National Library of Energy BETA

Sample records for gas distil lpg

  1. Conversion of LPG hydrocarbons into distillate fuels using an integral LPG dehydrogenation-MOGD process

    SciTech Connect (OSTI)

    Owen, H.; Zahner, J.C.

    1987-06-23

    This patent describes a process for converting lower paraffinic hydrocarbon feedstock comprising propane and/or butane into heavier hydrocarbons comprising gasoline and distillate, comprising the steps of: feeding the paraffinic feedstock to a dehydrogenation zone under conversion conditions for dehydrogenating at least a portion of the feedstock; recovering a first dehydrogenation gaseous effluent stream comprising propene and/or butene; contacting the first gaseous effluent steam with a liquid lean oil sorbent stream comprising C/sub 5//sup +/ hydrocarbons under sorption conditions to produce a C/sub 3//sup +/ rich liquid absorber stream and a light gas stream; sequentially pressurizing, heating and passing the C/sub 3//sup +/ rich liquid absorber stream to an oligomerization reactor zone at elevated temperature and pressure; contacting the C/sub 3//sup +/ rich stream with oligomerization catalyst in the oligomerization reactor zone for conversion of at least a portion of lower olefins to heavier hydrocarbons under oligomerization reaction conditions to provide a second reactor effluent stream comprising gasoline and distillate boiling range hydrocarbons; flash separating the second reactor effluent stream into a separator vapor stream comprising a major portion of the hydrocarbons which later form the lean oil stream, and a major portion of the C/sub 4//sup -/ hydrocarbons and a separator liquid stream comprising the gasoline and distillate boiling range materials produced in the oligomerization reactor zone; fractionating the separator liquid stream in a first product debutanizer tower into a first debutanizer overhead vapor stream comprising C/sub 4//sup -/ hydrocarbons and a product debutanizer liquid bottoms stream comprising C/sub 5//sup +/ gasoline and distillate boiling range hydrocarbons.

  2. Conversion of lpg hydrocarbons to distillate fuels or lubes using integration of lpg dehydrogenation and mogdl

    SciTech Connect (OSTI)

    Chang, C. D.; Penick, J. E.; Socha, R. F.

    1985-09-17

    Disclosed is a method and apparatus for producing distillate and/or lubes which employ integrating catalytic (or thermal) dehydrogenation of paraffins with MOGDL. The process feeds the product from a low temperature propane and/or butane dehydrogenation zone into a first catalytic reactor zone, which operates at low pressure and contains zeolite oligomerization catalysts, where the low molecular weight olefins are reacted to primarily gasoline range materials. These gasoline range materials can then be pressurized to the pressure required for reacting to distillate in a second catalytic reactor zone operating at high pressure and containing a zeolite oligomerization catalyst. The distillate is subsequently sent to a hydrotreating unit and product separation zone to form lubes and other finished products.

  3. Conversion of LPG hydrocarbons to distillate fuels or lubes using integration of LPG dehydrogenation and mogdl

    SciTech Connect (OSTI)

    Chang, C.D.; Penick, J.E.; Socha, R.F.

    1987-07-07

    This patent describes an apparatus for producing distillates of lubes from paraffins, which comprise: (a) a dehydrogenation reactor including means for passing a paraffinic feedstock stream into a dehydrogenation zone at conditions of pressure and temperature selected to convert the paraffins to an olefin rich effluent stream comprising at least one of the group consisting of propylene and butylene; (b) a low pressure oligomerization catalytic reactor including means for contacting the olefin rich effluent stream in a low pressure oligomerization catalytic reactor zone with a crystalline zeolite oligomerization catalyst at conditions of pressure and temperature selected to convert olefins to a first reactor effluent stream rich in liquid olefinic gasoline range hydrocarbons; (c) a first means for separating the first reactor effluent stream to form a substantially liquid C/sub 5/+ rich stream and a C/sub 4/- rich stream; (d) means for passing the C/sub 5/+ rich stream to a high pressure oligomerization catalytic reactor zone; (e) a high pressure oligomerization catalytic reactor including means for contacting the substantially liquid C/sub 5/+ rich stream in the high pressure oligomerization catalytic reactor zone with a crystalline zeolite oligomerization catalyst at conditions of temperature and pressure selected to produce a second reactor effluent stream which is rich in distillate; (f) second means for separating the second reactor effluent stream to recover an olefinic gasoline stream and a distillate stream; and (g) a hydrotreating reactor including means for contacting the distillate stream with hydrogen in a hydrotreating unit to produce a hydrotreated distillate stream comprising lube range hydrocarbons.

  4. Legal nature of LPG (liquefied petroleum gas) regulation

    SciTech Connect (OSTI)

    Liddell, G.

    1986-08-01

    The commercial exploitation of Liquefied Petroleum Gas (LPG) in New Zealand has occurred without a particular and comprehensive concern for any legal implications. The paper in Part I examines definitional questions, assesses in Part II the ability of courts and quasi-courts to evaluate risks associated with the product, examines in Part III the utility of common law remedies for injuries or associated with or arising from LPG, analyzes in Part IV the statutory regulation of LPG, concentrating particularly on the Dangerous Goods (Class 2 - Gases) Regulations 1980, discusses in Part V recent planning case-law concerning LPG development, and concludes that some reform is necessary to produce a more-coherent and precise regulatory regime that takes into account both the needs of developers and those affected by the development of LPG.

  5. "Table A10. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel" " Oil for Selected Purposes by Census Region and Economic Characteristics of the" " Establishment, 1991" " (Estimates in Barrels per Day)" ,,,," Inputs for Heat",,," Primary Consumption" " "," Primary Consumption for all Purposes",,," Power, and Generation of Electricity",,," for Nonfuel Purposes",,,"RSE" ,"

  6. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel" " Oil for Selected Purposes by Census Region, Industry Group, and Selected" " Industries, 1991" " (Estimates in Barrels per Day) " ,,,,," Input for Heat,",,," Primary" " ",," Consumption for All Purposes",,,"Power, and Generation of Electricity",,," Consumption for Nonfuel Purposes ",,,"RSE" "SIC",,"

  7. Cryogenic recovery of LPG from natural gas

    SciTech Connect (OSTI)

    Gray, M.L.; McClintock, W.A.

    1984-02-07

    In accordance with the present invention a natural gas stream predominating in methane and containing significant amounts of C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is cooled in a plurality of cooling stages to a temperature sufficient to produce at least one liquid phase portion predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons. Then at least one liquid phase portion predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is separated from the main gas stream during the course of the cooling. The thus separated liquid phase portion or portions predominating in C/sub 2/, C/sub 3/, C/sub 4/ and C/sub 5/ and higher molecular weight hydrocarbons is further separated into a vapor phase portion predominating in C/sub 2/, C/sub 3/, and C/sub 4/ hydrocarbons and at least one liquid phase portion predominating in C/sub 5/ and higher molecular weight hydrocarbons, at least one second separation step, at least one portion of the at least one vapor phase portion predominating in C/sub 2/, C/sub 3/ and C/sub 4/, hydrocarbons is recovered as at least one product of the process and at least one portion of the remaining portion of the at least one phase portion predominating in C/sub 2/, C/sub 3/ and C/sub 4/ hydrocarbons is recycled to and recombined with the main gas stream as a liquid phase.

  8. Upgrading Fischer-Tropsch LPG (liquefied petroleum gas) with the Cyclar process

    SciTech Connect (OSTI)

    Gregor, J.H.; Gosling, C.D.; Fullerton, H.E.

    1989-04-28

    The use of the UOP/BP Cyclar{reg sign} process for upgrading Fischer-Tropsch (F-T) liquefied petroleum gas (LPG) was studied at UOP{reg sign}. The Cyclar process converts LPG into aromatics. The LPG derived from F-T is highly olefinic. Two routes for upgrading F-T LPG were investigated. In one route, olefinic LPG was fed directly to a Cyclar unit (Direct Cyclar). The alternative flow scheme used the Huels CSP process to saturate LPG olefins upstream of the Cyclar unit (Indirect Cyclar). An 18-run pilot plant study verified that each route is technically feasible. An economic evaluation procedure was designed to choose between the Direct and Indirect Cyclar options for upgrading LPG. Four situations involving three different F-T reactor technologies were defined. The main distinction between the cases was the degree of olefinicity, which ranged between 32 and 84 wt % of the fresh feed. 8 refs., 80 figs., 44 tabs.

  9. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  10. Synthesis gas conversion to LPG over molybdenum catalysts

    SciTech Connect (OSTI)

    Murchison, C.B.; Murdick, D.A.

    1980-01-01

    By using a new Dow Chemical Co. carbon-supported molybdenum oxide catalyst promoted with 4.4% K/sub 2/O or Na/sub 2/O, 90%+ conversions of synthesis gas at space velocities of 500-600/hr were achieved with 60-75% selectivities for C/sub 2/-C/sub 5/ paraffins, including 33 and 27% for ethane and propane, respectively, and no liquid products formed. This LPG product is an excellent ethylene cracking feedstock. The catalyst, which can be used in both oxide and sulfided forms, has demonstrated stable performance with feeds containing up to 20 ppm sulfur (H/sub 2/S + COS) and had no coking problems for up to 2000 hr on stream. Excessive sulfur exposure can be reversed by regeneration with hydrogen. Because of the catalyst's low coking rate, high temperatures, i.e., 350/sup 0/-500/sup 0/C, and near-stoichiometric H/sub 2//CO feed ratios can be used.

  11. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Snow, N.J. Jr.

    1983-12-06

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a well-head; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; and separating LPG from gas vapors of the refrigerated natural gas. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for cooling the compressed gases therefrom; and a product separator downstream of the refrigeration unit for receiving cooled and compressed gases discharged from the refrigeration unit and separating LPG therein from gases remaining in vapor form.

  12. Fire protection considerations for the design and operation of liquefied petroleum gas (LPG) storage facilities

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This standard addresses the design, operation, and maintenance of LPG storage facilities from the standpoint of prevention and control of releases, fire-protection design, and fire-control measures, as well as the history of LPG storage facility failure, facility design philosophy, operating and maintenance procedures, and various fire-protection and firefighting approaches and presentations. The storage facilities covered are LPG installations (storage vessels and associated loading/unloading/transfer systems) at marine and pipeline terminals, natural gas processing plants, refineries, petrochemical plants, and tank farms.

  13. New and existing gas wells promise bountiful LPG output in Michigan

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    Michigan remains the leading LP-gas producer in the Northeast quadrant of the U.S. This paper reports that boosted by a number of new natural gas wells and a couple of new gas processing plants, the state is firmly anchored in the butane/propane production business. Since 1981, more than 100 deep gas wells, most in excess of 8000 feet in depth, have been completed as indicated producers in the state. Many of these are yielding LPG-grade stock. So, combined with LPG-grade production from shallower geologic formations, the supply picture in this area looks promising for the rest of the country.

  14. Converting LPG caverns to natural-gas storage permits fast response to market

    SciTech Connect (OSTI)

    Crossley, N.G.

    1996-02-19

    Deregulation of Canada`s natural-gas industry in the late 1980s led to a very competitive North American natural-gas storage market. TransGas Ltd., Regina, Sask., began looking for method for developing cost-effective storage while at the same time responding to new market-development opportunities and incentives. Conversion of existing LPG-storage salt caverns to natural-gas storage is one method of providing new storage. To supply SaskEnergy Inc., the province`s local distribution company, and Saskatchewan customers, TransGas previously had developed solution-mined salt storage caverns from start to finish. Two Regina North case histories illustrate TransGas` experiences with conversion of LPG salt caverns to gas storage. This paper provides the testing procedures for the various caverns, cross-sectional diagrams of each cavern, and outlines for cavern conversion. It also lists storage capacities of these caverns.

  15. Local government energy management: liquid petroleum gas (LPG) as a motor vehicle fuel

    SciTech Connect (OSTI)

    McCoy, G.A.; Kerstetter, J.

    1983-10-01

    The retrofit or conversion of automotive engines to operate on liquid petroleum gas (LPG) or propane fuel is one of many potentially cost-effective strategies for reducing a local government's annual fleet operating and maintenance costs. The cost effectiveness of an LPG conversion decision is highly dependent on the initial conversion cost, vehicle type, current and projected fuel costs, vehicle fuel economy (miles per gallon), and yearly average mileage. A series of plots have been developed which indicate simple paybacks for the conversion of several vehicle types (passenger car, small and standard pickups, and two and three ton trucks) over a wide range of fuel economies and annual usage patterns. A simple payback of less than three years can be achieved for vehicles with poor fuel economy and high annual use. The figures provided in this report may be used by fleet management personnel as a screening tool to identify those passenger cars, small or standard pickups, or light duty trucks which are candidates for LPG conversion. In addition to examining the benefits of an LPG conversion, local governments should also consider the competing energy management strategies of downsizing, and the acquisition of fuel efficient, diesel powered vehicles.

  16. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    U.S. Energy Information Administration (EIA) Indexed Site

    10.9;" " Unit: Percents." ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)" ...tchable","Switchable","Receipts(e)","Gas","Fuel Oil","Coal","LPG","Breeze","Other(f)" ...

  17. LPG in Venezuela

    SciTech Connect (OSTI)

    Romero, O.

    1986-01-01

    The use of LPG for domestic consumption in Venezuela began in late 1929 when LPG was imported in lots of 500 cylinders. These cylinders were then returned to the U.S. for refilling. Total consumption at that time was some 40M/sup 3/ (250 barrels) per year and by 1937 had grown to some 540M/sup 3/ (3,400 barrels) per year. Local production of LPG from gas began in the mid thirties with a small cooling plant in the Mene Grande Field in the Lake Maracaibo area, the first field to produce oil in Venezuela (1914). This plant produced gasoline for a refinery and some of the first LPG used in Venezuela for domestic consumption. The capacity of this plant was insufficient to satisfy the growing demand for LPG which was supplied from refinery production until the development of the natural gas processing industry. At the present time, Venezuelan refineries are net consumers of LPG.

  18. "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    "," ",," "," " ,,"Residual","Distillate",,"LPG and" "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal" "Characteristic(a)","(kWh)","(gallons)","...

  19. Excess fuel gas. Recover H/sub 2//LPG

    SciTech Connect (OSTI)

    Banks, R.; Isalski, W.H.

    1987-10-01

    Refiners have traditionally been isolated from low temperature cryogenic processing. Energy conservation measures can be complemented by highly efficient cryogenic turbo-expander technology to remove almost all C/sub 3/ and C/sub 4/ components from the fuel header in a separated modular gas processing plant. When appropriate, ethane and ethylene can be accommodated by this technology without the necessity for revamp of existing equipment. The wide experience of cryogenic technology worldwide makes it an excellent means of improving refinery efficiency.

  20. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. )

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the best-case'' results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author's experience with fuel delivery systems for light-duty vehicles.

  1. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B.

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the ``best-case`` results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author`s experience with fuel delivery systems for light-duty vehicles.

  2. Make aromatics from LPG

    SciTech Connect (OSTI)

    Doolan, P.C. ); Pujado, P.R. )

    1989-09-01

    Liquefied petroleum gas (LPG) consists mainly of the propane and butane fraction recovered from gas fields, associated petroleum gas and refinery operations. Apart from its use in steam cracking and stream reforming, LPG has few petrochemical applications. The relative abundance of LPG and the strong demand for aromatics - benzene, toluene and xylenes (BTX) - make it economically attractive to produce aromatics via the aromatization of propane and butanes. This paper describes the Cyclar process, which is based on a catalyst formulation developed by BP and which uses UOP's CCR catalyst regeneration technology, converts propane, butanes or mixtures thereof to petrochemical-quality aromatics in a single step.

  3. Additional Development of a Dedicated Liquefied Petroleum Gas (LPG) Ultra Low Emissions Vehicle (ULEV)

    SciTech Connect (OSTI)

    IMPCO Technologies

    1998-10-28

    This report describes the last in a series of three projects designed to develop a commercially competitive LPG light-duty passenger car that meets California ULEV standards and corporate average fuel economy (CAFE) energy efficiency guidelines for such a vehicle. In this project, IMPCO upgraded the vehicle's LPG vapor fuel injection system and performed emissions testing. The vehicle met the 1998 ULEV standards successfully, demonstrating the feasibility of meeting ULEV standards with a dedicated LPG vehicle.

  4. Jet fuel from LPG

    SciTech Connect (OSTI)

    Maples, R.E.; Jones, J.R.

    1983-02-01

    Explains how jet fuel can be manufactured from propane and/or butane with attractive rates of return. This scheme is advantageous where large reserves of LPG-bearing gas is available or LPG is in excess. The following sequence of processes in involved: dehydrogenation of propane (and/or butane) to propylene (and/or butylene); polymerization of this monomer to a substantial yield of the desired polymer by recycling undesired polymer; and hydrotreating the polymer to saturate double bonds. An attribute of this process scheme is that each of the individual processes has been practiced commercially. The process should have appeal in those parts of the world which have large reserves of LPG-bearing natural gas but little or no crude oil, or where large excesses of LPG are available. Concludes that economic analysis shows attractive rates of return in a range of reasonable propane costs and product selling prices.

  5. LPG emergency response training

    SciTech Connect (OSTI)

    Dix, R.B.; Newton, B.

    1995-12-31

    ROVER (Roll Over Vehicle for Emergency Response) is a specially designed and constructed unit built to allow emergency response personnel and LPG industry employees to get ``up close and personal`` with the type of equipment used for the highway transportation of liquefied petroleum gas (LPG). This trailer was constructed to simulate an MC 331 LPG trailer. It has all the valves, piping and emergency fittings found on highway tankers. What makes this unit different is that it rolls over and opens up to allow program attendees to climb inside the trailer and see it in a way they have never seen one before. The half-day training session is composed of a classroom portion during which attendees will participate in a discussion of hazardous material safety, cargo tank identification and construction. The specific properties of LPG, and the correct procedures for dealing with an LPG emergency. Attendees will then move outside to ROVER, where they will participate in a walkaround inspection of the rolled over unit. All fittings and piping will be representative of both modern and older equipment. Participants will also be able to climb inside the unit through a specially constructed hatch to view cutaway valves and interior construction. While the possibility of an LPG emergency remains remote, ROVER represents Amoco`s continuing commitment to community, education, and safety.

  6. Clean air program: Design guidelines for bus transit systems using liquefied petroleum gas (LPG) as an alternative fuel. Final report, July 1995-April 1996

    SciTech Connect (OSTI)

    Raj, P.K.; Hathaway, W.T.; Kangas, R.

    1996-09-01

    The Federal Transit Administration (FTA) has initiated the development of `Design Guidelines for Bus Transit Systems Using Alternative Fuels.` This report provides design guidelines for the safe uses of Liquefied Petroleum Gas (LPG). It forms a part of the series of individual monographs being published by the FTA on (the guidelines for the safe use of) Compressed Natural Gas (CNG), Liquefied Natural Gas (LNG), Liquefied Petroleum Gas (LPG) and alcohol fuels (Methanol and Ethanol). Each report in this series describes for the subject fuel the important fuel properties, guidelines for the design and operation of bus fueling, storage and maintenance facilities, issues on personnel training and emergency preparedness.

  7. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  8. New LPG loss-control standards

    SciTech Connect (OSTI)

    Blomquist, D.L. )

    1988-12-01

    API'S (American Petroleum Institute) Committee on Liquified Hydrocarbon Gas and the Committee and Safety and Fire Protection have modified Standard 2510 and added a supplemental Standard 2510A, in response to bad LPG incidents. Requirements have been tightened, with a major objective to prevent LPG releases. Fire protection Standards for the design and operation of LPG facilities are specifically revised. Following important changes are specifically discussed: Versel design, site selection, spacing and impounding; foundations and supports; and piping requirements.

