National Library of Energy BETA

Sample records for gas desulfurization unit

  1. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, Kwan H.; Ahluwalia, Rajesh K.

    1985-01-01

    A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

  2. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  3. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T.; Shen, Ming-Shing

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  4. Flue gas desulfurization wastewater treatment primer

    SciTech Connect (OSTI)

    Higgins, T.E.; Sandy, A.T.; Givens, S.W.

    2009-03-15

    Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.

  5. Sorbent for use in hot gas desulfurization

    DOE Patents [OSTI]

    Gasper-Galvin, Lee D.; Atimtay, Aysel T.

    1993-01-01

    A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

  6. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  7. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  8. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  9. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  10. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  11. Core-in-shell sorbent for hot coal gas desulfurization

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Akiti, Jr., Tetteh T.

    2004-02-10

    A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical characteristics to withstand the conditions of use.

  12. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  13. Desulfurized gas production from vertical kiln pyrolysis

    DOE Patents [OSTI]

    Harris, Harry A.; Jones, Jr., John B.

    1978-05-30

    A gas, formed as a product of a pyrolysis of oil shale, is passed through hot, retorted shale (containing at least partially decomposed calcium or magnesium carbonate) to essentially eliminate sulfur contaminants in the gas. Specifically, a single chambered pyrolysis vessel, having a pyrolysis zone and a retorted shale gas into the bottom of the retorted shale zone and cleaned product gas is withdrawn as hot product gas near the top of such zone.

  14. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    Unknown

    1999-07-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2}TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. Overall chemical reactions with Zn{sub 2}TiO{sub 4} during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO{sub 2}.

  15. High temperature desulfurization of synthesis gas

    DOE Patents [OSTI]

    Najjar, Mitri S.; Robin, Allen M.

    1989-01-01

    The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

  16. Process for production desulfurized of synthesis gas

    DOE Patents [OSTI]

    Wolfenbarger, James K.; Najjar, Mitri S.

    1993-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

  17. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  18. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    Unknown

    1999-10-01

    The U.S. Department of Energy (DOE), Federal Energy Technology Center (FETC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2} TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. Overall chemical reactions with Zn{sub 2} TiO{sub 4} during the desulfurization (sulfidation)-regeneration cycle are shown below: Sulfidation: Zn{sub 2} TiO{sub 4} + 2H{sub 2}S {yields} 2ZnS + TiO{sub 2} + 2H{sub 2}O; Regeneration: 2ZnS + TiO{sub 2} + 3O{sub 2} {yields} Zn{sub 2} TiO{sub 4} + 2SO{sub 2} The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO{sub 2}.

  19. An experimental study of flue gas desulfurization in a pilot spray dryer

    SciTech Connect (OSTI)

    Ollero, P.; Salvador, L.; Canadas, L.

    1997-12-31

    More than 45 experimental tests have been conducted on a 10,000 Nm{sup 3}/h spray-drying desulfurization pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/S ratio, approach to saturation temperature, unit load changes, and the utilization of seawater as make-up water on both spray dryer behavior and treated flue gas properties were analyzed. This experimental study allows us to reach some conclusions about how to achieve optimum operating conditions and to assess the impact of spray drying on a downstream ESP. 5 refs., 14 figs., 2 tabs.

  20. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  1. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  2. Dry FGD (flue-gas desulfurization) at Argonne National Laboratory

    SciTech Connect (OSTI)

    Livengood, C.D.

    1990-01-01

    Flue-gas desulfurization (FGD) systems based on spray drying are a relatively recent addition to the spectrum of sulfur dioxide (SO{sub 2}) control options available to utility and industrial boiler operators. Such systems appear to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. These advantages have promoted rapid acceptance of dry scrubbers for applications using western low-sulfur coal, but uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. At Argonne National Laboratory (ANL) we have had more than eight years of operating experience with an industrial-scale dry scrubber used with a boiler firing high-sulfur (3.5%) midwestern coal. This paper describes our operating experience with that system and summarizes several research programs that have utilized it. 7 refs., 15 figs., 6 tabs.

  3. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  4. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  5. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  6. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  7. An integrated process for simultaneous desulfurization, dehydration, and recovery of hydrocarbon liquids from natural gas streams

    SciTech Connect (OSTI)

    Sciamanna, S.F. ); ))

    1988-01-01

    Conventional processing schemes for desulfurizing, drying, and separation of natural gas liquids from natural gas streams require treating the gas by a different process for each separation step. In a simpler process, based on the University of California, Berkeley Sulfur Recovery Process (UCBSRP) technology, hydrogen sulfide, propane and heavier hydrocarbons, and water are absorbed simultaneously by a polyglycol ether solvent containing a homogenous liquid phase catalyst. The catalyst promotes the subsequent reaction of hydrogen sulfide with added sulfur dioxide to produce a high quality sulfur product. Hydrocarbons are separated as two product streams with the split between propane and butane. This new process offers an overall reduction in both capital and energy costs.

  8. Regeneration and Durability of Advanced Zinc Ferrite Sorbent for Hot Coal Gas Desulfurization

    SciTech Connect (OSTI)

    Shirai, H.; Kobayashi, M.; Nunokawa, M.; Noda, N.

    2002-09-19

    In this study, we investigate the regeneration characteristics, desulfurization performance after regeneration and the durability of zinc ferrite sorbent in the desulfurization/regeneration cycles.

  9. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  10. BUILDING MATERIALS MADE FROM FLUE GAS DESULFURIZATION BY-PRODUCTS

    SciTech Connect (OSTI)

    Michael W. Grutzeck; Maria DiCola; Paul Brenner

    2006-03-30

    Flue gas desulphurization (FGD) materials are produced in abundant quantities by coal burning utilities. Due to environmental restrains, flue gases must be ''cleaned'' prior to release to the atmosphere. They are two general methods to ''scrub'' flue gas: wet and dry. The choice of scrubbing material is often defined by the type of coal being burned, i.e. its composition. Scrubbing is traditionally carried out using a slurry of calcium containing material (slaked lime or calcium carbonate) that is made to contact exiting flue gas as either a spay injected into the gas or in a bubble tower. The calcium combined with the SO{sub 2} in the gas to form insoluble precipitates. Some plants have been using dry injection of these same materials or their own Class C fly ash to scrub. In either case the end product contains primarily hannebachite (CaSO{sub 3} {center_dot} 1/2H{sub 2}O) with smaller amounts of gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). These materials have little commercial use. Experiments were carried out that were meant to explore the feasibility of using blends of hannebachite and fly ash mixed with concentrated sodium hydroxide to make masonry products. The results suggest that some of these mixtures could be used in place of conventional Portland cement based products such as retaining wall bricks and pavers.

  11. Process for the manufacture of an attrition resistant sorbent used for gas desulfurization

    DOE Patents [OSTI]

    Venkataramani, Venkat S.; Ayala, Raul E.

    2003-09-16

    This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

  12. Apparatus for hot-gas desulfurization of fuel gases

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV)

    1992-01-01

    An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.

  13. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  14. Advanced fuel gas desulfurization (AFGD) demonstration project. Technical progress report No. 19, July 1, 1994--September 30, 1994

    SciTech Connect (OSTI)

    1995-12-01

    The {open_quotes}Advanced Flue Gas Desulfurization (AFGD) Demonstration Project{close_quotes} is a $150.5 million cooperative effort between the U.S. Department of Energy and Pure Air, a general partnership of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc. The AFGD process is one of several alternatives to conventional flue gas desulfurization (FGD) being demonstrated under the Department of Energy`s Clean Coal Technology Demonstration Program. The AFGD demonstration project is located at the Northern Indiana Public Service Company`s Bailly Generating Station, about 12 miles northeast of Gary, Indiana.

  15. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  16. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  17. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, John B. L.; Doctor, Richard D.; Wingender, Ronald J.

    1986-01-01

    A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

  18. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  19. Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

    1994-01-01

    The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

  20. Model for flue-gas desulfurization in a circulating dry scrubber

    SciTech Connect (OSTI)

    Neathery, J.K.

    1996-01-01

    A simple model was developed to describe the absorption of SO{sub 2} in a circulating dry scrubbing (CDS) process, which is a semi dry, lime-based, flue-gas desulfurization (FGD) process that utilizes a circulating fluidized bed arrangement for contacting a sorbent with SO{sub 2}-laden flue gas under coolside conditions. The reaction chemistry is thought to be similar to that of spray-drying absorption. The liquid-phase mass-transfer coefficient was successfully modeled as a function of the sorbent particle spacing on the wetted surfaces. Gas-phase mass-transfer resistances were assumed to be insignificant. Due to the high surface area available in a CDS reactor, the evaporation rate of water from the slurry was modeled as constant-rate drying according to classic spray-dryer theory. However, the falling-rate and diffusion evaporation stages were negligible in CDS since sorbent particle bunching at the surface of the slurry is nonexistent.

  1. The Clean Coal Technology Program 100 MWe demonstration of gas suspension absorption for flue gas desulfurization

    SciTech Connect (OSTI)

    Hsu, F.E.; Hedenhag, J.G.; Marchant, S.K.; Pukanic, G.W.; Norwood, V.M.; Burnett, T.A.

    1997-12-31

    AirPol Inc., with the cooperation of the Tennessee Valley Authority (TVA) under a Cooperative Agreement with the United States Department of Energy, installed and tested a 10 MWe Gas Suspension Absorption (GSA) Demonstration system at TVA`s Shawnee Fossil Plant near Paducah, Kentucky. This low-cost retrofit project demonstrated that the GSA system can remove more than 90% of the sulfur dioxide from high-sulfur coal-fired flue gas, while achieving a relatively high utilization of reagent lime. This paper presents a detailed technical description of the Clean Coal Technology demonstration project. Test results and data analysis from the preliminary testing, factorial tests, air toxics texts, 28-day continuous demonstration run of GSA/electrostatic precipitator (ESP), and 14-day continuous demonstration run of GSA/pulse jet baghouse (PJBH) are also discussed within this paper.

  2. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  3. State-of-the-art review of materials-related problems in flue gas desulfurization systems

    SciTech Connect (OSTI)

    Maiya, P. S.

    1980-10-01

    This report characterizes the chemical and mechanical environments to which the structural components used in flue-gas desulfurization (FGD) are exposed. It summarizes the necessary background information pertinent to various FGD processes currently in use, with particular emphasis on lime/limestone scrubbing technology, so that the materials problems and processing variables encountered in FGD systems can be better defined and appreciated. The report also describes the materials currently used and their performance to date in existing wet scrubbers. There is little doubt that with more extensive use of coal and flue-gas scrubbers by utilities and other segments of private industry, a better understanding of the material failure mechanisms, performance limitations, and potential problem areas is required for the design of more reliable and cost-effective FGD systems. To meet the above objectives, a materials evaluation program is proposed. The important experimental variables and the number of tests required to evaluate a given material are discussed. 55 references, 9 figures, 6 tables.

  4. Spare parts program practices for flue gas desulfurization systems: Final report

    SciTech Connect (OSTI)

    Morgan, W.E.; Stresewski, J.E.; Cannell, A.L.

    1987-04-01

    Reliability and availability of a flue gas desulfurization (FGD) system is dependent to some extent on adequate system maintenance. System maintenance must be supported by a well planned spare parts program. The objective of this project was to determine the current practices followed by electric utilities in planning spare parts programs. Utilities with operational FGD systems were surveyed to determine the types of practices and typical inventory levels for spare parts for various items of FGD system equipment. FGD system suppliers and consulting engineering firms were also surveyed to obtain their recommendations regarding system sparing philosophy. The survey results were examined to determine significant trends and identify areas where further work could be beneficial. In general, spare parts problems typically have not been a cause for loss of availability except in some specific cases where a late start in planning the spare parts program contributed to problems during early stages of FGD system operation. Computerized methods for inventory surveillance and reordering are replacing manual methods. Stock levels for spare parts typically have been adjusted to reflect the individual utilities' operating experience. Documentation of spare parts usage rates over an extended time period would provide a data base for utilities planning spare parts programs for their first FGD system installation.

  5. LIFAC flue gas desulfurization process an alternative SO{sub 2} control strategy

    SciTech Connect (OSTI)

    Patel, J.G.; Vilala, J.

    1995-12-01

    This paper discusses the results from two recently completed LIFAC flue gas desulfurization plants - 300 MW Shand lignite powered station owned by Saskatchewan Power Corporation and 60 MW Whitewater Valley high sulfur coal fired station owned by Richmond Powerand Light. LIFACis a dry FGD process in which limestone is injected into the upper regions of the boiler furnace and an activation reactor is used to humidify the unreacted limestone to achieve additional sulfur capture. The performance in both plants indicates that 70 to 80% sulfur is removed at a Ca/S ratio of 2. Cost performance data from these plants has shown that LI FAC both on construction cost and $/ton SO{sub 2} removed basis is very cost competitive compared to other SO{sub 2} control technologies. The Richmond plant has been realized under the auspices of the U.S. Department of Energy`s Clean Coal Technology program. The Shand plant is the first commercial installation in North America. The paper also discusses highlights of operating and maintenance experience, availability and handling of the solid waste product.

  6. Status of spray-dryer flue-gas desulfurization. Final report

    SciTech Connect (OSTI)

    Ireland, P.A.

    1982-01-01

    Utility interest and commitment to spray drying for SO/sub 2/ and particulate control has increased dramatically in response to vendor claims (lower costs, dry wastes, lower energy requirements, and simplicity) and newly promulgated federal emission regulations that allow lower SO/sub 2/ removal requirements (70%) for low-sulfur coals. Unfortunately, limited data are available from which to evaluate vendor claims prior to commercial commitment or to improve the cost and reliability of this potentially important flue gas desulfurization (FGD) option. Accordingly, EPRI is conducting a pilot-scale project (RP1870) to provide a systematic evaluation of the technology unconstrained by specific vendor designs, operating philosophy, or commercial limitation. It will result in guidelines for system design and optimization in order to ensure reliable utility operation at minimum cost. This final report (TPS 80-741) contains a review of the design practices for the full-scale systems ordered and a discussion of the important spray-drying FGD process variables. Other EPRI work in this area includes a cost study with the Tennessee Valley Authority (RP1180-7) and a spray-dryer waste solids characterization (RP1870-2). The EPA has published a similar status document, which, in addition to spray drying, also covers dry injection and burning coal-alkali mixtures. However, the EPA document is not as detailed on either the design of full-scale systems or the technical issues.

  7. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect (OSTI)

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R.

    2009-08-15

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  8. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  9. Hot coal gas desulfurization with manganese-based sorbents. Annual report, September 1992--September 1993

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1993-12-01

    The focus of work being performed on Hot Coal Gas Desulfurization at the Morgantown Energy Technology Center is primarily in the use of zinc ferrite and zinc titanate sorbents; however, prior studies at the US Steel Fundamental Research Laboratories in Monroeville, PA, by E. T. Turkdogan indicated that an alternate sorbent, manganese dioxide-containing ore in mixture with alumina (75 wt % ore + 25 wt % Al{sub 2}O{sub 3}) may be a viable alternative to zinc-based sorbents. Manganese, for example, has a lower vapor pressure in the elemental state than zinc hence it is not as likely to undergo depletion from the sorbent surface upon loading and regeneration cycles. Also manganese oxide is less readily reduced to the elemental state than iron hence the range of reduction potentials for oxygen is somewhat greater than for zinc ferrite. In addition, thermodynamic analysis of the manganese-oxygen-sulfur system shows it to be less amenable to sulfation than zinc ferrite. Potential also exists for utilization of manganese at higher temperatures than zinc ferrite or zinc titanate. This Annual Topical Report documents progress in pelletizing and testing via thermo-gravimetric analysis of individual pellet formulations of manganese ore/ alumina combinations and also manganese carbonate/alumina with two binders, dextrin and bentonite. It includes the prior Quarterly Technical Reports which indicate that the manganese carbonate material, being of higher purity than the manganese ore, has a higher degree of sulfur capacity and more rapid absorption kinetics. A 2-inch fixed-bed reactor has been fabricated and is now ready for subjecting pellets to cyclic loading and regeneration.

  10. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-10-01

    New coal gasification processes are now being developed which can generate electricity with high thermal efficiency either in an integrated gasification combined cycle (IGCC) or in a fuel cell (MCFC). Both of these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCl) in the coal-gas. This project investigates the effect of HCl, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by the HCI, both in absorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences of utilizing high-chlorine Illinois coal in these processes. The work activity during the third quarter of this project involved the performance of the second block-set of experiments in the bench-scale fluidized-bed reactor. These experiments were designed to study the effect of HCl in the desulfurization of a low-Btu fuel gas. Nine single-cycle experiments were performed, at operating temperature of 538, 650, and 750{degrees}C, with HCl concentrations of 0, 200, and 800 ppMv. The presence of HCl in the coal gas significantly enhanced the desulfurization efficacy of the sorbent. A 10-cycle sulfidation-regeneration sequence is currently being performed at 650{degrees}C with 800 ppMv HCl in the simulated fuel gas to determine any adverse effects on the sorbent structure or its desulfurization capability.

  11. Desulfurization apparatus and method

    DOE Patents [OSTI]

    Rong, Charles; Jiang, Rongzhong; Chu, Deryn

    2013-06-18

    A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved by utilizing two to three units by weight of the first metal oxide for every unit of the second metal oxide.

  12. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  13. Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 1

    SciTech Connect (OSTI)

    Underkoffler, V.S.

    1986-12-01

    The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Optimum operating parameters for zinc ferrite such as temperatures, gas compositions, and space velocities are discussed. From the test results, salient features of zinc ferrite were derived and discussed in regard to system implications, issues raised, and technical requirements. 47 refs., 53 figs., 41 tabs.

  14. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-12-31

    In this project, simulated gasifier-product streams were contacted with the zinc titanate desulfurization sorbent in a bench-scale atmospheric fluidized-bed reactor at temperatures ranging from 538 to 750 {degree}C (1000 to 1382 {degree}F). The first set of experiments involved treating a medium-Btu fuel gas (simulating that of a ``Texaco`` oxygen-blown, entrained-bed gasifier) containing 1.4 percent H{sub 2}S and HCl concentrations of 0, 200, and 1500 ppmv. The second experimental set evaluated hot-gas desulfurization of a low-Btu fuel gas (simulating the product of the ``U-Gas`` air-blown gasifier), with HCl concentrations of 0, 200, and 800 ppmv. These operating conditions were typical of the gas-treatment requirements of gasifiers fueled by Illinois basin coals containing up to 0.6 percent chlorine. The results of the experiments at 538 and 650 {degree}C at all the HCl concentrations revealed no deleterious effects on the capability of the sorbent to remove H{sub 2}S from the fuel gas mixtures. In most cases, the presence of the HCl significantly enhanced the desulfurization reaction rate. Some zinc loss, however, was encountered in certain situations at 750 {degree}C when low-steam operating conditions were present. Also of interest, a portion of the incoming HCl was removed from the gas stream and was retained permanently by the sorbent. This behavior was examined in more detail in a limited set of experiments aimed at identifying ways to modify the sorbents composition so that the sorbent could act as a simultaneous desulfurization and dechlorination agent in the hot-gas cleanup process.

  15. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  16. System for removing solids from a used lime or limestone slurry scrubbing liquor in flue gas desulfurization

    SciTech Connect (OSTI)

    Randolph, A.D.

    1981-10-13

    The flue gas desulfurization process using a lime or limestone slurry scrubbing solution produces used liquor containing calcium sulfite or sulfate (Typically gypsum). Precipitated particles are removed by feeding the used scrubbing liquor to an agitated crystallization zone to grow crystals and directing part of the used scrubbing liquor from that zone to a quiescent crystallization zone, in which particles are settled back into the agitated zone. An underflow stream from the agitated zone containing large crystals is combined with an overflow stream from the quiescent zone, which combined stream is clarified with the fines being returned to the scrubber and the large crystals being removed as a waste product. Apparatus for performing the above process in which the agitated and quiescent crystallization zones form part of a single crystallization vessel, and the two zones are separated by a baffle.

  17. Philippine refiner completes diesel desulfurization project

    SciTech Connect (OSTI)

    Candido, S.S.; Crisostomo, E.V.

    1997-01-27

    In anticipation of tightening sulfur specifications on diesel fuel, Petron Corp. built a new 18,000 b/sd gas oil desulfurization unit (GODU) at its refinery in Bataan, Philippines. The GODU gives Petron sufficient diesel oil desulfurization capacity to meet demand for lower-sulfur diesel in the country. The project places the refinery in a pacesetter position to comply with the Philippine government`s moves to reduce air pollution, especially in urban centers, by reducing the sulfur specification for diesel to 0.5 wt% in 1996 from 0.7 wt% at the start of the project. Performance tests and initial operations of the unit have revealed a desulfurization efficiency of 91% vs. a guaranteed efficiency of 90%. A feed sulfur content of 1.33 wt% is reduced to 0.12 wt% at normal operating conditions. Operating difficulties during start-up were minimized through use of a detailed prestartup check conducted during the early stages of construction work.

  18. Desulfurization Sorbents for Transport-Bed Applications

    SciTech Connect (OSTI)

    Gupta, Raghubir P.; Turk, Brian S.; Vierheilig, Albert A.

    1997-07-01

    This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. The specific objectives are: (1) To develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{micro}m particle size range for transport reactor applications; (2) To transfer sorbent production technology to private sector; and (3) To provide technical support to Sierra Pacific Clean Coal Technology Demonstration plant and FETC's Hot-Gas Desulfurization Process Development Unit (PDU), both employing a transport reactor system.

  19. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the US Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate two technologies for the placement of coal combustion residues in abandoned underground coal mines, and will assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement, using virtually dry materials, and (2) hydraulic placement, using a {open_quotes}paste{close_quotes} mixture of materials with about 70% solids. Phase II of the overall program began April 1, 1996. The principal objective of Phase II is to develop and fabricate the equipment for placing the coal combustion by-products underground, and to conduct a demonstration of the technologies on the surface. Therefore, this quarter has been largely devoted to developing specifications for equipment components, visiting fabrication plants throughout Southern Illinois to determine their capability for building the equipment components in compliance with the specifications, and delivering the components in a timely manner.

  20. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1995-01-01

    On September 30, 1993, the US Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative agreement entitled ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` (DE-FC21-93MC30252). Under the agreement, Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. The major event during the quarter was the demonstration of the SEEC, Inc. technology for loading and transporting coal combustion residues in the SEEC developed Collapsible Intermodal Containers (CIC). The demonstration was held on November 17, 1994, at the Illinois Power Company Baldwin power plant, and was attended by about eighty (80) invited guest. Also during the quarter meetings were held with Peabody Coal Company officials to finalize the area in the Peabody No. 10 mine to be used for the placement of coal combustion residues. Work under the Materials Handling and Systems Economics area continued, particularly in refining the costs and systems configuration and in economic evaluation of various systems using equipment leasing rather than equipment purchases. Likewise, work progressed on residues characterization, with some preparations being made for long-term testing.

  1. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  2. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the U.S. Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SITJC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC-30252). Under the agreement SIUC will develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mine workings, and assess the environmental impact of such underground placements. This report discusses the technical progress achieved during the period October 1 - December 31, 1995. Rapid Aging Test columns were placed in operation during the second quarter of 1995, and some preliminary data were acquired during this quarter. These data indicate that the highly caustic pH is initially generated in the pneumatic mix, but that such pH is short lived. The initial pH rapidly declines to the range of 8 to 9. Leachates in this pH range will have little or no effect on environmental concerns. Dedicated sampling equipment was installed in the groundwater monitoring wells at the proposed placement site at the Peabody Number 10 mine. Also, the groundwater monitoring wells were {open_quotes}developed{close_quotes} during the quarter to remove the fines trapped in the sand pack and screen. A new procedure was used in this process, and proved successful. A series of tests concerning the geotechnical characteristics of the pneumatic mixes were conducted. Results show that both moisture content and curing time have a direct effect on the strength of the mixes. These are, of course, the expected general results. The Christmas holidays and the closing of the University during an extended period affected the progress of the program during the quarter. However, the program is essentially on schedule, both technically and fiscally, and any delays will be overcome during the first quarter of 1996.

  3. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, January--March 1995

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.

    1995-04-01

    On September 30, 1993, the U.S. Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC 30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, as well as the management plan and the test plan for the overall program, and a discussion of these will not be repeated here. Rather, this report, will set forth the technical progress made during the period January 1 through March 31, 1995. The demonstration of the SEEC, Inc. technology for the transporting of coal combustion residues was completed with the unloading and final disposition of the three Collapsible Intermodal Containers (CIC). The loading and transport by rail of the three CIC`s was quire successful; however some difficulties were encountered in the unloading of the containers. A full topical report on the entire SEEC demonstration is being prepared. As a result of the demonstration some modifications of the SEEC concept may be undertaken. Also during the quarter the location of the injection wells at the Peabody No. 10 mine demonstration site were selected. Peabody Coal Company has developed the specifications for the wells and sought bids for the actual drilling. It is expected that the wells will be drilled early in May.

  4. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-07-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, and a discussion of these is not repeated here. Rather, this report discusses the technical progress made during the period April 1 - June 30, 1995. A final topical report on the SEEC, Inc. demonstration of its technology for the transporting of coal combustion residues was completed during the quarter, although final printing of the report was accomplished early in July, 1995. The SEEC technology involves the use of Collapsible Intermodal Containers (CIC`s) developed by SEEC, and the transportation of such containers - filled with fly ash or other coal combustion residues - on rail coal cars or other transportation means. Copies of the final topical report, entitled {open_quotes}The Development and Testing of Collapsible Intermodal Containers for the Handling and Transport of Coal Combustion Residues{close_quotes} were furnished to the Morgantown Energy Technology Center. The Rapid Aging Test colums were placed in operation during the quarter. This test is to determine the long-term reaction of both the pneumatic and hydraulic mixtures to brine as a leaching material, and simulates the conditions that will be encountered in the actual underground placement of the coal combustion residues mixtures. The tests will continue for about one year.

  5. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes

    SciTech Connect (OSTI)

    Jozewicz, W. . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide (Ca(OH){sub 2}) slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  6. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  7. KINETICS OF Mn-BASED SORBENTS FOR HOT COAL GAS DESULFURIZATION

    SciTech Connect (OSTI)

    K.A. SADECKI; M.T. HEPWORTH

    1997-06-15

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H2S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In previous reports, the sulfidation and regeneration results from cyclic testing done at 550 and 600 °C were presented. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H2S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent at 600 °C. Regeneration tests determined that loaded pellets can be essentially completely regenerated in air/steam mixture at 750 °C with minimal sulfate formation. In this report, the performance of the leading formulation (designated C6-2) was investigated for high temperature removal of H2S from simulated coal-derived fuel gas under varying sorbent induration temperature, reaction temperature, and superficial gas velocity. Sulfidation experiments were performed in an ambient pressure fixed-bed reactor between 500 °C and 600 °C. Four tests were conducted with each test consisting of four cycles of sulfidation and regeneration. Results showed that the induration temperature of the sorbent and the reaction temperature greatly affected the H2S removal capacity of the sorbent while the superficial gas velocity between 1090 and 1635 cm/min had minimal affect on the sorbent's breakthrough capacity. Sorbent also showed 30 to 53% loss of its strength over four cycles of sulfidation and regeneration. The former being sorbent indurated at 1115 °C and the prior being sorbent indurated at 1100 °C.

  8. The United States natural gas industry

    SciTech Connect (OSTI)

    Gibson, D.E.

    1988-01-01

    The U.S. natural gas industry can only be understood within the context of the nation's attitudes toward the proper role of government within the U.S. economy. A review of regulatory history provides valuable insights to understanding the unique structure and functioning of the gas industry in the United States, as well as future directions for the industry. Tomorrow's natural gas industry will feature adequate gas supplies, unbundling of services, continuing competition with oil, and changed regulation.

  9. EFM units monitor gas flow

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    This paper describes the radio-controlled pipeline monitoring system established by Transcontinental Gas Pipe Line Corp. which was designed to equip all its natural gas purchasing metering facilities with electronic flow measurement computers. The paper describes the actual radio equipment used and the features and reliability of the equipment.

  10. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-12-31

    This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

  11. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-11-01

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  12. Influence of CO{sub 2} and O{sub 2} on the reaction of Ca(OH){sub 2} under spray-drying flue gas desulfurization conditions

    SciTech Connect (OSTI)

    Ho, C.S.; Shih, S.M.; Lee, C.D.

