H{sub 2} v = 1-0 S(1) emission is spatially resolved and encompasses the inner binary, with emission detected at locations that should be dynamically cleared on several hundred year timescales. Extensions of H{sub 2} gas emission are seen to {approx}100 AU distances from the central stars. The v = 2-1 S(1) emission at 2.24 {mu}m is also detected at {approx}30 AU from the central stars, with a line ratio of 0.05 {+-} 0.01 with respect to the v = 1-0 S(1) emission. Assuming gas in LTE, this ratio corresponds to an emission environment at {approx}1700 K. We estimate that this temperature is too high for quiescent gas heated by X-ray or UV emission from the central stars. Surprisingly, we find that the brightest region of H{sub 2} emission arises from a spatial location that is exactly coincident with a recently revealed dust 'streamer' which seems to be transferring material from the outer circumbinary ring around GG Tau A into the inner region. As a result, we identify a new excitation mechanism for ro-vibrational H{sub 2} stimulation in the environment of young stars. The H{sub 2} in the GG Tau A system appears to be stimulated by mass accretion infall as material in the circumbinary ring accretes onto the system to replenish the inner circumstellar disks. We postulate that H{sub 2} stimulated by accretion infall could be present in other systems, particularly binaries and 'transition disk' systems which have dust-cleared gaps in their circumstellar environments.

  1. Control of SOx emission in tail gas of the Claus Plant at Kwangyang Steel Works

    SciTech Connect (OSTI)

    Kang, H.S.; Park, J.W.; Hyun, H.D.; Lee, D.S.; Paik, S.C.; Chung, J.S.

    1995-12-01

    Pilot and/or laboratory studies were conducted in order to find methods for reducing the SOx emission in the Claus tail gas of the cokes unit. The TGT process which is based on the complete hydrogenation of the sulfur-containing compounds (SO{sub 2}, S) into H{sub 2}S and returning to the COG main line can reduce the SOx emission to zero. In case the return to the COG main is impossible, the SPOR process (Sulfur removal based on Partial Oxidation and Reduction) can be successfully applied to reduce the SOx emission.

  2. Effects of Travel Reduction and Efficient Driving on Transportation: Energy Use and Greenhouse Gas Emissions

    Broader source: Energy.gov [DOE]

    Numerous transportation strategies are directed at reducing energy use and greenhouse gas (GHG) emissions by changing the behavior of individual drivers or travelers. These behavioral changes may have the effect of reducing travel, shifting travel to more efficient modes, or improving the efficiency of existing travel. Since the 1970s, federal, regional, state and municipal agencies have tried to reduce energy use, emissions, and congestion by influencing travel behavior. This report reviews and summarizes the literature on relationships between these strategies and transportation-related energy use and GHG emissions to examine how changes to travel behavior can reduce transportation energy use and discuss the potential for federal actions to affect travel behavior.

  3. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  4. Comparing the greenhouse gas emissions from three alternative waste combustion concepts

    SciTech Connect (OSTI)

    Vainikka, Pasi; Tsupari, Eemeli; Sipilae, Kai; Hupa, Mikko

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Significant GHG reductions are possible by efficient WtE technologies. Black-Right-Pointing-Pointer CHP and high power-to-heat ratio provide significant GHG savings. Black-Right-Pointing-Pointer N{sub 2}O and coal mine type are important in LCA GHG emissions of FBC co-combustion. Black-Right-Pointing-Pointer Substituting coal and fuel oil by waste is beneficial in electricity and heat production. Black-Right-Pointing-Pointer Substituting natural gas by waste may not be reasonable in CHP generation. - Abstract: Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO{sub 2}-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.

  5. Transformative Reduction of Transportation Greenhouse Gas Emissions. Opportunities for Change in Technologies and Systems

    SciTech Connect (OSTI)

    Vimmerstedt, Laura; Brown, Austin; Newes, Emily; Markel, Tony; Schroeder, Alex; Zhang, Yimin; Chipman, Peter; Johnson, Shawn

    2015-04-30

    The transportation sector is changing, influenced by concurrent, ongoing, dynamic trends that could dramatically affect the future energy landscape, including effects on the potential for greenhouse gas emissions reductions. Battery cost reductions and improved performance coupled with a growing number of electric vehicle model offerings are enabling greater battery electric vehicle market penetration, and advances in fuel cell technology and decreases in hydrogen production costs are leading to initial fuel cell vehicle offerings. Radically more efficient vehicles based on both conventional and new drivetrain technologies reduce greenhouse gas emissions per vehicle-mile. Net impacts also depend on the energy sources used for propulsion, and these are changing with increased use of renewable energy and unconventional fossil fuel resources. Connected and automated vehicles are emerging for personal and freight transportation systems and could increase use of low- or non-emitting technologies and systems; however, the net effects of automation on greenhouse gas emissions are uncertain. The longstanding trend of an annual increase in transportation demand has reversed for personal vehicle miles traveled in recent years, demonstrating the possibility of lower-travel future scenarios. Finally, advanced biofuel pathways have continued to develop, highlighting low-carbon and in some cases carbon-negative fuel pathways. We discuss the potential for transformative reductions in petroleum use and greenhouse gas emissions through these emerging transportation-sector technologies and trends and present a Clean Transportation Sector Initiative scenario for such reductions, which are summarized in Table ES-1.

  6. White House Announces New Executive Order To Reduce Greenhouse Gas Emissions in the Federal Government

    Broader source: Energy.gov [DOE]

    The White House today announced that President Obama will issue a new executive order that will cut the federal government's greenhouse gas emissions 40% over the next decade (from 2008 levels) and increase the share of electricity the federal government consumes from renewable sources to 30%.

  7. Evaluation of metrics and baselines for tracking greenhouse gas emissions trends: Recommendations for the California climate action registry

    SciTech Connect (OSTI)

    Price, Lynn; Murtishaw, Scott; Worrell, Ernst

    2003-06-01

    Executive Summary: The California Climate Action Registry, which was initially established in 2000 and began operation in Fall 2002, is a voluntary registry for recording annual greenhouse gas (GHG) emissions. The purpose of the Registry is to assist California businesses and organizations in their efforts to inventory and document emissions in order to establish a baseline and to document early actions to increase energy efficiency and decrease GHG emissions. The State of California has committed to use its ''best efforts'' to ensure that entities that establish GHG emissions baselines and register their emissions will receive ''appropriate consideration under any future international, federal, or state regulatory scheme relating to greenhouse gas emissions.'' Reporting of GHG emissions involves documentation of both ''direct'' emissions from sources that are under the entity's control and indirect emissions controlled by others. Electricity generated by an off-site power source is consider ed to be an indirect GHG emission and is required to be included in the entity's report. Registry participants include businesses, non-profit organizations, municipalities, state agencies, and other entities. Participants are required to register the GHG emissions of all operations in California, and are encouraged to report nationwide. For the first three years of participation, the Registry only requires the reporting of carbon dioxide (CO2) emissions, although participants are encouraged to report the remaining five Kyoto Protocol GHGs (CH4, N2O, HFCs, PFCs, and SF6). After three years, reporting of all six Kyoto GHG emissions is required. The enabling legislation for the Registry (SB 527) requires total GHG emissions to be registered and requires reporting of ''industry-specific metrics'' once such metrics have been adopted by the Registry. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) was asked to provide technical assistance to the California Energy Commission (Energy Commission) related to the Registry in three areas: (1) assessing the availability and usefulness of industry-specific metrics, (2) evaluating various methods for establishing baselines for calculating GHG emissions reductions related to specific actions taken by Registry participants, and (3) establishing methods for calculating electricity CO2 emission factors. The third area of research was completed in 2002 and is documented in Estimating Carbon Dioxide Emissions Factors for the California Electric Power Sector (Marnay et al., 2002). This report documents our findings related to the first areas of research. For the first area of research, the overall objective was to evaluate the metrics, such as emissions per economic unit or emissions per unit of production that can be used to report GHG emissions trends for potential Registry participants. This research began with an effort to identify methodologies, benchmarking programs, inventories, protocols, and registries that u se industry-specific metrics to track trends in energy use or GHG emissions in order to determine what types of metrics have already been developed. The next step in developing industry-specific metrics was to assess the availability of data needed to determine metric development priorities. Berkeley Lab also determined the relative importance of different potential Registry participant categories in order to asses s the availability of sectoral or industry-specific metrics and then identified industry-specific metrics in use around the world. While a plethora of metrics was identified, no one metric that adequately tracks trends in GHG emissions while maintaining confidentiality of data was identified. As a result of this review, Berkeley Lab recommends the development of a GHG intensity index as a new metric for reporting and tracking GHG emissions trends.Such an index could provide an industry-specific metric for reporting and tracking GHG emissions trends to accurately reflect year to year changes while protecting proprietary data. This GHG intensity index changes while protecting proprietary data. This GHG intensity index would provide Registry participants with a means for demonstrating improvements in their energy and GHG emissions per unit of production without divulging specific values. For the second research area, Berkeley Lab evaluated various methods used to calculate baselines for documentation of energy consumption or GHG emissions reductions, noting those that use industry-specific metrics. Accounting for actions to reduce GHGs can be done on a project-by-project basis or on an entity basis. Establishing project-related baselines for mitigation efforts has been widely discussed in the context of two of the so-called ''flexible mechanisms'' of the Kyoto Protocol to the United Nations Framework Convention on Climate Change (Kyoto Protocol) Joint Implementation (JI) and the Clean Development Mechanism (CDM).

  8. Emission factors for leaks in refinery components in heavy liquid service

    SciTech Connect (OSTI)

    Taback, H.; Godec, M.

    1996-12-31

    The objective of this program was to provide sufficient screening data so that EPA can develop an official set of emission factors (expressed in lb/hr/component) for refinery components (valves, flanged connectors, non-flanged connectors, pumps, open-ended lines, and other) in heavy liquid (BL) service. To accomplish this, 211,000 existing HL screening values from Southern California refineries were compiled and compared with 2,500 new HL screening measurements taken at two refineries in the state of Washington. Since Southern California is an area in extreme non-attainment of the National Ambient Air Quality Standards (NAAQS) and therefore has tight emission control regulations, it was felt that its screening data may not be representative of refineries without tight emission controls. Thus, the Southern California screening data were compared to screening measurements at refineries in an area that is in attainment of the NAAQS and without emissions control, which is the case for those refineries in Washington. It was found that statistically there was no significant difference in emission factors between the two areas and, therefore, there appears to be no difference in emissions from heavy liquid components in areas with and without leak detection and repair (LDAR) programs. The new emission factors range from 1/7 to 1/3 times the current EPA emission factors. This program was sponsored by the American Petroleum Institute (API) and an API report will soon be released providing complete details.

  9. A DETECTION OF MOLECULAR GAS EMISSION IN THE HOST GALAXY OF GRB080517

    SciTech Connect (OSTI)

    Stanway, E. R.; Levan, A. J.; Tanvir, N. R.; Wiersema, K.; Van der Laan, T. P. R.

    2015-01-01

    We have observed the host galaxy of the low-redshift, low-luminosity Swift GRB080517 at 105.8 GHz using the IRAM Plateau de Bure interferometer. We detect an emission line with integrated flux S?? = 0.39 0.05Jykms{sup 1}consistent both spatially and in velocity with identification as the J = 1-0 rotational transition of carbon monoxide (CO) at the host galaxy redshift. This represents only the third long gamma-ray burst (GRB) host galaxy with molecular gas detected in emission. The inferred molecular gas mass, M{sub H{sub 2}}?6.310{sup 8} M {sub ?}, implies a gas consumption timescale of ?40Myr if star formation continues at its current rate. Similar short timescales appear characteristic of the long GRB population with CO observations to date, suggesting that the GRB in these sources occurs toward the end of their star formation episode.

  10. Technology and Greenhouse Gas Emissions: An IntegratedScenario Analysis

    SciTech Connect (OSTI)

    Koomey, J.G.; Latiner, S.; Markel, R.J.; Marnay, C.; Richey, R.C.

    1998-09-01

    This report describes an analysis of possible technology-based scenarios for the U.S. energy system that would result in both carbon savings and net economic benefits. We use a modified version of the Energy Information Administration's National Energy Modeling System (LBNL-NEMS) to assess the potential energy, carbon, and bill savings from a portfolio of carbon saving options. This analysis is based on technology resource potentials estimated in previous bottom-up studies, but it uses the integrated LBNL-NEMS framework to assess interactions and synergies among these options. The analysis in this paper builds on previous estimates of possible "technology paths" to investigate four major components of an aggressive greenhouse gas reduction strategy: (1) the large scale implementation of demand-side efficiency, comparable in scale to that presented in two recent policy studies on this topic; (2) a variety of "alternative" electricity supply-side options, including biomass cofiring, extension of the renewable production tax credit for wind, increased industrial cogeneration, and hydropower refurbishment. (3) the economic retirement of older and less efficient existing fossil-find power plants; and (4) a permit charge of $23 per metric ton of carbon (1996 $/t),l assuming that carbon trading is implemented in the US, and that the carbon permit charge equilibrates at this level. This level of carbon permit charge, as discussed later in the report, is in the likely range for the Clinton Administration's position on this topic.

  11. A Long Term Field Emissions Study of Natural Gas Fueled Refuse Haulers in New York City

    SciTech Connect (OSTI)

    Nigel N. Clark; Byron l. Rapp; Mridul Gautam; Wenguang Wang; Donald W. Lyons

    1998-10-19

    New York City Department of Sanitation has operated natural gas fueled refuse haulers in a pilot study: a major goal of this study was to compare the emissions from these natural gas vehicles with their diesel counterparts. The vehicles were tandem axle trucks with GVW (gross vehicle weight) rating of 69,897 pounds. The primary use of these was for street collection and transporting the refuse to a landfill. West Virginia University Transportable Heavy Duty Emissions Testing Laboratories have been engaged in monitoring the tailpipe emissions from these trucks for seven-years. In the later years of testing the hydrocarbons were speciated for non-methane and methane components. Six of these vehicles employed the older technology (mechanical mixer) Cummins L-10 lean burn natural gas engines. Five trucks were equipped with electronically controlled Detroit Diesel Series 50 lean burn engines, while another five were powered by Caterpillar stoichiometric burn 3306 natural gas engines, The Ca terpillar engines employed an exhaust oxygen sensor feedback and three way catalysts. Since the refuse haulers had automatic Allison transmissions, and since they were employed in stop-and-go city service, initial emissions measurements were made using the Central Business Cycle (SAE Jl376) for buses at 42,000 pound test weight. Some additional measurements were made using an ad hoc cycle that has been designed to be more representative of the real refuse hauler use that included several compaction cycles. The Cummins powered natural gas vehicles showed oxides of nitrogen and carbon monoxide emission variations typically associated with variable fuel mixer performance. In the first Year of testing, the stoichiometric Caterpillar engines yielded low emission levels, but in later years two of these refuse haulers had high carbon monoxide attributed to failure of the feedback system. For example, carbon monoxide on these two vehicles rose from 1.4 g/mile and 10 g/mile in 1995 to 144.9 g/mile and 57.8 g/mile in 1996. These stoichiometric engines were also less fuel efficient than their lean burn counterparts. The Detroit Diesel Series 50 powered refuse haulers produced high levels of oxides of nitrogen. However, it was found that changing the shifting patterns of the transmission lowered the oxides of nitrogen. All three engine types showed the potential for low emissions operation and the particulate matter reduction advantage offered by natural gas was evident from the results.

  12. Opportunities to change development pathways toward lower greenhouse gas emissions through energy efficiency

    SciTech Connect (OSTI)

    Alterra, Swart; Masanet, Eric; Lecocq, Franck; Najam, Adil; Schaeffer, Robert; Winkler, Harald; Sathaye, Jayant

    2008-07-04

    There is a multiplicity of development pathways in which low energy sector emissions are not necessarily associated with low economic growth. However, changes in development pathways can rarely be imposed from the top. On this basis, examples of energy efficiency opportunities to change development pathways toward lower emissions are presented in this paper. We review opportunities at the sectoral and macro level. The potential for action on nonclimate policies that influence energy use and emissions are presented. Examples are drawn from policies already adopted and implemented in the energy sector. The paper discusses relationships between energy efficiency policies and their synergies and tradeoffs with sustainable development and greenhouse gas emissions. It points to ways that energy efficiency could be mainstreamed into devel?opment choices.

  13. Curbing Air Pollution and Greenhouse Gas Emissions from Industrial Boilers in China

    SciTech Connect (OSTI)

    Shen, Bo; Price, Lynn K; Lu, Hongyou; Liu, Xu; Tsen, Katherine; Xiangyang, Wei; Yunpeng, Zhang; Jian, Guan; Rui, Hou; Junfeng, Zhang; Yuqun, Zhuo; Shumao, Xia; Yafeng, Han; Manzhi, Liu

    2015-10-28

    China’s industrial boiler systems consume 700 million tons of coal annually, accounting for 18% of the nation’s total coal consumption. Together these boiler systems are one of the major sources of China’s greenhouse gas (GHG) emissions, producing approximately 1.3 gigatons (Gt) of carbon dioxide (CO2) annually. These boiler systems are also responsible for 33% and 27% of total soot and sulfur dioxide (SO2) emissions in China, respectively, making a substantial contribution to China’s local environmental degradation. The Chinese government - at both the national and local level - is taking actions to mitigate the significant greenhouse gas (GHG) emissions and air pollution related to the country’s extensive use of coal-fired industrial boilers. The United States and China are pursuing a collaborative effort under the U.S.-China Climate Change Working Group to conduct a comprehensive assessment of China’s coal-fired industrial boilers and to develop an implementation roadmap that will improve industrial boiler efficiency and maximize fuel-switching opportunities. Two Chinese cities – Ningbo and Xi’an – have been selected for the assessment. These cities represent coastal areas with access to liquefied natural gas (LNG) imports and inland regions with access to interprovincial natural gas pipelines, respectively.

  14. Life Cycle GHG Emissions from Conventional Natural Gas Power Generation: Systematic Review and Harmonization (Presentation)

    SciTech Connect (OSTI)

    Heath, G.; O'Donoughue, P.; Whitaker, M.

    2012-12-01

    This research provides a systematic review and harmonization of the life cycle assessment (LCA) literature of electricity generated from conventionally produced natural gas. We focus on estimates of greenhouse gases (GHGs) emitted in the life cycle of electricity generation from conventionally produced natural gas in combustion turbines (NGCT) and combined-cycle (NGCC) systems. A process we term "harmonization" was employed to align several common system performance parameters and assumptions to better allow for cross-study comparisons, with the goal of clarifying central tendency and reducing variability in estimates of life cycle GHG emissions. This presentation summarizes preliminary results.

  15. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    SciTech Connect (OSTI)

    Greenblatt, Jeffery B.

    2013-10-10

    A California Greenhouse Gas Inventory Spreadsheet (GHGIS) model was developed to explore the impact of combinations of state policies on state greenhouse gas (GHG) and regional criteria pollutant emissions. The model included representations of all GHG- emitting sectors of the California economy (including those outside the energy sector, such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees of detail, and was carefully calibrated using available data and projections from multiple state agencies and other sources. Starting from basic drivers such as population, numbers of households, gross state product, numbers of vehicles, etc., the model calculated energy demands by type (various types of liquid and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three criteria pollutants: reactive organic gases (ROG), nitrogen oxides (NOx), and fine (2.5 ?m) particulate matter (PM2.5). Calculations were generally statewide, but in some sectors, criteria pollutants were also calculated for two regional air basins: the South Coast Air Basin (SCAB) and the San Joaquin Valley (SJV). Three scenarios were developed that attempt to model: (1) all committed policies, (2) additional, uncommitted policy targets and (3) potential technology and market futures. Each scenario received extensive input from state energy planning agencies, in particular the California Air Resources Board. Results indicate that all three scenarios are able to meet the 2020 statewide GHG targets, and by 2030, statewide GHG emissions range from between 208 and 396 MtCO2/yr. However, none of the scenarios are able to meet the 2050 GHG target of 85 MtCO2/yr, with emissions ranging from 188 to 444 MtCO2/yr, so additional policies will need to be developed for California to meet this stringent future target. A full sensitivity study of major scenario assumptions was also performed. In terms of criteria pollutants, targets were less well-defined, but while all three scenarios were able to make significant reductions in ROG, NOx and PM2.5 both statewide and in the two regional air basins, they may nonetheless fall short of what will be required by future federal standards. Specifically, in Scenario 1, regional NOx emissions are approximately three times the estimated targets for both 2023 and 2032, and in Scenarios 2 and 3, NOx emissions are approximately twice the estimated targets. Further work is required in this area, including detailed regional air quality modeling, in order to determine likely pathways for attaining these stringent targets.

  16. Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.

    SciTech Connect (OSTI)

    Mintz, M.; Gillette, J.; Elgowainy, A.

    2009-01-01

    Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption and significant GHG emissions (in the absence of carbon caps, taxes or sequestration); (5) Nuclear pathway is most favorable from energy use and GHG emissions perspective; (6) GH2 Truck and Pipeline delivery have much lower energy use and GHG emissions than LH2 Truck delivery; and (7) For LH2 Truck delivery, the liquefier accounts for most of the energy and GHG emissions.

  17. DUST CONTINUUM EMISSION AS A TRACER OF GAS MASS IN GALAXIES

    SciTech Connect (OSTI)

    Groves, Brent A.; Schinnerer, Eva; Walter, Fabian; Leroy, Adam; Galametz, Maud; Bolatto, Alberto; Hunt, Leslie; Dale, Daniel; Calzetti, Daniela; Croxall, Kevin; Kennicutt, Robert Jr.

    2015-01-20

    We use a sample of 36 galaxies from the KINGFISH (Herschel IR), HERACLES (IRAM CO), and THINGS (Very Large Array H I) surveys to study empirical relations between Herschel infrared (IR) luminosities and the total mass of the interstellar gas (H{sub 2} + H I). Such a comparison provides a simple empirical relationship without introducing the uncertainty of dust model fitting. We find tight correlations, and provide fits to these relations, between Herschel luminosities and the total gas mass integrated over entire galaxies, with the tightest, almost linear, correlation found for the longest wavelength data (SPIRE 500). However, we find that accounting for the gas-phase metallicity (affecting the dust to gas ratio) is crucial when applying these relations to low-mass, and presumably high-redshift, galaxies. The molecular (H{sub 2}) gas mass is found to be better correlated with the peak of the IR emission (e.g., PACS160), driven mostly by the correlation of stellar mass and mean dust temperature. When examining these relations as a function of galactocentric radius, we find the same correlations, albeit with a larger scatter, up to a radius of r ? 0.7 r {sub 25} (containing most of a galaxy's baryonic mass). However, beyond that radius, the same correlations no longer hold, with increasing gas (predominantly H I) mass relative to the infrared emission. The tight relations found for the bulk of the galaxy's baryonic content suggest that total gas masses of disk-like (non-merging/ULIRG) galaxies can be inferred from far-infrared continuum measurements in situations where only the latter are available, e.g., in ALMA continuum observations of high-redshift galaxies.

  18. References and Appendices: U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis, November 2012

    Energy Savers [EERE]

    4 U.S. Manufacturing Energy Use and Greenhouse Gas Emissions Analysis REFERENCES AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012a. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators. U.S. Department of Energy. http://www1.eere.energy.gov/manufacturing/tech_deployment/pdfs/steam22_backpressure.pdf AMO (Advanced Manufacturing Office), EERE (Energy Efficiency and Renewable Energy). 2012b. Improving Steam System Performance: A

  19. Estimating U.S. Methane Emissions from the Natural Gas Supply Chain. Approaches, Uncertainties, Current Estimates, and Future Studies

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-08-01

    A growing number of studies have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain. In particular, a number of measurement studies have suggested that actual levels of CH4 emissions may be higher than estimated by EPA" tm s U.S. GHG Emission Inventory. We reviewed the literature to identify the growing number of studies that have raised questions regarding uncertainties in our understanding of methane (CH4) emissions from fugitives and venting along the natural gas (NG) supply chain.

  20. Emission factors for several toxic air pollutants from fluidized-bed combustion of coal

    SciTech Connect (OSTI)

    Smith, A.E.

    1986-03-01

    Clean coal technologies such as fluidized-bed combustion have the potential to emit the same trace elements as conventional combustors. Since the US Environmental Protection Agency (EPA) is likely to promulgate National Emission Standards for Hazardous Air Pollutants for several trace elements, the feasibility of using fluidized-bed combustors to reduce sulfur dioxide emissions may depend in part on the relative amounts of trace elements emitted by fluidized-bed and conventional combustors. Emissions of trace elements from both atmospheric and pressurized fluidized-bed combustors were compared with those from conventional combustors by developing fluidized-bed emission factors from information available in the literature and comparing them with the emission factors for conventional combustors recommended in a literature search conducted for EPA. The comparisons are based on the mass of emission per unit of heat input for antimony, arsenic, beryllium, cadmium, chromium, cobalt, copper, lead, manganese, mercury, nickel, vanadium, and zinc. When inaccuracies in the data were taken into account, the trace element emissions from atmospheric fluidized-bed combustion seem to be somewhat higher than those from a conventional utility boiler burning pulverized coal and somewhat lower than those from pressurized fluidized-bed combustion.

  1. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    SciTech Connect (OSTI)

    Heath, G. A.; Burkhardt, J. J.

    2011-09-01

    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  2. Meeting State Carbon Emission Requirements through Industrial Energy Efficiency: The Southern California Gas Companys Industrial End User Program

    SciTech Connect (OSTI)

    2010-06-25

    This case study describes the Southern California Gas Companys Industrial End User program that helps large industrial customers increase energy efficiency and reduce energy use and GHG emissions.

  3. FE-Funded Study Released on Key Factors Affecting China Shale Gas

    Office of Environmental Management (EM)

    Development | Department of Energy FE-Funded Study Released on Key Factors Affecting China Shale Gas Development FE-Funded Study Released on Key Factors Affecting China Shale Gas Development September 12, 2014 - 7:14am Addthis As many people know, over the past decade the United States has experienced a shale gas revolution that has beneficially transformed its energy landscape. In witnessing this transformation, other nations with significant shale resources are understandably interested in

  4. UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

    SciTech Connect (OSTI)

    Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

    2011-10-01

    This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses. Depending on the value of gas, simple, low-cost measures, such as adjusting leaking equipment components, or larger-scale measures, such as installing dry seals on compressors, can be applied.

  5. Small-Chamber Measurements of Chemical-Specific Emission Factors for Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy; Russell, Marion; Apte, Michael G.

    2010-06-01

    Imported drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. To support an investigation of those building materials by the Consumer Products Safety Commission (CPSC), Lawrence Berkeley National Laboratory (LBNL) measured chemical-specific emission factors for 30 samples of drywall materials. Emission factors are reported for 75 chemicals and 30 different drywall samples encompassing both domestic and imported stock and incorporating natural, synthetic, or mixed gypsum core material. CPSC supplied all drywall materials. First the drywall samples were isolated and conditioned in dedicated chambers, then they were transferred to small chambers where emission testing was performed. Four sampling and analysis methods were utilized to assess (1) volatile organic compounds, (2) low molecular weight carbonyls, (3) volatile sulfur compounds, and (4) reactive sulfur gases. LBNL developed a new method that combines the use of solid phase microextraction (SPME) with small emission chambers to measure the reactive sulfur gases, then extended that technique to measure the full suite of volatile sulfur compounds. The testing procedure and analysis methods are described in detail herein. Emission factors were measured under a single set of controlled environmental conditions. The results are compared graphically for each method and in detailed tables for use in estimating indoor exposure concentrations.

  6. Estimating carbon dioxide emission factors for the California electric power sector

    SciTech Connect (OSTI)

    Marnay, Chris; Fisher, Diane; Murtishaw, Scott; Phadke, Amol; Price, Lynn; Sathaye, Jayant

    2002-08-01

    The California Climate Action Registry (''Registry'') was initially established in 2000 under Senate Bill 1771, and clarifying legislation (Senate Bill 527) was passed in September 2001. The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab) has been asked to provide technical assistance to the California Energy Commission (CEC) in establishing methods for calculating average and marginal electricity emissions factors, both historic and current, as well as statewide and for sub-regions. This study is exploratory in nature. It illustrates the use of three possible approaches and is not a rigorous estimation of actual emissions factors. While the Registry will ultimately cover emissions of all greenhouse gases (GHGs), presently it is focusing on carbon dioxide (CO2). Thus, this study only considers CO2, which is by far the largest GHG emitted in the power sector. Associating CO2 emissions with electricity consumption encounters three major complications. First, electricity can be generated from a number of different primary energy sources, many of which are large sources of CO2 emissions (e.g., coal combustion) while others result in virtually no CO{sub 2} emissions (e.g., hydro). Second, the mix of generation resources used to meet loads may vary at different times of day or in different seasons. Third, electrical energy is transported over long distances by complex transmission and distribution systems, so the generation sources related to electricity usage can be difficult to trace and may occur far from the jurisdiction in which that energy is consumed. In other words, the emissions resulting from electricity consumption vary considerably depending on when and where it is used since this affects the generation sources providing the power. There is no practical way to identify where or how all the electricity used by a certain customer was generated, but by reviewing public sources of data the total emission burden of a customer's electricity supplier can b e found and an average emissions factor (AEF) calculated. These are useful for assigning a net emission burden to a facility. In addition, marginal emissions factors (MEFs) for estimating the effect of changing levels of usage can be calculated. MEFs are needed because emission rates at the margin are likely to diverge from the average. The overall objective of this task is to develop methods for estimating AEFs and MEFs that can provide an estimate of the combined net CO2 emissions from all generating facilities that provide electricity to California electricity customers. The method covers the historic period from 1990 to the present, with 1990 and 1999 used as test years. The factors derived take into account the location and time of consumption, direct contracts for power which may have certain atypical characteristics (e.g., ''green'' electricity from renewable resources), resource mixes of electricity providers, import and export of electricity from utility owned and other sources, and electricity from cogeneration. It is assumed that the factors developed in this way will diverge considerably from simple statewide AEF estimates based on standardized inventory estimates that use conventions inconsistent with the goals of this work. A notable example concerns the treatment of imports, which despite providing a significant share of California's electricity supply picture, are excluded from inventory estimates of emissions, which are based on geographical boundaries of the state.

  7. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  8. Greenhouse gas emissions from landfill leachate treatment plants: A comparison of young and aged landfill

    SciTech Connect (OSTI)

    Wang, Xiaojun; Jia, Mingsheng; Chen, Xiaohai; Xu, Ying; Lin, Xiangyu; Kao, Chih Ming; Chen, Shaohua

    2014-07-15

    Highlights: • Young and aged leachate works accounted for 89.1% and 10.9% of 33.35 Gg CO{sub 2} yr{sup −1}. • Fresh leachate owned extremely low ORP and high organic matter content. • Strong CH{sub 4} emissions occurred in the fresh leachate ponds, but small in the aged. • N{sub 2}O emissions became dominant in the treatment units of both systems. • 8.45–11.9% of nitrogen was removed as the form of N{sub 2}O under steady-state. - Abstract: With limited assessment, leachate treatment of a specified landfill is considered to be a significant source of greenhouse gas (GHG) emissions. In our study, the cumulative GHG emitted from the storage ponds and process configurations that manage fresh or aged landfill leachate were investigated. Our results showed that strong CH{sub 4} emissions were observed from the fresh leachate storage pond, with the fluxes values (2219–26,489 mg C m{sup −2} h{sup −1}) extremely higher than those of N{sub 2}O (0.028–0.41 mg N m{sup −2} h{sup −1}). In contrast, the emission values for both CH{sub 4} and N{sub 2}O were low for the aged leachate tank. N{sub 2}O emissions became dominant once the leachate entered the treatment plants of both systems, accounting for 8–12% of the removal of N-species gases. Per capita, the N{sub 2}O emission based on both leachate treatment systems was estimated to be 7.99 g N{sub 2}O–N capita{sup −1} yr{sup −1}. An increase of 80% in N{sub 2}O emissions was observed when the bioreactor pH decreased by approximately 1 pH unit. The vast majority of carbon was removed in the form of CO{sub 2}, with a small portion as CH{sub 4} (<0.3%) during both treatment processes. The cumulative GHG emissions for fresh leachate storage ponds, fresh leachate treatment system and aged leachate treatment system were 19.10, 10.62 and 3.63 Gg CO{sub 2} eq yr{sup −1}, respectively, for a total that could be transformed to 9.09 kg CO{sub 2} eq capita{sup −1} yr{sup −1}.

  9. Impacts of Vehicle Weight Reduction via Material Substitution on Life-Cycle Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Kelly, Jarod C.; Sullivan, John L.; Burnham, Andrew; Elgowainy, Amgad

    2015-10-20

    This study examines the vehicle-cycle impacts associated with substituting lightweight materials for those currently found in light-duty passenger vehicles. We determine part-based energy use and greenhouse gas (GHG) emission ratios by collecting material substitution data from both the literature and automotive experts and evaluating that alongside known mass-based energy use and GHG emission ratios associated with material pair substitutions. Several vehicle parts, along with full vehicle systems, are examined for lightweighting via material substitution to observe the associated impact on GHG emissions. Results are contextualized by additionally examining fuel-cycle GHG reductions associated with mass reductions relative to the baseline vehicle during the use phase and also determining material pair breakeven driving distances for GHG emissions. The findings show that, while material substitution is useful in reducing vehicle weight, it often increases vehicle-cycle GHGs depending upon the material substitution pair. However, for a vehicles total life cycle, fuel economy benefits are greater than the increased burdens associated with the vehicle manufacturing cycle, resulting in a net total life-cycle GHG benefit. The vehicle cycle will become increasingly important in total vehicle life-cycle GHGs, since fuel-cycle GHGs will be gradually reduced as automakers ramp up vehicle efficiency to meet fuel economy standards.

  10. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  11. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl

    2003-05-15

    Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this study, ALSTOM Power Inc. (ALSTOM) has investigated several coal fired power plant configurations designed to capture CO{sub 2} from effluent gas streams for use or sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB units results in significant Boiler Island cost savings. Additionally, ALSTOM has identified several advanced/novel plant configurations, which improve the efficiency and cost of the CO{sub 2} product cleanup and compression process. These advanced/novel concepts require long development efforts. An economic analysis indicates that the proposed oxygen-firing technology in circulating fluidized boilers could be developed and deployed economically in the near future in enhanced oil recovery (EOR) applications or enhanced gas recovery (EGR), such as coal bed methane recovery. ALSTOM received a Cooperative Agreement from the US Department of Energy National Energy Technology Laboratory (DOE) in 2001 to carry out a project entitled ''Greenhouse Gas Emissions Control by Oxygen Firing in Circulating Fluidized Bed Boilers.'' This two-phased project is in effect from September 28, 2001, to October 27, 2004. (U.S. DOE NETL Cooperative Agreement No. DE-FC26-01NT41146). Phase I consisted of an evaluation of the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants, and supporting bench-scale testing. And Phase II consists of pilot-scale testing, supporting a refined performance and economic evaluation of the oxygen-fired AFC concept. Phase I, detailed in this report, entails a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen separate but related cases (listed below), representing various levels of technology development, were evaluated as described herein. The first seven cases represent coal combustion cases in CFB type equipment. The next four cases represent Integrated Gasification Combined Cycle (IGCC) systems. The last two cases represent advanced Chemical Looping systems, which were completely paid for by ALSTOM and included herein for completeness.

  12. Beyond the Inventory: An Interagency Collaboration to Reduce Greenhouse Gas Emissions in the Greater Yellowstone Area

    SciTech Connect (OSTI)

    Kandt, A.; Hotchkiss, E.; Fiebig, M.

    2010-10-01

    As one of the largest, intact ecosystems in the continental United States, land managers within the Greater Yellowstone Area (GYA) have recognized the importance of compiling and understanding agency greenhouse gas (GHG) emissions. The 10 Federal units within the GYA have taken an active role in compiling GHG inventories on a unit- and ecosystem-wide level, setting goals for GHG mitigation, and identifying mitigation strategies for achieving those goals. This paper details the processes, methodologies, challenges, solutions, and lessons learned by the 10 Federal units within the GYA throughout this ongoing effort.

