National Library of Energy BETA

Sample records for gas desulfurization systems

  1. Spare parts program practices for flue gas desulfurization systems: Final report

    SciTech Connect (OSTI)

    Morgan, W.E.; Stresewski, J.E.; Cannell, A.L.

    1987-04-01

    Reliability and availability of a flue gas desulfurization (FGD) system is dependent to some extent on adequate system maintenance. System maintenance must be supported by a well planned spare parts program. The objective of this project was to determine the current practices followed by electric utilities in planning spare parts programs. Utilities with operational FGD systems were surveyed to determine the types of practices and typical inventory levels for spare parts for various items of FGD system equipment. FGD system suppliers and consulting engineering firms were also surveyed to obtain their recommendations regarding system sparing philosophy. The survey results were examined to determine significant trends and identify areas where further work could be beneficial. In general, spare parts problems typically have not been a cause for loss of availability except in some specific cases where a late start in planning the spare parts program contributed to problems during early stages of FGD system operation. Computerized methods for inventory surveillance and reordering are replacing manual methods. Stock levels for spare parts typically have been adjusted to reflect the individual utilities' operating experience. Documentation of spare parts usage rates over an extended time period would provide a data base for utilities planning spare parts programs for their first FGD system installation.

  2. State-of-the-art review of materials-related problems in flue gas desulfurization systems

    SciTech Connect (OSTI)

    Maiya, P. S.

    1980-10-01

    This report characterizes the chemical and mechanical environments to which the structural components used in flue-gas desulfurization (FGD) are exposed. It summarizes the necessary background information pertinent to various FGD processes currently in use, with particular emphasis on lime/limestone scrubbing technology, so that the materials problems and processing variables encountered in FGD systems can be better defined and appreciated. The report also describes the materials currently used and their performance to date in existing wet scrubbers. There is little doubt that with more extensive use of coal and flue-gas scrubbers by utilities and other segments of private industry, a better understanding of the material failure mechanisms, performance limitations, and potential problem areas is required for the design of more reliable and cost-effective FGD systems. To meet the above objectives, a materials evaluation program is proposed. The important experimental variables and the number of tests required to evaluate a given material are discussed. 55 references, 9 figures, 6 tables.

  3. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, Kwan H.; Ahluwalia, Rajesh K.

    1985-01-01

    A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

  4. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  5. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T.; Shen, Ming-Shing

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  6. Flue gas desulfurization wastewater treatment primer

    SciTech Connect (OSTI)

    Higgins, T.E.; Sandy, A.T.; Givens, S.W.

    2009-03-15

    Purge water from a typical wet flue gas desulfurization system contains myriad chemical constituents and heavy metals whose mixture is determined by the fuel source and combustion products as well as the stack gas treatment process. A well-designed water treatment system can tolerate upstream fuel and sorbent arranged in just the right order to produce wastewater acceptable for discharge. This article presents state-of-the-art technologies for treating the waste water that is generated by wet FGD systems. 11 figs., 3 tabs.

  7. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  8. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, Deborah A.; Farthing, George A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse.

  9. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-09-29

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  10. Flue gas desulfurization method and apparatus

    SciTech Connect (OSTI)

    Madden, D.A.; Farthing, G.A.

    1998-08-18

    A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

  11. Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system

    SciTech Connect (OSTI)

    Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

    1991-01-01

    Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

  12. Sorbent for use in hot gas desulfurization

    DOE Patents [OSTI]

    Gasper-Galvin, Lee D.; Atimtay, Aysel T.

    1993-01-01

    A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

  13. System for removing solids from a used lime or limestone slurry scrubbing liquor in flue gas desulfurization

    SciTech Connect (OSTI)

    Randolph, A.D.

    1981-10-13

    The flue gas desulfurization process using a lime or limestone slurry scrubbing solution produces used liquor containing calcium sulfite or sulfate (Typically gypsum). Precipitated particles are removed by feeding the used scrubbing liquor to an agitated crystallization zone to grow crystals and directing part of the used scrubbing liquor from that zone to a quiescent crystallization zone, in which particles are settled back into the agitated zone. An underflow stream from the agitated zone containing large crystals is combined with an overflow stream from the quiescent zone, which combined stream is clarified with the fines being returned to the scrubber and the large crystals being removed as a waste product. Apparatus for performing the above process in which the agitated and quiescent crystallization zones form part of a single crystallization vessel, and the two zones are separated by a baffle.

  14. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  15. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    Unknown

    1999-07-01

    The U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2}TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. Overall chemical reactions with Zn{sub 2}TiO{sub 4} during the desulfurization (sulfidation)-regeneration cycle are shown. The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO{sub 2}.

  16. Flue gas desulfurization: Physicochemical and biotechnological approaches

    SciTech Connect (OSTI)

    Pandey, R.A.; Biswas, R.; Chakrabarti, T.; Devotta, S.

    2005-07-01

    Various flue gas desulfurization processes - physicochemical, biological, and chemobiological - for the reduction of emission of SO{sub 2} with recovery of an economic by-product have been reviewed. The physicochemical processes have been categorized as 'once-through' and 'regenerable.' The prominent once-through technologies include wet and dry scrubbing. The wet scrubbing technologies include wet limestone, lime-inhibited oxidation, limestone forced oxidation, and magnesium-enhanced lime and sodium scrubbing. The dry scrubbing constitutes lime spray drying, furnace sorbent injection, economizer sorbent injection, duct sorbent injection, HYPAS sorbent injection, and circulating fluidized bed treatment process. The regenerable wet and dry processes include the Wellman Lord's process, citrate process, sodium carbonate eutectic process, magnesium oxide process, amine process, aqueous ammonia process, Berglau Forchung's process, and Shell's process. Besides these, the recently developed technologies such as the COBRA process, the OSCAR process, and the emerging biotechnological and chemobiological processes are also discussed. A detailed outline of the chemistry, the advantages and disadvantages, and the future research and development needs for each of these commercially viable processes is also discussed.

  17. BENCH-SCALE DEMONSTRATION OF HOT-GAS DESULFURIZATION TECHNOLOGY

    SciTech Connect (OSTI)

    Unknown

    1999-10-01

    The U.S. Department of Energy (DOE), Federal Energy Technology Center (FETC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2} TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc oxide (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. Overall chemical reactions with Zn{sub 2} TiO{sub 4} during the desulfurization (sulfidation)-regeneration cycle are shown below: Sulfidation: Zn{sub 2} TiO{sub 4} + 2H{sub 2}S {yields} 2ZnS + TiO{sub 2} + 2H{sub 2}O; Regeneration: 2ZnS + TiO{sub 2} + 3O{sub 2} {yields} Zn{sub 2} TiO{sub 4} + 2SO{sub 2} The sulfidation/regeneration cycle can be carried out in a fixed-bed, moving-bed, or fluidized-bed reactor configuration. The fluidized-bed reactor configuration is most attractive because of several potential advantages including faster kinetics and the ability to handle the highly exothermic regeneration to produce a regeneration offgas containing a constant concentration of SO{sub 2}.

  18. Core-in-shell sorbent for hot coal gas desulfurization

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Akiti, Jr., Tetteh T.

    2004-02-10

    A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical characteristics to withstand the conditions of use.

  19. Workshop on sulfur chemistry in flue gas desulfurization

    SciTech Connect (OSTI)

    Wallace, W.E. Jr.

    1980-05-01

    The Flue Gas Desulfurization Workshop was held at Morgantown, West Virginia, June 7-8, 1979. The presentations dealt with the chemistry of sulfur and calcium compounds in scrubbers. DOE and EPRI programs in this area are described. Ten papers have been entered individually into EDB and ERA. (LTN)

  20. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  1. Dry FGD (flue-gas desulfurization) at Argonne National Laboratory

    SciTech Connect (OSTI)

    Livengood, C.D.

    1990-01-01

    Flue-gas desulfurization (FGD) systems based on spray drying are a relatively recent addition to the spectrum of sulfur dioxide (SO{sub 2}) control options available to utility and industrial boiler operators. Such systems appear to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. These advantages have promoted rapid acceptance of dry scrubbers for applications using western low-sulfur coal, but uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. At Argonne National Laboratory (ANL) we have had more than eight years of operating experience with an industrial-scale dry scrubber used with a boiler firing high-sulfur (3.5%) midwestern coal. This paper describes our operating experience with that system and summarizes several research programs that have utilized it. 7 refs., 15 figs., 6 tabs.

  2. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu; King, David L.; Liu, Jun; Huo, Qisheng

    2012-04-17

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  3. Desulfurized gas production from vertical kiln pyrolysis

    DOE Patents [OSTI]

    Harris, Harry A.; Jones, Jr., John B.

    1978-05-30

    A gas, formed as a product of a pyrolysis of oil shale, is passed through hot, retorted shale (containing at least partially decomposed calcium or magnesium carbonate) to essentially eliminate sulfur contaminants in the gas. Specifically, a single chambered pyrolysis vessel, having a pyrolysis zone and a retorted shale gas into the bottom of the retorted shale zone and cleaned product gas is withdrawn as hot product gas near the top of such zone.

  4. Economic assessment of advanced flue gas desulfurization processes. Final report

    SciTech Connect (OSTI)

    Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

    1981-09-01

    This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final reprot, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluations, was completed in October 1980. A slightly modified and condensed version of that report appears as appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

  5. High temperature desulfurization of synthesis gas

    DOE Patents [OSTI]

    Najjar, Mitri S.; Robin, Allen M.

    1989-01-01

    The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

  6. Process for production desulfurized of synthesis gas

    DOE Patents [OSTI]

    Wolfenbarger, James K.; Najjar, Mitri S.

    1993-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

  7. Confined zone dispersion flue gas desulfurization demonstration

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler's outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  8. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  9. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  10. High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents

    SciTech Connect (OSTI)

    Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

    2002-09-20

    The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

  11. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  12. Influence factors on the flue gas desulfurization in the circulating fluidized bed reactor

    SciTech Connect (OSTI)

    Gao, J.; Tang, D.; Liu, H.; Suzuki, Yoshizo; Kito, Nobo

    1997-12-31

    This paper describes a dry SO{sub 2} removal method -- the absorbent (Ca(OH){sub 2}) was injected into the Circulating Fluidized Bed (CFB) reactor at the coolside of the duct to abate SO{sub 2} in the flue gas -- with the potential to significantly enhance desulfurization performance over that of existing dry/semi-dry Flue Gas Desulfurization (FGD) technology such as Spray Drying. A patent for coolside Flue Gas Desulfurization in the Circulating Fluidized Bed reactor (CFB-FGD) was approved by the China Patent Bureau in September of 1995 and the additional laboratory experiment was carried out in an electrically heated bench scale quartz circulating fluidized bed reactor of 2350mm in height and 23mm in diameter in January, 1996. The influences of steam, ratio of calcium and sulfur, reactor temperature, and absorbent utilization efficiency were invested. The results show that: (1) Water steam plays a key role in the reaction of Ca(OH){sub 2} and SO{sub 2} in the CFB reactor; (2) There is a positive effect of Ca/S on SO{sub 2} removal efficiency; (3) The temperature is an another key factor for SO{sub 2} removal efficiency for the CFB-FGD process; (4) The absorbent can be enhanced in the CFB reactor; (5) The CFB reactor is better than the dry/semi-dry FDG technology. SO{sub 2} removal efficiency can be as high as 84.8%.

  13. An integrated process for simultaneous desulfurization, dehydration, and recovery of hydrocarbon liquids from natural gas streams

    SciTech Connect (OSTI)

    Sciamanna, S.F. ); ))

    1988-01-01

    Conventional processing schemes for desulfurizing, drying, and separation of natural gas liquids from natural gas streams require treating the gas by a different process for each separation step. In a simpler process, based on the University of California, Berkeley Sulfur Recovery Process (UCBSRP) technology, hydrogen sulfide, propane and heavier hydrocarbons, and water are absorbed simultaneously by a polyglycol ether solvent containing a homogenous liquid phase catalyst. The catalyst promotes the subsequent reaction of hydrogen sulfide with added sulfur dioxide to produce a high quality sulfur product. Hydrocarbons are separated as two product streams with the split between propane and butane. This new process offers an overall reduction in both capital and energy costs.

  14. Regeneration and Durability of Advanced Zinc Ferrite Sorbent for Hot Coal Gas Desulfurization

    SciTech Connect (OSTI)

    Shirai, H.; Kobayashi, M.; Nunokawa, M.; Noda, N.

    2002-09-19

    In this study, we investigate the regeneration characteristics, desulfurization performance after regeneration and the durability of zinc ferrite sorbent in the desulfurization/regeneration cycles.

  15. Status of spray-dryer flue-gas desulfurization. Final report

    SciTech Connect (OSTI)

    Ireland, P.A.

    1982-01-01

    Utility interest and commitment to spray drying for SO/sub 2/ and particulate control has increased dramatically in response to vendor claims (lower costs, dry wastes, lower energy requirements, and simplicity) and newly promulgated federal emission regulations that allow lower SO/sub 2/ removal requirements (70%) for low-sulfur coals. Unfortunately, limited data are available from which to evaluate vendor claims prior to commercial commitment or to improve the cost and reliability of this potentially important flue gas desulfurization (FGD) option. Accordingly, EPRI is conducting a pilot-scale project (RP1870) to provide a systematic evaluation of the technology unconstrained by specific vendor designs, operating philosophy, or commercial limitation. It will result in guidelines for system design and optimization in order to ensure reliable utility operation at minimum cost. This final report (TPS 80-741) contains a review of the design practices for the full-scale systems ordered and a discussion of the important spray-drying FGD process variables. Other EPRI work in this area includes a cost study with the Tennessee Valley Authority (RP1180-7) and a spray-dryer waste solids characterization (RP1870-2). The EPA has published a similar status document, which, in addition to spray drying, also covers dry injection and burning coal-alkali mixtures. However, the EPA document is not as detailed on either the design of full-scale systems or the technical issues.

  16. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  17. Investigation of a mercury speciation technique for flue gas desulfurization materials

    SciTech Connect (OSTI)

    Lee, J.Y.; Cho K.; Cheng L.; Keener, T.C.; Jegadeesan G.; Al-Abed, S.R.

    2009-08-15

    Most of the synthetic gypsum generated from wet flue gas desulfurization (FGD) scrubbers is currently being used for wallboard production. Because oxidized mercury is readily captured by the wet FGD scrubber, and coal-fired power plants equipped with wet scrubbers desire to benefit from the partial mercury control that these systems provide, some mercury is likely to be bound in with the FGD gypsum and wallboard. In this study, the feasibility of identifying mercury species in the FGD gypsum and wallboard samples was investigated using a large sample size thermal desorption method and samples from power plants in Pennsylvania. Potential candidates of pure mercury standards including mercuric chloride, mercurous chloride, mercury oxide, mercury sulfide, and mercuric sulfate were analyzed to compare their results with those obtained from FGD gypsum and dry wallboard samples. Although any of the thermal evolutionary curves obtained from these pure mercury standards did not exactly match with those of the FGD gypsum and wallboard samples, it was identified that Hg{sub 2}Cl{sub 2} and HgCl{sub 2} could be candidates. An additional chlorine analysis from the gypsum and wallboard samples indicated that the chlorine concentrations were approximately 2 orders of magnitude higher than the mercury concentrations, suggesting possible chlorine association with mercury. 21 refs., 5 figs., 3 tabs.

  18. Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report

    SciTech Connect (OSTI)

    1996-04-30

    The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

  19. BUILDING MATERIALS MADE FROM FLUE GAS DESULFURIZATION BY-PRODUCTS

    SciTech Connect (OSTI)

    Michael W. Grutzeck; Maria DiCola; Paul Brenner

    2006-03-30

    Flue gas desulphurization (FGD) materials are produced in abundant quantities by coal burning utilities. Due to environmental restrains, flue gases must be ''cleaned'' prior to release to the atmosphere. They are two general methods to ''scrub'' flue gas: wet and dry. The choice of scrubbing material is often defined by the type of coal being burned, i.e. its composition. Scrubbing is traditionally carried out using a slurry of calcium containing material (slaked lime or calcium carbonate) that is made to contact exiting flue gas as either a spay injected into the gas or in a bubble tower. The calcium combined with the SO{sub 2} in the gas to form insoluble precipitates. Some plants have been using dry injection of these same materials or their own Class C fly ash to scrub. In either case the end product contains primarily hannebachite (CaSO{sub 3} {center_dot} 1/2H{sub 2}O) with smaller amounts of gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O). These materials have little commercial use. Experiments were carried out that were meant to explore the feasibility of using blends of hannebachite and fly ash mixed with concentrated sodium hydroxide to make masonry products. The results suggest that some of these mixtures could be used in place of conventional Portland cement based products such as retaining wall bricks and pavers.

  20. Process for the manufacture of an attrition resistant sorbent used for gas desulfurization

    DOE Patents [OSTI]

    Venkataramani, Venkat S.; Ayala, Raul E.

    2003-09-16

    This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

  1. An experimental study of flue gas desulfurization in a pilot spray dryer

    SciTech Connect (OSTI)

    Ollero, P.; Salvador, L.; Canadas, L.

    1997-12-31

    More than 45 experimental tests have been conducted on a 10,000 Nm{sup 3}/h spray-drying desulfurization pilot plant. The effects of SO{sub 2} and fly ash concentration, Ca/S ratio, approach to saturation temperature, unit load changes, and the utilization of seawater as make-up water on both spray dryer behavior and treated flue gas properties were analyzed. This experimental study allows us to reach some conclusions about how to achieve optimum operating conditions and to assess the impact of spray drying on a downstream ESP. 5 refs., 14 figs., 2 tabs.

  2. Apparatus for hot-gas desulfurization of fuel gases

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV)

    1992-01-01

    An apparatus for removing sulfur values from a hot fuel gas stream in a fdized bed contactor containing particulate sorbent material by employing a riser tube regeneration arrangement. Sulfur-laden sorbent is continuously removed from the fluidized bed through a stand pipe to the riser tube and is rapidly regenerated in the riser tube during transport of the sorbent therethrough by employing an oxygen-containing sorbent regenerating gas stream. The riser tube extends from a location below the fluidized bed to an elevation above the fluidized bed where a gas-solid separating mechanism is utilized to separate the regenerated particulate sorbent from the regeneration gases and reaction gases so that the regenerated sorbent can be returned to the fluidized bed for reuse.

  3. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  4. Advanced fuel gas desulfurization (AFGD) demonstration project. Technical progress report No. 19, July 1, 1994--September 30, 1994

    SciTech Connect (OSTI)

    1995-12-01

    The {open_quotes}Advanced Flue Gas Desulfurization (AFGD) Demonstration Project{close_quotes} is a $150.5 million cooperative effort between the U.S. Department of Energy and Pure Air, a general partnership of Air Products and Chemicals, Inc. and Mitsubishi Heavy Industries America, Inc. The AFGD process is one of several alternatives to conventional flue gas desulfurization (FGD) being demonstrated under the Department of Energy`s Clean Coal Technology Demonstration Program. The AFGD demonstration project is located at the Northern Indiana Public Service Company`s Bailly Generating Station, about 12 miles northeast of Gary, Indiana.

  5. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, J.B.L.; Doctor, R.D.; Wingender, R.J.

    1985-08-05

    A method of simultaneously removing SO/sub 2/ and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO/sub 2/ and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled. 3 figs.

  6. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C.; Blandon, Antonio E.; Hepworth, Malcolm T.

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  7. Flue gas desulfurization/denitrification using metal-chelate additives

    DOE Patents [OSTI]

    Harkness, John B. L.; Doctor, Richard D.; Wingender, Ronald J.

    1986-01-01

    A method of simultaneously removing SO.sub.2 and NO from oxygen-containing flue gases resulting from the combustion of carbonaceous material by contacting the flue gas with an aqueous scrubber solution containing an aqueous sulfur dioxide sorbent and an active metal chelating agent which promotes a reaction between dissolved SO.sub.2 and dissolved NO to form hydroxylamine N-sulfonates. The hydroxylamine sulfonates are then separated from the scrubber solution which is recycled.

  8. Hot coal gas desulfurization with manganese-based sorbents. Annual report, September 1992--September 1993

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1993-12-01

    The focus of work being performed on Hot Coal Gas Desulfurization at the Morgantown Energy Technology Center is primarily in the use of zinc ferrite and zinc titanate sorbents; however, prior studies at the US Steel Fundamental Research Laboratories in Monroeville, PA, by E. T. Turkdogan indicated that an alternate sorbent, manganese dioxide-containing ore in mixture with alumina (75 wt % ore + 25 wt % Al{sub 2}O{sub 3}) may be a viable alternative to zinc-based sorbents. Manganese, for example, has a lower vapor pressure in the elemental state than zinc hence it is not as likely to undergo depletion from the sorbent surface upon loading and regeneration cycles. Also manganese oxide is less readily reduced to the elemental state than iron hence the range of reduction potentials for oxygen is somewhat greater than for zinc ferrite. In addition, thermodynamic analysis of the manganese-oxygen-sulfur system shows it to be less amenable to sulfation than zinc ferrite. Potential also exists for utilization of manganese at higher temperatures than zinc ferrite or zinc titanate. This Annual Topical Report documents progress in pelletizing and testing via thermo-gravimetric analysis of individual pellet formulations of manganese ore/ alumina combinations and also manganese carbonate/alumina with two binders, dextrin and bentonite. It includes the prior Quarterly Technical Reports which indicate that the manganese carbonate material, being of higher purity than the manganese ore, has a higher degree of sulfur capacity and more rapid absorption kinetics. A 2-inch fixed-bed reactor has been fabricated and is now ready for subjecting pellets to cyclic loading and regeneration.

  9. Land application uses for dry flue gas desulfurization by-products: Phase 3

    SciTech Connect (OSTI)

    Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

    1999-01-31

    New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

  10. Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 1

    SciTech Connect (OSTI)

    Underkoffler, V.S.

    1986-12-01

    The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Optimum operating parameters for zinc ferrite such as temperatures, gas compositions, and space velocities are discussed. From the test results, salient features of zinc ferrite were derived and discussed in regard to system implications, issues raised, and technical requirements. 47 refs., 53 figs., 41 tabs.

  11. Management of dry flue gas desulfurization by-products in underground mines. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-10-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues (CCBs) in abandoned coal mines, and will assess the environmental impact of such underground CCB placement. This report describes progress in the following areas: environmental characterization, mix development and geotechnical characterization, material handling and system economics, underground placement, and field demonstration.

  12. Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

    1994-01-01

    The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

  13. Model for flue-gas desulfurization in a circulating dry scrubber

    SciTech Connect (OSTI)

    Neathery, J.K.

    1996-01-01

    A simple model was developed to describe the absorption of SO{sub 2} in a circulating dry scrubbing (CDS) process, which is a semi dry, lime-based, flue-gas desulfurization (FGD) process that utilizes a circulating fluidized bed arrangement for contacting a sorbent with SO{sub 2}-laden flue gas under coolside conditions. The reaction chemistry is thought to be similar to that of spray-drying absorption. The liquid-phase mass-transfer coefficient was successfully modeled as a function of the sorbent particle spacing on the wetted surfaces. Gas-phase mass-transfer resistances were assumed to be insignificant. Due to the high surface area available in a CDS reactor, the evaporation rate of water from the slurry was modeled as constant-rate drying according to classic spray-dryer theory. However, the falling-rate and diffusion evaporation stages were negligible in CDS since sorbent particle bunching at the surface of the slurry is nonexistent.

  14. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.; Ghafoori, N.; Paul, B.; Sevim, H.; Thomasson, E.

    1995-01-01

    On September 30, 1993, the US Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative agreement entitled ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` (DE-FC21-93MC30252). Under the agreement, Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. The major event during the quarter was the demonstration of the SEEC, Inc. technology for loading and transporting coal combustion residues in the SEEC developed Collapsible Intermodal Containers (CIC). The demonstration was held on November 17, 1994, at the Illinois Power Company Baldwin power plant, and was attended by about eighty (80) invited guest. Also during the quarter meetings were held with Peabody Coal Company officials to finalize the area in the Peabody No. 10 mine to be used for the placement of coal combustion residues. Work under the Materials Handling and Systems Economics area continued, particularly in refining the costs and systems configuration and in economic evaluation of various systems using equipment leasing rather than equipment purchases. Likewise, work progressed on residues characterization, with some preparations being made for long-term testing.

  15. The Clean Coal Technology Program 100 MWe demonstration of gas suspension absorption for flue gas desulfurization

    SciTech Connect (OSTI)

    Hsu, F.E.; Hedenhag, J.G.; Marchant, S.K.; Pukanic, G.W.; Norwood, V.M.; Burnett, T.A.

    1997-12-31

    AirPol Inc., with the cooperation of the Tennessee Valley Authority (TVA) under a Cooperative Agreement with the United States Department of Energy, installed and tested a 10 MWe Gas Suspension Absorption (GSA) Demonstration system at TVA`s Shawnee Fossil Plant near Paducah, Kentucky. This low-cost retrofit project demonstrated that the GSA system can remove more than 90% of the sulfur dioxide from high-sulfur coal-fired flue gas, while achieving a relatively high utilization of reagent lime. This paper presents a detailed technical description of the Clean Coal Technology demonstration project. Test results and data analysis from the preliminary testing, factorial tests, air toxics texts, 28-day continuous demonstration run of GSA/electrostatic precipitator (ESP), and 14-day continuous demonstration run of GSA/pulse jet baghouse (PJBH) are also discussed within this paper.

  16. LIFAC flue gas desulfurization process an alternative SO{sub 2} control strategy

    SciTech Connect (OSTI)

    Patel, J.G.; Vilala, J.

    1995-12-01

    This paper discusses the results from two recently completed LIFAC flue gas desulfurization plants - 300 MW Shand lignite powered station owned by Saskatchewan Power Corporation and 60 MW Whitewater Valley high sulfur coal fired station owned by Richmond Powerand Light. LIFACis a dry FGD process in which limestone is injected into the upper regions of the boiler furnace and an activation reactor is used to humidify the unreacted limestone to achieve additional sulfur capture. The performance in both plants indicates that 70 to 80% sulfur is removed at a Ca/S ratio of 2. Cost performance data from these plants has shown that LI FAC both on construction cost and $/ton SO{sub 2} removed basis is very cost competitive compared to other SO{sub 2} control technologies. The Richmond plant has been realized under the auspices of the U.S. Department of Energy`s Clean Coal Technology program. The Shand plant is the first commercial installation in North America. The paper also discusses highlights of operating and maintenance experience, availability and handling of the solid waste product.

  17. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, March 1, 1992--May 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-10-01

    New coal gasification processes are now being developed which can generate electricity with high thermal efficiency either in an integrated gasification combined cycle (IGCC) or in a fuel cell (MCFC). Both of these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCl) in the coal-gas. This project investigates the effect of HCl, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by the HCI, both in absorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences of utilizing high-chlorine Illinois coal in these processes. The work activity during the third quarter of this project involved the performance of the second block-set of experiments in the bench-scale fluidized-bed reactor. These experiments were designed to study the effect of HCl in the desulfurization of a low-Btu fuel gas. Nine single-cycle experiments were performed, at operating temperature of 538, 650, and 750{degrees}C, with HCl concentrations of 0, 200, and 800 ppMv. The presence of HCl in the coal gas significantly enhanced the desulfurization efficacy of the sorbent. A 10-cycle sulfidation-regeneration sequence is currently being performed at 650{degrees}C with 800 ppMv HCl in the simulated fuel gas to determine any adverse effects on the sorbent structure or its desulfurization capability.

  18. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S.; Gupta, R.P.

    1992-12-31

    In this project, simulated gasifier-product streams were contacted with the zinc titanate desulfurization sorbent in a bench-scale atmospheric fluidized-bed reactor at temperatures ranging from 538 to 750 {degree}C (1000 to 1382 {degree}F). The first set of experiments involved treating a medium-Btu fuel gas (simulating that of a ``Texaco`` oxygen-blown, entrained-bed gasifier) containing 1.4 percent H{sub 2}S and HCl concentrations of 0, 200, and 1500 ppmv. The second experimental set evaluated hot-gas desulfurization of a low-Btu fuel gas (simulating the product of the ``U-Gas`` air-blown gasifier), with HCl concentrations of 0, 200, and 800 ppmv. These operating conditions were typical of the gas-treatment requirements of gasifiers fueled by Illinois basin coals containing up to 0.6 percent chlorine. The results of the experiments at 538 and 650 {degree}C at all the HCl concentrations revealed no deleterious effects on the capability of the sorbent to remove H{sub 2}S from the fuel gas mixtures. In most cases, the presence of the HCl significantly enhanced the desulfurization reaction rate. Some zinc loss, however, was encountered in certain situations at 750 {degree}C when low-steam operating conditions were present. Also of interest, a portion of the incoming HCl was removed from the gas stream and was retained permanently by the sorbent. This behavior was examined in more detail in a limited set of experiments aimed at identifying ways to modify the sorbents composition so that the sorbent could act as a simultaneous desulfurization and dechlorination agent in the hot-gas cleanup process.

  19. Desulfurization Effects on a Light-Duty Diesel Vehicle NOx Adsorber Exhaust Emission Control System

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Tyrer, H.; Thornton, M.; Kubsh, J.

    2006-05-01

    Analyzes the effects on gaseous emissions, before and after desulfurization, on a light-duty diesel vehicle with a NOx adsorber catalyst.

  20. Revamping AK-Ashland gas cleaning system

    SciTech Connect (OSTI)

    Brandes, H.; Koerbel, R.; Haberkamp, K.; Keeton, S.

    1995-07-01

    AK Steel`s (formerly Armco) BOF shop was using a static precipitator for the primary collection. The system was designed for full combustion in the gas collecting hoods. No secondary dust collection was in place. A detailed study on alternative solutions led to a completely different system in 1990, and an order was awarded to Mannesmann Demag Corp. (MDC) in Dec. 1990. The new gas collection system is using suppressed combustion with the capability to collect Co at a later stage. The gas cleaning uses the Mannesmann Demag Baumco scrubber with a venturi throat for gas flow control. All auxiliary components, water treatment plant, electric substations and sludge handling were designed and supplied by MDC. The secondary dust collection covers the hot metal and scrap charging into the BOF`s, reladling, desulfurization and deslagging by a pulse jet baghouse. All emission limits set by the EPA and guaranteed by MDC have been met by the systems installed.

  1. Integrated Mg/TiO{sub 2}-ionic liquid system for deep desulfurization

    SciTech Connect (OSTI)

    Yin, Yee Cia; Kait, Chong Fai E-mail: hayyiratulfatimah@yahoo.com Fatimah, Hayyiratul E-mail: hayyiratulfatimah@yahoo.com Wilfred, Cecilia E-mail: hayyiratulfatimah@yahoo.com

    2014-10-24

    A series of Mg/TiO{sub 2} photocatalysts were prepared using wet impregnation method followed by calcination at 300, 400 and 500°C for 1 h. The photocatalysts were characterized using Thermal Gravimetric Analysis, Fourier-Transform Infrared Spectroscopy, X-Ray Diffraction, and Field Emission Scanning Electron Microscopy. The performance for deep desulfurization was investigated using model oil with 100 ppm sulfur (in the form of dibenzothiophene). The integrated system involves photocatalytic oxidation followed by ionic liquid-extraction processes. The best performing photocatalyst was 0.25wt% Mg loaded on titania calcined at 400°C (0.25Mg400), giving 98.5% conversion of dibenzothiophene to dibenzothiophene sulfone. The highest extraction efficiency of 97.8% was displayed by 1,2-diethylimidazolium diethylphosphate. The overall total sulfur removal was 96.3%.

  2. Desulfurization apparatus and method

    DOE Patents [OSTI]

    Rong, Charles; Jiang, Rongzhong; Chu, Deryn

    2013-06-18

    A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved by utilizing two to three units by weight of the first metal oxide for every unit of the second metal oxide.

  3. Two-stage coal gasification and desulfurization apparatus

    DOE Patents [OSTI]

    Bissett, Larry A.; Strickland, Larry D.

    1991-01-01

    The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.

  4. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the US Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate two technologies for the placement of coal combustion residues in abandoned underground coal mines, and will assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement, using virtually dry materials, and (2) hydraulic placement, using a {open_quotes}paste{close_quotes} mixture of materials with about 70% solids. Phase II of the overall program began April 1, 1996. The principal objective of Phase II is to develop and fabricate the equipment for placing the coal combustion by-products underground, and to conduct a demonstration of the technologies on the surface. Therefore, this quarter has been largely devoted to developing specifications for equipment components, visiting fabrication plants throughout Southern Illinois to determine their capability for building the equipment components in compliance with the specifications, and delivering the components in a timely manner.

  5. Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997

    SciTech Connect (OSTI)

    Chugh, Y.P.; Brackebusch, F.; Carpenter, J.

    1998-12-31

    This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

  6. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1995

    SciTech Connect (OSTI)

    1997-05-01

    On September 30, 1993, the U.S. Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SITJC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC-30252). Under the agreement SIUC will develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mine workings, and assess the environmental impact of such underground placements. This report discusses the technical progress achieved during the period October 1 - December 31, 1995. Rapid Aging Test columns were placed in operation during the second quarter of 1995, and some preliminary data were acquired during this quarter. These data indicate that the highly caustic pH is initially generated in the pneumatic mix, but that such pH is short lived. The initial pH rapidly declines to the range of 8 to 9. Leachates in this pH range will have little or no effect on environmental concerns. Dedicated sampling equipment was installed in the groundwater monitoring wells at the proposed placement site at the Peabody Number 10 mine. Also, the groundwater monitoring wells were {open_quotes}developed{close_quotes} during the quarter to remove the fines trapped in the sand pack and screen. A new procedure was used in this process, and proved successful. A series of tests concerning the geotechnical characteristics of the pneumatic mixes were conducted. Results show that both moisture content and curing time have a direct effect on the strength of the mixes. These are, of course, the expected general results. The Christmas holidays and the closing of the University during an extended period affected the progress of the program during the quarter. However, the program is essentially on schedule, both technically and fiscally, and any delays will be overcome during the first quarter of 1996.

  7. Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, January--March 1995

    SciTech Connect (OSTI)

    Chugh, Y.; Dutta, D.; Esling, S.

    1995-04-01

    On September 30, 1993, the U.S. Department of Energy, Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC 30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, as well as the management plan and the test plan for the overall program, and a discussion of these will not be repeated here. Rather, this report, will set forth the technical progress made during the period January 1 through March 31, 1995. The demonstration of the SEEC, Inc. technology for the transporting of coal combustion residues was completed with the unloading and final disposition of the three Collapsible Intermodal Containers (CIC). The loading and transport by rail of the three CIC`s was quire successful; however some difficulties were encountered in the unloading of the containers. A full topical report on the entire SEEC demonstration is being prepared. As a result of the demonstration some modifications of the SEEC concept may be undertaken. Also during the quarter the location of the injection wells at the Peabody No. 10 mine demonstration site were selected. Peabody Coal Company has developed the specifications for the wells and sought bids for the actual drilling. It is expected that the wells will be drilled early in May.

  8. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, April 1995--June 1995

    SciTech Connect (OSTI)

    Chugh, Y.P.; Dutta, D.; Esling, S.

    1995-07-01

    On September 30, 1993, the U.S. Department of Energy-Morgantown Energy Technology Center and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate several technologies for the placement of coal combustion residues in abandoned coal mines, and will assess the environmental impact of such underground residues placement. Previous quarterly Technical Progress Reports have set forth the specific objectives of the program, and a discussion of these is not repeated here. Rather, this report discusses the technical progress made during the period April 1 - June 30, 1995. A final topical report on the SEEC, Inc. demonstration of its technology for the transporting of coal combustion residues was completed during the quarter, although final printing of the report was accomplished early in July, 1995. The SEEC technology involves the use of Collapsible Intermodal Containers (CIC`s) developed by SEEC, and the transportation of such containers - filled with fly ash or other coal combustion residues - on rail coal cars or other transportation means. Copies of the final topical report, entitled {open_quotes}The Development and Testing of Collapsible Intermodal Containers for the Handling and Transport of Coal Combustion Residues{close_quotes} were furnished to the Morgantown Energy Technology Center. The Rapid Aging Test colums were placed in operation during the quarter. This test is to determine the long-term reaction of both the pneumatic and hydraulic mixtures to brine as a leaching material, and simulates the conditions that will be encountered in the actual underground placement of the coal combustion residues mixtures. The tests will continue for about one year.

  9. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes

    SciTech Connect (OSTI)

    Jozewicz, W. . Environmental Systems Div.); Rochelle, G.T. . Dept. of Chemical Engineering)

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide (Ca(OH){sub 2}) slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  10. Enzymatic desulfurization of coal

    SciTech Connect (OSTI)

    Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P.; Nochur, S.V.

    1991-05-16

    The overall objective of this program was to investigate the feasibility of an enzymatic desulfurization process specifically intended for organic sulfur removal from coal. Toward that end, a series of specific objectives were defined: (1) establish the feasibility of (bio)oxidative pretreatment followed by biochemical sulfate cleavage for representative sulfur-containing model compounds and coals using commercially-available enzymes; (2) investigate the potential for the isolation and selective use of enzyme preparations from coal-utilizing microbial systems for desulfurization of sulfur-containing model compounds and coals; and (3) develop a conceptual design and economic analysis of a process for enzymatic removal of organic sulfur from coal. Within the scope of this program, it was proposed to carry out a portion of each of these efforts concurrently. (VC)

  11. Desulfurization Sorbents for Transport-Bed Applications

    SciTech Connect (OSTI)

    Gupta, Raghubir P.; Turk, Brian S.; Vierheilig, Albert A.

    1997-07-01

    This project extends the prior work on the development of fluidizable zinc titanate particles using a spray-drying technique to impart high reactivity and attrition resistance. The specific objectives are: (1) To develop highly reactive and attrition-resistant zinc titanate sorbents in 40- to 150-{micro}m particle size range for transport reactor applications; (2) To transfer sorbent production technology to private sector; and (3) To provide technical support to Sierra Pacific Clean Coal Technology Demonstration plant and FETC's Hot-Gas Desulfurization Process Development Unit (PDU), both employing a transport reactor system.

  12. KINETICS OF Mn-BASED SORBENTS FOR HOT COAL GAS DESULFURIZATION

    SciTech Connect (OSTI)

    K.A. SADECKI; M.T. HEPWORTH

    1997-06-15

    Manganese-based sorbents have been investigated for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases. Four formulations of Mn-based sorbents were tested in an ambient-pressure fixed-bed reactor to determine steady state H2S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. In previous reports, the sulfidation and regeneration results from cyclic testing done at 550 and 600 °C were presented. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H2S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent at 600 °C. Regeneration tests determined that loaded pellets can be essentially completely regenerated in air/steam mixture at 750 °C with minimal sulfate formation. In this report, the performance of the leading formulation (designated C6-2) was investigated for high temperature removal of H2S from simulated coal-derived fuel gas under varying sorbent induration temperature, reaction temperature, and superficial gas velocity. Sulfidation experiments were performed in an ambient pressure fixed-bed reactor between 500 °C and 600 °C. Four tests were conducted with each test consisting of four cycles of sulfidation and regeneration. Results showed that the induration temperature of the sorbent and the reaction temperature greatly affected the H2S removal capacity of the sorbent while the superficial gas velocity between 1090 and 1635 cm/min had minimal affect on the sorbent's breakthrough capacity. Sorbent also showed 30 to 53% loss of its strength over four cycles of sulfidation and regeneration. The former being sorbent indurated at 1115 °C and the prior being sorbent indurated at 1100 °C.

  13. Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solid Oxide Fuel Cell Market Opportunity US Stationary - APU & CHP Natural Gas, LPG European ... Hot Reformate Desulfurizer Non-Regenerating Bed SOFC System Integration 21 DOE ...

  14. Management of dry flue gas desulfurization by-products in underground mines

    SciTech Connect (OSTI)

    Sevim, H.

    1997-06-01

    Disposal of coal combustion by-products (CCBs) in an environmentally sound manner is a major issue facing the coal and utility industries in the US today. Disposal into abandoned sections of underground coal mines may overcome many of the surface disposal problems along with added benefits such as mitigation of subsidence and acid mine drainage. However, many of the abandoned underground coal mines are located far from power plants, requiring long distance hauling of by-products which will significantly contribute to the cost of disposal. For underground disposal to be economically competitive, the transportation and handling cost must be minimized. This requires careful selection of the system and optimal design for efficient operation. The materials handling and system economics research addresses these issues. Transportation and handling technologies for CCBs were investigated from technical, environmental and economic points of view. Five technologies were found promising: (1) Pneumatic Trucks, (2) Pressure Differential Rail Cars, (3) Collapsible Intermodal Containers, (4) Cylindrical Intermodal Tanks, and (5) Coal Hopper Cars with Automatic Retractable Tarping. The first two technologies are currently being utilized in transporting by-products from power plants to disposal sites, whereas the next three are either in development or in conceptualization phases. In this research project, engineering design and cost models were developed for the first four technologies. The engineering design models are in the form of spreadsheets and serve the purpose of determining efficient operating schedules and sizing of system components.

