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1

Electricity production levelized costs for nuclear, gas and coal  

Office of Scientific and Technical Information (OSTI)

Levelized costs for nuclear, gas and coal for Electricity, under the Mexican scenario. Javier C. Palacios, Gustavo Alonso, Ramn Ramrez, Armando Gmez, Javier Ortiz, Luis C....

2

Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power  

SciTech Connect (OSTI)

This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

Milbrandt, A.; Mann, M.

2009-02-01T23:59:59.000Z

3

Coal beneficiation by gas agglomeration  

DOE Patents [OSTI]

Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

Wheelock, Thomas D.; Meiyu, Shen

2003-10-14T23:59:59.000Z

4

Assessment of coal bed gas prospects  

SciTech Connect (OSTI)

Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

1996-12-31T23:59:59.000Z

5

Interaction of coal-derived synthesis gas impurities with solid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

coal-derived synthesis gas impurities with solid oxide fuel cell metallic components. Interaction of coal-derived synthesis gas impurities with solid oxide fuel cell metallic...

6

Gas distributor for fluidized bed coal gasifier  

DOE Patents [OSTI]

A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

1980-01-01T23:59:59.000Z

7

Coal seam natural gas producing areas (Louisiana)  

Broader source: Energy.gov [DOE]

In order to prevent waste and to avoid the drilling of unnecessary wells and to encourage the development of coal seam natural gas producing areas in Louisiana, the commissioner of conservation is...

8

System Analysis of Nuclear-Assisted Syngas Production from Coal  

SciTech Connect (OSTI)

A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via hightemperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 64.4% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

E. A. Harvego; M. G. McKellar; J. E. O'Brien

2009-07-01T23:59:59.000Z

9

Advanced Coal-Fueled Gas Turbine Program  

SciTech Connect (OSTI)

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

10

Production of Substitute Natural Gas from Coal  

SciTech Connect (OSTI)

The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

Andrew Lucero

2009-01-31T23:59:59.000Z

11

Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

12

Coal and nuclear power: Illinois' energy future  

SciTech Connect (OSTI)

This conference was sponsored by the Energy Resources Center, University of Illinois at Chicago; the US Department of Energy; the Illinois Energy Resources Commission; and the Illinois Department of Energy and Natural Resources. The theme for the conference, Coal and Nuclear Power: Illinois' Energy Future, was based on two major observations: (1) Illinois has the largest reserves of bituminous coal of any state and is surpassed in total reserves only by North Dakota, and Montana; and (2) Illinois has made a heavy commitment to the use of nuclear power as a source of electrical power generation. Currently, nuclear power represents 30% of the electrical energy produced in the State. The primary objective of the 1982 conference was to review these two energy sources in view of the current energy policy of the Reagan Administration, and to examine the impact these policies have on the Midwest energy scene. The conference dealt with issues unique to Illinois as well as those facing the entire nation. A separate abstract was prepared for each of the 30 individual presentations.

Not Available

1982-01-01T23:59:59.000Z

13

E-Print Network 3.0 - advanced slagging coal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reductions... technologies such as clean coal, natural gas, nuclear, hydro, wind, and solar photovoltaic technologies... -firing switchgrass and coal in existing coal fired...

14

Testing for market integration crude oil, coal, and natural gas  

SciTech Connect (OSTI)

Prompted by the contemporaneous spike in coal, oil, and natural gas prices, this paper evaluates the degree of market integration both within and between crude oil, coal, and natural gas markets. Our approach yields parameters that can be readily tested against a priori conjectures. Using daily price data for five very different crude oils, we conclude that the world oil market is a single, highly integrated economic market. On the other hand, coal prices at five trading locations across the United States are cointegrated, but the degree of market integration is much weaker, particularly between Western and Eastern coals. Finally, we show that crude oil, coal, and natural gas markets are only very weakly integrated. Our results indicate that there is not a primary energy market. Despite current price peaks, it is not useful to think of a primary energy market, except in a very long run context.

Bachmeier, L.J.; Griffin, J.M. [Texas A& amp; M Univ, College Station, TX (United States)

2006-07-01T23:59:59.000Z

15

Unconventional (borehole) Technologies for Gas Fuel Producing from Coal  

E-Print Network [OSTI]

The scheme discribtion of borehole thechnologies for coal fields utilization is cited in the report. The merits and shortages of the technologies are discussed. The several conclusions are expressed. Key words: borehole technology, coal seam, coalbed methane, recovery, comparision. Geotechnology is the method of raw fossil recovery through the surface boreholes. The raw fossil may be presented both liquid and gas or hard materials. The geotechnological methods have used since beginning of XX century. Conventional methods of coal mining permit to receive 7-9 % useful energy from coal in situ potential energy (calorific value of it). This energy effectiveness have calculated on the base of mining and transportation and processing of the coal [1]. Besides, capacity of labour during underground mining activity is not very high and is evaluated as 0.02-0.5 man-sheet per one ton of coal. The coal mining is accompanied high shake of extracted rock (in Russian coal fields as many as 25-27%). As much as 8-12 tones of clean air are given for one ton of the produced coal. The coefficient of fatal accidents in the coal mines ranges as 1.2-1.5 per 1 million tons of the coal recovery. Underground (mines) and surface (open pits) mining make negative influence on the environment.

Vasyuchkov Yu. F; Vasyuchkov M. Yu

16

Coal liquefaction and gas conversion: Proceedings. Volume 1  

SciTech Connect (OSTI)

Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1993-12-31T23:59:59.000Z

17

Two-stage coal liquefaction without gas-phase hydrogen  

DOE Patents [OSTI]

A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

Stephens, H.P.

1986-06-05T23:59:59.000Z

18

Combining Nuclear Power With Coal-to-Gasoline Conversion  

SciTech Connect (OSTI)

With coal representing 95% and oil only 2.5% of the US fossil fuel reserves and with the abundant nuclear fuel reserves in the US, such combined plants should be built in the near future. (authors)

Hamel, H.J.; Jaeger, Walter; Termuehlen, Heinz

2006-07-01T23:59:59.000Z

19

Gas Centrifuges and Nuclear Proliferation  

SciTech Connect (OSTI)

Gas centrifuges have been an ideal enrichment method for a wide variety of countries. Many countries have built gas centrifuges to make enriched uranium for peaceful nuclear purposes. Other countries have secretly sought centrifuges to make highly enriched uranium for nuclear weapons. In more recent times, several countries have secretly sought or built gas centrifuges in regions of tension. The main countries that have been of interest in the last two decades have been Pakistan, Iraq, Iran, and North Korea. Currently, most attention is focused on Iran, Pakistan, and North Korea. These states did not have the indigenous abilities to make gas centrifuges, focusing instead on illicit and questionable foreign procurement. The presentation covered the following main sections: Spread of centrifuges through illicit procurement; Role of export controls in stopping proliferation; Increasing the transparency of gas centrifuge programs in non-nuclear weapon states; and, Verified dismantlement of gas centrifuge programs. Gas centrifuges are important providers of low enriched uranium for civil nuclear power reactors. They also pose special nuclear proliferation risks. We all have special responsibilities to prevent the spread of gas centrifuges into regions of tension and to mitigate the consequences of their spread into the Middle East, South Asia, and North Asia.

Albright, David

2004-09-15T23:59:59.000Z

20

Uncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal  

E-Print Network [OSTI]

analyses involving coal. Greenhouse gas emissions from fuel use and methane releases at coal mines, fuel.5 million metric tons of methane emissions. Close to 95% of domestic coal was consumed by the electricityUncertainty in Life Cycle Greenhouse Gas Emissions from United States Coal Aranya Venkatesh

Jaramillo, Paulina

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents [OSTI]

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

22

Optimal transition from coal to gas and renewable power under capacity constraints and adjustment costs  

E-Print Network [OSTI]

Optimal transition from coal to gas and renewable power under capacity constraints and adjustment existing coal power plants to gas and renewable power under a carbon budget. It solves a model of polluting, exhaustible resources with capacity constraints and adjustment costs (to build coal, gas, and renewable power

Paris-Sud XI, Université de

23

Demonstration of a Carbonate Fuel Cell on Coal Derived Gas  

E-Print Network [OSTI]

system has run on actual syn-gas. Consequently, the Electric Power Research Institute (“EPRI”) has sponsored a 20 kW carbonate fuel cell pilot plant that will begin operating in March at Destec Energy’s coal gasification plant in Plaquemine, Louisiana...

Rastler, D. M.; Keeler, C. G.; Chi, C. V.

24

Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier  

DOE Patents [OSTI]

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

Grindley, Thomas (Morgantown, WV)

1989-01-01T23:59:59.000Z

25

The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1  

E-Print Network [OSTI]

technologies. · Coal Conversion Technologies. Coal-based power generation technologies were analyzed in detail1 The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1 , James Katzer1 1 M coal can make to the growing world energy demand during a period of increasing concern about global

26

Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION MEANS  

E-Print Network [OSTI]

Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION to the surface is especially significant in the context of coal mines. This is because mine gas can migrate of the scheduled closure of all coal mining operations in France, INERIS has drawn up, at the request of national

Paris-Sud XI, Université de

27

Comparative Assessment of Coal-and Natural Gas-fired Power Plants under a  

E-Print Network [OSTI]

Comparative Assessment of Coal- and Natural Gas-fired Power Plants under a CO2 Emission Performance standard (EPS) for pulverized coal (PC) and natural gas combined cycle (NGCC) power plants; · Evaluate% · Natural Gas-fired Power Plant: Adv. 7F Gas Turbine Capacity Factor 75% · Cost Basis: 2007$, constant 7

28

Slag processing system for direct coal-fired gas turbines  

DOE Patents [OSTI]

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

Pillsbury, Paul W. (Winter Springs, FL)

1990-01-01T23:59:59.000Z

29

Advanced Coal-Fueled Gas Turbine Program. Final report  

SciTech Connect (OSTI)

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

30

Durable zinc ferrite sorbent pellets for hot coal gas desulfurization  

DOE Patents [OSTI]

Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

1988-01-01T23:59:59.000Z

31

Slag processing system for direct coal-fired gas turbines  

DOE Patents [OSTI]

Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

Pillsbury, Paul W. (Winter Springs, FL)

1990-01-01T23:59:59.000Z

32

Using Auxiliary Gas Power for CCS Energy Needs in Retrofitted Coal Power Plants  

E-Print Network [OSTI]

1 Using Auxiliary Gas Power for CCS Energy Needs in Retrofitted Coal Power Plants by Sarah Bashadi and Policy Program #12;2 #12;3 Using Auxiliary Gas Power for CCS Energy Needs in Retrofitted Coal Power, a significant amount of excess power was produced using both gas turbine configurations. This excess power could

33

Rock, Mineral, Coal, Oil, and Gas Resources on State Lands (Montana)  

Broader source: Energy.gov [DOE]

This chapter authorizes and regulates prospecting permits and mining leases for the exploration and development of rock, mineral, oil, coal, and gas resources on state lands.

34

CO2 gas production understanding above a partly flooded coal post-mining area  

E-Print Network [OSTI]

- The Westphalian deposit is constituted by numerous exploited coal seams of different thicknesses. These seamsCO2 gas production understanding above a partly flooded coal post-mining area Candice Lagnya, a former coal mining area. To understand the origin of this production, a borehole of 90 meters deep

Paris-Sud XI, Université de

35

Gas-cooled nuclear reactor  

DOE Patents [OSTI]

A gas-cooled nuclear reactor includes a central core located in the lower portion of a prestressed concrete reactor vessel. Primary coolant gas flows upward through the core and into four overlying heat-exchangers wherein stream is generated. During normal operation, the return flow of coolant is between the core and the vessel sidewall to a pair of motor-driven circulators located at about the bottom of the concrete pressure vessel. The circulators repressurize the gas coolant and return it back to the core through passageways in the underlying core structure. If during emergency conditions the primary circulators are no longer functioning, the decay heat is effectively removed from the core by means of natural convection circulation. The hot gas rising through the core exits the top of the shroud of the heat-exchangers and flows radially outward to the sidewall of the concrete pressure vessel. A metal liner covers the entire inside concrete surfaces of the concrete pressure vessel, and cooling tubes are welded to the exterior or concrete side of the metal liner. The gas coolant is in direct contact with the interior surface of the metal liner and transfers its heat through the metal liner to the liquid coolant flowing through the cooling tubes. The cooler gas is more dense and creates a downward convection flow in the region between the core and the sidewall until it reaches the bottom of the concrete pressure vessel when it flows radially inward and up into the core for another pass. Water is forced to flow through the cooling tubes to absorb heat from the core at a sufficient rate to remove enough of the decay heat created in the core to prevent overheating of the core or the vessel.

Peinado, Charles O. (La Jolla, CA); Koutz, Stanley L. (San Diego, CA)

1985-01-01T23:59:59.000Z

36

Manganese-based sorbents for coal gas desulfurization  

SciTech Connect (OSTI)

The intent of this study is to perform a preliminary screening on a particular Mn-based sorbent, CST-939 (from Chemetals), for hot gas desulfurization. The purpose of the preliminary screening is to determine which temperature and type of coal gas this sorbent demonstrates the greatest capacity and efficiency for sulfur removal. The following conclusions were made from the data collected on the CST-939 sorbent: The sorbent efficiency and capacity are much greater at 343{degrees}C (650{degrees}F) than at 871{degrees}C (1,600{degrees}F). The sorbent efficiency and capacity are much greater in the presence of the more highly-reducing Shell gas than with the less-reducing KRW gas. The sorbent showed tremendous capacity for sulfur pickup, with actual loadings as high as 21 weight percent. Oxidative regeneration at 871{degrees}C (1,600{degrees}F) appeared to decompose sulfate; however, unusually high SO{sub 2} release during the second sulfidations and/or reductive regenerations indicated incomplete regeneration. The average crush strength of the reacted sorbent did not indicate any loss of strength as compared to the fresh sorbent. Superior sorbent performance was obtained in the presence of simulated Shell gas at 538{degrees}C (1,000{degrees}F).

Gasper-Galvin, L.D.; Fisher, E.P. [USDOE Morgantown Energy Technology Center, WV (United States); Goyette, W.J. [Chemetals, Inc., Baltimore, MD (United States)

1996-12-31T23:59:59.000Z

37

Water Extraction from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

2006-06-30T23:59:59.000Z

38

Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown – Dataset  

Broader source: Energy.gov [DOE]

Excel file with dataset for Fact #844: Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

39

Silica membranes for hydrogen separation from coal gas. Final report  

SciTech Connect (OSTI)

This project is a continuation of a previous DOE-UCR project (DE-FG22- 89PC89765) dealing with the preparation of silica membranes highly permselective to hydrogen at elevated temperatures, suitable for hydrogen separation from coal gas. The membranes prepared in the previous project had very high selectivity but relatively low permeance. Therefore, the general objectives of this project were to improve the permeance of these membranes and to obtain fundamental information about membrane structure and properties. The specific objectives were: (1) to explore new silylation reagents and reaction conditions with the purpose of reducing the thickness and increasing the permeance of silica membranes prepared by chemical vapor deposition (CVD), (2) to characterize the membrane structure, (3) to delineate mechanism and kinetics of deposition, (4) to measure the permeability of silica layers at different extents of deposition, and (5) to mathematically model the relationship between structure and deposition kinetics.

Gavalas, G.R.

1996-01-01T23:59:59.000Z

40

Hot coal gas desulfurization with manganese-based sorbents  

SciTech Connect (OSTI)

The primary major deposit of manganese in the US which can be readily mined by an in situ process is located in the Emily district of Minnesota. The US Bureau of Mines Research Centers at both the Twin Cities and Salt Lake City have developed a process for extracting and refining manganese in the form of a high-purity carbonate product. This product has been formulated into pellets by a multi-step process of drying, calcination, and induration to produce relatively high-strength formulations which are capable of being used for hot fuel gas desulfurization. These pellets, which have been developed at the University of Minnesota under joint sponsorship of the US Department of Energy and the US Bureau of Mines, appear superior to other, more expensive, formulations of zinc titanate and zinc ferrite which have previously been studied for multi-cycle loading (desulfurization) and regeneration (evolution of high-strength SO{sub 2} and restoration of pellet reactivity). Although these other formulations have been under development for the past twelve years, their prices still exceed $7 per pound. If manganese pellets perform as predicted in fixed bed testing, and if a significant number of utilities which burn high-sulfur coals incorporate combined-cycle gasification with hot coal gas desulfurization as a viable means of increasing conversion efficiencies, then the potential market for manganese pellets may be as high as 200,000 tons per year at a price not less than $3 per pound. This paper discusses the role of manganese pellets in the desulfurization process with respect to the integrated gasification combined-cycle (IGCC) for power generation.

Hepworth, M.T.; Ben-Slimane, R.

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems  

SciTech Connect (OSTI)

The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

Not Available

1990-12-01T23:59:59.000Z

42

Process for the production of fuel gas from coal  

DOE Patents [OSTI]

An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

Patel, Jitendra G. (Bolingbrook, IL); Sandstrom, William A. (Chicago, IL); Tarman, Paul B. (Elmhurst, IL)

1982-01-01T23:59:59.000Z

43

Dry flue gas desulfurization process for various coals  

SciTech Connect (OSTI)

Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coal-fired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone. Calcium-based wet systems have, in general, satisfied SO/sub 2/ removal requirements; however, reliability of the early systems was affected by some operational problems. Additionally, sludge dewatering and disposal equipment results in overall system complexity. A dry FGD process which minimizes these problems was developed in late 1970's. It incorporates a spray drying concept for removal of SO/sub 2/ by reaction with lime slurry or soda ash solution. The spray dryer absorber is followed by an electrostatic precipitator or a fabric filter where particulates are collected. The waste product, which is a mixture of FGD reaction products, unreacted reagent and fly ash, is dry thus eliminating the need for dewatering equipment.

Widico, M.J.; Dhargalkar, P.H.

1985-01-01T23:59:59.000Z

44

An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters  

E-Print Network [OSTI]

of these factors, the difference between coal and natural gas prices and the project life are difficult to predict. The resulting uncertainty has caused Monsanto to pursue coal gasification for process heaters with cautious optimism, on a site by site basis....

Nebeker, C. J.

1982-01-01T23:59:59.000Z

45

The competition between coal and natural gas : the importance of sunk costs  

E-Print Network [OSTI]

This paper explores the seeming paradox between the predominant choice of natural gas for capacity additions to generate electricity in the United States and the continuing large share of coal in meeting incremental ...

Ellerman, A. Denny

1996-01-01T23:59:59.000Z

46

Modeling of Gas Extraction from Closed Coal Mines C. Lagny & Z. Pokryszka  

E-Print Network [OSTI]

Modeling of Gas Extraction from Closed Coal Mines C. Lagny & Z. Pokryszka Direction des risques du gas flow rate. Validations were made for several years. This model is able to evaluate firedamp of indus- trial gas drainage from the surface. In this aim, a specific mathematical model has been

Paris-Sud XI, Université de

47

Modeling of gas generation from the Cameo coal zone in the Piceance Basin Colorado  

SciTech Connect (OSTI)

The gas generative potential of the Cretaceous Cameo coal in the Piceance Basin, northwestern Colorado, was evaluated quantitatively by sealed gold tube pyrolysis. The H/C and O/C elemental ratios show that pyrolyzed Cameo coal samples follow the Van Krevelen humic coal evolution pathway, reasonably simulating natural coal maturation. Kinetic parameters (activation energy and frequency factor) for gas generation and vitrinite reflectance (R{sub o}) changes were calculated from pyrolysis data. Experimental R{sub o} results from this study are not adequately predicted by published R{sub o} kinetics and indicate the necessity of deriving basin-specific kinetic parameters when building predictive basin models. Using derived kinetics for R{sub o}, evolution and gas generation, basin modeling was completed for 57 wells across the Piceance Basin, which enabled the mapping of coal-rank and coalbed gas potential. Quantities of methane generated at approximately 1.2% R{sub o} are about 300 standard cubic feet per ton (scf/ton) and more than 2500 scf/ton (in-situ dry-ash-free coal) at R{sub o}, values reaching 1.9%. Gases generated in both low- and high-maturity coals are less wet, whereas the wetter gas is expected where R{sub o} is approximately 1.4-1.5%. As controlled by regional coal rank and net coal thickness, the largest in-place coalbed gas resources are located in the central part of the basin, where predicted volumes exceed 150 bcf/mi, excluding gases in tight sands.

Zhang, E.; Hill, R.J.; Katz, B.J.; Tang, Y.C. [Shell Exploration and Production Co., BTC, Houston, TX (United States)

2008-08-15T23:59:59.000Z

48

Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier  

DOE Patents [OSTI]

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

Grindley, T.

1988-04-05T23:59:59.000Z

49

Potential growth of nuclear and coal electricity generation in the US  

SciTech Connect (OSTI)

Electricity demand should continue to grow at about the same rate as GNP, creating a need for large amounts of new generating capacity over the next fifty years. Only coal and nuclear at this time have the abundant domestic resources and assured technology to meet this need. However, large increase in both coal and nuclear usage will require solutions to many of the problems that now deter their increased usage. For coal, the problems center around the safety and environmental impacts of increased coal mining and coal combustion. For nuclear, the problems center around reactor safety, radioactive waste disposal, financial risk, and nuclear materials safeguards. This report assesses the impacts associated with a range of projected growth rates in electricity demand over the next 50 years. The resource requirements and waste generation resulting from pursuing the coal and nuclear fuel options to meet the projected growth rates are estimated. The fuel requirements and waste generation for coal plants are orders of magnitude greater than for nuclear. Improvements in technology and waste management practices must be pursued to mitigate environmental and safety concerns about electricity generation from both options. 34 refs., 18 figs., 14 tabs.

Bloomster, C.H.; Merrill, E.T.

1989-08-01T23:59:59.000Z

50

Viability of an expanded United States nuclear power program and its effects on energy markets  

E-Print Network [OSTI]

The four biggest energy sources in the United States are coal, crude oil, natural gas, and nuclear power. While coal and nuclear power are produced domestically, more than 70% of crude oil and 20% of natural gas is imported. ...

Khan, Tanzeer S

2006-01-01T23:59:59.000Z

51

Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright 2014 Inderscience Enterprises Ltd.  

E-Print Network [OSTI]

Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright © 2014 Inderscience fields in Saudi Arabia', Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, pp.115­131. Biographical economic recovery of oil and gas from a reservoir. The purpose of reservoir management is to control

Mohaghegh, Shahab

52

Neural net controlled tag gas sampling system for nuclear reactors  

DOE Patents [OSTI]

A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

Gross, Kenneth C. (Bolingbrook, IL); Laug, Matthew T. (Idaho Fall, ID); Lambert, John D. B. (Wheaton, IL); Herzog, James P. (Downers Grove, IL)

1997-01-01T23:59:59.000Z

53

Neural net controlled tag gas sampling system for nuclear reactors  

DOE Patents [OSTI]

A method and system are disclosed for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod. 12 figs.

Gross, K.C.; Laug, M.T.; Lambert, J.B.; Herzog, J.P.

1997-02-11T23:59:59.000Z

54

Comment on the “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”  

SciTech Connect (OSTI)

A communication in response to the excellent and timely paper entitled “Role of SO2 for Elemental Mercury Removal from Coal Combustion Flue Gas by Activated Carbon”.

Granite, E.J.; Presto, A.A.

2008-09-01T23:59:59.000Z

55

Environmental trends in Asia are accelerating the introduction of clean coal technologies and natural gas  

SciTech Connect (OSTI)

This paper examines the changing energy mix for Asia to 2020, and impacts of increased coal consumption on Asia`s share of world SO{sub 2} and CO{sub 2} emissions. Stricter SO{sub 2} emissions laws are summarized for eight Asian economies along with implications for fuel and technology choices. The paper compares the economics of different technologies for coal and natural gas in 1997 and in 2007. Trends toward introducing clean coal technologies and the use of natural gas will accelerate in response to tighter environmental standards by 2000. The most important coal conversion technology for Asia, particularly China, in the long term is likely to be integrated gasification combined-cycle (IGCC), but only under the assumption of multiple products.

Johnson, C.J.

1997-09-01T23:59:59.000Z

56

E-Print Network 3.0 - alaska natural gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Ecology 17 Some "Lessons Learned" FromSome Lessons Learned From A Career In The Energy Business Summary: Consumption* Coal Oil 38% Nuclear 9% Natural Gas Coal Coal 22%...

57

NNSA implements nondestructive gas sampling technique for nuclear...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

implements ... NNSA implements nondestructive gas sampling technique for nuclear weapon components Posted: June 12, 2012 - 1:34pm The National Nuclear Security Administration...

58

Modeling gas displacement kinetics in coal with Maxwell-Stefan diffusion theory  

SciTech Connect (OSTI)

The kinetics of binary gas counter-diffusion and Darcy flow in a large coal sample were modeled, and the results compared with data from experimental laboratory investigations. The study aimed for a better understanding of the CO{sub 2}-sequestration enhanced coalbed methane (ECBM) recovery process. The transport model used was based on the bidisperse diffusion mechanism and Maxwell-Stefan (MS) diffusion theory. This provides an alternative approach to simulate multicomponent gas diffusion and flow in bulk coals. A series of high-stress core flush tests were performed on a large coal sample sourced from a Bowen Basin coal mine in Queensland, Australia to investigate the kinetics of one gas displacing another. These experimental results were used to derive gas diffusivities, and to examine the predictive capability of the diffusion model. The simulations show good agreements with the displacement experiments revealing that MS diffusion theory is superior for describing diffusion of mixed gases in coals compared with the constant Fick diffusivity model. The optimized effective micropore and macropore diffusivities are comparable with experimental measurements achieved by other researchers.

Wei, X.R.; Wang, G.X.; Massarotto, P.; Rudolph, V.; Golding, S.D. [University of Queensland, Brisbane, Qld. (Australia). Division of Chemical Engineering

2007-12-15T23:59:59.000Z

59

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect (OSTI)

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (SO{sub x}) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Because of cost growth and lack of available funding, no further work has been done after Phase 1 at site B; the wall fired unit.