  13. Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires

    SciTech Connect (OSTI)

    Yokelson, Robert J.; Burling, Ian R.; Gilman, Jessica; Warneke, Carsten; Stockwell, Chelsea E.; de Gouw, Joost A.; Akagi, Sheryl; Urbanski, Shawn; Veres, Patrick; Roberts, James M.; Kuster, W. C.; Reardon, James; Griffith, David WT; Johnson, Timothy J.; Hosseini, SeyedEhsan; Miller, J. Wayne; Cocker, David R.; Jung, H.; Weise, David

    2013-01-07

    Vegetative fuels commonly consumed in prescribed fires were collected from five locations in the southeastern and southwestern U.S. and burned in a series of 77 fires at the U.S. Forest Service Fire Sciences Laboratory in Missoula, Montana. The particulate matter (PM2.5) emissions were measured by gravimetric filter sampling with subsequent analysis for elemental carbon (EC), organic carbon (OC), and 38 elements. The trace gas emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP FTIR) spectrometer, proton-transfer-reaction mass spectrometry (PTR-MS), proton-transfer ion-trap mass spectrometry (PIT-MS), negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS), and gas chromatography with MS detection (GC-MS). 204 trace gas species (mostly non-methane organic compounds (NMOC)) were identified and quantified with the above instruments. An additional 152 significant peaks in the unit mass resolution mass spectra were quantified, but either could not be identified or most of the signal at that molecular mass was unaccounted for by identifiable species. As phase II of this study, we conducted airborne and ground-based sampling of the emissions from real prescribed fires mostly in the same land management units where the fuels for the lab fires were collected. A broad variety, but smaller number of species (21 trace gas species and PM2.5) was measured on 14 fires in chaparral and oak savanna in the southwestern US, as well as pine forest understory in the southeastern US and Sierra Nevada mountains of California. These extensive field measurements of emission factors (EF) for temperate biomass burning are useful both for modeling and to examine the representativeness of our lab fire EF. The lab/field EF ratio for the pine understory fuels was not statistically different from one, on average. However, our lab EF for smoldering compounds emitted by burning the semi-arid SW fuels should likely be increased by about a factor of 2.7 to better represent field fires. Based on the lab/field comparison, we present a table with emission factors for 365 pyrogenic species (including unidentified species) for 4 broad fuel types: pine understory, semi-arid shrublands, evergreen canopy, and duff. To our knowledge this is the most complete measurement of biomass burning emissions to date and it should enable improved representation of smoke in atmospheric models. The results provide important insights into the nature of smoke. For example, ~35% (range from 16-71%) of the mass of gas-phase NMOC species was attributed to the species that we could not identify. These unidentified species are likely not represented in most models, but some provision should be made for the fact that they will react in the atmosphere. In addition, the total mass of gas-phase NMOC divided by the mass of co-emitted PM2.5 averaged ~2.6 for the main fire types with a range from ~1.8-8.8. About 36-63% of the NMOC were likely semivolatile or of intermediate volatility. Thus, the gas-phase NMOC represent a large reservoir of potential precursors for secondary formation of organic aerosol. For the one fire in organic soil (Alaskan duff) about 28% of the emitted carbon was present as gas-phase NMOC in contrast to the other fuels for which NMOC accounted for only ~1-3% of emitted carbon. 71% of the mass of NMOC emitted by the smoldering duff was un-identified. The duff results highlight the need to learn more about the emissions from smoldering organic soils. The ?NMOC/NOx-as-NO ratio was consistently about ten for the main fire types when accounting for all NMOC, indicating strongly NOx-limited O3 production conditions. Finally, the fuel consumption per unit area was measured on 6 of the 14 prescribed fires and averaged 7.08 2.09 (1?) Mg ha-1.

  14. Comparison of emissions and efficiency of a turbocharged lean-burn natural gas and Hythane-fueled engine

    SciTech Connect (OSTI)

    Larsen, J.F.; Wallace, J.S.

    1997-01-01

    An experiment was conducted to evaluate the potential for reduced exhaust emissions and improved efficiency, by way of lean-burn engine fueling with hydrogen supplemented natural gas (Hythane). The emissions and efficiency of the Hythane fuel (15% hydrogen, 85% natural gas by volume), were compared to the emissions and efficiency of pure natural gas using a turbocharged, spark ignition, 3.1 L, V-6 engine. The feasibility of heavy duty engine fueling with Hythane was assessed through testing conducted at engine speed and load combinations typical of heavy-duty engine operation. Comparison of the efficiency and emissions at MBT spark timing revealed that Hythane fueling of the test engine resulted in consistently lower brake specific energy consumption and emissions of total hydrocarbons (THC), carbon monoxide (CO), and carbon dioxide (CO{sub 2}), at a given equivalence ratio. There was no clear trend with respect to MBT oxides of nitrogen (NO{sub x}) emissions. It was also discovered that an improved NO{sub x}-THC tradeoff resulted when Hythane was used to fuel the test engine. Consequently, Hythane engine operating parameters can be adjusted to achieve a concurrent reduction in NO{sub x} and THC emissions relative to natural gas fueling.

  15. Greenhouse gas emission impacts of electric vehicles under varying driving cycles in various counties and US cities

    SciTech Connect (OSTI)

    Wang, M.Q.; Marr, W.W.

    1994-02-10

    Electric vehicles (EVs) can reduce greenhouse gas emissions, relative to emissions from gasoline-fueled vehicles. However, those studies have not considered all aspects that determine greenhouse gas emissions from both gasoline vehicles (GVs) and EVs. Aspects often overlooked include variations in vehicle trip characteristics, inclusion of all greenhouse gases, and vehicle total fuel cycle. In this paper, we estimate greenhouse gas emission reductions for EVs, including these important aspects. We select four US cities (Boston, Chicago, Los Angeles, and Washington, D.C.) and six countries (Australia, France, Japan, Norway, the United Kingdom, and the United States) and analyze greenhouse emission impacts of EVs in each city or country. We also select six driving cycles developed around the world (i.e., the US federal urban driving cycle, the Economic Community of Europe cycle 15, the Japanese 10-mode cycle, the Los Angeles 92 cycle, the New York City cycle, and the Sydney cycle). Note that we have not analyzed EVs in high-speed driving (e.g., highway driving), where the results would be less favorable to EVs; here, EVs are regarded as urban vehicles only. We choose one specific driving cycle for a given city or country and estimate the energy consumption of four-passenger compact electric and gasoline cars in the given city or country. Finally, we estimate total fuel cycle greenhouse gas emissions of both GVs and EVs by accounting for emissions from primary energy recovery, transportation, and processing; energy product transportation; and powerplant and vehicle operations.

  16. Evaluating greenhouse gas emissions from hydropower complexes on large rivers in Eastern Washington

    SciTech Connect (OSTI)

    Arntzen, Evan V.; Miller, Benjamin L.; O'Toole, Amanda C.; Niehus, Sara E.; Richmond, Marshall C.

    2013-03-15

    Water bodies, such as freshwater lakes, are known to be net emitters of carbon dioxide (CO2), and methane (CH4). In recent years, significant greenhouse gas (GHG) emissions from tropical, boreal, and mid-latitude reservoirs have been reported. At a time when hydropower is increasing worldwide, better understanding of seasonal and regional variation in GHG emissions is needed in order to develop a predictive understanding of such fluxes within man-made impoundments. We examined power-producing dam complexes within xeric temperate locations in the northwestern United States. Sampling environments on the Snake (Lower Monumental Dam Complex) and Columbia Rivers (Priest Rapids Dam Complex) included tributary, mainstem, embayment, forebay, and tailrace areas during winter and summer 2012. At each sampling location, GHG measurement pathways included surface gas flux, degassing as water passed through dams during power generation, ebullition within littoral embayments, and direct sampling of hyporheic pore-water. Measurements were also carried out in a free-flowing reach of the Columbia River to estimate unaltered conditions. Surface flux resulted in very low emissions, with reservoirs acting as a sink for CO2 (up to –262 mg m-2 d-1, which is within the range previously reported for similarly located reservoirs). Surface flux of methane remained below 1 mg CH4 m-2d-1, a value well below fluxes reported previously for temperate reservoirs. Water passing through hydroelectric projects acted as a sink for CO2 during winter and a small source during summer, with mean degassing fluxes of –117 and 4.5 t CO2 d-1, respectively. Degassing of CH4 was minimal, with mean fluxes of 3.1 × 10-6 and –5.6 × 10-4 t CH4 d-1 during winter and summer, respectively. Gas flux due to ebullition was greater in coves located within reservoirs than in coves within the free flowing Hanford Reach–and CH4 flux exceeded that of CO2. Methane emissions varied widely across sampling locations, ranging from 10.5 to 1039 mg CH4 m-2 d-1, with mean fluxes of 324 mg CH4 m-2 d-1in Lower Monumental Dam reservoir and 482 mg CH4 m-2d-1 in the Priest Rapids Dam reservoir. The magnitude of methane flux due to ebullition was unexpectedly high, and falls within the range recently reported for other temperate reservoirs around the world, further suggesting that this methane source should be considered in estimates of global greenhouse gas emissions. Methane flux from sediment pore-water within littoral embayments averaged 4.2 mg m-2 d-1 during winter and 8.1 mg m-2 d-1 during summer, with a peak flux of 19.8 mg m-2d-1 (at the same location where CH4 ebullition was also the greatest). Carbon dioxide flux from sediment pore-water averaged approximately 80 mg m-2d-1 with little difference between winter and summer. Similar to emissions from ebullition, flux from sediment pore-water was higher in reservoirs than in the free flowing reach.

  17. Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils

    SciTech Connect (OSTI)

    Jeremy Semrau; Sung-Woo Lee; Jeongdae Im; Sukhwan Yoon; Michael Barcelona

    2010-09-30

    The overall objective of this project, 'Strategies to Optimize Microbially-Mediated Mitigation of Greenhouse Gas Emissions from Landfill Cover Soils' was to develop effective, efficient, and economic methodologies by which microbial production of nitrous oxide can be minimized while also maximizing microbial consumption of methane in landfill cover soils. A combination of laboratory and field site experiments found that the addition of nitrogen and phenylacetylene stimulated in situ methane oxidation while minimizing nitrous oxide production. Molecular analyses also indicated that methane-oxidizing bacteria may play a significant role in not only removing methane, but in nitrous oxide production as well, although the contribution of ammonia-oxidizing archaea to nitrous oxide production can not be excluded at this time. Future efforts to control both methane and nitrous oxide emissions from landfills as well as from other environments (e.g., agricultural soils) should consider these issues. Finally, a methanotrophic biofiltration system was designed and modeled for the promotion of methanotrophic activity in local methane 'hotspots' such as landfills. Model results as well as economic analyses of these biofilters indicate that the use of methanotrophic biofilters for controlling methane emissions is technically feasible, and provided either the costs of biofilter construction and operation are reduced or the value of CO{sub 2} credits is increased, can also be economically attractive.

  18. Non-Kyoto Radiative Forcing in Long-Run Greenhouse Gas Emissions and Climate Change Scenarios

    SciTech Connect (OSTI)

    Rose, Steven K.; Richels, Richard G.; Smith, Steven J.; Riahi, Keywan; Stefler, Jessica; Van Vuuren, Detlef

    2014-04-27

    Climate policies designed to achieve climate change objectives must consider radiative forcing from the Kyoto greenhouse gas, as well as other forcing constituents, such as aerosols and tropospheric ozone. Net positive forcing leads to global average temperature increases. Modeling of non-Kyoto forcing is a relatively new component of climate management scenarios. Five of the nineteen models in the EMF-27 Study model both Kyoto and non-Kyoto forcing. This paper describes and assesses current non-Kyoto radiative forcing modeling within these integrated assessment models. The study finds negative forcing from aerosols masking significant positive forcing in reference non-climate policy projections. There are however large differences across models in projected non-Kyoto emissions and forcing, with differences stemming from differences in relationships between Kyoto and non-Kyoto emissions and fundamental differences in modeling structure and assumptions. Air pollution and non-Kyoto forcing decline in the climate policy scenarios. However, non-Kyoto forcing appears to be influencing mitigation results, including allowable carbon dioxide emissions, and further evaluation is merited. Overall, there is substantial uncertainty related to non-Kyoto forcing that must be considered.

  19. Emissions and performance evaluation of a dedicated compressed natural gas saturn

    SciTech Connect (OSTI)

    Hodgson, J.W.; Taylor, J.D.

    1997-07-01

    The use of compressed natural gas (CNG) as a transportation fuel has been identified as one strategy that can help ameliorate some problems, which include a growing dependence on imported oil (and all its ramifications) and the persistent contributions that mobile sources make to urban air pollution, associated with the use of conventional petroleum fuels. The attributes and limitations of CNG as a fuel for spark-ignition engines have been presented by others. The attributes are associated with its high octane rating, low cost relative to other alternative fuels, its availability, the absence of running and diurnal evaporative emissions, and its demonstrated potential for producing extremely low exhaust emissions-particularly if the volatile organic compounds (VOCs) emitted are expressed in terms of reactivity adjusted non-methane organic gases (RANMOG). The limitations associated with the use of CNG include its limited refueling infrastructure, the cost of refueling facilities, the cost of on-board fuel storage tanks, and its relatively low energy density. Because one impediment to CNG use is the cost associated with producing a CNG-powered vehicle, a study was initiated at the University of Tennessee under sponsorship by the Saturn Corporation to determine how a CNG vehicle (specifically, a 1991 Saturn SL1) could be engineered so it could be produced with a minimal impact on the production of the base vehicle. The present study was undertaken to further investigate the emissions reduction potential of the Saturn CNG vehicle. In the previous study the role of exhaust gas recirculation was not thoroughly investigated. Those involved in the study agreed that the NO{sub x} levels could be brought down well below California ULEV levels without increasing either the non-methane organic gases or the CO levels.

  20. Contribution of cooperative sector recycling to greenhouse gas emissions reduction: A case study of Ribeiro Pires, Brazil

    SciTech Connect (OSTI)

    King, Megan F.; Gutberlet, Jutta

    2013-12-15

    Highlights: Cooperative recycling achieves environmental, economic and social objectives. We calculate GHG emissions reduction for a recycling cooperative in So Paulo, Brazil. The cooperative merits consideration as a Clean Development Mechanism (CDM) project. A CDM project would enhance the achievements of the recycling cooperative. National and local waste management policies support the recycling cooperative. - Abstract: Solid waste, including municipal waste and its management, is a major challenge for most cities and among the key contributors to climate change. Greenhouse gas emissions can be reduced through recovery and recycling of resources from the municipal solid waste stream. In So Paulo, Brazil, recycling cooperatives play a crucial role in providing recycling services including collection, separation, cleaning, stocking, and sale of recyclable resources. The present research attempts to measure the greenhouse gas emission reductions achieved by the recycling cooperative Cooperpires, as well as highlight its socioeconomic benefits. Methods include participant observation, structured interviews, questionnaire application, and greenhouse gas accounting of recycling using a Clean Development Mechanism methodology. The results show that recycling cooperatives can achieve important energy savings and reductions in greenhouse gas emissions, and suggest there is an opportunity for Cooperpires and other similar recycling groups to participate in the carbon credit market. Based on these findings, the authors created a simple greenhouse gas accounting calculator for recyclers to estimate their emissions reductions.

  1. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2007-09-15

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  2. Electromagnetic vacuum of complex media: Dipole emission versus light propagation, vacuum energy, and local field factors

    SciTech Connect (OSTI)

    Donaire, M.

    2011-02-15

    We offer a unified approach to several phenomena related to the electromagnetic vacuum of a complex medium made of point electric dipoles. To this aim, we apply the linear response theory to the computation of the polarization field propagator and study the spectrum of vacuum fluctuations. The physical distinction among the local density of states which enter the spectra of light propagation, total dipole emission, coherent emission, total vacuum energy, and Schwinger-bulk energy is made clear. Analytical expressions for the spectrum of dipole emission and for the vacuum energy are derived. Their respective relations with the spectrum of external light and with the Schwinger-bulk energy are found. The light spectrum and the Schwinger-bulk energy are determined by the Dyson propagator. The emission spectrum and the total vacuum energy are determined by the polarization propagator. An exact relationship of proportionality between both propagators is found in terms of local field factors. A study of the nature of stimulated emission from a single dipole is carried out. Regarding coherent emission, it contains two components. A direct one which is transferred radiatively and directly from the emitter into the medium and whose spectrum is that of external light. And an indirect one which is radiated by induced dipoles. The induction is mediated by one (and only one) local field factor. Regarding the vacuum energy, we find that in addition to the Schwinger-bulk energy the vacuum energy of an effective medium contains local field contributions proportional to the resonant frequency and to the spectral line width.

  3. Greenhouse Emission Reductions and Natural Gas Vehicles: A Resource Guide on Technology Options and Project Development

    SciTech Connect (OSTI)

    Orestes Anastasia; NAncy Checklick; Vivianne Couts; Julie Doherty; Jette Findsen; Laura Gehlin; Josh Radoff

    2002-09-01

    Accurate and verifiable emission reductions are a function of the degree of transparency and stringency of the protocols employed in documenting project- or program-associated emissions reductions. The purpose of this guide is to provide a background for law and policy makers, urban planners, and project developers working with the many Greenhouse Gas (GHG) emission reduction programs throughout the world to quantify and/or evaluate the GHG impacts of Natural Gas Vehicle (NGVs). In order to evaluate the GHG benefits and/or penalties of NGV projects, it is necessary to first gain a fundamental understanding of the technology employed and the operating characteristics of these vehicles, especially with regard to the manner in which they compare to similar conventional gasoline or diesel vehicles. Therefore, the first two sections of this paper explain the basic technology and functionality of NGVs, but focus on evaluating the models that are currently on the market with their similar conventional counterparts, including characteristics such as cost, performance, efficiency, environmental attributes, and range. Since the increased use of NGVs, along with Alternative Fuel Vehicle (AFVs) in general, represents a public good with many social benefits at the local, national, and global levels, NGVs often receive significant attention in the form of legislative and programmatic support. Some states mandate the use of NGVs, while others provide financial incentives to promote their procurement and use. Furthermore, Federal legislation in the form of tax incentives or procurement requirements can have a significant impact on the NGV market. In order to implement effective legislation or programs, it is vital to have an understanding of the different programs and activities that already exist so that a new project focusing on GHG emission reduction can successfully interact with and build on the experience and lessons learned of those that preceded it. Finally, most programs that deal with passenger vehicles--and with transportation in general--do not address the climate change component explicitly, and thus there are few GHG reduction goals that are included in these programs. Furthermore, there are relatively few protocols that exist for accounting for the GHG emissions reductions that arise from transportation and, specifically, passenger vehicle projects and programs. These accounting procedures and principles gain increased importance when a project developer wishes to document in a credible manner, the GHG reductions that are achieved by a given project or program. Section four of this paper outlined the GHG emissions associated with NGVs, both upstream and downstream, and section five illustrated the methodology, via hypothetical case studies, for measuring these reductions using different types of baselines. Unlike stationary energy combustion, GHG emissions from transportation activities, including NGV projects, come from dispersed sources creating a need for different methodologies for assessing GHG impacts. This resource guide has outlined the necessary context and background for those parties wishing to evaluate projects and develop programs, policies, projects, and legislation aimed at the promotion of NGVs for GHG emission reduction.

  4. Performances of a bent-crystal spectrometer adapted to resonant x-ray emission measurements on gas-phase samples

    SciTech Connect (OSTI)

    Journel, Loiec; El Khoury, Lara; Marin, Thierry; Guillemin, Renaud; Carniato, Stephane; Avila, Antoine; Delaunay, Renaud; Hague, Coryn F.; Simon, Marc

    2009-09-15

    We describe a bent-crystal spectrometer adapted to measure x-ray emission resulting from core-level excitation of gas-phase molecules in the 0.8-8 keV energy range. The spectrometer is based on the Johann principle, and uses a microfocused photon beam to provide high-resolution (resolving power of {approx}7500). A gas cell was designed to hold a high-pressure (300 mbar) sample of gas while maintaining a high vacuum (10{sup -9} mbar) in the chamber. The cell was designed to optimize the counting rate (2000 cts/s at the maximum of the Cl K{alpha} emission line), while minimizing self-absorption. Example of the K{alpha} emission lines of CH{sub 3}Cl molecules is presented to illustrate the capabilities of this new instrument.

  5. Well-to-wheels energy use and greenhouse gas emissions analysis of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Burnham, A.; Wang, M.; Molburg, J.; Rousseau, A.; Energy Systems

    2009-03-31

    Researchers at Argonne National Laboratory expanded the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model and incorporated the fuel economy and electricity use of alternative fuel/vehicle systems simulated by the Powertrain System Analysis Toolkit (PSAT) to conduct a well-to-wheels (WTW) analysis of energy use and greenhouse gas (GHG) emissions of plug-in hybrid electric vehicles (PHEVs). The WTW results were separately calculated for the blended charge-depleting (CD) and charge-sustaining (CS) modes of PHEV operation and then combined by using a weighting factor that represented the CD vehicle-miles-traveled (VMT) share. As indicated by PSAT simulations of the CD operation, grid electricity accounted for a share of the vehicle's total energy use, ranging from 6% for a PHEV 10 to 24% for a PHEV 40, based on CD VMT shares of 23% and 63%, respectively. In addition to the PHEV's fuel economy and type of on-board fuel, the marginal electricity generation mix used to charge the vehicle impacted the WTW results, especially GHG emissions. Three North American Electric Reliability Corporation regions (4, 6, and 13) were selected for this analysis, because they encompassed large metropolitan areas (Illinois, New York, and California, respectively) and provided a significant variation of marginal generation mixes. The WTW results were also reported for the U.S. generation mix and renewable electricity to examine cases of average and clean mixes, respectively. For an all-electric range (AER) between 10 mi and 40 mi, PHEVs that employed petroleum fuels (gasoline and diesel), a blend of 85% ethanol and 15% gasoline (E85), and hydrogen were shown to offer a 40-60%, 70-90%, and more than 90% reduction in petroleum energy use and a 30-60%, 40-80%, and 10-100% reduction in GHG emissions, respectively, relative to an internal combustion engine vehicle that used gasoline. The spread of WTW GHG emissions among the different fuel production technologies and grid generation mixes was wider than the spread of petroleum energy use, mainly due to the diverse fuel production technologies and feedstock sources for the fuels considered in this analysis. The PHEVs offered reductions in petroleum energy use as compared with regular hybrid electric vehicles (HEVs). More petroleum energy savings were realized as the AER increased, except when the marginal grid mix was dominated by oil-fired power generation. Similarly, more GHG emissions reductions were realized at higher AERs, except when the marginal grid generation mix was dominated by oil or coal. Electricity from renewable sources realized the largest reductions in petroleum energy use and GHG emissions for all PHEVs as the AER increased. The PHEVs that employ biomass-based fuels (e.g., biomass-E85 and -hydrogen) may not realize GHG emissions benefits over regular HEVs if the marginal generation mix is dominated by fossil sources. Uncertainties are associated with the adopted PHEV fuel consumption and marginal generation mix simulation results, which impact the WTW results and require further research. More disaggregate marginal generation data within control areas (where the actual dispatching occurs) and an improved dispatch modeling are needed to accurately assess the impact of PHEV electrification. The market penetration of the PHEVs, their total electric load, and their role as complements rather than replacements of regular HEVs are also uncertain. The effects of the number of daily charges, the time of charging, and the charging capacity have not been evaluated in this study. A more robust analysis of the VMT share of the CD operation is also needed.

  6. DOE Launches Natural Gas Infrastructure R&D Program Enhancing Pipeline and Distribution System Operational Efficiency, Reducing Methane Emissions

    Broader source: Energy.gov [DOE]

    Following the White House and the Department of Energy Capstone Methane Stakeholder Roundtable on July 29th, DOE announced a series of actions, partnerships, and stakeholder commitments to help modernize the nation’s natural gas transmission and distribution systems and reduce methane emissions. Through common-sense standards, smart investments, and innovative research, DOE seeks to advance the state of the art in natural gas system performance. DOE’s effort is part of the larger Administration’s Climate Action Plan Interagency Strategy to Reduce Methane Emissions.

  7. Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units

    SciTech Connect (OSTI)

    Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

    2010-10-01

    Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3. Emissions of phenol were also found to be slightly higher than values reported in earlier studies1,2,3. This study can assist in retrospective formaldehyde exposure assessments of THUs where estimates of the occupants indoor formaldehyde exposures are needed.

  8. The Use of Exhaust Gas Recirculation to Optimize Fuel Economy and Minimize Emission in Engines Operating on E85 Fuel

    SciTech Connect (OSTI)

    Wu, Ko-Jen

    2011-12-31

    This report summarizes activities conducted for the project The Use of Exhaust Gas Recirculation to Optimized Fuel Economy and Minimize Emissions in Engines Operating on E85 Fuel under COOPERATIVE AGREEMENT NUMBER DE-FC26-07NT43271, which are as outlined in the STATEMENT OF PROJECT OBJECTIVES (SOPO) dated March 2007 and in the supplemental SOPO dated October 2010. The project objective was to develop and demonstrate an internal combustion engine that is optimized for E85 (85% ethanol and 15% gasoline) fuel operation to achieve substantially improved fuel economy while operating with E85 fuel and that is also production viable in the near- to medium-term. The key engine technology selected for research and development was turbocharging, which is known to improve fuel economy thru downsizing and is in particular capable of exploiting ethanol fuels characteristics of high octane number and high latent heat of vaporization. The engine further integrated synergistic efficiency improving technologies of cooled exhaust gas recirculation (EGR), direct fuel injection and dual continuously variable intake and exhaust cam phasers. On the vehicle level, fuel economy was furthered thru powertrain system optimization by mating a state-of-the-art six-speed automatic transmission to the engine. In order to achieve the projects objective of near- to medium-term production viability, it was essential to develop the engine to be flex-fuel capable of operating with fuels ranging from E0 (0% ethanol and 100% gasoline) to E85 and to use three-way type of catalyst technology for exhaust aftertreatment. Within these scopes, various technologies were developed through systems approach to focus on ways to help accelerate catalyst light-off. Significant amount of development took place during the course of the project within General Motors, LLC. Many prototype flex-fuel engines were designed, built and developed with various hardware configurations selected to achieve the project goals. Several flex-fuel demonstration vehicles were designed and built for carrying out calibration development and final testing to quantify the technology merits. Based on the extensive test results collected from dynamometer and vehicle testing, the fuel economy benefits of cooled EGR from the intended level of turbocharger technology were quantified. When combined with turbo downsizing, the FE benefits are considered large enough for E0 fuel as well as for E85 fuel to warrant further development of the technology beyond the current proof-of-concept level to a level that can meet production driveability quality and durability requirements in order to meet customers expectations. Cold-start cart test results from the emissions segment of the project were positive, confirming the assumption of faster thermal response of turbo exhaust system for emissions reductions for both E0 and E85 fuels. Vehicle emissions test results directionally correlated to the cold-start cart findings. The limited number of test runs did demonstrate the potentials of meeting stringent emission standards, however, they did not comprehend the factors such as hardware variability and long-term durability, 3 which are essential for mass production to satisfy customers expectations. It is therefore recommended, moving forward, durability concerns over turbocharger, EGR system and aftertreatment system, which would likely impact production viability, should be addressed. The data moreover suggested that further FE increase is likely with turbocharger technology advancement.

  9. Control of NO/sub x/ emissions in gas engines using pre-stratified charge - Applications and field experience

    SciTech Connect (OSTI)

    Tice, J.K.; Nalim, M.R.

    1988-01-01

    Since 1983, development of the Pre-Stratified Charge (PSC) means of NO/sub x/ control has focused upon gas fueled industrial engines following a decade of development in automobile-type liquid fueled engines. The early test results indicated exceptional potential and wre previously reported. In the two years following the initial tests of PSC on in-field gas engines, over 140 units have been installed in a wide range of applications including compression, generation, and pumping service. Importantly, the applications have demonstrated PSC effectiveness and longevity where other means of emissions control are either not applicable or ineffective. These include higher digester gas, landfill gas, and sour natural gas (containing substantial H/sub 2/S). This work is concerned with the Field experience in general, but with emphasis on particular applications and specific results.

  10. Battery-Powered Electric and Hybrid Electric Vehicle Projects to Reduce Greenhouse Gas Emissions: A Resource for Project Development

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-07-31

    The transportation sector accounts for a large and growing share of global greenhouse gas (GHG) emissions. Worldwide, motor vehicles emit well over 900 million metric tons of carbon dioxide (CO2) each year, accounting for more than 15 percent of global fossil fuel-derived CO2 emissions.1 In the industrialized world alone, 20-25 percent of GHG emissions come from the transportation sector. The share of transport-related emissions is growing rapidly due to the continued increase in transportation activity.2 In 1950, there were only 70 million cars, trucks, and buses on the worlds roads. By 1994, there were about nine times that number, or 630 million vehicles. Since the early 1970s, the global fleet has been growing at a rate of 16 million vehicles per year. This expansion has been accompanied by a similar growth in fuel consumption.3 If this kind of linear growth continues, by the year 2025 there will be well over one billion vehicles on the worlds roads.4 In a response to the significant growth in transportation-related GHG emissions, governments and policy makers worldwide are considering methods to reverse this trend. However, due to the particular make-up of the transportation sector, regulating and reducing emissions from this sector poses a significant challenge. Unlike stationary fuel combustion, transportation-related emissions come from dispersed sources. Only a few point-source emitters, such as oil/natural gas wells, refineries, or compressor stations, contribute to emissions from the transportation sector. The majority of transport-related emissions come from the millions of vehicles traveling the worlds roads. As a result, successful GHG mitigation policies must find ways to target all of these small, non-point source emitters, either through regulatory means or through various incentive programs. To increase their effectiveness, policies to control emissions from the transportation sector often utilize indirect means to reduce emissions, such as requiring specific technology improvements or an increase in fuel efficiency. Site-specific project activities can also be undertaken to help decrease GHG emissions, although the use of such measures is less common. Sample activities include switching to less GHG-intensive vehicle options, such as electric vehicles (EVs) or hybrid electric vehicles (HEVs). As emissions from transportation activities continue to rise, it will be necessary to promote both types of abatement activities in order to reverse the current emissions path. This Resource Guide focuses on site- and project-specific transportation activities. .

  11. Long-Term Changes in Gas- and Particle-Phase Emissions from On...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon deer07ban-weiss.pdf More Documents & Publications Advanced Collaborative Emissions Study (ACES): Phase 2 Status Report Advanced Collaborative Emissions Study (ACES) DOE's ...

  12. A greenhouse-gas information system monitoring and validating emissions reporting and mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K; Dimotakis, Paul E; Walker, Bruce C

    2011-09-26

    Current GHG-mitigating regimes, whether internationally agreed or self-imposed, rely on the aggregation of self-reported data, with limited checks for consistency and accuracy, for monitoring. As nations commit to more stringent GHG emissions-mitigation actions and as economic rewards or penalties are attached to emission levels, self-reported data will require independent confirmation that they are accurate and reliable, if they are to provide the basis for critical choices and actions that may be required. Supporting emissions-mitigation efforts and agreements, as well as monitoring energy- and fossil-fuel intensive national and global activities would be best achieved by a process of: (1) monitoring of emissions and emission-mitigation actions, based, in part, on, (2) (self-) reporting of pertinent bottom-up inventory data, (3) verification that reported data derive from and are consistent with agreed-upon processes and procedures, and (4) validation that reported emissions and emissions-mitigation action data are correct, based on independent measurements (top-down) derived from a suite of sensors in space, air, land, and, possibly, sea, used to deduce and attribute anthropogenic emissions. These data would be assessed and used to deduce and attribute measured GHG concentrations to anthropogenic emissions, attributed geographically and, to the extent possible, by economic sector. The validation element is needed to provide independent assurance that emissions are in accord with reported values, and should be considered as an important addition to the accepted MRV process, leading to a MRV&V process. This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS. Present monitoring systems would be heavily relied on in any GHGIS implementation at the outset and would likely continue to provide valuable future contributions to GHGIS. However, present monitoring systems were developed to serve science/research purposes. This study concludes that no component or capability presently available is at the level of technological maturity and readiness required for implementation in an operational GHGIS today. However, purpose-designed and -built components could be developed and implemented in support of a future GHGIS. The study concludes that it is possible to develop and provide a capability-driven prototype GHGIS, as part of a Phase-1 effort, within three years from project-funding start, that would make use of and integrate existing sensing and system capabilities. As part of a Phase-2 effort, a requirements-driven, operational GHGIS could be developed, within ten years from project funding start. That schedule is driven by the development and long lead-times for some system components. The two efforts would be focused on different deliverables but could commence concurrently, to save time, if that was deemed desirable. We note that, developing and supporting an operational GHGIS will require a new approach and management, sustained funding and other support, as well as technical advances and development of purpose-built components that meet the requisite specifications. A functioning GHGIS will provide the basis for reasoned choices on how best to respond to rising GHG levels, especially when proposed U.S. actions are compared with or conditioned on the actions of other nations.

  13. H? and [SII] emission from warm Ionized GAS in the Scutum-Centaurus Arm

    SciTech Connect (OSTI)

    Hill, Alex S. [CSIRO Astronomy and Space Science, Marsfield, NSW (Australia); Benjamin, Robert A.; Gostisha, Martin C. [Department of Physics, University of Wisconsin-Whitewater, Whitewater, WI (United States); Haffner, L. Matthew [Department of Astronomy, University of Wisconsin-Madison, Madison, WI (United States); Barger, Kathleen A., E-mail: alex.hill@csiro.au [Department of Physics, University of Notre Dame, South Bend, IN (United States)

    2014-06-01

    We present Wisconsin H-Alpha Mapper [SII] ?6716 and H? spectroscopic maps of the warm ionized medium (WIM) in the Scutum-Centaurus Arm at Galactic longitudes 310 < l < 345. Using extinction-corrected H? intensities (I{sub H?}{sup c}), we measure an exponential scale height of electron density squared in the arm of H{sub n{sub e{sup 2}}}=0.30 kpc (assuming a distance of 3.5 kpc), intermediate between that observed in the inner Galaxy and in the Perseus Arm. The [S II]/H? line ratio is enhanced at large |z| and in sightlines with faint I{sub H?}{sup c}. We find that the [S II]/H? line ratio has a power-law relationship with I{sub H?}{sup c} from a value of ?1.0 at I{sub H?}{sup c}<0.2 R (Rayleighs) to a value of ?0.08 at I{sub H?}{sup c}?100 R. The line ratio is better correlated with H? intensity than with height above the plane, indicating that the physical conditions within the WIM vary systematically with electron density. We argue that the variation of the line ratio with height is a consequence of the decrease of electron density with height. Our results reinforce the well-established picture in which the diffuse H? emission is due primarily to emission from in situ photoionized gas, with scattered light only a minor contributor.

  14. Uncertainties in Life Cycle Greenhouse Gas Emissions from Advanced Biomass Feedstock Logistics Supply Chains in Kansas

    SciTech Connect (OSTI)

    Cafferty, Kara G.; Searcy, Erin M.; Nguyen, Long; Spatari, Sabrina

    2014-11-01

    To meet Energy Independence and Security Act (EISA) cellulosic biofuel mandates, the United States will require an annual domestic supply of about 242 million Mg of biomass by 2022. To improve the feedstock logistics of lignocellulosic biofuels and access available biomass resources from areas with varying yields, commodity systems have been proposed and designed to deliver on-spec biomass feedstocks at preprocessing “depots”, which densify and stabilize the biomass prior to long-distance transport and delivery to centralized biorefineries. The harvesting, preprocessing, and logistics (HPL) of biomass commodity supply chains thus could introduce spatially variable environmental impacts into the biofuel life cycle due to needing to harvest, move, and preprocess biomass from multiple distances that have variable spatial density. This study examines the uncertainty in greenhouse gas (GHG) emissions of corn stover logisticsHPL within a bio-ethanol supply chain in the state of Kansas, where sustainable biomass supply varies spatially. Two scenarios were evaluated each having a different number of depots of varying capacity and location within Kansas relative to a central commodity-receiving biorefinery to test GHG emissions uncertainty. Monte Carlo simulation was used to estimate the spatial uncertainty in the HPL gate-to-gate sequence. The results show that the transport of densified biomass introduces the highest variability and contribution to the carbon footprint of the logistics HPL supply chain (0.2-13 g CO2e/MJ). Moreover, depending upon the biomass availability and its spatial density and surrounding transportation infrastructure (road and rail), logistics HPL processes can increase the variability in life cycle environmental impacts for lignocellulosic biofuels. Within Kansas, life cycle GHG emissions could range from 24 to 41 g CO2e/MJ depending upon the location, size and number of preprocessing depots constructed. However, this range can be minimized through optimizing the siting of preprocessing depots where ample rail infrastructure exists to supply biomass commodity to a regional biorefinery supply system

  15. Optimizing Techology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2004-01-31

    More than 56,000 coal quality data records from five public data sets have been selected for use in this project. These data will be used to create maps showing where coals with low mercury and acid-gas emissions might be found for power plants classified by air-pollution controls. Average coal quality values, calculated for 51,156 commercial coals by U.S. county-of-origin, are listed in the appendix. Coal moisture values are calculated for commercially shipped coal from 163 U.S. counties, where the raw assay data (including mercury and chlorine values) are reported on a dry basis. The calculated moisture values are verified by comparison with observed moisture values in commercial coal. Moisture in commercial U.S. coal shows provincial variation. For example, high volatile C bituminous rank coal from the Interior province has 3% to 4% more moisture than equivalent Rocky Mountain province coal. Mott-Spooner difference values are calculated for 4,957 data records for coals collected from coal mines and exploration drill holes. About 90% of the records have Mott-Spooner difference values within {+-}250 Btu/lb.

