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Sample records for gabon mauri tania

  1. Tania Smith Taylor | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tania Smith Taylor About Us Tania Smith Taylor Director, Office of Site Operations Tania Smith Taylor became the new Director of the LM Office of Site Operations in January 2016. Prior to joining LM, Tania worked for the DOE Office of Environmental Management (EM), leading several initiatives pertinent to managing facilities and infrastructure, eliminating excess contaminated facilities, reusing assets for economic development, using project management lessons learned, creating contractor

  2. Microsoft PowerPoint - 3-ARI presentation - Mound - Tania Smith

    Office of Legacy Management (LM)

    Asset Revitalization Initiative Moving Toward a Vision Tania Smith ARI Vision for DOE * Site operations are conducted in a sustainable manner, facilities and transit are powered by clean energy, and major environmental remediation is complete. * Site infrastructure is modern, adaptable, and efficient, and multiple federal agencies conduct operations in a seamless manner. * Public-private partnerships thrive, and commercial entities invest in new opportunities to create jobs. * Local communities

  3. Gabon: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Country Profile Name Gabon Population 1,475,000 GDP 20,664,000,000 Energy Consumption 0.05 Quadrillion Btu 2-letter ISO code GA 3-letter ISO code GAB Numeric ISO...

  4. Maury Tigner, 1990 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Maury Tigner, 1990 The Ernest Orlando Lawrence Award Lawrence Award Home Nomination & Selection Guidelines Award Laureates 2010's 2000's 1990's 1980's 1970's 1960's Ceremony The Life of Ernest Orlando Lawrence Contact Information The Ernest Orlando Lawrence Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us 1990's Maury Tigner, 1990 Print Text Size: A A A FeedbackShare Page Physics: For his contributions to

  5. Gabon-World Bank Climate Activities | Open Energy Information

    Open Energy Info (EERE)

    World Bank Climate Activities Jump to: navigation, search Name Gabon-World Bank Climate Activities AgencyCompany Organization World Bank Sector Land Focus Area Forestry Topics...

  6. Gabon-Enhancing Capacity for Low Emission Development Strategies...

    Open Energy Info (EERE)

    illustrates the U.S. perspective on LEDS: Integrated development goals and objectives, national greenhouse gas inventory, and economic and resource data Long-term projections of...

  7. Forum des Jeuns du Gabon | Open Energy Information

    Open Energy Info (EERE)

    drought and land degradation, Environmentally sound technologies, Gender, Human rights and Sustainable development plans References "UNEP Major Groups Directory"...

  8. Gabon-Supporting Low Carbon Development and Climate Resilient...

    Open Energy Info (EERE)

    Strategies in Africa AgencyCompany Organization France Agency of Development (AFD) Partner ADETEF Sector Climate Focus Area People and Policy Topics Low emission...

  9. Microsoft PowerPoint - 2013_2-22_Waste_Management_Symposium_...

    Office of Environmental Management (EM)

    Asset Revitalization Initiative Goals, Task Force, and Deliverables Tania Smith, DOE-EM ... Contact Information: Tania Smith, DOE-EM ARI Task Force Co-Lead 202-586-5008 ...

  10. Browse by Discipline -- E-print Network Subject Pathways: Fossil...

    Office of Scientific and Technical Information (OSTI)

    of Technology Vu, Tania (Tania Vu) - Division of Biomedical Engineering, Oregon Health and Science University Go back to Individual Researchers Collections: A B C D E F G H ...

  11. Team Summary | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Steering Committee Objective: Set the strategic direction, provide overarching leadership, and support the ARI Task Force. Leads: Dave Geiser (Legacy Management LM), Tania Smith ...