    1996-11-01

    The influence of CO{sub 2} and O{sub 2} in the flue gas on the reaction of hydrated lime sorbent with SO{sub 2} was studied using a fixed-bed differential reactor under conditions prevailing in the spray-drying flue gas desulfurization process. With the presence of CO{sub 2}, the sulfation and carbonation reactions of Ca(OH){sub 2} took place simultaneously until Ca(OH){sub 2} ceased to react. The CaCO{sub 3} produced reacted further to form CaSO{sub 3}{center_dot}{1/2}H{sub 2}O. The apparent sulfation rate, total reaction rate, and final total conversion of Ca(OH){sub 2} were greater than those for the case without CO{sub 2}. The final total conversion was about 1.45 times that for the latter case at the conditions of 1,000 ppm SO{sub 2}, 60 C, and 70% relative humidity. The same effect was observed whether CO{sub 2} was present with O{sub 2} or not. Kinetic expressions obtained by assuming chemical reaction control and considering the surface coverage by product crystals best represented the kinetic data.

  13. The United States has significant natural gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to locate and bring into production. To help meet this challenge, the U.S. Department of Energy's Office of Fossil Energy over the years has amassed wide ranging expertise in areas related to deepwater resource location, production, safety and environmental protection. The goal of these activities has been to not only help overcome production and technical hurdles, but also improve the

  14. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, [October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Thomasson, E.M.; Chugh, Y.P.; Esling, S.; Honaker, R.; Paul, B.; Sevin, H.

    1994-01-01

    The ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` program is one of the largest programs ever undertaken by the Mining Engineering Department of Southern Illinois university, both in terms of complexity and in terms of funding. Total funding over the expected four-year extent of the program, including both Department of Energy, matching Southern Illinois University funds, and contributed funds, this program exceeds three million dollars. The number of cooperating organizations adds to the management complexity of the program. It was believed, therefore, that sound management plan and management base is essential for the efficient and effective conduct of the program. This first quarter period (i.e., October 1--December 31, 1993) was developed to establishing the management base, developing a sound management plan, developing a test plan, and developing sound fiscal management and control. Actual technical operations, such as residue sample acquisition, residue analyses, groundwater sample acquisition and analyses, and material handling studies will get underway early in the next quarter (i.e., January 1--March 31, 1994). Some early results of residue analyses and groundwater analyses should be available by the end of the second quarter. These results will be reported in the next Technical Progress Report.

  15. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  16. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  17. CONVERSION EXTRACTION DESULFURIZATION (CED) PHASE III

    SciTech Connect (OSTI)

    James Boltz

    2005-03-01

    This project was undertaken to refine the Conversion Extraction Desulfurization (CED) technology to efficiently and economically remove sulfur from diesel fuel to levels below 15-ppm. CED is considered a generic term covering all desulfurization processes that involve oxidation and extraction. The CED process first extracts a fraction of the sulfur from the diesel, then selectively oxidizes the remaining sulfur compounds, and finally extracts these oxidized materials. The Department of Energy (DOE) awarded Petro Star Inc. a contract to fund Phase III of the CED process development. Phase III consisted of testing a continuous-flow process, optimization of the process steps, design of a pilot plant, and completion of a market study for licensing the process. Petro Star and the Degussa Corporation in coordination with Koch Modular Process Systems (KMPS) tested six key process steps in a 7.6-centimeter (cm) (3.0-inch) inside diameter (ID) column at gas oil feed rates of 7.8 to 93.3 liters per hour (l/h) (2.1 to 24.6 gallons per hour). The team verified the technical feasibility with respect to hydraulics for each unit operation tested and successfully demonstrated pre-extraction and solvent recovery distillation. Test operations conducted at KMPS demonstrated that the oxidation reaction converted a maximum of 97% of the thiophenes. The CED Process Development Team demonstrated that CED technology is capable of reducing the sulfur content of light atmospheric gas oil from 5,000-ppm to less than 15-ppm within the laboratory scale. In continuous flow trials, the CED process consistently produced fuel with approximately 20-ppm of sulfur. The process economics study calculated an estimated process cost of $5.70 per product barrel. The Kline Company performed a marketing study to evaluate the possibility of licensing the CED technology. Kline concluded that only 13 refineries harbored opportunity for the CED process. The Kline study and the research team's discussions with

  18. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  19. Management of dry flue gas desulfurization by-products in underground mines. Technical progress report, 1 January--31 March 1994

    SciTech Connect (OSTI)

    Chugh, Y.P.; Esling, S.; Ghafoori, N.; Honaker, R.; Paul, B.; Sevim, H.; Thomasson, E.

    1994-04-01

    Southern Illinois University at Carbondale will develop and demonstrate several technologies for the handling and transport of dry coal combustion residues and for the underground placement in abandoned coal mines and assess associated environmental impacts. Although parts of the Residue Characterization portion of the program were delayed because residue samples were not obtained, other parts of the program are proceeding on schedule. The delays in obtaining residue samples were primarily caused by adverse weather conditions, the shut-down of one unit at the City Water, Light, and Power Company Plant for routing maintenance and problems due to conflicting schedules of utility and program personnel. However, by the end of the quarter most residue samples had been obtained, and the residue characterization studies were under way. Progress is described for five studies: environmental assessment and geotechnical stability and subsidence impacts; residue characterization; physico-chemical characterization of residues; identification and assessment of handling/transportation systems for FGD residues; and residue handling and transport.

  20. Efficiency United (Gas) - Commercial Efficiency Program | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Furnace Tune-up: 15-100unit Infrared Heaters: 4MBH Hotel Guest Room Occupancy Sensor: 13unit Demand Control Ventilation: 0.05sq. ft. HVAC Occupancy Sensor: 0.02...

  1. Diesel Desulfurization Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfurization Filter Diesel Desulfurization Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005deerrohrbach.pdf More ...

  2. Enzymatic desulfurization of coal

    SciTech Connect (OSTI)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V.

    1991-05-16

    The overall objective of this program was to investigate the feasibility of an enzymatic desulfurization process specifically intended for organic sulfur removal from coal. Toward that end, a series of specific objectives were defined: (1) establish the feasibility of (bio)oxidative pretreatment followed by biochemical sulfate cleavage for representative sulfur-containing model compounds and coals using commercially-available enzymes; (2) investigate the potential for the isolation and selective use of enzyme preparations from coal-utilizing microbial systems for desulfurization of sulfur-containing model compounds and coals; and (3) develop a conceptual design and economic analysis of a process for enzymatic removal of organic sulfur from coal. Within the scope of this program, it was proposed to carry out a portion of each of these efforts concurrently. (VC)

  3. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  4. Two-stage coal gasification and desulfurization apparatus

    DOE Patents [OSTI]

    Bissett, Larry A.; Strickland, Larry D.

    1991-01-01

    The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.

  5. ,"U.S. Liquefied Natural Gas Imports From The United Arab Emirates...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Data 1","U.S. Liquefied Natural Gas Imports From The United Arab Emirates ... 1: U.S. Liquefied Natural Gas Imports From The United Arab Emirates (MMcf)" ...

  6. Where is shale gas found in the United States? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Where is shale gas found in the United States? Where is shale gas found in the United States? Where is shale gas found in the United States? (2.7 MB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Development Challenges: Surface Impacts Shale Gas Glossary

  7. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  8. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R.

    1987-01-01

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  9. Kinetics of Mn-based sorbents for hot coal gas desulfurization: Task 2, Exploratory experimental studies: Single pellet tests; Rate mechanism analysis. Quarterly report, June 15, 1996--September 15, 1996

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1996-09-11

    Currently, the Morgantown Energy Technology Center, Department of Energy (DOE/METC) is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressures, and under varying degrees of reducing atmospheres. Also, it must regenerate nearly ideally to maintain activity over numerous cycles. Furthermore, regeneration must yield a sulfur product which is economically recoverable directly or indirectly. Several metal oxides have been investigated as regenerable sorbents for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot fuel gases. MnO was shown to have an intrinsic reaction rate approximately one order of magnitude greater than the rate or reaction with either CaO or ZnO and two orders of magnitude greater than the reaction rate with V{sub 2}0{sub 3}. Manganese also shows desulfurization potential in the temperature range of 600-700{degrees}C where metal oxides currently known to be reactive with H{sub 2}S are unsatisfactorily. In response to stability difficulties of single and binary metal oxide sorbents, increasing effort is being directed towards incorporation of an inert component into sorbent formulation as witnessed by the various Zn-titanates. Primarily, the inert component increases pore structure integrity while stabilizing the active metal oxide against reduction. This report will address testing of Mn-based sorbents in an ambient pressure fixed-bed reactor. Steady-state H{sub 2}S concentrations and breakthrough times will be presented.

  10. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  15. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  16. The Biocatalytic Desulfurization Project

    SciTech Connect (OSTI)

    David Nunn; James Boltz; Philip M. DiGrazia; Larry Nace

    2006-03-03

    The material in this report summarizes the Diversa technical effort in development of a biocatalyst for the biodesulfurization of Petro Star diesel as well as an economic report of standalone and combined desulfurization options, prepared by Pelorus and Anvil, to support and inform the development of a commercially viable process. We will discuss goals of the projected as originally stated and their modification as guided by parallel efforts to evaluate commercialization economics and process parameters. We describe efforts to identify novel genes and hosts for the generation of an optimal biocatalyst, analysis of diesel fuels (untreated, chemically oxidized and hydrotreated) for organosulfur compound composition and directed evolution of enzymes central to the biodesulfurization pathway to optimize properties important for their use in a biocatalyst. Finally we will summarize the challenges and issues that are central to successful development of a viable biodesulfurization process.

  17. Strengthened MILP formulation for certain gas turbine unit commitment problems

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pan, Kai; Guan, Yongpei; Watson, Jean -Paul; Wang, Jianhui

    2015-05-22

    In this study, we derive a strengthened MILP formulation for certain gas turbine unit commitment problems, in which the ramping rates are no smaller than the minimum generation amounts. This type of gas turbines can usually start-up faster and have a larger ramping rate, as compared to the traditional coal-fired power plants. Recently, the number of this type of gas turbines increases significantly due to affordable gas prices and their scheduling flexibilities to accommodate intermittent renewable energy generation. In this study, several new families of strong valid inequalities are developed to help reduce the computational time to solve these typesmore » of problems. Meanwhile, the validity and facet-defining proofs are provided for certain inequalities. Finally, numerical experiments on a modified IEEE 118-bus system and the power system data based on recent studies verify the effectiveness of applying our formulation to model and solve this type of gas turbine unit commitment problems, including reducing the computational time to obtain an optimal solution or obtaining a much smaller optimality gap, as compared to the default CPLEX, when the time limit is reached with no optimal solutions obtained.« less

  18. Strengthened MILP formulation for certain gas turbine unit commitment problems

    SciTech Connect (OSTI)

    Pan, Kai; Guan, Yongpei; Watson, Jean -Paul; Wang, Jianhui

    2015-05-22

    In this study, we derive a strengthened MILP formulation for certain gas turbine unit commitment problems, in which the ramping rates are no smaller than the minimum generation amounts. This type of gas turbines can usually start-up faster and have a larger ramping rate, as compared to the traditional coal-fired power plants. Recently, the number of this type of gas turbines increases significantly due to affordable gas prices and their scheduling flexibilities to accommodate intermittent renewable energy generation. In this study, several new families of strong valid inequalities are developed to help reduce the computational time to solve these types of problems. Meanwhile, the validity and facet-defining proofs are provided for certain inequalities. Finally, numerical experiments on a modified IEEE 118-bus system and the power system data based on recent studies verify the effectiveness of applying our formulation to model and solve this type of gas turbine unit commitment problems, including reducing the computational time to obtain an optimal solution or obtaining a much smaller optimality gap, as compared to the default CPLEX, when the time limit is reached with no optimal solutions obtained.

  19. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 250 citations and includes a subject term index and title list.)

  20. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  1. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-04-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  2. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 250 citations and includes a subject term index and title list.)

  3. Kinetics of Mn-based sorbents for hot coal gas desulfurization. Task 2 -- Exploratory experimental studies: Single pellet tests; rate mechanism analysis. Quarterly report, December 15, 1995--March 15, 1996

    SciTech Connect (OSTI)

    Hepworth, M.T.; Berns, J.

    1996-03-15

    Currently, the Morgantown Energy Technology Center, is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressure`s, and under varying degrees of reducing atmospheres. Thus, high conversion of the metal oxide and low hydrogen sulfide exit partial pressures. Also, it must regenerate nearly ideally to maintain activity over numerous cycles. Furthermore, regeneration must yield a sulfur product which is economically recoverable directly or indirectly. This cyclic process requires a holistic approach as any one criteria may eliminate a candidate sorbent from further consideration. Over fifty induration campaigns have been conducted among the fifteens Mn-based sorbent formulations. All indurated sorbents has been tested for crush strength and chemical analysis. Also, fifteen sorbent formulations have been tested in a TGA for at least on e induration condition. Subsequently described are the three main groups of formulations tested. They are the MnCO{sub 3} supported with TiO{sub 2} (with or without bentonite), MnCO{sub 3} supported with Al{sub 2}O{sub 3} (with or without porosity enhancers), and MnO{sub 2} ore supported with alundum (with and without bentonite).

  4. Performance of Gas-Engine Driven Heat Pump Unit

    SciTech Connect (OSTI)

    Abdi Zaltash; Randy Linkous; Randall Wetherington; Patrick Geoghegan; Ed Vineyard; Isaac Mahderekal; Robert Gaylord

    2008-09-30

    Air-conditioning (cooling) for buildings is the single largest use of electricity in the United States (U.S.). This drives summer peak electric demand in much of the U.S. Improved air-conditioning technology thus has the greatest potential impact on the electric grid compared to other technologies that use electricity. Thermally-activated technologies (TAT), such as natural gas engine-driven heat pumps (GHP), can provide overall peak load reduction and electric grid relief for summer peak demand. GHP offers an attractive opportunity for commercial building owners to reduce electric demand charges and operating expenses. Engine-driven systems have several potential advantages over conventional single-speed or single-capacity electric motor-driven units. Among them are variable speed operation, high part load efficiency, high temperature waste heat recovery from the engine, and reduced annual operating costs (SCGC 1998). Although gas engine-driven systems have been in use since the 1960s, current research is resulting in better performance, lower maintenance requirements, and longer operating lifetimes. Gas engine-driven systems are typically more expensive to purchase than comparable electric motor-driven systems, but they typically cost less to operate, especially for commercial building applications. Operating cost savings for commercial applications are primarily driven by electric demand charges. GHP operating costs are dominated by fuel costs, but also include maintenance costs. The reliability of gas cooling equipment has improved in the last few years and maintenance requirements have decreased (SCGC 1998, Yahagi et al. 2006). Another advantage of the GHP over electric motor-driven is the ability to use the heat rejected from the engine during heating operation. The recovered heat can be used to supplement the vapor compression cycle during heating or to supply other process loads, such as water heating. The use of the engine waste heat results in greater

  5. Anion-exchange resin-based desulfurization process

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.

    1991-01-01

    The University of Tennessee Space Institute (UTSI) has been directed to further develop an anion-exchange, resin-based desulfurization concept that has been developed and tested on a limited scope for feasibility. From environmental as well as the economic viewpoints, it is necessary that the soluble sulfates of alkali metal sorbents be desulfurized (regenerated) and recycled to make regenerative flue gas desulfurization options more attractive. In order to achieve this, a low-temperature, low-cost desulfurization process to reactivate spent alkali metal sorbents is necessary. During the reporting period, January 1, 1991--March 31, 1991, the following progress has been made: (1) A batch mode screening procedure was developed to evaluate performance of candidate resins, relatively easily and quickly. (2) Using this procedure, screening experiments were carried out for IRA-68 (base case) and IRA-35 resins. From preliminary results, IRA-68 resin appears to perform better than the IRA-35 resin. Also, both the resins appear to maintain their SO{sub 4}{sup 2{minus}} ion capacity very well, up to 4 cycles.

  6. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  7. Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy of the Department of Energy gives notice of the availability of the report Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United...

  8. Modern Shale Gas Development in the United States: A Primer | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Modern Shale Gas Development in the United States: A Primer Modern Shale Gas Development in the United States: A Primer This Primer on Modern Shale Gas Development in the United States was commissioned through the Ground Water Protection Council (GWPC). It is an effort to provide sound technical information on and additional insight into the relationship between today's fastest growing, and sometimes controversial, natural gas resource development activity, and environmental

  9. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes. Volume 2, Duct spray drying: Final report

    SciTech Connect (OSTI)

    Jozewicz, W.; Rochelle, G.T.

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  10. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  11. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    7. Natural Gas Processing Plants in Alaska, 2009 Figure 7. Natural Gas Processing Plants in Alaska, 2009...

  12. Desulfurization sorbent regeneration

    DOE Patents [OSTI]

    Jalan, V.M.; Frost, D.G.

    1982-07-07

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

  13. Unit vent airflow measurements using a tracer gas technique

    SciTech Connect (OSTI)

    Adams, D.G.; Lagus, P.L.; Fleming, K.M.

    1997-08-01

    An alternative method for assessing flowrates that does not depend on point measurements of air flow velocity is the constant tracer injection technique. In this method one injects a tracer gas at a constant rate into a duct and measures the resulting concentration downstream of the injection point. A simple equation derived from the conservation of mass allows calculation of the flowrate at the point of injection. Flowrate data obtained using both a pitot tube and a flow measuring station were compared with tracer gas flowrate measurements in the unit vent duct at the Callaway Nuclear Station during late 1995 and early 1996. These data are presented and discussed with an eye toward obtaining precise flowrate data for release rate calculations. The advantages and disadvantages of the technique are also described. In those test situations for which many flowrate combinations are required, or in large area ducts, a tracer flowrate determination requires fewer man-hours than does a conventional traverse-based technique and does not require knowledge of the duct area. 6 refs., 10 figs., 6 tabs.

  14. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, William A.; Healy, Francis E.; Sapienza, Richard S.

    1985-01-01

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  15. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, W.A.; Healy, F.E.; Sapienza, R.S.

    1985-04-18

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  16. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    1. Natural Gas Processing Plants and Production Basins, 2009 Figure 1. Natural Gas Processing Plants and Production Basins, 2009 Source: U.S. Energy Information Administration,...

  17. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Natural Gas Processing Capacity (Million Cubic Feet per Day) Number of Natural Gas Plants Average Plant Capacity (Million Cubic Feet per Day) Change Between 2004 and 2009 State...

  18. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    3. Natural Gas Processing Plants Utilization Rates Based on 2008 Flows Figure 3. Natural Gas Processing Plants Utilization Rates Based on 2008 Flows Note: Average utilization rates...

  19. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5. Natural Gas Processing Plants, Production Basins, and Plays in the Rocky Mountain States and California, 2009 Figure 5. Natural Gas Processing Plants, Production Basins, and...

  20. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    6. Natural Gas Processing Plants, Production Basins, and Plays in the Midwestern and Eastern States, 2009 Figure 6. Natural Gas Processing Plants, Production Basins, and Plays in...

  1. Liquefied U.S. Natural Gas Exports to United Kingdom (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    United Kingdom (Million Cubic Feet) Liquefied U.S. Natural Gas Exports to United Kingdom (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 0 0 0 0 0...

  2. High-volume, high-value usage of Flue Gas Desulfurization (FGD) by-products in underground mines Phase 1: Laboratory investigations. Quarterly report, July 1994--September 1994

    SciTech Connect (OSTI)

    1994-12-01

    During the quarter a second series of samples were collected and partially characterized chemically and mineralogically. The samples were collected at the disposal site operated by Freeman United Coal Co. The second collection was necessary because of deterioration due to hydration of the original samples. A study of the hydration characteristics was completed during the quarter. Important reactions included the immediate formation of ettringite and portlandite. The hydration and transformation was found to be a slow process. A second phase of gypsum formation from ettringite deterioration was identified. The slow hydration of anhydrite with its resultant swell is a potential problem which will be addressed further. Geotechnical characterization, during the quarter included completion of the preliminary characterization, analysis of the findings, experimentation with sample preparation for the final characterization/mix design, and design of the final experimental program. The analysis of the coals collected during the core drilling and hydrologic planning were completed. Also during the quarter a meeting was held with representatives of the shotcrete industry to discuss transport systems for emplacement. The pros and cons of pneumatic and hydraulic systems were discussed and plans formulated for further investigations.

  3. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    4. Natural Gas Processing Plants, Production Basins, and Plays in the Gulf of Mexico States, 2009 Figure 4. Natural Gas Processing Plants, Production Basins, and Plays in the Gulf...

  4. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    States along the Gulf of Mexico. Gulf States have been some of the most prolific natural gas producing areas. U.S. natural gas processing capacity showed a net increase of about 12...

  5. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu; King, David L.; Liu, Jun; Huo, Qisheng

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  6. World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States

    Reports and Publications (EIA)

    2011-01-01

    The Energy Information Administration sponsored Advanced Resources International, Inc., to assess 48 gas shale basins in 32 countries, containing almost 70 shale gas formations. This effort has culminated in the report: World Shale Gas Resources: An Initial Assessment of 14 Regions Outside the United States.

  7. Flue gas desulfurization gypsum and fly ash

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

  8. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of new production basins, including the San Juan Basin, Powder River Basin, and Green River Basin, natural gas processing capacity in this region has expanded...

  9. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    National Overview Btu Content The natural gas received and transported by the major intrastate and interstate mainline transmission systems must be within a specific energy (Btu)...

  10. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  11. A review of water and greenhouse gas impacts of unconventional natural gas development in the United States

    SciTech Connect (OSTI)

    Arent, Doug; Logan, Jeff; Macknick, Jordan; Boyd, William; Medlock , Kenneth; O'Sullivan, Francis; Edmonds, James A.; Clarke, Leon E.; Huntington, Hill; Heath, Garvin; Statwick, Patricia M.; Bazilian, Morgan

    2015-01-01

    This paper reviews recent developments in the production and use of unconventional natural gas in the United States with a focus on water and greenhouse gas emission implications. If unconventional natural gas in the U.S. is produced responsibly, transported and distributed with little leakage, and incorporated into integrated energy systems that are designed for future resiliency, it could play a significant role in realizing a more sustainable energy future; however, the increased use of natural gas as a substitute for more carbon intensive fuels will alone not substantially alter world carbon dioxide concentration projections.

  12. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    has in the past accounted for the majority of natural gas production. Processing plants are especially important in this part of the country because of the amount of NGLs in...

  13. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    which saw a 65 percent drop in processing capacity. At the same time, the number of plants in Kansas decreased by four. The decrease was likely the result of falling natural gas...

  14. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    3. Btu Content at Plant Inlets for Processing Plants in the United States, 2009 Minimum Annual Btu Content Maximum Annual Btu Content Average Annual Btu Content Alaska 850 1071 985...

  15. ,"U.S. Liquefied Natural Gas Imports From The United Arab Emirates...

    U.S. Energy Information Administration (EIA) Indexed Site

    586-8800",,,"01292016 9:45:38 AM" "Back to Contents","Data 1: U.S. Liquefied Natural Gas Imports From The United Arab Emirates (MMcf)" "Sourcekey","N9103UA2" "Date","U.S....

  16. ,"Price of U.S. Liquefied Natural Gas Imports From The United...

    U.S. Energy Information Administration (EIA) Indexed Site

    Contents","Data 1: Price of U.S. Liquefied Natural Gas Imports From The United Arab Emirates (Dollars per Thousand Cubic Feet)" "Sourcekey","N9103UA3" "Date","Price of U.S....

  17. ,"Liquefied U.S. Natural Gas Re-Exports to United Kingdom (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    2016 11:48:54 AM" "Back to Contents","Data 1: Liquefied U.S. Natural Gas Re-Exports to United Kingdom (Million Cubic Feet)" "Sourcekey","NGMEPG0ERENUS-NUKMMCF"...

  18. ,"Liquefied U.S. Natural Gas Re-Exports to United Kingdom (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    2016 11:48:55 AM" "Back to Contents","Data 1: Liquefied U.S. Natural Gas Re-Exports to United Kingdom (Million Cubic Feet)" "Sourcekey","NGMEPG0ERENUS-NUKMMCF"...

  19. Draft Addendum to Environmental Review Documents Concerning Exports of Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    On August 15, 2014, the Department of Energy's Office of Fossil Energy published the final Addendum To Environmental Review Documents Concerning Exports Of Natural Gas From The United States ...

  20. Addendum to Environmental Review Documents Concerning Exports of Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    On August 15, 2014, the Department of Energy's Office of Fossil Energy published the final Addendum To Environmental Review Documents Concerning Exports Of Natural Gas From The United States ...

  1. ,"Price of U.S. Liquefied Natural Gas Imports From The United...

    U.S. Energy Information Administration (EIA) Indexed Site

    "Back to Contents","Data 1: Price of U.S. Liquefied Natural Gas Imports From The United Arab Emirates (Dollars per Thousand Cubic Feet)" "Sourcekey","N9103UA3" "Date","Price of...

  2. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Office of Energy Efficiency and Renewable Energy (EERE)

    This analysis calculates the life cycle greenhouse gas (GHG) emissions for regional coal and imported natural gas power in Europe and Asia. The primary research questions are as follows:...

  3. Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) United Arab Emirates (Million Cubic Feet) Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 0 0 0 0 0 0 0 0 0 0 0 0 2016 0 0 3,391

  4. Price of Liquefied U.S. Natural Gas Exports by Vessel to United Arab

    U.S. Energy Information Administration (EIA) Indexed Site

    Emirates (Dollars per Thousand Cubic Feet) United Arab Emirates (Dollars per Thousand Cubic Feet) Price of Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 -- -- -- -- -- -- -- -- -- -- -- -- 2016 -- -- 4.18 -- -- --

  5. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  6. United States, Canada and Mexico Release the "North American Natural Gas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vision" | Department of Energy and Mexico Release the "North American Natural Gas Vision" United States, Canada and Mexico Release the "North American Natural Gas Vision" February 25, 2005 - 10:29am Addthis WASHINGTON, DC -- The North American Energy Working Group (NAEWG), a group of senior energy officials from Canada, Mexico and the United States, today released the "North American Natural Gas Vision," a trilateral report by the three governments that

  7. Sabine Pass, LA Exports to United kingdom Liquefied Natural Gas (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) United kingdom Liquefied Natural Gas (Million Cubic Feet) Sabine Pass, LA Exports to United kingdom Liquefied Natural Gas (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 2,862 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit Sabine Pass, LA Liquefied

  8. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 8, July--September 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  9. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 9, October--December 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  10. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  11. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 2, January--March 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  12. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  13. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 7, April--June 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  14. Recombinant DNA encoding a desulfurization biocatalyst

    DOE Patents [OSTI]

    Rambosek, J.; Piddington, C.S.; Kovacevich, B.R.; Young, K.D.; Denome, S.A.

    1994-10-18

    This invention relates to a recombinant DNA molecule containing a gene or genes which encode a biocatalyst capable of desulfurizing a fossil fuel which contains organic sulfur molecules. For example, the present invention encompasses a recombinant DNA molecule containing a gene or genes of a strain of Rhodococcus rhodochrous. 13 figs.

  15. Recombinant DNA encoding a desulfurization biocatalyst

    DOE Patents [OSTI]

    Rambosek, John; Piddington, Chris S.; Kovacevich, Brian R.; Young, Kevin D.; Denome, Sylvia A.

    1994-01-01

    This invention relates to a recombinant DNA molecule containing a gene or genes which encode a biocatalyst capable of desulfurizing a fossil fuel which contains organic sulfur molecules. For example, the present invention encompasses a recombinant DNA molecule containing a gene or genes of a strain of Rhodococcus rhodochrous.

  16. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R

    1991-09-01

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  17. Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States

    Broader source: Energy.gov [DOE]

    On May 29, 2014, the Department of Energy’s (DOE) Office of Fossil Energy announced the availability for public review and comment the report Life Cycle Greenhouse Gas Perspective on Exporting...

