Status of the Fundamental Laws of Thermodynamics
Walid K. Abou Salem; Juerg Froehlich
2006-11-14T23:59:59.000Z
We describe recent progress towards deriving the Fundamental Laws of thermodynamics (the 0th, 1st and 2nd Law) from nonequilibrium quantum statistical mechanics in simple, yet physically relevant models. Along the way, we clarify some basic thermodynamic notions and discuss various reversible and irreversible thermodynamic processes from the point of view of quantum statistical mechanics.
FUNDAMENTAL PARAMETERS AND CHEMICAL COMPOSITION OF ARCTURUS
Ramirez, I. [Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Allende Prieto, C., E-mail: ivan@obs.carnegiescience.edu, E-mail: callende@iac.es [Instituto de Astrofisica de Canarias, 38205 La Laguna, Tenerife (Spain)
2011-12-20T23:59:59.000Z
We derive a self-consistent set of atmospheric parameters and abundances of 17 elements for the red giant star Arcturus: T{sub eff} = 4286 {+-} 30 K, log g = 1.66 {+-} 0.05, and [Fe/H] = -0.52 {+-} 0.04. The effective temperature was determined using model atmosphere fits to the observed spectral energy distribution from the blue to the mid-infrared (0.44 to 10 {mu}m). The surface gravity was calculated using the trigonometric parallax of the star and stellar evolution models. A differential abundance analysis relative to the solar spectrum allowed us to derive iron abundances from equivalent width measurements of 37 Fe I and 9 Fe II lines, unblended in the spectra of both Arcturus and the Sun; the [Fe/H] value adopted is derived from Fe I lines. We also determine the mass, radius, and age of Arcturus: M = 1.08 {+-} 0.06 M{sub Sun }, R = 25.4 {+-} 0.2 R{sub Sun }, and {tau} = 7.1{sup +1.5}{sub -1.2} Gyr. Finally, abundances of the following elements are measured from an equivalent width analysis of atomic features: C, O, Na, Mg, Al, Si, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, and Zn. We find the chemical composition of Arcturus typical of that of a local thick-disk star, consistent with its kinematics.
accurate fundamental parameters: Topics by E-print Network
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
endeavor can also be applied to similar problems such as the determination of the Higgs boson couplings at the LHC. Dirk Zerwas 2009-09-30 4 Fundamental Parameters of Massive...
Fundamental Thermodynamics of Actinide-Bearing Mineral Waste Forms - Final Report
Williamson, Mark A.; Ebbinghaus, Bartley B.; Navrotsky, Alexandra
2001-03-01T23:59:59.000Z
The end of the Cold War raised the need for the technical community to be concerned with the disposition of excess nuclear weapon material. The plutonium will either be converted into mixed-oxide fuel for use in nuclear reactors or immobilized in glass or ceramic waste forms and placed in a repository. The stability and behavior of plutonium in the ceramic materials as well as the phase behavior and stability of the ceramic material in the environment is not well established. In order to provide technically sound solutions to these issues, thermodynamic data are essential in developing an understanding of the chemistry and phase equilibria of the actinide-bearing mineral waste form materials proposed as immobilization matrices. Mineral materials of interest include zircon, zirconolite, and pyrochlore. High temperature solution calorimetry is one of the most powerful techniques, sometimes the only technique, for providing the fundamental thermodynamic data needed to establish optimum material fabrication parameters, and more importantly understand and predict the behavior of the mineral materials in the environment. The purpose of this project is to experimentally determine the enthalpy of formation of actinide orthosilicates, the enthalpies of formation of actinide substituted zirconolite and pyrochlore, and develop an understanding of the bonding characteristics and stabilities of these materials.
DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 2
Not Available
1992-06-01T23:59:59.000Z
The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.
DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 1
Not Available
1992-06-01T23:59:59.000Z
The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.
DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 3
Not Available
1992-06-01T23:59:59.000Z
The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.
Thermodynamics and phase transitions of electrolytes on lattices with different discretization February 2005; in final form 14 April 2005) Lattice models are crucial for studying thermodynamic thermodynamics and the nature of phase transitions in systems with charged particles. A discretization parameter
Office of Scientific and Technical Information (OSTI)
. * : TID-267 11-P2 '4 ' Fundamental Aspects of Nuclear Reactor Fuel Elements Solutions to Problems Donald R. Olander Department - of Nuclear Engineering University of Cacfornia,...
assess thermodynamic parameters: Topics by E-print Network
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
for each parameter, and environmental impacts uncertainties in the future? Application to photovoltaic systems installed in Spain Camille Marini1 and Isabelle- certainties in the...