  12. HQ Human Resources - Points of Contact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HQ Human Resources - Points of Contact HQ Human Resources - Points of Contact Name Division Phone Room # Email Address ARPA-E Burkley, Tania Executive Resources 202-586-7657 4E-084 Robinson, Peggy Labor and Employee Relations 202-586-2591 8E-092 Kennedy, Rhonda HR Business Partner (HRBP) 202-586-3544 4E-084 ARRA Burkey Tania Executive Resources 202-586-7657 4E-084 Hawkins, Renee HR Operations

  13. Divisional Mentoring Program Contacts | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ES Sandy Davis EVS John Krummel** HEP Maury Goodman LCF Scott Parker MCS Tom Peterka...

  14. CX-003270: Categorical Exclusion Determination

    Broader source: [DOE]

    Tennessee-County-MauryCX(s) Applied: B2.5, B5.1Date: 07/26/2010Location(s): Maury County, TennesseeOffice(s): Energy Efficiency and Renewable Energy

  15. Leadership | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Leadership Leadership David Geiser Director and Acting Deputy Director, Office of Legacy Management More about Director David Geiser Thomas Pauling Director, Office of Business Operations More about Director Thomas Pauling Tania Smith Taylor Director, Office of Site Operations More about Tania Smith Taylor More Legacy Management Team Leaders News News Archive Program Updates Spotlights Archive Congressional Testimony Professional Papers Leadership Team Leaders

  16. POCs for Secretarial Offices and Management and Performance ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Tyesha Bennett 202-586-1444 Shane Humphreys 202-586-9661 Cathlyne Smith 202-586-7384 Tania Burkley ...

  17. Legacy Management Contacts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Collins Team Leader (202) 586-8259 (202) 586-1540 Office of Site Operations Tania Smith Taylor Director (202) 586-5008 (202) 586-1540 Environment Team 1 (UMTRCANVO Sites) ...

  18. Climate Zone 4A | Open Energy Information

    Open Energy Info (EERE)

    Virginia Mason County, Kentucky Mason County, West Virginia Massac County, Illinois Mathews County, Virginia Maury County, Tennessee McCracken County, Kentucky McCreary County,...

  19. Recent progress in neutrino factory and muon collider research...

    Office of Scientific and Technical Information (OSTI)

    Gilardoni, Simone ; Van Ginneken, Andreas J. ; Ginzburg, Ilya F. ; Godang, Romulus ; Goodman, Maury ; Gosz, Michael R. ; Green, Michael A. ; Gruber, Peter ; Gunion, John F. ; ...

  20. Clean Cities: Middle-West Tennessee Clean Fuels coalition

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Maury, McNairy, Montgomery, Moore, Obion, Perry, Robertson, Rutherford, Shelby, Smith, Stewart, Sumner, Tipton, Trousdale, Wayne, Weakley, Williamson, Wilson Designated:...

  1. 1990's | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zachary Fisk Richard Fortner Rulon Linford Peter Schultz Richard E. Smalley J. Pace Vandevender 1990 John J. Dorning James R. Norris S. Thomas Picraux Wayne J. Shotts Maury Tigner ...

  2. Wind and Water Materials and Structures Database Download

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & ... Eritrea Estonia Ethiopia Fiji Finland France French Polynesia Gabon Gambia Georgia ...

  3. Total Crude Oil and Products Imports from All Countries

    U.S. Energy Information Administration (EIA) Indexed Site

    Costa Rica Croatia Curacao Cyprus Czech Republic Denmark Dominican Republic Egypt El Salvador Equatorial Guinea Estonia Finland France French Guiana Gabon Georgia, Republic ...

  4. U.S. Imports from All Countries

    U.S. Energy Information Administration (EIA) Indexed Site

    Costa Rica Croatia Curacao Cyprus Czech Republic Denmark Dominican Republic Egypt El Salvador Equatorial Guinea Estonia Finland France French Guiana Gabon Georgia, Republic ...

  5. National Action Programmes on Desertification | Open Energy Informatio...

    Open Energy Info (EERE)

    Faso, Burundi, Cameroon, Cape Verde, Chad, Democratic Republic of Congo, Djibouti, Egypt, Equatorial Guinea, Eritrea, Ethiopia, Gabon, Gambia, Ghana, Guinea, Kenya, Lesotho,...