Not Available

1992-02-07T23:59:59.000Z

60

Secondary porosity and permeability of coal vs. gas composition and pressure  

SciTech Connect (OSTI)

We have been investigating the sequestration of atmospheric pollutants by injection into coal seams while at the same time enhancing hydrocarbon productivity by displacement of methane with pollutants. We found that changing the composition of the gas sorbed into the coal changes the porosity and permeability of the coal natural-fracture system owing to gas-content changes, which cause matrix swelling or shrinkage due to relative adsorption of different gases. We collected sufficient information to develop a method for predicting the permeability and porosity of a coalbed as a function of the secondary porosity system (SPS) pressure and the gas content and composition of the primary porosity system (PPS). The method uses data from injection/falloff tests with water and/or a weaker adsorbing gas (WAG) than CH{sub 4} and a stronger adsorbing gas (SAG) than CH{sub 4}. Estimates of effective permeability to gas and water obtained from these tests are used with an iterative computation procedure subject to constraints to solve for equivalent SPS porosity and absolute permeability at atmospheric pressure. Once calibrated, the model can be used to predict a coalbed's permeability and porosity as a function of injection pressure and injected-fluid composition, which in turn are used to predict injection performance. The model is applicable to production forecasts to account for SPS permeability and porosity changes as reservoir pressure declines with changes in gas composition. This paper describes the new model and discusses well-test procedures to obtain the data required for model calibration. Also included are coal property estimates resulting from Alberta Medicine River (Manville) coal core and test data and an example model calibration.

Mavor, M.J,; Gunter, W.D. [Tesseract Corp., San Francisco, CA (United States)

2006-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Improved gas tagging and cover gas combination for nuclear reactor  

DOE Patents [OSTI]

The invention discloses the use of stable isotopes of neon and argon, sealed as tags in different cladding nuclear fuel elements to be used in a liquid metal fast breeder reactor. Cladding failure allows fission gases and these tag isotopes to escape and to combine with the cover gas. The isotopes are Ne/sup 20/, Ne/sup 21/ and Ne/sup 22/ and Ar/sup 36/, Ar/sup 38/ and Ar/sup 40/, and the cover gas is He. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between 0 and -25/sup 0/C to remove the fission gases from the cover gas and tags, and the second or tag recovery system bed between -170 and -185/sup 0/C to isolate the tags from the cover gas. Spectrometric analysis is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be determined.

Gross, K.C.; Laug, M.T.

1983-09-26T23:59:59.000Z

62

Gas tagging and cover gas combination for nuclear reactor  

DOE Patents [OSTI]

The invention discloses the use of stable isotopes of neon and argon, that are grouped in preselected different ratios one to the other and are then sealed as tags in different cladded nuclear fuel elements to be used in a liquid metal fast breeder reactor. Failure of the cladding of any fuel element allows fission gases generated in the reaction and these tag isotopes to escape and to combine with the cover gas held in the reactor over the fuel elements. The isotopes specifically are Ne.sup.20, Ne.sup.21 and Ne.sup.22 of neon and Ar.sup.36, Ar.sup.38 and Ar.sup.40 of argon, and the cover gas is helium. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between approximately 0.degree. and -25.degree. C. operable to remove the fission gases from the cover gas and tags and the second or tag recovery system bed is held between approximately -170.degree. and -185.degree. C. operable to isolate the tags from the cover gas. Spectrometric analysis further is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be specifically determined.

Gross, Kenny C. (Lemont, IL); Laug, Matthew T. (Idaho Falls, ID)

1985-01-01T23:59:59.000Z

63

Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in COAL IGCC Powerplants  

SciTech Connect (OSTI)

The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, has been re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for Coal IGCC powerplants. The new program has been re-titled as ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants'' to better match the new scope. This technical progress report summarizes the work accomplished in the reporting period April 1, 2004 to August 31, 2004 on the revised Re-Directed and De-Scoped program activity. The program Tasks are: Task 1--IGCC Environmental Impact on high Temperature Materials: This first materials task has been refocused to address Coal IGCC environmental impacts on high temperature materials use in gas turbines and remains in the program. This task will screen material performance and quantify the effects of high temperature erosion and corrosion of hot gas path materials in Coal IGCC applications. The materials of interest will include those in current service as well as advanced, high-performance alloys and coatings. Task 2--Material In-Service Health Monitoring: This second task develops and demonstrates new sensor technologies to determine the in-service health of advanced technology Coal IGCC powerplants, and remains in the program with a reduced scope. Its focus is now on only two critical sensor need areas for advanced Coal IGCC gas turbines: (1) Fuel Quality Sensor for detection of fuel impurities that could lead to rapid component degradation, and a Fuel Heating Value Sensor to rapidly determine the fuel heating value for more precise control of the gas turbine, and (2) Infra-Red Pyrometer to continuously measure the temperature of gas turbine buckets, nozzles, and combustor hardware.

Kenneth A. Yackly

2004-09-30T23:59:59.000Z

64

Advanced coal-fueled industrial cogeneration gas turbine system  

SciTech Connect (OSTI)

This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

1992-06-01T23:59:59.000Z

65

A Reusable Calcium-Based Sorbent for Desulfurizing Hot Coal Gas  

SciTech Connect (OSTI)

The overall objective of this project has been to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas. The sorbent should be strong, durable, inexpensive to manufacture, and capable of being reused many times. To achieve these objectives the project has focused on the development of the very promising core-in-shell sorbent.

Wheelock, T.D.; Hasler, D.J.L.

2002-09-19T23:59:59.000Z

66

Nuclear response beyond the Fermi gas model  

E-Print Network [OSTI]

The Fermi gas model, while providing a reasonable qualitative description of the continuum nuclear response, does not include the effects of dynamical nucleon-nucleon correlations in the initial and final states, that have long been recognized to play a critical role in specific kinematical regions. We review a many-body approach in which these effects are consistently taken into account and discuss the results of a calculation of the quasielastic neutrino-oxygen cross section as an illustrative example.

Omar Benhar

2003-07-14T23:59:59.000Z

67

System and method for producing substitute natural gas from coal  

DOE Patents [OSTI]

The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

Hobbs, Raymond (Avondale, AZ)

2012-08-07T23:59:59.000Z

68

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

69

Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal  

SciTech Connect (OSTI)

This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

Eric P. Robertson

2007-09-01T23:59:59.000Z

70

Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report  

SciTech Connect (OSTI)

Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

Not Available

1986-12-01T23:59:59.000Z

71

Controls of coal fabric on coalbed gas production and compositional shift in both field production and canister desorption tests  

SciTech Connect (OSTI)

The production rates of coalbed gas wells commonly vary significantly, even in the same field with similar reservoir permeability and gas content. The compositional variation in produced gas is also not everywhere predictable, although in most fields produced gas becomes progressively enriched in CO, through the production life of a reservoir, such as parts of the San Juan basin. In contrast, it is generally observed that the ratio of CO{sub 2}:CH{sub 4} declines with time during field and laboratory desorption testing of coal cores. In this study, we investigate numerically the importance of coal fabric, namely cleat spacing and aperture width, on the performance of coalbed gas wells and gas compositional shifts during production. Because of the cubic relationship between fracture permeability and fracture aperture width (and thus fracture porosity) for a given cleat permeability, the production profile of coal seams varies depending on whether the permeability is distributed among closely spaced fractures (cleat) with narrower apertures or more widely spaced fractures (cleat) with wider apertures. There is a lower fracture porosity for coal with widely spaced fractures than for coal with closely spaced fractures. Therefore, the relative permeability to gas increases more rapidly for coals with more widely spaced cleats as less dewatering from fractures is required, assuming that the fractures are initially water saturated. The enrichment of CO{sub 2} in the production gas with time occurs because of the stronger adsorption of coals for CO{sub 2} than CH{sub 4}. However, during desorption of coal cores, CO{sub 2} desorbs more rapidly than methane because desorption rate is governed more by diffusion than by sorption affinity, and CO{sub 2} has much higher effective diffusivity in microporous coals than CH{sub 4}.

Cui, X.J.; Bustin, R.M. [University of British Columbia, Vancouver, BC (Canada)

2006-03-15T23:59:59.000Z

72

Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel  

E-Print Network [OSTI]

Energy's patented technology produces a clean-burning by-product from the widest variety of processed-efficient technology represented by the coal-substitute technology. The same technology will be deployed by DIGGDigital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital

Columbia University

73

Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum  

SciTech Connect (OSTI)

The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

Jain, M.K.

1991-01-01T23:59:59.000Z

74

Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques  

SciTech Connect (OSTI)

Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

Mastalerz, Maria [Indiana Geological Survey; He, Lilin [ORNL; Melnichenko, Yuri B [ORNL; Rupp, John A [ORNL

2012-01-01T23:59:59.000Z

75

Coal pump  

DOE Patents [OSTI]

A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

1983-01-01T23:59:59.000Z

76

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect (OSTI)

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (sox) and oxides of nitrogen (NO[sub x]). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO[sub x] and SO[sub x] emissions. Gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO[sub x] to molecular nitrogen (N[sub 2]) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO[sub x] emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO[sub x]. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO[sub 4], an injection temperature of about 1230[degrees]C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H[sub 2]O added for humidification. The specific goal of this project is to demonstrate NO[sub x] and SO[sub x] emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-07-27T23:59:59.000Z

77

Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz  

SciTech Connect (OSTI)

The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-03-15T23:59:59.000Z

78

AEO 2015 Electricity, Coal, Nuclear and Renewables Preliminary Results  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquids Reserve3.Revenue

79

Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity Generation  

E-Print Network [OSTI]

1 Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity from the LNG life-cycle. Notice that local distribution of natural gas falls outside our analysis boundary. Figure 1S: Domestic Natural Gas Life-cycle. Figure 2S: LNG Life-cycle. Processing Transmission

Jaramillo, Paulina

80

104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright 2011 Inderscience Enterprises Ltd.  

E-Print Network [OSTI]

approach in modelling and simulation of shale gas reservoirs: application to New Albany Shale', Int. J. Oil104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright © 2011 Inderscience Enterprises Ltd. A new practical approach in modelling and simulation of shale gas reservoirs: application

Mohaghegh, Shahab

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81

Comprehensive two-dimensional gas chromatography coupled to time-of-flight mass spectrometry of coal liquids produced during a coal liquefaction process  

SciTech Connect (OSTI)

Comprehensive two-dimensional gas chromatography (GC) coupled to time-of-flight mass spectrometry (MS) has been applied to the analysis of coal-derived liquids from the former British Coal Point-of-Ayr coal liquefaction plant. The feed to the hydrocracker and the resulting product were analyzed. The results refer almost exclusively to the plant-derived recycle solvent, known as the liquefaction solvent; the molecular mass range of the GC does not exceed that of the solvent. The method allows for the resolution of the numerous structural isomers of tetralin and methyl indan, one pair of hydrogen-donor (necessary for the dissolution of coal) and isomeric nondonor (that reduce the hydrogen donors) components of the recycle solvent. In addition, the n-alkanes that concentrate in the recycle solvent are easily observed in comparison with the results from one-dimensional GC-MS. 24 refs., 6 figs., 1 tab.

Jacqui F. Hamilton; Alistair. C. Lewis; Marcos Millan; Keith D. Bartle; Alan A. Herod; Rafael Kandiyoti [University of York, York (United Kingdom). Department of Chemistry

2007-01-15T23:59:59.000Z

82

PRELIMINARY CHARACTERIZATION OF CO2 SEPARATION AND STORAGE PROPERTIES OF COAL GAS RESERVOIRS  

SciTech Connect (OSTI)

An attractive alternative of sequestering CO{sub 2} is to inject it into coalbed methane reservoirs, particularly since it has been shown to enhance the production of methane during near depletion stages. The basis for enhanced coalbed methane recovery and simultaneous sequestration of carbon dioxide in deep coals is the preferential sorption property of coal, with its affinity for carbon dioxide being significantly higher than that for methane. Yet, the sorption behavior of coal under competitive sorptive environment is not fully understood. Hence, the original objective of this research study was to carry out a laboratory study to investigate the effect of studying the sorption behavior of coal in the presence of multiple gases, primarily methane, CO{sub 2} and nitrogen, in order to understand the mechanisms involved in displacement of methane and its movement in coal. This had to be modified slightly since the PVT property of gas mixtures is still not well understood, and any laboratory work in the area of sorption of gases requires a definite equation of state to calculate the volumes of different gases in free and adsorbed forms. This research study started with establishing gas adsorption isotherms for pure methane and CO{sub 2}. The standard gas expansion technique based on volumetric analysis was used for the experimental work with the additional feature of incorporating a gas chromatograph for analysis of gas composition. The results were analyzed first using the Langmuir theory. As expected, the Langmuir analysis indicated that CO{sub 2} is more than three times as sorptive as methane. This was followed by carrying out a partial desorption isotherm for methane, and then injecting CO{sub 2} to displace methane. The results indicated that CO{sub 2} injection at low pressure displaced all of the sorbed methane, even when the total pressure continued to be high. However, the displacement appeared to be occurring due to a combination of the preferential sorption property of coal and reduction in the partial pressure of methane. As a final step, the Extended Langmuir (EL) model was used to model the coal-methane-CO{sub 2} binary adsorption system. The EL model was found to be very accurate in predicting adsorption of CO{sub 2}, but not so in predicting desorption of methane. The selectivity of CO{sub 2} over methane was calculated to be 4.3:1. This is, of course, not in very good agreement with the measured values which showed the ratio to be 3.5:1. However, the measured results are in good agreement with the field observation at one of the CO{sub 2} injection sites. Based on the findings of this study, it was concluded that low pressure injection of CO{sub 2} can be fairly effective in displacing methane in coalbed reservoirs although this might be difficult to achieve in field conditions. Furthermore, the displacement of methane appears to be not only due to the preferential sorption of methane, but reduction in partial pressure as well. Hence, using a highly adsorbing gas, such as CO{sub 2}, has the advantages of inert gas stripping and non-mixing since the injected gas does not mix with the recovered methane.

John Kemeny; Satya Harpalani

2004-03-01T23:59:59.000Z

83

Volumetric strain associated with methane desorption and its impact on coalbed gas production from deep coal seams  

SciTech Connect (OSTI)

For deep coal seams, significant reservoir pressure drawdown is required to promote gas desorption because of the Langmuir-type isotherm that typifies coals. Hence, a large permeability decline may occur because of pressure drawdown and the resulting increase in effective stress, depending on coal properties and the stress field during production. However, the permeability decline can potentially be offset by the permeability enhancement caused by the matrix shrinkage associated with methane desorption. The predictability of varying permeability is critical for coalbed gas exploration and production-well management. We have investigated quantitatively the effects of reservoir pressure and sorption-induced volumetric strain on coal-seam permeability with constraints from the adsorption isotherm and associated volumetric strain measured on a Cretaceous Mesaverde Group coal (Piceance basin) and derived a stress-dependent permeability model. Our results suggest that the favorable coal properties that can result in less permeability reduction during earlier production and an earlier strong permeability rebound (increase in permeability caused by coal shrinkage) with methane desorption include (1) large bulk or Young's modulus; (2) large adsorption or Langmuir volume; (3) high Langmuir pressure; (4) high initial permeability and dense cleat spacing; and (5) low initial reservoir pressure and high in-situ gas content. Permeability variation with gas production is further dependent on the orientation of the coal seam, the reservoir stress field, and the cleat structure. Well completion with injection of N2 and displacement of CH{sub 4} only results in short-term enhancement of permeability and does not promote the overall gas production for the coal studied.

Cui, X.J.; Bustin, R.M. [University of British Columbia, Vancouver, BC (Canada). Dept. of Earth & Ocean Science

2005-09-01T23:59:59.000Z

84

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

85

The gas centrifuge and nuclear weapons proliferation  

SciTech Connect (OSTI)

Uranium enrichment by centrifugation is the basis for the quick and efficient production of nuclear fuel-or nuclear weapons.

Wood, Houston G. [Mechanical and Aerospace Engineering Department, University of Virginia, Charlottesville, Virginia (United States); Glaser, Alexander [Woodrow Wilson School of Public and International Affairs, Program on Science, Technology and Environmental Policy, Princeton University, Princeton, New Jersey (United States); Kemp, R. Scott [Nuclear Science and Engineering Department, Massachusetts Institute of Technology, Cambridge, Massachusetts (United States)

2014-05-09T23:59:59.000Z

86

Electricity production levelized costs for nuclear, gas and coal  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite--FOR IMMEDIATE RELEASE AprilGrowthERDAEffects

87

Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994  

SciTech Connect (OSTI)

The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

Hepworth, M.T.; Slimane, R.B.

1994-11-01T23:59:59.000Z

88

Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development  

SciTech Connect (OSTI)

The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

Radisav Vidic; Joseph Flora; Eric Borguet

2008-12-31T23:59:59.000Z

89

Hot Coal Gas Desulfurization With Manganese-Based Sorbents  

SciTech Connect (OSTI)

The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina. They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000 ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2 mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100 ppmv H{sub 2}S and loading temperatures of 5000 {degrees}C and an empty-bed space velocity of 4, 000 per hour, breakthrough occurred an effective loading of sulfur of 27 to 29% over 5 loading and regeneration cycles. At 90% of this saturation condition, the observed level of H{sub 2}S was below 10 ppmv. For regeneration, a temperature of 9000 {degrees}C is required to dissociate the sulfide into sulfur dioxide using air at atmospheric pressure. The mean sulfur dioxide concentration which is achieved during regeneration is 8% with empty-bed space velocities of 700/hr. TGA tests on individual pellets indicate that bentonite is not desirable as a bonding material and that Mn/Ti ratios higher than 7:1 produce relatively non-porous pellets. Whereas the reactivity is rapid below 12% conversion, the kinetics of conversion decreased significantly above this level. This observation may be the result of plugging of the pellet pores with sulfided product creating inaccessible pore volumes or alternately an increase in diffusional resistance by formation of MnS.

Berns, J.J.; Hepworth, M.T. [Dept. of Civil Engineering, Univ. of Minnesota, Minneapolis, MN (United States)

1996-12-31T23:59:59.000Z

90

Method for producing low and medium BTU gas from coal  

SciTech Connect (OSTI)

A process for producing low and medium BTU gas from carbonizable material is described which comprises: partly devolatizing the material and forming hot incandescent coke therefrom by passing a bed of the same part way through a hot furnace chamber on a first horizontally moving grate while supplying a sub-stoichiometric quantity of air to the same and driving the reactions: C + O/sub 2/ = CO/sub 2/; 2C + O/sub 2/ = 2CO discharging the hot incandescent coke from the end of the first grate run onto a second horizontally moving grate run below the first grate run in the same furnace chamber so as to form a bed thereon, the bed formed on the second grate run being considerably thicker than the bed formed on the first grate run, passing the hot incandescent coke bed on the second grate run further through the furnace chamber in a substantially horizontal direction while feeding air and stream thereto so as to fully burn the coke and in ratio of steam to air driving the following reactions: 2C + O/sub 2/ = 2CO; C + H/sub 2/O = H/sub 2/ + CO; C + 2H/sub 2/O = 2H/sub 2/ + CO/sub 2/; CO + H/sub 2/O = H/sub 2/ + CO/sub 2/ taking off the ash residue of the burned coke and taking off the gaseous products of the reactions.

Mansfield, V.; Francoeur, C.M.

1988-06-07T23:59:59.000Z

91

Most Viewed Documents for Fission and Nuclear Technologies: December...  

Office of Scientific and Technical Information (OSTI)

Nicolas; Pruess, Karsten (2004) 21 Levelized Costs for Nuclear, Gas and Coal for Electricity, under the Mexican Scenario Palacios, J.C.; Alonso, G.; Ramirez, R.; Gomez, A.;...

92

Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization  

SciTech Connect (OSTI)

This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

2012-04-01T23:59:59.000Z

93

Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant  

E-Print Network [OSTI]

- BACKGROUND: In December 2009, the Combined Heat and Power Plant at Cornell Cornell's conversion of a coal fired heating plant to natural Gas the power plant #12;

Keinan, Alon

94

College Of Wooster 2012 Greenhouse Gas Emissions From Coal and Natural Gas Combustion Default Values From EPA Greenhouse Gas Rule  

E-Print Network [OSTI]

56410 CO2 = 1 X 10 -3 X Fuel X HHV X EF Where CO2 = Annual CO2 mass emissions for the specific fuel type high heat value. EF =Fuel default CO2 Emission Factor from Table C-1Page 56410 CO2 Coal CO2 = 1 X 10 -3 Default CO2 Emission Factor For Bituminous Coal = 93.40 kg/mmbtu Default CH4 Emission Factor

Wilson, Mark A.

95

Development of biological coal gasification (MicGAS process). Final report, May 1, 1990--May 31, 1995  

SciTech Connect (OSTI)

ARCTECH has developed a novel process (MicGAS) for direct, anaerobic biomethanation of coals. Biomethanation potential of coals of different ranks (Anthracite, bitumious, sub-bitumious, and lignites of different types), by various microbial consortia, was investigated. Studies on biogasification of Texas Lignite (TxL) were conducted with a proprietary microbial consortium, Mic-1, isolated from hind guts of soil eating termites (Zootermopsis and Nasutitermes sp.) and further improved at ARCTECH. Various microbial populations of the Mic-1 consortium carry out the multi-step MicGAS Process. First, the primary coal degraders, or hydrolytic microbes, degrade the coal to high molecular weight (MW) compounds. Then acedogens ferment the high MW compounds to low MW volatile fatty acids. The volatile fatty acids are converted to acetate by acetogens, and the methanogens complete the biomethanation by converting acetate and CO{sub 2} to methane.

NONE

1998-12-31T23:59:59.000Z

96

Impact of mine closure and access facilities on gas emissions from old mine workings to surface: examples of French iron and coal  

E-Print Network [OSTI]

: examples of French iron and coal Lorraine basins C. Lagny, R. Salmon, Z. Pokryszka and S. Lafortune (INERIS of mine shafts located in the iron Lorraine basin, in the Lorraine and in North-East coal basins are quite in mine workings but gas entrance and exit are allowed. Coal shafts are secured and can be equipped

Boyer, Edmond

97

Gas cofiring in coal-fired stokers for emissions reduction and performance improvement  

SciTech Connect (OSTI)

Adding gas burners above the grate of a coal-fired stoker can be an economical method of reducing gaseous and particulate emissions and improving efficiency and operational flexibility. With this cofiring configuration, the improved heat distribution and mixing with the stoker combustion products can give reduced opacity, reduced emissions of particulate, NO{sub x} and SO{sub 2}, improved carbon burnout and lower overall ash, reduced excess air, faster load response, cleaner and quicker lightoffs, improved turndown at both lower and upper capacity limits, and improved performance with problematic coals. To develop and validate the cofiring technology, three cofire field experiments have been conducted. A 165,000 lb/hr spreader stoker and mass feed chain grate stokers rated at 40,000 and 75,000 lb/hr have been retrofit with gas burners and tested in the field. The two larger units used dual, opposed burners, while the smaller unit was retrofit with a single burner. With the spreader stoker, the primary benefits of gas cofire was reduction in opacity episodes with coal quality variability and recovery of lost derate. With the larger chain grate unit, the primary benefit was reduction of NO{sub x} and SO{sub 2} to within Title V limits and elimination of opacity episodes during startup and load swings. With the smaller chain grate, the primary benefit was ability to operate at low loads without unacceptable opacity excursions which had previously required a backup boiler. In all cases, the economics justified the capital burner system retrofit cost and incremental fuel costs.

Mason, H.B.; Drennan, S.; Chan, I.; Kinney, W.L.; Borland, D.

1996-12-31T23:59:59.000Z

98

Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass  

SciTech Connect (OSTI)

This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

Huffman, Gerald

2012-12-31T23:59:59.000Z

99

Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutronEnvironmentZIRKLE FRUITYear 1MATERIALSTiO2(110). | EMSLCoal Gas

100

Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas  

SciTech Connect (OSTI)

This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

2012-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals  

SciTech Connect (OSTI)

Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

Kloosterman, Jeff

2012-12-31T23:59:59.000Z

102

Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal  

SciTech Connect (OSTI)

HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

2009-09-15T23:59:59.000Z

103

Environmental performance of air staged combustor with flue gas recirculation to burn coal/biomass  

SciTech Connect (OSTI)

The environmental and thermal performance of a 1.07 m diameter, 440 kW atmospheric fluidized bed combustor operated at 700{degrees}C-920{degrees}C and burning coal was studied. Flue gas recirculation was incorporated to enhance the thermal performance and air staging was used to control emissions of SO{sub 2}, CO, NO{sub x} and N{sub 2}O. Studies focused on the effect of excess air, firing rate, and use of sorbent on system performance. The recirculation-staging mode with limestone had the highest thermal efficiency (0.67) using the firing equation. Emission data showed that flue gas recirculation (ratio of 0.7) significantly reduced NO{sub x} emissions; and that use of limestone sorbent at a Ca/S ratio of 3 reduced SO{sub 2} emissions by 64% to approximately 0.310 g/MJ.

Anuar, S.H.; Keener, H.M.

1995-12-31T23:59:59.000Z

104

Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect (OSTI)

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

None

1998-09-01T23:59:59.000Z

105

Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual  

SciTech Connect (OSTI)

The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

None

1998-06-01T23:59:59.000Z

106

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect (OSTI)

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. Progress is discussed.

Not Available

1990-10-20T23:59:59.000Z

107

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect (OSTI)

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is on hold'' because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

Not Available

1990-07-19T23:59:59.000Z

108

Combustion of ultrafine coal/water mixtures and their application in gas turbines: Final report  

SciTech Connect (OSTI)

The feasibility of using coal-water fuels (CWF) in gas turbine combustors has been demonstrated in recent pilot plant experiments. The demands of burning coal-water fuels with high flame stability, complete combustion, low NO/sub x/ emission and a resulting fly ash particle size that will not erode turbine blades represent a significant challenge to combustion scientists and engineers. The satisfactory solution of these problems requires that the variation of the structure of CWF flames, i.e., the fields of flow, temperature and chemical species concentration in the flame, with operating conditions is known. Detailed in-flame measurements are difficult at elevated pressures and it has been proposed to carry out such experiments at atmospheric pressure and interpret the data by means of models for gas turbine combustor conditions. The research was carried out in five sequential tasks: cold flow studies; studies of conventional fine-grind CWF; combustion studies with ultrafine CWF fuel; reduction of NO/sub x/ emission by staged combustion; and data interpretation-ignition and radiation aspects. 37 refs., 61 figs., 9 tabs.

Toqan, M.A.; Srinivasachar, S.; Staudt, J.; Varela, F.; Beer, J.M.

1987-10-01T23:59:59.000Z

109

Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change  

E-Print Network [OSTI]

renewables, including large hydropower, by 2020. In 2009,coal mining and hydropower), iron and steel, machinery, andoil, and natural gas. Hydropower, nuclear, and wind energy

Kahrl, Fredrich James

2011-01-01T23:59:59.000Z

110

Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect  

E-Print Network [OSTI]

Mallants, D. , 2002. Gas generation and migration in Boomof Post-Disposal Gas Generation in a Repository for SpentCorrosion-Induced Gas Generation in a Nuclear Waste

Xu, T.

2009-01-01T23:59:59.000Z

111

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 6, October 1--December 31, 1991  

SciTech Connect (OSTI)

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (SO{sub x}) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Because of cost growth and lack of available funding, no further work has been done after Phase 1 at site B; the wall fired unit.