  16. Co-benefits of mitigating global greenhouse gas emissions for future air quality and human health

    SciTech Connect (OSTI)

    West, Jason; Smith, Steven J.; Silva, Raquel; Naik, Vaishali; Zhang, Yuqiang; Adelman, Zacariah; Fry, Meridith M.; Anenberg, Susan C.; Horowitz, L.; Lamarque, Jean-Francois

    2013-10-01

    Reducing greenhouse gas (GHG) emissions also influences air quality. We simulate the co-benefits of global GHG reductions on air quality and human health via two mechanisms: a) reducing co-emitted air pollutants, and b) slowing climate change and its effect on air quality. Relative to a reference scenario, global GHG mitigation in the RCP4.5 scenario avoids 0.50.2, 1.30.6, and 2.21.6 million premature deaths in 2030, 2050, and 2100, from changes in fine particulate matter and ozone. Global average marginal co-benefits of avoided mortality are $40-400 (ton CO2)-1, exceeding marginal abatement costs in 2030 and 2050, and within the low range of costs in 2100. East Asian co-benefits are 10-80 times the marginal cost in 2030. These results indicate that transitioning to a low-carbon future might be justified by air quality and health co-benefits.

  17. Russian Policy on Methane Emissions in the Oil and Gas Sector: A Case Study in Opportunities and Challenges in Reducing Short-Lived Forcers

    SciTech Connect (OSTI)

    Evans, Meredydd; Roshchanka, Volha

    2014-08-04

    This paper uses Russian policy in the oil and gas sector as a case study in assessing options and challenges for scaling-up emission reductions. We examine the challenges to achieving large-scale emission reductions, successes that companies have achieved to date, how Russia has sought to influence methane emissions through its environmental fine system, and options for helping companies achieve large-scale emission reductions in the future through simpler and clearer incentives.

  18. Maintaining low exhaust emissions with turbocharged gas engines using a feedback air-fuel ratio control system

    SciTech Connect (OSTI)

    Eckard, D.W.; Serve, J.V.

    1987-10-01

    Maintaining low exhaust emissions on a turbocharged, natural gas engine through the speed and load range requires precise control of the air-fuel ratio. Changes in ambient conditions or fuel heating value will cause the air-fuel ratio to change substantially. By combining air-gas pressure with preturbine temperature control, the air-fuel ratio can be maintained regardless of changes in the ambient conditions or the fuel's heating value. Design conditions and operating results are presented for an air-fuel controller for a turbocharged engine.

  19. Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emission intensities and line ratios from a fast neutral helium beam J-W. Ahn a͒ Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA D. Craig, b͒ G. Fiksel, and D. J. Den Hartog Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA and Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, Madison, Wisconsin 53706, USA J. K. Anderson Department of Physics, University of Wisconsin, Madison, Wisconsin 53706, USA M. G.

  20. Remote sensing of fugitive methane emissions from oil and gas production in North American tight geologic formations

    Energy Savers [EERE]

    Earth's Future Remote sensing of fugitive methane emissions from oil and gas production in North American tight geologic formations Oliver Schneising 1 , John P. Burrows 1,2,3 , Russell R. Dickerson 2 , Michael Buchwitz 1 , Maximilian Reuter 1 , and Heinrich Bovensmann 1 1 Institute of Environmental Physics (IUP), University of Bremen, Bremen, Germany, 2 Department of Atmospheric and Oceanic Science, University of Maryland, College Park, Maryland, USA, 3 NERC Centre for Ecology and Hydrology,

  1. Round 1 Emissions Results from Compressed Natural Gas Vans and Gasoline Controls Operating in the U.S. Federal Fleet

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Round 1 Emissions Results from Compressed Natural Gas Vans and Gasoline Controls Operating in the U.S. Federal Fleet Kenneth J. Kelly, Brent K. Bailey, and Timothy C. Coburn National Renewable Energy Laboratory Leslie Eudy ManTech Environmental Technology, Inc. Peter Lissiuk Environmental Research and Development Corp. Presented at Society for Automotive Engineers International Spring Fuels and Lubricants Meeting Dearborn, MI May 6-8, 1996 The work described here was wholly funded by the U.S.

  2. Well-to-wheels analysis of energy use and greenhouse gas emissions of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Han, J.; Poch, L.; Wang, M.; Vyas, A.; Mahalik, M.; Rousseau, A.

    2010-06-14

    Plug-in hybrid electric vehicles (PHEVs) are being developed for mass production by the automotive industry. PHEVs have been touted for their potential to reduce the US transportation sector's dependence on petroleum and cut greenhouse gas (GHG) emissions by (1) using off-peak excess electric generation capacity and (2) increasing vehicles energy efficiency. A well-to-wheels (WTW) analysis - which examines energy use and emissions from primary energy source through vehicle operation - can help researchers better understand the impact of the upstream mix of electricity generation technologies for PHEV recharging, as well as the powertrain technology and fuel sources for PHEVs. For the WTW analysis, Argonne National Laboratory researchers used the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model developed by Argonne to compare the WTW energy use and GHG emissions associated with various transportation technologies to those associated with PHEVs. Argonne researchers estimated the fuel economy and electricity use of PHEVs and alternative fuel/vehicle systems by using the Powertrain System Analysis Toolkit (PSAT) model. They examined two PHEV designs: the power-split configuration and the series configuration. The first is a parallel hybrid configuration in which the engine and the electric motor are connected to a single mechanical transmission that incorporates a power-split device that allows for parallel power paths - mechanical and electrical - from the engine to the wheels, allowing the engine and the electric motor to share the power during acceleration. In the second configuration, the engine powers a generator, which charges a battery that is used by the electric motor to propel the vehicle; thus, the engine never directly powers the vehicle's transmission. The power-split configuration was adopted for PHEVs with a 10- and 20-mile electric range because they require frequent use of the engine for acceleration and to provide energy when the battery is depleted, while the series configuration was adopted for PHEVs with a 30- and 40-mile electric range because they rely mostly on electrical power for propulsion. Argonne researchers calculated the equivalent on-road (real-world) fuel economy on the basis of U.S. Environmental Protection Agency miles per gallon (mpg)-based formulas. The reduction in fuel economy attributable to the on-road adjustment formula was capped at 30% for advanced vehicle systems (e.g., PHEVs, fuel cell vehicles [FCVs], hybrid electric vehicles [HEVs], and battery-powered electric vehicles [BEVs]). Simulations for calendar year 2020 with model year 2015 mid-size vehicles were chosen for this analysis to address the implications of PHEVs within a reasonable timeframe after their likely introduction over the next few years. For the WTW analysis, Argonne assumed a PHEV market penetration of 10% by 2020 in order to examine the impact of significant PHEV loading on the utility power sector. Technological improvement with medium uncertainty for each vehicle was also assumed for the analysis. Argonne employed detailed dispatch models to simulate the electric power systems in four major regions of the US: the New England Independent System Operator, the New York Independent System Operator, the State of Illinois, and the Western Electric Coordinating Council. Argonne also evaluated the US average generation mix and renewable generation of electricity for PHEV and BEV recharging scenarios to show the effects of these generation mixes on PHEV WTW results. Argonne's GREET model was designed to examine the WTW energy use and GHG emissions for PHEVs and BEVs, as well as FCVs, regular HEVs, and conventional gasoline internal combustion engine vehicles (ICEVs). WTW results are reported for charge-depleting (CD) operation of PHEVs under different recharging scenarios. The combined WTW results of CD and charge-sustaining (CS) PHEV operations (using the utility factor method) were also examined and reported. According to the utility factor method, the share of vehicle miles traveled during CD operation is 25% for PHEV10 and 51% for PHEV40. Argonne's WTW analysis of PHEVs revealed that the following factors significantly impact the energy use and GHG emissions results for PHEVs and BEVs compared with baseline gasoline vehicle technologies: (1) the regional electricity generation mix for battery recharging and (2) the adjustment of fuel economy and electricity consumption to reflect real-world driving conditions. Although the analysis predicted the marginal electricity generation mixes for major regions in the United States, these mixes should be evaluated as possible scenarios for recharging PHEVs because significant uncertainties are associated with the assumed market penetration for these vehicles. Thus, the reported WTW results for PHEVs should be directly correlated with the underlying generation mix, rather than with the region linked to that mix.

  3. Emissions

    Office of Scientific and Technical Information (OSTI)

    Emissions of Greenhouse Gases from the Use of Transportation Fuels and Electricity Volume 1: Main Text ::_:_ii_i!!._i_!!!i_!!_!_!i!ii_!).._i!iiii!!_i!i_!!_iii!i!_ii_iii!!_i!i!ii_!i!!_!!!_ii!!_)i!i_i_i!!ii!i!_!!ii!!i_!i_!iii_!!i!i_i!i!!_!ii_i!i._!ii_i!i!_i!_!!!i!!_!_!!_!_!!!!i_!_!!!i_:``.!ii!!_i_i_i!!!_!_!_ii_i_!_i_i_!!i!i!i!!!ii:!i_i!_ii!_!!ii_! ,qh_...dllri" :._m..41W..- ,,mm,m_ - Centerfor TransportationResearch Argonne NationalLaboratory Operated by lhe University of Chicago, under

  4. Measurement and interpretation of threshold stress intensity factors for steels in high-pressure hydrogen gas.

    SciTech Connect (OSTI)

    Nibur, Kevin A.

    2010-11-01

    Threshold stress intensity factors were measured in high-pressure hydrogen gas for a variety of low alloy ferritic steels using both constant crack opening displacement and rising crack opening displacement procedures. The sustained load cracking procedures are generally consistent with those in ASME Article KD-10 of Section VIII Division 3 of the Boiler and Pressure Vessel Code, which was recently published to guide design of high-pressure hydrogen vessels. Three definitions of threshold were established for the two test methods: K{sub THi}* is the maximum applied stress intensity factor for which no crack extension was observed under constant displacement; K{sub THa} is the stress intensity factor at the arrest position for a crack that extended under constant displacement; and K{sub JH} is the stress intensity factor at the onset of crack extension under rising displacement. The apparent crack initiation threshold under constant displacement, K{sub THi}*, and the crack arrest threshold, K{sub THa}, were both found to be non-conservative due to the hydrogen exposure and crack-tip deformation histories associated with typical procedures for sustained-load cracking tests under constant displacement. In contrast, K{sub JH}, which is measured under concurrent rising displacement and hydrogen gas exposure, provides a more conservative hydrogen-assisted fracture threshold that is relevant to structural components in which sub-critical crack extension is driven by internal hydrogen gas pressure.

  5. Measurement and interpretation of threshold stress intensity factors for steels in high-pressure hydrogen gas.

    SciTech Connect (OSTI)

    Dadfarnia, Mohsen; Nibur, Kevin A.; San Marchi, Christopher W.; Sofronis, Petros; Somerday, Brian P.; Foulk, James W., III; Hayden, Gary A.

    2010-07-01

    Threshold stress intensity factors were measured in high-pressure hydrogen gas for a variety of low alloy ferritic steels using both constant crack opening displacement and rising crack opening displacement procedures. The sustained load cracking procedures are generally consistent with those in ASME Article KD-10 of Section VIII Division 3 of the Boiler and Pressure Vessel Code, which was recently published to guide design of high-pressure hydrogen vessels. Three definitions of threshold were established for the two test methods: K{sub THi}* is the maximum applied stress intensity factor for which no crack extension was observed under constant displacement; K{sub THa} is the stress intensity factor at the arrest position for a crack that extended under constant displacement; and K{sub JH} is the stress intensity factor at the onset of crack extension under rising displacement. The apparent crack initiation threshold under constant displacement, K{sub THi}*, and the crack arrest threshold, K{sub THa}, were both found to be non-conservative due to the hydrogen exposure and crack-tip deformation histories associated with typical procedures for sustained-load cracking tests under constant displacement. In contrast, K{sub JH}, which is measured under concurrent rising displacement and hydrogen gas exposure, provides a more conservative hydrogen-assisted fracture threshold that is relevant to structural components in which sub-critical crack extension is driven by internal hydrogen gas pressure.

  6. Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

    SciTech Connect (OSTI)

    Kirby S. Chapman; Amar Patil

    2007-06-30

    Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a reciprocating four stroke cycle engine. The test matrix varied engine load and air-to-fuel ratio at throttle openings of 50% and 100% at equivalence ratios of 1.00 and 0.90 for hydrogen percentages of 10%, 20% and 30% by volume. In addition, tests were performed at 100% throttle opening, with an equivalence ratio of 0.98 and a hydrogen blend of 20% to further investigate CO emission variations. Data analysis indicated that the use of hydrogen/natural gas fuel blend penalizes the engine operation with a 1.5 to 2.0% decrease in torque, but provided up to a 36% reduction in CO, a 30% reduction in NOX, and a 5% increase in brake thermal efficiency. These results concur with previous results published in the open literature. Further reduction in emissions can be obtained by retarding the ignition timing.

  7. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  8. U.S. Natural Gas System Methane Emissions: State of Knowledge from LCAs, Inventories, and Atmospheric Measurements (Presentation)

    SciTech Connect (OSTI)

    Heath, G.

    2014-04-01

    Natural gas (NG) is a potential "bridge fuel" during transition to a decarbonized energy system: It emits less carbon dioxide during combustion than other fossil fuels and can be used in many industries. However, because of the high global warming potential of methane (CH4, the major component of NG), climate benefits from NG use depend on system leakage rates. Some recent estimates of leakage have challenged the benefits of switching from coal to NG, a large near-term greenhouse gas (GHG) reduction opportunity. During this presentation, Garvin will review evidence from multiple perspectives - life cycle assessments (LCAs), inventories and measurements - about NG leakage in the US. Particular attention will be paid to a recent article in Science magazine which reviewed over 20 years of published measurements to better understand what we know about total methane emissions and those from the oil and gas sectors. Scientific and policy implications of the state of knowledge will be discussed.

  9. Well-to-wheels Analysis of Energy Use and Greenhouse Gas Emissions of Hydrogen Produced with Nuclear Energy

    SciTech Connect (OSTI)

    Wu, Ye; Wang, Michael Q.; Vyas, Anant D.; Wade, David C.; Taiwo, Temitope A.

    2004-07-01

    A fuel-cycle model-called the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model-has been developed at Argonne National Laboratory to evaluate well-to-wheels (WTW) energy and emission impacts of motor vehicle technologies fueled with various transportation fuels. The GREET model contains various hydrogen (H{sub 2}) production pathways for fuel-cell vehicles (FCVs) applications. In this effort, the GREET model was expanded to include four nuclear H{sub 2} production pathways: (1) H{sub 2} production at refueling stations via electrolysis using Light Water Reactor (LWR)-generated electricity; (2) H{sub 2} production in central plants via thermo-chemical water cracking using steam from High Temperature Gas cooled Reactor (HTGR); (3) H{sub 2} production in central plants via high-temperature electrolysis using HTGR-generated electricity and steam; and (4) H{sub 2} production at refueling stations via electrolysis using HTGR-generated electricity The WTW analysis of these four options include these stages: uranium ore mining and milling; uranium ore transportation; uranium conversion; uranium enrichment; uranium fuel fabrication; uranium fuel transportation; electricity or H{sub 2} production in nuclear power plants; H{sub 2} transportation; H{sub 2} compression; and H{sub 2} FCVs operation. Due to large differences in electricity requirements for uranium fuel enrichment between gas diffusion and centrifuge technologies, two scenarios were designed for uranium enrichment: (1) 55% of fuel enriched through gaseous diffusion technology and 45% through centrifuge technology (the current technology split for U.S. civilian nuclear power plants); and (2) 100% fuel enrichment using the centrifuge technology (a future trend). Our well-to-pump (WTP) results show that significant reductions in fossil energy use and greenhouse gas (GHG) emissions are achieved by nuclear-based H{sub 2} compared to natural gas-based H{sub 2} production via steam methane reforming for a unit of H{sub 2} delivered at refueling stations. In particular, 73-98% of GHG emissions and 81- 99% of fossil energy use are reduced by nuclear-based H{sub 2} relative to natural gas-based H{sub 2}, depending on the uranium enrichment technology and type of nuclear reactor used. When H{sub 2} is applied to FCVs, the WTW results also show large benefit in reducing fossil energy use and GHG emissions. (authors)

  10. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, Michael Dean; Schlager, Richard John; Ebner, Timothy George; Stewart, Robin Michele; Bustard, Cynthia Jean

    1999-01-01

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency.

  11. Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-11-01

    The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that makes great strides in clarifying inconsistent and conflicting GHG emission estimates in the published literature while providing more precise estimates of GHG emissions from utility-scale CSP systems.

  12. Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2009 … Main Text

    National Nuclear Security Administration (NNSA)

    xiii Table 4-82: HCFC-22 Production (Gg) .................................................................................................................. 4-61 Table 4-83: Quantitative Uncertainty Estimates for HFC-23 Emissions from HCFC-22 Production (Tg CO 2 Eq. and Percent) .................................................................................................................................................................... 4-62 Table 4-84: Emissions of HFCs and PFCs from ODS

  13. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  14. Energy and greenhouse gas emission effects of corn and cellulosic ethanol with technology improvements and land use changes.

    SciTech Connect (OSTI)

    Wang, M.; Han, J.; Haq, Z; Tyner, .W.; Wu, M.; Elgowainy, A.

    2011-05-01

    Use of ethanol as a transportation fuel in the United States has grown from 76 dam{sup 3} in 1980 to over 40.1 hm{sup 3} in 2009 - and virtually all of it has been produced from corn. It has been debated whether using corn ethanol results in any energy and greenhouse gas benefits. This issue has been especially critical in the past several years, when indirect effects, such as indirect land use changes, associated with U.S. corn ethanol production are considered in evaluation. In the past three years, modeling of direct and indirect land use changes related to the production of corn ethanol has advanced significantly. Meanwhile, technology improvements in key stages of the ethanol life cycle (such as corn farming and ethanol production) have been made. With updated simulation results of direct and indirect land use changes and observed technology improvements in the past several years, we conducted a life-cycle analysis of ethanol and show that at present and in the near future, using corn ethanol reduces greenhouse gas emission by more than 20%, relative to those of petroleum gasoline. On the other hand, second-generation ethanol could achieve much higher reductions in greenhouse gas emissions. In a broader sense, sound evaluation of U.S. biofuel policies should account for both unanticipated consequences and technology potentials. We maintain that the usefulness of such evaluations is to provide insight into how to prevent unanticipated consequences and how to promote efficient technologies with policy intervention.

  15. The potential for biomass to mitigate greenhouse gas emissions in the Northeastern US. Northeast Regional Biomass Program

    SciTech Connect (OSTI)

    Bernow, S.S.; Gurney, K.; Prince, G.; Cyr, M.

    1992-04-01

    This study, for the Northeast Regional Biomass Program (NRBP) of the Coalition of Northeast Governors (CONEG), evaluates the potential for local, state and regional biomass policies to contribute to an overall energy/biomass strategy for the reduction of greenhouse gas releases in the Northeastern United States. Biomass is a conditionally renewable resource that can play a dual role: by reducing emissions of greenhouse gases in meeting our energy needs; and by removing carbon from the atmosphere and sequestering it in standing biomass stocks and long-lived products. In this study we examine the contribution of biomass to the energy system in the Northeast and to the region`s net releases of carbon dioxide and methane, and project these releases over three decades, given a continuation of current trends and policies. We then compare this Reference Case with three alternative scenarios, assuming successively more aggressive efforts to reduce greenhouse gas emissions through strategic implementation of energy efficiency and biomass resources. Finally, we identify and examine policy options for expanding the role of biomass in the region`s energy and greenhouse gas mitigation strategies.

  16. Black Carbon Concentrations and Diesel Vehicle Emission FactorsDerived from Coefficient of Haze Measurements in California:1967-2003

    SciTech Connect (OSTI)

    Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.

    2007-10-01

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population's exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of {approx}3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  17. Black Carbon Concentrations and Diesel Vehicle Emission Factors Derived from Coefficient of Haze Measurements in California: 1967-2003

    SciTech Connect (OSTI)

    Tast, CynthiaL; Kirchstetter, Thomas W.; Aguiar, Jeffery; Tonse, Shaheen; Novakov, T.; Fairley, David

    2007-11-09

    We have derived ambient black carbon (BC) concentrations and estimated emission factors for on-road diesel vehicles from archived Coefficient of Haze (COH) data that was routinely collected beginning in 1967 at 11 locations in the San Francisco Bay Area. COH values are a measure of the attenuation of light by particles collected on a white filter, and available data indicate they are proportional to BC concentrations measured using the conventional aethalometer. Monthly averaged BC concentrations are up to five times greater in winter than summer, and, consequently, so is the population?s exposure to BC. The seasonal cycle in BC concentrations is similar for all Bay Area sites, most likely due to area-wide decreased pollutant dispersion during wintertime. A strong weekly cycle is also evident, with weekend concentrations significantly lower than weekday concentrations, consistent with decreased diesel traffic volume on weekends. The weekly cycle suggests that, in the Bay Area, diesel vehicle emissions are the dominant source of BC aerosol. Despite the continuous increase in diesel fuel consumption in California, annual Bay Area average BC concentrations decreased by a factor of ~;;3 from the late 1960s to the early 2000s. Based on estimated annual BC concentrations, on-road diesel fuel consumption, and recent measurements of on-road diesel vehicle BC emissions, diesel BC emission factors decreased by an order of magnitude over the study period. Reductions in the BC emission factor reflect improved engine technology, emission controls and changes in diesel fuel composition. A new BC monitoring network is needed to continue tracking ambient BC trends because the network of COH monitors has recently been retired.

  18. Greenhouse Gas Emissions from U.S. Hydropower Reservoirs: FY2011 Annual Progress Report

    SciTech Connect (OSTI)

    Stewart, Arthur J; Mosher, Jennifer J; Mulholland, Patrick J; Fortner, Allison M; Phillips, Jana Randolph; Bevelhimer, Mark S

    2012-05-01

    The primary objective of this study is to quantify the net emissions of key greenhouse gases (GHG) - notably, CO{sub 2} and CH{sub 4} - from hydropower reservoirs in moist temperate areas within the U.S. The rationale for this objective is straightforward: if net emissions of GHG can be determined, it would be possible to directly compare hydropower to other power-producing methods on a carbon-emissions basis. Studies of GHG emissions from hydropower reservoirs elsewhere suggest that net emissions can be moderately high in tropical areas. In such areas, warm temperatures and relatively high supply rates of labile organic matter can encourage high rates of decomposition, which (depending upon local conditions) can result in elevated releases of CO{sub 2} and CH{sub 4}. CO{sub 2} and CH{sub 4} emissions also tend to be higher for younger reservoirs than for older reservoirs, because vegetation and labile soil organic matter that is inundated when a reservoir is created can continue to decompose for several years (Galy-Lacaux et al. 1997, Barros et al. 2011). Water bodies located in climatically cooler areas, such as in boreal forests, could be expected to have lower net emissions of CO{sub 2} and CH{sub 4} because their organic carbon supplies tend to be relatively recalcitrant to microbial action and because cooler water temperatures are less conducive to decomposition.

  19. Emission assessment at the Burj Hammoud inactive municipal landfill: Viability of landfill gas recovery under the clean development mechanism

    SciTech Connect (OSTI)

    El-Fadel, Mutasem; Abi-Esber, Layale; Salhab, Samer

    2012-11-15

    Highlights: Black-Right-Pointing-Pointer LFG emissions are measured at an abandoned landfill with highly organic waste. Black-Right-Pointing-Pointer Mean headspace and vent emissions are 0.240 and 0.074 l CH{sub 4}/m{sup 2} hr, respectively. Black-Right-Pointing-Pointer At sites with high food waste content, LFG generation drops rapidly after site closure. Black-Right-Pointing-Pointer The viability of LFG recovery for CDMs in developing countries is doubtful. - Abstract: This paper examines landfill gas (LFG) emissions at a large inactive waste disposal site to evaluate the viability of investment in LFG recovery through the clean development mechanism (CDM) initiative. For this purpose, field measurements of LFG emissions were conducted and the data were processed by geospatial interpolation to estimate an equivalent site emission rate which was used to calibrate and apply two LFG prediction models to forecast LFG emissions at the site. The mean CH{sub 4} flux values calculated through tessellation, inverse distance weighing and kriging were 0.188 {+-} 0.014, 0.224 {+-} 0.012 and 0.237 {+-} 0.008 l CH{sub 4}/m{sup 2} hr, respectively, compared to an arithmetic mean of 0.24 l/m{sup 2} hr. The flux values are within the reported range for closed landfills (0.06-0.89 l/m{sup 2} hr), and lower than the reported range for active landfills (0.42-2.46 l/m{sup 2} hr). Simulation results matched field measurements for low methane generation potential (L{sub 0}) values in the range of 19.8-102.6 m{sup 3}/ton of waste. LFG generation dropped rapidly to half its peak level only 4 yrs after landfill closure limiting the sustainability of LFG recovery systems in similar contexts and raising into doubt promoted CDM initiatives for similar waste.

  20. California Greenhouse Gas Emissions Standards for Light-Duty Vehicles (Update) (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    The state of California was given authority under the Clean Air Act Amendments of 1990 (CAAA90) to set emissions standards for light-duty vehicles that exceed federal standards. In addition, other states that do not comply with the National Ambient Air Quality Standards (NAAQS) set by the Environmental Protection Agency under CAAA90 were given the option to adopt Californias light-duty vehicle emissions standards in order to achieve air quality compliance. CAAA90 specifically identifies hydrocarbon, carbon monoxide, and NOx as vehicle-related air pollutants that can be regulated. California has led the nation in developing stricter vehicle emissions standards, and other states have adopted the California standards.

  1. Method and apparatus for decreased undesired particle emissions in gas streams

    DOE Patents [OSTI]

    Durham, M.D.; Schlager, R.J.; Ebner, T.G.; Stewart, R.M.; Bustard, C.J.

    1999-04-13

    The present invention discloses a process for removing undesired particles from a gas stream including the steps of contacting a composition containing an adhesive with the gas stream; collecting the undesired particles and adhesive on a collection surface to form an aggregate comprising the adhesive and undesired particles on the collection surface; and removing the agglomerate from the collection zone. The composition may then be atomized and injected into the gas stream. The composition may include a liquid that vaporizes in the gas stream. After the liquid vaporizes, adhesive particles are entrained in the gas stream. The process may be applied to electrostatic precipitators and filtration systems to improve undesired particle collection efficiency. 5 figs.

  2. Search for particle emission from a gas-loaded deuterium-palladium system in the alpha-beta phase

    SciTech Connect (OSTI)

    Nicholson, J.P.

    1996-12-01

    Neutron and proton emission due to possible solid state fusion events is monitored from a palladium sample loaded with deuterium gas to atomic fractions up to 0.7. Most of the experimental runs show no detectable activity above background rates, indicating a fusion rate <2.7x10{sup -22} s{sup -1}/deuterium-deuterium (D-D) pair. Two brief excursions by the proton counter might indicate a temporary rate of 3.5x10{sup -21} s{sup -1}/D-D pair. 25 refs., 1 fig.

  3. Causal Factors of Weld Porosity in Gas Tungsten Arc Welding of Powder Metallurgy Produced Titanium Alloys

    SciTech Connect (OSTI)

    Muth, Thomas R; Yamamoto, Yukinori; Frederick, David Alan; Contescu, Cristian I; Chen, Wei; Lim, Yong Chae; Peter, William H; Feng, Zhili

    2013-01-01

    ORNL undertook an investigation using gas tungsten arc (GTA) welding on consolidated powder metallurgy (PM) titanium (Ti) plate, to identify the causal factors behind observed porosity in fusion welding. Tramp element compounds of sodium and magnesium, residual from the metallothermic reduction of titanium chloride used to produce the titanium, were remnant in the starting powder and were identified as gas forming species. PM-titanium made from revert scrap where sodium and magnesium were absent, showed fusion weld porosity, although to a lesser degree. We show that porosity was attributable to hydrogen from adsorbed water on the surface of the powders prior to consolidation. The removal / minimization of both adsorbed water on the surface of titanium powder and the residues from the reduction process prior to consolidation of titanium powders, are critical to achieve equivalent fusion welding success similar to that seen in wrought titanium produced via the Kroll process.

  4. Carbon emissions and sequestration in forests: Case studies from seven developing countries. Volume 2, Greenhouse gas emissions from deforestration in the Brazilian Amazon

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J.; Fearnside, P.M.

    1992-08-01

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as ``committed carbon,`` or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil`s use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  5. An investigation of gas separation membranes for reduction of thermal treatment emissions

    SciTech Connect (OSTI)

    Stull, D.M.; Logsdon, B.W.; Pellegrino, J.J.

    1994-05-16

    Gas permeable membranes were evaluated for possible use as air pollution control devices on a fluidized bed catalytic incineration unit. The unit is a candidate technology for treatment of certain mixed hazardous and radioactive wastes at the Rocky Flats Plant. Cellulose acetate and polyimide membranes were tested to determine the permeance of typical off-gas components such as carbon dioxide, nitrogen, and oxygen. Multi-component permeation studies included gas mixtures containing light hydrocarbons. Experiments were also conducted to discover information about potential membrane degradation in the presence of organic compounds.

  6. Kalman-filtered compressive sensing for high resolution estimation of anthropogenic greenhouse gas emissions from sparse measurements.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-09-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. The limited nature of the measured data leads to a severely-underdetermined estimation problem. If the estimation is performed at fine spatial resolutions, it can also be computationally expensive. In order to enable such estimations, advances are needed in the spatial representation of ffCO2 emissions, scalable inversion algorithms and the identification of observables to measure. To that end, we investigate parsimonious spatial parameterizations of ffCO2 emissions which can be used in atmospheric inversions. We devise and test three random field models, based on wavelets, Gaussian kernels and covariance structures derived from easily-observed proxies of human activity. In doing so, we constructed a novel inversion algorithm, based on compressive sensing and sparse reconstruction, to perform the estimation. We also address scalable ensemble Kalman filters as an inversion mechanism and quantify the impact of Gaussian assumptions inherent in them. We find that the assumption does not impact the estimates of mean ffCO2 source strengths appreciably, but a comparison with Markov chain Monte Carlo estimates show significant differences in the variance of the source strengths. Finally, we study if the very different spatial natures of biogenic and ffCO2 emissions can be used to estimate them, in a disaggregated fashion, solely from CO2 concentration measurements, without extra information from products of incomplete combustion e.g., CO. We find that this is possible during the winter months, though the errors can be as large as 50%.

  7. Effects of the Built Environment on Transportation: Energy Use, Greenhouse Gas Emissions, and Other Factors

    Broader source: Energy.gov [DOE]

    Urban form has evolved in response to a variety of demographic, social, economic, technological, and policy drivers. While direct authority over land use resides primarily at the local level, the federal government's transportation and housing policies have indirectly influenced the built environment.Local governments are increasingly implementing smart growth policies in attempts to manage growth and land use change, and constrain sprawl, with governments at higher levels supporting initiatives through funding, technical assistance, and incentives. This study examines the energy implications of the built environment, and the role the federal government could play.

  8. State-level Greenhouse Gas Emission Factors for Electricity Generation, Updated 2002

    Reports and Publications (EIA)

    2002-01-01

    This report documents the preparation of updated state-level electricity coefficients for carbon dioxide (CO ), methane (CH ), and nitrous oxide (NO), which represent a three-year weighted average for 1998-2000.

  9. Optimizing Technology to Reduce Mercury and Acid Gas Emissions from Electric Power Plants

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-01-31

    Revised maps and associated data show potential mercury, sulfur, and chlorine emissions for U.S. coal by county of origin. Existing coal mining and coal washing practices result in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Selection of low-mercury coal is a good mercury control option for plants having hot-side ESP, cold-side ESP, or hot-side ESP/FGD emission controls. Chlorine content is more important for plants having cold-side ESP/FGD or SDA/FF controls; optimum net mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions.

  10. Life Cycle Greenhouse Gas Emissions of Thin-film Photovoltaic Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  11. Life Cycle Greenhouse Gas Emissions of Utility-Scale Wind Power: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  12. Life Cycle Greenhouse Gas Emissions of Crystalline Silicon Photovoltaic Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  13. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  14. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  15. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  16. Natural Gas Variability In California: Environmental Impacts And Device Performance Combustion Modeling of Pollutant Emissions From a Residential Cooking Range

    SciTech Connect (OSTI)

    Tonse, S. R.; Singer, B. C.

    2011-07-01

    As part of a larger study of liquefied natural gas impacts on device performance and pollutant emissions for existing equipment in California, this report describes a cmoputer modeling study of a partially premixed flame issueing from a single cooktop burner port. The model consisted of a reactive computational fluid dynamics three-dimensional spatial grid and a 71-species chemical mechanism with propane combustion capability. Simulations were conducted with a simplified fuel mixture containing methane, ethane, and propane in proportions that yield properties similar to fuels distributed throughout much of California now and in recent years (baseline fuel), as well as with two variations of simulated liquefied natural gas blends. A variety of simulations were conducted with baseline fuel to explore the effect of several key parameters on pollutant formation and other flame characteristics. Simulations started with fuel and air issuing through the burner port, igniting, and continuing until the flame was steady with time. Conditions at this point were analyzed to understand fuel, secondary air and reaction product flows, regions of pollutant formation, and exhaust concentrations of carbon monoxide, nitric oxide and formaldehyde. A sensitivity study was conducted, varying the inflow parameters of this baseline gs about real-world operating conditions. Flame properties responded as expected from reactive flow theory. In the simulation, carbon monoxide levels were influenced more by the mixture's inflow velocity than by the gas-to-air ratio in the mixture issuing from the inflow port. Additional simulations were executed at two inflow conditions - high heat release and medium heat release - to examine the impact of replacing the baseline gas with two mixtures representative of liquefied natural gas. Flame properties and pollutant generation rates were very similar among the three fuel mixtures.