  15. Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-09-27

    The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

  16. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-12-31

    This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

  17. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993

    SciTech Connect (OSTI)

    Sublette, K.L.

    1993-11-01

    There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

  18. Influence of CO{sub 2} and O{sub 2} on the reaction of Ca(OH){sub 2} under spray-drying flue gas desulfurization conditions

    SciTech Connect (OSTI)

    Ho, C.S.; Shih, S.M.; Lee, C.D.

    1996-11-01

    The influence of CO{sub 2} and O{sub 2} in the flue gas on the reaction of hydrated lime sorbent with SO{sub 2} was studied using a fixed-bed differential reactor under conditions prevailing in the spray-drying flue gas desulfurization process. With the presence of CO{sub 2}, the sulfation and carbonation reactions of Ca(OH){sub 2} took place simultaneously until Ca(OH){sub 2} ceased to react. The CaCO{sub 3} produced reacted further to form CaSO{sub 3}{center_dot}{1/2}H{sub 2}O. The apparent sulfation rate, total reaction rate, and final total conversion of Ca(OH){sub 2} were greater than those for the case without CO{sub 2}. The final total conversion was about 1.45 times that for the latter case at the conditions of 1,000 ppm SO{sub 2}, 60 C, and 70% relative humidity. The same effect was observed whether CO{sub 2} was present with O{sub 2} or not. Kinetic expressions obtained by assuming chemical reaction control and considering the surface coverage by product crystals best represented the kinetic data.

  19. Gas venting system

    DOE Patents [OSTI]

    Khan, Amjad; Dreier, Ken Wayne; Moulthrop, Lawrence Clinton; White, Erik James

    2010-06-29

    A system to vent a moist gas stream is disclosed. The system includes an enclosure and an electrochemical cell disposed within the enclosure, the electrochemical cell productive of the moist gas stream. A first vent is in fluid communication with the electrochemical cell for venting the moist gas stream to an exterior of the enclosure, and a second vent is in fluid communication with an interior of the enclosure and in thermal communication with the first vent for discharging heated air to the exterior of the enclosure. At least a portion of the discharging heated air is for preventing freezing of the moist gas stream within the first vent.

  20. Management of dry flue gas desulfurization by-products in underground mines. Quarterly technical progress report, [October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Thomasson, E.M.; Chugh, Y.P.; Esling, S.; Honaker, R.; Paul, B.; Sevin, H.

    1994-01-01

    The ``Management of Dry Flue Gas Desulfurization By-Products in Underground Mines`` program is one of the largest programs ever undertaken by the Mining Engineering Department of Southern Illinois university, both in terms of complexity and in terms of funding. Total funding over the expected four-year extent of the program, including both Department of Energy, matching Southern Illinois University funds, and contributed funds, this program exceeds three million dollars. The number of cooperating organizations adds to the management complexity of the program. It was believed, therefore, that sound management plan and management base is essential for the efficient and effective conduct of the program. This first quarter period (i.e., October 1--December 31, 1993) was developed to establishing the management base, developing a sound management plan, developing a test plan, and developing sound fiscal management and control. Actual technical operations, such as residue sample acquisition, residue analyses, groundwater sample acquisition and analyses, and material handling studies will get underway early in the next quarter (i.e., January 1--March 31, 1994). Some early results of residue analyses and groundwater analyses should be available by the end of the second quarter. These results will be reported in the next Technical Progress Report.

  1. Fluid/particle separation and coal cleaning: Progress, potential advances, and their effects on FGD (flue-gas desulfurization)

    SciTech Connect (OSTI)

    Livengood, C.D.; Doctor, R.D.

    1989-01-01

    Argonne National Laboratory (ANL) has been investigating several approaches to SO{sub 2} and NO{sub x} control that could play significant roles in future emission-control strategies. These techniques include greater application of an existing technology, physical coal cleaning (PCC), as a precombustion complement to FGD, and the combined removal of NO{sub x} and SO{sub 2} in flue-gas cleanup (FGC) systems based on spray drying (a wet/dry process) or in-duct injection of dry sorbents. This paper discusses the results of some of that research with particular attention to the beneficial role of fabric filtration in the dry and wet/dry FGC processes. 7 refs., 5 figs.

  2. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  3. Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 4, August 1, 1991--October 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-02-27

    The confined zone dispersion (CZD) process involves flue gas post-treatment, physically located between a boiler`s outlet and its particulate collector, which in the majority of cases is an electrostatic precipitator. The features that distinguish this process from other similar injection processes are: Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. Low residence time, made possible by the high effective surface area of the Type S lime. Localized dispersion of the reagent. Slurry droplets contact only part of the gas while the droplets are drying, to remove up to 50 percent of the S0{sub 2} and significant amounts of NO{sub x}. The process uses dual fluid rather than rotary atomizers. Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. Supplemental conditioning with S0{sub 3} is not believed necessary for satisfactory removal of particulate matter.

  4. Gas turbine premixing systems

    SciTech Connect (OSTI)

    Kraemer, Gilbert Otto; Varatharajan, Balachandar; Evulet, Andrei Tristan; Yilmaz, Ertan; Lacy, Benjamin Paul

    2013-12-31

    Methods and systems are provided for premixing combustion fuel and air within gas turbines. In one embodiment, a combustor includes an upstream mixing panel configured to direct compressed air and combustion fuel through premixing zone to form a fuel-air mixture. The combustor includes a downstream mixing panel configured to mix additional combustion fuel with the fule-air mixture to form a combustion mixture.

  5. Diesel Desulfurization Filter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desulfurization Filter Diesel Desulfurization Filter 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005deerrohrbach.pdf More ...

  6. Gas Recovery Systems | Open Energy Information

    Open Energy Info (EERE)

    Systems Jump to: navigation, search Name: Gas Recovery Systems Place: California Zip: 94550 Product: Turnkey landfill gas (LFG) energy extraction systems. References: Gas Recovery...

  7. Management of dry flue gas desulfurization by-products in underground mines. Technical progress report, 1 January--31 March 1994

    SciTech Connect (OSTI)

    Chugh, Y.P.; Esling, S.; Ghafoori, N.; Honaker, R.; Paul, B.; Sevim, H.; Thomasson, E.

    1994-04-01

    Southern Illinois University at Carbondale will develop and demonstrate several technologies for the handling and transport of dry coal combustion residues and for the underground placement in abandoned coal mines and assess associated environmental impacts. Although parts of the Residue Characterization portion of the program were delayed because residue samples were not obtained, other parts of the program are proceeding on schedule. The delays in obtaining residue samples were primarily caused by adverse weather conditions, the shut-down of one unit at the City Water, Light, and Power Company Plant for routing maintenance and problems due to conflicting schedules of utility and program personnel. However, by the end of the quarter most residue samples had been obtained, and the residue characterization studies were under way. Progress is described for five studies: environmental assessment and geotechnical stability and subsidence impacts; residue characterization; physico-chemical characterization of residues; identification and assessment of handling/transportation systems for FGD residues; and residue handling and transport.

  8. CONVERSION EXTRACTION DESULFURIZATION (CED) PHASE III

    SciTech Connect (OSTI)

    James Boltz

    2005-03-01

    This project was undertaken to refine the Conversion Extraction Desulfurization (CED) technology to efficiently and economically remove sulfur from diesel fuel to levels below 15-ppm. CED is considered a generic term covering all desulfurization processes that involve oxidation and extraction. The CED process first extracts a fraction of the sulfur from the diesel, then selectively oxidizes the remaining sulfur compounds, and finally extracts these oxidized materials. The Department of Energy (DOE) awarded Petro Star Inc. a contract to fund Phase III of the CED process development. Phase III consisted of testing a continuous-flow process, optimization of the process steps, design of a pilot plant, and completion of a market study for licensing the process. Petro Star and the Degussa Corporation in coordination with Koch Modular Process Systems (KMPS) tested six key process steps in a 7.6-centimeter (cm) (3.0-inch) inside diameter (ID) column at gas oil feed rates of 7.8 to 93.3 liters per hour (l/h) (2.1 to 24.6 gallons per hour). The team verified the technical feasibility with respect to hydraulics for each unit operation tested and successfully demonstrated pre-extraction and solvent recovery distillation. Test operations conducted at KMPS demonstrated that the oxidation reaction converted a maximum of 97% of the thiophenes. The CED Process Development Team demonstrated that CED technology is capable of reducing the sulfur content of light atmospheric gas oil from 5,000-ppm to less than 15-ppm within the laboratory scale. In continuous flow trials, the CED process consistently produced fuel with approximately 20-ppm of sulfur. The process economics study calculated an estimated process cost of $5.70 per product barrel. The Kline Company performed a marketing study to evaluate the possibility of licensing the CED technology. Kline concluded that only 13 refineries harbored opportunity for the CED process. The Kline study and the research team's discussions with

  9. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  10. Gas turbine cooling system

    DOE Patents [OSTI]

    Bancalari, Eduardo E.

    2001-01-01

    A gas turbine engine (10) having a closed-loop cooling circuit (39) for transferring heat from the hot turbine section (16) to the compressed air (24) produced by the compressor section (12). The closed-loop cooling system (39) includes a heat exchanger (40) disposed in the flow path of the compressed air (24) between the outlet of the compressor section (12) and the inlet of the combustor (14). A cooling fluid (50) may be driven by a pump (52) located outside of the engine casing (53) or a pump (54) mounted on the rotor shaft (17). The cooling circuit (39) may include an orifice (60) for causing the cooling fluid (50) to change from a liquid state to a gaseous state, thereby increasing the heat transfer capacity of the cooling circuit (39).

  11. Gas-recovery system

    DOE Patents [OSTI]

    Heckman, R.A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  12. Gas-Recovery System

    DOE Patents [OSTI]

    Heckman, R. A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  13. Philippine refiner completes diesel desulfurization project

    SciTech Connect (OSTI)

    Candido, S.S.; Crisostomo, E.V.

    1997-01-27

    In anticipation of tightening sulfur specifications on diesel fuel, Petron Corp. built a new 18,000 b/sd gas oil desulfurization unit (GODU) at its refinery in Bataan, Philippines. The GODU gives Petron sufficient diesel oil desulfurization capacity to meet demand for lower-sulfur diesel in the country. The project places the refinery in a pacesetter position to comply with the Philippine government`s moves to reduce air pollution, especially in urban centers, by reducing the sulfur specification for diesel to 0.5 wt% in 1996 from 0.7 wt% at the start of the project. Performance tests and initial operations of the unit have revealed a desulfurization efficiency of 91% vs. a guaranteed efficiency of 90%. A feed sulfur content of 1.33 wt% is reduced to 0.12 wt% at normal operating conditions. Operating difficulties during start-up were minimized through use of a detailed prestartup check conducted during the early stages of construction work.

  14. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  15. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, M.P.; Kedl, R.J.

    1984-09-12

    The invention presented relates to the development of a process utilizing a gas hydrate as a cool storage medium for alleviating electric load demands during peak usage periods. Several objectives of the invention are mentioned concerning the formation of the gas hydrate as storage material in a thermal energy storage system within a heat pump cycle system. The gas hydrate was formed using a refrigerant in water and an example with R-12 refrigerant is included. (BCS)

  16. Process gas solidification system

    DOE Patents [OSTI]

    Fort, William G. S.; Lee, Jr., William W.

    1978-01-01

    It has been the practice to (a) withdraw hot, liquid UF.sub.6 from various systems, (b) direct the UF.sub.6 into storage cylinders, and (c) transport the filled cylinders to another area where the UF.sub.6 is permitted to solidify by natural cooling. However, some hazard attends the movement of cylinders containing liquid UF.sub.6, which is dense, toxic, and corrosive. As illustrated in terms of one of its applications, the invention is directed to withdrawing hot liquid UF.sub.6 from a system including (a) a compressor for increasing the pressure and temperature of a stream of gaseous UF.sub.6 to above its triple point and (b) a condenser for liquefying the compressed gas. A network containing block valves and at least first and second portable storage cylinders is connected between the outlet of the condenser and the suction inlet of the compressor. After an increment of liquid UF.sub.6 from the condenser has been admitted to the first cylinder, the cylinder is connected to the suction of the compressor to flash off UF.sub.6 from the cylinder, thus gradually solidifying UF.sub.6 therein. While the first cylinder is being cooled in this manner, an increment of liquid UF.sub.6 from the condenser is transferred into the second cylinder. UF.sub.6 then is flashed from the second cylinder while another increment of liquid UF.sub.6 is being fed to the first. The operations are repeated until both cylinders are filled with solid UF.sub.6, after which they can be moved safely. As compared with the previous technique, this procedure is safer, faster, and more economical. The method also provides the additional advantage of removing volatile impurities from the UF.sub.6 while it is being cooled.

  17. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  18. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R.

    1987-01-01

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  19. Compressed gas fuel storage system

    DOE Patents [OSTI]

    Wozniak, John J.; Tiller, Dale B.; Wienhold, Paul D.; Hildebrand, Richard J.

    2001-01-01

    A compressed gas vehicle fuel storage system comprised of a plurality of compressed gas pressure cells supported by shock-absorbing foam positioned within a shape-conforming container. The container is dimensioned relative to the compressed gas pressure cells whereby a radial air gap surrounds each compressed gas pressure cell. The radial air gap allows pressure-induced expansion of the pressure cells without resulting in the application of pressure to adjacent pressure cells or physical pressure to the container. The pressure cells are interconnected by a gas control assembly including a thermally activated pressure relief device, a manual safety shut-off valve, and means for connecting the fuel storage system to a vehicle power source and a refueling adapter. The gas control assembly is enclosed by a protective cover attached to the container. The system is attached to the vehicle with straps to enable the chassis to deform as intended in a high-speed collision.

  20. Kinetics of Mn-based sorbents for hot coal gas desulfurization: Task 2, Exploratory experimental studies: Single pellet tests; Rate mechanism analysis. Quarterly report, June 15, 1996--September 15, 1996

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1996-09-11

    Currently, the Morgantown Energy Technology Center, Department of Energy (DOE/METC) is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressures, and under varying degrees of reducing atmospheres. Also, it must regenerate nearly ideally to maintain activity over numerous cycles. Furthermore, regeneration must yield a sulfur product which is economically recoverable directly or indirectly. Several metal oxides have been investigated as regenerable sorbents for the removal of hydrogen sulfide (the primary sulfur bearing compound) from hot fuel gases. MnO was shown to have an intrinsic reaction rate approximately one order of magnitude greater than the rate or reaction with either CaO or ZnO and two orders of magnitude greater than the reaction rate with V{sub 2}0{sub 3}. Manganese also shows desulfurization potential in the temperature range of 600-700{degrees}C where metal oxides currently known to be reactive with H{sub 2}S are unsatisfactorily. In response to stability difficulties of single and binary metal oxide sorbents, increasing effort is being directed towards incorporation of an inert component into sorbent formulation as witnessed by the various Zn-titanates. Primarily, the inert component increases pore structure integrity while stabilizing the active metal oxide against reduction. This report will address testing of Mn-based sorbents in an ambient pressure fixed-bed reactor. Steady-state H{sub 2}S concentrations and breakthrough times will be presented.

  1. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  2. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  3. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  4. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  5. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  6. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research Development Center (AMAX R D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  7. System of treating flue gas

    DOE Patents [OSTI]

    Ziegler, D.L.

    1975-12-01

    A system is described for treating or cleaning incinerator flue gas containing acid gases and radioactive and fissionable contaminants. Flue gas and a quench solution are fed into a venturi and then tangentially into the lower portion of a receptacle for restricting volumetric content of the solution. The upper portion of the receptacle contains a scrub bed to further treat or clean the flue gas.

  8. Combustion-gas recirculation system

    DOE Patents [OSTI]

    Baldwin, Darryl Dean

    2007-10-09

    A combustion-gas recirculation system has a mixing chamber with a mixing-chamber inlet and a mixing-chamber outlet. The combustion-gas recirculation system may further include a duct connected to the mixing-chamber inlet. Additionally, the combustion-gas recirculation system may include an open inlet channel with a solid outer wall. The open inlet channel may extend into the mixing chamber such that an end of the open inlet channel is disposed between the mixing-chamber inlet and the mixing-chamber outlet. Furthermore, air within the open inlet channel may be at a pressure near or below atmospheric pressure.

  9. The Biocatalytic Desulfurization Project

    SciTech Connect (OSTI)

    David Nunn; James Boltz; Philip M. DiGrazia; Larry Nace

    2006-03-03

    The material in this report summarizes the Diversa technical effort in development of a biocatalyst for the biodesulfurization of Petro Star diesel as well as an economic report of standalone and combined desulfurization options, prepared by Pelorus and Anvil, to support and inform the development of a commercially viable process. We will discuss goals of the projected as originally stated and their modification as guided by parallel efforts to evaluate commercialization economics and process parameters. We describe efforts to identify novel genes and hosts for the generation of an optimal biocatalyst, analysis of diesel fuels (untreated, chemically oxidized and hydrotreated) for organosulfur compound composition and directed evolution of enzymes central to the biodesulfurization pathway to optimize properties important for their use in a biocatalyst. Finally we will summarize the challenges and issues that are central to successful development of a viable biodesulfurization process.

  10. Backscatter absorption gas imaging system

    DOE Patents [OSTI]

    McRae, T.G. Jr.

    A video imaging system for detecting hazardous gas leaks. Visual displays of invisible gas clouds are produced by radiation augmentation of the field of view of an imaging device by radiation corresponding to an absorption line of the gas to be detected. The field of view of an imager is irradiated by a laser. The imager receives both backscattered laser light and background radiation. When a detectable gas is present, the backscattered laser light is highly attenuated, producing a region of contrast or shadow on the image. A flying spot imaging system is utilized to synchronously irradiate and scan the area to lower laser power requirements. The imager signal is processed to produce a video display.

  11. Backscatter absorption gas imaging system

    DOE Patents [OSTI]

    McRae, Jr., Thomas G.

    1985-01-01

    A video imaging system for detecting hazardous gas leaks. Visual displays of invisible gas clouds are produced by radiation augmentation of the field of view of an imaging device by radiation corresponding to an absorption line of the gas to be detected. The field of view of an imager is irradiated by a laser. The imager receives both backscattered laser light and background radiation. When a detectable gas is present, the backscattered laser light is highly attenuated, producing a region of contrast or shadow on the image. A flying spot imaging system is utilized to synchronously irradiate and scan the area to lower laser power requirements. The imager signal is processed to produce a video display.

  12. Fuel cell gas management system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur

    2000-01-11

    A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  13. EIA - Natural Gas Pipeline Network - Largest Natural Gas Pipeline Systems

    U.S. Energy Information Administration (EIA) Indexed Site

    Interstate Pipelines Table About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Thirty Largest U.S. Interstate Natural Gas Pipeline Systems, 2008 (Ranked by system capacity) Pipeline Name Market Regions Served Primary Supply Regions States in Which Pipeline Operates Transported in 2007 (million dekatherm)1 System Capacity (MMcf/d) 2 System Mileage Columbia Gas Transmission Co. Northeast Southwest, Appalachia DE, PA, MD, KY, NC, NJ, NY,

  14. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 250 citations and includes a subject term index and title list.)

  15. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  16. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-04-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  17. Desulfurization of coal and petroleum. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    The bibliography contains citations concerning the desulfurization of coal, coal liquids, and crude oil. Flotation heap leaching, oxydesulfurization, metal oxide, microwave process, and chlorination are among the pre-combustion processes discussed. Coal liquefaction and gasification are only included if sulfur removal is stressed. Flue gas desulfurization and other post-combustion sulfur control processes are excluded. (Contains 250 citations and includes a subject term index and title list.)

  18. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Berggren, M.H.; Jha, M.C.

    1989-10-01

    AMAX Research Development Center (AMAX R D) investigated methods for enhancing the reactivity and durability of zinc ferrite desulfurization sorbents. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For this program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and oxidation. Two base case sorbents, a spherical pellet and a cylindrical extrude used in related METC-sponsored projects, were used to provide a basis for the aimed enhancement in durability and reactivity. Sorbent performance was judged on the basis of physical properties, single particle kinetic studies based on thermogravimetric (TGA) techniques, and multicycle bench-scale testing of sorbents. A sorbent grading system was utilized to quantify the characteristics of the new sorbents prepared during the program. Significant enhancements in both reactivity and durability were achieved for the spherical pellet shape over the base case formulation. Overall improvements to reactivity and durability were also made to the cylindrical extrude shape. The primary variables which were investigated during the program included iron oxide type, zinc oxide:iron oxide ratio, inorganic binder concentration, organic binder concentration, and induration conditions. The effects of some variables were small or inconclusive. Based on TGA studies and bench-scale tests, induration conditions were found to be very significant.

  19. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  20. Kinetics of Mn-based sorbents for hot coal gas desulfurization. Task 2 -- Exploratory experimental studies: Single pellet tests; rate mechanism analysis. Quarterly report, December 15, 1995--March 15, 1996

    SciTech Connect (OSTI)

    Hepworth, M.T.; Berns, J.

    1996-03-15

    Currently, the Morgantown Energy Technology Center, is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressure`s, and under varying degrees of reducing atmospheres. Thus, high conversion of the metal oxide and low hydrogen sulfide exit partial pressures. Also, it must regenerate nearly ideally to maintain activity over numerous cycles. Furthermore, regeneration must yield a sulfur product which is economically recoverable directly or indirectly. This cyclic process requires a holistic approach as any one criteria may eliminate a candidate sorbent from further consideration. Over fifty induration campaigns have been conducted among the fifteens Mn-based sorbent formulations. All indurated sorbents has been tested for crush strength and chemical analysis. Also, fifteen sorbent formulations have been tested in a TGA for at least on e induration condition. Subsequently described are the three main groups of formulations tested. They are the MnCO{sub 3} supported with TiO{sub 2} (with or without bentonite), MnCO{sub 3} supported with Al{sub 2}O{sub 3} (with or without porosity enhancers), and MnO{sub 2} ore supported with alundum (with and without bentonite).

  1. Anion-exchange resin-based desulfurization process

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.

    1991-01-01

    The University of Tennessee Space Institute (UTSI) has been directed to further develop an anion-exchange, resin-based desulfurization concept that has been developed and tested on a limited scope for feasibility. From environmental as well as the economic viewpoints, it is necessary that the soluble sulfates of alkali metal sorbents be desulfurized (regenerated) and recycled to make regenerative flue gas desulfurization options more attractive. In order to achieve this, a low-temperature, low-cost desulfurization process to reactivate spent alkali metal sorbents is necessary. During the reporting period, January 1, 1991--March 31, 1991, the following progress has been made: (1) A batch mode screening procedure was developed to evaluate performance of candidate resins, relatively easily and quickly. (2) Using this procedure, screening experiments were carried out for IRA-68 (base case) and IRA-35 resins. From preliminary results, IRA-68 resin appears to perform better than the IRA-35 resin. Also, both the resins appear to maintain their SO{sub 4}{sup 2{minus}} ion capacity very well, up to 4 cycles.

  2. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect (OSTI)

    Unknown

    2000-01-01

    The activities of the Advanced Gas Turbine Systems Research (AGRSR) program are described in the quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education) and Research. Items worthy of note are presented in extended bullet format following the appropriate heading.

  3. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect (OSTI)

    Unknown

    2002-04-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for this reporting period are described in this quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education), Research and Miscellaneous Related Activity. Items worthy of note are presented in extended bullet format following the appropriate heading.

  4. ADVANCED GAS TURBINE SYSTEMS RESEARCH

    SciTech Connect (OSTI)

    Unknown

    2002-02-01

    The activities of the Advanced Gas Turbine Systems Research (AGTSR) program for this reporting period are described in this quarterly report. The report is divided into discussions of Membership, Administration, Technology Transfer (Workshop/Education), Research and Miscellaneous Related Activity. Items worthy of note are presented in extended bullet format following the appropriate heading.

  5. Gas sampling system for a mass spectrometer

    DOE Patents [OSTI]

    2003-12-30

    The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

  6. Gas characterization system software acceptance test report

    SciTech Connect (OSTI)

    Vo, C.V.

    1996-03-28

    This document details the results of software acceptance testing of gas characterization systems. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  7. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1991-06-01

    Advanced integrated gasification combined cycle (IGCC) power systems require the development of high-temperature desulfurization sorbents capable of removing hydrogen sulfide from coal gasifier down to very low levels. The objective of this investigation was to identify and demonstrate methods for enhancing the long-term chemical reactivity and mechanical strength of zinc ferrite, a leading regenerable sorbent, for fluidized-bed applications. Fluidized sorbent beds offer significant potential in IGCC systems because of their ability to control the highly exothermic regeneration involved. However, fluidized beds require a durable, attrition-resistant sorbent in the 100--300 {mu}m size range. A bench-scale high-temperature, high- pressure (HTHP) fluidized-bed reactor (7.6-cm I.D.) system capable of operating up to 24 atm and 800{degree}C was designed, built and tested. A total of 175 sulfidation-regeneration cycles were carried out using KRW-type coal gas with various zinc ferrite formulations. A number of sorbent manufacturing techniques including spray drying, impregnation, crushing and screening, and granulation were investigated. While fluidizable sorbents prepared by crushing durable pellets and screening had acceptable sulfur capacity, they underwent excessive attrition during multicycle testing. The sorbent formulations prepared by a proprietary technique were found to have excellent attrition resistance and acceptable chemical reactivity during multicycle testing. However, zinc ferrite was found to be limited to 550{degree}C, beyond which excessive sorbent weakening due to chemical transformations, e.g., iron oxide reduction, was observed.

  8. Theoretical approach for enhanced mass transfer effects in-duct flue gas desulfurization processes. Volume 2, Duct spray drying: Final report

    SciTech Connect (OSTI)

    Jozewicz, W.; Rochelle, G.T.

    1992-01-29

    Removal of sulfur dioxide (SO{sub 2}) from the flue gas of coal- burning power plants can be achieved by duct spray drying using calcium hydroxide [Ca(OH){sub 2}] slurries. A primary objective of this research was to discover the aspects of mass transfer into Ca(OH){sub 2} slurries which limit SO{sub 2} absorption. A bench- scale stirred tank reactor with a flat gas/liquid interface was used to simulate SO{sub 2} absorption in a slurry droplet. The absorption rate of SO{sub 2} from gas concentrations of 500 to 5000 ppm was measured at 55{degrees}C in clear solutions and slurries of Ca(OH){sub 2} up to 1.0 M (7 wt percent). Results are reported in terms of the enhancement factor, {O}. This research will allow prediction of conditions where the absorption of SO{sub 2} in Ca(OH){sub 2} slurries can be enhanced by changes to liquid phase constituents (under which SO{sub 2} absorption is controlled by liquid film mass transfer). Experiments in the stirred tank have shown that SO{sub 2} absorption in a 1.0 M Ca(OH){sub 2} slurry was completely dominated by gas film mass transfer with a large excess of Ca(OH){sub 2} but becomes controlled by liquid film resistance at greater than 50 percent Ca(OH){sub 2} utilization. (VC)

  9. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research Development Center (AMAX R D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  10. EIA - Natural Gas Pipeline System - Northeast Region

    U.S. Energy Information Administration (EIA) Indexed Site

    Northeast Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Northeast Region Overview | Domestic Gas | Canadian Imports | Regional Pipeline Companies & Links Overview Twenty interstate natural gas pipeline systems operate within the Northeast Region (Connecticut, Delaware, Massachusetts, Maine, New Hampshire, New Jersey, New York, Pennsylvania, Rhode Island, Virginia, and West Virginia). These

  11. Desulfurization sorbent regeneration

    DOE Patents [OSTI]

    Jalan, V.M.; Frost, D.G.

    1982-07-07

    A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

  12. Utility FGD Survey, January--December 1989. Volume 2, Design performance data for operating FGD systems, Part 1

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M.

    1992-03-01

    The Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. The development status (operational, under construction, or in the planning stages), system supplier, process, waste disposal practice, and regulatory class are tabulated alphabetically by utility company.

  13. Mercury sorbent delivery system for flue gas

    DOE Patents [OSTI]

    Klunder; ,Edgar B.

    2009-02-24

    The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

  14. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, William A.; Healy, Francis E.; Sapienza, Richard S.

    1985-01-01

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  15. Low temperature aqueous desulfurization of coal

    DOE Patents [OSTI]

    Slegeir, W.A.; Healy, F.E.; Sapienza, R.S.

    1985-04-18

    This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

  16. Flammable Gas Detection for the D-Zero Gas System

    SciTech Connect (OSTI)

    Spires, L.D.; Foglesong, J.; /Fermilab

    1991-02-11

    The use of flammable gas and high voltage in detector systems is common in many experiments at Fermilab. To mitigate the hazards associated with these systems, Fermilab Engineering Standard SD-45B (Ref. 1) was adopted. Since this note is meant to be a guide and not a mandatory standard, each experiment is reviewed for compliance with SD-45B by the flammable gas safety subcommittee. Currently, there are only two types of flammable gas in use, ethane (Appendix A) and methane (Appendix B). The worst flammable-gas case is C2H6 (ethane), which has an estimated flow rate that is 73% of the CH4 (methane) flow but a heat of combustion (in kcal/g-mole) that is 173% of that of methane. In the worst case, if ethane were to spew through its restricting orifice into its gas line at 0 psig and then through a catastrophic leak into Room 215 (TRD) or Room 511 (CDC/FDCNTX), the time that would be required to build up a greater than Class 1 inventory (0.4kg H2 equivalent) would be 5.2 hours (Ref. 2). Therefore a worst-case flammable gas leak would have to go undetected for over 5 hours in order to transform a either mixing room to an environment with a Risk Class greater than Class 1. The mixing systems, gas lines, and detectors themselves will be thoroughly leak checked prior to active service. All vessels that are part of the mixing systems will be protected from overpressure by safety valves vented outside the building. Both the input and output of all detector volumes are protected from overpressure in the same way. The volume immediately outside the central tracking detectors is continuously purged by nitrogen from boiloff from the main nitrogen dewar at the site. However, if flammable gas were to build up in the mixing rooms or particular detector areas, no matter how unlikely, flammable gas detectors that are part of the interlock chain of each gas mixing system will shut down the appropriate system. This includes shutting off the output of flammable gas manifolds within the

  17. Utility FGD survey, January--December 1989. Volume 2, Design performance data for operating FGD systems: Part 2

    SciTech Connect (OSTI)

    Hance, S.L.; McKibben, R.S.; Jones, F.M.

    1992-03-01

    This is Volume 2 part 2, of the Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. This volume particularly contains basic design and performance data.

  18. Adaptive control system for gas producing wells

    SciTech Connect (OSTI)

    Fedor, Pashchenko; Sergey, Gulyaev; Alexander, Pashchenko

    2015-03-10

    Optimal adaptive automatic control system for gas producing wells cluster is proposed intended for solving the problem of stabilization of the output gas pressure in the cluster at conditions of changing gas flow rate and changing parameters of the wells themselves, providing the maximum high resource of hardware elements of automation.

  19. EIS-0139: Trans-Alaska Gas System

    Broader source: Energy.gov [DOE]

    This EIS analyzes the Yukon Pacific Corporation's proposed construction of the Trans-Alaska Gas System (TAGS), a 796.5-mile long, 36-inch diameter pipeline to transport high-pressured natural gas between Prudhoe Bay and a tidewater terminal and liquefied natural gas plant near Anderson Bay, Alaska.

  20. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken; Moulthrop, Lawrence Clinton; Dreier, Ken Wayne; Miller, Jacob Andrew

    2010-03-16

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  1. Turbocharged engine exhaust gas recirculation system

    SciTech Connect (OSTI)

    Stachowicz, R.W.

    1984-01-24

    Improved exhaust gas recirculation systems for turbocharged gas engines that include an exhaust pipe, a turbocharger connected thereto, and a carburetor connected with a source of gas for the engine. The recirculation system includes an air conduit extending from the turbocharger compressor discharge to a venturi, an exhaust gas conduit that extends from a connection with the exhaust pipe between the engine and the turbocharger to the venturi, a second air conduit that extends from the exhaust pipe to a connection with the first air conduit, and control valves located in the exhaust gas conduit and in the second air conduit. The valves are closed when the engine is being started or idling at no load and open when a load is imposed or when engine rpm's are increased. No pumps, blowers, etc. are needed because the system operates on a differential in pressure created within the system to cause the exhaust gas recirculation.

  2. High-volume, high-value usage of Flue Gas Desulfurization (FGD) by-products in underground mines Phase 1: Laboratory investigations. Quarterly report, July 1994--September 1994

    SciTech Connect (OSTI)

    1994-12-01

    During the quarter a second series of samples were collected and partially characterized chemically and mineralogically. The samples were collected at the disposal site operated by Freeman United Coal Co. The second collection was necessary because of deterioration due to hydration of the original samples. A study of the hydration characteristics was completed during the quarter. Important reactions included the immediate formation of ettringite and portlandite. The hydration and transformation was found to be a slow process. A second phase of gypsum formation from ettringite deterioration was identified. The slow hydration of anhydrite with its resultant swell is a potential problem which will be addressed further. Geotechnical characterization, during the quarter included completion of the preliminary characterization, analysis of the findings, experimentation with sample preparation for the final characterization/mix design, and design of the final experimental program. The analysis of the coals collected during the core drilling and hydrologic planning were completed. Also during the quarter a meeting was held with representatives of the shotcrete industry to discuss transport systems for emplacement. The pros and cons of pneumatic and hydraulic systems were discussed and plans formulated for further investigations.

  3. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology As natural gas travels through infrastructure, from well-head to customer meter, small ...

  4. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, D.D.

    A chromatographic system is described that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a nontransparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extreme low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  5. Dual liquid and gas chromatograph system

    DOE Patents [OSTI]

    Gay, Don D.

    1985-01-01

    A chromatographic system that utilizes one detection system for gas chromatographic and micro-liquid chromatographic determinations. The detection system is a direct-current, atmospheric-pressure, helium plasma emission spectrometer. The detector utilizes a non-transparent plasma source unit which contains the plasma region and two side-arms which receive effluents from the micro-liquid chromatograph and the gas chromatograph. The dual nature of this chromatographic system offers: (1) extreme flexibility in the samples to be examined; (2) extremely low sensitivity; (3) element selectivity; (4) long-term stability; (5) direct correlation of data from the liquid and gas samples; (6) simpler operation than with individual liquid and gas chromatographs, each with different detection systems; and (7) cheaper than a commercial liquid chromatograph and a gas chromatograph.

  6. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H.

    1995-12-01

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  7. Hand-held multiple system gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M.

    2001-01-01

    A multiple parallel hand-held gas chromatograph (GC) system which includes several independent GCs. Each independent GC has its own injector, separation column, detector and oven and the GCs are mounted in a light weight hand-held assembly. Each GC operates independently and simultaneously. Because of different coatings in different separation columns, different retention times for the same gas will be measured. Thus, for a GC system with multiple parallel GCs, the system can measure, in a short period, different retention times and provide a cross-reference in the determination of the measured gas and to become a two-dimensional system for direct field use.

  8. Flue gas desulfurization gypsum and fly ash

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

  9. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  10. Southern California Gas | Energy Systems Integration | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Southern California Gas Southern California Gas Company has joined with NREL and the National Fuel Cell Research Center to launch demonstration projects to create and test a carbon-free, power-to-gas system for the first time ever in the United States. The technology converts electricity into gaseous energy and could provide North America with a large-scale, cost-effective solution for storing excess energy produced from renewable sources. Read our news story on the project.

  11. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A.; Townsend, Carl W.

    1989-01-01

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  12. Reliability of natural gas cogeneration systems

    SciTech Connect (OSTI)

    1995-12-01

    Cogeneration systems fueled by natural gas exceed the reliability of most central station power generating units, according to a study conducted by RINC Corporation for Gas Research Institute (GRI). In the study, researchers obtained operating data from 122 natural gas cogeneration units nationwide representing 2,200 megawatts (MW) of capacity and nearly 2 million hours of operating time at 37 facilities. Units were grouped into categories reflecting size (from 60 kilowatts to 100 MW), type of system (gas engine or gas turbine technology), use of emission controls, and type of thermal application. Various types and sizes of gas systems reported average availability factors ranging from 90.0 to 95.8 versus a weighted average of 85.9 percent for fossil-fuel steam, nuclear, and gas-turbine-based central station power generating units. Comparisons are based on study data and data reported by the North American Electric Reliability Council for utility power plants. Gas cogeneration can improve utility operations because as a group the relatively small, dispersed cogeneration units are more reliable than one or more large central station units of similar capacity.

  13. Gas hydrate cool storage system

    DOE Patents [OSTI]

    Ternes, Mark P. (Knoxville, TN); Kedl, Robert J. (Oak Ridge, TN)

    1985-01-01

    This invention is a process for formation of a gas hydrate to be used as a cool storage medium using a refrigerant in water. Mixing of the immiscible refrigerant and water is effected by addition of a surfactant and agitation. The difficult problem of subcooling during the process is overcome by using the surfactant and agitation and performance of the process significantly improves and approaches ideal.

  14. Hot gas filter and system assembly

    DOE Patents [OSTI]

    Lippert, Thomas Edwin; Palmer, Kathryn Miles; Bruck, Gerald Joseph; Alvin, Mary Anne; Smeltzer, Eugene E.; Bachovchin, Dennis Michael

    1999-01-01

    A filter element for separating fine dirty particles from a hot gas. The filter element comprises a first porous wall and a second porous wall. Each porous wall has an outer surface and an inner surface. The first and second porous walls being coupled together thereby forming a substantially closed figure and open at one end. The open end is formed to be coupled to a hot gas clean up system support structure. The first and second porous walls define a channel beginning at the open end and terminate at the closed end through which a filtered clean gas can flow through and out into the clean gas side of a hot gas clean up system.

  15. Hot gas filter and system assembly

    DOE Patents [OSTI]

    Lippert, T.E.; Palmer, K.M.; Bruck, G.J.; Alvin, M.A.; Smeltzer, E.E.; Bachovchin, D.M.

    1999-08-31

    A filter element is described for separating fine dirty particles from a hot gas. The filter element comprises a first porous wall and a second porous wall. Each porous wall has an outer surface and an inner surface. The first and second porous walls being coupled together thereby forming a substantially closed figure and open at one end. The open end is formed to be coupled to a hot gas clean up system support structure. The first and second porous walls define a channel beginning at the open end and terminate at the closed end through which a filtered clean gas can flow through and out into the clean gas side of a hot gas clean up system. 8 figs.

  16. Diagnostic system for exhaust gas recirculation device

    SciTech Connect (OSTI)

    Tsurusaki, S.

    1988-12-27

    A diagnostic system of an exhaust gas recirculation device is described having an exhaust gas recirculation control valve which is arranged in an exhaust gas recirculation passage interconnecting an exhaust passage to an intake passage of an internal combustion engine, the diagnostic system comprising: determining whether the engine is operating in a state at which the recirculation of exhaust gas is to be carried out; detecting a temperature in the exhaust gas recirculation passage downstream of the exhaust gas recirculation control valve; having a count value which is variable between a predetermined first value and a predetermined second value, the count value being changed from the first value toward the second value when the engine is operating in a state where the recirculation of exhaust is to be carried out; means for storing a first temperature detected by the detecting means when the count value is equal to the first value; and second determining means for obtaining a difference between the first temperature and second temperature detected by the detecting means when the count value becomes equal to the second value, to thereby determine that a malfunction has occurred in the exhaust gas recirculation device when the difference is lower than a predetermined value.

  17. Computer systems and software description for gas characterization system

    SciTech Connect (OSTI)

    Vo, C.V.

    1997-04-01

    The Gas Characterization System Project was commissioned by TWRS management with funding from TWRS Safety, on December 1, 1994. The project objective is to establish an instrumentation system to measure flammable gas concentrations in the vapor space of selected watch list tanks, starting with tank AN-105 and AW-101. Data collected by this system is meant to support first tank characterization, then tank safety. System design is premised upon Characterization rather than mitigation, therefore redundancy is not required.

  18. NEXT GENERATION GAS TURBINE SYSTEMS STUDY

    SciTech Connect (OSTI)

    Benjamin C. Wiant; Ihor S. Diakunchak; Dennis A. Horazak; Harry T. Morehead

    2003-03-01

    Under sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse Power Corporation has conducted a study of Next Generation Gas Turbine Systems that embraces the goals of the DOE's High Efficiency Engines and Turbines and Vision 21 programs. The Siemens Westinghouse Next Generation Gas Turbine (NGGT) Systems program was a 24-month study looking at the feasibility of a NGGT for the emerging deregulated distributed generation market. Initial efforts focused on a modular gas turbine using an innovative blend of proven technologies from the Siemens Westinghouse W501 series of gas turbines and new enabling technologies to serve a wide variety of applications. The flexibility to serve both 50-Hz and 60-Hz applications, use a wide range of fuels and be configured for peaking, intermediate and base load duty cycles was the ultimate goal. As the study progressed the emphasis shifted from a flexible gas turbine system of a specific size to a broader gas turbine technology focus. This shift in direction allowed for greater placement of technology among both the existing fleet and new engine designs, regardless of size, and will ultimately provide for greater public benefit. This report describes the study efforts and provides the resultant conclusions and recommendations for future technology development in collaboration with the DOE.