  9. Cr-free Fe-based metal oxide catalysts for high temperature water gas shift reaction of fuel processor using LPG

    SciTech Connect (OSTI)

    lee, Joon Y.; Lee, Dae-Won; Lee, Kwan Young; Wang, Yong

    2009-08-15

    The goal of this study was to identify the most suitable chromium-free iron-based catalysts for the HTS (high temperature shift) reaction of a fuel processor using LPG. Hexavalent chromium (Cr6+) in the commercial HTS catalyst has been regarded as hazardous material. We selected Ni and Co as the substitution for chromium in the Fe-based HTS catalyst and investigated the HTS activities of these Crfree catalysts at LPG reformate condition. Cr-free Fe-based catalysts which contain Ni, Zn, or Co instead of Cr were prepared by coprecipitation method and the performance of the catalysts in HTS was evaluated under gas mixture conditions (42% H2, 10% CO, 37% H2O, 8% CO2, and 3% CH4; R (reduction factor): about 1.2) similar to the gases from steam reforming of LPG (100% conversion at steam/carbon ratio = 3), which is higher than R (under 1) of typically studied LNG reformate condition. Among the prepared Cr-free Febased catalysts, the 5 wt%-Co/Fe/20 wt%-Ni and 5 wt%-Zn/Fe/20 wt%-Ni catalysts showed good catalytic activity under this reaction condition simulating LPG reformate gas.

  10. Spread of natural gas lines in Arkansas hurts LPG marketers anew

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This article discusses the marketing of LP gas in Arkansas. The reaction of natural gas marketers in the state is described. Federal subsidation, through the U.S. Department of Housing and Urban Development, of utilities in Arkansas is described.

  11. Liquefied Petroleum Gas (LPG) storage facility study, Fort Gordon, Georgia. Final report

    SciTech Connect (OSTI)

    1992-09-01

    Fort Gordon currently purchases natural gas from Atlanta Gas Light Company under a rate schedule for Large Commercial Interruptible Service. This offers a very favorable rate for `interruptible` gas service, however, Fort Gordon must maintain a base level of `firm gas`, purchased at a significantly higher cost, to assure adequate natural gas supplies during periods of curtailment to support family housing requirements and other single fuel users. It is desirable to provide a standby fuel source to meet the needs of family housing and other single fuel users and eliminate the extra costs for the firm gas commitment to Atlanta Gas Light Company. Therefore, a propane-air standby fuel system is proposed to be installed at Fort Gordon.

  12. Liquefied Petroleum Gas (LPG) storage facility study Fort Gordon, Georgia. Final report

    SciTech Connect (OSTI)

    1992-09-01

    Fort Gordon currently purchases natural gas from Atlanta Gas Light Company under a rate schedule for Large Commercial Interruptible Service. This offers a very favorable rate for `interruptible` gas service, however, Fort Gordon must maintain a base level of `firm gas`, purchased at a significantly higher cost, to assure adequate natural gas supplies during periods of curtailment to support family housing requirements and other single fuel users. It is desirable to provide a standby fuel source to meet the needs of family housing and other single fuel users and eliminate the extra costs for the firm gas commitment to Atlanta Gas Light Company. Therefore, a propane-air standby fuel system is proposed to be installed at Fort Gordon.

  13. LPG storage vessel cracking experience

    SciTech Connect (OSTI)

    Cantwell, J.E. )

    1988-10-01

    In order to evaluate liquefied petroleum gas (LPG) handling and storage hazards, Caltex Petroleum Corp. (Dallas) surveyed several installations for storage vessel cracking problems. Cracking was found in approximately one-third of the storage vessels. In most cases, the cracking appeared to be due to original fabrication problems and could be removed without compromising the pressure containment. Several in-service cracking problems found were due to exposure to wet hydrogen sulfide. Various procedures were tried in order to minimize the in-service cracking potential. One sphere was condemned because of extensive subsurface cracking. This article's recommendations concern minimizing cracking on new and existing LPG storage vessels.

  14. The SONATRACH jumbo LPG plant

    SciTech Connect (OSTI)

    Ahmed Khodja, A.; Bennaceur, A.

    1988-01-01

    The authors aim is to give to the 17 TH world gas conference a general idea on SONATRACH LPG PLANT which is located in the ARZEW area. They develop this communication as follows: general presentation of LPG plant: During the communication, the author's will give the assistance all the information concerning the contractions the erection's date and the LPG PLANT process, start-up of the plant: In this chapter, the authors's will describe the start-up condition, the performance test result, the flexibility test result and the total mechanical achievement of the plant; operation by SONATRACH: After the success that obtained during the mechanical achievement and performance test, the contractor handed over the plant to SONATRACH.

  15. Catalytic conversion of LPG

    SciTech Connect (OSTI)

    Pujado, P.R.; Vora, B.V.; Mowry, J.R.; Anderson, R.F.

    1986-01-01

    The low reactivity of light paraffins has long hindered their utilization as petrochemical feedstocks. Except for their use in ethylene crackers, LPG fractions have traditionally been consumed as fuel. New catalytic processes now being commercialized open new avenues for the utilization of LPG as sources of valuable petrochemical intermediates. This paper discusses processes for the dehydrogenation and aromatization of LPG.

  16. Estimating household fuel oil/kerosine, natural gas, and LPG prices by census region

    SciTech Connect (OSTI)

    Poyer, D.A.; Teotia, A.P.S.

    1994-08-01

    The purpose of this research is to estimate individual fuel prices within the residential sector. The data from four US Department of Energy, Energy Information Administration, residential energy consumption surveys were used to estimate the models. For a number of important fuel types - fuel oil, natural gas, and liquefied petroleum gas - the estimation presents a problem because these fuels are not used by all households. Estimates obtained by using only data in which observed fuel prices are present would be biased. A correction for this self-selection bias is needed for estimating prices of these fuels. A literature search identified no past studies on application of the selectivity model for estimating prices of residential fuel oil/kerosine, natural gas, and liquefied petroleum gas. This report describes selectivity models that utilize the Dubin/McFadden correction method for estimating prices of residential fuel oil/kerosine, natural gas, and liquefied petroleum gas in the Northeast, Midwest, South, and West census regions. Statistically significant explanatory variables are identified and discussed in each of the models. This new application of the selectivity model should be of interest to energy policy makers, researchers, and academicians.

  17. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-01-01

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  18. Emissions from ethanol and LPG fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1992-12-31

    This paper addresses the environmental concerns of using neat ethanol and liquified petroleum gas (LPG) as transportation fuels in the US Low-level blends of ethanol (10%) with gasoline have been used as fuels in the US for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the US, but its use has been limited primarily to converted fleet vehicles. Increasing US interest in alternative fuels has raised the possibility of introducing neat ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles and increased production and consumption of fuel ethanol and LPG will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural emissions from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG compared to other transportation fuels. The environmental concerns are reviewed and summarized, but the only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat ethanol fueled vehicles or the increase in LPG fueled vehicles.

  19. LPG in Mexico

    SciTech Connect (OSTI)

    Miles, E.L.

    1986-01-01

    The authors review LPG in Mexico. They attempt to project numbers to the year 2000 using a supply/demand comparison.

  20. Indonesia's Arun LPG plant production is unique in Far East markets

    SciTech Connect (OSTI)

    Naklie, M.M.; Penick, D.P.; Denton, L.A.; Kartiyoso, I.

    1987-08-03

    Entry of the Arun (Indonesia) LNG plant into the LPG Far East markets is significant because its supplies for those markets are not tied to gas being extracted in association with crude oil. Arun LPG products are extracted from gas that is processed into and marketed as LNG. This article on the Arun LNG plant analyzes its LPG process and the significance of the LPG project on the plant's markets. Particular attention is paid to: 1.) LPG recovery; 2.) LPG fractionation; and 3.) Far East trade.

  1. U.S. LPG pipeline begins deliveries to Pemex terminal

    SciTech Connect (OSTI)

    Bodenhamer, K.C.

    1997-08-11

    LPG deliveries began this spring to the new Mendez LPG receiving terminal near Juarez, State of Chihuahua, Mexico. Supplying the terminal is the 265-mile, 8-in. Rio Grande Pipeline that includes a reconditioned 217-mile, 8-in. former refined-products pipeline from near Odessa, Texas, and a new 48-mile, 8-in. line beginning in Hudspeth County and crossing the US-Mexico border near San Elizario, Texas. Capacity of the pipeline is 24,000 b/d. The LPG supplied to Mexico is a blend of approximately 85% propane and 15% butane. Before construction and operation of the pipeline, PGPB blended the propane-butane mix at a truck dock during loading. Demand for LPG in northern Mexico is strong. Less than 5% of the homes in Juarez have natural gas, making LPG the predominant energy source for cooking and heating in a city of more than 1 million. LPG also is widely used as a motor fuel.

  2. Custody transfer measurements for LNG/LPG

    SciTech Connect (OSTI)

    Williams, R.A.

    1984-04-01

    The buying, selling, and transportation of Liquefied Natural Gas (LNG) and Liquefied Petroleum Gas (LPG) requires the use of sophisticated measurement systems for accurate determination of the total quantity and energy content for custody transfer reporting and safe cargo handling of these cryogenic products. These systems must meet strict safety standards for operation in a hazardous environment and, at the same time, provide accurate, reliable information for the storage, transfer, and data reporting required for both operational and financial accounting purposes. A brief discussion of LNG and LPG characteristics and detailed description of these special measurement techniques are given in this presentation.

  3. Impact of foreign LPG operations on domestic LPG markets

    SciTech Connect (OSTI)

    Jones, C.

    1981-01-01

    During 1978 the federal government passed legislation allowing a major increase in natural gas prices and offering hope that some portion of the supply will be allowed to reach free market levels. The mechanism for decontrol of crude oil was also put into effect. This favorable government action and higher world oil prices have led to a major resurgence in domestic exploration. In addition to the supply effects, there appears to have been a substantial demand response to the latest round of world oil price increases. The purpose of this paper is to discuss how these events have affected domestic LPG markets and pricing.

  4. Determination of usage patterns and emissions for propane/LPG in California. Final report

    SciTech Connect (OSTI)

    Sullivan, M.

    1992-05-01

    The purpose of the study was to determine California usage patterns of Liquified Petroleum Gas (LPG), and to estimate propane emissions resulting from LPG transfer operations statewide, and by county and air basin. The study is the first attempt to quantify LPG transfer emissions for California. This was accomplished by analyzing data from a telephone survey of California businesses that use LPG, by extracting information from existing databases.

  5. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect (OSTI)

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  6. Monitoring, safety systems for LNG and LPG operators

    SciTech Connect (OSTI)

    True, W.R.

    1998-11-16

    Operators in Korea and Australia have chosen monitoring and control systems in recent contracts for LNG and LPG storage. Korea Gas Corp. (Kogas) has hired Whessoe Varec, Calais, to provide monitoring systems for four LNG storage tanks being built at Kogas` Inchon terminal. For Elgas Ltd., Port Botany, Australia, Whessoe Varec has already shipped a safety valve-shutdown system to a new LPG cavern-storage facility under construction. The paper describes the systems, terminal monitoring, dynamic approach to tank management, and meeting the growing demand for LPG.

  7. LPG-recovery processes for baseload LNG plants examined

    SciTech Connect (OSTI)

    Chiu, C.H.

    1997-11-24

    With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

  8. Fire safety of LPG in marine transportation

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-08-01

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  9. LPG fuel shutoff system

    SciTech Connect (OSTI)

    Watanabe, T.; Miyata, K.

    1988-01-26

    An LPG fuel shutoff system for use with a vehicle having an LPG fuel engine and having a solenoid valve to supply and shut off LPG fuel is described including: a relay having a relay contact which is closed when an electric current is fed to a coil of the relay; a pressure switch having a first position and a second position and adapted to be in the first position when engine oil pressure rises above a predetermined level; and an oil lamp adapted to light when the engine oil pressure is below the predetermined level, and wherein a solenoid coil of the solenoid valve is connected at one side to a battery through an ignition switch and a fuel switch. The solenoid coil also is connected, at another side of the solenoid coil, in series to the relay contact and the pressure switch in the second position respectively, the coil of the relay is connected to the solenoid valve side of the ignition switch through a starting switch, the oil lamp is connected between the ignition switch and the pressure switch.

  10. Emissions from ethanol- and LPG-fueled vehicles

    SciTech Connect (OSTI)

    Pitstick, M.E.

    1995-06-01

    This paper addresses the environmental concerns of using neat ethanol and liquefied petroleum gas (LPG) as transportation fuels in the United States. Low-level blends of ethanol (10%) with gasoline have been used as fuels in the United States for more than a decade, but neat ethanol (85% or more) has only been used extensively in Brazil. LPG, which consists mostly of propane, is already used extensively as a vehicle fuel in the United States, but its use has been limited primarily to converted fleet vehicles. Increasing U.S. interest in alternative fuels has raised the possibility of introducing neat-ethanol vehicles into the market and expanding the number of LPG vehicles. Use of such vehicles, and increased production and consumption of fuel ethanol and LPG, will undoubtedly have environmental impacts. If the impacts are determined to be severe, they could act as barriers to the introduction of neat-ethanol and LPG vehicles. Environmental concerns include exhaust and evaporative emissions and their impact on ozone formation and global warming, toxic emissions from fuel combustion and evaporation, and agricultural impacts from production of ethanol. The paper is not intended to be judgmental regarding the overall attractiveness of ethanol or LPG as compared with other transportation fuels. The environmental concerns are reviewed and summarized, but only conclusion reached is that there is no single concern that is likely to prevent the introduction of neat-ethanol-fueled vehicles or the increase in LPG-fueled vehicles.

  11. LPG fuel supply system. [Patent for automotive

    SciTech Connect (OSTI)

    Pierson, W.V.

    1982-09-07

    A fuel supply system for an internal combustion engine operated on gaseous fuels, for example, liquid petroleum gas (Lpg). The system includes a housing having a chamber for vaporizing liquid gas, including means for heating the vaporizing chamber. Also included in the housing is a mixing chamber for mixing the vaporized gas with incoming air for delivery to the intake manifold of an internal combustion engine through a standard carburetor. The fuel supply system includes means for mounting the system on the carburetor, including means for supporting an air filter circumjacent the mixing chamber.

  12. Blast rips Texas LPG storage site

    SciTech Connect (OSTI)

    Not Available

    1992-04-13

    This paper reports that Seminole Pipeline Co. at presstime last week had planned to reopen its 775 mile liquefied petroleum gas pipeline in South Texas by Apr. 12 after a huge explosion devastated the area around a Seminole LPG storage salt dome near Brenham, Tex., forcing the pipeline shutdown. A large fire was still burning at the storage site at presstime last week. The blast - shortly after 7 a.m. Apr. 7 - occurred at a pipeline connecting the main Seminole line with the storage facility and caused shock waves felt 130 miles away. A 5 year old boy who lived in a trailer near Seminole's LPG storage dome was killed, and 20 persons were injured.

  13. Mounded LPG storage - Experience and developments

    SciTech Connect (OSTI)

    Barber, D.

    1988-01-01

    Liquefied petroleum gas (LPG) is stored after production, and for distribution and use, in pressure vessels which vary in size from a few kilogrammes to many thousands of tons. The types of LPG under consideration are commercial butane, commercial propane, or mixtures of the two gases in varying proportions. Mounded storage systems are becoming popular as an alternative to the better-known traditional systems. The most widely used and therefore best-known of the traditional systems are the above-ground pressure-vessel designs. These more commonly comprise factory-made cylinders which are installed horizontally, being supported on saddles at each end of the vessel. When such vessels are installed in an LPG terminal, depot, or filling plant, they are required in multiple units to facilitate the storage of more than one grade of product and to enable regular maintenance and inspection to be carried out. Today's safety regulations require such installations to be divided into sub-groups of six tanks, with all the tanks located at a safe distance from one another, and from other facilities in the immediate area. These safety distances are being increased as a result of experience, which means terminals now require large areas of land.

  14. Risks of LNG and LPG. [Review

    SciTech Connect (OSTI)

    Fay, J.A.

    1980-01-01

    Since the use of liquefied natural gas (LNG) and liquefied petroleum gases (LPG) as fuels is likely to increase and will certainly persist for some time to come, assessment of the safety of LNG/LPG systems will continue to draw attention and is quite likely to force continuing review of operating and design standards for LNG/LPG facilities. Scientific investigations to date appear to have identified the major hazards. Except for the dispersive behavior of vapor clouds - a not-insignificant factor in risk evaluation - the consequences of spills are well circumscribed by current analyses. The physically significant effects accompanying nonexplosive combustion of spilled material are fairly well documented; yet, potentially substantial uncertainties remain. Catastrophic spills of 10/sup 4/-10/sup 5/ m/sup 3/ on land or water are possible, given the current size of storage vessels. Almost all experimental spills have used less than 10 m/sup 3/ of liquid. There is thus some uncertainty regarding the accuracy and validity of extrapolation of current empirical information and physical models to spills of catastrophic size. The less-likely but still-possible explosive or fireball combustion modes are not well understood in respect to their inception. The troubling experience with such violent combustion of similar combustible vapors suggests that this possibility will need further definition. Extant LNG and LPG risk analyses illustrate the difficulties of substantiating the numerous event probabilities and the determination of all event sequences that can lead to hazardous consequences. Their disparate results show that significant improvements are needed. Most importantly, a detailed critique of past efforts and a determination of an exhaustive set of criteria for evaluating the adequacy of a risk analysis should precede any further attempts to improve on existing studies. 44 references, 1 table.

  15. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    SciTech Connect (OSTI)

    Yamamoto, Hajime; Pruess, Karsten

    2004-09-01

    To secure a stable supply of petroleum gas, underground storage caverns for liquified petroleum gas (LPG) are commonly used in many countries worldwide. Storing LPG in underground caverns requires that the surrounding rock mass remain saturated with groundwater and that the water pressure be higher than the liquid pressure inside the cavern. In previous studies, gas containment criteria for underground gas storage based on hydraulic gradient and pressure have been discussed, but these studies do not consider the physicochemical characteristics and behavior of LPG such as vaporization and dissolution in groundwater. Therefore, while these studies are very useful for designing storage caverns, they do not provide better understanding of the either the environmental effects of gas contamination or the behavior of vaporized LPG. In this study, we have performed three-phase fluid flow simulations of gas leakage from underground LPG storage caverns, using the multiphase multicomponent nonisothermal simulator TMVOC (Pruess and Battistelli, 2002), which is capable of solving the three-phase nonisothermal flow of water, gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. A two-dimensional cross-sectional model resembling an actual underground LPG facility in Japan was developed, and gas leakage phenomena were simulated for three different permeability models: (1) a homogeneous model, (2) a single-fault model, and (3) a heterogeneous model. In addition, the behavior of stored LPG was studied for the special case of a water curtain suddenly losing its function because of operational problems, or because of long-term effects such as clogging of boreholes. The results of the study indicate the following: (1) The water curtain system is a very powerful means for preventing gas leakage from underground storage facilities. By operating with appropriate pressure and layout, gas containment can be ensured. (2

  16. Demand for petrochem feedstock to buoy world LPG industry

    SciTech Connect (OSTI)

    Not Available

    1992-05-18

    This paper reports that use of liquefied petroleum gas as petrochemical feedstock will increase worldwide, providing major growth opportunities for LPG producers. World exports of liquefied petroleum gas will increase more slowly than production as producers choose to use LPG locally as chemical feedstock and export in value added forms such as polyethylene. So predicts Poten and Partners Inc., New York. Poten forecasts LPG production in exporting countries will jump to 95 million tons in 2010 from 45 million tons in 1990. However, local and regional demand will climb to 60 million tons/year from 23 million tons/year during the same period. So supplies available for export will rise to 35 million tons in 2010 from 22 million tons in 1990.

  17. End to deficit of LPG. [Argentina

    SciTech Connect (OSTI)

    Andrich, V.

    1980-03-01

    In the Buenos Aires province of Argentina, Gas de Estado is constructing the future heart of the petrochemical complex, Bahia Blanca. The complex contains 2 absorption-refrigeration plants, a gas compressing plant, equipment maintenance shops and an important operations base for the Argentine truck gas pipelines. This will be the largest LPG plant in Latin America. The General Cerri plant, under construction, is located in an area of 40,000 sq m with new installations to extract ethane and higher hydrocarbons. The design optimizes the extraction of hydrocarbons from the natural gas and recovers 76% of the ethane. Selection of the process resulted from an investigation that compared the system with processes that use water cooling and absorption with refrigerated oil.