  17. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  18. Building Commissioning: A Golden Opportunity for Reducing Energy Costs and Greenhouse-gas Emissions

    SciTech Connect (OSTI)

    Mills, Evan

    2009-07-16

    The aim of commissioning new buildings is to ensure that they deliver, if not exceed, the performance and energy savings promised by their design. When applied to existing buildings, commissioning identifies the almost inevitable 'drift' from where things should be and puts the building back on course. In both contexts, commissioning is a systematic, forensic approach to quality assurance, rather than a technology per se. Although commissioning has earned increased recognition in recent years - even a toehold in Wikipedia - it remains an enigmatic practice whose visibility severely lags its potential. Over the past decade, Lawrence Berkeley National Laboratory has built the world's largest compilation and meta-analysis of commissioning experience in commercial buildings. Since our last report (Mills et al. 2004) the database has grown from 224 to 643 buildings (all located in the United States, and spanning 26 states), from 30 to 100 million square feet of floorspace, and from $17 million to $43 million in commissioning expenditures. The recorded cases of new-construction commissioning took place in buildings representing $2.2 billion in total construction costs (up from 1.5 billion). The work of many more commissioning providers (18 versus 37) is represented in this study, as is more evidence of energy and peak-power savings as well as cost-effectiveness. We now translate these impacts into avoided greenhouse gases and provide new indicators of cost-effectiveness. We also draw attention to the specific challenges and opportunities for high-tech facilities such as labs, cleanrooms, data centers, and healthcare facilities. The results are compelling. We developed an array of benchmarks for characterizing project performance and cost-effectiveness. The median normalized cost to deliver commissioning was $0.30/ft2 for existing buildings and $1.16/ft2 for new construction (or 0.4% of the overall construction cost). The commissioning projects for which data are available revealed over 10,000 energy-related problems, resulting in 16% median whole-building energy savings in existing buildings and 13% in new construction, with payback time of 1.1 years and 4.2 years, respectively. In terms of other cost-benefit indicators, median benefit-cost ratios of 4.5 and 1.1, and cash-on-cash returns of 91% and 23% were attained for existing and new buildings, respectively. High-tech buildings were particularly cost-effective, and saved higher amounts of energy due to their energy-intensiveness. Projects with a comprehensive approach to commissioning attained nearly twice the overall median level of savings and five-times the savings of the least-thorough projects. It is noteworthy that virtually all existing building projects were cost-effective by each metric (0.4 years for the upper quartile and 2.4 years for the lower quartile), as were the majority of new-construction projects (1.5 years and 10.8 years, respectively). We also found high cost-effectiveness for each specific measure for which we have data. Contrary to a common perception, cost-effectiveness is often achieved even in smaller buildings. Thanks to energy savings valued more than the cost of the commissioning process, associated reductions in greenhouse gas emissions come at 'negative' cost. In fact, the median cost of conserved carbon is negative - -$110 per tonne for existing buildings and -$25/tonne for new construction - as compared with market prices for carbon trading and offsets in the +$10 to +$30/tonne range. Further enhancing the value of commissioning, its non-energy benefits surpass those of most other energy-management practices. Significant first-cost savings (e.g., through right-sizing of heating and cooling equipment) routinely offset at least a portion of commissioning costs - fully in some cases. When accounting for these benefits, the net median commissioning project cost was reduced by 49% on average, while in many cases they exceeded the direct value of the energy savings. Commissioning also improves worker comfort, mitigates indoor air quality problems

  19. Evaluation of Efficiency Activities in the Industrial Sector Undertaken in Response to Greenhouse Gas Emission Reduction Targets

    SciTech Connect (OSTI)

    Price, Lynn; de la Rue du Can, Stephane; Lu, Hongyou; Horvath, Arpad

    2010-05-21

    The 2006 California Global Warming Solutions Act calls for reducing greenhouse gas (GHG) emissions to 1990 levels by 2020. Meeting this target will require action from all sectors of the California economy, including industry. The industrial sector consumes 25% of the energy used and emits 28% of the carbon dioxide (CO{sub 2}) produced in the state. Many countries around the world have national-level GHG reduction or energy-efficiency targets, and comprehensive programs focused on implementation of energy efficiency and GHG emissions mitigation measures in the industrial sector are essential for achieving their goals. A combination of targets and industry-focused supporting programs has led to significant investments in energy efficiency as well as reductions in GHG emissions within the industrial sectors in these countries. This project has identified program and policies that have effectively targeted the industrial sector in other countries to achieve real energy and CO{sub 2} savings. Programs in Ireland, France, The Netherlands, Denmark, and the UK were chosen for detailed review. Based on the international experience documented in this report, it is recommended that companies in California's industrial sector be engaged in a program to provide them with support to meet the requirements of AB32, The Global Warming Solution Act. As shown in this review, structured programs that engage industry, require members to evaluate their potential efficiency measures, plan how to meet efficiency or emissions reduction goals, and provide support in achieving the goals, can be quite effective at assisting companies to achieve energy efficiency levels beyond those that can be expected to be achieved autonomously.

  20. Size-Resolved Particle Number and Volume Emission Factors for On-Road Gasoline and Diesel Motor Vehicles

    SciTech Connect (OSTI)

    Ban-Weiss, George A.; Lunden, Melissa M.; Kirchstetter, Thomas W.; Harley, Robert A.

    2009-04-10

    Average particle number concentrations and size distributions from {approx}61,000 light-duty (LD) vehicles and {approx}2500 medium-duty (MD) and heavy-duty (HD) trucks were measured during the summer of 2006 in a San Francisco Bay area traffic tunnel. One of the traffic bores contained only LD vehicles, and the other contained mixed traffic, allowing pollutants to be apportioned between LD vehicles and diesel trucks. Particle number emission factors (particle diameter D{sub p} > 3 nm) were found to be (3.9 {+-} 1.4) x 10{sup 14} and (3.3 {+-} 1.3) x 10{sup 15} kg{sup -1} fuel burned for LD vehicles and diesel trucks, respectively. Size distribution measurements showed that diesel trucks emitted at least an order of magnitude more particles for all measured sizes (10 < D{sub p} < 290 nm) per unit mass of fuel burned. The relative importance of LD vehicles as a source of particles increased as D{sub p} decreased. Comparing the results from this study to previous measurements at the same site showed that particle number emission factors have decreased for both LD vehicles and diesel trucks since 1997. Integrating size distributions with a volume weighting showed that diesel trucks emitted 28 {+-} 11 times more particles by volume than LD vehicles, consistent with the diesel/gasoline emission factor ratio for PM{sub 2.5} mass measured using gravimetric analysis of Teflon filters, reported in a companion paper.

  1. Estimating U.S. Methane Emissions from the Natural Gas Supply...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is to develop the empirical foundation for activity factor uncertainty estimation. 6. Transparency and credibility of inventory estimates can be improved by bolstering...

  2. Emissions from US waste collection vehicles

    SciTech Connect (OSTI)

    Maimoun, Mousa A.; Reinhart, Debra R.; Gammoh, Fatina T.; McCauley Bush, Pamela

    2013-05-15

    Highlights: ? Life-cycle emissions for alternative fuel technologies. ? Fuel consumption of alternative fuels for waste collection vehicles. ? Actual driving cycle of waste collection vehicles. ? Diesel-fueled waste collection vehicle emissions. - Abstract: This research is an in-depth environmental analysis of potential alternative fuel technologies for waste collection vehicles. Life-cycle emissions, cost, fuel and energy consumption were evaluated for a wide range of fossil and bio-fuel technologies. Emission factors were calculated for a typical waste collection driving cycle as well as constant speed. In brief, natural gas waste collection vehicles (compressed and liquid) fueled with North-American natural gas had 610% higher well-to-wheel (WTW) greenhouse gas (GHG) emissions relative to diesel-fueled vehicles; however the pump-to-wheel (PTW) GHG emissions of natural gas waste collection vehicles averaged 6% less than diesel-fueled vehicles. Landfill gas had about 80% lower WTW GHG emissions relative to diesel. Biodiesel waste collection vehicles had between 12% and 75% lower WTW GHG emissions relative to diesel depending on the fuel source and the blend. In 2011, natural gas waste collection vehicles had the lowest fuel cost per collection vehicle kilometer travel. Finally, the actual driving cycle of waste collection vehicles consists of repetitive stops and starts during waste collection; this generates more emissions than constant speed driving.

  3. Additional Development of a Dedicated Liquefied Petroleum Gas (LPG) Ultra Low Emissions Vehicle (ULEV)

    SciTech Connect (OSTI)

    IMPCO Technologies

    1998-10-28

    This report describes the last in a series of three projects designed to develop a commercially competitive LPG light-duty passenger car that meets California ULEV standards and corporate average fuel economy (CAFE) energy efficiency guidelines for such a vehicle. In this project, IMPCO upgraded the vehicle's LPG vapor fuel injection system and performed emissions testing. The vehicle met the 1998 ULEV standards successfully, demonstrating the feasibility of meeting ULEV standards with a dedicated LPG vehicle.

  4. Application of holographic neural networks for flue gas emissions prediction in the Burnaby incinerator

    SciTech Connect (OSTI)

    Zheng, L.; Dockrill, P.; Clements, B.

    1997-12-31

    This article describes the development of a parametric prediction system (PPS) for various emission species at the Burnaby incinerator. The continuous emissions monitoring system at the Burnaby incinerator is shared between three boilers and therefore actual results are only available 5 minutes out of every 15 minutes. The PPS was developed to fill in data for the 10 minutes when the Continuous Emission Monitor (CEM) is measuring the other boilers. It bases its prediction on the last few actual readings taken and parametrically predicts CO, SO2 and NOx. The Burnaby Incinerator is located in the commercial/industrial area of South Burnaby, British Columbia. It consists of three separate lines, each burning ten tonnes of garbage per hour and producing about three tonnes of steam for every tonne of garbage burned. The air pollution control system first cools the combustion products with water injection and then scrubs them with very fine hydrated lime. Carbon is added to the lime to enhance the scrubbing of the combustion products. The CEM monitors the levels of oxygen, carbon monoxide, nitrogen oxides, sulphur dioxide and opacity. In 1996, an expert system was installed on one of boilers at the Burnaby Incinerator plant to determine if it could improve the plant=s operations and reduce overall emission. As part of the expert system, the PPS was developed. Holographic Neural Technology (HNeT), developed by AND Corporation of Toronto, Ontario, is a novel neural network technology using complex numbers in its architecture. Compared to the traditional neural networks, HNeT has some significant advantage. It is more resilient against converging on local minima; is faster training and executing; less prone to over fitting; and, in most cases, has significantly lower error. Selection of independent variabs, training set preparation, testing neural nets and other related issue will be discussed.

  5. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Schlosser, Courtney Adam; Walter-Anthony, Katey; Zhuang, Qianlai; Melillo, Jerry

    2013-04-26

    Our overall goal was to quantify the potential for threshold changes in natural emission rates of trace gases, particularly methane and carbon dioxide, from pan-arctic terrestrial systems under the spectrum of anthropogenically forced climate warming, and the extent to which these emissions provide a strong feedback mechanism to global climate warming. This goal is motivated under the premise that polar amplification of global climate warming will induce widespread thaw and degradation of the permafrost, and would thus cause substantial changes in the extent of wetlands and lakes, especially thermokarst (thaw) lakes, over the Arctic. Through a coordinated effort of field measurements, model development, and numerical experimentation with an integrated assessment model framework, we have investigated the following hypothesis: There exists a climate-warming threshold beyond which permafrost degradation becomes widespread and thus instigates strong and/or sharp increases in methane emissions (via thermokarst lakes and wetland expansion). These would outweigh any increased uptake of carbon (e.g. from peatlands) and would result in a strong, positive feedback to global climate warming.

  6. MOBILE4. 1: Highway-vehicle mobile-source emission-factor model (Apple MacIntosh version) (for microcomputers). Model-Simulation

    SciTech Connect (OSTI)

    Not Available

    1991-08-01

    MOBILE4.1 is the latest revision to EPA's highway vehicle mobile source emission factor model. Relative to MOBILE4, it contains numerous revisions and provides the user with additional options for modeling highway vehicle emission factors. it will calculate emission factors for hydrocarbons (HC), carbon monoxide, (CO), and oxides of nitrogen (NOx) from highway motor vehicles. It calculates emission factors for eight individual vehicle types, in two regions of the country (low and high altitude). The emission factors depend on various conditions such as ambient temperature, fuel volatility, speed, and mileage accrual rates. It will estimate emission factors for any calendar year between 1960 and 2020 inclusive. The 25 most recent model years are considered in operation in each calendar year. EPA is requiring that states and others preparing emission inventories for nonattainment areas for CO and ozone to use MOBILE4.1 in the development of the base year 1990 emission inventories required under the Clean Air Act of 1990.

  7. Natural Gas Infrastructure R&D and Methane Emissions Mitigation Workshop

    Office of Environmental Management (EM)

    12-13, 2014  Overall pipeline efficiency is a complex puzzle that includes both economic efficiency and transportation efficiency.  Due to economic efficiency Interstate Natural Gas Pipelines typically do not operate at their optimum design condition.  So, most compressor/driver combinations are operated at off-design conditions.  In addition, there is a large range of installed compressor efficiencies due to installation effects. Pipeline from A to B Compressor Station A Compressor

  8. The Use of Positive Matrix Factorization with Conditional Probability Functions in Air Quality Studies: An Application to Hydrocarbon Emissions in Houston, Texas

    SciTech Connect (OSTI)

    Xie, YuLong; Berkowitz, Carl M.

    2006-06-01

    As part of a study to identify groups of compounds (source categories) associated with different processing facilities, a multivariate receptor model called Positive Matrix Factorization (PMF) was applied to hourly average concentrations of volatile organic compounds (VOCs) measured at five Photochemical Assessment Monitoring Stations (PAMS) located near the Ship Channel in Houston, Texas. The observations were made between June and October, 2003, and limited to nighttime measurements (21:00 pm 6:00 am) in order to remove the complexity of photochemical processing and associated changes in the concentrations of primary and secondary VOCs. Six to eight volatile organic compounds source categories were identified for the five Ship Channel sites. The dominant source categories were found to be those associated with petrochemical, chemical industries and fuel evaporation. In contrast, source categories associated with on-road vehicles were found to be relatively insignificant. Although evidence of biogenic emissions was found at almost all the sites, this broad category was significant only at the Wallisville site, which was also the site furthest away from the Ship Channels area and closest to the northeast forest of Texas. Natural gas, accumulation and fuel evaporation sources were found to contribute most to the ambient VOCs, followed by the petrochemical emission of highly reactive ethene and propylene. Solvent / paint industry and fuel evaporation and emission from refineries were next in importance while the on-road vehicle exhaust generally contributed less than 10% of the total ambient VOCs. Specific geographic areas associated with each source category were identified through the use of a Conditional Probability Function (CPF) analysis that related elevated concentrations of key VOCs in each category to a network of grids superimposed on the source inventories of the VOCs.

  9. Comparing three vegetation monoterpene emission models to measured gas concentrations with a model of meteorology, air chemistry and chemical transport

    SciTech Connect (OSTI)

    Smolander, S.; He, Q.; Mogensen, Ditte; Zhou, L.; Back, J.; Ruuskanen, T.; Noe, S.; Guenther, Alex B.; Aaltonen, H.; Kulmala, M.; Boy, Michael

    2014-10-07

    Biogenic volatile organic compounds (BVOCs) are essential in atmospheric chemistry because of their chemical reactions that produce and destroy tropospheric ozone, their effects on aerosol formation and growth, and their potential influence on global warming. As one of the important BVOC groups, monoterpenes have been a focus of scientific attention in atmospheric research. Detailed regional measurements and model estimates are needed to study emission potential and the monoterpene budget on a global scale. Since the use of empirical measurements for upscaling is limited by many physical and biological factors such as genetic variation, temperature and light, water availability, seasonal changes, and environmental stresses, comprehensive inventories over larger areas are difficult to obtain.

  10. Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

    DOE Patents [OSTI]

    Garrett, W. Ray (Oak Ridge, TN)

    1997-01-01

    A method and apparatus for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components.

  11. Gas concentration measurement instrument based on the effects of a wave-mixing interference on stimulated emissions

    DOE Patents [OSTI]

    Garrett, W.R.

    1997-11-11

    A method and apparatus are disclosed for measuring partial pressures of gaseous components within a mixture. The apparatus comprises generally at least one tunable laser source, a beam splitter, mirrors, optical filter, an optical spectrometer, and a data recorder. Measured in the forward direction along the path of the laser, the intensity of the emission spectra of the gaseous component, at wavelengths characteristic of the gas component being measured, are suppressed. Measured in the backward direction, the peak intensities characteristic of a given gaseous component will be wavelength shifted. These effects on peak intensity wavelengths are linearly dependent on the partial pressure of the compound being measured, but independent of the partial pressures of other gases which are present within the sample. The method and apparatus allow for efficient measurement of gaseous components. 9 figs.

  12. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil...

  13. Quantifying Climate Feedbacks from Abrupt Changes in High-Latitude Trace-Gas Emissions

    SciTech Connect (OSTI)

    Qianlai Zhuang

    2012-11-16

    During the three-year project period, Purdue University has specifically accomplished the following: revised the existing Methane Dynamics Model (MDM) to consider the effects of changes of atmospheric pressure; applied the methane dynamics model (MDM) to Siberian region to demonstrate that ebullition estimates could increase previous estimates of regional terrestrial CH{sub 4} emissions 3- to 7-fold in Siberia; Conducted an analysis of the carbon balance of the Arctic Basin from 1997 to 2006 to show that terrestrial areas of the Arctic were a net source of 41.5 Tg CH{sub 4} yr{sup ??1} that increased by 0.6 Tg CH{sub 4} yr{sup ??1} during the decade of analysis, a magnitude that is comparable with an atmospheric inversion of CH{sub 4}; improved the quantification of CH{sub 4} fluxes in the Arctic with inversion methods; evaluated AIRS CH4 retrieval data with a transport and inversion model and surface flux and aircraft data; to better quantify methane emissions from wetlands, we extended the MDM within a biogeochemistry model, the Terrestrial Ecosystem Model (TEM), to include a large-scale hydrology model, the variable infiltration capacity (VIC) model; more recently, we developed a single box atmospheric chemistry model involving atmospheric methane (CH{sub 4}), carbon monoxide (CO) and radical hydroxyl (OH) to analyze atmospheric CH{sub 4} concentrations from 1984 to 2008.

  14. Near-Zero Emissions Oxy-Combustion Flue Gas Purification - Power Plant Performance

    SciTech Connect (OSTI)

    Andrew Seltzer; Zhen Fan

    2011-03-01

    A technical feasibility assessment was performed for retrofitting oxy-fuel technology to an existing power plant burning low sulfur PRB fuel and high sulfur bituminous fuel. The focus of this study was on the boiler/power generation island of a subcritical steam cycle power plant. The power plant performance in air and oxy-firing modes was estimated and modifications required for oxy-firing capabilities were identified. A 460 MWe (gross) reference subcritical PC power plant was modeled. The reference air-fired plant has a boiler efficiency (PRB/Bituminous) of 86.7%/89.3% and a plant net efficiency of 35.8/36.7%. Net efficiency for oxy-fuel firing including ASU/CPU duty is 25.6%/26.6% (PRB/Bituminous). The oxy-fuel flue gas recirculation flow to the boiler is 68%/72% (PRB/bituminous) of the flue gas (average O{sub 2} in feed gas is 27.4%/26.4%v (PRB/bituminous)). Maximum increase in tube wall temperature is less than 10ºF for oxy-fuel firing. For oxy-fuel firing, ammonia injected to the SCR was shut-off and the FGD is applied to remove SOx from the recycled primary gas stream and a portion of the SOx from the secondary stream for the high sulfur bituminous coal. Based on CFD simulations it was determined that at the furnace outlet compared to air-firing, SO{sub 3}/SO{sub 2} mole ratio is about the same, NOx ppmv level is about the same for PRB-firing and 2.5 times for bituminous-firing due to shutting off the OFA, and CO mole fraction is approximately double. A conceptual level cost estimate was performed for the incremental equipment and installation cost of the oxyfuel retrofit in the boiler island and steam system. The cost of the retrofit is estimated to be approximately 81 M$ for PRB low sulfur fuel and 84 M$ for bituminous high sulfur fuel.

  15. Enhancement of the EUV emission of a metallic capillary discharge operated with argon ambient gas

    SciTech Connect (OSTI)

    Chan, L. S. Tan, D. Saboohi, S. Yap, S. L. Wong, C. S.

    2014-03-05

    In this work, the metallic capillary discharge is operated with two different ambients: air and argon. In the experiments reported here, the chamber is first evacuated to 10{sup ?5} mbar. The discharge is initiated by the transient hollow cathode effect generated electron beam, with either air ambient or argon ambient at 10{sup ?4} mbar. The bombardment of electron beam at the tip of the stainless steel anode gives rise to a metallic vapor, which is injected into the capillary and initiates the main discharge through the capillary. The EUV emission is measured for different discharge voltages for both conditions and compared. It is found that the metallic capillary discharge with argon ambientis able to produce higher EUV energy compared to that with air ambient.

  16. Controlling Methane Emissions in the Natural Gas Sector. A Review of Federal and State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution

    SciTech Connect (OSTI)

    Paranhos, Elizabeth; Kozak, Tracy G.; Boyd, William; Bradbury, James; Steinberg, D. C.; Arent, D. J.

    2015-04-23

    This report provides an overview of the regulatory frameworks governing natural gas supply chain infrastructure siting, construction, operation, and maintenance. Information was drawn from a number of sources, including published analyses, government reports, in addition to relevant statutes, court decisions and regulatory language, as needed. The scope includes all onshore facilities that contribute to methane emissions from the natural gas sector, focusing on three areas of state and federal regulations: (1) natural gas pipeline infrastructure siting and transportation service (including gathering, transmission, and distribution pipelines), (2) natural gas pipeline safety, and (3) air emissions associated with the natural gas supply chain. In addition, the report identifies the incentives under current regulatory frameworks to invest in measures to reduce leakage, as well as the barriers facing investment in infrastructure improvement to reduce leakage. Policy recommendations regarding how federal or state authorities could regulate methane emissions are not provided; rather, existing frameworks are identified and some of the options for modifying existing regulations or adopting new regulations to reduce methane leakage are discussed.

  17. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K.; Dimotakis, Paul E.; Walker, Bruce C.

    2011-09-26

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  18. Measurements of 222Rn, 220Rn, and CO Emissions in Natural CO2 Fields in Wyoming: MVA Techniques for Determining Gas Transport and Caprock Integrity

    SciTech Connect (OSTI)

    Kaszuba, John; Sims, Kenneth

    2014-09-30

    An integrated field-laboratory program evaluated the use of radon and CO2 flux measurements to constrain source and timescale of CO2 fluxes in environments proximate to CO2 storage reservoirs. By understanding the type and depth of the gas source, the integrity of a CO2 storage reservoir can be assessed and monitored. The concept is based on correlations of radon and CO2 fluxes observed in volcanic systems. This fundamental research is designed to advance the science of Monitoring, Verification, and Accounting (MVA) and to address the Carbon Storage Program goal of developing and validating technologies to ensure 99 percent storage performance. Graduate and undergraduate students conducted the research under the guidance of the Principal Investigators; in doing so they were provided with training opportunities in skills required for implementing and deploying CCS technologies. Although a final method or tool was not developed, significant progress was made. The field program identified issues with measuring radon in environments rich in CO2. Laboratory experiments determined a correction factor to apply to radon measurements made in CO2-bearing environments. The field program also identified issues with radon and CO2-flux measurements in soil gases at a natural CO2 analog. A systematic survey of radon and CO2 flux in soil gases at the LaBarge CO2 Field in Southwest Wyoming indicates that measurements of 222Rn (radon), 220Rn (thoron), and CO2 flux may not be a robust method for monitoring the integrity of a CO2 storage reservoir. The field program was also not able to correlate radon and CO2 flux in the CO2-charged springs of the Thermopolis hydrothermal system. However, this part of the program helped to motivate the aforementioned laboratory experiments that determined correction factors for measuring radon in CO2-rich environments. A graduate student earned a Master of Science degree for this part of the field program; she is currently employed with a geologic consulting company. Measurement of radon in springs has improved significantly since the field program first began; however, in situ measurement of 222Rn and particularly 220Rn in springs is problematic. Future refinements include simultaneous salinity measurements and systematic corrections, or adjustments to the partition coefficient as needed for more accurate radon concentration determination. A graduate student earned a Master of Science degree for this part of the field program; he is currently employed with a geologic consulting company. Both graduate students are poised to begin work in a CCS technology area. Laboratory experiments evaluated important process-level fundamentals that effect measurements of radon and CO2. Laboratory tests established that fine-grained source minerals yield higher radon emissivity compared to coarser-sized source minerals; subtleties in the dataset suggest that grain size alone is not fully representative of all the processes controlling the ability of radon to escape its mineral host. Emissivity for both 222Rn and 220Rn increases linearly with temperature due to reaction of rocks with water, consistent with faster diffusion and enhanced mineral dissolution at higher temperatures. The presence of CO2 changes the relative importance of the factors that control release of radon. Emissivity for both 222Rn and 220Rn in CO2-bearing experiments is greater at all temperatures compared to the experiments without CO2, but emissivity does not increase as a simple function of temperature. Governing processes may include a balance between enhanced dissolution versus carbonate mineral formation in CO2-rich waters.

  19. Reduction of Non-CO2 Gas Emissions Through The In Situ Bioconversion of Methane

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, B; Balin, D F

    2012-09-06

    The primary objectives of this research were to seek previously unidentified anaerobic methanotrophs and other microorganisms to be collected from methane seeps associated with coal outcrops. Subsurface application of these microbes into anaerobic environments has the potential to reduce methane seepage along coal outcrop belts and in coal mines, thereby preventing hazardous explosions. Depending upon the types and characteristics of the methanotrophs identified, it may be possible to apply the microbes to other sources of methane emissions, which include landfills, rice cultivation, and industrial sources where methane can accumulate under buildings. Finally, the microbes collected and identified during this research also had the potential for useful applications in the chemical industry, as well as in a variety of microbial processes. Sample collection focused on the South Fork of Texas Creek located approximately 15 miles east of Durango, Colorado. The creek is located near the subsurface contact between the coal-bearing Fruitland Formation and the underlying Pictured Cliffs Sandstone. The methane seeps occur within the creek and in areas adjacent to the creek where faulting may allow fluids and gases to migrate to the surface. These seeps appear to have been there prior to coalbed methane development as extensive microbial soils have developed. Our investigations screened more than 500 enrichments but were unable to convince us that anaerobic methane oxidation (AMO) was occurring and that anaerobic methanotrophs may not have been present in the samples collected. In all cases, visual and microscopic observations noted that the early stage enrichments contained viable microbial cells. However, as the levels of the readily substrates that were present in the environmental samples were progressively lowered through serial transfers, the numbers of cells in the enrichments sharply dropped and were eliminated. While the results were disappointing we acknowledge that anaerobic methane oxidizing (AOM) microorganisms are predominantly found in marine habitats and grow poorly under most laboratory conditions. One path for future research would be to use a small rotary rig to collect samples from deeper soil horizons, possibly adjacent to the coal-bearing horizons that may be more anaerobic.

  20. Eco-efficiency for greenhouse gas emissions mitigation of municipal solid waste management: A case study of Tianjin, China

    SciTech Connect (OSTI)

    Zhao Wei; Huppes, Gjalt; Voet, Ester van der

    2011-06-15

    The issue of municipal solid waste (MSW) management has been highlighted in China due to the continually increasing MSW volumes being generated and the limited capacity of waste treatment facilities. This article presents a quantitative eco-efficiency (E/E) analysis on MSW management in terms of greenhouse gas (GHG) mitigation. A methodology for E/E analysis has been proposed, with an emphasis on the consistent integration of life cycle assessment (LCA) and life cycle costing (LCC). The environmental and economic impacts derived from LCA and LCC have been normalized and defined as a quantitative E/E indicator. The proposed method was applied in a case study of Tianjin, China. The study assessed the current MSW management system, as well as a set of alternative scenarios, to investigate trade-offs between economy and GHG emissions mitigation. Additionally, contribution analysis was conducted on both LCA and LCC to identify key issues driving environmental and economic impacts. The results show that the current Tianjin's MSW management system emits the highest GHG and costs the least, whereas the situation reverses in the integrated scenario. The key issues identified by the contribution analysis show no linear relationship between the global warming impact and the cost impact in MSW management system. The landfill gas utilization scenario is indicated as a potential optimum scenario by the proposed E/E analysis, given the characteristics of MSW, technology levels, and chosen methodologies. The E/E analysis provides an attractive direction towards sustainable waste management, though some questions with respect to uncertainty need to be discussed further.

  1. Well-to-Wheels Analysis of Advanced Fuel/Vehicle Systems: A North American Study of Energy Use, Greenhouse Gas Emissions, and Criteria Pollutant Emissions

    SciTech Connect (OSTI)

    Brinkman, Norman; Wang, Michael; Weber, Trudy; Darlington, Thomas

    2005-05-01

    An accurate assessment of future fuel/propulsion system options requires a complete vehicle fuel-cycle analysis, commonly called a well-to-wheels (WTW) analysis. This WTW study analyzes energy use and emissions associated with fuel production (or well-to-tank [WTT]) activities and energy use and emissions associated with vehicle operation (or tank-to-wheels [TTW]) activities.

  2. Land and Water Use, CO2 Emissions, and Worker Radiological Exposure Factors for the Nuclear Fuel Cycle

    SciTech Connect (OSTI)

    Brett W Carlsen; Brent W Dixon; Urairisa Pathanapirom; Eric Schneider; Bethany L. Smith; Timothy M. AUlt; Allen G. Croff; Steven L. Krahn

    2013-08-01

    The Department of Energy Office of Nuclear Energys Fuel Cycle Technologies program is preparing to evaluate several proposed nuclear fuel cycle options to help guide and prioritize Fuel Cycle Technology research and development. Metrics are being developed to assess performance against nine evaluation criteria that will be used to assess relevant impacts resulting from all phases of the fuel cycle. This report focuses on four specific environmental metrics. land use water use CO2 emissions radiological Dose to workers Impacts associated with the processes in the front-end of the nuclear fuel cycle, mining through enrichment and deconversion of DUF6 are summarized from FCRD-FCO-2012-000124, Revision 1. Impact estimates are developed within this report for the remaining phases of the nuclear fuel cycle. These phases include fuel fabrication, reactor construction and operations, fuel reprocessing, and storage, transport, and disposal of associated used fuel and radioactive wastes. Impact estimates for each of the phases of the nuclear fuel cycle are given as impact factors normalized per unit process throughput or output. These impact factors can then be re-scaled against the appropriate mass flows to provide estimates for a wide range of potential fuel cycles. A companion report, FCRD-FCO-2013-000213, applies the impact factors to estimate and provide a comparative evaluation of 40 fuel cycles under consideration relative to these four environmental metrics.

  3. Real-time measurements of particulate matter and polycyclic aromatic hydrocarbon emissions from stationary combustion sources used in oil and gas production

    SciTech Connect (OSTI)

    D. w. Hahn; K. r. Hencken; H. A. Johnsen; J. R. Ross; P. M. Walsh

    1998-12-10

    Particulate matter emissions and some components of the particles were measured in the exhaust from combustion equipment used in oil and gas production operations near Bakersfield, California. The combustion sources included a 22.5 MW (electric) turbine generator, a 342-Bhp rich-burn spark ignition engine, and a 50 million Btu/h steam generator, all fired using natural gas. The particle components and measurement techniques were as follows: (1) Calcium, magnesium, sodium, silicon, and iron were measured using laser-induced breakdown spectroscopy (LIBS), (2) particle-bound polycyclic aromatic hydrocarbons (PAH) were detected using the charge produced by photoionization, (3) particles having sizes between 0.1 and 7.5 {micro}m were counted using an instrument based on light scattering, and (4) total particulate matter was measured according to US EPA Method 5. Not all of the methods were applied to all of the sources. Measurements were also made in the ambient air near the combustion air inlets to the units, for comparison with the concentrations in the exhaust, but the inlet and outlet measurements were not done simultaneously. Calcium, sodium, and silicon were found in the exhaust from the steam generator at concentrations similar to those in the ambient air near the inlet to the burner. Sodium and silicon were observed in the engine exhaust at levels a factor of four higher than their concentrations in the air. The principal metal observed in the engine exhaust was calcium, a component of the lubricating oil, at a concentration of 11.6 {micro}g/m{sup 3}. The air entering the gas turbine is filtered, so the average concentrations of metals in the turbine exhaust under steady operating conditions were even lower than in the air. During start-up following a shut-down to wash the turbine, silicon and iron were the major species in the stack, at concentrations of 6.4 and 16.2 {micro}g/m{sup 3}, respectively. A possible source of silicon is the water injected into the turbine for NO{sub x} control. Iron-containing particles are expected to be scale from ferrous metals. A commercial photoelectric aerosol sensor was used to measure PAH adsorbed on particles in the exhaust from the steam generator and the rich-burn engine. The conversion of the instrument readings to PAH concentrations is dependent upon the specific distribution of PAH species present. Using the typical calibration factor recommended by the instrument manufacturer, the estimated average concentration of particle-bound PAH was below the instrument detection limit (3--10 ng/m{sup 3}) in the stack gas from the steam generator, and was estimated to be 0.045--0.15 {micro}g/m{sup 3} in the exhaust from the rich-burn engine. Particle mass concentrations estimated from number concentrations determined using the particle counting and sizing instrument were only small fractions of the concentrations measured using Method 5. This is thought to be due primarily to the limited range over which size was quantified (0.1 to 7.5 {micro}m) and the poor efficiency with which the sampling system transferred large particles.

  4. GBTL Workshop GHG Emissions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GHG Emissions GBTL Workshop GHG Emissions EERE Presentation of Greenhouse Gas EmissionsResource Potential gbtlworkshopghgemissions.pdf More Documents & Publications GBTL...

  5. Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution

    Broader source: Energy.gov (indexed) [DOE]

    Controlling Methane Emissions in the Natural Gas Sector: A Review of Federal & State Regulatory Frameworks Governing Production, Gathering, Processing, Transmission, and Distribution Elizabeth Paranhos and Tracy G. Kozak Energy Innovation Partners William Boyd Energy Innovation Partners and University of Colorado - Boulder James Bradbury U.S. Department of Energy Office of Energy Policy and Systems Analysis Daniel C. Steinberg National Renewable Energy Laboratory Douglas J. Arent Joint

  6. Intergalactic medium emission observations with the cosmic web imager. I. The circum-QSO medium of QSO 1549+19, and evidence for a filamentary gas inflow

    SciTech Connect (OSTI)

    Martin, D. Christopher; Chang, Daphne; Matuszewski, Matt; Morrissey, Patrick; Rahman, Shahin; Moore, Anna; Steidel, Charles C.

    2014-05-10

    The Palomar Cosmic Web Imager (PCWI), an integral field spectrograph designed to detect and map low surface brightness emission, has obtained imaging spectroscopic maps of Ly? from the circum-QSO medium (CQM) of QSO HS1549+19 at redshift z = 2.843. Extensive extended emission is detected from the CQM, consistent with fluorescent and pumped Ly? produced by the ionizing and Ly? continuum of the QSO. Many features present in PCWI spectral images match those detected in narrow-band images. Filamentary structures with narrow line profiles are detected in several cases as long as 250-400 kpc. One of these is centered at a velocity redshifted with respect to the systemic velocity, and displays a spatially collimated and kinematically cold line profile increasing in velocity width approaching the QSO. This suggests that the filament gas is infalling onto the QSO, perhaps in a cold accretion flow. Because of the strong ionizing flux, the neutral column density is low, typically N(H I)?10{sup 12}--10{sup 15} cm{sup ?2}, and the line center optical depth is also low (typically ?{sub 0} < 10), insufficient to display well separated double peak emission characteristic of higher line optical depths. With a simple ionization and cloud model we can very roughly estimate the total gas mass (log M {sub gas} = 12.5 0.5) and the total (log M {sub tot} = 13.3 0.5). We can also calculate a kinematic mass from the total line profile (2 10{sup 13} M {sub ?}), which agrees with the mass estimated from the gas emission. The intensity-binned spectrum of the CQM shows a progression in kinematic properties consistent with heirarchical structure formation.

  7. Nitrogen availability and indirect measurements of greenhouse gas emissions from aerobic and anaerobic biowaste digestates applied to agricultural soils

    SciTech Connect (OSTI)

    Rigby, H.; Smith, S.R.

