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Sample records for gabbs alkali flat

  1. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    GEA Development Phase: Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean...

  2. Gabbs Alkali Flat Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean Capacity: Click "Edit With...

  3. Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008...

    Open Energy Info (EERE)

    Mark Coolbaugh, Chris Sladek, Rick Zehner, Robin Penfield, Ben Delwiche (2008) A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  4. 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open...

    Open Energy Info (EERE)

    Mark Coolbaugh, Chris Sladek, Rick Zehner, Robin Penfield, Ben Delwiche (2008) A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  5. Hydroprobe At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Hydroprobe At Gabbs Valley Area (DOE GTP) Exploration Activity...

  6. Slim Holes At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Gabbs Valley Area (DOE GTP) Exploration Activity...

  7. LiDAR At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: LiDAR At Gabbs Valley Area (DOE GTP) Exploration Activity Details...

  8. Core Analysis At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Core Analysis At Gabbs Valley Area (DOE GTP) Exploration Activity...

  9. 2-M Probe At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Gabbs Valley Area (DOE GTP) Exploration Activity Details Location Gabbs Valley...

  10. Gas Sampling At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Gabbs Valley Area (DOE GTP)...

  11. Gas Sampling At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Gabbs Valley Area (DOE GTP) (Redirected from Water-Gas Samples At Gabbs Valley Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  12. Over Core Stress At Gabbs Valley Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Stress At Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Over Core Stress At Gabbs Valley Area (DOE GTP) Exploration...

  13. Field Mapping At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Gabbs Valley Area (DOE GTP) Exploration Activity Details Location Gabbs Valley...

  14. Density Log at Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log at Gabbs Valley Area (DOE GTP) Exploration Activity Details Location Gabbs Valley...

  15. Flow Test At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Gabbs Valley Area (DOE GTP) Exploration Activity Details Location Gabbs Valley Area...

  16. Property:Reference material | Open Energy Information

    Open Energy Info (EERE)

    ARRA Spreadsheet + 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) + A New Gold Pan For The West- Discovering Blind Geothermal Systems With Shallow Temperature Surveys...

  17. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E.; Reed, William H.; Berkey, Edgar

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  18. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  19. Alkali metal ion battery with bimetallic electrode

    DOE Patents [OSTI]

    Boysen, Dane A; Bradwell, David J; Jiang, Kai; Kim, Hojong; Ortiz, Luis A; Sadoway, Donald R; Tomaszowska, Alina A; Wei, Weifeng; Wang, Kangli

    2015-04-07

    Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten the alkali metal and the electrode comprising the combined alkali/non-alkali metals.

  20. Methods of recovering alkali metals

    SciTech Connect (OSTI)

    Krumhansl, James L; Rigali, Mark J

    2014-03-04

    Approaches for alkali metal extraction, sequestration and recovery are described. For example, a method of recovering alkali metals includes providing a CST or CST-like (e.g., small pore zeolite) material. The alkali metal species is scavenged from the liquid mixture by the CST or CST-like material. The alkali metal species is extracted from the CST or CST-like material.

  1. Hydrothermal alkali metal recovery process

    DOE Patents [OSTI]

    Wolfs, Denise Y.; Clavenna, Le Roy R.; Eakman, James M.; Kalina, Theodore

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

  2. PROCESS OF RECOVERING ALKALI METALS

    DOE Patents [OSTI]

    Wolkoff, J.

    1961-08-15

    A process is described of recovering alkali metal vapor by sorption on activated alumina, activated carbon, dehydrated zeolite, activated magnesia, or Fuller's earth preheated above the vaporization temperature of the alkali metal and subsequent desorption by heating the solvent under vacuum. (AEC)

  3. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Gregory, Kevin M.

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  4. Flat | Open Energy Information

    Open Energy Info (EERE)

    ENERGYGeothermal Home Print PDF Flat Dictionary.png Flat: A relatively smooth landscape with no topographic relief Other definitions:Wikipedia Reegle Topographic Features...

  5. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  6. Windy Flats | Open Energy Information

    Open Energy Info (EERE)

    Flats Jump to: navigation, search Name Windy Flats Facility Windy Flats Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Cannon Power Group...

  7. Hydrothermal alkali metal catalyst recovery process

    DOE Patents [OSTI]

    Eakman, James M.; Clavenna, LeRoy R.

    1979-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles primarily in the form of water soluble alkali metal formates by treating the particles with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of added carbon monoxide. During the treating process the water insoluble alkali metal compounds comprising the insoluble alkali metal residues are converted into water soluble alkali metal formates. The resultant aqueous solution containing water soluble alkali metal formates is then separated from the treated particles and any insoluble materials formed during the treatment process, and recycled to the gasification process where the alkali metal formates serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. This process permits increased recovery of alkali metal constituents, thereby decreasing the overall cost of the gasification process by reducing the amount of makeup alkali metal compounds necessary.

  8. Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator

    DOE Patents [OSTI]

    Joshi, Ashok V.; Balagopal, Shekar; Pendelton, Justin

    2011-12-13

    Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

  9. DHS Flat Stanley Project

    Broader source: Energy.gov [DOE]

    To provide information on the DHS Flat Stanley Project. The goal of the project is to help kids learn about the importance of cybersecurity.

  10. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  11. SHEPHERDS FLAT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SHEPHERDS FLAT SHEPHERDS FLAT DOE-LPO_Project-Posters_WIND_Shepherds-Flat.pdf (381.97 KB) More Documents & Publications EIS-0183: Record of Decision EIS-0183: Record of Decision EIS-0419: Supplement Analysis

  12. Regenerable activated bauxite adsorbent alkali monitor probe

    DOE Patents [OSTI]

    Lee, Sheldon H. D.

    1992-01-01

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases.

  13. Regenerable activated bauxite adsorbent alkali monitor probe

    DOE Patents [OSTI]

    Lee, S.H.D.

    1992-12-22

    A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

  14. Rocky flats teams forming

    SciTech Connect (OSTI)

    1994-08-01

    Bidding teams are shaping up to go after the $3.5-billion, five-year contract to manage ongoing operations and cleanup of the US Dept. of Energy`s Rocky Flats nuclear weapon plant near Denver.

  15. Rocky Flats Overview

    Broader source: Energy.gov [DOE]

    At the August 20, 2014 NNMCAB Site Tour Scott Surovchak DOE, Provided Information on Activities that Took Place on the Rocky Flats Site. Information on the Clean-up Process was Also Given.

  16. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, D.F.; Kwan, S.W.

    1997-04-08

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide. 5 figs.

  17. Diamond films treated with alkali-halides

    DOE Patents [OSTI]

    Anderson, David F.; Kwan, Simon W.

    1997-01-01

    A secondary electron emitter is provided and includes a substrate with a diamond film, the diamond film is treated or coated with an alkali-halide.

  18. Process for the disposal of alkali metals

    DOE Patents [OSTI]

    Lewis, Leroy C.

    1977-01-01

    Large quantities of alkali metals may be safely reacted for ultimate disposal by contact with a hot concentrated caustic solution. The alkali metals react with water in the caustic solution in a controlled reaction while steam dilutes the hydrogen formed by the reaction to a safe level.

  19. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, Raymond D.; McPheeters, Charles C.

    1980-01-01

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  20. Method of handling radioactive alkali metal waste

    DOE Patents [OSTI]

    Wolson, R.D.; McPheeters, C.C.

    Radioactive alkali metal is mixed with particulate silica in a rotary drum reactor in which the alkali metal is converted to the monoxide during rotation of the reactor to produce particulate silica coated with the alkali metal monoxide suitable as a feed material to make a glass for storing radioactive material. Silica particles, the majority of which pass through a 95 mesh screen or preferably through a 200 mesh screen, are employed in this process, and the preferred weight ratio of silica to alkali metal is 7 to 1 in order to produce a feed material for the final glass product having a silica to alkali metal monoxide ratio of about 5 to 1.

  1. Diesel prices flat

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices flat The U.S. average retail price for on-highway diesel fuel saw no movement from last week. Prices remained flat at $3.89 a gallon on Monday, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the West Coast states at 4.05 a gallon, up 2-tenths of a penny from a week ago. Prices were lowest in the Gulf Coast region at 3.80 a gallon, up 3-tenths of a penny

  2. Is flat fair?

    SciTech Connect (OSTI)

    Bunzl, Martin

    2010-07-15

    Dynamic pricing holds out the promise of shifting peak demand as well as reducing overall demand. But it also raises thorny issues of fairness. All practical pricing systems involve tradeoffs between equity and efficiency. I examine the circumstances under which equity ought to be allowed to trump efficiency and whether or not this constitutes a defense of flat pricing. (author)

  3. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A.; Beach, Raymond J.; Dawson, Jay W.; Krupke, William F.

    2007-10-23

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  4. Diode pumped alkali vapor fiber laser

    DOE Patents [OSTI]

    Payne, Stephen A.; Beach, Raymond J.; Dawson, Jay W.; Krupke, William F.

    2006-07-26

    A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

  5. Gabbs Valley Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Reservoir Temp (Measured): Sanyal Classification (Reservoir): Depth to Top of Reservoir: Depth to Bottom of Reservoir: Average Depth to Reservoir: Use the "Edit with...

  6. Gabbs Valley Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Sanyal Classification (Reservoir): Depth to Top of Reservoir: Depth to Bottom of Reservoir: Average Depth to Reservoir: Use the "Edit with Form" button at the top of the...

  7. Diesel prices flat nationally

    U.S. Energy Information Administration (EIA) Indexed Site

    Diesel prices flat nationally The U.S. average retail price for on-highway diesel fuel remained the same from a week ago at $3.98 a gallon on Monday, based on the weekly price survey by the U.S. Energy Information Administration. Diesel prices were highest in the West Coast states at 4.14 a gallon, up 1.4 cents from a week ago. Prices were lowest in the Gulf Coast region at 3.90 a gallon, up a tenth of a penny.

  8. SHEPHERDS FLAT | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    It is expected to prevent 1,000,000 metric tons of carbon dioxide emissions annually. PROJECT STATISTICS: SHEPHERDS FLAT PROJECT SUMMARY OWNER Caithness Energy, LLC LOCATIONS ...

  9. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a...

  10. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, W.Y.

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide to precipitate silicon constituents, the pH of the resultant solution is increased, preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  11. Salts of alkali metal anions and process of preparing same

    DOE Patents [OSTI]

    Dye, James L.; Ceraso, Joseph M.; Tehan, Frederick J.; Lok, Mei Tak

    1978-01-01

    Compounds of alkali metal anion salts of alkali metal cations in bicyclic polyoxadiamines are disclosed. The salts are prepared by contacting an excess of alkali metal with an alkali metal dissolving solution consisting of a bicyclic polyoxadiamine in a suitable solvent, and recovered by precipitation. The salts have a gold-color crystalline appearance and are stable in a vacuum at -10.degree. C. and below.

  12. METATHESIS OF PLUTONIUM CARRIER LANTHANUM FLUORIDE PRECIPITATE WITH AN ALKALI

    DOE Patents [OSTI]

    Duffield, R.B.

    1960-04-01

    A plutonium fluoride precipitate is converted to plutonium hydroxide by digesting the precipitate with an aqueous alkali metal hydroxide solution.

  13. Alkali resistant optical coatings for alkali lasers and methods of production thereof

    DOE Patents [OSTI]

    Soules, Thomas F; Beach, Raymond J; Mitchell, Scott C

    2014-11-18

    In one embodiment, a multilayer dielectric coating for use in an alkali laser includes two or more alternating layers of high and low refractive index materials, wherein an innermost layer includes a thicker, >500 nm, and dense, >97% of theoretical, layer of at least one of: alumina, zirconia, and hafnia for protecting subsequent layers of the two or more alternating layers of high and low index dielectric materials from alkali attack. In another embodiment, a method for forming an alkali resistant coating includes forming a first oxide material above a substrate and forming a second oxide material above the first oxide material to form a multilayer dielectric coating, wherein the second oxide material is on a side of the multilayer dielectric coating for contacting an alkali.

  14. Computational studies of solid-state alkali conduction in rechargeable alkali-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deng, Zhi; Mo, Yifei; Ong, Shyue Ping

    2016-03-25

    The facile conduction of alkali ions in a crystal host is of crucial importance in rechargeable alkali-ion batteries, the dominant form of energy storage today. In this review, we provide a comprehensive survey of computational approaches to study solid-state alkali diffusion. We demonstrate how these methods have provided useful insights into the design of materials that form the main components of a rechargeable alkali-ion battery, namely the electrodes, superionic conductor solid electrolytes and interfaces. We will also provide a perspective on future challenges and directions. Here, the scope of this review includes the monovalent lithium- and sodium-ion chemistries that aremore » currently of the most commercial interest.« less

  15. Absolute calibration of optical flats

    DOE Patents [OSTI]

    Sommargren, Gary E.

    2005-04-05

    The invention uses the phase shifting diffraction interferometer (PSDI) to provide a true point-by-point measurement of absolute flatness over the surface of optical flats. Beams exiting the fiber optics in a PSDI have perfect spherical wavefronts. The measurement beam is reflected from the optical flat and passed through an auxiliary optic to then be combined with the reference beam on a CCD. The combined beams include phase errors due to both the optic under test and the auxiliary optic. Standard phase extraction algorithms are used to calculate this combined phase error. The optical flat is then removed from the system and the measurement fiber is moved to recombine the two beams. The newly combined beams include only the phase errors due to the auxiliary optic. When the second phase measurement is subtracted from the first phase measurement, the absolute phase error of the optical flat is obtained.

  16. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, Craig R.

    1998-01-01

    A microgap flat panel display which includes a thin gas-filled display tube that utilizes switched X-Y "pixel" strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a "pixel" in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel.

  17. Microgap flat panel display

    DOE Patents [OSTI]

    Wuest, C.R.

    1998-12-08

    A microgap flat panel display is disclosed which includes a thin gas-filled display tube that utilizes switched X-Y ``pixel`` strips to trigger electron avalanches and activate a phosphor at a given location on a display screen. The panel utilizes the principal of electron multiplication in a gas subjected to a high electric field to provide sufficient electron current to activate standard luminescent phosphors located on an anode. The X-Y conductive strips of a few micron widths may for example, be deposited on opposite sides of a thin insulating substrate, or on one side of the adjacent substrates and function as a cathode. The X-Y strips are separated from the anode by a gap filled with a suitable gas. Electrical bias is selectively switched onto X and Y strips to activate a ``pixel`` in the region where these strips overlap. A small amount of a long-lived radioisotope is used to initiate an electron avalanche in the overlap region when bias is applied. The avalanche travels through the gas filled gap and activates a luminescent phosphor of a selected color. The bias is adjusted to give a proportional electron multiplication to control brightness for given pixel. 6 figs.

  18. Alkali metal recovery from carbonaceous material conversion process

    DOE Patents [OSTI]

    Sharp, David W.; Clavenna, LeRoy R.; Gorbaty, Martin L.; Tsou, Joe M.