  19. Maintaining urban gas systems demands special technologies

    SciTech Connect (OSTI)

    Anglero, T.F. )

    1994-04-01

    Brooklyn Union Gas Co. has been providing gas to 50% of the population of New York City for the last 100 years. The company has constructed an elaborate gas distribution network that includes a gas main under nearly every city street in a service territory that includes Brooklyn, Staten Island and parts of Queens. Conventional ways of pipeline construction and maintenance are inadequate in today's environment of heightened competition, increased regulations and, most importantly, demanding customer expectations of quality service. As a result, Brooklyn Union Gas must use special construction and maintenance methods in its operations, and in particular trenchless technologies. Over the past 10 years the company has paid close attention to developing a variety of trenchless techniques. Like many gas distribution companies providing service in densely populated urban areas, Brooklyn Union must operate and maintain its gas distribution network in a challenging environment of increasing governmental regulation and escalating field construction costs. Technological innovation is not a luxury, but instead a necessity to achieve corporate growth, regulatory compliance and greater customer satisfaction. Trenchless technologies offset rising pipe installation costs and provide benefits both to the customer and the company. Of special value to Brooklyn Union is the development of systems that renovate old metal pipes by lining. Such techniques are described.

  20. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  1. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1990-01-01

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  2. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1989-01-01

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  3. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 8, July--September 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-11-14

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  4. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 9, October--December 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-03-06

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  5. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report No. 3, April--June 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-08-28

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  6. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 2, January--March 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Baltich, L.K.; Berggren, M.H.

    1987-05-18

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  7. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Volume 1, Bench-scale testing and analysis

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1989-05-02

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  8. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 7, April--June 1988

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-08-19

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for enhancing the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hot coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. For the present program, the reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point and at saturation in a bench-scale, fixed-bed reactor. Durability may be defined as the ability of the sorbent to maintain important physical characteristics such As size, strength, and specific surface area during 10 cycles of sulfidation and oxidation.

  9. ,"U.S. Intrastate Natural Gas Pipeline Systems"

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Co","Kinder Morgan Energy Partners LP ... Gas Storage LLC","Intrastate",100,30,"Midwest","MI",,,... "Cardinal Pipeline System","Quicksilver ...

  10. Recombinant DNA encoding a desulfurization biocatalyst

    DOE Patents [OSTI]

    Rambosek, J.; Piddington, C.S.; Kovacevich, B.R.; Young, K.D.; Denome, S.A.

    1994-10-18

    This invention relates to a recombinant DNA molecule containing a gene or genes which encode a biocatalyst capable of desulfurizing a fossil fuel which contains organic sulfur molecules. For example, the present invention encompasses a recombinant DNA molecule containing a gene or genes of a strain of Rhodococcus rhodochrous. 13 figs.

  11. Recombinant DNA encoding a desulfurization biocatalyst

    DOE Patents [OSTI]

    Rambosek, John; Piddington, Chris S.; Kovacevich, Brian R.; Young, Kevin D.; Denome, Sylvia A.

    1994-01-01

    This invention relates to a recombinant DNA molecule containing a gene or genes which encode a biocatalyst capable of desulfurizing a fossil fuel which contains organic sulfur molecules. For example, the present invention encompasses a recombinant DNA molecule containing a gene or genes of a strain of Rhodococcus rhodochrous.

  12. Oilfield Flare Gas Electricity Systems (OFFGASES Project)

    SciTech Connect (OSTI)

    Rachel Henderson; Robert Fickes

    2007-12-31

    The Oilfield Flare Gas Electricity Systems (OFFGASES) project was developed in response to a cooperative agreement offering by the U.S. Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) under Preferred Upstream Management Projects (PUMP III). Project partners included the Interstate Oil and Gas Compact Commission (IOGCC) as lead agency working with the California Energy Commission (CEC) and the California Oil Producers Electric Cooperative (COPE). The project was designed to demonstrate that the entire range of oilfield 'stranded gases' (gas production that can not be delivered to a commercial market because it is poor quality, or the quantity is too small to be economically sold, or there are no pipeline facilities to transport it to market) can be cost-effectively harnessed to make electricity. The utilization of existing, proven distribution generation (DG) technologies to generate electricity was field-tested successfully at four marginal well sites, selected to cover a variety of potential scenarios: high Btu, medium Btu, ultra-low Btu gas, as well as a 'harsh', or high contaminant, gas. Two of the four sites for the OFFGASES project were idle wells that were shut in because of a lack of viable solutions for the stranded noncommercial gas that they produced. Converting stranded gas to useable electrical energy eliminates a waste stream that has potential negative environmental impacts to the oil production operation. The electricity produced will offset that which normally would be purchased from an electric utility, potentially lowering operating costs and extending the economic life of the oil wells. Of the piloted sites, the most promising technologies to handle the range were microturbines that have very low emissions. One recently developed product, the Flex-Microturbine, has the potential to handle the entire range of oilfield gases. It is deployed at an oilfield near Santa Barbara to run on waste gas that is only 4% the

  13. Two-stage regeneration of zinc ferrite desulfurization sorbent

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1988-06-28

    The Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE) is interested in the potential of using a two-step process for regenerating the zinc ferrite desulfurization sorbent. In the first regeneration step, a gas mixture consisting of 12 percent SO{sub 2}, 2 percent O{sub 2}, and 86 percent N{sub 2} is used to convert zinc and iron sulfides to their sulfate forms using a sorbent bed inlet temperature of about 850{degrees}F (454{degrees}C). For the second step, the temperature is raised to about 1400{degrees}F (760{degrees}C), and the sulfates are decomposed to oxides with the concurrent release of sulfur dioxide. The same gas composition used for first step is also used for the second step. The proposed technique would require no steam and also has the advantage of producing a regeneration gas rich in sulfur dioxide. In a commercial operation, recirculating regeneration gas would be supplemented with air as required to supply the necessary oxygen. A bleed stream from regeneration (concentrated SO{sub 2} gas in nitrogen) would constitute feed to sulfur recovery.

  14. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  15. Exhaust gas recirculation system for an internal combustion engine

    SciTech Connect (OSTI)

    Wu, Ko-Jen

    2013-05-21

    An exhaust gas recirculation system for an internal combustion engine comprises an exhaust driven turbocharger having a low pressure turbine outlet in fluid communication with an exhaust gas conduit. The turbocharger also includes a low pressure compressor intake and a high pressure compressor outlet in communication with an intake air conduit. An exhaust gas recirculation conduit fluidly communicates with the exhaust gas conduit to divert a portion of exhaust gas to a low pressure exhaust gas recirculation branch extending between the exhaust gas recirculation conduit and an engine intake system for delivery of exhaust gas thereto. A high pressure exhaust gas recirculation branch extends between the exhaust gas recirculation conduit and the compressor intake and delivers exhaust gas to the compressor for mixing with a compressed intake charge for delivery to the intake system.

  16. Power control system for a hot gas engine

    DOE Patents [OSTI]

    Berntell, John O.

    1986-01-01

    A power control system for a hot gas engine of the type in which the power output is controlled by varying the mean pressure of the working gas charge in the engine has according to the present invention been provided with two working gas reservoirs at substantially different pressure levels. At working gas pressures below the lower of said levels the high pressure gas reservoir is cut out from the control system, and at higher pressures the low pressure gas reservoir is cut out from the system, thereby enabling a single one-stage compressor to handle gas within a wide pressure range at a low compression ratio.

  17. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, Kenneth C.; Laug, Matthew T.; Lambert, John D. B.; Herzog, James P.

    1997-01-01

    A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

  18. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.; Lambert, J.B.; Herzog, J.P.

    1997-02-11

    A method and system are disclosed for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod. 12 figs.

  19. Trace desulfurization. [DOE patent application

    DOE Patents [OSTI]

    Chen, H.L.; Stevens, C.G.

    A method for reducing a trace concentration of sulfur-containing compounds in a gas stream from about one part in 10/sup 4/ to about one part in 10/sup 7/. The method includes the steps of irradiating the gas stream with an energy source which has a central emission frequency chosen to substantially match a wavelength of energy absorption of the sulfur-containing compounds and of subsequently contacting the gas stream with a reactive surface which includes a reactant selected from elemental metals and metal oxides so that metallic sulfur-containing compounds are formed. The reduction in concentration allows the gas stream to be processed in certain reactions having catalysts which would otherwise be poisoned by the sulfur-containing compounds.

  20. Exhaust gas system for internal combustion engines

    SciTech Connect (OSTI)

    Jans, K.; Ohlendorf, R.; Schuster, H.

    1981-09-08

    An exhaust gas system is disclosed for a multi-cylinder internal combustion engine, in which some cylinders are adapted to be effectively disconnected; the exhaust gas system includes in a common exhaust line, an O/sub 2/-probe and two series-connected catalysts while a separate exhaust gas line is coordinated to the cylinders adapted to be effectively disconnected; a control member operable as a function of load opens three separate branch connections from the separate exhaust line to the common exhaust line in such a manner that when all cylinders are firing, the branch connection terminating upstream of the O/sub 2/-probe is opened; the branch terminating in the common exhaust line between the O/sub 2/-probe and the first of the series-connected catalysts is opened when at least one of the cylinders is effectively disconnected and when the internal combustion engine is still relatively cold or warms up to a middle temperature; at temperatures exceeding the middle operating temperature, the branch connection terminating between the two catalysts is opened.

  1. All metal valve structure for gas systems

    DOE Patents [OSTI]

    Baker, Ray W.; Pawlak, Donald A.; Ramey, Alford J.

    1984-11-13

    A valve assembly with a resilient metal seat member is disclosed for providing a gas-tight seal in a gas handling system. The valve assembly also includes a valve element for sealing against the valve seat member; and an actuating means for operating the valve element. The valve seat member is a one-piece stainless steel ring having a central valve port and peripheral mounting flange, and an annular corrugation in between. A groove between the first and second ridges serves as a flexure zone during operation of the valve member and thus provides the seating pressure between the inner ridge or valve seat and the valve element. The outer annular ridge has a diameter less than said valve element to limit the seating motion of the valve element, preventing non-elastic deformation of the seat member.

  2. EIA - Natural Gas Pipeline System - Links to U.S. Natural Gas Pipeline

    U.S. Energy Information Administration (EIA) Indexed Site

    Systems Links About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Links to U.S. Natural Gas Pipeline Information - The links below will either direct the user to a narrative describing the system, a pipeline system map, a FERC prescribed "Informational Postings" page, or a FERC Tariff Sheet. Pipeline Name Type of System Regions of Operations Acadian Gas Pipeline System Intrastate Southwest Algonquin Gas Transmission Co

  3. Gas Main Sensor and Communications Network System

    SciTech Connect (OSTI)

    Hagen Schempf

    2006-05-31

    Automatika, Inc. was contracted by the Department of Energy (DOE) and with co-funding from the Northeast Gas Association (NGA), to develop an in-pipe natural gas prototype measurement and wireless communications system for assessing and monitoring distribution networks. This projected was completed in April 2006, and culminated in the installation of more than 2 dozen GasNet nodes in both low- and high-pressure cast-iron and steel mains owned by multiple utilities in the northeastern US. Utilities are currently logging data (off-line) and monitoring data in real time from single and multiple networked sensors over cellular networks and collecting data using wireless bluetooth PDA systems. The system was designed to be modular, using in-pipe sensor-wands capable of measuring, flow, pressure, temperature, water-content and vibration. Internal antennae allowed for the use of the pipe-internals as a waveguide for setting up a sensor network to collect data from multiple nodes simultaneously. Sensor nodes were designed to be installed with low- and no-blow techniques and tools. Using a multi-drop bus technique with a custom protocol, all electronics were designed to be buriable and allow for on-board data-collection (SD-card), wireless relaying and cellular network forwarding. Installation options afforded by the design included direct-burial and external polemounted variants. Power was provided by one or more batteries, direct AC-power (Class I Div.2) and solar-array. The utilities are currently in a data-collection phase and intend to use the collected (and processed) data to make capital improvement decisions, compare it to Stoner model predictions and evaluate the use of such a system for future expansion, technology-improvement and commercialization starting later in 2006.

  4. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V.; Cicero, Daniel C. (U.S. Department of Energy, National Energy Technology Laboratory, Morgantown); Stiegel, Gary J.; Gupta, Raghubir P. (U.S. Department of Energy, National Energy Technology Laboratory, Pittsburgh); Turk, Brian S. (Research Triangle Institute)

    2001-11-06

    A fixed-bed regenerable desulfurization sorbent, identified as RVS-land developed by researchers at the U.S. Department of Energy's National Energy Technology Laboratory, was awarded the R&D 100 award in 2000 and is currently offered as a commercial product by Sued-Chemie Inc. An extensive testing program for this sorbent was undertaken which included tests at a wide range of temperatures, pressures and gas compositions both simulated and generated in an actual gasifier for sulfidation and regeneration. This testing has demonstrated that during these desulfurization tests, the RVS-1 sorbent maintained an effluent H2S concentration of <5 ppmv at temperatures from 260 to 600 C (500-1100 F) and pressures of 203-2026 kPa(2 to 20 atm) with a feed containing 1.2 vol% H{sub 2}S. The types of syngas tested ranged from an oxygen-blown Texaco gasifier to biomass-generated syngas. The RVS-1 sorbent has high crush strength and attrition resistance, which, unlike past sorbent formulations, does not decrease with extended testing at actual at operating conditions. The sulfur capacity of the sorbent is roughly 17 to 20 wt.% and also remains constant during extended testing (>25 cycles). In addition to H{sub 2}S, the RVS-1 sorbent has also demonstrated the ability to remove dimethyl sulfide and carbonyl sulfide from syngas. During regeneration, the RVS-1 sorbent has been regenerated with dilute oxygen streams (1 to 7 vol% O{sub 2}) at temperatures as low as 370 C (700 F) and pressures of 304-709 kPa(3 to 7 atm). Although regeneration can be initiated at 370 C (700 F), regeneration temperatures in excess of 538 C (1000 F) were found to be optimal. The presence of steam, carbon dioxide or sulfur dioxide (up to 6 vol%) did not have any visible effect on regeneration or sorbent performance during either sulfidation or regeneration. A number of commercial tests involving RVS-1 have been either conducted or are planned in the near future. The RVS-1 sorbent has been tested by Epyx, Aspen

  5. EIA - Natural Gas Pipeline System - Midwest Region

    U.S. Energy Information Administration (EIA) Indexed Site

    Midwest Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Midwest Region Overview | Domestic Gas | Canadian Imports | Regional Pipeline Companies & Links Overview Twenty-six interstate and at least eight intrastate natural gas pipeline companies operate within the Midwest Region (Illinois, Indiana, Michigan, Minnesota, Ohio, and Wisconsin). The principal sources of natural gas supply for the

  6. Gas-phase propane fuel delivery system

    SciTech Connect (OSTI)

    Clements, J.

    1991-04-30

    This patent describes a gas-phase fuel delivery system for delivering a vapor phase fuel independent of exterior temperatures. It comprises:a storage tank for storing a volume of fuel; a regulator in fluid communication with the tank for receiving fuel from the tank and for outputting the fuel in a vapor phase; a pressure sensor in fluid communication with the tank for monitoring pressure within the tank, the pressure sensor being operative to generate a pump enable signal when the pressure within the tank is less than a predetermined threshold; a pump in fluid communication with the tank.

  7. Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, September 11, 1992--December 11, 1992

    SciTech Connect (OSTI)

    Sublette, K.L.

    1992-12-31

    With the continual increase in the utilization of high sulfur and high nitrogen containing fossil fuels, the release of airborne pollutants into the environment has become a critical problem. The fuel sulfur is converted to SO{sub 2} during combustion. Fuel nitrogen and a fraction of the nitrogen from the combustion air are converted to nitric oxide and nitrogen dioxide, NO{sub x}. For the past five years Combustion Engineering (now Asea Brown Boveri or ABB) and, since 1986, the University of Tulsa (TU) have been investigating the oxidation of H{sub 2}S by the facultatively anaerobic and autotrophic bacterium Thiobacillus denitrificans and have developed a process, concept for the microbial removal of H{sub 2}S from a gas stream the simultaneous removal of SO{sub 2} and NO by D. desulfuricans and T. denitrificans co-cultures and cultures-in-series was demonstrated. These systems could not be sustained due to NO inhibition of D. desulfuricans. However, a preliminary economic analysis has shown that microbial reduction of SO{sub 2} to H{sub 2}S with subsequent conversion to elemental sulfur by the Claus process is both technically and economically feasible if a less expensive carbon and/or energy source can be found. It has also been demonstrated that T. denitrificans can be grown anaerobically on NO(g) as a terminal electron acceptor with reduction to elemental nitrogen. Microbial reduction of NO{sub x} is a viable process concept for the disposal of concentrated streams of NO{sub x} as may be produced by certain regenerable processes for the removal of SO{sub 2} and NO{sub x} from flue gas.

  8. Hot gas path component cooling system

    DOE Patents [OSTI]

    Lacy, Benjamin Paul; Bunker, Ronald Scott; Itzel, Gary Michael

    2014-02-18

    A cooling system for a hot gas path component is disclosed. The cooling system may include a component layer and a cover layer. The component layer may include a first inner surface and a second outer surface. The second outer surface may define a plurality of channels. The component layer may further define a plurality of passages extending generally between the first inner surface and the second outer surface. Each of the plurality of channels may be fluidly connected to at least one of the plurality of passages. The cover layer may be situated adjacent the second outer surface of the component layer. The plurality of passages may be configured to flow a cooling medium to the plurality of channels and provide impingement cooling to the cover layer. The plurality of channels may be configured to flow cooling medium therethrough, cooling the cover layer.

  9. EIA - Natural Gas Pipeline System - Central Region

    U.S. Energy Information Administration (EIA) Indexed Site

    Central Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Central Region Overview | Domestic Gas | Exports | Regional Pipeline Companies & Links Overview Twenty-two interstate and at least thirteen intrastate natural gas pipeline companies (see Table below) operate in the Central Region (Colorado, Iowa, Kansas, Missouri, Montana, Nebraska, North Dakota, South Dakota, Utah, and Wyoming). Twelve

  10. Advanced Liquid Natural Gas Onboard Storage System

    SciTech Connect (OSTI)

    Greg Harper; Charles Powars

    2003-10-31

    Cummins Westport Incorporated (CWI) has designed and developed a liquefied natural gas (LNG) vehicle fuel system that includes a reciprocating pump with the cold end submerged in LNG contained in a vacuum-jacketed tank. This system was tested and analyzed under the U.S. Department of Energy (DOE) Advanced LNG Onboard Storage System (ALOSS) program. The pumped LNG fuel system developed by CWI and tested under the ALOSS program is a high-pressure system designed for application on Class 8 trucks powered by CWI's ISX G engine, which employs high-pressure direct injection (HPDI) technology. A general ALOSS program objective was to demonstrate the feasibility and advantages of a pumped LNG fuel system relative to on-vehicle fuel systems that require the LNG to be ''conditioned'' to saturation pressures that exceeds the engine fuel pressure requirements. These advantages include the capability to store more fuel mass in given-size vehicle and station tanks, and simpler lower-cost LNG refueling stations that do not require conditioning equipment. Pumped LNG vehicle fuel systems are an alternative to conditioned LNG systems for spark-ignition natural gas and port-injection dual-fuel engines (which typically require about 100 psi), and they are required for HPDI engines (which require over 3,000 psi). The ALOSS program demonstrated the feasibility of a pumped LNG vehicle fuel system and the advantages of this design relative to systems that require conditioning the LNG to a saturation pressure exceeding the engine fuel pressure requirement. LNG tanks mounted on test carts and the CWI engineering truck were repeatedly filled with LNG saturated at 20 to 30 psig. More fuel mass was stored in the vehicle tanks as well as the station tank, and no conditioning equipment was required at the fueling station. The ALOSS program also demonstrated the general viability and specific performance of the CWI pumped LNG fuel system design. The system tested as part of this program is

  11. System for controlling the flow of gas into and out of a gas laser

    DOE Patents [OSTI]

    Alger, Terry; Uhlich, Dennis M.; Benett, William J.; Ault, Earl R.

    1994-01-01

    A modularized system for controlling the gas pressure within a copper vapor or like laser is described herein. This system includes a gas input assembly which serves to direct gas into the laser in a controlled manner in response to the pressure therein for maintaining the laser pressure at a particular value, for example 40 torr. The system also includes a gas output assembly including a vacuum pump and a capillary tube arrangement which operates within both a viscous flow region and a molecular flow region for drawing gas out of the laser in a controlled manner.

  12. Exhaust gas recirculation system with an auxiliary valve

    SciTech Connect (OSTI)

    Tanaka, M.

    1980-09-30

    An exhaust gas recirculation system for an internal combustion engine is described that has an exhaust gas recirculation flow control valve provided at a middle position of the exhaust gas recirculation passage, the control valve being operated depending upon comparison between target and actual values of a control parameter with regard to the amount of exhaust gas recirculation. An auxiliary valve is provided in the exhaust gas recirculation passage in series with the exhaust gas recirculation flow control valve so as to control the crosssectional area of the exhaust gas recirculation passage in accordance with the opening amount of the throttle valve provided in the intake passage of the engine.

  13. Energy Department Expands Gas Gouging Reporting System to Include...

    Energy Savers [EERE]

    Expands Gas Gouging Reporting System to Include 1-800 Number: 1-800-244-3301 Energy Department Expands Gas ... of reformulated gasoline in storage and is already helping to ...

  14. EIA - Natural Gas Pipeline Network - Network Configuration & System Design

    U.S. Energy Information Administration (EIA) Indexed Site

    Network Configuration & System Design About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Network Configuration and System Design Overview | Transmission/Storage | Design Criteria | Importance of Storage| Overall Pipeline System Configuration Overview A principal requirement of the natural gas transmission system is that it be capable of meeting the peak demand of its shippers who have contracts for firm service. To meet this

  15. EIA - Natural Gas Pipeline System - Southwest Region

    U.S. Energy Information Administration (EIA) Indexed Site

    Southwest Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Southwest Region Overview | Export Transportation | Intrastate | Connection to Gulf of Mexico | Regional Pipeline Companies & Links Overview Most of the major onshore interstate natural gas pipeline companies (see Table below) operating in the Southwest Region (Arkansas, Louisiana, New Mexico, Oklahoma, and Texas) are primarily

  16. EIA - Natural Gas Pipeline System - Western Region

    U.S. Energy Information Administration (EIA) Indexed Site

    Western Region About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Pipelines in the Western Region Overview | Transportation South | Transportation North | Regional Pipeline Companies & Links Overview Ten interstate and nine intrastate natural gas pipeline companies provide transportation services to and within the Western Region (Arizona, California, Idaho, Nevada, Oregon, and Washington), the fewest number serving

  17. Method for the desulfurization of hot product gases from coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas

    1988-01-01

    The gasification of sulfur-bearing coal produces a synthesis gas which contains a considerable concentration of sulfur compounds especially hydrogen sulfide that renders the synthesis gas environmentally unacceptable unless the concentration of the sulfur compounds is significantly reduced. To provide for such a reduction in the sulfur compounds a calcium compound is added to the gasifier with the coal to provide some sulfur absorption. The synthesis gas from the gasifier contains sulfur compounds and is passed through an external bed of a regenerable solid absorbent, preferably zinc ferrite, for essentially completed desulfurizing the hot synthesis gas. This absorbent is, in turn, periodically or continuously regenerated by passing a mixture of steam and air or oxygen through the bed for converting absorbed hydrogen sulfide to sulfur dioxide. The resulting tail gas containing sulfur dioxide and steam is injected into the gasifier where the sulfur dioxide is converted by the calcium compound into a stable form of sulfur such as calcium sulfate.

  18. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  19. Fuel Cell/Gas Turbine System Performance Studies

    Office of Scientific and Technical Information (OSTI)

    (NG-SOFCCC) novel power plant systems were earlier introduced as high efficient systems. ... This work is focused on novel power plant systems by combining gas turbines, solid oxide ...

  20. On-Board Hydrogen Gas Production System For Stirling Engines...

    Office of Scientific and Technical Information (OSTI)

    Patent: On-Board Hydrogen Gas Production System For Stirling Engines Citation Details ... OSTI Identifier: 879832 Report Number(s): US 6755021 US patent application 10246064 DOE ...

  1. Fuel Cell/Gas Turbine System Performance Studies

    Office of Scientific and Technical Information (OSTI)

    ... Table 6. Advantages of Fuel CellGas Turbine Technologies System has lower capital costs ... power generation. Additionally, the capital and life costs of the fuel cellgas ...

  2. System and method for cooling a combustion gas charge

    DOE Patents [OSTI]

    Massey, Mary Cecelia; Boberg, Thomas Earl

    2010-05-25

    The present invention relates to a system and method for cooling a combustion gas charge prior. The combustion gas charge may include compressed intake air, exhaust gas, or a mixture thereof. An evaporator is provided that may then receive a relatively high temperature combustion gas charge and discharge at a relatively lower temperature. The evaporator may be configured to operate with refrigeration cycle components and/or to receive a fluid below atmospheric pressure as the phase-change cooling medium.

  3. Gas stream cleaning system and method

    DOE Patents [OSTI]

    Kunchal, S. Kumar; Erck, Louis J.; Harris, Harry A.

    1979-04-13

    An oil mist and solid particle laden gas from an oil shale retorting operation is initially treated with a temperature controlled oil spray and then by a coalescer to reduce the quantity of oil mist and remove most of the solid particle content of the gas stream and then finally treated by an electrostatic precipitator to essentially remove the oil mist remaining in the gas.

  4. Natural Gas Annual Respondent Query System

    Gasoline and Diesel Fuel Update (EIA)

    (Volumes in Thousand Cubic Feet, Prices in Dollars per Thousand Cubic Feet) Form EIA-176 * User Guide * Definitions, Sources, & Notes Natural Gas Deliveries (2011 - 2014)...

  5. Expert system technology for natural gas resource development

    SciTech Connect (OSTI)

    Munro, R.G.

    1997-12-31

    Materials data are used in all aspects of the development of natural gas resources. Unconventional gas resources require special attention in their development and may benefit from heuristic assessments of the materials data, geological site conditions, and the knowledge base accumulated from previous unconventional site developments. Opportunities for using expert systems in the development of unconventional natural gas resources are discussed. A brief introduction to expert systems is provided in a context that emphasizes the practical nature of their service. The discussion then focuses on the development of unconventional gas reserves. Whenever possible, the likelihood of success in constructing useful expert systems for gas resource development is indicated by comparisons to existing expert systems that perform comparable functions in other industries. Significant opportunities are found for applications to site assessment, the interpretation of well log data, and the monitoring and optimization of gas processing in small-scale recovery operations.

  6. Two-tank working gas storage system for heat engine

    DOE Patents [OSTI]

    Hindes, Clyde J.

    1987-01-01

    A two-tank working gas supply and pump-down system is coupled to a hot gas engine, such as a Stirling engine. The system has a power control valve for admitting the working gas to the engine when increased power is needed, and for releasing the working gas from the engine when engine power is to be decreased. A compressor pumps the working gas that is released from the engine. Two storage vessels or tanks are provided, one for storing the working gas at a modest pressure (i.e., half maximum pressure), and another for storing the working gas at a higher pressure (i.e., about full engine pressure). Solenoid valves are associated with the gas line to each of the storage vessels, and are selectively actuated to couple the vessels one at a time to the compressor during pumpdown to fill the high-pressure vessel with working gas at high pressure and then to fill the low-pressure vessel with the gas at low pressure. When more power is needed, the solenoid valves first supply the low-pressure gas from the low-pressure vessel to the engine and then supply the high-pressure gas from the high-pressure vessel. The solenoid valves each act as a check-valve when unactuated, and as an open valve when actuated.

  7. Electrical swing adsorption gas storage and delivery system

    DOE Patents [OSTI]

    Judkins, R.R.; Burchell, T.D.

    1999-06-15

    Systems and methods for electrical swing natural gas adsorption are described. An apparatus includes a pressure vessel; an electrically conductive gas adsorptive material located within the pressure vessel; and an electric power supply electrically connected to said adsorptive material. The adsorptive material can be a carbon fiber composite molecular sieve (CFCMS). The systems and methods provide advantages in that both a high energy density and a high ratio of delivered to stored gas are provided. 5 figs.

  8. Electrical swing adsorption gas storage and delivery system

    DOE Patents [OSTI]

    Judkins, Roddie R.; Burchell, Timothy D.

    1999-01-01

    Systems and methods for electrical swing natural gas adsorption are described. An apparatus includes a pressure vessel; an electrically conductive gas adsorptive material located within the pressure vessel; and an electric power supply electrically connected to said adsorptive material. The adsorptive material can be a carbon fiber composite molecular sieve (CFCMS). The systems and methods provide advantages in that both a high energy density and a high ratio of delivered to stored gas are provided.

  9. Process and system for removing impurities from a gas

    DOE Patents [OSTI]

    Henningsen, Gunnar; Knowlton, Teddy Merrill; Findlay, John George; Schlather, Jerry Neal; Turk, Brian S

    2014-04-15

    A fluidized reactor system for removing impurities from a gas and an associated process are provided. The system includes a fluidized absorber for contacting a feed gas with a sorbent stream to reduce the impurity content of the feed gas; a fluidized solids regenerator for contacting an impurity loaded sorbent stream with a regeneration gas to reduce the impurity content of the sorbent stream; a first non-mechanical gas seal forming solids transfer device adapted to receive an impurity loaded sorbent stream from the absorber and transport the impurity loaded sorbent stream to the regenerator at a controllable flow rate in response to an aeration gas; and a second non-mechanical gas seal forming solids transfer device adapted to receive a sorbent stream of reduced impurity content from the regenerator and transfer the sorbent stream of reduced impurity content to the absorber without changing the flow rate of the sorbent stream.

  10. Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization...

    Office of Scientific and Technical Information (OSTI)

    in a Fixed-Bed Reactor Citation Details In-Document Search Title: Durable Zinc Oxide-Based Regenerable Sorbents for Desulfurization of Syngas in a Fixed-Bed Reactor You are ...

  11. Gas characterization system 241-AN-105 field acceptance test procedure

    SciTech Connect (OSTI)

    Schneider, T.C.

    1996-03-01

    This document details the field Acceptance Testing of a gas characterization system being installed on waste tank 241-AN-105. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  12. Gas characterization system 241-AW-101 field acceptance test procedure

    SciTech Connect (OSTI)

    Schneider, T.C.

    1996-03-01

    This document details the field Acceptance Testing of a gas characterization system being installed on waste tank 241-AW-101. The gas characterization systems will be used to monitor the vapor spaces of waste tanks known to contain measurable concentrations of flammable gases.

  13. Fuel Cell System Challenges Utilizing Natural Gas and Methanol

    Broader source: Energy.gov (indexed) [DOE]

    Smarter Solutions for a Clean Energy Future Fuel Cell System Challenges Utilizing Natural Gas ... fuel processing hardware and system integration March 19, 2014 2 NASDAQ:BLDP TSX:BLD ...

  14. A gas-loading system for LANL two-stage gas guns

    SciTech Connect (OSTI)

    Gibson, Lloyd Lee; Bartram, Brian Douglas; Dattelbaum, Dana Mcgraw; Lang, John Michael; Morris, John Scott

    2015-09-01

    A novel gas loading system was designed for the specific application of remotely loading high purity gases into targets for gas-gun driven plate impact experiments. The high purity gases are loaded into well-defined target configurations to obtain Hugoniot states in the gas phase at greater than ambient pressures.The small volume of the gas samples is challenging, as slight changing in the ambient temperature result in measurable pressure changes. Therefore, the ability to load a gas gun target and continually monitor the sample pressure prior to firing provides the most stable and reliable target fielding approach. We present the design and evaluation of a gas loading system built for the LANL 50 mm bore two-stage light gas gun. Targets for the gun are made of 6061 Al or OFHC Cu, and assembled to form a gas containment cell with a volume of approximately 1.38 cc. The compatibility of materials was a major consideration in the design of the system, particularly for its use with corrosive gases. Piping and valves are stainless steel with wetted seals made from Kalrez® and Teflon®. Preliminary testing was completed to ensure proper flow rate and that the proper safety controls were in place. The system has been used to successfully load Ar, Kr, Xe, and anhydrous ammonia with purities of up to 99.999 percent. The design of the system and example data from the plate impact experiments will be shown.

  15. EIA - Natural Gas Pipeline System - Southeast Region

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Island and a new 875 MW natural gas fired power plant located in southeastern South Carolina. ... also from the developing coal-bed methane production sources in the State as well. ...

  16. Systems for delivering liquified gas to an engine

    DOE Patents [OSTI]

    Bingham, Dennis N.; Wilding, Bruce M.; O'Brien, James E.; Siahpush, Ali S.; Brown, Kevin B.

    2006-05-16

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  17. Systems and method for delivering liquified gas to an engine

    DOE Patents [OSTI]

    Bingham, Dennis N.; Wilding, Bruce M.; O'Brien, James E.; Siahpush, Ali S.; Brown, Kevin B.

    2002-01-01

    A liquified gas delivery system for a motorized platform includes a holding tank configured to receive liquified gas. A first conduit extends from a vapor holding portion of the tank to a valve device. A second conduit extends from a liquid holding portion of the tank to the valve device. Fluid coupled to the valve device is a vaporizer which is in communication with an engine. The valve device selectively withdraws either liquified gas or liquified gas vapor from the tank depending on the pressure within the vapor holding portion of the tank. Various configurations of the delivery system can be utilized for pressurizing the tank during operation.

  18. Spark gap switch system with condensable dielectric gas

    DOE Patents [OSTI]

    Thayer, III, William J.

    1991-01-01

    A spark gap switch system is disclosed which is capable of operating at a high pulse rate comprising an insulated switch housing having a purging gas entrance port and a gas exit port, a pair of spaced apart electrodes each having one end thereof within the housing and defining a spark gap therebetween, an easily condensable and preferably low molecular weight insulating gas flowing through the switch housing from the housing, a heat exchanger/condenser for condensing the insulating gas after it exits from the housing, a pump for recirculating the condensed insulating gas as a liquid back to the housing, and a heater exchanger/evaporator to vaporize at least a portion of the condensed insulating gas back into a vapor prior to flowing the insulating gas back into the housing.

  19. Enhanced durability and reactivity for zinc ferrite desulfurization sorbent. Quarterly technical progress report 4, July--September 1987

    SciTech Connect (OSTI)

    Jha, M.C.; Berggren, M.H.

    1987-10-27

    AMAX Research & Development Center (AMAX R&D) has been investigating methods for improving the reactivity and durability of the zinc ferrite desulfurization sorbent. Zinc ferrite sorbents are intended for use in desulfurization of hog coal gas in integrated gasification combined cycle (IGCC) or molten carbonate fuel cell (MCFC) applications. The reactivity of the sorbent may be defined as its sulfur sorption capacity at the breakthrough point in a bench-scale fixed-bed reactor. The durability may be defined as the ability of the sorbent to maintain its reactivity and other important physical characteristics such as size, strength, and specific surface area during 10 cycles of sulfidation and regeneration. Two base case sorbents, spherical pellets and cylindrical extrudes used in related METC sponsored projects, are being used to provide a basis for the comparison of physical characteristics and chemical reactivity.

  20. Natural Gas Pipeline and System Expansions

    Reports and Publications (EIA)

    1997-01-01

    This special report examines recent expansions to the North American natural gas pipeline network and the nature and type of proposed pipeline projects announced or approved for construction during the next several years in the United States. It includes those projects in Canada and Mexico that tie in with U.S. markets or projects.

  1. Development of a gas systems analysis model (GSAM)

    SciTech Connect (OSTI)

    Godec, M.L.

    1995-04-01

    The objectives of developing a Gas Systems Analysis Model (GSAM) are to create a comprehensive, non-proprietary, PC based model of domestic gas industry activity. The system is capable of assessing the impacts of various changes in the natural gas system within North America. The individual and collective impacts due to changes in technology and economic conditions are explicitly modeled in GSAM. Major gas resources are all modeled, including conventional, tight, Devonian Shale, coalbed methane, and low-quality gas sources. The modeling system asseses all key components of the gas industry, including available resources, exploration, drilling, completion, production, and processing practices, both for now and in the future. The model similarly assesses the distribution, storage, and utilization of natural gas in a dynamic market-based analytical structure. GSAM is designed to provide METC managers with a tool to project the impacts of future research, development, and demonstration (RD&D) benefits in order to determine priorities in a rapidly changing, market-driven gas industry.

  2. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, P.W.; Bannister, R.L.

    1995-07-11

    A gas turbine system is described in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas. 4 figs.

  3. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, Paul W.; Bannister, Ronald L.

    1995-01-01

    A gas turbine system in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas.

  4. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, T.; Gross, K.C.; Wegerich, S.

    1998-01-06

    A method and system are disclosed for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established. 6 figs.

  5. Method for nonlinear optimization for gas tagging and other systems

    DOE Patents [OSTI]

    Chen, Ting; Gross, Kenny C.; Wegerich, Stephan

    1998-01-01

    A method and system for providing nuclear fuel rods with a configuration of isotopic gas tags. The method includes selecting a true location of a first gas tag node, selecting initial locations for the remaining n-1 nodes using target gas tag compositions, generating a set of random gene pools with L nodes, applying a Hopfield network for computing on energy, or cost, for each of the L gene pools and using selected constraints to establish minimum energy states to identify optimal gas tag nodes with each energy compared to a convergence threshold and then upon identifying the gas tag node continuing this procedure until establishing the next gas tag node until all remaining n nodes have been established.

  6. Detection system for a gas chromatograph

    DOE Patents [OSTI]

    Hayes, John M.; Small, Gerald J.

    1984-01-01

    A method and apparatus are described for the quantitative analysis of vaporizable compounds, and in particular of polycyclic aromatic hydrocarbons which may be induced to fluoresce. The sample to be analyzed is injected into a gas chromatography column and is eluted through a narrow orifice into a vacuum chamber. The free expansion of the eluted sample into the vacuum chamber creates a supersonic molecular beam in which the sample molecules are cooled to the extent that the excited vibrational and rotational levels are substantially depopulated. The cooled molecules, when induced to fluoresce by laser excitation, give greatly simplified spectra suitable for analytical purposes. The laser induced fluorimetry provides great selectivity, and the gas chromatograph provides quantitative transfer of the sample to the molecular beam.

  7. Tips: Natural Gas and Oil Heating Systems | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    more about energy-efficient furnaces and boilers. Addthis Related Articles Tips: Natural Gas and Oil Heating Systems Energy Saver Guide: Tips on Saving Money and Energy at Home...

  8. Gas characterization system operation, maintenance, and calibration plan

    SciTech Connect (OSTI)

    Tate, D.D.

    1996-03-04

    This document details the responsibilities and requirements for operation, maintenance, and calibration of the Gas Characterization Systems (GCS) analytical instrumentation. It further, defines the division of responsibility between the Characterization Monitoring Development organization and Tank Farms Operations.

  9. World Energy Projection System Plus Model Documentation: Natural Gas Model

    Reports and Publications (EIA)

    2011-01-01

    This report documents the objectives, analytical approach and development of the World Energy Projection System Plus (WEPS ) Natural Gas Model. It also catalogues and describes critical assumptions, computational methodology, parameter estimation techniques, and model source code.

  10. Virtual Pipeline System Testbed to Optimize the U.S. Natural Gas Transmission Pipeline System

    SciTech Connect (OSTI)

    Kirby S. Chapman; Prakash Krishniswami; Virg Wallentine; Mohammed Abbaspour; Revathi Ranganathan; Ravi Addanki; Jeet Sengupta; Liubo Chen

    2005-06-01

    The goal of this project is to develop a Virtual Pipeline System Testbed (VPST) for natural gas transmission. This study uses a fully implicit finite difference method to analyze transient, nonisothermal compressible gas flow through a gas pipeline system. The inertia term of the momentum equation is included in the analysis. The testbed simulate compressor stations, the pipe that connects these compressor stations, the supply sources, and the end-user demand markets. The compressor station is described by identifying the make, model, and number of engines, gas turbines, and compressors. System operators and engineers can analyze the impact of system changes on the dynamic deliverability of gas and on the environment.

  11. Offshore LNG (liquefied natural gas) production and storage systems

    SciTech Connect (OSTI)

    Barden, J.K.