    2013-12-15

    Highlights: Nitrogen release in digestate-amended soil depends on the digestate type. Overall N release is modulated by digestate mineral and mineralisable N contents. Microbial immobilisation does not influence overall release of digestate N in soil. Digestate physical properties and soil type interact to affect overall N recovery. High labile C inputs in digestate may promote denitrification in fine-textured soil. - Abstract: Recycling biowaste digestates on agricultural land diverts biodegradable waste from landfill disposal and represents a sustainable source of nutrients and organic matter (OM) to improve soil for crop production. However, the dynamics of nitrogen (N) release from these organic N sources must be determined to optimise their fertiliser value and management. This laboratory incubation experiment examined the effects of digestate type (aerobic and anaerobic), waste type (industrial, agricultural and municipal solid waste or sewage sludge) and soil type (sandy loam, sandy silt loam and silty clay) on N availability in digestate-amended soils and also quantified the extent and significance of the immobilisation of N within the soil microbial biomass, as a possible regulatory mechanism of N release. The digestate types examined included: dewatered, anaerobically digested biosolids (DMAD); dewatered, anaerobic mesophilic digestate from the organic fraction of municipal solid waste (DMADMSW); liquid, anaerobic co-digestate of food and animal slurry (LcoMAD) and liquid, thermophilic aerobic digestate of food waste (LTAD). Ammonium chloride (NH{sub 4}Cl) was included as a reference treatment for mineral N. After 48 days, the final, maximum net recoveries of mineral N relative to the total N (TN) addition in the different digestates and unamended control treatments were in the decreasing order: LcoMAD, 68%; LTAD, 37%, DMAD, 20%; and DMADMSW, 11%. A transient increase in microbial biomass N (MBN) was observed with LTAD application, indicating greater microbial activity in amended soil and reflecting the lower stability of this OM source, compared to the other, anaerobic digestate types, which showed no consistent effects on MBN compared to the control. Thus, the overall net release of digestate N in different soil types was not regulated by N transfer into the soil microbial biomass, but was determined primarily by digestate properties and the capacity of the soil type to process and turnover digestate N. In contrast to the sandy soil types, where nitrate (NO{sub 3}{sup -}) concentrations increased during incubation, there was an absence of NO{sub 3}{sup -} accumulation in the silty clay soil amended with LTAD and DMADMSW. This provided indirect evidence for denitrification activity and the gaseous loss of N, and the associated increased risk of greenhouse gas emissions under certain conditions of labile C supply and/or digestate physical structure in fine-textured soil types. The significance and influence of the interaction between soil type and digestate stability and physical properties on denitrification processes in digestate-amended soils require urgent investigation to ensure management practices are appropriate to minimise greenhouse gas emissions from land applied biowastes.

  8. DUST AND GAS IN THE MAGELLANIC CLOUDS FROM THE HERITAGE HERSCHEL KEY PROJECT. I. DUST PROPERTIES AND INSIGHTS INTO THE ORIGIN OF THE SUBMILLIMETER EXCESS EMISSION

    SciTech Connect (OSTI)

    Gordon, Karl D.; Roman-Duval, Julia; Meixner, Margaret; Bot, Caroline; Babler, Brian; Bernard, Jean-Philippe; Bolatto, Alberto; Jameson, Katherine; Boyer, Martha L.; Clayton, Geoffrey C.; Engelbracht, Charles; Fukui, Yasuo; Galametz, Maud; Galliano, Frederic; Hony, Sacha; Lebouteiller, Vianney; Indebetouw, Remy; Israel, Frank P.; Kawamura, Akiko; and others

    2014-12-20

    The dust properties in the Large and Small Magellanic clouds (LMC/SMC) are studied using the HERITAGE Herschel Key Project photometric data in five bands from 100 to 500?m. Three simple models of dust emission were fit to the observations: a single temperature blackbody modified by a power-law emissivity (SMBB), a single temperature blackbody modified by a broken power-law emissivity (BEMBB), and two blackbodies with different temperatures, both modified by the same power-law emissivity (TTMBB). Using these models, we investigate the origin of the submillimeter excess, defined as the submillimeter emission above that expected from SMBB models fit to observations <200 ?m. We find that the BEMBB model produces the lowest fit residuals with pixel-averaged 500?m submillimeter excesses of 27% and 43% for the LMC and SMC, respectively. Adopting gas masses from previous works, the gas-to-dust ratios calculated from our fitting results show that the TTMBB fits require significantly more dust than are available even if all the metals present in the interstellar medium (ISM) were condensed into dust. This indicates that the submillimeter excess is more likely to be due to emissivity variations than a second population of colder dust. We derive integrated dust masses of (7.3 1.7) 10{sup 5} and (8.3 2.1) 10{sup 4} M {sub ?} for the LMC and SMC, respectively. We find significant correlations between the submillimeter excess and other dust properties; further work is needed to determine the relative contributions of fitting noise and ISM physics to the correlations.

  9. Factors Affecting the Relationship between Crude Oil and Natural Gas Prices (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01

    Over the 1995-2005 period, crude oil prices and U.S. natural gas prices tended to move together, which supported the conclusion that the markets for the two commodities were connected. Figure 26 illustrates the fairly stable ratio over that period between the price of low-sulfur light crude oil at Cushing, Oklahoma, and the price of natural gas at the Henry Hub on an energy-equivalent basis.

  10. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J. (Oak Ridge, TN); Lowrie, Robert S. (Oak Ridge, TN); Sease, John D. (Knoxville, TN)

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  12. Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-in Hybrid Electric Vehicles

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report examines energy use and emissions from primary energy source through vehicle operation to help researchers understand the impact of the upstream mix of electricity generation technologies

  13. Greenhouse gas emissions trading in U.S. States: observations and lessons from the OTC NOx Budget Program

    SciTech Connect (OSTI)

    Andrew Aulisi; Alexander E. Farrell; Jonathan Pershing; Stacy VanDeveer

    2005-07-01

    A number of U.S. states are considering market-based policies to reduce emissions of greenhouse gases (GHGs). The experience gained from emissions trading for sulfur dioxide and oxides of nitrogen (NOx) offers a useful body of information and data to draw on to design a GHG emissions trading system. This report examines NOx trading under the Ozone Transport Commission (OTC) NOx Budget Program, which resulted principally from the leadership, decisions, and actions by a group of states, ultimately becoming the first multilateral cap-and-trade system for emissions of air pollutants. 72 refs.

  14. Assessment of Factors Influencing Effective CO{sub 2} Storage Capacity and Injectivity in Eastern Gas Shales

    SciTech Connect (OSTI)

    Godec, Michael

    2013-06-30

    Building upon advances in technology, production of natural gas from organic-rich shales is rapidly developing as a major hydrocarbon supply option in North America and around the world. The same technology advances that have facilitated this revolution - dense well spacing, horizontal drilling, and hydraulic fracturing - may help to facilitate enhanced gas recovery (EGR) and carbon dioxide (CO{sub 2}) storage in these formations. The potential storage of CO {sub 2} in shales is attracting increasing interest, especially in Appalachian Basin states that have extensive shale deposits, but limited CO{sub 2} storage capacity in conventional reservoirs. The goal of this cooperative research project was to build upon previous and on-going work to assess key factors that could influence effective EGR, CO{sub 2} storage capacity, and injectivity in selected Eastern gas shales, including the Devonian Marcellus Shale, the Devonian Ohio Shale, the Ordovician Utica and Point Pleasant shale and equivalent formations, and the late Devonian-age Antrim Shale. The project had the following objectives: (1) Analyze and synthesize geologic information and reservoir data through collaboration with selected State geological surveys, universities, and oil and gas operators; (2) improve reservoir models to perform reservoir simulations to better understand the shale characteristics that impact EGR, storage capacity and CO{sub 2} injectivity in the targeted shales; (3) Analyze results of a targeted, highly monitored, small-scale CO{sub 2} injection test and incorporate into ongoing characterization and simulation work; (4) Test and model a smart particle early warning concept that can potentially be used to inject water with uniquely labeled particles before the start of CO{sub 2} injection; (5) Identify and evaluate potential constraints to economic CO{sub 2} storage in gas shales, and propose development approaches that overcome these constraints; and (6) Complete new basin-level characterizations for the CO{sub 2} storage capacity and injectivity potential of the targeted eastern shales. In total, these Eastern gas shales cover an area of over 116 million acres, may contain an estimated 6,000 trillion cubic feet (Tcf) of gas in place, and have a maximum theoretical storage capacity of over 600 million metric tons. Not all of this gas in-place will be recoverable, and economics will further limit how much will be economic to produce using EGR techniques with CO{sub 2} injection. Reservoir models were developed and simulations were conducted to characterize the potential for both CO{sub 2} storage and EGR for the target gas shale formations. Based on that, engineering costing and cash flow analyses were used to estimate economic potential based on future natural gas prices and possible financial incentives. The objective was to assume that EGR and CO{sub 2} storage activities would commence consistent with the historical development practices. Alternative CO{sub 2} injection/EGR scenarios were considered and compared to well production without CO{sub 2} injection. These simulations were conducted for specific, defined model areas in each shale gas play. The resulting outputs were estimated recovery per typical well (per 80 acres), and the estimated CO{sub 2} that would be injected and remain in the reservoir (i.e., not produced), and thus ultimately assumed to be stored. The application of this approach aggregated to the entire area of the four shale gas plays concluded that they contain nearly 1,300 Tcf of both primary production and EGR potential, of which an estimated 460 Tcf could be economic to produce with reasonable gas prices and/or modest incentives. This could facilitate the storage of nearly 50 Gt of CO{sub 2} in the Marcellus, Utica, Antrim, and Devonian Ohio shales.

  15. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  16. Factors that will influence oil and gas supply and demand in the 21st century

    SciTech Connect (OSTI)

    Holditch, S.A.; Chianelli, R.R.

    2008-04-15

    A recent report published by the National Petroleum Council (NPC) in the United States predicted a 50-60% growth in total global demand for energy by 2030. Because oil, gas, and coal will continue to be the primary energy sources during this time, the energy industry will have to continue increasing the supply of these fuels to meet this increasing demand. Achieving this goal will require the exploitation of both conventional and unconventional reservoirs of oil and gas in (including coalbed methane) an environmentally acceptable manner. Such efforts will, in turn, require advancements in materials science, particularly in the development of materials that can withstand high-pressure, high-temperature, and high-stress conditions.

  17. Methane emissions from rice fields: The effects of climatic and agricultural factors. Final report, March 1, 1994--April 30, 1997

    SciTech Connect (OSTI)

    Khalil, M.A.K.; Rasmussen, R.A.

    1997-10-01

    The work reported was performed for the purpose of refining estimates of methane emissions from rice fields. Research performed included methane flux measurements, evaluation of variables affecting emissions, compilation of a data base, and continental background measurements in China. The key findings are briefly described in this report. Total methane emissions, seasonal patterns, and spatial variability were measured for a 7-year periods. Temperature was found to be the most important variable studies affecting methane emissions. The data archives for the research are included in the report. 5 refs., 6 figs.

  18. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J.

    2011-04-01

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  19. Implications of High Renewable Electricity Penetration in the U.S. for Water Use, Greenhouse Gas Emissions, Land-Use, and Materials Supply

    Broader source: Energy.gov [DOE]

    Recent work found that renewable energy could supply 80% of electricity demand in the contiguous United States in 2050 at the hourly level. This paper explores some of the implications of achieving such high levels of renewable electricity for supply chains and the environment in scenarios with renewable supply up to such levels. Transitioning to high renewable electricity supply would lead to significant reductions in greenhouse gas emissions and water use, with only modest land-use implications. While renewable energy expansion implies moderate growth of the renewable electricity supply chains, no insurmountable long-term constraints to renewable electricity technology manufacturing capacity or materials supply are identified.

  20. Experimental and life cycle assessment analysis of gas emission from mechanicallybiologically pretreated waste in a landfill with energy recovery

    SciTech Connect (OSTI)

    Di Maria, Francesco Sordi, Alessio; Micale, Caterina

    2013-11-15

    Highlights: Bio-methane landfill emissions from different period (0, 4, 8, 16 weeks) MTB waste have been evaluated. Electrical energy recoverable from landfill gas ranges from 11 to about 90 kW h/tonne. Correlation between oxygen uptake, energy recovery and anaerobic gas production shows R{sup 2} ranging from 0.78 to 0.98. LCA demonstrate that global impact related to gaseous emissions achieve minimum for 4 week of MBT. - Abstract: The global gaseous emissions produced by landfilling the Mechanically Sorted Organic Fraction (MSOF) with different weeks of Mechanical Biological Treatment (MBT) was evaluated for an existing waste management system. One MBT facility and a landfill with internal combustion engines fuelled by the landfill gas for electrical energy production operate in the waste management system considered. An experimental apparatus was used to simulate 0, 4, 8 and 16 weeks of aerobic stabilization and the consequent biogas potential (Nl/kg) of a large sample of MSOF withdrawn from the full-scale MBT. Stabilization achieved by the waste was evaluated by dynamic oxygen uptake and fermentation tests. Good correlation coefficients (R{sup 2}), ranging from 0.7668 to 0.9772, were found between oxygen uptake, fermentation and anaerobic test values. On the basis of the results of several anaerobic tests, the methane production rate k (year{sup ?1}) was evaluated. k ranged from 0.436 to 0.308 year{sup ?1} and the bio-methane potential from 37 to 12 N m{sup 3}/tonne, respectively, for the MSOF with 0 and 16 weeks of treatment. Energy recovery from landfill gas ranged from about 11 to 90 kW h per tonne of disposed MSOF depending on the different scenario investigated. Life cycle analysis showed that the scenario with 0 weeks of pre-treatment has the highest weighted global impact even if opposite results were obtained with respect to the single impact criteria. MSOF pre-treatment periods longer than 4 weeks showed rather negligible variation in the global impact of system emissions.

  1. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  2. Capital investment requirements for greenhouse gas emissions mitigation in power generation on near term to century time scales and global to regional spatial scales

    SciTech Connect (OSTI)

    Chaturvedi, Vaibhav; Clarke, Leon E.; Edmonds, James A.; Calvin, Katherine V.; Kyle, G. Page

    2014-11-01

    Electrification plays a crucial role in cost-effective greenhouse gas emissions mitigation strategies. Such strategies in turn carry implications for financial capital markets. This paper explores the implication of climate mitigation policy for capital investment demands by the electric power sector on decade to century time scales. We go further to explore the implications of technology performance and the stringency of climate policy for capital investment demands by the power sector. Finally, we discuss the regional distribution of investment demands. We find that stabilizing GHG emissions will require additional investment in the electricity generation sector over and above investments that would be need in the absence of climate policy, in the range of 16 to 29 Trillion US$ (60-110%) depending on the stringency of climate policy during the period 2015 to 2095 under default technology assumptions. This increase reflects the higher capital intensity of power systems that control emissions. Limits on the penetration of nuclear and carbon capture and storage technology could increase costs substantially. Energy efficiency improvements can reduce the investment requirement by 8 to21 Trillion US$ (default technology assumptions), depending on climate policy scenario with higher savings being obtained under the most stringent climate policy. The heaviest investments in power generation were observed in the China, India, SE Asia and Africa regions with the latter three regions dominating in the second half of the 21st century.

  3. Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-in Hybrid Electric Vehicles

    SciTech Connect (OSTI)

    Elgowainy, A.; Han, J.; Poch, L.; Wang, M.; Vyas, A.; Mahalik, M.; Rousseau, A.

    2010-06-01

    This report examines energy use and emissions from primary energy source through vehicle operation to help researchers understand the impact of the upstream mix of electricity generation technologies for recharging plug-in hybrid electric vehicles (PHEVs), as well as the powertrain technology and fuel sources for PHEVs.

  4. Analyzing the Impact of Residential Building Attributes, Demographic and Behavioral Factors on Natural Gas Usage

    SciTech Connect (OSTI)

    Livingston, Olga V.; Cort, Katherine A.

    2011-03-03

    This analysis examines the relationship between energy demand and residential building attributes, demographic characteristics, and behavioral variables using the U.S. Department of Energys Residential Energy Consumption Survey 2005 microdata. This study investigates the applicability of the smooth backfitting estimator to statistical analysis of residential energy consumption via nonparametric regression. The methodology utilized in the study extends nonparametric additive regression via local linear smooth backfitting to categorical variables. The conventional methods used for analyzing residential energy consumption are econometric modeling and engineering simulations. This study suggests an econometric approach that can be utilized in combination with simulation results. A common weakness of previously used econometric models is a very high likelihood that any suggested parametric relationships will be misspecified. Nonparametric modeling does not have this drawback. Its flexibility allows for uncovering more complex relationships between energy use and the explanatory variables than can possibly be achieved by parametric models. Traditionally, building simulation models overestimated the effects of energy efficiency measures when compared to actual "as-built" observed savings. While focusing on technical efficiency, they do not account for behavioral or market effects. The magnitude of behavioral or market effects may have a substantial influence on the final energy savings resulting from implementation of various energy conservation measures and programs. Moreover, variability in behavioral aspects and user characteristics appears to have a significant impact on total energy consumption. Inaccurate estimates of energy consumption and potential savings also impact investment decisions. The existing modeling literature, whether it relies on parametric specifications or engineering simulation, does not accommodate inclusion of a behavioral component. This study attempts to bridge that gap by analyzing behavioral data and investigate the applicability of additive nonparametric regression to this task. This study evaluates the impact of 31 regressors on residential natural gas usage. The regressors include weather, economic variables, demographic and behavioral characteristics, and building attributes related to energy use. In general, most of the regression results were in line with previous engineering and economic studies in this area. There were, however, some counterintuitive results, particularly with regard to thermostat controls and behaviors. There are a number of possible reasons for these counterintuitive results including the inability to control for regional climate variability due to the data sanitization (to prevent identification of respondents), inaccurate data caused by to self-reporting, and the fact that not all relevant behavioral variables were included in the data set, so we were not able to control for them in the study. The results of this analysis could be used as an in-sample prediction for approximating energy demand of a residential building whose characteristics are described by the regressors in this analysis, but a certain combination of their particular values does not exist in the real world. In addition, this study has potential applications for benefit-cost analysis of residential upgrades and retrofits under a fixed budget, because the results of this study contain information on how natural gas consumption might change once a particular characteristic or attribute is altered. Finally, the results of this study can help establish a relationship between natural gas consumption and changes in behavior of occupants.

  5. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  6. Table 11.5a Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Total (All Sectors), 1989-2010 (Sum of Tables 11.5b and 11.5c; Metric Tons of Gas)

    U.S. Energy Information Administration (EIA) Indexed Site

    a Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Total (All Sectors), 1989-2010 (Sum of Tables 11.5b and 11.5c; Metric Tons of Gas) Year Carbon Dioxide 1 Sulfur Dioxide Nitrogen Oxides Coal 2 Natural Gas 3 Petroleum 4 Geo- thermal 5 Non- Biomass Waste 6 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total 1989 1,573,566,415 218,383,703 145,398,976 363,247 5,590,014 1,943,302,355 14,468,564 1,059 984,406

  7. Table 11.5b Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Electric Power Sector, 1989-2010 (Subset of Table 11.5a; Metric Tons of Gas)

    U.S. Energy Information Administration (EIA) Indexed Site

    b Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Electric Power Sector, 1989-2010 (Subset of Table 11.5a; Metric Tons of Gas) Year Carbon Dioxide 1 Sulfur Dioxide Nitrogen Oxides Coal 2 Natural Gas 3 Petroleum 4 Geo- thermal 5 Non- Biomass Waste 6 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total 1989 1,520,229,870 169,653,294 133,545,718 363,247 4,365,768 1,828,157,897 13,815,263 832 809,873 6,874

  8. Table 11.5c Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Commercial and Industrial Sectors, 1989-2010 (Subset of Table 11.5a; Metric Tons of Gas)

    U.S. Energy Information Administration (EIA) Indexed Site

    c Emissions From Energy Consumption for Electricity Generation and Useful Thermal Output: Commercial and Industrial Sectors, 1989-2010 (Subset of Table 11.5a; Metric Tons of Gas) Year Carbon Dioxide 1 Sulfur Dioxide Nitrogen Oxides Coal 2 Natural Gas 3 Petroleum 4 Geo- thermal 5 Non- Biomass Waste 6 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total Coal 2 Natural Gas 3 Petroleum 4 Other 7 Total Commercial Sector 8<//td> 1989 2,319,630 1,542,083 637,423 [ –] 803,754 5,302,890 37,398 4

  9. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping . E-mail: zzhong@seu.edu.cn; Jin Baosheng; Huang Yaji; Zhou Hongcang; Lan Jixiang

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  10. Verification of maximum radial power peaking factor due to insertion of FPM-LEU target in the core of RSG-GAS reactor

    SciTech Connect (OSTI)

    Setyawan, Daddy; Rohman, Budi

    2014-09-30

    Verification of Maximum Radial Power Peaking Factor due to insertion of FPM-LEU target in the core of RSG-GAS Reactor. Radial Power Peaking Factor in RSG-GAS Reactor is a very important parameter for the safety of RSG-GAS reactor during operation. Data of radial power peaking factor due to the insertion of Fission Product Molybdenum with Low Enriched Uranium (FPM-LEU) was reported by PRSG to BAPETEN through the Safety Analysis Report RSG-GAS for FPM-LEU target irradiation. In order to support the evaluation of the Safety Analysis Report incorporated in the submission, the assessment unit of BAPETEN is carrying out independent assessment in order to verify safety related parameters in the SAR including neutronic aspect. The work includes verification to the maximum radial power peaking factor change due to the insertion of FPM-LEU target in RSG-GAS Reactor by computational method using MCNP5and ORIGEN2. From the results of calculations, the new maximum value of the radial power peaking factor due to the insertion of FPM-LEU target is 1.27. The results of calculations in this study showed a smaller value than 1.4 the limit allowed in the SAR.

  11. The Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    2009-01-18

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH,

  12. Emission Abatement System

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2003-05-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  13. Methane emissions from MBT landfills

    SciTech Connect (OSTI)

    Heyer, K.-U. Hupe, K.; Stegmann, R.

    2013-09-15

    Highlights: Compilation of methane generation potential of mechanical biological treated (MBT) municipal solid waste. Impacts and kinetics of landfill gas production of MBT landfills, approach with differentiated half-lives. Methane oxidation in the waste itself and in soil covers. Estimation of methane emissions from MBT landfills in Germany. - Abstract: Within the scope of an investigation for the German Federal Environment Agency (Umweltbundesamt), the basics for the estimation of the methane emissions from the landfilling of mechanically and biologically treated waste (MBT) were developed. For this purpose, topical research including monitoring results regarding the gas balance at MBT landfills was evaluated. For waste treated to the required German standards, a methane formation potential of approximately 1824 m{sup 3} CH{sub 4}/t of total dry solids may be expected. Monitoring results from MBT landfills show that a three-phase model with differentiated half-lives describes the degradation kinetics in the best way. This is due to the fact that during the first years of disposal, the anaerobic degradation processes still proceed relatively intensively. In addition in the long term (decades), a residual gas production at a low level is still to be expected. Most of the soils used in recultivation layer systems at German landfills show a relatively high methane oxidation capacity up to 5 l CH{sub 4}/(m{sup 2} h). However, measurements at MBT disposal sites indicate that the majority of the landfill gas (in particular at non-covered areas), leaves the landfill body via preferred gas emission zones (hot spots) without significant methane oxidation. Therefore, rather low methane oxidation factors are recommended for open and temporarily covered MBT landfills. Higher methane oxidation rates can be achieved when the soil/recultivation layer is adequately designed and operated. Based on the elaborated default values, the First Order Decay (FOD) model of the IPCC Guidelines for National Greenhouse Gas Inventories, 2006, was used to estimate the methane emissions from MBT landfills. Due to the calculation made by the authors emissions in the range of 60,000135,000 t CO{sub 2-eq.}/a for all German MBT landfills can be expected. This wide range shows the uncertainties when the here used procedure and the limited available data are applied. It is therefore necessary to generate more data in the future in order to calculate more precise methane emission rates from MBT landfills. This is important for the overall calculation of the climate gas production in Germany which is required once a year by the German Government.

  14. How the Carbon Emissions Were Estimated

    U.S. Energy Information Administration (EIA) Indexed Site

    dioxide emissions are the main component of greenhouse gas emissions caused by human activity. Carbon dioxide is emitted mostly as a byproduct of the combustion of fossil fuels...

  15. Feebates and Fuel Economy Standards: Impacts on Fuel Use in Light-Duty Vehicles and Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Greene, David L

    2011-01-01

    This study evaluates the potential impacts of a national feebate system, a market-based policy that consists of graduated fees on low-fuel-economy (or high-emitting) vehicles and rebates for high-fuel-economy (or lowemitting) vehicles. In their simplest form, feebate systems operate under three conditions: a benchmark divides all vehicles into two categories-those charged fees and those eligible for rebates; the sizes of the fees and rebates are a function of a vehicle's deviation from its benchmark; and placement of the benchmark ensures revenue neutrality or a desired level of subsidy or revenue. A model developed by the University of California for the California Air Resources Board was revised and used to estimate the effects of six feebate structures on fuel economy and sales of new light-duty vehicles, given existing and anticipated future fuel economy and emission standards. These estimates for new vehicles were then entered into a vehicle stock model that simulated the evolution of the entire vehicle stock. The results indicate that feebates could produce large, additional reductions in emissions and fuel consumption, in large part by encouraging market acceptance of technologies with advanced fuel economy, such as hybrid electric vehicles.

  16. Hardware assembly and prototype testing for the development of a dedicated liquefied propane gas ultra low emission vehicle

    SciTech Connect (OSTI)

    1995-07-01

    On February 3, 1994, IMPCO Technologies, Inc. started the development of a dedicated LPG Ultra Low Emissions Vehicle (ULEV) under contract to the Midwest Research Institute National Renewable Energy Laboratory Division (NREL). The objective was to develop a dedicated propane vehicle that would meet or exceed the California ULEV emissions standards. The project is broken into four phases to be performed over a two year period. The four phases of the project include: (Phase 1) system design, (Phase 2) prototype hardware assembly and testing, (Phase 3) full-scale systems testing and integration, (Phase 4) vehicle demonstration. This report describes the approach taken for the development of the vehicle and the work performed through the completion of Phase II dynamometer test results. Work was started on Phase 2 (Hardware Assembly and Prototype Testing) in May 1994 prior to completion of Phase 1 to ensure that long lead items would be available in a timely fashion for the Phase 2 work. In addition, the construction and testing of the interim electronic control module (ECM), which was used to test components, was begun prior to the formal start of Phase 2. This was done so that the shortened revised schedule for the project (24 months) could be met. In this report, a brief summary of the activities of each combined Phase 1 and 2 tasks will be presented, as well as project management activities. A technical review of the system is also given, along with test results and analysis. During the course of Phase 2 activities, IMPCO staff also had the opportunity to conduct cold start performance tests of the injectors. The additional test data was most positive and will be briefly summarized in this report.

  17. NREL: Transportation Research - NREL Study Predicts Fuel and Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Automated Mobility District NREL Study Predicts Fuel and Emissions Impact of Automated Mobility District January 21, 2016 With emerging technologies, travel behavior may shift from personal vehicles to automated transit systems. An NREL study shows that a campus-sized -- ranging from four to 10 square miles -- automated mobility district (AMD) has the potential to reduce fuel consumption and greenhouse gas emissions by 4% to 14% depending on various operating and ridership factors.

  18. Incorporating Agricultural Management Practices into the Assessment of Soil Carbon Change and Life-Cycle Greenhouse Gas Emissions of Corn Stover Ethanol Production

    SciTech Connect (OSTI)

    Qin, Zhangcai; Canter, Christina E.; Dunn, Jennifer B.; Mueller, Steffen; Kwon, Ho-young; Han, Jeongwoo; Wander, Michelle M.; Wang, Michael

    2015-09-01

    Land management practices such as cover crop adoption or manure application that can increase soil organic carbon (SOC) may provide a way to counter SOC loss upon removal of stover from corn fields for use as a biofuel feedstock. This report documents the data, methodology, and assumptions behind the incorporation of land management practices into corn-soybean systems that dominate U.S. grain production using varying levels of stover removal in the GREETTM (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model and its CCLUB (Carbon Calculator for Land Use change from Biofuels production) module. Tillage (i.e., conventional, reduced and no tillage), corn stover removal (i.e., at 0, 30% and 60% removal rate), and organic matter input techniques (i.e., cover crop and manure application) are included in the analysis as major land management practices. Soil carbon changes associated with land management changes were modeled with a surrogate CENTURY model. The resulting SOC changes were incorporated into CCLUB while GREET was expanded to include energy and material consumption associated with cover crop adoption and manure application. Life-cycle greenhouse gas (GHG) emissions of stover ethanol were estimated using a marginal approach (all burdens and benefits assigned to corn stover ethanol) and an energy allocation approach (burdens and benefits divided between grain and stover ethanol). In the latter case, we considered corn grain and corn stover ethanol to be produced at an integrated facility. Life-cycle GHG emissions of corn stover ethanol are dependent upon the analysis approach selected (marginal versus allocation) and the land management techniques applied. The expansion of CCLUB and GREET to accommodate land management techniques can produce a wide range of results because users can select from multiple scenario options such as choosing tillage levels, stover removal rates, and whether crop yields increase annually or remain constant. In a scenario with conventional tillage and a 30% stover removal rate, life-cycle GHG emissions for a combined gallon of corn grain and stover ethanol without cover crop adoption or manure application are 49 g CO2eq MJ-1, in comparison with 91 g CO2eq MJ-1 for petroleum gasoline. Adopting a cover crop or applying manure reduces the former ethanol life-cycle GHG emissions by 8% and 10%, respectively. We considered two different life cycle analysis approaches to develop estimates of life-cycle GHG emissions for corn stover ethanol, marginal analysis and energy allocation. In the same scenario, this fuel has GHG emissions of 12 20 g CO2eq MJ-1 (for manure and cover crop application, respectively) and 45 48 g CO2eq MJ-1 with the marginal approach and the energy allocation approach, respectively.

  19. EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions

    Gasoline and Diesel Fuel Update (EIA)

    of nitrogen only in regions with sufficient rainfall or irrigation, include below-ground crop residues while omitting biological fixation of nitrogen, and transfer...

  20. Transportation Energy Futures Series. Effects of Travel Reduction and Efficient Driving on Transportation. Energy Use and Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; DeFlorio, J.; McKenzie, E.; Tao, W.; Vimmerstedt, L.

    2013-03-01

    Since the 1970s, numerous transportation strategies have been formulated to change the behavior of drivers or travelers by reducing trips, shifting travel to more efficient modes, or improving the efficiency of existing modes. This report summarizes findings documented in existing literature to identify strategies with the greatest potential impact. The estimated effects of implementing the most significant and aggressive individual driver behavior modification strategies range from less than 1% to a few percent reduction in transportation energy use and GHG emissions. Combined strategies result in reductions of 7% to 15% by 2030. Pricing, ridesharing, eco-driving, and speed limit reduction/enforcement strategies are widely judged to have the greatest estimated potential effect, but lack the widespread public acceptance needed to accomplish maximum results. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  1. Transportation Energy Futures Series: Effects of Travel Reduction and Efficient Driving on Transportation: Energy Use and Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Porter, C. D.; Brown, A.; DeFlorio, J.; McKenzie, E.; Tao, W.; Vimmerstedt, L.

    2013-03-01

    Since the 1970s, numerous transportation strategies have been formulated to change the behavior of drivers or travelers by reducing trips, shifting travel to more efficient modes, or improving the efficiency of existing modes. This report summarizes findings documented in existing literature to identify strategies with the greatest potential impact. The estimated effects of implementing the most significant and aggressive individual driver behavior modification strategies range from less than 1% to a few percent reduction in transportation energy use and GHG emissions. Combined strategies result in reductions of 7% to 15% by 2030. Pricing, ridesharing, eco-driving, and speed limit reduction/enforcement strategies are widely judged to have the greatest estimated potential effect, but lack the widespread public acceptance needed to accomplish maximum results. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored strategies for abating GHGs and reducing petroleum dependence related to transportation.

  2. Power plant emissions reduction

    DOE Patents [OSTI]

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy

    2015-10-20

    A system for improved emissions performance of a power plant generally includes an exhaust gas recirculation system having an exhaust gas compressor disposed downstream from the combustor, a condensation collection system at least partially disposed upstream from the exhaust gas compressor, and a mixing chamber in fluid communication with the exhaust gas compressor and the condensation collection system, where the mixing chamber is in fluid communication with the combustor.

  3. Technologies and policies for controlling greenhouse gas emissions from the U. S. automobile and light truck fleet.

    SciTech Connect (OSTI)

    Plotkin, S.

    1999-01-01

    The message conveyed by the above discussion is that there are no shortages of technologies available to improve the fuel efficiency of the U.S. fleet of autos and light trucks. It clearly is technically feasible to improve greatly the fuel economy of the average new light-duty vehicle. Many of these technologies require tradeoffs, however, that manufacturers are unwilling or (as yet) unable to make in today's market and regulatory environment. These tradeoffs involve higher costs (that might be reduced substantially over time with learning and economies of scale), technical risk and added complexity, emissions concerns (especially for direct injection engines, and especially with respect to diesel engine technology), and customer acceptance issues. Even with current low U.S. oil prices, however, many of these technologies may find their way into the U.S. market, or increase their market share, as a consequence of their penetration of European and Japanese markets with their high gasoline prices. Automotive technology is ''fungible'' that is, it can be easily transported from one market to another. Nevertheless, it probably is unrealistic to expect substantial increases in the average fuel economy of the U.S. light-duty fleet without significant changes in the market. Without such changes, the technologies that do penetrate the U.S. market are more likely to be used to increase acceleration performance or vehicle structures or enable four wheel drive to be included in vehicles without a net mpg penalty. In other words, technology by itself is not likely to be enough to raise fleet fuel economy levels - this was the conclusion of the 1995 Ailomar Conference on Energy and Sustainable Transportation, organized by the Transportation Research Board's Committees on Energy and Alternative Fuels, and it is one I share.

  4. Control of Greenhouse Gas Emissions by Optimal DER Technology Investment and Energy Management in Zero-Net-Energy Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Siddiqui, Afzal; Marnay, Chris; Aki, Hirohisa; Lai, Judy

    2009-08-10

    The U.S. Department of Energy has launched the commercial building initiative (CBI) in pursuit of its research goal of achieving zero-net-energy commercial buildings (ZNEB), i.e. ones that produce as much energy as they use. Its objective is to make these buildings marketable by 2025 such that they minimize their energy use through cutting-edge, energy-efficiency technologies and meet their remaining energy needs through on-site renewable energy generation. This paper examines how such buildings may be implemented within the context of a cost- or CO2-minimizing microgrid that is able to adopt and operate various technologies: photovoltaic modules (PV) and other on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and passive/demand-response technologies. A mixed-integer linear program (MILP) that has a multi-criteria objective function is used. The objective is minimization of a weighted average of the building's annual energy costs and CO2 emissions. The MILP's constraints ensure energy balance and capacity limits. In addition, constraining the building's energy consumed to equal its energy exports enables us to explore how energy sales and demand-response measures may enable compliance with the ZNEB objective. Using a commercial test site in northernCalifornia with existing tariff rates and technology data, we find that a ZNEB requires ample PV capacity installed to ensure electricity sales during the day. This is complemented by investment in energy-efficient combined heat and power (CHP) equipment, while occasional demand response shaves energy consumption. A large amount of storage is also adopted, which may be impractical. Nevertheless, it shows the nature of the solutions and costs necessary to achieve a ZNEB. Additionally, the ZNEB approach does not necessary lead to zero-carbon (ZC) buildings as is frequently argued. We also show a multi-objective frontier for the CA example, whichallows us to estimate the needed technologies and costs for achieving a ZC building or microgrid.

  5. Reversible Acid Gas Capture

    ScienceCinema (OSTI)

    Dave Heldebrant

    2012-12-31

    Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

  6. Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.

    2008-11-18

    This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

  7. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbon??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  8. Natural Gas Weekly Update, Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    Gas Prices Contributing to Increases in Greenhouse Gas Emissions: The United States Environmental Protection Agency (EPA) cited increasing natural gas prices as one of three...

  9. Effects of uncertainty in SAPRC90 rate constants and selected product yields on reactivity adjustment factors for alternative fuel vehicle emissions. Final report

    SciTech Connect (OSTI)

    Bergin, M.S.; Russell, A.G.; Yang, Y.J.; Milford, J.B.; Kirchner, F.; Stockwell, W.R.