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced in the gasifier or similar reaction zone, alkali metal constitutents are recovered from the particles by withdrawing and passing the particles from the reaction zone to an alkali metal recovery zone in the substantial absence of molecular oxygen and treating the particles in the recovery zone with water or an aqueous solution in the substantial absence of molecular oxygen. The solution formed by treating the particles in the recovery zone will contain water-soluble alkali metal constituents and is recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preventing contact of the particles with oxygen as they are withdrawn from the reaction zone and during treatment in the recovery zone avoids the formation of undesirable alkali metal constituents in the aqueous solution produced in the recovery zone and insures maximum recovery of water-soluble alkali metal constituents from the alkali metal residues.

  19. Flat Ridge Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Flat Ridge Wind Farm Jump to: navigation, search Name Flat Ridge Wind Farm Facility Flat Ridge Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  20. Removal of Retired Alkali Metal Test Systems

    SciTech Connect (OSTI)

    BREHM, W.F.

    2003-01-01

    This paper describes the successful effort to remove alkali metals, alkali metal residues, and piping and structures from retired non-radioactive test systems on the Hanford Site. These test systems were used between 1965 and 1982 to support the Fast Flux Test Facility and the Liquid Metal Fast Breeder Reactor Program. A considerable volume of sodium and sodium-potassium alloy (NaK) was successfully recycled to the commercial sector; structural material and electrical material such as wiring was also recycled. Innovative techniques were used to safely remove NaK and its residues from a test system that could not be gravity-drained. The work was done safely, with no environmental issues or significant schedule delays.

  1. Windy Flats IIa extension | Open Energy Information

    Open Energy Info (EERE)

    IIa extension Jump to: navigation, search Name Windy Flats IIa extension Facility Windy Flats IIa extension Sector Wind energy Facility Type Commercial Scale Wind Facility Status...

  2. Windy Flats Phase III | Open Energy Information

    Open Energy Info (EERE)

    Phase III Jump to: navigation, search Name Windy Flats Phase III Facility Windy Flats Phase III Sector Wind energy Facility Type Commercial Scale Wind Facility Status Proposed...

  3. Flat Water Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Water Wind Farm Jump to: navigation, search Name Flat Water Wind Farm Facility Flat Water Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  4. Alkali metal protective garment and composite material

    DOE Patents [OSTI]

    Ballif, III, John L.; Yuan, Wei W.

    1980-01-01

    A protective garment and composite material providing satisfactory heat resistance and physical protection for articles and personnel exposed to hot molten alkali metals, such as sodium. Physical protection is provided by a continuous layer of nickel foil. Heat resistance is provided by an underlying backing layer of thermal insulation. Overlying outer layers of fireproof woven ceramic fibers are used to protect the foil during storage and handling.

  5. DOE - Office of Legacy Management -- Rocky Flats External Resources

    Office of Legacy Management (LM)

    Rocky Flats Site, Colorado External Resources Rocky Flats Stewardship Council Disclaimer Rocky Flats Cold War Museum Disclaimer U.S. Fish and Wildlife Service Rocky Flats National ...

  6. Revegetation of the Rocky Flats Site | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Revegetation of the Rocky Flats Site Revegetation of the Rocky Flats Site Revegetation of the Rocky Flats, Colorado Site PDF icon Revegetation of the Rocky Flats Site More...

  7. Method for the safe disposal of alkali metal

    DOE Patents [OSTI]

    Johnson, Terry R.

    1977-01-01

    Alkali metals such as those employed in liquid metal coolant systems can be safely reacted to form hydroxides by first dissolving the alkali metal in relatively inert metals such as lead or bismuth. The alloy thus formed is contacted with a molten salt including the alkali metal hydroxide and possibly the alkali metal carbonate in the presence of oxygen. This oxidizes the alkali metal to an oxide which is soluble within the molten salt. The salt is separated and contacted with steam or steam-CO.sub.2 mixture to convert the alkali metal oxide to the hydroxide. These reactions can be conducted with minimal hydrogen evolution and with the heat of reaction distributed between the several reaction steps.

  8. Jidong Chlorine and Alkali Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Place: Tangshan, Hebei Province, China Zip: 63021 Sector: Hydro Product: Chinese chemical products manufacturer whose products including chlorine, alkali, hydrochloric acid...

  9. Electrochemical devices utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Hitchcock, David C.; Mailhe, Catherine C.; De Jonghe, Lutgard C.

    1986-01-01

    Electrochemical cells are provided with a reactive metal to reduce the oxide of the alkali metal electrode-reactant. Cells employing a molten alkali metal electrode, e.g., sodium, in contact with a ceramic electrolyte, which is a conductor of the ions of the alkali metal forming the electrode, exhibit a lower resistance when a reactive metal, e.g., vanadium, is allowed to react with and reduce the alkali metal oxide. Such cells exhibit less degradation of the electrolyte and of the glass seals often used to joining the electrolyte to the other components of the cell under cycling conditions.

  10. Diode-Pumped Alkali Laser: A New Combination

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser-Compton Light Source Technology Short-Pulse Lasers High-Powered Lasers Journal Articles home science photon science directed energy Diode-Pumped Alkali Laser: A ...

  11. Effect of furnace operating conditions on alkali vaporization...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ALKALI METALS; EVAPORATION; FURNACES; ...

  12. Electrochemical devices utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Hitchcock, D.C.; Mailhe, C.C.; De Jonghe, L.C.

    1985-07-10

    Electrochemical cells are provided with a reactive metal to reduce the oxide of the alkali metal electrode-reactant. Cells employing a molten alkali metal electrode, e.g., sodium, in contact with a ceramic electrolyte, which is a conductor of the ions of the alkali metal forming the electrode, exhibit a lower resistance when a reactive metal, e.g., vanadium, is allowed to react with and reduce the alkali metal oxide. Such cells exhibit less degradation of the electrolyte and of the glass seals often used to joining the electrolyte to the other components of the cell under cycling conditions.

  13. Evaluation of alkali concentration in conditions relevant to...

    Office of Scientific and Technical Information (OSTI)

    Conference: Evaluation of alkali concentration in conditions relevant to oxygennatural gas glass furnaces by laser-induced breakdown spectroscopy. Citation Details In-Document ...

  14. Cathode architectures for alkali metal / oxygen batteries

    SciTech Connect (OSTI)

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  15. COMPLEX FLUORIDES OF PLUTONIUM AND AN ALKALI METAL

    DOE Patents [OSTI]

    Seaborg, G.T.

    1960-08-01

    A method is given for precipitating alkali metal plutonium fluorides. such as KPuF/sub 5/, KPu/sub 2/F/sub 9/, NaPuF/sub 5/, and RbPuF/sub 5/, from an aqueous plutonium(IV) solution by adding hydrogen fluoride and alkali-metal- fluoride.

  16. Recovery of alkali metal constituents from catalytic coal conversion residues

    DOE Patents [OSTI]

    Soung, Wen Y.

    1984-01-01

    In a coal gasification operation (32) or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by contacting them (46, 53, 61, 69) with water or an aqueous solution to remove water-soluble alkali metal constituents and produce an aqueous solution enriched in said constituents. The aqueous solution thus produced is then contacted with carbon dioxide (63) to precipitate silicon constituents, the pH of the resultant solution is increased (81), preferably to a value in the range between about 12.5 and about 15.0, and the solution of increased pH is evaporated (84) to increase the alkali metal concentration. The concentrated aqueous solution is then recycled to the conversion process (86, 18, 17) where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  17. Graphene folding on flat substrates

    SciTech Connect (OSTI)

    Chen, Xiaoming; Zhao, Yadong; Ke, Changhong; Zhang, Liuyang; Wang, Xianqiao

    2014-10-28

    We present a combined experimental-theoretical study of graphene folding on flat substrates. The structure and deformation of the folded graphene sheet are experimentally characterized by atomic force microscopy. The local graphene folding behaviors are interpreted based on nonlinear continuum mechanics modeling and molecular dynamics simulations. Our study on self-folding of a trilayer graphene sheet reports a bending stiffness of about 6.57?eV, which is about four times the reported values for monolayer graphene. Our results reveal that an intriguing free sliding phenomenon occurs at the interlayer van der Waals interfaces during the graphene folding process. This work demonstrates that it is a plausible venue to quantify the bending stiffness of graphene based on its self-folding conformation on flat substrates. The findings reported in this work are useful to a better understanding of the mechanical properties of graphene and in the pursuit of its applications.

  18. Corrugated cover plate for flat plate collector

    DOE Patents [OSTI]

    Hollands, K. G. Terry; Sibbitt, Bruce

    1978-01-01

    A flat plate radiant energy collector is providing having a transparent cover. The cover has a V-corrugated shape which reduces the amount of energy reflected by the cover away from the flat plate absorber of the collector.

  19. Residue management at Rocky Flats

    SciTech Connect (OSTI)

    Olencz, J.

    1995-12-31

    Past plutonium production and manufacturing operations conducted at the Rocky Flats Environmental Technology Site (RFETS) produced a variety of plutonium-contaminated by-product materials. Residues are a category of these materials and were categorized as {open_quotes}materials in-process{close_quotes} to be recovered due to their inherent plutonium concentrations. In 1989 all RFETS plutonium production and manufacturing operations were curtailed. This report describes the management of plutonium bearing liquid and solid wastes.

  20. Flat space physics from holography

    SciTech Connect (OSTI)

    Bousso, Raphael

    2004-02-06

    We point out that aspects of quantum mechanics can be derived from the holographic principle, using only a perturbative limit of classical general relativity. In flat space, the covariant entropy bound reduces to the Bekenstein bound. The latter does not contain Newton's constant and cannot operate via gravitational backreaction. Instead, it is protected by--and in this sense, predicts--the Heisenberg uncertainty principle.

  1. Controlled in-situ dissolution of an alkali metal

    DOE Patents [OSTI]

    Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

    2012-09-11

    A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

  2. Independent Oversight Special Review, Rocky Flats Closure Project...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Closure Project Site - April 2001 Independent Oversight Special Review, Rocky Flats Closure Project Site - April 2001 April 2001 Special Review of the Rocky Flats...

  3. ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 | Department of Energy

    Energy Savers [EERE]

    AUG 2006 ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 PDF icon Rocky Flats Closure Project-Lessons Learned-August 2006.pdf More Documents & Publications Rocky Flats Overview...

  4. Increasing Class C fly ash reduces alkali silica reactivity

    SciTech Connect (OSTI)

    Hicks, J.K.

    2007-07-01

    Contrary to earlier studies, it has been found that incremental additions of Class C fly ash do reduce alkali silica reactivity (ASR), in highly reactive, high alkali concrete mixes. AST can be further reduced by substituting 5% metakaolin or silica fume for the aggregate in concrete mixes with high (more than 30%) Class C fly ash substitution. The paper reports results of studies using Class C fly ash from the Labadie Station plant in Missouri which typically has between 1.3 and 1.45% available alkalis by ASTM C311. 7 figs.

  5. Electrochemical cell utilizing molten alkali metal electrode-reactant

    DOE Patents [OSTI]

    Virkar, Anil V.; Miller, Gerald R.

    1983-11-04

    An improved electrochemical cell comprising an additive-modified molten alkali metal electrode-reactant and/or electrolyte is disclosed. Various electrochemical cells employing a molten alkali metal, e.g., sodium, electrode in contact with a cationically conductive ceramic membrane experience a lower resistance and a lower temperature coefficient of resistance whenever small amounts of selenium are present at the interface of the electrolyte and the molten alkali metal. Further, cells having small amounts of selenium present at the electrolyte-molten metal interface exhibit less degradation of the electrolyte under long term cycling conditions.

  6. IBM's New Flat Panel Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by J. Stöhr (SSRL), M. Samant (IBM), J. Lüning (SSRL) Today's laptop computers utilize flat panel displays where the light transmission from the back to the front of the display is modulated by orientation changes in liquid crystal (LC) molecules. Details are discussed in Ref. 2 below. One of the key steps in the manufacture of the displays is the alignment of the LC molecules in the display. Today this is done by mechanical rubbing of two polymer surfaces and then sandwiching the LC between

  7. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, Marca M.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard

    1995-01-01

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  8. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or...

  9. Method for intercalating alkali metal ions into carbon electrodes

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1995-08-22

    A low cost, relatively flexible, carbon electrode for use in a secondary battery is described. A method is provided for producing same, including intercalating alkali metal salts such as sodium and lithium into carbon.

  10. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons.

  11. Electrochemical cell having an alkali-metal-nitrate electrode

    DOE Patents [OSTI]

    Roche, M.F.; Preto, S.K.

    1982-06-04

    A power-producing secondary electrochemical cell includes a molten alkali metal as the negative-electrode material and a molten-nitrate salt as the positive-electrode material. The molten material in the respective electrodes are separated by a solid barrier of alkali-metal-ion conducting material. A typical cell includes active materials of molten sodium separated from molten sodium nitrate and other nitrates in mixture by a layer of sodium ..beta..'' alumina.

  12. Solvation Structure and Transport Properties of Alkali Cations in Dimethyl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sulfoxide Under Exogenous Static Electric Fields - Joint Center for Energy Storage Research June 14, 2015, Research Highlights Solvation Structure and Transport Properties of Alkali Cations in Dimethyl Sulfoxide Under Exogenous Static Electric Fields Top: Snapshots of molecular dynamics simulations of alkali ions in DMSO at 298 K and zero-applied electric field: (left) Li+ and (right) Cs+. Sulfur atoms are shown in yellow, oxygen atoms in red, and methyl groups in gray. Graph: Average

  13. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Characterization of Selective Binding of Alkali Cations with Carboxylate Print Wednesday, 24 September 2008 00:00 During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of

  14. Closing Rocky Flats by 2006

    SciTech Connect (OSTI)

    Tuor, N. R.; Schubert, A. L.

    2002-02-26

    Safely accelerating the closure of Rocky Flats to 2006 is a goal shared by many: the State of Colorado, the communities surrounding the site, the U.S. Congress, the Department of Energy, Kaiser-Hill and its team of subcontractors, the site's employees, and taxpayers across the country. On June 30, 2000, Kaiser-Hill (KH) submitted to the Department of Energy (DOE), KH's plan to achieve closure of Rocky Flats by December 15, 2006, for a remaining cost of $3.96 billion (February 1, 2000, to December 15, 2006). The Closure Project Baseline (CPB) is the detailed project plan for accomplishing this ambitious closure goal. This paper will provide a status report on the progress being made toward the closure goal. This paper will: provide a summary of the closure contract completion criteria; give the current cost and schedule variance of the project and the status of key activities; detail important accomplishments of the past year; and discuss the challenges ahead.