  18. Experience with Bi-Fuel LPG Pickups in Texas

    SciTech Connect (OSTI)

    Whalen, P.

    1999-05-12

    The State of Texas requires state agencies to purchase alternative fuel vehicles (AFVs). In 1996, Texas Department of Transportation (TxDOT) representatives added about 400 bi-fuel liquefied petroleum gas (LPG) pickup trucks to their fleet. The fleet managers were willing to share information about their fleets and the operation of these vehicles, so a study was launched to collect operations, maintenance, and cost data for selected LPG and gasoline vehicles (as controls) throughout 18 months of vehicle operation. This case study presents the results of that data collection and its subsequent analysis.

  19. LPG storage vessel cracking experience

    SciTech Connect (OSTI)

    Cantwell, J.E.

    1988-01-01

    As part of an overall company program to evaluate LPG handling and storage hazards the authors surveyed several installations for storage vessel cracking problems. Cracking was found in approximately one third of the storage vessels. In most cases the cracking appeared due to original fabrication problems and could be removed without compromising the pressure containment. Several in-service cracking problems due to exposure to wet hydrogen sulfide were found. Various procedures were tried in order to minimize the in-service cracking potential. One sphere was condemned because of extensive subsurface cracking. Recommendations are made to minimize cracking on new and existing LPG storage vessels.

  20. Industrial cooperation in the field of LPG

    SciTech Connect (OSTI)

    Stefano, M.; Trollux, J.; Dune, J.J.

    1988-01-01

    The years to come should confirm the availability of LPG worldwide and enable future users in developing countries to satisfy energy requirements which today are only partly covered, if at all. This paper is designed to point the benefits that these new LPG markets could derive from active cooperation with experienced companies operating in mature LPG markets.

  1. Utilization of LPG for vehicles in Japan

    SciTech Connect (OSTI)

    Kusakabe, M.; Makino, M.; Tokunoh, M.

    1988-01-01

    LPG demand for vehicles amounts to 1.8 MM tons annually, equivalent to about 11% of the total LPG consumption in Japan. The feature which dominates the demand of LPG as a vehicle fuel in Japan is the high penetration of LPG powered vehicles into taxi fleets. This has been made possible following the rationalization in the taxi business in the early 1960s. Today, three quarters of LPG vehicles, numbering some 235,000 while representing only about 1% of the total number of vehicles, account for nearly 93% of all taxicabs.

  2. Process for LPG recovery

    SciTech Connect (OSTI)

    Khan, S.A.; Haliburton, J.

    1990-10-30

    This patent describes an improvement in a process for separating propane and heavier hydrocarbons from a gaseous feedstream containing hydrocarbon components of different boiling points wherein the feedstream is cooled and separated into a first vapor fraction and a first liquid fraction and the first liquid fraction is distilled in a deethanizer to form a second vapor fraction and a second liquid fraction. The improvement comprises expanding and transferring the first vapor fraction to the lower portion of a direct heat exchanger, cooling {ital at least a portion of} the second vapor fraction {ital by passing it through an indirect heat exchanger} to form a substantially liquefied stream, {ital partially flashing at least a portion of the liquefied stream and transferring it} to the upper portion of the direct heat exchanger whereby the liquefied stream contacts the first vapor fraction to form a third vapor fraction and a third liquid fraction, {ital transferring} the third liquid fraction to the deethanizer, and removing the third vapor fraction from the direct heat exchanger {ital and passing the third vapor fraction through the indirect heat exchanger}.

  3. Cylinder surface, temperature may affect LPG odorization

    SciTech Connect (OSTI)

    McWilliams, H.

    1988-01-01

    A study of possible odorant fade in propane by the Arthur D. Little Co. (Boston) has indicated that oxidation of interior surfaces of LPG containers may cause the odorant, ethyl mercaptan, to fade. The oxidation, ferous oxide, is a black, easily oxidizable powder that is the monoxide of iron. The study, contracted for by the Consumer Product Safety Commission (CPSC), is part of that agency's study of residential LP-gas systems. Another study is currently underway by an NLPGA task force headed by Bob Reid of Petrolane (Long Beach, Calif.). It may not be finished until the end of next year. Recently, the Propane Gas Association of Canada completed a study of odorant fade with the conclusion that much more study is needed on the subject. In addition to the cylinder surface problem, the CPSC study indicated that ambient temperatures might also affect the presence of odorant in product. This article reviews some of the results.

  4. Successful operation of a large LPG plant. [Kuwait

    SciTech Connect (OSTI)

    Shtayieh, S.; Durr, C.A.; McMillan, J.C.; Collins, C.

    1982-03-01

    The LPG plant located at Mina-Al Ahmadi, Kuwait, is the heart of Kuwait Oil Co.'s massive Gas Project to use the associated gas from Kuwait's oil production. Operation of this three-train plant has been very successful. A description is given of the three process trains consisting of four basic units: extraction, fractionation, product treating, and refrigeration. Initial problems relating to extraction, fractionation, product treating and, refrigeration are discussed. 1 ref.

  5. Fire safety of LPG in marine transportation. Final report

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-06-01

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  6. Dehydrocyclodimerization, converting LPG to aromatics

    SciTech Connect (OSTI)

    Johnson, J.A.; Hilder, G.K.

    1984-03-01

    British Petroleum (BP) recognized the potential need for ways of exploiting feedstocks with low opportunity cost and commenced a research program at its Sunbury Research Center to discover and develop a catalyst for the conversion of LPG to a liquid product. The successful outcome of this research program is the Cyclar /SUP SM/ process, a joint development of UOP Process Division and British Petroleum. The Cyclar process offers a single-step conversion of LPG to an aromatic product which has a highvalue, is easily transported and useful both to fuel and petrochemical applications. The LPG producer can invest in a single unit, avoiding the need to identify and develop markets for multiple C/sub 3/ and C/sub 4/ products. This catalytic process, which employs UOP Continuous Catalyst Regeneration (CCR) technology, can also be applied to refinery light ends to produce a high-quality gasoline. Aromatic and hydrogen yields from propane and butane feeds surpass those obtained from catalytic reforming of Light Arabian naphtha. This paper describes the principles of the Cyclar process and illustrates yields and economics for several interesting applications.

  7. LPG Electrical, Inc | Open Energy Information

    Open Energy Info (EERE)

    LPG Electrical, Inc Jump to: navigation, search Name: ANGWIN Electrical Address: 13833 Wellington Trace Rd. 4 Place: Wellington, Florida Zip: 33414 Sector: Services Product:...

  8. Carbon footprints of heating oil and LPG heating systems

    SciTech Connect (OSTI)

    Johnson, Eric P.

    2012-07-15

    For European homes without access to the natural gas grid, the main fuels-of-choice for heating are heating oil and LPG. How do the carbon footprints of these compare? Existing literature does not clearly answer this, so the current study was undertaken to fill this gap. Footprints were estimated in seven countries that are representative of the EU and constitute two-thirds of the EU-27 population: Belgium, France, Germany, Ireland, Italy, Poland and the UK. Novelties of the assessment were: systems were defined using the EcoBoiler model; well-to-tank data were updated according to most-recent research; and combustion emission factors were used that were derived from a survey conducted for this study. The key finding is that new residential heating systems fuelled by LPG are 20% lower carbon and 15% lower overall-environmental-impact than those fuelled by heating oil. An unexpected finding was that an LPG system's environmental impact is about the same as that of a bio heating oil system fuelled by 100% rapeseed methyl ester, Europe's predominant biofuel. Moreover, a 20/80 blend (by energy content) with conventional heating oil, a bio-heating-oil system generates a footprint about 15% higher than an LPG system's. The final finding is that fuel switching can pay off in carbon terms. If a new LPG heating system replaces an ageing oil-fired one for the final five years of its service life, the carbon footprint of the system's final five years is reduced by more than 50%.

  9. LPG dealers, manufacturers report diverse effects of recession and war

    SciTech Connect (OSTI)

    Prowler, S.

    1991-01-01

    The author presents a survey of LPG marketers. The effects of the Persian Gulf War and U.S. recession on the LPG industry are discussed.

  10. Influence of H{sub 2}O{sub 2} on LPG fuel performance evaluation

    SciTech Connect (OSTI)

    Khan, Muhammad Saad Ahmed, Iqbal Mutalib, Mohammad Ibrahim bin Abdul Nadeem, Saad Ali, Shahid

    2014-10-24

    The objective of this mode of combustion is to insertion of hydrogen peroxide (H{sub 2}O{sub 2}) to the Liquefied Petroleum Gas (LPG) combustion on spark plug ignition engines. The addition of hydrogen peroxide may probably decrease the formation of NO{sub x}, CO{sub x} and unburned hydrocarbons. Hypothetically, Studies have shown that addition of hydrogen peroxide to examine the performance of LPG/H{sub 2}O{sub 2} mixture in numerous volumetric compositions starting from lean LPG until obtaining a better composition can reduce the LPG fuel consumption. The theory behind this idea is that, the addition of H{sub 2}O{sub 2} can cover the lean operation limit, increase the lean burn ability, diminution the burn duration along with controlling the exhaust emission by significantly reducing the greenhouse gaseous.

  11. Algeria LPG pipeline is build by Bechtel

    SciTech Connect (OSTI)

    Horner, C.

    1984-08-01

    The construction of the 313 mile long, 24 in. LPG pipeline from Hassi R'Mel to Arzew, Algeria is described. The pipeline was designed to deliver 6 million tons of LPG annually using one pumping station. Eventually an additional pumping station will be added to raise the system capacity to 9 million tons annually.

  12. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  13. Technical evaluation and assessment of CNG/LPG bi-fuel and flex-fuel vehicle viability

    SciTech Connect (OSTI)

    Sinor, J E

    1994-05-01

    This report compares vehicles using compressed natural gas (CNG), liquefied petroleum gas (LPG), and combinations of the two in bi-fuel or flex-fuel configurations. Evidence shows that environmental and energy advantages can be gained by replacing two-fuel CNG/gasoline vehicles with two-fuel or flex-fuel systems to be economically competitive, it is necessary to develop a universal CNG/LPG pressure-regulator-injector and engine control module to switch from one tank to the other. For flex-fuel CNG/LPG designs, appropriate composition sensors, refueling pumps, fuel tanks, and vaporizers are necessary.

  14. Next generation processes for NGL/LPG recovery

    SciTech Connect (OSTI)

    Pitman, R.N.; Hudson, H.M.; Wilkinson, J.D.; Cuellar, K.T.

    1998-12-31

    Up to now, Ortloff`s Gas Subcooled Process (GSP) and OverHead Recycle Process (OHR) have been the state-of-the-art for efficient NGL/LPG recovery from natural gas, particularly for those gases containing significant concentrations of carbon dioxide (CO{sub 2}). Ortloff has recently developed new NGL recovery processes that advance the start-of-the-art by offering higher recovery levels, improved efficiency, and even better CO{sub 2} tolerance. The simplicity of the new process designs and the significantly lower gas compression requirements of the new processes reduce the investment and operating costs for gas processing plants. For gas streams containing significant amounts of carbon dioxide, the CO{sub 2} removal equipment upstream of the NGL recovery plant can be smaller or eliminated entirely, reducing both the investment cost and the operating cost for gas processing companies. In addition, the new liquids extraction processes can be designed to efficiently recover or reject ethane, allowing the gas processor to respond quickly to changing market conditions. This next generation of NGL/LPG recovery processes is now being applied to natural gas processing here in the US and abroad. Two of the new plants currently under construction provide practical examples of the benefits of the new processes.

  15. Africa gaining importance in world LPG trade

    SciTech Connect (OSTI)

    Haun, R.R.; Otto, K.W.; Whitley, S.C.

    1997-05-12

    Major LPG projects planned or under way in Africa will increase the importance of that region`s presence in world LPG trade. Supplies will nearly double between 1995 and 2005, at which time they will remain steady for at least 10 years. At the same time that exports are leveling, however, increasing domestic demand for PG is likely to reduce export-market participation by Algeria, Nigeria, Egypt, and Libya. The growth of Africa`s participation in world LPG supply is reflected in comparisons for the next 15--20 years. Total world supply of LPG in 1995 was about 165 million metric tons (tonnes), of which Africans share was 7.8 million tonnes. By 2000, world supply will grow to slightly more than 200 million tonnes, with Africa`s share expected to increase to 13.2 million tonnes (6.6%). And by 2005, world LPG supply will reach nearly 230 million tonnes; Africa`s overall supply volumes by that year will be nearly 16.2 million tonnes (7%). World LPG supply for export in 1995 was on order of 44 million tonnes with Africa supply about 4 million tonnes (9%). By 2005, world export volumes of LPG will reach nearly 70 million tonnes; Africa`s share will have grown by nearly 10 million tonnes (14.3%).

  16. LPG land transportation and storage safety. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-09-01

    This report contains an analytical examination of fatal accidents involving liquefied petroleum gas (LPG) releases during transportation and/or transportation related storage. Principal emphasis was on accidents during the nine-year period 1971 to 1979. Fatalities to members of the general public (i.e., those at the scene of the accident through coincidence or curiosity) were of special interest. Transportation accidents involving railroad tank cars, trucks, and pipelines were examined as were accidents at storage facilities, including loading and unloading at such facilities. The main sources of the necessary historical accident data were the accident reports submitted to the Department of Transportation by LPG carriers, National Transportation Safety Board accident reports, articles in the National Fire Protection Association journals, other literature, and personal interviews with firemen, company personnel, and others with knowledge of certain accidents. The data indicate that, on the average, releases of LPG during transportation and intermediate storage cause approximately six fatalities per year to members of the general public. The individual risk is about 1 death per 37,000,000 persons; about the same as the risk of a person on the ground being killed by an airplane crash, and much less than the risk of death by lightning, tornadoes, or dam failures.

  17. LPG land transportation and storage safety. Final report

    SciTech Connect (OSTI)

    Martinsen, W.E.; Cavin, W.D.

    1981-09-01

    This report contains an analytical examination of fatal accidents involving liquefied petroleum gas (LPG) releases during transportation and/or transportation related storage. Principal emphasis was on accidents during the nine-year period 1971 through 1979. Fatalities to members of the general public (i.e., those at the scene of the accident through coincidence or curiosity) were of special interest. Transportation accidents involving railroad tank cars, trucks, and pipelines were examined as were accidents at storage facilities, including loading and unloading at such facilities. The main sources of the necessary historical accident data were the accident reports submitted to the Department of Transportation by LPG carriers, National Transportation Safety Board accident reports, articles in the National Fire Protection Association journals, other literature, and personal interviews with firemen, company personnel, and others with knowledge of certain accidents. The data indicate that, on the average, releases of LPG during transportation and intermediate storage cause approximately six fatalities per year to members of the general public. The individual risk is about 1 death per 37,000,000 persons; about the same as the risk of a person on the ground being killed by an airplane crash, and much less than the risk of death by lightning, tornadoes, or dam failures.

  18. Overfilling of cavern blamed for LPG blasts

    SciTech Connect (OSTI)

    Not Available

    1992-07-06

    Three explosions and a fire Apr. 7 at an LPG salt dome storage cavern near Brenham, Tex., were triggered when the cavern was overfilled, the Texas Railroad Commission (TRC) has reported. This paper reports that a TRC investigation found that LPG escaped to the surface at the Brenham site through brine injection tubing after excessive fill from an LPG line forced the cavern's water level below the brine tubing's bottom. At the surface, LPG was released into a brine storage pit where it turned into a dense, explosive vapor. At 7:08 a.m., the vapor was ignited by an unknown source. The resulting blast killed three persons and injured 19 and brought operations at the site to a halt.

  19. DISTILLATION OF CALCIUM

    DOE Patents [OSTI]

    Barton, J.

    1954-07-27

    This invention relates to an improvement in the process for the purification of caicium or magnesium containing an alkali metal as impurity, which comprises distiiling a batch of the mixture in two stages, the first stage distillation being carried out in the presence of an inert gas at an absolute pressure substantially greater than the vapor pressure of calcium or maguesium at the temperature of distillation, but less than the vaper pressure at that temperature of the alkali metal impurity so that only the alkali metal is vaporized and condensed on a condensing surface. A second stage distilso that substantially only the calcium or magnesium distills under its own vapor pressure only and condenses in solid form on a lower condensing surface.

  20. Cause not found for Texas LPG site blast

    SciTech Connect (OSTI)

    Not Available

    1992-04-20

    This paper reports that National Transportation Safety Board investigators completed the first phase of tests at Seminole Pipeline Co.'s liquid petroleum gas storage dome near Brenham, Tex., without finding the cause of an explosion there Apr. 7. But in a week of investigation, NTSB determined that a release of brine and product occurred at the 350,000 bbl LPG storage dome, about 45 miles northwest of Houston, just before the blast. The explosion sent shock waves felt as far as 130 miles away. Three persons have died from injuries suffered in the accident. Another 18 were injured.

  1. A simple correlation to predict the hydrate quadruple point temperature for LPG mixtures

    SciTech Connect (OSTI)

    Yousif, M.H.

    1997-12-31

    A simple correlation to predict the hydrate upper quadruple point temperature, T{sub Q2B} for liquefied petroleum gas (LPG) mixtures was developed. It was developed for use as a part of a modeling and control system for a LPG pipeline in Russia. For performance reasons, a simple hydrate prediction correlation was required that could be incorporated into the real-time and predictive pipeline simulation models. The operating company required both real time and predictive simulation tools be developed to assist in preventing hydrate blockages while minimizing the use of methanol. In this particular pipeline, LPG fluid moves through the pipeline as a single phase liquid above its bubble point pressure. Because of the very low flow rates, the trace amount of water present in the LPG drops out and creates water pools at low points in the pipeline. The pipeline pressure and seasonal temperatures are conducive for hydrate formation in these pools. Methanol and monoethylene glycol (MEG) are injected in the pipeline to help prevent hydrate formation. The newly developed correlation predicts the hydrate quadruple point temperature using only the composition and the molecular weight of the LPG mixture while retaining an accuracy comparable to the statistical thermodynamic models throughout the range of normal operating conditions.

  2. Ageing effect in spray pyrolysed B:SnO{sub 2} thin films for LPG sensing

    SciTech Connect (OSTI)

    Skariah, Benoy E-mail: dr.boben1@gmail.com; Thomas, Boben E-mail: dr.boben1@gmail.com

    2014-10-15

    For LPG sensing, boron doped (0.2 to 0.8 wt. %) polycrystalline tin oxide thin films are deposited by spray pyrolysis in the temperature range 325 - 430 °C. Sensor response of 56 % is achieved for 1000 ppm of LPG, at an operating temperature of 350 °C. The effects of ageing under ambient conditions on the sensor response are investigated for a storage period of six years. Ageing increases the film resistance but the gas response is lowered. XRD, SEM, FESEM, FTIR and XPS are utilized for structural, morphological and compositional charaterisations.

  3. LPG odorization with an audit trail

    SciTech Connect (OSTI)

    Astala, A.A.

    1995-12-01

    In this article I have tried to cover a very broad subject in a very limited time while only touching on a few of the ways you could odorize LPG and have an audit trail. I would recommend that if you are interested in this type of odorizing for LPG, you contact your odorant manufacturer and two or three odorant equipment manufacturers and talk to them about what you would like and get their recommendations. By talking to more then one manufacturer you may want to incorporate the ideals of two or three manufacturers into your odorant system to have a system that meets all your needs and requirements.

  4. New method developed for LPG offshore loading

    SciTech Connect (OSTI)

    Not Available

    1985-10-01

    An innovative concept for refrigerated LPG offshore loading has been developed by TOTAL and Enterprise D'Equipments Mecaniques at Hydrauliques. Known as CHAGAL, the system integrates with the catenary anchor leg mooring offshore loading system commonly used for crude oil. CHAGAL provides a suitable answer to short-term development schemes of LPG trade. It can be adapted for possible extrapolation to cryogenic temperatures of LNG and it opens a new way to the development of offshore liquefaction projects for which the offloading of production is still an unsolved key problem.