    1996-07-01

    Tropospheric ozone is formed in the atmosphere by a series of reactions involving volatile organic compounds (VOCs) and nitrogen oxides (NO{sub x}). While NOx emissions are primarily composed of only two compounds, nitrogen oxide (NO) and nitrogen dioxide (NO{sub 2}), there are hundreds of different VOCs being emitted. In general, VOCs promote ozone formation, however, the rate and extent of ozone produced by the individual VOCs varies considerably. For example, it is widely acknowledged that formaldehyde (HCHO) is a very reactive VOC, and produces ozone rapidly and efficiently under most conditions. On the other hand, VOCs such as methane, ethane, propane, and methanol do not react as quickly, and are likely to form less urban ozone than a comparable mass of HCHO. The difference in ozone forming potential is one of the bases for the use of alternative fuels. The fuels considered in this study included compressed natural gas, LPG, mixtures of methanol and gasoline, ethanol and gasoline, and a reformulated gasoline.

  10. Using Cool Roofs to Reduce Energy Use, Greenhouse Gas Emissions, and Urban Heat-island Effects: Findings from an India Experiment

    SciTech Connect (OSTI)

    Akbari, Hashem; Xu, Tengfang; Taha, Haider; Wray, Craig; Sathaye, Jayant; Garg, Vishal; Tetali, Surekha; Babu, M. Hari; Reddy, K. Niranjan

    2011-05-25

    Cool roofs, cool pavements, and urban vegetation reduce energy use in buildings, lower local air pollutant concentrations, and decrease greenhouse gas emissions from urban areas. This report summarizes the results of a detailed monitoring project in India and related simulations of meteorology and air quality in three developing countries. The field results quantified direct energy savings from installation of cool roofs on individual commercial buildings. The measured annual energy savings potential from roof-whitening of previously black roofs ranged from 20-22 kWh/m2 of roof area, corresponding to an air-conditioning energy use reduction of 14-26% in commercial buildings. The study estimated that typical annual savings of 13-14 kWh/m2 of roof area could be achieved by applying white coating to uncoated concrete roofs on commercial buildings in the Metropolitan Hyderabad region, corresponding to cooling energy savings of 10-19%. With the assumption of an annual increase of 100,000 square meters of new roof construction for the next 10 years in the Metropolitan Hyderabad region, the annual cooling energy savings due to whitening concrete roof would be 13-14 GWh of electricity in year ten alone, with cumulative 10-year cooling energy savings of 73-79 GWh for the region. The estimated savings for the entire country would be at least 10 times the savings in Hyderabad, i.e., more than 730-790 GWh. We estimated that annual direct CO2 reduction associated with reduced energy use would be 11-12 kg CO2/m2 of flat concrete roof area whitened, and the cumulative 10-year CO2 reduction would be approximately 0.60-0.65 million tons in India. With the price of electricity estimated at seven Rupees per kWh, the annual electricity savings on air-conditioning would be approximately 93-101 Rupees per m2 of roof. This would translate into annual national savings of approximately one billion Rupees in year ten, and cumulative 10-year savings of over five billion Rupees for cooling energy in India. Meteorological simulations in this study indicated that a reduction of 2C in air temperature in the Hyderabad area would be likely if a combination of increased surface albedo and vegetative cover are used as urban heat-island control strategies. In addition, air-temperature reductions on the order of 2.5-3.5C could be achieved if moderate and aggressive heat-island mitigation measures are adopted, respectively. A large-scale deployment of mitigation measures can bring additional indirect benefit to the urban area. For example, cooling outside air can improve the efficiency of cooling systems, reduce smog and greenhouse gas (GHG) emissions, and indirectly reduce pollution from power plants - all improving environmental health quality. This study has demonstrated the effectiveness of cool-roof technology as one of the urban heat-island control strategies for the Indian industrial and scientific communities and has provided an estimate of the national energy savings potential of cool roofs in India. These outcomes can be used for developing cool-roof building standards and related policies in India. Additional field studies, built upon the successes and lessons learned from this project, may be helpful to further confirm the scale of potential energy savings from the application of cooler roofs in various regions of India. In the future, a more rigorous meteorological simulation using urbanized (meso-urban) meteorological models should be conducted, which may produce a more accurate estimate of the air-temperature reductions for the entire urban area.

  11. Opportunities for market-based programs worldwide that reduce greenhouse gas emissions: Initial Observations from Missions to the Philippines, South Africa, and Mexico

    SciTech Connect (OSTI)

    Stanton-Hoyle, D.R.

    1998-07-01

    Globally, governments and industries are implementing innovative voluntary programs to reduce greenhouse gas emissions. Often these programs encourage groups to use cost effective technologies that capture market-based forces. These programs are successful because they capitalize on existing opportunities where both the environment and the participants can benefit (i.e., win-win opportunities). This paper documents efforts to investigate these kinds of win-win opportunities in three developing countries: the Philippines, South Africa, and Mexico. Initial observations are provided as fresh information from the field, drawing on six missions during the last nine months. Utility costs, interest rates, and overall economic health appear to critically affect opportunities in each country. By contrast, details of heating, ventilating and air-conditioning (HVAC) design and local climate were often important differences between countries. These affect opportunities, for example, to achieve significant savings from cooling systems or not. Looking at the success of ESCOs was somewhat surprising. One might expect to see the most successful ESCO activity where utility costs are high and upgrade opportunities are plentiful (such as in the Philippines). This was not the case, however, as research in the Philippines did not reveal even one active ESCO contract yet. Design practices for new construction were in need of the same thing that helps US design teams do a better job of energy-efficient design, better communications between design team members. Finally, industrial firms were doing a variety of EE upgrades in each country, but this level of activity was relatively small compared to what should be cost effective.

  12. EIA - Greenhouse Gas Emissions Overview

    Gasoline and Diesel Fuel Update (EIA)

    A2. Glossary Acid stabilization: A circumstance where the pH of the waste mixture in an animal manure management system is maintained near 7.0, optimal conditions for methane production. Aerobic bacteria: Microorganisms living, active, or occurring only in the presence of oxygen. Aerobic decomposition: The breakdown of a molecule into simpler molecules or atoms by microorganisms under favorable conditions of oxygenation. Aerosols: Airborne particles. Afforestation: Planting of new forests on

  13. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas

    Office of Environmental Management (EM)

    from the United States | Department of Energy Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows: *How does exported liquefied natural gas (LNG) from the U.S. compare

  14. MOtor Vehicle Emission Simulator (MOVES) | Open Energy Information

    Open Energy Info (EERE)

    of low-emission development strategies (LEDS). Key Outputs Greenhouse gas and air toxic emissions. How to Use This Tool Training Available Training available at http:...

  15. Oil & Gas Research | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to produce. Fugitive Emissions | Produced Water Management | Subsurface Fluid & Gas Migration | Induced Seismicity Offshore Resources Building the scientific understanding and...

  16. Life-cycle analysis of shale gas and natural gas.

    SciTech Connect (OSTI)

    Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M.

    2012-01-27

    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

  17. Carbon Dioxide and Helium Emissions from a Reservoir of Magmatic...

    Open Energy Info (EERE)

    in eastern California. The gas is released mainly as diffuse emissions from normal-temperature soils, but some gas issues from steam vents or leaves the mountain dissolved...

  18. GREENHOUSE GAS EMISSIONS CONTROL BY OXYGEN FIRING IN CIRCULATING FLUIDIZED BED BOILERS: PHASE II--PILOT SCALE TESTING AND UPDATED PERFORMANCE AND ECONOMICS FOR OXYGEN FIRED CFB WITH CO2 CAPTURE

    SciTech Connect (OSTI)

    Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

    2004-10-27

    Because fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic CO{sub 2} emissions. In this Phase II study, ALSTOM Power Inc. (ALSTOM) has investigated one promising near-term coal fired power plant configuration designed to capture CO{sub 2} from effluent gas streams for sequestration. Burning fossil fuels in mixtures of oxygen and recirculated flue gas (made principally of CO{sub 2}) essentially eliminates the presence of atmospheric nitrogen in the flue gas. The resulting flue gas is comprised primarily of CO{sub 2}, along with some moisture, nitrogen, oxygen, and trace gases like SO{sub 2} and NO{sub x}. Oxygen firing in utility scale Pulverized Coal (PC) fired boilers has been shown to be a more economical method for CO{sub 2} capture than amine scrubbing (Bozzuto, et al., 2001). Additionally, oxygen firing in Circulating Fluid Bed Boilers (CFB's) can be more economical than in PC or Stoker firing, because recirculated gas flow can be reduced significantly. Oxygen-fired PC and Stoker units require large quantities of recirculated flue gas to maintain acceptable furnace temperatures. Oxygen-fired CFB units, on the other hand, can accomplish this by additional cooling of recirculated solids. The reduced recirculated gas flow with CFB plants results in significant Boiler Island cost savings resulting from reduced component The overall objective of the Phase II workscope, which is the subject of this report, is to generate a refined technical and economic evaluation of the Oxygen fired CFB case (Case-2 from Phase I) utilizing the information learned from pilot-scale testing of this concept. The objective of the pilot-scale testing was to generate detailed technical data needed to establish advanced CFB design requirements and performance when firing coals and delayed petroleum coke in O{sub 2}/CO{sub 2} mixtures. Firing rates in the pilot test facility ranged from 2.2 to 7.9 MM-Btu/hr. Pilot-scale testing was performed at ALSTOM's Multi-use Test Facility (MTF), located in Windsor, Connecticut.

  19. FINAL REPORT REGULATORY OFF GAS EMISSIONS TESTING ON THE DM1200 MELTER SYSTEM USING HLW AND LAW SIMULANTS VSL-05R5830-1 REV 0 10/31/05

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; GONG W; BARDAKCI T; D'ANGELO NA; BRANDYS M; KOT WK; PEGG IL

    2011-12-29

    The operational requirements for the River Protection Project - Waste Treatment Plant (RPP-WTP) Low Activity Waste (LAW) and High Level Waste (HLW) melter systems, together with the feed constituents, impose a number of challenges to the off-gas treatment system. The system must be robust from the standpoints of operational reliability and minimization of maintenance. The system must effectively control and remove a wide range of solid particulate matter, acid mists and gases, and organic constituents (including those arising from products of incomplete combustion of sugar and organics in the feed) to concentration levels below those imposed by regulatory requirements. The baseline design for the RPP-WTP LAW primary off-gas system includes a submerged bed scrubber (SBS), a wet electrostatic precipitator (WESP), and a high efficiency particulate air (HEPA) filter. The secondary off-gas system includes a sulfur-impregnated activated carbon bed (AC-S), a thermal catalytic oxidizer (TCO), a single-stage selective catalytic reduction NOx treatment system (SCR), and a packed-bed caustic scrubber (PBS). The baseline design for the RPP-WTP HLW primary off-gas system includes an SBS, a WESP, a high efficiency mist eliminator (HEME), and a HEPA filter. The HLW secondary off-gas system includes a sulfur-impregnated activated carbon bed, a silver mordenite bed, a TCO, and a single-stage SCR. The one-third scale HLW DM1200 Pilot Melter installed at the Vitreous State Laboratory (VSL) was equipped with a prototypical off-gas train to meet the needs for testing and confirmation of the performance of the baseline off-gas system design. Various modifications have been made to the DM1200 system as the details of the WTP design have evolved, including the installation of a silver mordenite column and an AC-S column for testing on a slipstream of the off-gas flow; the installation of a full-flow AC-S bed for the present tests was completed prior to initiation of testing. The DM1200 system was reconfigured to enable testing of the baseline HLW or LAW off-gas trains to perform off-gas emissions testing with both LAW and HLW simulants in the present work. During 2002 and 2003, many of these off-gas components were tested individually and in an integrated manner with the DM1200 Pilot Melter. Data from these tests are being used to support engineering design confirmation and to provide data to support air permitting activities. In fiscal year 2004, the WTP Project was directed by the Office of River Protection (ORP) to comply with Environmental Protection Agency (EPA) Maximum Achievable Control Technology (MACT) requirements for organics. This requires that the combined melter and off-gas system have destruction and removal efficiency (DRE) of >99.99% for principal organic dangerous constituents (PODCs). In order to provide confidence that the melter and off-gas system are able to achieve the required DRE, testing has been directed with both LAW and HLW feeds. The tests included both 'normal' and 'challenge' WTP melter conditions in order to obtain data for the potential range of operating conditions for the WTP melters and off-gas components. The WTP Project, Washington State Department of Ecology, and ORP have agreed that naphthalene will be used for testing to represent semi-volatile organics and allyl alcohol will be used to represent volatile organics. Testing was also performed to determine emissions of halides, metals, products of incomplete combustion (PICs), dioxins, furans, coplanar PCBs, total hydrocarbons, and COX and NOX, as well as the particle size distribution (PSD) of particulate matter discharged at the end of the off-gas train. A description of the melter test requirements and analytical methods used is provided in the Test Plan for this work. Test Exceptions were subsequently issued which changed the TCO catalyst, added total organic emissions (TOE) to exhaust sampling schedule, and allowing modification of the test conditions in response to attainable plenum temperatures as well as temperature increases in the sulfur impregnated activated carbon (AC-S) column. Data are provided in this final report for all the required emission samples as well as melter and off-gas conditions during all the sampling periods. Appended to this report are previously issued VSL Letter Reports on method development for monitoring allyl alcohol in melter exhaust streams, on the results of characterization of the selected AC-S carbon media (Donnau BAT37), and on DM1200 off-line tests on the AC-S bed; also appended are reports from Air Tech on emissions sampling, and reports from Keika Ventures on validation of analytical data provided by Severn Trent Laboratories of Knoxville, Tennessee.

  20. Urban Transportation Emission Calculator | Open Energy Information

    Open Energy Info (EERE)

    Calculator (UTEC) is a user-friendly tool for estimating annual emissions from personal, commercial, and public transit vehicles. It estimates greenhouse gas (GHG) and...

  1. Reliability of natural gas cogeneration systems

    SciTech Connect (OSTI)

    1995-12-01

    Cogeneration systems fueled by natural gas exceed the reliability of most central station power generating units, according to a study conducted by RINC Corporation for Gas Research Institute (GRI). In the study, researchers obtained operating data from 122 natural gas cogeneration units nationwide representing 2,200 megawatts (MW) of capacity and nearly 2 million hours of operating time at 37 facilities. Units were grouped into categories reflecting size (from 60 kilowatts to 100 MW), type of system (gas engine or gas turbine technology), use of emission controls, and type of thermal application. Various types and sizes of gas systems reported average availability factors ranging from 90.0 to 95.8 versus a weighted average of 85.9 percent for fossil-fuel steam, nuclear, and gas-turbine-based central station power generating units. Comparisons are based on study data and data reported by the North American Electric Reliability Council for utility power plants. Gas cogeneration can improve utility operations because as a group the relatively small, dispersed cogeneration units are more reliable than one or more large central station units of similar capacity.

  2. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    withdrawal from working gas storage reported last Thursday. A contributing factor to the run-up in natural gas prices could be climbing crude oil prices, which rallied late last...

  3. Selective catalytic reduction system and process for control of NO.sub.x emissions in a sulfur-containing gas stream

    DOE Patents [OSTI]

    Sobolevskiy, Anatoly

    2015-08-11

    An exhaust gas treatment process, apparatus, and system for reducing the concentration of NOx, CO and hydrocarbons in a gas stream, such as an exhaust stream (29), via selective catalytic reduction with ammonia is provided. The process, apparatus and system include a catalytic bed (32) having a reducing only catalyst portion (34) and a downstream reducing-plus-oxidizing portion (36). Each portion (34, 36) includes an amount of tungsten. The reducing-plus-oxidizing catalyst portion (36) advantageously includes a greater amount of tungsten than the reducing catalyst portion (36) to markedly limit ammonia salt formation.

  4. Bioenergy Impacts … Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    researchers at Argonne National Laboratory developed the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model to develop non-food biofuels from agricultural residues, forestry trimmings, energy crops, and algae that have greater greenhouse gas reduction benefits compared to petroleum fuels. Greenhouse gas emission data is helping researchers develop more sustainable biofuels

  5. Greenhouse gas and air pollutant emission reduction potentials of renewable energy - case studies on photovoltaic and wind power introduction considering interactions among technologies in Taiwan

    SciTech Connect (OSTI)

    Yu-Ming Kuo; Yasuhiro Fukushima

    2009-03-15

    To achieve higher energy security and lower emission of greenhouse gases (GHGs) and pollutants, the development of renewable energy has attracted much attention in Taiwan. In addition to its contribution to the enhancement of reliable indigenous resources, the introduction of renewable energy such as photovoltaic (PV) and wind power systems reduces the emission of GHGs and air pollutants by substituting a part of the carbon- and pollutant-intensive power with power generated by methods that are cleaner and less carbon-intensive. To evaluate the reduction potentials, consequential changes in the operation of different types of existing power plants have to be taken into account. In this study, a linear mathematical programming model is constructed to simulate a power mix for a given power demand in a power market sharing a cost-minimization objective. By applying the model, the emission reduction potentials of capacity extension case studies, including the enhancement of PV and wind power introduction at different scales, were assessed. In particular, the consequences of power mix changes in carbon dioxide, nitrogen oxides, sulfur oxides, and particulates were discussed. Seasonally varying power demand levels, solar irradiation, and wind strength were taken into account. In this study, we have found that the synergetic reduction of carbon dioxide emission induced by PV and wind power introduction occurs under a certain level of additional installed capacity. Investigation of a greater variety of case studies on scenario development with emerging power sources becomes possible by applying the model developed in this study. 15 refs., 8 figs., 11 tabs.

  6. Navigating the Numbers: Greenhouse Gas Data and International...

    Open Energy Info (EERE)

    Gas Data and International Climate Policy1 Overview "This report examines greenhouse gas (GHG) emissions at the global, national, sectoral, and fuel levels and identifies...

  7. The Potential of Elelcltric Exhaust Gas Turbocharging for HD...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Elelcltric Exhaust Gas Turbocharging for HD DIesel Engines The Potential of Elelcltric Exhaust Gas Turbocharging for HD DIesel Engines 2005 Diesel Engine Emissions Reduction (DEER)...

  8. Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Greenhouse Gas Emissions: The Combined Potential of Hybrid Technology and Behavioral Adaptation Title Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas...

  9. Emission abatement system utilizing particulate traps

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2004-04-13

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  10. A Review of Materials for Gas Turbines Firing Syngas Fuels

    SciTech Connect (OSTI)

    Gibbons, Thomas; Wright, Ian G

    2009-05-01

    Following the extensive development work carried out in the 1990's, gas turbine combined-cycle (GTCC) systems burning natural gas represent a reliable and efficient power generation technology widely used in many parts of the world. A critical factor was that, in order to operate at the high turbine entry temperatures required for high efficiency operation, aero-engine technology, i.e., single-crystal blades, thermal barrier coatings, and sophisticated cooling techniques had to be rapidly scaled up and introduced into these large gas turbines. The problems with reliability that resulted have been largely overcome, so that the high-efficiency GTCC power generation system is now a mature technology, capable of achieving high levels of availability. The high price of natural gas and concern about emission of greenhouse gases has focused attention on the desirability of replacing natural gas with gas derived from coal (syngas) in these gas turbine systems, since typical systems analyses indicate that IGCC plants have some potential to fulfil the requirement for a zero-emissions power generation system. In this review, the current status of materials for the critical hot gas path parts in large gas turbines is briefly considered in the context of the need to burn syngas. A critical factor is that the syngas is a low-Btu fuel, and the higher mass flow compared to natural gas will tend to increase the power output of the engine. However, modifications to the turbine and to the combustion system also will be necessary. It will be shown that many of the materials used in current engines will also be applicable to units burning syngas but, since the combustion environment will contain a greater level of impurities (especially sulfur, water vapor, and particulates), the durability of some components may be prejudiced. Consequently, some effort will be needed to develop improved coatings to resist attack by sulfur-containing compounds, and also erosion.

  11. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Emissions (Conference) | SciTech Connect Conference: Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions Citation Details In-Document Search Title: Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize

  12. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  13. Evaluation of Gas Reburning and Low N0x Burners on a Wall Fired Boiler

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NO, reduction (70VO) could be achieved. Sponsors of the project included the U.S. Depatiment of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was petformed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado bituminous, low-sulfur coal. It had a baseline NO, emission level of 0.73 lb/1 OG Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50Y0. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NO, in the flue gas by staged fuel combustion. This technology involves the introduction of' natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NO, emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18%. The performance goal of 70/40 reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18%.

  14. Vehicle Emission Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emission Basics Vehicle Emission Basics November 22, 2013 - 2:07pm Addthis Vehicle emissions are the gases emitted by the tailpipes of internal combustion engine vehicles. These vehicles can run on gasoline, diesel, natural gas, or propane. Vehicle emissions are composed of varying amounts of: water vapor carbon dioxide (CO2) nitrogen oxygen pollutants such as: carbon monoxide (CO) nitrogen oxides (NOx) unburned hydrocarbons (UHCs) volatile organic compounds (VOCs) particulate matter (PM) A

  15. Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Gaseous Emissions - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  16. QER- Comment of American Gas Association 4

    Broader source: Energy.gov [DOE]

    From: Peterson, Christopher (EIA)Sent: Tuesday, October 14, 2014 12:11 PMTo: Pierpoint, LaraSubject: FW: AGA comments to QER: Natural Gas Emissions Section

  17. Cost-effectiveness of controlling emissions for various alternative-fuel vehicle types, with vehicle and fuel price subsidies estimated on the basis of monetary values of emission reductions

    SciTech Connect (OSTI)

    Wang, M.Q.

    1993-12-31

    Emission-control cost-effectiveness is estimated for ten alternative-fuel vehicle (AFV) types (i.e., vehicles fueled with reformulated gasoline, M85 flexible-fuel vehicles [FFVs], M100 FFVs, dedicated M85 vehicles, dedicated M100 vehicles, E85 FFVS, dual-fuel liquefied petroleum gas vehicles, dual-fuel compressed natural gas vehicles [CNGVs], dedicated CNGVs, and electric vehicles [EVs]). Given the assumptions made, CNGVs are found to be most cost-effective in controlling emissions and E85 FFVs to be least cost-effective, with the other vehicle types falling between these two. AFV cost-effectiveness is further calculated for various cases representing changes in costs of vehicles and fuels, AFV emission reductions, and baseline gasoline vehicle emissions, among other factors. Changes in these parameters can change cost-effectiveness dramatically. However, the rank of the ten AFV types according to their cost-effectiveness remains essentially unchanged. Based on assumed dollars-per-ton emission values and estimated AFV emission reductions, the per-vehicle monetary value of emission reductions is calculated for each AFV type. Calculated emission reduction values ranged from as little as $500 to as much as $40,000 per vehicle, depending on AFV type, dollar-per-ton emission values, and baseline gasoline vehicle emissions. Among the ten vehicle types, vehicles fueled with reformulated gasoline have the lowest per-vehicle value, while EVs have the highest per-vehicle value, reflecting the magnitude of emission reductions by these vehicle types. To translate the calculated per-vehicle emission reduction values to individual AFV users, AFV fuel or vehicle price subsidies are designed to be equal to AFV emission reduction values. The subsidies designed in this way are substantial. In fact, providing the subsidies to AFVs would change most AFV types from net cost increases to net cost decreases, relative to conventional gasoline vehicles.

  18. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  19. Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams

    SciTech Connect (OSTI)

    Towler, G.P.; Lynn, S.

    1993-05-01

    Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

  20. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A.P.Evans; K.E. Redinger; M.J. Holmes

    1998-04-01

    The objective of the Advanced Emissions Control Development Program (AECDP) is to develop practical, cost-effective strategies for reducing the emissions of air toxics from coal-fired boilers. Ideally, the project aim is to effectively control air toxic emissions through the use of conventional flue gas cleanup equipment such as electrostatic precipitators (ESPS), fabric filters (baghouse), and wet flue gas desulfurization. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate and hydrogen chloride. Following the construction and evaluation of a representative air toxics test facility in Phase I, Phase II focused on the evaluation of mercury and several other air toxics emissions. The AECDP is jointly funded by the United States Department of Energy's Federal Energy Technology Center (DOE), the Ohio Coal Development Office within the Ohio Department of Development (oCDO), and Babcock& Wilcox-a McDermott company (B&W).

  1. Natural Gas Modernization Clearinghouse | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modernization Clearinghouse Natural Gas Modernization Clearinghouse Overview This Natural Gas Modernization Clearinghouse provides information about the implications of natural gas infrastructure modernization, including strategies and technologies that increase public safety, improve efficiency and environmental performance and enhance natural gas deliverability. Specific topic areas include information on measuring and reducing methane emissions, technology research and development, job

  2. Voluntary Reporting of Greenhouse Gases Program - Electricity Factors

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Voluntary Reporting Program > Coefficients Voluntary Reporting of Greenhouse Gases Program (Voluntary Reporting of Greenhouse Gases Program Fuel Carbon Dioxide Emission Coefficients) Voluntary Reporting of Greenhouse Gases Program Fuel Emission Coefficients Table 1: Carbon Dioxide Emission Factors for Stationary Combustion Table 2: Carbon Dioxide Emission Factors for Transportation Fuels Table 3: Generic Methane and Nitrous Oxide Emission Factors for Stationary Fuel Combustion Table 4:

  3. An Internet-based interactive module for air emissions from fossil fuel based power generation

    SciTech Connect (OSTI)

    Karman, D.; O`Leary, K.; O`Reilly, S.

    1997-12-31

    The proliferation of the Internet, Web pages and associated software tools available for developing multimedia material provides significant opportunities in training, education and information transfer. This paper will describe the development, testing and evaluation of an interactive teaching module aimed at college and university students that have previous education in thermodynamics and basic chemistry. The module is currently in development at the Department of Civil and Environmental Engineering at Carleton University with support from Environment Canada. Preliminary testing of this module is expected to begin late January. The module contains options to look at CO, CO{sub 2}, SO{sub 2} and NO{sub x} emissions associated with electric power generation in thermal stations that use coal, natural gas, crude and distillate oil. Factors governing the thermal efficiency of typical boiler systems and the thermodynamic limitations for converting heat into work are discussed. Supporting background information such as emission trends and emission factors used in calculations are also included as part of this module. A simple Rankine cycle without reheat or regeneration is considered to compare the emissions per unit energy delivered from each of the fuels considered. For natural gas and distillate oil, combined cycle operation is considered with a gas turbine-heat recovery steam generator combination replacing the boiler in the simple Rankine cycle. For all fuels, the cogeneration option is investigated by expanding the steam to an intermediate pressure in the turbine and utilizing the remaining heat by condensing the steam in a heat recovery application. Emission factors and basic information on CO, SO{sub 2} and NO{sub x} control technologies are utilized to calculate and report the emissions per unit energy delivered under the various scenarios investigated.

  4. Diesel and CNG Transit Bus Emissions Characterization By Two Chassis Dynamometer Laboratories: Results and Issues

    SciTech Connect (OSTI)

    Nigel N. Clark, Mridul Gautam; Byron L. Rapp; Donald W. Lyons; Michael S. Graboski; Robert L. McCormick; Teresa L. Alleman; Paul Norton

    1999-05-03

    Emissions of six 32 passenger transit buses were characterized using one of the West Virginia University (WVU) Transportable Heavy Duty Emissions Testing Laboratories, and the fixed base chassis dynamometer at the Colorado Institute for Fuels and High Altitude Engine Research (CIFHAER). Three of the buses were powered with 1997 ISB 5.9 liter Cummins diesel engines, and three were powered with the 1997 5.9 liter Cummins natural gas (NG) counterpart. The NG engines were LEV certified. Objectives were to contrast the emissions performance of the diesel and NG units, and to compare results from the two laboratories. Both laboratories found that oxides of nitrogen and particulate matter (PM) emissions were substantially lower for the natural gas buses than for the diesel buses. It was observed that by varying the rapidity of pedal movement during accelerations in the Central Business District cycle (CBD), CO and PM emissions from the diesel buses could be varied by a factor of three or more. The driving styles may be characterized as aggressive and non-aggressive, but both styles followed the CBD speed command acceptably. PM emissions were far higher for the aggressive driving style. For the NG fueled vehicles driving style had a similar, although smaller, effect on NO{sub x}. It is evident that driver habits may cause substantial deviation in emissions for the CBD cycle. When the CO emissions are used as a surrogate for driver aggression, a regression analysis shows that NO{sub x} and PM emissions from the two laboratories agree closely for equivalent driving style. Implications of driver habit for emissions inventories and regulations are briefly considered.

  5. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    began to transition to an inventory data management system that consolidates criteria, toxic and greenhouse gas inventories. The Air Emissions Inventory can be found here. Source...

  6. Harmonized Emissions Analysis Tool (HEAT) | Open Energy Information

    Open Energy Info (EERE)

    to support local governments in planning, implementing and monitoring greenhouse gas and air pollution emission reduction programs. LEDSGP green logo.png This tool is included in...

  7. Relationship Between Composition and Toxicity of Engine Emission...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles Comparative Toxicity of Combined Particle ...

  8. Indonesia-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  9. Thailand-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  10. Philippines-Low Emissions Asian Development (LEAD) Program |...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  11. Papua New Guinea-Low Emissions Asian Development (LEAD) Program...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  12. India-Low Emissions Asian Development (LEAD) Program | Open Energy...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  13. Cambodia-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  14. Bangladesh-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  15. Vietnam-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  16. Malaysia-Low Emissions Asian Development (LEAD) Program | Open...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  17. Nepal-Low Emissions Asian Development (LEAD) Program | Open Energy...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  18. Laos-Low Emissions Asian Development (LEAD) Program | Open Energy...

    Open Energy Info (EERE)

    the growth of greenhouse gas emissions. The LEAD program supports and enhances country-led development programs, plans, and policies, and complements efforts of other...

  19. CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas

    Energy Savers [EERE]

    Emissions and the Effects of Climate Change in NEPA Reviews | Department of Energy Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews CEQ Issues Revised Draft Guidance on Consideration of Greenhouse Gas Emissions and the Effects of Climate Change in NEPA Reviews December 22, 2014 - 12:59pm Addthis The Council on Environmental Quality (CEQ) issued revised draft guidance on consideration of greenhouse gas (GHG) emissions and the effects of

  20. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the strength of natural gas. The cost of producing oil is to a large extent the cost of electric power used to extract and deliver the oil. Researchers have identified stranded and flared gas in California that could generate 400 megawatts of power, and believe that there is at least an additional 2,000 megawatts that have not been identified. Since California accounts for about 14.5% of the total domestic oil production, it is reasonable to assume that about 16,500 megawatts could be generated throughout the United States. This power could restore the cost-effectiveness of thousands of oil wells, increasing oil production by millions of barrels a year, while reducing emissions and greenhouse gas emissions by burning the gas in clean distributed generators rather than flaring or venting the stranded gases. Most turbines and engines are designed for standardized, high-quality gas. However, emerging technologies such as microturbines have increased the options for a broader range of fuels. By demonstrating practical means to consume the four gas streams, the project showed that any gases whose properties are between the extreme conditions also could be utilized. The economics of doing so depends on factors such as the value of additional oil recovered, the price of electricity produced, and the alternate costs to dispose of stranded gas.

  1. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was achieved at an average gas heat input of 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. The performance goal of 70% reduction was met on many test runs, but at a higher reburn gas heat input. S02 emissions, based on coal replacement, were reduced by 18Y0. Toward the end of the program, a Second Generation gas injection system was installed. Higher injector gas pressures were used that eliminated the need for flue gas recirculation as used in the first generation design. The Second Generation GR resulted in similar NOX reduction performance as that for the First Generation. With an improvement in the LNB performance in combination with the new gas injection system , the reburn gas could be reduced to 12.5% of the total boiler heat input to achieve al 64?40 reduction in NO, emissions. In addition, the OFA injectors were modified to provide for better mixing to lower CO emissions.

  2. Emissions trading: principles and practice. 2nd

    SciTech Connect (OSTI)

    Tietenberg, T.H.

    2006-02-15

    The author demonstrates how emissions trading became an attractive alternative to command-and-control policies that would have required the EPA to disallow the opening of new plants in the middle of the recession-burdened 1970s. His examination of the evolution of this system includes, among other applications, the largest multinational trading system ever conceived, the European Union's Greenhouse Gas Emission Trading Scheme (EUETG), and the use of emissions trading in the Kyoto Protocol.

  3. Transformative Reduction of Transportation Greenhouse Gas Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Boiler Circulation Pumps 100% 46% 100% 67% Other Uses 100% 19% 100% 27% Commercial Building Codes Low Building Code ... discussed immediate pressure points for transitioning ...

  4. Recommended Practice for Quantifying Greenhouse Gas Emissions...

    Open Energy Info (EERE)

    Public Transportation Association Website: www.apta.comresourceshottopicssustainabilityDocumentsQuantifying- Transport Toolkit Region(s): Australia & North America...

  5. EIA - Greenhouse Gas Emissions - Land use

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Additionally, the CO2 released from biofuel or bioenergy combustion is assumed to be fully ... There has been gradual growth of biofuel consumption in the commercial sector. Industrial ...

  6. Greenhouse Gas Emissions and Fuel Use

    Broader source: Energy.gov (indexed) [DOE]

    use (i.e., "lease fuel") is reported by the EIA. As explained below, this assumes a global warming potential of 25 for methane. 6 of the source rock (regional or play **...

  7. A Community Emissions Data System (CEDS) for Historical Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Zhou, Yuyu; Kyle, G. Page; Wang, Hailong; Yu, Hongbin

    2015-04-21

    Historical emission estimates for anthropogenic aerosol and precursor compounds are key data needed for Earth system models, climate models, and atmospheric chemistry and transport models; both for general analysis and assessment and also for model validation through comparisons with observations. Current global emission data sets have a number of shortcomings, including timeliness and transparency. Satellite and other earth-system data are increasingly available in near real-time, but global emission estimates lag by 5-10 years. The CEDS project will construct a data-driven, open source framework to produce annually updated emission estimates. The basic methodologies to be used for this system have been used for SO2 (Smith et al. 2011, Klimont, Smith and Cofala 2013), and are designed to complement existing inventory efforts. The goal of this system is to consistently extend current emission estimates both forward in time to recent years and also back over the entire industrial era. The project will produce improved datasets for global and (potentially) regional model, allow analysis of trends across time, countries, and sectors of emissions and emission factors, and facilitate improved scientific analysis in general. Consistent estimation of uncertainty will be an integral part of this system. This effort will facilitate community evaluation of emissions and further emission-related research more generally.

  8. Shale Gas R&D | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shale Gas R&D Shale Gas R&D Shale Gas R&D Natural gas from shales has the potential to significantly increase America's security of energy supply, reduce greenhouse gas emissions, and lower prices for consumers. Although shale gas has been produced in the United State for many decades, it was not considered to be a significant resource until the last decade when new horizontal drilling and hydraulic fracturing technology facilitated economic production. Shale gas currently

  9. Life Cycle Greenhouse Gas Emissions: Natural Gas and Power Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Laboratory Electricity Generation Forecast: 25% Growth in Next 20 Years EIA, AEO 2015: Reference Case 37% Coal ... a clearinghouse of information on technologies, ...

  10. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  11. Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas (CNG)-Powered Vehicles | Department of Energy Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_mauderly.pdf More Documents & Publications Relationship Between Composition and Toxicity of Engine Emission Samples

  12. Geothermal Power/Oil & Gas Coproduction Opportunity

    SciTech Connect (OSTI)

    DOE

    2012-02-01

    Coproduced geothermal resources can deliver near-term energy savings, diminish greenhouse gas emissions, extend the economic life of oil and gas fields, and profitably utilize oil and gas field infrastructure. This two-pager provides an overview of geothermal coproduced resources.

  13. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Gas Technology Institute (GTI), June 2011 | Department of Energy Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Presentation on Flexible CHP System with Low NOx, CO, and VOC Emissions, given by David Cygan of the Gas Technology Institute, at the U.S. DOE Industrial Distributed Energy Portfolio

  14. The estimation of N{sub 2}O emissions from municipal solid waste incineration facilities: The Korea case

    SciTech Connect (OSTI)

    Park, Sangwon; Choi, Jun-Ho; Park, Jinwon

    2011-08-15

    The greenhouse gases (GHGs) generated in municipal solid waste (MSW) incineration are carbon dioxide (CO{sub 2}), methane (CH{sub 4}), and nitrous oxide (N{sub 2}O). In South Korea case, the total of GHGs from the waste incineration facilities has been increasing at an annual rate 10%. In these view, waste incineration facilities should consider to reduce GHG emissions. This study is designed to estimate the N{sub 2}O emission factors from MSW incineration plants, and calculate the N{sub 2}O emissions based on these factors. The three MSW incinerators examined in this study were either stoker or both stoker and rotary kiln facilities. The N{sub 2}O concentrations from the MSW incinerators were measured using gas chromatography-electron capture detection (GC-ECD) equipment. The average of the N{sub 2}O emission factors for the M01 plant, M02 plant, and M03 plant are 71, 75, and 153 g-N{sub 2}O/ton-waste, respectively. These results showed a significant difference from the default values of the intergovernmental panel on climate change (IPCC), while approaching those values derived in Japan and Germany. Furthermore, comparing the results of this study to the Korea Energy Economics Institute (KEEI) (2007) data on waste incineration, N{sub 2}O emissions from MSW incineration comprised 19% of the total N{sub 2}O emissions.