Not Available

1992-02-07T23:59:59.000Z

112

Experimental observables on nuclear liquid gas phase transition  

E-Print Network [OSTI]

Progress on nuclear liquid gas phase transition (LGPT) or critical behavior has been simply reviewed and some signals of LGPT in heavy ion collisions, especially in NIMROD data, are focused. These signals include the power-law charge distribution, the largest fluctuation of the fragment observables, the nuclear Zipf law, caloric curve and critical exponent analysis etc.

Y. G. Ma

2006-10-07T23:59:59.000Z

113

ENVIRONMENTAL EFFECTS IN GALAXIES: MOLECULAR GAS AND NUCLEAR ACTIVITY  

E-Print Network [OSTI]

ENVIRONMENTAL EFFECTS IN GALAXIES: MOLECULAR GAS AND NUCLEAR ACTIVITY DUILIA DE MELLO and TOMMY;ENVIRONMENTAL EFFECTS IN GALAXIES 69 a. log(MH2 /LB) versus Morphology b. Kolmogorov-Smirnov Statistic Figure 2 in dense envir- onments and in the field and to study whether there is any correlation between nuclear

Maia, Marcio Antonio Geimba

114

Enhancing the use of coals by gas reburning-sorbent injection  

SciTech Connect (OSTI)

This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO[sub x] and SO[sub x] emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO[sub x] to molecular nitrogen (N[sub 2]) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO[sub x] emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO[sub x]. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO[sub 4], an injection temperature of about 1230[degrees]C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H[sub 2]0 added for humidification. The calcium sulfate or sulfite products are collected together with unreacted sorbent fly ash by the electrostatic precipitator. The specific goal of this project is to demonstrate NO[sub x] and SO[sub x] emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-11-16T23:59:59.000Z

115

Control of temperature and heat flux in a combustor using coal-derived gas of varying heat content. [Patent application  

SciTech Connect (OSTI)

The present invention is directed to a fuel-air control system for a combustor in which coal-derived gas of varying heat content is used. To maintain the temperature in the combustor at an essentially constant value the fuel-to-air ratio is adjusted by using a temperature actuated variable pressure regulator in the gas feed line to compensate for the variability of the heat content of the gas. The velocity of the products of combustion is maintained at an essentially constant flow rate by controlling the mass flow of the air and fuel through linked valves on the gas and air feed lines.

Loth, J.L.; Nakaishi, C.V.; Carpenter, L.K.; Bird, J.D.

1981-06-03T23:59:59.000Z

116

2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright 2009 Inderscience Enterprises Ltd.  

E-Print Network [OSTI]

2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright © 2009 Inderscience@yahoo.com Hafez Hafez ADCO-PDD, Abu Dhabi Company for Onshore Oil Operation (ADCO), P.O. Box 270, Abu Dhabi Dhabi Company for Onshore Oil Operation (ADCO), P.O. Box 270, Abu Dhabi, United Arab Emirates Email

Mohaghegh, Shahab

117

Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright 2008 Inderscience Enterprises Ltd.  

E-Print Network [OSTI]

Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright © 2008 Inderscience Enterprises Ltd. Building the foundation for Prudhoe Bay oil production optimisation using neural networks E-mail: siskd@Bp.com Abstract: Field data from the Prudhoe Bay oil field in Alaska was used

Mohaghegh, Shahab

118

Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.  

SciTech Connect (OSTI)

In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

Parkinson, W. J. (William Jerry),

2003-01-01T23:59:59.000Z

119

Gas separation by pressure swing adsorption for producing hydrogen from coal: Final report  

SciTech Connect (OSTI)

This project demonstrated the feasibility of producing high purity hydrogen from a coal gasification product gas mixture by Pressure Swing Adsorption (PSA) using a commercial 5A zeolite as the adsorbent. The major advantage of PSA over conventional hydrogen upgrading processes is associated with lower overall production costs. This is mainly due to the integration of PSA into H/sub 2/ production plants as a single unit operation by replacing the low temperature carbon monoxide shift, carbon dioxide wash and methanation steps. In this way, hydrogen production costs are typically reduced from 7 to 40%. A single bed PSA process was designed to simulate the various steps of commercial multibed PSA plants. A new and very important step, ''Vacuum Purge'', was also investigated. 45 refs., 38 figs., 50 tabs.

Kapoor, A.; Ritter, J.A.; Yang, R.T.

1988-02-01T23:59:59.000Z

120

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, R.V.

1997-12-30T23:59:59.000Z

122

Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, R.V.

1999-02-02T23:59:59.000Z

123

Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas  

DOE Patents [OSTI]

Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

Siriwardane, Ranjani V. (Morgantown, WV)

1999-01-01T23:59:59.000Z

124

Secondary atomization of coal-water fuels for gas turbine applications: Final report  

SciTech Connect (OSTI)

The main research objective was to determine the effectiveness of the CWF treatments on atomization quality when applied to an ultrafine coal-water fuel (solids loading reduced to 50%) and to gas turbine operating conditions (atomization at elevated pressures). Three fuel treatment techniques were studied: (1) heating of CWF under pressure to produce steam as the pressure drops during passage of the CWF through the atomizer nozzle, (2) absorption of CO/sub 2/ gas in the CWF to produce a similar effect, and (3) a combination of the two treatments above. These techniques were expected to produce secondary atomization, that is, disruptive shattering of CWF droplets subsequent to their leaving the atomizing nozzle, and to lead to better burnout and finer fly ash size distribution. A parallel objective was to present quantitative information on the spray characteristics (mean droplet size, radial distribution of droplet size, and spray shape) of CWF with and without fuel treatment, applicable to the design of CWF-burning gas turbine combustors. The experiments included laser diffraction droplet size measurements and high-speed photographic studies in the MIT Spray Test Facility to determine mean droplet size (mass median diameter), droplet size distribution, and spray shape and angle. Three systems of atomized sprays were studied: (1) water sprays heated to a range of temperatures at atmospheric pressure; (2) CWF sprays heated at atmospheric pressure to different temperatures; and (3) sprays at elevated pressure. 31 refs., 47 figs., 1 tab.

Yu, T.U.; Kang, S.W.; Beer, J.M.

1988-12-01T23:59:59.000Z

125

Nuclear symmetry energy effects on liquid-gas phase transition in hot asymmetric nuclear matter  

E-Print Network [OSTI]

The liquid-gas phase transition in hot asymmetric nuclear matter is investigated within relativistic mean-field model using the density dependence of nuclear symmetry energy constrained from the measured neutron skin thickness of finite nuclei. We find symmetry energy has a significant influence on several features of liquid-gas phase transition. The boundary and area of the liquid-gas coexistence region, the maximal isospin asymmetry and the critical values of pressure and isospin asymmetry all of which systematically increase with increasing softness in the density dependence of symmetry energy. The critical temperature below which the liquid-gas mixed phase exists is found higher for a softer symmetry energy.

Bharat K. Sharma; Subrata Pal

2010-01-14T23:59:59.000Z

126

The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics  

SciTech Connect (OSTI)

This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

NONE

1995-10-01T23:59:59.000Z

127

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

128

China's Coal: Demand, Constraints, and Externalities  

E-Print Network [OSTI]

of natural gas, along with the coal reserve base of 326s Fossil Fuel Reserve Base, 2007 Oil Natural Gas Coal 233ensured reserves”) of coal, oil and natural gas published in

Aden, Nathaniel

2010-01-01T23:59:59.000Z

129

Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification  

SciTech Connect (OSTI)

This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

None

1982-01-01T23:59:59.000Z

130

DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS  

SciTech Connect (OSTI)

The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

2012-09-30T23:59:59.000Z

131

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a liquid flue gas conditioning system was completed at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Two cohesivity-specific additive formulations, ADA-44C and ADA-51, will be evaluated. In addition, ammonia conditioning will also be compared.

Kenneth E. Baldrey

2003-01-01T23:59:59.000Z

132

Theoretical and experimental investigations into the particular features of the process of converting coal gas hydrocarbons on incandescent coke  

SciTech Connect (OSTI)

The prospects of the use of reducing gases in ferrous metallurgy and the possibilities for using them as a basis for coke production have been presented by the authors of the present article in the past. In the present report, the authors present certain results of theoretical and experimental investigations into the process of converting coal gas hydrocarbons on incandescent coke. The modification of the present-day method of thermodynamically calculating stable compositions of coking products, which was developed by the authors, has made it possible to apply it to specific chemical systems and process conditions not met with before, such as the conversion of hydrocarbons in mixtures of actual industrial gases (coal gas and blast furnace gas) in the presence of carbon and considerable amounts of hydrogen.

Zubilin, I.G.; Umanskii, V.E.

1984-01-01T23:59:59.000Z

133

Update report on the performance of 400 megawatt and larger nuclear and coal-fired generating units. Performance through 1977  

SciTech Connect (OSTI)

Forty-seven nuclear generating units and 125 coal-fired generating plants that have had at least one full year of commercial operation are covered in this report. Their performances are evaluated using the capacity factor, availability factor, equivalent availability, and forced outage rate. The data are arranged by state and utility. (DLC)

None

1981-01-01T23:59:59.000Z

134

Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures  

E-Print Network [OSTI]

Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

Couling, David Joseph

2012-01-01T23:59:59.000Z

135

Using auxiliary gas power for CCS energy needs in retrofitted coal power plants  

E-Print Network [OSTI]

Post-combustion capture retrofits are expected to a near-term option for mitigating CO 2 emissions from existing coal-fired power plants. Much of the literature proposes using power from the existing coal plant and thermal ...

Bashadi, Sarah (Sarah Omer)

2010-01-01T23:59:59.000Z

136

China's Coal: Demand, Constraints, and Externalities  

SciTech Connect (OSTI)

This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

Aden, Nathaniel; Fridley, David; Zheng, Nina

2009-07-01T23:59:59.000Z

137

BioCoComb -- Gasification of biomass and co-combustion of the gas in a pulverized-coal-boiler  

SciTech Connect (OSTI)

In a demonstration project supported by an European Community Thermie Fund a biomass gasifier for bark, wood chips, saw dust, etc. has been installed by Austrian Energy and Environment at the 137 MW{sub el} pulverized-coal fired power station in Zeltweg, Austria. The project title BioCoComb is an abbreviation for Preparation of Biofuel for Co-Combustion, where co-combustion means combustion together with coal in existing power plants. According to the thermal capacity of 10 MW the produced gas substitutes approx. 3% of the coal fired in the boiler. Only the coarse fraction of the biomass has to pass a shredder and is then fed together with the fine fraction without any further pretreatment into the gasifier. In the gasification process the biomass will combust in a substoichiometric atmosphere, create the necessary temperature of 820 C and partly gasify due to the lack of oxygen in the combustion chamber (autothermal operation). The gasifier uses circulating fluidized bed technology, which guarantees even relatively low temperatures in all parts of the gasifier to prevent slagging. The intense motion of the bed material also favors attrition of the biomass particles. Via a hot gas duct the produced low calorific value (LCV) gas is directly led into the furnace of the existing pulverized coal fired boiler for combustion. The gas also contains fine wood char particles, that can pass the retention cyclone and burn out in the furnace of the coal boiler. The main advantages of the BioCoComb concept are: low gas quality sufficient for co-firing; no gas cleaning or cooling; no predrying of the biomass; relatively low temperatures in the gasifier to prevent slagging; favorable effects on power plant emissions (CO{sub 2}, NO{sub x}); no severe modifications of the existing coal fired boiler; and high flexibility in arranging and integrating the main components into existing plants. The plant started its trial run in November 1997 and has been in successful commercial operation since January 1998.

Anderl, H.; Zotter, T.; Mory, A.

1999-07-01T23:59:59.000Z

138

Modeling high-pressure adsorption of gas mixtures on activated carbon and coal using a simplified local-density model  

SciTech Connect (OSTI)

The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO{sub 2} sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO{sub 2} on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO{sub 2} on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties.

Fitzgerald, J.E.; Robinson, R.L.; Gasem, K.A.M. [Oklahoma State University, Stillwater, OK (United States). School of Chemical Engineering

2006-11-07T23:59:59.000Z

139

Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

Jain, M.K.

1991-12-31T23:59:59.000Z

140

Outlook and Challenges for Chinese Coal  

SciTech Connect (OSTI)

China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

2008-06-20T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
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141

Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal  

SciTech Connect (OSTI)

The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

Siriwardane, Ranjani V. [U.S. DOE; Ksepko, Ewelina; Tian, Hanging [URS

2013-01-01T23:59:59.000Z

142

Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application  

SciTech Connect (OSTI)

This study identifies vital gas turbine (GT) parameters and quantifies their influence in meeting the DOE Turbine Program overall Integrated Gasification Combined Cycle (IGCC) plant goals of 50% net HHV efficiency, $1000/kW capital cost, and low emissions. The project analytically evaluates GE advanced F class air cooled technology level gas turbine conceptual cycle designs and determines their influence on IGCC plant level performance including impact of Carbon capture. This report summarizes the work accomplished in each of the following six Tasks. Task 1.0--Overall IGCC Plant Level Requirements Identification: Plant level requirements were identified, and compared with DOE's IGCC Goal of achieving 50% Net HHV Efficiency and $1000/KW by the Year 2008, through use of a Six Sigma Quality Functional Deployment (QFD) Tool. This analysis resulted in 7 GT System Level Parameters as the most significant. Task 2.0--Requirements Prioritization/Flow-Down to GT Subsystem Level: GT requirements were identified, analyzed and prioritized relative to achieving plant level goals, and compared with the flow down of power island goals through use of a Six Sigma QFD Tool. This analysis resulted in 11 GT Cycle Design Parameters being selected as the most significant. Task 3.0--IGCC Conceptual System Analysis: A Baseline IGCC Plant configuration was chosen, and an IGCC simulation analysis model was constructed, validated against published performance data and then optimized by including air extraction heat recovery and GE steam turbine model. Baseline IGCC based on GE 207FA+e gas turbine combined cycle has net HHV efficiency of 40.5% and net output nominally of 526 Megawatts at NOx emission level of 15 ppmvd{at}15% corrected O2. 18 advanced F technology GT cycle design options were developed to provide performance targets with increased output and/or efficiency with low NOx emissions. Task 4.0--Gas Turbine Cycle Options vs. Requirements Evaluation: Influence coefficients on 4 key IGCC plant level parameters (IGCC Net Efficiency, IGCC Net Output, GT Output, NOx Emissions) of 11 GT identified cycle parameters were determined. Results indicate that IGCC net efficiency HHV gains up to 2.8 pts (40.5% to 43.3%) and IGCC net output gains up to 35% are possible due to improvements in GT technology alone with single digit NOx emission levels. Task 5.0--Recommendations for GT Technical Improvements: A trade off analysis was conducted utilizing the performance results of 18 gas turbine (GT) conceptual designs, and three most promising GT candidates are recommended. A roadmap for turbine technology development is proposed for future coal based IGCC power plants. Task 6.0--Determine Carbon Capture Impact on IGCC Plant Level Performance: A gas turbine performance model for high Hydrogen fuel gas turbine was created and integrated to an IGCC system performance model, which also included newly created models for moisturized syngas, gas shift and CO2 removal subsystems. This performance model was analyzed for two gas turbine technology based subsystems each with two Carbon removal design options of 85% and 88% respectively. The results show larger IGCC performance penalty for gas turbine designs with higher firing temperature and higher Carbon removal.

Ashok K. Anand

2005-12-16T23:59:59.000Z

143

Critical Temperature for the Nuclear Liquid-Gas Phase Transition  

E-Print Network [OSTI]

The charge distribution of the intermediate mass fragments produced in p (8.1 GeV) + Au collisions is analyzed in the framework of the statistical multifragmentation model with the critical temperature for the nuclear liquid-gas phase transition $T_c$ as a free parameter. It is found that $T_c=20\\pm3$ MeV (90% CL).

V. A. Karnaukhov; H. Oeschler; S. P. Avdeyev; E. V. Duginova; V. K. Rodionov; A. Budzanowski; W. Karcz; O. V. Bochkarev; E. A. Kuzmin; L. V. Chulkov; E. Norbeck; A. S. Botvina

2003-02-07T23:59:59.000Z

144

Pennsylvania Farmland and Forest Land Assessment Act of 1974- Utilization of Land or Conveyance of Rights for Exploration or Extraction of Gas, Oil or Coal Bed Methane  

Broader source: Energy.gov [DOE]

This act prescribes the procedure utilization of land or conveyance of rights for exploration or extraction of gas, oil or coal bed methane in agricultural and forest reserve areas.

145

Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan  

SciTech Connect (OSTI)

With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

Tegen, S.

2006-05-01T23:59:59.000Z

146

Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan: Preprint  

SciTech Connect (OSTI)

With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power, and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

Tegen, S.

2005-08-01T23:59:59.000Z

147

E-Print Network 3.0 - advanced coal-fired gas Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CHLORINE LINK IN COMMERCIAL SCALE SYSTEM FLUE GASES? Summary: that Battelle measured dioxins in coal fired utility boiler stack emissions in the United States and by ETSU... in...

148

Nuclear liquid-gas phase transition within the lattice gas model  

E-Print Network [OSTI]

We study the nuclear liquid-gas phase transition on the basis of a two-component lattice gas model. A Metropolis type of sampling method is used to generate microscopic states in the canonical ensemble. The effective equation of state and fragment mass distributions are evaluated in a wide range of temperatures and densities. A definition of the phase coexistence region appropriate for mesoscopic systems is proposed. The caloric curve resulting from different types of freeze-out conditions are presented.

J. Borg; I. N. Mishustin; J. P. Bondorf

1998-09-25T23:59:59.000Z

149

Method for treating a nuclear process off-gas stream  

DOE Patents [OSTI]

Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

Pence, Dallas T. (San Diego, CA); Chou, Chun-Chao (San Diego, CA)

1984-01-01T23:59:59.000Z

150

Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors  

DOE Patents [OSTI]

Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pocoima, CA); Benander, Robert E. (Pacoima, CA)

2010-02-23T23:59:59.000Z

151

Porous nuclear fuel element for high-temperature gas-cooled nuclear reactors  

DOE Patents [OSTI]

Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pacoima, CA); Benander, Robert E. (Pacoima, CA)

2011-03-01T23:59:59.000Z

152

Porous nuclear fuel element with internal skeleton for high-temperature gas-cooled nuclear reactors  

DOE Patents [OSTI]

Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

2013-09-03T23:59:59.000Z

153

Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas  

SciTech Connect (OSTI)

Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews [Carnegie Mellon University, Pittsburgh, PA (USA). Civil and Environmental Engineering Department

2008-10-15T23:59:59.000Z

154

Advanced coal-fueled gas turbine systems reference system definition update  

SciTech Connect (OSTI)

The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

Not Available

1991-09-01T23:59:59.000Z

155

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was underway at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. This represents the first long-term full-scale testing of this class of products. Modifications to the flue gas conditioning system at Jim Bridger, including development of alternate injection lances, was also undertaken to improve chemical spray distribution and to avoid spray deposition to duct interior surfaces. Also in this quarter, a firm commitment was received for another long-term test of the cohesivity additives. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-05-01T23:59:59.000Z

156

Improved heat recovery and high-temperature clean-up for coal-gas fired combustion turbines  

SciTech Connect (OSTI)

This study investigates the performance of an Improved Heat Recovery Method (IHRM) applied to a coal-gas fired power-generating system using a high-temperature clean-up. This heat recovery process has been described by Higdon and Lynn (1990). The IHRM is an integrated heat-recovery network that significantly increases the thermal efficiency of a gas turbine in the generation of electric power. Its main feature is to recover both low- and high-temperature heat reclaimed from various gas streams by means of evaporating heated water into combustion air in an air saturation unit. This unit is a packed column where compressed air flows countercurrently to the heated water prior to being sent to the combustor, where it is mixed with coal-gas and burned. The high water content of the air stream thus obtained reduces the amount of excess air required to control the firing temperature of the combustor, which in turn lowers the total work of compression and results in a high thermal efficiency. Three designs of the IHRM were developed to accommodate three different gasifying process. The performances of those designs were evaluated and compared using computer simulations. The efficiencies obtained with the IHRM are substantially higher those yielded by other heat-recovery technologies using the same gasifying processes. The study also revealed that the IHRM compares advantageously to most advanced power-generation technologies currently available or tested commercially. 13 refs., 34 figs., 10 tabs.

Barthelemy, N.M.; Lynn, S.

1991-07-01T23:59:59.000Z

157

Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal  

SciTech Connect (OSTI)

The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

Barton, Tom

2013-06-30T23:59:59.000Z

158

Hard truths: facing the hard truths about energy. Topic Paper No. 18: Coal to liquids and gas  

SciTech Connect (OSTI)

The report presents the issues associated with and the potential of coal to liquids (CTL) and coal to gas (CTG) technologies. The other important outcome from this report is to view and understand the inputs and assumptions from various publications and the range of production estimates from CTG and CTL technology. The examination of the publications demonstrates a large uncertainty for CTL, due to various assumptions from petroleum price to technological abilities. Key assumptions are left unexamined, such as product transportation, labor, equipment availability, and environmental risk. Overall, the published CTL production estimates are small in the total global petroleum market perspective; even in the most optimistic scenario the volume from CTL amounts to only 20% of the U.S. petroleum market in the Southern States Energy Board (SSEB) report. The National Coal Council (NCC) saw a 10% market share, whereas the various Energy Information Administration (EIA) scenarios saw 0% to 6% of the U.S market share. The NCC and SSEB both mentioned the added benefit of using the CO{sub 2} for enhanced oil recovery (EOR). It begins by introducing the process, giving a detailed technological understanding, and then outlining each issue with each report from coal availability to oil price assumptions. The incremental gains from CTL and other technology areas, such as oil shale, could have a significant impact on U.S. energy cost and foreign dependency. The use of coal allows the added benefit of relying on a resource that is domestically more plentiful than petroleum, but this reliance must be carefully balanced with the economics of developing the resource, since CTL facilities can cost more than $1 billion per 10,000 days of production, which implicates the competitiveness of the U.S. economy within the global economy. 33 refs.

NONE

2007-07-18T23:59:59.000Z

159

Using auxiliary gas power for CCS energy needs in retrofitted coal power plants  

E-Print Network [OSTI]

Adding post-combustion capture technology to existing coal-fired power plants is being considered as a near-term option for mitigating CO[subscript 2] emissions. To supply the thermal energy needed for CO[subscript 2] ...

Bashadi, Sarah O.

160

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, installation of a flue gas conditioning system was completed at PacifiCorp Jim Bridger Power Plant. Performance testing was underway. Results will be detailed in the next quarterly and subsequent technical summary reports. Also in this quarter, discussions were initiated with a prospective long-term candidate plant. This plant fires a bituminous coal and has opacity performance issues related to fly ash re-entrainment. Ammonia conditioning has been proposed here, but there is interest in liquid additives as a safer alternative.

Kenneth E. Baldrey

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
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161

JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas  

SciTech Connect (OSTI)

This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

Ye Zhuang; Christopher Martin; John Pavlish

2009-03-31T23:59:59.000Z

162

Simultaneous removal of H{sub 2}S and NH{sub 3} from coal gas. Final report  

SciTech Connect (OSTI)

Hydrogen sulfide (H{sub 2}S) and ammonia (NH{sub 3}) are the primary sulfur and nitrogen contaminants released when coal is gasified. Before coal gas can be utilized in an integrated gasification combined cycle (IGCC) plant to produce electricity, these contaminants need to be removed. The objective of this research was to develop sorbent-catalysts with the ability to simultaneously remove H{sub 2}S and NH{sub 3} from coal gas. Microreactor tests with HART-49, a zinc-based sorbent-catalyst with Ni, Co, and Mo as catalyst additives, showed that this material had the potential to remove 90% NH{sub 3} and reduce H{sub 2}S to <20 ppmv at 1 atm and 550 to 700 C. HART-49 was prepared in attrition-resistant fluidizable form (HART-56) using up to 75 wt% binder. Bench-scale fluidized-bed multicycle tests were conducted with the attrition-resistant sorbent-catalyst, HART-56, at 20 atm and 550 C. The H{sub 2}S and NH{sub 3} removal performance over the first two cycles was good in the presence of 5% steam but deteriorated thereafter when steam level was increased to 15%. The results point to a complex mechanism for simultaneous H{sub 2}S and NH{sub 3} removal, potentially involving both chemisorption and catalytic decomposition of NH{sub 3}. Further research and development is needed to develop a sorbent-catalyst for simultaneous H{sub 2}S and NH{sub 3} removal at IGCC hot-gas cleanup conditions.

Gangwal, S.K.; Portzer, J.W.

1998-05-01T23:59:59.000Z

163

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS  

SciTech Connect (OSTI)

Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({approx}10 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H{sub 2} separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 40} alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

J. Douglas Way; Robert L. McCormick

2001-06-01T23:59:59.000Z

164

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, performance testing of flue gas conditioning was completed at the PacifiCorp Jim Bridger Power Plant. The product tested, ADA-43, was a combination resistivity modifier with cohesivity polymers. The product was effective as a flue gas conditioner. However, ongoing problems with in-duct deposition resulting from the flue gas conditioning were not entirely resolved. Primarily these problems were the result of difficulties encountered with retrofit of an existing spray humidification system. Eventually it proved necessary to replace all of the original injection lances and to manually bypass the PLC-based air/liquid feed control. This yielded substantial improvement in spray atomization and system reliability. However, the plant opted not to install a permanent system. Also in this quarter, preparations continued for a test of the cohesivity additives at the American Electric Power Conesville Plant, Unit 3. This plant fires a bituminous coal and has opacity and particulate emissions performance issues related to fly ash re-entrainment. Ammonia conditioning is employed here on one unit, but there is interest in liquid cohesivity additives as a safer alternative.

Kenneth E. Baldrey

2002-07-01T23:59:59.000Z

165

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems  

SciTech Connect (OSTI)

CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

Not Available

1990-07-01T23:59:59.000Z

166

The liquid-gas phase transition and the caloric curve of nuclear matter  

E-Print Network [OSTI]

in the critical phenomena [5-8], the caloric curve [9,10], the negative heat capacity [11,12] and the bimodalityThe liquid-gas phase transition and the caloric curve of nuclear matter K. Miyazaki E in the liquid-gas phase transition of nuclear matter. The recent great experimental progress [1-4] in nuclear

167

Coal systems analysis  

SciTech Connect (OSTI)

This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.

Warwick, P.D. (ed.)

2005-07-01T23:59:59.000Z

168

Gas Permeability of Fractured Sandstone/Coal Samples under Variable Confining Pressure  

E-Print Network [OSTI]

argillite under con?nement: gas and water testing. Phys.Gascoyne, M. , Wuschke, D.M. : Gas migration through water-fractured rock: results of a gas injection test. J.