  15. Alkali metal yttrium neo-pentoxide double alkoxide precursors to alkali metal yttrium oxide nanomaterials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boyle, Timothy J.; Neville, Michael L.; Sears, Jeremiah Matthew; Cramer, Roger

    2016-03-15

    In this study, a series of alkali metal yttrium neo-pentoxide ([AY(ONep)4]) compounds were developed as precursors to alkali yttrium oxide (AYO2) nanomaterials. The reaction of yttrium amide ([Y(NR2)3] where R=Si(CH3)3) with four equivalents of H-ONep followed by addition of [A(NR2)] (A=Li, Na, K) or Ao (Ao=Rb, Cs) led to the formation of a complex series of AnY(ONep)3+n species, crystallographically identified as [Y2Li3(μ3-ONep)(μ3-HONep)(μ-ONep)5(ONep)3(HONep)2] (1), [YNa2(μ3-ONep)4(ONep)]2 (2), {[Y2K3(μ3-ONep)3(μ-ONep)4(ONep)2(ηξ-tol)2][Y4K2(μ4-O)(μ3-ONep)8(ONep)4]•ηx-tol]} (3), [Y4K2(μ4-O)(μ3-ONep)8(ONep)4] (3a), [Y2Rb3(μ4-ONep)3(μ-ONep)6] (4), and [Y2Cs4(μ6-O)(μ3-ONep)6(μ3-HONep)2(ONep)2(ηx-tol)4]•tol (5). Compounds 1–5 were investigated as single source precursors to AYOx nanomaterials following solvothermal routes (pyridine, 185 °C for 24h). The final products after thermal processing weremore » found by powder X-ray diffraction experiments to be Y2O3 with variable sized particles based on transmission electron diffraction. Energy dispersive X-ray spectroscopy studies indicated that the heavier alkali metal species were present in the isolated nanomaterials.« less

  16. Two-phase alkali-metal experiments in reduced gravity

    SciTech Connect (OSTI)

    Antoniak, Z.I.

    1986-06-01

    Future space missions envision the use of large nuclear reactors utilizing either a single or a two-phase alkali-metal working fluid. The design and analysis of such reactors require state-of-the-art computer codes that can properly treat alkali-metal flow and heat transfer in a reduced-gravity environment. A literature search of relevant experiments in reduced gravity is reported on here, and reveals a paucity of data for such correlations. The few ongoing experiments in reduced gravity are noted. General plans are put forth for the reduced-gravity experiments which will have to be performed, at NASA facilities, with benign fluids. A similar situation exists regarding two-phase alkali-metal flow and heat transfer, even in normal gravity. Existing data are conflicting and indequate for the task of modeling a space reactor using a two-phase alkali-metal coolant. The major features of past experiments are described here. Data from the reduced-gravity experiments with innocuous fluids are to be combined with normal gravity data from the two-phase alkali-metal experiments. Analyses undertaken here give every expectation that the correlations developed from this data base will provide a valid representation of alkali-metal heat transfer and pressure drop in reduced gravity.

  17. Independent Oversight Review, Rocky Flats Environmental Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of the Rocky Flats Environmental Technology Site Transportation Emergency Management Program This report provides the results of an independent review of the Transportation ...

  18. Stable Flats LLC | Open Energy Information

    Open Energy Info (EERE)

    to build the first multi-family LEED (Leadership in Energy & Environmental Design) Gold certified structure in the country. References: Stable Flats LLC1 This article is a...

  19. Rocky Flats beryllium health surveillance

    SciTech Connect (OSTI)

    Stange, A.W.; Furman, F.J.; Hilmas, D.E.

    1996-10-01

    The Rocky Flats Beryllium Health Surveillance Program (BHSP), initiated in June 1991, was designed to provide medical surveillance for current and former employees exposed to beryllium. The BHSP identifies individuals who have developed beryllium sensitivity using the beryllium lymphocyte proliferation test (BeLPT). A detailed medical evaluation to determine the prevalence of chronic beryllium disease (CBD) is offered to individuals identified as beryllium sensitized or to those who have chest X-ray changes suggestive of CBD. The BHSP has identified 27 cases of CBD and another 74 cases of beryllium sensitization out of 4268 individuals tested. The distribution of BeLPT values for normal, sensitized, and CBD-identified individuals is described. Based on the information collected during the first 3 1/3 years of the BHSP, the BeLPT is the most effective means for the early identification of beryllium-sensitized individuals and to identify individuals who may have CBD. The need for BeLPT retesting is demonstrated through the identification of beryllium sensitization in individuals who previously tested normal. Posterior/anterior chest X-rays were not effective in the identification of CBD. 12 refs., 8 tabs.

  20. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  1. Magnetic states of the two-leg-ladder alkali metal iron selenides...

    Office of Scientific and Technical Information (OSTI)

    states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Prev Next Title: Magnetic states of the two-leg-ladder alkali metal iron selenides AFe2Se3 Authors: Luo, ...

  2. Ternary alkali-metal and transition metal or metalloid acetylides as alkali-metal intercalation electrodes for batteries

    DOE Patents [OSTI]

    Nemeth, Karoly; Srajer, George; Harkay, Katherine C; Terdik, Joseph Z

    2015-02-10

    Novel intercalation electrode materials including ternary acetylides of chemical formula: A.sub.nMC.sub.2 where A is alkali or alkaline-earth element; M is transition metal or metalloid element; C.sub.2 is reference to the acetylide ion; n is an integer that is 0, 1, 2, 3 or 4 when A is alkali element and 0, 1, or 2 when A is alkaline-earth element. The alkali elements are Lithium (Li), Sodium (Na), Potassium (K), Rubidium (Rb), Cesium (Cs) and Francium (Fr). The alkaline-earth elements are Berilium (Be), Magnesium (Mg), Calcium (Ca), Strontium (Sr), Barium (Ba), and Radium (Ra). M is a transition metal that is any element in groups 3 through 12 inclusive on the Periodic Table of Elements (elements 21 (Sc) to element 30 (Zn)). In another exemplary embodiment, M is a metalloid element.

  3. Rocky Flats ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Winstead, M.L.

    1995-09-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

  4. Windy Flats(3Q09 portion) | Open Energy Information

    Open Energy Info (EERE)

    Flats(3Q09 portion) Jump to: navigation, search Name Windy Flats(3Q09 portion) Facility Windy Flats(3Q09 portion) Sector Wind energy Facility Type Commercial Scale Wind Facility...

  5. ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 ROCKY FLATS CLOSURE PROJECT EM, AUG 2006 PDF icon Rocky Flats Closure Project-Lessons Learned-August 2006.pdf More Documents & Publications...

  6. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, P.E.; Bell, J.E.; Harlow, R.A.; Chase, G.G.

    1983-03-01

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed there between. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants there through at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed there between. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal there between. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal. 4 figs.

  7. Method of assembling and sealing an alkali metal battery

    DOE Patents [OSTI]

    Elkins, Perry E.; Bell, Jerry E.; Harlow, Richard A.; Chase, Gordon G.

    1983-01-01

    A method of initially assembling and then subsequently hermetically sealing a container portion of an alkali metal battery to a ceramic portion of such a battery is disclosed. Sealing surfaces are formed respectively on a container portion and a ceramic portion of an alkali metal battery. These sealing surfaces are brought into juxtaposition and a material is interposed therebetween. This interposed material is one which will diffuse into sealing relationship with both the container portion and the ceramic portion of the alkali metal battery at operational temperatures of such a battery. A pressure is applied between these sealing surfaces to cause the interposed material to be brought into intimate physical contact with such juxtaposed surfaces. A temporary sealing material which will provide a seal against a flow of alkali metal battery reactants therethrough at room temperatures and is applied over the juxtaposed sealing surfaces and material interposed therebetween. The entire assembly is heated to an operational temperature so that the interposed material diffuses into the container portion and the ceramic portion to form a hermetic seal therebetween. The pressure applied to the juxtaposed sealing surfaces is maintained in order to ensure the continuation of the hermetic seal.

  8. High capacity nickel battery material doped with alkali metal cations

    DOE Patents [OSTI]

    Jackovitz, John F.; Pantier, Earl A.

    1982-05-18

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  9. Modeling of alkali aggregate reaction effects in concrete dams

    SciTech Connect (OSTI)

    Capra, B.; Bournazel, J.P.; Bourdarot, E.

    1995-12-31

    Alkali Aggregate Reactions (AAR) are difficult to model due to the random distribution of the reactive sites and the imperfect knowledge of these chemical reactions. A new approach, using fracture mechanics and probabilities, capable to describe the anisotropic swelling of a structure is presented.

  10. PVC waterproofing membranes and alkali-aggregated reaction in dams

    SciTech Connect (OSTI)

    Scuero, A.M.

    1995-12-31

    A waterproofing polyvinylchloride (PVC) based geocomposite was installed on two dams subject to alkali-aggregate reaction, to eliminate water intrusion and to protect the facing from further deterioration. The installation system allows drainage of the infiltrated water, thus accomplishing dehydration of the dam body. On one dam, the membrane also provided protection for future slot cutting.

  11. Landfill Cover Revegetation at the Rocky Flats Environmental Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Site | Department of Energy Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site Landfill Cover Revegetation at the Rocky Flats Environmental Technology Site (507.34 KB) More Documents & Publications Revegetation of the Rocky Flats Site Smooth Brome Monitoring at Rocky Flats-2005 Results EIS-0285-SA-134:

  12. Microsoft Word - TurtleFlats_CX

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Turtle Flats Property Acquisition Funding Fish and Wildlife Project No.: 2011-003-00, ... This is part of BPA's ongoing efforts to mitigate for the impacts to fish and wildlife ...

  13. Rocky Flats Ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Funston, G.A.

    1995-06-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. The test will provide information to determine charge sizes, soak times and mesh screen sizes (if available at time of test) for stabilization of Rocky Flats Ash items to be processed in the HC-21C Muffle Furnace Process. Once the charge size and soak times have been established, a program for the temperature controller of the HC-21C Muffle Furnace process will be generated for processing Rocky Flats Ash.

  14. Rocky Flats resumes shipments to WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rocky Flats Resumes Shipments to WIPP CARLSBAD, N.M., March 11, 2000 - The U.S. Department of Energy (DOE) has resumed transuranic radioactive waste shipments from DOE's Rocky Flats Environmental Technology Site (RFETS) to the Waste Isolation Pilot Plant (WIPP). A shipment consisting of 28 drums of transuranic waste today arrived safely at WIPP at 5:07 p.m. (Mountain Standard Time). The truck, carrying two TRUPACT-II (Transuranic Packaging Transporter Model II) shipping containers, departed

  15. Flat panel ferroelectric electron emission display system

    DOE Patents [OSTI]

    Sampayan, Stephen E.; Orvis, William J.; Caporaso, George J.; Wieskamp, Ted F.

    1996-01-01

    A device which can produce a bright, raster scanned or non-raster scanned image from a flat panel. Unlike many flat panel technologies, this device does not require ambient light or auxiliary illumination for viewing the image. Rather, this device relies on electrons emitted from a ferroelectric emitter impinging on a phosphor. This device takes advantage of a new electron emitter technology which emits electrons with significant kinetic energy and beam current density.

  16. Flat panel ferroelectric electron emission display system

    DOE Patents [OSTI]

    Sampayan, S.E.; Orvis, W.J.; Caporaso, G.J.; Wieskamp, T.F.

    1996-04-16

    A device is disclosed which can produce a bright, raster scanned or non-raster scanned image from a flat panel. Unlike many flat panel technologies, this device does not require ambient light or auxiliary illumination for viewing the image. Rather, this device relies on electrons emitted from a ferroelectric emitter impinging on a phosphor. This device takes advantage of a new electron emitter technology which emits electrons with significant kinetic energy and beam current density. 6 figs.

  17. Rocky Flats Environmental Technology Site Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky ...

  18. Preliminary Notice of Violation , Rocky Flats Environmental Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Violation , Rocky Flats Environmental Technology Site - EA-96-05 Preliminary Notice of Violation , Rocky Flats Environmental Technology Site - EA-96-05 October 7, 1996 Preliminary...

  19. LM Records Handling System (LMRHS01) - Rocky Flats Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy ...

  20. Procedure for measuring the solar reflectance of flat or curved...

    Office of Scientific and Technical Information (OSTI)

    Procedure for measuring the solar reflectance of flat or curved roofing assemblies Citation Details In-Document Search Title: Procedure for measuring the solar reflectance of flat ...

  1. DOE - Office of Legacy Management -- Rocky Flats Archive

    Office of Legacy Management (LM)

    ... Memorandum Regarding Instrumentation and Monitoring at the Rocky Flats OLF Appendix F Solar-Powered Air Stripping at the Rocky Flats Site, Colorado Appendix G RFLMA Contact ...

  2. Rocky Flats Site Expands Solar Power for Treating Groundwater...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Site Expands Solar Power for Treating Groundwater Rocky Flats Site Expands Solar Power for Treating Groundwater April 17, 2013 - 1:26pm Addthis Subcontractor personnel ...

  3. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W.

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  4. Rocky Flats Compliance Program; Technology summary

    SciTech Connect (OSTI)

    1994-02-01

    The Department of Energy (DOE) established the Office of Technology Development (EM-50) (OTD) as an element of Environmental Restoration and Waste Management (EM) in November 1989. The primary objective of the Office of Technology Development, Rocky Flats Compliance Program (RFCP), is to develop altemative treatment technologies for mixed low-level waste (wastes containing both hazardous and radioactive components) to use in bringing the Rocky Flats Plant (RFP) into compliance with Federal and state regulations and agreements. Approximately 48,000 cubic feet of untreated low-level mixed waste, for which treatment has not been specified, are stored at the RFP. The cleanup of the Rocky Flats site is driven by agreements between DOE, the Environmental Protection Agency (EPA), and the Colorado Department of Health (CDH). Under these agreements, a Comprehensive Treatment and Management Plan (CTMP) was drafted to outline the mechanisms by which RFP will achieve compliance with the regulations and agreements. This document describes DOE`s strategy to treat low-level mixed waste to meet Land Disposal Restrictions and sets specific milestones related to the regulatory aspects of technology development. These milestones detail schedules for the development of technologies to treat all of the mixed wastes at the RFP. Under the Federal Facilities Compliance Act (FFCA), the CTMP has been incorporated into Rocky Flats Plant Conceptual Site Treatment Plan (CSTP). The CSTP will become the Rocky Flats Plant site Treatment Plan in 1995 and will supersede the CTMP.

  5. An improved method for flat-field correction of flat panel x-ray detector

    SciTech Connect (OSTI)

    Kwan, Alexander L.C.; Seibert, J. Anthony; Boone, John M.

    2006-02-15

    In this Technical Note, the effects of different flat-field techniques are examined for a cesium iodide flat panel detector, which exhibited a slightly nonlinear exposure response. The results indicate that the variable flat-field correction method with the appropriate polynomial fit provides excellent correction throughout the entire exposure range. The averaged normalized variation factor, used to assess the nonuniformity of the flat-field correction, decreased from 30.76 for the fixed correction method to 4.13 for the variable flat-field correction method with a fourth-order polynomial fit for the 60 kVp spectrum, and from 16.42 to 3.97 for the 95 kVp spectrum.

  6. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel,

  7. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel,

  8. Lithological influence of aggregate in the alkali-carbonate reaction

    SciTech Connect (OSTI)

    Lopez-Buendia, A.M. . E-mail: angel.lopez@aidico.es; Climent, V. . E-mail: vcliment@grupogla.com; Verdu, P.