  5. Alvord (3000-ft Strawn) LPG flood: design and performance evaluation

    SciTech Connect (OSTI)

    Frazier, G.D.; Todd, M.R.

    1982-01-01

    Mitchell Energy Corporation has implemented a LPG-dry gas miscible process in the Alvord (3000 ft Strawn) Unit in Wise County, Texas utilizing the DOE tertiary incentive program. The field had been waterflooded for 14 years and was producing near its economic limit at the time this project was started. This paper presents the results of the reservoir simulation study that was conducted to evaluate pattern configuration and operating alternatives so as to maximize LPG containment and oil recovery performance. Several recommendations resulting from this study were implemented for the project. Based on the model prediction, tertiary oil recovery is expected to be between 100,000 and 130,000 bbls, or about 7 percent of th oil originally in place in the Unit. An evaluation of the project performance to date is presented. In July of 1981 the injection of a 16% HPV slug of propane was completed. Natural gas is being used to drive the propane slug. A peak oil response of 222 BOPD was achieved in August of 1981 and production has since been declining. The observed performance of the flood indicates that the actual tertiary oil recovered will reach the predicted value, although the project life will be longer than expected. The results presented in this paper indicate that, without the DOE incentive program, the economics for this project would still be uncertain at this time.

  6. Alternative fuel information: Facts about CNG and LPG conversion

    SciTech Connect (OSTI)

    O`Connor, K.

    1994-06-01

    As new environmental and energy related laws begin to take effect, increasing numbers of alternative fuel vehicles (AFVs) will be required in federal, state, municipal, and private fleets across the country. The National Energy Policy Act of 1992 and the Clean Air Act Amendments of 1990, along with several new state and local laws, will require fleet managers to either purchase original equipment manufacturer (OEM) vehicles, which are produced by automakers, or convert existing vehicles to run on alternative fuels. Because there is a limited availability and selection of OEM vehicles, conversions are seen as a transition to the time when automakers will produce more AFVs for public sale. A converted vehicle is any vehicle that originally was designed to operate on gasoline, and has been altered to run on an alternative fuel such as compressed natural gas (CNG) or propane (liquefied petroleum gas -- LPG), the two most common types of fuel conversions. In the United States, more than 25,000 vehicles already have been converted to COG, and 300,000 have been converted to LPG.

  7. Fuel switching from wood to LPG can benefit the environment

    SciTech Connect (OSTI)

    Nautiyal, Sunil Kaechele, Harald

    2008-11-15

    The Himalaya in India is one of the world's biodiversity hotspots. Various scientific studies have reported and proven that many factors are responsible for the tremendous decline of the Himalayan forests. Extraction of wood biomass from the forests for fuel is one of the factors, as rural households rely entirely on this for their domestic energy. Efforts continue for both conservation and development of the Himalayan forests and landscape. It has been reported that people are still looking for more viable solutions that could help them to improve their lifestyle as well as facilitate ecosystem conservation and preservation of existing biodiversity. In this direction, we have documented the potential of the introduction of liquefied petroleum gas (LPG), which is one of the solutions that have been offered to the local people as a substitute for woodfuel to help meet their domestic energy demand. The results of the current study found dramatic change in per capita woodfuel consumption in the last two decades in the villages where people are using LPG. The outcome showed that woodfuel consumption had been about 475 kg per capita per year in the region, but after introduction of LPG, this was reduced to 285 kg per capita per year in 1990-1995, and was further reduced to 46 kg per capita per year in 2000-2005. Besides improving the living conditions of the local people, this transformation has had great environmental consequences. Empirical evidence shows that this new paradigm shift is having positive external effects on the surrounding forests. Consequently, we have observed a high density of tree saplings and seedlings in adjacent forests, which serves as an assessment indicator of forest health. With the help of the current study, we propose that when thinking about a top-down approach to conservation, better solutions, which are often ignored, should be offered to local people.

  8. Product transfer service chosen over LPG flaring

    SciTech Connect (OSTI)

    Horn, J.; Powers, M.

    1994-07-01

    Seadrift Pipeline Corp. recently decommissioned its Ella Pipeline, an 108-mile, 8-in. line between the King Ranch and a Union Carbide plant at Seadrift, Texas. The pipeline company opted for the product transfer services of pipeline Dehydrators Inc. to evacuate the ethane-rich LPG mixture from the pipeline instead of flaring the LPG or displacing it with nitrogen at operating pressures into another pipeline. The product transfer system of Pipeline Dehydrators incorporates the use of highly specialized portable compressors, heat exchangers and interconnected piping. The product transfer process of evacuating a pipeline is an economically viable method that safely recovers a very high percentage of the product while maintaining product purity. Using positive-displacement compressors, PLD transferred the LPG from the idled 8-in. Ella line into an adjacent 12-in. ethane pipeline that remained in service at approximately 800 psig. Approximately 4.3 million lb of LPG (97% ethane, 2.7% methane and 0.3% propane) were transferred into the ethane pipeline, lowering the pressure on the Ella Pipeline from 800 psig to 65 psig.

  9. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  10. Risk analysis of an LPG facility

    SciTech Connect (OSTI)

    Daley, H.F.; Chapman, P.D.L.

    1986-01-01

    This paper describes methods used to conduct a safety review of an existing LPG loading, processing, and storage facility. An engineering team conducted a Hazard and Operability study of the plant to identify potential problems. A Probabilistic Risk Assessment was also made on the facility where the probability and consequences of worst case accidents were estimated. Stone and Webster recently completed an analysis of an LPG terminal to determine if there were any engineering, design, or operating deficiencies which could jeopardize the operability of the facility or make operation hazardous. The facility includes a dock for off-loading refrigerated propane and butane, transfer piping from the dock to storage, a heating system, pressurized storage, dehydration, product transfer and loading.

  11. Vacuum Distillation

    U.S. Energy Information Administration (EIA) Indexed Site

    Thermal Cracking: OtherGas Oil Thermal Cracking: Coking (BarrelsCalendar Day) Catalytic Cracking Fresh Feed Catalytic Cracking Fresh Feed (BarrelsCalendar Day) Catalytic ...

  12. The operation of LPG relief valves

    SciTech Connect (OSTI)

    Stannard, J.H. Jr

    1989-11-01

    As stipulated by NFPA 58, all LPG storage containers must be equipped with one or more pressure relief devices. These devices are sized to prevent rupture of a normally charged container when exposed to fire. This paper describes in detail the functioning of the spring-loaded relief valve. The author discusses how the venting of LPGs can produce unacceptable risks and how training is a necessary part of controlling such a situation.

  13. Monitoring system tested during LPG tanker unloading

    SciTech Connect (OSTI)

    Not Available

    1990-05-14

    A specially developed computer-based hazardous-materials monitoring system has been successfully field tested. The test of the portable system occurred during the unloading of 45,000 metric tons of LPG from a 740-ft tanker at the petroleum dock of a plant along the Mississippi River. The function of this system is to detect, report, alarm, and record unacceptable concentrations of hazardous vapors during marine-transfer operations.

  14. Novel coiled tubing application controls large LPG storage well fire

    SciTech Connect (OSTI)

    Gebhardt, F.; Eby, D.; Barnett, D.

    1996-06-01

    Conventional well control techniques for normal oil and gas wells are widely known and have been presented on numerous occasions. However, LPG storage (or cavern) wells rarely blow out and/or catch on fire. As a result, little information has been presented on the topic of well control for these types of wells. This article chronicles a case history of a high-volume liquid propane storage well fire. Because conventional wellhead removal methods could not be applied in this case, the capping/kill plan called for use of coiled tubing in a novel manner to cut the tubing downhole and install an inflatable packer to shut off propane flow. The plan was successfully executed, saving the operator millions of dollars in LPC product loss and cost of control.

  15. Australian liquids-handling system cuts surges to LPG plant

    SciTech Connect (OSTI)

    McKee, G.; Stenner, T.D. )

    1990-08-06

    This paper reports how a pipeline liquids-handling facility recently commissioned allows gas production to be quickly ramped up to meet customer demand. Its design eliminates trouble-some liquid surges which had hampered plant operations. The pipeline-loop system, located at the Wallumbilla LPG processing plant, Queensland, was built for 60 of the cost of an equivalently sized conventional slug catcher. Its control system enables automatic, unattended handling of liquid surges and pigging slugs from the 102-km Silver Springs to Wallumbilla two-phase pipeline. Because of this system's simple hydraulics, normal slug-catcher piping design problems are eliminated. Safety is improved because the potentially hazardous condensate liquid is contained in a buried pipeline.

  16. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A.

    1984-01-01

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  17. Radiological health implications of lead-210 and polonium-210 accumulations in LPG refineries

    SciTech Connect (OSTI)

    Summerlin, J. Jr.; Prichard, H.M.

    1985-04-01

    Radon-222, a naturally occurring radioactive noble gas, is often a contaminant in natural gas. During fractionation at processing plants, Radon tends to be concentrated in the Liquified Petroleum Gas (LPG) product stream. Radon-222 decays into a number of radioactive metallic daughters which can plate out on the interior surfaces of plant machinery. The hazards associated with gamma-emitting short-lived radon daughters have been investigated previously. The present work reports an analysis of the hazards associated with the long-lived daughters; Pb-210, Bi-210, and Po-210. These nuclides do not emit appreciable penetrating radiation, and hence do not represent a hazard as long as they remain on the inside surfaces of equipment. However, when equipment that has had prolonged exposure to an LPG stream is disassembled for repair or routine maintenance, opportunities for exposure to radioactive materials can occur. A series of measurements made on an impeller taken from a pump in an LPG facility is reported. Alpha spectroscopy revealed the presence of Po-210, and further measurements showed that the amount on the impeller surface was well above the exempt quantity. Breathing zone measurements made in the course of cleaning the impeller showed that an inhalation exposure equivalent to breathing Po-210 at the Maximum Permissible Concentration (MPC) for 60 hours could be delivered in less than half an hour. It was concluded that maintenance and repair work on LPG and derivitive product stream equipment must be carried out with the realization that a potential radiological health problem exists.

  18. Current and future USA-world seaborne imports at LPG

    SciTech Connect (OSTI)

    Bassa, G.

    1980-01-01

    An outline of the current and historical situation of the international LPG trade and comparison between the US and other countries covers methods of marine transportation, including fully refrigerated vessels, semirefrigerated vessels, pressure vessels, and LNG ships fitted for LPG; the temporary abundance of LPG; a comparison of the markets in Japan, Europe, South America, and the US to indicate the potential market in the future, e.g., the need in Japan for LPG as a basic fuel, main use in Europe as a feedstock and as domestic fuel, use as a basic fuel but mainly in the winter months inSouth America, and the volatile spot market in the US; and the conclusion that the capacity to produce LPG will keep pace with demand only as long as adequate prices are paid to offset production costs.

  19. Alvord (3,000-ft strawn) LPG flood - design and performance evaluation

    SciTech Connect (OSTI)

    Frazier, G.D.; Todd, M.R.

    1982-01-01

    Mitchell Energy Corporation has implemented a LPG-dry gas miscible process in the Alvord (3000' Strawn) Unit in Wise County, Texas utilizing the DOE tertiary incentive program. The field had been waterflooded for 14 years and was producing near its economic limit at the time this project was started. This paper presents the results of the reservoir simulation study that was conducted to evaluate pattern configuration and operating alternatives so as to maximize LPG containment and oil recovery performance. Several recommendations resulting from this study were implemented for the project. Based on the model predictions, tertiary oil recovery is expected to be between 100,000 and 130,000 bbls, or about 7 percent of the oil originally in place in the Unit. 12 refs.

  20. N/sub 2/-driven LPG achieves miscibitity at high temperatures

    SciTech Connect (OSTI)

    Carlisle, L.; Crawford, P.B.; Montes, M. Jr.; Reeves, S.

    1982-11-01

    Shows that miscibility can be achieved at very low pressures above the critical temperature of propane. One can calculate the critical pressure and temperature for a variety of fluids of practical interest in achieving miscibility between the miscible slug and driving gas when applying enhanced oil recovery programs. A study of the critical properties of normally available reservoir fluids indicates that one method of achieving miscibility at lower pressures, even at high reservoir temperatures, might be to use LPG slugs pushed by nitrogen. Table gives the oil recovery for different LPG slug sizes when operating at a reservoir pressure of 2,000 psig and a reservoir temperature of 250F. Diagram shows the approximate critical temperature loci for ternary systems made up of 3 components from the group nitrogen, methane, ethane, and propane. By finding the desired reservoir temperature and then estimating the critical pressure required, one may select compositions and operating pressures required to achieve critical slug-driving gas mixtures for use in enhanced oil recovery programs. When using CO/sub 2/ for miscibility, the miscibility pressure increases with temperature. Use of LPG slugs results in a substantial reduction in the pressure required for miscibility.

  1. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  2. Charcoal versus LPG grilling: A carbon-footprint comparison

    SciTech Connect (OSTI)

    Johnson, Eric

    2009-11-15

    Undoubtedly, grilling is popular. Britons fire up their barbeques some 60 million times a year, consuming many thousands of tonnes of fuel. In milder climates consumption is even higher, and in the developing world, charcoal continues to be an essential cooking fuel. So it is worth comparing the carbon footprints of the two major grill types, charcoal and LPG, and that was the purpose of the study this paper documents. Charcoal and LPG grill systems were defined, and their carbon footprints were calculated for a base case and for some plausible variations to that base case. In the base case, the charcoal grilling footprint of 998 kg CO{sub 2}e is almost three times as large as that for LPG grilling, 349 kg CO{sub 2}e. The relationship is robust under all plausible sensitivities. The overwhelming factors are that as a fuel, LPG is dramatically more efficient than charcoal in its production and considerably more efficient in cooking. Secondary factors are: use of firelighters, which LPG does not need; LPG's use of a heavier, more complicated grill; and LPG's use of cylinders that charcoal does not need.

  3. Carbon adsorption system protects LPG storage sphere

    SciTech Connect (OSTI)

    Gothenquist, C.A.; Rooker, K.M.

    1996-07-01

    Chevron U.S.A. Products Co. installed a carbon adsorption system to protect an LPG storage sphere at its refinery in Richmond, Calif. Vessel damage can result when amine contamination leads to emulsion formation and consequent amine carry-over, thus promoting wet-H{sub 2}S cracking. In Chevron`s No. 5 H{sub 2}S recovery plant, a mixture of butane and propane containing H{sub 2}S is contacted with diethanolamine (DEA) in a liquid-liquid absorber. The absorber is a countercurrent contactor with three packed beds. Because the sweetening system did not include a carbon adsorption unit for amine purification, contaminants were building up in the DEA. The contaminants comprised: treatment chemicals, hydrocarbons, foam inhibitors, and amine degradation products. The paper describes the solution to this problem.

  4. LPG export growth will exceed demand by 2000

    SciTech Connect (OSTI)

    True, W.R.

    1994-08-08

    LPG supplies for international trade will increase sharply through 2000 and begin to outstrip demand by 1997 or 1998. This outlook depends on several production projects proceeding as planned. Leading the way to increased volumes are projects in Algeria, Nigeria, and Australia, among others. Purvin and Gertz, Dallas, projected this trend earlier this year at an international LPG seminar near Houston. Representatives from LPG-supplying countries also presented information to support this view and subsequently supplied more specifics to OGJ in response to questions. This paper discusses this information. Trends in Africa, Australia, North America, and South America are forecast.

  5. FCC LPG olefinicity and branching enhanced by octane catalysts

    SciTech Connect (OSTI)

    Keyworth, D.A.; Reid, T.A.; Kreider, K.R.; Yatsu, C.A.

    1989-05-29

    Refiners are increasingly recognizing the downstream opportunities for fluid catalytic cracking LPG olefins for the production of methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE, if the ethanol subsidy is extended to the production of ETBE), and as petrochemical feedstocks. Some of new gasoline FCC octane-enhancing catalysts can support those opportunities because their low non-framework alumina (low NFA) preserve both LPG olefinicity and promote branching of the LPG streams from the FCCU. The combined effect results in more isobutane for alkylate feed, more propylene in the propane/propylene stream, and more isobutene - which makes the addition of an MTBE unit very enticing.

  6. Accurate LPG analysis begins with sampling procedures, equipment

    SciTech Connect (OSTI)

    Wilkins, C.M. )

    1990-11-05

    Proper equipment and procedures are essential for obtaining representative samples from an LPG stream. This paper discusses how sampling of light liquid hydrocarbons generally involves one of two methods: flow- proportional composite sampling by a mechanical device or physical transfer of hydrocarbon fluids from a flowing pipeline or other source into a suitable portable sample container. If sampling by proper techniques and equipment supports careful chromatographic analysis, full advantage of accurate mass measurement of LPG can be realized.

  7. River resort owners find LPG a power behind their success

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This paper reports on a restaurant and resort which runs entirely on LPG. It has two generators converted to LPG that supply the power for the complex. Energy supplied from the propane is used in the kitchens, to drive the water pump and provide electricity for lighting and other power needs, and to heat the swimming pool. Far more importantly for the owners has been the fuel cost savings of at least 60%.

  8. World`s LPG supply picture will change by 2000

    SciTech Connect (OSTI)

    True, W.R.

    1995-11-06

    Middle East LPG producers will continue to dominate world export markets in 1996. Led by Saudi Arabia, the Middle East will produce nearly 26 million metric tons of LPG in million metric tons of LPG in 1996, more than 54% of the world`s almost 48 million metric tons of export LPG. In 2000, however, with world exports of LPG expanding to 58.9 million metric tons, Middle East suppliers; share will have remained flat, making up 31.7 million metric tons, or 53.9%. Saudi Arabia`s contribution will exceed 15 million metric tons, reflecting essentially no growth since 1995. These and other patterns, from data compiled by Purvin and Gertz, Dallas, and published earlier this year, show other suppliers of LPG, especially African (Algeria/Nigeria), North Sea, and Latin American (Venezuela/Argentina), picking up larger shares in the last 5 years of this decade. This scenario assumes completion of several major supply projects that are either panned, under construction, or nearing start up in most of these areas. The paper discusses the global picture, the supply situation in the Middle East, Africa, the North Sea, and South America.

  9. Retraying and revamp double big LPG fractionators's capacity

    SciTech Connect (OSTI)

    Sasson, R. , Friendswood, TX ); Pate, R. )

    1993-08-02

    Enterprise operates two LPG fractionation units at Mont Belvieu: the Seminole unit and the West Texas unit. In 1985, Nye Engineering Inc., Friendswood, Texas, designed improvements to expand the Seminole plant from 60,000 b/d of C[sub 2] + feed to 90,000 b/d. The primary modifications made to increase the West Texas plant's capacity and reduce fuel consumption were the following: retraying the deethanizer and depropanizer columns with new High Capacity Nye Trays. Lowering the pressure in the de-ethanizer and depropanizer to improve the separating efficiency of the columns. Replacing the debutanizer with a high-pressure column that rejects its condensing heat as reboil for the de-ethanizer. Adjusting the feed temperature to balance the load in the top and bottom of the depropanizer column to prevent premature flooding in one section of the tower. Installing convection heaters to recover existing stack gas heat into the process. In conjunction with the capacity expansion, there was a strong incentive to improve the fuel efficiency of the unit. The modifications are described.

  10. Investigation on effects of surface morphologies on response of LPG sensor based on nanostructured copper ferrite system

    SciTech Connect (OSTI)

    Singh, Satyendra; Yadav, B.C.; Gupta, V.D.; Dwivedi, Prabhat K.