Liu, Weiqun; Li, Yushou; Wang, Bo

2010-01-01T23:59:59.000Z

169

Coal Combustion Science  

SciTech Connect (OSTI)

The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

1991-08-01T23:59:59.000Z

170

Firing microfine coal with a low NOx, RSFC burner in an industrial boiler designed for oil and gas  

SciTech Connect (OSTI)

ABB Power Plant Laboratories (ABB-PPL) working under a US Department of Energy-Pittsburgh Energy Technology Center (DOE-PETC) contract has carried out tests with the Radially Stratified Flame Core (RSFC) burner which was licensed from the Massachusetts Institute of Technology who developed and patented the RSFC burner. Tests were carried out in a small industrial boiler, designed for oil and natural gas, located at the Energy and Fuels Research Center of Penn State University who was working as a subcontractor to ABB-PPL. The paper presents results from the long-term testing task in the DOE-PETC program with particular attention being paid to the challenges faced in maintaining high combustion efficiencies while achieving low NOx in a small industrial boiler designed for firing oil or natural gas. The paper will also address the issue of ash management when firing coal in a boiler designed for fuels having essentially no ash.

Thornhock, D.E.; Patel, R.; Borio, R.W. [Combustion Engineering, Inc., Windsor, CT (United States). ABB Power Plant Labs.; Miller, B.G.; Scaroni, A.W. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center

1996-12-31T23:59:59.000Z

171

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 11, April 1--June 30, 1990  

SciTech Connect (OSTI)

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, is ``on hold`` because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80{endash}85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device.

Not Available

1990-07-19T23:59:59.000Z

172

The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 5, October 1, 1992--December 31, 1992  

SciTech Connect (OSTI)

Two base case flow sheets have now been prepared. In the first, which was originally presented in TPR4, a Texaco gasifier is used. Natural gas is also burned in sufficient quantity to increase the hydrogen to carbon monoxide ratio of the synthesis gas to the required value of 1. 1 for alcohol synthesis. Acid gas clean up and sulfur removal are accomplished using the Rectisol process followed by the Claus and Beavon processes. About 10% of the synthesis gas is sent to a power generation unit in order to produce electric power, with the remaining 90% used for alcohol synthesis. For this process, the estimated installed cost is $474.2 mm. The estimated annual operating costs are $64.5 MM. At a price of alcohol fuels in the vicinity of $1. 00/gal, the pay back period for construction of this plant is about four years. The details of this case, called Base Case 1, are presented in Appendix 1. The second base case, called Base Case 2, also has a detailed description and explanation in Appendix 1. In Base Case 2, a Lurgi Gasifier is used. The motivation for using a Lurgi Gasifier is that it runs at a lower temperature and pressure and, therefore, produces by-products such as coal liquids which can be sold. Based upon the economics of joint production, discussed in Technical Progress Report 4, this is a necessity. Since synthesis gas from natural gas is always less expensive to produce than from coal, then alcohol fuels will always be less expensive to produce from natural gas than from coal. Therefore, the only way to make coal- derived alcohol fuels economically competitive is to decrease the cost of production of coal-derived synthesis gas. one method for accomplishing this is to sell the by-products from the gasification step. The details of this strategy are discussed in Appendix 3.

Not Available

1993-01-01T23:59:59.000Z

173

Samson Sherman President Obama's Energy Plan & Natural Gas  

E-Print Network [OSTI]

Samson Sherman President Obama's Energy Plan & Natural Gas The Plan On March 30, President Obama" but includes wind, solar, nuclear, natural gas, and coal plants that can capture and store CO2 emissions period. Natural Gas Natural gas is considered the cleanest of all fossil fuels. Mostly comprised

Toohey, Darin W.

174

Field evaluation of cofiring gas with coal for quantifying operational benefits and emissions trim in a utility boiler. Volume 2. Topical report, 1989-1990  

SciTech Connect (OSTI)

The volume consists of 14 appendixes to accompany volume 1 of the report, and covers the following test data: analysis of coal, fylash, and bottom ash samples; cleanliness factors; slagging observation record sheets; stack opacity measurements; stack sulphur dioxide and nitrogen oxides measurements; total coal flow; fuel gas flow; furnace exit gas temperature; percent oxygen at economizer outlet; percent excess air; bulk steam temperatures at secondary superheater and reheater outlets; secondary superheater and reheater tube outlet leg temperatures; unit heat rate; and models used for data interpretation.

Clark, K.J.; Torbov, T.S.; Impey, R.J.; Hara, K.G.; Burnett, T.D.

1993-02-01T23:59:59.000Z

175

User-Friendly Tool to Calculate Economic Impacts from Coal, Natural Gas, and Wind: The Expanded Jobs and Economic Development Impact Model (JEDI II); Preprint  

SciTech Connect (OSTI)

In this paper we examine the impacts of building new coal, gas, or wind plants in three states: Colorado, Michigan, and Virginia. Our findings indicate that local/state economic impacts are directly related to the availability and utilization of local industries and services to build and operate the power plant. For gas and coal plants, the economic benefit depends significantly on whether the fuel is obtained from within the state, out of state, or some combination. We also find that the taxes generated by power plants can have a significant impact on local economies via increased expenditures on public goods.

Tegen, S.; Goldberg, M.; Milligan, M.

2006-06-01T23:59:59.000Z

176

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS  

SciTech Connect (OSTI)

For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

J. Douglas Way

2003-01-01T23:59:59.000Z

177

Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals  

SciTech Connect (OSTI)

This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

Sun, Xiaolei; Rink, Nancy

2011-04-30T23:59:59.000Z

178

Coal market momentum converts skeptics  

SciTech Connect (OSTI)

Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

Fiscor, S.

2006-01-15T23:59:59.000Z

179

Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings  

SciTech Connect (OSTI)

Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase, and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.

Jianping Jing; Zhengqi Li; Guangkui Liu; Zhichao Chen; Chunlong Liu [Harbin Institute of Technology, Harbin (China). School of Energy Science and Engineering

2009-07-15T23:59:59.000Z

180

Advanced coal-fueled industrial cogeneration gas turbine system. Annual report, June 1991--June 1992  

SciTech Connect (OSTI)

This report covers the activity during the period from 2 June 1991 to 1 June 1992. The major areas of work include: the combustor sub-scale and full size testing, cleanup, coal fuel specification and processing, the Hot End Simulation rig and design of the engine parts required for use with the coal-fueled combustor island. To date Solar has demonstrated: Stable and efficient combustion burning coal-water mixtures using the Two Stage Slagging Combustor; Molten slag removal of over 97% using the slagging primary and the particulate removal impact separator; and on-site preparation of CWM is feasible. During the past year the following tasks were completed: The feasibility of on-site CWM preparation was demonstrated on the subscale TSSC. A water-cooled impactor was evaluated on the subscale TSSC; three tests were completed on the full size TSSC, the last one incorporating the PRIS; a total of 27 hours of operation on CWM at design temperature were accumulated using candle filters supplied by Refraction through Industrial Pump & Filter; a target fuel specification was established and a fuel cost model developed which can identify sensitivities of specification parameters; analyses of the effects of slag on refractory materials were conducted; and modifications continued on the Hot End Simulation Rig to allow extended test times.

LeCren, R.T.; Cowell, L.H.; Galica, M.A.; Stephenson, M.D.; When, C.S.

1992-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of...

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2013-01-01T23:59:59.000Z

182

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems  

SciTech Connect (OSTI)

The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro's estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

1991-01-01T23:59:59.000Z

183

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

Kenneth E. Baldrey

2003-07-30T23:59:59.000Z

184

Bioconversion of coal-derived synthesis gas to liquid fuels. Annual report, September 29, 1992--September 28, 1993  

SciTech Connect (OSTI)

The overall objective of the project is to develop and optimize a two-stage fermentation process for the conversion of coal derived synthesis gas in an mixture of alcohols. The goals include the development of superior strains with high product tolerance and productivity, optimization of process conditions for high volumetric productivity and product concentrations, integration and optimization of two stage syngas fermentation, evaluation of bioreactor configurations for enhanced mass transfer, evaluation of syngas conversion by a culture of Butyribacterium methyltrophicum and Clostridium acetobutylicum, development of a membrane based pervaporation system for in situ removal of alcohols, and development of a process for reduction of carbon and electron loss. The specific goals for year one (September 1992 - September 1993) were (1) development of a project work plan, (2) development of superior CO-utilizing strains, (3) optimization of process conditions for conversion of synthesis gas to a mixture of acids in a continuously stirred reactor (CSTR), (4) evaluation of different bioreactor configurations for maximization of mass transfer of synthesis gas, (5) development of a membrane based pervaporation system, and (6) reduction of carbon and electron loss via H{sub 2}CO{sub 2} fermentation. Experimentation and progress toward these goals are described in this report.

Jain, M.K.; Worden, R.M.; Grethlein, H.E.

1993-10-21T23:59:59.000Z

185

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report, January 1--March 31, 1996  

SciTech Connect (OSTI)

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, and (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel. Phase I of the project commenced on June 5, 1987. Phases I, II and III for the Illinois Power Project have been completed; Phases I and II for the CWLP project have been completed; Phase III is in progress. All site activities have been completed with the exception of restoration at CWLP.

NONE

1996-04-15T23:59:59.000Z

186

Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 33, October 1--December 31, 1995  

SciTech Connect (OSTI)

The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub 2}), on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. SO{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting, (2) Construction and Startup, shed through the formation of an industry, and (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel. Phase 1 of the project commenced on June 5, 1987. Phases 1, 2 and 3 for the Illinois Power Project have been completed; Phases 1 and 2 for the CWLP project have been completed; Phase 3 is in progress. All site activities have been completed with the exception of restoration at CWLP.

NONE

1996-01-15T23:59:59.000Z

187

Liquid-gas phase transition in a two-components isospin lattice gas model for asymmetric nuclear matter  

E-Print Network [OSTI]

A two-components isospin lattice gas model has been employed to study the liquid-gas phase transition for asymmetric nuclear matter. An additional degree of freedom, namely, the asymmetry parameter alpha has been considered carefully for studying the phase transition. We have shown that under the mean field approximation, the liquid-gas phase transition given by this model is of second order. The entropy continues at the phase transition point. The binodal surface is addressed.

Wei Liang Qian; Ru-Keng Su

2002-10-04T23:59:59.000Z

188

The Asia-Pacific coal technology conference  

SciTech Connect (OSTI)

The Asia-Pacific coal technology conference was held in Honolulu, Hawaii, November 14--16, 1989. Topics discussed included the following: Expanded Horizons for US Coal Technology and Coal Trade; Future Coal-Fired Generation and Capacity Requirements of the Philippines; Taiwan Presentation; Korean Presentation; Hong Kong Future Coal Requirements; Indonesian Presentation; Electric Power System in Thailand; Coal in Malaysia -- A Position Paper; The US and Asia: Pacific Partners in Coal and Coal Technology; US Coal Production and Export; US Clean Coal Technologies; Developments in Coal Transport and Utilization; Alternative/Innovative Transport; Electricity Generation in Asia and the Pacific: Power Sector Demand for Coal, Oil and Natural Gas; Role of Clean Coal Technology in the Energy Future of the World; Global Climate Change: A Fossil Energy Perspective; Speaker: The Role of Coal in Meeting Hawaii's Power Needs; and Workshops on Critical Issues Associated with Coal Usage. Individual topics are processed separately for the data bases.

Not Available

1990-02-01T23:59:59.000Z

189

Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants  

E-Print Network [OSTI]

The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

190

Design of generic coal conversion facilities: Production of oxygenates from synthesis gas---A technology review  

SciTech Connect (OSTI)

This report concentrates on the production of oxygenates from coal via gasification and indirect liquefaction. At the present the majority of oxygenate synthesis programs are at laboratory scale. Exceptions include commercial and demonstration scale plants for methanol and higher alcohols production, and ethers such as MTBE. Research and development work has concentrated on elucidating the fundamental transport and kinetic limitations governing various reactor configurations. But of equal or greater importance has been investigations into the optimal catalyst composition and process conditions for the production of various oxygenates.

Not Available

1991-10-01T23:59:59.000Z

191

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

192

A new coal-permeability model: Internal swelling stress and fracture-matrix interaction  

E-Print Network [OSTI]

gas sequestration into coal seams. J Geophys Res. (2007)Reservoir engineering in coal seams: Part 1 – the physicaland movement in coal seams. SPE Reservoir engineering.

Liu, H.H.

2010-01-01T23:59:59.000Z

193

A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction  

E-Print Network [OSTI]

L. : Adsorption-induced coal swelling and stress:acid gas sequestration into coal seams. J Geophys. Res. (fracturing on permeability of coal. Min. Sci. Technol. 3,

Liu, Hui-Hai; Rutqvist, Jonny

2010-01-01T23:59:59.000Z

194

A new coal-permeability model: Internal swelling stress and fracture-matrix interaction  

E-Print Network [OSTI]

of carbon dioxide in coal with enhanced coalbed methaneL. Adsorption-induced coal swelling and stress: Implicationsand acid gas sequestration into coal seams. J Geophys Res. (

Liu, H.H.

2010-01-01T23:59:59.000Z

195

Simulated coal-gas fueled carbonate fuel cell power plant system verification. Final report, September 1990--June 1995  

SciTech Connect (OSTI)

This report summarizes work performed under U.S. Department of Energy, Morgantown Energy Technology Center (DOE/METC) Contract DE-AC-90MC27168 for September 1990 through March 1995. Energy Research Corporation (ERC), with support from DOE, EPRI, and utilities, has been developing a carbonate fuel cell technology. ERC`s design is a unique direct fuel cell (DFC) which does not need an external fuel reformer. An alliance was formed with a representative group of utilities and, with their input, a commercial entry product was chosen. The first 2 MW demonstration unit was planned and construction begun at Santa Clara, CA. A conceptual design of a 10OMW-Class dual fuel power plant was developed; economics of natural gas versus coal gas use were analyzed. A facility was set up to manufacture 2 MW/yr of carbonate fuel cell stacks. A 100kW-Class subscale power plant was built and several stacks were tested. This power plant has achieved an efficiency of {approximately}50% (LHV) from pipeline natural gas to direct current electricity conversion. Over 6,000 hours of operation including 5,000 cumulative hours of stack operation were demonstrated. One stack was operated on natural gas at 130 kW, which is the highest carbonate fuel cell power produced to date, at 74% fuel utilization, with excellent performance distribution across the stack. In parallel, carbonate fuel cell performance has been improved, component materials have been proven stable with lifetimes projected to 40,000 hours. Matrix strength, electrolyte distribution, and cell decay rate have been improved. Major progress has been achieved in lowering stack cost.

NONE

1995-03-01T23:59:59.000Z

196

Clean Coal Technology III: 10 MW Demonstration of Gas Suspension Absorption final project performance and economics report  

SciTech Connect (OSTI)

The 10 MW Demonstration of the Gas Suspension Absorption (GSA) program is a government and industry co-funded technology development. The objective of the project is to demonstrate the performance of the GSA system in treating a 10 MW slipstream of flue gas resulting from the combustion of a high sulfur coal. This project involves design, fabrication, construction and testing of the GSA system. The Project Performance and Economics Report provides the nonproprietary information for the ``10 MW Demonstration of the Gas Suspension Absorption (GSA) Project`` installed at Tennessee Valley Authority`s (TVA) Shawnee Power Station, Center for Emissions Research (CER) at Paducah, Kentucky. The program demonstrated that the GSA flue-gas-desulfurization (FGD) technology is capable of achieving high SO{sub 2} removal efficiencies (greater than 90%), while maintaining particulate emissions below the New Source Performance Standards (NSPS), without any negative environmental impact (section 6). A 28-day test demonstrated the reliability and operability of the GSA system during continuous operation. The test results and detailed discussions of the test data can be obtained from TVA`s Final Report (Appendix A). The Air Toxics Report (Appendix B), prepared by Energy and Environmental Research Corporation (EERC) characterizes air toxic emissions of selected hazardous air pollutants (HAP) from the GSA process. The results of this testing show that the GSA system can substantially reduce the emission of these HAP. With its lower capital costs and maintenance costs (section 7), as compared to conventional semi-dry scrubbers, the GSA technology commands a high potential for further commercialization in the United States. For detailed information refer to The Economic Evaluation Report (Appendix C) prepared by Raytheon Engineers and Constructors.

Hsu, F.E.

1995-08-01T23:59:59.000Z

197

Regional GHG Emissions Stat s Greenhouse Gas and the Regional  

E-Print Network [OSTI]

(milliontonsCO2) Petroleum + Pet Coke Natural Gas Coal 8 0.0 10.0 20.0 1995 1996 1997 1998 1999 2000 2001 2002 and ½ Valmy coal plants) 2 #12;6/5/2013 2 GHG Emissions by Economic Sector in the Pacific Northwest (2010 Renewables 7 6%In 2011, the region 0.2% 6.4% Coal, 15.7% Nuclear, 2.0% 7.6%, g generated ~27,000 MWa ­ 68

198

Coal - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA) Indexed Site

Scheduled 2015 capacity additions mostly wind and natural gas; retirements mostly coal natural gaselectricityrenewablenucleargeneration capacitywindsolarretirementscapacity...

199

System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines  

SciTech Connect (OSTI)

Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

Shahrokh Etemad; Lance Smith; Kevin Burns

2004-12-01T23:59:59.000Z

200

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, further laboratory-screening tests of additive formulations were completed. For these tests, the electrostatic tensiometer method was used for determination of fly ash cohesivity. Resistivity was measured for each screening test with a multi-cell laboratory fly ash resistivity furnace constructed for this project. Also during this quarter chemical formulation testing was undertaken to identify stable and compatible resistivity/cohesivity liquid products.

Kenneth E. Baldrey

2001-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. During this reporting quarter, two cohesivity-specific additive formulations, ADA-44C and ADA-51, were evaluated in a full-scale trial at the American Electric Power Conesville plant. Ammonia conditioning was also evaluated for comparison. ADA-51 and ammonia conditioning significantly reduced rapping and non-rapped particulate re-entrainment based on stack opacity monitor data. Based on the successful tests to date, ADA-51 will be evaluated in a long-term test.

Kenneth E. Baldrey

2003-02-01T23:59:59.000Z

202

Advanced turbine design for coal-fueled engines. Phase 1, Erosion of turbine hot gas path blading: Final report  

SciTech Connect (OSTI)

The investigators conclude that: (1) Turbine erosion resistance was shown to be improved by a factor of 5 by varying the turbine design. Increasing the number of stages and increasing the mean radius reduces the peak predicted erosion rates for 2-D flows on the blade airfoil from values which are 6 times those of the vane to values of erosion which are comparable to those of the vane airfoils. (2) Turbine erosion was a strong function of airfoil shape depending on particle diameter. Different airfoil shapes for the same turbine operating condition resulted in a factor of 7 change in airfoil erosion for the smallest particles studied (5 micron). (3) Predicted erosion for the various turbines analyzed was a strong function of particle diameter and weaker function of particle density. (4) Three dimensional secondary flows were shown to cause increases in peak and average erosion on the vane and blade airfoils. Additionally, the interblade secondary flows and stationary outer case caused unique erosion patterns which were not obtainable with 2-D analyses. (5) Analysis of the results indicate that hot gas cleanup systems are necessary to achieve acceptable turbine life in direct-fired, coal-fueled systems. In addition, serious consequences arise when hot gas filter systems fail for even short time periods. For a complete failure of the filter system, a 0.030 in. thick corrosion-resistant protective coating on a turbine blade would be eroded at some locations within eight minutes.

Wagner, J.H.; Johnson, B.V.

1993-04-01T23:59:59.000Z

203

Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts  

SciTech Connect (OSTI)

Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

2010-12-31T23:59:59.000Z

204

Nuclear Power: a Hedge against Uncertain Gas and Carbon Prices?  

E-Print Network [OSTI]

conducted in Belgium (Ampere, 2000), the U.K. (RAE, 2004), Finland (Tarjanne and Rissanen, 2000), France (Dideme, 2003), and the USA (Deutch et al., 2003, and Tolley et al., 2004). The table shows wide differences in the results, arising mainly from... Belgium (Ampere) Finland (Tarjanne) France (DGEMP) UK (RAE) USA (Deutch et al., MIT) USA (Tolley et al., University of Chicago) Date 2000 2001 2003 2004 2003 2004 Nuclear CCGT Nuclear CCGT Nuclear CCGT Nuclear CCGT Nuclear CCGT...

Roques, Fabien A; Nuttall, William J; Newbery, David; de Neufville, Richard

2006-03-14T23:59:59.000Z

205

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

206

Enhancing the use of coals by gas reburning-sorbent injection. Environmental monitoring quarterly report No. 8, April 1--June 30, 1992  

SciTech Connect (OSTI)

Clean Coal Technology implies the use of coal in an environmentally acceptable manner. Coal combustion results in the emission of two types of acid rain precursors: oxides of sulfur (sox) and oxides of nitrogen (NO{sub x}). This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions. Gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO{sub 4}, an injection temperature of about 1230{degrees}C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H{sub 2}O added for humidification. The specific goal of this project is to demonstrate NO{sub x} and SO{sub x} emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-07-27T23:59:59.000Z

207

The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 8, 1 July, 1993--30 September, 1993  

SciTech Connect (OSTI)

Task 1, the preparation of catalyst materials, is proceeding actively. At WVU, catalysts based on Mo are being prepared using a variety of approaches to alter the oxidation state and environment of the Mo. At UCC and P, copper-based zinc chromite spinel catalysts will be prepared and tested. The modeling of the alcohol-synthesis reaction in a membrane reactor is proceeding actively. Under standard conditions, pressure drop in the membrane reactor has been shown to be negligible. In Task 2, base case designs had previously been completed with a Texaco gasifier. Now, similar designs have been completed using the Shell gasifier. A comparison of the payback periods or production cost of these plants shows significant differences among the base cases. However, a natural gas only design, prepared for comparison purposes, gives a lower payback period or production cost. Since the alcohol synthesis portion of the above processes is the same, the best way to make coal-derived higher alcohols more attractive economically than natural gas-derived higher alcohols is by making coal-derived syngas less expensive than natural gas-derived syngas. The maximum economically feasible capacity for a higher alcohol plant from coal-derived syngas appears to be 32 MM bbl/yr. This is based on consideration of regional coal supply in the eastern US, coal transportation, and regional product demand. The benefits of economics of scale are illustrated for the base case designs. A value for higher alcohol blends has been determined by appropriate combination of RVP, octane number, and oxygen content, using MTBE as a reference. This analysis suggests that the high RVP of methanol in combination with its higher water solubility make higher alcohols more valuable than methanol.

Not Available

1993-10-01T23:59:59.000Z

208

Coal: the new black  

SciTech Connect (OSTI)

Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

Tullo, A.H.; Tremblay, J.-F.

2008-03-15T23:59:59.000Z

209

Nuclear PowerNuclear PowerNuclear PowerNuclear PowerNuclear PowerNuclear PowerNuclear PowerNuclear Power''''''''s Dirty Littles Dirty Littles Dirty Littles Dirty Littles Dirty Littles Dirty Littles Dirty Littles Dirty Little Secret: Uranium MiningSecret:  

E-Print Network [OSTI]

,000,000 2,500,000 3,000,000 3,500,000 4,000,000 4,500,000 1 2 3 4 5 6 7 8 9 10 11 12 Coal[1] Petroleum Liquids[2] Petroleum Coke Natural Gas Other Gases[3] Nuclear Hydroelectric Conventional Other Renewables[4 Consumption Petroleum Coal Natural Gas Non-biogenic MSW and Geothermal Energy Subtotal http

Sheridan, Jennifer

210

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

211

A gas-rich nuclear bar fuelling a powerful central starburst in NGC 2782  

E-Print Network [OSTI]

We present evidence that the peculiar interacting starburst galaxy NGC 2782 (Arp 215) harbors a gas-rich nuclear stellar bar feeding an M82-class powerful central starburst, from a study based on OVRO CO (J=1->0) data, WIYN BVR & Halpha observations, along with available NIR images, a 5 GHz RC map and HST images. NGC 2782 harbors a clumpy, bar-like CO feature of radius ~ 7.5'' (1.3 kpc) which leads a nuclear stellar bar of similar size. The nuclear CO bar is massive: it contains ~2.5x10**9 M_sun of molecular gas, which makes up ~ 8 % of the dynamical'mass present within a 1.3 kpc radius. Within the CO bar, emission peaks in two extended clumpy lobes which lie on opposite sides of the nucleus, separated by ~ 6'' (1 kpc). Between the CO lobes, in the inner 200 pc radius, resides a powerful central starburst which is forming stars at a rate of 3 to 6 M_sun yr-1. While circular motions dominate the CO velocity field, the CO lobes show weak bar-like streaming motions on the leading side of the nuclear stellar bar, suggestive of gas inflow. We estimate semi-analytically the gravitational torque from the nuclear stellar bar on the gas, and suggest large gas inflow rates from the CO lobes into the central starburst. These observations, which are amongst the first ones showing a nuclear stellar bar fuelling molecular gas into an intense central starburst, are consistent with simulations and theory which suggest that nuclear bars provide an efficient way of transporting gas closer to the galactic center to fuel central activity. Furthermore, several massive clumps are present at low radii, and dynamical friction might produce further gas inflow. We suggest that the nuclear molecular gas bas and central activity will be very short-lived, likely disappearing within 5x10**8 years.

Shardha Jogee; Jeffrey D. P. Kenney; Beverly J. Smith

1999-07-07T23:59:59.000Z

212

Supersonic coal water slurry fuel atomizer  

DOE Patents [OSTI]

A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

1991-01-01T23:59:59.000Z

213

Minimum carbon tax level needed to prompt a widespread shift to nuclear power  

E-Print Network [OSTI]

Carbon dioxide is suspected to be a major contributor to global warming. In the United States, nearly 70% of electricity is produced using coal or natural gas, both of which emit carbon dioxide into the environment. Nuclear ...

Thornton, Katherine C. (Katherine Claire)

2007-01-01T23:59:59.000Z

214

Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes  

SciTech Connect (OSTI)

This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

1982-01-01T23:59:59.000Z

215

Physical features of accumulation and distribution processes of small disperse coal dust precipitations and absorbed radioactive chemical elements in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of absorption process of radioactive chemical elements and their isotopes in the iodine air filters of the type of AU-1500 at the nuclear power plants are researched. It is shown that the non-homogenous spatial distribution of absorbed radioactive chemical elements and their isotopes in the iodine air filter, probed by the gamma-activation analysis method, is well correlated with the spatial distribution of small disperse coal dust precipitations in the iodine air filter. This circumstance points out to an important role by the small disperse coal dust fractions of absorber in the absorption process of radioactive chemical elements and their isotopes in the iodine air filter. The physical origins of characteristic interaction between the radioactive chemical elements and the accumulated small disperse coal dust precipitations in an iodine air filter are considered. The analysis of influence by the researched physical processes on the technical characteristics and functionality of iodine ...