Fundamental Parameters of Low Mass X-ray Binaries II: X-Ray Persistent Systems
Jorge Casares; Phil Charles
2005-06-24T23:59:59.000Z
The determination of fundamental parameters in X-ray luminous (persistent) X-ray binaries has been classically hampered by the large optical luminosity of the accretion disc. New methods, based on irradiation of the donor star and burst oscillations, provide the opportunity to derive dynamical information and mass constraints in many persistent systems for the first time. These techniques are here reviewed and the latest results presented.
Non-extensivity Parameter of Thermodynamical Model of Hadronic Interactions at LHC energies
Tadeusz Wibig
2010-05-31T23:59:59.000Z
The LHC measurements above SPS and Tevatron energies give the opportunity to test predictions of non-extensive thermodynamical picture of hadronic interaction to examine measured transverse momenta distributions for new interaction energy range. We determined Tsallis model non-extensivity parameter for the hadronization process before short-lived particles decayed and distort the initial p_t distribution. We have shown that it follows exactly smooth rise determined at lower energies below present LHC record. The shape of the q parameter energy dependence is consistent with expectations and the evidence of the asymptotic limit may be seen.
Thermal equation of state and thermodynamic Grüneisen parameter of beryllium metal
Zhang, Jianzhong, E-mail: jzhang@lanl.gov; Zhu, Jinlong [Los Alamos Neutron Science Center, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Velisavljevic, Nenad [Dynamic and Energetic Materials Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Wang, Liping; Zhao, Yusheng [High Pressure Science and Engineering Center and Department of Physics and Astronomy, University of Nevada, Las Vegas, Nevada 89154 (United States)
2013-11-07T23:59:59.000Z
We conducted in-situ high-pressure synchrotron x-ray experiments on beryllium metal at pressures up to 7.9?GPa and temperatures up to 1373?K. A complete pressure (P)–volume (V)–temperature (T) equation of state (EOS) is determined based on the experiment, which includes temperature derivatives of elastic bulk modulus (at both constant pressure and constant volume) and pressure dependence of thermal expansivity. From this EOS, we calculate thermal pressure, heat capacity at constant volume, and thermodynamic Grüneisen parameter as a function of temperature. Above ?600?K, our results show notable deviation from theoretical predictions using the quasiharmonic and local-density approximations, indicating that the free energy calculations need to be further improved within the current scheme of approximations.
Thermodynamic Metrics and Optimal Paths
Sivak, David; Crooks, Gavin
2012-05-08T23:59:59.000Z
A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a Riemannian manifold on the space of thermodynamic states. Within the linear-response regime, this metric structure controls the dissipation of finite-time transformations, and bestows optimal protocols with many useful properties. We discuss the connection to the existing thermodynamic length formalism, and demonstrate the utility of this metric by solving for optimal control parameter protocols in a simple nonequilibrium model.
Sai Venkata Ramana, A., E-mail: asaivenk@barc.gov.in [Theoretical Physics Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)
2014-04-21T23:59:59.000Z
The coupling parameter series expansion and the high temperature series expansion in the thermodynamic perturbation theory of fluids are shown to be equivalent if the interaction potential is pairwise additive. As a consequence, for the class of fluids with the potential having a hardcore repulsion, if the hard-sphere fluid is chosen as reference system, the terms of coupling parameter series expansion for radial distribution function, direct correlation function, and Helmholtz free energy follow a scaling law with temperature. The scaling law is confirmed by application to square-well fluids.
Sang-Yoon Kim; Woochang Lim
2014-10-06T23:59:59.000Z
We are interested in characterization of population synchronization of bursting neurons which exhibit both the slow bursting and the fast spiking timescales, in contrast to spiking neurons. Population synchronization may be well visualized in the raster plot of neural spikes which can be obtained in experiments. The instantaneous population firing rate (IPFR) $R(t)$, which may be directly obtained from the raster plot of spikes, is often used as a realistic collective quantity describing population behaviors in both the computational and the experimental neuroscience. For the case of spiking neurons, realistic thermodynamic order parameter and statistical-mechanical spiking measure, based on $R(t)$, were introduced in our recent work to make practical characterization of spike synchronization. Here, we separate the slow bursting and the fast spiking timescales via frequency filtering, and extend the thermodynamic order parameter and the statistical-mechanical measure to the case of bursting neurons. Consequently, it is shown in explicit examples that both the order parameters and the statistical-mechanical measures may be effectively used to characterize the burst and spike synchronizations of bursting neurons.