  18. Price of Liquefied U.S. Natural Gas Exports to United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Dollars per Thousand Cubic Feet) United Arab Emirates (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2010's -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price of Liquefied Natural Gas Exports by Point of Exit U.S. Liquefied Natural Gas Exports to United Arab Emirates

  19. Sabine Pass, LA Liquefied Natural Gas Exports to United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) United Arab Emirates (Million Cubic Feet) Sabine Pass, LA Liquefied Natural Gas Exports to United Arab Emirates (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2016 3,391 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit Sabine Pass, LA Liquefied

  20. Two-stage regeneration of zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-06-28

    The Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE) is interested in the potential of using a two-step process for regenerating the zinc ferrite desulfurization sorbent. In the first regeneration step, a gas mixture consisting of 12 percent SO{sub 2}, 2 percent O{sub 2}, and 86 percent N{sub 2} is used to convert zinc and iron sulfides to their sulfate forms using a sorbent bed inlet temperature of about 850{degrees}F (454{degrees}C). For the second step, the temperature is raised to about 1400{degrees}F (760{degrees}C), and the sulfates are decomposed to oxides with the concurrent release of sulfur dioxide. The same gas composition used for first step is also used for the second step. The proposed technique would require no steam and also has the advantage of producing a regeneration gas rich in sulfur dioxide. In a commercial operation, recirculating regeneration gas would be supplemented with air as required to supply the necessary oxygen. A bleed stream from regeneration (concentrated SO{sub 2} gas in nitrogen) would constitute feed to sulfur recovery.

  1. Use of GTE-65 gas turbine power units in the thermal configuration of steam-gas systems for the refitting of operating thermal electric power plants

    SciTech Connect (OSTI)

    Lebedev, A. S.; Kovalevskii, V. P.; Getmanov, E. A.; Ermaikina, N. A.

    2008-07-15

    Thermal configurations for condensation, district heating, and discharge steam-gas systems (PGU) based on the GTE-65 gas turbine power unit are described. A comparative multivariant analysis of their thermodynamic efficiency is made. Based on some representative examples, it is shown that steam-gas systems with the GTE-65 and boiler-utilizer units can be effectively used and installed in existing main buildings during technical refitting of operating thermal electric power plants.

  2. Trace desulfurization. [DOE patent application

    DOE Patents [OSTI]

    Chen, H.L.; Stevens, C.G.

    A method for reducing a trace concentration of sulfur-containing compounds in a gas stream from about one part in 10/sup 4/ to about one part in 10/sup 7/. The method includes the steps of irradiating the gas stream with an energy source which has a central emission frequency chosen to substantially match a wavelength of energy absorption of the sulfur-containing compounds and of subsequently contacting the gas stream with a reactive surface which includes a reactant selected from elemental metals and metal oxides so that metallic sulfur-containing compounds are formed. The reduction in concentration allows the gas stream to be processed in certain reactions having catalysts which would otherwise be poisoned by the sulfur-containing compounds.

  3. J.K. Spruce power plant, Unit 1, San Antonio, Texas

    SciTech Connect (OSTI)

    Peltier, R.

    2008-10-15

    CPS Energy's J.K. Spruce power plant, Unit 1 was recently recognised by the EUCG Fossil Productivity Committee as the best performer in the large coal plant category over the 2002-2006 evaluation period. The competition was tough, with more than 80 plants in the running, but Unit 1 emerged as the clear winner by earning top points for high plant reliability and very low nonfuel O & M costs. It meets its environmental goals when burning PRB coal in its tangentially fired furnace with recently upgraded low NOx burners, overfire air and a new combustion control system. A baghouse and wet flue gas desulfurization system clean up combustion products. 3 photos.

  4. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  5. Liquefied U.S. Natural Gas Exports to United Arab Emirates (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Arab Emirates (Million Cubic Feet) Liquefied U.S. Natural Gas Exports to United Arab Emirates (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 0 0 0 0 0 0 0 0 0 0 0 0 2016 0 0 3,391 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Liquefied Natural Gas Exports by Point of Exit U.S. Liquefied Natural

  6. Price Liquefied Freeport, TX Natural Gas Exports Price to United Kingdom

    U.S. Energy Information Administration (EIA) Indexed Site

    (Dollars per Thousand Cubic Feet) United Kingdom (Dollars per Thousand Cubic Feet) Price Liquefied Freeport, TX Natural Gas Exports Price to United Kingdom (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2000's -- -- -- 2010's 7.56 -- -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring

  7. Price of Lake Charles, LA Natural Gas LNG Imports from United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Dollars per Thousand Cubic Feet) United Arab Emirates (Dollars per Thousand Cubic Feet) Price of Lake Charles, LA Natural Gas LNG Imports from United Arab Emirates (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 3.03 2000's 3.53 NA NA - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring

  8. Price of Sabine Pass, LA Liquefied Natural Gas Exports to United Arab

    U.S. Energy Information Administration (EIA) Indexed Site

    Emirates (Dollars per Thousand Cubic Feet) United Arab Emirates (Dollars per Thousand Cubic Feet) Price of Sabine Pass, LA Liquefied Natural Gas Exports to United Arab Emirates (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2016 4 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring Pages: U.S. Price of Liquefied

  9. Price of Liquefied U.S. Natural Gas Exports to United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Dollars per Thousand Cubic Feet) Arab Emirates (Dollars per Thousand Cubic Feet) Price of Liquefied U.S. Natural Gas Exports to United Arab Emirates (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 -- -- -- -- -- -- -- -- -- -- -- -- 2016 -- -- 4.18 -- -- -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 08/31/2016 Next Release Date: 09/30/2016 Referring

  10. Natural gas resource data base for the United States (1987). Final report, June-December 1987

    SciTech Connect (OSTI)

    Kent, H.C.; Finney, J.J.

    1988-02-01

    This data base gives a detailed summary of the estimated potential resources of natural gas in the United States, including postulated depth distributions, field sizes, well recoveries and success rates. The study (an expansion on the 1986 resource estimates of the Potential Gas Committee) analyzed the distribution and characteristics of the resource potential estimated to occur in the onshore geologic provinces of the lower 48 states, as well as the resources beneath the continental shelf and slope offshore from Louisiana and Texas. The areas that hold the greatest potential for future natural gas exploration and development include the Atlantic, Gulf Coast, Mid-Continent and Rocky Mountain areas, which contain approximately 92% of the estimated undiscovered resources. The results of the study are intended to be used to assist in making cost determinations which can be utilized in the development of supply models and in planning.

  11. Table 1. Summary statistics for natural gas in the United States, 2010-2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1. Summary statistics for natural gas in the United States, 2010-2014 See footnotes at end of table. Number of Wells Producing at End of Year 487,627 514,637 482,822 R 484,994 514,786 Production (million cubic feet) Gross Withdrawals From Gas Wells 13,247,498 12,291,070 12,504,227 R 10,759,545 10,384,119 From Oil Wells 5,834,703 5,907,919 4,965,833 R 5,404,699 5,922,088 From Coalbed Wells 1,916,762 1,779,055 1,539,395 R 1,425,783 1,285,189 From Shale Gas Wells 5,817,122 8,500,983

  12. Method for the desulfurization of hot product gases from coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1988-01-01

    The gasification of sulfur-bearing coal produces a synthesis gas which contains a considerable concentration of sulfur compounds especially hydrogen sulfide that renders the synthesis gas environmentally unacceptable unless the concentration of the sulfur compounds is significantly reduced. To provide for such a reduction in the sulfur compounds a calcium compound is added to the gasifier with the coal to provide some sulfur absorption. The synthesis gas from the gasifier contains sulfur compounds and is passed through an external bed of a regenerable solid absorbent, preferably zinc ferrite, for essentially completed desulfurizing the hot synthesis gas. This absorbent is, in turn, periodically or continuously regenerated by passing a mixture of steam and air or oxygen through the bed for converting absorbed hydrogen sulfide to sulfur dioxide. The resulting tail gas containing sulfur dioxide and steam is injected into the gasifier where the sulfur dioxide is converted by the calcium compound into a stable form of sulfur such as calcium sulfate.

  13. Federal Register Notice for Addendum to Environmental Review Documents Concerning Exports of Natural Gas from the United States

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) announces the availability of the Addendum To Environmental Review Documents Concerning Exports Of Natural Gas From The United...

  14. Hot-Gas Filter Testing with a Transport Reactor Development Unit

    SciTech Connect (OSTI)

    Swanson, M.L.; Ness, R.O., Jr.

    1996-12-31

    The objective of the hot-gas cleanup (HGC) work on the transport reactor demonstration unit (TRDU) located at the Environmental Research Center is to demonstrate acceptable performance of hot-gas filter elements in a pilot-scale system prior to long-term demonstration tests. The primary focus of the experimental effort in the 2-year project will be the testing of hot- gas filter elements as a function of particulate collection efficiency, filter pressure differential, filter cleanability, and durability during relatively short-term operation (100-200 hours). A filter vessel will be used in combination with the TRDU to evaluate the performance of selected hot- gas filter elements under gasification operating conditions. This work will directly support the Power Systems Development Facility utilizing the M.W. Kellogg transport reactor located at Wilsonville, Alabama and indirectly the Foster Wheeler advanced pressurized fluid-bed combustor, also located at Wilsonville and the Clean Coal IV Pinon Pine IGCC Power Project. This program has a phased approach involving modification and upgrades to the TRDU and the fabrication, assembly, and operation of a hot-gas filter vessel (HGFV) capable of operating at the outlet design conditions of the TRDU. Phase 1 upgraded the TRDU based upon past operating experiences. Additions included a nitrogen supply system upgrade, upgraded LASH auger and 1807 coal feed lines, the addition of a second pressurized coal feed hopper and a dipleg ash hopper, and modifications to spoil the performance of the primary cyclone. Phase 2 included the HGFV design, procurement, and installation. Phases 3 through 5 consist of 200-hour hot-gas filter tests under gasification conditions using the TRDU at temperatures of 540-650{degrees}C (1000-1200{degrees}F), 9.3 bar, and face velocities of 1.4, 2. and 3.8 cm/s, respectively. The increased face velocities are achieved by removing candles between each test.

  15. Application of commercial simulator to reproduce a real natural gas processing unit

    SciTech Connect (OSTI)

    Gomes, L.G.; Maciel, M.R.W.

    1996-12-31

    In this work the intention is, using a commercial simulator, to reproduce the operating conditions of a Natural Gas Processing Unit. This is a complex task since in a real plant there are several kinds of equipments, accessories and designs that the most important available simulators cannot represent properly. This being the case, in this study, the simulation has been built in a unique computer file, simulating 48 equipments and 16 valves of the process unit. It was created five additional equipments and some adjust, recycle and set operations to adjust the simulator equipments to the real ones. The simulations has 84 operations and 116 streams of mass and energy. To bring near the column internal flows and temperatures to the real values, it were incorporated the column stage efficiencies, using a method, beginning with O`Connell global efficiency. 7 refs., 4 tabs.

  16. Corrective action decision document, Second Gas Station, Tonopah test range, Nevada (Corrective Action Unit No. 403)

    SciTech Connect (OSTI)

    1997-11-01

    This Corrective Action Decision Document (CADD) for Second Gas Station (Corrective Action Unit [CAU] No. 403) has been developed for the U.S. Department of Energy`s (DOE) Nevada Environmental Restoration Project to meet the requirements of the Federal Facility Agreement and Consent Order (FFACO) of 1996 as stated in Appendix VI, {open_quotes}Corrective Action Strategy{close_quotes} (FFACO, 1996). The Second Gas Station Corrective Action Site (CAS) No. 03-02-004-0360 is the only CAS in CAU No. 403. The Second Gas Station CAS is located within Area 3 of the Tonopah Test Range (TTR), west of the Main Road at the location of former Underground Storage Tanks (USTs) and their associated fuel dispensary stations. The TTR is approximately 225 kilometers (km) (140 miles [mi]) northwest of Las Vegas, Nevada, by air and approximately 56 km (35 mi) southeast of Tonopah, Nevada, by road. The TTR is bordered on the south, east, and west by the Nellis Air Force Range and on the north by sparsely populated public land administered by the Bureau of Land Management and the U.S. Forest Service. The Second Gas Station CAS was formerly known as the Underground Diesel Tank Site, Sandia Environmental Restoration Site Number 118. The gas station was in use from approximately 1965 to 1980. The USTs were originally thought to be located 11 meters (m) (36 feet [ft]) east of the Old Light Duty Shop, Building 0360, and consisted of one gasoline UST (southern tank) and one diesel UST (northern tank) (DOE/NV, 1996a). The two associated fuel dispensary stations were located northeast (diesel) and southeast (gasoline) of Building 0360 (CAU 423). Presently the site is used as a parking lot, Building 0360 is used for mechanical repairs of vehicles.

  17. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization...

    Office of Scientific and Technical Information (OSTI)

    in a Fixed-Bed Reactor Citation Details In-Document Search Title: Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor You are ...

  18. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1991-06-01

    Advanced integrated gasification combined cycle (IGCC) power systems require the development of high-temperature desulfurization sorbents capable of removing hydrogen sulfide from coal gasifier down to very low levels. The objective of this investigation was to identify and demonstrate methods for enhancing the long-term chemical reactivity and mechanical strength of zinc ferrite, a leading regenerable sorbent, for fluidized-bed applications. Fluidized sorbent beds offer significant potential in IGCC systems because of their ability to control the highly exothermic regeneration involved. However, fluidized beds require a durable, attrition-resistant sorbent in the 100--300 {mu}m size range. A bench-scale high-temperature, high- pressure (HTHP) fluidized-bed reactor (7.6-cm I.D.) system capable of operating up to 24 atm and 800{degree}C was designed, built and tested. A total of 175 sulfidation-regeneration cycles were carried out using KRW-type coal gas with various zinc ferrite formulations. A number of sorbent manufacturing techniques including spray drying, impregnation, crushing and screening, and granulation were investigated. While fluidizable sorbents prepared by crushing durable pellets and screening had acceptable sulfur capacity, they underwent excessive attrition during multicycle testing. The sorbent formulations prepared by a proprietary technique were found to have excellent attrition resistance and acceptable chemical reactivity during multicycle testing. However, zinc ferrite was found to be limited to 550{degree}C, beyond which excessive sorbent weakening due to chemical transformations, e.g., iron oxide reduction, was observed.

  19. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 4, July--September 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  20. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect (OSTI)

    Sublette, K.L.

    1992-12-31

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  1. New Claus tail-gas process proved in German operation

    SciTech Connect (OSTI)

    Kettner, R.; Liermann, N.

    1988-01-11

    A process for removing sulfur components from Claus-plant tail gases increases sulfur-recovery rates to 99.5%. It has been in use for more than 4 years. In December 1983, a tail-gas cleaning unit was started up for the sulfur-recovery plants of the Nordeutsche Erdgas Aufbereitungsgesellschaft (NEAG) natural-gas treating complex at Voigten, West Germany. NEAG, a joint venture of Exxon, Shell, and Mobil Oil, desulfurizes 7.7 million normal cu m/day (approximately 271.2 million cfd) of sour gas in three plants. Up to 1,050 tons/day of elemental sulfur are produced (Fig. 1). Mobil Oil AG developed the process which has been dubbed the Mobil direct-oxidation process (Modop).

  2. Management of dry flue gas desulfurization by-products in underground mines. The development and testing of collapsible intermodal containers for the handling and transport of coal combustion residues

    SciTech Connect (OSTI)

    Carpenter, J.L.; Thomasson, E.M.

    1995-07-01

    SEEC, Incorporated, is developing a collapsible intermodal container (CIC{trademark}) designed for containment and transport of fly ash and other dry-flowable bulk commodities. The CIC is specially configured to ride in open top rail cars, but as an intermodal container, it also rides in barges and on flat bed trailers. This allows SEEC to use unit coal train back haul capacity to transport fly ash to markets at and near coal mines. SEEC`s goals for this project were to design a CIC for handling and transporting dry fly ash, and then demonstrate the CIC technology. During this project, SEEC has performed extensive initial design work, leading to the manufacture of three prototype CICs for demonstration. Preliminary tests to examine safety issues included finite element analyses and an overload test in which the CIC was lifted while carrying weight in excess of its rated capacity. In both cases, the CIC met all safety requirements. With the above information satisfying possible safety concerns in hand, SEEC worked with SIU and other cooperators to plan and carry out field demonstration and testing of three CICs. This demonstration/testing including filling the CICs with fly ash, transporting them in a coal hopper car, handling with standard intermodal equipment, and emptying by inverting (two CICs) and by vacuuming (one CIC). Results were very positive. Filling with fly ash, transporting, and intermodal handling went very well, as did emptying by vacuum. Emptying by inverting was less successful, but most of the problems were predicted ahead of time, and were mostly due to lack of fly ash fluidizing equipment as much as anything. Throughout the testing, valuable information was gathered that will greatly accelerate refinement of both the CIC and the system of CIC handling.

  3. Optimal integrated design of air separation unit and gas turbine block for IGCC systems

    SciTech Connect (OSTI)

    Kamath, R.; Grossman, I.; Biegler, L.; Zitney, S.

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  4. Optimal Integrated Design of Air Separation Unit and Gas Turbine Block for IGCC Systems

    SciTech Connect (OSTI)

    Ravindra S. Kamath; Ignacio E. Grossmann; Lorenz T. Biegler; Stephen E. Zitney

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  5. A 50-month gasifier mechanistic study and downstream unit process development program for the pressurized ash-agglomerating fluidized-bed gasification system

    SciTech Connect (OSTI)

    Haldipur, G.B.; Schmidt, D.K.; Smith, K.J.

    1989-03-01

    This technology development program scope included studies of those processes and components necessary to convert coal, oxidant and steam into a clean fuel gas. The configuration of the processes and components constitutes a Gasifier Island which is a key concept in the application of the KRW gasification and cleanup technologies. This Gasifier Island typically consists of process units that perform the following functions: feedstock preparation, gasification, desulfurization, heat recovery, particulate removal, and solid waste treatment. The processing has been conducted in a variety of gasifier operating modes including air-blown and oxygen-blown, both with and without in-bed desulfurization which includes injection of limestone or dolomite sorbent. Process configurations downstream of the gasifier have included recycle and non-recycle cyclones, sintered filters, and zinc ferrite fixed beds. Because of the developmental nature of the KRW technology program and the flexibility of the pilot plant itself, a wide range of gasifier-cleanup process configurations has been investigated. The KRW pilot plant program evaluated a system comprised of the following major process elements: gasifier and in-bed desulfurizer, particulate cleanup train, external sulfur polishing bed, and solid waste disposal system.

  6. Natural Gas Methane Emissions in the United States Greenhouse Gas Inventory: Sources, Uncertainties and Opportunities for Improvement

    SciTech Connect (OSTI)

    Heath, Garvin; Warner, Ethan; Steinberg, Daniel; Brandt, Adam

    2015-11-19

    Presentation summarizing key findings of a Joint Institute for Strategic Energy Analysis Report at an Environmental Protection Agency workshop: 'Stakeholder Workshop on EPA GHG Data on Petroleum and Natural Gas Systems' on November 19, 2015. For additional information see the JISEA report, 'Estimating U.S. Methane Emissions from the Natural Gas Supply Chain: Approaches, Uncertainties, Current Estimates, and Future Studies' NREL/TP-6A50-62820.

  7. Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates

    U.S. Energy Information Administration (EIA) Indexed Site

    (Million Cubic Feet) United Arab Emirates (Million Cubic Feet

  8. Price of Liquefied U.S. Natural Gas Exports by Vessel to United Arab

    U.S. Energy Information Administration (EIA) Indexed Site

    Emirates (Dollars per Thousand Cubic Feet) United Arab Emirates (Dollars per

  9. Oil and Gas Development in the United States in the Early 1990's

    Reports and Publications (EIA)

    1995-01-01

    An analysis of the growing prominence of smaller energy companies in U.S. oil and natural gas production.

  10. United States Producing and Nonproducing Crude Oil and Natural Gas Reserves From 1985 Through 2004

    Reports and Publications (EIA)

    2006-01-01

    This report discusses the regional and temporal trends in producing and nonproducing crude oil and natural gas reserves using the Energy Information Administration's (EIA) categorization of reserves. The report first focuses on EIA's collection and reporting of crude oil and natural gas reserves data, followed by a discussion of the natural gas reserve trends, and then the crude oil reserve trends.

  11. Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide

    DOE Patents [OSTI]

    Poston, James A.

    1997-01-01

    Mixed metal oxide pellets for removing hydrogen sulfide from fuel gas mixes derived from coal are stabilized for operation over repeated cycles of desulfurization and regeneration reactions by addition of a large promoter metal oxide such as lanthanum trioxide. The pellets, which may be principally made up of a mixed metal oxide such as zinc titanate, exhibit physical stability and lack of spalling or decrepitation over repeated cycles without loss of reactivity. The lanthanum oxide is mixed with pellet-forming components in an amount of 1 to 10 weight percent.

  12. Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide

    DOE Patents [OSTI]

    Poston, J.A.

    1997-12-02

    Mixed metal oxide pellets for removing hydrogen sulfide from fuel gas mixes derived from coal are stabilized for operation over repeated cycles of desulfurization and regeneration reactions by addition of a large promoter metal oxide such as lanthanum trioxide. The pellets, which may be principally made up of a mixed metal oxide such as zinc titanate, exhibit physical stability and lack of spalling or decrepitation over repeated cycles without loss of reactivity. The lanthanum oxide is mixed with pellet-forming components in an amount of 1 to 10 weight percent.

  13. ,"Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates (Million Cubic Feet)"

    U.S. Energy Information Administration (EIA) Indexed Site

    United Arab Emirates (Million Cubic Feet)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Liquefied U.S. Natural Gas Exports by Vessel to United Arab Emirates (Million Cubic Feet)",1,"Monthly","6/2016" ,"Release Date:","08/31/2016" ,"Next Release

  14. Solvent-refined-coal (SRC) process. Determination of trace hydrocarbon, sulfur, and nitrogen compounds in SRC-II process development Unit P-99 gas streams. [Impure hydrogen in recycle gas and low pressure gas processing

    SciTech Connect (OSTI)

    Gray, J.A.; Galli, R.D.; McCracken, J.H.

    1982-02-01

    A knowledge of the identity and concentration of trace hydrocarbon, sulfur, and nitrogen compounds in the various gas streams of the SRC-II Coal Liquefaction Process is needed in order to design the recycle gas purification and low pressure gas processing systems in large-scale plants. This report discusses the results of an experimental study to identify and quantify trace compounds in the various high and low pressure gas streams of SRC-II Process Development Unit P-99. A capillary column trace hydrocarbon analysis has been developed which can quantify 41 hydrocarbons from methane to xylenes in SRC-II gas streams. With more work a number of other hydrocarbons could be quantified. A fixed gas analysis was also developed which can be integrated with the hydrocarbon analysis to yield a complete stream analysis. A gas chromatographic procedure using a flame photometric detector was developed for trace sulfur compounds, and six sulfur compounds were identified and quantified. A chemiluminescence method was developed for determination of NO and NO/sub 2/ down to 10 ppB in concentration. A gas chromatographic procedure using an electron capture detector was developed for HCN analysis down to 5 ppM. Drager tube analyses gave semiquantitative data on HCl and NH/sub 3/ content of the gas streams.

  15. Sour landfill gas problem solved

    SciTech Connect (OSTI)

    Nagl, G.; Cantrall, R.

    1996-05-01

    In Broward County, Fla., near Pompano Beach, Waste Management of North America (WMNA, a subsidiary of WMX Technologies, Oak Brook, IL) operates the Central Sanitary Landfill and Recycling Center, which includes the country`s largest landfill gas-to-energy plant. The landfill consists of three collection sites: one site is closed, one is currently receiving garbage, and one will open in the future. Approximately 9 million standard cubic feet (scf) per day of landfill gas is collected from approximately 300 wells spread over the 250-acre landfill. With a dramatic increase of sulfur-containing waste coming to a South Florida landfill following Hurricane Andrew, odors related to hydrogen sulfide became a serious problem. However, in a matter of weeks, an innovative desulfurization unit helped calm the landfill operator`s fears. These very high H{sub 2}S concentrations caused severe odor problems in the surrounding residential area, corrosion problems in the compressors, and sulfur dioxide (SO{sub 2}) emission problems in the exhaust gas from the turbine generators.

  16. Severe gas bubble disease in a warmwater fishery in the midwestern United States

    SciTech Connect (OSTI)

    Crunkilton, R.L.; Czarnezki, J.M.; Trial, L.

    1980-11-01

    Gas bubble disease below Harry S. Truman Dam, sited on the upper Osage River and spilling into Lake of the Ozarks, caused the largest fish kill on record in Missouri. This is the first recorded evidence of serious supersaturation in the Midwest. Total gas saturation levels up to 139% killed nearly a half million fish in the upper 85 km of the Osage Arm, Lake of the Ozarks, during April to June, 1978 and 1979. Gas supersaturation occurred throughout the 150 km of this main-stem reservoir. Nitrogen was the primary gas responsible for gas bubble disease mortalities. Pelagic and near-shore species suffered the earliest and heaviest mortalities, but fish characteristic of deeper waters were increasingly killed as supersaturation persisted. Instream cage bioassays defined the zone of lethal supersaturation. Significant mortality occurred in bottom-dwelling fish of several species, due to long-term intermittent exposure. Susceptibility to gas bubble disease was related to fish size.

  17. Addendum To Environmental Review Documents Concerning Exports Of Natural Gas From The United States

    Broader source: Energy.gov [DOE]

    The purpose of the Addendum is to provide additional information to the public regarding the potential environmental impacts of unconventional natural gas exploration and production activities. DOE...

  18. Estimate of Maximum Underground Working Gas Storage Capacity in the United States: 2007 Update

    Reports and Publications (EIA)

    2007-01-01

    This report provides an update to an estimate for U.S. aggregate natural gas storage capacity that was released in 2006.

  19. Table B1. Summary statistics for natural gas in the United States, metric equivalents, 2010-2014

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Table B1. Summary statistics for natural gas in the United States, metric equivalents, 2010-2014 See footnotes at end of table. Number of Wells Producing at End of Year 487,627 514,637 482,822 R 484,994 514,786 Production (million cubic meters) Gross Withdrawals From Gas Wells 375,127 348,044 354,080 R 304,676 294,045 From Oil Wells 165,220 167,294 140,617 R 153,044 167,695 From Coalbed Wells 54,277 50,377 43,591 R 40,374 36,392 From Shale Gas Wells 164,723 240,721 298,257 R 337,891 389,474

  20. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  1. Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

    2006-05-01

    Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

  2. Penetration of gas delivery systems in the United States: A state-level data analysis

    SciTech Connect (OSTI)

    Guldmann, J.M. . Environmental Assessment and Information Sciences Div. Ohio State Univ., Columbus, OH )

    1990-02-01

    The purpose of this study is to assess the degree to which the gas delivery infrastructure penetrates US regions and states and to pinpoint those areas in which the lack of a sufficient infrastructure impedes the expansion of the natural gas market. Regions and states are ranked according to several indicators developed with data published by the American Gas Association, the US Department of Energy/Energy Information Administration, and the US Bureau of the Census. These include the numbers of gas customers and gas deliveries by sector, mileages of distribution and transmission pipelines, underground storage capacities and operating characteristics, heating degree-days, populations and numbers of households, and areal measures of states and metropolitan areas. The market penetration of gas distribution systems is measured by two indicators: (1) the ratio of the number of residential gas customers to the number of households in 1985 and (2) the distribution pipeline density, measured by the ratio of the 1985 distribution mileage divided by the number of households, while accounting for the effect of urban population density (using earlier econometric results). 11 refs., 1 fig., 27 tabs.

  3. Severe gas bubble disease in a warmwater fishery in the midwestern united states

    SciTech Connect (OSTI)

    Crunkilton, R.L.; Czarnezki, J.M.; Trial, L.

    1980-11-01

    Supersaturation of the water of the Osage River below the Harry S. Truman Dam resulted in an epidemic of gas bubble disease that caused the largest fish kill in the history of Missouri. This is the first recorded evidence of serious supersaturation in the midwestern U.S. Total gas saturation levels up to 139% killed nearly 500,000 fish in the Osage River and the Lake of the Ozarks during April-May 1978. Nitrogen was the primary gas responsible for gas bubble disease mortalities. Instream cage bioassays defined the zone of lethal supersaturation. Significant mortality occurred in pelagic and near-shore species, deepwater species, and bottom-dwelling species. Susceptibility to disease was related to fish size.

  4. Process for demetallizing and desulfurizing heavy crude oil

    SciTech Connect (OSTI)

    Brown, R.E.; Hogan, R.J.; Combs, D.M.; Kukes, S.G.