  6. USAID West Africa Climate Program | Open Energy Information

    Open Energy Info (EERE)

    Guinea, Guinea-Bissau, Cameroon, Gabon, Equatorial Guinea, Chad, Sao Tome and Principe, Cape Verde Western Africa, Western Africa, Western Africa, Western Africa, Western...

  7. Microsoft PowerPoint - 2013_2-22_Waste_Management_Symposium_-_T._Smith_ARI_Creating_a_2020_DOE

    Energy Savers [EERE]

    Asset Revitalization Initiative Goals, Task Force, and Deliverables Tania Smith, DOE-EM ARI Task Force Leader February 2013 ARI Mission The Asset Revitalization Initiative (ARI) is a U.S. Department of Energy (DOE)-wide effort to advance the beneficial reuse of its unique and diverse mix of assets, including land, facilities, infrastructure, equipment, technologies, natural resources, and a highly skilled workforce. ARI promotes a more efficient business environment to encourage collaboration

  8. Slide 1

    Energy Savers [EERE]

    Site Restoration Overview Tania Smith Acting Associate Deputy Assistant Secretary for Site Restoration Office of Environmental Management September 2, 2015 2 Mission  Identify and advance strategies to plan and optimize EM soil and groundwater remediation, deactivation & decommissioning and facility engineering projects, all within a risk-informed, sustainable framework  Ensure optimized management of projects and technical practices and incorporate transformational

  9. Sandia National Labs: PCNSC: News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Awards Featured Projects News Releases Partnering Research News The Solid State Lighting Science Energy Frontier Research Center (SSLS EFRC) entered a video competition for the DOE EFRC Summit and Forum. The 3-minute video explores the science behind enabling greater energy efficiency, and features George Wang and Tania Henry." Awards Featured Projects News Releases Archives News Releases 2011 (Coming Soon)

  10. User:GregZiebold/Developing Country Programs Map | Open Energy...

    Open Energy Info (EERE)

    of Congo 12 Djibouti 3 Dominica 9 Dominican Republic 12 Ecuador 7 Egypt 14 El Salvador 8 Equatorial Guinea 4 Eritrea 3 Estonia 2 Ethiopia 21 Fiji 1 Gabon 10 ... further...

  11. U.S. Crude Oil Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    (Brazzaville) 24 8 13 20 12 15 1993-2015 Congo (Kinshasa) 1993-2013 Denmark 1997-2004 Egypt 17 1993-2015 Equatorial Guinea 1996-2014 Estonia 1999-1999 Gabon 4 18 1993-2015...

  12. Microsoft PowerPoint - 3 Dave Esh

    Office of Environmental Management (EM)

    of Energy 2009.10.27 Bridge Inspection Follow-up Microsoft PowerPoint - 2009.10.27 Bridge Inspection Follow-up PDF icon Microsoft PowerPoint - 2009.10.27 Bridge Inspection Follow-up More Documents & Publications Slide 1 Slide 1 Microsoft Word - Issue FY2009 Q4 Draft 20090910.doc

    Asset Revitalization Initiative Goals, Task Force, and Deliverables Tania Smith, DOE-EM ARI Task Force Leader February 2013 ARI Mission The Asset Revitalization Initiative (ARI) is a U.S. Department of Energy

  13. Microsoft Word - FY07AnnualReport.doc

    Broader source: (indexed) [DOE]

    (EZ) 1 18,000,000 FRANCE (FR) 5 8,093,198 GABON (GB) 1 441,600 GAMBIA (GA) 1 49,300 GERMANY FEDERAL REPUBLIC OF (GE) 3 1,698,498 HUNGARY (HU) 1 4,000,000 KAZAKHSTAN (KZ) 3...

  14. Oil and gas developments in central and southern Africa in 1987

    SciTech Connect (OSTI)

    Hartman, J.B.; Walker, T.L.