Carlos Allende Prieto; David L. Lambert
1999-11-02T23:59:59.000Z
The Hipparcos mission has made it possible to constrain the positions of nearby field stars in the colour-magnitude diagram with very high accuracy. These positions can be compared with the predictions of stellar evolutionary calculations to provide information on the basic parameters of the stars: masses, radii, effective temperatures, ages, and chemical composition. The degeneracy between mass, age, and metallicity is not so large as to prevent a reliable estimate of masses, radii and effective temperatures, at least for stars of solar metallicity. The evolutionary models of Bertelli et al. (1994) predict those parameters finely, and furthermore, the applied transformation from the theoretical (log g-Teff) to the observational (Mv-B-V) plane is precise enough to derive radii with an uncertainty of ~ 6%, masses within ~ 8%, and Teffs within ~ 2% for a certain range of the stellar parameters. This is demonstrated by means of comparison with the measurements in eclipsing binaries and the InfraRed Flux Method. The application of the interpolation procedure in the theoretical isochrones to the stars within 100 pc from the Sun observed with Hipparcos provides estimates for 17,219 stars
Fundamental Parameters and Abundances of Metal-Poor Stars: The SDSS Standard BD +17 4708
I. Ramirez; C. Allende Prieto; S. Redfield; D. L. Lambert
2006-08-25T23:59:59.000Z
The atmospheric parameters and iron abundance of the Sloan Digital Sky Survey (SDSS) spectrophotometric standard star BD +17 4708 are critically examined using up-to-date Kurucz model atmospheres, LTE line formation calculations, and reliable atomic data. We find Teff = 6141+-50 K, log g = 3.87+-0.08, and [Fe/H]=-1.74+-0.09. The line-of-sight interstellar reddening, bolometric flux, limb-darkened angular diameter, stellar mass, and the abundances of Mg, Si, and Ca are also obtained. This star is a unique example of a moderately metal-poor star for which the effective temperature can be accurately constrained from the observed spectral energy distribution (corrected for reddening). Such analysis leads to a value that is higher than most spectroscopic results previously reported in the literature (~5950 K). We find that the ionization balance of Fe lines is satisfied only if a low Teff (~5950 K) is adopted. With our preferred Teff (6141 K), the mean iron abundance we obtain from the FeII lines is lower by about 0.15 dex than that from the FeI lines, and therefore, the discrepancy between the mean iron abundance from FeI and FeII lines cannot be explained by overionization by UV photons as the main non-LTE effect. We also comment on non-LTE effects and the importance of inelastic collisions with neutral H atoms in the determination of oxygen abundances in metal-poor stars from the 777 nm OI triplet. (Abridged)
Energy and Centrality Dependence of Chemical Freeze-out Thermodynamics parameters
N. Yu; F. Liu; K. Wu
2014-09-03T23:59:59.000Z
Driven by the Beam Energy Scan (BES) program at the RHIC, researches and discussions on the QCD phase diagram have flourished recently. In order to provide a reference from microscopic transport models, we performed a systematic analysis, using a multiphase transport (AMPT) model for the particle yields and a statistical model (THERMUS) for the thermal fit, for Au+Au collisions at $\\sqrt{s_{\\text{NN}}}$=7.7-200 GeV. It is found that at a fixed collision centrality the chemical freeze-out parameter, temperature $T_{\\text{ch}}$, increases with collision energy and somehow saturates at certain values of $T_{\\text{ch}}$ in collisions near $\\sqrt{s_{\\text{NN}}}$=10 GeV, indicating the limiting temperature in hadronic interactions; meanwhile the baryon chemical potential $\\mu_B$ decrease with the collision energy. The saturation temperature is also found to be dependent on partonic interaction. At a given collision energy, it is found that both $T_{\\text{ch}}$ and $\\mu_B$ decrease towards more peripheral collisions in the grand canonical approach. The energy and centrality dependence of other chemical freeze-out parameters, strangeness chemical potential $\\mu_S$, strangeness undersaturation factor $\\gamma_S$, and the volume of the fireball $V$ are also presented in this paper. The chemical potential ratio $\\mu_s/\\mu_B$ is also compared with lattice QCD calculation. The AMPT default model gives better descriptions on both the particle yields and the chemical freeze-out parameters than those from the AMPT string-melting model.