    1982-01-01

    A barge, outfitted with gas liquefaction processing equipment and liquefied natural gas (LNG) storage tanks, is suggested as a possible way to exploit remote offshore gas production. A similar study with a barge-mounted methanol plant was conducted several years ago, also using remote offshore feed gas. This barge-mounted, LNG system is bow-moored to a single point mooring through which feed gas is piped via seafloor pipeline from a nearby gas production facility. The barge is arranged with personnel accommodation forward, LNG storage midships, and gas liquefaction processing equipment aft. A flare boom is cantilevered off the barge's stern. The basis of design stipulates feed gas properties, area environmental data, gas liquefaction process, LNG storage tank type plus other parameters desirable in a floating process plant. The latter were concerned with safety, low maintenance characteristics, and the fact that the process barge also would serve as an offshore port where LNG export tankers would moor periodically. A brief summary of results for a barge-mounted methanol plant from an earlier study is followed then by a comparison of LNG and methanol alternatives.

  12. Apparatus and method for the desulfurization of petroleum by bacteria

    DOE Patents [OSTI]

    Lizama, H.M.; Scott, T.C.; Scott, C.D.

    1995-10-17

    A method is described for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the ``Sulfate Reducing Bacteria``. These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing. 5 figs.

  13. Apparatus and method for the desulfurization of petroleum by bacteria

    DOE Patents [OSTI]

    Lizama, Hector M.; Scott, Timothy C.; Scott, Charles D.

    1995-01-01

    A method for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the "Sulfate Reducing Bacteria." These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing.

  14. Management of dry flue gas desulfurization by-products in underground mines. The development and testing of collapsible intermodal containers for the handling and transport of coal combustion residues

    SciTech Connect (OSTI)

    Carpenter, J.L.; Thomasson, E.M.

    1995-07-01

    SEEC, Incorporated, is developing a collapsible intermodal container (CIC{trademark}) designed for containment and transport of fly ash and other dry-flowable bulk commodities. The CIC is specially configured to ride in open top rail cars, but as an intermodal container, it also rides in barges and on flat bed trailers. This allows SEEC to use unit coal train back haul capacity to transport fly ash to markets at and near coal mines. SEEC`s goals for this project were to design a CIC for handling and transporting dry fly ash, and then demonstrate the CIC technology. During this project, SEEC has performed extensive initial design work, leading to the manufacture of three prototype CICs for demonstration. Preliminary tests to examine safety issues included finite element analyses and an overload test in which the CIC was lifted while carrying weight in excess of its rated capacity. In both cases, the CIC met all safety requirements. With the above information satisfying possible safety concerns in hand, SEEC worked with SIU and other cooperators to plan and carry out field demonstration and testing of three CICs. This demonstration/testing including filling the CICs with fly ash, transporting them in a coal hopper car, handling with standard intermodal equipment, and emptying by inverting (two CICs) and by vacuuming (one CIC). Results were very positive. Filling with fly ash, transporting, and intermodal handling went very well, as did emptying by vacuum. Emptying by inverting was less successful, but most of the problems were predicted ahead of time, and were mostly due to lack of fly ash fluidizing equipment as much as anything. Throughout the testing, valuable information was gathered that will greatly accelerate refinement of both the CIC and the system of CIC handling.

  15. PRESSURIZED SOLID OXIDE FUEL CELL/GAS TURBINE POWER SYSTEM

    SciTech Connect (OSTI)

    W.L. Lundberg; G.A. Israelson; R.R. Moritz; S.E. Veyo; R.A. Holmes; P.R. Zafred; J.E. King; R.E. Kothmann

    2000-02-01

    Power systems based on the simplest direct integration of a pressurized solid oxide fuel cell (SOFC) generator and a gas turbine (GT) are capable of converting natural gas fuel energy to electric power with efficiencies of approximately 60% (net AC/LHV), and more complex SOFC and gas turbine arrangements can be devised for achieving even higher efficiencies. The results of a project are discussed that focused on the development of a conceptual design for a pressurized SOFC/GT power system that was intended to generate 20 MWe with at least 70% efficiency. The power system operates baseloaded in a distributed-generation application. To achieve high efficiency, the system integrates an intercooled, recuperated, reheated gas turbine with two SOFC generator stages--one operating at high pressure, and generating power, as well as providing all heat needed by the high-pressure turbine, while the second SOFC generator operates at a lower pressure, generates power, and provides all heat for the low-pressure reheat turbine. The system cycle is described, major system components are sized, the system installed-cost is estimated, and the physical arrangement of system components is discussed. Estimates of system power output, efficiency, and emissions at the design point are also presented, and the system cost of electricity estimate is developed.

  16. BASIN-CENTERED GAS SYSTEMS OF THE U.S.

    SciTech Connect (OSTI)

    Marin A. Popov; Vito F. Nuccio; Thaddeus S. Dyman; Timothy A. Gognat; Ronald C. Johnson; James W. Schmoker; Michael S. Wilson; Charles Bartberger

    2000-11-01

    The USGS is re-evaluating the resource potential of basin-centered gas accumulations in the U.S. because of changing perceptions of the geology of these accumulations, and the availability of new data since the USGS 1995 National Assessment of United States oil and gas resources (Gautier et al., 1996). To attain these objectives, this project used knowledge of basin-centered gas systems and procedures such as stratigraphic analysis, organic geochemistry, modeling of basin thermal dynamics, reservoir characterization, and pressure analysis. This project proceeded in two phases which had the following objectives: Phase I (4/1998 through 5/1999): Identify and describe the geologic and geographic distribution of potential basin-centered gas systems, and Phase II (6/1999 through 11/2000): For selected systems, estimate the location of those basin-centered gas resources that are likely to be produced over the next 30 years. In Phase I, we characterize thirty-three (33) potential basin-centered gas systems (or accumulations) based on information published in the literature or acquired from internal computerized well and reservoir data files. These newly defined potential accumulations vary from low to high risk and may or may not survive the rigorous geologic scrutiny leading towards full assessment by the USGS. For logistical reasons, not all basins received the level of detail desired or required.

  17. On-Board Hydrogen Gas Production System For Stirling Engines

    DOE Patents [OSTI]

    Johansson, Lennart N.

    2004-06-29

    A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed. A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated Stirling engine. The hydrogen gas may be generated by various techniques including electrolysis and stored by various means including the use of a metal hydride absorbing material. By controlling the temperature of the absorbing material, the stored hydrogen gas may be provided to the Stirling engine as needed.

  18. Plug-to-plug gas transfer system

    DOE Patents [OSTI]

    Poindexter, Allan M. (Pleasant Hills, PA)

    1978-01-01

    A system for conducting a fluid from one component to another component of a nuclear reactor wherein at least one such component is a rotatable closure head plug capable of movement relative to the other component. The conducting system utilizes the annulus located between the components as a connecting passageway for the fluid.

  19. Exhaust gas purification system for lean burn engine

    SciTech Connect (OSTI)

    Haines, Leland Milburn

    2002-02-19

    An exhaust gas purification system for a lean burn engine includes a thermal mass unit and a NO.sub.x conversion catalyst unit downstream of the thermal mass unit. The NO.sub.x conversion catalyst unit includes at least one catalyst section. Each catalyst section includes a catalytic layer for converting NO.sub.x coupled to a heat exchanger. The heat exchanger portion of the catalyst section acts to maintain the catalytic layer substantially at a desired temperature and cools the exhaust gas flowing from the catalytic layer into the next catalytic section in the series. In a further aspect of the invention, the exhaust gas purification system includes a dual length exhaust pipe upstream of the NO.sub.x conversion catalyst unit. The dual length exhaust pipe includes a second heat exchanger which functions to maintain the temperature of the exhaust gas flowing into the thermal mass downstream near a desired average temperature.

  20. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W.

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  1. Steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian David; Barb, Kevin Joseph; Li, Ming Cheng; Hyde, Susan Marie; Mashey, Thomas Charles; Wesorick, Ronald Richard; Glynn, Christopher Charles; Hemsworth, Martin C.

    2002-01-01

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows.

  2. Method of gas purification and system therefor

    DOE Patents [OSTI]

    Szwarc, R.

    1983-12-29

    A method and device are disclosed for conducting gettering. The gettering is conducted with one of an LiB, LiSi or LiAl system. Preferably the LiB system is of the formula Li/sub x/B/sub 1-x/ wherein 0 < x < 1 with gettering conducted at room or slightly elevated temperature of about 100 to 200/sup 0/C.

  3. Compressive stress system for a gas turbine engine

    SciTech Connect (OSTI)

    Hogberg, Nicholas Alvin

    2015-03-24

    The present application provides a compressive stress system for a gas turbine engine. The compressive stress system may include a first bucket attached to a rotor, a second bucket attached to the rotor, the first and the second buckets defining a shank pocket therebetween, and a compressive stress spring positioned within the shank pocket.

  4. Water-saving liquid-gas conditioning system (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Patent: Water-saving liquid-gas conditioning system Citation Details In-Document Search Title: Water-saving liquid-gas conditioning system A method for treating a process gas with ...

  5. Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook (Technical...

    Office of Scientific and Technical Information (OSTI)

    Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook Citation Details In-Document Search Title: Aerosol Observing System Greenhouse Gas (AOS GhG) Handbook The Greenhouse Gas ...

  6. Flexible fuel cell gas manifold system

    DOE Patents [OSTI]

    Cramer, Michael; Shah, Jagdish; Hayes, Richard P.; Kelley, Dana A.

    2005-05-03

    A fuel cell stack manifold system in which a flexible manifold body includes a pan having a central area, sidewall extending outward from the periphery of the central area, and at least one compound fold comprising a central area fold connecting adjacent portions of the central area and extending between opposite sides of the central area, and a sidewall fold connecting adjacent portions of the sidewall. The manifold system further includes a rail assembly for attachment to the manifold body and adapted to receive pins by which dielectric insulators are joined to the manifold assembly.

  7. Gas Centrifuge Enrichment Plant Safeguards System Modeling

    SciTech Connect (OSTI)

    Elayat, H A; O'Connell, W J; Boyer, B D

    2006-06-05

    The U.S. Department of Energy (DOE) is interested in developing tools and methods for potential U.S. use in designing and evaluating safeguards systems used in enrichment facilities. This research focuses on analyzing the effectiveness of the safeguards in protecting against the range of safeguards concerns for enrichment plants, including diversion of attractive material and unauthorized modes of use. We developed an Extend simulation model for a generic medium-sized centrifuge enrichment plant. We modeled the material flow in normal operation, plant operational upset modes, and selected diversion scenarios, for selected safeguards systems. Simulation modeling is used to analyze both authorized and unauthorized use of a plant and the flow of safeguards information. Simulation tracks the movement of materials and isotopes, identifies the signatures of unauthorized use, tracks the flow and compilation of safeguards data, and evaluates the effectiveness of the safeguards system in detecting misuse signatures. The simulation model developed could be of use to the International Atomic Energy Agency IAEA, enabling the IAEA to observe and draw conclusions that uranium enrichment facilities are being used only within authorized limits for peaceful uses of nuclear energy. It will evaluate improved approaches to nonproliferation concerns, facilitating deployment of enhanced and cost-effective safeguards systems for an important part of the nuclear power fuel cycle.

  8. Pulsed laser linescanner for a backscatter absorption gas imaging system

    DOE Patents [OSTI]

    Kulp, Thomas J.; Reichardt, Thomas A.; Schmitt, Randal L.; Bambha, Ray P.

    2004-02-10

    An active (laser-illuminated) imaging system is described that is suitable for use in backscatter absorption gas imaging (BAGI). A BAGI imager operates by imaging a scene as it is illuminated with radiation that is absorbed by the gas to be detected. Gases become "visible" in the image when they attenuate the illumination creating a shadow in the image. This disclosure describes a BAGI imager that operates in a linescanned manner using a high repetition rate pulsed laser as its illumination source. The format of this system allows differential imaging, in which the scene is illuminated with light at least 2 wavelengths--one or more absorbed by the gas and one or more not absorbed. The system is designed to accomplish imaging in a manner that is insensitive to motion of the camera, so that it can be held in the hand of an operator or operated from a moving vehicle.

  9. Solid fuel combustion system for gas turbine engine

    DOE Patents [OSTI]

    Wilkes, Colin; Mongia, Hukam C.

    1993-01-01

    A solid fuel, pressurized fluidized bed combustion system for a gas turbine engine includes a carbonizer outside of the engine for gasifying coal to a low Btu fuel gas in a first fraction of compressor discharge, a pressurized fluidized bed outside of the engine for combusting the char residue from the carbonizer in a second fraction of compressor discharge to produce low temperature vitiated air, and a fuel-rich, fuel-lean staged topping combustor inside the engine in a compressed air plenum thereof. Diversion of less than 100% of compressor discharge outside the engine minimizes the expense of fabricating and maintaining conduits for transferring high pressure and high temperature gas and incorporation of the topping combustor in the compressed air plenum of the engine minimizes the expense of modifying otherwise conventional gas turbine engines for solid fuel, pressurized fluidized bed combustion.

  10. Feed gas contaminant control in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis; Minford, Eric; Waldron, William Emil

    2009-07-07

    Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

  11. Airfoil seal system for gas turbine engine

    DOE Patents [OSTI]

    Diakunchak, Ihor S.

    2013-06-25

    A turbine airfoil seal system of a turbine engine having a seal base with a plurality of seal strips extending therefrom for sealing gaps between rotational airfoils and adjacent stationary components. The seal strips may overlap each other and may be generally aligned with each other. The seal strips may flex during operation to further reduce the gap between the rotational airfoils and adjacent stationary components.

  12. Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide

    DOE Patents [OSTI]

    Poston, James A.

    1997-01-01

    Mixed metal oxide pellets for removing hydrogen sulfide from fuel gas mixes derived from coal are stabilized for operation over repeated cycles of desulfurization and regeneration reactions by addition of a large promoter metal oxide such as lanthanum trioxide. The pellets, which may be principally made up of a mixed metal oxide such as zinc titanate, exhibit physical stability and lack of spalling or decrepitation over repeated cycles without loss of reactivity. The lanthanum oxide is mixed with pellet-forming components in an amount of 1 to 10 weight percent.

  13. Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide

    DOE Patents [OSTI]

    Poston, J.A.

    1997-12-02

    Mixed metal oxide pellets for removing hydrogen sulfide from fuel gas mixes derived from coal are stabilized for operation over repeated cycles of desulfurization and regeneration reactions by addition of a large promoter metal oxide such as lanthanum trioxide. The pellets, which may be principally made up of a mixed metal oxide such as zinc titanate, exhibit physical stability and lack of spalling or decrepitation over repeated cycles without loss of reactivity. The lanthanum oxide is mixed with pellet-forming components in an amount of 1 to 10 weight percent.

  14. Cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian David; Salamah, Samir Armando; Bylina, Noel Jacob

    2003-01-01

    A plurality of arcuate circumferentially spaced supply and return manifold segments are arranged on the rim of a rotor for respectively receiving and distributing cooling steam through exit ports for distribution to first and second-stage buckets and receiving spent cooling steam from the first and second-stage buckets through inlet ports for transmission to axially extending return passages. Each of the supply and return manifold segments has a retention system for precluding substantial axial, radial and circumferential displacement relative to the rotor. The segments also include guide vanes for minimizing pressure losses in the supply and return of the cooling steam. The segments lie substantially equal distances from the centerline of the rotor and crossover tubes extend through each of the segments for communicating steam between the axially adjacent buckets of the first and second stages, respectively.

  15. Exhaust gas recirculation control system for an internal combustion engine

    SciTech Connect (OSTI)

    Nishida, M.; Inoue, N.

    1988-03-01

    An exhaust gas recirculation control system for an internal combustion engine is described which comprises; an exhaust gas recirculation control valve for controlling a recirculation rate for exhaust gas to be mixed with intake air which is supplied to the internal combustion engine, an oxygen sensor disposed in an intake air passage downstream of the control valve to detect the concentration of oxygen in the intake air, a control means which compares the oxygen concentration detected by the oxygen sensor with a desired oxygen concentration previously determined depending on operational conditions of the engine and controls the degree of opening of the exhaust gas recirculation control valve so as to cancel the deviation between the detected oxygen concentration and the desired oxygen concentration, a detecting means for detecting the exhaust gas recirculation rate being zero to supply a signal to the control means on the basis of the detection, and a correcting means for correcting the corresponding relation between the output of the oxygen sensor and the detected oxygen concentration on the basis of the output of the oxygen sensor when the exhaust gas recirculation rate is zero.

  16. Forming liquid sprays in compressed-gas energy storage systems for effective heat exchange

    SciTech Connect (OSTI)

    McBride, Troy O.; Bell, Alexander; Bollinger, Benjamin R.

    2012-08-07

    In various embodiments, efficiency of energy storage and recovery systems compressing and expanding gas is improved via heat exchange between the gas and a heat-transfer fluid.

  17. Forming liquid sprays in compressed-gas energy storage systems for effective heat exchange

    DOE Patents [OSTI]

    McBride, Troy O; Bell, Alexander; Bollinger, Benjamin R; Shang, Andrew; Chmiel, David; Richter, Horst; Magari, Patrick; Cameron, Benjamin

    2013-07-02

    In various embodiments, efficiency of energy storage and recovery systems compressing and expanding gas is improved via heat exchange between the gas and a heat-transfer fluid.

  18. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W.

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  19. Albany Interim Landfill gas extraction and mobile power system: Using landfill gas to produce electricity. Final report

    SciTech Connect (OSTI)

    1997-06-01

    The Albany Interim Landfill Gas Extraction and Mobile Power System project served three research objectives: (1) determination of the general efficiency and radius of influence of horizontally placed landfill gas extraction conduits; (2) determination of cost and effectiveness of a hydrogen sulfide gas scrubber utilizing Enviro-Scrub{trademark} liquid reagent; and (3) construction and evaluation of a dual-fuel (landfill gas/diesel) 100 kW mobile power station. The horizontal gas extraction system was very successful; overall, gas recovery was high and the practical radius of influence of individual extractors was about 50 feet. The hydrogen sulfide scrubber was effective and its use appears feasible at typical hydrogen sulfide concentrations and gas flows. The dual-fuel mobile power station performed dependably and was able to deliver smooth power output under varying load and landfill gas fuel conditions.

  20. Testing in flue gas cleaning systems of waste incineration plants

    SciTech Connect (OSTI)

    Wallen, B.; Bergquist, A.; Nordstroem, J.

    1995-07-01

    Test racks containing creviced, welded coupons of stainless steels (SS), nickel-based alloys, and titanium were exposed in gas cleaning systems in municipal waste incineration plants. The environments in the cleaning systems were very corrosive. The best corrosion resistance was shown by the superaustenitic SS UNS S32654 and the nickel-based alloys UNS N10276 (C-276) and N06022 (C-22). Titanium performed poorly and was attacked by excessive uniform corrosion.

  1. Danish sour-gas pipeline has subsea safety system

    SciTech Connect (OSTI)

    Thygesen, J.E. )

    1990-06-04

    Dansk Olie og Gasproduktion A/S has gained valuable experience installing a subsea safety system on a 30-in., 215-km (134-mile) subsea sour-gas pipeline. The system is designed to reduce the risk of explosion or suffocation of personnel aboard a nearby platform. It consists of a subsea check valve and a fullbore ball valve. Experience from operation of the system has been gained in pigging through the check valve, scour around the installation, repairs, and function tests. This is the basis for recommendations for operators intending to install subsea safety systems of the same or similar type.

  2. Systems for delivering liquified natural gas to an engine

    DOE Patents [OSTI]

    Bingham, Dennis N.; Wilding, Bruce M.; O'Brien, James E.; Siahpush, Ali S.; Brown, Kevin B.

    2000-01-01

    A fuel delivery system includes a fuel tank configured to receive liquid natural gas. A first conduit extends from a vapor holding portion of the fuel tank to an economizer valve. A second conduit extends from a liquid holding portion of the fuel tank to the economizer valve. Fluid coupled to the economizer valve is a vaporizer which is heated by coolant from the engine and is positioned below the fuel tank. The economizer valve selectively withdraws either liquid natural gas or vaporized natural gas from the fuel tank depending on the pressure within the vapor holding portion of the fuel tank. A delivery conduit extends from the vaporizer to the engine. A return conduit having a check valve formed therein extends from the delivery conduit to the vapor holding portion of the fuel tank for pressurizing the fuel tank.

  3. Deliverability on the interstate natural gas pipeline system

    SciTech Connect (OSTI)

    1998-05-01

    Deliverability on the Interstate Natural Gas Pipeline System examines the capability of the national pipeline grid to transport natural gas to various US markets. The report quantifies the capacity levels and utilization rates of major interstate pipeline companies in 1996 and the changes since 1990, as well as changes in markets and end-use consumption patterns. It also discusses the effects of proposed capacity expansions on capacity levels. The report consists of five chapters, several appendices, and a glossary. Chapter 1 discusses some of the operational and regulatory features of the US interstate pipeline system and how they affect overall system design, system utilization, and capacity expansions. Chapter 2 looks at how the exploration, development, and production of natural gas within North America is linked to the national pipeline grid. Chapter 3 examines the capability of the interstate natural gas pipeline network to link production areas to market areas, on the basis of capacity and usage levels along 10 corridors. The chapter also examines capacity expansions that have occurred since 1990 along each corridor and the potential impact of proposed new capacity. Chapter 4 discusses the last step in the transportation chain, that is, deliverability to the ultimate end user. Flow patterns into and out of each market region are discussed, as well as the movement of natural gas between States in each region. Chapter 5 examines how shippers reserve interstate pipeline capacity in the current transportation marketplace and how pipeline companies are handling the secondary market for short-term unused capacity. Four appendices provide supporting data and additional detail on the methodology used to estimate capacity. 32 figs., 15 tabs.

  4. Integrated exhaust gas recirculation and charge cooling system

    SciTech Connect (OSTI)

    Wu, Ko-Jen

    2013-12-10

    An intake system for an internal combustion engine comprises an exhaust driven turbocharger configured to deliver compressed intake charge, comprising exhaust gas from the exhaust system and ambient air, through an intake charge conduit and to cylinders of the internal combustion engine. An intake charge cooler is in fluid communication with the intake charge conduit. A cooling system, independent of the cooling system for the internal combustion engine, is in fluid communication with the intake charge cooler through a cooling system conduit. A coolant pump delivers a low temperature cooling medium from the cooling system to and through the intake charge cooler for the transfer of heat from the compressed intake charge thereto. A low temperature cooler receives the heated cooling medium through the cooling system conduit for the transfer or heat therefrom.

  5. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Bannister, R.L.

    1999-04-27

    A system and method are disclosed for efficiently generating power using a gas turbine, a steam generating system and a reformer. The gas turbine receives a reformed fuel stream and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer. The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine. 2 figs.

  6. Thermal chemical recuperation method and system for use with gas turbine systems

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Bannister, Ronald L.

    1999-01-01

    A system and method for efficiently generating power using a gas turbine, a steam generating system (20, 22, 78) and a reformer. The gas turbine receives a reformed fuel stream (74) and an air stream and produces shaft power and exhaust. Some of the thermal energy from the turbine exhaust is received by the reformer (18). The turbine exhaust is then directed to the steam generator system that recovers thermal energy from it and also produces a steam flow from a water stream. The steam flow and a fuel stream are directed to the reformer that reforms the fuel stream and produces the reformed fuel stream used in the gas turbine.

  7. Process for demetallizing and desulfurizing heavy crude oil

    SciTech Connect (OSTI)

    Brown, R.E.; Hogan, R.J.; Combs, D.M.; Kukes, S.G.

    1989-12-05

    This patent describes a process for producing a synthetic crude oil of improved properties by desulfurizing, denitrogenating and demetallizing a heavy crude oil feed stock. The feed stock being a crude oil having an average boiling point at least as high as 500{degrees} F., an API gravity at 60{degrees} F. of less than 20, and containing at least about 1 weight percent sulfur.

  8. Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents

    SciTech Connect (OSTI)

    David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

    2006-09-30

    This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

  9. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, P.; George, R.A.

    1999-07-27

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

  10. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, Prabhakar; George, Raymond A.

    1999-01-01

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

  11. Water augmented indirectly-fired gas turbine systems and method

    DOE Patents [OSTI]

    Bechtel, Thomas F.; Parsons, Jr., Edward J.

    1992-01-01

    An indirectly-fired gas turbine system utilizing water augmentation for increasing the net efficiency and power output of the system is described. Water injected into the compressor discharge stream evaporatively cools the air to provide a higher driving temperature difference across a high temperature air heater which is used to indirectly heat the water-containing air to a turbine inlet temperature of greater than about 1,000.degree. C. By providing a lower air heater hot side outlet temperature, heat rejection in the air heater is reduced to increase the heat recovery in the air heater and thereby increase the overall cycle efficiency.

  12. New challenges to air/gas cleaning systems

    SciTech Connect (OSTI)

    Kovach, J.L.

    1997-08-01

    This paper discusses the need for changes in the design and manufacturing of air and gas cleaning systems to meet waste management and site remediation requirements. Current design and manufacturing practices are primarily directed toward evaluating operational problems with existing systems in nuclear reactor facilities. However, nuclear waste management needs have developed which are much broader in scope and have different processing conditions. Numerous examples of air cleaning needs for waste management activities are provided; the major differences from operating facility needs are the requirement for continuous effluent treatment under widely different processing conditions. Related regulatory issues are also discussed briefly. 1 ref.

  13. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems...

    Office of Scientific and Technical Information (OSTI)

    Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems Citation Details In-Document Search Title: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems You ...

  14. ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT (Technical...

    Office of Scientific and Technical Information (OSTI)

    ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT Citation Details In-Document Search Title: ART CCIM PHASE II-A OFF-GAS SYSTEM EVALUATION TEST REPORT AREVA Federal ...

  15. All-metal valve structure for gas systems

    DOE Patents [OSTI]

    Baker, R.W.; Pawlak, D.A.; Ramey, A.J.

    1982-06-10

    A valve assembly with a resilient metal seat member is disclosed for providing a gas-tight seal in a gas handling system. The valve assembly also includes a valve element for sealing against the valve seat member; and an actuating means for operating the valve element. The valve seat member is a one-piece stainless steel ring having a central valve port and peripheral mounting flange, and an annular corrugation in between. A groove between the first and second ridges serves as a flexure zone during operation of the valve member and thus provides the seating pressure between the inner ridge or valve seat and the valve element. The outer annular ridge has a diameter less than said valve element to limit the seating motion of the valve element, preventing non-elastic deformation of the seat member.

  16. Research Division flammable gas system calibration procedure and stability studies

    SciTech Connect (OSTI)

    Semenchenko, A.; Hojvat, C.

    1993-03-01

    The number of detectors which shifted from initial 50% LEL calibration by more than 5% over 90 days period is small enough in order to increase the time interval between calibrations at least to 120 days, but with any further increase in time between the calibrations probability of SC100 failure greatly increases. In order to keep the number of detectors with abnormal sensitivity low, we would recommend 120 days to be the maximum allowable interval for our present environmental conditions. Information is also presentd on the calibration of the SC100 Combustible Gas Sensor and the DC110 controller. The sensorand controlled form part of the flammable gas detecting systems installed at Fermilab.

  17. A High Efficiency PSOFC/ATS-Gas Turbine Power System

    SciTech Connect (OSTI)

    W.L. Lundberg; G.A. Israelson; M.D. Moeckel; S.E. Veyo; R.A. Holmes; P.R. Zafred; J.E. King; R.E. Kothmann

    2001-02-01

    A study is described in which the conceptual design of a hybrid power system integrating a pressurized Siemens Westinghouse solid oxide fuel cell generator and the Mercury{trademark} 50 gas turbine was developed. The Mercury{trademark} 50 was designed by Solar Turbines as part of the US. Department of Energy Advanced Turbine Systems program. The focus of the study was to develop the hybrid power system concept that principally would exhibit an attractively-low cost of electricity (COE). The inherently-high efficiency of the hybrid cycle contributes directly to achieving this objective, and by employing the efficient, power-intensive Mercury{trademark} 50, with its relatively-low installed cost, the higher-cost SOFC generator can be optimally sized such that the minimum-COE objective is achieved. The system cycle is described, major system components are specified, the system installed cost and COE are estimated, and the physical arrangement of the major system components is discussed. Estimates of system power output, efficiency, and emissions at the system design point are also presented. In addition, two bottoming cycle options are described, and estimates of their effects on overall-system performance, cost, and COE are provided.

  18. 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing

    Office of Energy Efficiency and Renewable Energy (EERE)

    SCR system provides direct ammonia gas dosing for optimal SCR performance with simplified and flexible exhaust layout.

  19. China develops natural gas industry

    SciTech Connect (OSTI)

    An, Z.

    1982-09-06

    As of 1981, China was producing some 474.4 billion CF (12.74 billion m/sup 3/)/yr of natural gas from over 60 gas fields, 40 of them in Sichuan Province. The Sichuan gas lies in fractures and solution cavities in limestone and dolomite formations that generally require stimulation. After desulfurization, the gas is used by the steel and chemical industries and for residential heating. Recent discoveries in other areas of China include the Guxinzhuang field in the Bohai-North China basin, where geological conditions favor large gas pools, and the Sebei fields in Qaidam basin, northwest China.

  20. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect (OSTI)

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated

  1. A Glove Box Enclosed Gas-Tungsten Arc Welding System

    SciTech Connect (OSTI)

    Reevr, E, M; Robino, C.V.

    1999-07-01

    This report describes an inert atmosphere enclosed gas-tungsten arc welding system which has been assembled in support of the MC2730, MC2730A and MC 3500 Radioisotope Thermoelectric Generator (RTG) Enhanced Surveillance Program. One goal of this program is to fabricate welds with microstructures and impurity levels which are similar to production heat source welds previously produced at Los Alamos National Laboratory and the Mound Facility. These welds will subsequently be used for high temperature creep testing as part of the overall component lifetime assessment. In order to maximize the utility of the welding system, means for local control of the arc atmosphere have been incorporated and a wide range of welding environments can easily be evaluated. The gas-tungsten arc welding system used in the assembly is computer controlled, includes two-axis and rotary motion, and can be operated in either continuous or pulsed modes. The system can therefore be used for detailed research studies of welding impurity effects, development of prototype weld schedules, or to mimic a significant range of production-like welding conditions. Fixturing for fabrication of high temperature creep test samples have been designed and constructed, and weld schedules for grip-tab and test welds have been developed. The microstructure of these welds have been evaluated and are consistent with those used during RTG production.

  2. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, J.; Koskinen, J.

    1995-08-22

    Hot gases from a pressurized fluidized bed reactor system are purified. Under super atmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a filtrate cake on the surface of the separator, and a reducing agent--such as an NO{sub x} reducing agent (like ammonia)--is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1--20 cm/s) during passage of the gas through the filtrate cake while at super atmospheric pressure. Separation takes place within a distinct pressure vessel, the interior of which is at a pressure of about 2--100 bar, and introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine). 8 figs.

  3. Exhaust gas recirculation system for a V-type engine

    SciTech Connect (OSTI)

    Choushi, M.; Ishimi, H.

    1986-10-07

    This patent describes an exhaust gas recirculation system for a V-type engine having a pair of cylinder banks arranged at an angle to each other on opposite sides of a crankshaft, each cylinder bank having cylinders therein and an intake passage being separately provided for each cylinder. The improvement described here comprises that the intake passages have respective proximate portions at which the intake passages to the cylinders in one cylinder bank and the intake passages to the cylinders in the other cylinder bank are aligned with each other as viewed in the direction of the crankshaft. The proximate portions are in the middle of the engine between the cylinder banks, and an exhaust recirculation passage for recirculating exhaust gas from an exhaust passage to the cylinders extending along the proximate portions in the direction of the crankshaft and communicating with each intake passage by way of a communicating aperture, an exhaust recirculation valve, for controlling the amount of exhaust gas, in the open end of the exhaust recirculation passage, and a branch exhaust passage, one end of which communicates with the exhaust recirculation passage by way of the exhaust recirculation valve and the other end of which communicates with an exhaust passage of the engine.

  4. Treating exhaust gas from a pressurized fluidized bed reaction system

    DOE Patents [OSTI]

    Isaksson, Juhani; Koskinen, Jari

    1995-01-01

    Hot gases from a pressurized fluidized bed reactor system are purified. Under superatmospheric pressure conditions hot exhaust gases are passed through a particle separator, forming a flitrate cake on the surface of the separator, and a reducing agent--such as an NO.sub.x reducing agent (like ammonia), is introduced into the exhaust gases just prior to or just after particle separation. The retention time of the introduced reducing agent is enhanced by providing a low gas velocity (e.g. about 1-20 cm/s) during passage of the gas through the filtrate cake while at superatmospheric pressure. Separation takes place within a distinct pressure vessel the interior of which is at a pressure of about 2-100 bar, and-introduction of reducing agent can take place at multiple locations (one associated with each filter element in the pressure vessel), or at one or more locations just prior to passage of clean gas out of the pressure vessel (typically passed to a turbine).

  5. Advanced Combustion Systems for Next Generation Gas Turbines

    SciTech Connect (OSTI)

    Joel Haynes; Jonathan Janssen; Craig Russell; Marcus Huffman

    2006-01-01

    Next generation turbine power plants will require high efficiency gas turbines with higher pressure ratios and turbine inlet temperatures than currently available. These increases in gas turbine cycle conditions will tend to increase NOx emissions. As the desire for higher efficiency drives pressure ratios and turbine inlet temperatures ever higher, gas turbines equipped with both lean premixed combustors and selective catalytic reduction after treatment eventually will be unable to meet the new emission goals of sub-3 ppm NOx. New gas turbine combustors are needed with lower emissions than the current state-of-the-art lean premixed combustors. In this program an advanced combustion system for the next generation of gas turbines is being developed with the goal of reducing combustor NOx emissions by 50% below the state-of-the-art. Dry Low NOx (DLN) technology is the current leader in NOx emission technology, guaranteeing 9 ppm NOx emissions for heavy duty F class gas turbines. This development program is directed at exploring advanced concepts which hold promise for meeting the low emissions targets. The trapped vortex combustor is an advanced concept in combustor design. It has been studied widely for aircraft engine applications because it has demonstrated the ability to maintain a stable flame over a wide range of fuel flow rates. Additionally, it has shown significantly lower NOx emission than a typical aircraft engine combustor and with low CO at the same time. The rapid CO burnout and low NOx production of this combustor made it a strong candidate for investigation. Incremental improvements to the DLN technology have not brought the dramatic improvements that are targeted in this program. A revolutionary combustor design is being explored because it captures many of the critical features needed to significantly reduce emissions. Experimental measurements of the combustor performance at atmospheric conditions were completed in the first phase of the program

  6. Robust packaging system for diesel/natural gas oxidation catalysts

    SciTech Connect (OSTI)

    Gulati, S.T.; Sherwood, D.L.; Corn, S.H.

    1996-09-01

    The 290,000 vehicle-mile durability requirement for diesel/natural gas oxidation catalysts calls for robust packaging systems which ensure a positive mounting pressure on the ceramic flow-through converter under all operating conditions. New data for substrate/washcoat interaction, intumescent mat performance in dry and wet states, and high temperature strength and oxidation resistance of stainless steels, and canning techniques insensitive to tolerance stack-up are reviewed which help optimize packaging durability. Factors contributing to robustness of converter components are identified and methods to quantify their impact on design optimization are described.

  7. Systems acceptance and operability testing for rotary mode core sampling in flammable gas tanks

    SciTech Connect (OSTI)

    Corbett, J.E., Westinghouse Hanford

    1996-07-29

    This document provides instructions for the system acceptance and operability testing of the rotary mode core sampling system, modified for use in flammable gas tanks.

  8. A Gas-Cooled Reactor Surface Power System

    SciTech Connect (OSTI)

    Harms, G.A.; Lenard, R.X.; Lipinski, R.J.; Wright, S.A.

    1998-11-09

    A human outpost on Mars requires plentiful power to assure survival of the astronauts. Anywhere from 50 to 500 kW of electric power (kWe) will be needed, depending on the number of astronauts, level of scientific activity, and life- cycle closure desired. This paper describes a 250-kWe power system based on a gas-cooled nuclear reactor with a recuperated closed Brayton cycle conversion system. The design draws upon the extensive data and engineering experience developed under the various high-temperature gas cooled reactor programs and under the SP-100 program. The reactor core is similar in power and size to the research reactors found on numerous university campuses. The fuel is uranium nitide clad in Nb 1 %Zr, which has been extensively tested under the SP-I 00 program The fiel rods are arranged in a hexagonal array within a BeO block. The BeO softens the spectrum, allowing better use of the fbel and stabilizing the geometty against deformation during impact or other loadings. The system has a negative temperature feedback coefficient so that the power level will automatically follow a variable load without the need for continuous adjustment of control elements. Waste heat is removed by an air-cooled heat exchanger using cold Martian air. The amount of radioactivity in the reactor at launch is very small (less than a Curie, and about equal to a truckload of uranium ore). The system will need to be engineered so that criticality cannot occur for any launch accident. This system is also adaptable for electric propulsion or life-support during transit to and from Mars.

  9. Igniter for gas discharge pipe with a flame detection system

    SciTech Connect (OSTI)

    Guerra, R.E.

    1990-03-06

    This patent describes a method of burning waste gas, using an igniter of the type having a nozzle, a main gas conduit extending to the nozzle, and an electrical spark means for creating a spark in the nozzle. It comprises: mounting the igniter to a waste gas discharge pipe with the nozzle directed across the opening of the gas discharge pipe; supplying a gaseous fuel to the main gas conduit; igniting the gaseous fuel with the electrical spark means, creating a flame for igniting the waste gas being discharged from the gas discharge pipe; providing the igniter with an auxiliary gas line extending to the vicinity of the nozzle; and supplying a second and lower volume source of waste gas to the auxiliary gas line for burning at the nozzle.

  10. Performance and economics of a spray-dryer FGD system used with high-sulfur coal

    SciTech Connect (OSTI)

    Livengood, C.D.; Farber, P.S.

    1986-04-01

    Flue-gas desulfurization (FGD) systems based on spray drying to offer advantages over wet lime/limestone systems in a number of areas: low energy consumption, low capital cost, high reliability, and production of a dry waste that is easily handled and disposed of. Uncertainties regarding the performance and economics of such systems for control of high-sulfur-coal emissions have slowed adoption of the technology in the Midwest and East. This paper summarizes 4 years, operating and research experience with that system and describes the current research program, which includes an indepth characterization of an industrial scale dry scrubber with 3.5% sulfur coal.

  11. Fuel Use and Greenhouse Gas Emissions from the Natural Gas System; Sankey Diagram Methodology

    Office of Energy Efficiency and Renewable Energy (EERE)

    As natural gas travels through infrastructure, from well-head to customer meter, small portions are routinely used as fuel, vented, flared, or inadvertently leaked to the atmosphere. This paper describes the analytical and methodological basis for three diagrams that illustrate the natural gas losses and greenhouse gas emissions that result from these processes. The paper examines these emissions in some detail, focusing in particular on the production, processing, transmission and storage, and distribution segments of natural gas infrastructure.

  12. Advanced Materials for Mercury 50 Gas Turbine Combustion System

    SciTech Connect (OSTI)

    Price, Jeffrey

    2008-09-30

    Solar Turbines Incorporated (Solar), under cooperative agreement number DE-FC26-0CH11049, has conducted development activities to improve the durability of the Mercury 50 combustion system to 30,000 hours life and reduced life cycle costs. This project is part of Advanced Materials in the Advanced Industrial Gas Turbines program in DOE's Office of Distributed Energy. The targeted development engine was the Mercury{trademark} 50 gas turbine, which was developed by Solar under the DOE Advanced Turbine Systems program (DOE contract number DE-FC21-95MC31173). As a generator set, the Mercury 50 is used for distributed power and combined heat and power generation and is designed to achieve 38.5% electrical efficiency, reduced cost of electricity, and single digit emissions. The original program goal was 20,000 hours life, however, this goal was increased to be consistent with Solar's standard 30,000 hour time before overhaul for production engines. Through changes to the combustor design to incorporate effusion cooling in the Generation 3 Mercury 50 engine, which resulted in a drop in the combustor wall temperature, the current standard thermal barrier coated liner was predicted to have 18,000 hours life. With the addition of the advanced materials technology being evaluated under this program, the combustor life is predicted to be over 30,000 hours. The ultimate goal of the program was to demonstrate a fully integrated Mercury 50 combustion system, modified with advanced materials technologies, at a host site for a minimum of 4,000 hours. Solar was the Prime Contractor on the program team, which includes participation of other gas turbine manufacturers, various advanced material and coating suppliers, nationally recognized test laboratories, and multiple industrial end-user field demonstration sites. The program focused on a dual path development route to define an optimum mix of technologies for the Mercury 50 and future gas turbine products. For liner and injector

  13. Power plant including an exhaust gas recirculation system for injecting recirculated exhaust gases in the fuel and compressed air of a gas turbine engine

    DOE Patents [OSTI]

    Anand, Ashok Kumar; Nagarjuna Reddy, Thirumala Reddy; Shaffer, Jason Brian; York, William David

    2014-05-13

    A power plant is provided and includes a gas turbine engine having a combustor in which compressed gas and fuel are mixed and combusted, first and second supply lines respectively coupled to the combustor and respectively configured to supply the compressed gas and the fuel to the combustor and an exhaust gas recirculation (EGR) system to re-circulate exhaust gas produced by the gas turbine engine toward the combustor. The EGR system is coupled to the first and second supply lines and configured to combine first and second portions of the re-circulated exhaust gas with the compressed gas and the fuel at the first and second supply lines, respectively.