    Significant rightholding changes took place in central and southern Africa during 1987. Angola, Benin, Congo, Gabon, Ghana, Guinea, Guinea Bissau, Mauritania, Seychelles, Somali Republic, Tanzania, Zaire, and Zambia announced awards or acreage open for bidding. Decreases in exploratory rightholdings occurred in Cameroon, Congo, Cote d'Ivoire, Equatorial Guinea, Gabon, Kenya, Namibia, South Africa, and Tanzania. More wells and greater footage were drilled in 1987 than in 1986. Total wells increased by 18% as 254 wells were completed compared to 217 in 1986. Footage drilled during the year increased by 46% as about 1.9 million ft were drilled compared to about 1.3 million ft in 1986. The success rate for exploration wells in 1987 improved slightly to 36% compared to 34% in 1986. Significant discoveries were made in Nigeria, Angola, Congo, and Gabon. Seismic acquisition in 1987 was the major geophysical activity during the year. Total oil production in 1987 was 773 million bbl (about 2.1 million b/d), a decrease of 7%. The decrease is mostly due to a 14% drop in Nigerian production, which comprises 60% of total regional production. The production share of OPEC countries (Nigeria and Gabon) versus non-OPEC countries of 67% remained unchanged from 1986. 24 figs., 5 tabs.

  15. Microsoft Word - Luminescent_revised.docx

    Office of Scientific and Technical Information (OSTI)

    NEAR-IR TWO PHOTON MICROSCOPY IMAGING OF SILICA NANOPARTICLES FUNCTIONALIZED WITH ISOLATED SENSITIZED Yb(lll) CENTERS. Giuseppe Lapadula,1 Adrien Bourdelle,2,3 Fieri an Allouche,1 Matthew P. Conley,1 Iker del Rosal,4 Laurent M aron,4 Wayne W. Lukens,5 Yannick G uyot,6 Chantal Andraud,2 Sophie Brasselet,7 Christophe Coperet,14,3* Olivier Maury,2* Richard A. Andersen.8 ■ ETH Zurich, Department of Chemistry and Applied Biosciences, Vladimir Prelog Weg 2, C H -8093 Zurich, Switzerland * Universite

  16. NREL: International Activities - Bilateral Partnerships

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printable Version Bilateral Partnerships NREL partners with more than 50 countries around the world to advance development and use of renewable energy and energy efficiency technologies: Angola Argentina Australia Bangladesh Brazil Canada Chile China Colombia Costa Rica Gabon Haiti India Indonesia Japan Kazakhstan Kenya Korea Mexico North America Philippines Saudi Arabia U.S. Pacific Territories United Arab Emirates Vietnam Asia Bangladesh Under sponsorship from the U.S. Agency for International

  17. Africa: Unrest and restrictive terms limit abundant potential. [Oil and gas exploration and development in Africa

    SciTech Connect (OSTI)

    Not Available


    This paper summarizes the drilling and exploration activity of the oil and gas industries of Egypt, Libya, Tunisia, Algeria, Morocco, Nigeria, Cameroon, Gabon, the Congo, Angola, and South Africa. Information is provided on current and predicted trends in well drilling activities (both onshore and offshore), numbers of new wells, footage information, production statistics and what fields accounted for this production, and planned new exploration activities. The paper also describes the current status of government policies and political problems affecting the oil and gas industry.

  18. Turmoil doesn`t dampen enthusiasm

    SciTech Connect (OSTI)


    The paper discusses the outlook for the African gas and oil industries. Though Africa remains politically and economically volatile, its vast energy potential is becoming increasingly attractive to foreign oil and gas companies. Separate evaluations are given for Algeria, Egypt, Nigeria, Angola, Libya, Congo, Gabon, Tunisia, Cameroon, Cote D`Ivoire, and briefly for South Africa, Sudan, Equatorial Guinea, Ghana, Zaire, Benin, Mozambique, Chad, Namibia, Tanzania, Eritrea, Guinea-Bissau, Senegal, Morocco, Sao Tome and Principe, Ethiopia, Niger, Madagascar, Rwanda, Mauritania, Seychelles, Uganda, and Liberia.