    2006-08-15

    The reactivity of carbonate rock with the alkali content of cement, commonly called alkali-carbonate reaction (ACR), has been investigated. Alkali-silica reaction (ASR) can also contribute in the alkali-aggregate reaction (AAR) in carbonate rock, mainly due to micro- and crypto-crystalline quartz or clay content in carbonate aggregate. Both ACR and ASR can occur in the same system, as has been also evidenced on this paper. Carbonate aggregate samples were selected using lithological reactivity criteria, taking into account the presence of dedolomitization, partial dolomitization, micro- and crypto-crystalline quartz. Selected rocks include calcitic dolostone with chert (CDX), calcitic dolostone with dedolomitization (CDD), limestone with chert (LX), marly calcitic dolostone with partial dolomitization (CD), high-porosity ferric dolostone with clays (FD). To evaluate the reactivity, aggregates were studied using expansion tests following RILEM AAR-2, AAR-5, a modification using LiOH AAR-5Li was also tested. A complementary study was done using petrographic monitoring with polarised light microscopy on aggregates immersed in NaOH and LiOH solutions after different ages. SEM-EDAX has been used to identify the presence of brucite as a product of dedolomitization. An ACR reaction showed shrinkage of the mortar bars in alkaline solutions explained by induced dedolomitization, while an ASR process typically displayed expansion. Neither shrinkage nor expansion was observed when mortar bars were immersed in solutions of lithium hydroxide. Carbonate aggregate classification with AAR pathology risk has been elaborated based on mechanical behaviours by expansion and shrinkage. It is proposed to be used as a petrographic method for AAR diagnosis to complement the RILEM AAR1 specifically for carbonate aggregate. Aggregate materials can be classified as I (non-reactive), II (potentially reactive), and III (probably reactive), considering induced dedolomitization ACR

  9. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  10. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  11. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  12. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  13. Characterization of Selective Binding of Alkali Cations with Carboxylate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Selective Binding of Alkali Cations with Carboxylate Print During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions

  14. Solid waste recycling programs at Rocky Flats

    SciTech Connect (OSTI)

    Millette, R.L.; Blackman, T.E.; Shepard, M.D.

    1994-12-31

    The Rocky Flats (RFP) recycling programs for solid waste materials have been in place for over ten years. Within the last three years, the programs were centralized under the direction of the Rocky Flats Waste Minimization department, with the assistance of various plant organizations (e.g., Trucking, Building Services, Regulated Waste Operations, property Utilization and Disposal and Security). Waste Minimization designs collection and transportation systems for recyclable materials and evaluates recycling markets for opportunities to add new commodities to the existing programs. The Waste Minimization department also promotes employee participation in the Rocky Flats Recycling Programs, and collects all recycling data for publication. A description of the program status as of January 1994 is given.

  15. Chemical tracking at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Costain, D.B.

    1994-04-01

    EG&G Rocky Flats, Inc., has developed a chemical tracking system to support compliance with the Emergency Planning and community Right-to-Know Act (EPCRA) at the Rocky Flats Plant. This system, referred to as the EPCRA Chemical Control system (ECCS), uses bar code technology to uniquely identify and track the receipt, distribution, and use of chemicals. Chemical inventories are conducted using hand-held electronic scanners to update a site wide chemical database on a VAX 6000 computer. Information from the ECCS supports preparation of the EPCRA Tier II and Form R reports on chemical storage and use.

  16. Issues evaluation process at Rocky Flats Plant

    SciTech Connect (OSTI)

    Smith, L.C.

    1992-04-16

    This report describes the issues evaluation process for Rocky Flats Plant as established in July 1990. The issues evaluation process was initiated February 27, 1990 with a Charter and Process Overview for short-term implementation. The purpose of the process was to determine the projects required for completion before the Phased Resumption of Plutonium Operations. To determine which projects were required, the issues evaluation process and emphasized risk mitigation, based on a ranking system. The purpose of this report is to document the early design of the issues evaluation process to record the methodologies used that continue as the basis for the ongoing Issues Management Program at Rocky Flats Plant.

  17. Neal Lane: Science in a Flat World

    SciTech Connect (OSTI)

    Neal Lane

    2006-09-12

    Lane discusses the changes that have taken place in the world since World War II that have made it "flatter," referring to Thomas L. Friedman's book, The World is Flat. Friedman's main premise is that inexpensive telecommunications is bringing about unhampered international competition, the demise of economic stability, and a trend toward outsourcing services, such as computer programming, engineering and science research.

  18. Neal Lane: Science in a Flat World

    ScienceCinema (OSTI)

    Neal Lane

    2010-09-01

    Lane discusses the changes that have taken place in the world since World War II that have made it "flatter," referring to Thomas L. Friedman's book, The World is Flat. Friedman's main premise is that inexpensive telecommunications is bringing about unhampered international competition, the demise of economic stability, and a trend toward outsourcing services, such as computer programming, engineering and science research.

  19. Crystallized alkali-silica gel in concrete from the late 1890s

    SciTech Connect (OSTI)

    Peterson, Karl . E-mail: cee@mtu.edu; Gress, David . E-mail: dlgress@unh.edu; Van Dam, Tom . E-mail: cee@mtu.edu; Sutter, Lawrence . E-mail: cee@mtu.edu

    2006-08-15

    The Elon Farnsworth Battery, a concrete structure completed in 1898, is in an advanced state of disrepair. To investigate the potential for rehabilitation, cores were extracted from the battery. Petrographic examination revealed abundant deposits of alkali silica reaction products in cracks associated with the quartz rich metasedimentary coarse aggregate. The products of the alkali silica reaction are variable in composition and morphology, including both amorphous and crystalline phases. The crystalline alkali silica reaction products are characterized by quantitative X-ray energy dispersive spectrometry (EDX) and X-ray diffraction (XRD). The broad extent of the reactivity is likely due to elevated alkali levels in the cements used.

  20. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.; Franco, Sofia C. S.

    1994-01-01

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  1. Tuning of the Metal-Insulator Transition via Alkali Adsorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tulane University: 2016 Energy Expo Tulane University: 2016 Energy Expo September 9, 2016 9:00AM to 5:00PM EDT Location: 1200 Louisiana Street, Houston, TX 77002 Attendees: Morgan McKnight

    Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic

  2. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  3. Cubic Ionic Conductor Ceramics for Alkali Ion Batteries - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cuban Missile Crisis Cuban Missile Crisis Cuba Reconnaissance reveals Soviet missiles in Cuba. The United States blockades Cuba for 13 days until the Soviet Union agrees to remove its missiles Portal

    Advanced Materials Advanced Materials Find More Like This Return to Search Cubic Ionic Conductor Ceramics for Alkali Ion Batteries Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ionic conduction in cubic Na3TiP3O9N, a secondary Na-ion

  4. Release fractions for Rocky Flats specific accidents

    SciTech Connect (OSTI)

    Weiss, R.C.

    1992-09-01

    As Rocky Flats and other DOE facilities begin the transition process towards decommissioning, the nature of the scenarios to be studied in safety analysis will change. Whereas the previous emphasis in safety accidents related to production, now the emphasis is shifting to accidents related tc decommissioning and waste management. Accident scenarios of concern at Rocky Flats now include situations of a different nature and different scale than are represented by most of the existing experimental accident data. This presentation will discuss approaches@to use for applying the existing body of release fraction data to this new emphasis. Mention will also be made of ongoing efforts to produce new data and improve the understanding of physical mechanisms involved.

  5. Emergent universe in spatially flat cosmological model

    SciTech Connect (OSTI)

    Zhang, Kaituo; Yu, Hongwei; Wu, Puxun E-mail: wpx0227@gmail.com

    2014-01-01

    The scenario of an emergent universe provides a promising resolution to the big bang singularity in universes with positive or negative spatial curvature. It however remains unclear whether the scenario can be successfully implemented in a spatially flat universe which seems to be favored by present cosmological observations. In this paper, we study the stability of Einstein static state solutions in a spatially flat Shtanov-Sahni braneworld scenario. With a negative dark radiation term included and assuming a scalar field as the only matter energy component, we find that the universe can stay at an Einstein static state past eternally and then evolve to an inflation phase naturally as the scalar field climbs up its potential slowly. In addition, we also propose a concrete potential of the scalar field that realizes this scenario.

  6. Towards a flat 45%-efficient concentrator module

    SciTech Connect (OSTI)

    Mohedano, Rubén Hernandez, Maikel; Vilaplana, Juan; Chaves, Julio; Sorgato, S.; Falicoff, Waqidi; Miñano, Juan C.; Benitez, Pablo

    2015-09-28

    The so-called CCS{sup 4}FK is an ultra-flat photovoltaic system of high concentration and high efficiency, with potential to convert, ideally, the equivalent of a 45% of direct solar radiation into electricity by optimizing the usage of sun spectrum and by collecting part of the diffuse radiation, as a flat plate does. LPI has recently finished a design based on this concept and is now developing a prototype based on this technology, thanks to the support of FUNDACION REPSOL-Fondo de Emprendedores, which promotes entrepreneur projects in different areas linked to energy. This works shows some details of the actual design and preliminary potential performance expected, according to accurate spectral simulations.

  7. Final Transuranic Waste Shipment Leaves Rocky Flats | Department...

    Office of Environmental Management (EM)

    Transuranic Waste Shipment Leaves Rocky Flats Final Transuranic Waste Shipment Leaves Rocky Flats April 19, 2005 - 12:23pm Addthis Cleanup Ahead of Schedule, On Track to Save ...

  8. Salt Wells, Eight Mile Flat | Open Energy Information

    Open Energy Info (EERE)

    Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau...

  9. SLIDESHOW: Shepherds Flat Wind Farm | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shepherds Flat Wind Farm SLIDESHOW: Shepherds Flat Wind Farm Addthis 1 of 5 Image: Caithness Energy 2 of 5 Image: Caithness Energy 3 of 5 Image: Caithness Energy 4 of 5 Image: Caithness Energy 5 of 5 Image: Caithness Energy

  10. Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado, USA August 2010 Jody K. Nelson PDF icon Vascular Flora of the Rocky Flats Area, Jefferson County, Colorado, USA ...

  11. Sandia National Laboratories: Better flat-panel displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Facebook Twitter YouTube Flickr RSS News Better, brighter, cheaper flat-panel displays By ... colors and better images for flat-panel displays built from less expensive ...

  12. DOE - Office of Legacy Management -- Rocky Flats Regulatory Documents

    Office of Legacy Management (LM)

    Notification that GS01 is no longer an RFLMA Point of Compliance (POC) Third Five-Year Review Report for the Rocky Flats Site Rocky Flats Legacy Management Agreement Environmental ...

  13. An Alternative High Luminosity LHC with Flat Optics and Long...

    Office of Scientific and Technical Information (OSTI)

    LHC with Flat Optics and Long-Range Beam-Beam Compensation Citation Details In-Document Search Title: An Alternative High Luminosity LHC with Flat Optics and Long-Range ...

  14. An Alternative High Luminosity LHC with Flat Optics and Long...

    Office of Scientific and Technical Information (OSTI)

    with Flat Optics and Long-Range Beam-Beam Compensation Citation Details In-Document Search Title: An Alternative High Luminosity LHC with Flat Optics and Long-Range Beam-Beam ...

  15. Immobilization of Rocky Flats graphite fines residues

    SciTech Connect (OSTI)

    Rudisill, T.S.; Marra, J.C.; Peeler, D.K.

    1999-07-01

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt% graphite, 15 wt% calcium fluoride (CaF{sub 2}), and 12 wt% plutonium oxide (PuO{sub 2}). Approximately 950 kg of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO{sub 2} concentration in the residue averages 12 wt%, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF{sub 2} dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO{sub 2}) as a surrogate for PuO{sub 2} and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF{sub 2} and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.

  16. Status Update: Closing Rocky Flats by 2006

    SciTech Connect (OSTI)

    Tuor, N.; Schubert, A.

    2003-02-25

    Safely closing Rocky Flats by December 2006 is a goal shared by many: the State of Colorado, the communities surrounding the site, the U.S. Congress, the Department of Energy (DOE), Kaiser-Hill and its team of subcontractors, the site's employees and taxpayers across the country. This paper will: provide a status of the Closure Project to date; describe important accomplishments of the past year; describe some of the closure-enhancing technologies enabling acceleration; and discuss the remaining challenges ahead.

  17. Microwave solidification development for Rocky Flats waste

    SciTech Connect (OSTI)

    Dixon, D.; Erle, R.; Eschen, V.

    1994-04-01

    The Microwave Engineering Team at the Rocky Flats Plant has developed a production-scale system for the treatment of hazardous, radioactive, and mixed wastes using microwave energy. The system produces a vitreous final form which meets the acceptance criteria for shipment and disposal. The technology also has potential for application on various other waste streams from the public and private sectors. Technology transfer opportunities are being identified and pursued for commercialization of the microwave solidification technology.

  18. Basic TRUEX process for Rocky Flats Plant

    SciTech Connect (OSTI)

    Leonard, R.A.; Chamberlain, D.B.; Dow, J.A.; Farley, S.E.; Nunez, L.; Regalbuto, M.C.; Vandegrift, G.F.

    1994-08-01

    The Generic TRUEX Model was used to develop a TRUEX process flowsheet for recovering the transuranics (Pu, Am) from a nitrate waste stream at Rocky Flats Plant. The process was designed so that it is relatively insensitive to changes in process feed concentrations and flow rates. Related issues are considered, including solvent losses, feed analysis requirements, safety, and interaction with an evaporator system for nitric acid recycle.

  19. DOE - NNSA/NFO -- News & Views Frenchman Flat

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frenchman Flat Photo - Wooden bleachers at Yucca Flats Between January 27, 1951 and March 25, 1968 fourteen atmospheric and five underground tests were detonated at Frenchman Flat. The 320-square-kilometer (123-square-mile) dry lake bed is one of three major closed desert valley basins at the Nevada Test Site, the others being Yucca and Jackass Flats. From 1953 to 1958, reinforced structures were exposed to of nuclear blasts and accompanying overpressures. Among the items exposed to the blasts

  20. LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Database, Office of Legacy Management | Department of Energy Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management LM Records Handling System (LMRHS01) - Rocky Flats Environmental Records Database, Office of Legacy Management (470.9 KB) More Documents

  1. Independent Oversight Review, Rocky Flats Environmental Technology Site -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 2000 | Department of Energy Rocky Flats Environmental Technology Site - March 2000 Independent Oversight Review, Rocky Flats Environmental Technology Site - March 2000 March 2000 Review of the Rocky Flats Environmental Technology Site Transportation Emergency Management Program This report provides the results of an independent review of the Transportation Emergency Management Program at the Department of Energy's Rocky Flats Environmental Technology Site that was conducted by the

  2. Independent Oversight Special Review, Rocky Flats Closure Project Site -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 2001 | Department of Energy Rocky Flats Closure Project Site - April 2001 Independent Oversight Special Review, Rocky Flats Closure Project Site - April 2001 April 2001 Special Review of the Rocky Flats Closure Project Site This report provides the results of a Special Review at the Rocky Flats Closure Project that was performed U.S. Department of Energy's (DOE) Office of Independent Environment, Safety, and Health Oversight. The Special Review was conducted in February and March 2001

  3. Synthesis and studies on microhardness of alkali zinc borate glasses

    SciTech Connect (OSTI)

    Subhashini, Bhattacharya, Soumalya Shashikala, H. D. Udayashankar, N. K.