  14. Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems...

    Office of Scientific and Technical Information (OSTI)

    Conference: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas Systems Citation Details In-Document Search Title: Avoiding Carbon Bed Hot Spots in Thermal Process Off-Gas ...

  15. A Path to Reduce Methane Emissions from Gas Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Path to Reduce Methane Emissions from Gas Systems A Path to Reduce Methane Emissions from Gas Systems July 29, 2014 - 3:33pm Addthis A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy Department. A researcher evaluates methane produced in a unique conservation process. Methane is both a potent greenhouse gas and valuable energy resource.| Photo courtesy of the Energy

  16. Operation of cover-gas system during SLSF tests. [LMFBR

    SciTech Connect (OSTI)

    Braid, T.H.; Harper, H.A.; Wilson, R.E.

    1982-01-01

    During two tests in the Sodium Loop Safety Facility (W1 and P4), high resolution gamma-ray spectroscopy was used to detect pin failure by observing radioactive fission product isotopes of Kr and Xe from exposed fuel. A continuous stream of argon cover gas from the in-pile loop was transferred to a shielded sample volume. Two germanium crystal spectrometers continuously recorded spectra of gamma rays in the energy range 80 keV to approx. 2.7 MeV. A very wide range of signal strength was accommodated without saturation by dilution of the sample, reduction of the sample chamber volume and insertion of detecter collimators. The cover gas system provided an unambiguous indication of fuel failure during a series of boiling tests in W1. In P4, spectra were recorded after a power transient that released molten fuel and from a mass of exposed fuel at a range of reactor power levels. Gamma rays were observed from isotopes of Kr and Xe with half-lives from 3.8 m to 5.2 d.

  17. Systems and methods for regulating pressure of a filled-in gas

    DOE Patents [OSTI]

    Stautner, Ernst Wolfgang; Michael, Joseph Darryl

    2016-05-03

    A system for regulating a pressure of a filled-in gas is presented. The system includes a reservoir that stores a reservoir gas adsorbed in a sorbent material at a storage temperature, a gas-filled tube containing the filled-in gas, a controller configured to determine a pressure change required in the filled-in gas based upon signals representative of a pressure of the filled-in gas inside the gas-filled tube and a required pressure threshold, determine an updated temperature of the sorbent material based upon the pressure change required in the filled-in gas, and regulate the pressure of the filled-in gas by controlling the reservoir to change the storage temperature of the sorbent material to reach the updated temperature of the sorbent material.

  18. Stack Characterization System for Inspection of Contaminated Off-Gas Stacks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Stack Characterization System for Inspection of Contaminated Off-Gas Stacks Stack Characterization System for Inspection of Contaminated Off-Gas Stacks The stack characterization system (SCS) is a tele-operated remote system that collects samples and data to characterize the quantitative and qualitative levels of contamination inside off-gas stacks protecting workers from the physical, radiological and chemical hazards of deteriorating contaminated stacks. Stack

  19. On-Board Hydrogen Gas Production System For Stirling Engines (Patent) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Patent: On-Board Hydrogen Gas Production System For Stirling Engines Citation Details In-Document Search Title: On-Board Hydrogen Gas Production System For Stirling Engines A hydrogen production system for use in connection with Stirling engines. The production system generates hydrogen working gas and periodically supplies it to the Stirling engine as its working fluid in instances where loss of such working fluid occurs through usage through operation of the associated

  20. Axially staged combustion system for a gas turbine engine

    DOE Patents [OSTI]

    Bland, Robert J.

    2009-12-15

    An axially staged combustion system is provided for a gas turbine engine comprising a main body structure having a plurality of first and second injectors. First structure provides fuel to at least one of the first injectors. The fuel provided to the one first injector is adapted to mix with air and ignite to produce a flame such that the flame associated with the one first injector defines a flame front having an average length when measured from a reference surface of the main body structure. Each of the second injectors comprising a section extending from the reference surface of the main body structure through the flame front and having a length greater than the average length of the flame front. Second structure provides fuel to at least one of the second injectors. The fuel passes through the one second injector and exits the one second injector at a location axially spaced from the flame front.

  1. Backscatter absorption gas imaging systems and light sources therefore

    DOE Patents [OSTI]

    Kulp, Thomas Jan; Kliner, Dahv A. V.; Sommers, Ricky; Goers, Uta-Barbara; Armstrong, Karla M.

    2006-12-19

    The location of gases that are not visible to the unaided human eye can be determined using tuned light sources that spectroscopically probe the gases and cameras that can provide images corresponding to the absorption of the gases. The present invention is a light source for a backscatter absorption gas imaging (BAGI) system, and a light source incorporating the light source, that can be used to remotely detect and produce images of "invisible" gases. The inventive light source has a light producing element, an optical amplifier, and an optical parametric oscillator to generate wavelength tunable light in the IR. By using a multi-mode light source and an amplifier that operates using 915 nm pump sources, the power consumption of the light source is reduced to a level that can be operated by batteries for long periods of time. In addition, the light source is tunable over the absorption bands of many hydrocarbons, making it useful for detecting hazardous gases.

  2. Deliverability on the Interstate Natural Gas Pipeline System

    Reports and Publications (EIA)

    1998-01-01

    Examines the capability of the national pipeline grid to transport natural gas to various U.S. markets.

  3. EIA - Natural Gas Pipeline Network - Region To Region System Capacity

    U.S. Energy Information Administration (EIA) Indexed Site

    Levels Interregional Capacity About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Interregional Natural Gas Transmission Pipeline Capacity, Close of 2008 (Million cubic feet per day) Map of Interregional Natural Gas Transmission Pipeline Capacity in 2008 The EIA has determined that the informational map displays here do not raise security concerns, based on the application of the Federal Geographic Data Committee's Guidelines for

  4. Removal of Mercury from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    2005-09-29

    A paper study was completed to survey literature, patents, and companies for mercury removal technologies applicable to gasification technologies. The objective was to determine if mercury emissions from gasification of coal are more or less difficult to manage than those from a combustion system. The purpose of the study was to define the extent of the mercury problem for gasification-based coal utilization and conversion systems. It is clear that in coal combustion systems, the speciation of mercury between elemental vapor and oxidized forms depends on a number of factors. The most important speciation factors are the concentration of chlorides in the coal, the temperatures in the ducting, and residence times. The collection of all the mercury was most dependent upon the extent of carbon in the fly ash, and the presence of a wet gas desulfurization system. In combustion, high chloride content plus long residence times at intermediate temperatures leads to oxidation of the mercury. The mercury is then captured in the wet gas desulfurization system and in the fly ash as HgCl{sub 2}. Without chloride, the mercury oxidizes much slower, but still may be trapped on thick bag house deposits. Addition of limestone to remove sulfur may trap additional mercury in the slag. In gasification where the mercury is expected to be elemental, activated carbon injection has been the most effective method of mercury removal. The carbon is best injected downstream where temperatures have moderated and an independent collector can be established. Concentrations of mercury sorbent need to be 10,000 to 20,000 the concentrations of the mercury. Pretreatment of the activated carbon may include acidification or promotion by sulfur.

  5. Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D Initiative |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Advanced Natural Gas Systems Manufacturing R&D Initiative Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D Initiative The following fact sheet outlines one of the Department of Energy's series of actions, partnerships, and stakeholder commitments to help modernize the nation¹s natural gas transmission and distribution systems and reduce methane emissions. DOE will launch a collaborative effort with industry to evaluate and scope high-impact

  6. [Advanced Gas Turbine Systems Research]. Technical Quarterly Progress Report

    SciTech Connect (OSTI)

    1998-09-30

    Major Accomplishments by Advanced Gas Turbine Systems Research (AGTSR) during this reporting period are highlighted below and amplified in later sections of this report: AGTSR distributed 50 proposals from the 98RFP to the IRB for review, evaluation and rank-ordering during the summer; AGTSR conducted a detailed program review at DOE-FETC on July 24; AGTSR organized the 1998 IRB proposal review meeting at SCIES on September 15-16; AGTSR consolidated all the IRB proposal scores and rank-orderings to facilitate the 98RFP proposal deliberations; AGTSR submitted meeting minutes and proposal short-list recommendation to the IRB and DOE for the 98RFP solicitation; AGTSR reviewed two gas turbine related proposals as part of the CU RFP State Project for renovating the central energy facility; AGTSR reviewed and cleared research papers with the IRB from the University of Pittsburgh, Wisconsin, and Minnesota; AGTSR assisted GTA in obtaining university stakeholder support of the ATS program from California, Pennsylvania, and Colorado; AGTSR assisted GTA in distributing alert notices on potential ATS budget cuts to over 150 AGTSR performing university members; AGTSR submitted proceedings booklet and organizational information pertaining to the OAI hybrid gas turbine workshop to DOE-FETC; For DOE-FETC, AGTSR updated the university consortium poster to include new members and research highlights; For DOE-FETC, the general AGTSR Fact Sheet was updated to include new awards, workshops, educational activity and select accomplishments from the research projects; For DOE-FETC, AGTSR prepared three fact sheets highlighting university research supported in combustion, aero-heat transfer, and materials; For DOE-FETC, AGTSR submitted pictures on materials research for inclusion in the ATS technology brochure; For DOE-FETC, AGTSR submitted a post-2000 roadmap showing potential technology paths AGTSR could pursue in the next decade; AGTSR distributed the ninth newsletter UPDATE to DOE, the

  7. Superconducting cable cooling system by helium gas and a mixture of gas and liquid helium

    DOE Patents [OSTI]

    Dean, John W.

    1977-01-01

    Thermally contacting, oppositely streaming cryogenic fluid streams in the same enclosure in a closed cycle that changes from a cool high pressure helium gas to a cooler reduced pressure helium fluid comprised of a mixture of gas and boiling liquid so as to be near the same temperature but at different pressures respectively in go and return legs that are in thermal contact with each other and in thermal contact with a longitudinally extending superconducting transmission line enclosed in the same cable enclosure that insulates the line from the ambient at a temperature T.sub.1. By first circulating the fluid in a go leg from a refrigerator at one end of the line as a high pressure helium gas near the normal boiling temperature of helium; then circulating the gas through an expander at the other end of the line where the gas becomes a mixture of reduced pressure gas and boiling liquid at its boiling temperature; then by circulating the mixture in a return leg that is separated from but in thermal contact with the gas in the go leg and in the same enclosure therewith; and finally returning the resulting low pressure gas to the refrigerator for compression into a high pressure gas at T.sub.2 is a closed cycle, where T.sub.1 >T.sub.2, the temperature distribution is such that the line temperature is nearly constant along its length from the refrigerator to the expander due to the boiling of the liquid in the mixture. A heat exchanger between the go and return lines removes the gas from the liquid in the return leg while cooling the go leg.

  8. Gas Fired Test System For Stirling Engines. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Gas Fired Test System For Stirling Engines. ... Security Administration (NNSA) Country of Publication: United States Language: English

  9. Gas species, their evolution and segregation through the ITER vacuum systems

    SciTech Connect (OSTI)

    Pearce, R.J.H.; Antipenkov, Alexander; Bersier, Jean-Louis; Boussier, Bastien; Baylor, Larry R; Gardner, Walter L; Meitner, Steven J

    2012-01-01

    This paper takes the ITER fueling requirements and current knowledge of gas balance and exhaust from operating tokamaks to predict all likely gas inputs into the ITER Vacuum systems. Areas where gas dynamics modeling is relevant to the ITER design are highlighted. The design and operation of the ITER vacuum system gives an element of segregation of different gas flows and species. This paper analyses the time dependent gas segregation in the vacuum system resulting from different temperature dependences of cryogenic sorption and condensation processes of different gas species. As a specific example, the optimal transfer of Ar-41 through the vacuum system is studied with respect to its decay and the resulting effects on the design of system components.

  10. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Miller, Christopher Francis (Macungie, PA)

    2008-09-16

    Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.

  11. Characterization of suspended flue gas particle systems with...

    Office of Scientific and Technical Information (OSTI)

    Subject: 01 COAL, LIGNITE, AND PEAT; CASCADE IMPACTORS; PERFORMANCE TESTING; FLUE GAS; PARTICLE SIZE; FLUIDIZED-BED COMBUSTION; AIR FILTERS; DISTRIBUTION; MEASURING INSTRUMENTS; ...

  12. Coal desulfurization in a rotary kiln combustor

    SciTech Connect (OSTI)

    Cobb, J.T. Jr.

    1992-09-11

    The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

  13. Enhanced durability for high-temperature desulfurization sorbents for moving-bed applications -- Option 3 program: Development and testing of additional zinc titanate sorbents. Final report, September 1992--May 1996

    SciTech Connect (OSTI)

    Ayala, R.E.; Chuck, T.L.

    1996-12-31

    GE is developing a moving-bed, high-temperature desulfurization system for the integrated gasification combined-cycle (IGCC) power cycle in which zinc-based regenerable sorbents are currently being used as desulfurization sorbents. Zinc titanate and other zinc-based oxides are being considered as sorbents for use in the Clean Coal Technology Demonstration Program at Tampa Electric Co.`s Polk Power Station. A key to success in the development of high-temperature desulfurization systems is the matching of sorbent properties for the selected process operating conditions, namely, sustainable desulfurization kinetics, high sulfur capacity, and mechanical durability over multiple cycles. Additionally, the sulfur species produced during regeneration of the sorbent must be in a form compatible with sulfur recovery systems, such as sulfuric acid or elemental sulfur processes. The objective of this contract is to identify and test sorbent fabrication methods and chemical compositions that enhance the long-term chemical reactivity and mechanical strength of zinc titanate and other novel sorbents for moving-bed, high-temperature desulfurization of coal-derived gases. A parametric study on the use of calcium sulfate additives to zinc titanate was conducted for zinc titanates having a 2:1 and 1.5:1 zinc-to-titanium molar ratio, and they showed a beneficial effect on crush strength of fresh 2:1 zinc titanate sorbents. In addition, a test procedure was developed to screen sorbent formulations based on resistance to spalling and pellet breakage induced by zinc sulfate formation in the presence of sulfur dioxide and excess oxygen conditions.

  14. Construction and start-up of a 250 kW natural gas fueled MCFC demonstration power plant

    SciTech Connect (OSTI)

    Figueroa, R.A.; Carter, J.; Rivera, R.; Otahal, J.

    1996-12-31

    San Diego Gas & Electric (SDG&E) is participating with M-C Power in the development and commercialization program of their internally manifolded heat exchanger (IMHEX{reg_sign}) carbonate fuel cell technology. Development of the IMHEX technology base on the UNOCAL test facility resulted in the demonstration of a 250 kW thermally integrated power plant located at the Naval Air Station at Miramar, California. The members of the commercialization team lead by M-C Power (MCP) include Bechtel Corporation, Stewart & Stevenson Services, Inc., and Ishikawajima-Harima Heavy Industries (IHI). MCP produced the fuel cell stack, Bechtel was responsible for the process engineering including the control system, Stewart & Stevenson was responsible for packaging the process equipment in a skid (pumps, desulfurizer, gas heater, turbo, heat exchanger and stem generator), IHI produced a compact flat plate catalytic reformer operating on natural gas, and SDG&E assumed responsibility for plant construction, start-up and operation of the plant.

  15. Superconducting cable cooling system by helium gas at two pressures

    DOE Patents [OSTI]

    Dean, John W.

    1977-01-01

    Thermally contacting, oppositely streaming, cryogenic fluid streams in the same enclosure in a closed cycle that changes the fluid from a cool high pressure helium gas to a cooler reduced pressure helium gas in an expander so as to be at different temperature ranges and pressures respectively in go and return legs that are in thermal contact with each other and in thermal contact with a longitudinally extending superconducting transmission line enclosed in the same cable enclosure that insulates the line from the ambient at a temperature T.sub.1. By first circulating the fluid from a refrigerator at one end of the line as a cool gas at a temperature range T.sub.2 to T.sub.3 in the go leg, then circulating the gas through an expander at the other end of the line where the gas becomes a cooler gas at a reduced pressure and at a reduced temperature T.sub.4 and finally by circulating the cooler gas back again to the refrigerator in a return leg at a temperature range T.sub.4 to T.sub.5, while in thermal contact with the gas in the go leg, and in the same enclosure therewith for compression into a higher pressure gas at T.sub.2 in a closed cycle, where T.sub.2 >T.sub.3 and T.sub.5 >T.sub.4, the fluid leaves the enclosure in the go leg as a gas at its coldest point in the go leg, and the temperature distribution is such that the line temperature decreases along its length from the refrigerator due to the cooling from the gas in the return leg.

  16. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Snow, N.J. Jr.

    1983-12-06

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a well-head; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; and separating LPG from gas vapors of the refrigerated natural gas. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for cooling the compressed gases therefrom; and a product separator downstream of the refrigeration unit for receiving cooled and compressed gases discharged from the refrigeration unit and separating LPG therein from gases remaining in vapor form.

  17. Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Applications - Volume I, January 2000 | Department of Energy Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications - Volume I, January 2000 Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications - Volume I, January 2000 In this January 2000 report, Arthur D. Little provides an assessment of the opportunities for micropower and fuel cell/gas turbine hybrid technologies in the industrial sector for

  18. Chapter 7: Advancing Systems and Technologies to Produce Cleaner Fuels | Natural Gas Delivery Infrastructure Technology Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infrastructure Offshore Safety and Spill Prevention Unconventional Oil and Gas ENERGY U.S. DEPARTMENT OF Quadrennial Technology Review 2015 1 Quadrennial Technology Review 2015 Natural Gas Delivery Infrastructure Chapter 7: Technology Assessments Introduction and Background The U.S. natural gas delivery system is an extensive network composed of over 315,000 miles of transmission pipeline and over 2.1 million miles of distribution mains. 1 In 2015, this system moved over 25 trillion cubic feet

  19. Cold box shuttle - a system for the recovery of offshore gas - applied to Sweden

    SciTech Connect (OSTI)

    Smith, D.; Eriksson, L.; Pehrsson, L.O.; Strom-Olsen, H.

    1982-01-01

    The recovery of offshore gas as LNG, by heat exchange on an LNG carrier with liquid nitrogen, was studied in the context of a North Sea gas source and a Swedish market. The technical suitability of each component of this cold-box shuttle system was examined and the capital and operating costs were estimated. It was concluded that the system is technically robust and flexible and that, for the case studied, gas could be landed at a competitive cost.

  20. Measurements of gas sorption from seawater and the influence of gas release on open-cycle ocean thermal energy conversion (OC-OTEC) system performance

    SciTech Connect (OSTI)

    Penney, T.R.; Althof, J.A.

    1985-06-01

    The technical community has questioned the validity and cost-effectiveness of open-cycle ocean thermal energy conversion (OC-OTEC) systems because of the unknown effect of noncondensable gas on heat exchanger performance and the power needed to run vacuum equipment to remove this gas. To date, studies of seawater gas desorption have not been prototypical for system level analysis. This study gives preliminary gas desorption data on a vertical spout, direct contact evaporator and multiple condenser geometries. Results indicate that dissolved gas can be substantially removed before the seawater enters the heat exchange process, reducing the uncertainty and effect of inert gas on heat exchanger performance.

  1. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  2. Enhanced durability of desulfurization sorbents for fluidized-bed applications

    SciTech Connect (OSTI)

    Gupta, R.P.; Gangwal, S.K.

    1992-11-01

    To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

  3. Gas chromatograph-mass spectrometer (GC/MS) system for quantitative analysis of reactive chemical compounds

    DOE Patents [OSTI]

    Grindstaff, Quirinus G.

    1992-01-01

    Described is a new gas chromatograph-mass spectrometer (GC/MS) system and method for quantitative analysis of reactive chemical compounds. All components of such a GC/MS system external to the oven of the gas chromatograph are programmably temperature controlled to operate at a volatilization temperature specific to the compound(s) sought to be separated and measured.

  4. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Underwood, Richard Paul; Makitka, III, Alexander; Carolan, Michael Francis

    2012-04-03

    An oxygen ion transport membrane process wherein a heated oxygen-containing gas having one or more contaminants is contacted with a reactive solid material to remove the one or more contaminants. The reactive solid material is provided as a deposit on a support. The one or more contaminant compounds in the heated oxygen-containing gas react with the reactive solid material. The contaminant-depleted oxygen-containing gas is contacted with a membrane, and oxygen is transported through the membrane to provide transported oxygen.

  5. Degradation of TBC Systems in Environments Relevant to Advanced Gas Turbines for IGCC Systems

    SciTech Connect (OSTI)

    Gleeson, Brian

    2014-09-30

    Air plasma sprayed (APS) thermal barrier coatings (TBCs) are used to provide thermal insulation for the hottest components in gas turbines. Zirconia stabilized with 7wt% yttria (7YSZ) is the most common ceramic top coat used for turbine blades. The 7YSZ coating can be degraded from the buildup of fly-ash deposits created in the power-generation process. Fly ash from an integrated gasification combined cycle (IGCC) system can result from coal-based syngas. TBCs are also exposed to harsh gas environments containing CO2, SO2, and steam. Degradation from the combined effects of fly ash and harsh gas atmospheres has the potential to severely limit TBC lifetimes. The main objective of this study was to use lab-scale testing to systematically elucidate the interplay between prototypical deposit chemistries (i.e., ash and its constituents, K2SO4, and FeS) and environmental oxidants (i.e., O2, H2O and CO2) on the degradation behavior of advanced TBC systems. Several mechanisms of early TBC failure were identified, as were the specific fly-ash constituents responsible for degradation. The reactivity of MCrAlY bondcoats used in TBC systems was also investigated. The specific roles of oxide and sulfate components were assessed, together with the complex interplay between gas composition, deposit chemistry and alloy reactivity. Bondcoat composition design strategies to mitigate corrosion were established, particularly with regard to controlling phase constitution and the amount of reactive elements the bondcoat contains in order to achieve optimal corrosion resistance.

  6. Method for eliminating gas blocking in electrokinetic pumping systems

    DOE Patents [OSTI]

    Arnold, Don W.; Paul, Phillip H.; Schoeniger, Joseph S.

    2001-09-11

    A method for eliminating gas bubble blockage of current flow during operation of an electrokinetic pump. By making use of the ability to modify the surface charge on the porous dielectric medium used in electrokinetic pumps, it becomes possible to place electrodes away from the pressurized region of the electrokinetic pump. While gas is still generated at the electrodes they are situated such that the generated gas can escape into a larger buffer reservoir and not into the high pressure region of the pump where the gas bubbles can interrupt current flow. Various combinations of porous dielectric materials and ionic conductors can be used to create pumps that have desirable electrical, material handling, and flow attributes.

  7. Tips: Natural Gas and Oil Heating Systems | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Furnaces and boilers Oil-fired boilers and furnaces Gas-fired boilers and furnaces ... Federal tax credits are available for geothermal heat pumps through 2016. Learn more. Federal ...

  8. Reduce Natural Gas Use in Your Industrial Process Heating Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Think again. Cutting your natural gas bill can be as simple as adjusting a dial. Get ... water, and oils or in preheating charge material going into a furnace or oven. n Consider ...

  9. Gas phase chemical detection with an integrated chemical analysis system

    SciTech Connect (OSTI)

    CASALNUOVO,STEPHEN A.; FRYE-MASON,GREGORY CHARLES; KOTTENSTETTE,RICHARD; HELLER,EDWIN J.; MATZKE,CAROLYN M.; LEWIS,PATRICK R.; MANGINELL,RONALD P.; BACA,ALBERT G.; HIETALA,VINCENT M.

    2000-04-12

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  10. Kinetics of combined SO/sub 2//NO in flue gas clean-up

    SciTech Connect (OSTI)

    Chang, S.G.; Littlejohn, D.

    1985-03-01

    The kinetics of reactions involving SO/sub 2/, NO, and ferrous chelate additives in wet flue gas simultaneous desulfurization and denitrification scrubbers are discussed. The relative importance of these reactions are assessed. The relevance of these reactions to spray dryer processes for combined SO/sub 2//NO flue gas clean-up is addressed. 37 refs., 7 figs.

  11. A 50-month gasifier mechanistic study and downstream unit process development program for the pressurized ash-agglomerating fluidized-bed gasification system

    SciTech Connect (OSTI)

    Haldipur, G.B.; Schmidt, D.K.; Smith, K.J.

    1989-03-01

    This technology development program scope included studies of those processes and components necessary to convert coal, oxidant and steam into a clean fuel gas. The configuration of the processes and components constitutes a Gasifier Island which is a key concept in the application of the KRW gasification and cleanup technologies. This Gasifier Island typically consists of process units that perform the following functions: feedstock preparation, gasification, desulfurization, heat recovery, particulate removal, and solid waste treatment. The processing has been conducted in a variety of gasifier operating modes including air-blown and oxygen-blown, both with and without in-bed desulfurization which includes injection of limestone or dolomite sorbent. Process configurations downstream of the gasifier have included recycle and non-recycle cyclones, sintered filters, and zinc ferrite fixed beds. Because of the developmental nature of the KRW technology program and the flexibility of the pilot plant itself, a wide range of gasifier-cleanup process configurations has been investigated. The KRW pilot plant program evaluated a system comprised of the following major process elements: gasifier and in-bed desulfurizer, particulate cleanup train, external sulfur polishing bed, and solid waste disposal system.

  12. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  13. Development and demonstration of a wood-fired gas turbine system

    SciTech Connect (OSTI)

    Smith, V.; Selzer, B.; Sethi, V.

    1993-08-01

    The objectives of the test program were to obtain some preliminary information regarding the nature of particulate and vapor phase alkali compounds produced and to assess any deleterious impact they might have on materials of construction. Power Generating Incorporated (PGI) is developing a wood-fired gas turbine system for specialized cogeneration applications. The system is based on a patented pressurized combustor designed and tested by PGI in conjunction with McConnell Industries. The other components of the system are fuel receiving, preparation, storage and feeding system, gas clean-up equipment, and a gas turbine generator.

  14. DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants DOE, RTI to Design and Build Gas Cleanup System for IGCC Power Plants July 13, 2009 - 1:00pm Addthis Washington, DC - The U.S. Department of Energy (DOE) announces a collaborative project with Research Triangle Institute (RTI) International to design, build, and test a warm gas cleanup system to remove multiple contaminants from coal-derived syngas. The 50-MWe system will include technologies to remove

  15. Gas mixing system for imaging of nanomaterials under dynamic environments by environmental transmission electron microscopy

    SciTech Connect (OSTI)

    Akatay, M. Cem; Zvinevich, Yury; Ribeiro, Fabio H. E-mail: estach@bnl.gov; Baumann, Philipp; Stach, Eric A. E-mail: estach@bnl.gov

    2014-03-15

    A gas mixing manifold system that is capable of delivering a stable pressure stream of a desired composition of gases into an environmental transmission electron microscope has been developed. The system is designed to provide a stable imaging environment upon changes of either the composition of the gas mixture or upon switching from one gas to another. The design of the system is described and the response of the pressure inside the microscope, the sample temperature, and sample drift in response to flow and composition changes of the system are reported.

  16. Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. [Rhodococcus erythropolis, Thiobacillus acidophilus, Thiobacillus novellus

    SciTech Connect (OSTI)

    Krawiec, S.

    1992-01-01

    Research continues on desulfurization of coal using microorganisms. Topics reported on this quarter include: desulfurization with N1-36 (presumptively identified as Rhodochrous erythropolis), pulsed-field gel electrophoresis of chromosomal DNA's of Thiobacillus spp., and fresh isolates with the presumptive capacity to desulfurize dibenzothiophenes.

  17. Molecular biological enhancement of coal desulfurization: Cloning and expression of the sulfoxide/sulfone/sulfonate/sulfate genes in Pseudomonads and Thiobacillae. Eleventh quarterly report

    SciTech Connect (OSTI)

    Krawiec, S.

    1992-08-01

    Research continues on desulfurization of coal using microorganisms. Topics reported on this quarter include: desulfurization with N1-36 (presumptively identified as Rhodochrous erythropolis), pulsed-field gel electrophoresis of chromosomal DNA`s of Thiobacillus spp., and fresh isolates with the presumptive capacity to desulfurize dibenzothiophenes.

  18. System and method to determine thermophysical properties of a multi-component gas

    DOE Patents [OSTI]

    Morrow, Thomas B.; Behring, II, Kendricks A.

    2003-08-05

    A system and method to characterize natural gas hydrocarbons using a single inferential property, such as standard sound speed, when the concentrations of the diluent gases (e.g., carbon dioxide and nitrogen) are known. The system to determine a thermophysical property of a gas having a first plurality of components comprises a sound velocity measurement device, a concentration measurement device, and a processor to determine a thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the concentration measurements, wherein the number of concentration measurements is less than the number of components in the gas. The method includes the steps of determining the speed of sound in the gas, determining a plurality of gas component concentrations in the gas, and determining the thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the plurality of concentrations.

  19. Anode shroud for off-gas capture and removal from electrolytic oxide reduction system

    DOE Patents [OSTI]

    Bailey, James L.; Barnes, Laurel A.; Wiedmeyer, Stanley G.; Williamson, Mark A.; Willit, James L.

    2014-07-08

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies and an anode shroud for each of the anode assemblies. The anode shroud may be used to dilute, cool, and/or remove off-gas from the electrolytic oxide reduction system. The anode shroud may include a body portion having a tapered upper section that includes an apex. The body portion may have an inner wall that defines an off-gas collection cavity. A chimney structure may extend from the apex of the upper section and be connected to the off-gas collection cavity of the body portion. The chimney structure may include an inner tube within an outer tube. Accordingly, a sweep gas/cooling gas may be supplied down the annular space between the inner and outer tubes, while the off-gas may be removed through an exit path defined by the inner tube.

  20. Inert gas rejection device for zinc-halogen battery systems

    DOE Patents [OSTI]

    Hammond, Michael J.; Arendell, Mark W.

    1981-01-01

    An electrolytic cell for separating chlorine gas from other (foreign) gases, having an anode, a cathode assembly, an aqueous electrolyte, a housing, and a constant voltage power supply. The cathode assembly is generally comprised of a dense graphite electrode having a winding channel formed in the face opposing the anode, a gas impermeable (but liquid permeable) membrane sealed into the side of the cathode electrode over the channel, and a packing of graphite particles contained in the channel of the cathode electrode. The housing separates and parallelly aligns the anode and cathode assembly, and provides a hermetic seal for the cell. In operation, a stream of chlorine and foreign gases enters the cell at the beginning of the cathode electrode channel. The chlorine gas is dissolved into the electrolyte and electrochemically reduced into chloride ions. The chloride ions disfuse through the gas impermeable membrane, and are electrochemically oxidized at the anode into purified chlorine gas. The foreign gases do not participate in the above electrochemical reactions, and are vented from the cell at the end of the cathode electrode channel.

  1. JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Priorities - News Releases | NREL JISEA News: Study on Methane Emissions from Natural Gas Systems Indicates New Priorities Study findings published in Policy Forum of Journal Science February 18, 2014 A new study published in the journal Science says that the total impact of switching to natural gas depends heavily on leakage of methane (CH4) during the natural gas life cycle, and suggests that more can be done to reduce methane emissions and to improve measurement tools which help

  2. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  3. Radiation and gas conduction heat transport across a helium dewer multilayer insulation system

    SciTech Connect (OSTI)

    Green, M.A.

    1995-02-01

    This report describes a method for calculating mixed heat transfer through the multilayer insulation used to insulated a 4K liquid helium cryostat. The method described permits one to estimate the insulation potential for a multilayer insulation system from first principles. The heat transfer regimes included are: radiation, conduction by free molecule gas conduction, and conduction through continuum gas conduction. Heat transfer in the transition region between the two gas conduction regimes is also included.

  4. System and method for converting wellhead gas to liquefied petroleum gases (LPG)

    SciTech Connect (OSTI)

    May, R.L.; Sinclair, B.W.

    1984-07-31

    A method of converting natural wellhead gas to liquefied petroleum gases (LPG) may comprise the steps of: separating natural gas from petroleum fluids exiting a wellhead; compressing the natural gas; refrigerating the natural gas, liquefying at least a portion thereof; separating LPG from gas vapors of the refrigerated natural gas; storing the separated LPG in a storage tank with a vapor space therein; and recirculating a portion of the LPG vapors in the storage tank with the natural gas exiting the wellhead to enhance recovery of LPG. A system for performing the method may comprise: a two-stage gas compressor connected to the wellhead; a refrigeration unit downstream of the gas compressor for refrigerating the compressed gases therefrom; at least one product separator downstream of the refrigerator unit for receiving refrigerated and compressed gases discharged from the refrigerator unit and separating LPG therein from gases remaining in vapor form; and a storage tank for receiving and storing the separated LPG therein, the storage tank having a vapor space therein connected upstream of the gas compressor through a pressure regulator allowing recirculation of some LPG vapors with the natural gases through said system.

  5. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  6. Fluidized bed and method and system for gas component capture

    DOE Patents [OSTI]

    Krutka, Holly; Wilson, Cody; Starns, Travis

    2016-05-31

    The present disclosure is directed to a process that allows dry sorbents to remove a target constituent, such as carbon dioxide (CO.sub.2), from a gas stream. A staged fluidized bed separator enables gas and sorbent to move in opposite directions. The sorbent is loaded with target constituent in the separator. It is then transferred to a regenerator where the target constituent is stripped. The temperature of the separator and regenerator are controlled. After it is removed from the regenerator, the sorbent is then transferred back to the separator.

  7. Gas Phase Chemical Detection with an Integrated Chemical Analysis System

    SciTech Connect (OSTI)

    Baca, Albert G.; Casalnuovo, Stephen A.; Frye-Mason, Gregory C.; Heller, Edwin J.; Hietala, Susan L.; Hietala, Vincent M.; Kottenstette, Richard J.; Lewis, Patrick R.; Manginell, Ronald P.; Matzke, Carloyn M.; Reno, John L.; Sasaki, Darryl Y.; Schubert, W. Kent

    1999-07-08

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample concentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described. The design and performance of novel micromachined acoustic wave devices, with the potential for improved chemical sensitivity, are also described.

  8. Ion transport membrane reactor systems and methods for producing synthesis gas

    SciTech Connect (OSTI)

    Repasky, John Michael

    2015-05-12

    Embodiments of the present invention provide cost-effective systems and methods for producing a synthesis gas product using a steam reformer system and an ion transport membrane (ITM) reactor having multiple stages, without requiring inter-stage reactant injections. Embodiments of the present invention also provide techniques for compensating for membrane performance degradation and other changes in system operating conditions that negatively affect synthesis gas production.

  9. Flight Testing of an Advanced Airborne Natural Gas Leak Detection System

    SciTech Connect (OSTI)

    Dawn Lenz; Raymond T. Lines; Darryl Murdock; Jeffrey Owen; Steven Stearns; Michael Stoogenke

    2005-10-01

    ITT Industries Space Systems Division (Space Systems) has developed an airborne natural gas leak detection system designed to detect, image, quantify, and precisely locate leaks from natural gas transmission pipelines. This system is called the Airborne Natural Gas Emission Lidar (ANGEL) system. The ANGEL system uses a highly sensitive differential absorption Lidar technology to remotely detect pipeline leaks. The ANGEL System is operated from a fixed wing aircraft and includes automatic scanning, pointing system, and pilot guidance systems. During a pipeline inspection, the ANGEL system aircraft flies at an elevation of 1000 feet above the ground at speeds of between 100 and 150 mph. Under this contract with DOE/NETL, Space Systems was funded to integrate the ANGEL sensor into a test aircraft and conduct a series of flight tests over a variety of test targets including simulated natural gas pipeline leaks. Following early tests in upstate New York in the summer of 2004, the ANGEL system was deployed to Casper, Wyoming to participate in a set of DOE-sponsored field tests at the Rocky Mountain Oilfield Testing Center (RMOTC). At RMOTC the Space Systems team completed integration of the system and flew an operational system for the first time. The ANGEL system flew 2 missions/day for the duration for the 5-day test. Over the course of the week the ANGEL System detected leaks ranging from 100 to 5,000 scfh.

  10. Development of a Liquid Metal Based Fuel Gas Scrubbing System

    SciTech Connect (OSTI)

    Chang, B.F.; Swithenbank, J.; Sharifi, V.N.; Warner, N.

    2002-09-20

    The objective of this research project is to perform studies on an analogous room temperature packed bed scrubber operating under non-wetting conditions, providing insight and understanding towards the development of a high temperature packed bed gas scrubber irrigated by molten tin.

  11. Energy Department Expands Gas Gouging Reporting System to Include 1-800

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number: 1-800-244-3301 | Department of Energy Expands Gas Gouging Reporting System to Include 1-800 Number: 1-800-244-3301 Energy Department Expands Gas Gouging Reporting System to Include 1-800 Number: 1-800-244-3301 September 6, 2005 - 9:50am Addthis Washington, DC - Energy Secretary Samuel W. Bodman announced today that the Department of Energy has expanded its gas gouging reporting system to include a toll-free telephone hotline. The hotline is available to American consumers starting

  12. Thermal Analysis of the Divertor Primary Heat Transfer System Piping During the Gas Baking Process

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Harvey, Karen; Ferrada, Juan J

    2011-02-01

    A preliminary analysis has been performed examining the temperature distribution in the Divertor Primary Heat Transfer System (PHTS) piping and the divertor itself during the gas baking process. During gas baking, it is required that the divertor reach a temperature of 350 C. Thermal losses in the piping and from the divertor itself require that the gas supply temperature be maintained above that temperature in order to ensure that all of the divertor components reach the required temperature. The analysis described in this report was conducted in order to estimate the required supply temperature from the gas heater.

  13. Ion transport membrane module and vessel system with directed internal gas flow

    DOE Patents [OSTI]

    Holmes, Michael Jerome; Ohrn, Theodore R.; Chen, Christopher Ming-Poh

    2010-02-09

    An ion transport membrane system comprising (a) a pressure vessel having an interior, an inlet adapted to introduce gas into the interior of the vessel, an outlet adapted to withdraw gas from the interior of the vessel, and an axis; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region; and (c) one or more gas flow control partitions disposed in the interior of the pressure vessel and adapted to change a direction of gas flow within the vessel.

  14. Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus

    SciTech Connect (OSTI)

    Miller, K.W.

    1991-01-01

    Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

  15. Model documentation: Natural gas transmission and distribution model of the National Energy Modeling System. Volume 1

    SciTech Connect (OSTI)

    1995-02-17

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. NEMS was developed in the Office of integrated Analysis and Forecasting of the Energy information Administration (EIA). NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the EIA and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. The NGTDM is the model within the NEMS that represents the transmission, distribution, and pricing of natural gas. The model also includes representations of the end-use demand for natural gas, the production of domestic natural gas, and the availability of natural gas traded on the international market based on information received from other NEMS models. The NGTDM determines the flow of natural gas in an aggregate, domestic pipeline network, connecting domestic and foreign supply regions with 12 demand regions. The methodology employed allows the analysis of impacts of regional capacity constraints in the interstate natural gas pipeline network and the identification of pipeline capacity expansion requirements. There is an explicit representation of core and noncore markets for natural gas transmission and distribution services, and the key components of pipeline tariffs are represented in a pricing algorithm. Natural gas pricing and flow patterns are derived by obtaining a market equilibrium across the three main elements of the natural gas market: the supply element, the demand element, and the transmission and distribution network that links them. The NGTDM consists of four modules: the Annual Flow Module, the Capacity F-expansion Module, the Pipeline Tariff Module, and the Distributor Tariff Module. A model abstract is provided in Appendix A.

  16. Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D initiative

    Office of Environmental Management (EM)

    Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D initiative 1 of 1 Summary: DOE will launch a collaborative effort with industry to evaluate and scope high- impact ...