    2012-11-15

    Graphical abstract: Figure shows the variations in resistance with time for copper ferrite system synthesized in various molar ratio. A maximum variation in resistance was observed for copper ferrite prepared in 1:1 molar ratio. Highlights: ? Evaluation of structural, optical and surface morphologies. ? Significant variation in LPG sensing properties. ? Surface modification of ferric oxide pellet by copper ferrite. ? CuFe{sub 2}O{sub 4} pellets for LPG sensing at room temperature. -- Abstract: Synthesis of a copper ferrite system (CuFe{sub 2}O{sub 4}) via chemical co-precipitation method is characterized by X-ray diffraction, surface morphology (scanning electron microscope) and optical absorption spectroscopy. These characteristics show their dependence on the relative compositions of the two subsystems. They are further confirmed by the variation in the band gap. A study of gas sensing properties shows the spinel CuFe{sub 2}O{sub 4} synthesized in 1:1 molar ratio exhibit best response to LPG adsorption/resistance measurement. Thus resistance based LPG sensor is found robust, cheap and may be applied for kitchens and industrial applications.

  11. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  12. Gas Cleaning for Remote Solid Oxide Fuel Cell (SOFC) Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    up for Fuel Cell Applications, Argonne National Lab Fuel (NG, LPG, LFG, ADG, APG, biodiesel) opportunities and impurity issues Gas Cleaning for Remote SOFC Applications Acumentrics ...

  13. Rio Grande pipeline introduces LPG to Mexico

    SciTech Connect (OSTI)

    1997-06-01

    Rio Grande Pipeline, a joint venture between Mid-America Pipeline Co., Amoco Pipeline Co. and Navajo Pipeline Co., has broken new ground in the energy industry as the first LPG pipeline to cross the US-Mexico border. Plans for the project were announced in November 1995 and first deliveries started three months ago on March 21, 1997. The 8-inch, 265-mile pipeline originates near Odessa, TX, where it receives an 85-15 propane-butane mix via a connection to Mid-America Pipeline. From Odessa, product moves west through the Texas desert and crosses the Rio Grande River about 15 miles south of El Paso near Clint, TX and extends 20 miles into Mexico. Capacity of the line is 24,000 bpd and it has been averaging about 22,000 bpd since line-fill. All in all, it sounded like a reasonably feasible, routine project. But perceptions can be deceiving, or at least misleading. In other words, the project can be summarized as follows: one river, two cultures and a world of difference. The official border crossing for pipeline construction took place on Dec. 2, 1996, with a directional drill under the Rio Grande River, but in actuality, the joint venture partners were continually bridging differences in language, laws, customs and norms with Pemex and contracted workers from Mexico.

  14. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  15. "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze)"

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Relative Standard Errors for Table 5.8;" " Unit: Percents." ,,,"Distillate" ,,,"Fuel Oil",,,"Coal" ,"Net Demand","Residual","and",,"LPG and","(excluding Coal" "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze

  16. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  17. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  18. The importance of FCC catalyst selection on LPG profitability

    SciTech Connect (OSTI)

    Keyworth, D.A.; Gilman, R.; Pearce, J.R. )

    1989-01-01

    Recently the value of LPG in chemical operations downstream of the FCC unit has increased. Such downstream operations utilize propylene not only in alkylate, but also in rapid growth petrochemical applications such as for a raw material in the manufacture of polypropylene and propylene oxide. Isobutane and the butenes (particularly butene-2 in sulfuric acid catalyzed alkylation units) are prized for alkylate feed. The profit potential and incentives to use other LPG components such as isobutene to make MTBE is now increased because of legislative actions and increased octane performance demand; and because of the greater isobutene content in the LPG from the new FCC octane catalysts. A low non-framework alumina (NFA) zeolite studied made a more olefinic LPG with higher iso-to normal C4 ratio than the other zeolites. Pilot plant data has also shown the new low NFA zeolite gave not only outstanding motor octane (MON) performance, but produced an LPG with better propylene to propane ratio, more isobutene, more n-butenes and more C4 branching than other RE promoted zeolite catalysts. Commercial results have verified the improved performance and profitability for the new low-NFA type zeolite catalysts. Three commercial examples are described.

  19. Nonresidential buildings energy consumption survey: 1979 consumption and expenditures. Part 2. Steam, fuel oil, LPG, and all fuels

    SciTech Connect (OSTI)

    Patinkin, L.

    1983-12-01

    This report presents data on square footage and on total energy consumption and expenditures for commercial buildings in the contiguous United States. Also included are detailed consumption and expenditures tables for fuel oil or kerosene, liquid petroleum gas (LPG), and purchased steam. Commercial buildings include all nonresidential buildings with the exception of those where industrial activities occupy more of the total square footage than any other type of activity. 7 figures, 23 tables.

  20. Cascaded'' pilot regulators help reduce LPG loss in hot weather

    SciTech Connect (OSTI)

    Not Available

    1994-08-08

    Fina Oil and Chemical Co. and Fisher Controls International used engineering resourcefulness to overcome heat-induced product loss from LPG storage bullets at Fina's Port Arthur, Tex., refinery. Fina had installed Fisher's Easy Joe 399A-6365, a pilot-operated, back-pressure-type regulator, on its LPG storage facility in 1991 as part of a fuel products modernization project. The regulators helped control the accumulation of noncondensible vapors, which collect in the storage bullets above the LPG. But summer heat extremes and surges in the tanks and lines made it possible for the operating pressure to increase so that the safety relief valve was activated before the pilot regulator was able to stabilize the pressure. The installation of pilot-type regulators, in cascaded, or series, formation, reduced product venting through relief valves.

  1. Low temperature type new TMCP steel plate for LPG carriers

    SciTech Connect (OSTI)

    Suzuki, Shuichi; Bessyo, Kiyoshi; Arimochi, Kazushige; Yajima, Hiroshi; Tada, Masuo; Sakai, Daisuke

    1994-12-31

    New Thermo-Mechanical Control Process (TMCP) steel plate for LPG carriers of completely liquefied type was developed with non-nickel chemistry. The new steel plate has a capability to arrest a long running brittle crack at {minus}46 C (which is the design temperature of the liquefied LPG tanks). A high heat-input one-pass welding can be applied to this steel despite its nickel-less chemistry. These capabilities were enabled by microalloying technology with low aluminum-medium nitrogen-boron, as well as by the advanced Thermo-Mechanical Control Process. This paper describes the new concept of utilizing the trace elements and the evaluation test results as the steel plate for the LPG tank and hull, especially from the standpoints of the fracture safe reliability at high heat input welding and from that of the shop workability.

  2. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were

  3. Assessment of research and development (R and D) needs in LPG safety and environmental control

    SciTech Connect (OSTI)

    DeSteese, J.G.

    1982-05-01

    The report characterizes the LPG industry covering all operations from production to end use, reviews current knowledge of LPG release phenomenology, summarizes the status of current LPG release prevention and control methodology, and identifies any remaining safety and environmental problems and recommends R and D strategies that may mitigate these problems. (ACR)

  4. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  5. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    2002-02-01

    This factsheet describes a research project whose goal is to develop the flooding predictor, an advanced process control strategy, into a universally useable tool that will maximize the separation yield of a distillation column.

  6. "Code(a)","End Use","Total","Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural Gas(d)","NGL(e)","Coke and Breeze)","Other(f)"

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Relative Standard Errors for Table 5.2;" " Unit: Percents." ,,,,,"Distillate" ,,,,,"Fuel Oil",,,"Coal" "NAICS",,,"Net","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","Total","Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural Gas(d)","NGL(e)","Coke and Breeze)&

  7. Control and extinguishment of LPG fires. Final report

    SciTech Connect (OSTI)

    Johnson, D.W.; Martinsen, W.E.; Cavin, W.D.; Chilton, P.D.; Lawson, H.P.; Welker, J.R.

    1980-08-01

    Approximately 100 fire control and fire extinguishment tests were run on free-burning liquefied petroleum gases (LPG) pool fires from 25 ft/sup 2/ to 1600 ft/sup 2/ in area. The LPG was contained in concrete pits, and the pit floors were allowed to cool before the fires were ignited so that the burning rates were not influenced by boiloff from the warm floor. High expansion foam was used for fire control. The foam was applied from fixed generators located on the upwind side of the pit. Fires were controlled after foam application of less than a minute to about 10 minutes, depending on the application rate. Fires were extinguished with dry chemical agents applied through fixed piping systems with tankside nozzles and by manual application using hoselines and portable extinguishers. Fires could readily be extinguished in times ranging from a few seconds to about half a minute, depending on the application rate, system design, and ambient conditions. Additional tests were conducted in 1-ft/sup 2/ and 5-ft/sup 2/ pits to determine the boiloff rates for LPG spilled on concrete, a sand/soil mix, and polyurethane foam substrates. Burning rates for free-burning LPG pool fires from 1 ft/sup 2/ to 1600 ft/sup 2/ in area are also reported.

  8. Design considerations for sweetening LPG`s with amines

    SciTech Connect (OSTI)

    Bullin, J.A.; Polasek, J.; Rogers, J.

    1995-11-01

    In recent years, there has been increasing interest in sweetening LPG with amines. However, limited data and design information are available in the literature. In the present paper, the design considerations and alternatives including static mixers, jet educator mixers and columns with structured packing, random packing and sieve trays are compared based on plant operating data.

  9. Expansion fractionation capacity of the LPG-ULE plant

    SciTech Connect (OSTI)

    Morin, L.M.C.

    1999-07-01

    The Western Division of PDVSA has among other facilities a NGL Fractionation Complex located onshore in Ul'e. The complex consists of three plants, the first and second older plants, LPG-1 and LPG-2, which fractionate the NGL to produce propane, a butane mix and natural gasoline. The third plant, LPG-3, fractionates the butane mix from the LPG-1 and 2 plants to produce iso and normal butane. Several optimization projects already in progress will increase the NGL production to 12,200 b/d. For this reason it was decided to conduct a study of the existing fractionation facilities and utilities systems to determine their capacities. This evaluation revealed that some of the fractionation towers would have some limitations in the processing of the expected additional production. The study recommended an option to increase the capacity of the fractionation towers by lowering their operating pressure, in order to take advantage of relative volatility increase between the key components, which allows easier separation, as well as reducing the heat duty required. The completed study also determined that this option is more economically convenient than the replacement of the existing fractionation towers.

  10. Control and extinguishment of LPG fires. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    Approximately 100 fire control and fire extinguishment tests were run on free-burning LPG pool fires from 25 ft/sup 2/ to 1600 ft/sup 2/ in area. The LPG was contained in concrete pits, and the pit floors were allowed to cool before the fires were ignited so that the burning rates were not influenced by boiloff from the warm floor. High expansion foam was used for fire control. The foam was applied from fixed generators located on the upwind side of the pit. Fires were controlled after foam application of less than a minute to about 10 minutes, depending on the application rate. Fires were extinguished with dry chemical agents applied through fixed piping systems with tankside nozzles and by manual application using hoselines and portable extinguishers. Fires could readily be extinguished in times ranging from a few seconds to about half a minute, depending on the application rate, system design, and ambient conditions. Additional tests were conducted in 1-ft/sup 2/ and 5-ft/sup 2/ pits to determine the boiloff rates for LPG spilled on concrete, a sand/soil mix, and polyurethane foam substrates. Burning rates for free-burning LPG pool fires from 1 ft/sup 2/ to 1600 ft/sup 2/ in area are also reported.

  11. Cost-effectiveness analysis of TxDOT LPG fleet conversion. Volume 1. Interim research report

    SciTech Connect (OSTI)

    Euritt, M.A.; Taylor, D.B.; Mahmassani, H.

    1992-10-01

    Increased emphasis on energy efficiency and air quality has resulted in a number of state and federal initiatives examining the use of alternative fuels for motor vehicles. Texas' program for alternate fuels includes liquefied petroleum gas (LPG). Based on an analysis of 30-year life-cycle costs, development of a propane vehicle program for the Texas Department of Transportation (TxDOT) would cost about $24.3 million (in 1991 dollars). These costs include savings from lower-priced LPG and differentials between propane and gasoline/diesel in infrastructure costs for a fueling station, vehicle costs, and operating costs. The 30-year life-cycle costs translate into an average annual vehicle cost increase of $308, or about 2.5 cents more per vehicle mile of travel. Sensitivity analyses are performed on the discount rate, price of propane, maintenance savings, vehicle utilization, diesel vehicles, extended vehicle life, original equipment manufacturer (OEM) vehicles, and operating and infrastructure costs. The best results are obtained when not converting diesel vehicles, converting only large fleets, and extending the period the vehicle is kept in service. Combining these factors yields results that are most cost-effective for TxDOT. This is volume one of two volumes.

  12. Six years' operating experience at Ardjuna field helps prove out LPG SBS system

    SciTech Connect (OSTI)

    Smulders, L.H.

    1983-02-21

    The permanent yoke mooring system and the two-product flexpipe riser of the Arjuna Sakti LPG storage barge have completely lived up to their expectations. The LPG offtake system, the terminaling function of the storage unit, has also performed extremely well. Experience gained at Ardjuna provides confidence for future openocean mooring of large methanol or LNG plants. Mooring systems of these future units will likely have a different configuration, such as the single anchor leg storage (SALS) mooring. However, the basic system components have been used, both at Ardjuna and in comparable situations elsewhere in the world. Engineers who are working on floating, large scale, gas processing plants for mooring in the open ocean could profitably join their efforts in a team comprised of process specialists, naval architects, and mooring experts. Specific areas of consideration should be: length-to-beam and lengthto-depth ratios and shape of bow. This could result in a storage/process barge design with better motion characteristics and lower mooring forces than proposed at present.

  13. Design and construction of liquefied petroleum gas installations (LPG)

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    This standard applies principally to both refrigerated and non-refrigerated installations that are larger in size than or closely associated with operating units, or both. The more complex problems presented by such installations require wider latitude for the designer than installations that are covered by the present National Fire Protection Association standards.

  14. Atomic Force Microscopy Studies of Lipophosphoglycan (LPG) Molecules in Lipid Bilayers

    SciTech Connect (OSTI)

    LAST, JULIE A.; HUBER, TINA; SASAKI, DARRYL Y.; SALVATORE, BRIAN; TURCO, SALVATORE J.

    2003-03-01

    Lipophosphoglycan (LPG) is a lypopolysaccharide found on the surface of the parasite Leishmania donovani that is thought to play an essential role in the infection of humans with leishamniasis. LPG acts as an adhesion point for the parasite to the gut of the sand fly, whose bite is responsible for transmitting the disease. In addition, LPG acts to inhibit protein kinase C (PKC) in the human macrophage, possibly by structural changes in the membrane. The Ca{sup 2+} ion is believed to play a role in the infection cycle, acting both as a crosslinker between LPG molecules and by playing a part in modulating PKC activity. To gain insight into the structure of LPG within a supported lipid membrane and into the structural changes that occur due to Ca{sup 2+} ions, we have employed the atomic force microscope (AFM). We have observed that the LPG molecules inhibit bilayer fusion, resulting in bilayer islands on the mica surface. One experiment suggests that the LPG molecules are parallel to the mica surface and that the structure of the LPG changes upon addition of Ca{sup 2+}, with an increase in the height of the LPG molecules from the bilayer surface and an almost complete coverage of LPG on the bilayer island.

  15. Distillate Fuel Oil Sales for Residential Use

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate ...

  16. Cracking in liquid petroleum gas Horton spheres

    SciTech Connect (OSTI)

    Trivedi, D.K. Gupta, S.C.

    1997-07-01

    A gas processing plant on the western coast of India produces sweet gas after processing sour natural gas. Liquid petroleum gas (LPG) is recovered from the sweet gas. The LPG, containing a H{sub 2}S concentration of 10 ppm to 20 ppm, is stored in Horton spheres, each 17 m in diameter with a capacity of {minus}27 C to 55 C. Horton spheres for containing liquid petroleum gas (LPG) were fabricated on-site using prestressed plates of high-strength carbon steel (CS) SA 537 Class-1 with post-weld heat treatment. High-residual tensile stresses and hydrogen absorption from H{sub 2}S present in LPG could be the cause of cracking at weld and heat-affected zone interfaces at high hardness locations. Recommendations are given for inspection and use of lower-strength CS and improved welding procedures.

  17. New construction era reflected in East Texas LPG pipeline

    SciTech Connect (OSTI)

    Mittler, T.J. )

    1990-04-02

    Installation of 240 miles of 6, 10, and 12-in. LPG pipelines from Mont Belvieu to Tyler, Tex., has provided greater feedstock-supply flexibility to a petrochemical plant in Longview, Tex. The project, which took place over 18 months, included tie-ins with metering at four Mont Belvieu suppliers. The new 10 and 12-in. pipelines now transport propane while the new and existing parts of a 6-in. pipeline transport propylene.

  18. Far East LPG sales will grow faster than in West

    SciTech Connect (OSTI)

    1996-12-30

    LPG sales through 2010 in regions east of the Suez Canal (East of Suez) will grow at more than twice those in regions west of the canal. East-of-Suez sales will grow at more than 4.0%/year, compared to slightly less than 2.0%/year growth in sales West of Suez. East-of-Suez sales will reach 92 million tons/year (tpy) by 2010, accounting for 39% of the worldwide total. This share was 31% in1995 and only 27% in 1990. LPG sales worldwide will reach 192 million tons in 2000 and 243 million tpy by 2010. In 1995, they were 163 million tons. These are some of the major conclusions of a recent study by Frank R. Spadine, Christine Kozar, and Rudy Clark of New York City-based consultant Poten and Partners Inc. Details of the study are in the fall report ``World Trade in LPG 1990--2010``. This paper discusses demand segments, seaborne balance, Western sources, largest trading region, North American supplies, and other supplies.

  19. Asia, North America lead way in growth of NGL, LPG trade

    SciTech Connect (OSTI)

    Otto, K.; Gist, R.; Whitley, C.; Haun, R.

    1998-01-12

    Recent analyses of world NGL trade indicate that important changes in LPG supply and demand are under way in Asia and North America. LPG markets in the 1990s reflect a rapidly shifting balance between East-of-Suez and West-of-Suez markets. This shift has increased concern about availability of future LPG supplies for Asia. The paper discusses world developments, East versus West of Suez, end uses and supplies in Asia, Canadian ethane, propane, butane, and natural gasoline, Mexican ethane, LPG, and natural gasoline, US ethane, propane, butanes, and iso-C{sub 4} and C{sub 5}.

  20. Urban leakage of liquefied petroleum gas and its impact on Mexico City air quality

    SciTech Connect (OSTI)

    Blake, D.R.; Rowland, F.S.

    1995-08-18

    Alkane hydrocarbons (propane, isobutane, and n-butane) from liquefied petroleum gas (LPG) are present in major quantities throughout Mexico City air because of leakage of the unburned gas from numerous urban sources. These hydrocarbons, together with olefinic minor LPG components, furnish substantial amounts of hydroxyl radical reactivity, a major precursor to formation of the ozone component of urban smog. The combined processes of unburned leakage and incomplete combustion of LPG play significant role in causing the excessive ozone characteristic of Mexico City. Reductions in ozone levels should be possible through changes in LPG composition and lowered rates of leakage. 23 refs., 3 tabs.

  1. Compressed natural gas and liquefied petroleum gas as alternative fuels

    SciTech Connect (OSTI)

    Moussavi, M.; Al-Turk, M. . Civil Engineering Dept.)

    1993-12-01

    The use of alternative fuels in the transportation industry has gained a strong support in recent years. In this paper an attempt was made to evaluate the use of liquefied petroleum gas (LPG) and compressed natural gas (NG) by 25 LPG-bifuel and 14 NG-bifuel vehicles that are operated by 33 transit systems throughout Nebraska. A set of performance measures such as average fuel efficiency in kilometers per liter, average fuel cost per kilometer, average oil consumption, and average operation and maintenance cost for alternatively fueled vehicles were calculated and compared with similar performance measures of gasoline powered vehicles. The results of the study showed that the average fuel efficiency of gasoline is greater than those of LPG and NG, and the average fuel costs (dollars per kilometer) for LPG and NG are smaller than those for gasoline for most of the vehicles under this study.

  2. Global gas processing will strengthen to meet expanding markets

    SciTech Connect (OSTI)

    Haun, R.R.; Otto, K.W.; Whitley, S.C.; Gist, R.L.