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

216

Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +  

E-Print Network [OSTI]

pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system scrubber (pH ~ 6) 60 - 70 7 Re-heater 350 - 400 8 SCR DeNOx 300 - 400 9 Active coke bed 100 - 150 Figure 10

Zevenhoven, Ron

217

MS_Coal_Studyguide.indd  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

what about costs? Th e mining, transportation, electricity generation, and pollution-control costs associated with using coal are increasing, but both natural gas and oil are...

218

Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming  

SciTech Connect (OSTI)

Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

Not Available

1982-01-01T23:59:59.000Z

219

Surfactant based imbibition and induced solution gas drive process: investigation by nuclear magnetic resonance  

E-Print Network [OSTI]

drive mechanism. This imbibition and induced solution gas drive study employed nuclear magnetic resonance (NMR) spectroscopy techniques to monitor and characterize the progress of oil recovery inside the rock sample core. A specially designed core...SURFACTANT BASED IMBIBITION AND INDUCED SOLUTION GAS DRIVE PROCESS: INVESTIGATION BY NUCLEAR MAGNETIC RESONANCE A Thesis by JAMES CALVIN COX Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Cox, James Calvin

1993-01-01T23:59:59.000Z

220

Bio-coal briquette  

SciTech Connect (OSTI)

Some of the developing nations aim to earn foreign currency by exporting oil and/or gas and to increase the domestic consumption of coal to ensure a secure energy supply. Therefore, it is very important to promote effective coal utilization in these nations. Currently, these countries experience problems associated with coal use for household cooking and household industries. For household cooking, coal creates too much smoke and smells unpleasant. In addition, illegally obtained firewood is almost free in local agricultural regions. Coal is also used in household industries; however, simple stoker boilers are inefficient, since unburned coal particles tend to drop through screens during the combustion process. The bio-coal briquette, on the other hand, is an effective and efficient fuel, since it utilizes coal, which is to be used extensively in households and in small and medium-scale industry sectors in some coal-producing countries, as a primary fuel and bamboos (agricultural waste) as a secondary fuel. In addition, the use of bio-coal briquettes will greatly help reduce unburned coal content.

Honda, Hiroshi

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
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221

Comparative Life-Cycle Air Emissions of Coal, Domestic Natural  

E-Print Network [OSTI]

come domestically from the production of synthetic natural gas (SNG) via coal gasification- methanation gasification technologies that use coal to produce SNG. This National Gasification Strategy calls

Jaramillo, Paulina

222

Fact #844: October 27, 2014 Electricity Generated from Coal has...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

4: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has...

223

Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications  

SciTech Connect (OSTI)

The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

Joseph Rabovitser

2009-06-30T23:59:59.000Z

224

Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Regionat Cornell Batteries & Fuel Cells In ThisMetalCenter for Gas

225

Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high-temperature furnace (HITAF): Volume 3. Final report  

SciTech Connect (OSTI)

Testing of an atmospheric circulating bed pyrolyzer was done at Southern Illinois University. A variety of experiments have been conducted in a laboratory scale pyrolyzer with coal input flow rates from 2 to 6 lb/h. three feed coal particle sizes, corresponding to a nominal -40 mesh, -30 mesh and -18 mesh were used. The limestone used in the tests was a Genstar limestone. Parameters investigated in the tests include the influence of superficial velocity, temperature and coal-air mass ratios. Char particle size distributions under various test conditions have been measured and the char composition determined. Fuel gas composition, yields and heating values have been investigated. Char morphology has been studied using scanning electron microscopy. Char reactivity for selected samples has been measures, and the influence of feed coal size, bed temperature and superficial velocity has been determined. Material balance calculations have been performed and found to be in very good agreement. Energy audit calculations for the process have been made to investigate the flow of energy and to estimate the losses during the process. Full details of the data, results obtained and conclusions drawn are presented.

NONE

1996-05-01T23:59:59.000Z

226

Sectoral trends in global energy use and greenhouse gas emissions  

E-Print Network [OSTI]

produced. Primary energy associated with coal products wasUse EJ China Residential Energy Use Gas Coal Oil Biomass GasUse EJ China Residential Energy Use Gas Coal Oil Gas Biomass

2006-01-01T23:59:59.000Z

227

Biogeochemistry of Microbial Coal-Bed Methane  

E-Print Network [OSTI]

Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo´c,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

Macalady, Jenn

228

Nuclear Fusion (Nuclear Fusion ( )) as Clean Energy Source for Mankindas Clean Energy Source for Mankind  

E-Print Network [OSTI]

from renewables (wind power, solar power, hydropower, geothermal, ocean wave & tidal power, biomass energy resources (coal 43%, natural gas 19%, oil 6%, cogeneration 7%); ~21% by nuclear fission power the Moon. #12;ADVANTAGES OF FUSION · Abundant Supply of Fuel (deuterium and tritium) · No Risk of Nuclear

Chen, Yang-Yuan

229

Study of factors affecting syngas quality and their interactions in fluidized bed gasification of lignite coal  

E-Print Network [OSTI]

gas emissions from coal-fired power plants has led to renewed interest in gasification as a clean-coal with the Canada's Clean Coal Technology Roadmap [2] and CO2 Capture and Storage Technology Roadmap [3], clean coal

Spiteri, Raymond J.

230

Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching. | EMSL Bubbles andof the Trough and its60-42773

231

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of the aerodynamic resistance of a model of the vertical iodine air filter is completed. The comparative analysis of the technical characteristics of the vertical and horizontal iodine air filters is also made.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2013-02-18T23:59:59.000Z

232

Coal combustion system  

DOE Patents [OSTI]

In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

1988-01-01T23:59:59.000Z

233

Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report  

SciTech Connect (OSTI)

A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

NONE

1996-03-01T23:59:59.000Z

234

Method of extracting coal from a coal refuse pile  

DOE Patents [OSTI]

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Yavorsky, Paul M. (Monongahela, PA)

1991-01-01T23:59:59.000Z

235

Clean coal  

SciTech Connect (OSTI)

The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

2006-07-15T23:59:59.000Z

236

REMEDIAT1NG AT MANUFACTURED GAS  

E-Print Network [OSTI]

, comhusti- hle gas manufactured Pfrom coke, coal, and oil 1 served as the major gas- eous fuel for urban for the three primary gas production meth- ods: coal carbonization, carbureted water gas production, and oil gas, and metals. Tar resid- uals were produced from the vola- tiIe component of bituminous coals in coal

Peters, Catherine A.

237

Coal-oil slurry preparation  

DOE Patents [OSTI]

A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

Tao, John C. (Perkiomenville, PA)

1983-01-01T23:59:59.000Z

238

Effect of cavitation on the properties of coal-tar pitch as studied by gas-liquid chromatography  

SciTech Connect (OSTI)

The applicability of the cavitation-wave effect to coal-tar pitch processing is considered. The results of the GLC analysis of the test material before and after rotor-pulsation cavitation treatment are given. The organic matter of coal-tar pitch was found to degrade upon cavitation; as a result of this, the yields of light and medium fractions considerably increased. 5 refs., 2 figs., 4 tabs.

M.I. Baikenov; T.B. Omarbekov; S.K. Amerkhanova (and others) [Buketov State University, Karaganda (Kazakhstan)

2008-02-15T23:59:59.000Z

239

Non-congruence of liquid-gas phase transition of asymmetric nuclear matter  

E-Print Network [OSTI]

We first explore the liquid-gas mixed phase in a bulk calculation, where two phases coexist without the geometrical structures. In the case of symmetric nuclear matter, the system behaves congruently, and the Maxwell construction becomes relevant. For asymmetric nuclear matter, on the other hand, the phase equilibrium is no more attained by the Maxwell construction since the liquid and gas phases are non-congruent; the particle fractions become completely different with each other. One of the origins of such non-congruence is attributed to the large symmetry energy. Subsequently we explore the charge-neutral nuclear matter with electrons by fully applying the Gibbs conditions to figure out the geometrical (pasta) structures in the liquid-gas mixed phase. We emphasize the effects of the surface tension and the Coulomb interaction on the pasta structures. We also discuss the thermal effects on the pasta structures.

Maruyama, Toshiki

2012-01-01T23:59:59.000Z

240

Non-congruence of liquid-gas phase transition of asymmetric nuclear matter  

E-Print Network [OSTI]

We first explore the liquid-gas mixed phase in a bulk calculation, where two phases coexist without the geometrical structures. In the case of symmetric nuclear matter, the system behaves congruently, and the Maxwell construction becomes relevant. For asymmetric nuclear matter, on the other hand, the phase equilibrium is no more attained by the Maxwell construction since the liquid and gas phases are non-congruent; the particle fractions become completely different with each other. One of the origins of such non-congruence is attributed to the large symmetry energy. Subsequently we explore the charge-neutral nuclear matter with electrons by fully applying the Gibbs conditions to figure out the geometrical (pasta) structures in the liquid-gas mixed phase. We emphasize the effects of the surface tension and the Coulomb interaction on the pasta structures. We also discuss the thermal effects on the pasta structures.

Toshiki Maruyama; Toshitaka Tatsumi

2012-04-25T23:59:59.000Z

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241

Comprehensive report to Congress: Clean Coal Technology program: Evaluation of gas reburning and low-NO sub x burners on a wall-fired boiler  

SciTech Connect (OSTI)

This report briefly describes the Gas Reburning and Low-NO{sub x} Burners technology which is a low-cost technology that can be applied in both retrofit and new applications. This demonstration will be conducted on a utility boiler in Colorado at Cherokee Station {number sign}3; however, the technology is applicable to industrial boilers and other combustion systems. Although this technology is primarily a NO{sub x} reduction technology, some reductions in other emissions will take place. Since 15--20% of the coal is replaced with natural gas, SO{sub 2} and particulate emissions are reduced commensurately. Also the lower carbon-to-hydrogen ratio of natural gas compared to coal reduces CO{sub 2} emissions. The formation of NO{sub x} is controlled by several factors: (1) the amount of nitrogen that is chemically bound in the fuel; (2) the flame temperature; (3) the residence time that combustion products remain at very high temperatures; and (4) the amount of excess oxygen available, especially at the hottest parts of the flame. Decreasing any of these parameters, tends to reduce NO{sub x} formation. 6 figs., 1 tab.

Not Available

1990-09-01T23:59:59.000Z

242

Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts  

SciTech Connect (OSTI)

Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120�, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230�, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky Center for Applied Energy Research (UK-CAER) led by Dr. Burt Davis. We first conducted a detailed thermodynamic analysis. The three primary mechanisms whereby the contaminants may deactivate the catalyst are condensation, deposition, and reaction. AsH{sub 3}, PH{sub 3}, H{sub 2}S, HCl, NH{sub 3} and HCN were found to have a major impact on the Fe-FT catalyst by producing reaction products, while NaCl, KCl and PH{sub 3} produce trace amounts of deposition products. The impact of the contaminants on the activity, selectivity, and deactivation rates (lifetime) of the catalysts was determined in bench-scale tests. Most of the contaminants appeared to adsorb onto (or react with) the HT- and LT-WGS catalysts were they were co-fed with the syngas: � 4.5 ppmv AsH{sub 3} or 1 ppmv PH{sub 3} in the syngas impacted the selectivity and CO conversion of both catalysts; � H{sub 2}S slowly degraded both WGS catalysts; - A binary mixture of H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv) impacted the activity of the LT-WGS catalyst, but not the HT-WGS catalyst � Moderate levels of NH{sub 3} (100 ppmv) or HCN (10 ppmv) had no impact � NaCl or KCl had essentially no effect on the HT-WGS catalyst, but the activity of the LT-WGS catalyst decreased very slowly Long-term experiments on the Co-FT catalyst at 260 and 270 °C showed that all of the contaminants impacted it to some extent with the exception of NaCl and HF. Irrespective of its source (e.g., NH{sub 3}, KNO{sub 3}, or HNO{sub 3}), ammonia suppressed the activity of the Co-FT catalyst to a moderate degree. There was essentially no impact the Fe-FT catalyst when up to 100 ppmw halide compounds (NaCl and KCl), or up to 40 ppmw alkali bicarbonates (NaHCO{sub 3} and KHCO{sub 3}). After testing, BET analysis showed that the surface areas, and pore volumes and diameters of both WGS catalysts decreased during both single and binary H2S and NH3 tests, which was attributed to sintering and pore filling by the impurities. The HT-WGS catalyst was evaluated with XRD after testing in syngas that contained 1 ppmv PH{sub 3}, or 2 ppmv H{sub 2}S, or both H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv). The peaks became sharper during testing, which was indicative of crystal growth and sintering, but no new phases were detected. After LT-WGS tests (3-33 ppmv NH{sub 3} and/or 0-88 ppmv H{sub 2}S) there were a few new phases that appeared, including sulfides. The fresh Fe-FT catalyst was nanocrystalline and amorphous. ICP-AA spectroscopy and other methods (e.g., chromatography) were used to analyze for

Gokhan Alptekin

2012-09-30T23:59:59.000Z

243

FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC{trademark} baghouse. Activated carbon was injected between the ESP and COHPAC{trademark} units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC{trademark} unit. The test also showed that activated carbon was effective in removing both forms of mercury--elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC{trademark}. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC{trademark} system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC{trademark} performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

2004-01-29T23:59:59.000Z

244

Tritium Transport at the Rulison Site, a Nuclear-stimulated Low-permeability Natural Gas Reservoir  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) and its predecessor agencies conducted a program in the 1960s and 1970s that evaluated technology for the nuclear stimulation of low-permeability natural gas reservoirs. The second project in the program, Project Rulison, was located in west-central Colorado. A 40-kiltoton nuclear device was detonated 2,568 m below the land surface in the Williams Fork Formation on September 10, 1969. The natural gas reservoirs in the Williams Fork Formation occur in low permeability, fractured sandstone lenses interbedded with shale. Radionuclides derived from residual fuel products, nuclear reactions, and activation products were generated as a result of the detonation. Most of the radionuclides are contained in a cooled, solidified melt glass phase created from vaporized and melted rock that re-condensed after the test. Of the mobile gas-phase radionuclides released, tritium ({sup 3}H or T) migration is of most concern. The other gas-phase radionuclides ({sup 85}Kr, {sup 14}C) were largely removed during production testing in 1969 and 1970 and are no longer present in appreciable amounts. Substantial tritium remained because it is part of the water molecule, which is present in both the gas and liquid (aqueous) phases. The objectives of this work are to calculate the nature and extent of tritium contamination in the subsurface from the Rulison test from the time of the test to present day (2007), and to evaluate tritium migration under natural-gas production conditions to a hypothetical gas production well in the most vulnerable location outside the DOE drilling restriction. The natural-gas production scenario involves a hypothetical production well located 258 m horizontally away from the detonation point, outside the edge of the current drilling exclusion area. The production interval in the hypothetical well is at the same elevation as the nuclear chimney created by the detonation, in order to evaluate the location most vulnerable to tritium migration.

C. Cooper; M. Ye; J. Chapman

2008-04-01T23:59:59.000Z

245

Caloric Curves for small systems in the Nuclear Lattice Gas Model  

E-Print Network [OSTI]

For pedagogical reasons we compute the caloric curve for 11 particles in a $3^3$ lattice. Monte-Carlo simulation can be avoided and exact results are obtained. There is no back-bending in the caloric curve and negative specific heat does not appear. We point out that the introduction of kinetic energy in the nuclear Lattice Gas Model modifies the results of the standard Lattice Gas Model in a profound way.

C. B. Das; S. Das Gupta

2000-09-27T23:59:59.000Z

246

NNSA implements nondestructive gas sampling technique for nuclear weapon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | National Nuclear SecurityAdministration emergencycomponents

247

Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I  

SciTech Connect (OSTI)

The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of the CO{sub 2} in the original process as converted to methane. The process could under another option avoid emissions following the conversion to SNG through an adjunct algae conversion process. The algae would then be converted to fuels or other products. An additional application of the algae process at the end use natural gas fired plant could further reduce emissions. The APS team fully recognizes the competition facing the process from natural gas and imported liquid natural gas. While we expect those resources to set the price for methane in the near-term, the team's work to date indicates that the AHP process can be commercially competitive, with the added benefit of assuring long-term energy supplies from North American resources. Conversion of coal to a more readily transportable fuel that can be employed near load centers with an overall reduction of greenhouses gases is edging closer to reality.

Raymond Hobbs

2007-05-31T23:59:59.000Z

248

The potential utilization of nuclear hydrogen for synthetic fuels production at a coal–to–liquid facility / Steven Chiuta.  

E-Print Network [OSTI]

??The production of synthetic fuels (synfuels) in coal–to–liquids (CTL) facilities has contributed to global warming due to the huge CO2 emissions of the process. This… (more)

Chiuta, Steven

2010-01-01T23:59:59.000Z

249

CORROSION OF IRON-BASE ALLOYS BY COAL CHAR AT 871 AND 982 C  

E-Print Network [OSTI]

Coal Processing . Corrosion . Preliminary Screening2. A. B. C. Gas Phase Corrosion Equilibrium Thermodynamicsof Gas Phase Corrosion Thermodynamic Stability Diagrams

Gordon, Bruce Abbott

2011-01-01T23:59:59.000Z

250

Response to Comment on "Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power"  

E-Print Network [OSTI]

Response to Comment on "Prevented Mortality and Greenhouse Gas Emissions from Historical, and properly (sustain- ably) designed biomass energy (e.g., see ref 3). This is rooted in the fact that wind production by 2022 following Japan's Fukushima nuclear accident. Despite a major, laudable expansion of wind

251

MOLECULAR GAS AND NUCLEAR ACTIVITY IN ULTRALUMINOUS INFRARED GALAXIES WITH DOUBLE NUCLEI  

E-Print Network [OSTI]

an assumption that the radio and infrared emission arise from supernovae and dust heating by massive starsMOLECULAR GAS AND NUCLEAR ACTIVITY IN ULTRALUMINOUS INFRARED GALAXIES WITH DOUBLE NUCLEI A. S August 2 ABSTRACT High-resolution CO(1 ! 0) observations of five ultraluminous infrared galaxies [ULIGs

Evans, Aaron S.

252

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

253

Co-combustion of refuse derived fuel and coal in a cyclone furnace at the Baltimore Gas and Electric Company, C. P. Crane Station  

SciTech Connect (OSTI)

A co-combustion demonstration burn of coal and fluff refuse-derived fuel (RDF) was conducted by Teledyne National and Baltimore Gas and Electric Company. This utility has two B and W cyclone furnaces capable of generating 400 MW. The facility is under a prohibition order to convert from No. 6 oil to coal; as a result, it was desirable to demonstrate that RDF, which has a low sulfur content, can be burned in combination with coals containing up to 2% sulfur, thus reducing overall sulfur emissions without deleterious effects. Each furnace consists of four cyclones capable of generating 1,360,000 pounds per hour steam. The tertiary air inlet of one of the cyclones was modified with an adapter to permit fluff RDF to be pneumatically blown into the cyclone. At the same time, coal was fed into the cyclone furnace through the normal coal feeding duct, where it entered the burning chamber tangentially and mixed with the RDF during the burning process. Secondary shredded fluff RDF was prepared by the Baltimore County Resource Recovery Facility. The RDF was discharged into a receiving station consisting of a belt conveyor discharging into a lump breaker, which in turn, fed the RDF into a pneumatic line through an air-lock feeder. A total of 2316 tons were burned at an average rate of 5.6 tons per hour. The average heat replacement by RDF for the cyclone was 25%, based on Btu input for a period of forty days. The range of RDF burned was from 3 to 10 tons per hour, or 7 to 63% heat replacement. The average analysis of the RDF (39 samples) for moisture, ash, heat (HHV) and sulfur content were 18.9%, 13.4%, 6296 Btu/lb and 0.26% respectively. RDF used in the test was secondary shredded through 1-1/2 inch grates producing the particle size distribution of from 2 inches to .187 inches. Findings to date after inspection of the boiler and superheater indicate satisfactory results with no deleterious effects from the RDF.

Not Available

1982-03-01T23:59:59.000Z

254

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antinodes of the acoustic waves are positioned. Finally, we completed the comparative analysis of the theoretical calculations with the experimental results, obtained for the cases of: 1) the experimental aerodynamic modeling of physical processes of the absorbed radioactive chemical elements and their isotopes distribution in the IAF; and 2) the gamma-activation spectroscopy analysis of the absorbed radioactive chemical elements and their isotopes distribution in the IAF. We made the innovative propositions on the necessary technical modifications with the purpose to improve the IAF technical characteristics and increase its operational time at the nuclear power plant (NPP), going from the completed precise characterization of the IAF parameters at the long term operation.

Oleg P. Ledenyov; Ivan M. Neklyudov

2013-06-14T23:59:59.000Z

255

Coal: the cornerstone of America's energy future  

SciTech Connect (OSTI)

In April 2005, US Secretary of Energy Samuel W. Bodman asked the National Coal Council to develop a 'report identifying the challenges and opportunities of more fully exploring our domestic coal resources to meet the nation's future energy needs'. The Council has responded with eight specific recommendations for developing and implementing advanced coal processing and combustion technologies to satisfy our unquenchable thirst for energy. These are: Use coal-to-liquids technologies to produce 2.6 million barrels/day; Use coal-to-natural gas technologies to produce 4 trillion ft{sup 3}/yr; Build 100 GW of clean coal plants by 2025; Produce ethanol from coal; Develop coal-to-hydrogen technologies; Use CO{sub 2} to enhance recovery of oil and coal-bed methane; Increase the capacity of US coal mines and railroads; and Invest in technology development and implementation. 1 ref.; 4 figs.; 1 tab.

Beck, R.A. [National Coal Council (United Kingdom)

2006-06-15T23:59:59.000Z

256

Enhancing the use of coals by gas reburning-sorbent injection. Environmental monitoring quarterly report No. 9, July 1--September 30, 1992  

SciTech Connect (OSTI)

This Clean Coal Technology project will demonstrate a combination of two developed technologies to reduce both NO{sub x} and SO{sub x} emissions: gas reburning and calcium based dry sorbent injection. The demonstrations will be conducted on two pre-NSPS utility boilers representative of the US boilers which contribute significantly to the inventory of acid rain precursor emissions: tangentially and cyclone fired units. Gas reburning is a combustion modification technique that consists of firing 80--85 percent of the fuel (corresponding to the total heat release) in the lower furnace. Reduction of NO{sub x} to molecular nitrogen (N{sub 2}) is accomplished via the downstream injection of the remaining fuel requirement in the form of natural gas (which also reduces the total SO{sub x} emissions). In a third stage, burnout air is injected at lower temperatures in the upper furnace to complete the combustion process without generating significant additional NO{sub x}. Dry sorbent injection consists of injecting calcium based sorbents (such as limestone, dolomite, or hydrated lime) into the combustion products. For sulfation of the sorbent to CaSO{sub 4}, an injection temperature of about 1230{degrees}C is optimum, but calcium-sulfur reactions can also take place at lower temperatures. Thus, the sorbent may be injected at different locations, such as with the burnout air, at the exit from the superheater, or into the ducting downstream of the air heater with H{sub 2}0 added for humidification. The calcium sulfate or sulfite products are collected together with unreacted sorbent fly ash by the electrostatic precipitator. The specific goal of this project is to demonstrate NO{sub x} and SO{sub x} emission reductions of 60 percent and 50 percent, respectively, on two coal fired utility boilers having the design characteristics mentioned above.

Not Available

1992-11-16T23:59:59.000Z

257

Energy and environmental research emphasizing low-rank coal: Task 3.4 -- Hot-gas cleaning. Topical report (includes semiannual report for January--June 1995)  

SciTech Connect (OSTI)

This report summarizes the accomplishments of three subtasks completed in support of the current and future hot-gas cleanup activities at the Energy and Environmental Research Center (EERC). The overall objective of the EERC hot-gas cleanup task is to develop reliable methods to remove particulate matter from high-temperature, high-pressure gas streams produced from coal combustion and/or gasification. Near-term task objectives include (1) design, fabrication, and assembly of a high-temperature, high-pressure bench-scale filter vessel; (2) design, fabrication, and assembly of a high-temperature, high-pressure sampling train; and (3) the preliminary design of a pilot-scale high-temperature, high-pressure filter vessel and support systems. Bench-scale hot-gas filter research will be performed with the pressurized fluid-bed reactor (PFBR) or the continuous fluid-bed reactor (CFBR) and a hot-gas filter vessel. The objectives of future work with the bench-scale system will be to determine particulate and vapor-phase alkali degradation of candidate ceramic filter structures as well as filter performance relative to particulate collection efficiency, differential pressure, and filter cleanability. Construction of the high-temperature, high-pressure sampling system was intended to support bench- and pilot-scale activities with respect to conventional particulate sampling (total mass and particle-size distribution) and hazardous air pollutant (HAP) sampling. Finally, pilot-scale tests will be performed to evaluate filter performance and determine alkali corrosion of ceramic materials with a hot-gas filter vessel attached to the EERC Transport Reactor Development Unit (TRDU).

Weber, G.F.; Swanson, M.L.

1995-06-01T23:59:59.000Z

258

Int. J. Oil, Gas and Coal Technology, Vol. 5, No. 1, 2012 1 Copyright 2012 Inderscience Enterprises Ltd.  

E-Print Network [OSTI]

Enterprises Ltd. Top-Down, Intelligent Reservoir Modeling of Oil and Gas Producing Shale Reservoirs; Case.Bromhal@netl.doe.gov Abstract: Producing hydrocarbon (both oil and gas) from Shale plays has attracted much attention in recent modeling approach to history matching, forecasting and analyzing oil and gas production from shale

Mohaghegh, Shahab

259

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

260

Panel Discussion: New Directions in Human Reliability Analysis for Oil & Gas, Cybersecurity, Nuclear, and Aviation  

SciTech Connect (OSTI)

This panel will discuss what new directions are necessary to maximize the usefulness of HRA techniques across different areas of application. HRA has long been a part of Probabilistic Risk Assessment in the nuclear industry as it offers a superior standard for risk-based decision-making. These techniques are continuing to be adopted by other industries including oil & gas, cybersecurity, nuclear, and aviation. Each participant will present his or her ideas concerning industry needs followed by a discussion about what research is needed and the necessity to achieve cross industry collaboration.