    1989-12-05

    This patent describes a process for producing a synthetic crude oil of improved properties by desulfurizing, denitrogenating and demetallizing a heavy crude oil feed stock. The feed stock being a crude oil having an average boiling point at least as high as 500{degrees} F., an API gravity at 60{degrees} F. of less than 20, and containing at least about 1 weight percent sulfur.

  5. Gas hydrates on the Atlantic Continental Margin of the United States - controls on concentration

    SciTech Connect (OSTI)

    Dillon, W.P.; Fehlhaber, K.; Coleman, D.F. ); Lee, M.W. )

    1993-01-01

    Large volumes of gas hydrates exist within ocean-floor deposits at water depths exceeding about 300 to 500 m. They cement a surface layer of sediments as much as about 1,000 m thick, limited at its base by increasing temperature. Gas hydrates are identified by drilled samples and by their characteristic responses in seismic reflection profiles. These seismic responses include, at the base of the hydrate-cemented surface layer, a marked velocity decrease and a sea-floor-paralleling reflection (known as the bottom-simulating reflection, or BSR), and, within the hydrate-cemented layer, a reduction in amplitude of seismic reflections (known as blanking), which is apparently caused by cementation of strata. By using seismic-reflection data we have mapped the volume of hydrate and thickness of the hydrate-cemented layer off the US East Coast. The sources of gas at these concentrations are probably bacterial generation of methane at the locations of rapid deposition, and possibly the migration of deep, thermogenic gap up faults near diapirs. The thickness of the gas-hydrate layer decreases markedly at landslide scars, possibly due to break-down of hydrate resulting from pressure reduction caused by removal of sediment by the slide. Gas traps appear to exist where a seal is formed by the gas-hydrate-cemented layer. Such traps are observed (1) where the sea floor forms a dome, and therefore the bottom-paralleling, hydrate-cemented layer also forms a dome; (2) above diapirs, where the greater thermal conductivity of salt creates a warm spot and salt ions act as antifreeze, both effects resulting in a local shallowing of the base of the hydrate; and (3) at locations where strata dip relative to the sea floor, and the updip regions of porous strata are sealed by the gas-hydrate-cemented layer to form a trap. In such situations the gas in the hydrate-sealed trap, as well as the gas that forms the hydrate, may become a resource. 32 refs., 19 figs.

  6. Estimate of Maximum Underground Working Gas Storage Capacity in the United States

    Reports and Publications (EIA)

    2006-01-01

    This report examines the aggregate maximum capacity for U.S. natural gas storage. Although the concept of maximum capacity seems quite straightforward, there are numerous issues that preclude the determination of a definitive maximum volume. The report presents three alternative estimates for maximum capacity, indicating appropriate caveats for each.

  7. China develops natural gas industry

    SciTech Connect (OSTI)

    An, Z.

    1982-09-06

    As of 1981, China was producing some 474.4 billion CF (12.74 billion m/sup 3/)/yr of natural gas from over 60 gas fields, 40 of them in Sichuan Province. The Sichuan gas lies in fractures and solution cavities in limestone and dolomite formations that generally require stimulation. After desulfurization, the gas is used by the steel and chemical industries and for residential heating. Recent discoveries in other areas of China include the Guxinzhuang field in the Bohai-North China basin, where geological conditions favor large gas pools, and the Sebei fields in Qaidam basin, northwest China.

  8. Repowering with pressurized fluidized-bed combustion units

    SciTech Connect (OSTI)

    Goidich, S.J. ); Rubow, L.N. ); Kumar, S. . Environmental Services and Technologies Div.); Mukherjee, D. ); Childress, N.B. )

    1991-05-01

    Turbocharged pressurized fluidized bed combustion (PFBC) power plants operating with a gas turbine inlet temperature lower than 800{degrees}F can produce electricity more efficiently (34.2 vs. 33.5% net plant efficiency) and at a lower cost of electricity (87.8 vs. 96. 6 mill/kWh over 30 years) than conventional pulverized-coal-fired plants with scrubbers. Since the PFBC process produces lower NO{sub x} emissions than conventional pulverized-coal combustion systems and captures sulfur as part of the combustion process, and since major equipment components can be shop-assembled and shipped by barge, retrofit of an existing unit with a turbocharged PFBC boiler can be a cost-effective means for extending the life of the unit and meeting NSPS without retrofitting flue gas desulfurization systems. Using the Wisconsin Electric Power Company's Port Washington Unit 5 as an example, preliminary engineering and economic evaluations were made to investigate the merits of turbocharged PFBC retrofits. This report describes the conceptual designs of the new, major plant components; discusses how the new components are integrated with the existing balance-of-plant equipment; describes the proposed plant control system; and presents an overall economic evaluation. Because design and economic evaluations were prepared on the basis of a commercial design, first-of-a-kind costs and test programs are not included. 5 refs., 58 figs., 55 tabs.

  9. U.S. Liquefied Natural Gas Exports to United Arab Emirates

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Exports to Spain (Million Cubic Feet) U.S. Liquefied Natural Gas Exports to Spain (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2010 0 3,149 0 0 0 0 0 0 0 0 968 0 2011 3,007 0 0 2,911 0 0 0 0 0 0 0 0 2015 0 0 0 0 0 0 0 0 0 0 0 0 2016 0 0 0 0 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 07/29/2016 Next Release Date: 08/31/2016 Referring Pages: U.S. Liquefied Natural Gas

  10. Coal desulfurization in a rotary kiln combustor

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  11. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    SciTech Connect (OSTI)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.; Oshinuga, A.; Miyasato, M.; Lucht, E.; van der Merwe, D.; Schaberg, P.

    2010-05-01

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimes almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.

  12. Fuel Summary for Peach Bottom Unit 1 High-Temperature Gas-Cooled Reactor Cores 1 and 2

    SciTech Connect (OSTI)

    Karel I. Kingrey

    2003-04-01

    This fuel summary report contains background and summary information for the Peach Bottom Unit 1, High-Temperature, Gas-Cooled Reactor Cores 1 and 2. This report contains detailed information about the fuel in the two cores, the Peach Bottom Unit 1 operating history, nuclear parameters, physical and chemical characteristics, and shipping and storage canister related data. The data in this document have been compiled from a large number of sources and are not qualified beyond the qualification of the source documents. This report is intended to provide an overview of the existing data pertaining to spent fuel management and point to pertinent reference source documents. For design applications, the original source documentation must be used. While all referenced sources are available as records or controlled documents at the Idaho National Engineering and Environmental Laboratory (INEEL), some of the sources were marked as informal or draft reports. This is noted where applicable. In some instances, source documents are not consistent. Where they are known, this document identifies those instances and provides clarification where possible. However, as stated above, this document has not been independently qualified and such clarifications are only included for information purposes. Some of the information in this summary is available in multiple source documents. An effort has been made to clearly identify at least one record document as the source for the information included in this report.

  13. Steam Generator Component Model in a Combined Cycle of Power Conversion Unit for Very High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Oh, Chang H; Han, James; Barner, Robert; Sherman, Steven R

    2007-06-01

    The Department of Energy and the Idaho National Laboratory are developing a Next Generation Nuclear Plant (NGNP), Very High Temperature Gas-Cooled Reactor (VHTR) to serve as a demonstration of state-of-the-art nuclear technology. The purpose of the demonstration is two fold 1) efficient low cost energy generation and 2) hydrogen production. Although a next generation plant could be developed as a single-purpose facility, early designs are expected to be dual-purpose. While hydrogen production and advanced energy cycles are still in its early stages of development, research towards coupling a high temperature reactor, electrical generation and hydrogen production is under way. A combined cycle is considered as one of the power conversion units to be coupled to the very high-temperature gas-cooled reactor (VHTR). The combined cycle configuration consists of a Brayton top cycle coupled to a Rankine bottoming cycle by means of a steam generator. A detailed sizing and pressure drop model of a steam generator is not available in the HYSYS processes code. Therefore a four region model was developed for implementation into HYSYS. The focus of this study was the validation of a HYSYS steam generator model of two phase flow correlations. The correlations calculated the size and heat exchange of the steam generator. To assess the model, those calculations were input into a RELAP5 model and its results were compared with HYSYS results. The comparison showed many differences in parameters such as the heat transfer coefficients and revealed the different methods used by the codes. Despite differences in approach, the overall results of heat transfer were in good agreement.

  14. Advancing strategic environmental assessment in the offshore oil and gas sector: Lessons from Norway, Canada, and the United Kingdom

    SciTech Connect (OSTI)

    Fidler, Courtney; Noble, Bram

    2012-04-15

    Abstract: Strategic environmental assessment (SEA) for offshore oil and gas planning and development is utilized in select international jurisdictions, but the sector has received limited attention in the SEA literature. While the potential benefits of and rationale for SEA are well argued, there have been few empirical studies of SEA processes for the offshore sector. Hence, little is known about the efficacy of SEA offshore, in particular its influence on planning and development decisions. This paper examines SEA practice and influence in three international offshore systems: Norway, Atlantic Canada and the United Kingdom, with the intent to identify the challenges, lessons and opportunities for advancing SEA in offshore planning and impact assessment. Results demonstrate that SEA can help inform and improve the efficacy and efficiency of project-based assessment in the offshore sector, however weak coordination between higher and lower tiers limit SEA's ability to influence planning and development decisions in a broad regional environmental and socioeconomic context. - Highlights: Black-Right-Pointing-Pointer SEA can inform and improve the efficacy and efficiency of project EA offshore Black-Right-Pointing-Pointer Scope and deliverables of SEA offshore often differ from stakeholder expectations Black-Right-Pointing-Pointer Considerable variability in influence of SEA output beyond licensing decisions Black-Right-Pointing-Pointer Sector-based SEA offshore is often too restrictive to generate expected benefits.

  15. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; et al

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richnessmore » in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.« less

  16. Benefits of Greenhouse Gas Mitigation on the Supply, Management, and Use of Water Resources in the United States

    SciTech Connect (OSTI)

    Strzepek, K.; Neumann, Jim; Smith, Joel; Martinich, Jeremy; Boehlert, Brent; Hejazi, Mohamad I.; Henderson, Jim; Wobus, Cameron; Jones, Russ; Calvin, Katherine V.; Johnson, D.; Monier, Erwan; Strzepek, J.; Yoon, Jin-Ho

    2014-11-29

    Climate change impacts on water resources in the U.S. are likely to be far-reaching and substantial, because the water sector spans many parts of the economy, from supply and demand for agriculture, industry, energy production, transportation and municipal use to damages from natural hazards. This paper provides impact and damage estimates from five water resource-related models in the CIRA frame work, addressing drought risk, flooding damages, water supply and demand, and global water scarcity. The four models differ in the water system assessed, their spatial scale, and the units of assessment, but together they provide a quantitative and descriptive richness in characterizing water resource sector effects of climate change that no single model can capture. The results also address the sensitivity of these estimates to greenhouse gas emission scenarios, climate sensitivity alternatives, and global climate model selection. While calculating the net impact of climate change on the water sector as a whole may be impractical, because each of the models applied here uses a consistent set of climate scenarios, broad conclusions can be drawn regarding the patterns of change and the benefits of GHG mitigation policies for the water sector. Two key findings emerge: 1) climate mitigation policy substantially reduces the impact of climate change on the water sector across multiple dimensions; and 2) the more managed the water resources system, the more tempered the climate change impacts and the resulting reduction of impacts from climate mitigation policies.

  17. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Cicero, Daniel C. (U.S. Department of Energy, National Energy Technology Laboratory, Morgantown); Stiegel, Gary J.; Gupta, Raghubir P. (U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh); Turk, Brian S. (Research Triangle Institute)

    2001-11-06

    A fixed-bed regenerable desulfurization sorbent, identified as RVS-land developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory, was awarded the R&D 100 award in 2000 and is currently offered as a commercial product by Sued-Chemie Inc. An extensive testing program for this sorbent was undertaken which included tests at a wide range of temperatures, pressures and gas compositions both simulated and generated in an actual gasifier for sulfidation and regeneration. This testing has demonstrated that during these desulfurization tests, the RVS-1 sorbent maintained an effluent H2S concentration of <5 ppmv at temperatures from 260 to 600 C (500-1100 F) and pressures of 203-2026 kPa(2 to 20 atm) with a feed containing 1.2 vol% H{sub 2}S. The types of syngas tested ranged from an oxygen-blown Texaco gasifier to biomass-generated syngas. The RVS-1 sorbent has high crush strength and attrition resistance, which, unlike past sorbent formulations, does not decrease with extended testing at actual at operating conditions. The sulfur capacity of the sorbent is roughly 17 to 20 wt.% and also remains constant during extended testing (>25 cycles). In addition to H{sub 2}S, the RVS-1 sorbent has also demonstrated the ability to remove dimethyl sulfide and carbonyl sulfide from syngas. During regeneration, the RVS-1 sorbent has been regenerated with dilute oxygen streams (1 to 7 vol% O{sub 2}) at temperatures as low as 370 C (700 F) and pressures of 304-709 kPa(3 to 7 atm). Although regeneration can be initiated at 370 C (700 F), regeneration temperatures in excess of 538 C (1000 F) were found to be optimal. The presence of steam, carbon dioxide or sulfur dioxide (up to 6 vol%) did not have any visible effect on regeneration or sorbent performance during either sulfidation or regeneration. A number of commercial tests involving RVS-1 have been either conducted or are planned in the near future. The RVS-1 sorbent has been tested by Epyx, Aspen

  18. Kinetics of combined SO/sub 2//NO in flue gas clean-up

    SciTech Connect (OSTI)

    Chang, S.G.; Littlejohn, D.

    1985-03-01

    The kinetics of reactions involving SO/sub 2/, NO, and ferrous chelate additives in wet flue gas simultaneous desulfurization and denitrification scrubbers are discussed. The relative importance of these reactions are assessed. The relevance of these reactions to spray dryer processes for combined SO/sub 2//NO flue gas clean-up is addressed. 37 refs., 7 figs.

  19. Optimal control system design of an acid gas removal unit for an IGCC power plants with CO2 capture

    SciTech Connect (OSTI)

    Jones, D.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01

    Future IGCC plants with CO{sub 2} capture should be operated optimally in the face of disturbances without violating operational and environmental constraints. To achieve this goal, a systematic approach is taken in this work to design the control system of a selective, dual-stage Selexol-based acid gas removal (AGR) unit for a commercial-scale integrated gasification combined cycle (IGCC) power plant with pre-combustion CO{sub 2} capture. The control system design is performed in two stages with the objective of minimizing the auxiliary power while satisfying operational and environmental constraints in the presence of measured and unmeasured disturbances. In the first stage of the control system design, a top-down analysis is used to analyze degrees of freedom, define an operational objective, identify important disturbances and operational/environmental constraints, and select the control variables. With the degrees of freedom, the process is optimized with relation to the operational objective at nominal operation as well as under the disturbances identified. Operational and environmental constraints active at all operations are chosen as control variables. From the results of the optimization studies, self-optimizing control variables are identified for further examination. Several methods are explored in this work for the selection of these self-optimizing control variables. Modifications made to the existing methods will be discussed in this presentation. Due to the very large number of candidate sets available for control variables and due to the complexity of the underlying optimization problem, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel Computing® toolbox from Mathworks®. The second stage is a bottom-up design of the control layers used for the operation of the process. First, the regulatory control layer is

  20. A NOVEL VAPOR-PHASE PROCESS FOR DEEP DESULFURIZATION OF NAPHTHA/DIESEL

    SciTech Connect (OSTI)

    B.S. Turk; R.P. Gupta; S.K. Gangwal

    2003-06-30

    Tier 2 regulations issued by the U.S. Environmental Protection Agency (EPA) require a substantial reduction in the sulfur content of gasoline. Similar regulations have been enacted for the sulfur level in on-road diesel and recently off-road diesel. The removal of this sulfur with existing and installed technology faces technical and economic challenges. These challenges created the opportunity for new emerging technologies. Research Triangle Institute (RTI) with subcontract support from Kellogg Brown & Root, Inc., (KBR) used this opportunity to develop RTI's transport reactor naphtha desulfurization (TReND) process. Starting with a simple conceptual process design and some laboratory results that showed promise, RTI initiated an accelerated research program for sorbent development, process development, and marketing and commercialization. Sorbent development has resulted in the identification of an active and attrition resistant sorbent that has been prepared in commercial equipment in 100 lb batches. Process development has demonstrated both the sulfur removal performance and regeneration potential of this sorbent. Process development has scaled up testing from small laboratory to pilot plant transport reactor testing. Testing in the transport reactor pilot plant has demonstrated the attrition resistance, selective sulfur removal activity, and regeneration activity of this sorbent material. Marketing and commercialization activities have shown with the existing information that the process has significant capital and operating cost benefits over existing and other emerging technologies. The market assessment and analysis provided valuable feedback about the testing and performance requirements for the technical development program. This market analysis also provided a list of potential candidates for hosting a demonstration unit. Although the narrow window of opportunity generated by the new sulfur regulations and the conservative nature of the refining industry

  1. Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. [Rhodococcus erythropolis, Thiobacillus acidophilus, Thiobacillus novellus

    SciTech Connect (OSTI)

    Krawiec, S.

    1992-01-01

    Research continues on desulfurization of coal using microorganisms. Topics reported on this quarter include: desulfurization with N1-36 (presumptively identified as Rhodochrous erythropolis), pulsed-field gel electrophoresis of chromosomal DNA's of Thiobacillus spp., and fresh isolates with the presumptive capacity to desulfurize dibenzothiophenes.

  2. Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. Eleventh quarterly report

    SciTech Connect (OSTI)

    Krawiec, S.

    1992-08-01

    Research continues on desulfurization of coal using microorganisms. Topics reported on this quarter include: desulfurization with N1-36 (presumptively identified as Rhodochrous erythropolis), pulsed-field gel electrophoresis of chromosomal DNA`s of Thiobacillus spp., and fresh isolates with the presumptive capacity to desulfurize dibenzothiophenes.

  3. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life

  4. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  5. Natural Gas Storage in the United States in 2001: A Current Assessment and Near-Term Outlook

    Reports and Publications (EIA)

    2001-01-01

    This report examines the large decline of underground natural gas storage inventories during the 2000-2001 heating season and the concern that the nation might run out of working gas in storage prior to the close of the heating season on March 31, 2001. This analysis also looks at the current profile and capabilities of the U.S. natural gas underground storage sector.

  6. Apparatus and method for the desulfurization of petroleum by bacteria

    DOE Patents [OSTI]

    Lizama, H.M.; Scott, T.C.; Scott, C.D.

    1995-10-17

    A method is described for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the ``Sulfate Reducing Bacteria``. These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing. 5 figs.

  7. Apparatus and method for the desulfurization of petroleum by bacteria

    DOE Patents [OSTI]

    Lizama, Hector M.; Scott, Timothy C.; Scott, Charles D.

    1995-01-01

    A method for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the "Sulfate Reducing Bacteria." These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing.

  8. Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus

    SciTech Connect (OSTI)

    Miller, K.W.

    1991-01-01

    Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

  9. Addendum to the Closure Report for Corrective Action Unit 403: Second Gas Station, Tonopah Test Range, Nevada, Revision 0

    SciTech Connect (OSTI)

    Grant Evenson

    2009-05-01

    This document constitutes an addendum to the Closure Report for Corrective Action Unit 403: Second Gas Station, Tonopah Test Range, Nevada, September 1998 as described in the document Supplemental Investigation Report for FFACO Use Restrictions, Nevada Test Site, Nevada (SIR) dated November 2008. The SIR document was approved by NDEP on December 5, 2008. The approval of the SIR document constituted approval of each of the recommended UR removals. In conformance with the SIR document, this addendum consists of: • This page that refers the reader to the SIR document for additional information • The cover, title, and signature pages of the SIR document • The NDEP approval letter • The corresponding section of the SIR document This addendum provides the documentation justifying the cancellation of the UR for CAS 03-02-004-0360, Underground Storage Tanks. This UR was established as part of a Federal Facility Agreement and Consent Order (FFACO) corrective action and is based on the presence of contaminants at concentrations greater than the action levels established at the time of the initial investigation (FFACO, 1996). Since this UR was established, practices and procedures relating to the implementation of risk-based corrective actions (RBCA) have changed. Therefore, this UR was reevaluated against the current RBCA criteria as defined in the Industrial Sites Project Establishment of Final Action Levels (NNSA/NSO, 2006). This re-evaluation consisted of comparing the original data (used to define the need for the UR) to risk-based final action levels (FALs) developed using the current Industrial Sites RBCA process. The re-evaluation resulted in a recommendation to remove the UR because contamination is not present at the site above the risk-based FALs. Requirements for inspecting and maintaining this UR will be canceled, and the postings and signage at this site will be removed. Fencing and posting may be present at this site that are unrelated to the FFACO UR

  10. “Assessment of the Adequacy of Natural Gas Pipeline Capacity in the Northeast United States” Report Now Available

    Broader source: Energy.gov [DOE]

    In 2013, OE conducted an assessment to determine how changes to the Northeast gas market may have affected the ability of the interstate pipeline system to meet natural gas demand for “essential human needs” in the event of a disruption in pipeline capacity.

  11. Evaluation of Gas Reburning & Low NOx Burners on a Wall Fired Boiler Performance and Economics Report Gas Reburning-Low NOx Burner System Cherokee Station Unit 3 Public Service Company of Colorado

    SciTech Connect (OSTI)

    1998-07-01

    Under the U.S. Department of Energy's Clean Coal Technology Program (Round 3), a project was completed to demonstrate control of boiler NOX emissions and to a lesser degree, due to coal replacement, SO2 emissions. The project involved combining Gas Reburning with Low NOX Burners (GR-LNB) on a coal-fired electric utility boiler to determine if high levels of NOX reduction (70%) could be achieved. Sponsors of the project included the U.S. Department of Energy, the Gas Research Institute, Public Service Company of Colorado, Colorado Interstate Gas, Electric Power Research Institute, and the Energy and Environmental Research Corporation. The GR-LNB demonstration was performed on Public Service Company of Colorado's (PSCO) Cherokee Unit #3, located in Denver, Colorado. This unit is a 172 MW~ wall-fired boiler that uses Colorado Bituminous, low-sulfur coal. It had a baseline NOX emission level of 0.73 lb/106 Btu using conventional burners. Low NOX burners are designed to yield lower NOX emissions than conventional burners. However, the NOX control achieved with this technique is limited to 30-50%. Also, with LNBs, CO emissions can increase to above acceptable standards. Gas Reburning (GR) is designed to reduce NOX in the flue gas by staged fuel combustion. This technology involves the introduction of natural gas into the hot furnace flue gas stream. When combined, GR and LNBs minimize NOX emissions and maintain acceptable levels of CO emissions. A comprehensive test program was completed, operating over a wide range of boiler conditions. Over 4,000 hours of operation were achieved, providing substantial data. Measurements were taken to quantify reductions in NOX emissions, the impact on boiler equipment and operability and factors influencing costs. The GR-LNB technology achieved good NOX emission reductions and the goals of the project were achieved. Although the performance of the low NOX burners (supplied by others) was less than expected, a NOX reduction of 65% was

  12. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  13. Conceptual Framework for Developing Resilience Metrics for the Electricity, Oil, and Gas Sectors in the United States

    Office of Energy Efficiency and Renewable Energy (EERE)

    This study assessed five potential methane reduction scenarios from natural gas transmission, storage, and distribution (TS&D) infrastructure using published literature on the costs and the estimated quantity of methane reduced. The results show that implementation of these five measures could support approximately 85,000 jobs annually from 2015 to 2019 and reduce CH4 emissions from natural gas TS&D by over 40%. Based on standard input/output analysis methodology, measures are estimated to support over $8 billion in GDP annually over the same time period and allow producers to recover approximately $912 million annually in captured gas. Mitigation of methane emission reductions through repair, replacement and new technologies are found to support economic development and jobs. The study also found that a portfolio approach to infrastructure modernization may be appropriate to meaningfully improve safety, maintain or create high levels of employment, and significant losses of methane from across TS&D segments of natural gas systems.

  14. Energy Savings and Economics of Advanced Control Strategies for Packaged Air-Conditioning Units with Gas Heat

    SciTech Connect (OSTI)

    Wang, Weimin; Katipamula, Srinivas; Huang, Yunzhi; Brambley, Michael R.

    2011-12-31

    Pacific Northwest National Laboratory (PNNL) with funding from the U.S. Department of Energy's Building Technologies Program (BTP) evaluated a number of control strategies that can be implemented in a controller, to improve the operational efficiency of the packaged air conditioning units. The two primary objectives of this research project are: (1) determine the magnitude of energy savings achievable by retrofitting existing packaged air conditioning units with advanced control strategies not ordinarily used for packaged units and (2) estimating what the installed cost of a replacement control with the desired features should be in various regions of the U.S. This document reports results of the study.

  15. Tampa Electric Company, Polk Power Station Unit No. 1. Annual report, January--December 1992

    SciTech Connect (OSTI)

    1993-10-01

    As part of the Tampa Electric Polk Power Unit No. 1, a Texaco pressurized, oxygen-blown entrained-flow coal gasifier will convert approximately 2300 tons per day of coal (dry basis) into a medium-BTU fuel gas with a heat content of about 250 BTU/scf (LHV). Syngas produced in the gasifier flows through a high-temperature heat recovery unit which cools the gases prior to entering two parallel clean-up areas. A portion (up to 50%) of the hot syngas is cooled to 1000{degrees}F and passed through a moving bed of zinc titanate sorbent which removed sulfur containing components of the fuel gas. The project will be the first in the world to demonstrate this advanced metal oxide hot gas desulfurization technology at a commercial scale. The remaining portion of the syngas is cooled to 400{degrees}F for conventional acid gas removal. This portion of the plant is capable of processing between 50% and 100% of the dirty syngas. The cleaned low-BTU syngas is then routed to the combined cycle power generation system where it is mixed with air and burned in the gas turbine combustor. Heat is extracted from the expanded exhaust gases by a heat recovery steam generator to produce high pressure steam. This steam, along with the steam generated in the gasification process, drives a steam turbine to generate an additional 132MW of power. Internal process power consumption is approximately 62MW, and includes power for coal grinding, air separation, and feed pumps. Net output from the IGCC demonstration plant will be 260MW.

  16. Oil and gas development in the United States in the early 1990`s: An expanded role for independent producers

    SciTech Connect (OSTI)

    1995-10-01

    Since 1991, the major petroleum companies` foreign exploration and development expenditures have exceeded their US exploration and development expenditures. The increasing dependence of US oil and gas development on the typically much smaller nonmajor companies raises a number of issues. Did those companies gain increased prominence largely through the reduced commitments of the majors or have they been significantly adding to the US reserve base? What are the characteristics of surviving and growing producers compared with companies exiting the US oil and gas business? Differences between majors` development strategies and those of other US oil and gas producers appear considerable. As the mix of exploration and development strategies in US oil and gas increasingly reflects the decisions of smaller, typically more specialized producers, what consequences can be seen regarding the costs of adding to US reserves? How are capital markets accessed? Are US oil and gas investments by the nonmajors likely to be undertaken only with higher costs of capital? This report analyzes these issues. 20 figs., 6 tabs.

  17. Coal desulfurization by chlorinolysis: production and combustion-test evaluation of product coals. Final report

    SciTech Connect (OSTI)

    Kalvinskas, J.; Daly, D.

    1982-04-30

    Laboratory-scale screening tests were carried out on PSOC 276, Pittsburgh Coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, Pittsburgh No. 8 from Greene County, PA, Illinois No. 6 from Jackson County, Illinois and Eagle No. 5 from Moffat County, Colorado were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals (PSOC 276, Pittsburgh Coal from Harrison County, Ohio and 282, Illinois No. 6 Coal from Jefferson County, Illinois) and one subbituminous coal (PSOC 230, Rosebud Coal fom Rosebud County, Montana) were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29 to 69%, reductions in volatiles (12 to 37%) and hydrogen (6 to 31%). Hydrodesulfurization provided a much greater desulfurization (56 to 86%), reductions in volatiles (77 to 84%) and hydrogen (56 to 64%). The three coals were combustion tested in the Penn State plane flame furance to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning. 4 figures, 2 tables.

  18. Analysis of an industrial cogeneration unit driven by a gas engine. Part 1: Experimental testing under full and part-load operating conditions

    SciTech Connect (OSTI)

    De Lucia, M.; Lanfranchi, C.