  17. Feasibility study: utilization of landfill gas for a vehicle fuel system, Rossman's landfill, Clackamas County, Oregon

    SciTech Connect (OSTI)

    1981-01-01

    In 1978, a landfill operator in Oregon became interested in the technical and economic feasibility of recovering the methane generated in the landfill for the refueling of vehicles. DOE awarded a grant for a site-specific feasibility study of this concept. This study investigated the expected methane yield and the development of a conceptual gas-gathering system; gas processing, compressing, and storage systems; and methane-fueled vehicle systems. Cost estimates were made for each area of study. The results of the study are presented. Reasoning that gasoline prices will continue to rise and that approximately 18,000 vehicles in the US have been converted to operate on methane, a project is proposed to use this landfill as a demonstration site to produce and process methane and to fuel a fleet (50 to 400) vehicles with the gas produced in order to obtain performance and economic data on the systems used from gas collection through vehicle operation. (LCL)

  18. Control Scheme Modifications Increase Efficiency of Steam Generation System at Exxon Mobil Gas Plant

    SciTech Connect (OSTI)

    2002-01-01

    This case study highlights control scheme modifications made to the steam system at ExxonMobil's Mary Ann Gas Plant in Mobile, Alabama, which improved steam flow efficiency and reduced energy costs.

  19. Use of GTE-65 gas turbine power units in the thermal configuration of steam-gas systems for the refitting of operating thermal electric power plants

    SciTech Connect (OSTI)

    Lebedev, A. S.; Kovalevskii, V. P.; Getmanov, E. A.; Ermaikina, N. A.

    2008-07-15

    Thermal configurations for condensation, district heating, and discharge steam-gas systems (PGU) based on the GTE-65 gas turbine power unit are described. A comparative multivariant analysis of their thermodynamic efficiency is made. Based on some representative examples, it is shown that steam-gas systems with the GTE-65 and boiler-utilizer units can be effectively used and installed in existing main buildings during technical refitting of operating thermal electric power plants.

  20. DOE to Launch Collaborative Effort with Industry to Improve Natural Gas Systems

    Broader source: Energy.gov [DOE]

    DOE announced a series of actions, partnerships, and stakeholder commitments to help modernize the nation’s natural gas transmission and distribution systems and reduce methane emissions. As part of these DOE actions, AMO will lead a collaborative effort with industry to evaluate and scope high-impact manufacturing R&D to improve natural gas systems efficiency and leak reduction. The goal of this effort is to establish an advanced manufacturing initiative.

  1. Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D initiative

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet: Advanced Natural Gas Systems Manufacturing R&D initiative 1 of 1 Summary: DOE will launch a collaborative effort with industry to evaluate and scope high- impact manufacturing R&D to improve natural gas system efficiency and reduce leaks with the goal of establishing an advanced manufacturing initiative. This will include a formal request for information, public workshops, and technical analysis and will leverage technology development areas already in progress through DOE's

  2. Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrial Applications - Volume II (Appendices), January 2000 | Department of Energy Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications - Volume II (Appendices), January 2000 Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications - Volume II (Appendices), January 2000 This January 2000 document consists of the appendices for the main report quantifying the total market for onsite power generation within the Industries of

  3. Mid-South Metallurgical Makes Electrical and Natural Gas System Upgrades to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduce Energy Use and Achieve Cost Savings | Department of Energy Mid-South Metallurgical Makes Electrical and Natural Gas System Upgrades to Reduce Energy Use and Achieve Cost Savings Mid-South Metallurgical Makes Electrical and Natural Gas System Upgrades to Reduce Energy Use and Achieve Cost Savings This case study describes how Mid-South Metallurgical implemented several recommendations resulting from a plant-wide energy assessment from DOE's Industrial Assessment Center (IAC) at

  4. Optimization problems in natural gas transportation systems. A state-of-the-art review

    SciTech Connect (OSTI)

    Ríos-Mercado, Roger Z.; Borraz-Sánchez, Conrado

    2015-03-24

    Our paper provides a review on the most relevant research works conducted to solve natural gas transportation problems via pipeline systems. The literature reveals three major groups of gas pipeline systems, namely gathering, transmission, and distribution systems. In this work, we aim at presenting a detailed discussion of the efforts made in optimizing natural gas transmission lines.There is certainly a vast amount of research done over the past few years on many decision-making problems in the natural gas industry and, specifically, in pipeline network optimization. In this work, we present a state-of-the-art survey focusing on specific categories that include short-term basis storage (line-packing problems), gas quality satisfaction (pooling problems), and compressor station modeling (fuel cost minimization problems). We also discuss both steady-state and transient optimization models highlighting the modeling aspects and the most relevant solution approaches known to date. Although the literature on natural gas transmission system problems is quite extensive, this is, to the best of our knowledge, the first comprehensive review or survey covering this specific research area on natural gas transmission from an operations research perspective. Furthermore, this paper includes a discussion of the most important and promising research areas in this field. Hence, our paper can serve as a useful tool to gain insight into the evolution of the many real-life applications and most recent advances in solution methodologies arising from this exciting and challenging research area of decision-making problems.

  5. Hybrid lean premixing catalytic combustion system for gas turbines

    DOE Patents [OSTI]

    Critchley, Ian L.

    2003-12-09

    A system and method of combusting a hydrocarbon fuel is disclosed. The system combines the accuracy and controllability of an air staging system with the ultra-low emissions achieved by catalytic combustion systems without the need for a pre-heater. The result is a system and method that is mechanically simple and offers ultra-low emissions over a wide range of power levels, fuel properties and ambient operating conditions.

  6. Operating experience review of an INL gas monitoring system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cadwallader, Lee C.; DeWall, K. G.; Herring, J. S.

    2015-03-01

    This article describes the operations of several types of gas monitors in use at the Idaho National Laboratory (INL) High Temperature Electrolysis Experiment (HTE) laboratory. The gases monitored in the lab room are hydrogen, carbon monoxide, carbon dioxide, and oxygen. The operating time, calibration, and both actual and unwanted alarms are described. The calibration session time durations are described. Some simple calculations are given to estimate the reliability of these monitors and the results are compared to operating experiences of other types of monitors.

  7. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-05-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  8. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-01-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  9. Operating experience review of an INL gas monitoring system

    SciTech Connect (OSTI)

    Cadwallader, Lee C.; DeWall, K. G.; Herring, J. S.

    2015-03-12

    This article describes the operations of several types of gas monitors in use at the Idaho National Laboratory (INL) High Temperature Electrolysis Experiment (HTE) laboratory. The gases monitored in the lab room are hydrogen, carbon monoxide, carbon dioxide, and oxygen. The operating time, calibration, and both actual and unwanted alarms are described. The calibration session time durations are described. In addition, some simple calculations are given to estimate the reliability of these monitors and the results are compared to operating experiences of other types of monitors.

  10. Critical issues in the development of hybrid solar/gas receivers for dish/Stirling systems

    SciTech Connect (OSTI)

    Adkins, D.R.; Rawlinson, K.S.

    1991-01-01

    A hybrid solar/gas receiver system will allow Stirling engines to operate with combined solar and gas power sources. One of the most attractive options for building a hybrid system is to integrate a gas-fired heat pipe directly into a heat-pipe solar receiver. Before this union can take place, however, a number of technical issues must be resolved. A design must be found that properly distributes the heat-pipe's working fluid over the heated surfaces and prevents fluid from accumulating at undesirable locations in the heat pipe. Experience that has been gained in developing solar receivers and gas-fired heat pipes under recent Department of Energy solar-thermal dish-electric programs is used in this paper to address many of the technical obstacles to building receiver systems. 16 refs.

  11. Critical issues in the development of hybrid solar/gas receivers for dish/Stirling systems

    SciTech Connect (OSTI)

    Adkins, D.R.; Rawlinson, K.S.

    1991-12-31

    A hybrid solar/gas receiver system will allow Stirling engines to operate with combined solar and gas power sources. One of the most attractive options for building a hybrid system is to integrate a gas-fired heat pipe directly into a heat-pipe solar receiver. Before this union can take place, however, a number of technical issues must be resolved. A design must be found that properly distributes the heat-pipe`s working fluid over the heated surfaces and prevents fluid from accumulating at undesirable locations in the heat pipe. Experience that has been gained in developing solar receivers and gas-fired heat pipes under recent Department of Energy solar-thermal dish-electric programs is used in this paper to address many of the technical obstacles to building receiver systems. 16 refs.

  12. Particle trap for compressed gas insulated transmission systems

    DOE Patents [OSTI]

    Cookson, Alan H.

    1985-01-01

    A particle trap is provided for gas insulated transmission lines having a central high voltage conductor supported within an outer coaxial conductive sheath by a dielectric support member. A cavity between the inner conductor and outer sheath is filled with a dielectric insulating gas. A cone-like particle deflector, mounted to the inner conductor, deflects moving particles away from the support member, to radially outer portions of the cavity. A conductive shield is disposed adjacent the outer sheath to form a field-free region in radially outer portions of the cavity, between the shield and the sheath. Particles traveling along the cavity are deflected by the cone-like deflector into the field-free region where they are held immobile. In a vertical embodiment, particles enter the field-free region through an upper end of a gap formed between shield and sheath members. In a horizontal embodiment, the deflector cone has a base which is terminated radially internally of the shield. Apertures in the shield located adjacent the deflector allow passage of deflected particles into the field-free region. The dielectric support member is thereby protected from contaminating particles that may otherwise come to rest thereon.

  13. Particle trap for compressed gas insulated transmission systems

    DOE Patents [OSTI]

    Cookson, A.H.

    1984-04-26

    A particle trap is provided for gas insulated transmission lines having a central high voltage conductor supported within an outer coaxial conductive sheath by a dielectric support member. A cavity between the inner conductor and outer sheath is filled with a dielectric insulating gas. A cone-like particle deflector, mounted to the inner conductor, deflects moving particles away from the support member, to radially outer portions of the cavity. A conductive shield is disposed adjacent the outer sheath to form a field-free region in radially outer portions of the cavity, between the shield and the sheath. Particles traveling along the cavity are deflected by the cone-like deflector into the field-free region where they are held immobile. In a vertical embodiment, particles enter the field-free region through an upper end of a gap formed between shield and sheath members. In a horizontal embodiment, the deflector cone has a base which is terminated radially internally of the shield. Apertures in the shield located adjacent the deflector allow passage of deflected particles into the field-free region. The dielectric support member is thereby protected from contaminating particles that may otherwise come to rest thereon.

  14. Method of testing gas insulated systems for the presence of conducting particles utilizing a gas mixture of nitrogen and sulfur hexafluoride

    DOE Patents [OSTI]

    Wootton, Roy E.

    1979-01-01

    A method of testing a gas insulated system for the presence of conducting particles. The method includes inserting a gaseous mixture comprising about 98 volume percent nitrogen and about 2 volume percent sulfur hexafluoride into the gas insulated system at a pressure greater than 60 lb./sq. in. gauge, and then applying a test voltage to the system. If particles are present within the system, the gaseous mixture will break down, providing an indicator of the presence of the particles.

  15. Optical methods and systems for detecting a constituent in a gas containing oxygen in harsh environments

    DOE Patents [OSTI]

    Carpenter, Michael A.; Sirinakis, George

    2011-01-04

    A method for detecting a gas phase constituent such as carbon monoxide, nitrogen dioxide, hydrogen, or hydrocarbons in a gas comprising oxygen such as air, includes providing a sensing material or film having a metal embedded in a catalytically active matrix such as gold embedded in a yttria stabilized zirconia (YSZ) matrix. The method may include annealing the sensing material at about 900.degree. C., exposing the sensing material and gas to a temperature above 400.degree. C., projecting light onto the sensing material, and detecting a change in the absorption spectrum of the sensing material due to the exposure of the sensing material to the gas in air at the temperature which causes a chemical reaction in the sensing material compared to the absorption spectrum of the sensing material in the absence of the gas. Systems employing such a method are also disclosed.

  16. Systems approach used in the Gas Centrifuge Enrichment Plant

    SciTech Connect (OSTI)

    Rooks, W.A. Jr.

    1982-01-01

    A requirement exists for effective and efficient transfer of technical knowledge from the design engineering team to the production work force. Performance-Based Training (PBT) is a systematic approach to the design, development, and implementation of technical training. This approach has been successfully used by the US Armed Forces, industry, and other organizations. The advantages of the PBT approach are: cost-effectiveness (lowest life-cycle training cost), learning effectiveness, reduced implementation time, and ease of administration. The PBT process comprises five distinctive and rigorous phases: Analysis of Job Performance, Design of Instructional Strategy, Development of Training Materials and Instructional Media, Validation of Materials and Media, and Implementation of the Instructional Program. Examples from the Gas Centrifuge Enrichment Plant (GCEP) are used to illustrate the application of PBT.

  17. Reduce Natural Gas Use in Your Industrial Process Heating Systems

    Office of Energy Efficiency and Renewable Energy (EERE)

    This fact sheet describes ten effective ways to save energy and money in industrial process heating systems by making some changes in equipment, operations, and maintenance.

  18. Solar heating, cooling and domestic hot water system installed at Columbia Gas System Service Corp. , Columbus, Ohio. Final report

    SciTech Connect (OSTI)

    1980-11-01

    The Solar Energy System located at the Columbia Gas Corporation, Columbus, Ohio, has 2978 ft/sup 2/ of Honeywell single axis tracking, concentrating collectors and provides solar energy for space heating, space cooling and domestic hot water. A 1,200,000 Btu/h Bryan water-tube gas boiler provides hot water for space heating. Space cooling is provided by a 100 ton Arkla hot water fired absorption chiller. Domestic hot water heating is provided by a 50 gallon natural gas domestic storage water heater. Extracts are included from the site files, specification references, drawings, installation, operation and maintenance instructions.

  19. Natural Gas Transmission and Distribution Model of the National Energy Modeling System. Volume 1

    SciTech Connect (OSTI)

    1998-01-01

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. The NGTDM is the model within the NEMS that represents the transmission, distribution, and pricing of natural gas. The model also includes representations of the end-use demand for natural gas, the production of domestic natural gas, and the availability of natural gas traded on the international market based on information received from other NEMS models. The NGTDM determines the flow of natural gas in an aggregate, domestic pipeline network, connecting domestic and foreign supply regions with 12 demand regions. The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic design, provides detail on the methodology employed, and describes the model inputs, outputs, and key assumptions. Subsequent chapters of this report provide: an overview of NGTDM; a description of the interface between the NEMS and NGTDM; an overview of the solution methodology of the NGTDM; the solution methodology for the Annual Flow Module; the solution methodology for the Distributor Tariff Module; the solution methodology for the Capacity Expansion Module; the solution methodology for the Pipeline Tariff Module; and a description of model assumptions, inputs, and outputs.

  20. Coal desulfurization by chlorinolysis: production and combustion-test evaluation of product coals. Final report

    SciTech Connect (OSTI)

    Kalvinskas, J.; Daly, D.

    1982-04-30

    Laboratory-scale screening tests were carried out on PSOC 276, Pittsburgh Coal from Harrison County, Ohio to establish chlorination and hydrodesulfurization conditions for the batch reactor production of chlorinolysis and chlorinolysis-hydrodesulfurized coals. In addition, three bituminous coals, Pittsburgh No. 8 from Greene County, PA, Illinois No. 6 from Jackson County, Illinois and Eagle No. 5 from Moffat County, Colorado were treated on the lab scale by the chlorinolysis process to provide 39 to 62% desulfurization. Two bituminous coals (PSOC 276, Pittsburgh Coal from Harrison County, Ohio and 282, Illinois No. 6 Coal from Jefferson County, Illinois) and one subbituminous coal (PSOC 230, Rosebud Coal fom Rosebud County, Montana) were then produced in 11 to 15 pound lots as chlorinolysis and hydrodesulfurized coals. The chlorinolysis coals had a desulfurization of 29 to 69%, reductions in volatiles (12 to 37%) and hydrogen (6 to 31%). Hydrodesulfurization provided a much greater desulfurization (56 to 86%), reductions in volatiles (77 to 84%) and hydrogen (56 to 64%). The three coals were combustion tested in the Penn State plane flame furance to determine ignition and burning characteristics. All three coals burned well to completion as: raw coals, chlorinolysis processed coals and hydrodesulfurized coals. The hydrodesulfurized coals experienced greater ignition delays and reduced burning rates than the other coals because of the reduced volatile content. It is thought that the increased open pore volume in the desulfurized-devolatilized coals compensates in part for the decreased volatiles effect on ignition and burning. 4 figures, 2 tables.

  1. Oil and Gas Supply Module of the National Energy Modeling System: Model Documentation 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Oil and Gas Supply Module of the National Energy Modeling System: Model Documentation 2014 July 2014 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | NEMS Model Documentation 2014: Oil and Gas Supply Module i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are

  2. INTEGRATED 15KV SIC VSD AND HIGH-SPEED MW MOTOR FOR GAS COMPRESSION SYSTEMS

    Broader source: Energy.gov [DOE]

    Eaton Corporation – Arden, NC A 15 kilovolt (kV) SiC variable-speed drive will be integrated with a high-speed megawatt motor for gas compression applications. This new drive technology will be developed and tested to operate at greater than 99% efficiency and achieve 10 times the power density of competing drives, providing an integrated, highly-efficient motor and drive system for natural gas applications. Fact sheet coming soon.

  3. Tips: Natural Gas and Oil Heating Systems | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    a new energy-efficient furnace to save money over the long term. Install a new energy-efficient furnace to save money over the long term. If you plan to buy a new heating system,...

  4. Method for controlling exhaust gas heat recovery systems in vehicles

    DOE Patents [OSTI]

    Spohn, Brian L.; Claypole, George M.; Starr, Richard D

    2013-06-11

    A method of operating a vehicle including an engine, a transmission, an exhaust gas heat recovery (EGHR) heat exchanger, and an oil-to-water heat exchanger providing selective heat-exchange communication between the engine and transmission. The method includes controlling a two-way valve, which is configured to be set to one of an engine position and a transmission position. The engine position allows heat-exchange communication between the EGHR heat exchanger and the engine, but does not allow heat-exchange communication between the EGHR heat exchanger and the oil-to-water heat exchanger. The transmission position allows heat-exchange communication between the EGHR heat exchanger, the oil-to-water heat exchanger, and the engine. The method also includes monitoring an ambient air temperature and comparing the monitored ambient air temperature to a predetermined cold ambient temperature. If the monitored ambient air temperature is greater than the predetermined cold ambient temperature, the two-way valve is set to the transmission position.

  5. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, J.R.; Downs, W.C.; Kaser, T.G.; Hall, H.J.

    1997-12-16

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources. 4 figs.

  6. System for the removal of contaminant soil-gas vapors

    DOE Patents [OSTI]

    Weidner, Jerry R.; Downs, Wayne C.; Kaser, Timothy G.; Hall, H. James

    1997-01-01

    A system extracts contaminated vapors from soil or other subsurface regions by using changes in barometric pressure to operate sensitive check valves that control air entry and removal from wells in the ground. The system creates an efficient subterranean flow of air through a contaminated soil plume and causes final extraction of the contaminants from the soil to ambient air above ground without any external energy sources.

  7. Desulfurization of coal: Enhanced selectivity using phase transfer catalysts. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Palmer, S.R.; Hippo, E.J.

    1995-12-31

    Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development of viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigates the application of phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions than otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidations for selective sulfur oxidation are also being studied. If successful this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal. During this quarter aliquots of the IBC-101 coal have been ground to various particle sizes in an attempt to find the optimum physical pretreatment for mineral, especially pyrite, removal. Analysis of these various aliquots shows them to be representative of the original coal. In addition, preliminary desulfurization reactions using fly ash and scrubber sludges have been performed on an unoxidized IBC-101 sample. Results will be available next quarter. Also, SEM-EDAX analysis of the fly ash indicates that it contains oxides that have shown activity in base desulfurization reactions.

  8. System Chemical Decontamination Technology by the IF7 Gas

    SciTech Connect (OSTI)

    Ema, Akira; Sugitsue, Noritake; Zaitsu, Tomohisa

    2008-01-15

    When we decommission the equipments contaminated by the uranium, both the dismantling process of the equipments and the disposal process of the radioactive waste will be carried out. However, costs of these processes will be very expensive because the dismantling facilities are required in the dismantling process and many radioactive wastes are generated. Here, if it is possible to decontaminate the equipments below the clearance level, the amount of radioactive wastes is reduced very much. As a result, costs of the disposal will be able to reduce extremely. Moreover, if it is possible to decontaminate the equipments before dismantling, costs of the dismantling will be reduced, too. In other words, the total costs of the dismantling process and the disposal process will be minimized by decontaminating below the clearance level without dismantling. So, we have developed new decontamination technology to decontaminate below the clearance level without dismantling. In this paper, as an example, we tried to decontaminate the uranium enrichment plant in order to reveal the practicality of our technology. In conclusion: we proposed new decontamination technology by the IF7 gas. And, as an example, we tried to decontaminate the uranium enrichment plant. As a result, we could reveal that our technology has the high performance which can decontaminate below the assumed clearance level: 1.0 Bq/g in the limited time. Finally, we simulated the amount of the radioactive waste for decommissioning the uranium enrichment plant. As a result, though a lot of radioactive wastes will usually be generated, we obtained the prospect that it is possible to reduced 85% of the radioactive waste by using our technology.

  9. Low pressure cooling seal system for a gas turbine engine

    SciTech Connect (OSTI)

    Marra, John J

    2014-04-01

    A low pressure cooling system for a turbine engine for directing cooling fluids at low pressure, such as at ambient pressure, through at least one cooling fluid supply channel and into a cooling fluid mixing chamber positioned immediately downstream from a row of turbine blades extending radially outward from a rotor assembly to prevent ingestion of hot gases into internal aspects of the rotor assembly. The low pressure cooling system may also include at least one bleed channel that may extend through the rotor assembly and exhaust cooling fluids into the cooling fluid mixing chamber to seal a gap between rotational turbine blades and a downstream, stationary turbine component. Use of ambient pressure cooling fluids by the low pressure cooling system results in tremendous efficiencies by eliminating the need for pressurized cooling fluids for sealing this gap.

  10. Natural gas transmission and distribution model of the National Energy Modeling System

    SciTech Connect (OSTI)

    1997-02-01

    The Natural Gas Transmission and Distribution Model (NGTDM) is the component of the National Energy Modeling System (NEMS) that is used to represent the domestic natural gas transmission and distribution system. NEMS was developed in the Office of Integrated Analysis and Forecasting of the Energy Information Administration (EIA). NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the EIA and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. From 1982 through 1993, the Intermediate Future Forecasting System (IFFS) was used by the EIA for its analyses, and the Gas Analysis Modeling System (GAMS) was used within IFFS to represent natural gas markets. Prior to 1982, the Midterm Energy Forecasting System (MEFS), also referred to as the Project Independence Evaluation System (PIES), was employed. NEMS was developed to enhance and update EIA`s modeling capability by internally incorporating models of energy markets that had previously been analyzed off-line. In addition, greater structural detail in NEMS permits the analysis of a broader range of energy issues. The time horizon of NEMS is the midterm period (i.e., through 2015). In order to represent the regional differences in energy markets, the component models of NEMS function at regional levels appropriate for the markets represented, with subsequent aggregation/disaggregation to the Census Division level for reporting purposes.

  11. Penetration of gas delivery systems in the United States: A state-level data analysis

    SciTech Connect (OSTI)

    Guldmann, J.M. . Environmental Assessment and Information Sciences Div. Ohio State Univ., Columbus, OH )

    1990-02-01

    The purpose of this study is to assess the degree to which the gas delivery infrastructure penetrates US regions and states and to pinpoint those areas in which the lack of a sufficient infrastructure impedes the expansion of the natural gas market. Regions and states are ranked according to several indicators developed with data published by the American Gas Association, the US Department of Energy/Energy Information Administration, and the US Bureau of the Census. These include the numbers of gas customers and gas deliveries by sector, mileages of distribution and transmission pipelines, underground storage capacities and operating characteristics, heating degree-days, populations and numbers of households, and areal measures of states and metropolitan areas. The market penetration of gas distribution systems is measured by two indicators: (1) the ratio of the number of residential gas customers to the number of households in 1985 and (2) the distribution pipeline density, measured by the ratio of the 1985 distribution mileage divided by the number of households, while accounting for the effect of urban population density (using earlier econometric results). 11 refs., 1 fig., 27 tabs.

  12. FULL-SCALE TESTING OF ENHANCED MERCURY CONTROL TECHNOLOGIES FOR WET FGD SYSTEMS

    SciTech Connect (OSTI)

    D.K. McDonald; G.T. Amrhein; G.A. Kudlac; D. Madden Yurchison

    2003-05-07

    Wet flue gas desulfurization (wet FGD) systems are currently installed on about 25% of the coal-fired utility generating capacity in the U.S., representing about 15% of the number of coal-fired units. Depending on the effect of operating parameters such as mercury content of the coal, form of mercury (elemental or oxidized) in the flue gas, scrubber spray tower configuration, liquid-to-gas ratio, and slurry chemistry, FGD systems can provide cost-effective, near-term mercury emissions control options with a proven history of commercial operation. For boilers already equipped with FGD systems, the incremental cost of any vapor phase mercury removal achieved is minimal. To be widely accepted and implemented, technical approaches that improve mercury removal performance for wet FGD systems should also have low incremental costs and have little or no impact on operation and SO{sub 2} removal performance. The ultimate goal of the Full-scale Testing of Enhanced Mercury Control for Wet FGD Systems Program was to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The program was funded by the U.S. Department of Energy's National Energy Technology Laboratory, the Ohio Coal Development Office within the Ohio Department of Development, and Babcock & Wilcox. Host sites and associated support were provided by Michigan South Central Power Agency (MSCPA) and Cinergy. Field-testing was completed at two commercial coal-fired utilities with wet FGD systems: (1) MSCPA's 55 MW{sub e} Endicott Station and (2) Cinergy's 1300 MW{sub e} Zimmer Station. Testing was conducted at these two locations because of the large differences in size and wet scrubber chemistry. Endicott employs a limestone, forced oxidation (LSFO) wet FGD system, whereas Zimmer uses Thiosorbic{reg_sign} Lime (magnesium enhanced lime) and ex situ oxidation. Both locations burn Ohio bituminous coal.

  13. Strategies to diagnose and control microbial souring in natural gas storage reservoirs and produced water systems

    SciTech Connect (OSTI)

    Morris, E.A.; Derr, R.M.; Pope, D.H.

    1995-12-31

    Hydrogen sulfide production (souring) in natural gas storage reservoirs and produced water systems is a safety and environmental problem that can lead to operational shutdown when local hydrogen sulfide standards are exceeded. Systems affected by microbial souring have historically been treated using biocides that target the general microbial community. However, requirements for more environmentally friendly solutions have led to treatment strategies in which sulfide production can be controlled with minimal impact to the system and environment. Some of these strategies are based on microbial and/or nutritional augmentation of the sour environment. Through research sponsored by the Gas Research Institute (GRI) in Chicago, Illinois, methods have been developed for early detection of microbial souring in natural gas storage reservoirs, and a variety of mitigation strategies have been evaluated. The effectiveness of traditional biocide treatment in gas storage reservoirs was shown to depend heavily on the methods by which the chemical is applied. An innovative strategy using nitrate was tested and proved ideal for produced water and wastewater systems. Another strategy using elemental iodine was effective for sulfide control in evaporation ponds and is currently being tested in microbially sour natural gas storage wells.

  14. Optimization problems in natural gas transportation systems. A state-of-the-art review

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ríos-Mercado, Roger Z.; Borraz-Sánchez, Conrado

    2015-03-24

    Our paper provides a review on the most relevant research works conducted to solve natural gas transportation problems via pipeline systems. The literature reveals three major groups of gas pipeline systems, namely gathering, transmission, and distribution systems. In this work, we aim at presenting a detailed discussion of the efforts made in optimizing natural gas transmission lines.There is certainly a vast amount of research done over the past few years on many decision-making problems in the natural gas industry and, specifically, in pipeline network optimization. In this work, we present a state-of-the-art survey focusing on specific categories that include short-termmore » basis storage (line-packing problems), gas quality satisfaction (pooling problems), and compressor station modeling (fuel cost minimization problems). We also discuss both steady-state and transient optimization models highlighting the modeling aspects and the most relevant solution approaches known to date. Although the literature on natural gas transmission system problems is quite extensive, this is, to the best of our knowledge, the first comprehensive review or survey covering this specific research area on natural gas transmission from an operations research perspective. Furthermore, this paper includes a discussion of the most important and promising research areas in this field. Hence, our paper can serve as a useful tool to gain insight into the evolution of the many real-life applications and most recent advances in solution methodologies arising from this exciting and challenging research area of decision-making problems.« less

  15. Simulated coal gas MCFC power plant system verification. Final report

    SciTech Connect (OSTI)

    1998-07-30

    The objective of the main project is to identify the current developmental status of MCFC systems and address those technical issues that need to be resolved to move the technology from its current status to the demonstration stage in the shortest possible time. The specific objectives are separated into five major tasks as follows: Stack research; Power plant development; Test facilities development; Manufacturing facilities development; and Commercialization. This Final Report discusses the M-C power Corporation effort which is part of a general program for the development of commercial MCFC systems. This final report covers the entire subject of the Unocal 250-cell stack. Certain project activities have been funded by organizations other than DOE and are included in this report to provide a comprehensive overview of the work accomplished.

  16. Systems and methods for detecting a flame in a fuel nozzle of a gas turbine

    DOE Patents [OSTI]

    Kraemer, Gilbert Otto; Storey, James Michael; Lipinski, John; Mestroni, Julio Enrique; Williamson, David Lee; Marshall, Jason Randolph; Krull, Anthony

    2013-05-07

    A system may detect a flame about a fuel nozzle of a gas turbine. The gas turbine may have a compressor and a combustor. The system may include a first pressure sensor, a second pressure sensor, and a transducer. The first pressure sensor may detect a first pressure upstream of the fuel nozzle. The second pressure sensor may detect a second pressure downstream of the fuel nozzle. The transducer may be operable to detect a pressure difference between the first pressure sensor and the second pressure sensor.

  17. Preliminary Failure Modes and Effects Analysis of the US Massive Gas Injection Disruption Mitigation System Design

    SciTech Connect (OSTI)

    Lee C. Cadwallader

    2013-10-01

    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a candidate design for the ITER Disruption Mitigation System. This candidate is the Massive Gas Injection System that provides machine protection in a plasma disruption event. The FMEA was quantified with “generic” component failure rate data as well as some data calculated from operating facilities, and the failure events were ranked for their criticality to system operation.

  18. Integration and optimization of the gas removal system for hybrid-cycle OTEC power plants

    SciTech Connect (OSTI)

    Rabas, T.J.; Panchal, C.B.; Stevens, H.C. )

    1990-02-01

    A preliminary design of the noncondensible gas removal system for a 10 mWe, land-based hybrid-cycle OTEC power plant has been developed and is presented herein. This gas removal system is very different from that used for conventional power plants because of the substantially larger and continuous noncondensible gas flow rates and lower condenser pressure levels which predicate the need for higher-efficiency components. Previous OTEC studies discussed the need for multiple high-efficiency compressors with intercoolers; however, no previous design effort was devoted to the details of the intercoolers, integration and optimization of the intercoolers with the compressors, and the practical design constraints and feasibility issues of these components. The resulting gas removal system design uses centrifugal (radial) compressors with matrix-type crossflow aluminum heat exchangers as intercoolers. Once-through boiling of ammonia is used as the heat sink for the cooling and condensing of the steam-gas mixture. A computerized calculation method was developed for the performance analysis and subsystem optimization. For a specific number of compressor units and the stream arrangement, the method is used to calculate the dimensions, speeds, power requirements, and costs of all the components.

  19. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  20. Innovative Telemetry System Will Help Tap Hard-to-Reach Natural Gas Resources

    Office of Energy Efficiency and Renewable Energy (EERE)

    The commercialization of an innovative telemetry communications system developed through a U.S. Department of Energy research program will help U.S. producers tap previously hard-to-reach natural gas resources deep underground, resulting in access to additional supplies that will help enhance national energy security.

  1. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 2

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster dsplays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume II covers papers presented at sessions 5 and 6 on system for the production of synthesis gas, and on system for the production of power. All papers have been processed for inclusion in the Energy Data Base.

  2. DOE to Launch Collaborative Effort with Industry to Improve Natural Gas Systems

    Broader source: Energy.gov [DOE]

    DOE will launch a collaborative effort with industry to evaluate and scope high-impact manufacturing R&D to improve natural gas systems efficiency and leak reduction. The goal of this effort is to establish an advanced manufacturing initiative. AMO will lead this effort.

  3. Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    Venkatesan, Krishna

    2011-11-30

    The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to

  4. Improving Desulfurization to Enable Fuel Cell Utilization of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Both TDA and its project partner FuelCell Energy have suc- cessfully commercialized and ... FuelCell Energy has built numerous fuel cell plants fed by anaerobic digester gas, giving ...

  5. The RealGas and RealGasH2O Options of the TOUGH+ Code for the Simulation of Coupled Fluid and Heat Flow in Tight/Shale Gas Systems

    SciTech Connect (OSTI)

    Moridis, George; Freeman, Craig

    2013-09-30

    We developed two new EOS additions to the TOUGH+ family of codes, the RealGasH2O and RealGas . The RealGasH2O EOS option describes the non-isothermal two-phase flow of water and a real gas mixture in gas reservoirs, with a particular focus in ultra-tight (such as tight-sand and shale gas) reservoirs. The gas mixture is treated as either a single-pseudo-component having a fixed composition, or as a multicomponent system composed of up to 9 individual real gases. The RealGas option has the same general capabilities, but does not include water, thus describing a single-phase, dry-gas system. In addition to the standard capabilities of all members of the TOUGH+ family of codes (fully-implicit, compositional simulators using both structured and unstructured grids), the capabilities of the two codes include: coupled flow and thermal effects in porous and/or fractured media, real gas behavior, inertial (Klinkenberg) effects, full micro-flow treatment, Darcy and non-Darcy flow through the matrix and fractures of fractured media, single- and multi-component gas sorption onto the grains of the porous media following several isotherm options, discrete and fracture representation, complex matrix-fracture relationships, and porosity-permeability dependence on pressure changes. The two options allow the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in problems of geologic storage of greenhouse gas mixtures, and of geothermal reservoirs with multi-component condensable (H2O and CH4) and non-condensable gas mixtures. The codes are verified against available analytical and semi-analytical solutions. Their capabilities are demonstrated in a series of problems of increasing complexity, ranging from isothermal flow in simpler 1D and 2D conventional gas reservoirs, to non-isothermal gas flow in 3D fractured shale gas reservoirs involving 4 types of fractures, micro-flow, non-Darcy flow and gas

  6. Levelized life-cycle costs for four residue-collection systems and four gas-production systems

    SciTech Connect (OSTI)

    Thayer, G.R.; Rood, P.L.; Williamson, K.D. Jr.; Rollett, H.

    1983-01-01

    Technology characterizations and life-cycle costs were obtained for four residue-collection systems and four gas-production systems. All costs are in constant 1981 dollars. The residue-collection systems were cornstover collection, wheat-straw collection, soybean-residue collection, and wood chips from forest residue. The life-cycle costs ranged from $19/ton for cornstover collection to $56/ton for wood chips from forest residues. The gas-production systems were low-Btu gas from a farm-size gasifier, solar flash pyrolysis of biomass, methane from seaweed farms, and hydrogen production from bacteria. Life-cycle costs ranged from $3.3/10/sup 6/ Btu for solar flash pyrolysis of biomass to $9.6/10/sup 6/ Btu for hydrogen from bacteria. Sensitivity studies were also performed for each system. The sensitivity studies indicated that fertilizer replacement costs were the dominate costs for the farm-residue collection, while residue yield was most important for the wood residue. Feedstock costs were most important for the flash pyrolysis. Yields and capital costs are most important for the seaweed farm and the hydrogen from bacteria system.

  7. Cryogenic system with GM cryocooler for krypton, xenon separation from hydrogen-helium purge gas

    SciTech Connect (OSTI)

    Chu, X. X.; Zhang, D. X.; Qian, Y.; Liu, W.; Zhang, M. M.; Xu, D.

    2014-01-29

    In the thorium molten salt reactor (TMSR), fission products such as krypton, xenon and tritium will be produced continuously in the process of nuclear fission reaction. A cryogenic system with a two stage GM cryocooler was designed to separate Kr, Xe, and H{sub 2} from helium purge gas. The temperatures of two stage heat exchanger condensation tanks were maintained at about 38 K and 4.5 K, respectively. The main fluid parameters of heat transfer were confirmed, and the structural heat exchanger equipment and cold box were designed. Designed concentrations after cryogenic separation of Kr, Xe and H{sub 2} in helium recycle gas are less than 1 ppb.

  8. A desiccant/steam-injected gas-turbine industrial cogeneration system

    SciTech Connect (OSTI)

    Jody, B.J.; Daniels, E.J.; Karvelas, D.E.; Teotia, A.P.S.

    1993-12-31

    An integrated desiccant/steam-injected gas-turbine system was evaluated as an industrial cogenerator for the production of electricity and dry, heated air for product drying applications. The desiccant can be regenerated using the heated, compressed air leaving the compressor. The wet stream leaves the regenerator at a lower temperature than when it entered the desiccant regenerator, but with little loss of energy. The wet stream returns to the combustion chamber of the gas-turbine system after preheating by exchanging heat with the turbine exhaust strewn. Therefore, the desiccant is regenerated virtually energy-free. In the proposed system, the moisture-laden air exiting the desiccant is introduced into the combustion chamber of the gas-turbine power system. This paper discusses various possible design configurations, the impact of increased moisture content on the combustion process, the pressure drop across the desiccant regenerator, and the impact of these factors on the overall performance of the integrated system. A preliminary economic analysis including estimated potential energy savings when the system is used in several drying applications, and equipment and operating costs are also presented.

  9. A desiccant/steam-injected gas-turbine industrial cogeneration system

    SciTech Connect (OSTI)

    Jody, B.J.; Daniels, E.J.; Karvelas, D.E.; Teotia, A.P.S.

    1993-01-01

    An integrated desiccant/steam-injected gas-turbine system was evaluated as an industrial cogenerator for the production of electricity and dry, heated air for product drying applications. The desiccant can be regenerated using the heated, compressed air leaving the compressor. The wet stream leaves the regenerator at a lower temperature than when it entered the desiccant regenerator, but with little loss of energy. The wet stream returns to the combustion chamber of the gas-turbine system after preheating by exchanging heat with the turbine exhaust strewn. Therefore, the desiccant is regenerated virtually energy-free. In the proposed system, the moisture-laden air exiting the desiccant is introduced into the combustion chamber of the gas-turbine power system. This paper discusses various possible design configurations, the impact of increased moisture content on the combustion process, the pressure drop across the desiccant regenerator, and the impact of these factors on the overall performance of the integrated system. A preliminary economic analysis including estimated potential energy savings when the system is used in several drying applications, and equipment and operating costs are also presented.

  10. Cooling system having reduced mass pin fins for components in a gas turbine engine

    DOE Patents [OSTI]

    Lee, Ching-Pang; Jiang, Nan; Marra, John J

    2014-03-11

    A cooling system having one or more pin fins with reduced mass for a gas turbine engine is disclosed. The cooling system may include one or more first surfaces defining at least a portion of the cooling system. The pin fin may extend from the surface defining the cooling system and may have a noncircular cross-section taken generally parallel to the surface and at least part of an outer surface of the cross-section forms at least a quartercircle. A downstream side of the pin fin may have a cavity to reduce mass, thereby creating a more efficient turbine airfoil.

  11. Progress report on a fully automatic Gas Tungsten Arc Welding (GTAW) system development

    SciTech Connect (OSTI)

    Daumeyer, G.J. III

    1994-12-01

    A plan to develop a fully automatic gas tungsten arc welding (GTAW) system that will utilize a vision-sensing computer (which will provide in-process feedback control) is presently in work. Evaluations of different technological aspects and system design requirements continue. This report summaries major activities in the plan`s successful progress. The technological feasibility of producing the fully automated GTAW system has been proven. The goal of this process development project is to provide a production-ready system within the shortest reasonable time frame.

  12. ENERGY EFFICIENT THERMAL MANAGEMENT FOR NATURAL GAS ENGINE AFTERTREATMENT VIA ACTIVE FLOW CONTROL

    SciTech Connect (OSTI)

    David K. Irick; Ke Nguyen

    2004-04-01

    The project is focused on the development of an energy efficient aftertreatment system capable of reducing NOx and methane by 90% from lean-burn natural gas engines by applying active exhaust flow control. Compared to conventional passive flow-through reactors, the proposed scheme cuts supplemental energy by 50%-70%. The system consists of a Lean NOx Trap (LNT) system and an oxidation catalyst. Through alternating flow control, a major amount of engine exhaust flows through a large portion of the LNT system in the absorption mode, while a small amount of exhaust goes through a small portion of the LNT system in the regeneration or desulfurization mode. By periodically reversing the exhaust gas flow through the oxidation catalyst, a higher temperature profile is maintained in the catalyst bed resulting in greater efficiency of the oxidation catalyst at lower exhaust temperatures. The project involves conceptual design, theoretical analysis, computer simulation, prototype fabrication, and empirical studies. This report details the progress during the first twelve months of the project. The primary activities have been to develop the bench flow reactor system, develop the computer simulation and modeling of the reverse-flow oxidation catalyst, install the engine into the test cell, and begin design of the LNT system.