  15. Top-down methane emissions estimates for the San Francisco Bay Area from 1990 to 2012

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fairley, David; Fischer, Marc L.

    2015-01-30

    Methane is a potent greenhouse gas (GHG) that is now included in both California State and San Francisco Bay Area (SFBA) bottom-up emission inventories as part of California's effort to reduce anthropogenic GHG emissions. Here we provide a top-down estimate of methane (CH4) emissions from the SFBA by combining atmospheric measurements with the comparatively better estimated emission inventory for carbon monoxide (CO). Local enhancements of CH4 and CO are estimated using measurements from 14 air quality sites in the SFBA combined together with global background measurements. Mean annual CH4 emissions are estimated from the product of Bay Area Air Qualitymore » Management District (BAAQMD) emission inventory CO and the slope of ambient local CH4 to CO. The resulting top-down estimates of CH4 emissions are found to decrease slightly from 1990 to 2012, with a mean value of 240 ± 60 GgCH4 yr⁻¹ (at 95% confidence) in the most recent (2009–2012) period, and correspond to reasonably a constant factor of 1.5–2.0 (at 95% confidence) times larger than the BAAQMD CH4 emission inventory. However, we note that uncertainty in these emission estimates is dominated by the variation in CH4:CO enhancement ratios across the observing sites and we expect the estimates could represent a lower-limit on CH4 emissions because BAAQMD monitoring sites focus on urban air quality and may be biased toward CO rather than CH4 sources.« less

  16. Top-down methane emissions estimates for the San Francisco Bay Area from 1990 to 2012

    SciTech Connect (OSTI)

    Fairley, David; Fischer, Marc L.

    2015-01-30

    Methane is a potent greenhouse gas (GHG) that is now included in both California State and San Francisco Bay Area (SFBA) bottom-up emission inventories as part of California's effort to reduce anthropogenic GHG emissions. Here we provide a top-down estimate of methane (CH4) emissions from the SFBA by combining atmospheric measurements with the comparatively better estimated emission inventory for carbon monoxide (CO). Local enhancements of CH4 and CO are estimated using measurements from 14 air quality sites in the SFBA combined together with global background measurements. Mean annual CH4 emissions are estimated from the product of Bay Area Air Quality Management District (BAAQMD) emission inventory CO and the slope of ambient local CH4 to CO. The resulting top-down estimates of CH4 emissions are found to decrease slightly from 1990 to 2012, with a mean value of 240 60 GgCH4 yr? (at 95% confidence) in the most recent (20092012) period, and correspond to reasonably a constant factor of 1.52.0 (at 95% confidence) times larger than the BAAQMD CH4 emission inventory. However, we note that uncertainty in these emission estimates is dominated by the variation in CH4:CO enhancement ratios across the observing sites and we expect the estimates could represent a lower-limit on CH4 emissions because BAAQMD monitoring sites focus on urban air quality and may be biased toward CO rather than CH4 sources.

  17. Natural Gas | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Natural Gas Many heavy-duty fleets depend on diesel fuel. But an increasing number of trucking companies are transitioning their vehicles to run on liquefied natural gas (LNG), reducing fuel costs and harmful emissions in the process. <a href="/node/655801">Learn more</a> about the Energy Department's work to advance natural gas vehicle technology. | Photo courtesy of New Haven Clean Cities Coalition. Many heavy-duty fleets depend on diesel fuel. But an

  18. NATURAL GAS FROM SHALE: Questions and Answers Shale Gas Development Challenges -

    Office of Environmental Management (EM)

    Air Key Points: * Air quality risks from shale oil and gas development are generally the result of: (1) dust and engine exhaust from increased truck traffic; (2) emissions from diesel-powered pumps used to power equipment; (3) intentional flaring or venting of gas for operational reasons; and, (4) unintentional emissions of pollutants from faulty equipment or impoundments. 1 * Natural gas is efficient and clean compared to other fossil fuels, emitting less nitrogen oxide and sulfur dioxide than

  19. Method and apparatus for transport, introduction, atomization and excitation of emission spectrum for quantitative analysis of high temperature gas sample streams containing vapor and particulates without degradation of sample stream temperature

    DOE Patents [OSTI]

    Eckels, David E.; Hass, William J.

    1989-05-30

    A sample transport, sample introduction, and flame excitation system for spectrometric analysis of high temperature gas streams which eliminates degradation of the sample stream by condensation losses.

  20. Greenhouse Gas Services AES GE EFS | Open Energy Information

    Open Energy Info (EERE)

    Services (AESGE EFS) Place: Arlington, Virginia Zip: 22203-4168 Product: Develop and invest in a range of projects that reduce greenhouse gas emissions that produce verified GHG...

  1. The Greenhouse Gas Protocol Initiative: Measurement and Estimation...

    Open Energy Info (EERE)

    GHG Emissions AgencyCompany Organization: World Resources Institute, World Business Council for Sustainable Development Sector: Energy, Climate Focus Area: Greenhouse Gas Phase:...

  2. DOE Releases Draft Strategic Plan for Reducing Greenhouse Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of new and advanced technologies that avoid, reduce, or capture and store greenhouse gas emissions - the technology component of a comprehensive U.S. approach to climate change. ...

  3. The Use of Exhaust Gas Recirculation to Optimize Fuel Economy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Use of Exhaust Gas Recirculation to Optimize Fuel Economy and Minimize Emissions in Engines Operating on E85 Fuel 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  4. Automotive Fuel Efficiency Improvement via Exhaust Gas Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Waste Heat Conversion to Electricity Working to expand the usage of thermoelectric technology beyond seat heating and cooling and in doing so reduce CO2 emissions and...

  5. Life Cycle Assessment of Hydrogen Production via Natural Gas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A life cycle assessment of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases as well as other major environmental ...

  6. Natural Gas Engine Development: July 2003 -- July 2005

    SciTech Connect (OSTI)

    Lekar, T. C.; Martin, T. J.

    2006-11-01

    Discusses project to develop heavy-duty, 8.1L natural gas vehicle engines that would be certifiable below the 2004 federal emissions standards and commercially viable.

  7. Natural Gas Engine Development: July 2003--July 2005

    SciTech Connect (OSTI)

    Lekar, T. C.; Martin, T. J.

    2006-03-01

    Describes project to develop natural gas engines that would be certifiable to nitrogen oxide and nonmethane hydrocarbon emission levels below 2004 federal standards.

  8. Using landfill gas for energy: Projects that pay

    SciTech Connect (OSTI)

    1995-02-01

    Pending Environmental Protection Agency regulations will require 500 to 700 landfills to control gas emissions resulting from decomposing garbage. Conversion of landfill gas to energy not only meets regulations, but also creates energy and revenue for local governments.

  9. US10 Capable Prototype Volvo MG11 Natural Gas Engine Development: Final Report, December 16, 2003 - July 31, 2006

    SciTech Connect (OSTI)

    Tai, C.; Reppert, T.; Chiu, J.; Christensen, L.; Knoll, K.; Stewart, J.

    2006-10-01

    The report discusses a project to develop a low-emissions natural gas engine with exhaust gas recirculation (EGR) and a three-way catalyst (TWC).

  10. Measurements of volatile organic compounds at a suburban ground site (T1) in Mexico City during the MILAGRO 2006 campaign: Measurement comparison, emission ratios, and source attribution

    SciTech Connect (OSTI)

    Bon, D.M.; Springston, S.; M.Ulbrich, I.; de Gouw, J. A.; Warneke, C.; Kuster, W. C.; Alexander, M. L.; Baker, A.; Beyersdorf, A. J.; Blake, D.; Fall, R.; Jimenez, J. L., Herndon, S. C.; Huey, L. G.; Knighton, W. B.; Ortega, J.; Vargas, O.

    2011-03-16

    Volatile organic compound (VOC) mixing ratios were measured with two different instruments at the T1 ground site in Mexico City during the Megacity Initiative: Local and Global Research Observations (MILAGRO) campaign in March of 2006. A gas chromatograph with flame ionization detector (GC-FID) quantified 18 light alkanes, alkenes and acetylene while a proton-transfer-reaction ion-trap mass spectrometer (PIT-MS) quantified 12 VOC species including oxygenated VOCs (OVOCs) and aromatics. A GC separation system was used in conjunction with the PIT-MS (GC-PIT-MS) to evaluate PIT-MS measurements and to aid in the identification of unknown VOCs. The VOC measurements are also compared to simultaneous canister samples and to two independent proton-transfer-reaction mass spectrometers (PTR-MS) deployed on a mobile and an airborne platform during MILAGRO. VOC diurnal cycles demonstrate the large influence of vehicle traffic and liquid propane gas (LPG) emissions during the night and photochemical processing during the afternoon. Emission ratios for VOCs and OVOCs relative to CO are derived from early-morning measurements. Average emission ratios for non-oxygenated species relative to CO are on average a factor of {approx}2 higher than measured for US cities. Emission ratios for OVOCs are estimated and compared to literature values the northeastern US and to tunnel studies in California. Positive matrix factorization analysis (PMF) is used to provide insight into VOC sources and processing. Three PMF factors were distinguished by the analysis including the emissions from vehicles, the use of liquid propane gas and the production of secondary VOCs + long-lived species. Emission ratios to CO calculated from the results of PMF analysis are compared to emission ratios calculated directly from measurements. The total PIT-MS signal is summed to estimate the fraction of identified versus unidentified VOC species.

  11. The efficient use of natural gas in transportation

    SciTech Connect (OSTI)

    Stodolsky, F.; Santini, D.J.

    1992-04-01

    Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

  12. The efficient use of natural gas in transportation

    SciTech Connect (OSTI)

    Stodolsky, F.; Santini, D.J.

    1992-01-01

    Concerns over air quality and greenhouse gas emissions have prompted discussion as well as action on alternative fuels and energy efficiency. Natural gas and natural gas derived fuels and fuel additives are prime alternative fuel candidates for the transportation sector. In this study, we reexamine and add to past work on energy efficiency and greenhouse gas emissions of natural gas fuels for transportation (DeLuchi 1991, Santini et a. 1989, Ho and Renner 1990, Unnasch et al. 1989). We add to past work by looking at Methyl tertiary butyl ether (from natural gas and butane component of natural gas), alkylate (from natural gas butanes), and gasoline from natural gas. We also reexamine compressed natural gas, liquified natural gas, liquified petroleum gas, and methanol based on our analysis of vehicle efficiency potential. We compare the results against nonoxygenated gasoline.

  13. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  14. Energy Department Projects Focus on Sustainable Natural Gas Development |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Projects Focus on Sustainable Natural Gas Development Energy Department Projects Focus on Sustainable Natural Gas Development January 10, 2013 - 1:00pm Addthis Today shale gas accounts for about 25 percent of our natural gas production. And experts believe this abundant supply will mean lower energy costs for millions of families; fewer greenhouse gas emissions; and more American jobs. | Photo courtesy of the EIA. Today shale gas accounts for about 25 percent of our

  15. Relationship Between Composition and Toxicity of Engine Emission Samples |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Emission Samples Relationship Between Composition and Toxicity of Engine Emission Samples 2003 DEER Conference Presentation: Lovelace Respiratory Research Institute PDF icon 2003_deer_mauderly.pdf More Documents & Publications Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles Comparative Toxicity of Combined Particle and Semi-Volatile Organic Fractioins of Gasoline and Diesel Emissions Relationship Between

  16. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, B.T.; Arasteh, D.K.; Selkowitz, S.E.

    1993-12-14

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation. 18 figures.

  17. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, Brent T. (Berkeley, CA); Arasteh, Dariush K. (Oakland, CA); Selkowitz, Stephen E. (Piedmont, CA)

    1993-01-01

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation.

  18. Gas-Saving Tips

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Gas-Saving Tips Some consumers believe fuel economy ratings are a fixed number, like engine size or cargo volume. However, a vehicle's fuel economy can vary significantly due to several factors, including how the vehicle is driven, the vehicle's mechanical condition, and the environment in which it is driven. Fortunately, you may be able to improve your vehicle's gas mileage through proper maintenance and driving habits. Studies suggest the average driver can improve his/her fuel economy by

  19. Emissions of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans from the open burning of household waste in barrels

    SciTech Connect (OSTI)

    Lemieux, P.M.; Lutes, C.C.; Abbott, J.A.; Aldous, K.M.

    2000-02-01

    Backyard burning of household waste in barrels is a common waste disposal practice for which pollutant emissions have not been well characterized. This study measured the emissions of several pollutants, including polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/PCDFs), from burning mixtures designed to simulate waste generated by a recycling and a nonrecycling family in a 208-L (55-gal) burn barrel at the EPA's Open Burning Test Facility. This paper focuses on the PCDD/PCDF emissions and discusses the factors influencing PCDD/PCDF formation for different test burns. Four test burns were made in which the amount of waste placed in the barrel varied from 6.4 to 13.6 kg and the amount actually burned varied from 46.6% to 68.1%. Emissions of total PCDDs/PCDFs ranged between 0.0046 and 0.48 mg/kg of waste burned. Emissions are also presented in terms of 2,3,7,8-TCDD toxic equivalents. Emissions of PCDDs/PCDFs appear to correlate with both copper and hydrochloric acid emissions. The results of this study indicate that backyard burning emits more PCDDs/PCDFs on a mass of refuse burned basis than various types of municipal waste combustors (MWCs). Comparison of burn barrel emissions to emissions from a hypothetical modern MWC equipped with high-efficiency flue gas cleaning technology indicates that about 2--40 households burning their trash daily in barrels can produce average PCDD/PCDF emissions comparable to a 182,000 kg/day (200 ton/day) MWC facility. This study provides important data on a potentially significant source of emissions of PCDDs/PCDFs.

  20. Greenhouse Gas Reductions: SF6

    ScienceCinema (OSTI)

    Anderson, Diana

    2013-04-19

    Argonne National Laboratory is leading the way in greenhouse gas reductions, particularly with the recapture and recycling of sulfur hexafluoride (SF6). SF6 is a gas used in industry as an anti-arcing agent. It is an extremely potent greenhouse gas ? one pound of SF6 is equivalent to 12 tons of carbon dioxide. While the U.S. does not currently regulate SF6 emissions, Argonne is proactively and voluntarily recovering and recycling to reduce SF6 emissions. Argonne saves over 16,000 tons of SF6 from being emitted into the atmosphere each year, and by recycling the gas rather than purchasing it new, we save taxpayers over $208,000 each year.

  1. Methods for reduction of charging emissions

    SciTech Connect (OSTI)

    Schuecker, F.J.; Schulte, H.

    1997-12-31

    One of the most critical subjects in coking plants are charging emissions. The paper reviews the systems that have been used over the years to reduce charging emissions. The advantages and disadvantages are summarized for the following systems: Double collecting main with aspiration on both oven sides; Single collecting main with/without aspiration via standpipe, and extraction and cleaning of charging gas on charging car; Single collecting main with aspiration via standpipe and pretreatment of charging gas on the charging car as well as additional stationary exhaust and cleaning of charging gas; Single collecting main with aspiration via single standpipe; and Single collecting main with simultaneous aspiration via two standpipes and a U-tube connecting the oven chamber with the neighboring oven. The paper then briefly discusses prerequisites for reduction of charging emissions.

  2. Fuel-based motor vehicle emission inventory

    SciTech Connect (OSTI)

    Singer, B.C.; Harley, R.A.

    1996-06-01

    A fuel-based methodology for calculating motor vehicle emission inventories is presented. In the fuel-based method, emission factors are normalized to fuel consumption and expressed as grams of pollutant emitted per gallon of gasoline burned. Fleet-average emission factors are calculated from the measured on-road emissions of a large, random sample of vehicles. Using this method, a fuel-based motor vehicle CO inventory was calculated for the South Coast Air Basin in California for summer 1991. Emission factors were calculated from remote sensing measurements of more than 70,000 in-use vehicles. Results of the study are presented and a conclusion is provided. 40 refs., 4 figs., 6 tabs.

  3. Optical backscatter probe for sensing particulate in a combustion gas stream

    DOE Patents [OSTI]

    Parks, James E; Partridge, William P

    2013-05-28

    A system for sensing particulate in a combustion gas stream is disclosed. The system transmits light into a combustion gas stream, and thereafter detects a portion of the transmitted light as scattered light in an amount corresponding to the amount of particulates in the emissions. Purge gas may be supplied adjacent the light supply and the detector to reduce particles in the emissions from coating or otherwise compromising the transmission of light into the emissions and recovery of scattered light from the emissions.

  4. Fact #589: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions Standards | Department of Energy 9: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards Fact #589: September 21, 2009 Proposed Fuel Economy and Greenhouse Gas Emissions Standards On September 15, the U.S. Environmental Protection Agency (EPA) and U.S. Department of Transportation's National Highway Traffic Safety Administration (NHTSA) jointly announced a proposal to establish national standards for greenhouse gas (GHG) emissions and Corporate Average

  5. Flexible CHP System with Low NOx, CO and VOC Emissions - Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 Flexible CHP System with Low NOx, CO and VOC Emissions - Fact Sheet, 2014 The Gas Technology Institute, in ...

  6. Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible CHP System with Low NOx, CO, and VOC Emissions - Presentation by the Gas Technology Institute (GTI), June 2011 Flexible CHP System with Low NOx, CO, and VOC Emissions - ...

  7. Buildings Energy Data Book: 3.4 Commercial Environmental Emissions

    Buildings Energy Data Book [EERE]

    6 2009 Methane Emissions for U.S. Commercial Buildings Energy Production, by Fuel Type (1) Fuel Type Petroleum 0.5 Natural Gas 26.8 Coal 0.3 Wood 0.4 Electricity (2) 50.5 Total 78.5 Note(s): Source(s): MMT CO2 Equivalent 1) Sources of emissions include oil and gas production, processing, and distribution; coal mining; and utility and site combustion. Carbon Dioxide equivalent units are calculated by converting methane emissions to carbon dioxide emissions (methane's global warming potential is

  8. Integration of oxygen plants and gas turbines in IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Sorensen, J.C.; Woodward, D.W.

    1996-10-01

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NO{sub x} emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper reviews basic integration principles, highlights the integration scheme used at Polk County, and describes some advanced concepts based on emerging gas turbines. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  9. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species, hydrogen chloride and hydrogen fluoride.

  10. Advanced Emission Control Development Program.

    SciTech Connect (OSTI)

    Evans, A.P.

    1997-12-31

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W`s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  11. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    M. J. Holmes

    1998-12-03

    McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using the Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and hydrogen chloride and hydrogen fluoride.

  12. Advanced Emissions Control Development Program

    SciTech Connect (OSTI)

    A. P. Evans

    1998-12-03

    Babcock & Wilcox (B&W) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities with the technical and economic information necessary to reliably evaluate various air toxics emissions compliance options such as fuel switching, coal cleaning, and flue gas treatment. The development work is being carried out using B&W?s new Clean Environment Development Facility (CEDF) wherein air toxics emissions control strategies can be developed under controlled conditions, and with proven predictability to commercial systems. Tests conducted in the CEDF provide high quality, repeatable, comparable data over a wide range of coal properties, operating conditions, and emissions control systems. Development work to date has concentrated on the capture of mercury, other trace metals, fine particulate, and the inorganic species hydrogen chloride and hydrogen fluoride.

  13. Optical and Physical Properties from Primary On-Road Vehicle ParticleEmissions And Their Implications for Climate Change

    SciTech Connect (OSTI)

    Strawa, A.W.; Kirchstetter, T.W.; Hallar, A.G.; Ban-Weiss, G.A.; McLaughlin, J.P.; Harley, R.A.; Lunden, M.M.

    2009-01-23

    During the summers of 2004 and 2006, extinction and scattering coefficients of particle emissions inside a San Francisco Bay Area roadway tunnel were measured using a combined cavity ring-down and nephelometer instrument. Particle size distributions and humidification were also measured, as well as several gas phase species. Vehicles in the tunnel traveled up a 4% grade at a speed of approximately 60 km h{sup -1}. The traffic situation in the tunnel allows the apportionment of emission factors between light duty gasoline vehicles and diesel trucks. Cross-section emission factors for optical properties were determined for the apportioned vehicles to be consistent with gas phase and particulate matter emission factors. The absorption emission factor (the absorption cross-section per mass of fuel burned) for diesel trucks (4.4 {+-} 0.79 m{sup 2} kg{sup -1}) was 22 times larger than for light-duty gasoline vehicles (0.20 {+-} 0.05 m{sup 2} kg{sup -1}). The single scattering albedo of particles - which represents the fraction of incident light that is scattered as opposed to absorbed - was 0.2 for diesel trucks and 0.3 for light duty gasoline vehicles. These facts indicate that particulate matter from motor vehicles exerts a positive (i.e., warming) radiative climate forcing. Average particulate mass absorption efficiencies for diesel trucks and light duty gasoline vehicles were 3.14 {+-} 0.88 m{sup 2} g{sub PM}{sup -1} and 2.9 {+-} 1.07 m{sup 2} g{sub PM}{sup -1}, respectively. Particle size distributions and optical properties were insensitive to increases in relative humidity to values in excess of 90%, reinforcing previous findings that freshly emitted motor vehicle particulate matter is hydrophobic.

  14. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    SciTech Connect (OSTI)

    McMeeking, Gavin R.; Kreidenweis, Sonia M.; Baker, Stephen; Carrico, Christian M.; Chow, Judith C.; Collett, Jr., Jeffrey L.; Hao, Wei Min; Holden, Amanda S.; Kirchstetter, Thomas W.; Malm, William C.; Moosmuller, Hans; Sullivan, Amy P.; Wold, Cyle E.

    2009-05-15

    We characterized the gas- and speciated aerosol-phase emissions from the open combustion of 33 different plant species during a series of 255 controlled laboratory burns during the Fire Laboratory at Missoula Experiments (FLAME). The plant species we tested were chosen to improve the existing database for U.S. domestic fuels: laboratory-based emission factors have not previously been reported for many commonly-burned species that are frequently consumed by fires near populated regions and protected scenic areas. The plants we tested included the chaparral species chamise, manzanita, and ceanothus, and species common to the southeastern US (common reed, hickory, kudzu, needlegrass rush, rhododendron, cord grass, sawgrass, titi, and wax myrtle). Fire-integrated emission factors for gas-phase CO{sub 2}, CO, CH{sub 4}, C{sub 2-4} hydrocarbons, NH{sub 3}, SO{sub 2}, NO, NO{sub 2}, HNO{sub 3} and particle-phase organic carbon (OC), elemental carbon (EC), SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, Cl{sup -}, Na{sup +}, K{sup +}, and NH{sub 4}{sup +} generally varied with both fuel type and with the fire-integrated modified combustion efficiency (MCE), a measure of the relative importance of flaming- and smoldering-phase combustion to the total emissions during the burn. Chaparral fuels tended to emit less particulate OC per unit mass of dry fuel than did other fuel types, whereas southeastern species had some of the largest observed EF for total fine particulate matter. Our measurements often spanned a larger range of MCE than prior studies, and thus help to improve estimates for individual fuels of the variation of emissions with combustion conditions.

  15. Table 2. 2011 State energy-related carbon dioxide emissions by...

    U.S. Energy Information Administration (EIA) Indexed Site

    2011 State energy-related carbon dioxide emissions by fuel " ,"million metric tons of carbon dioxide",,,,,"shares" "State","Coal","Petroleum","Natural Gas ","Total",,"Coal","Petrol...

  16. Low Carbon Grid Study: Analysis of a 50% Emission Reduction in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... options tend to increase cycling at California gas generators; storage and demand response can help reduce emissions and curtailment while reducing cycling. * Imports from ...

  17. Method of depositing a high-emissivity layer

    DOE Patents [OSTI]

    Wickersham, Charles E. (Columbus, OH); Foster, Ellis L. (Powell, OH)

    1983-01-01

    A method of depositing a high-emissivity layer on a substrate comprising RF sputter deposition of a carbide-containing target in an atmosphere of a hydrocarbon gas and a noble gas. As the carbide is deposited on the substrate the hydrocarbon gas decomposes to hydrogen and carbon. The carbon deposits on the target and substrate causing a carbide/carbon composition gradient to form on the substrate. At a sufficiently high partial pressure of hydrocarbon gas, a film of high-emissivity pure carbon will eventually form over the substrate.

  18. CAN DUST EMISSION BE USED TO ESTIMATE THE MASS OF THE INTERSTELLAR MEDIUM IN GALAXIES-A PILOT PROJECT WITH THE HERSCHEL REFERENCE SURVEY

    SciTech Connect (OSTI)

    Eales, Stephen; Smith, Matthew W. L.; Auld, Robbie; Davies, Jon; Gear, Walter; Gomez, Haley; Baes, Maarten; De Looze, Ilse; Gentile, Gianfranco; Fritz, Jacopo; Bendo, George J.; Bianchi, Simone; Boselli, Alessandro; Ciesla, Laure; Clements, David; Cooray, Asantha; Cortese, Luca; Galametz, Maud; Hughes, Tom; Madden, Suzanne [Laboratoire AIM, CEA and others

    2012-12-20

    The standard method for estimating the mass of the interstellar medium (ISM) in a galaxy is to use the 21 cm line to trace the atomic gas and the CO 1-0 line to trace the molecular gas. In this paper, we investigate the alternative technique of using the continuum dust emission to estimate the mass of gas in all phases of the ISM. Using Herschel observations of 10 galaxies from the Herschel Reference Survey and the Herschel Virgo Cluster Survey, we show that the emission detected by Herschel is mostly from dust that has a temperature and emissivity index similar to that of dust in the local ISM in our galaxy, with the temperature generally increasing toward the center of each galaxy. We calibrate the dust method using the CO and 21 cm observations to provide an independent estimate of the mass of hydrogen in each galaxy, solving the problem of the uncertain ''X-factor'' for the CO observations by minimizing the dispersion in the ratio of the masses estimated using the two methods. With the calibration for the dust method and the estimate of the X-factor produced in this way, the dispersion in the ratio of the two gas masses is 25%. The calibration we obtain for the dust method is similar to those obtained from Herschel observations of M31 and from Planck observations of the Milky Way. We discuss the practical problems in using this method.

  19. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  20. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  1. Methane sources and emissions in Italy

    SciTech Connect (OSTI)

    Guidotti, G.R.; Castagnola, A.M.

    1994-12-31

    Methane emissions in Italy were assessed in the framework of the measures taken to follow out the commitments undertaken at the 1992 U.N. Conference for Environment and Development. Methane emissions of anthropic origin were estimated to be in the range of 1.6 to 2.3 million ton of methane per year. Some of these methane sources (natural gas production, transmission and distribution; rice paddies; managed livestock enteric fermentation and waste; solid waste landfills) are given here particular care as they mainly contribute to the total methane emission budget.

  2. U.S. Energy-Related Carbon Dioxide Emissions, 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Washington, DC 20585 November 2015 U.S. Energy Information Administration | U.S. ... two factors in the generation of electricity that have allowed emissions to ...

  3. Virginia Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  4. Colorado Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Colorado Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  5. Nebraska Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Nebraska Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  6. Missouri Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Missouri Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  7. Michigan Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Michigan Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  8. Kentucky Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Kentucky Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  9. Tennessee Natural Gas Number of Gas and Gas Condensate Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Tennessee Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  10. Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Pennsylvania Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  11. Mississippi Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Mississippi Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4...

  12. Oklahoma Natural Gas Number of Gas and Gas Condensate Wells ...

    Gasoline and Diesel Fuel Update (EIA)

    Gas and Gas Condensate Wells (Number of Elements) Oklahoma Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  13. Illinois Natural Gas Number of Gas and Gas Condensate Wells ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas and Gas Condensate Wells (Number of Elements) Illinois Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  14. Arkansas Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Arkansas Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  15. Maryland Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Maryland Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  16. Louisiana Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Louisiana Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  17. Energy Forecasting Framework and Emissions Consensus Tool (EFFECT...

    Open Energy Info (EERE)

    Tool (EFFECT) EFFECT is an open, Excel-based modeling tool used to forecast greenhouse gas emissions from a range of development scenarios at the regional and national levels....

  18. Short-Term Energy Carbon Dioxide Emissions Forecasts August 2009

    Reports and Publications (EIA)

    2009-01-01

    Supplement to the Short-Term Energy Outlook. Short-term projections for U.S. carbon dioxide emissions of the three fossil fuels: coal, natural gas, and petroleum.

  19. NETL - World CO2 Emissions - Projected Trends Tool | Open Energy...

    Open Energy Info (EERE)

    to look at both total and power sector CO2 emissions from the use of coal, oil, or natural gas, over the period 1990 to 2030. One can use the tool to compare five of the larger...

  20. Power plant emissions verified remotely at Four Corners sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Space-based measurements can support Clean Air Act regulations LOS ALAMOS, N.M., May 19, 2014-Air pollution and greenhouse gas emissions from two coal-fired power plants in the ...

  1. Discussion of ``Comparison of air emissions from waste management facilities``

    SciTech Connect (OSTI)

    1996-12-31

    The analysis of emissions from landfills is questioned. Why are the emissions estimated compared on a peak-year rather that on a life-cycle basis? The authors reply that unlike most traditional air pollutant sources, the annual emissions of landfill gas vary markedly, depending on the pace of MSW decomposition over the years. The peak-year emission rate projected over the landfill`s lifetime is what is compared to regulatory emission thresholds to determine whether Title V permitting, etc. applies.

  2. Final Technical Report HFC Concrete: A Low-???????­???¢???????Energy, Carbon-???????­Dioxide-???????­Negative Solution for reducing Industrial Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dr. Larry McCandlish, Principal Investigator; Dr. Richard Riman, Co-Principal Investigator

    2012-05-14

    Solidia/CCSM received funding for further research and development of its Low Temperature Solidification Process (LTS), which is used to create hydrate-free concrete (HFC). LTS/HFC is a technology/materials platform that offers wide applicability in the built infrastructure. Most importantly, it provides a means of making concrete without Portland cement. Cement and concrete production is a major consumer of energy and source of industrial greenhouse gas (GHG) emissions. The primary goal of this project was to develop and commercialize a novel material, HFC, which by replacing traditional concrete and cement, reduces both energy use and GHG emissions in the built infrastructure. Traditional concrete uses Portland Cement (PC) as a binder. PC production involves calcination of limestone at {approx}1450 C, which releases significant amounts of CO{sub 2} gas to the atmosphere and consumes a large amount of energy due to the high temperature required. In contrast, HFC is a carbonate-based hydrate-free concrete (HFC) that consumes CO{sub 2} gas in its production. HFC is made by reaction of silicate minerals with CO{sub 2} at temperatures below 100 C, more than an order-of-magnitude below the temperature required to make PC. Because of this significant difference in temperature, it is estimated that we will be able to reduce energy use in the cement and concrete industry by up to 30 trillion Btu by 2020. Because of the insulating properties of HFC, we believe we will also be able to significantly reduce energy use in the Building sector, though the extent of this saving is not yet quantified. It is estimated that production of a tonne of PC-based concrete requires about 6.2 million Btu of energy and produces over 1 tonne of CO{sub 2} emissions (Choate, 2003). These can be reduced to 1.9 million Btu and 0.025 tonnes of CO{sub 2} emissions per tonne of HFC (with overall CO{sub 2}-negativity possible by increasing carbonation yield). In this way, by replacing PC-based concrete with HFC in infrastructure we can reduce energy use in concrete production by 70%, and reduce CO{sub 2} emissions by 98%; thus the potential to reduce the impact of building materials on global warming and climate change is highly significant. Low Temperature Solidification (LTS) is a breakthrough technology that enables the densification of inorganic materials via a hydrothermal process. The resulting product exhibits excellent control of chemistry and microstructure, to provide durability and mechanical performance that exceeds that of concrete or natural stone. The technology can be used in a wide range of applications including facade panels, interior tiles, roof tiles, countertops, and pre-cast concrete. Replacing traditional building materials and concrete in these applications will result in significant reduction in both energy consumption and CO{sub 2} emissions.

  3. Field Emission and Nanostructure of Carbon Films

    SciTech Connect (OSTI)

    Merkulov, V.I.; Lowndes, D.H.; Baylor, L.R.

    1999-11-29

    The results of field emission measurements of various forms of carbon films are reported. It is shown that the films nanostructure is a crucial factor determining the field emission properties. In particular, smooth, pulsed-laser deposited amorphous carbon films with both high and low sp3 contents are poor field emitters. This is similar to the results obtained for smooth nanocrystalline, sp2-bonded carbon films. In contrast, carbon films prepared by hot-filament chemical vapor deposition (HE-CVD) exhibit very good field emission properties, including low emission turn-on fields, high emission site density, and excellent durability. HF-CVD carbon films were found to be predominantly sp2-bonded. However, surface morphology studies show that these films are thoroughly nanostructured, which is believed to be responsible for their promising field emission properties.

  4. Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks

    Energy Savers [EERE]

    Public Comment | Department of Energy Greenhouse Gas Reporting Guidance, Seeks Public Comment Energy Department Releases New Greenhouse Gas Reporting Guidance, Seeks Public Comment March 22, 2005 - 10:54am Addthis Program Will Ensure Greater Accuracy & Completeness WASHINGTON, D.C. - The U.S. Department of Energy (DOE) today asked for further public comment on its revised guidelines for voluntary reporting of greenhouse gas emissions, sequestration and emission reductions. The program

  5. CleanFleet. Final report: Volume 7, vehicle emissions

    SciTech Connect (OSTI)

    1995-12-01

    Measurements of exhaust and evaporative emissions from Clean Fleet vans running on M-85, compressed natural gas (CNG), California Phase 2 reformulated gasoline (RFG), propane gas, and a control gasoline (RF-A) are presented. Three vans from each combination of vehicle manufacturer and fuel were tested at the California Air Resources Board (ARB) as they accumulated mileage in the demonstration. Data are presented on regulated emissions, ozone precursors, air toxics, and greenhouse gases. The emissions tests provide information on in-use emissions. That is, the vans were taken directly from daily commercial service and tested at the ARB. The differences in alternative fuel technology provide the basis for a range of technology options. The emissions data reflect these differences, with classes of vehicle/fuels producing either more or less emissions for various compounds relative to the control gasoline.

  6. Anisotropic Lyman-alpha emission

    SciTech Connect (OSTI)

    Zheng, Zheng; Wallace, Joshua

    2014-10-20

    As a result of resonant scatterings off hydrogen atoms, Ly? emission from star-forming galaxies provides a probe of the (hardly isotropic) neutral gas environment around them. We study the effect of the environmental anisotropy on the observed Ly? emission by performing radiative transfer calculations for models of neutral hydrogen clouds with prescriptions of spatial and kinematic anisotropies. The environmental anisotropy leads to corresponding anisotropy in the Ly? flux and spectral properties and induces correlations among them. The Ly? flux (or observed luminosity) depends on the viewing angle and shows an approximate correlation with the initial Ly? optical depth in the viewing direction relative to those in all other directions. The distribution of Ly? flux from a set of randomly oriented clouds is skewed to high values, providing a natural contribution to the Ly? equivalent width (EW) distribution seen in observation. A narrower EW distribution is found at a larger peak offset of the Ly? line, similar to the trend suggested in observation. The peak offset appears to correlate with the line shape (full width at half-maximum and asymmetry), pointing to a possibility of using Ly? line features alone to determine the systemic redshifts of galaxies. The study suggests that anisotropies in the spatial and kinematic distributions of neutral hydrogen can be an important ingredient in shaping the observed properties of Ly? emission from star-forming galaxies. We discuss the implications of using Ly? emission to probe the circumgalactic and intergalactic environments of galaxies.