    1996-07-01

    The worldwide LPG industry continues to expand faster than the petroleum industry -- 4%/year for LPG vs. 2%/year for petroleum in 1995 and less than 1%/year in the early 1990s. This rapid expansion of LPG markets is occurring in virtually every region of the world, including such developing countries as China. The Far East is the focus of much of the LPG industry`s attention, but many opportunities exist in other regions such as the Indian subcontinent, Southeast Asia, and Latin America. The investment climate is improving in all phases of downstream LPG marketing, including terminaling, storage, and wholesale and retail distribution. The world LPG supply/demand balance has been relatively tight since the Gulf War and should remain so. Base demand (the portion of demand that is not highly price-sensitive) is expanding more rapidly than supplies. As a result, the proportion of total LPG supplies available for price-sensitive petrochemical feedstock markets is declining, at least in the short term. The paper discusses importers, price patterns, world LPG demand, world LPG supply, US NGL supply, US gas processing, ethane and propane supply, butane, isobutane, and natural gasoline supply, and US NGL demand.

  3. Dynamic load measurement on an LPG carrier during voyage

    SciTech Connect (OSTI)

    Kamoi, Noriyuki; Taniguchi, Tomokazu; Kiso, Takashi; Kada, Kazuo; Motoi, Tatsuya; Nakamura, Shinichi

    1994-12-31

    There are few actual ship measurement data showing the propriety of the design loads given by classification societies rules or other relevant rules. Therefore, the authors measured acceleration of ship motion and fluctuating loads on tank supports and chocks of a 75,000 m{sup 3} LPG carrier during her voyage. This paper introduces the subject ship and typical measurement results over about 1.3 years. From the analysis of these data, the authors have made clear the amount of frequency of fluctuating loads during actual navigation and ascertained the propriety of the ship`s design base.

  4. Latest techniques and equipment for the conversion of motor vehicles to LPG/petroleum use

    SciTech Connect (OSTI)

    Armstrong, R.

    1980-01-01

    Liquified petroleum gases (LPG) has been used for transportation in Europe, the United States, Japan and to a much lesser extent in Australia for many years. In most cases, the vehicles have been powered by engines designed for petrol operation and subsequently converted to use LPG. The application of LPG as an automotive fuel in different countries depends heavily on the availability of the fuel and the tax policy of the government. The demand for dual fuel equipment is increasing. Some of the problems facing Australia to convert vehicles to LPG use emphasize the institutional and hardware obstacles. Before LPG can be considered to be a safe, viable alternative fuel to petrol, improvements will have to be made in safety standards, in reduced exhaust emissions, in increased fuel efficiency, and in the involvement of car manufacturers. (SAC)

  5. New pemex agency, smog checks greet Mexican LPG vehicle users

    SciTech Connect (OSTI)

    Not Available

    1992-10-01

    This paper reports that the relaxation of prohibitions on the use of propane as a motor fuel has spurred sizeable business activity in carburetion and higher demand for LPG throughout Mexico and particularly in Mexico City. However, a number of unforeseen problems have developed that required tough, immediate solutions. After the alternative fuels project began at city hall in Mexico City, publicity spread nationwide, reportedly spurring conversion activity in many other cities. That led to additional demand for fuel of a magnitude that few people had anticipated. In order to assume control of the situation, the national oil company, Pemex, established an official LPG Motor Fuel Department on June 1. Operating in conjunction with the Ministry of Industry, the new department has been busy registering every major propane-powered fleet in the country. Most important, the rate of conversion work must now be pegged to the availability of fuel. It is believed that conversion activity has become more evenly paced since the new Pemex agency took over.over.

  6. "Characteristic(a)","Electricity","Fuel Oil","Fuel Oil(b)","Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    " Unit: Percents." " ",," "," ",," "," " "Economic",,"Residual","Distillate",,"LPG and" "Characteristic(a)","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal

  7. Vaporization, dispersion, and radiant fluxes from LPG spills. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools 25, 100, 400, and 1600 ft/sup 2/ in area. A Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes; the maximum effective flux emitted at the flame surface was about 50,000 Btu/h-ft/sup 2/. A few tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  8. American Distillation Inc | Open Energy Information

    Open Energy Info (EERE)

    Distillation Inc Jump to: navigation, search Name: American Distillation Inc. Place: Leland, North Carolina Zip: 28451 Product: Biodiesel producer in North Carolina. References:...

  9. Distributive Distillation Enabled by Microchannel Process Technology...

    Office of Scientific and Technical Information (OSTI)

    distillation for new plants. A design concept for a modular microchannel distillation unit was developed in Task 3. In Task 4, Ultrasonic Additive Machining (UAM) was evaluated...

  10. The growing world LP-gas supply

    SciTech Connect (OSTI)

    Hoare, M.C.

    1988-11-01

    The possible range of future (LPG) export availabilities is huge, but actual production levels depend on factors, many of which are beyond our direct control - world demand for crude oil and gas, developments in technology, and the price of both energy in general and LPG specifically. Although these factors limit some of the potential developments, a substantial increase in LPG supply is certain, and this is likely to depress its price relative to other products. Over the last few years, a dramatic expansion has taken place in the industry. From 1980 to 1987, non-Communist world production of LPG increased by close to 35%, to a total of 115 million tonnes. If this is set against the general energy scene, LPG represented 3.7% of crude oil production by weight in 1980, rising to 5.4% in 1987. This growth reflects rise in consciousness around the world of the value of the product. LPG is no longer regarded as a byproduct, which is flared or disposed of at low value, but increasingly as a co-product, and much of the growth in production has been due to the installation of tailored recovery systems. LPG markets historically developed around sources of supply, constrained by the costs of transportation. The major exceptions, of course, were the Middle East, the large exporter, and Japan, the large importer.

  11. Century-Midas steps slowly into the RV (recreational vehicles) LPG conversion market

    SciTech Connect (OSTI)

    Kincaid, J.

    1980-02-01

    Midas International will obtain LPG carburetion equipment from Century for installation in up to 20,000 RV. The market for gasoline-powered RV has been depressed since the surge in gasoline prices, and the installation of Century's equipment represents an attempt to attract customers by reducing RV operating costs. According to J. Kincaid (Midas Inst.), propane, besides being cheaper than gasoline, is also cheaper than diesel fuel, despite the better mileage obtained with diesel fuel, because the use of diesel fuel requires the installation of a diesel engine, which is far more expensive than installation of LPG carburetion. Although most of the LPG carburetion manufacturers, with a backlog of orders, did not evince interest in Midas' search for conversion equipment for RV, Century responded, at least partly because Midas also manufactures fleet delivery trucks, which represent a potentially much larger market for LPG conversion and use.

  12. Evaluation of aftermarket LPG conversion kits in light-duty vehicle applications. Final report

    SciTech Connect (OSTI)

    Bass, E.A.

    1993-06-01

    SwRI was contracted by NREL to evaluate three LPG conversion kits on a Chevrolet Lumina. The objective of the project was to measure the Federal Test Procedure (FTP) emissions and fuel economy of these kits, and compare their performance to gasoline-fueled operation and to each other. Varying LPG fuel blends allowed a preliminary look at the potential for fuel system disturbance. The project required kit installation and adjustment according to manufacturer`s instructions. A limited amount of trouble diagnosis was also performed on the fuel systems. A simultaneous contract from the Texas Railroad Commission, in cooperation with NREL, provided funds for additional testing with market fuels (HD5 propane and industry average gasoline) and hydrocarbon (HC) emissions speciation to determine the ozone-forming potential of LPG HC emissions. This report documents the procurement, installation, and testing of these LPG conversion kits.

  13. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee; Simmons, Wayne W.; Silva, Laura J.; Qiu, Dongming; Perry, Steven T.; Yuschak, Thomas; Hickey, Thomas P.; Arora, Ravi; Smith, Amanda; Litt, Robert Dwayne; Neagle, Paul

    2009-11-03

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  14. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  15. An analysis of weep holes as a product detection device for underground compensated LPG storage systems

    SciTech Connect (OSTI)

    Sarica, C.; Demir, H.M.; Brill, J.P.

    1996-09-01

    Weep holes have been used widely to detect the presence of Liquefied Petroleum Gases (LPG) in brine for underground compensated storage systems. When the brine level drops below the weep hole, LPG product enters the brine production system causing an increase in both tubing head pressure and flow rate. To prevent cavern overfill, a cavern shutdown is initiated upon detection of LPG in the surface brine system by pressure or flow instruments at the tubing head. In this study, we have investigated the multiphase flow characteristics of weep hole LPG detection systems to correctly estimate the operating limits. A simple and easy to use model has been developed to predict the tubing head pressure and flow rate increases. The model can be used to implement safer and more efficient operation procedures for underground compensated LPG storage systems. The model predictions for a typical field case are presented. An analysis of weep holes as product detection devices for LPG storage reservoirs has been carried out. It was found that the increases in pressure and flow rates at the tubing head change as a function of injection flow rate of the product. Therefore, a thorough consideration of cavern operating parameters is necessary to evaluate the use constant pressure and flow rate values to initiate emergency shut down of the cavern.

  16. Offshore refrigerated LPG loading/unloading terminal using a CALM buoy

    SciTech Connect (OSTI)

    Bonjour, E.L.; Simon, J.M.

    1985-03-01

    In existing Liquefied Petroleum Gases terminals, the transfer of liquefied gases to the tanker is performed via articulated loading arms or flexible hoses, working under quasistatic conditions. The tanker has to be firmly moored alongside a jetty or a process barge in a protected area (such as a harbour in most cases). This paper gives the main results of the development of an offshore refrigerated LPG (-48/sup 0/C) loading/unloading system, using a CALM buoy and LPG floating hoses working under dynamic conditions. The aim of this new concept is to replace the standard harbour structure for loading/unloading refrigerated LPG and to provide a considerable reduction in investments and a greater flexibility regarding the terminal location. The main components of that terminal have been designed so as to enable the loading of a 75 000 cubic meter LPG carrier in 15 hours. The results of static and dynamic low temperature tests on a LPG swivel joint for CALM buoy and LPG floating hoses show that such a SPM terminal is now a realistic solution.

  17. Cost-effectiveness analysis of TxDOT LPG fleet conversion. Volume 2. Interim research report

    SciTech Connect (OSTI)

    Euritt, M.A.; Taylor, D.B.; Mahmassani, H.

    1992-11-01

    Increased emphasis on energy efficiency and air quality has resulted in a number of state and federal initiatives examining the use of alternative fuels for motor vehicles. Texas' program for alternate fuels includes liquefied petroleum gas (LPG), commonly called propane. Based on an analysis of 30-year life-cycle costs, development of a propane vehicle program for the Texas Department of Transportation (TxDOT) would cost about $24.3 million (in 1991 dollars). These costs include savings from lower-priced propane and differentials between propane and gasoline/diesel in infrastructure costs, vehicle costs, and operating costs. The 30-year life-cycle costs translate into an average annual vehicle cost increase of $308, or about 2.5 cents more per vehicle mile of travel. Based on the cost-effectiveness analysis and assumptions, there are currently no TxDOT locations that can be converted to propane without additional financial outlays. This is volume two of two volumes.

  18. Fractional distillation of C/sub 2//C/sub 3/ hydrocarbons at optimum pressures

    SciTech Connect (OSTI)

    Tedder, D.W.

    1984-08-07

    A method of recovering by distillation the separate components of a hydrocarbon gas mixture comprising ethylene, ethane, propylene and propane which comprises separating the ethylene and ethane as an overhead from a propylene and propane bottom in a first distillation tower at from about 400 to about 600 psia, separating ethylene and ethane as an ethylene overhead and an ethane bottom in a second distillation tower at from about 600 to about 700 psia, and separating propylene as an overhead from a propane bottom in a third distillation tower at from about 280 to about 300 psia is disclosed.

  19. Determination of combustion products from alternative fuels - part 1. LPG and CNG combustion products

    SciTech Connect (OSTI)

    Whitney, K.A.; Bailey, B.K.

    1994-10-01

    This paper describes efforts underway to identify volatile organic exhaust species generated by a light-duty vehicle operating over the Federal Test Procedure (FTP) on CNG and LPG, and to compare them to exhaust constituents generated from the same vehicle operating on a fuel blended to meet California Phase 2 specifications. The exhaust species from this vehicle were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2, nominally, and were analyzed with and without the vehicle`s catalytic converter in place to determine the influence of the vehicle`s catalyst on species formation. Speciation data showed greater than 87 percent of all LPG and greater than 95 percent of all CNG hydrocarbon exhaust constituents to be composed of C{sub 1} to C{sub 3} compounds. In addition, toxic emissions from the combustion of CNG and LPG were as low as 10 percent of those generated by combustion of gasoline. A comparison of ozone forming potential of the three fuels was made based on the Maximum Incremental Reactivity scale used by the California Air Resources Board. Post-catalyst results from stoichiometric operation indicated that LPG and CNG produced 63 percent and 88 percent less potential ozone than reformulated gasoline, respectively. On average over all equivalence ratios, CNG and LPG exhaust constituents were approximately 65 percent less reactive than those from reformulated gasoline. 4 refs., 3 figs., 14 tabs.

  20. Adjusted Distillate Fuel Oil Sales for Residential Use

    Gasoline and Diesel Fuel Update (EIA)

    End Use Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate ...

  1. Corrosion inhibition for distillation apparatus

    DOE Patents [OSTI]

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.; Schweighardt, Frank K.

    1985-01-01

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  2. Omniphobic Membrane for Robust Membrane Distillation

    SciTech Connect (OSTI)

    Lin, SH; Nejati, S; Boo, C; Hu, YX; Osuji, CO; Ehmelech, M

    2014-11-01

    In this work, we fabricate an omniphobic microporous membrane for membrane distillation (MD) by modifying a hydrophilic glass fiber membrane with silica nanoparticles followed by surface fluorination and polymer coating. The modified glass fiber membrane exhibits an anti-wetting property not only against water but also against low surface tension organic solvents that easily wet a hydrophobic polytetrafluoroethylene (PTFE) membrane that is commonly used in MD applications. By comparing the performance of the PTFE and omniphobic membranes in direct contact MD experiments in the presence of a surfactant (sodium dodecyl sulfate, SDS), we show that SDS wets the hydrophobic PTFE membrane but not the omniphobic membrane. Our results suggest that omniphobic membranes are critical for MD applications with feed waters containing surface active species, such as oil and gas produced water, to prevent membrane pore wetting.

  3. ITP Chemicals: Hybrid Separations/Distillation Technology. Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Chemicals: Hybrid SeparationsDistillation Technology. Research ...

  4. ITP Chemicals: Hybripd Separations/Distillation Technology. Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybripd SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Chemicals: Hybripd SeparationsDistillation Technology. Research ...

  5. Conception and construction of an LPG tank using a composite membrane technology

    SciTech Connect (OSTI)

    Fuvel, P.; Claude, J.

    1985-03-01

    TECHNIGAZ and TOTAL C.F.P. have developed a new LPG storage technology derived from the membrane concept used for LNG storage and transportation. This technology called GMS uses a composite membrane as primary barrier. A 2 000 m/sup 3/ storage pilot unit, based on that concept, is under construction in TOTAL's refinery at DUNKIRK (France) since September 1983.

  6. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  7. Oil, gas tanker industry responding to demand, contract changes

    SciTech Connect (OSTI)

    True, W.R.

    1998-03-02

    Steady if slower growth in demand for crude oil and natural gas, low levels of scrapping, and a moderate newbuilding pace bode well for the world`s petroleum and natural-gas shipping industries. At year-end 1997, several studies of worldwide demand patterns and shipping fleets expressed short and medium-term optimism for seaborne oil and gas trade and fleet growth. The paper discusses steady demand and shifting patterns, the aging fleet, the slowing products traffic, the world`s fleet, gas carriers, LPG demand, and LPG vessels.

  8. Enthusiam greets establishment of vigorous LPG clean fuels coalition

    SciTech Connect (OSTI)

    Not Available

    1990-07-01

    In a concerted effort to promote the fair consideration of LP-gas as an alternative fuel nationwide, a number of prominent corporations and individuals have established a new group called the LP-Gas Clean Fuels Coalition (Irvine, Calif.). This paper discusses how the coalition will spearhead the industry's efforts to encourage favorable clean-air legislation and regulations through the gathering and dissemination of accurate information from all industry sources. Coalition members believe that LP-gas is not being equitably considered in the current Congressional push to legislate clean alternative fuels.

  9. LPG buses in southern California leave the competition at the curb

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    This paper reports that after the first year of a landmark experiment in which LPG has been competing against methanol and CNG in city buses, propane appears to be pulling out in front of the pack. According to Efren Medellin, superintendent of vehicle maintenance at the Orange County Transit Authority, two LPG buses had registered a total of 31,000 moles with relatively little, if any, downtime. The two methanol buses had run a total of 30,000 miles while the two CNG buses had traveled only 5000 miles. Furthermore the methanol and CNG buses have had their share of downtime for new parts and other problems. The propane-powered buses appear to be running consistently well without mechanical difficulties. The only problem that occurred was occasional backfiring. As a result, the electronic controls were replaced and no subsequent complaints were heard.

  10. The Influence of Molecular Structure of Distillate Fuels on HFRR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity The Influence of Molecular Structure of Distillate Fuels on HFRR Lubricity Presentation given at 2007 ...

  11. New Design Methods and Algorithms for Multi-component Distillation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf (517.32 KB) ...

  12. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  13. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  14. X-ray photoelectron spectroscopy studies on Pd doped SnO{sub 2} liquid petroleum gas sensor

    SciTech Connect (OSTI)

    Phani, A.R.

    1997-10-01

    The present investigation deals with the electrical response of palladium doped tin oxide, as a means of improving the selectivity for liquid petroleum gas (LPG) in the presence of CO, CH{sub 4}. The sensor element with the composition of Pd(1.5 wt{percent}) in the base material SnO{sub 2} sintered at 800{degree}C, has shown a high sensitivity towards LPG with a negligible cross interference of CO and CH{sub 4} at an operating temperature of 350{degree}C. This greatly suggests the possibility of utilizing the sensor for the detection of LPG. X-ray photoelectron spectroscopy studies have been carried out to determine the possible chemical species involved in the gas-solid interaction and the enhancing mechanism of the Pd doped SnO{sub 2} sensor element, towards LPG sensitivity. {copyright} {ital 1997 American Institute of Physics.}

  15. Distillation: Still towering over other options

    SciTech Connect (OSTI)

    Kunesh, J.G.; Kister, H.Z.; Lockett, M.J.; Fair, J.R.

    1995-10-01

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  16. Simultaneous boiling and spreading of liquefied petroleum gas on water. Final report, December 12, 1978-March 31, 1981

    SciTech Connect (OSTI)

    Chang, H.R.; Reid, R.C.

    1981-04-01

    An experimental and theoretical investigation was carried out to study the boiling and spreading of liquid nitrogen, liquid methane and liquefied petroleum gas (LPG) on water in a one-dimensional configuration. Primary emphasis was placed on the LPG studies. Experimental work involved the design and construction of a spill/spread/boil apparatus which permitted the measurement of spreading and local boil-off rates. With the equations of continuity and momentum transfer, a mathematical model was developed to describe the boiling-spreading phenomena of cryogens spilled on water. The model accounted for a decrease in the density of the cryogenic liquid due to bubble formation. The boiling and spreading rates of LPG were found to be the same as those of pure propane. An LPG spill was characterized by the very rapid and violent boiling initially and highly irregular ice formation on the water surface. The measured local boil-off rates of LPG agreed reasonably well with theoretical predictions from a moving boundary heat transfer model. The spreading velocity of an LPG spill was found to be constant and determined by the size of the distributor opening. The maximum spreading distance was found to be unaffected by the spilling rate. These observations can be explained by assuming that the ice formation on the water surface controls the spreading of LPG spills. While the mathematical model did not predict the spreading front adequately, it predicted the maximum spreading distance reasonably well.

  17. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L.; Sagues, Alberto A.; Davis, Burtron H.

    1985-01-01

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  18. Safety issues relating to the liquefied petroleum gas, compressed natural gas and liquefied natural gas

    SciTech Connect (OSTI)

    Petru, T.D.