    1994-12-31

    This paper describes and analyzes an industrial cogeneration plant driven by a gas fueled reciprocating engine installed in a textile factory. It presents the results of experimental testing conducted under full and part-load operating conditions, as well as first-law energy considerations. The experimental tests conducted on the cogeneration unit proved the validity of the plant design and also enabled evaluation of part-load performance, which is the most common operating mode in cogeneration plants in the small-size industries which typical of central Italy.

  19. Desulfurization of coal: Enhanced selectivity using phase transfer catalysts. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Palmer, S.R.; Hippo, E.J.

    1995-12-31

    Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development of viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigates the application of phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions than otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidations for selective sulfur oxidation are also being studied. If successful this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal. During this quarter aliquots of the IBC-101 coal have been ground to various particle sizes in an attempt to find the optimum physical pretreatment for mineral, especially pyrite, removal. Analysis of these various aliquots shows them to be representative of the original coal. In addition, preliminary desulfurization reactions using fly ash and scrubber sludges have been performed on an unoxidized IBC-101 sample. Results will be available next quarter. Also, SEM-EDAX analysis of the fly ash indicates that it contains oxides that have shown activity in base desulfurization reactions.

  20. Application of the Federal Petroleum Excise Tax to gas processors: Enron Gas Processing Company vs. United States of America (in the United States District Court for the Southern District of Texas, Houston Division)

    SciTech Connect (OSTI)

    Mintz, J.H.

    1996-12-31

    The Petroleum Excise Tax was established in 1980 as a tax on domestic refined crude oil and natural gasoline. The Government contends that natural gasoline produced by Enron in natural gas processing plants is refined natural gasoline, therefore these plants should be classed as refineries and the natural gasoline produced should be taxed at 14.7 cents per barrel. The government has an assessment of $643,594.33 for the six quarters beginning with the last quarter of 1991. Enron has filed a motion of Summary Judgment for these assessments to be dropped.

  1. Structural and sedimentological controls and diagenesis in the Ravenspurn north gas reservoir United Kingdom southern North Sea

    SciTech Connect (OSTI)

    Turner, P. ); Jones, M. ); Prosser, J. ); Williams, G. )

    1993-09-01

    The Ravenspurn area is divided into two main northwest-southeast-trending fault blocks which are markedly different in terms of their diagenetic evolution and reservoir performance. The northeasterly B structure contained gas earlier and was unaffected by Middle to Late Jurassic illitization. The southwesterly A structure was uplifted later and received accumulated gas after reservoir quality was reduced by pervasive illitization. The deposition of allogenic clay and the formation of early quartz, nonferroan dolomite, and anhydrite reduced the reservoir quality of fluvial sheetflood. Burial diagenesis resulted initially in ferroan dolomite, kaolinite, and later quartz precipitation in available primary and secondary porosity. Stable-isotope and fluid-inclusion studies indicate that Ferroan dolomite and later quartz precipitated at about 100[degrees]C in the Triassic-Early Jurassic from reduced fluids derived partly from the Carboniferous basement. Gas accumulation took place first in the northeasterly B structure, which had early closure. Elsewhere diagenetic fluids evolved to a more alkaline state, and widespread illitization took place which particularly affected more permeable eolian facies. The illitization reduced the reservoir quality of the lower Leman Sandstone and contributed to diagenetic sealing (to the northwest) of the field. K-Ar dating indicates that peak illitization took place between 150 and 170 Ma (Middle-Late Jurassic). Subsequent periods of uplift in the late Cimmerian and particularly during the early Tertiary-Miocene produced the final structure of Ravenspurn North and the spillage of gas into this structure. The combination of structural and diagenetic events explains the differences in reservoir quality and well performance of the two structural blocks in the field.

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... a wet flue gas desulfurization scrubber. MEST-H provided lower detection limits for hydrochloric acid than the reference method. Results from a dry stack unit had better ...

  3. Widget:GasMap | Open Energy Information

    Open Energy Info (EERE)

    GasMap Jump to: navigation, search Gas map widget: The Gas Map displays real-time gas prices for the United States Example Output Gas map widget: Denver Gas Prices provided by...

  4. The Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    2009-01-18

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH,

  5. Demonstration of natural gas reburn for NO{sub x} emissions reduction at Ohio Edison Company`s cyclone-fired Niles Plant Unit Number 1

    SciTech Connect (OSTI)

    Borio, R.W.; Lewis, R.D.; Koucky, R.W.; Lookman, A.A.; Manos, M.G.; Corfman, D.W.; Waddingham, A.L.; Johnson, S.A.

    1996-04-01

    Electric utility power plants account for about one-third of the NO{sub x} and two-thirds of the SO{sub 2} emissions in the US cyclone-fired boilers, while representing about 9% of the US coal-fired generating capacity, emit about 14% of the NO{sub x} produced by coal-fired utility boilers. Given this background, the Environmental Protection Agency, the Gas Research Institute, the Electric Power Research Institute, the Pittsburgh Energy Technology Center, and the Ohio Coal Development Office sponsored a program led by ABB Combustion Engineering, Inc. (ABB-CE) to demonstrate reburning on a cyclone-fired boiler. Ohio Edison provided Unit No. 1 at their Niles Station for the reburn demonstration along with financial assistance. The Niles Unit No. 1 reburn system was started up in September 1990. This reburn program was the first full-scale reburn system demonstration in the US. This report describes work performed during the program. The work included a review of reburn technology, aerodynamic flow model testing of reburn system design concepts, design and construction of the reburn system, parametric performance testing, long-term load dispatch testing, and boiler tube wall thickness monitoring. The report also contains a description of the Niles No. 1 host unit, a discussion of conclusions and recommendations derived from the program, tabulation of data from parametric and long-term tests, and appendices which contain additional tabulated test results.

  6. Improving Desulfurization to Enable Fuel Cell Utilization of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Both TDA and its project partner FuelCell Energy have suc- cessfully commercialized and ... FuelCell Energy has built numerous fuel cell plants fed by anaerobic digester gas, giving ...

  7. Desulfurization of coal: enhanced selectivity using phase transfer catalysts. Quarterly report, March 1 - May 31, 1996

    SciTech Connect (OSTI)

    Palmer, S.R.; Hippo, E.J.

    1996-12-31

    Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development in viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions that otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidation for selective sulfur oxidation are also being studied. If successful, this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal.

  8. CO2 is dominant greenhouse gas emitted from six hydropower reservoirs in southeastern United States during peak summer emissions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bevelhimer, Mark S.; Stewart, Aurthur J.; Fortner, Allison M.; Phillips, Jana Randolph; Mosher, Jennifer J.

    2016-01-06

    During August-September 2012, we sampled six hydropower reservoirs in southeastern United States. for CO2 and CH4 emissions via three pathways: diffusive emissions from water surface; ebullition in the water column; and losses from dam tailwaters during power generation. Average total emission rates of CO2 for the six reservoirs ranged from 1,127 to 2,051 mg m-2 d-1, which is low to moderate compared to CO2 emissions rates reported for tropical hydropower reservoirs and boreal ponds and lakes, and similar to rates reported for other temperate reservoirs. Similar average rates for CH4 were also relatively low, ranging from 5 to 83 mgmore » m-2 d-1. On a whole-reservoir basis, total emissions of CO2 ranged nearly 10-fold, from ~51,000 kg per day for Fontana to ~486,000 kg per day for Guntersville, and total emissions of CH4 ranged nearly 20-fold, from ~5 kg per day for Fontana to ~83 kg per day for Allatoona. Emissions through the tailwater pathway varied among reservoirs, comprising from 20 to 50% of total CO2 emissions and 0 to 90% of CH4 emissions, depending on the reservoir. Furthermore, several explanatory factors related to reservoir morphology and water quality were considered for observed differences among reservoirs.« less

  9. Management of dry flue gas desulfurization by-products in underground mines

    SciTech Connect (OSTI)

    Sevim, H.

    1997-06-01

    Disposal of coal combustion by-products (CCBs) in an environmentally sound manner is a major issue facing the coal and utility industries in the US today. Disposal into abandoned sections of underground coal mines may overcome many of the surface disposal problems along with added benefits such as mitigation of subsidence and acid mine drainage. However, many of the abandoned underground coal mines are located far from power plants, requiring long distance hauling of by-products which will significantly contribute to the cost of disposal. For underground disposal to be economically competitive, the transportation and handling cost must be minimized. This requires careful selection of the system and optimal design for efficient operation. The materials handling and system economics research addresses these issues. Transportation and handling technologies for CCBs were investigated from technical, environmental and economic points of view. Five technologies were found promising: (1) Pneumatic Trucks, (2) Pressure Differential Rail Cars, (3) Collapsible Intermodal Containers, (4) Cylindrical Intermodal Tanks, and (5) Coal Hopper Cars with Automatic Retractable Tarping. The first two technologies are currently being utilized in transporting by-products from power plants to disposal sites, whereas the next three are either in development or in conceptualization phases. In this research project, engineering design and cost models were developed for the first four technologies. The engineering design models are in the form of spreadsheets and serve the purpose of determining efficient operating schedules and sizing of system components.

  10. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect (OSTI)

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  11. Screening of zinc-based sorbents for hot-gas desulfurization

    SciTech Connect (OSTI)

    Joong B. Lee; Chong K. Ryu; Chang K. Yi; Sung H. Jo; Sung H. Kim

    2008-03-15

    Highly reactive and attrition-resistant ZnO-based sorbents that are suitable for bubbling fluidized-bed reactors can be produced using the spray-drying method. Most of the ZnO-based sorbents prepared here (ZAC-X, X = 18N-25N) satisfy the physical and chemical criteria for bubbling fluidized-bed application (spherical shape, average particle size, 90-110 {mu}m; size distribution, 40-230 {mu}m; bulk density, 0.9-1.0 g/mL; attrition index (AI), 40-80%; sulfur sorption capacity, 14-17 wt %; sorbent use, 70-80%). The performance test of the ZAC-C sorbent at Korea Institute of Energy Research (KIER) with a bubbling fluidized-bed for 70 h also demonstrated that it had good sulfidation and regeneration performance (11 wt % sorption capacity and 52% sorbent use) as well as reasonable attrition resistance (1.1% attrition loss for 70 h). 14 refs., 7 figs., 6 tabs.

  12. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  13. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  14. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A.

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  15. Deepwater Oil & Gas Resources | Department of Energy

    Office of Environmental Management (EM)

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to ...

  16. Deepwater Oil & Gas Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to...

  17. Shale Gas Glossary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Shale Gas Glossary Shale Gas Glossary (286.97 KB) More Documents & Publications Natural Gas from Shale: Questions and Answers Modern Shale Gas Development in the United States: A Primer How is shale gas produced?

  18. Evaluation of sulfur-reducing microorganisms for organic desulfurization. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Miller, K.W.

    1991-12-31

    Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

  19. Revamping AK-Ashland gas cleaning system

    SciTech Connect (OSTI)

    Brandes, H.; Koerbel, R.; Haberkamp, K.; Keeton, S.

    1995-07-01

    AK Steel`s (formerly Armco) BOF shop was using a static precipitator for the primary collection. The system was designed for full combustion in the gas collecting hoods. No secondary dust collection was in place. A detailed study on alternative solutions led to a completely different system in 1990, and an order was awarded to Mannesmann Demag Corp. (MDC) in Dec. 1990. The new gas collection system is using suppressed combustion with the capability to collect Co at a later stage. The gas cleaning uses the Mannesmann Demag Baumco scrubber with a venturi throat for gas flow control. All auxiliary components, water treatment plant, electric substations and sludge handling were designed and supplied by MDC. The secondary dust collection covers the hot metal and scrap charging into the BOF`s, reladling, desulfurization and deslagging by a pulse jet baghouse. All emission limits set by the EPA and guaranteed by MDC have been met by the systems installed.

  20. Intermountain Gas Company (IGC)- Gas Heating Rebate Program

    Broader source: Energy.gov [DOE]

    The Intermountain Gas Company's (IGC) Gas Heating Rebate Program offers customers a $200 per unit rebate when they convert to a high efficiency natural gas furnace that replaces a heating system...

  1. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasifiction combined sycle (IGCC) power plant with CO2 capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel

  2. Sensor placement algorithm development to maximize the efficiency of acid gas removal unit for integrated gasification combined cycle (IGCC) power plant with CO{sub 2} capture

    SciTech Connect (OSTI)

    Paul, P.; Bhattacharyya, D.; Turton, R.; Zitney, S.

    2012-01-01

    Future integrated gasification combined cycle (IGCC) power plants with CO{sub 2} capture will face stricter operational and environmental constraints. Accurate values of relevant states/outputs/disturbances are needed to satisfy these constraints and to maximize the operational efficiency. Unfortunately, a number of these process variables cannot be measured while a number of them can be measured, but have low precision, reliability, or signal-to-noise ratio. In this work, a sensor placement (SP) algorithm is developed for optimal selection of sensor location, number, and type that can maximize the plant efficiency and result in a desired precision of the relevant measured/unmeasured states. In this work, an SP algorithm is developed for an selective, dual-stage Selexol-based acid gas removal (AGR) unit for an IGCC plant with pre-combustion CO{sub 2} capture. A comprehensive nonlinear dynamic model of the AGR unit is developed in Aspen Plus Dynamics® (APD) and used to generate a linear state-space model that is used in the SP algorithm. The SP algorithm is developed with the assumption that an optimal Kalman filter will be implemented in the plant for state and disturbance estimation. The algorithm is developed assuming steady-state Kalman filtering and steady-state operation of the plant. The control system is considered to operate based on the estimated states and thereby, captures the effects of the SP algorithm on the overall plant efficiency. The optimization problem is solved by Genetic Algorithm (GA) considering both linear and nonlinear equality and inequality constraints. Due to the very large number of candidate sets available for sensor placement and because of the long time that it takes to solve the constrained optimization problem that includes more than 1000 states, solution of this problem is computationally expensive. For reducing the computation time, parallel computing is performed using the Distributed Computing Server (DCS®) and the Parallel

  3. United Energy Group PLC | Open Energy Information

    Open Energy Info (EERE)

    Group PLC Jump to: navigation, search Name: United Energy Group PLC Place: Haslemere, United Kingdom Sector: Hydro, Wind energy Product: The company develops small hydro, gas...

  4. OPTIMIZING TECHNOLOGY TO REDUCE MERCURY AND ACID GAS EMISSIONS FROM ELECTRIC POWER PLANTS

    SciTech Connect (OSTI)

    Jeffrey C. Quick; David E. Tabet; Sharon Wakefield; Roger L. Bon

    2005-10-01

    Maps showing potential mercury, sulfur, chlorine, and moisture emissions for U.S. coal by county of origin were made from publicly available data (plates 1, 2, 3, and 4). Published equations that predict mercury capture by emission control technologies used at U.S. coal-fired utilities were applied to average coal quality values for 169 U.S. counties. The results were used to create five maps that show the influence of coal origin on mercury emissions from utility units with: (1) hot-side electrostatic precipitator (hESP), (2) cold-side electrostatic precipitator (cESP), (3) hot-side electrostatic precipitator with wet flue gas desulfurization (hESP/FGD), (4) cold-side electrostatic precipitator with wet flue gas desulfurization (cESP/FGD), and (5) spray-dry adsorption with fabric filter (SDA/FF) emission controls (plates 5, 6, 7, 8, and 9). Net (lower) coal heating values were calculated from measured coal Btu values, and estimated coal moisture and hydrogen values; the net heating values were used to derive mercury emission rates on an electric output basis (plate 10). Results indicate that selection of low-mercury coal is a good mercury control option for plants having hESP, cESP, or hESP/FGD emission controls. Chlorine content is more important for plants having cESP/FGD or SDA/FF controls; optimum mercury capture is indicated where chlorine is between 500 and 1000 ppm. Selection of low-sulfur coal should improve mercury capture where carbon in fly ash is used to reduce mercury emissions. Comparison of in-ground coal quality with the quality of commercially mined coal indicates that existing coal mining and coal washing practice results in a 25% reduction of mercury in U.S. coal before it is delivered to the power plant. Further pre-combustion mercury reductions may be possible, especially for coal from Texas, Ohio, parts of Pennsylvania and much of the western U.S.

  5. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to the technology that drove Enron's North American wholesale electricity and natural gas trading unit. That technology, together with reportedly over 600 former Enron...

  6. NETL: Natural Gas Resources

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Resources Useful for heating, manufacturing, and as chemical feedstock, natural gas has the added benefit of producing fewer greenhouse gas emissions than other fossil fuels used in power production.The United States is endowed with an abundance of natural gas resources, so increasing use of natural gas power can help strengthen domestic energy security. NETL research efforts enhance technologies that reduce the cost, increase the efficiency, and reduce the environmental risk of

  7. Integrated Mg/TiO{sub 2}-ionic liquid system for deep desulfurization

    SciTech Connect (OSTI)

    Yin, Yee Cia; Kait, Chong Fai E-mail: hayyiratulfatimah@yahoo.com Fatimah, Hayyiratul E-mail: hayyiratulfatimah@yahoo.com Wilfred, Cecilia E-mail: hayyiratulfatimah@yahoo.com

    2014-10-24

    A series of Mg/TiO{sub 2} photocatalysts were prepared using wet impregnation method followed by calcination at 300, 400 and 500°C for 1 h. The photocatalysts were characterized using Thermal Gravimetric Analysis, Fourier-Transform Infrared Spectroscopy, X-Ray Diffraction, and Field Emission Scanning Electron Microscopy. The performance for deep desulfurization was investigated using model oil with 100 ppm sulfur (in the form of dibenzothiophene). The integrated system involves photocatalytic oxidation followed by ionic liquid-extraction processes. The best performing photocatalyst was 0.25wt% Mg loaded on titania calcined at 400°C (0.25Mg400), giving 98.5% conversion of dibenzothiophene to dibenzothiophene sulfone. The highest extraction efficiency of 97.8% was displayed by 1,2-diethylimidazolium diethylphosphate. The overall total sulfur removal was 96.3%.

  8. Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report

    SciTech Connect (OSTI)

    Hsu, F.E.

    1995-08-01

    The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

  9. Natural Gas Weekly Update, Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    Gas Prices Contributing to Increases in Greenhouse Gas Emissions: The United States Environmental Protection Agency (EPA) cited increasing natural gas prices as one of three...

  10. Federal Register Notice for Life Cycle Greenhouse Gas Perspective...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Life Cycle Greenhouse Gas Perspective on Exporting Liquefied Natural Gas from the United States Federal Register Notice for Life Cycle Greenhouse Gas Perspective on Exporting Liquefied ...

  11. DOE's Program Regulating Liquefied Natural Gas Export Applications...

    Office of Environmental Management (EM)

    of natural gas, including liquefied natural gas (LNG). Recent Developments in LNG Exports The boom in domestic shale gas provides unprecedented opportunities for the United States. ...

  12. Desulfurization of coal: Enhanced selectivity using phase transfer catalysts. Final technical report, September 1, 1995--August 31, 1996

    SciTech Connect (OSTI)

    Palmer, S.R.; Hippo, E.J.

    1997-05-01

    Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development of viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application of phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst was expected to function as a selectivity moderator by permitting the use of milder reaction conditions than otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidations for selective sulfur oxidation were also studied. If successful this project would have lead to the rapid development of a commercially viable desulfurization process. This would have significantly improved the marketability of Illinois coal. However, the phase transfer catalysts, the cerium and the scrubber sledge did not catalize the sulfur removal significantly.

  13. EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland

    Office of Energy Efficiency and Renewable Energy (EERE)

    The U.S. Department of Energy’s Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

  14. Desulfurization of coal with hydroperoxides of vegetable oils. [Quarterly] report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, Ruozhi; Cheng, Jianjun

    1994-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. Preliminary experiments showed that EBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During this first quarter the requirement of an added photosensitizer has been eliminated, the catalytic effect of coal has been confirmed, and the existence of a complex set of reactions revealed. These reactions between the oxygen, oil, hydroperoxides, and coal are hydroperoxide formation, which is catalyzed by the coal surface and by heat, an unknown coal-hydroperoxide reaction, and oil polymerization. Additionally, diffusion phenomena must be playing a role because oil polymerization occurs, but the importance of diffusion is difficult to assess because less polymerization occurs when coal is present. The first task has been completed and we are now ready to determine the ability of linseed oil hydroperoxides to oxidize organic sulfur in EBC 108 coal.

  15. Iran Oil and Gas | Open Energy Information

    Open Energy Info (EERE)

    Iran Oil and Gas Jump to: navigation, search Logo: Iran Oil and Gas Name: Iran Oil and Gas Address: Unit 16, 3rd Fl., Bldg. No. 2, 9th Narenjestan St., North Pasdaran Ave. Place:...

  16. Reduction of air in-leakage and flue gas by-passing in the penthouse of Duke Power-Marshall Unit No. 4

    SciTech Connect (OSTI)

    Campbell, R.; Rush, T.

    1995-12-31

    After a year of operation, the penthouse was inspected and found to be {open_quotes}lightly dusted{close_quotes} with barely sufficient accumulation to show footprints. This is contrasted with previous five foot deep ash dunes. The savings in maintenance repairs are estimated at $65,000 for vacuuming that was not required, and $80,000 in maintenance personnel weld repairs. The history of repairs was such that vacuuming and weld repair costs were predictable, and before the IOSMEMBRANE{reg_sign} installation, always expected as recurring maintenance costs. The heat rate improvement of reducing air in-leakage is well known, and significant. The principal quantified savings are in reduced maintenance costs, more expedient repairs (reduced cool down time for repairs in the penthouse), and safety. The heat rate improvements, though not quantified yet, are expected to be significant. The success of the ISOMEMBRANE{reg_sign} on Unit No. 4 has resulted in similar plans for Unit No. 3 and other units in the Duke Power system.

  17. NNSA Small Business Week Day 2: United Drilling, Inc. | National...

    National Nuclear Security Administration (NNSA)

    Today's profile highlights United Drilling, Inc., a small minority-owned business based in Roswell, N.M. United Drilling drills oil, gas, water, geothermal, and environmental wells ...

  18. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    part of a 65 billion project to supply the United States with oil, natural gas, and electricity from Siberia. The tunnel, which would be the world's longest, would take 10 to 15...

  19. Desulfurization of coal with hydroperoxides of vegetable oils. Technical progress report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, R.; Cheng, J.; Shi, Feng; Gholson, K.L.

    1995-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of solid products. Preliminary experiments showed that IBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During the first quarter the requirement of an added photosensitizer was eliminated, the catalytic effect of coal was confirmed, and the existence of a complex set of reactions was revealed. During the second quarter, working with IBC-108 coal (2.3% organic S, 0.4% pyrite S), the effects of different extraction solvents were examined. A new pretreatment which combines alkali with linseed oil was discovered. Best organic sulfur removal is approximately 26% using alkali pretreatment combined with linseed oil at 100[degrees]C. BTU loses can be kept to a minimum of 3% with proper use of solvents. During this third quarter the effects of different ratios of oil:coal, different temperatures, and different reaction times were completely examined. The effects of alkali on sulfur removal were further investigated. Best organic sulfur removal reaches 34% using ammonia pretreatment, then oil and finally aqNA2CO3 extraction.

  20. S.32: A Bill to amend the Internal Revenue Code of 1986 to provide a tax credit for the production of oil and gas from existing marginal oil and gas wells and from new oil and gas wells. Introduced in the Senate of the United States, One Hundred Fourth Congress, First session

    SciTech Connect (OSTI)

    1995-12-31

    This bill would establish tax credits for the production of oil and natural gas from existing marginal oil or gas wells, and from new oil and gas wells. It does so by adding a section to the Internal Revenue Code of 1986 which spells out the rules, the credit amounts, the scope of the terms used to define such facilities, and other rules.

  1. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.

    1997-12-31

    The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

  2. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1994-10-01

    Preliminary environmental risk assessment on the FGD by-products to be placed underground is virtually complete. The initial mixes for pneumatic and hydraulic placement have been selected and are being subject to TCLP, ASTM, and modified SLP shake tests as well as ASTM column leaching. Results of these analyses show that the individual coal combustion residues, and the residues mixes, are non-hazardous in character. Based on available information, including well logs obtained from Peabody Coal Company, a detailed study of the geology of the placement site was completed. The study shows that the disposal site in the abandoned underground mine workings at depths of between 325 and 375 feet are well below potable groundwater resources. This, coupled with the benign nature of the residues and residues mixtures, should alleviate any concern that the underground placement will have adverse effects on groundwater resources. Seven convergence stations were installed in the proposed underground placement area of the Peabody Coal Company No. 10 mine. Several sets of convergence data were obtained from the stations. A study of materials handling and transportation of coal combustion residues from the electric power plant to the injection site has been made. The study evaluated the economics of the transportation of coal combustion residues by pneumatic trucks, by pressure differential rail cars, and by SEEC, Inc. collapsible intermodal containers (CICs) for different annual handling rates and transport distances. The preliminary physico-chemical characteristics and engineering properties of various FBC fly ash-spent bed mixes have been determined, and long-term studies of these properties are continuing.

  3. Management of dry gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1996

    SciTech Connect (OSTI)

    1996-12-31

    The objective is to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement using virtually dry coal combustion by-products, and (2) hydraulic placement using a paste mixture of combustion by-products with about 70% solids. Phase 2 of the overall program began April 1, 1996. The principal objective of Phase 2 is to develop and fabricate the equipment for both the pneumatic and hydraulic placement technologies, and to conduct a limited, small-scale shakedown test of the pneumatic and hydraulic placement equipment. The shakedown test originally was to take place on the surface, in trenches dug for the tests. However, after a thorough study it was decided, with the concurrence of DOE-METC, to drill additional injection wells and conduct the shakedown tests underground. This will allow a more thorough test of the placement equipment.

  4. Kinetics of Mn-based sorbents for hot coal gas desulfurization. Quarterly report, December 15, 1993--March 15, 1997

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1997-03-03

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases prior to its use in combined cycle turbines. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H{sub 2}S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In previous reports, the sulfidation and regeneration results from cyclic testing done at 600{degrees}C were presented. Manganese-based sorbents, with molar ratios > 1:1 Mn:Substrate were effective in reducing the H{sub 2}S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent. Regeneration tests determined that loaded pellets can be fully regenerated in air/steam mixture at 750{degrees}C with minimal sulfate formation. In this report, the results from cyclic crush strength tests, Sulfur profile tests and cyclic testing at 550{degrees}C and lower flowrate cyclic testing are presented. Crush strength testing done after 5 cycles showed decreases in strength from 12.6% to 57.9%. Cyclic testing at 550{degrees}C showed pre breakthrough concentrations as low as 10 ppmv. Cyclic testing done at 2 L/min and 3 L/min did not show any significant difference in pre breakthrough concentrations or capacity.

  5. Kinetics of MN-based sorbents for hot coal gas desulfurization. Semiannual report, December 15, 1996--March 15, 1997

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1997-03-01

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases prior to its use in combined cycle turbines. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H{sub 2}S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In previous reports, the sulfidation and regeneration results from cyclic testing done at 600{degrees}C were presented. Manganese-based sorbents with molar ratios >1:1 Mn:substrate were effective in reducing the H{sub 2}S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent. Regeneration tests determined that loaded pellets can be fully regenerated in air/steam mixture at 750{degrees}C with minimal sulfate formation. In this report, the results from the cyclic crush strength tests, sulfur profile test, and cyclic testing done after 5 cycles showed decreases in strength from 12.6% to 57.9%. Cyclic testing at 550{degrees}C showed pre-breakthrough concentrations as low as 10 ppmv. Cyclic testing done at 2 L/min and 3 L/min did not show any significant difference in pre-breakthrough concentrations or capacity.

  6. Kinetics of Mn-based sorbents for hot coal gas desulfurization. Quarterly report, September 15 - December 15, 1996

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1996-12-31

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases prior to its use in combined cycle turbines. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H{sub 2}S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In a previous report, the sulfidation results were presented. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H{sub 2}S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent. In this report, the regeneration results will be presented. Regeneration tests determined that loaded pellets can be fully regenerated in air/steam mixture at 750{degrees}C with minimal sulfate formation. 16 refs., 9 figs., 5 tabs.

  7. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, S.E.; Arasteh, D.K.; Hartmann, J.L.

    1988-04-05

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas. 2 figs.