    2014-04-24

    The mixed alkali effect on zinc borate glasses have been reported. The glass systems of nominal composition 10Zn+xLi{sub 2}O+yNa{sub 2}O+80B{sub 2}O{sub 3} (x = y = 0, 5, 10, 15 mol%) were prepared using standard melt quenching method. The structural, physical and mechanical properties of the samples have been studied using X-ray diffraction(XRD), density measurement and Vickers hardness measurement, respectively. A consistent increase in the density was observed, which explains the role of the modifiers (Li{sub 2}O and Na{sub 2}O) in the network modification of borate structure. The molar volume is decreasing linearly with the alkali concentration, which is attributed to the conversion of tetrahedral boron (BO{sub 4/2}){sup −} into (BO{sub 3/2}){sup −}. The microhardness studies reveals the anisotropy nature of the material. It further confirms that the samples belong to hard glass category.

  4. Thermodynamic Properties Of Alkali Species In Coal Based Combined Cycle Power Systems

    SciTech Connect (OSTI)

    Willenborg, W.; Wolf, K.J.; Fricke, C.; Moeller, M.; Prikhodovsky, A.; Hilpert, K.; Singheiser, L.

    2002-09-20

    The aim of this project is to support the development of a concept for a successful alkali removal. Two strategies are possible: optimizing the alkali retention potential of the coal ash slag in the combustion chamber and the liquid slag separators and separate alkali removal with solid sorbents (getters) at temperatures below 1450 C. Therefore in a first step the alkali partial pressure over coal ash slag should be determined in order to get information about the retention potential of the slag. The influence of additives on the retention potential of the slag should be investigated. The measurements should show if the alkali partial pressure over the slag is generally low enough in case of thermodynamic equilibrium. In case of too high alkali partial pressures a separate alkali removal is needed. Therefore in a second step commercial sorbent materials should be investigated concerning their sorption potential for alkalis. To get information about the influence of getter components on the sorption potential some mixtures of pure components, predicted by thermodynamic modeling to be most effective, should be investigated.

  5. Repackaging Rocky Flats Legacy Transuranic Waste

    SciTech Connect (OSTI)

    McTaggart, Jerri Lynne

    2008-01-15

    Repackaging legacy Transuranic (TRU), Transuranic Mixed (TRM), Low Level Waste (LLW), and Low Level Mixed (LLM) waste requires good characterization skills and the ability to adapt to less than ideal conditions. Repackaging legacy waste in a facility that is not undergoing Decontamination and Decommission (D and D) is optimum. However, repackaging any waste in a D and D facility, under cold and dark conditions, can be difficult. Cold and dark conditions are when the heating and air conditioning are no longer in service and the lighting consists of strands of lights hung throughout each of the rooms. Working under these conditions adds an additional level of stress and danger that must be addressed. The use of glovebags was very useful at Rocky Flats during the D and D of many buildings. Glovebags can be adapted for many different types of wastes and unusual conditions. Repackaging of legacy TRU waste, in a D and D facility, can be accomplished safely and cost effectively with the use of glovebags. In conclusion: the use of glovebags to repackage legacy TRU, TRM, LLW, or LLM waste was done safely and cost effectively at Rocky Flats. The cost of using glovebags was minimal. Glovebags are easily adaptable to whatever the waste configuration is. The use of glovebags, for repackaging of Legacy waste, allows D and D efforts to stay on schedule and on task. Without the use of glovebags, additional gloveboxes would have been required at Rocky Flats. Larger items, such as the HEPA filters, would have required the construction of a new large item repackaging glovebox. Repackaging in glovebags allows the freedom to either locate the glovebag by the waste or locate the glovebag in a place that least impacts D and D efforts. The use of glovebags allowed numerous configurations of waste to be repackaged without the use of gloveboxes. During the D and D of the Rocky Flats facility, which was in a cold and dark stage, D and D work was not impacted by the repackaging activity

  6. Geometrical Wake of a Smooth Flat Collimator

    SciTech Connect (OSTI)

    Stupakov, G.V.; /SLAC

    2011-09-09

    A transverse geometrical wake generated by a beam passing through a smooth flat collimator with a gradually varying gap between the upper and lower walls is considered. Based on generalization of the approach recently developed for a smooth circular taper we reduce the electromagnetic problem of the impedance calculation to the solution of two much simpler static problems - a magnetostatic and an electrostatic ones. The solution shows that in the limit of not very large frequencies, the impedance increases with the ratio h/d where h is the width and d is the distance between the collimating jaws. Numerical results are presented for the NLC Post Linac collimator.

  7. Influence of lithium hydroxide on alkali-silica reaction

    SciTech Connect (OSTI)

    Bulteel, D.; Garcia-Diaz, E.; Degrugilliers, P.

    2010-04-15

    Several papers show that the use of lithium limits the development of alkali-silica reaction (ASR) in concrete. The aim of this study is to improve the understanding of lithium's role on the alteration mechanism of ASR. The approach used is a chemical method which allowed a quantitative measurement of the specific degree of reaction of ASR. The chemical concrete sub-system used, called model reactor, is composed of the main ASR reagents: reactive aggregate, portlandite and alkaline solution. Different reaction degrees are measured and compared for different alkaline solutions: NaOH, KOH and LiOH. Alteration by ASR is observed with the same reaction degrees in the presence of NaOH and KOH, accompanied by the consumption of hydroxyl concentration. On the other hand with LiOH, ASR is very limited. Reaction degree values evolve little and the hydroxyl concentration remains about stable. These observations demonstrate that lithium ions have an inhibitor role on ASR.

  8. Alkali-silica reaction and its effectes on concrete

    SciTech Connect (OSTI)

    Stark, D.

    1995-12-31

    Alkali-silica reactivity (ASR) has resulted in cracking of concrete in numerous dams in the United States and elsewhere. Many of these dams were constructed prior to the initial discovery of ASR in California in the late 1930`s, thus no special precautions could have been taken to prevent its development Since that time, ASR has been identified in all types of structures located in many parts of the world. Voluminous research has been carried out to better characterize its development, to more completely understand the mechanisms of expansion and distress, and to design means to mitigate its development in new and existing construction. Based on this work, this paper describes the nature of ASR, its effects on concrete, and means to control its development, with special reference to dams.

  9. 3718-F Alkali Metal Treatment and Storage Facility Closure Plan

    SciTech Connect (OSTI)

    1991-12-01

    Since 1987, Westinghouse Hanford Company has been a major contractor to the U.S. Department of Energy-Richland Operations Office and has served as co-operator of the 3718-F Alkali Metal Treatment and Storage Facility, the waste management unit addressed in this closure plan. The closure plan consists of a Part A Dangerous waste Permit Application and a RCRA Closure Plan. An explanation of the Part A Revision (Revision 1) submitted with this document is provided at the beginning of the Part A section. The closure plan consists of 9 chapters and 5 appendices. The chapters cover: introduction; facility description; process information; waste characteristics; groundwater; closure strategy and performance standards; closure activities; postclosure; and references.

  10. Vitrification of simulated radioactive Rocky Flats plutonium containing ash residue with a Stir Melter System

    SciTech Connect (OSTI)

    Marra, J.C.; Kormanyos, K.R.; Overcamp, T.J.

    1996-10-01

    A demonstration trial has been completed in which a simulated Rocky Flats ash consisting of an industrial fly-ash material doped with cerium oxide was vitrified in an alloy tank Stir-Melter{trademark} System. The cerium oxide served as a substitute for plutonium oxide present in the actual Rocky Flats residue stream. The glass developed falls within the SiO{sub 2} + Al{sub 2}O{sub 3}/{Sigma}Alkali/B{sub 2}O{sub 3} system. The glass batch contained approximately 40 wt% of ash, the ash was modified to contain {approximately} 5 wt% CeO{sub 2} to simulate plutonium chemistry in the glass. The ash simulant was mixed with water and fed to the Stir-Melter as a slurry with a 60 wt% water to 40 wt% solids ratio. Glass melting temperature was maintained at approximately 1,050 C during the melting trials. Melting rates as functions of impeller speed and slurry feed rate were determined. An optimal melting rate was established through a series of evolutionary variations of the control variables` settings. The optimal melting rate condition was used for a continuous six hour steady state run of the vitrification system. Glass mass flow rates of the melter were measured and correlated with the slurry feed mass flow. Melter off-gas was sampled for particulate and volatile species over a period of four hours during the steady state run. Glass composition and durability studies were run on samples collected during the steady state run.

  11. Risk, media, and stigma at Rocky Flats

    SciTech Connect (OSTI)

    Flynn, J.; Peters, E.; Mertz, C.K.; Slovic, P.

    1998-12-01

    Public responses to nuclear technologies are often strongly negative. Events, such as accidents or evidence of unsafe conditions at nuclear facilities, receive extensive and dramatic coverage by the news media. These news stories affect public perceptions of nuclear risks and the geographic areas near nuclear facilities. One result of these perceptions, avoidance behavior, is a form of technological stigma that leads to losses in property values near nuclear facilities. The social amplification of risk is a conceptual framework that attempts to explain how stigma is created through media transmission of information about hazardous places and public perceptions and decisions. This paper examines stigma associated with the US Department of energy`s Rocky Flats facility, a major production plant in the nation`s nuclear weapons complex, located near Denver, Colorado. This study, based upon newspaper analyses and a survey of Denver area residents, finds that the social amplification theory provides a reasonable framework for understanding the events and public responses that took place in regard to Rocky Flats during a 6-year period, beginning with an FBI raid of the facility in 1989.

  12. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S. . Rocky Flats Plant); Rivera, M.A. )

    1993-01-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  13. Disposal of Rocky Flats residues as waste

    SciTech Connect (OSTI)

    Dustin, D.F.; Sendelweck, V.S.; Rivera, M.A.

    1993-03-01

    Work is underway at the Rocky Flats Plant to evaluate alternatives for the removal of a large inventory of plutonium-contaminated residues from the plant. One alternative under consideration is to package the residues as transuranic wastes for ultimate shipment to the Waste Isolation Pilot Plant. Current waste acceptance criteria and transportation regulations require that approximately 1000 cubic yards of residues be repackaged to produce over 20,000 cubic yards of WIPP certified waste. The major regulatory drivers leading to this increase in waste volume are the fissile gram equivalent, surface radiation dose rate, and thermal power limits. In the interest of waste minimization, analyses have been conducted to determine, for each residue type, the controlling criterion leading to the volume increase, the impact of relaxing that criterion on subsequent waste volume, and the means by which rules changes may be implemented. The results of this study have identified the most appropriate changes to be proposed in regulatory requirements in order to minimize the costs of disposing of Rocky Flats residues as transuranic wastes.

  14. Immobilization of Rocky Flats Graphite Fines Residues

    SciTech Connect (OSTI)

    Rudisill, T. S.

    1998-11-06

    The Savannah River Technology Center (SRTC) is developing an immobilization process for graphite fines residues generated during nuclear materials production activities at the Rocky Flats Environmental Technology Site (Rocky Flats). The continued storage of this material has been identified as an item of concern. The residue was generated during the cleaning of graphite casting molds and potentially contains reactive plutonium metal. The average residue composition is 73 wt percent graphite, 15 wt percent calcium fluoride (CaF2), and 12 wt percent plutonium oxide (PuO2). Approximately 950 kilograms of this material are currently stored at Rocky Flats. The strategy of the immobilization process is to microencapsulate the residue by mixing with a sodium borosilicate (NBS) glass frit and heating at nominally 700 degrees C. The resulting waste form would be sent to the Waste Isolation Pilot Plant (WIPP) for disposal. Since the PuO2 concentration in the residue averages 12 wt percent, the immobilization process was required to meet the intent of safeguards termination criteria by limiting plutonium recoverability based on a test developed by Rocky Flats. The test required a plutonium recovery of less than 4 g/kg of waste form when a sample was leached using a nitric acid/CaF2 dissolution flowsheet. Immobilization experiments were performed using simulated graphite fines with cerium oxide (CeO2) as a surrogate for PuO2 and with actual graphite fines residues. Small-scale surrogate experiments demonstrated that a 4:1 frit to residue ratio was adequate to prevent recovery of greater than 4 g/kg of cerium from simulated waste forms. Additional experiments investigated the impact of varying concentrations of CaF2 and the temperature/heating time cycle on the cerium recovery. Optimal processing conditions developed during these experiments were subsequently demonstrated at full-scale with surrogate materials and on a smaller scale using actual graphite fines.In general, the

  15. A light water excess heat reaction suggests that cold fusion may be alkali-hydrogen fusion

    SciTech Connect (OSTI)

    Bush, R.T. )

    1992-09-01

    This paper reports that Mills and Kneizys presented data in support of a light water excess heat reaction obtained with an electrolytic cell highly reminiscent of the Fleischmann-Pons cold fusion cell. The claim of Mills and Kneizys that their excess heat reaction can be explained on the basis of a novel chemistry, which supposedly also explains cold fusion, is rejected in favor of their reaction being, instead, a light water cold fusion reaction. It is the first known light water cold fusion reaction to exhibit excess heat, it may serve as a prototype to expand our understanding of cold fusion. From this new reactions are deduced, including those common to past cold fusion studies. This broader pattern of nuclear reactions is typically seen to involve a fusion of the nuclides of the alkali atoms with the simplest of the alkali-type nuclides, namely, protons, deuterons, and tritons. Thus, the term alkali-hydrogen fusion seems appropriate for this new type of reaction with three subclasses: alkali-hydrogen fusion, alkali-deuterium fusion, and alkali-tritium fusion. A new three-dimensional transmission resonance model (TRM) is sketched. Finally, preliminary experimental evidence in support of the hypothesis of a light water nuclear reaction and alkali-hydrogen fusion is reported. Evidence is presented that appears to strongly implicate the transmission resonance phenomenon of the new TRM.

  16. Breakdown of ionic character of molecular alkali bromides in inner-valence photoionization

    SciTech Connect (OSTI)

    Karpenko, A. Iablonskyi, D.; Kettunen, J. A.; Cao, W.; Huttula, M.; Aksela, H.; Urpelainen, S.

    2014-05-28

    The inner-valence region of alkali bromide XBr (X=Li, Na, K, Rb) vapours has been studied experimentally by means of synchrotron radiation excited photoelectron spectroscopy. Experimental spectra were analyzed by comparing them with available theoretical results and previous experiments. Ionic character of alkali bromides is seen to change in the inner-valence region with increasing atomic number of the alkali atom. A mechanism involving mixing between Br 4s and Rb 4p orbitals has been suggested to account for the fine structure observed in inner-valence ionization region of RbBr.

  17. Flat minimal quantizations of Stckel systems and quantum separability

    SciTech Connect (OSTI)

    B?aszak, Maciej; Doma?ski, Ziemowit; Silindir, Burcu

    2014-12-15

    In this paper, we consider the problem of quantization of classical Stckel systems and the problem of separability of related quantum Hamiltonians. First, using the concept of Stckel transform, natural Hamiltonian systems from a given Riemann space are expressed by some flat coordinates of related Euclidean configuration space. Then, the so-called flat minimal quantization procedure is applied in order to construct an appropriate Hermitian operator in the respective Hilbert space. Finally, we distinguish a class of Stckel systems which remains separable after any of admissible flat minimal quantizations. - Highlights: Using Stckel transform, separable Hamiltonians are expressed by flat coordinates. The concept of admissible flat minimal quantizations is developed. The class of Stckel systems, separable after minimal flat quantization is established. Separability of related stationary Schrdinger equations is presented in explicit form.