  19. African oil plays

    SciTech Connect (OSTI)

    Clifford, A.J. )


    The vast continent of Africa hosts over eight sedimentary basins, covering approximately half its total area. Of these basins, only 82% have entered a mature exploration phase, 9% have had little or no exploration at all. Since oil was first discovered in Africa during the mid-1950s, old play concepts continue to bear fruit, for example in Egypt and Nigeria, while new play concepts promise to become more important, such as in Algeria, Angola, Chad, Egypt, Gabon, and Sudan. The most exciting developments of recent years in African oil exploration are: (1) the Gamba/Dentale play, onshore Gabon; (2) the Pinda play, offshore Angola; (3) the Lucula/Toca play, offshore Cabinda; (4) the Metlaoui play, offshore Libya/Tunisia; (5) the mid-Cretaceous sand play, Chad/Sudan; and (6) the TAG-I/F6 play, onshore Algeria. Examples of these plays are illustrated along with some of the more traditional oil plays. Where are the future oil plays likely to develop No doubt, the Saharan basins of Algeria and Libya will feature strongly, also the presalt of Equatorial West Africa, the Central African Rift System and, more speculatively, offshore Ethiopia and Namibia, and onshore Madagascar, Mozambique, and Tanzania.

  20. Climate and lake-level history of the northern Altiplano, Bolivia, as recorded in Holocene sediments of the Rio Desaguadero

    SciTech Connect (OSTI)

    Baucom, P.C.; Rigsby, C.A.


    Strata exposed in terraces and modern cutbanks along the Rio Desaguadero contain a variety of lithofacies that were deposited in four distinct facies associations. These facies associations document a history of aggradation and downcutting that is linked to Holocene climate change on the Altiplano. Braided-stream, meandering-stream, deltaic and shoreline, and lacustrine sediments preserved in multi-level terraces in the northern Rio Desaguadero valley record two high-water intervals: one between 4,500 and 3,900 yr BP and another between 2,000 and 2,200 yr BP. These wet periods were interrupted by three periods of fluvial downcutting, centered at approximately 4,000 yr BP, 3,600 yr BP, and after 2,000 yr BP. Braided-river sediments preserved in a single terrace level in the southern Rio Desaguadero valley record a history of nearly continuous fluvial sedimentation from at least 7,000 yr BP until approximately 3,200 yr BP that was followed by a single episode (post-3,210 yr BP) of down-cutting and lateral migration. The deposition and subsequent fluvial downcutting of the northern strata was controlled by changes in effective moisture that can be correlated to Holocene water-level fluctuations of Lake Titicaca. The deposition and dissection of braided-stream sediments to the south are more likely controlled by a combination of base-level change and sediment input from the Rio Mauri.

  1. Africa: the emphasis is exploration

    SciTech Connect (OSTI)

    Not Available


    Individual country reports on drilling, oil and gas production, and petroleum exploration and reserves are given for Africa. Nigeria was the continent's largest oil producer in 1979, averaging 2.3 million bpd, followed closely by Libya with 2.07 million bpd. Algeria cut production of crude oil in 1979 to a level of 1,194,350 bpd, and increased gas production to 2031 mmcfd. In Egypt, the return of Israeli-occupied oil fields and a surge in productive capacity enabled production averaging 524,000 bpd. Brief country reports are included for Gabon, Angola, Republic of the Congo, Cameroun, Tunisia, Morocco, Zaire, Ivory Coast, Ghana, Niger, Chad, Republic of South Africa, Sudan, Tanzania, Equatorial Guinea, Seychelles Islands, Mauritania, Republic of Mali, Benin, Kenya, Madagascar, Botswana, Gambia, Mozambique, and Senegal.