Harold S. Blackman; Ronald Boring; Julie L. Marble; Ali Mosleh; Najmedin Meshkati

2014-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

BLM biological assessment for T and E species for the WyCoalGas project. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project; Converse County, Wyoming  

SciTech Connect (OSTI)

This volume considers the water requirements of the proposed plant and possible sources of water supply. The water requirements are 7900 acre-feet per year at full production (1720 acre-feet would be supplied by the moisture in the coal). Surface and ground water sources are described and a private reservoir would be built to store water. The priority of use from each source is considered. Also, in some cases other present water rights come first. In almost every year little or no water would be available during August and September. Endangered species in the area are considered, in particular, the effect of the increased water usage on them. (LTN)

Not Available

1982-01-01T23:59:59.000Z

262

Process for heating coal-oil slurries  

DOE Patents [OSTI]

Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

1984-01-03T23:59:59.000Z

263

Process for heating coal-oil slurries  

DOE Patents [OSTI]

Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

1984-01-03T23:59:59.000Z

264

Integrated coal cleaning, liquefaction, and gasification process  

DOE Patents [OSTI]

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Chervenak, Michael C. (Pennington, NJ)

1980-01-01T23:59:59.000Z

265

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 5, Appendix D: Cost support information: Final report  

SciTech Connect (OSTI)

The cost estimate provided for the DOE sponsored study of Air Blown Coal Gasification was developed from vendor quotes obtained directly for the equipment needed in the 50 MW, 100 MW, and 200 MW sized plants and from quotes from other jobs that have been referenced to apply to the particular cycle. Quotes were generally obtained for the 100 MW cycle and a scale up/down factor was used to generate the cost estimates for the 200 MW and 50 MW cycles, respectively. Information from GTPro (property of Thermoflow, Inc.) was used to estimate the cost of the 200 MW and 50 MW gas turbine, HRSG, and steam turbines. To available the use of GTPro`s estimated values for this equipment, a comparison was made between the quotes obtained for the 100 MW cycle (ABB GT 11N combustion turbine and a HSRG) against the estimated values by GTPro.

Sadowski, R.S.; Brown, M.J.; Harriz, J.T.; Ostrowski, E.

1991-01-01T23:59:59.000Z

266

Modeling and valuing make-up clauses in gas swing Enrico Edoli1,2,3  

E-Print Network [OSTI]

purposes and is at present competing with coal as main fuel source for electric power generation. Hence the largest consumers of natural gas in the world, the gas being used mainly for heating and power generation-2013 forecasted [18]. Recent events concerning nuclear power generation, after the Fukushima accident

Vargiolu, Tiziano

267

Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator  

SciTech Connect (OSTI)

This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

2006-07-01T23:59:59.000Z

268

Process for electrochemically gasifying coal  

DOE Patents [OSTI]

A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

Botts, T.E.; Powell, J.R.

1985-10-25T23:59:59.000Z

269

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems  

SciTech Connect (OSTI)

The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

1991-02-01T23:59:59.000Z

270

Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes  

SciTech Connect (OSTI)

There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G. [University of Technology Sydney, Sydney, NSW (Australia). Dept. of Environmental Science

2009-07-15T23:59:59.000Z

271

Communication: Nuclear quadrupole moment-induced Cotton-Mouton effect in noble gas atoms  

SciTech Connect (OSTI)

New, high-sensitivity and high-resolution spectroscopic and imaging methods may be developed by exploiting nuclear magneto-optic effects. A first-principles electronic structure formulation of nuclear electric quadrupole moment-induced Cotton-Mouton effect (NQCME) is presented for closed-shell atoms. In NQCME, aligned quadrupole moments alter the index of refraction of the medium along with and perpendicular to the direction of nuclear alignment. The roles of basis-set convergence, electron correlation, and relativistic effects are investigated for three quadrupolar noble gas isotopes: {sup 21}Ne, {sup 83}Kr, and {sup 131}Xe. The magnitude of the resulting ellipticities is predicted to be 10{sup ?4}–10{sup ?6} rad/(M cm) for fully spin-polarized nuclei. These should be detectable in the Voigt setup. Particularly interesting is the case of {sup 131}Xe, in which a high degree of spin polarization can be achieved via spin-exchange optical hyperpolarization.

Fu, Li-juan; Vaara, Juha, E-mail: juha.vaara@iki.fi [NMR Research Group, Department of Physics, University of Oulu, P.O. Box 3000, FIN-90014 Oulu (Finland)] [NMR Research Group, Department of Physics, University of Oulu, P.O. Box 3000, FIN-90014 Oulu (Finland); Rizzo, Antonio [Istituto per i Processi Chimico-Fisici del Consiglio Nazionale delle Ricerche (IPCF-CNR), Area della Ricerca, via G. Moruzzi 1, I-56124 Pisa (Italy)] [Istituto per i Processi Chimico-Fisici del Consiglio Nazionale delle Ricerche (IPCF-CNR), Area della Ricerca, via G. Moruzzi 1, I-56124 Pisa (Italy)

2013-11-14T23:59:59.000Z

272

Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a  

E-Print Network [OSTI]

in the coal without chemical decomposition and pyrolysis converts dry coal into gas and coke [1]. The final1 Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a , Eric Blond1, b , Alain Gasser1 Forbach, France a damintode.kolani@univ-orleans.fr, b eric.blond@univ-orleans.fr Keywords: coal, drying

Paris-Sud XI, Université de

273

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 2, Appendices  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Data from sidestream testing are presented. 18 refs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

274

Commercialization of waste gob gas and methane produced in conjunction with coal mining operations. Final report, August 1992--December 1993  

SciTech Connect (OSTI)

The primary objectives of the project were to identify and evaluate existing processes for (1) using gas as a feedstock for production of marketable, value-added commodities, and (2) enriching contaminated gas to pipeline quality. The following gas conversion technologies were evaluated: (1) transformation to liquid fuels, (2) manufacture of methanol, (3) synthesis of mixed alcohols, and (4) conversion to ammonia and urea. All of these involved synthesis gas production prior to conversion to the desired end products. Most of the conversion technologies evaluated were found to be mature processes operating at a large scale. A drawback in all of the processes was the need to have a relatively pure feedstock, thereby requiring gas clean-up prior to conversion. Despite this requirement, the conversion technologies were preliminarily found to be marginally economic. However, the prohibitively high investment for a combined gas clean-up/conversion facility required that REI refocus the project to investigation of gas enrichment alternatives. Enrichment of a gas stream with only one contaminant is a relatively straightforward process (depending on the contaminant) using available technology. However, gob gas has a unique nature, being typically composed of from constituents. These components are: methane, nitrogen, oxygen, carbon dioxide and water vapor. Each of the four contaminants may be separated from the methane using existing technologies that have varying degrees of complexity and compatibility. However, the operating and cost effectiveness of the combined system is dependent on careful integration of the clean-up processes. REI is pursuing Phase 2 of this project for demonstration of a waste gas enrichment facility using the approach described above. This is expected to result in the validation of the commercial and technical viability of the facility, and the refinement of design parameters.

Not Available

1993-12-01T23:59:59.000Z

275

Abstract-Coal and hydro will be the main sources of electric energy in Chile for the near future, given that natural gas  

E-Print Network [OSTI]

Abstract- Coal and hydro will be the main sources of electric energy in Chile for the near future and the environmental dilemma faced by the country, where both coal and hydro produce some kind of impact. The role

Dixon, Juan

276

On the structurization of coal dust precipitations and their influence on aerodynamic resistance by granulated mediums in air filters at nuclear power plants  

E-Print Network [OSTI]

The processes of structurization of dust precipitations in granulated filtering mediums, formed by the monolithic glass spherical granules with the diameters of 2mm and 3mm, are re-searched. The distinctions between the distributions of filtered coal dust masses in the air filters with cylindrical granules and the air filters with spherical granules, are found. The influences by the filtered dust masses on the air resistance of both the air filters with the cylindrical granules and the air filters with the spherical granules are described. The conclusions on a possibility of the use of various chemical adsorbents with different geometric forms and volumetric dimensions to improve the filtering properties of granulated filtering mediums in air filters at nuclear power plants are formulated.

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2012-01-01T23:59:59.000Z

277

On the structurization of coal dust precipitations and their influence on aerodynamic resistance by granulated mediums in air filters at nuclear power plants  

E-Print Network [OSTI]

The processes of structurization of dust precipitations in granulated filtering mediums, formed by the monolithic glass spherical granules with the diameters of 2mm and 3mm, are re-searched. The distinctions between the distributions of filtered coal dust masses in the air filters with cylindrical granules and the air filters with spherical granules, are found. The influences by the filtered dust masses on the air resistance of both the air filters with the cylindrical granules and the air filters with the spherical granules are described. The conclusions on a possibility of the use of various chemical adsorbents with different geometric forms and volumetric dimensions to improve the filtering properties of granulated filtering mediums in air filters at nuclear power plants are formulated.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2012-07-02T23:59:59.000Z

278

A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction  

E-Print Network [OSTI]

gas sequestration into coal seams. J Geophys. Res. (2007).Reservoir engineering in coal seams: part 1—the physicalstorage and movement in coal seams. SPE Reserv. Eng. , 2(1),

Liu, Hui-Hai; Rutqvist, Jonny

2010-01-01T23:59:59.000Z

279

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents [OSTI]

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z

280

Combined cycle power plant incorporating coal gasification  

DOE Patents [OSTI]

A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams  

SciTech Connect (OSTI)

Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

1980-07-01T23:59:59.000Z

282

New developments in coal briquetting technology  

SciTech Connect (OSTI)

Briquetting of coal has been with us for well over a century. In the earliest applications of coal briquetting, less valuable fine coal was agglomerated into briquettes using a wide variety of binders, including coal tar, pitch and asphalt. Eventually, roll briquetters came into more widespread use, permitting the process to become a continuous one. Coal briquetting went out of favor during the 1950s in most of the industrialized world. The major reason for this decline in use was the discovery that the coal gas distillates used for binders were harmful to human health. Also, the abundance of cheap petroleum made coal briquettes a less attractive alternative as an industrial or domestic fuel. The re-emergence of coal as a primary industrial fuel and also its increased prominence as a fuel for thermal electric power stations led to a large increase in the annual volume of coal being mined worldwide. Coal preparation technology steadily improved over the years with the general exception of fine coal preparation. The processes available for treating this size range were considerably more expensive per unit mass of coal treated than coarse coal processes. Also, costly dewatering equipment was required after cleaning to remove surface moisture. Even with dewatering, the high surface area per unit mass of fine coal versus coarse coal resulted in high moisture contents. Therefore, little incentive existed to improve the performance of fine coal processes since this would only increase the amount of wet coal fines which would have to be dealt with. With such an ever-increasing volume of coal fines being created each year, there emerged an interest in recovering this valuable product. Several schemes were developed to recover coal fines discarded in abandoned tailings impoundments by previous operations.

Tucker, P.V. [Kilborn Inc., Ontario (Canada); Bosworth, G.B. [Kilborn Engineering Pacific Ltd., Vancouver, British Columbia (Canada); Kalb, G.W. [KKS Systems Inc., Wheeling, WV (United States)

1993-12-31T23:59:59.000Z

283

Assessment of undiscovered carboniferous coal-bed gas resources of the Appalachian Basin and Black Warrior Basin Provinces, 2002  

SciTech Connect (OSTI)

Coalbed methane (CBM) occurs in coal beds of Mississippian and Pennsylvanian (Carboniferous) age in the Appalachian basin, which extends almost continuously from New York to Alabama. In general, the basin includes three structural subbasins: the Dunkard basin in Pennsylvania, Ohio, and northern West Virginia; the Pocahontas basin in southern West Virginia, eastern Kentucky, and southwestern Virginia; and the Black Warrior basin in Alabama and Mississippi. For assessment purposes, the Appalachian basin was divided into two assessment provinces: the Appalachian Basin Province from New York to Alabama, and the Black Warrior Basin Province in Alabama and Mississippi. By far, most of the coalbed methane produced in the entire Appalachian basin has come from the Black Warrior Basin Province. 8 refs., 1 fig., 1 tab.

Milici, R.C.; Hatch, J.R.

2004-09-15T23:59:59.000Z

284

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 1  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Optimum operating parameters for zinc ferrite such as temperatures, gas compositions, and space velocities are discussed. From the test results, salient features of zinc ferrite were derived and discussed in regard to system implications, issues raised, and technical requirements. 47 refs., 53 figs., 41 tabs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

285

Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Quarterly progress report No. 7, July--September 1993  

SciTech Connect (OSTI)

A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluating the economic and technical feasibility of the concept, and preparing an R&D plan to develop the concept further. Foster Wheeler Development Corporation (FWDC) is leading a team of companies involved in this effort. The power generating system being developed in this project will be an improvement over current coal-fired systems. Goals have been specified that relate to the efficiency, emissions, costs, and general operation of the system. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800{degrees}F in furnaces fired with coal-derived fuels and then directly heated in a natural-gas-fired combustor to about 2400{degrees}F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuel gas is relatively clean, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need to be a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown in Figure 1.

Not Available

1993-11-01T23:59:59.000Z

286

Sectoral trends in global energy use and greenhouse gas emissions  

E-Print Network [OSTI]

all fuels including electricity and syngas will be used forGas Electricity Biomass Syngas Space Heating Coal Oil Gas

2006-01-01T23:59:59.000Z

287

A Carbon Dioxide Gas Turbine Direct Cycle with Partial Condensation for Nuclear Reactors  

SciTech Connect (OSTI)

A carbon dioxide gas turbine power generation system with a partial condensation cycle has been proposed for thermal and fast nuclear reactors, in which compression is done partly in the liquid phase and partly in the gas phase. This cycle achieves higher cycle efficiency than a He direct cycle mainly due to reduced compressor work of the liquid phase and of the carbon dioxide real gas effect, especially in the vicinity of the critical point. If this cycle is applied to a thermal reactor, efficiency of this cycle is about 55% at a reactor outlet temperature of 900 deg. C and pressure of 12.5 MPa, which is higher by about 10% than a typical helium direct gas turbine cycle plant (PBMR) at 900 deg. C and 8.4 MPa; this cycle also provides comparable cycle efficiency at the moderate core outlet temperature of 600 deg. C with that of the helium cycle at 900 deg. C. If this cycle is applied to a fast reactor, it is anticipated to be an alternative to liquid metal cooled fast reactors that can provide slightly higher cycle efficiency at the same core outlet temperature; it would eliminate safety problems, simplify the heat transport system and simplify plant maintenance. A passive decay heat removal system is realized by connecting a liquid carbon dioxide storage tank with the reactor vessel and by supplying carbon dioxide gasified from the tank to the core in case of depressurization event. (authors)

Yasuyoshi Kato; Takeshi Nitawaki; Yoshio Yoshizawa [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152-8550 (Japan)

2002-07-01T23:59:59.000Z

288

Critical temperature for the nuclear liquid-gas phase transition (from multifragmentation and fission)  

E-Print Network [OSTI]

Critical temperature Tc for the nuclear liquid-gas phase transition is stimated both from the multifragmentation and fission data. In the first case,the critical temperature is obtained by analysis of the IMF yields in p(8.1 GeV)+Au collisions within the statistical model of multifragmentation (SMM). In the second case, the experimental fission probability for excited 188Os is compared with the calculated one with Tc as a free parameter. It is concluded for both cases that the critical temperature is higher than 16 MeV.

V. A. Karnaukhov; H. Oeschler; A. Budzanowski; S. P. Avdeyev; A. S. Botvina; E. A. Cherepanov; W. Karcz; V. V. Kirakosyan; P. A. Rukoyatkin; I. Skwirczynska; E. Norbeck

2008-01-29T23:59:59.000Z

289

KEY DESIGN REQUIREMENTS FOR THE HIGH TEMPERATURE GAS-COOLED REACTOR NUCLEAR HEAT SUPPLY SYSTEM  

SciTech Connect (OSTI)

Key requirements that affect the design of the high temperature gas-cooled reactor nuclear heat supply system (HTGR-NHSS) as the NGNP Project progresses through the design, licensing, construction and testing of the first of a kind HTGR based plant are summarized. These requirements derive from pre-conceptual design development completed to-date by HTGR Suppliers, collaboration with potential end users of the HTGR technology to identify energy needs, evaluation of integration of the HTGR technology with industrial processes and recommendations of the NGNP Project Senior Advisory Group.

L.E. Demick

2010-09-01T23:59:59.000Z

290

Fuel-Cycle and Nuclear Material Disposition Issues Associated with High-Temperature Gas Reactors  

SciTech Connect (OSTI)

The objective of this paper is to facilitate a better understanding of the fuel-cycle and nuclear material disposition issues associated with high-temperature gas reactors (HTGRs). This paper reviews the nuclear fuel cycles supporting early and present day gas reactors, and identifies challenges for the advanced fuel cycles and waste management systems supporting the next generation of HTGRs, including the Very High Temperature Reactor, which is under development in the Generation IV Program. The earliest gas-cooled reactors were the carbon dioxide (CO2)-cooled reactors. Historical experience is available from over 1,000 reactor-years of operation from 52 electricity-generating, CO2-cooled reactor plants that were placed in operation worldwide. Following the CO2 reactor development, seven HTGR plants were built and operated. The HTGR came about from the combination of helium coolant and graphite moderator. Helium was used instead of air or CO2 as the coolant. The helium gas has a significant technical base due to the experience gained in the United States from the 40-MWe Peach Bottom and 330-MWe Fort St. Vrain reactors designed by General Atomics. Germany also built and operated the 15-MWe Arbeitsgemeinschaft Versuchsreaktor (AVR) and the 300-MWe Thorium High-Temperature Reactor (THTR) power plants. The AVR, THTR, Peach Bottom and Fort St. Vrain all used fuel containing thorium in various forms (i.e., carbides, oxides, thorium particles) and mixtures with highly enriched uranium. The operational experience gained from these early gas reactors can be applied to the next generation of nuclear power systems. HTGR systems are being developed in South Africa, China, Japan, the United States, and Russia. Elements of the HTGR system evaluated included fuel demands on uranium ore mining and milling, conversion, enrichment services, and fuel fabrication; fuel management in-core; spent fuel characteristics affecting fuel recycling and refabrication, fuel handling, interim storage, packaging, transportation, waste forms, waste treatment, decontamination and decommissioning issues; and low-level waste (LLW) and high-level waste (HLW) disposal.

Shropshire, D.E.; Herring, J.S.

2004-10-03T23:59:59.000Z

291

Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology  

SciTech Connect (OSTI)

The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

Shiquan Tao

2006-12-31T23:59:59.000Z

292

Pyrolysis of coal  

DOE Patents [OSTI]

A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

1992-01-01T23:59:59.000Z

293

Inclined fluidized bed system for drying fine coal  

DOE Patents [OSTI]

Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

1992-02-11T23:59:59.000Z

294

Hadron resonance gas and mean-field nuclear matter for baryon number fluctuations  

E-Print Network [OSTI]

We give an estimate for the skewness and the kurtosis of the baryon number distribution in two representative models; i.e., models of a hadron resonance gas and relativistic mean-field nuclear matter. We emphasize formal similarity between these two descriptions. The hadron resonance gas leads to a deviation from the Skellam distribution if quantum statistical correlation is taken into account at high baryon density, but this effect is not strong enough to explain fluctuation data seen in the beam-energy scan at RHIC/STAR. In the calculation of mean-field nuclear matter the density correlation with the vector \\omega-field rather than the effective mass with the scalar \\sigma-field renders the kurtosis suppressed at higher baryon density so as to account for the experimentally observed behavior of the kurtosis. We finally discuss the difference between the baryon number and the proton number fluctuations from correlation effects in isospin space. Our numerical results suggest that such effects are only minor even in the case of complete randomization of isospin.

Kenji Fukushima

2014-09-09T23:59:59.000Z

295

Bioconversion of coal-derived synthesis gas to liquid fuels. Final report, September 29, 1992--December 27, 1994  

SciTech Connect (OSTI)

The proposed research project consists of an integrated, two-stage fermentation and a highly energy-efficient product separation scheme. In the first fermentation, Butyribacterium methylotrophicum converts carbon monoxide (CO) into butyric acid and acetic acids which are then converted into butanol, ethanol, and a small amount of acetone in the second stage fermentation by Clostridium acetobutylicum. An advanced separation system process, based on pervaporation, removes the alcohols from the fermentation broth as they are formed, along with some of the hydrogen sulfide (H{sub 2}S), to minimize possible inhibition of the fermentations. This bioconversion process offers a critical advantage over conventional, catalytic processes for synthesis gas conversion: the microorganisms are several orders of magnitude more sulfur tolerant than metallic catalysts. The catalysts require sulfur removal to the parts per million level, while the microorganisms are unaffected by H{sub 2}S and carbonyl sulfide (COS) at one part per hundred--roughly the composition of sulfur in raw synthesis gas. During the two-year course of this project, the following major objectives have been accomplished: demonstrated long-term cell recycle of continuous fermentation of synthesis gas; demonstrated cell immobilization of Butyribacterium methylotrophicum; identified trickle-bed reactor as a viable alternative fermentation method; modulated metabolic pathways to increase C4 formation during synthesis gas fermentation; recovered carbon and electrons from H{sub 2} and CO{sub 2} with pathway modulation for increased C4 production; developed bacterial strains with improved selectivity for butyrate fermentation; demonstrated two-stage CO to alcohol fermentation; and concentrated alcohol from solventogenic fermentation by pervaporation.

Jain, M.K.; Worden, R.M.; Grethlein, H.E.

1995-01-15T23:59:59.000Z

296

Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities  

E-Print Network [OSTI]

gas emissions from conven- tional power sources like coal.total emissions from coal- or natural gas-fired power plantsemissions, the lifecycle for natural gas power production is more complicated than that of coal.

Hagan, Colin R.

2012-01-01T23:59:59.000Z

297

Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.  

SciTech Connect (OSTI)

This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

Xie, X.; Wang, M.; Han, J. (Energy Systems)

2011-04-01T23:59:59.000Z

298

Coal extraction  

SciTech Connect (OSTI)

Coal is extracted using a mixed solvent which includes a substantially aromatic component and a substantially naphthenic component, at a temperature of 400/sup 0/ to 500/sup 0/C. Although neither component is an especially good solvent for coal by itself, the use of mixed solvent gives greater flexibility to the process and offers efficiency gains.

Clarke, J.W.; Kimber, G.M.; Rantell, T.D.; Snape, C.E.

1985-06-04T23:59:59.000Z

299

Laboratory scale studies of Pd/y-Al2O3 sorbents for the removal of trace contaminents from coal-derived fuel gas at elevated temperatures  

SciTech Connect (OSTI)

The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150-540 C) to hot (>540 C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/{gamma}-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/{gamma}-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

2010-12-31T23:59:59.000Z

300

X-ray Computed Tomography of coal: Final report  

SciTech Connect (OSTI)

X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

1986-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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301

High conversion of coal to transportation fuels for the future with low HC gas production. Progress report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence a small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

Wiser, W.H.; Oblad, A.G.

1996-01-01T23:59:59.000Z

302

Coal: America's energy future. Volume I  

SciTech Connect (OSTI)

Secretary of Energy Samuel W. Bodman requested the National Coal Council in April 2005 a report identifying the challenges and opportunities of more fully exploring the USA's domestic coal resources to meet the nations' future energy needs. This resultant report addresses the Secretary's request in the context of the President's focus, with eight findings and recommendations that would use technology to leverage the USA's extensive coal assets and reduce dependence on imported energy. Volume I outlines these findings and recommendations. Volume II provides technical data and case histories to support the findings and recommendations. Chapter headings of Volume I are: Coal-to-Liquids to Produce 2.6 MMbbl/d; Coal-to-Natural Gas to Produce 4.0 Tcf Per Year; Coal-to-Clean Electricity; Coal to Produce Ethanol; Coal-to-Hydrogen; Enhanced Oil and Gas (Coalbed Methane); Recovery as Carbon Management Strategies; Delineate U.S. Coal Reserves and Transportation Constraints as Part of an Effort to Maximize U.S. Coal Production; and Penn State Study, 'Economic Benefits of Coal Conversion Investments'.

NONE

2006-03-15T23:59:59.000Z

303

Liquid-gas phase transition in hot asymmetric nuclear matter with density-dependent relativistic mean-field models  

E-Print Network [OSTI]

The liquid-gas phase transition in hot asymmetric nuclear matter is studied within density-dependent relativistic mean-field models where the density dependence is introduced according to the Brown-Rho scaling and constrained by available data at low densities and empirical properties of nuclear matter. The critical temperature of the liquid-gas phase transition is obtained to be 15.7 MeV in symmetric nuclear matter falling on the lower edge of the small experimental error bars. In hot asymmetric matter, the boundary of the phase-coexistence region is found to be sensitive to the density dependence of the symmetry energy. The critical pressure and the area of phase-coexistence region increases clearly with the softening of the symmetry energy. The critical temperature of hot asymmetric matter separating the gas phase from the LG coexistence phase is found to be higher for the softer symmetry energy.

Guang-Hua Zhang; Wei-Zhou Jiang

2012-03-17T23:59:59.000Z

304

Apparatus for fixed bed coal gasification  

DOE Patents [OSTI]

An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

305

Underground Coal Thermal Treatment  

SciTech Connect (OSTI)

The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?¢ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?¢ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?¢ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?¢ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

2011-10-30T23:59:59.000Z

306

Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification  

SciTech Connect (OSTI)

In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. Foams from the residual gases can significantly alter the melting rate through mass and heat transfers. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform quantitative evolved gas analysis (EGA) and developed a simple calibration model which correlates the overall mass loss rate with the evolution rates for individual gases. The model parameters are obtained from the least squares analysis, assuming that the gas-evolving reactions are independent. Thus, the EGA adds the ‘chemical identity’ to the reactions indicated by the ‘phenomenological’ kinetic model.

Rodriguez, Carmen P.; Chun, Jaehun; Schweiger, Michael J.; Kruger, Albert A.; Hrma, Pavel R.

2014-09-01T23:59:59.000Z

307

Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization  

SciTech Connect (OSTI)

A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

Warner, E. S.; Heath, G. A.

2012-04-01T23:59:59.000Z

308

ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS  

SciTech Connect (OSTI)

ADA Environmental Solutions (ADA-ES) has successfully completed a research and development program granted by the Department of Energy National Energy Technology Laboratory (NETL) to develop a family of non-toxic flue gas conditioning agents to provide utilities and industries with a cost-effective means of complying with environmental regulations on particulate emissions and opacity. An extensive laboratory screening of potential additives was completed followed by full-scale trials at four utility power plants. The developed cohesivity additives have been demonstrated on a 175 MW utility boiler that exhibited poor collection of unburned carbon in the electrostatic precipitator. With cohesivity conditioning, opacity spiking caused by rapping reentrainment was reduced and total particulate emissions were reduced by more than 30%. Ammonia conditioning was also successful in reducing reentrainment on the same unit. Conditioned fly ash from the process is expected to be suitable for dry or wet disposal and for concrete admixture.