  13. Energy Efficient Thermal Management for Natural Gas Engine Aftertreatment via Active Flow Control

    SciTech Connect (OSTI)

    David K. Irick; Ke Nguyen; Vitacheslav Naoumov; Doug Ferguson

    2006-04-01

    The project is focused on the development of an energy efficient aftertreatment system capable of reducing NOx and methane by 90% from lean-burn natural gas engines by applying active exhaust flow control. Compared to conventional passive flow-through reactors, the proposed scheme cuts supplemental energy by 50%-70%. The system consists of a Lean NOx Trap (LNT) system and an oxidation catalyst. Through alternating flow control, a major amount of engine exhaust flows through a large portion of the LNT system in the absorption mode, while a small amount of exhaust goes through a small portion of the LNT system in the regeneration or desulfurization mode. By periodically reversing the exhaust gas flow through the oxidation catalyst, a higher temperature profile is maintained in the catalyst bed resulting in greater efficiency of the oxidation catalyst at lower exhaust temperatures. The project involves conceptual design, theoretical analysis, computer simulation, prototype fabrication, and empirical studies. This report details the progress during the first twelve months of the project. The primary activities have been to develop the bench flow reactor system, develop the computer simulation and modeling of the reverse-flow oxidation catalyst, install the engine into the test cell, and begin design of the LNT system.

  14. Energy Efficient Thermal Management for Natural Gas Engine Aftertreatment via Active Flow Control

    SciTech Connect (OSTI)

    David K. Irick; Ke Nguyen; Vitacheslav Naoumov; Doug Ferguson

    2005-04-01

    The project is focused on the development of an energy efficient aftertreatment system capable of reducing NOx and methane by 90% from lean-burn natural gas engines by applying active exhaust flow control. Compared to conventional passive flow-through reactors, the proposed scheme cuts supplemental energy by 50%-70%. The system consists of a Lean NOx Trap (LNT) system and an oxidation catalyst. Through alternating flow control, a major amount of engine exhaust flows through a large portion of the LNT system in the absorption mode, while a small amount of exhaust goes through a small portion of the LNT system in the regeneration or desulfurization mode. By periodically reversing the exhaust gas flow through the oxidation catalyst, a higher temperature profile is maintained in the catalyst bed resulting in greater efficiency of the oxidation catalyst at lower exhaust temperatures. The project involves conceptual design, theoretical analysis, computer simulation, prototype fabrication, and empirical studies. This report details the progress during the first twelve months of the project. The primary activities have been to develop the bench flow reactor system, develop the computer simulation and modeling of the reverse-flow oxidation catalyst, install the engine into the test cell, and begin design of the LNT system.

  15. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 1

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J.

    1987-08-01

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster displays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume I covers information presented at sessions 1 through 4 on systems for the production of Co-products and industrial fuel gas, environmental projects, and components and materials. Individual papers have been processed for the Energy Data Base.

  16. CALCULATION OF DEMONSTRATION BULK VITRIFICATION SYSTEM MELTER INLEAKAGE AND OFF-GAS GENERATION RATE

    SciTech Connect (OSTI)

    MAY TH

    2008-04-16

    The River Protection Project (RPP) mission is to safely store, retrieve, treat, immobilize, and dispose of the Hanford Site tank waste. The Demonstration Bulk Vitrification System (DBVS) is a research and development project whose objective is to demonstrate the suitability of Bulk Vitrification treatment technology waste form for disposing of low-activity waste from the Tank Farms. The objective of this calculation is to determine the DBVS melter inleakage and off-gas generation rate based on full scale testing data from 38D. This calculation estimates the DBVS melter in leakage and gas generation rate based on test data. Inleakage is estimated before the melt was initiated, at one point during the melt, and at the end of the melt. Maximum gas generation rate is also estimated.

  17. Expert system for identification of simultaneous and sequential reactor fuel failures with gas tagging

    DOE Patents [OSTI]

    Gross, K.C.

    1994-07-26

    Failure of a fuel element in a nuclear reactor core is determined by a gas tagging failure detection system and method. Failures are catalogued and characterized after the event so that samples of the reactor's cover gas are taken at regular intervals and analyzed by mass spectroscopy. Employing a first set of systematic heuristic rules which are applied in a transformed node space allows the number of node combinations which must be processed within a barycentric algorithm to be substantially reduced. A second set of heuristic rules treats the tag nodes of the most recent one or two leakers as background'' gases, further reducing the number of trial node combinations. Lastly, a fuzzy'' set theory formalism minimizes experimental uncertainties in the identification of the most likely volumes of tag gases. This approach allows for the identification of virtually any number of sequential leaks and up to five simultaneous gas leaks from fuel elements. 14 figs.

  18. Expert system for identification of simultaneous and sequential reactor fuel failures with gas tagging

    DOE Patents [OSTI]

    Gross, Kenny C.

    1994-01-01

    Failure of a fuel element in a nuclear reactor core is determined by a gas tagging failure detection system and method. Failures are catalogued and characterized after the event so that samples of the reactor's cover gas are taken at regular intervals and analyzed by mass spectroscopy. Employing a first set of systematic heuristic rules which are applied in a transformed node space allows the number of node combinations which must be processed within a barycentric algorithm to be substantially reduced. A second set of heuristic rules treats the tag nodes of the most recent one or two leakers as "background" gases, further reducing the number of trial node combinations. Lastly, a "fuzzy" set theory formalism minimizes experimental uncertainties in the identification of the most likely volumes of tag gases. This approach allows for the identification of virtually any number of sequential leaks and up to five simultaneous gas leaks from fuel elements.

  19. Desulfurization of coal: enhanced selectivity using phase transfer catalysts. Quarterly report, March 1 - May 31, 1996

    SciTech Connect (OSTI)

    Palmer, S.R.; Hippo, E.J.

    1996-12-31

    Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development in viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions that otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidation for selective sulfur oxidation are also being studied. If successful, this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal.

  20. Selection of natural Gas Fired Advanced Turbine Systems (GFATS) program - Task 3. Topical report

    SciTech Connect (OSTI)

    1994-06-01

    Research continued on natural gas-fired turbines.The objective of Task 3 was to perform initial trade studies and select one engine system (Gas-Fired Advanced Turbine System [GFATS]) that the contractor could demonstrate, at full scale, in the 1998 to 2000 time frame. This report describes the results of the selection process. This task, including Allison internal management reviews of the selected system, has been completed. Allison`s approach to ATS is to offer an engine family that is based on the newest T406 high technology engine. This selection was based on a number of parameters including return on investment (ROI), internal rate of return (IRR) market size and potential sales into that market. This base engine family continues a history at Allison of converting flight engine products to industrial use.

  1. Control Sensitivity Study for a Hybrid Fuel Cell/Gas Turbine System

    SciTech Connect (OSTI)

    Banta, Larry; Absten, Jason; Tsai, Alex; Gemmen, R.S.; Tucker, D.A.

    2008-06-01

    The National Energy Technology Laboratory (NETL) has developed a hardware simulator to test the operating characteristics of Solid Oxide Fuel Cell/Gas Turbine (SOFC/GT) hybrid systems. The Hybrid Performance (HyPer) simulator has been described previously, and has contributed to the understanding of SOFC/GT system operation. HyPer contains not only the requisite elements of gas turbine/compressor/generator, recuperator, combustor, and associated piping, but also several air flow control valves that are proposed as system control mechanisms. It is necessary to know how operation of these valves affects the various entities such as cathode air flow, turbine speed, and various temperatures important to the safe and efficient operation of fuel cell/gas turbine hybrid systems. To determine the interactions among key variables, a series of experiments was performed in which the effect of modulating each of the key manipulated variables was recorded. This document outlines the test methods used and presents some of the data from those tests, along with analysis and interpretation of that data in the context of control system design.

  2. Advanced Multi-Effect Distillation System for Desalination Using Waste Heat fromGas Brayton Cycles

    SciTech Connect (OSTI)

    Haihua Zhao; Per F. Peterson

    2012-10-01

    Generation IV high temperature reactor systems use closed gas Brayton Cycles to realize high thermal efficiency in the range of 40% to 60%. The waste heat is removed through coolers by water at substantially greater average temperature than in conventional Rankine steam cycles. This paper introduces an innovative Advanced Multi-Effect Distillation (AMED) design that can enable the production of substantial quantities of low-cost desalinated water using waste heat from closed gas Brayton cycles. A reference AMED design configuration, optimization models, and simplified economics analysis are presented. By using an AMED distillation system the waste heat from closed gas Brayton cycles can be fully utilized to desalinate brackish water and seawater without affecting the cycle thermal efficiency. Analysis shows that cogeneration of electricity and desalinated water can increase net revenues for several Brayton cycles while generating large quantities of potable water. The AMED combining with closed gas Brayton cycles could significantly improve the sustainability and economics of Generation IV high temperature reactors.

  3. Transformative Reduction of Transportation Greenhouse Gas Emissions. Opportunities for Change in Technologies and Systems

    SciTech Connect (OSTI)

    Vimmerstedt, Laura; Brown, Austin; Newes, Emily; Markel, Tony; Schroeder, Alex; Zhang, Yimin; Chipman, Peter; Johnson, Shawn

    2015-04-30

    The transportation sector is changing, influenced by concurrent, ongoing, dynamic trends that could dramatically affect the future energy landscape, including effects on the potential for greenhouse gas emissions reductions. Battery cost reductions and improved performance coupled with a growing number of electric vehicle model offerings are enabling greater battery electric vehicle market penetration, and advances in fuel cell technology and decreases in hydrogen production costs are leading to initial fuel cell vehicle offerings. Radically more efficient vehicles based on both conventional and new drivetrain technologies reduce greenhouse gas emissions per vehicle-mile. Net impacts also depend on the energy sources used for propulsion, and these are changing with increased use of renewable energy and unconventional fossil fuel resources. Connected and automated vehicles are emerging for personal and freight transportation systems and could increase use of low- or non-emitting technologies and systems; however, the net effects of automation on greenhouse gas emissions are uncertain. The longstanding trend of an annual increase in transportation demand has reversed for personal vehicle miles traveled in recent years, demonstrating the possibility of lower-travel future scenarios. Finally, advanced biofuel pathways have continued to develop, highlighting low-carbon and in some cases carbon-negative fuel pathways. We discuss the potential for transformative reductions in petroleum use and greenhouse gas emissions through these emerging transportation-sector technologies and trends and present a Clean Transportation Sector Initiative scenario for such reductions, which are summarized in Table ES-1.

  4. Pressurized solid oxide fuel cell/gas turbine combined cycle systems

    SciTech Connect (OSTI)

    George, R.A.

    1997-12-31

    Over the last 10 years, Westinghouse Electric Corporation has made great strides in advancing tubular solid oxide fuel cell (SOFC) technology towards commercialization by the year 2001. In 1993, Westinghouse initiated a program to develop pressurized solid oxide fuel cell/gas turbine (PSOFC/GT) combined cycle power systems because of the ultra-high electrical efficiencies, 60-75% (net AC/LHV CH4), inherent with these systems. This paper will discuss SOFC technology advancements in recent years, and the final phase development program which will focus on the development and demonstration of PSOFC/GT power systems for distributed power applications.

  5. ART CCIM Phase II-A Off-Gas System Evaluation Test Plan

    SciTech Connect (OSTI)

    Nick Soelberg; Jay Roach

    2009-01-01

    This test plan defines testing to be performed using the Idaho National Laboratory (INL) engineering-scale cold crucible induction melter (CCIM) test system for Phase II-A of the Advanced Remediation Technologies (ART) CCIM Project. The multi-phase ART-CCIM Project is developing a conceptual design for replacing the joule-heated melter (JHM) used to treat high level waste (HLW) in the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS) with a cold crucible induction melter. The INL CCIM test system includes all feed, melter off-gas control, and process control subsystems needed for fully integrated operation and testing. Testing will include operation of the melter system while feeding a non-radioactive slurry mixture prepared to simulate the same type of waste feed presently being processed in the DWPF. Process monitoring and sample collection and analysis will be used to characterize the off-gas composition and properties, and to show the fate of feed constituents, to provide data that shows how the CCIM retrofit conceptual design can operate with the existing DWPF off-gas control system.

  6. Thermal Analysis of of Near-Isothermal Compressed Gas Energy Storage System

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Odukomaiya, Adewale; Abu-Heiba, Ahmad; Gluesenkamp, Kyle R.; Abdelaziz, Omar; Jackson, Roderick K.; Daniel, Claus; Graham, Samuel; Momen, Ayyoub M.

    2016-07-25

    In this paper, alternative system configurations for a novel Ground-Level Integrated Diverse Energy Storage (GLIDES) system, which can store energy via input of electricity and heat and deliver dispatchable electricity, is presented. The proposed system is low-cost and hybridizes compressed air and pumped hydro storage approaches that will allow for the off-peak storage of intermittent renewable energy for use during peak times. This study reveals that implementing direct-contact low grade heat exchange via sprayed falling droplets to cool the gas during charging (compression) and warm the gas during discharging (expansion) can be achieved through a secondary recirculating loop of liquid.more » This study shows that if the recirculating liquid loop is pre-conditioned with waste-heat prior to spraying during gas expansion and considering all the round trip conversion losses from standard 120 V 60 HZ electricity input and output with utilization of low grade heat at 90 C the alternative system design leads to a 16% boost in round trip efficiency of the electricity storage to elec = 82% with an energy density of ED = 3.59 MJ/m3.« less

  7. Clean coal reference plants: Pulverized coal boiler with flue gas desulfurization. Topical report

    SciTech Connect (OSTI)

    1995-09-01

    The Clean Coal Technology Demonstration Program (CCT) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of full-scale facilities. The goal of the program is to provide the U.S. energy marketplace with a number of advanced, more efficient, and environmentally responsive coal-using technologies. To achieve this goal, a multiphased effort consisting of five separate solicitations has been completed. The Morgantown Energy Technology Center (METC) has the responsibility for monitoring the CCT Projects within certain technology categories, which, in general, correspond to the center`s areas of technology development. Primarily the categories of METC CCT projects are: atmospheric fluid bed combustion, pressurized fluidized bed combustion, integrated gasification combined cycle, mild gasification, and industrial applications.

  8. Screening of zinc-based sorbents for hot-gas desulfurization

    SciTech Connect (OSTI)

    Joong B. Lee; Chong K. Ryu; Chang K. Yi; Sung H. Jo; Sung H. Kim

    2008-03-15

    Highly reactive and attrition-resistant ZnO-based sorbents that are suitable for bubbling fluidized-bed reactors can be produced using the spray-drying method. Most of the ZnO-based sorbents prepared here (ZAC-X, X = 18N-25N) satisfy the physical and chemical criteria for bubbling fluidized-bed application (spherical shape, average particle size, 90-110 {mu}m; size distribution, 40-230 {mu}m; bulk density, 0.9-1.0 g/mL; attrition index (AI), 40-80%; sulfur sorption capacity, 14-17 wt %; sorbent use, 70-80%). The performance test of the ZAC-C sorbent at Korea Institute of Energy Research (KIER) with a bubbling fluidized-bed for 70 h also demonstrated that it had good sulfidation and regeneration performance (11 wt % sorption capacity and 52% sorbent use) as well as reasonable attrition resistance (1.1% attrition loss for 70 h). 14 refs., 7 figs., 6 tabs.

  9. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect (OSTI)

    Rizzo, Jeffrey J.

    2010-04-30

    cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  10. Device to lower NOx in a gas turbine engine combustion system

    DOE Patents [OSTI]

    Laster, Walter R; Schilp, Reinhard; Wiebe, David J

    2015-02-24

    An emissions control system for a gas turbine engine including a flow-directing structure (24) that delivers combustion gases (22) from a burner (32) to a turbine. The emissions control system includes: a conduit (48) configured to establish fluid communication between compressed air (22) and the combustion gases within the flow-directing structure (24). The compressed air (22) is disposed at a location upstream of a combustor head-end and exhibits an intermediate static pressure less than a static pressure of the combustion gases within the combustor (14). During operation of the gas turbine engine a pressure difference between the intermediate static pressure and a static pressure of the combustion gases within the flow-directing structure (24) is effective to generate a fluid flow through the conduit (48).

  11. A natural-gas fuel processor for a residential fuel cell system.

    SciTech Connect (OSTI)

    Adachi, H.; Ahmed, S.; Lee, S. H. D.; Papadias, D.; Ahluwalia, R. K.; Bendert, J. C.; Kanner, S. A.; Yamazaki, Y.; Japan Institute of Energy

    2009-03-01

    A system model was used to develop an autothermal reforming fuel processor to meet the targets of 80% efficiency (higher heating value) and start-up energy consumption of less than 500 kJ when operated as part of a 1-kWe natural-gas fueled fuel cell system for cogeneration of heat and power. The key catalytic reactors of the fuel processor--namely the autothermal reformer, a two-stage water gas shift reactor and a preferential oxidation reactor--were configured and tested in a breadboard apparatus. Experimental results demonstrated a reformate containing {approx} 48% hydrogen (on a dry basis and with pure methane as fuel) and less than 5 ppm CO. The effects of steam-to-carbon and part load operations were explored.

  12. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  13. SAS Output

    U.S. Energy Information Administration (EIA) Indexed Site

    Flue Gas Desulfurization Systems Electrostatic Precipitators Baghouses Select Catalytic and Non-Catalytic Reduction Systems Activated Carbon Injection Systems Direct Sorbent ...

  14. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  15. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  16. The integrated melter off-gas treatment systems at the West Valley Demonstration Project

    SciTech Connect (OSTI)

    Vance, R.F.

    1991-12-01

    The West Valley Demonstration project was established by an act of Congress in 1980 to solidify the high level radioactive liquid wastes produced from operation of the Western New York Nuclear Services Center from 1966 to 1972. The waste will be solidified as borosilicate glass. This report describes the functions, the controlling design criteria, and the resulting design of the melter off-gas treatment systems.

  17. Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications - Volume I

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Micropower and Fuel Cell/Gas Turbine Hybrid Systems in Industrial Applications Volume I: Main Text Subcontract No. 85X-TA009V Final Report to Lockheed Martin Energy Research Corporation and the DOE Office of Industrial Technologies January 2000 Notice: This report was prepared by Arthur D. Little for the account of Lockheed Martin Energy Research Corporation and the DOE's Office of Industrial Technologies. This report represents Arthur D. Little's best judgment in light of information made

  18. Intergrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High Enthalpy, Extensional Geothermal Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrating Magnetotellurics, Soil Gas Geochemistry and Structural Analysis to Identify Hidden, High-Enthalpy, Extensional Geothermal Systems Principal Investigator: Philip E. Wannamaker University of Utah Energy & Geoscience Institute 423 Wakara Way, Ste 300 Salt Lake City, UT 84108 pewanna@egi.utah.edu April 24, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. Track1: Geophysics McGinness Hills, NV October, 2011 2 | US DOE

  19. UNDERSTANDING METHANE EMISSIONS SOURCES AND VIABLE MITIGATION MEASURES IN THE NATURAL GAS TRANSMISSION SYSTEMS: RUSSIAN AND U.S. EXPERIENCE

    SciTech Connect (OSTI)

    Ishkov, A.; Akopova, Gretta; Evans, Meredydd; Yulkin, Grigory; Roshchanka, Volha; Waltzer, Suzie; Romanov, K.; Picard, David; Stepanenko, O.; Neretin, D.

    2011-10-01

    This article will compare the natural gas transmission systems in the U.S. and Russia and review experience with methane mitigation technologies in the two countries. Russia and the United States (U.S.) are the world's largest consumers and producers of natural gas, and consequently, have some of the largest natural gas infrastructure. This paper compares the natural gas transmission systems in Russia and the U.S., their methane emissions and experiences in implementing methane mitigation technologies. Given the scale of the two systems, many international oil and natural gas companies have expressed interest in better understanding the methane emission volumes and trends as well as the methane mitigation options. This paper compares the two transmission systems and documents experiences in Russia and the U.S. in implementing technologies and programs for methane mitigation. The systems are inherently different. For instance, while the U.S. natural gas transmission system is represented by many companies, which operate pipelines with various characteristics, in Russia predominately one company, Gazprom, operates the gas transmission system. However, companies in both countries found that reducing methane emissions can be feasible and profitable. Examples of technologies in use include replacing wet seals with dry seals, implementing Directed Inspection and Maintenance (DI&M) programs, performing pipeline pump-down, applying composite wrap for non-leaking pipeline defects and installing low-bleed pneumatics. The research methodology for this paper involved a review of information on methane emissions trends and mitigation measures, analytical and statistical data collection; accumulation and analysis of operational data on compressor seals and other emission sources; and analysis of technologies used in both countries to mitigate methane emissions in the transmission sector. Operators of natural gas transmission systems have many options to reduce natural gas losses

  20. Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application

    SciTech Connect (OSTI)

    Ashok K. Anand

    2005-12-16

    This study identifies vital gas turbine (GT) parameters and quantifies their influence in meeting the DOE Turbine Program overall Integrated Gasification Combined Cycle (IGCC) plant goals of 50% net HHV efficiency, $1000/kW capital cost, and low emissions. The project analytically evaluates GE advanced F class air cooled technology level gas turbine conceptual cycle designs and determines their influence on IGCC plant level performance including impact of Carbon capture. This report summarizes the work accomplished in each of the following six Tasks. Task 1.0--Overall IGCC Plant Level Requirements Identification: Plant level requirements were identified, and compared with DOE's IGCC Goal of achieving 50% Net HHV Efficiency and $1000/KW by the Year 2008, through use of a Six Sigma Quality Functional Deployment (QFD) Tool. This analysis resulted in 7 GT System Level Parameters as the most significant. Task 2.0--Requirements Prioritization/Flow-Down to GT Subsystem Level: GT requirements were identified, analyzed and prioritized relative to achieving plant level goals, and compared with the flow down of power island goals through use of a Six Sigma QFD Tool. This analysis resulted in 11 GT Cycle Design Parameters being selected as the most significant. Task 3.0--IGCC Conceptual System Analysis: A Baseline IGCC Plant configuration was chosen, and an IGCC simulation analysis model was constructed, validated against published performance data and then optimized by including air extraction heat recovery and GE steam turbine model. Baseline IGCC based on GE 207FA+e gas turbine combined cycle has net HHV efficiency of 40.5% and net output nominally of 526 Megawatts at NOx emission level of 15 ppmvd{at}15% corrected O2. 18 advanced F technology GT cycle design options were developed to provide performance targets with increased output and/or efficiency with low NOx emissions. Task 4.0--Gas Turbine Cycle Options vs. Requirements Evaluation: Influence coefficients on 4 key

  1. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  2. Method and apparatus for removing non-condensible gas from a working fluid in a binary power system

    DOE Patents [OSTI]

    Mohr, Charles M.; Mines, Gregory L.; Bloomfield, K. Kit

    2002-01-01

    Apparatus for removing non-condensible gas from a working fluid utilized in a thermodynamic system comprises a membrane having an upstream side operatively connected to the thermodynamic system so that the upstream side of the membrane receives a portion of the working fluid. The first membrane separates the non-condensible gas from the working fluid. A pump operatively associated with the membrane causes the portion of the working fluid to contact the membrane and to be returned to the thermodynamic system.

  3. Corrosion testing in the flue gas cleaning and condensation systems in Swedish waste incineration plants

    SciTech Connect (OSTI)

    Wallen, B.; Bergqvist, A.; Nordstroem, J.

    1994-12-31

    Test racks containing creviced, welded coupons of stainless steels, nickel base alloys and titanium have been exposed in various parts of the gas cleaning systems in three municipal waste incineration plants. The flue gases were rich in hydrogen halides and the environments in the cleaning systems were very corrosive causing mainly crevice and pitting corrosion. The best corrosion resistance was shown by the superaustenitic stainless steel S32654 and the nickel base alloys N10276 and N06022. Titanium performed badly and was attacked by excessive uniform corrosion.

  4. Economic comparison of clean coal generating technologies with natural gas-combined cycle systems

    SciTech Connect (OSTI)

    Sebesta, J.J.; Hoskins, W.W. )

    1990-01-01

    This paper reports that there are four combustion technologies upon which U.S. electric utilities are expected to rely for the majority of their future power generating needs. These technologies are pulverized coal- fired combustion (PC); coal-fired fluidized bed combustion (AFBC); coal gasification, combined cycle systems (CGCC); and natural gas-fired combined cycle systems (NGCC). The engineering and economic parameters which affect the choice of a technology include capital costs, operating and maintenance costs, fuel costs, construction schedule, process risk, environmental and site impacts, fuel efficiency and flexibility, plant availability, capacity factors, timing of startup, and the importance of utility economic and financial factors.

  5. Cryogenic & Gas System Piping Pressure Tests (A Collection of PT Permits)

    SciTech Connect (OSTI)

    Rucinski, Russell A.; /Fermilab

    2002-08-22

    This engineering note is a collection of pipe pressure testing documents for various sections of piping for the D-Zero cryogenic and gas systems. High pressure piping must conform with FESHM chapter 5031.1. Piping lines with ratings greater than 150 psig have a pressure test done before the line is put into service. These tests require the use of pressure testing permits. It is my intent that all pressure piping over which my group has responsibility conforms to the chapter. This includes the liquid argon and liquid helium and liquid nitrogen cryogenic systems. It also includes the high pressure air system, and the high pressure gas piping of the WAMUS and MDT gas systems. This is not an all inclusive compilation of test documentation. Some piping tests have their own engineering note. Other piping section test permits are included in separate safety review documents. So if it isn't here, that doesn't mean that it wasn't tested. D-Zero has a back up air supply system to add reliability to air compressor systems. The system includes high pressure piping which requires a review per FESHM 5031.1. The core system consists of a pressurized tube trailer, supply piping into the building and a pressure reducing regulator tied into the air compressor system discharge piping. Air flows from the trailer if the air compressor discharge pressure drops below the regulator setting. The tube trailer is periodically pumped back up to approximately 2000 psig. A high pressure compressor housed in one of the exterior buildings is used for that purpose. The system was previously documented, tested and reviewed for Run I, except for the recent addition of piping to and from the high pressure compressor. The following documents are provided for review of the system: (1) Instrument air flow schematic, drg. 3740.000-ME-273995 rev. H; (2) Component list for air system; (3) Pressure testing permit for high pressure piping; (4) Documentation from Run I contained in D-Zero Engineering note

  6. Evaluation of sulfur-reducing microorganisms for organic desulfurization. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Miller, K.W.

    1991-12-31

    Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

  7. Application of systems engineering techniques (reliability, availability, maintainability, and dollars) to the Gas Centrifuge Enrichment Plant

    SciTech Connect (OSTI)

    Boylan, J.G.; DeLozier, R.C.

    1982-01-01

    The systems engineering function for the Gas Centrifuge Enrichment Plant (GCEP) covers system requirements definition, analyses, verification, technical reviews, and other system efforts necessary to assure good balance of performance, safety, cost, and scheduling. The systems engineering function will support the design, installation, start-up, and operational phases of GCEP. The principal objectives of the systems engineering function are to: assure that the system requirements of the GCEP process are adequately specified and documented and that due consideration and emphasis are given to all aspects of the project; provide system analyses of the designs as they progress to assure that system requirements are met and that GCEP interfaces are compatible; assist in the definition of programs for the necessary and sufficient verification of GCEP systems; and integrate reliability, maintainability, logistics, safety, producibility, and other related specialties into a total system effort. This paper addresses the GCEP reliability, availability, maintainability, and dollars (RAM dollars) analyses which are the primary systems engineering tools for the development and implementation of trade-off studies. These studies are basic to reaching cost-effective project decisions. The steps necessary to achieve optimum cost-effective design are shown.

  8. Integrated Combined Heat and Power/Advanced Reciprocating Internal Combustion Engine System for Landfill Gas to Power Applications

    SciTech Connect (OSTI)

    2009-02-01

    Gas Technology Institute will collaborate with Integrated CHP Systems Corporation, West Virginia University, Vronay Engineering Services, KAR Engineering Associates, Pioneer Air Systems, and Energy Concepts Company to recover waste heat from reciprocating engines. The project will integrate waste heat recovery along with gas clean-up technology system improvements. This will address fuel quality issues that have hampered expanded use of opportunity fuels such as landfill gas, digester biogas, and coal mine methane. This will enable increased application of CHP using renewable and domestically derived opportunity fuels.

  9. Investigation of austenitic alloys for advanced heat recovery and hot gas cleanup systems

    SciTech Connect (OSTI)

    Swindeman, R.W.; Ren, W.

    1996-06-01

    The objective of the research is to provide databases and design criteria to assist in the selection of optimum alloys for construction of components needed to contain process streams in advanced heat recovery and hot-gas cleanup systems. Typical components include: steam line piping and superheater tubing for low emission boilers (600 to 700{degrees}C), heat exchanger tubing for advanced steam cycles and topping cycle systems (650 to 800{degrees}C), foil materials for recuperators, on advanced turbine systems (700 to 750{degrees}C), and tubesheets for barrier filters, liners for piping, cyclones, and blowback system tubing for hot-gas cleanup systems (850 to 1000{degrees}C). The materials being examined fall into several classes, depending on which of the advanced heat recovery concepts is of concern. These classes include martensitic steels for service to 650{degrees}C, lean stainless steels and modified 25Cr-30Ni steels for service to 700{degrees}C, modified 25Cr-20Ni steels for service to 900{degrees}C, and high Ni-Cr-Fe or Ni-Cr-Co-Fe alloys for service to 1000{degrees}C.

  10. Gas production and behavior in the coolant of the SP-100 Space Nuclear Power System

    SciTech Connect (OSTI)

    McGhee, J.M.

    1989-08-01

    The radiologic generation and subsequent behavior of helium gas in the lithium coolant of SP-100 class space nuclear power reactors was investigated analytically in a two part study. Part One of the study consisted of a calculation of coolant radiologic helium gas production rates in a SP-100 class reactor using the discrete ordinates code TWODANT. Cross sections were developed from ENDF/B-V data via the MATXS6s master cross section library. Cross sections were self shielded assuming one homogeneous core region, and doppler broadened to 1300 K using the cross section preparation code TRANSX. Calculations were performed using an S{sub 4}/P{sub 1} approximation and 80 neutron energy groups. Part Two of the study consisted of a theoretical investigation into the behavior of helium gas in the primary loop of lithium cooled space reactors. The SP-100 space power system was used as a representative of such a system. Topics investigated included: (1) heterogeneous and homogeneous nucleation; (2) bubble growth/collapse by diffusion, mechanical temperature/pressure effects, and coalescence; and, (3) the effects on bubble distribution of microgravity, magnetic fields, and inertially induced buoyancy. 104 refs., 78 figs., 28 tabs.

  11. Study on systems based on coal and natural gas for producing dimethyl ether

    SciTech Connect (OSTI)

    Zhou, L.; Hu, S.Y.; Chen, D.J.; Li, Y.R.; Zhu, B.; Jin, Y.

    2009-04-15

    China is a coal-dependent country and will remain so for a long time. Dimethyl ether (DME), a potential substitute for liquid fuel, is a kind of clean diesel motor fuel. The production of DME from coal is meaningful and is studied in this article. Considering the C/H ratios of coal and natural gas (NG), the cofeed (coal and NG) system (CFS), which does not contain the water gas shift process, is studied. It can reduce CO{sub 2} emission and increase the conversion rate of carbon, producing more DME. The CFS is simulated and compared with the coal-based and NG-based systems with different recycling ratios. The part of the exhaust gas that is not recycled is burned, producing electricity. On the basis of the simulation results, the thermal efficiency, economic index, and CO{sub 2} emission ratio are calculated separately. The CFS with a 100% recycling ratio has the best comprehensive evaluation index, while the energy, economy, and environment were considered at the same time.

  12. Modular ultrahigh vacuum-compatible gas-injection system with an adjustable gas flow for focused particle beam-induced deposition

    SciTech Connect (OSTI)

    Klingenberger, D.; Huth, M.

    2009-09-15

    A gas-injection system (GIS) heats up a powdery substance and transports the resulting gas through a capillary into a vacuum chamber. Such a system can be used to guide a (metal)organic precursor gas very close to the focal area of an electron or ion beam, where a permanent deposit is created and adheres to the substrate. This process is known as focused particle beam-induced deposition. The authors present design principles and give construction details of a GIS suitable for ultrahigh vacuum usage. The GIS is composed of several self-contained components which can be customized rather independently. It allows for a continuously adjustable gas-flow rate. The GIS was attached to a standard scanning electron microscope (JEOL 6100) and tested with the tungsten precursor W(CO){sub 6}. The analysis of the deposits by means of atomic force microscopy and energy dispersive x-ray spectroscopy provides clear evidence that excellent gas-flow-rate stability and ensuing growth rate and metal-content reproducibility are experienced.

  13. Technology survey for real-time monitoring of plutonium in a vitrifier off-gas system

    SciTech Connect (OSTI)

    Berg, J.M.; Veirs, D.K.

    1996-01-01

    We surveyed several promising measurement technologies for the real-time monitoring of plutonium in a vitrifier off-gas system. The vitrifier is being developed by Westinghouse Savannah River Corp. and will be used to demonstrate vitrification of plutonium dissolved in nitric acid for fissile material disposition. The risk of developing a criticality hazard in the off-gas processing equipment can be managed by using available measurement technologies. We identified several potential technologies and methods for detecting plutonium that are sensitive enough to detect the accumulation of a mass sufficient to form a criticality hazard. We recommend gross alpha-monitoring technologies as the most promising option for Westinghouse Savannah River Corp. to consider because that option appears to require the least additional development. We also recommend further consideration for several other technologies because they offer specific advantages and because gross alpha-monitoring could prove unsuitable when tested for this specific application.

  14. Model documentation Natural Gas Transmission and Distribution Model of the National Energy Modeling System. Volume 1

    SciTech Connect (OSTI)

    1996-02-26

    The Natural Gas Transmission and Distribution Model (NGTDM) of the National Energy Modeling System is developed and maintained by the Energy Information Administration (EIA), Office of Integrated Analysis and Forecasting. This report documents the archived version of the NGTDM that was used to produce the natural gas forecasts presented in the Annual Energy Outlook 1996, (DOE/EIA-0383(96)). The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic approach, and provides detail on the methodology employed. Previously this report represented Volume I of a two-volume set. Volume II reported on model performance, detailing convergence criteria and properties, results of sensitivity testing, comparison of model outputs with the literature and/or other model results, and major unresolved issues.

  15. Uncertainty analysis of integrated gasification combined cycle systems based on Frame 7H versus 7F gas turbines

    SciTech Connect (OSTI)

    Yunhua Zhu; H. Christopher Frey

    2006-12-15

    Integrated gasification combined cycle (IGCC) technology is a promising alternative for clean generation of power and coproduction of chemicals from coal and other feedstocks. Advanced concepts for IGCC systems that incorporate state-of-the-art gas turbine systems, however, are not commercially demonstrated. Therefore, there is uncertainty regarding the future commercial-scale performance, emissions, and cost of such technologies. The Frame 7F gas turbine represents current state-of-practice, whereas the Frame 7H is the most recently introduced advanced commercial gas turbine. The objective of this study was to evaluate the risks and potential payoffs of IGCC technology based on different gas turbine combined cycle designs. Models of entrained-flow gasifier-based IGCC systems with Frame 7F (IGCC-7F) and 7H gas turbine combined cycles (IGCC-7H) were developed in ASPEN Plus. An uncertainty analysis was conducted. Gasifier carbon conversion and project cost uncertainty are identified as the most important uncertain inputs with respect to system performance and cost. The uncertainties in the difference of the efficiencies and costs for the two systems are characterized. Despite uncertainty, the IGCC-7H system is robustly preferred to the IGCC-7F system. Advances in gas turbine design will improve the performance, emissions, and cost of IGCC systems. The implications of this study for decision-making regarding technology selection, research planning, and plant operation are discussed. 38 refs., 11 figs., 5 tabs.

  16. Computational study of the shock driven instability of a multiphase particle-gas system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    None, None

    2016-02-01

    This paper considers the interaction of a shock wave with a multiphase particle-gas system which creates an instability somewhat similar to the Richtmyer-Meshkov instability but with a larger parameter space. Because this parameter space is large, we only present an introductory survey of the effects of many of these parameters. We highlight the effects of particle-gas coupling, incident shock strength, particle size, effective system density differences, and multiple particle relaxation time effects. We focus on dilute flows with mass loading up to 40% and do not attempt to cover all parametric combinations. Instead, we vary one parameter at a timemore » leaving additional parametric combinations for future work. The simulations are run with the Ares code, developed at Lawrence Livermore National Laboratory, which uses a multiphase particulate transport method to model two-way momentum and energy coupling. A brief validation of these models is presented and coupling effects are explored. It is shown that even for small particles, on the order of 1μm, multi-phase coupling effects are important and diminish the circulation deposition on the interface by up to 25%. These coupling effects are shown to create large temperature deviations from the dusty gas approximation, up to 20% greater, especially at higher shock strengths. It is also found that for a multiphase instability, the vortex sheet deposited at the interface separates into two sheets. In conclusion, depending on the particle and particle-gas Atwood numbers, the instability may be suppressed or enhanced by the interactions of these two vortex sheets.« less

  17. Evaluation of the Effects of Natural Gas Contaminants on Corrosion in Compressed Natural Gas Storage Systems - Phase II

    SciTech Connect (OSTI)

    Lyle, F.F. Jr.

    1988-01-01

    This report describes a research program that was conducted to define natural gas contaminant levels necessary to insure that internal corrosion of compressed natural gas (CNG) cylinders does not constitute a hazard over the lifetimes of the cylinders. A literature search was performed and companies in the natural gas transmission and distribution industries were contacted: to identify and determine the composition ranges of contaminants in natural gases; and to obtain information regarding corrosion damage of CNG cylinders and cylinder materials. Corrosion and stress corrosion cracking (SCC) tests were performed on the cylinder materials most widely used in CNG cylinders in the United States (4130X and 15B30 steels and 6061-T6 aluminum alloy). Tests were conducted in: natural gases from several producing wells and from an interstate pipeline; and in aqueous solutions saturated with varying concentrations of natural gas contaminants. Also, metallurgical analyses of nine (eight steel and one aluminum), used CNG cylinders were performed. Limiting concentrations of hydrogen sulfide (H{sub 2}S), carbon dioxide (CO{sub 2}), and other CNG contaminants necessary to prevent internal corrosion of CNG fuel and storage cylinders were defined. This knowledge will minimize potential hazards of using CNG as a vehicle fuel. It should also lead to reduced costs of CNG use, since it has been shown that reduction of contaminants to the very low levels currently specified by the U.S. Department of Transportation (DOT) and the Canadian Transport Commission (CTC) is not necessary. A gas-quality standard based on program results is recommended. The National Fire Protection Association (NFPA) has adopted the recommended gas-quality standard.

  18. Model documentation: Natural Gas Transmission and Distribution Model of the National Energy Modeling System; Volume 1

    SciTech Connect (OSTI)

    1994-02-24

    The Natural Gas Transmission and Distribution Model (NGTDM) is a component of the National Energy Modeling System (NEMS) used to represent the domestic natural gas transmission and distribution system. NEMS is the third in a series of computer-based, midterm energy modeling systems used since 1974 by the Energy Information Administration (EIA) and its predecessor, the Federal Energy Administration, to analyze domestic energy-economy markets and develop projections. This report documents the archived version of NGTDM that was used to produce the natural gas forecasts used in support of the Annual Energy Outlook 1994, DOE/EIA-0383(94). The purpose of this report is to provide a reference document for model analysts, users, and the public that defines the objectives of the model, describes its basic design, provides detail on the methodology employed, and describes the model inputs, outputs, and key assumptions. It is intended to fulfill the legal obligation of the EIA to provide adequate documentation in support of its models (Public Law 94-385, Section 57.b.2). This report represents Volume 1 of a two-volume set. (Volume 2 will report on model performance, detailing convergence criteria and properties, results of sensitivity testing, comparison of model outputs with the literature and/or other model results, and major unresolved issues.) Subsequent chapters of this report provide: (1) an overview of the NGTDM (Chapter 2); (2) a description of the interface between the National Energy Modeling System (NEMS) and the NGTDM (Chapter 3); (3) an overview of the solution methodology of the NGTDM (Chapter 4); (4) the solution methodology for the Annual Flow Module (Chapter 5); (5) the solution methodology for the Distributor Tariff Module (Chapter 6); (6) the solution methodology for the Capacity Expansion Module (Chapter 7); (7) the solution methodology for the Pipeline Tariff Module (Chapter 8); and (8) a description of model assumptions, inputs, and outputs (Chapter 9).