  18. Rocky Flats Closure Unit Cost Data

    SciTech Connect (OSTI)

    Sanford, P.C.; Skokan, B.

    2007-07-01

    The Rocky Flats Closure Project has completed the process of stabilizing residual nuclear materials, decommissioning nuclear facilities, remediating environmental media and closing the Rocky Flats Site (Site). The project cost approximately $4.1 B and included the decommissioning of over 700 structures including 5 major plutonium facilities and 5 major uranium facilities, shipping over 14,600 cubic meters of transuranic and 565,000 cubic meters of low level radioactive waste, and remediating a 385-acre industrial area and the surrounding land. Actual costs were collected for a large variety of closure activities. These costs can be correlated with metrics associated with the facilities and environmental media to capture cost factors from the project that could be applicable to a variety of other closure projects both within and outside of the Department of Energy's weapons complex. The paper covers four general topics: the process to correlate the actual costs and metrics, an example of the correlated data for one large sub-project, a discussion of the results, and the additional activities that are planned to correlate and make this data available to the public. The process to collect and arrange the project control data of the Closure Project relied on the actual Closure Project cost information. It was used to correlate these actual costs with the metrics for the physical work, such as building area or waste generated, to support the development of parametric cost factors. The example provides cost factors for the Industrial Sites Project. The discussion addresses the strengths and weaknesses of the data, followed by a section identifying future activities to improve and extend the analyses and integrate it within the Department's Environmental Cost Analysis System. (authors)

  19. ELECTROLUMINESCENT MATERIAL FOR FLAT PANEL DISPLAY

    SciTech Connect (OSTI)

    Smith, D.B.

    2000-11-13

    The purpose of this Cooperative Research and Development Agreement (CRADA) was to develop a new-generation electroluminescent (EL) material for flat panel displays and related applications by using unique and complementary research capabilities at Oak Ridge National Laboratory and OSRAM Sylvania, Inc. The goal was to produce an EL material with a luminance 10 times greater than conventional EL phosphors. An EL material with this increased luminance would have immediate applications for flat panel display devices (e.g., backlighting for liquid-crystal diodes) and for EL lamp technology. OSRAM Sylvania proposed that increased EL phosphor luminance could be obtained by creating composite EL materials capable of alignment under an applied electric field and capable of concentrating the applied electric field. Oak Ridge National Laboratory used pulsed laser deposition as a method for making these composite EL materials. The materials were evaluated for electroluminescence at laboratory facilities at OSRAM Sylvania, Inc. Many composite structures were thus made and evaluated, and it was observed that a composite structure based on alternating layers of a ferroelectric and a phosphor yielded electroluminescence. An enabling step that was not initially proposed but was conceived during the cooperative effort was found to be crucial to the success of the composite structure. The CRADA period expired before we were able to make quantitative measurements of the luminance and efficiency of the composite EL material. Future cooperative work, outside the scope of the CRADA, will focus on making these measurements and will result in the production of a prototype composite EL device.

  20. 2006 Annual Ecology Report for the Rocky Flats Site

    Office of Legacy Management (LM)

    Ecology Report for the Rocky Flats Site Click on the links below to access different portions of the electronic annual report. 2006 Annual Report Sections Diffuse Knapweed...

  1. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance...

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site .........9 2.2.3 Solar Ponds Plume Treatment System ...

  2. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance...

    Office of Legacy Management (LM)

    left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site .........8 2.2.3 Solar Ponds Plume Treatment System ...

  3. Microsoft Word - RockyFlatsPropLR111406.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BACKGROUND Nuclear weapons production operations at Rocky Flats were discontinued in 1992. ... Department's Office of Defense Programs to the Office of Environmental Management. ...

  4. Big Flat Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Electric Coop Inc Jump to: navigation, search Name: Big Flat Electric Coop Inc Place: Montana Phone Number: 406-654-2040 Website: bigflatelectric.comindex.htm Outage Hotline:...

  5. Long-Term Surveillance and Maintenance at Rocky Flats: Early...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Overview EA-1747: Final Environmental Assessment The Use of Ecological Restoration Principles To Achieve Remedy Protection at the Fernald Preserve and Weldon Spring ...

  6. Big Flats, Wisconsin: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Big Flats, Wisconsin: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 44.111913, -89.8079032 Show Map Loading map... "minzoom":false,"mappingse...

  7. DOE - Office of Legacy Management -- Rocky Flats SOG

    Office of Legacy Management (LM)

    Guide Appendixes Appendix A: Annual Site Inspection Checklist Appendix B: Example Contact Record Appendix C: Rocky Flats Site Soil Disturbance Evaluation Procedure Appendix D:...

  8. EIS-0276: Rocky Flats Plutonium Storage, Golden, Colorado

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's proposed action to provide safe interim storage of approximately 10 metric tons of plutonium at the Rocky Flats Environmental Technology Site (RFETS).

  9. Unique process combination decontaminates mixed wastewater at Rocky Flats

    SciTech Connect (OSTI)

    Kelso, William J.; Cirillo, J. Russ

    1999-08-01

    This paper describes the Sitewide Water Treatment Facility (SWTF) used to process environmental remediation wastewaters found at the Rocky Flats Environmental Technology Site.

  10. Method and composition for testing for the presence of an alkali metal

    DOE Patents [OSTI]

    Guon, Jerold

    1981-01-01

    A method and composition for detecting the presence of an alkali metal on the surface of a body such as a metal plate, tank, pipe or the like is provided. The method comprises contacting the surface with a thin film of a liquid composition comprising a light-colored pigment, an acid-base indicator, and a nonionic wetting agent dispersed in a liquid carrier comprising a minor amount of water and a major amount of an organic solvent selected from the group consisting of the lower aliphatic alcohols, ketones and ethers. Any alkali metal present on the surface in elemental form or as an alkali metal hydroxide or alkali metal carbonate will react with the acid-base indicator to produce a contrasting color change in the thin film, which is readily discernible by visual observation or automatic techniques.

  11. Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure and method of processing

    DOE Patents [OSTI]

    Brown, Jr., Jesse J.; Hirschfeld, Deidre A.; Li, Tingkai

    1993-12-07

    Alkali corrosion resistant coatings and ceramic foams having superfine open cell structure are created using sol-gel processes. The processes have particular application in creating calcium magnesium zirconium phosphate, CMZP, coatings and foams.

  12. In situ formation of coal gasification catalysts from low cost alkali metal salts

    DOE Patents [OSTI]

    Wood, Bernard J.; Brittain, Robert D.; Sancier, Kenneth M.

    1985-01-01

    A carbonaceous material, such as crushed coal, is admixed or impregnated with an inexpensive alkali metal compound, such as sodium chloride, and then pretreated with a stream containing steam at a temperature of 350.degree. to 650.degree. C. to enhance the catalytic activity of the mixture in a subsequent gasification of the mixture. The treatment may result in the transformation of the alkali metal compound into another, more catalytically active, form.

  13. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, Jr., George D.; Carey, J. William

    1998-01-01

    A method using concentrated aqueous solutions of sodium cobaltinitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na--K--Ca--Si gels are identified by yellow staining, and alkali-poor, Ca--Si gels are identified by pink staining.

  14. Detection of alkali-silica reaction swelling in concrete by staining

    DOE Patents [OSTI]

    Guthrie, G.D. Jr.; Carey, J.W.

    1998-04-14

    A method using concentrated aqueous solutions of sodium cobalt nitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na-K-Ca-Si gels are identified by yellow staining, and alkali-poor, Ca-Si gels are identified by pink staining.

  15. Solvation structure and transport properties of alkali cations in dimethyl sulfoxide under exogenous static electric fields

    SciTech Connect (OSTI)

    Kerisit, Sebastien; Vijayakumar, M. E-mail: karl.mueller@pnnl.gov; Han, Kee Sung; Mueller, Karl T. E-mail: karl.mueller@pnnl.gov

    2015-06-14

    A combination of molecular dynamics simulations and pulsed field gradient nuclear magnetic resonance spectroscopy is used to investigate the role of exogenous electric fields on the solvation structure and dynamics of alkali ions in dimethyl sulfoxide (DMSO) and as a function of temperature. Good agreement was obtained, for select alkali ions in the absence of an electric field, between calculated and experimentally determined diffusion coefficients normalized to that of pure DMSO. Our results indicate that temperatures of up to 400 K and external electric fields of up to 1 V nm{sup −1} have minimal effects on the solvation structure of the smaller alkali cations (Li{sup +} and Na{sup +}) due to their relatively strong ion-solvent interactions, whereas the solvation structures of the larger alkali cations (K{sup +}, Rb{sup +}, and Cs{sup +}) are significantly affected. In addition, although the DMSO exchange dynamics in the first solvation shell differ markedly for the two groups, the drift velocities and mobilities are not significantly affected by the nature of the alkali ion. Overall, although exogenous electric fields induce a drift displacement, their presence does not significantly affect the random diffusive displacement of the alkali ions in DMSO. System temperature is found to have generally a stronger influence on dynamical properties, such as the DMSO exchange dynamics and the ion mobilities, than the presence of electric fields.

  16. Method of treating alkali metal sulfide and carbonate mixtures

    DOE Patents [OSTI]

    Kohl, Arthur L.; Rennick, Robert D.; Savinsky, Martin W.

    1978-01-01

    A method of removing and preferably recovering sulfur values from an alkali metal sulfide and carbonate mixture comprising the steps of (1) introducing the mixture in an aqueous medium into a first carbonation zone and reacting the mixture with a gas containing a major amount of CO.sub.2 and a minor amount of H.sub.2 S; (2) introducing the resultant product from step 1 into a stripping zone maintained at subatmospheric pressure, and contacting this product with steam to produce a gaseous mixture, comprising H.sub.2 S and water vapor, and a liquor of reduced sulfide content; (3) introducing the liquor of reduced sulfide content into a second carbonation zone, and reacting the liquor with substantially pure gaseous CO.sub.2 in an amount sufficient to precipitate bicarbonate crystals and produce an offgas containing CO.sub.2 and H.sub.2 S for use in step 1; (4) recovering the bicarbonate crystals from step 3, and thermally decomposing the crystals to produce an alkaline metal carbonate product and a substantially pure CO.sub.2 offgas for use in step 3.

  17. Microfabricated alkali vapor cell with anti-relaxation wall coating

    SciTech Connect (OSTI)

    Straessle, R.; Ptremand, Y.; Briand, D.; Rooij, N. F. de; Pellaton, M.; Affolderbach, C.; Mileti, G.

    2014-07-28

    We present a microfabricated alkali vapor cell equipped with an anti-relaxation wall coating. The anti-relaxation coating used is octadecyltrichlorosilane and the cell was sealed by thin-film indium-bonding at a low temperature of 140?C. The cell body is made of silicon and Pyrex and features a double-chamber design. Depolarizing properties due to liquid Rb droplets are avoided by confining the Rb droplets to one chamber only. Optical and microwave spectroscopy performed on this wall-coated cell are used to evaluate the cell's relaxation properties and a potential gas contamination. Double-resonance signals obtained from the cell show an intrinsic linewidth that is significantly lower than the linewidth that would be expected in case the cell had no wall coating but only contained a buffer-gas contamination on the level measured by optical spectroscopy. Combined with further experimental evidence this proves the presence of a working anti-relaxation wall coating in the cell. Such cells are of interest for applications in miniature atomic clocks, magnetometers, and other quantum sensors.

  18. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  19. Kenaf Bast Fibers—Part I: Hermetical Alkali Digestion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Jinshu; Shi, Sheldon Q.; Barnes, H. Michael; Horstemeyer, Mark; Wang, Jinwu; Hassan, El-Barbary M.

    2011-01-01

    The objective of this study was to develop a hermetical alkali digestion process to obtain single cellulosic fibers from kenaf bast. Kenaf bast were hermetically digested into single fiber using a 5% sodium hydroxide solution for one hour at four different temperatures (80 ° C, 110 ° C, 130 ° C, and 160 ° C). The hermetical digestion process used in this study produced fibers with high cellulose content (84.2–92.3%) due to the removal of lignin and hemicelluloses. The surface hardness and elastic modulus of the fibers digested at 130 ° C and 160 ° C were improved significantlymore » compared with those digested at 80 ° C. The tensile modulus and tensile strength of the individual fibers reduced as the digestion temperature increased from 110 ° C to 160 ° C. Micropores were generated in fiber cell wall when the fibers were digested at 130 ° C and 160 ° C. The studies on the composites that were made from polypropylene reinforced with the digested fibers indicated that the compatibility between the digested fibers and polypropylene matrix was poor.« less

  20. Chemical leaching of coal to remove ash, alkali and vanadium

    SciTech Connect (OSTI)

    Smit, F.J.; Huggins, D.K.; Berggren, M.; Anast, K.R.

    1986-04-15

    A process is described for upgrading powdered coal to improve the usefulness thereof as a fuel for internal combustion engines which consists of: (a) pressure-leaching powdered coal having a particle size ranging from about 28 mesh to about 200 mesh in an aqueous caustic solution at a temperature ranging from about 175/sup 0/C, to about 350/sup 0/C., the amount of caustic in the solution ranging from about 5% to about 30% by weight, the amount of coal being sufficient to form a slurry comprising about 10% to 30% by weight of solids, (b) hydrochloric acid leaching the caustic leached coal to dissolve acid-soluble constituents resulting from the caustic leach, (c) pressure leaching the acid-leached coal with a liquid from the group consisting of water and dilute aqueous ammonia to remove sodium and chlorine, and thereafter (d) filtering and washing the pressure leached coal, whereby the coal is characterized by up to about 0.85% by weight of ash, up to about 150 ppm of alkali metals and up to about 4 ppm vanadium.

  1. The Critical Mass Laboratory at Rocky Flats

    SciTech Connect (OSTI)

    Rothe, Robert E

    2003-10-15

    The Critical Mass Laboratory (CML) at Rocky Flats northwest of Denver, Colorado, was built in 1964 and commissioned to conduct nuclear experiments on January 28, 1965. It was built to attain more accurate and precise experimental data to ensure nuclear criticality safety at the plant than were previously possible. Prior to its construction, safety data were obtained from long extrapolations of subcritical data (called in situ experiments), calculated parameters from reactor engineering 'models', and a few other imprecise methods. About 1700 critical and critical-approach experiments involving several chemical forms of enriched uranium and plutonium were performed between then and 1988. These experiments included single units and arrays of fissile materials, reflected and 'bare' systems, and configurations with various degrees of moderation, as well as some containing strong neutron absorbers. In 1989, a raid by the Federal Bureau of Investigation (FBI) caused the plant as a whole to focus on 'resumption' instead of further criticality safety experiments. Though either not recognized or not admitted for a few years, that FBI raid did sound the death knell for the CML. The plant's optimistic goal of resumption evolved to one of deactivation, decommissioning, and plantwide demolition during the 1990s. The once-proud CML facility was finally demolished in April of 2002.

  2. Seismic hazard analysis at Rocky Flats Plant

    SciTech Connect (OSTI)

    McGuire, R.K.