  2. Building international genomics collaboration for global health security

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cui, Helen H.; Erkkila, Tracy; Chain, Patrick S. G.; Vuyisich, Momchilo


    Genome science and technologies are transforming life sciences globally in many ways and becoming a highly desirable area for international collaboration to strengthen global health. The Genome Science Program at the Los Alamos National Laboratory is leveraging a long history of expertise in genomics research to assist multiple partner nations in advancing their genomics and bioinformatics capabilities. The capability development objectives focus on providing a molecular genomics-based scientific approach for pathogen detection, characterization, and biosurveillance applications. The general approaches include introduction of basic principles in genomics technologies, training on laboratory methodologies and bioinformatic analysis of resulting data, procurement, and installationmore » of next-generation sequencing instruments, establishing bioinformatics software capabilities, and exploring collaborative applications of the genomics capabilities in public health. Genome centers have been established with public health and research institutions in the Republic of Georgia, Kingdom of Jordan, Uganda, and Gabon; broader collaborations in genomics applications have also been developed with research institutions in many other countries.« less

  3. Tropical Africa: Land Use, Biomass, and Carbon Estimates for 1980 (NDP-055)

    SciTech Connect (OSTI)

    Brown, S.


    This document describes the contents of a digital database containing maximum potential aboveground biomass, land use, and estimated biomass and carbon data for 1980. The biomass data and carbon estimates are associated with woody vegetation in Tropical Africa. These data were collected to reduce the uncertainty associated with estimating historical releases of carbon from land use change. Tropical Africa is defined here as encompassing 22.7 x 10{sup 6} km{sup 2} of the earth's land surface and is comprised of countries that are located in tropical Africa (Angola, Botswana, Burundi, Cameroon, Cape Verde, Central African Republic, Chad, Congo, Benin, Equatorial Guinea, Ethiopia, Djibouti, Gabon, Gambia, Ghana, Guinea, Ivory Coast, Kenya, Liberia, Madagascar, Malawi, Mali, Mauritania, Mozambique, Namibia, Niger, Nigeria, Guinea-Bissau, Zimbabwe (Rhodesia), Rwanda, Senegal, Sierra Leone, Somalia, Sudan, Tanzania, Togo, Uganda, Burkina Faso (Upper Volta), Zaire, and Zambia). The database was developed using the GRID module in the ARC/INFO{trademark} geographic information system. Source data were obtained from the Food and Agriculture Organization (FAO), the U.S. National Geophysical Data Center, and a limited number of biomass-carbon density case studies. These data were used to derive the maximum potential and actual (ca. 1980) aboveground biomass values at regional and country levels. The land-use data provided were derived from a vegetation map originally produced for the FAO by the International Institute of Vegetation Mapping, Toulouse, France.

  4. Central and southern Africa

    SciTech Connect (OSTI)

    McGrew, H.J.


    Exploration in central and southern Africa continued to expand during 1980. The greatest concentration of activity was in Nigeria. However, there was considerable increase in the level of exploratory work in Cameroon and Congo. Significant new finds have been made in Ivory Coast. Geological and geophysical activity was carried out in 18 of the countries, with those in the western part having the largest share. Seismic work involved 225 party months of operation. Most of this time was spent on land, but marine operations accounted for 73,389 km of new control. Gravity and magnetic data were recorded during the marine surveys, and several large aeromagnetic projects were undertaken to obtain a total of 164,498 line km of data. Exploratory and development drilling accounted for a total of 304 wells and 2,605,044 ft (794,212 m) of hole. The 92 exploratory wells that were drilled resulted in 47 oil and gas discoveries. In development drilling 89% of the 212 wells were successful. At the end of the year, 27 exploratory wells were underway, and 34 development wells were being drilled for a total of 61. Oil production from the countries that this review covers was 918,747,009 bbl in 1980, a drop of about 9% from the previous year. Countries showing a decline in production were Nigeria, Gabon, Cabinda, and Zaire. Increases were recorded in Cameroon, Congo, and Ghana. A new country was added to the list of producers when production from the Belier field in Ivory Coast came on stream. 33 figures, 15 tables.