  8. Thermal insulated glazing unit

    DOE Patents [OSTI]

    Selkowitz, Stephen E. (Piedmont, CA); Arasteh, Dariush K. (Oakland, CA); Hartmann, John L. (Seattle, WA)

    1991-01-01

    An improved insulated glazing unit is provided which can attain about R5 to about R10 thermal performance at the center of the glass while having dimensions about the same as those of a conventional double glazed insulated glazing unit. An outer glazing and inner glazing are sealed to a spacer to form a gas impermeable space. One or more rigid, non-structural glazings are attached to the inside of the spacer to divide the space between the inner and outer glazings to provide insulating gaps between glazings of from about 0.20 inches to about 0.40 inches. One or more glazing surfaces facing each thermal gap are coated with a low emissivity coating. Finally, the thermal gaps are filled with a low conductance gas such as krypton gas.

  9. US crude oil, natural gas, and natural gas liquids reserves

    SciTech Connect (OSTI)

    Not Available

    1990-10-05

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1989, and production volumes for the year 1989 for the total United States and for selected states and state sub-divisions. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), its two major components (nonassociated and associated-dissolved gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, two components of natural gas liquids, lease condensate and natural gas plant liquids, have their reserves and production reported separately. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. 28 refs., 9 figs., 15 tabs.

  10. Energy Department Invests $3 Million to Train Future Energy Scientists...

    Energy Savers [EERE]

    ... The resulting demonstration unit will be used for extended in-field testing of flue gas desulfurization wastewaters at a coal-fired power plant, where it will also be validated for ...

  11. Assessment of the Adequacy of Natural Gas Pipeline Capacity in...

    Office of Environmental Management (EM)

    Assessment of the Adequacy of Natural Gas Pipeline Capacity in the Northeast United States - November 2013 Assessment of the Adequacy of Natural Gas Pipeline Capacity in the ...

  12. Applications of Modern Pyrolysis Gas Chromatography for the Study...

    Office of Scientific and Technical Information (OSTI)

    Publisher: Advances in Gas Chromatography, Applications of Modern Pyrolysis Gas ... Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, ...

  13. Sorbents for mercury removal from flue gas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Fossil Energy Country of Publication: United States Language: English Subject: 01 COAL, LIGNITE, AND PEAT; Flue Gas; Flue Gas; Mercury; Mercury; ...

  14. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

    2006-09-30

    This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

  15. Phasor Measurement Units

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phasor Measurement Units - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  16. Natural gas pipeline technology overview.

    SciTech Connect (OSTI)

    Folga, S. M.; Decision and Information Sciences

    2007-11-01

    The United States relies on natural gas for one-quarter of its energy needs. In 2001 alone, the nation consumed 21.5 trillion cubic feet of natural gas. A large portion of natural gas pipeline capacity within the United States is directed from major production areas in Texas and Louisiana, Wyoming, and other states to markets in the western, eastern, and midwestern regions of the country. In the past 10 years, increasing levels of gas from Canada have also been brought into these markets (EIA 2007). The United States has several major natural gas production basins and an extensive natural gas pipeline network, with almost 95% of U.S. natural gas imports coming from Canada. At present, the gas pipeline infrastructure is more developed between Canada and the United States than between Mexico and the United States. Gas flows from Canada to the United States through several major pipelines feeding U.S. markets in the Midwest, Northeast, Pacific Northwest, and California. Some key examples are the Alliance Pipeline, the Northern Border Pipeline, the Maritimes & Northeast Pipeline, the TransCanada Pipeline System, and Westcoast Energy pipelines. Major connections join Texas and northeastern Mexico, with additional connections to Arizona and between California and Baja California, Mexico (INGAA 2007). Of the natural gas consumed in the United States, 85% is produced domestically. Figure 1.1-1 shows the complex North American natural gas network. The pipeline transmission system--the 'interstate highway' for natural gas--consists of 180,000 miles of high-strength steel pipe varying in diameter, normally between 30 and 36 inches in diameter. The primary function of the transmission pipeline company is to move huge amounts of natural gas thousands of miles from producing regions to local natural gas utility delivery points. These delivery points, called 'city gate stations', are usually owned by distribution companies, although some are owned by transmission companies

  17. Peak Underground Working Natural Gas Storage Capacity

    Gasoline and Diesel Fuel Update (EIA)

    Previous Articles Previous Articles Estimates of Peak Underground Working Gas Storage Capacity in the United States, 2009 Update (Released, 8312009) Estimates of Peak Underground...

  18. Green Gas International | Open Energy Information

    Open Energy Info (EERE)

    International Jump to: navigation, search Name: Green Gas International Place: Richmond upon Thames, United Kingdom Zip: TW10 6UW Product: The company establishes coal mine,...

  19. Liberty Utilities (Gas)- Commercial Energy Efficiency Programs

    Broader source: Energy.gov [DOE]

    Liberty Utilities' program for commercial natural gas customers provides incentives for energy efficient equipment installations and upgrades. Incentives are available for boilers, furnaces, unit...

  20. United States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EA- 3 14 Order Authorizing Electricity Exports to Mexico Order No. EA-3 14 February ... to transmit electric energy from the United States to Mexico as a power marketer. ...

  1. United States

    Office of Legacy Management (LM)

    Office of Research and EPA 600/R-941209 Environmental Protection Development January 1993 Agency Washington, DC 20460 Offsite Environmental 57,,7 Monitoring Report Radiation Monitoring Around United States Nuclear Test Areas, Calendar Year 1992 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OFFICE OF RESEARCH AND DEVELOPMENT ENVIRONMENTAL MONITORING SYSTEMS LABORATORY-LAS VEGAS P.O. BOX 93478 LAS VEGAS. NEVADA 891 93-3478 702/798-2100 Dear Reader: Since 1954, the U.S. Environmental Protection

  2. Island Gas | Open Energy Information

    Open Energy Info (EERE)

    United Kingdom Zip: W1J 7BU Sector: Renewable Energy Product: UK-based coal bed methane company, Island Gas was the subject of a reverse takeover by KP Renewables in...

  3. Natural Gas Processing: The Crucial Link Between Natural Gas Production and Its Transportation to Market

    U.S. Energy Information Administration (EIA) Indexed Site

    Processing: The Crucial Link Between Natural Gas Production and Its Transportation to Market Energy Information Administration, Office of Oil and Gas, January 2006 1 The natural gas product fed into the mainline gas transportation system in the United States must meet specific quality measures in order for the pipeline grid to operate properly. Consequently, natural gas produced at the wellhead, which in most cases contains contaminants 1 and natural gas liquids, 2 must be processed, i.e.,

  4. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate

  5. UNITED STATES OF AMERICA DEPARTMENT OF ENERGY OFFICE OF FOSSIL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    export liquefied natural gas (LNG) to any country with which the United States has a free trade agreement (FTA) that requires national treatment for trade in natural gas (FTA...

  6. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    2005-09-29

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  7. Desulfurization of coal with hydroperoxides of vegetable oils. [Quarterly progress report], December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, Ruozhi; Cheng, Jianjun; Shi, Feng; Gholson, K.L.; Ho, K.K.

    1995-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. Preliminary experiments showed that IBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During the first quarter the requirement of an added photosensitizer was eliminated, the catalytic effect of coal was confirmed, and the existence of a complex set of reactions was revealed. During this second quarter working with IBC-108 coal (2.3% organic S. 0.4% pyrite S), the effects of different ratios of oil:coal, different extraction solvents, and different temperatures were examined. A new pretreatment which combines alkali with linseed oil was discovered. Best organic sulfur removal is approximately 26% using alkali pretreatment combined with linseed oil at 1OO{degree}C. BTU loses can be kept to a minimum of 3% with proper use of solvents.

  8. Investigation of the effects of various water mediums on desulfurization and deashing of a coal sample by flotation

    SciTech Connect (OSTI)

    Ayhan, F.D. [Dicle University, Diyarbakir (Turkey)

    2009-08-15

    The aim of this study was to investigate the effects of various water mediums on desulfurization and deashing of a coal sample using flotation. For this purpose, experimental studies were conducted on a coal sample containing high ash and sulfur contents. The effects of pH, solid concentration, collector amount and frother amount on the flotation were investigated separately in Mediterranean Sea water, Cermik thermal spring water, snow water and tap water. Flotation, results indicated that, when comparing the various water mediums, the following order for the ash content was obtained: snow water < Cermik thermal spring water < tap water < the Mediterranean Sea water. For the reduction of total sulfur, the following order was obtained: snow water > Cermik thermal spring water > Mediterranean Sea water > tap water. When snow water was used as a flotation medium, it was found that a concentrate containing 3.01% total sulfur and 27.64% ash with a total sulfur reduction of 57.06% was obtained from a feed containing 7.01% total sulfur and 4.1.17% ash.

  9. Gas venting

    DOE Patents [OSTI]

    Johnson, Edwin F.

    1976-01-01

    Improved gas venting from radioactive-material containers which utilizes the passageways between interbonded impervious laminae.

  10. UNITED STATES OF AMERICA DEPARTMENT OF ENERGY OFFICE OF FOSSIL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    domestically produced liquefied natural gas (LNG) by vessel to nations with which the United States has not entered into a free trade agreement providing for national treatment...

  11. The Honorable Ernest Moniz Secretary, United States Department...

    Broader source: Energy.gov (indexed) [DOE]

    ME1 19100572v.1 October 22, 2014 The Honorable Ernest Moniz Secretary, United States ... Residential Gas Furnaces Dear Secretary Moniz: Thank you for the opportunity to brief ...

  12. Cement Kiln Flue Gas Recovery Scrubber Project

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2001-11-30

    The Cement Kiln Flue Gas Recovery Scrubber Project was a technical success and demonstrated the following: CKD can be used successfully as the sole reagent for removing SO2 from cement kiln flue gas, with removal efficiencies of 90 percent or greater; Removal efficiencies for HCl and VOCs were approximately 98 percent and 70 percent, respectively; Particulate emissions were low, in the range of 0.005 to 0.007 grains/standard cubic foot; The treated CKD sorbent can be recycled to the kiln after its potassium content has been reduced in the scrubber, thereby avoiding the need for landfilling; The process can yield fertilizer-grade K2SO4, a saleable by-product; and Waste heat in the flue gas can provide the energy required for evaporation and crystallization in the by-product recovery operation. The demonstration program established the feasibility of using the Recovery Scrubber{trademark} for desulfurization of flue gas from cement kilns, with generally favorable economics, assuming tipping fees are available for disposal of ash from biomass combustion. The process appears to be suitable for commercial use on any type of cement kiln. EPA has ruled that CKD is a nonhazardous waste, provided the facility meets Performance Standards for the Management of CKD (U.S. Environmental Protection Agency 1999d). Therefore, regulatory drivers for the technology focus more on reduction of air pollutants and pollution prevention, rather than on treating CKD as a hazardous waste. Application of the Recovery Scrubbe{trademark} concept to other waste-disposal operations, where pollution and waste reductions are needed, appears promising.

  13. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters ... Vacant housing units, seasonal units, second homes, military housing, and group quarters ...

  14. " Million Housing Units, Final"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters ... Vacant housing units, seasonal units, second homes, military housing, and group quarters ...

  15. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel Morrison

    2005-09-14

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2005 through June 30, 2005. During this time period efforts were directed toward (1) GSTC administration changes, (2) participating in the American Gas Association Operations Conference and Biennial Exhibition, (3) issuing a Request for Proposals (RFP) for proposal solicitation for funding, and (4) organizing the proposal selection meeting.

  16. Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  17. A method for direct, semi-quantitative analysis of gas phase...

    Office of Scientific and Technical Information (OSTI)

    ... Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY GC-ICP-MS; Gas phase analysis; Gas chromatography-inducti...

  18. Porous desulfurization sorbent pellets containing a reactive metal oxide and an inert zirconium compound

    SciTech Connect (OSTI)

    Gardner, Todd H.; Gasper-Galvin, Lee D.

    1996-12-01

    Sorbent pellets for removing hydrogen sulfide from coal gas are prepared by combining a reactive oxide, in particular zinc oxide, with a zirconium compound such as an oxide, silicate, or aluminate of zirconium, and an inorganic binder and pelletizing and calcining the mixture. Alternately, the zinc oxide may be replaced by copper oxide or a combination of copper, molybdenum, and manganese oxides. The pellet components may be mixed in dry form, moistened to produce a paste, and converted to pellets by forming an aqueous slurry of the components and spray drying the slurry, or the reactive oxide may be formed on existing zirconium-containing catalyst-carrier pellets by infusing a solution of a salt of the active metal onto the existing pellets and firing at a high temperature to produce the oxide. Pellets made according to this invention show a high reactivity with hydrogen sulfide and durability such as to be useful over repeated cycles of sorption and regeneration.

  19. Using high temperature baghouses to enhance desulfurization following economizer sorbent injection

    SciTech Connect (OSTI)

    Li, G.; Keener, T.C.

    1995-12-31

    In order to explore the potential of using high temperature baghouses to enhance SO{sub 2} removal following upstream sorbent injection, an integrated two-stage reactor system has been built. It consists of an injection stage and a filtration stage. Distinct from one-stage fixed-bed reactors, sorbent particles in this system are initially converted under controlled injection conditions before entering the filtration reactor chamber. By the aid of the system, several unique features regarding the gas-solid reactions in the baghouse after economizer zone sorbent injection have been revealed. Results have shown that the appropriate usage of a high temperature baghouse may substantially enhance the performance of the process. The further SO{sub 2} removal in the baghouse is comprehensively affected by both the conditions in the injection zone and those in the baghouse.

  20. NATURAL GAS FROM SHALE: Questions and Answers Why is Shale Gas Important?

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Why is Shale Gas Important? With the advance of extraction technology, shale gas production has led to a new abundance of natural gas supply in the United States over the past decade, and is expected to continue to do so for the foreseeable future. According to the Energy Information Administration (EIA), the unproved technically recoverable U.S. shale gas resource is estimated at 482 trillion cubic feet. 1 Estimated proved and unproved shale gas resources amount to a combined 542 trillion cubic

  1. Construction and start-up of a 250 kW natural gas fueled MCFC demonstration power plant

    SciTech Connect (OSTI)

    Figueroa, R.A.; Carter, J.; Rivera, R.; Otahal, J.

    1996-12-31

    San Diego Gas & Electric (SDG&E) is participating with M-C Power in the development and commercialization program of their internally manifolded heat exchanger (IMHEX{reg_sign}) carbonate fuel cell technology. Development of the IMHEX technology base on the UNOCAL test facility resulted in the demonstration of a 250 kW thermally integrated power plant located at the Naval Air Station at Miramar, California. The members of the commercialization team lead by M-C Power (MCP) include Bechtel Corporation, Stewart & Stevenson Services, Inc., and Ishikawajima-Harima Heavy Industries (IHI). MCP produced the fuel cell stack, Bechtel was responsible for the process engineering including the control system, Stewart & Stevenson was responsible for packaging the process equipment in a skid (pumps, desulfurizer, gas heater, turbo, heat exchanger and stem generator), IHI produced a compact flat plate catalytic reformer operating on natural gas, and SDG&E assumed responsibility for plant construction, start-up and operation of the plant.

  2. United States

    Office of Environmental Management (EM)

    E-T Global Energy, LLC OE Docket No. EA-381 Order Authorizing Electricity Exports to Mexico Order No. EA-381 June 10, 2011 I. BACKGROUND E-T Global Energy, LLC Order No. EA-381 Exports of electricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 301(b) and 402(f) of the Department ofEnergy Organization Act (42 U.S.C. 7151(b), 7172(f)) and require authorization under section 202(e) ofthe Federal Power Act (FPA) (16 U.S.C.824a(e))

  3. United States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    E-T Global Energy, LLC OE Docket No. EA-381 Order Authorizing Electricity Exports to Mexico Order No. EA-381 June 10, 2011 I. BACKGROUND E-T Global Energy, LLC Order No. EA-381 Exports of electricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 301(b) and 402(f) of the Department ofEnergy Organization Act (42 U.S.C. 7151(b), 7172(f)) and require authorization under section 202(e) ofthe Federal Power Act (FPA) (16 U.S.C.824a(e))

  4. United States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tenaslta Power Services Co. OE Docket No. EA-243-A Order Authorizing Electricity Exports to Canada Order No. EA-243-A March 1,2007 Tenaska Power Services Co. Order No. EA-243-A I. BACKGROUND Exports of elcctricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 30 I(b) and 402(f) of the Departrncnt of' Energy Organizatio~l Act (42 U, S.C. 7 15 1 (b), 7 1 72Cf)) and rcquirc authorization under section 202(e) of the Federal Power Act

  5. United States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TexMex Energy, LLC OE Docket No. EA-294-A Order Authorizing Electricity Exports to Mexico Order No. EA-294-A February 22, 2007 TexMex Energy, LLC Order No. EA-294-A I. BACKGROUND Exports of electricity from the United States to a foreign count~y are regulated by the Department of Energy (DOE) pursuant to sections 301(b) and 402(f) of the Department of Energy Organization Act (42 U.S.C. 7 15 1 (b), 71 72(f)) and require authorization under section 202(e) of the Federal Power Act (FPA) (16

  6. United States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CSW Power Marketing OE Docket No. EA-3 1 8 Order Authorizing Electricity Exports to Mexico Order No. EA-3 18 February 22,2007 CSW Power Marketing Order No. EA-318 I. BACKGROUND Exports of electricity from the United States to a foreign country are regulated by the Department of Energy (DOE) pursuant to sections 30l(b) and 402(f) of the Department of Energy Organization Act (42 U.S.C. 7 1 5 1 (b), 7 1 72(f)) and require authorization under section 202(e) of the Federal Power Act (FPA) (16

  7. US crude oil, natural gas, and natural gas liquids reserves, 1992 annual report

    SciTech Connect (OSTI)

    Not Available

    1993-10-18

    This report presents estimates of proved reserves of crude oil, natural gas, and natural gas liquids as of December 31, 1992, as well as production volumes for the United States, and selected States and State subdivisions for the year 1992. Estimates are presented for the following four categories of natural gas: total gas (wet after lease separation), its two major components (nonassociated and associated-dissolved gas), and total dry gas (wet gas adjusted for the removal of liquids at natural gas processing plants). In addition, two components of natural gas liquids, lease condensate and natural gas plant liquids, have their reserves and production data presented. Also included is information on indicated additional crude oil reserves and crude oil, natural gas, and lease condensate reserves in nonproducing reservoirs. A discussion of notable oil and gas exploration and development activities during 1992 is provided.

  8. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  9. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  10. Unconventional gas outlook: resources, economics, and technologies

    SciTech Connect (OSTI)

    Drazga, B.

    2006-08-15

    The report explains the current and potential of the unconventional gas market including country profiles, major project case studies, and new technology research. It identifies the major players in the market and reports their current and forecasted projects, as well as current volume and anticipated output for specific projects. Contents are: Overview of unconventional gas; Global natural gas market; Drivers of unconventional gas sources; Forecast; Types of unconventional gas; Major producing regions Overall market trends; Production technology research; Economics of unconventional gas production; Barriers and challenges; Key regions: Australia, Canada, China, Russia, Ukraine, United Kingdom, United States; Major Projects; Industry Initiatives; Major players. Uneconomic or marginally economic resources such as tight (low permeability) sandstones, shale gas, and coalbed methane are considered unconventional. However, due to continued research and favorable gas prices, many previously uneconomic or marginally economic gas resources are now economically viable, and may not be considered unconventional by some companies. Unconventional gas resources are geologically distinct in that conventional gas resources are buoyancy-driven deposits, occurring as discrete accumulations in structural or stratigraphic traps, whereas unconventional gas resources are generally not buoyancy-driven deposits. The unconventional natural gas category (CAM, gas shales, tight sands, and landfill) is expected to continue at double-digit growth levels in the near term. Until 2008, demand for unconventional natural gas is likely to increase at an AAR corresponding to 10.7% from 2003, aided by prioritized research and development efforts. 1 app.

  11. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-05-10

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January 1, 2006 through March 31, 2006. Activities during this time period were: (1) Organize and host the 2006 Spring Meeting in San Diego, CA on February 21-22, 2006; (2) Award 8 projects for co-funding by GSTC for 2006; (3) New members recruitment; and (4) Improving communications.

  12. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-03-31

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created - the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January1, 2007 through March 31, 2007. Key activities during this time period included: {lg_bullet} Drafting and distributing the 2007 RFP; {lg_bullet} Identifying and securing a meeting site for the GSTC 2007 Spring Proposal Meeting; {lg_bullet} Scheduling and participating in two (2) project mentoring conference calls; {lg_bullet} Conducting elections for four Executive Council seats; {lg_bullet} Collecting and compiling the 2005 GSTC Final Project Reports; and {lg_bullet} Outreach and communications.

  13. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-06-30

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2007 through June 30, 2007. Key activities during this time period included: (1) Organizing and hosting the 2007 GSTC Spring Meeting; (2) Identifying the 2007 GSTC projects, issuing award or declination letters, and begin drafting subcontracts; (3) 2007 project mentoring teams identified; (4) New NETL Project Manager; (5) Preliminary planning for the 2007 GSTC Fall Meeting; (6) Collecting and compiling the 2005 GSTC project final reports; and (7) Outreach and communications.

  14. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-07-06

    Gas storage is a critical element in the natural gas industry. Producers, transmission & distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1 to June 30, 2006. Key activities during this time period include: (1) Develop and process subcontract agreements for the eight projects selected for cofunding at the February 2006 GSTC Meeting; (2) Compiling and distributing the three 2004 project final reports to the GSTC Full members; (3) Develop template, compile listserv, and draft first GSTC Insider online newsletter; (4) Continue membership recruitment; (5) Identify projects and finalize agenda for the fall GSTC/AGA Underground Storage Committee Technology Transfer

  15. Virginia Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 ...

  16. Reliability of natural gas cogeneration systems

    SciTech Connect (OSTI)

    1995-12-01

    Cogeneration systems fueled by natural gas exceed the reliability of most central station power generating units, according to a study conducted by RINC Corporation for Gas Research Institute (GRI). In the study, researchers obtained operating data from 122 natural gas cogeneration units nationwide representing 2,200 megawatts (MW) of capacity and nearly 2 million hours of operating time at 37 facilities. Units were grouped into categories reflecting size (from 60 kilowatts to 100 MW), type of system (gas engine or gas turbine technology), use of emission controls, and type of thermal application. Various types and sizes of gas systems reported average availability factors ranging from 90.0 to 95.8 versus a weighted average of 85.9 percent for fossil-fuel steam, nuclear, and gas-turbine-based central station power generating units. Comparisons are based on study data and data reported by the North American Electric Reliability Council for utility power plants. Gas cogeneration can improve utility operations because as a group the relatively small, dispersed cogeneration units are more reliable than one or more large central station units of similar capacity.

  17. LIFAC sorbent injection desulfurization demonstration project. Final report, volume II: Project performance and economics

    SciTech Connect (OSTI)

    1996-01-01

    This publication discusses the demonstration of the LIFAC sorbent injection technology at Richmond Power and Light`s Whitewater Valley Unit No. 2, performed under the auspices of the U.S. Department of Energy`s (DOE) Clean Coal Technology Program. LIFAC is a sorbent injection technology capable of removing 75 to 85 percent of a power plant`s SO{sub 2} emissions using limestone at calcium to sulfur molar ratios of between 2 and 2.5 to 1. The site of the demonstration is a coal-fired electric utility power plant located in Richmond, Indiana. The project is being conducted by LIFAC North America (LIFAC NA), a joint venture partnership of Tampella Power Corporation and ICF Kaiser Engineers, in cooperation with DOE, RP&L, and Research Institute (EPRI), the State of Indiana, and Black Beauty Coal Company. The purpose of Public Design Report Volume 2: Project Performance and Economics is to consolidate, for public use, the technical efficiency and economy of the LIFAC Process. The report has been prepared pursuant to the Cooperative Agreement No. DE-FC22-90PC90548 between LIFAC NA and the U.S. Department of Energy.

  18. What is shale gas and why is it important?

    Reports and Publications (EIA)

    2012-01-01

    Shale gas refers to natural gas that is trapped within shale formations. Shales are fine-grained sedimentary rocks that can be rich sources of petroleum and natural gas. Over the past decade, the combination of horizontal drilling and hydraulic fracturing has allowed access to large volumes of shale gas that were previously uneconomical to produce. The production of natural gas from shale formations has rejuvenated the natural gas industry in the United States.

  19. Hydrogen Production: Natural Gas Reforming | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Reforming Hydrogen Production: Natural Gas Reforming Photo of Petroleum Refinery Natural gas reforming is an advanced and mature production process that builds upon the existing natural gas pipeline delivery infrastructure. Today, 95% of the hydrogen produced in the United States is made by natural gas reforming in large central plants. This is an important technology pathway for near-term hydrogen production. How Does It Work? Natural gas contains methane (CH4) that can be used to

  20. Water management technologies used by Marcellus Shale Gas Producers.

    SciTech Connect (OSTI)

    Veil, J. A.; Environmental Science Division

    2010-07-30

    Natural gas represents an important energy source for the United States. According to the U.S. Department of Energy's (DOE's) Energy Information Administration (EIA), about 22% of the country's energy needs are provided by natural gas. Historically, natural gas was produced from conventional vertical wells drilled into porous hydrocarbon-containing formations. During the past decade, operators have increasingly looked to other unconventional sources of natural gas, such as coal bed methane, tight gas sands, and gas shales.

  1. Nebraska Dry Natural Gas Production (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    Processing: The Crucial Link Between Natural Gas Production and Its Transportation to Market Energy Information Administration, Office of Oil and Gas, January 2006 1 The natural gas product fed into the mainline gas transportation system in the United States must meet specific quality measures in order for the pipeline grid to operate properly. Consequently, natural gas produced at the wellhead, which in most cases contains contaminants 1 and natural gas liquids, 2 must be processed, i.e.,

  2. EIA - Natural Gas Pipeline Network - Natural Gas Import/Export Locations

    U.S. Energy Information Administration (EIA) Indexed Site

    List Pipelines > Import/Export Location List About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Currently, there are 58 locations at which natural gas can be exported or imported into the United States, including 9 LNG (liquefied natural gas) facilities in the continental United States and Alaska (There is a tenth U.S. LNG import facility located in Puerto Rico). At 28 of these locations natural gas or LNG currently can only

  3. Enhanced durability for high-temperature desulfurization sorbents for moving-bed applications -- Option 3 program: Development and testing of additional zinc titanate sorbents. Final report, September 1992--May 1996

    SciTech Connect (OSTI)

    Ayala, R.E.; Chuck, T.L.

    1996-12-31

    GE is developing a moving-bed, high-temperature desulfurization system for the integrated gasification combined-cycle (IGCC) power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.`s Polk Power Station. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The objective of this contract is to identify and test sorbent fabrication methods and chemical compositions that enhance the long-term chemical reactivity and mechanical strength of zinc titanate and other novel sorbents for moving-bed, high-temperature desulfurization of coal-derived gases. A parametric study on the use of calcium sulfate additives to zinc titanate was conducted for zinc titanates having a 2:1 and 1.5:1 zinc-to-titanium molar ratio, and they showed a beneficial effect on crush strength of fresh 2:1 zinc titanate sorbents. In addition, a test procedure was developed to screen sorbent formulations based on resistance to spalling and pellet breakage induced by zinc sulfate formation in the presence of sulfur dioxide and excess oxygen conditions.

  4. Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report

    SciTech Connect (OSTI)

    Dismukes, E.B.

    1994-10-20

    This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

  5. Termination unit

    DOE Patents [OSTI]

    Traeholt, Chresten [Frederiksberg, DK; Willen, Dag [Klagshamn, SE; Roden, Mark [Newnan, GA; Tolbert, Jerry C [Carrollton, GA; Lindsay, David [Carrollton, GA; Fisher, Paul W [Heiskell, TN; Nielsen, Carsten Thidemann [Jaegerspris, DK

    2014-01-07

    This invention relates to a termination unit comprising an end-section of a cable. The end section of the cable defines a central longitudinal axis and comprising end-parts of N electrical phases, an end-part of a neutral conductor and a surrounding thermally insulation envelope adapted to comprising a cooling fluid. The end-parts of the N electrical phases and the end-part of the neutral conductor each comprising at least one electrical conductor and being arranged in the cable concentrically around a core former with a phase 1 located relatively innermost, and phase N relatively outermost in the cable, phase N being surrounded by the neutral conductor, electrical insulation being arrange between neighboring electrical phases and between phase N and the neutral conductor, and wherein the end-parts of the neutral conductor and the electrical phases each comprise a contacting surface electrically connected to at least one branch current lead to provide an electrical connection: The contacting surfaces each having a longitudinal extension, and being located sequentially along the longitudinal extension of the end-section of the cable. The branch current leads being individually insulated from said thermally insulation envelope by individual electrical insulators.