  19. The Case for Natural Gas Fueled Solid Oxide Fuel Cell Power Systems for Distributed Generation

    SciTech Connect (OSTI)

    Chick, Lawrence A.; Weimar, Mark R.; Whyatt, Greg A.; Powell, Michael R.

    2015-02-01

    Natural-gas-fueled solid oxide fuel cell (NGSOFC) power systems yield electrical conversion efficiencies exceeding 60% and may become a viable alternative for distributed generation (DG) if stack life and manufacturing economies of scale can be realized. Currently, stacks last approximately 2 years and few systems are produced each year because of the relatively high cost of electricity from the systems. If mass manufacturing (10,000 units per year) and a stack life of 15 years can be reached, the cost of electricity from an NGSOFC system is estimated to be about 7.7 ¢/kWh, well within the price of commercial and residential retail prices at the national level (9.9-10¢/kWh and 11-12 ¢/kWh, respectively). With an additional 5 ¢/kWh in estimated additional benefits from DG, NGSOFC could be well positioned to replace the forecasted 59-77 gigawatts of capacity loss resulting from coal plant closures due to stricter emissions regulations and low natural gas prices.

  20. Filter systems for IGCC applications

    SciTech Connect (OSTI)

    Bevan, S.; Gieger, R.; Sobel, N.; Johnson, D.

    1995-11-01

    The objectives of this program were to identify metallic filter medium to be utilized in the Integrated Gasification Combined Cycle process (IGCC). In IGCC processes utilizing high efficiency desulfurizing technology, the traditional corrosion attack, sulfidation, is minimized so that metallic filters are viable alternatives over ceramic filters. Tampa Electric Company`s Polk Power Station is being developed to demonstrate Integrated Gasification Combined Cycle technology. The Pall Gas Solid Separation (GSS) System is a self cleaning filtration system designed to remove virtually all particulate matter from gas streams. The heart of the system is the filter medium used to collect the particles on the filter surface. The medium`s filtration efficiency, uniformity, permeability, voids volume, and surface characteristics are all important to establishing a permeable permanent cake. In-house laboratory blowback tests, using representative full scale system particulate, were used to confirm the medium selection for this project. Test elements constructed from six alloys were supplied for exposure tests: PSS 310SC (modified 310S alloy); PSS 310SC heat treated; PSS 310SC-high Cr; PSS 310SC-high Cr heat treated; PSS Hastelloy X; and PSS Hastelloy X heat treated.

  1. EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

    Energy Science and Technology Software Center (OSTI)

    2015-06-22

    EOS7CA is a TOUGH2 module for mixtures of a non-condensible gas (NCG) and air (with or without a gas tracer), an aqueous phase, and water vapor. The user can select the NCG as being CO2, N2, or CH4. EOS7CA uses a cubic equation of state with a multiphase version of Darcy’s Law to model flow and transport of gas and aqueous phase mixtures over a range of pressures and temperatures appropriate to shallow subsurface porousmore » media systems. The limitation to shallow systems arises from the use of Henry’s Law for gas solubility which is appropriate for low pressures but begins to over-predict solubility starting at pressures greater than approximately 1 MPa (10 bar). The components modeled in EOS7CA are water, brine, NCG, gas tracer, air, and optional heat.« less

  2. EOS7CA Version 1.0: TOUGH2 Module for Gas Migration in Shallow Subsurface Porous Media Systems

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.

    2015-06-22

    EOS7CA is a TOUGH2 module for mixtures of a non-condensible gas (NCG) and air (with or without a gas tracer), an aqueous phase, and water vapor. The user can select the NCG as being CO2, N2, or CH4. EOS7CA uses a cubic equation of state with a multiphase version of Darcy’s Law to model flow and transport of gas and aqueous phase mixtures over a range of pressures and temperatures appropriate to shallow subsurface porous media systems. The limitation to shallow systems arises from the use of Henry’s Law for gas solubility which is appropriate for low pressures but begins to over-predict solubility starting at pressures greater than approximately 1 MPa (10 bar). The components modeled in EOS7CA are water, brine, NCG, gas tracer, air, and optional heat.

  3. The oil and gas potential of southern Bolivia: Contributions from a dual source rock system

    SciTech Connect (OSTI)

    Hartshorn, K.G.

    1996-08-01

    The southern Sub-Andean and Chaco basins of Bolivia produce oil, gas and condensate from reservoirs ranging from Devonian to Tertiary in age. Geochemical evidence points to contributions from two Paleozoic source rocks: the Devonian Los Monos Formation and the Silurian Kirusillas Formation. Rock-Eval pyrolysis, biomarker data, microscopic kerogen analysis, and burial history modeling are used to assess the quality, distribution, and maturity of both source rock systems. The geochemical results are then integrated with the structural model for the area in order to determine the most likely pathways for migration of oil and gas in the thrust belt and its foreland. Geochemical analysis and modeling show that the primary source rock, shales of the Devonian Los Monos Formation, entered the oil window during the initial phase of thrusting in the sub-Andean belt. This provides ideal timing for oil accumulation in younger reservoirs of the thrust belt. The secondary source rock, although richer, consumed most of its oil generating capacity prior to the development of the thrust related structures. Depending on burial depth and location, however, the Silurian source still contributes gas, and some oil, to traps in the region.

  4. Pathways to Decarbonization. Natural Gas and Renewable Energy. Lessons Learned from Energy System Stakeholders

    SciTech Connect (OSTI)

    Pless, Jacquelyn; Arent, Douglas J.; Logan, Jeffrey; Cochran, Jaquelin; Zinaman, Owen; Stark, Camila

    2015-04-30

    Ensuring the resilience, reliability, flexibility, and affordability of the U.S. electric grid is increasingly important as the country addresses climate change and an aging infrastructure. State and federal policy and actions by industry, non-profits, and others create a dynamic framework for achieving these goals. Three principle low-carbon generation technologies have formed the basis for multiple scenarios leading toward a low-carbon, resilient, and affordable power system. While there is no “silver bullet,” one avenue identified by key stakeholders is the opportunity to invest in natural gas (NG) and renewable resources, both of which offer abundant domestic resource bases and contribute to energy independence, carbon mitigation, and economic growth. NG and renewable electricity (RE) have traditionally competed for market share in the power sector, but there is a growing experience base and awareness for their synergistic use (Cochran et al. 2014). Building upon these observations and previous work, the Joint Institute for Strategic Energy Analysis (JISEA), in collaboration with the Center for the New Energy Economy and the Gas Technology Institute, convened a series of workshops in 2014 to explore NG and RE synergies in the U.S. power sector. This report captures key insights from the workshop series, Synergies of Natural Gas and Renewable Energy: 360 Degrees of Opportunity, as well as supporting economic valuation analyses conducted by JISEA researchers that quantify the value proposition of investing in NG and RE together as complements.

  5. Genesis of a three-phase subsea metering system. [Oil and gas metering systems for subsea operations

    SciTech Connect (OSTI)

    Dowty, E.L.; Hatton, G.J.; Durrett, M.G. ); Dean, T.L.; Jiskoot, R.J.J.

    1993-08-01

    Periodic well flow testing is necessary to monitor well and reservoir performance over time to optimize decisions on well production rates and new well requirements through improved reservoir models, to determine the timing of well workovers, and to identify when wells become uneconomical to produce. A dedicated test separator' conventionally is used to meter individual wells. Fluids from a well are separated into the three component phases (oil, gas, and water) in a large vessel, and the flow rate of each phase is measured on the respective outlet lines from the vessel. The same method currently is used for subsea satellite developments by providing a dedicated test pipeline' from the subsea field to carry a selected well's production to a test separator for metering on the host platform. The capital cost of these systems rises rapidly with distance. Greater distances between the wellhead and flow test system increase the cost of the test pipeline and require larger and hence more expensive slug catchers and risers. Clearly, a subsea-based well-test system could result in large capital cost savings by eliminating the need for conventional test systems. This paper tracks the development of one subsea well test system from conception to field testing on the Tartan. A platform in the North Sea. This work defines the design requirements of the system, reviews system development and fabrication, describes modifications made as a result of initial field tests, and reports the results of topside tests completed through Dec. 1990.

  6. KEY DESIGN REQUIREMENTS FOR THE HIGH TEMPERATURE GAS-COOLED REACTOR NUCLEAR HEAT SUPPLY SYSTEM

    SciTech Connect (OSTI)

    L.E. Demick

    2010-09-01

    Key requirements that affect the design of the high temperature gas-cooled reactor nuclear heat supply system (HTGR-NHSS) as the NGNP Project progresses through the design, licensing, construction and testing of the first of a kind HTGR based plant are summarized. These requirements derive from pre-conceptual design development completed to-date by HTGR Suppliers, collaboration with potential end users of the HTGR technology to identify energy needs, evaluation of integration of the HTGR technology with industrial processes and recommendations of the NGNP Project Senior Advisory Group.

  7. Cooling system for a gas turbine using a cylindrical insert having V-shaped notch weirs

    DOE Patents [OSTI]

    Grondahl, Clayton M.; Germain, Malcolm R.

    1981-01-01

    An improved cooling system for a gas turbine is disclosed. A plurality of V-shaped notch weirs are utilized to meter a coolant liquid from a pool of coolant into a plurality of platform and airfoil coolant channels formed in the buckets of the turbine. The V-shaped notch weirs are formed in a separately machined cylindrical insert and serve to desensitize the flow of coolant into the individual platform and airfoil coolant channels to design tolerances and non-uniform flow distribution.

  8. Methods for ensuring compliance in an international greenhouse gas trading system

    SciTech Connect (OSTI)

    Hargrave, T.; Helme, E.A.

    1998-12-31

    At the third Conference of the Parties to the UN Framework Convention on Climate Change held in December, 1997, the international community established binding greenhouse gas (GHG) emissions obligations for industrialized countries. The Parties to the new Kyoto Protocol also agreed on the use of a number of market-based mechanisms, including international GHG emissions trading. These market mechanisms were of critical to the importance because they have the potential to significantly reduce the costs of treaty compliance. In principle, an international cap-and-trade system appears to be one of the most cost-effective means of reducing GHG emissions. Maintaining the integrity of the trading system is of primary importance in ensuring that trading helps countries to meet their GHG commitments. This paper explores methods for ensuring compliance in an international greenhouse gas trading system, starting with a discussion of preconditions for participation in trading and then moving to features of an international compliance system. Achieving maximum compliance with international requirements may best be accomplished by limiting participation in trading to Annex I countries that maintain strong domestic compliance systems. Prior to the climate negotiations in Kyoto in December 1997, the US Administration proposed a number of preconditions for participation in trading, including the adoption of international measurement standards and the establishment of domestic compliance and enforcement programs. This paper explores these and other preconditions, including the establishment of tough domestic financial penalties on companies that exceed allowed emissions and seller responsibility for the delivery of real reductions. The paper also discusses several necessary features of the international compliance system.

  9. Balance of Plant System Analysis and Component Design of Turbo-Machinery for High Temperature Gas Reactor Systems

    SciTech Connect (OSTI)

    Ballinger, Ronald G.; Wang, Chun Yun; Kadak, Andrew; Todreas, Neil; Mirick, Bradley; Demetri, Eli; Koronowski, Martin

    2004-08-30

    The Modular Pebble Bed Reactor system (MPBR) requires a gas turbine cycle (Brayton cycle) as the power conversion system for it to achieve economic competitiveness as a Generation IV nuclear system. The availability of controllable helium turbomachinery and compact heat exchangers are thus the critical enabling technology for the gas turbine cycle. The development of an initial reference design for an indirect helium cycle has been accomplished with the overriding constraint that this design could be built with existing technology and complies with all current codes and standards. Using the initial reference design, limiting features were identified. Finally, an optimized reference design was developed by identifying key advances in the technology that could reasonably be expected to be achieved with limited R&D. This final reference design is an indirect, intercooled and recuperated cycle consisting of a three-shaft arrangement for the turbomachinery system. A critical part of the design process involved the interaction between individual component design and overall plant performance. The helium cycle overall efficiency is significantly influenced by performance of individual components. Changes in the design of one component, a turbine for example, often required changes in other components. To allow for the optimization of the overall design with these interdependencies, a detailed steady state and transient control model was developed. The use of the steady state and transient models as a part of an iterative design process represents a key contribution of this work. A dynamic model, MPBRSim, has been developed. The model integrates the reactor core and the power conversion system simultaneously. Physical parameters such as the heat exchangers; weights and practical performance maps such as the turbine characteristics and compressor characteristics are incorporated into the model. The individual component models as well as the fully integrated model of the

  10. Engineering Development of Ceramic Membrane Reactor System for Converting Natural Gas to Hydrogen and Synthesis Gas for Liquid Transportation Fuels

    SciTech Connect (OSTI)

    Air Products and Chemicals

    2008-09-30

    An Air Products-led team successfully developed ITM Syngas technology from the concept stage to a stage where a small-scale engineering prototype was about to be built. This technology produces syngas, a gas containing carbon monoxide and hydrogen, by reacting feed gas, primarily methane and steam, with oxygen that is supplied through an ion transport membrane. An ion transport membrane operates at high temperature and oxygen ions are transported through the dense membrane's crystal lattice when an oxygen partial pressure driving force is applied. This development effort solved many significant technical challenges and successfully scaled-up key aspects of the technology to prototype scale. Throughout the project life, the technology showed significant economic benefits over conventional technologies. While there are still on-going technical challenges to overcome, the progress made under the DOE-funded development project proved that the technology was viable and continued development post the DOE agreement would be warranted.

  11. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. )

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the best-case'' results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author's experience with fuel delivery systems for light-duty vehicles.

  12. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B.

    1992-09-01

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the ``best-case`` results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author`s experience with fuel delivery systems for light-duty vehicles.

  13. Ultra Clean 1.1MW High Efficiency Natural Gas Engine Powered System

    SciTech Connect (OSTI)

    Zurlo, James; Lueck, Steve

    2011-08-31

    Dresser, Inc. (GE Energy, Waukesha gas engines) will develop, test, demonstrate, and commercialize a 1.1 Megawatt (MW) natural gas fueled combined heat and power reciprocating engine powered package. This package will feature a total efficiency > 75% and ultra low CARB permitting emissions. Our modular design will cover the 1 – 6 MW size range, and this scalable technology can be used in both smaller and larger engine powered CHP packages. To further advance one of the key advantages of reciprocating engines, the engine, generator and CHP package will be optimized for low initial and operating costs. Dresser, Inc. will leverage the knowledge gained in the DOE - ARES program. Dresser, Inc. will work with commercial, regulatory, and government entities to help break down barriers to wider deployment of CHP. The outcome of this project will be a commercially successful 1.1 MW CHP package with high electrical and total efficiency that will significantly reduce emissions compared to the current central power plant paradigm. Principal objectives by phases for Budget Period 1 include: • Phase 1 – market study to determine optimum system performance, target first cost, lifecycle cost, and creation of a detailed product specification. • Phase 2 – Refinement of the Waukesha CHP system design concepts, identification of critical characteristics, initial evaluation of technical solutions, and risk mitigation plans. Background

  14. SU-E-J-190: Development of Abdominal Compression & Respiratory Guiding System Using Gas Pressure Sensor

    SciTech Connect (OSTI)

    Kim, T; Kim, D; Kang, S; Cho, M; Kim, K; Shin, D; Suh, T; Kim, S

    2015-06-15

    Purpose: Abdominal compression is known to be effective but, often makes external-marker-based monitoring of breathing motion not feasible. In this study, we developed and evaluated a system that enables both abdominal compression and monitoring of residual abdominal motion simultaneously. The system can also provide visual-biofeedback capability. Methods: The system developed consists of a compression belt, an abdominal motion monitoring sensor (gas pressure sensor) and a visual biofeedback device. The compression belt was designed to be able to compress the frontal side of the abdomen. The pressure level of the belt is controlled by air volume and monitored in real time using the gas pressure sensor. The system displays not only the real-time monitoring curve but also a guiding respiration model (e.g., a breath hold or shallow breathing curve) simultaneously on the head mounted display to help patients keep their breathing pattern as consistent as possible. Three healthy volunteers were enrolled in this pilot study and respiratory signals (pressure variations) were obtained both with and without effective abdominal compression to investigate the feasibility of the developed system. Two guidance patterns, breath hold and shallow breathing, were tested. Results: All volunteers showed smaller abdominal motion with compression (about 40% amplitude reduction compared to without compression). However, the system was able to monitor residual abdominal motion for all volunteers. Even under abdominal compression, in addition, it was possible to make the subjects successfully follow the guide patterns using the visual biofeedback system. Conclusion: The developed abdominal compression & respiratory guiding system was feasible for residual abdominal motion management. It is considered that the system can be used for a respiratory motion involved radiation therapy while maintaining the merit of abdominal compression. This work was supported by the Radiation Technology R

  15. Investigation of austenitic alloys for advanced heat recovery and hot-gas cleanup systems

    SciTech Connect (OSTI)

    Swindeman, R.W.

    1997-12-01

    Materials properties were collected for the design and construction of structural components for use in advanced heat recovery and hot gas cleanup systems. Alloys systems included 9Cr-1Mo-V steel, modified 316 stainless steel, modified type 310 stainless steel, modified 20Cr-25Ni-Nb stainless steel, and modified alloy 800. Experimental work was undertaken to expand the databases for potentially useful alloys. Types of testing included creep, stress-rupture, creep-crack growth, fatigue, and post-exposure short-time tensile tests. Because of the interest in relatively inexpensive alloys for service at 700 C and higher, research emphasis was placed on a modified type 310 stainless steel and a modified 20Cr-25Ni-Nb stainless steel. Both steels were found to have useful strength to 925 C with good weldability and ductility.

  16. LASER STABILIZATION FOR NEAR ZERO NO{sub x} GAS TURBINE COMBUSTION SYSTEMS

    SciTech Connect (OSTI)

    Vivek Khanna

    2002-09-30

    Historically, the development of new industrial gas turbines has been primarily driven by the intent to achieve higher efficiency, lower operating costs and lower emissions. Higher efficiency and lower cost is obtained through higher turbine operating temperatures, while reduction in emissions is obtained by extending the lean operating limit of the combustor. However reduction in the lean stability limit of operation is limited greatly by the chemistry of the combustion process and by the occurrence of thermo-acoustic instabilities. Solar Turbines, CFD Research Corporation, and Los Alamos National Laboratory have teamed to advance the technology associated with laser-assisted ignition and flame stabilization, to a level where it could be incorporated onto a gas turbine combustor. The system being developed is expected to enhance the lean stability limit of the swirl stabilized combustion process and assist in reducing combustion oscillations. Such a system has the potential to allow operation at the ultra-lean conditions needed to achieve NO{sub x} emissions below 5 ppm without the need of exhaust treatment or catalytic technologies. The research effort was focused on analytically modeling laser-assisted flame stabilization using advanced CFD techniques, and experimentally demonstrating the technology, using a solid-state laser and low-cost durable optics. A pulsed laser beam was used to generate a plasma pool at strategic locations within the combustor flow field such that the energy from the plasma became an ignition source and helped maintain a flame at ultra lean operating conditions. The periodic plasma generation and decay was used to nullify the fluctuations in the heat release from the flame itself, thus decoupling the heat release from the combustor acoustics and effectively reducing the combustion oscillations. The program was built on an existing technology base and includes: extending LANL's existing laser stabilization experience to a sub

  17. Process system evaluation-consolidated letters. Volume 1. Alternatives for the off-gas treatment system for the low-level waste vitrification process

    SciTech Connect (OSTI)

    Peurrung, L.M.; Deforest, T.J; Richards, J.R.

    1996-03-01

    This report provides an evaluation of alternatives for treating off-gas from the low-level waste (LLW) melter. The study used expertise obtained from the commercial nonradioactive off-gas treatment industry. It was assumed that contact maintenance is possible, although the subsequent risk to maintenance personnel was qualitatively considered in selecting equipment. Some adaptations to the alternatives described may be required, depending on the extent of contact maintenance that can be achieved. This evaluation identified key issues for the off-gas system design. To provide background information, technology reviews were assembled for various classifications of off-gas treatment equipment, including off-gas cooling, particulate control, acid gas control, mist elimination, NO{sub x} reduction, and SO{sub 2} removal. An order-of-magnitude cost estimate for one of the off-gas systems considered is provided using both the off-gas characteristics associated with the Joule-heated and combustion-fired melters. The key issues identified and a description of the preferred off-gas system options are provided below. Five candidate treatment systems were evaluated. All of the systems are appropriate for the different melting/feed preparations currently being considered. The lowest technical risk is achieved using option 1, which is similar to designs for high-level waste (HLW) vitrification in the Hanford Waste Vitrification Project (HWVP) and the West Valley. Demonstration Project. Option 1 uses a film cooler, submerged bed scrubber (SBS), and high-efficiency mist eliminator (HEME) prior to NO{sub x} reduction and high-efficiency particulate air (HEPA) filtration. However, several advantages were identified for option 2, which uses high-temperature filtration. Based on the evaluation, option 2 was identified as the preferred alternative. The characteristics of this option are described below.

  18. Oil and gas exploration system and method for detecting trace amounts of hydrocarbon gases in the atmosphere

    DOE Patents [OSTI]

    Wamsley, Paula R.; Weimer, Carl S.; Nelson, Loren D.; O'Brien, Martin J.

    2003-01-01

    An oil and gas exploration system and method for land and airborne operations, the system and method used for locating subsurface hydrocarbon deposits based upon a remote detection of trace amounts of gases in the atmosphere. The detection of one or more target gases in the atmosphere is used to indicate a possible subsurface oil and gas deposit. By mapping a plurality of gas targets over a selected survey area, the survey area can be analyzed for measurable concentration anomalies. The anomalies are interpreted along with other exploration data to evaluate the value of an underground deposit. The system includes a differential absorption lidar (DIAL) system with a spectroscopic grade laser light and a light detector. The laser light is continuously tunable in a mid-infrared range, 2 to 5 micrometers, for choosing appropriate wavelengths to measure different gases and avoid absorption bands of interference gases. The laser light has sufficient optical energy to measure atmospheric concentrations of a gas over a path as long as a mile and greater. The detection of the gas is based on optical absorption measurements at specific wavelengths in the open atmosphere. Light that is detected using the light detector contains an absorption signature acquired as the light travels through the atmosphere from the laser source and back to the light detector. The absorption signature of each gas is processed and then analyzed to determine if a potential anomaly exists.

  19. System Design Description and Requirements for Modeling the Off-Gas Systems for Fuel Recycling Facilities

    SciTech Connect (OSTI)

    Daryl R. Haefner; Jack D. Law; Troy J. Tranter

    2010-08-01

    This document provides descriptions of the off-gases evolved during spent nuclear fuel processing and the systems used to capture the gases of concern. Two reprocessing techniques are discussed, namely aqueous separations and electrochemical (pyrochemical) processing. The unit operations associated with each process are described in enough detail so that computer models to mimic their behavior can be developed. The document also lists the general requirements for the desired computer models.

  20. A Greenhouse-Gas Information System: Monitoring and Validating Emissions Reporting and Mitigation

    SciTech Connect (OSTI)

    Jonietz, Karl K.; Dimotakis, Paul E.; Walker, Bruce C.

    2011-09-26

    This study and report focus on attributes of a greenhouse-gas information system (GHGIS) needed to support MRV&V needs. These needs set the function of such a system apart from scientific/research monitoring of GHGs and carbon-cycle systems, and include (not exclusively): the need for a GHGIS that is operational, as required for decision-support; the need for a system that meets specifications derived from imposed requirements; the need for rigorous calibration, verification, and validation (CV&V) standards, processes, and records for all measurement and modeling/data-inversion data; the need to develop and adopt an uncertainty-quantification (UQ) regimen for all measurement and modeling data; and the requirement that GHGIS products can be subjected to third-party questioning and scientific scrutiny. This report examines and assesses presently available capabilities that could contribute to a future GHGIS. These capabilities include sensors and measurement technologies; data analysis and data uncertainty quantification (UQ) practices and methods; and model-based data-inversion practices, methods, and their associated UQ. The report further examines the need for traceable calibration, verification, and validation processes and attached metadata; differences between present science-/research-oriented needs and those that would be required for an operational GHGIS; the development, operation, and maintenance of a GHGIS missions-operations center (GMOC); and the complex systems engineering and integration that would be required to develop, operate, and evolve a future GHGIS.

  1. Long-Range Untethered Real-Time Live Gas Main Robotic Inspection System

    SciTech Connect (OSTI)

    Hagen Schempf; Daphne D'Zurko

    2004-10-31

    Under funding from the Department of Energy (DOE) and the Northeast Gas Association (NGA), Carnegie Mellon University (CMU) developed an untethered, wireless remote controlled inspection robot dubbed Explorer. The project entailed the design and prototyping of a wireless self-powered video-inspection robot capable of accessing live 6- and 8-inch diameter cast-iron and steel mains, while traversing turns and Ts and elbows under real-time control with live video feedback to an operator. The design is that of a segmented actively articulated and wheel-leg powered robot design, with fisheye imaging capability and self-powered battery storage and wireless real-time communication link. The prototype was functionally tested in an above ground pipe-network, in order to debug all mechanical, electrical and software subsystems, and develop the necessary deployment and retrieval, as well as obstacle-handling scripts. A pressurized natural gas test-section was used to certify it for operation in natural gas at up to 60 psig. Two subsequent live-main field-trials in both cast-iron and steel pipe, demonstrated its ability to be safely launched, operated and retrieved under real-world conditions. The system's ability to safely and repeatably exidrecover from angled and vertical launchers, traverse multi-thousand foot long pipe-sections, make T and varied-angle elbow-turns while wirelessly sending live video and handling command and control messages, was clearly demonstrated. Video-inspection was clearly shown to be a viable tool to understand the state of this critical buried infrastructure, irrespective of low- (cast-iron) or high-pressure (steel) conditions. This report covers the different aspects of specifications, requirements, design, prototyping, integration and testing and field-trialing of the Explorer platform.

  2. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Wood Feedstock

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for treatment of wood-derived syngas for use in the synthesis of liquid fuels. Two different 2,000 metric tonne per day gasification schemes, a low-pressure, indirect system using the gasifier, and a high-pressure, direct system using gasification technology were evaluated. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  3. Incentives for Methane Mitigation and Energy-Efficiency Improvements in Case of Ukraine’s Natural Gas Transmission System

    SciTech Connect (OSTI)

    Roshchanka, Volha; Evans, Meredydd

    2014-06-01

    Reducing methane losses is a concern for climate change policy and energy policy. The energy sector is the major source of methane emissions into the atmosphere. Reducing methane emissions and avoiding combustion can be very cost-effective, but various barriers prevent such energy-efficiency measures from taking place. To date, few examples of industry-wide improvements exist. One example of substantial investments into upgrading natural gas transmission system comes from Ukraine. The Ukrainian transmission company, Ukrtransgaz, reduced its own system’s natural gas consumption by 68 percent in 2011 compared to the level in 2005. Evaluating reductions in methane emissions is challenging because of lack of accurate data and gaps in accounting methodologies. At the same time, Ukraine’s transmission system has undergone improvements that, at the very least, have contained methane emissions, if not substantially reduced them. In this paper, we describe recent developments in Ukraine’s natural gas transmission system and analyze the incentives that forced the sector to pay close attention to its methane losses. Ukraine is one of most energy-intensive countries, among the largest natural gas consumers in the world, and a significant emitter of methane. The country is also dependent on imports of natural gas. A combination of steep increases in the price of imported natural gas, and comprehensive domestic environmental and energy policies, regional integration policy, and international environmental agreements has created conditions for successful methane emission and combustion reductions. Learning about such case studies can help us design better policies elsewhere.

  4. Proposition of a stratified charge system by using in-cylinder gas motion

    SciTech Connect (OSTI)

    Moriyoshi, Yasuo; Muroki, Takumi

    1995-12-31

    A new idea for controlling the in-cylinder mixture formation in SI engines is proposed. This concept was developed by applying the results of numerical calculations. Fuel that is directly injected into the cylinder is transferred toward the cylinder head to form a mixture stratification by using the in-cylinder gas motion that is generated by the interaction between the swirl and squish flows inside a combustion chamber. At first, the flow characteristics were measured in the whole in-cylinder space using an LDV system. Also, numerical calculations of the in-cylinder flow were made using measured data as the initial conditions. Secondly, the local equivalence ratio at several points inside the combustion chamber was measured by using a fast gas sampling device. The results showed that this idea generates the desired stratified charge when the fuel is injected with a higher injection pressure (about 1.3 MPa) at near the intake-BDC timing than with a usual pressure of 0.2 MPa in the port-injection case. Further numerical calculations were performed to examine other factors that might enhance mixture stratification during the compression stroke.

  5. Intelligent Bioreactor Management Information System (IBM-IS) for Mitigation of Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Paul Imhoff; Ramin Yazdani; Don Augenstein; Harold Bentley; Pei Chiu

    2010-04-30

    Methane is an important contributor to global warming with a total climate forcing estimated to be close to 20% that of carbon dioxide (CO2) over the past two decades. The largest anthropogenic source of methane in the US is 'conventional' landfills, which account for over 30% of anthropogenic emissions. While controlling greenhouse gas emissions must necessarily focus on large CO2 sources, attention to reducing CH4 emissions from landfills can result in significant reductions in greenhouse gas emissions at low cost. For example, the use of 'controlled' or bioreactor landfilling has been estimated to reduce annual US greenhouse emissions by about 15-30 million tons of CO2 carbon (equivalent) at costs between $3-13/ton carbon. In this project we developed or advanced new management approaches, landfill designs, and landfill operating procedures for bioreactor landfills. These advances are needed to address lingering concerns about bioreactor landfills (e.g., efficient collection of increased CH4 generation) in the waste management industry, concerns that hamper bioreactor implementation and the consequent reductions in CH4 emissions. Collectively, the advances described in this report should result in better control of bioreactor landfills and reductions in CH4 emissions. Several advances are important components of an Intelligent Bioreactor Management Information System (IBM-IS).

  6. Gas pollution control apparatus and method and wood drying system employing same

    SciTech Connect (OSTI)

    Eatherton, J.R.

    1984-02-14

    Pollution control apparatus and method are disclosed in which hot exhaust gas containing pollutants including solid particles and hydrocarbon vapors is treated by transmitting such exhaust gas through a container containing wood members, such as wood chips, which serve as a filter media for filtering out such pollutants by causing such solids to deposit and such hydrocarbon vapors to condense upon the surface of the wood members. The contaminated wood chips are discharged from the filter and further processed into chip board or other commercial wood products thereby disposing of the pollutants. Lumber may be used as the wood members of the filter in a lumber kiln by deposition of solid particles on the rough surface of such lumber. The contaminated surfaces of the lumber are removed by a planer which produces a smooth finished lumber and contaminated wood chips that may be processed into chip board or other commercial wood products. A wood drying system employing such pollution control apparatus and method includes a hot air dryer for wood or other organic material, such as a wood chip rotary dryer or a wood veneer dryer, which produces hot exhaust gases containing pollutants including hydrocarbon vapors and solid particles. This hot exhaust air is transmitted through a lumber kiln to dry lumber thereby conserving heat energy and causing solid particle pollutants to deposit on the surface of the lumber. The kiln exhaust air containing solid and hydrocarbon vapor pollutants is then transmitted up through a filter stack of wood chips.

  7. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    SciTech Connect (OSTI)

    Reigel, M. M.

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  8. Literature review: Assessment of DWPF melter and melter off-gas system lifetime

    SciTech Connect (OSTI)

    Reigel, M.

    2015-07-30

    A glass melter for use in processing radioactive waste is a challenging environment for the materials of construction (MOC) resulting from a combination of high temperatures, chemical attack, and erosion/corrosion; therefore, highly engineered materials must be selected for this application. The focus of this report is to review the testing and evaluations used in the selection of the Defense Waste Processing Facility (DWPF), glass contact MOC specifically the Monofrax® K-3 refractory and Inconel® 690 alloy. The degradation or corrosion mechanisms of these materials during pilot scale testing and in-service operation were analyzed over a range of oxidizing and reducing flowsheets; however, DWPF has primarily processed a reducing flowsheet (i.e., Fe2+/ΣFe of 0.09 to 0.33) since the start of radioactive operations. This report also discusses the materials selection for the DWPF off-gas system and the corrosion evaluation of these materials during pilot scale testing and non-radioactive operations of DWPF Melter #1. Inspection of the off-gas components has not been performed during radioactive operations with the exception of maintenance because of plugging.

  9. Optimal integrated design of air separation unit and gas turbine block for IGCC systems

    SciTech Connect (OSTI)

    Kamath, R.; Grossman, I.; Biegler, L.; Zitney, S.

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  10. Optimal Integrated Design of Air Separation Unit and Gas Turbine Block for IGCC Systems

    SciTech Connect (OSTI)

    Ravindra S. Kamath; Ignacio E. Grossmann; Lorenz T. Biegler; Stephen E. Zitney

    2009-01-01

    The Integrated Gasification Combined Cycle (IGCC) systems are considered as a promising technology for power generation. However, they are not yet in widespread commercial use and opportunities remain to improve system feasibility and profitability via improved process integration. This work focuses on the integrated design of gasification system, air separation unit (ASU) and the gas turbine (GT) block. The ASU supplies oxygen to the gasification system and it can also supply nitrogen (if required as a diluent) to the gas turbine block with minimal incremental cost. Since both GT and the ASU require a source of compressed air, integrating the air requirement of these units is a logical starting point for facility optimization (Smith et al., 1997). Air extraction from the GT can reduce or avoid the compression cost in the ASU and the nitrogen injection can reduce NOx emissions and promote trouble-free operation of the GT block (Wimer et al., 2006). There are several possible degrees of integration between the ASU and the GT (Smith and Klosek, 2001). In the case of 'total' integration, where all the air required for the ASU is supplied by the GT compressor and the ASU is expected to be an elevated-pressure (EP) type. Alternatively, the ASU can be 'stand alone' without any integration with the GT. In this case, the ASU operates at low pressure (LP), with its own air compressor delivering air to the cryogenic process at the minimum energy cost. Here, nitrogen may or may not be injected because of the energy penalty issue and instead, syngas humidification may be preferred. A design, which is intermediate between these two cases, involves partial supply of air by the gas turbine and the remainder by a separate air compressor. These integration schemes have been utilized in some IGCC projects. Examples include Nuon Power Plant at Buggenum, Netherlands (both air and nitrogen integration), Polk Power Station at Tampa, US (nitrogen-only integration) and LGTI at Plaquemine

  11. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  12. EIA - Natural Gas Pipeline Network - Largest Natural Gas Pipeline...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... distribution, or storage operations. 2 Capacity ... as found in the Energy Information Administration, Natural Gas Transportation Information System, Natural Gas ...

  13. Design of an Online Fission Gas Monitoring System for Post-irradiation Examination Heating Tests of Coated Fuel Particles for High-Temperature Gas-Cooled Reactors

    SciTech Connect (OSTI)

    Dawn Scates

    2010-10-01

    A new Fission Gas Monitoring System (FGMS) has been designed at the Idaho National Laboratory (INL) for use of monitoring online fission gas-released during fuel heating tests. The FGMS will be used with the Fuel Accident Condition Simulator (FACS) at the Hot Fuels Examination Facility (HFEF) located at the Materials and Fuels Complex (MFC) within the INL campus. Preselected Advanced Gas Reactor (AGR) TRISO (Tri-isotropic) fuel compacts will undergo testing to assess the fission product retention characteristics under high temperature accident conditions. The FACS furnace will heat the fuel to temperatures up to 2,000ºC in a helium atmosphere. Released fission products such as Kr and Xe isotopes will be transported downstream to the FGMS where they will accumulate in cryogenically cooledcollection traps and monitored with High Purity Germanium (HPGe) detectors during the heating process. Special INL developed software will be used to monitor the accumulated fission products and will report data in near real-time. These data will then be reported in a form that can be readily available to the INL reporting database. This paper describes the details of the FGMS design, the control and acqusition software, system calibration, and the expected performance of the FGMS. Preliminary online data may be available for presentation at the High Temperature Reactor (HTR) conference.

  14. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    SciTech Connect (OSTI)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobility in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.

  15. LaTiO₃/KTaO₃ interfaces: A new two-dimensional electron gas system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zou, K.; Ismail-Beigi, Sohrab; Kisslinger, Kim; Shen, Xuan; Su, Dong; Walker, F. J.; Ahn, C. H.

    2015-03-01

    We report a new 2D electron gas (2DEG) system at the interface between a Mott insulator, LaTiO₃, and a band insulator, KTaO₃. For LaTiO₃/KTaO₃ interfaces, we observe metallic conduction from 2 K to 300 K. One serious technological limitation of SrTiO₃-based conducting oxide interfaces for electronics applications is the relatively low carrier mobility (0.5-10 cm²/V s) of SrTiO₃ at room temperature. By using KTaO₃, we achieve mobilities in LaTiO₃/KTaO₃ interfaces as high as 21 cm²/V s at room temperature, over a factor of 3 higher than observed in doped bulk SrTiO₃. By density functional theory, we attribute the higher mobilitymore » in KTaO₃ 2DEGs to the smaller effective mass for electrons in KTaO₃.« less

  16. Chapter 7: Advancing Systems and Technologies to Produce Cleaner Fuels | Unconventional Oil and Gas Technology Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infrastructure Offshore Safety and Spill Prevention Unconventional Oil and Gas ENERGY U.S. DEPARTMENT OF Quadrennial Technology Review 2015 1 Quadrennial Technology Review 2015 Unconventional Oil and Gas Chapter 7: Technology Assessments Executive Summary The United States will, for the foreseeable future, continue to rely heavily upon oil and natural gas to support our economy, national security, and energy security. Given the increasing reliance on unconventional oil and gas (UOG) resources,

  17. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  18. Operational Challenges in Gas-To-Liquid (GTL) Transportation Through Trans Alaska Pipeline System (TAPS)

    SciTech Connect (OSTI)

    Godwin A. Chukwu; Santanu Khataniar; Shirish Patil; Abhijit Dandekar

    2006-06-30

    Oil production from Alaskan North Slope oil fields has steadily declined. In the near future, ANS crude oil production will decline to such a level (200,000 to 400,000 bbl/day) that maintaining economic operation of the Trans-Alaska Pipeline System (TAPS) will require pumping alternative products through the system. Heavy oil deposits in the West Sak and Ugnu formations are a potential resource, although transporting these products involves addressing important sedimentation issues. One possibility is the use of Gas-to-Liquid (GTL) technology. Estimated recoverable gas reserves of 38 trillion cubic feet (TCF) on the North Slope of Alaska can be converted to liquid with GTL technology and combined with the heavy oils for a product suitable for pipeline transport. Issues that could affect transport of this such products through TAPS include pumpability of GTL and crude oil blends, cold restart of the pipeline following a prolonged winter shutdown, and solids deposition inside the pipeline. This study examined several key fluid properties of GTL, crude oil and four selected blends under TAPS operating conditions. Key measurements included Reid Vapor Pressure, density and viscosity, PVT properties, and solids deposition. Results showed that gel strength is not a significant factor for the ratios of GTL-crude oil blend mixtures (1:1; 1:2; 1:3; 1:4) tested under TAPS cold re-start conditions at temperatures above - 20 F, although Bingham fluid flow characteristics exhibited by the blends at low temperatures indicate high pumping power requirements following prolonged shutdown. Solids deposition is a major concern for all studied blends. For the commingled flow profile studied, decreased throughput can result in increased and more rapid solid deposition along the pipe wall, resulting in more frequent pigging of the pipeline or, if left unchecked, pipeline corrosion.

  19. Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream

    DOE Patents [OSTI]

    Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

    2014-07-08

    The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

  20. Initial Requirements for Gas-Cooled Fast Reactor (GFR) System Design, Performance, and Safety Analysis Models

    SciTech Connect (OSTI)

    Kevan D. Weaver; Thomas Y. C. Wei

    2004-08-01

    The gas-cooled fast reactor (GFR) was chosen as one of the Generation IV nuclear reactor systems to be developed based on its excellent potential for sustainability through reduction of the volume and radio toxicity of both its own fuel and other spent nuclear fuel, and for extending/utilizing uranium resources orders of magnitude beyond what the current open fuel cycle can realize. In addition, energy conversion at high thermal efficiency is possible with the current designs being considered, thus increasing the economic benefit of the GFR. However, research and development challenges include the ability to use passive decay heat removal systems during accident conditions, survivability of fuels and in-core materials under extreme temperatures and radiation, and economical and efficient fuel cycle processes. Nevertheless, the GFR was chosen as one of only six Generation IV systems to be pursued based on its ability to meet the Generation IV goals in sustainability, economics, safety and reliability, proliferation resistance and physical protection.