C. Jean Bustard

2003-12-01T23:59:59.000Z

309

Development of gas production type curves for coalbed methane reservoirs.  

E-Print Network [OSTI]

??Coalbed methane is an unconventional gas resource that consists on methane production from the coal seams. The unique coal characteristic results in a dual-porosity system.… (more)

Garcia Arenas, Anangela.

2004-01-01T23:59:59.000Z

310

Fuel Performance Experiments and Modeling: Fission Gas Bubble Nucleation and Growth in Alloy Nuclear Fuels  

SciTech Connect (OSTI)

Advanced fast reactor systems being developed under the DOE's Advanced Fuel Cycle Initiative are designed to destroy TRU isotopes generated in existing and future nuclear energy systems. Over the past 40 years, multiple experiments and demonstrations have been completed using U-Zr, U-Pu-Zr, U-Mo and other metal alloys. As a result, multiple empirical and semi-empirical relationships have been established to develop empirical performance modeling codes. many mechamistic questions about fission as mobility, bubble coalescience, and gas release have been answered through industrial experience, reearch, and empirical understanding. The advent of modern computational materials science, however, opens new doors of development such that physics-based multi-scale models may be developed to enable a new generation of predictive fuel performance codes that are not limited by empiricism.

McDeavitt, Sean; Shao, Lin; Tsvetkov, Pavel; Wirth, Brian; Kennedy, Rory

2014-04-07T23:59:59.000Z

311

Coal industry annual 1994  

SciTech Connect (OSTI)

This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

NONE

1995-10-01T23:59:59.000Z

312

Modeling of UF{sub 6} enrichment with gas centrifuges for nuclear safeguards activities  

SciTech Connect (OSTI)

The physical modeling of uranium isotopes ({sup 235}U, {sup 238}U) separation process by centrifugation of is a key aspect for predicting the nuclear fuel enrichment plant performances under surveillance by the Nuclear Safeguards Authorities. In this paper are illustrated some aspects of the modeling of fast centrifuges for UF{sub 6} gas enrichment and of a typical cascade enrichment plant with the Theoretical Centrifuge and Cascade Simulator (TCCS). The background theory for reproducing the flow field characteristics of a centrifuge is derived from the work of Cohen where the separation parameters are calculated using the solution of a differential enrichment equation. In our case we chose to solve the hydrodynamic equations for the motion of a compressible fluid in a centrifugal field using the Berman - Olander vertical velocity radial distribution and the solution was obtained using the Matlab software tool. The importance of a correct estimation of the centrifuge separation parameters at different flow regimes, lies in the possibility to estimate in a reliable way the U enrichment plant performances, once the separation external parameters are set (feed flow rate and feed, product and tails assays). Using the separation parameters of a single centrifuge allow to determine the performances of an entire cascade and, for this purpose; the software Simulink was used. The outputs of the calculation are the concentrations (assays) and the flow rates of the enriched (product) and depleted (tails) gas mixture. These models represent a valid additional tool, in order to verify the compliance of the U enrichment plant operator declarations with the 'on site' inspectors' measurements.

Mercurio, G.; Peerani, P.; Richir, P.; Janssens, W.; Eklund, G. [European Commission, Joint Research Centre, Institute for Transuranium Elements Via Fermi, 2749-TP181,20127 Ispra (Italy)

2012-09-26T23:59:59.000Z

313

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

314

DEVELOPMENT OF SUPERIOR SORBENTS FOR SEPARATION OF CO2 FROM FLUE GAS AT A WIDE TEMPERATURE RANGE DURING COAL COMBUSTION  

SciTech Connect (OSTI)

For this part of the project the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed.

Panagiotis G. Smirniotis

2005-01-30T23:59:59.000Z

315

Environmental data energy technology characterizations: coal  

SciTech Connect (OSTI)

This document describes the activities leading to the conversion of coal to electricity. Specifically, the activities consist of coal mining and beneficiation, coal transport, electric power generation, and power transmission. To enhance the usefulness of the material presented, resource requirements, energy products, and residuals for each activity area are normalized in terms of 10/sup 12/ Btus of energy produced. Thus, the total effect of producing electricity from coal can be determined by combining the residuals associated with the appropriate activity areas. Emissions from the coal cycle are highly dependent upon the type of coal consumed as well as the control technology assigned to the activity area. Each area is assumed to be equipped with currently available control technologies that meet environmental regulations. The conventional boiler, for example, has an electrostatic precipitator and a flue gas desulfurization scrubber. While this results in the removal of most of the particulate matter and sulfur dioxide in the flue gas stream, it creates other new environmental residuals -- solid waste, sludge, and ash. There are many different types of mined coal. For informational purposes, two types from two major producing regions, the East and the West, are characterized here. The eastern coal is typical of the Northern Appalachian coal district with a high sulfur and heat content. The western coal, from the Powder River Basin, has much less sulfur, but also has a substantially lower heating value.

Not Available

1980-04-01T23:59:59.000Z

316

Division of Oil, Gas, and Mining Permitting  

E-Print Network [OSTI]

" or "Gas" does not include any gaseous or liquid substance processed from coal, oil shale, or tar sands

Utah, University of

317

Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change  

E-Print Network [OSTI]

coal mining, petroleum extraction and refining, coking, andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking and

Kahrl, Fredrich James

2011-01-01T23:59:59.000Z

318

Microsoft PowerPoint - Americas Energy Security.ppt [Read-Only...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

gas * electrolysis * coal * biomass Long term * water splitting * gas hydrates * oil shale Near term * coal * natural gas * nuclear Long term * coal * shale * nuclear * gas...

319

Enhancing the use of coals by Gas Reburning: Sorbent injection. [Quarterly report], July 28--October 1, 1993  

SciTech Connect (OSTI)

Energy and Environmental Research Corporation (EER) has completed demonstrations of Gas Reburning-Sorbent Injection (GR-SI) at two field sites. The discussions which follow pertain to measurements taken from the demonstration at City Water, Light and Power`s (CWLP) Lakeside Station Unit 7 in Springfield, Illinois. Environmental monitoring was conducted for two purposes, to satisfy the requirements of operating permits granted by the Illinois Environmental Protection Agency (IEPA) and to verify environmental acceptability of the GR-SI process. The GR-SI demonstration program at Lakeside Unit 7 was performed in three phases. Phase I -- Design and Permitting, entailed characterization of the host boiler, then finalization of process and engineering, design of the GR-SI system. Phase I was initiated in June 1987 and completed in March 1989. Phase II -- Construction and Startup, was initiated upon completion of design tasks and was completed in February 1993. Phase III -- Operation, Data Collection, Reporting and Disposition, was conducted from July 1993 to June 1994. In Phase III, the GR-SI system performance was evaluated initially through optimization tests, which are short-term tests in which specific operating parameters are varied to determine their impact on emissions and boiler performance. The optimization testing included GR only tests, SI only tests, and GR-SI tests. Results from these tests, carried out from July 28 to October 1, 1993, are presented in this report. Following Optimization testing, long-term GR-SI operation was initiated to demonstrate the combined technology over an extended period with the unit under dispatch load control. Long-term GR-SI testing was conducted from October 4, 1993 to June 3, 1994. The long-term environmental monitoring data are presented in a separate report.

NONE

1995-02-01T23:59:59.000Z

320

Formation and retention of methane in coal. Final report  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Clean coal technology. Coal utilisation by-products  

SciTech Connect (OSTI)

The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

NONE

2006-08-15T23:59:59.000Z

322

Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification  

SciTech Connect (OSTI)

In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform evolved gas analysis (EGA). Apart from identifying the gases evolved, we performed quantitative analysis relating the weighed sum of intensities of individual gases linearly proportional with the differential themogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.; Rodriguez, Carmen P.; Schweiger, Michael J.

2014-04-30T23:59:59.000Z

323

Adsorption and Strain: The CO2-Induced Swelling of Coal  

E-Print Network [OSTI]

.07.014 #12;Abstract Enhanced coal bed methane recovery (ECBM) consists in injecting carbon dioxide in coal bed methane reservoirs in order to facilitate the recovery of the methane. The injected carbon dioxide as Coal Bed Methane (CBM)- has amounted in 2008 to about 10% of the total natural gas production

Paris-Sud XI, Université de

324

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents [OSTI]

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

325

Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature Range During Coal Combustion  

SciTech Connect (OSTI)

In chapter 1, the studies focused on the development of novel sorbents for reducing the carbon dioxide emissions at high temperatures. Our studies focused on cesium doped CaO sorbents with respect to other major flue gas compounds in a wide temperature range. The thermo-gravimetric analysis of sorbents with loadings of CaO doped on 20 wt% cesium demonstrated high CO{sub 2} sorption uptakes (up to 66 wt% CO{sub 2}/sorbent). It is remarkable to note that zero adsorption affinity for N{sub 2}, O{sub 2}, H{sub 2}O and NO at temperatures as high as 600 C was observed. For water vapor and nitrogen oxide we observed a positive effect for CO{sub 2} adsorption. In the presence of steam, the CO{sub 2} adsorption increased to the highest adsorption capacity of 77 wt% CO{sub 2}/sorbent. In the presence of nitrogen oxide, the final CO{sub 2} uptake remained same, but the rate of adsorption was higher at the initial stages (10%) than the case where no nitrogen oxide was fed. In chapter 2, Ca(NO{sub 3}){sub 2} {center_dot} 4H{sub 2}O, CaO, Ca(OH){sub 2}, CaCO{sub 3}, and Ca(CH{sub 3}COO){sub 2} {center_dot} H{sub 2}O were used as precursors for synthesis of CaO sorbents on this work. The sorbents prepared from calcium acetate (CaAc{sub 2}-CaO) resulted in the best uptake characteristics for CO{sub 2}. It possessed higher BET surface area and higher pore volume than the other sorbents. According to SEM images, this sorbent shows 'fluffy' structure, which probably contributes to its high surface area and pore volume. When temperatures were between 550 and 800 C, this sorbent could be carbonated almost completely. Moreover, the carbonation progressed dominantly at the initial short period. Under numerous adsorption-desorption cycles, the CaAc{sub 2}-CaO demonstrated the best reversibility, even under the existence of 10 vol % water vapor. In a 27 cyclic running, the sorbent sustained fairly high carbonation conversion of 62%. Pore size distributions indicate that their pore volume decreased when experimental cycles went on. Silica was doped on the CaAc{sub 2}-CaO in various weight percentages, but the resultant sorbent did not exhibit better performance under cyclic operation than those without dopant. In chapter 3, the Calcium-based carbon dioxide sorbents were made in the gas phase by flame spray pyrolysis (FSP) and compared to the ones made by standard high temperature calcination (HTC) of selected calcium precursors. The FSP-made sorbents were solid nanostructured particles having twice as large specific surface area (40-60 m{sup 2}/g) as the HTC-made sorbents (i.e. from calcium acetate monohydrate). All FSP-made sorbents showed high capacity for CO{sub 2} uptake at high temperatures (773-1073 K) while the HTC-made ones from calcium acetate monohydrate (CaAc{sub 2} {center_dot} H{sub 2}O) demonstrated the best performance for CO{sub 2} uptake among all HTC-made sorbents. At carbonation temperatures less than 773 K, FSP-made sorbents demonstrated better performance for CO{sub 2} uptake than all HTC-made sorbents. Above that, both FSP-made, and HTC-made sorbents from CaAc{sub 2} {center_dot} H{sub 2}O exhibited comparable carbonation rates and maximum conversion. In multiple carbonation/decarbonation cycles, FSP-made sorbents demonstrated stable, reversible and high CO{sub 2} uptake capacity sustaining maximum molar conversion at about 50% even after 60 such cycles indicating their potential for CO{sub 2} uptake. In chapter 4 we investigated the performance of CaO sorbents with dopant by flame spray pyrolysis at higher temperature. The results show that the sorbent with zirconia gave best performance among sorbents having different dopants. The one having Zr to Ca of 3:10 by molar gave stable performance. The calcium conversion around 64% conversion during 102-cycle operations at 973 K. When carbonation was performance at 823 K, the Zr/Ca sorbent (3:10) exhibited stable performance of 56% by calcium molar conversion, or 27% by sorbent weight, both of which are less than those at 973 K as expected. In chapter 5 we investigated the perfor

Panagiotis G. Smirniotis

2007-06-30T23:59:59.000Z

326

Clean Coal Diesel Demonstration Project  

SciTech Connect (OSTI)

A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

Robert Wilson

2006-10-31T23:59:59.000Z

327

Method of operating a two-stage coal gasifier  

DOE Patents [OSTI]

A method of operating an entrained flow coal gasifier (10) via a two-stage gasification process. A portion of the coal (18) to be gasified is combusted in a combustion zone (30) with near stoichiometric air to generate combustion products. The combustion products are conveyed from the combustion zone into a reduction zone (32) wherein additional coal is injected into the combustion products to react with the combustion products to form a combustible gas. The additional coal is injected into the reduction zone as a mixture (60) consisting of coal and steam, preferably with a coal-to-steam weight ratio of approximately ten to one.

Tanca, Michael C. (Tariffville, CT)

1982-01-01T23:59:59.000Z

328

Accepted for publication in Energy Policy Greenhouse-gas Emissions from Solar Electric-and Nuclear Power: A Life-cycle  

E-Print Network [OSTI]

Accepted for publication in Energy Policy Greenhouse-gas Emissions from Solar Electric- and Nuclear, photovoltaic, nuclear, life cycle 1 #12;Introduction The production of energy by burning fossil fuels generates, it is envisioned that expanding generation technologies based on nuclear power and renewable energy sources would

329

A resource and technology assessment of coal utilization in India  

SciTech Connect (OSTI)

Electricity production in India is projected to expand dramatically in the near term to energize new industrial development, while also easing the energy shortages throughout the country. Much of the new growth in electricity production will be fueled by domestic coal resources; however, there is worldwide concern about increased coal use, as greater carbon dioxide emissions from coal combustion will exacerbate climate change. At the same time, there are now a number of different existing and emerging technological options for coal conversion and greenhouse gas (GHG) reduction worldwide that could potentially be useful for the Indian coal-power sector. This paper reviews coal utilization in India and examines current and emerging coal power technologies with near- and long-term potential for reducing greenhouse gas emissions from coal power generation. 107 refs., 8 figs., 6 tabs.

Chikkatur, A.P. [Harvard University, Cambridge, MA (United States). Kennedy School of Government

2008-10-15T23:59:59.000Z

330

High-pressure gasification of Montana subbituminous coal  

SciTech Connect (OSTI)

A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

Goyal, A.; Bryan, B.; Rehmat, A.

1991-01-01T23:59:59.000Z

331

Industrial Utilization of Coal-Oil Mixtures  

E-Print Network [OSTI]

Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

Dunn, J. E.; Hawkins, G. T.

1982-01-01T23:59:59.000Z

332

Process for electrochemically gasifying coal using electromagnetism  

DOE Patents [OSTI]

A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

1987-01-01T23:59:59.000Z

333

Fluidized bed injection assembly for coal gasification  

DOE Patents [OSTI]

A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

1981-01-01T23:59:59.000Z

334

Autothermal coal gasification  

SciTech Connect (OSTI)

This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

1982-03-01T23:59:59.000Z

335

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

336

Analysis of model equations for stress-enhanced diffusion in coal  

E-Print Network [OSTI]

the coal seams. Carbon dioxide displaces the methane adsorbed on the internal surface of the coal. A production well gathers the methane as free gas. This process, known as carbon dioxide-enhanced coal bedAnalysis of model equations for stress-enhanced diffusion in coal layers Andro Mikeli´c Andro

Segatti, Antonio

337

Coal Bed Methane Primer  

SciTech Connect (OSTI)

During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

Dan Arthur; Bruce Langhus; Jon Seekins

2005-05-25T23:59:59.000Z

338

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 3, Appendix B: NO{sub x} and alkali vapor control strategies: Final report  

SciTech Connect (OSTI)

CRS Sirrine (CRSS) is evaluating a novel IGCC process in which gases exiting the gasifier are burned in a gas turbine combustion system. The turbine exhaust gas is used to generate additional power in a conventional steam generator. This results in a significant increase in efficiency. However, the IGCC process requires development of novel approaches to control SO{sub 2} and NO{sub x} emissions and alkali vapors which can damage downstream turbine components. Ammonia is produced from the reaction of coal-bound nitrogen with steam in the reducing zone of any fixed bed coal gasifier. This ammonia can be partially oxidized to NO{sub x} when the product gas is oxidized in a gas turbine combustor. Alkali metals vaporize in the high-temperature combustion zone of the gasifier and laser condense on the surface of small char or ash particles or on cooled metal surfaces. It these alkali-coated materials reach the gas turbine combustor, the alkali will revaporize condense on turbine blades and cause rapid high temperature corrosion. Efficiency reduction will result. PSI Technology Company (PSIT) was contracted by CRSS to evaluate and recommend solutions for NO{sub x} emissions and for alkali metals deposition. Various methods for NO{sub x} emission control and the potential process and economic impacts were evaluated. This included estimates of process performance, heat and mass balances around the combustion and heat transfer units and a preliminary economic evaluation. The potential for alkali metal vaporization and condensation at various points in the system was also estimated. Several control processes and evaluated, including an order of magnitude cost for the control process.

Not Available

1990-07-01T23:59:59.000Z

339

Carbon Dioxide Sequestration in Geologic Coal Formations  

SciTech Connect (OSTI)

BP Corporation North America, Inc. (BP) currently operates a nitrogen enhanced recovery project for coal bed methane at the Tiffany Field in the San Juan Basin, Colorado. The project is the largest and most significant of its kind wherein gas is injected into a coal seam to recover methane by competitive adsorption and stripping. The Idaho National Engineering and Environmental Laboratory (INEEL) and BP both recognize that this process also holds significant promise for the sequestration of carbon dioxide, a greenhouse gas, while economically enhancing the recovery of methane from coal. BP proposes to conduct a CO2 injection pilot at the tiffany Field to assess CO2 sequestration potential in coal. For its part the INEEL will analyze information from this pilot with the intent to define the Co2 sequestration capacity of coal and its ultimate role in ameliorating the adverse effects of global warming on the nation and the world.

None

2001-09-30T23:59:59.000Z

340

Materials performance in coal gasification pilot plants  

SciTech Connect (OSTI)

This paper presents the results of several materials testing projects which were conducted in operating coal gasification pilot plants in the United States. These projects were designed to test potential materials of construction for commercial plants under actual operating conditions. Pilot plants included in the overall test program included the Hygas, Conoco Coal, Synthane, Bi-Gas, Peatgas (Hygas operating with peat), Battelle, U-Gas, Westinghouse (now KRW), General Electric (Gegas), and Mountain Fuel Resources plants. Test results for a large variety of alloys are discussed and conclusions regarding applicability of these materials in coal gasification environments are presented. 14 refs., 2 tabs.

Judkins, R.R.; Bradley, R.A.

1987-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

THR-TH: a high-temperature gas-cooled nuclear reactor core thermal hydraulics code  

SciTech Connect (OSTI)

The ORNL version of PEBBLE, the (RZ) pebble bed thermal hydraulics code, has been extended for application to a prismatic gas cooled reactor core. The supplemental treatment is of one-dimensional coolant flow in up to a three-dimensional core description. Power density data from a neutronics and exposure calculation are used as the basic information for the thermal hydraulics calculation of heat removal. Two-dimensional neutronics results may be expanded for a three-dimensional hydraulics calculation. The geometric description for the hydraulics problem is the same as used by the neutronics code. A two-dimensional thermal cell model is used to predict temperatures in the fuel channel. The capability is available in the local BOLD VENTURE computation system for reactor core analysis with capability to account for the effect of temperature feedback by nuclear cross section correlation. Some enhancements have also been added to the original code to add pebble bed modeling flexibility and to generate useful auxiliary results. For example, an estimate is made of the distribution of fuel temperatures based on average and extreme conditions regularly calculated at a number of locations.

Vondy, D.R.

1984-07-01T23:59:59.000Z

342

Present coal potential of Turkey and coal usage in electricity generation  

SciTech Connect (OSTI)

Total coal reserve (hard coal + lignite) in the world is 984 billion tons. While hard coal constitutes 52% of the total reserve, lignite constitutes 48% of it. Turkey has only 0.1% of world hard coal reserve and 1.5% of world lignite reserves. Turkey has 9th order in lignite reserve, 8th order in lignite production, and 12th order in total coal (hard coal and lignite) consumption. While hard coal production meets only 13% of its consumption, lignite production meets lignite consumption in Turkey. Sixty-five percent of produced hard coal and 78% of produced lignite are used for electricity generation. Lignites are generally used for electricity generation due to their low quality. As of 2003, total installed capacity of Turkey was 35,587 MW, 19% (6,774 MW) of which is produced from coal-based thermal power plants. Recently, use of natural gas in electricity generation has increased. While the share of coal in electricity generation was about 50% for 1986, it is replaced by natural gas today.

Yilmaz, A.O. [Karadeniz Technical University, Trabzon (Turkey). Mining Engineering Department

2009-07-01T23:59:59.000Z

343

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antin...

Ledenyov, Oleg P

2013-01-01T23:59:59.000Z

344

Coal preparation: The essential clean coal technology  

SciTech Connect (OSTI)

This chapter is a brief introduction to a broad topic which has many highly specialized areas. The aim is to summarize the essential elements of coal preparation and illustrate its important role in facilitating the clean use of coal. Conventional coal preparation is the essential first step in ensuring the economic and environmentally acceptable use of coal. The aim of coal preparation is to produce saleable products of consistent, specified quality which satisfy customer requirements while optimizing the utilization of the coal resource. Coal preparation covers all aspects of preparing coal for the market. It includes size reduction, blending and homogenization and, most importantly, the process of physical beneficiation or washing, which involves separation of undesirable mineral matter from the coal substance itself. Coal preparation can be performed at different levels of sophistication and cost. The degree of coal preparation required is decided by considering the quality of the raw coal, transport costs and, in particular, the coal quality specified by the consumer. However, the cost of coal beneficiation rises rapidly with the complexity of the process and some coal is lost with the waste matter because of process inefficiencies, therefore each situation requires individual study to determine the optimum coal preparation strategy. The necessary expertise is available within APEC countries such as Australia. Coals destined for iron making are almost always highly beneficiated. Physical beneficiation is mostly confined to the higher rank, hard coals, but all other aspects of coal preparation can be applied to subbituminous and lignitic coals to improve their utilization. Also, there are some interesting developments aimed specifically at reducing the water content of lower rank coals.

Cain, D.

1993-12-31T23:59:59.000Z

345

Oxy-coal Combustion Studies  

SciTech Connect (OSTI)

The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?¢ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?¢ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?¢ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?¢ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?¢ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?¢ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

2012-01-01T23:59:59.000Z

346

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

2011-09-30T23:59:59.000Z

347

Advanced Gas Cooled Nuclear Reactor Materials Evaluation and Development Program. Progress report, January 1, 1980-March 31, 1980  

SciTech Connect (OSTI)

Results are presented of work performed on the Advanced Gas-Cooled Nuclear Reactor Materials Evaluation and Development Program. The objectives of this program are to evaluate candidate alloys for Very High Temperature Reactor (VHTR) Nuclear Process Heat (NPH) and Direct Cycle Helium Turbine (DCHT) applications, in terms of the effect of simulated reactor primary coolant (helium containing small amounts of various other gases), high temperatures, and long time exposures, on the mechanical properties and structural and surface stability of selected candidate alloys. A second objective is to select and recommend materials for future test facilities and more extensive qualification programs. Included are the activities associated with the status of the simulated reactor helium supply system, testing equipment and gas chemistry analysis instrumentation and equipment. The progress in the screening test program is described, including screening creep results and metallographic analysis for materials thermally exposed or tested at 750, 850, and 950/sup 0/C.

Not Available

1980-06-25T23:59:59.000Z

348

Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas  

SciTech Connect (OSTI)

This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

C. Jean Bustard; Charles Lindsey; Paul Brignac

2006-05-01T23:59:59.000Z

349

High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 14, January 1--March 31, 1996  

SciTech Connect (OSTI)

The objective of this project is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous- flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal. A continuous system has been constructed and operated, with a one-half inch inside diameter (ID) tube as the reaction vessel. As the work in this project proceeded toward its conclusion, an unexpected benefit was discovered. As the residence times were decreased to values of 10 seconds or less, ratios of liquids/HC gases of 20/1 or higher were achieved. But very importantly, it was discovered that the chemical reactions which produce the primary liquids can be carried to high conversions at pressures much lower than reported, and indeed required, in the processes at longer times.

Wiser, W.H.; Oblad, A.G.

1996-04-01T23:59:59.000Z

350

Role of Nuclear Grade Graphite in Oxidation in Modular HTGRs  

SciTech Connect (OSTI)

The passively safe High Temperature Gas-cooled Reactor (HTGR) design is one of the primary concepts considered for Generation IV and Small Modular Reactor (SMR) programs. The helium cooled, nuclear grade graphite moderated core achieves extremely high operating temperatures allowing either industrial process heat or electricity generation at high efficiencies. In addition to their neutron moderating properties, nuclear grade graphite core components provide excellent high temperature stability, thermal conductivity, and chemical compatibility with the high temperature nuclear fuel form. Graphite has been continuously used in nuclear reactors since the 1940’s and has performed remarkably well over a wide range of core environments and operating conditions. Graphite moderated, gas-cooled reactor designs have been safely used for research and power production purposes in multiple countries since the inception of nuclear energy development. However, graphite is a carbonaceous material, and this has generated a persistent concern that the graphite components could actually burn during either normal or accident conditions [ , ]. The common assumption is that graphite, since it is ostensibly similar to charcoal and coal, will burn in a similar manner. While charcoal and coal may have the appearance of graphite, the internal microstructure and impurities within these carbonaceous materials are very different. Volatile species and trapped moisture provide a source of oxygen within coal and charcoal allowing them to burn. The fabrication process used to produce nuclear grade graphite eliminates these oxidation enhancing impurities, creating a dense, highly ordered form of carbon possessing high thermal diffusivity and strongly (covalently) bonded atoms.