  6. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  7. Assessment of the Adequacy of Natural Gas Pipeline Capacity in the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Northeast United States - November 2013 | Department of Energy Assessment of the Adequacy of Natural Gas Pipeline Capacity in the Northeast United States - November 2013 Assessment of the Adequacy of Natural Gas Pipeline Capacity in the Northeast United States - November 2013 In 2005-06, the Office of Electricity Delivery and Energy Reliability (OE) conducted a study on the adequacy of interstate natural gas pipeline capacity serving the northeastern United States to meet natural gas demand

  8. Renewable Energy Holdings Landfill Gas Wales Ltd REH Wales |...

    Open Energy Info (EERE)

    Gas Wales Ltd REH Wales Jump to: navigation, search Name: Renewable Energy Holdings Landfill Gas (Wales) Ltd (REH Wales) Place: United Kingdom Product: A joint venture to own and...

  9. Natural Gas Weekly Update, Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    gas into the United States continue to grow steadily. Pipeline imports of natural gas from Canada increased by slightly more than 5 percent in 2000 to 3.54 Tcf, following a...

  10. Gas magnetometer

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2016-05-03

    Measurement of a precessional rate of a gas, such as an alkali gas, in a magnetic field is made by promoting a non-uniform precession of the gas in which substantially no net magnetic field affects the gas during a majority of the precession cycle. This allows sensitive gases that would be subject to spin-exchange collision de-phasing to be effectively used for extremely sensitive measurements in the presence of an environmental magnetic field such as the Earth's magnetic field.

  11. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  12. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  13. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, ... Grid Integration & Advanced Inverters Materials & Fabrication Microsystems Enabled ...

  14. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Use of central air conditioning equipment for another housing unit also ...

  15. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Housing units are classified as urban or rural using definitions created by ...

  16. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Use of heating equipment for another housing unit also includes the use of ...

  17. " Million Housing Units, Final"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Use of central air conditioning equipment for another housing unit also ...

  18. ARM - Measurement - Trace gas concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsTrace gas concentration ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Trace gas concentration The amount per unit volume of trace gases other than carbon dioxide, nitrogen oxides, ozone and water vapor, typically measured in conjunction with in situ aerosol measurements, e.g. carbon monoxide, and sulfur dioxide. Categories Atmospheric State, Atmospheric Carbon Instruments The above

  19. Reducing water freshwater consumption at coal-fired power plants : approaches used outside the United States.

    SciTech Connect (OSTI)

    Elcock, D.

    2011-05-09

    Coal-fired power plants consume huge quantities of water, and in some water-stressed areas, power plants compete with other users for limited supplies. Extensive use of coal to generate electricity is projected to continue for many years. Faced with increasing power demands and questionable future supplies, industries and governments are seeking ways to reduce freshwater consumption at coal-fired power plants. As the United States investigates various freshwater savings approaches (e.g., the use of alternative water sources), other countries are also researching and implementing approaches to address similar - and in many cases, more challenging - water supply and demand issues. Information about these non-U.S. approaches can be used to help direct near- and mid-term water-consumption research and development (R&D) activities in the United States. This report summarizes the research, development, and deployment (RD&D) status of several approaches used for reducing freshwater consumption by coal-fired power plants in other countries, many of which could be applied, or applied more aggressively, at coal-fired power plants in the United States. Information contained in this report is derived from literature and Internet searches, in some cases supplemented by communication with the researchers, authors, or equipment providers. Because there are few technical, peer-reviewed articles on this topic, much of the information in this report comes from the trade press and other non-peer-reviewed references. Reducing freshwater consumption at coal-fired power plants can occur directly or indirectly. Direct approaches are aimed specifically at reducing water consumption, and they include dry cooling, dry bottom ash handling, low-water-consuming emissions-control technologies, water metering and monitoring, reclaiming water from in-plant operations (e.g., recovery of cooling tower water for boiler makeup water, reclaiming water from flue gas desulfurization [FGD] systems), and

  20. Compact, high energy gas laser

    DOE Patents [OSTI]

    Rockwood, Stephen D.; Stapleton, Robert E.; Stratton, Thomas F.

    1976-08-03

    An electrically pumped gas laser amplifier unit having a disc-like configuration in which light propagation is radially outward from the axis rather than along the axis. The input optical energy is distributed over a much smaller area than the output optical energy, i.e., the amplified beam, while still preserving the simplicity of parallel electrodes for pumping the laser medium. The system may thus be driven by a comparatively low optical energy input, while at the same time, owing to the large output area, large energies may be extracted while maintaining the energy per unit area below the threshold of gas breakdown.

  1. RESEARCH AND DEVELOPMENT OF AN INTEGRAL SEPARATOR FOR A CENTRIFUGAL GAS PROCESSING FACILITY

    SciTech Connect (OSTI)

    LANCE HAYS

    2007-02-27

    A COMPACT GAS PROCESSING DEVICE WAS INVESTIGATED TO INCREASE GAS PRODUCTION FROM REMOTE, PREVIOUSLY UN-ECONOMIC RESOURCES. THE UNIT WAS TESTED ON AIR AND WATER AND WITH NATURAL GAS AND LIQUID. RESULTS ARE REPORTED WITH RECOMMENDATIONS FOR FUTURE WORK.

  2. Pacific Gas and Electric Company | Open Energy Information

    Open Energy Info (EERE)

    Company Jump to: navigation, search Name: Pacific Gas and Electric Company Address: PO Box 770000 Place: San Francisco Zip: 94177 Region: United States Sector: Marine and...

  3. BP Gas Power and Renewables | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: BP Gas, Power and Renewables Place: Central Milton Keynes, United Kingdom Zip: MK9 1ES Sector: Renewable Energy Product: Subsidiary of...

  4. Secretary Moniz: What the Natural Gas Boom Means for Renewables...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    United States should take advantage of the natural gas boom and use it as an opportunity to further develop renewable energy sources like wind, solar, geothermal, and hydropower. ...

  5. Natural Gas Vehicle Cost Calculator | Open Energy Information

    Open Energy Info (EERE)

    Vehicle Cost Calculator Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Natural Gas Vehicle Cost Calculator AgencyCompany Organization: United States Department of...

  6. File:EIA-shale-gas.pdf | Open Energy Information

    Open Energy Info (EERE)

    Lower 48 States Sources Energy Information Administration Related Technologies Natural Gas Creation Date 2010-03-10 Extent National Countries United States UN Region Northern...

  7. File:EIA-tight-gas.pdf | Open Energy Information

    Open Energy Info (EERE)

    48 States Sources U.S. Energy Information Administration Related Technologies Natural Gas Creation Date 2010-06-06 Extent National Countries United States UN Region Northern...

  8. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    to the technology that drove Enron's North American wholesale electricity and natural gas trading unit. That technology, together with reportedly over 600 former Enron...

  9. Unconventional Oil and Gas Projects Help Reduce Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    Unconventional Oil and Gas Projects Help Reduce Environmental Impact of Development Since the first commercial oil well was drilled in the United States in 1859, most of the ...

  10. Distribution of Natural Gas: The Final Step in the Transmission...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Figure 1. Storage Gas Plant LNG Storage Imports Trucked Source: Energy Information ... electric generation units in existing coal- and oil-fired power plants and the construction of ...

  11. Hot gas engine heater head

    DOE Patents [OSTI]

    Berntell, John O.

    1983-01-01

    A heater head for a multi-cylinder double acting hot gas engine in which each cylinder is surrounded by an annular regenerator unit, and in which the tops of each cylinder and its surrounding regenerator are interconnected by a multiplicity of heater tubes. A manifold for the heater tubes has a centrally disposed duct connected to the top of the cylinder and surrounded by a wider duct connecting the other ends of the heater tubes with the regenerator unit.

  12. Middle East oil and gas

    SciTech Connect (OSTI)

    Not Available

    1984-12-01

    The following subjects are covered in this publication: (1) position of preeminence of the Middle East; (2) history of area's oil operations for Iran, Iraq, Bahrain, Kuwait, Saudi Arabia, neutral zone, Qatar, United Arab Emirates, Oman and Egypt; (3) gas operations of Saudi Arabia, Iran, Kuwait, Qatar, Iraq and United Arab Emirates; (4) changing relationships with producing countries; (5) a new oil pricing environment; (6) refining and other industrial activities; and (7) change and progress. 10 figs., 12 tabs.

  13. Trends in U.S. Residential Natural Gas Consumption

    Reports and Publications (EIA)

    2010-01-01

    This report presents an analysis of residential natural gas consumption trends in the United States through 2009 and analyzes consumption trends for the United States as a whole (1990 through 2009) and for each Census division (1998 through 2009).

  14. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    Water Heating in U.S. Homes, by Housing Unit Type, 2009" " Million Housing Units, Final" ... Units","5 or More Units","Mobile Homes" "Water Heating" "Total Homes",113.6,71.8,6.7,9,19...

  15. Hot-gas conditioning of biomass derived synthesis gas

    SciTech Connect (OSTI)

    Paisley, M.A.; Litt, R.D.

    1993-12-31

    Battelle has tested selected catalysts to evaluate the potential for hot-gas conditioning of biomass gasifier product gas to modify the product gas to produce a gas suitable for methanol synthesis. The Battelle Process Research Unit (PRU) gasifier was utilized as a source of a stable supply of product gas that contained all of the trace constituents that might be present in a commercial scale gasification system. One goal of alternate fuel generation with renewable biomass fuels is the production of a liquid transportation fuel such as methanol. The hot-gas conditioning tests run were planned to evaluate commercial catalysts that would crack hydrocarbons and provide water gas shift activity to adjust the product gas composition for methanol synthesis. During the test program, a novel, low cost catalyst, was identified that showed high levels of activity and stability. The composition of this catalyst is such that it has the potential to be a disposable catalyst and is free from hazardous materials. The initial tests with this catalyst showed high levels of water gas shift activity superior to, and hydrocarbon cracking activity nearly as high as, a commercial cracking catalyst tested.

  16. Table 7.7 Quantity of Purchased Electricity, Natural Gas, and Steam, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Quantity of Purchased Electricity, Natural Gas, and Steam, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Supplier Sources of Purchased Electricity, Natural Gas, and Steam; Unit: Physical Units or Btu. Electricity Components Natural Gas Components Steam Components Electricity Natural Gas Steam Electricity from Sources Natural Gas from Sources Steam from Sources Electricity from Local Other than Natural Gas from Local Other than Steam from Local Other than NAICS Total

  17. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R. K.; Im, K. H.

    1996-01-01

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

  18. Method for removing metal vapor from gas streams

    DOE Patents [OSTI]

    Ahluwalia, R.K.; Im, K.H.

    1996-04-02

    A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

  19. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-09-30

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created-the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of July 1, 2006 to September 30, 2006. Key activities during this time period include: {lg_bullet} Subaward contracts for all 2006 GSTC projects completed; {lg_bullet} Implement a formal project mentoring process by a mentor team; {lg_bullet} Upcoming Technology Transfer meetings: {sm_bullet} Finalize agenda for the American Gas Association Fall Underground Storage Committee/GSTC Technology Transfer Meeting in San Francisco, CA. on October 4, 2006; {sm_bullet} Identify projects and finalize agenda for the Fall GSTC Technology

  20. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-07-15

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. Base funding for the consortium is provided by the U.S. Department of Energy (DOE). In addition, funding is anticipated from the Gas Technology Institute (GTI). The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with

  1. GAS STORAGE TECHNOLGOY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-04-23

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. Base funding for the consortium is provided by the U.S. Department of Energy (DOE). In addition, funding is anticipated from the Gas Technology Institute (GTI). The first phase, Phase 1A, was initiated on September 30, 2003, and is scheduled for completion on March 31, 2004. Phase 1A of the project includes the creation of the GSTC structure, development of constitution (by-laws) for the consortium, and development and refinement of a technical approach (work plan) for

  2. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-04-17

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. Base funding for the consortium is provided by the U.S. Department of Energy (DOE). In addition, funding is anticipated from the Gas Technology Institute (GTI). The first phase, Phase 1A, was initiated on September 30, 2003, and is scheduled for completion on March 31, 2004. Phase 1A of the project includes the creation of the GSTC structure, development of constitution (by-laws) for the consortium, and development and refinement of a technical approach (work plan) for

  3. EIA - Natural Gas Pipeline Network - Natural Gas Imports/Exports Pipelines

    U.S. Energy Information Administration (EIA) Indexed Site

    Pipelines About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Import/Export Pipelines As of the close of 2008 the United States has 58 locations where natural gas can be exported or imported. 24 locations are for imports only 18 locations are for exports only 13 locations are for both imports and exports 8 locations are liquefied natural gas (LNG) import facilities Imported natural gas in 2007 represented almost 16 percent

  4. High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines: Phase 1, Laboratory investigations. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    1995-03-01

    Research under Subtask 2.2, Chemical and Mineralogical Characterization, included further refinement of mineralogical transformation and the initiation of a kinetic study. The expansion of the FGD materials during moisturizing is attributable to three reactions: the hydration of portlandite to slaked lime; the formation of ettringite from fly ash and anhydrite, and; the formation of gypsum from anhydrite. The sequence of these reactions are being examined in a kinetic study. Completion of the first 15 days of study finds the steady decrease in anhydrite with concomitant formation of ettringite (on fly ash surfaces) and gypsum (pore and crack in-fillings). Geotechnical characterization (Subtask 2.3) focused on swell experiments which will model in situ emplacement. Specimens of FGD material have been stored in 3-inch diameter pipe and, after 39 days, 0.5% of axial swell has been recorded with material strengths of 600 to 1,000 psi. Experiments to determine the amount of moisture loss due to the heat of hydration indicate about 9 to 10% of the water is lost. Confined swell tests are also underway with pressures of 15 to 20 psi recorded at 25 days. Work performed under Task 4 (Background for Phase II) included determination of the compressive strengths for the experimental mine roof rock. Values in the 5,000 to 7,500 psi range were found, which is typical for this type of strata in the region. Work on the hydrologic monitoring program (Subtask 4.2) included completion of the hydraulic conductivity assessment of the strata, as well as completion of the monitoring well plan. The highest hydraulic conductivity was found for the Princess No. 3 coal seam with values of 1{times}10{sup {minus}3} feet/min. The weathered sandstone over the coal had conductivities in the 10{sup {minus}4} to 10{sup {minus}5} feet/min. range.

  5. High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    1995-03-01

    Research under Subtask 2.2, Chemical and Mineralogical Characterization, included further refinement of mineralogical transformation and the initiation of a kinetic study. The expansion of the FGD materials during moisturizing is attributable to three reactions: the hydration of portlandite to slaked lime; the formation of ettringite from fly ash and anhydrite, and; the formation of gypsum from anhydrite. The sequence of these reactions are being examined in a kinetic study. Completion of the first 15 days of study finds the steady decrease in anhydrite with concomitant formation of ettringite (on fly ash surfaces) and gypsum (pore and crack in-fillings). Geotechnical characterization (Subtask 2.3) focused on swell experiments which will model in situ emplacement. Specimens of FGD material have been stored in 3-inch diameter pipe and, after 39 days, 0.5% of axial swell has been recorded with material strengths of 600 to 1,000 psi. Experiments to determine the amount of moisture loss due to the heat of hydration indicate about 9 to 10% of the water is lost. Confined swell tests are also underway with pressures of 15 to 20 psi recorded at 25 days. Work performed under Task 4 (Background for Phase 11) included determination of the compressive strengths for the experimental mine roof rock. Values in the 5,000 to 7,500 psi range were found, which is typical for this type of strata in the region. Work on the hydrologic monitoring program (Subtask 4.2) included completion of the hydraulic conductivity assessment of the strata, as well as completion of the monitoring well plan. The highest hydraulic conductivity was found for the Princes No. 3 coal seam with values of 1x10{sup -3} feet/min. The weathered sandstone over the coal had conductivities in the 10{sup -4} to 10{sup -5} feet/min range.

  6. High volume - high value usage of Flue Gas Desulfurization (FGD) by-products in underground mines. Quarterly report, October 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    The amount of dry FGD materials produced in the U.S. has not been increasing at the high rate originally anticipated. This has been due to a number of economic factors affecting the utility industry. Technologies for the disposal of large amounts of materials are not going to be implemented in the near term. In light of this development the target application for this project is being changed from highwall adit filling to the filling of auger holes to allow for highwall mining. This application focuses on using the dry FGD material to recover coal isolated by excessive augering. It produces 10 or more times the amount of coal per ton of dry FGD utilized than the originally proposed methodology. It also does not require extensive equipment development and, if applied to abandoned mine lands, may have substantially more significant environmental benefit. We also propose to use a spray dryer material for the demonstration instead of the fluidized bed material originally proposed. The spray dryer material is already slacked eliminating problems associated with heat generation at the mine site. Auger hole grouting with FGD material is also best performed by hydraulic emplacement methods.

  7. Separation of flue-gas scrubber sludge into marketable products

    SciTech Connect (OSTI)

    Kawatra, S.K.; Eisele, T.C.

    1997-08-31

    A tremendous amount of wet flue-gas desulfurization scrubber sludge (estimated 20 million metric tons per year in the US) is currently being landfilled at a huge cost to utility companies. Scrubber sludge is the solid precipitate produced during desulfurization of flue-gas from burning high sulfur coal. The amount of this sludge is expected to increase in the near future due to ever increasing governmental regulation concerning the amount of sulfur emissions. Scrubber sludge is a fine, grey colored powder that contains calcium sulfite hemihydrate (CaSO{sub 3} {center_dot} 1/2H{sub 2}), calcium sulfate dihydrate (CaSO{sub 4} {center_dot} 2H{sub 2}O), limestone (CaCO{sub 3}), silicates, and iron oxides. This material can continue to be landfilled at a steadily increasing cost, or an alternative for utilizing this material can be developed. This study explores the characteristics of a naturally oxidized wet flue-gas desulfurization scrubber sludge and uses these characteristics to develop alternatives for recycling this material. In order for scrubber sludge to be used as a feed material for various markets, it was necessary to process it to meet the specifications of these markets. A physical separation process was therefore needed to separate the components of this sludge into useful products at a low cost. There are several physical separation techniques available to separate fine particulates. These techniques can be divided into four major groups: magnetic separation, electrostatic separation, physico-chemical separation, and density-based separation. The properties of this material indicated that two methods of separation were feasible: water-only cycloning (density-based separation), and froth flotation (physico-chemical separation). These processes could be used either separately, or in combination. The goal of this study was to reduce the limestone impurity in this scrubber sludge from 5.6% by weight to below 2.0% by weight. The resulting clean calcium

  8. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-10-18

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with Phase 1B and encompasses the period July 1, 2004, through September 30, 2004. During this time period there were three main activities. First was the ongoing

  9. Majors' Shift to Natural Gas, The

    Reports and Publications (EIA)

    2001-01-01

    The Majors' Shift to Natural Gas investigates the factors that have guided the United States' major energy producers' growth in U.S. natural gas production relative to oil production. The analysis draws heavily on financial and operating data from the Energy Information Administration's Financial Reporting System (FRS)

  10. ARM - Lesson Plans: Measuring Quantities of Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measuring Quantities of Gas Outreach Home Room News Publications Traditional Knowledge Kiosks Barrow, Alaska Tropical Western Pacific Site Tours Contacts Students Study Hall About ARM Global Warming FAQ Just for Fun Meet our Friends Cool Sites Teachers Teachers' Toolbox Lesson Plans Lesson Plans: Measuring Quantities of Gas Objective The objective is to enable students to become familiar with the measuring units of small amounts of gas in the atmosphere which may otherwise be confusing Materials

  11. Southern California Gas | Energy Systems Integration | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Southern California Gas Southern California Gas Company has joined with NREL and the National Fuel Cell Research Center to launch demonstration projects to create and test a carbon-free, power-to-gas system for the first time ever in the United States. The technology converts electricity into gaseous energy and could provide North America with a large-scale, cost-effective solution for storing excess energy produced from renewable sources. Read our news story on the project.

  12. IEA Webinar: Green Gas

    Broader source: Energy.gov [DOE]

    As part of the International Energy Agency (IEA) Bioenergy Internal Webinar Series, the Energy Department’s Bioenergy Technologies Office invites you to join a webinar on Thursday, June 2, 2016, at 8 a.m. Eastern Time. During the webinar, participants will learn about the technologies and feedstocks that can contribute to reaching 100% green gas in the gas grid by 2050. The international webinar—Green Gas—will be presented by Professor Jerry D. Murphy, task leader for IEA Bioenergy Task 37 on Energy from Biogas. IEA is an autonomous international organization that studies energy issues related to reliability, affordability, and sustainability. Instructions on how to join the webinar are below. View the international toll free numbers to find your dial-in number (for the United States and Canada, dial 1-888-289-4573).

  13. Maintaining gas cooling equipment

    SciTech Connect (OSTI)

    Rector, J.D.

    1997-05-01

    An often overlooked key to satisfactory operation and longevity of any mechanical device is proper operation and maintenance in accordance with the manufacturer`s written instructions. Absorption chillers, although they use a different technology than the more familiar vapor compression cycle to produce chilled water, operate successfully in a variety of applications if operated and maintained properly. Maintenance procedures may be more frequent than those required for vapor compression chillers, but they are also typically less complex. The goal of this article is to describe the basic operation of an absorption chiller to provide an understanding of the relatively simple tasks required to keep the machine operating at maximum efficiency for its design life and beyond. A good starting point is definitions. Gas cooling equipment is generally defined as alternative energy, non-electric cooling products. This includes absorption chillers, engine-drive chillers and packaged desiccant units, among others. Natural gas combustion drives the equipment.

  14. Produce diesel from gas

    SciTech Connect (OSTI)

    Singleton, A.H.; Regier, S.

    1983-05-01

    The Gulf Badger process converts natural gas directly to hydrocarbon liquids by a catalytic chemical route. Fischer-Tropsch process--which is a carbon monoxide polymerization/ hydrogenation process--is used. Because the process is exothermal, heat removal by either tubular fixed bed, fluidized bed, or slurry are considered. A wax build up of high molecular weight material is removed by hydro-stripping two-bed system. The demonstration plant flow diagram shows the process to be: natural gas is compressed, recycled with CO/sub 2/, sulfur is removed in a zinc oxide drum, CO is removed in amine scrubbers, H/sub 2//CO ratio is adjusted to produce a hydrogen rich stream, and stabilization and distribution follow. A monitoring system using computers is part of the demonstration unit.

  15. Desulfurization Fuel Filter

    Broader source: Energy.gov [DOE]

    Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

  16. Estimated United States Transportation Energy Use 2005

    SciTech Connect (OSTI)

    Smith, C A; Simon, A J; Belles, R D

    2011-11-09

    A flow chart depicting energy flow in the transportation sector of the United States economy in 2005 has been constructed from publicly available data and estimates of national energy use patterns. Approximately 31,000 trillion British Thermal Units (trBTUs) of energy were used throughout the United States in transportation activities. Vehicles used in these activities include automobiles, motorcycles, trucks, buses, airplanes, rail, and ships. The transportation sector is powered primarily by petroleum-derived fuels (gasoline, diesel and jet fuel). Biomass-derived fuels, electricity and natural gas-derived fuels are also used. The flow patterns represent a comprehensive systems view of energy used within the transportation sector.

  17. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... central air conditioning equipment for a business or farm building as well as another ... for Housing Unit Type" ,,,,"Single-Family Units",,,,"Apartments in Buildings With" ...

  18. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... central air conditioning equipment for a business or farm building as well as another ... ,,"RSEs for Housing Unit Type" ,,"Single-Family Units",,"Apartments in Buildings With" ...

  19. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Cooking includes fuels used by the major cooking equipment (ovens, cooktops, ...

  20. Utility FGD Survey, January--December 1989

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M. )

    1992-03-01

    The Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. The development status (operational, under construction, or in the planning stages), system supplier, process, waste disposal practice, and regulatory class are tabulated alphabetically by utility company.

  1. Utility FGD survey, January--December 1989

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M. )

    1992-03-01

    This is Volume 2 part 2, of the Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. This volume particularly contains basic design and performance data.

  2. Utility FGD survey, January--December 1989. Volume 2, Design performance data for operating FGD systems: Part 2

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M.

    1992-03-01

    This is Volume 2 part 2, of the Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. This volume particularly contains basic design and performance data.

  3. Utility FGD Survey, January--December 1989. Volume 2, Design performance data for operating FGD systems, Part 1

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M.

    1992-03-01

    The Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. The development status (operational, under construction, or in the planning stages), system supplier, process, waste disposal practice, and regulatory class are tabulated alphabetically by utility company.

  4. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  5. US imports and exports of natural gas, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-03

    United States pipeline imports and exports of natural gas and of liquefied natural gas (LNG) are given for 1979. Data are filed on Federal Energy Regulatory Commission (FERC) Form FPC-14 by 28 pipeline companies. Volume and unit cost for imports and for exports of both natural gas and LNG are given by company and by year. Most data are for the two most recent years, with a summary table of the US natural gas pipeline import/export balance since 1955. An introductory text highlights gas and LNG imports and exports for the countries of destination. 7 tables.

  6. Top 100 Oil and Gas Fields of 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Top 100 Oil and Gas Fields of 2009 Introduction This supplement to the Energy Information Administration's summary of U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Proved Reserves, 2009 ranks the United States' largest oil and gas fields by their estimated 2009 proved reserves. The Top 100's Share of U.S. Proved Reserves in 2009 The Top 100 oil fields and Top 100 gas fields each accounted for about 60 percent of the respective total proved reserves of the United States. The Top 100 oil

  7. Natural gas vehicles : Status, barriers, and opportunities.

    SciTech Connect (OSTI)

    Rood Werpy, M.; Santini, D.; Burnham, A.; Mintz, M.; Energy Systems

    2010-11-29

    In the United States, recent shale gas discoveries have generated renewed interest in using natural gas as a vehicular fuel, primarily in fleet applications, while outside the United States, natural gas vehicle use has expanded significantly in the past decade. In this report for the U.S. Department of Energy's Clean Cities Program - a public-private partnership that advances the energy, economic, and environmental security of the U.S. by supporting local decisions that reduce petroleum use in the transportation sector - we have examined the state of natural gas vehicle technology, current market status, energy and environmental benefits, implications regarding advancements in European natural gas vehicle technologies, research and development efforts, and current market barriers and opportunities for greater market penetration. The authors contend that commercial intracity trucks are a prime area for advancement of this fuel. Therefore, we examined an aggressive future market penetration of natural gas heavy-duty vehicles that could be seen as a long-term goal. Under this scenario using Energy Information Administration projections and GREET life-cycle modeling of U.S. on-road heavy-duty use, natural gas vehicles would reduce petroleum consumption by approximately 1.2 million barrels of oil per day, while another 400,000 barrels of oil per day reduction could be achieved with significant use of natural gas off-road vehicles. This scenario would reduce daily oil consumption in the United States by about 8%.

  8. How EIA Estimates Natural Gas Production

    Reports and Publications (EIA)

    2004-01-01

    The Energy Information Administration (EIA) publishes estimates monthly and annually of the production of natural gas in the United States. The estimates are based on data EIA collects from gas producing states and data collected by the U. S. Minerals Management Service (MMS) in the Department of Interior. The states and MMS collect this information from producers of natural gas for various reasons, most often for revenue purposes. Because the information is not sufficiently complete or timely for inclusion in EIA's Natural Gas Monthly (NGM), EIA has developed estimation methodologies to generate monthly production estimates that are described in this document.

  9. UNITED STATES OF AMERICA

    Office of Environmental Management (EM)

    of natural gas, including LNG, from and to a nation with which there is in effect a free trade agreement requiring national treatment for trade in natural gas and the import of...

  10. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  11. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas demand, thereby contributing to larger net injections of natural gas into storage. Other Market Trends: EIA Releases The Natural Gas Annual 2006: The Energy...

  12. GAS SEAL

    DOE Patents [OSTI]

    Monson, H.; Hutter, E.