  5. Epsilon Metal Summary Report FY 2011

    SciTech Connect (OSTI)

    Strachan, Denis M.; Crum, Jarrod V.; Zumhoff, Mac R.; Bovaird, Chase C.; Windisch, Charles F.; Riley, Brian J.


    The Epsilon-metal ({var_epsilon}-metal) phase was selected in FY 2009 as a potential waste form to for immobilizing the noble metals found in the undissolved solids + aqueous stream, and the soluble Tc from ion-exchange process, each resulting from proposed aqueous reprocessing. {var_epsilon}-metal phase is observed in used nuclear fuel and the natural reactors of Oklobono in Gabon, where the long-term corrosion behavior was demonstrated. This makes {var_epsilon}-metal a very attractive waste form. Last fiscal year, {var_epsilon}-metal was successfully fabricated by combining the five-metals, Mo, Ru, Rh, Pd and Re (surrogate for Tc), into pellets followed by consolidation with an arc melter. The arc melter produced fully dense samples with the epsilon structure. However, some chemistry differences were observed in the microstructure that resulted in regions rich in Re and Mo, and others rich in Pd, while Ru and Rh remained fairly constant throughout. This year, thermal stability (air), and corrosion testing of the samples fabricated by arc melting were the main focus for experimental work. Thermal stability was measured with a differential scanning calorimeter - thermogravimetric analyzer, by both ramp heating as well as step heating. There is clear evidence during the ramp heating experiment of an exothermic event + a weight loss peak both beginning at {approx}700 C. Step heating showed an oxidation event at {approx}690 C with minimal weight gain that occurs just before the weight loss event at 700 C. The conclusion being that the e-metal begins to oxidize and then become volatile. These findings are useful for considering the effects of voloxidation process. Three different pellets were subjected to electrochemical testing to study the corrosion behavior of the epsilon-metal phase in various conditions, namely acidic, basic, saline, and inert. Test was done according to an interim procedure developed for the alloy metal waste form. First an open circuit potential was measured, followed by linear polarization sweeps. The linear polarization sweep range was the Tafel equation was fit to the linear polarization sweep data to determine the corrosion rate of each pellet in each test solution. The average calculated corrosion rates of the three pellets according to solution conditions were: -1.91 x 10{sup -4} mm/yr (0.001 M NaOH), -1.48 x 10{sup -3} mm/yr (0.01 M NaCl), -8.77 x 10{sup -4} mm/yr (0.001 M H{sub 2}SO{sub 4}), -2.09 x 10{sup -3} mm/yr (0.001 M NaOH + 0.01 M NaCl), and -1.54 x 10{sup -3} mm/yr (0.001 M H{sub 2}SO{sub 4} + 0.01 M NaCl). Three single-pass flow through (SPFT) test were conducted at a flow rate of 10 ml/day, at 90 C, and pH of 2.5, 7.0, and 9.0 for up to 322 days. Results of the tests indicate that dissolution rates were 5 x 10{sup -4} g m{sup 2} d{sup -1} at pH 9.0, 1.2 x 10{sup -4} g m{sup -2} d{sup -1} at pH 7.0, and 2 x 10{sup -4} g m{sup -2} d{sup -1} at pH 2.5. The sample used for the pH 7.0 SPFT test contains extra Re compared to samples used for the other two SPFT test, which came from a single pellet. The corrosion data measured this year indicate that the {var_epsilon}-metal phase is chemically durable. The two chemically different phases, but structurally the same, behave differently during dissolution according to the microstructure changes observed in both the electrochemical and in SPFT test. Characterization of the test specimens after testing suggests that the dissolution is complex and involves oxidative dissolution followed by precipitation of both oxide and metallic phases. These data suggest that the dissolution in the electrochemical and SPFT tests is different; a process that needs further investigation.