    1993-10-01

    A probabilistic seismic hazard analysis is being conducted for the DOE Rocky Flats Plant, Jefferson County, Colorado. This is part of the overall review of the seismic exposure to facilities being conducted by DOE. The study has four major elements. (1) The historical seismicity in Colorado is being reviewed and synthesized to estimate historical rates of earthquake activity in the region of the site. (2) The geologic and tectonic evidence in Colorado and along the Front Range is being reviewed to determine appropriate seismic zones, potentially active faults, and constraints on fault slip rates. (3) Earthquake ground motion equations are being derived based on seismological knowledge of the earth`s crust. Site specific soil amplification factors are also being developed using on-site shear wave velocity measurements. (4) The probability of exceedence of various seismic ground motion levels is being calculated based on the inputs developed on tectonic sources, faults, ground motion, and soil amplification. Deterministic ground motion estimates are also being made. This study is a state-of-the-art analysis of seismic hazard. It incorporates uncertainties in the major aspects governing seismic hazard, and has a documented basis founded on solid data interpretations for the ranges of inputs used. The results will be a valid basis on which to evaluate plant structures, equipment, and components for seismic effects.

  3. Adsorption of superplasticizer admixtures on alkali-activated slag pastes

    SciTech Connect (OSTI)

    Palacios, M. Houst, Y.F.; Bowen, P.; Puertas, F.

    2009-08-15

    Alkali-activated slag (AAS) binders are obtained by a manufacturing process less energy-intensive than ordinary Portland cement (OPC) and involves lower greenhouse gasses emission. These alkaline cements allow the production of high mechanical strength and durable concretes. In the present work, the adsorption of different superplasticizer admixtures (naphthalene-based, melamine-based and a vinyl copolymer) on the slag particles in AAS pastes using alkaline solutions with different pH values have been studied in detail. The effect of the superplasticizers on the yield stress and plastic viscosity of the AAS and OPC pastes have been also evaluated. The results obtained allowed us to conclude that the adsorption of the superplasticizers on AAS pastes is independent of the pH of the alkaline solutions used and lower than on OPC pastes. However, the effect of the admixtures on the rheological parameters depends directly on the type and dosage of the superplasticizer as well as of the binder used and, in the case of the AAS, on the pH of the alkaline activator solution. In 11.7-pH NaOH-AAS pastes the dosages of the superplasticizers required to attain similar reduction in the yield stress are ten-fold lower than for Portland cement. In this case the superplasticizers studied show a fluidizing effect considerably higher in 11.7-pH NaOH-AAS pastes than in OPC pastes. In 13.6-pH NaOH-AAS pastes, the only admixture observed to affect the rheological parameters is the naphthalene-based admixture due to its higher chemical stability in such extremely alkaline media.

  4. Rocky Flats 100th Shipments Arrives at WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RELEASE Rocky Flats For Immediate Release Contact: Karen Lutz, DOE RFFO, 303/966-4546 01-08 Jennifer Thompson, Kaiser-Hill, 303/966-6285 Kate Foster, Westinghouse TRU Solutions, 505/234-7589 Rocky Flats' 100 th Shipment Arrives at Waste Isolation Pilot Plant DENVER, Colo., March 14, 2001- The 100 th shipment of transuranic waste from the U.S. Department of Energy's (DOE) Rocky Flats Environmental Technology Site (RFETS) has arrived at DOE's Waste Isolation Pilot Plant (WIPP) in New Mexico. Rocky

  5. DOE - NNSA/NFO -- Frenchman Flat Peer Review

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frenchman Flat Peer Review NNSA/NFO Language Options U.S. DOE/NNSA - Nevada Field Office Click to subscribe to NNSS News Frenchman Flat Peer Review Following are the Frenchman Flat Peer Review documents: PDF icon Completion Report for Well Cluster ER-5-3 DOE/NV-11718-1093 [PDF, 5.8 MB] PDF icon Completion Report for Well Cluster ER-5-4 DOE/NV-11718-998 [PDF, 5.2 MB] PDF icon Errata for Nevada National Security Site Radionuclide Inventory, Bowen et al LA-13859-MS [PDF, 96 KB] PDF icon Evaluation

  6. Eddy-current transducer based on flat spiral coils

    SciTech Connect (OSTI)

    Franyuk, V.A.; Ivan'kovich, L.F.

    1988-12-01

    The article deals with the experimental investigation of flat-coil eddy current transducers with spiral windings. It is shown that it is possible to use them for detecting discontinuities on electrically conducting products with different configuration of the surface. The instrument is described. The use of crossed flat coils makes it possible effectively to detect flaws in electrically conducting products of any shape. A transducer containing crossed flat coils helps, in addition to detecting flaws, in evaluating anisotropy (magnetic and mechanical) from which conclusions as to the physicomechanical properties of the product can be drawn.

  7. The direct observation of alkali vapor species in biomass combustion and gasification

    SciTech Connect (OSTI)

    French, R.J.; Dayton, D.C.; Milne, T.A.

    1994-01-01

    This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

  8. Water Monitoring Flume Replaced at the Rocky Flats, Colorado, Site

    Broader source: Energy.gov [DOE]

    In August of this year the U.S. Department of Energy (DOE) Office of Legacy Management (LM) Rocky Flats, site took advantage of an existing water diversion structure that was no longer needed, to...

  9. Flat-Plate Photovoltaic Module Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Module Basics Flat-Plate Photovoltaic Module Basics August 20, 2013 - 4:25pm Addthis ... a high transmission in the wavelengths that can be used by the solar cells in the module. ...

  10. The use of performance parameters in monitoring the safety of dams experiencing alkali-aggregate reaction

    SciTech Connect (OSTI)

    Veesaert, C.J.; LaBoon, J.H.

    1995-12-31

    As the Bureau of Reclamation (Reclamation) moves away from design and construction of new water resource projects toward optimizing the management of existing water resource projects, monitoring the condition of high risk structures such as dams becomes very important. To address this need, Reclamation has developed a logical approach of monitoring the safety of a dam over time. This approach analyzes visual and instrumentation performance parameters unique to each dam, Performance parameters specify the expected performance (behavior) of both embankment and concrete dams, including those concrete dams effected by alkali-aggregate reaction. This paper presents an overview of the concept of performance parameters in monitoring the safety of dams, which have experienced alkali-aggregate reaction. Three case studies are presented to illustrate the use of performance parameters in monitoring a dam`s behavior over time, relative to the effects of alkali-aggregate reaction.

  11. 2006 Annual Ecology Report for the Rocky Flats Site

    Office of Legacy Management (LM)

    Ecology Report for the Rocky Flats Site Click on the links below to access different portions of the electronic annual report. 2006 Annual Report Sections Diffuse Knapweed Biocontrol Monitoring Report Dalmatian Toadflax Monitoring Report High-Value Vegetation Monitoring Report Revegetation Monitoring Report Present and Original Landfill Revegetation Monitoring Report Frog Vocalization Monitoring Report Appendix A (Files below comprise Appendix A for the above listed reports.) Rocky Flats Flora

  12. 2D 'Flat' Boron Yields a Superconducting Surprise

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2D 'Flat' Boron Yields a Superconducting Surprise 2D 'Flat' Boron Yields a Superconducting Surprise Simulations Run at NERSC Help Reveal Material's Superconducting Superpowers April 22, 2016 2Dboron Electrons with opposite momenta and spins pair up via lattice vibrations at low temperatures in 2D boron and give it superconducting properties. Image: Evgeni Penev, Rice University Density functional theory simulations run at NERSC helped Rice University researchers determine that two-dimensional

  13. Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance

    Office of Legacy Management (LM)

    Second Quarter Calendar Year 2013 October 2013 LMS/RFS/S10694 This page intentionally left blank LMS/RFS/S10694 Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance and Maintenance Activities Second Quarter Calendar Year 2013 October 2013 This page intentionally left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site Surveillance and Maintenance Activities-2nd Quarter CY 2013 October 2013 Doc. No. S10694 Page i Contents Abbreviations

  14. Benchmarking and performance improvement at Rocky Flats Technology Site

    SciTech Connect (OSTI)

    Elliott, C.; Doyle, G.; Featherman, W.L.

    1997-03-01

    The Rocky Flats Environmental Technology Site has initiated a major work process improvement campaign using the tools of formalized benchmarking and streamlining. This paper provides insights into some of the process improvement activities performed at Rocky Flats from November 1995 through December 1996. It reviews the background, motivation, methodology, results, and lessons learned from this ongoing effort. The paper also presents important gains realized through process analysis and improvement including significant cost savings, productivity improvements, and an enhanced understanding of site work processes.

  15. Averaged null energy condition violation in a conformally flat spacetime

    SciTech Connect (OSTI)

    Urban, Douglas; Olum, Ken D.

    2010-01-15

    We show that the averaged null energy condition can be violated by a conformally coupled scalar field in a conformally flat spacetime in 3+1 dimensions. The violation is dependent on the quantum state and can be made as large as desired. It does not arise from the presence of anomalies, although anomalous violations are also possible. Since all geodesics in conformally flat spacetimes are achronal, the achronal averaged null energy condition is likewise violated.

  16. LPO5-002-Proj-Poster-WIND-ShepardsFlat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SHEPHERDS FLAT Spanning two counties of working heritage ranch land in eastern Oregon, Shepherds Flat is one of the world's largest wind farms. INVESTING in AMERICAN ENERGY OWNER Caithness Energy, LLC LOCATIONS Gilliam County & Morrow County, Oregon LOAN AMOUNT $1.3 Billion ISSUANCE DATE December 2010 GENERATION CAPACITY 845 MW PROJECTED ANNUAL GENERATION 1,800,000 MWh CLIMATE BENEFIT 1,000,000 Metric Tons of CO 2 Prevented Annually

  17. Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report

    SciTech Connect (OSTI)

    Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

    1994-02-01

    Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

  18. Theory of magic optical traps for Zeeman-insensitive clock transitions in alkali-metal atoms

    SciTech Connect (OSTI)

    Derevianko, Andrei

    2010-05-15

    Precision measurements and quantum-information processing with cold atoms may benefit from trapping atoms with specially engineered, 'magic' optical fields. At the magic trapping conditions, the relevant atomic properties remain immune to strong perturbations by the trapping fields. Here we develop a theoretical analysis of magic trapping for especially valuable Zeeman-insensitive clock transitions in alkali-metal atoms. The involved mechanism relies on applying a magic bias B field along a circularly polarized trapping laser field. We map out these B fields as a function of trapping laser wavelength for all commonly used alkalis. We also highlight a common error in evaluating Stark shifts of hyperfine manifolds.

  19. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  20. Alkali slurry ozonation to produce a high capacity nickel battery material

    DOE Patents [OSTI]

    Jackovitz, John F.; Pantier, Earl A.

    1984-11-06

    A high capacity battery material is made, consisting essentially of hydrated Ni(II) hydroxide, and about 5 wt. % to about 40 wt. % of Ni(IV) hydrated oxide interlayer doped with alkali metal cations selected from potassium, sodium and lithium cations.

  1. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  2. Method for inhibiting alkali metal corrosion of nickel-containing alloys

    DOE Patents [OSTI]

    DeVan, Jackson H.; Selle, James E.

    1983-01-01

    Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

  3. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A.

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  4. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M.; Peng, Marcus Y.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard C.

    1996-01-01

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  5. High temperature alkali corrosion of ceramics in coal gas: Final report

    SciTech Connect (OSTI)

    Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

    1994-12-31

    There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.

  6. Dissolution of HTGR TRISO beads by the alkali fluoride fusion method

    SciTech Connect (OSTI)

    Byster, S.E.

    1980-07-01

    The alkali fluoride fusion method for the dissolution of HTGR TRISO fuel beads offers significant time advantage over other commonly used fusion procedures when applied to samples weighing less than three grams. The method is straightforward, utilizes standard analytical laboratory equipment, and yields solutions which may be utilized by customary procedures.

  7. Magnetotelluric Data, Northern Frenchman Flat, Nevada Test Site Nevada

    SciTech Connect (OSTI)

    J.M. Williams; B.D. Rodriguez, and T. H. Asch

    2005-11-23

    Nuclear weapons are integral to the defense of the United States. The U.S. Department of Energy, as the steward of these devices, must continue to gauge the efficacy of the individual weapons. This could be accomplished by occasional testing at the Nevada Test Site (NTS) in Nevada, northwest of Las Vegas. Yucca Flat Basin is one of the testing areas at the NTS. One issue of concern is the nature of the somewhat poorly constrained pre-Tertiary geology and its effects on ground-water flow in the area subsequent to a nuclear test. Ground-water modelers would like to know more about the hydrostratigraphy and geologic structure to support a hydrostratigraphic framework model that is under development for the Yucca Flat Corrective Action Unit (CAU). During 2003, the U.S. Geological Survey (USGS) collected and processed Magnetotelluric (MT) and Audio-magnetotelluric (AMT) data at the Nevada Test Site in and near Yucca Flat to help characterize this pre-Tertiary geology. That work will help to define the character, thickness, and lateral extent of pre-Tertiary confining units. In particular, a major goal has been to define the upper clastic confining unit (UCCU) in the Yucca Flat area. Interpretation will include a three-dimensional (3-D) character analysis and two-dimensional (2-D) resistivity model. The purpose of this report is to release the MT sounding data for Frenchman Flat Profile 3, as shown in Figure 1. No interpretation of the data is included here.

  8. Data Acquisition Scan for Large Area Flat Panel Digital X-ray Detector Array

    Energy Science and Technology Software Center (OSTI)

    2004-05-01

    Interface large area flat panel digital detector and motion control system for computed tomographic data acquisition.

  9. Rocky Flats Plant Site Environmental Report, January--December 1990

    SciTech Connect (OSTI)

    Cirrincione, D.A.; Costain, D.B.

    1990-12-31

    This report provides information to the public about the impact of the Rocky Flats Plant on the environment and public health. The report contains a compliance summary, a description of environmental monitoring programs, and radiation dose estimates for the surrounding population for the period January 1 through December 31, 1990. An environmental surveillance program has been ongoing at the Rocky Flats Plant since the 1950s. Early programs focused on radiological impacts to the environment. The current program examines potential impacts to air, surface water, groundwater, and soils from radiological and nonradiological sources. Environmental operations at Rocky Flats Plant are under the jurisdiction of several local, state, and federal agencies, most notably the Colorado Department of Health, Environmental Protection Agency, and Department of Energy. A variety of reports are prepared at different intervals for these and other agencies in addition to the annual environmental report.

  10. NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS

    SciTech Connect (OSTI)

    Hemrick, James Gordon; Smith, Jeffrey D; O'Hara, Kelley; Rodrigues-Schroer, Angela; Colavito,

    2012-08-01

    A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new

  11. Benchmarking and Performance Improvement at Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    Elliott, C. , Doyle, D. , Featherman, W.D.

    1997-12-31

    The Rocky Flats Environmental Technology Site (RFETS) has initiated a major work process improvement campaign using the tools of formalized benchmarking and streamlining. This paper provides insights into some of the process improvement activities performed at Rocky Flats from November 1995 through December 1996. It reviews the background, motivation, methodology, results, and lessons learned from this ongoing effort. The paper also presents important gains realized through process analysis and improvement including significant cost savings, productivity improvements, and an enhanced understanding of site work processes.