    1961-07-11

    A seal is described for a cover closing an opening in the top of a pressure vessel that may house a nuclear reactor. The seal comprises a U-shaped trough formed on the pressure vessel around the opening therein, a mass of metal in the trough, and an edge flange on the cover extending loosely into the trough and dipping into the metal mass. The lower portion of the metal mass is kept melted, and the upper portion, solid. The solid pontion of the metal mass prevents pressure surges in the vessel from expelling the liquid portion of the metal mass from the trough; the liquld portion, thus held in place by the solid portion, does not allow gas to go through, and so gas cannot escape through shrinkage holes in the solid portion.

  13. The Honorable Ernest Moniz Secretary, United States Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ME1 19100572v.1 October 22, 2014 The Honorable Ernest Moniz Secretary, United States Department of Energy 1000 Independence Avenue, SW Washington, D.C. 20585 RE: Separate Product Classes for Non-Weatherized Residential Gas Furnaces Dear Secretary Moniz: Thank you for the opportunity to brief your staff in recent weeks on an impact analysis of a national condensing furnace standard, which was conducted jointly by the American Gas Association (AGA), the American Public Gas Association (APGA), and

  14. New Mexico Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) New Mexico Natural Gas in Underground Storage (Base Gas) ... Underground Base Natural Gas in Storage - All Operators New Mexico Underground Natural Gas ...

  15. New York Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) New York Natural Gas in Underground Storage (Base Gas) ... Underground Base Natural Gas in Storage - All Operators New York Underground Natural Gas ...

  16. Separation of Flue-Gas Scrubber Sludge into Marketable Products

    SciTech Connect (OSTI)

    1998-02-28

    The reduction of sulfur oxides from high sulfur coal burning utility companies has resulted in the production of huge quantities of wet flue-gas desulfurization scrubber sludge. A typical 400 MW power station burning a coal containing 3.5% sulfur by weight and using a limestone absorbent would produce approximately 177,000 tons (dry weight) of scrubber sludge per year. This brownish colored, finely divided material contains calcium sulfite (CaSO{sub 3} {center_dot} 1/2 H{sub 2}O), calcium sulfate (CaSO{sub 4} {center_dot} 2H{sub 2}O), unreacted limestone (CaCO{sub 3}), and various other impurities such as fly-ash and iron oxide particles. The physical separation of the components of scrubber sludge would result in the re-use of this material. The primary use would be conversion to a highly pure synthetic gypsum. This technical report concentrates on the effect of baffle configuration on the separation of calcium sulfite/sulfate from limestone. The position of the baffles as they related to the feed inlet, and the quantity of the baffles were examined. A clean calcium sulfite/sulfate (less than 2.0% limestone by weight) was achieved with the combination of water-only cyclone and horizontally baffled column.

  17. Quantity, quality, and availability of waste heat from United States thermal power generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gingerich, Daniel B; Mauter, Meagan S

    2015-06-10

    Secondary application of unconverted heat produced during electric power generation has the potential to improve the life-cycle fuel efficiency of the electric power industry and the sectors it serves. This work quantifies the residual heat (also known as waste heat) generated by U.S. thermal power plants and assesses the intermittency and transport issues that must be considered when planning to utilize this heat. Combining Energy Information Administration plant-level data with literature-reported process efficiency data, we develop estimates of the unconverted heat flux from individual U.S. thermal power plants in 2012. Together these power plants discharged an estimated 18.9 billion GJthmoreof residual heat in 2012, 4% of which was discharged at temperatures greater than 90 C. We also characterize the temperature, spatial distribution, and temporal availability of this residual heat at the plant level and model the implications for the technical and economic feasibility of its end use. Increased implementation of flue gas desulfurization technologies at coal-fired facilities and the higher quality heat generated in the exhaust of natural gas fuel cycles are expected to increase the availability of residual heat generated by 10.6% in 2040.less

  18. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  19. Shale gas is natural gas trapped inside

    Broader source: Energy.gov (indexed) [DOE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary ... Fossil Energy Research Benefits FE's early investments in shale research in the 1970s ...

  20. Summary Max Total Units

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary Max Total Units *If All Splits, No Rack Units **If Only FW, AC Splits 1000 52 28 28 2000 87 59 35 3000 61 33 15 4000 61 33 15 Totals 261 153 93 ***Costs $1,957,500.00 $1,147,500.00 $697,500.00 Notes: added several refrigerants removed bins from analysis removed R-22 from list 1000lb, no Glycol, CO2 or ammonia Seawater R-404A only * includes seawater units ** no seawater units included *** Costs = (total units) X (estimate of $7500 per unit) 1000lb, air cooled split systems, fresh water

  1. gas-hydrate-global-assessment | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas-hydrate-global-assessment Frozen Heat: A Global Outlook on Methane Hydrate cover of executive summary The United Nations Environmental Programme released this new, two-volume report in March 2015. Frozen Heat: A Global Outlook on Methane Hydrate details the science and history of gas hydrates, evaluates the current state of gas hydrate research, and explores the potential impact of this untapped natural gas source on the future global energy mix. An executive summary of report is also

  2. Fact Sheet: Efficiency Standards for Natural Gas Compressors | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Fact Sheet: Efficiency Standards for Natural Gas Compressors Fact Sheet: Efficiency Standards for Natural Gas Compressors The following fact sheet outlines one of the Department of Energy's series of actions, partnerships, and stakeholder commitments to help modernize the nation¹s natural gas transmission and distribution systems and reduce methane emissions. DOE will take the first step toward establishing energy efficiency standards for new natural gas compressor units by

  3. EIA - Natural Gas Pipeline Network - Regional Overview and Links

    U.S. Energy Information Administration (EIA) Indexed Site

    Overview and Links About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Regional Overviews and Links to Pipeline Companies Through a series of interconnecting interstate and intrastate pipelines the transportation of natural gas from one location to another within the United States has become a relatively seamless operation. While intrastate pipeline systems often transports natural gas from production areas directly to consumers in

  4. Fabrication of photocatalytic composite of multi-walled carbon nanotubes/TiO{sub 2} and its application for desulfurization of diesel

    SciTech Connect (OSTI)

    Vu, Thu Ha Thi; Nguyen, Thu Trang Thi; Nguyen, Phuong Hoa Thi; Do, Manh Hung; Au, Hang Thi; Nguyen, Thanh Binh; Nguyen, Dinh Lam; Park, Jun Seo

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer MWNTs and TiO{sub 2} were mixed well, forming uniform microstructure in MWNTs/TiO{sub 2} composites. Black-Right-Pointing-Pointer The combination of MWNTs and TiO{sub 2} contribute to improving photocatalytic activity of TiO{sub 2}. Black-Right-Pointing-Pointer MWNTs/TiO{sub 2} composite is an effective photo-catalyst for the removal of sulfur from commercial diesel. -- Abstract: Composite of multi-walled carbon nanotubes (MWNTs) and titanium (IV) oxide (TiO{sub 2}) were prepared by a heterogeneous gelation method. The activities of the MWNTs/TiO{sub 2} composites were evaluated by photocatalytic oxidative desulfurization using dibenzothiophene (DBT), 4,6-dimethyl dibenzothiophene (4,6-DMDBT), n-tetradecane, and commercial diesel under irradiation using a high-pressure Hg lamp. The microstructures of MWNTs/TiO{sub 2} composites were characterized by N{sub 2} adsorption, scanning electron microscopy, transmission electron microscope, and X-ray diffraction. It was found that more than 98% of sulfur compounds in commercial diesel were oxidized and removed by the use of the MWNTs/TiO{sub 2} composite as a photocatalyst.

  5. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  6. Natural Gas and Other Petroleum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Annual Plan Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Research and Development Program Report to Congress June 2013 United States Department of Energy Washington, DC 20585 Department of Energy |June 2013 Department of Energy |June 2013 Message from the Secretary The Nation needs to deploy American assets, innovation, and technology so that it can safely and responsibly develop more energy here at home and be a leader in the global energy economy. To this end,

  7. NREL: Technology Deployment - NREL Teams with Southern California Gas to

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Launch First Power-to-Gas Project in U.S. NREL Teams with Southern California Gas to Launch First Power-to-Gas Project in U.S. April 14, 2015 Southern California Gas Company (SoCalGas) has joined with the Energy Department's National Renewable Energy Laboratory (NREL) and the National Fuel Cell Research Center (NFCRC) to launch demonstration projects to create and test a carbon-free, power-to-gas system for the first time ever in the United States. The technology converts electricity into

  8. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... the use of the heating equipment for a business or farm building as well as another ... for Housing Unit Type" ,,,,"Single-Family Units",,,,"Apartments in Buildings With" ...

  9. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... the use of the heating equipment for a business or farm building as well as another ... ,,"RSEs for Housing Unit Type" ,,"Single-Family Units",,"Apartments in Buildings With" ...

  10. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Vacant housing units, seasonal units, second homes, military housing, and group quarters are excluded. 2Energy Star is a joint program of the U.S. Environmental Protection Agency ...

  11. Exhaust gas purification system for lean burn engine

    SciTech Connect (OSTI)

    Haines, Leland Milburn

    2002-02-19

    An exhaust gas purification system for a lean burn engine includes a thermal mass unit and a NO.sub.x conversion catalyst unit downstream of the thermal mass unit. The NO.sub.x conversion catalyst unit includes at least one catalyst section. Each catalyst section includes a catalytic layer for converting NO.sub.x coupled to a heat exchanger. The heat exchanger portion of the catalyst section acts to maintain the catalytic layer substantially at a desired temperature and cools the exhaust gas flowing from the catalytic layer into the next catalytic section in the series. In a further aspect of the invention, the exhaust gas purification system includes a dual length exhaust pipe upstream of the NO.sub.x conversion catalyst unit. The dual length exhaust pipe includes a second heat exchanger which functions to maintain the temperature of the exhaust gas flowing into the thermal mass downstream near a desired average temperature.

  12. New York Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) New York Natural Gas Number of Gas and ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) New York Natural Gas ...

  13. Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues

    SciTech Connect (OSTI)

    Melaina, M. W.; Antonia, O.; Penev, M.

    2013-03-01

    The United States has 11 distinct natural gas pipeline corridors: five originate in the Southwest, four deliver natural gas from Canada, and two extend from the Rocky Mountain region. This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and natural gas mixture to defray the cost of building dedicated hydrogen pipelines.

  14. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck ...

  15. UNITED STATES OF AMERICA

    Office of Environmental Management (EM)

    ) ORDER GRANTING LONG-TERM MULTI-CONTRACT AUTHORIZATION TO IMPORT NATURAL GAS FROM CANADA TO THE PROPOSED JORDAN COVE LNG TERMINAL IN THE PORT OF COOS BAY,...

  16. Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Across the Continental United States | Department of Energy Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Real-World Greenhouse Gas Emissions from a MY2010 Diesel Truck Traveling Across the Continental United States Data analysis from this study will provide insight into real-world performance of current emissions reduction devices, under various operating conditions, and with respect to greenhouse gas emissions. p-03_carder.pdf

  17. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  18. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  19. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  20. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  2. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  3. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  4. Alternative fuels and chemicals from synthesis gas

    SciTech Connect (OSTI)

    Unknown

    1998-08-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. District of Columbia Heat Content of Natural Gas Deliveries to Consumers

    Gasoline and Diesel Fuel Update (EIA)

    June 2008 1 Each day, close to 70 million customers in the United States depend upon the national natural gas distribution network, including natural gas distribution companies and pipelines, to deliver natural gas to their home or place of business (Figure 1). These customers currently consume approximately 20 trillion cubic feet (Tcf) of natural gas per annum, accounting for about 22 percent of the total energy consumed in the United States each year. This end- use customer base is 92 percent

  6. Gas Fired Test System For Stirling Engines. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Gas Fired Test System For Stirling Engines. ... Security Administration (NNSA) Country of Publication: United States Language: English

  7. Special Delivery for Sustainability: Clean Cities Supports UPS in Expanding Natural Gas Operations

    Office of Energy Efficiency and Renewable Energy (EERE)

    With support from the Energy Department's Clean Cities program, United Parcel Service plans to deploy 1,000 liquefied natural gas trucks, making it the biggest private fleet of its kind in the United States.

  8. United States Natural Gas Industrial Price (Dollars per Thousand Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's 3.59 3.14 3.12 2000's 4.45 5.24 4.02 5.89 6.53 8.56 7.87 7.68 9.65 5.33 2010's 5.49 5.13 3.88 4.64 5.55 3.92

  9. United States Natural Gas Industrial Price (Dollars per Thousand Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2001 8.84 7.21 6.30 6.08 5.46 4.75 4.10 3.99 3.50 3.18 3.88 3.69 2002 4.05 3.70 3.78 3.64 4.07 3.86 3.80 3.62 3.89 4.18 4.72 4.92 2003 5.65 6.40 8.27 5.96 5.78 6.59 5.69 5.28 5.32 4.93 5.19 5.90 2004 6.72 6.52 5.97 6.06 6.34 6.82 6.41 6.36 5.68 6.03 7.64 7.54 2005 7.06 7.15 7.12 7.71 7.19 6.91 7.40 7.98 10.18 12.06 12.11 11.17 2006 10.85 9.38 8.24 7.93 7.63 6.92 6.78 7.36 7.21 5.62 7.74 8.23 2007 7.36 8.25 8.42 8.14 8.11 7.92 7.51

  10. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    response rate for this survey exceeded 94 percent as of August 2009. Because of the nature of the information, its value in the competitive industry, and to protect the...

  11. Natural Gas Processing Plants in the United States: 2010 Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    compiled by various sources and published by EIA in 2006. For more information, see http:www.eia.govpuboilgasnaturalgasfeaturearticles2006ngprocessngprocess.pdf...

  12. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    for about 12 percent of total U.S. capacity. As of 2009, there were a total of 4 plants in the State, with the largest one reporting a capacity of 8.5 Bcf per day. Average...

  13. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    2. Processing Plant Capacity and Percent of Total U.S. Capacity, 2009 Figure 2. Processing Plant Capacity and Percent of Total U.S. Capacity, 2009...

  14. Natural Gas Processing Plants in the United States: 2010 Update...

    Gasoline and Diesel Fuel Update (EIA)

    National Overview Processing Plant Utilization Data collected for 2009 show that the States with the highest total processing capacity are among the States with the highest average...

  15. Natural Gas Processing Plants in the United States: 2010 Update...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Wyoming 4,462 8.7 21 100 61 Colorado 2,934 5.7 15 100 77 Oklahoma 2,789 5.4 12 100 75 New Mexico 2,221 4.3 17 95 73 Illinois 1,601 3.1 35 76 76 Kansas 852 1.7 51 84 68 Alabama 746...

  16. " Million U.S. Housing Units"

    U.S. Energy Information Administration (EIA) Indexed Site

    Unit" ,"Housing Units (millions)","Single-Family Units",,"Apartments in Buildings ... Housing Unit" ,"RSEs for Housing Units ","Single-Family Units",,"Apartments in Buildings ...

  17. Tag gas capsule with magnetic piercing device

    DOE Patents [OSTI]

    Nelson, Ira V.

    1976-06-22

    An apparatus for introducing a tag (i.e., identifying) gas into a tubular nuclear fuel element. A sealed capsule containing the tag gas is placed in the plenum in the fuel tube between the fuel and the end cap. A ferromagnetic punch having a penetrating point is slidably mounted in the plenum. By external electro-magnets, the punch may be caused to penetrate a thin rupturable end wall of the capsule and release the tag gas into the fuel element. Preferably the punch is slidably mounted within the capsule, which is in turn loaded as a sealed unit into the fuel element.

  18. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    Characteristics of U.S. Homes, by Year of Construction, 2009" " Million Housing Units, Final" ,,"Year of Construction" ,"Total U.S.1 (millions)" "Structural and ...

  19. " Million Housing Units, Final...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... "Routine Service or Maintenance" "Performed on Central Air" ... unit 3Only includes routine service or maintenance performed in the last year. 4Energy ...

  20. Advanced Rooftop Unit Control

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced-Rooftop-Unit-Control Sign In About | Careers | Contact | Investors | bpa.gov Search Policy & Reporting Expand Policy & Reporting EE Sectors Expand EE Sectors...

  1. UNITED STATES GOVERNMENT

    Office of Legacy Management (LM)

    AEC ..J. Ccnmigl.io - Chief of Middlesex Operaticns A. PIhot -Hadiation Section, ... (loose in case of large contaminated units) loaded on truck&and lsonltored at' MIddlesex. ...

  2. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, D.D.

    A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  3. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, Don D.

    1985-01-01

    A chromatographic system that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a non-transparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extremely low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  4. Natural gas-assisted steam electrolyzer

    DOE Patents [OSTI]

    Pham, Ai-Quoc; Wallman, P. Henrik; Glass, Robert S.

    2000-01-01

    An efficient method of producing hydrogen by high temperature steam electrolysis that will lower the electricity consumption to an estimated 65 percent lower than has been achievable with previous steam electrolyzer systems. This is accomplished with a natural gas-assisted steam electrolyzer, which significantly reduces the electricity consumption. Since this natural gas-assisted steam electrolyzer replaces one unit of electrical energy by one unit of energy content in natural gas at one-quarter the cost, the hydrogen production cost will be significantly reduced. Also, it is possible to vary the ratio between the electricity and the natural gas supplied to the system in response to fluctuations in relative prices for these two energy sources. In one approach an appropriate catalyst on the anode side of the electrolyzer will promote the partial oxidation of natural gas to CO and hydrogen, called Syn-Gas, and the CO can also be shifted to CO.sub.2 to give additional hydrogen. In another approach the natural gas is used in the anode side of the electrolyzer to burn out the oxygen resulting from electrolysis, thus reducing or eliminating the potential difference across the electrolyzer membrane.

  5. Natural Gas Regulation - Other Gas-Related Information Sources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Gas Regulation - Other Gas-Related Information Sources Natural Gas Regulation - Other Gas-Related Information Sources The single largest source of energy information...

  6. Natural Gas Weekly Update, Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    part of a 65 billion project to supply the United States with oil, natural gas, and electricity from Siberia. The tunnel, which would be the world's longest, would take 10 to 15...

  7. Microsoft Word - 3Q2011Gas_Compress

    Office of Legacy Management (LM)

    Water Vapor in Gas at the Holmes Mesa Compressor Station, Garfield County, Colorado U.S. ... 10072011 Parameter Units Sample Date ID Result TPU 1 Qualifiers Lab Data QA ...

  8. DOE - Fossil Energy: A Brief Introduction to Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane is highly flammable and burns almost completely. There is no ash and very little air pollution. Natural gas provides one-fifth of all the energy used in the United States. ...

  9. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of the Alaska gas pipeline. The opening of ANWR might reduce the gas resource risk of building an Alaska gas pipeline, as the area has an estimated 3.6 trillion cubic...

  10. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  11. Gas amplified ionization detector for gas chromatography

    DOE Patents [OSTI]

    Huston, Gregg C.

    1992-01-01

    A gas-amplified ionization detector for gas chromatrography which possesses increased sensitivity and a very fast response time. Solutes eluding from a gas chromatographic column are ionized by UV photoionization of matter eluting therefrom. The detector is capable of generating easily measured voltage signals by gas amplification/multiplication of electron products resulting from the UV photoionization of at least a portion of each solute passing through the detector.

  12. Portable tester for determining gas content within a core sample

    DOE Patents [OSTI]

    Garcia, Jr., Fred; Schatzel, Steven J.

    1998-01-01

    A portable tester is provided for reading and displaying the pressure of a gas released from a rock core sample stored within a sealed container and for taking a sample of the released pressurized gas for chemical analysis thereof for subsequent use in a modified direct method test which determines the volume of gas and specific type of gas contained within the core sample. The portable tester includes a pair of low and high range electrical pressure transducers for detecting a gas pressure; a pair of low and high range display units for displaying the pressure of the detected gas- a selector valve connected to the low and high range pressure transducers, a selector knob for selecting gas flow to one of the flow paths; control valve having an inlet connection to the sealed container, and outlets connected to: a sample gas canister, a second outlet port connected to the selector valve means for reading the pressure of the gas from the sealed container to either the low range or high range pressure transducers, and a connection for venting gas contained within the sealed container to the atmosphere. A battery is electrically connected to and supplies the power for operating the unit. The pressure transducers, display units, selector and control valve means and the battery is mounted to and housed within a protective casing for portable transport and use.

  13. Portable tester for determining gas content within a core sample

    DOE Patents [OSTI]

    Garcia, F. Jr.; Schatzel, S.J.

    1998-04-21

    A portable tester is provided for reading and displaying the pressure of a gas released from a rock core sample stored within a sealed container and for taking a sample of the released pressurized gas for chemical analysis thereof for subsequent use in a modified direct method test which determines the volume of gas and specific type of gas contained within the core sample. The portable tester includes a pair of low and high range electrical pressure transducers for detecting a gas pressure; a pair of low and high range display units for displaying the pressure of the detected gas; a selector valve connected to the low and high range pressure transducers and a selector knob for selecting gas flow to one of the flow paths; control valve having an inlet connection to the sealed container; and outlets connected to: a sample gas canister, a second outlet port connected to the selector valve means for reading the pressure of the gas from the sealed container to either the low range or high range pressure transducers, and a connection for venting gas contained within the sealed container to the atmosphere. A battery is electrically connected to and supplies the power for operating the unit. The pressure transducers, display units, selector and control valve means and the battery is mounted to and housed within a protective casing for portable transport and use. 5 figs.

  14. New Mexico Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) New Mexico Natural Gas Number of Gas and ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) New Mexico Natural ...

  15. North Dakota Natural Gas Number of Gas and Gas Condensate Wells...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) North Dakota Natural Gas Number of Gas ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) North Dakota Natural ...

  16. Natural gas imports and exports, third quarter report 2000

    SciTech Connect (OSTI)

    2000-12-01

    The Office of Natural Gas and Petroleum Import and Export Activities prepares quarterly reports showing natural gas import and export activity. Companies are required to file quarterly reports. Attachments show the percentage of takes to maximum firm contract levels and the weighted average per unit price for each of the long-term importers during the 5 most recent quarters, volumes and prices of gas purchased by long-term importers and exporters during the past 12 months, volume and price data for gas imported on a short-term or spot market basis, and the gas exported on a short-term or spot market basis to Canada and Mexico.

  17. Natural gas imports and exports: First quarter report 1995

    SciTech Connect (OSTI)

    1995-07-01

    The Office of Fuels Programs prepares quarterly reports summarizing the data provided by companies authorized to import or export natural gas. Companies are required, as a condition of their authorizations, to file quarterly reports with the OFP. This quarter`s focus is market penetration of gas imports into New England. Attachments show the following: % takes to maximum firm contract levels and weighted average per unit price for the long-term importers, volumes and prices of gas purchased by long-term importers and exporters, volumes and prices for gas imported on short-term or spot market basis, and gas exported short-term to Canada and Mexico.

  18. Natural gas imports and exports, first quarter report 2000

    SciTech Connect (OSTI)

    2000-06-01

    The Office of Natural Gas and Petroleum Import and Export Activities prepares quarterly reports showing natural gas import and export activity. Companies are required to file quarterly reports. Attachments show the percentage of takes to maximum firm contract levels and the weighted average per unit price for each of the long-term importers during the 5 most recent reporting quarters, volumes and prices of gas purchased by long-term importers and exporters during the past 12 months, volume and price data for gas imported on a short-term or spot market basis, and the gas exported on a short-term or spot market basis to Canada and Mexico.

  19. Natural gas imports and exports, fourth quarter report 1999

    SciTech Connect (OSTI)

    2000-03-01

    The Office of Natural Gas and Petroleum Import and Export Activities prepares quarterly reports showing natural gas import and export activity. Companies are required to file quarterly reports. Attachments show the percentage of takes to maximum firm contract levels and the weighted average per unit price for each of the long-term importers during the five most recent quarters, volumes and prices of gas purchased by long-term importers and exporters during the past 12 months, volume and price data for gas imported on a short-term or spot market basis, and the gas exported on a short-term or spot market basis to Canada and Mexico.

  20. Natural Gas and the Environment - Energy Explained, Your Guide To

    U.S. Energy Information Administration (EIA) Indexed Site

    Understanding Energy - Energy Information Administration Gas > Natural Gas & the Environment Energy Explained - Home What Is Energy? Forms of Energy Sources of Energy Laws of Energy Units and Calculators Energy Conversion Calculators British Thermal Units (Btu) Degree-Days U.S. Energy Facts State and U.S. Territory Data Use of Energy In Industry For Transportation In Homes In Commercial Buildings Efficiency and Conservation Energy and the Environment Greenhouse Gases Effect on the

  1. MODULAR CORE UNITS FOR A NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Gage, J.F. Jr.; Sherer, D.B.

    1964-04-01

    A modular core unit for use in a nuclear reactor is described. Many identical core modules can be placed next to each other to make up a complete core. Such a module includes a cylinder of moderator material surrounding a fuel- containing re-entrant coolant channel. The re-entrant channel provides for the circulation of coolant such as liquid sodium from one end of the core unit, through the fuel region, and back out through the same end as it entered. Thermal insulation surrounds the moderator exterior wall inducing heat to travel inwardly to the coolant channel. Spaces between units may be used to accommodate control rods and support structure, which may be cooled by a secondary gas coolant, independently of the main coolant. (AEC)

  2. Associative list processing unit

    DOE Patents [OSTI]

    Hemmert, Karl Scott; Underwood, Keith D.

    2013-01-29

    An associative list processing unit and method comprising employing a plurality of prioritized cell blocks and permitting inserts to occur in a single clock cycle if all of the cell blocks are not full. Also, an associative list processing unit and method comprising employing a plurality of prioritized cell blocks and using a tree of prioritized multiplexers descending from the plurality of cell blocks.

  3. Composite stabilizer unit

    DOE Patents [OSTI]

    Ebaugh, Larry R.; Sadler, Collin P.; Carter, Gary D.

    1992-01-01

    An improved fin stabilized projectile including multiple stabilizer fins upon a stabilizer unit situated at the aft end of the projectile is provided, the improvement wherein the stabilizer fins are joined into the stabillizer unit by an injection molded engineering grade polymer.

  4. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    of natural gas vehicles. The Department of Energys Office of Energy Efficiency and Renewable Energy reports that there were 841 compressed natural gas (CNG) fuel stations and 41...

  5. Oil and Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  6. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Market Trends: MMS Announces New Incentives for Gulf Gas Production: The Minerals Management Service (MMS) unveiled proposed new incentives to increase deep gas production...

  7. Gas scrubbing liquids

    DOE Patents [OSTI]

    Lackey, Walter J.; Lowrie, Robert S.; Sease, John D.

    1981-01-01

    Fully chlorinated and/or fluorinated hydrocarbons are used as gas scrubbing liquids for preventing noxious gas emissions to the atmosphere.

  8. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    ability to process gas. The company's Main Pass 260 line to Pascagoula Gas Plant in Jackson, Mississippi, will not be available for transportation services. While the plant is...

  9. CONTINUOUS GAS ANALYZER

    DOE Patents [OSTI]

    Katz, S.; Weber, C.W.

    1960-02-16

    A reagent gas and a sample gas are chemically combined on a continuous basis in a reaction zone maintained at a selected temperature. The reagent gas and the sample gas are introduced to the reaction zone at preselected. constant molar rates of flow. The reagent gas and the selected gas in the sample mixture combine in the reaction zone to form a product gas having a different number of moles from the sum of the moles of the reactants. The difference in the total molar rates of flow into and out of the reaction zone is measured and indicated to determine the concentration of the selected gas.

  10. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  11. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    strong price contango during the report week, mitigated withdrawals of natural gas from storage. Other Market Trends: EIA Releases New Report on U.S. Greenhouse Gas Emissions:...

  12. Natural Gas Weekly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 12, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Spot gas at most market locations (outside the Rocky Mountain Region) traded...

  13. Historical Natural Gas Annual

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  14. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  15. Historical Natural Gas Annual

    Gasoline and Diesel Fuel Update (EIA)

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  16. Imported resources - gas

    SciTech Connect (OSTI)

    Marxt, J.

    1995-12-01

    This paper examines aspects of the supply and demand of natural gas and natural gas products such as LNG in the Czech Republic.

  17. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    5, 2009 Next Release: July 2, 2009 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview (For the Week Ending Wednesday, June 24, 2009) Natural gas...

  18. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    , 2008 Next Release: July 10, 2008 Overview Prices Storage Other Market Trends Natural Gas Transportation Update Overview Since Wednesday, June 25, natural gas spot prices...

  19. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Sources & Uses Petroleum & Other Liquids Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas...

  20. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...