Willaim Windes; G. Strydom; J. Kane; R. Smith

2014-11-01T23:59:59.000Z

351

Federal Offshore California Natural Gas Withdrawals from Gas Wells (Million  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96Nebraska NuclearDecade2003Cubic Feet) Gas Wells

352

Annual Coal Report 2013  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781Title: Telephone:shortOil and Natural Gas AEO2015EnergyAnnual Coal

353

By Coal Destination State  

Gasoline and Diesel Fuel Update (EIA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S.30Natural Gas Glossary529 633 622 566 8021 1 2 22008662 564CubicAnnual Coal

354

EIA -Quarterly Coal Distribution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed NewcatalystNeutron scatteringDelawareTexasMissouri NuclearTennesseeWashington- Coal

355

Strategic Center for Coal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSiteNeutron Scattering4American'!Stores Catalogof SVO ResearchCoal

356

Comparative Analysis of the Production Costs and Life-Cycle GHG Emissions of FT-Liquid Fuels from Coal and  

E-Print Network [OSTI]

Coal and Natural Gas Figure S1 shows a graphical description of the life cycle of coal-to-liquids (CTL) and gas-to-liquids (GTL). Figure S1: Life Cycle of Coal-Based and Natural Gas-Based Fischer-Tropsch LiquidComparative Analysis of the Production Costs and Life- Cycle GHG Emissions of FT-Liquid Fuels from

Jaramillo, Paulina

357

Coal industry annual 1997  

SciTech Connect (OSTI)

Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

NONE

1998-12-01T23:59:59.000Z

358

Coal Industry Annual 1995  

SciTech Connect (OSTI)

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

NONE

1996-10-01T23:59:59.000Z

359

Coal industry annual 1996  

SciTech Connect (OSTI)

This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

NONE

1997-11-01T23:59:59.000Z

360

Microbial solubilization of coal  

DOE Patents [OSTI]

The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

Strandberg, G.W.; Lewis, S.N.

1988-01-21T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Development of fission gas swelling and release models for metallic nuclear fuels  

E-Print Network [OSTI]

Fuel swelling and fission gas generation for fast reactor fuels are of high importance since they are among the main limiting factors in the development of metallic fast reactor fuel. Five new fission gas and swelling ...

Andrews, Nathan Christopher

2012-01-01T23:59:59.000Z

362

EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy’s Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

363

Nuclear material safeguards for enrichments plants: Part 4, Gas Centrifuge Enrichment Plant: Diversion scenarios and IAEA safeguards activities: Safeguards training course  

SciTech Connect (OSTI)

This publication is Part 4 of a safeguards training course in Nuclear Material Safeguards for enrichment plants. This part of the course deals with diversion scenarios and safeguards activities at gas centrifuge enrichment plants.

Not Available

1988-10-01T23:59:59.000Z

364

Kinetics of coal pyrolysis and devolatilization  

SciTech Connect (OSTI)

An experimentally based, conceptual model of the devolatilization of a HV bituminous coal is outlined in this report. This model contends that the relative dominance of a process type-chemical kinetic, heat transport, mass transport -- varies with the extent of reaction for a given set of heating conditions and coal type and with experimental conditions for a given coal type and extent of reaction. The rate of devolatilization mass loss process is dominated initially by heat transfer processes, then coupled mass transfer and chemical kinetics, and finally by chemical processes alone. However, the chemical composition of the initial tars are determined primarily by the chemical characteristics of the parent coal. Chemically controlled gas phase reactions of the initial tars and coupled mass transfer and chemically controlled reactions of heavy tars determine the bulk of the light gas yields. For a HV bituminous coal this conceptual model serves to quantify the Two-Component Hypothesis'' of volatiles evolution. The model postulates that the overall rates of coal devolatilization should vary with coal type insofar as the characteristics of the parent coal determine the potential tar yield and the chemical characteristics of the initial tars. Experimental evidence indicates chemical characteristics and yields of primary'' tars vary significantly with coal type. Consequently, the conceptual model would indicate a shift from transport to chemical dominance of rate processes with variation in coal type. Using the conceptual model, United Technologies Research Center has been able to correlate initial mass loss with a heat transfer index for a wide range of conditions for high tar yielding coals. 33 refs., 30 figs., 6 tabs.

Not Available

1987-01-01T23:59:59.000Z

365

Experimental Characterization and Molecular Study of Natural Gas Mixtures  

E-Print Network [OSTI]

) 5, advanced gas turbine 5 and coal-based zero emissions power plant 6 are some of the technological advances recently reported. It is important to note that these technologies are adaptable to natural gas feedstock. However, until clean coal...

Cristancho Blanco, Diego Edison

2011-08-08T23:59:59.000Z

366

Coal industry annual 1993  

SciTech Connect (OSTI)

Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

Not Available

1994-12-06T23:59:59.000Z

367

Coal liquefaction and hydrogenation  

DOE Patents [OSTI]

Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

1985-01-01T23:59:59.000Z

368

Method for reducing NOx during combustion of coal in a burner  

DOE Patents [OSTI]

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

2008-04-15T23:59:59.000Z

369

Coal combustion science  

SciTech Connect (OSTI)

The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

1990-11-01T23:59:59.000Z

370

4th Annual Clean Coal  

E-Print Network [OSTI]

Proceedings he emphasis of the Fourth Clean Coal Technology Conference wm the marketability of clean coal projects both domestically and abroad. The success rate of clean coal projects in the U.S. for coalfired electricity generation is a beacon to foreign governments that are working toward effectively using advanced NO, and SO2 technology to substantially reduce flue-gas emissions for a cleaner environment. There is a continuing dialogue between U.S. Government, North American private industry, and the electricity producing governmental ministries and the private sector abroad. The international community was well represented at this conference. The Administration is determined to move promising, near-term technologies from the public to the private sector a ~ well a8 into the international marketplace.

Ferriter John P

371

Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream  

DOE Patents [OSTI]

A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (S. Somerville, NJ)

1989-01-01T23:59:59.000Z

372

CO2 SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS  

SciTech Connect (OSTI)

The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The main tasks for this reporting period were to correlate well logs and refine coal property maps, evaluate methane content and gas composition of Wilcox Group coals, and initiate discussions concerning collection of additional, essential data with Anadarko. To assess the volume of CO{sub 2} that may be sequestered and volume of methane that can be produced in the vicinity of the proposed Sam Seymour sequestration site, we used approximately 200 additional wells logs from Anadarko Petroleum Corp. to correlate and map coal properties of the 3 coal-bearing intervals of Wilcox group. Among the maps we are making are maps of the number of coal beds, number of coal beds greater than 5 ft thick, and cumulative coal thickness for each coal interval. This stratigraphic analysis validates the presence of abundant coal for CO{sub 2} sequestration in the Wilcox Group in the vicinity of Sam Seymour power plant. A typical wellbore in this region may penetrate 20 to 40 coal beds with cumulative coal thickness between 80 and 110 ft. Gas desorption analyses of approximately 75 coal samples from the 3 Wilcox coal intervals indicate that average methane content of Wilcox coals in this area ranges between 216 and 276 scf/t, basinward of the freshwater boundary indicated on a regional hydrologic map. Vitrinite reflectance data indicate that Wilcox coals are thermally immature for gas generation in this area. Minor amounts of biogenic gas may be present, basinward of the freshwater line, but we infer that most of the Wilcox coalbed gas in the deep coal beds is migrated thermogenic gas. Analysis based on limited data suggest that sites for CO{sub 2} sequestration and enhanced coalbed gas recovery should be located basinward of the Wilcox freshwater contour, where methane content is high and the freshwater aquifer can be avoided.

Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

2004-07-01T23:59:59.000Z

373

Coal Mining (Iowa)  

Broader source: Energy.gov [DOE]

These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

374

Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program  

SciTech Connect (OSTI)

The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

2014-08-15T23:59:59.000Z

375

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

2010-09-30T23:59:59.000Z

376

Coal combustion by wet oxidation  

SciTech Connect (OSTI)

The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

1980-11-15T23:59:59.000Z

377

Fuel supply system and method for coal-fired prime mover  

DOE Patents [OSTI]

A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

1995-01-01T23:59:59.000Z

378

Modelling and Numerical Simulation of Gas Migration in a Nuclear Waste Repository  

E-Print Network [OSTI]

We present a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological radioactive waste repository. This model includes capillary effects and the gas diffusivity. The choice of the main variables in this model, Total or Dissolved Hydrogen Mass Concentration and Liquid Pressure, leads to a unique and consistent formulation of the gas phase appearance and disappearance. After introducing this model, we show computational evidences of its adequacy to simulate gas phase appearance and disappearance in different situations typical of underground radioactive waste repository.

Bourgeat, Alain; Smai, Farid

2010-01-01T23:59:59.000Z

379

Repowering with clean coal technologies  

SciTech Connect (OSTI)

Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

Freier, M.D. [USDOE Morgantown Energy Technology Center, WV (United States); Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N. [Parsons Power Group, Inc., Reading, PA (United States)

1996-02-01T23:59:59.000Z

380

Apparatus and method for solar coal gasification  

DOE Patents [OSTI]

Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

Gregg, David W. (Moraga, CA)

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Microsoft Word - Nuclear_hybrid_systems_for_Wyoming_-__final...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of primary energy resources in the forms of coal, natural gas, wind, uranium, and oil shale. Most of Wyoming's coal and gas resources are exported from the state in unprocessed...

382

Numerical modeling of gas migration at a proposed repository for low and intermediate level nuclear wastes at Oberbauenstock, Switzerland  

SciTech Connect (OSTI)

Hydrologic impacts of corrosive gas release from a hypothetical L/ILW nuclear waste repository at Oberbauenstock are explored by means of numerical simulation. A schematic two dimensional vertical section through the mountain is modeled with the simulator TOUGH, which describes two-phase flow of water and gas in porous and fractured media. Two reference cases are considered which represent the formations as a porous and as a fractured-porous (dual permeability) medium, respectively. Both cases predict similar and rather modest pressure increases, from ambient 10 bars to near 25 bars at the repository level. These results are to be considered preliminary because important parameters affecting two-phase flow, such as relative permeabilities of a fractured medium, are not well known at present. 24 refs., 15 figs., 5 tabs.

Pruess, K.

1990-03-01T23:59:59.000Z

383

DEVELOPMENT OF A HYDROGEN MORDENITE SORBENT FOR THE CAPTURE OF KRYPTON FROM USED NUCLEAR FUEL REPROCESSING OFF-GAS STREAMS  

SciTech Connect (OSTI)

A novel new sorbent for the separation of krypton from off-gas streams resulting from the reprocessing of used nuclear fuel has been developed and evaluated. A hydrogen mordenite powder was successfully incorporated into a macroporous polymer binder and formed into spherical beads. The engineered form sorbent retained the characteristic surface area and microporosity indicative of mordenite powder. The sorbent was evaluated for krypton adsorption capacities utilizing thermal swing operations achieving capacities of 100 mmol of krypton per kilogram of sorbent at a temperature of 191 K. A krypton adsorption isotherm was also obtained at 191 K with varying krypton feed gas concentrations. Adsorption/desorption cycling effects were also evaluated with results indicating that the sorbent experienced no decrease in krypton capacity throughout testing.

Mitchell Greenhalgh; Troy G. Garn; Jack D. Law

2014-04-01T23:59:59.000Z

384

Structural characteristics and gasification reactivity of chars prepared from K{sub 2}CO{sub 3} mixed HyperCoals and coals  

SciTech Connect (OSTI)

HyperCoal is a clean coal with mineral matter content <0.05 wt %. Oaky Creek (C = 82%), and Pasir (C = 68%) coals were subjected to solvent extraction method to prepare Oaky Creek HyperCoal, and Pasir HyperCoal. Experiments were carried out to compare the gasification reactivity of HyperCoals and parent raw coals with 20, 40, 50 and 60% K{sub 2}CO{sub 3} as a catalyst at 600, 650, 700, and 775{sup o}C with steam. Gasification rates of coals and HyperCoals were strongly influenced by the temperature and catalyst loading. Catalytic steam gasification of HyperCoal chars was found to be chemical reaction controlled in the 600-700{sup o}C temperature range for all catalyst loadings. Gasification rates of HyperCoal chars were found to be always higher than parent coals at any given temperature for all catalyst loadings. However, X-ray diffraction results showed that the microstructures of chars prepared from coals and HyperCoals were similar. Results from nuclear magnetic resonance spectroscopy show no significant difference between the chemical compositions of the chars. Significant differences were observed from scanning electron microscopy images, which showed that the chars from HyperCoals had coral-reef like structures whereas dense chars were observed for coals. 26 refs., 8 figs., 2 tabs.

Atul Sharma; Hiroyuki Kawashima; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

2009-04-15T23:59:59.000Z

385

Negative heat capacity in the critical region of nuclear fragmentation: an experimental evidence of the liquid-gas phase transition  

E-Print Network [OSTI]

An experimental indication of negative heat capacity in excited nuclear systems is inferred from the event by event study of energy fluctuations in $Au$ quasi-projectile sources formed in $Au+Au$ collisions at 35 A.MeV. The excited source configuration is reconstructed through a calorimetric analysis of its de-excitation products. Fragment partitions show signs of a critical behavior at about 5 A.MeV excitation energy. In the same energy range the heat capacity shows a negative branch providing a direct evidence of a first order liquid gas phase transition.

M. D'Agostino; F. Gulminelli; Ph. Chomaz; M. Bruno; F. Cannata; R. Bougault; N. Colonna; F. Gramegna; I. Iori; N. Le Neindre; G. V. Margagliotti; P. F. Mastinu; P. M. Milazzo; A. Moroni; G. Vannini

1999-06-07T23:59:59.000Z

386

Low-rank coal research. Quarterly report, January--March 1990  

SciTech Connect (OSTI)

This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

Not Available

1990-08-01T23:59:59.000Z

387

Pulverized coal combustion characterization at the KEPRI  

SciTech Connect (OSTI)

A pilot-scale combustion test facility that can be utilized to burn pulverized coals such as anthracite coals, bituminous coals, and their blends at the rate of 200 kg/hr has been constructed to study coal-related impacts on utility boiler operations. The impacts include pulverizer performance, combustion stability, slagging, fouling, heat transfer, erosion, corrosion, pollutant emission, etc. The facility, a scale-down model of an existing boiler in Korea, consists of all the necessary components for the boiler with a distributed control system except steam generation components which have been replaced with slag panels, fouling probes, and heat exchangers. The facility, in addition, incorporates the advanced boiler technologies including tangentially-fired burners, flue gas recirculation, direct sorbent injection for desulfurization, electrostatic precipitator, wet scrubber, etc., and employs an opacity meter and gas analyzers. Low NOx burners and gas reburning system will be facilitated in the future to study low emission boiler systems being demonstrated in the developed countries. This paper represents preliminary test results including flame shapes, fouling based on the fouling factor, and pollutant emission with different coals and combustion aerodynamics. Flow fields in the furnace have been changed by varying the swirl number and the burner configurations in terms of single-wall, opposed-wall, and corner firing mode. An extensive investigation will continue to find optimum conditions for various coals of interest.

Cha, D.J.; Kim, S.C.; Bae, B.H.; Kim, T.H.; Shin, Y.J.; Lee, H.D.; Park, O.Y.; Choi, B.S.

1997-12-31T23:59:59.000Z

388

Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 1, Final report  

SciTech Connect (OSTI)

The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

1991-02-01T23:59:59.000Z

389

Future Impacts of Coal Distribution Constraints on Coal Cost  

E-Print Network [OSTI]

transportation component of coal price should also increase;investment. Coal costs and prices are functions of a numberto forecast coal demand, supply, and prices from now to

McCollum, David L

2007-01-01T23:59:59.000Z

390

Investigation of coal tar mobility at a former MGP site  

SciTech Connect (OSTI)

The presence of coal tar in the subsurface of former manufactured gas plant sites poses an environmental hazard and a potential threat to public health. Coal tar can release various chemical compounds that are transported into the groundwater. Before any efforts can be made to remove coal tar from contaminated subsurface soils, it is recommended to characterize coal tar properties and composition and to delineate the residual saturation point between mobile and immobile coal tar. This paper presents a new innovative field device, the Res-SAT field tool, and laboratory procedures that can be used to determine the saturation-capillary pressure relationship for a soil-water coal-tar system and the critical pressure for coal tar mobility.

Moo-Young, H.K.; Mo, X.H.; Waterman, R.; Coleman, A.; Saroff, S. [California State University Los Angeles, Los Angeles, CA (United States)

2009-11-15T23:59:59.000Z

391

E-Print Network 3.0 - advanced gas-cooled nuclear Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy 9 UNM engineering s p r i N g 2 0 0 6 Summary: Re); the gas cooled Submersion-Subcritical Safe Space reactor (S4) designed to operate with multiple Closed... for reducing...

392

Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow Conditkms  

E-Print Network [OSTI]

the presenceof water in the coal seam and its co- production with gas. The developed type curves are capable and necessary dimensionless groups were identified. The terms which relate to desorption process were included operating and exploration costs. Gas drained from coal seams are high quality natural gas which generally

Mohaghegh, Shahab

393

Process for fixed bed coal gasification  

DOE Patents [OSTI]

The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

394

Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams  

SciTech Connect (OSTI)

The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

2013-10-01T23:59:59.000Z

395

Novel Sorbent Development and Evaluation for the Capture of Krypton and Xenon from Nuclear Fuel Reprocessing Off-Gas Streams  

SciTech Connect (OSTI)

The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, INL sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up.

Troy G. Garn; Mitchell R. Greenhalgh; Jack D. Law

2013-09-01T23:59:59.000Z

396

Novel sorbent development and evaluation for the capture of krypton and xenon from nuclear fuel reprocessing off-gas stream  

SciTech Connect (OSTI)

The release of volatile radionuclides generated during Used Nuclear Fuel reprocessing in the US will most certainly need to be controlled to meet US regulatory emission limits. A US DOE sponsored Off-Gas Sigma Team has been tasked with a multi-lab collaborative research and development effort to investigate and evaluate emissions and immobilization control technologies for the volatile radioactive species generated from commercial Used Nuclear Fuel (UNF) Reprocessing. Physical Adsorption technology is a simpler and potential economical alternative to cryogenic distillation processes that can be used for the capture of krypton and xenon and has resulted in a novel composite sorbent development procedure using synthesized mordenite as the active material. Utilizing the sorbent development procedure, Idaho National Laboratory sigma team members have developed two composite sorbents that have been evaluated for krypton and xenon capacities at ambient and 191 K temperature using numerous test gas compositions. Adsorption isotherms have been generated to predict equilibration and maximum capacities enabling modeling to support process equipment scale-up. (authors)

Garn, T.G.; Greenhalgh, M.R.; Law, J.D. [Idaho National Laboratory, 1625 N. Fremont Ave., Idaho Falls, ID 83415 (United States)

2013-07-01T23:59:59.000Z

397

Process for clean-burning fuel from low-rank coal  

DOE Patents [OSTI]

A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

Merriam, Norman W. (Laramie, WY); Sethi, Vijay (Laramie, WY); Brecher, Lee E. (Laramie, WY)

1994-01-01T23:59:59.000Z

398

COAL DESULFURIZATION PRIOR TO COMBUSTION  

E-Print Network [OSTI]

90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

Wrathall, J.

2013-01-01T23:59:59.000Z

399

Coal data: A reference  

SciTech Connect (OSTI)

This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

Not Available

1995-02-01T23:59:59.000Z

400

Combustor for fine particulate coal  

DOE Patents [OSTI]

A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

Carlson, L.W.

1988-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Combustor for fine particulate coal  

DOE Patents [OSTI]

A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

Carlson, L.W.

1988-11-08T23:59:59.000Z

402

Combustor for fine particulate coal  

DOE Patents [OSTI]

A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

Carlson, Larry W. (Oswego, IL)

1988-01-01T23:59:59.000Z

403

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

404

Determination of Coal Permeability Using Pressure Transient Methods  

SciTech Connect (OSTI)

Coalbed methane is a significant natural resource in the Appalachian region. It is believed that coalbed methane production can be enhanced by injection of carbon dioxide into coalbeds. However, the influence of carbon dioxide injection on coal permeability is not yet well understood. Competitive sorption of carbon dioxide and methane gases onto coal is a known process. Laboratory experiments and limited field experience indicate that coal will swell during sorption of a gas and shrink during desorption of a gas. The swelling and shrinkage may change the permeability of the coal. In this study, the permeability of coal was determined by using carbon dioxide as the flowing fluid. Coal samples with different dimensions were prepared for laboratory permeability tests. Carbon dioxide was injected into the coal and the permeability was determined by using pressure transient methods. The confining pressure was variedto cover a wide range of depths. The permeability was also determined as a function of exposure time of carbon dioxide while the confining stress was kept constant. CT scans were taken before and after the introduction of carbon dioxide. Results show that the porosity and permeability of the coal matrix was very low. The paper presents experimental data and theoretical aspects of the flow of carbon dioxide through a coal sample during pressure transient tests. The suitability of the pressure transient methods for determining permeability of coal during carbon dioxide injection is discussed in the paper.

McLendon, T.R.; Siriwardane, H. (West Virginia University, Morgantown, WV); Haljasmaa, I.V.; Bromhal, G.S.; Soong, Y.; Irdi, G.A.

2007-05-01T23:59:59.000Z

405

Economic assessment of coal-burning locomotives: Topical report  

SciTech Connect (OSTI)

The General Electric Company embarked upon a study to evaluate various alternatives for the design and manufacture a coal fired locomotive considering various prime movers, but retaining the electric drive transmission. The initial study was supported by the Burlington-Northern and Norfolk-Southern railroads, and included the following alternatives: coal fired diesel locomotive; direct fired gas turbine locomotives; direct fired gas turbine locomotive with steam injection; raw coal gasifier gas turbine locomotive; and raw coal fluid bed steam turbine locomotive. All alternatives use the electric drive transmission and were selected for final evaluation. The first three would use a coal water slurry as a fuel, which must be produced by new processing plants. Therefore, use of a slurry would require a significant plant capital investment. The last two would use classified run-of-the-mine (ROM) coal with much less capital expenditure. Coal fueling stations would be required but are significantly lower in capital cost than a coal slurry plant. For any coal fired locomotive to be commercially viable, it must pass the following criteria: be technically feasible and environmentally acceptable; meet railroads' financial expectations; and offer an attractive return to the locomotive manufacturer. These three criteria are reviewed in the report.

Not Available

1986-02-01T23:59:59.000Z

406

Evaluation of factors that influence microbial communities and methane production in coal microcosms.  

E-Print Network [OSTI]

??Vast reserves of coal represent a largely untapped resource that can be used to produce methane gas, a cleaner energy alternative compared to burning oil… (more)

Gallagher, Lisa K.

2014-01-01T23:59:59.000Z

407

Clean coal technology using process integration : a focus on the IGCC.  

E-Print Network [OSTI]

?? The integrated gasification combined cycle (IGCC) is the most environmentally friendly coal-fired power generation technology that offers near zero green house gas emissions. This… (more)

Madzivhandila, Vhutshilo

2011-01-01T23:59:59.000Z

408

CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR  

E-Print Network [OSTI]

off-gas from a typical gasifier contains large percentagesIOAl-Cr alloys at coal-gasifier This FeS and CaS0 operating

Gordon, B.A.

2011-01-01T23:59:59.000Z

409

E-Print Network 3.0 - abandoned underground coal Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Universitet, Department of Theoretical Physics Collection: Physics 4 Division of Oil, Gas, and Mining Permitting Summary: John R. Baza DirectorCoal Minerals Abandoned Mine...

410

E-Print Network 3.0 - advanced coal combustor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ash, boiler slag, and flue gas desulfurization (FGD) by-products from advanced clean coal technology... combustors. This paper briefly ... Source: Wisconsin-Milwaukee,...

411

E-Print Network 3.0 - advanced coal-fired systems Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Program Collection: Fossil Fuels 13 Nuclear Engineering Graduate Program Summary: pollutants, a coal-fired power plant, in contrast, annually releases 10 billion kg of carbon...

412

E-Print Network 3.0 - advanced coal-fired low-emission Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plasma Physics and Fusion 27 Nuclear Engineering Graduate Program Summary: pollutants, a coal-fired power plant, in contrast, annually releases 10 billion kg of carbon...

413

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

414

Sixth annual coal preparation, utilization, and environmental control contractors conference  

SciTech Connect (OSTI)

A conference was held on coal preparation, utilization and environmental control. Topics included: combustion of fuel slurries; combustor performance; desulfurization chemically and by biodegradation; coal cleaning; pollution control of sulfur oxides and nitrogen oxides; particulate control; and flue gas desulfurization. Individual projects are processed separately for the databases. (CBS).

Not Available

1990-01-01T23:59:59.000Z

415

Retrofitted coal-fired firetube boiler and method employed therewith  

DOE Patents [OSTI]

A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

Wagoner, C.L.; Foote, J.P.

1995-07-04T23:59:59.000Z

416

NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS  

SciTech Connect (OSTI)

This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O'Dowd; Dr. Hien Pham; Jian Xu

2001-01-07T23:59:59.000Z

417

Retrofitted coal-fired firetube boiler and method employed therewith  

DOE Patents [OSTI]

A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

1995-01-01T23:59:59.000Z

418

Particle number fluctuations in nuclear collisions within excluded volume hadron gas model  

E-Print Network [OSTI]

The multiplicity fluctuations are studied in the van der Waals excluded volume hadron-resonance gas model. The calculations are done in the grand canonical ensemble within the Boltzmann statistics approximation. The scaled variances for positive, negative and all charged hadrons are calculated along the chemical freeze-out line of nucleus-nucleus collisions at different collision energies. The multiplicity fluctuations are found to be suppressed in the van der Waals gas. The numerical calculations are presented for two values of hard-core hadron radius, $r=0.3$ fm and 0.5 fm, as well as for the upper limit of the excluded volume suppression effects.

M. I. Gorenstein; M. Hauer; D. O. Nikolajenko

2007-02-26T23:59:59.000Z

419

CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS  

SciTech Connect (OSTI)

This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

2009-11-30T23:59:59.000Z

420

Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050  

E-Print Network [OSTI]

Hydrogen (Natural Gas, pipeline) Hydrogen (Natural Gas,liquid H2 truck) Hydrogen (Coal, pipeline) Electricity (production? Hydrogen Production Mix Natural Gas, pipeline,

Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gas coal nuclear" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network [OSTI]

Plant - without coking (lb/hr) Feed Coal* Hydrogen YieldsCoking Summary Cost Estimates for Solvent Refining of Five U.S. CoalsCoal Handling and Preparation Preheaters and Dissolvers Mineral Separation (Filters) Solvent Recovery Gas Recovery Mineral Residue Processing and Storage Coking

Ferrell, G.C.

2010-01-01T23:59:59.000Z

422

Coal Severance Tax (North Dakota)  

Broader source: Energy.gov [DOE]

The Coal Severance Tax is imposed on all coal severed for sale or industrial purposes, except coal used for heating buildings in the state, coal used by the state or any political subdivision of...

423

Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power  

E-Print Network [OSTI]

as deaths and emissions per unit electric energy generated, for relevant electricity sources (Table 1 Nuclear energy (and other low-carbon/carbon-free energy sources) could help to mitigate both deaths and GHG emissions, we start with data for global annual electricity generation by energy source