  12. Hydrogeologic characterization report for the Rocky Flats environmental technology site

    SciTech Connect (OSTI)

    Reeder, D.C.; Burcar, S.; Smith, R.

    1996-12-31

    The Denver groundwater basin encompasses approximately 6,700 square miles, extending east from the Front Range of the Rocky Mountains. This structural basin contains four Cretaceous bedrock aquifers overlain by a regional Quaternary alluvial aquifer. The Rocky Flats Site is located on the northwest margin of the basin. The shallow groundwater system at the Rocky Flats Site is divided into upper and lower hydrostratigraphic units (UHSU and LHSU, respectively). The UHSU at the Rocky Flats site comprises Quaternary alluvium, colluvium, valley-fill alluvium, artificial fill, weathered bedrock of the undifferentiated Arapahoe and Laramie formations and all sandstones that are hydraulically connected with overlying surficial groundwater. The LHSU comprises unweathered claystone with interbedded siltstones and sandstones of the undifferentiated Arapahoe and Laramie formations. The contact separating the UHSU and LHSU is identified as the base of the weathered zone. The separation of hydrostratigraphic units is supported by the contrasting permeabilities of the units comprising the UHSU and LHSU, well hydrograph data indicating that the units respond differently to seasonal recharge events, and geochemical data reflecting distinct major ion chemistries in the groundwaters of the UHSU and LHSU. Surface-water/groundwater interactions at the Rocky Flats site generally respond to seasonal fluctuations in precipitation, recharge, groundwater storage, and stream and ditch flow. Effluent conditions are dominant in the spring along western stream segments and influent conditions are common in the late summer and fall along most stream reaches.

  13. Rocky Flats Cleanup Agreement implementation successes and challenges

    SciTech Connect (OSTI)

    Shelton, D.C.

    1997-02-01

    On July 19, 1996 the US Department of Energy (DOE), State of Colorado (CDPHE), and US Environmental Protection Agency (EPA) entered into an agreement called the Rocky Flats Cleanup Agreement (RFCA) for the cleanup and closure of the Rocky Flats Environmental Technology Site (RFETS or Rocky Flats). Major elements of the agreement include: an Integrated Site-Wide Baseline; up to twelve significant enforceable milestones per year; agreed upon soil and water action levels and standards for cleanup; open space as the likely foreseeable land use; the plutonium and TRU waste removed by 2015; streamlined regulatory process; agreement with the Defense Nuclear Facilities Safety Board (DNFSB) to coordinate activities; and a risk reduction focus. Successful implementation of RFCA requires a substantial effort by the parties to change their way of thinking about RFETS and meet the deliverables and commitments. Substantial progress toward Site closure through the implementation of RFCA has been accomplished in the short time since the signing, yet much remains to be done. Much can be learned from the Rocky Flats experience by other facilities in similar situations.

  14. TGS measurements of pyrochemical salts at Rocky Flats

    SciTech Connect (OSTI)

    Mercer, D. J.; Hansen, J. S.; Lestone, J. P.; Prettyman, T. H.

    2001-01-01

    A new skid-mounted tomographic gamma scanner (TGS) was designed to assist in the decommissioning of Rocky Flats Building 37 1, This instrument was used to assay pyrochemical salts as a prerequisite for disposal at the Waste Isolation Pilot Plant (WIPP). The following paper discusses measurement challenges and results from the first year of operation of the instrument.

  15. Site wide integration of the Rocky Flats closure project

    SciTech Connect (OSTI)

    Burdge, L.F.; Golan, P.

    1998-06-01

    The prime contractor for the Rocky Flats Closure Project (RFCP), Kaiser-Hill, in concert with the Department of Energy--Rocky Flats Field Office (DOE-RFFO) has applied a fully integrated, life-cycle, critical path schedule and work planning system to manage the work that is required to close the Site. The closure of the Site is complex, in that it houses over 700 facilities, 19,600 kilograms of Special Nuclear Material (Plutonium and Uranium), and over 160,000 cubic meters of Transuranic, Low Level, and Hazardous Waste. The deactivation, decommissioning, decontaminating, and demolition of this large number of facilities, while at the same time accommodating difficult on-going activities, significantly increases the sophistication required in the planning process. The Rocky Flats team has overcome these difficulties by establishing a money oriented critical path process, to provide a least-cost avenue to supporting on-going activities and a line-of-balance process for production oriented activities. These processes, when integrated with a typical activity-based project planning system, guide the way to the shortest and most cost-effective course for the closure of the Rocky Flats Site.

  16. Flat panel display development activities at Sandia National Laboratories

    SciTech Connect (OSTI)

    DiBello, E.G.; Worobey, W.; Burchett, S.; Hareland, W.; Felter, T.; Mays, B.

    1994-12-31

    The flat panel display development activities underway at Sandia National Laboratories are described. Research is being conducted in the areas of glass substrates, phosphors, large area processes, and electron emissions. Projects are focused on improving process yield, developing large area processes, and using modeling techniques to predict design performance.

  17. Adsorption study for uranium in Rocky Flats groundwater

    SciTech Connect (OSTI)

    Laul, J.C.; Rupert, M.C.; Harris, M.J.; Duran, A.

    1995-01-01

    Six adsorbents were studied to determine their effectiveness in removing uranium in Rocky Flats groundwater. The bench column and batch (Kd) tests showed that uranium can be removed (>99.9%) by four adsorbents. Bone Charcoal (R1O22); F-1 Alumina (granular activated alumina); BIOFIX (immobilized biological agent); SOPBPLUS (mixed metal oxide); Filtrasorb 300 (granular activated carbon); and Zeolite (clinoptilolite).

  18. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    SciTech Connect (OSTI)

    Ward, Patrick A.; Teprovich, Jr., Jospeph A.; Compton, Robert N.; Schwartz, Viviane; Veith, Gabriel M.; Zidan, Ragiay

    2015-01-11

    Here, alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm and 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.

  19. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ward, Patrick A.; Teprovich, Jr., Jospeph A.; Compton, Robert N.; Schwartz, Viviane; Veith, Gabriel M.; Zidan, Ragiay

    2015-01-11

    Here, alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm andmore » 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.« less

  20. An Aqueous Redox Flow Battery Based on Neutral Alkali Metal Ferri/ferrocyanide and Polysulfide Electrolytes

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Xia, Gordon; Kirby, Brent W.; Thomsen, Edwin C.; Li, Bin; Nie, Zimin; Graff, Gordon L.; Liu, Jun; Sprenkle, Vincent L.; Wang, Wei

    2015-11-13

    Aiming to explore low-cost redox flow battery systems, a novel iron-polysulfide (Fe/S) flow battery has been demonstrated in a laboratory cell. This system employs alkali metal ferri/ferrocyanide and alkali metal polysulfides as the redox electrolytes. When proper electrodes, such as pretreated graphite felts, are used, 78% energy efficiency and 99% columbic efficiency are achieved. The remarkable advantages of this system over current state-of-the-art redox flow batteries include: 1) less corrosive and relatively environmentally benign redox solutions used; 2) excellent energy and utilization efficiencies; 3) low cost for redox electrolytes and cell components. These attributes can lead to significantly reduced capital cost and make the Fe/S flow battery system a promising low-cost energy storage technology. The major drawbacks of the present cell design are relatively low power density and possible sulfur species crossover. Further work is underway to address these concerns.

  1. Petrography study of two siliceous limestones submitted to alkali-silica reaction

    SciTech Connect (OSTI)

    Monnin, Y. . E-mail: monnin@ensm-douai.fr; Degrugilliers, P.; Bulteel, D.; Garcia-Diaz, E.

    2006-08-15

    This study presents the contribution of petrography to the comprehension of the alkali-silica reaction mechanism applied to two siliceous limestones. A petrography study was made on the two aggregates before reaction to define their relative proportions and types of reactive silica and to observe their distribution in the microstructure. Then a model reactor, constituted by the reactive siliceous limestone aggregate, portlandite and NaOH, was used to measure the swelling due to reaction of the silica with alkalis and the free expansion of the aggregates. The volume evolution between both aggregates was very different and could be explained by the preliminary petrographic study. It appears that the swelling of the aggregates is conditioned by the microstructure of the carbonated matrix, the quantity and the distribution of the reactive silica.

  2. Evaluation of the physi- and chemisorption of hydrogen in alkali (Na, Li) doped fullerenes

    SciTech Connect (OSTI)

    Ward, Patrick; Teprovich, Jospeph A.; Compton, Robert; Affholter, Kathleen A; Schwartz, Viviane; Veith, Gabriel M; Zidan, Ragiay

    2015-01-01

    Alkali doped fullerenes synthesized by two different solvent assisted mixing techniques are compared for their hydrogen uptake activity. In this study we investigated the interaction of hydrogen with alkali doped fullerenes via physisorption. In addition, we present the first mass spectrometric evidence for the formation of C60H60 via chemisorption. Hydrogen physisorption isotherms up to 1 atm at temperatures ranging from 77-303 K were measured demonstrating an increase in hydrogen uptake versus pure C60 and increased isosteric heats of adsorption for the lithium doped fullerene Li12C60. However, despite these improvements the low amount of physisorbed hydrogen at 1 atm and 77 K in these materials suggests that fullerenes do not possess enough accessible surface area to effectively store hydrogen due to their close packed crystalline nature.

  3. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, John W.; Wender, Irving; Palekar, Vishwesh M.

    1995-01-01

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  4. Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters

    DOE Patents [OSTI]

    Tierney, J.W.; Wender, I.; Palekar, V.M.

    1995-01-31

    The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

  5. Second international conference on alkali-aggregate reactions in hydroelectric plants and dams

    SciTech Connect (OSTI)

    1995-12-31

    This document is the report of the Second International Conference on Alkali-Aggregate Reactions in Hydroelectric Plants and Dams. This conference was held in October 1995 in Chattanooga, TN and sponsored by the Tennessee Valley Authority. Thirty five papers were presented, with technical sessions covering: (1) The TVA experience, (2) AAR in Hydroelectric Powerplants, (3) AAR in Dams and Spillways, and (4) Long-term management of AAR. Additionally, there were several workshop sessions.

  6. Gel nanostructure in alkali-activated binders based on slag and fly ash, and effects of accelerated carbonation

    SciTech Connect (OSTI)

    Bernal, Susan A.; Provis, John L.; Walkley, Brant; San Nicolas, Rackel; Gehman, John D.; Brice, David G.; Kilcullen, Adam R.; Duxson, Peter; Deventer, Jannie S.J. van

    2013-11-15

    Binders formed through alkali-activation of slags and fly ashes, including ‘fly ash geopolymers’, provide appealing properties as binders for low-emissions concrete production. However, the changes in pH and pore solution chemistry induced during accelerated carbonation testing provide unrealistically low predictions of in-service carbonation resistance. The aluminosilicate gel remaining in an alkali-activated slag system after accelerated carbonation is highly polymerised, consistent with a decalcification mechanism, while fly ash-based binders mainly carbonate through precipitation of alkali salts (bicarbonates at elevated CO{sub 2} concentrations, or carbonates under natural exposure) from the pore solution, with little change in the binder gel identifiable by nuclear magnetic resonance spectroscopy. In activated fly ash/slag blends, two distinct gels (C–A–S–H and N–A–S–H) are formed; under accelerated carbonation, the N–A–S–H gel behaves comparably to fly ash-based systems, while the C–A–S–H gel is decalcified similarly to alkali-activated slag. This provides new scope for durability optimisation, and for developing appropriate testing methodologies. -- Highlights: •C-A-S-H gel in alkali-activated slag decalcifies during accelerated carbonation. •Alkali-activated fly ash gel changes much less under CO{sub 2} exposure. •Blended slag-fly ash binder contains two coexisting gel types. •These two gels respond differently to carbonation. •Understanding of carbonation mechanisms is essential in developing test methods.

  7. Colorado and the Accelerated Cleanup at Rocky Flats

    SciTech Connect (OSTI)

    Spreng, C.

    2007-07-01

    When the Rocky Flats closure project was declared complete in October 2005, it was the largest environmental cleanup to date. Even more impressive, it was ahead of schedule and well under budget. Several factors combined to produce this success including a performance-based contract with financial incentives, development and application of innovative technologies, and a regulator-backed accelerated approach to the cleanup process. The factor in this success in which the State of Colorado had the largest role was in developing and enforcing the Rocky Flats Cleanup Agreement. In compliance with this agreement, cleanup was accomplished by means of multiple interim actions that led to a comprehensive final decision at the end. A key element that allowed the accelerated cleanup was constant consultation among DOE, its contractor, and the regulators plus collaboration with stakeholders. (authors)

  8. Facility overview for commercial application of selected Rocky Flats facilities

    SciTech Connect (OSTI)

    1996-11-01

    The purpose of this Facility Overview is to support the Rocky Flats Local Impacts Initiative`s Request for Interest, to solicit interest from commercial corporations for utilizing buildings 865 and 883, and the equipment contained within each building, for a commercial venture. In the following sections, this document describes the Rocky Flats Site, the buildings available for lease, the equipment within these buildings, the site services available to a tenant, the human resources available to support operations in buildings 865 and 883, and the environmental condition of the buildings and property. In addition, a brief description is provided of the work performed to date to explore the potential products that might be manufactured in Buildings 865 and 883, and the markets for these products.

  9. Polymer solidification of mixed wastes at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Faucette, A.M.; Logsdon, B.W.; Lucerna, J.J.; Yudnich, R.J.

    1994-02-01

    The Rocky Flats Plant is pursuing polymer solidification as a viable treatment option for several mixed waste streams that are subject to land disposal restrictions within the Resource Conservation and Recovery Act provisions. Tests completed to date using both surrogate and actual wastes indicate that polyethylene microencapsulation is a viable treatment option for several mixed wastes at the Rocky Flats Plant, including nitrate salts, sludges, and secondary wastes such as ash. Treatability studies conducted on actual salt waste demonstrated that the process is capable of producing waste forms that comply with all applicable regulatory criteria, including the Toxicity Characteristic Leaching Procedure. Tests have also been conducted to evaluate the feasibility of macroencapsulating certain debris wastes in polymers. Several methods and plastics have been tested for macroencapsulation, including post-consumer recycle and regrind polyethylene.

  10. Actinide solution processing at the Rocky Flats Environmental Technology Site

    SciTech Connect (OSTI)

    1995-04-01

    The Department of Energy (DOE) has prepared an Environmental Assessment (EA), DOE/EA-1039, for radioactive solution removal and processing at Rocky Flats Environmental Technology Site, Golden, Colorado. The proposal for solution removal and processing is in response to independent safety assessments and an agreement with the State of Colorado to remove mixed residues at Rocky Flats and reduce the risk of future accidents. Monthly public meetings were held during the scoping and preparation of the EA. The scope of the EA included evaluations of alternative methods and locations of solution processing. A comment period from February 20, 1995 through March 21, 1995 was provided to the public and the State of Colorado to offer written comment on the EA. Comments were received from the State of Colorado and the U.S. Environmental Protection Agency. A response to the agency comments is included in the Final EA.