    1995-12-31

    The Railroad Commission of Texas, LP-Gas Division, is statutorily responsible for the safety aspects of liquefied petroleum gas (LPG) most commonly known as LP-gas or propane, compressed natural gas (CNG) and liquefied natural gas (LNG). This presentation will address the safety issues relating to their use as alternative fuels. The paper discusses the safety of pressure vessels used for storage of the fuels at refueling facilities and the containers mounted in vehicles. Other topics include the lack of odorants in LNG, the use of protective clothing when handling cryogenic fluids, and where to obtain a copy of the safety regulations for handling these three fuels.

  19. LPG--a direct source of C/sub 3/-C/sub 4/ olefins

    SciTech Connect (OSTI)

    Pujado, P.R.; Berg, R.C.; Vora, B.V.

    1983-03-28

    This article describes the selective production of olefins by the catalytic dehydrogenation of the corresponding paraffins by means of UOP's Oleflex process. In this process, propylene can be obtained at about 85 mol % selectivity by the catalytic dehydrogenation of propane. Isobutylene can be obtained at selectivities in excess of 90 mol % from isobutane, and n-butenes (1-butene plus 2-butene) at about 80 mol % from n-butane. The availability of this technology, coupled with an abundant supply of LPG (C/sub 3/ and C/sub 4/ paraffins), opens new avenues for the selective production of propylene and butylenes.

  20. Determination of combustion products from alternative fuels. Part I. LPG and CNG combustion products

    SciTech Connect (OSTI)

    Whitney, K.A.; Bailey, B.K.

    1994-10-01

    This paper describes efforts underway to identify volatile organic exhaust species generated by a light-duty vehicle operating over the Federal Test Procedure (FTP) on CNG and LPG, and to compare them to exhaust constituents generated from the same vehicle operating on a fuel blended to meet California Phase 2 specifications. The exhaust species from this vehicle were identified and quantified for fuel/air equivalence ratios of 0.8, 1.0, and 1.2 nominally, and were analyzed with and without the vehicle`s catalytic converter in place to determine the influence of the vehicle`s catalyst on species formation. 4 refs., 3 figs., 14 tabs.

  1. Energy-Related Carbon Dioxide Emissions at the State Level, 2000-2013

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Appendix A. Comparison of fuel detail for the State Energy Data System and the annual series appearing in the Monthly Energy Review data system Energy Source State Energy Data System Monthly Energy Review Consumption Sector Category Fuel Detail Fuel Detail Residential Coal Coal Coal Residential Natural Gas Natural Gas Natural Gas Residential Petroleum Distillate Fuel Distillate Fuel Residential Petroleum Kerosene Kerosene Residential Petroleum LPG LPG Commercial Coal Coal Coal Commercial

  2. Energy-Sipping House Receives Technology Award

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Appendix A. Comparison of fuel detail for the State Energy Data System and the annual series appearing in the Monthly Energy Review data system Energy Source State Energy Data System Monthly Energy Review Consumption Sector Category Fuel Detail Fuel Detail Residential Coal Coal Coal Residential Natural Gas Natural Gas Natural Gas Residential Petroleum Distillate Fuel Distillate Fuel Residential Petroleum Kerosene Kerosene Residential Petroleum LPG LPG Commercial Coal Coal Coal Commercial

  3. Environment - U.S. Energy Information Administration (EIA) - U.S. Energy

    Gasoline and Diesel Fuel Update (EIA)

    3 Appendix A. Comparison of fuel detail for the State Energy Data System and the annual series appearing in the Monthly Energy Review data system Energy Source State Energy Data System Monthly Energy Review Consumption Sector Category Fuel Detail Fuel Detail Residential Coal Coal Coal Residential Natural Gas Natural Gas Natural Gas Residential Petroleum Distillate Fuel Distillate Fuel Residential Petroleum Kerosene Kerosene Residential Petroleum LPG LPG Commercial Coal Coal Coal Commercial

  4. Planning and care mark repair of 14-year old leak in Kuwait Oil Co. LPG tank 95

    SciTech Connect (OSTI)

    Shtayieh, S.

    1983-01-10

    This paper points out that the leak, which had been present for such a long time, completely saturated the perlite insulation with hydrocarbons, thus rendering the entire operation of inspection, repair, and maintenance of the inner tank a hazardous operation. It emphasizes the safety aspects, which were complicated by the saturated perlite as well as by the fact that the tank is situated in the middle of the LPG storage area with LPG tanks on either side. Tank design, making preparations, inspection, and repair are discussed. The fact that the leaking flanges were originally installed damaged, indicated the future need of tighter company quality control of all contractors work.

  5. ,"for Electricity(a)","Fuel Oil","Diesel Fuel(b)","(billion"...

    U.S. Energy Information Administration (EIA) Indexed Site

    Unit: Percents." ,,,"Distillate",,,"Coal" ,,,"Fuel Oil",,,"(excluding Coal" ,"Net Demand","Residual","and","Natural Gas(c)","LPG and","Coke and Breeze)" ,"for Electricity(a)","Fuel ...

  6. Oxidation catalyst systems for emission control of LPG-powered forklift trucks

    SciTech Connect (OSTI)

    Majewski, W.A.; Martin, E.P.; Pietrasz, E.

    1994-10-01

    An oxidation catalyst was installed on an industrial LPG-powered forklift truck. For high conversion efficiency in an oxidation system on a rich burning engine a secondary air supply to the catalyst is necessary. Two simple and cost-effective ways of secondary air supply were tested: an air valve and a venturi type injector. The amount of secondary air supplied by both devices was measured under a variety of conditions - different engine speed, load and exhaust system pressure. Carbon monoxide emissions and the catalyst performance were measured and evaluated in terms of the secondary air flow. Advantages and drawbacks of the air valve and venturi injector systems are discussed and compared. 1 refs., 11 figs., 3 tabs.

  7. Vaporization, dispersion, and radiant fluxes from LPG spills. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1982-05-01

    Both burning and non-burning spills of LPG (primarily propane) were studied. Vaporization rates for propane spills on soil, concrete, insulating concrete, asphalt, sod, wood, and polymer foams were measured. Thermal conductivity, heat transfer coefficients, and steady state vaporization rates were determined. Vapor concentrations were measured downwind of open propane pools and a Gaussian dispersion model modified for area sources provided a good correlation of measured concentrations. Emitted and incident radiant fluxes from propane fires were measured. Simplified flame radiation models were adequate for predicting radiant fluxes. Tests in which propane was sprayed into the air showed that at moderately high spray rates all the propane flashed to vapor or atomized; no liquid collected on the ground.

  8. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  9. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M.

    1984-01-01

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  10. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M.

    1985-01-01

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  11. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  12. Catalytic hydroprocessing of petroleum and distillates

    SciTech Connect (OSTI)

    Oballa, M.C.; Shih, S.S.

    1994-12-31

    There is a strong push for the processing of heavy oils, bitumen and/or residue, which carries with it some problems. These are connected with obtaining state-of-the-art technologies at reasonable capital and operating costs to the refiner. Then there are problems associated with choosing the best catalyst--one specially designed to lower considerably the high content of heteroatoms (S, N, O) and metals (V, Ni, Fe). To address the above considerations, engineers and scientists working in the processing of petroleum and distillates from different parts of the world presented papers covering different facets of residue upgrading and distillate hydrotreating. This book is a compilation of most of the papers presented in the five sessions of the symposium. The editors have broadly classified the papers in terms of content into the following four categories: catalyst deactivation; upgrading of heavy oils and residue; hydrotreating of distillates; and general papers. All papers have been processed separately for inclusion on the data base.

  13. PV based systems, with wind, diesel or LPG genset backup, supplying small TV rebroadcast stations in Portugal

    SciTech Connect (OSTI)

    Ramos, H.F.

    1994-12-31

    This paper describes the implementation of a program intended to introduce PV based hybrid power systems to supply electrical power to small size TV rebroadcast stations in Portugal. Reliability is a major concern to this type of application, as well as economical and social constraints, so wind or diesel/LPG genset backup are used. This paper includes a description of the systems behavior, comparison among these topologies and economical viability data from a users viewpoint.

  14. New Design Methods and Algorithms for Multi-component Distillation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processes | Department of Energy Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf (517.32 KB) More Documents & Publications Development of Method and Algorithms To Identify Easily Implementable Energy-Efficient Low-Cost Multicomponent Distillation Column Trains With Large Energy Savings For Wide Number of Separations CX-100137 Categorical Exclusion Determination ITP

  15. Urban leakage of liquefied petroleum gas and its potential impact of Mexico City air quality

    SciTech Connect (OSTI)

    Blake, D.R.; Rowland, F.S.

    1995-12-01

    Seventy eight whole air samples were collected at various park locations throughout Mexico City and later assayed for methane, carbon monoxide, 20 halocarbons and 40 C{sub 2}-C{sub 10} hydrocarbons. Propane had the highest median mixing ratio value of all assayed non-methane hydrocarbon compounds (NMHCs) with a concentration as high as 0.1 ppmv. The concentration of n-butane, i-butane, n-pentane and i-pentane were all notably elevated as well. The only significant identified source of propane in Mexico City is liquefied petroleum gas (LPG), which also has a strong component of C{sub 4} and C{sub 5} alkanes. All of these alkanes were present at concentrations well above those observed in other cities where LPG is not the main domestic fuel. Data strongly suggest that as much as 50% of total Mexico City NMHCs is a result of losses associated with the transfer, storage and delivery of LPG. Additionally, using median concentrations and laboratory determined hydroxyl reaction rate constants, LPG emissions account for about 20% of initial reactivities. This suggests that LPG losses may significantly impact photochemical oxidant levels in Mexico City.

  16. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  17. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    U.S. Energy Information Administration (EIA) Indexed Site

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  18. Increasing Distillate Production at U.S. Refineries

    Reports and Publications (EIA)

    2010-01-01

    Paper explores the potential for U.S. refiners to create more distillate and less gasoline without major additional investments beyond those already planned.

  19. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  20. Development of natural gas vehicles in China

    SciTech Connect (OSTI)

    Zongmin, Cheng

    1996-12-31

    Past decade and current status of development of natural gas vehicles (NGVs) in China is described. By the end of 1995, 35 CNG refueling stations and 9 LPG refueling stations had been constructed in 12 regions, and 33,100 vehicles had been converted to run on CNG or LPG. China`s automobile industry, a mainstay of the national economy, is slated for accelerated development over next few years. NGVs will help to solve the problems of environment protection, GHGs mitigation, and shortage of oil supply. The Chinese government has started to promote the development of NGVs. Projects, investment demand, GHG mitigation potential, and development barriers are discussed. China needs to import advanced foreign technologies of CNGs. China`s companies expect to cooperate with foreign partners for import of CNG vehicle refueling compressors, conversions, and light cylinders, etc.

  1. Distillate Fuel Oil Assessment for Winter 1996-1997

    Reports and Publications (EIA)

    1997-01-01

    This article describes findings of an analysis of the current low level of distillate stocks which are available to help meet the demand for heating fuel this winter, and presents a summary of the Energy Information Administration's distillate fuel oil outlook for the current heating season under two weather scenarios.

  2. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael; Papadopoulos, Christos G.; Logsdon, Jeffrey S.; Eng, Wayne W. Y.; Lee, Guang-Chung; Sinclair, Ian

    2007-12-25

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  3. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali; Orler, Bruce; Tornga, Stephanie; Welch, Cindy

    2011-01-26

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study

  4. Integrated hydroprocessing scheme for production of premium quality distillates and lubricants

    SciTech Connect (OSTI)

    Chen, N.Y.; LaPierre, R.B.; Partridge, R.D.; Wong, S.S.

    1989-07-25

    This patent describes a method of upgrading a gas oil hydrocarbon feedstock into a naphtha product and a distillate product having a boiling range above that of the naptha product and below that of the gas oil and also having content of iso-paraffins. The method comprises hydrocracking the gas oil feedstock over a large pore size, aromatic selective hydrocracking catalyst having acidic functionality and hydrogenation-deydrogenation functionality, at a hydrogen pressure up to about 10,000 kPa and at a conversion below 50 percent to 650{sup 0}F.-products, to effects a removal of aromatic components by hydrocracking and to form the naptha product and a product boiling above the naptha product which is enriched in paraffinic components; separating the naptha product from the product enriched in paraffinic components; and hydroprocessing the product enriched in paraffinic components over a hydroprocessing catalyst comprising zeolite beta as an acidic component and a hydrogenation-dehydrogenation component, to produce a distillate boiling range product having an enhanced content of isoparaffinic components.

  5. ,"New Mexico Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumers (Thousand Gallons)","New Mexico Total Distillate SalesDeliveries to Military Consumers (Thousand Gallons)","New Mexico No 2 Diesel SalesDeliveries to Off-Highway ...

  6. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  7. A Method to Distill Hydrogen Isotopes from Lithium | Princeton...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Distill Hydrogen Isotopes from Lithium This white paper outlines a method for the removal of tritium and deuterium from liquid lithium. The method is based on rapid or flash ...

  8. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  9. Correlations estimate volume distilled using gravity, boiling point

    SciTech Connect (OSTI)

    Moreno, A.; Consuelo Perez de Alba, M. del; Manriquez, L.; Guardia Mendoz, P. de la

    1995-10-23

    Mathematical nd graphic correlations have been developed for estimating cumulative volume distilled as a function of crude API gravity and true boiling point (TBP). The correlations can be used for crudes with gravities of 21--34{degree} API and boiling points of 150--540 C. In distillation predictions for several mexican and Iraqi crude oils, the correlations have exhibited accuracy comparable to that of laboratory measurements. The paper discusses the need for such a correlation and the testing of the correlation.

  10. ITP Chemicals: Hybrid Separations/Distillation Technology. Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Opportunities for Energy and Emissions Reduction | Department of Energy Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Chemicals: Hybrid Separations/Distillation Technology. Research Opportunities for Energy and Emissions Reduction hybrid_separation.pdf (315.31 KB) More Documents & Publications Review of Historical Membrane Workshop Results Membrane Technology Workshop Summary Report, November 2012 Membrane Technology W

  11. Zn-doped and undoped SnO{sub 2} nanoparticles: A comparative structural, optical and LPG sensing properties study

    SciTech Connect (OSTI)

    Mishra, R.K.; Sahay, P.P.

    2012-12-15

    Graphical abstract: The X-ray diffraction (XRD) analyses confirm that all the materials prepared are polycrystalline SnO{sub 2} possessing tetragonal rutile structure. On Zn-doping, the crystallite size has been found to decrease from 25 nm (undoped sample) to 13 nm (1 at% Zn-doped sample). Display Omitted Highlights: ? Zn-doped SnO{sub 2} nanoparticles show smaller crystallite size (11–17 nm). ? Optical band gap in SnO{sub 2} nanoparticles increases on Zn-doping. ? 2 at% Zn-doped sample show minimum room temperature resistivity. ? LPG response of the Zn-doped SnO{sub 2} nanoparticles increases considerably. ? 1 at% Zn-doped sample shows maximum response (87%) at 300 °C to 1 vol% concentration. -- Abstract: SnO{sub 2} nanoparticles were prepared by the co-precipitation method with SnCl{sub 4}·5H{sub 2}O as the starting material and Zn(CH{sub 3}COO){sub 2}·2H{sub 2}O as the source of dopant. All the materials prepared have been found to be polycrystalline SnO{sub 2} possessing tetragonal rutile structure with crystallite sizes in the range 11–25 nm. Optical analyses reveal that for the SnO{sub 2} nanoparticles, both undoped and Zn-doped, direct transition occurs with the bandgap energies in the range 3.05–3.41 eV. Variation in the room temperature resistivity of the SnO{sub 2} nanoparticles as a function of dopant concentration has been explained on the basis of two competitive processes: (i) replacement of Sn{sup 4+} ion by an added Zn{sup 2+} ion, and (ii) ionic compensation of Zn{sup 2+} by the formation of oxygen vacancies. Among all the samples examined for LPG sensing, the 1 at% Zn-doped sample exhibits fast and maximum response (?87%) at 300 °C for 1 vol% concentration of LPG in air.

  12. Distillate Fuel Oil Days of Supply

    Gasoline and Diesel Fuel Update (EIA)

    Changes to proved reserves of U.S. natural gas by source, 2013-14 trillion cubic feet Year-end 2013 2014 Year-end 2014 proved 2014 revisions and 2014 proved Source of natural gas reserves Discoveries other changes production reserves Coalbed methane 12.4 0.4 4.3 -1.4 15.7 Shale 159.1 37.8 16.2 -13.4 199.7 Other U.S. natural gas Lower 48 onshore 166.0 11.4 -8.4 -11.7 157.2 Lower 48 offshore 9.1 0.8 0.8 -1.3 9.4 Alaska 7.4 0.1 -0.4 -0.3 6.8 U.S. TOTAL 354.0 50.5 12.4 -28.1 388.8 Note: Lower 48

  13. FRACTIONAL DISTILLATION SEPARATION OF PLUTONIUM VALUES FROM LIGHT ELEMENT VALUES

    DOE Patents [OSTI]

    Cunningham, B.B.

    1957-12-17

    A process is described for removing light element impurities from plutonium. It has been found that plutonium contaminated with impurities may be purified by converting the plutonium to a halide and purifying the halide by a fractional distillation whereby impurities may be distilled from the plutonium halide. A particularly effective method includes the step of forming a lower halide such as the trior tetrahalide and distilling the halide under conditions such that no decomposition of the halide occurs. Molecular distillation methods are particularly suitable for this process. The apparatus may comprise an evaporation plate with means for heating it and a condenser surface with means for cooling it. The condenser surface is placed at a distance from the evaporating surface less than the mean free path of molecular travel of the material being distilled at the pressure and temperature used. The entire evaporating system is evacuated until the pressure is about 10/sup -4/ millimeters of mercury. A high temperuture method is presented for sealing porous materials such as carbon or graphite that may be used as a support or a moderator in a nuclear reactor. The carbon body is subjected to two surface heats simultaneously in an inert atmosphere; the surface to be sealed is heated to 1500 degrees centigrade; and another surface is heated to 300 degrees centigrade, whereupon the carbon vaporizes and flows to the cooler surface where it is deposited to seal that surface. This method may be used to seal a nuclear fuel in the carbon structure.

  14. LPG marketers thank the rain gods for hefty crop-drying market in '89

    SciTech Connect (OSTI)

    Not Available

    1990-04-01

    One of the pleasant bits of news that sprouted in many places across the country last fall concerned the increased LP-gas gallonage for crop drying. It is difficult to predict the farmers or dryers' consumption of propane in any given season. The demand for this fuel in drying operations is determined almost entirely by weather conditions, and since climate remains a perennial question mark, no one knows until the season is well under way how much moisture content the plants will exhibit. In another area, predictions can be complicated by the variations of individual farm practices as well as the evolving technology of drying equipment, including burners. This article, reports on the crop drying market as seen by various LP-gas dealers and others outside the industry.

  15. ,"No. 2 Distillate Sales to End Users Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Refiners (Thousand Gallons per Day)","New Mexico No 2 Distillate Retail Sales by Refiners ...57.7,6018.7,64.6,101.5,691.5,1553.8,1576.9,2030.5,4320.3,1350.4,683.2,792.4,316.4,804.3,37...

  16. Conceptual design and optimization for JET water detritiation system cryo-distillation facility

    SciTech Connect (OSTI)

    Lefebvre, X.; Hollingsworth, A.; Parracho, A.; Dalgliesh, P.; Butler, B.; Smith, R.