  7. ALMA imaging of gas and dust in a galaxy protocluster at redshift 5.3: [C II] emission in 'typical' galaxies and dusty starbursts ?1 billion years after the big bang

    SciTech Connect (OSTI)

    Riechers, Dominik A.; Carilli, Christopher L.; Capak, Peter L.; Yan, Lin; Scoville, Nicholas Z.; Smol?i?, Vernesa; Schinnerer, Eva; Yun, Min; Cox, Pierre; Bertoldi, Frank; Karim, Alexander

    2014-12-01

    We report interferometric imaging of [C II]({sup 2} P {sub 3/2}?{sup 2} P {sub 1/2}) and OH({sup 2}?{sub 1/2} J = 3/2?1/2) emission toward the center of the galaxy protocluster associated with the z = 5.3 submillimeter galaxy (SMG) AzTEC-3, using the Atacama Large (sub)Millimeter Array (ALMA). We detect strong [C II], OH, and rest-frame 157.7 ?m continuum emission toward the SMG. The [C II]({sup 2} P {sub 3/2}?{sup 2} P {sub 1/2}) emission is distributed over a scale of 3.9 kpc, implying a dynamical mass of 9.7 10{sup 10} M {sub ?}, and a star formation rate (SFR) surface density of ?{sub SFR} = 530 M {sub ?} yr{sup 1} kpc{sup 2}. This suggests that AzTEC-3 forms stars at ?{sub SFR} approaching the Eddington limit for radiation pressure supported disks. We find that the OH emission is slightly blueshifted relative to the [C II] line, which may indicate a molecular outflow associated with the peak phase of the starburst. We also detect and dynamically resolve [C II]({sup 2} P {sub 3/2}?{sup 2} P {sub 1/2}) emission over a scale of 7.5 kpc toward a triplet of Lyman-break galaxies with moderate UV-based SFRs in the protocluster at ?95 kpc projected distance from the SMG. These galaxies are not detected in the continuum, suggesting far-infrared SFRs of <18-54 M {sub ?} yr{sup 1}, consistent with a UV-based estimate of 22 M {sub ?} yr{sup 1}. The spectral energy distribution of these galaxies is inconsistent with nearby spiral and starburst galaxies, but resembles those of dwarf galaxies. This is consistent with expectations for young starbursts without significant older stellar populations. This suggests that these galaxies are significantly metal-enriched, but not heavily dust-obscured, 'normal' star-forming galaxies at z > 5, showing that ALMA can detect the interstellar medium in 'typical' galaxies in the very early universe.

  8. Emission control cost-effectiveness of alternative-fuel vehicles

    SciTech Connect (OSTI)

    Wang, Q.; Sperling, D.; Olmstead, J.

    1993-06-14

    Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. Emission control cost-effectiveness presented in dollars per ton of emission reduction was calculated for each alternative-fuel vehicle types from the estimated vehicle life-cycle emission reductions and costs. Among various alternative-fuel vehicle types, compressed natural gas vehicles are the most cost-effective vehicle type in controlling vehicle emissions. Dedicated methanol vehicles are the next most cost-effective vehicle type. The cost-effectiveness of electric vehicles depends on improvements in electric vehicle battery technology. With low-cost, high-performance batteries, electric vehicles are more cost-effective than methanol, ethanol, and liquified petroleum gas vehicles.

  9. Emissions Benefits of Distributed Generation in the Texas Market

    SciTech Connect (OSTI)

    Hadley, SW

    2005-06-16

    One potential benefit of distributed generation (DG) is a net reduction in air emissions. While DG will produce emissions, most notably carbon dioxide and nitrogen oxides, the power it displaces might have produced more. This study used a system dispatch model developed at Oak Ridge National Laboratory to simulate the 2012 Texas power market with and without DG. This study compares the reduction in system emissions to the emissions from the DG to determine the net savings. Some of the major findings are that 85% of the electricity displaced by DG during peak hours will be simple cycle natural gas, either steam or combustion turbine. Even with DG running as baseload, 57% of electricity displaced will be simple cycle natural gas. Despite the retirement of some gas-fired steam units and the construction of many new gas turbine and combined cycle units, the marginal emissions from the system remain quite high (1.4 lb NO{sub x}/MWh on peak and 1.1 lb NO{sub x}/MWh baseload) compared to projected DG emissions. Consequently, additions of DG capacity will reduce emissions in Texas from power generation in 2012. Using the DG exhaust heat for combined heat and power provides an even greater benefit, since it eliminates further boiler emissions while adding none over what would be produced while generating electricity. Further studies are warranted concerning the robustness of the result with changes in fuel prices, demands, and mixes of power generating technology.

  10. Effect of Fuel Wobbe Number on Pollutant Emissions from Advanced Technology Residential Water Heaters: Results of Controlled Experiments

    SciTech Connect (OSTI)

    Rapp, Vi H.; Singer, Brett C.

    2014-03-01

    The research summarized in this report is part of a larger effort to evaluate the potential air quality impacts of using liquefied natural gas in California. A difference of potential importance between many liquefied natural gas blends and the natural gas blends that have been distributed in California in recent years is the higher Wobbe number of liquefied natural gas. Wobbe number is a measure of the energy delivery rate for appliances that use orifice- or pressure-based fuel metering. The effect of Wobbe number on pollutant emissions from residential water heaters was evaluated in controlled experiments. Experiments were conducted on eight storage water heaters, including five with “ultra low-NO{sub X}” burners, and four on-demand (tankless) water heaters, all of which featured ultra low-NO{sub X} burners. Pollutant emissions were quantified as air-free concentrations in the appliance flue and fuel-based emission factors in units of nanogram of pollutant emitter per joule of fuel energy consumed. Emissions were measured for carbon monoxide (CO), nitrogen oxides (NO{sub X}), nitrogen oxide (NO), formaldehyde and acetaldehyde as the water heaters were operated through defined operating cycles using fuels with varying Wobbe number. The reference fuel was Northern California line gas with Wobbe number ranging from 1344 to 1365. Test fuels had Wobbe numbers of 1360, 1390 and 1420. The most prominent finding was an increase in NO{sub X} emissions with increasing Wobbe number: all five of the ultra low-NO{sub X} storage water heaters and two of the four ultra low-NO{sub X} on-demand water heaters had statistically discernible (p<0.10) increases in NO{sub X} with fuel Wobbe number. The largest percentage increases occurred for the ultra low-NO{sub X} water heaters. There was a discernible change in CO emissions with Wobbe number for all four of the on-demand devices tested. The on-demand water heater with the highest CO emissions also had the largest CO increase with increasing fuel Wobbe number.

  11. Estimating emissions of 20 VOCs. 2: Diffused aeration (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Estimating emissions of 20 VOCs. 2: Diffused aeration Citation Details In-Document Search Title: Estimating emissions of 20 VOCs. 2: Diffused aeration A relationship developed in a companion paper to estimate emissions from surface-aerated reactors that accounts for both gas- and liquid-phase mass-transfer resistances is extended to reactors with diffused-aeration systems. The method accurately predicts the observed stripping rate of 20 volatile organic compounds (VOCs) with

  12. Diesel engine emissions reduction by multiple injections having increasing pressure

    DOE Patents [OSTI]

    Reitz, Rolf D. (Madison, WI); Thiel, Matthew P. (Madison, WI)

    2003-01-01

    Multiple fuel charges are injected into a diesel engine combustion chamber during a combustion cycle, and each charge after the first has successively greater injection pressure (a higher injection rate) than the prior charge. This injection scheme results in reduced emissions, particularly particulate emissions, and can be implemented by modifying existing injection system hardware. Further enhancements in emissions reduction and engine performance can be obtained by using known measures in conjunction with the invention, such as Exhaust Gas Recirculation (EGR).

  13. Collaborative Lubricating Oil Study on Emissions (CLOSE Project) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace046_lawson_2010_o.pdf More Documents & Publications Collaborative Lubricating Oil Study on Emissions (CLOSE Project) Collaborative Lubricating Oil Study on Emissions (CLOSE) Project Lung Toxicity and Mutagenicity of Emissions From Heavy-Duty Compressed Natural Gas (CNG)-Powered Vehicles

  14. Vehicle Technologies Office: Fuel Efficiency and Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Vehicle Technologies Office: Fuel Efficiency and Emissions Vehicle Technologies Office: Fuel Efficiency and Emissions Substantially improving vehicle efficiency has the potential to drastically increase the United States' economic, energy, and environmental security. On-road vehicles account for nearly 60 percent of total U.S. oil consumption and more than a quarter of the country's greenhouse gas emissions, the major contributor to climate change. The Vehicle Technologies Office is

  15. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  16. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  17. Exhaust emission control and diagnostics

    DOE Patents [OSTI]

    Mazur, Christopher John; Upadhyay, Devesh

    2006-11-14

    A diesel engine emission control system uses an upstream oxidation catalyst and a downstream SCR catalyst to reduce NOx in a lean exhaust gas environment. The engine and upstream oxidation catalyst are configured to provide approximately a 1:1 ratio of NO to NO2 entering the downstream catalyst. In this way, the downstream catalyst is insensitive to sulfur contamination, and also has improved overall catalyst NOx conversion efficiency. Degradation of the system is determined when the ratio provided is no longer near the desired 1:1 ratio. This condition is detected using measurements of engine operating conditions such as from a NOx sensor located downstream of the catalysts. Finally, control action to adjust an injected amount of reductant in the exhaust gas based on the actual NO to NO2 ratio upstream of the SCR catalyst and downstream of the oxidation catalyst.

  18. Reducing GHG emissions in the United States' transportation sector

    SciTech Connect (OSTI)

    Das, Sujit [ORNL; Andress, David A [ORNL; Nguyen, Tien [U.S. DOE

    2011-01-01

    Reducing GHG emissions in the U.S. transportation sector requires both the use of highly efficient propulsion systems and low carbon fuels. This study compares reduction potentials that might be achieved in 2060 for several advanced options including biofuels, hybrid electric vehicles (HEV), plug-in hybrid electric vehicles (PHEV), and fuel cell electric vehicles (FCEV), assuming that technical and cost reduction targets are met and necessary fueling infrastructures are built. The study quantifies the extent of the reductions that can be achieved through increasing engine efficiency and transitioning to low-carbon fuels separately. Decarbonizing the fuels is essential for achieving large reductions in GHG emissions, and the study quantifies the reductions that can be achieved over a range of fuel carbon intensities. Although renewables will play a vital role, some combination of coal gasification with carbon capture and sequestration, and/or nuclear energy will likely be needed to enable very large reductions in carbon intensities for hydrogen and electricity. Biomass supply constraints do not allow major carbon emission reductions from biofuels alone; the value of biomass is that it can be combined with other solutions to help achieve significant results. Compared with gasoline, natural gas provides 20% reduction in GHG emissions in internal combustion engines and up to 50% reduction when used as a feedstock for producing hydrogen or electricity, making it a good transition fuel for electric propulsion drive trains. The material in this paper can be useful information to many other countries, including developing countries because of a common factor: the difficulty of finding sustainable, low-carbon, cost-competitive substitutes for petroleum fuels.

  19. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, Kenneth C.; Laug, Matthew T.; Lambert, John D. B.; Herzog, James P.

    1997-01-01

    A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

  20. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.; Lambert, J.B.; Herzog, J.P.

    1997-02-11

    A method and system are disclosed for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod. 12 figs.

  1. Evaluation of Partial Oxidation Reformer Emissions

    SciTech Connect (OSTI)

    Unnasch, Stefan; Fable, Scott; Waterland, Larry

    2006-01-06

    In this study, a gasoline fuel processor and an ethanol fuel processor were operated under conditions simulating both startup and normal operation. Emissions were measured before and after the AGB in order to quantify the effectiveness of the burner catalyst in controlling emissions. The emissions sampling system includes CEM for O2, CO2, CO, NOx, and THC. Also, integrated gas samples are collected in evacuated canisters for hydrocarbon speciation analysis via GC. This analysis yields the concentrations of the hydrocarbon species required for the California NMOG calculation. The PM concentration in the anode burner exhaust was measured through the placement of a filter in the exhaust stream. The emissions from vehicles with fully developed on board reformer systems were estimated.

  2. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. )

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the best-case'' results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author's experience with fuel delivery systems for light-duty vehicles.

  3. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B.

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the ``best-case`` results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author`s experience with fuel delivery systems for light-duty vehicles.

  4. Expression of barley SUSIBA2 transcription factor yields high-starch low-methane rice

    SciTech Connect (OSTI)

    Su, J.; Hu, C.; Yan, X.; Jin, Y.; Chen, Z.; Guan, Q.; Wang, Y.; Zhong, D.; Jansson, Georg C.; Wang, F.; Schnrer, Anna; Sun, Chuanxin

    2015-07-22

    Atmospheric methane is the second most important greenhouse gas after carbon dioxide, and is responsible for about 20% of the global warming effect since pre-industrial times. Rice paddies are the largest anthropogenic methane source and produce 717% of atmospheric methane. Warm waterlogged soil and exuded nutrients from rice roots provide ideal conditions for methanogenesis in paddies with annual methane emissions of 25100-million tonnes. This scenario will be exacerbated by an expansion in rice cultivation needed to meet the escalating demand for food in the coming decades4. There is an urgent need to establish sustainable technologies for increasing rice production while reducing methane fluxes from rice paddies. However, ongoing efforts for methane mitigation in rice paddies are mainly based on farming practices and measures that are difficult to implement5. Despite proposed strategies to increase rice productivity and reduce methane emissions4,6, no high-starch low-methane-emission rice has been developed. Here we show that the addition of a single transcription factor gene, barley SUSIBA2, conferred a shift of carbon flux to SUSIBA2 rice, favouring the allocation of photosynthates to aboveground biomass over allocation to roots. The altered allocation resulted in an increased biomass and starch content in the seeds and stems, and suppressed methanogenesis, possibly through a reduction in root exudates. Three-year field trials in China demonstrated that the cultivation of SUSIBA2 rice was associated with a significant reduction in methane emissions and a decrease in rhizospheric methanogen levels. SUSIBA2 rice offers a sustainable means of providing increased starch content for food production while reducing greenhouse gas emissions from rice cultivation. Approaches to increase rice productivity and reduce methane emissions as seen in SUSIBA2 rice may be particularly beneficial in a future climate with rising temperatures resulting in increased methane emissions from paddies.

  5. US Department of Energy - Office of FreedomCar and Vehicle Technologies and US Centers for Disease Control and Prevention - National Institute for Occupational Safety and Health Inter-Agency Agreement Research on "The Analysis of Genotoxic Activities of Exhaust Emissions from Mobile Natural Gas, Diesel, and Spark-Ignition Engines"

    SciTech Connect (OSTI)

    William E. Wallace

    2006-09-30

    The US Department of Energy-Office of Heavy Vehicle Technologies (now the DOE-Office of FreedomCar and Vehicle Technologies) signed an Interagency Agreement (IAA) with National Institute for Occupational Safety and Health (NIOSH), No.01-15 DOE, 9/4/01, for 'The analysis of genotoxic activities of exhaust emissions from mobile natural gas, diesel, and spark-ignition engines'; subsequently modified on 3/27/02 (DOE IAG No.01-15-02M1); subsequently modified 9/02/03 (IAA Mod No. 01-15-03M1), as 'The analysis of genotoxic activities of exhaust emissions from mobile internal combustion engines: identification of engine design and operational parameters controlling exhaust genotoxicity'. The DOE Award/Contract number was DE-AI26-01CH11089. The IAA ended 9/30/06. This is the final summary technical report of National Institute for Occupational Safety and Health research performed with the US Department of Energy-Office of FreedomCar and Vehicle Technologies under that IAA: (A) NIOSH participation was requested by the DOE to provide in vitro genotoxicity assays of the organic solvent extracts of exhaust emissions from a suite of in-use diesel or spark-ignition vehicles; (B) research also was directed to develop and apply genotoxicity assays to the particulate phase of diesel exhaust, exploiting the NIOSH finding of genotoxicity expression by diesel exhaust particulate matter dispersed into the primary components of the surfactant coating the surface of the deep lung; (C) from the surfactant-dispersed DPM genotoxicity findings, the need for direct collection of DPM aerosols into surfactant for bioassay was recognized, and design and developmental testing of such samplers was initiated.

  6. ALDEHYDE AND OTHER VOLATILE ORGANIC CHEMICAL EMISSIONS IN FOUR FEMA TEMPORARY HOUSING UNITS ? FINAL REPORT

    SciTech Connect (OSTI)

    Salazar, Olivia; Maddalena, Randy L.; Russell, Marion; Sullivan, Douglas P.; Apte, Michael G.

    2008-05-04

    Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THU VOC and aldehyde emission factors (mu g h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehyde concentrations ranged from 378 mu g m-3 (0.31ppm) to 632 mu g m-3 (0.52 ppm) in the AM, and from 433 mu g m-3 (0.35 ppm) to 926 mu g m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography -- mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (mu g h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and material specific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was the only one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 mu g m-2 h 1 in the morning and 257 to 347 mu g m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 mu g m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 mu g/m2 h-1 for particleboard and 130 mu g/m2 h-1 for plywood). The high loading factor (material surface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde.

  7. Advanced integration concepts for oxygen plants and gas turbines in gasification/IGCC facilities

    SciTech Connect (OSTI)

    Smith, A.R.; Klosek, J.; Woodward, D.W.

    1996-12-31

    The commercialization of Integrated Gasification Combined-Cycle (IGCC) power has been aided by concepts involving the integration of a cryogenic air separation unit (ASU) with the gas turbine combined-cycle module. Other processes, such as coal-based ironmaking and combined power and industrial gas production facilities, can benefit from the integration of these two units. It is known and now widely accepted that an ASU designed for elevated pressure service and optimally integrated with the gas turbine can increase overall IGCC power output, increase overall efficiency, and decrease the net cost of power generation compared to non-integrated facilities employing low pressure ASU`s. Depending upon the specific gas turbine, gasification technology, NOx emission specification, and other site specific factors, various degrees of compressed air and nitrogen integration are optimal. Air Products has supplied ASU`s with no integration (Destec/Plaquemine IGCC), nitrogen-only integration (Tampa Electric/Polk County IGCC), and full air and nitrogen integration (Demkolec/Buggenum IGCC). Continuing advancements in both air separation and gas turbine technologies offer new integration opportunities to further improve performance and reduce costs. This paper will review basic integration principles and describe advanced concepts based on emerging high compression ratio gas turbines. Humid Air Turbine (HAT) cycles, and integration of compression heat and refrigeration sources from the ASU. Operability issues associated with integration will be reviewed and control measures described for the safe, efficient, and reliable operation of these facilities.

  8. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A.

    1993-11-01

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  9. Low-NOx Gas Turbine Injectors Utilizing Hydrogen-Rich Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    combustion system to operate on hydrogen-rich opportunity fuels. Increasing the usability of opportunity fuels will avoid greenhouse gas emissions from the combustion of...

  10. NREL: News - UPS Fleet Study Quantifies the Reliability, Low Emissions of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CNG Trucks UPS Fleet Study Quantifies the Reliability, Low Emissions of CNG Trucks Tuesday October 29, 2002 Golden, CO. - A large study comparing trucks fueled by natural gas with others fueled by diesel found the natural gas vehicles produced only a quarter of the carbon monoxide emissions and half the oxides of nitrogen emissions of their diesel counterparts. The study was conducted using package trucks operated by United Parcel Service (UPS), which has the nation's largest private

  11. On-Road Development of the C-Gas Plus Engine in Heavy-Duty Vehicles

    SciTech Connect (OSTI)

    Not Available

    2003-06-01

    Fact sheet details on-road development of C-Gas Plus natural gas engine in Viking Freight heavy-duty trucks, including emissions, fuel costs, and petroleum displacement.

  12. ZERO EMISSION POWER GENERATION TECHNOLOGY DEVELOPMENT

    SciTech Connect (OSTI)

    Ronald Bischoff; Stephen Doyle

    2005-01-20

    Clean Energy Systems (CES) was previously funded by DOE's ''Vision 21'' program. This program provided a proof-of-concept demonstration that CES' novel gas generator (combustor) enabled production of electrical power from fossil fuels without pollution. CES has used current DOE funding for additional design study exercises which established the utility of the CES-cycle for retrofitting existing power plants for zero-emission operations and for incorporation in zero-emission, ''green field'' power plant concepts. DOE funding also helped define the suitability of existing steam turbine designs for use in the CES-cycle and explored the use of aero-derivative turbines for advanced power plant designs. This work is of interest to the California Energy Commission (CEC) and the Norwegian Ministry of Petroleum & Energy. California's air quality districts have significant non-attainment areas in which CES technology can help. CEC is currently funding a CES-cycle technology demonstration near Bakersfield, CA. The Norwegian government is supporting conceptual studies for a proposed 40 MW zero-emission power plant in Stavager, Norway which would use the CES-cycle. The latter project is called Zero-Emission Norwegian Gas (ZENG). In summary, current engineering studies: (1) supported engineering design of plant subsystems applicable for use with CES-cycle zero-emission power plants, and (2) documented the suitability and availability of steam turbines for use in CES-cycle power plants, with particular relevance to the Norwegian ZENG Project.

  13. Waste-to-wheel analysis of anaerobic-digestion-based renewable natural gas pathways with the GREET model.

    SciTech Connect (OSTI)

    Han, J.; Mintz, M.; Wang, M.

    2011-12-14

    In 2009, manure management accounted for 2,356 Gg or 107 billion standard cubic ft of methane (CH{sub 4}) emissions in the United States, equivalent to 0.5% of U.S. natural gas (NG) consumption. Owing to the high global warming potential of methane, capturing and utilizing this methane source could reduce greenhouse gas (GHG) emissions. The extent of that reduction depends on several factors - most notably, how much of this manure-based methane can be captured, how much GHG is produced in the course of converting it to vehicular fuel, and how much GHG was produced by the fossil fuel it might displace. A life-cycle analysis was conducted to quantify these factors and, in so doing, assess the impact of converting methane from animal manure into renewable NG (RNG) and utilizing the gas in vehicles. Several manure-based RNG pathways were characterized in the GREET (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model, and their fuel-cycle energy use and GHG emissions were compared to petroleum-based pathways as well as to conventional fossil NG pathways. Results show that despite increased total energy use, both fossil fuel use and GHG emissions decline for most RNG pathways as compared with fossil NG and petroleum. However, GHG emissions for RNG pathways are highly dependent on the specifics of the reference case, as well as on the process energy emissions and methane conversion factors assumed for the RNG pathways. The most critical factors are the share of flared controllable CH{sub 4} and the quantity of CH{sub 4} lost during NG extraction in the reference case, the magnitude of N{sub 2}O lost in the anaerobic digestion (AD) process and in AD residue, and the amount of carbon sequestered in AD residue. In many cases, data for these parameters are limited and uncertain. Therefore, more research is needed to gain a better understanding of the range and magnitude of environmental benefits from converting animal manure to RNG via AD.

  14. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  15. Fact Sheet: Efficiency Standards for Natural Gas Compressors | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Efficiency Standards for Natural Gas Compressors Fact Sheet: Efficiency Standards for Natural Gas Compressors The following fact sheet outlines one of the Department of Energy's series of actions, partnerships, and stakeholder commitments to help modernize the nation¹s natural gas transmission and distribution systems and reduce methane emissions. DOE will take the first step toward establishing energy efficiency standards for new natural gas compressor units by issuing a Request

  16. Gas releases from salt

    SciTech Connect (OSTI)

    Ehgartner, B.; Neal, J.; Hinkebein, T.

    1998-06-01

    The occurrence of gas in salt mines and caverns has presented some serious problems to facility operators. Salt mines have long experienced sudden, usually unexpected expulsions of gas and salt from a production face, commonly known as outbursts. Outbursts can release over one million cubic feet of methane and fractured salt, and are responsible for the lives of numerous miners and explosions. Equipment, production time, and even entire mines have been lost due to outbursts. An outburst creates a cornucopian shaped hole that can reach heights of several hundred feet. The potential occurrence of outbursts must be factored into mine design and mining methods. In caverns, the occurrence of outbursts and steady infiltration of gas into stored product can effect the quality of the product, particularly over the long-term, and in some cases renders the product unusable as is or difficult to transport. Gas has also been known to collect in the roof traps of caverns resulting in safety and operational concerns. The intent of this paper is to summarize the existing knowledge on gas releases from salt. The compiled information can provide a better understanding of the phenomena and gain insight into the causative mechanisms that, once established, can help mitigate the variety of problems associated with gas releases from salt. Outbursts, as documented in mines, are discussed first. This is followed by a discussion of the relatively slow gas infiltration into stored crude oil, as observed and modeled in the caverns of the US Strategic Petroleum Reserve. A model that predicts outburst pressure kicks in caverns is also discussed.

  17. Enabling Clean Consumption of Low Btu and Reactive Fuels in Gas Turbines

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels ADVANCED MANUFACTURING OFFICE Enabling Clean Combustion of Low-Btu and Reactive Fuels in Gas Turbines By enabling ultralow-emission, lean premixed combustion of a wide range of gaseous opportunity fuels, this unique, fuel- fexible catalytic combustor for gas turbines can reduce natural gas consumption in industry. Introduction Gas turbines are commonly used in industry for onsite power and heating needs because of their high

  18. BROAD Ly{alpha} EMISSION FROM THREE NEARBY BL LACERTAE OBJECTS

    SciTech Connect (OSTI)

    Stocke, John T.; Danforth, Charles W. [CASA, Department of Astrophysical and Planetary Sciences, University of Colorado, 389-UCB, Boulder, CO 80309 (United States); Perlman, Eric S., E-mail: danforth@casa.colorado.edu, E-mail: stocke@casa.colorado.edu, E-mail: eperlman@fit.edu [Florida Institute of Technology, Physics and Space Sciences Department, 150 West University Boulevard, Melbourne, FL 32901 (United States)

    2011-05-10

    We present far-UV HST/COS spectra of four nearby BL Lac objects. BL Lac spectra are dominated by a smooth, power-law continuum which arises in a relativistic jet. However, the spectra are not necessarily featureless; weak, broad- and/or narrow-line emission is sometimes seen in high-quality optical spectra. We present detections of Ly{alpha} emission in HST/COS spectra of Mrk 421 (z = 0.030) and PKS 2005-489 (z = 0.071) as well as an archival HST/GHRS observation of Mrk 501 (z = 0.0337). Archival HST/STIS observations of PKS 2155-304 (z = 0.116) show no Ly{alpha} emission to a very low upper limit. Using the assumption that the broad-line region (BLR) clouds are symmetrically placed around the active galactic nucleus (AGN), we use these measured Ly{alpha} emission features to constrain either the relativistic {Gamma} values for the ionizing continuum produced by the jet (in the ionization-bounded case) or the mass of warm gas (in the density-bounded case). While realistic {Gamma} values can be obtained for all four cases, the values for Mrk 421 and PKS 2155-304 are high enough to suggest that covering factors of BLR clouds of {approx}1%-2% might be required to provide consistency with earlier values of Doppler boosting and viewing angles suggested for this class of BL Lacs. This discrepancy also exists in the case of M 87, where the amount of Doppler boosting in our direction is expected to be minimal, again suggestive of a small covering factor of BLR clouds. If, as these small covering factors might suggest, the assumptions of a density-bounded model could be more correct, then the observed Ly{alpha} luminosities require that BL Lac/FR 1 nuclei possess very little warm gas (10{sup -4} to 10{sup -5} M{sub sun}) as suggested by Guilbert et al. If these clouds are in pressure balance with a hotter ({approx}10{sup 6} K) gas, the BLR contains too little mass to power the AGN by accretion alone.

  19. Compressed natural gas (CNG) measurement

    SciTech Connect (OSTI)

    Husain, Z.D.; Goodson, F.D.

    1995-12-01

    The increased level of environmental awareness has raised concerns about pollution. One area of high attention is the internal combustion engine. The internal combustion engine in and of itself is not a major pollution threat. However, the vast number of motor vehicles in use release large quantities of pollutants. Recent technological advances in ignition and engine controls coupled with unleaded fuels and catalytic converters have reduced vehicular emissions significantly. Alternate fuels have the potential to produce even greater reductions in emissions. The Natural Gas Vehicle (NGV) has been a significant alternative to accomplish the goal of cleaner combustion. Of the many alternative fuels under investigation, compressed natural gas (CNG) has demonstrated the lowest levels of emission. The only vehicle certified by the State of California as an Ultra Low Emission Vehicle (ULEV) was powered by CNG. The California emissions tests of the ULEV-CNG vehicle revealed the following concentrations: Non-Methane Hydrocarbons 0.005 grams/mile Carbon Monoxide 0.300 grams/mile Nitrogen Oxides 0.040 grams/mile. Unfortunately, CNG vehicles will not gain significant popularity until compressed natural gas is readily available in convenient locations in urban areas and in proximity to the Interstate highway system. Approximately 150,000 gasoline filling stations exist in the United States while number of CNG stations is about 1000 and many of those CNG stations are limited to fleet service only. Discussion in this paper concentrates on CNG flow measurement for fuel dispensers. Since the regulatory changes and market demands affect the flow metering and dispenser station design those aspects are discussed. The CNG industry faces a number of challenges.

  20. Natural gas storage - end user interaction. Task 2. Topical report

    SciTech Connect (OSTI)

    1996-01-01

    New opportunities have been created for underground gas storage as a result of recent regulatory developments in the energy industry. The Federal Energy Regulatory Commission (FERC) Order 636 directly changed the economics of gas storage nationwide. This paper discusses the storage of natural gas, storage facilities, and factors affecting the current, and future situation for natural gas storage.

  1. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  2. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott; Theiss, Timothy J; Bunce, Michael

    2012-01-01

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  3. New Report Compares Performance of Compressed Natural Gas Refuse...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A new report that compares the performance of compressed natural gas (CNG) refuse haulers ... The study reviews the fuel economy, range, cost and emissions of CNG garbage trucks. Free ...

  4. Short-Term Outlook for Hydrocarbon Gas Liquids - Energy Information...

    U.S. Energy Information Administration (EIA) Indexed Site

    and Other Liquids Natural Gas Coal Electricity Renewables and Carbon Dioxide Emissions ... day (bd) in 2008 to 13.75 million bd in 2015. However, the Short-Term Energy Outlook ...

  5. Research Challenge 5: Enhanced Spontaneous Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5: Enhanced Spontaneous Emission - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  6. Research Challenge 6: Beyond Spontaneous Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6: Beyond Spontaneous Emission - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  7. NREL: Sustainable NREL - Greenhouse Gas Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greenhouse Gas Reduction A leader in federal greenhouse gas (GHG) management, NREL has conducted GHG inventories, developed reduction goals, and reported emissions since 2000. NREL was the first federal facility to become a partner in the Environmental Protection Agency's Climate Leaders program, and has played a critical support role in the development of federal guidelines for GHG accounting and reporting through DOE's Federal Energy Management Program. Carbon Neutrality NREL is committed to

  8. Bibliography of greenhouse-gas reduction strategies

    SciTech Connect (OSTI)

    Tompkins, M.M.; Mintz, M.M.

    1995-03-01

    A bibliography of greenhouse-gas reduction strategies has been compiled to assist the Climate change Action Plan Task Force in their consideration of strategies to reduce greenhouse-gas emissions from personal motor vehicles. The document contains a summary of the literature, including it major directions and implications; and annotated listing of 32 recent pertinent documents; and a listing of a larger group of related reports.

  9. THE DARK MOLECULAR GAS

    SciTech Connect (OSTI)

    Wolfire, Mark G.; Hollenbach, David; McKee, Christopher F. E-mail: dhollenbach@seti.or

    2010-06-20

    The mass of molecular gas in an interstellar cloud is often measured using line emission from low rotational levels of CO, which are sensitive to the CO mass, and then scaling to the assumed molecular hydrogen H{sub 2} mass. However, a significant H{sub 2} mass may lie outside the CO region, in the outer regions of the molecular cloud where the gas-phase carbon resides in C or C{sup +}. Here, H{sub 2} self-shields or is shielded by dust from UV photodissociation, whereas CO is photodissociated. This H{sub 2} gas is 'dark' in molecular transitions because of the absence of CO and other trace molecules, and because H{sub 2} emits so weakly at temperatures 10 K gas and far-infrared/submillimeter wavelength dust continuum radiation. In this paper, we theoretically model this dark mass and find that the fraction of the molecular mass in this dark component is remarkably constant ({approx}0.3 for average visual extinction through the cloud A-bar{sub V{approx_equal}}8) and insensitive to the incident ultraviolet radiation field strength, the internal density distribution, and the mass of the molecular cloud as long as A-bar{sub V}, or equivalently, the product of the average hydrogen nucleus column and the metallicity through the cloud, is constant. We also find that the dark mass fraction increases with decreasing A-bar{sub V}, since relatively more molecular H{sub 2} material lies outside the CO region in this case.

  10. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  11. Microwave off-gas treatment apparatus and process

    DOE Patents [OSTI]

    Schulz, Rebecca L.; Clark, David E.; Wicks, George G.

    2003-01-01

    The invention discloses a microwave off-gas system in which microwave energy is used to treat gaseous waste. A treatment chamber is used to remediate off-gases from an emission source by passing the off-gases through a susceptor matrix, the matrix being exposed to microwave radiation. The microwave radiation and elevated temperatures within the combustion chamber provide for significant reductions in the qualitative and quantitative emissions of the gas waste stream.

  12. Department of Energy Announces Steps to Help Modernize Natural Gas

    Energy Savers [EERE]

    Infrastructure | Department of Energy Help Modernize Natural Gas Infrastructure Department of Energy Announces Steps to Help Modernize Natural Gas Infrastructure July 29, 2014 - 3:58pm Addthis News Media Contact 202-586-4940 Plan Follows Final Capstone Roundtable on Reducing Methane Emissions Washington, D.C. - Building on the President's Climate Action Plan, today the White House and the Department of Energy hosted the fifth in a series of meetings on reducing methane emissions from natural

  13. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  14. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    withdrawal from working gas storage reported last Thursday. A contributing factor to the run-up in natural gas prices could be climbing crude oil prices, which rallied late last...

  15. A review of dissolved gas supersaturation literature

    SciTech Connect (OSTI)

    Weitkamp, D.E.; Katz, M.

    1980-11-01

    Gas bubble disease in a condition that affects aquatic animals residing in fresh or marine waters that are supersaturated with atmospheric gases. The majority of research concerning dissolved gas supersaturation has been stimulated by a serious supersaturation problem that was first observed in the Columbia and Snake river systems in 1970. Available literature dealing with dissolved gas supersaturation and recorded cases of gas bubble disease are reviewed. The causes of supersaturation, the organisms affected by supersaturation, factors influencing susceptibility of aquatic organisms to gas bubble disease, and various other related topics are explored.

  16. Unconventional Oil and Gas Resources

    SciTech Connect (OSTI)

    2006-09-15

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  17. Development of the Low Swirl Injector for Fuel-Flexible GasTurbines

    SciTech Connect (OSTI)

    Littlejohn, D.; Cheng, R.K.; Nazeer,W.A.; Smith, K.O

    2007-02-14

    Industrial gas turbines are primarily fueled with natural gas. However, changes in fuel cost and availability, and a desire to control carbon dioxide emissions, are creating pressure to utilize other fuels. There is an increased interest in the use of fuels from coal gasification, such as syngas and hydrogen, and renewable fuels, such as biogas and biodiesel. Current turbine fuel injectors have had years of development to optimize their performance with natural gas. The new fuels appearing on the horizon can have combustion properties that differ substantially from natural gas. Factors such as turbulent flame speed, heat content, autoignition characteristics, and range of flammability must be considered when evaluating injector performance. The low swirl injector utilizes a unique flame stabilization mechanism and is under development for gas turbine applications. Its design and mode of operation allow it to operate effectively over a wide range of conditions. Studies conducted at LBNL indicate that the LSI can operate on fuels with a wide range of flame speeds, including hydrogen. It can also utilize low heat content fuels, such as biogas and syngas. We will discuss the low swirl injector operating parameters, and how the LSC performs with various alternative fuels.

  18. Secondary Emission Calorimetry

    SciTech Connect (OSTI)

    Winn, David Roberts

    2015-03-24

    This report describes R&D on a new type of calorimeter using secondary emission to measure the energy of radiation, particularly high energy particles.

  19. Carbon Emissions: Paper Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994...

  20. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.