    2015-03-15

    The aim of the Exhaust Detritiation System (EDS) of the JET Active Gas Handling System (AGHS) is to convert all Q-based species (Q{sub 2}, Q-hydrocarbons) into Q{sub 2}O (Q being indifferently H, D or T) which is then trapped on molecular sieve beds (MSB). Regenerating the saturated MSBs leads to the production of tritiated water which is stored in Briggs drums. An alternative disposal solution to offsite shipping, is to process the tritiated water onsite via the implementation of a Water Detritiation System (WDS) based, in part, on the combination of an electrolyser and a cryo-distillation (CD) facility. The CD system will separate a Q{sub 2} mixture into a de-tritiated hydrogen stream for safe release and a tritiated stream for further processing on existing AGHS subsystems. A sensitivity study of the Souers' model using the simulation program ProSimPlus (edited by ProSim S.A.) has then been undertaken in order to perform an optimised dimensioning of the cryo-distillation system in terms of available cooling technologies, cost of investment, cost of operations, process performance and safety. (authors)

  17. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  18. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    U.S. Energy Information Administration (EIA) Indexed Site

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  19. New Design Methods and Algorithms for Multi-component Distillation Processes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Methods and Algorithms for Multi-component Distillation Processes Improved Energy Efficiency through the Determination of Optimal Distillation Configuration The ability to apply low-energy distillation confgurations can allow chemical manufacturers to reduce energy consumption of both existing and grassroots plants. However, the determina- tion of an appropriate confguration is limited by an incomplete knowledge of the 'search space' for a proper distillation network. Currently, no

  20. Medium-speed diesel propulsion plant for new shallow-draft LPG tankers

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    Propulsion equipment from engine builder Krupp MaK and power transmission specialist Lohmann Stolterfoht has been specified for a series of liquefied petroleum gas tankers being built for various customers by Pattje Shipyards, of Waterhuizen, Holland. Pattje reports that the tankers are built using an innovative system of modular construction that has led to the very short building time of only nine months per ship. The tankers have a capacity of 4200 m[sup 3] of gas and a draft of only 5.2 m when fully loaded, to enable the use of shallow water ports. Further particulars of the vessels include an overall length of 100 m, beam dimension of 15.9 m and maximum speed of 14 knots. The tankers' propulsion system is based on a single, in-line, nine-cylinder type 9M453C medium-speed diesel from the [open quotes]C[close quotes] engine series of Krupp MaK, Kiel, Germany. The 33.8 L/cyl engine (bore 320 x stroke 420 mm) develops 3000 kW at 600 r/min. 2 figs.

  1. Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures

    SciTech Connect (OSTI)

    Waghmare, Shivaji D.; Jadhav, Vijaykumar V.; Gore, Shaym K.; Yoon, Seog-Joon; Ambade, Swapnil B.; Lokhande, B.J.; Mane, Rajaram S.; Han, Sung-Hwan

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? Micro (cubes) structure embedded in nano (plates) of bismuth ferrite was prepared by a chemical method. ? These structures were characterized by XRD and SEM. ? LPG, CO{sub 2} and NH{sub 4} gases were exposed. ? Properties related to gas sensors were measured and reported. -- Abstract: Mixed micro (cubes) and nano (plates) structures of bismuth ferrite (BFO) have been synthesized by a simple and cost-effective wet-chemical method. Structural, morphological and phase confirmation characteristics are measured using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis techniques. The digital FE-SEM photo-images of BFO sample confirmed an incubation of discrete micro-cubes into thin and regularly placed large number of nano-plates. The bismuth ferrite, with mixed structures, films show considerable performance when used in liquefied petroleum (LPG), carbon dioxide (CO{sub 2}) and ammonium (NH{sub 3}) gas sensors application. Different chemical entities in LPG have made it more efficient with higher sensitivity, recovery and response times compared to CO{sub 2} and NH{sub 3} gases. Furthermore, effect of palladium surface treatment on the gas sensitivity and the charge transfer resistances of BFO mixed structures is investigated and reported.

  2. The best news for LPG in Denmark is diesel conversion breakthrough

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    Throughout Scandanavia, taxes seem to drive the marketplace. Governments do not want to encourage consumption of alcoholic beverages, so they tax them heavily, thereby actually discouraging their use. Using the same means, they dictate the fate of the various fuels. Taxes have depressed propane's use to a large extent; today it is priced at three times natural gas, with the result that it accounts for only 0.5%-0.7% of total energy consumption. But, this paper reports on a potential new star that has appeared on the horizon, as participants in the People-to-People sojourn to Scandanavia last August learned. It's a program of converting diesel buses to propane, and officials of the company that is marketing it, Skibby Motor A/S, are so confident of its success that they have already begun a campaign of introducing it to the U.S.

  3. "Characteristic(a)","Total","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal","Breeze","Other(e)"

    U.S. Energy Information Administration (EIA) Indexed Site

    2.3 Relative Standard Errors for Table 2.3;" " Unit: Percents." " "," "," "," "," "," "," "," "," " " "," "," "," ",," "," ",," " "Economic",,"Residual","Distillate",,"LPG and",,"Coke and"," " "Characteristic(a)","Total","Fuel

  4. "Code(a)","End Use","Electricity(b)","Fuel Oil","Diesel Fuel(c)"," Gas(d)","NGL(e)","Coke and Breeze)"

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Relative Standard Errors for Table 5.3;" " Unit: Percents." " "," " " "," ",," ","Distillate"," "," " " "," ","Net Demand",,"Fuel Oil",,,"Coal" "NAICS"," ","for ","Residual","and","Natural","LPG and","(excluding Coal" "Code(a)","End

  5. Integrated process of distillation with side reactors for synthesis of organic acid esters

    DOE Patents [OSTI]

    Panchal, Chandrakant B; Prindle, John C; Kolah, Aspri; Miller, Dennis J; Lira, Carl T

    2015-11-04

    An integrated process and system for synthesis of organic-acid esters is provided. The method of synthesizing combines reaction and distillation where an organic acid and alcohol composition are passed through a distillation chamber having a plurality of zones. Side reactors are used for drawing off portions of the composition and then recycling them to the distillation column for further purification. Water is removed from a pre-reactor prior to insertion into the distillation column. An integrated heat integration system is contained within the distillation column for further purification and optimizing efficiency in the obtaining of the final product.

  6. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential

  7. Landi-Hartog U. S. A. adjusts to the U. S. market. [Marketing of LPG carburetor systems for using propane as an automotive fuel

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    Landi-Hartog U.S.A. has adjusted to the U.S. market in providing LPG carburetor systems for passenger cars. Landi-Hartog (LH) had to completely redesign the components on the system to be compatible with U.S. 300-525 cu in. engines. The company has California Air Resources Board approval for 300 cu in. engines and above in dual-fuel service. However, the U.S. market will remain severely restricted unless basic distribution (and the political) changes are made. The U.S. is st

  8. Electrical and gas sensing properties of self-aligned copper-doped zinc oxide nanoparticles

    SciTech Connect (OSTI)

    Sonawane, Yogesh S.; Kanade, K.G.; Kale, B.B. Aiyer, R.C.

    2008-10-02

    Electrical and gas sensing properties of nanocrystalline ZnO:Cu, having Cu X wt% (X = 0.0, 0.5, 1.0, and 1.5) in ZnO, in the form of pellet were investigated. Copper chloride and zinc acetate were used as precursors along with oxalic acid as a precipitating reagent in methanol. Material characterization was done by X-ray diffraction (XRD), scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM) and inductive coupled plasma with optical emission spectrometry (ICP-OES). FE-SEM showed the self-aligned Cu-doped ZnO nano-clusters with particles in the range of 40-45 nm. The doping of 0.5% of copper changes the electrical conductivity by an order of magnitude whereas the temperature coefficient of resistance (TCR) reduces with increase in copper wt% in ZnO. The material has shown an excellent sensitivity for the H{sub 2}, LPG and CO gases with limited temperature selectivity through the optimized operating temperature of 130, 190 and 220 deg. C for H{sub 2}, LPG and CO gases, respectively at 625 ppm gas concentration. The %SF was observed to be 1460 for H{sub 2} at 1% Cu doping whereas the 0.5% Cu doping offered %SF of 950 and 520 for CO and LPG, respectively. The response and recovery time was found to be 6 to 8 s and 16 s, respectively.

  9. "Characteristic(a)","Total","Electricity(b)","Fuel Oil","Fuel Oil(c)","Natural Gas(d)","NGL(e)","Coal","Breeze","Other(f)"

    U.S. Energy Information Administration (EIA) Indexed Site

    3.3 Relative Standard Errors for Table 3.3;" " Unit: Percents." " "," "," "," "," "," "," "," "," "," " " "," ",," "," ",," "," ",," " "Economic",,"Net","Residual","Distillate",,"LPG and",,"Coke and"," "

  10. "Characteristic(a)","Total(b)","Electricity(c)","Fuel Oil","Fuel Oil(d)","Natural Gas(e)","NGL(f)","Coal","Breeze","Other(g)","Produced Onsite(h)"

    U.S. Energy Information Administration (EIA) Indexed Site

    1.3 Relative Standard Errors for Table 1.3;" " Unit: Percents." " "," "," "," "," "," "," "," "," "," " " "," ",," "," ",," "," ",," ","Shipments" "Economic",,"Net","Residual","Distillate",,"LPG and",,"Coke and"," ","of Energy

  11. "Code(a)","End Use","for Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural Gas(d)","NGL(e)","Coke and Breeze)"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Relative Standard Errors for Table 5.4;" " Unit: Percents." " "," ",," ","Distillate"," "," " " "," ",,,"Fuel Oil",,,"Coal" "NAICS"," ","Net Demand","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","for Electricity(b)","Fuel Oil","Diesel

  12. "Code(a)","Subsector and Industry","Source(b)","Electricity(c)","Fuel Oil","Fuel Oil(d)","Natural Gas(e)","NGL(f)","Coal","Breeze","Other(g)","Produced Onsite(h)"

    U.S. Energy Information Administration (EIA) Indexed Site

    1.4 Relative Standard Errors for Table 1.4;" " Unit: Percents." ,,"Any",,,,,,,,,"Shipments" "NAICS",,"Energy","Net","Residual","Distillate",,"LPG and",,"Coke and",,"of Energy Sources" "Code(a)","Subsector and Industry","Source(b)","Electricity(c)","Fuel Oil","Fuel Oil(d)","Natural

  13. "Code(a)","Subsector and Industry","Source(b)","Electricity(c)","Fuel Oil","Fuel Oil(d)","Natural Gas(e)","NGL(f)","Coal","and Breeze","Other(g)"

    U.S. Energy Information Administration (EIA) Indexed Site

    3.4 Relative Standard Errors for Table 3.4;" " Unit: Percents." " "," "," ",," "," "," "," "," "," "," ",," " " "," ","Any" "NAICS"," ","Energy","Net","Residual","Distillate",,"LPG and",,"Coke"," " "Code(a)","Subsector and

  14. "Code(a)","Subsector and Industry","Source(b)","Fuel Oil","Fuel Oil(c)","Natural Gas(d)","NGL(e)","Coal","and Breeze","Other(f)"

    U.S. Energy Information Administration (EIA) Indexed Site

    2.4 Relative Standard Errors for Table 2.4;" " Unit: Percents." " "," "," "," "," "," "," "," "," "," ",," " " "," ","Any Combustible" "NAICS"," ","Energy","Residual","Distillate",,"LPG and",,"Coke"," " "Code(a)","Subsector and

  15. "Code(a)","Subsector and Industry","Total","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal","and Breeze","Other(e)"

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Relative Standard Errors for Table 7.9;" " Unit: Percents." " "," "," ",," "," "," "," "," "," "," "," " " "," " "NAICS"," "," ",,"Residual","Distillate",,"LPG and",,"Coke"," " "Code(a)","Subsector and

  16. "End Use","Total","Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural Gas(c)","NGL(d)","Coke and Breeze)","Other(e)"

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Relative Standard Errors for Table 5.6;" " Unit: Percents." " "," ",," ","Distillate"," "," ",," " " ",,,,"Fuel Oil",,,"Coal" " "," ","Net","Residual","and",,"LPG and","(excluding Coal"," " "End Use","Total","Electricity(a)","Fuel Oil","Diesel

  17. Table 10.24 Reasons that Made Distillate Fuel Oil Unswitchable, 2006;

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Reasons that Made Distillate Fuel Oil Unswitchable, 2006; Level: National Data; Row: NAICS Codes; Column: Reasons that Made Quantity Unswitchable; Unit: Million barrels. Total Amount of Total Amount of Equipment is Not Switching Unavailable Long-Term Unavailable Combinations of NAICS Distillate Fuel Oil Unswitchable Distillate Capable of Using Adversely Affects Alternative Environmenta Contract Storage for Another Columns F, G, Code(a) Subsector and Industry Consumed as a Fue Fuel Oil Fuel Use

  18. T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment...

    Broader source: Energy.gov (indexed) [DOE]

    PROBLEM: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server. PLATFORM: * BlackBerry Enterprise Server Express version...

  19. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  20. Process for LPG recovery

    SciTech Connect (OSTI)

    Khan, Sh. A.; Haliburton, J.

    1985-03-26

    An improved process is described for the separation and recovery of substantially all the propane and heavier hydrocarbon components in a hydrocarbon gaseous feedstream. In this process, the vapor stream from a deethanizer is cooled to liquefaction and contacted with a vapor phase from the hydrocarbon gaseous feedstream. The contact takes place within a direct heat exchanger, and the resulting vapor fraction, which is essentially ethane and methane, is the gaseous product of the process.

  1. LPG in Argentina

    SciTech Connect (OSTI)

    Calcagno, O.

    1986-01-01

    The GNP for Argentina in 1985 was of about 70 billion dollars ( a little over 2200 dollars/capita), the same as 1970 in real terms; foreign debt being over 40 billion. After several years of negative GNP growth, it will probably show a moderate increase in 1986. Industry represents 21 percent of the GNP, agriculture 16 percent. Total exports 12-14 percent. Imports are 8-9 percent. Historical investment of the energy sector was about 3.4 percent. The State, the Public Sector, plays an important role in every aspect, concentrating about 50 percent of the economy. For example, the Central Government sets official prices for most of the forms of energy. Normally, these prices do not relate to international price levels. The country has to catch up with the developed world and it is striving to increase productivity. There is a need to get its products to the external market as well as to attract foreign investment. The government has apparently become fully aware of that, being now a matter of how those goals are accomplished. It may take some time and reeducation of people at all levels to do so.

  2. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1997-07-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  3. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  4. UV resonance Raman characterization of polycyclic aromatic hydrocarbons in coal liquid distillates

    SciTech Connect (OSTI)

    Rumelfanger, R.; Asher, S.A.; Perry, M.B.

    1988-02-01

    Ultraviolet resonance Raman spectroscopy has been used to characterize the polycyclic aromatic hydrocarbon composition of a series of distillates of coal-derived liquids. The UV Raman spectra easily monitor changes in the polycyclic aromatic hydrocarbon composition as a function of distillation temperature. Specific species, such as pyrene, can be determined by judicious choice of excitation wavelength.

  5. Gas response properties of citrate gel synthesized nanocrystalline MgFe{sub 2}O{sub 4}: Effect of sintering temperature

    SciTech Connect (OSTI)

    Patil, J.Y.; Mulla, I.S.; Suryavanshi, S.S.

    2013-02-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of nanocrystalline MgFe{sub 2}O{sub 4} by economical citrate gel combustion method. ? Structural, morphological, and gas response properties of MgFe{sub 2}O{sub 4}. ? Enhancement in selectivity of MgFe{sub 2}O{sub 4} towards LPG with sintering temperature. ? Use of MgFe{sub 2}O{sub 4} to detect different gases at different operating temperatures. -- Abstract: Spinel type MgFe{sub 2}O{sub 4} material was synthesized by citrate gel combustion method. The effect of sintering temperature on structural, morphological, and gas response properties was studied. The powder X-ray diffraction pattern and transmission electron microscope study confirms nanocrystalline spinel structure of the synthesized powder. The material was tested for response properties to various reducing gases like liquid petroleum gas (LPG), acetone, ethanol, and ammonia. The results demonstrated n-type semiconducting behavior of MgFe{sub 2}O{sub 4} material. It was revealed that MgFe{sub 2}O{sub 4} sintered at 973 K was most sensitive to LPG at 648 K and to acetone at 498 K. However MgFe{sub 2}O{sub 4} sintered at 1173 K exhibited higher response and selectivity to LPG with marginal increase in the operating temperature. Furthermore, the sensor exhibited a fast response and a good recovery. It was observed that the particles size, porosity, and surface activity of the sensor material is affected by the sintering temperature.

  6. Kinetic and reactor models for HDT of middle distillates

    SciTech Connect (OSTI)

    Cotta, R.M.; Filho, R.M.

    1996-12-31

    Hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of middle distillates over a commercial Ni-Mo/y-Al{sub 2}O{sub 3} has been studied under wide operating conditions just as 340 to 380{degrees}C and 38 to 98 atm. A Power Law model was presented to each one of those reactions. The parameters of kinetic equations were estimated solving the ordinary differential equations by the 4 order Runge-Kutta-Gill algorithm and Marquardt method for searching of set of kinetic parameters (kinetic constants as well as the orders of reactions). An adiabatic diesel hydrotreating trickle-bed reactor packed with the same catalyst was simulated numerically in order to check up the behavior of this specific reaction system. One dimensional pseudo-homogeneous model was used in this work. For each feed, the mass and energy balance equations were integrated along the length of the catalytic bed using the 4th Runge-Kutta-Gill method. The performance of two industrial reactors was checked. 5 refs., 2 tabs.

  7. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del )

    1993-12-06

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  8. Use of extractive distillation to produce concentrated nitric acid

    SciTech Connect (OSTI)

    Campbell, P.C.; Griffin, T.P.; Irwin, C.F.

    1981-04-01

    Concentrated nitric acid (> 95 wt %) is needed for the treatment of off-gases from a fuels-reprocessing plant. The production of concentrated nitric acid by means of extractive distillation in the two-pot apparatus was studied to determine the steady-state behavior of the system. Four parameters, EDP volume (V/sub EDP/) and temperature (T/sub EDP/), acid feed rate, and solvent recycle, were independently varied. The major response factors were percent recovery (CPRR) and product purity (CCP). Stage efficiencies also provided information about the system response. Correlations developed for the response parameters are: CPRR = 0.02(V/sub EDP/ - 800 cc) + 53.5; CCP = -0.87 (T/sub EDP/ - 140/sup 0/C) + 81; eta/sub V,EDP/ = 9.1(F/sub feed/ - 11.5 cc/min) - 0.047(V/sub EDP/ - 800 cc) - 2.8(F/sub Mg(NO/sub 3/)/sub 2// - 50 cc/min) + 390; and eta/sub L,EDP/ = 1.9(T/sub EDP/ - 140/sup 0/C) + 79. A computer simulation of the process capable of predicting steady-state conditions was developed, but it requires further work.

  9. Refiner/marketer targets production of transportation fuels and distillates

    SciTech Connect (OSTI)

    Thompson, J.E.

    1997-01-01

    Citgo Petroleum Corp., the wholly owned subsidiary of Petroleos de Venezuela, S.A. (PDVSA), the Venezuelan national oil company, owns two gasoline producing refineries, a 305,000-b/d system in Lake Charles, La., and a 130,000-b/d facility in Corpus Christi, Texas. Each is considered a deep conversion facility capable of converting heavy, sour crudes into a high percentage of transportation fuels and distillates. Two smaller refineries, one in Paulsboro, N.J., and one in Savannah, GA., have the capacity to process 40,000 b/d and 28,000 b/d of crude, respectively, for asphalt products. In the past two years, Citgo`s light oils refineries operated safely and reliably with a minimum of unscheduled shutdowns. An ongoing emphasis to increase reliability has resulted in extended run lengths at the refineries. Citgo has invested $314 million at its facilities in 1995, much of this toward environmental and regulatory projects, such as the new waste water treatment unit at the Lake Charles refinery. Over the next few years, Citgo expects to complete $1.5 billion in capital spending for major processing units such as a 60,000-b/d FCC feed hydrotreater unit at the Lake Charles refinery and crude expansion at the Corpus Christi refinery. Product exchanges and expanded transport agreements are allowing Citgo to extend its marketing reach.

  10. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect (OSTI)

    1996-11-01

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls. ATV identification with on-line detuning was used for tuning the diagonal PI composition controllers. Each configuration was evaluated with respect to steady-state RGA values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity), were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.