McDonald, I.; Zijlstra, A. A. [Jodrell Bank Centre for Astrophysics, Alan Turing Building, Manchester, M13 9PL (United Kingdom); Boyer, M. L.; Gordon, K.; Meixner, M.; Sewilo, M.; Shiao, B.; Whitney, B. [STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Van Loon, J. Th. [Lennard-Jones Laboratories, Keele University, ST5 5BG (United Kingdom); Hora, J. L.; Robitaille, T. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS 65, Cambridge, MA 02138-1516 (United States); Babler, B.; Meade, M. [Department of Astronomy, University of Wisconsin, Madison, 475 North Charter Street, Madison, WI 53706-1582 (United States); Block, M.; Misselt, K., E-mail: iain.mcdonald-2@manchester.ac.uk [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tuscon, AZ 85721 (United States)
2011-04-01T23:59:59.000Z
Fundamental parameters and time evolution of mass loss are investigated for post-main-sequence stars in the Galactic globular cluster 47 Tucanae (NGC 104). This is accomplished by fitting spectral energy distributions (SEDs) to existing optical and infrared photometry and spectroscopy, to produce a true Hertzsprung-Russell diagram. We confirm the cluster's distance as d = 4611{sup +213}{sub -200} pc and age as 12 {+-} 1 Gyr. Horizontal branch models appear to confirm that no more red giant branch mass loss occurs in 47 Tuc than in the more metal-poor {omega} Centauri, though difficulties arise due to inconsistencies between the models. Using our SEDs, we identify those stars that exhibit infrared excess, finding excess only among the brightest giants: dusty mass loss begins at a luminosity of {approx}1000 L{sub sun}, becoming ubiquitous above L = 2000 L{sub sun}. Recent claims of dust production around lower-luminosity giants cannot be reproduced, despite using the same archival Spitzer imagery.
Dean E. McLaughlin; Roeland P. van der Marel
2006-05-04T23:59:59.000Z
[Abridged]: We present a database of structural and dynamical properties for 153 spatially resolved star clusters (50 "young massive clusters" and 103 old globulars) in the Milky Way, the Large and Small Magellanic Clouds, and the Fornax dwarf spheroidal. This database complements and extends others in the literature, such as those of Harris, and Mackey & Gilmore. By fitting a number of models to the clusters' density profiles, we derive various characteristic surface brightnesses and radii; central potentials, velocity dispersions, and escape velocities; total luminosities, masses, and binding energies; phase-space densities and relaxation timescales; and ``kappa-space'' parameters. Population-synthesis models are used to predict intrinsic (B-V) colors, reddenings, and V-band mass-to-light ratios for the same 153 clusters plus another 63 globulars in the Milky Way, and we compare these predictions to the observed quantities where available. These results are intended to serve as the basis for future investigations of structural correlations and the fundamental plane of massive star clusters, including especially comparisons between the systemic properties of young and old clusters. We also address the question of what structural model fits each cluster best, and argue that the extended halos known to characterize many Magellanic Cloud clusters may be examples of the generic envelope structure of self-gravitating star clusters, not just transient features associated strictly with young age.
Algorithmic Thermodynamics John C. Baez
Tomkins, Andrew
Algorithmic Thermodynamics John C. Baez Department of Mathematics, University of California in statistical mechanics. This viewpoint allows us to apply many techniques developed for use in thermodynamics and chemical potential. We derive an analogue of the fundamental thermodynamic relation dE = TdS - PdV + Âµd
Thermodynamics Henri J.F. Jansen
Jansen, Henri J. F.
Thermodynamics Henri J.F. Jansen Department of Physics Oregon State University August 19, 2010 #12;II #12;Contents PART I. Thermodynamics Fundamentals 1 1 Basic Thermodynamics. 3 1.1 Introduction of Thermodynamics. . . . . . . . . . . . . . . . . . 12 1.4 First law: Energy
Thermodynamics of microstructure evolution: grain growth Victor L. Berdichevsky
Berdichevsky, Victor
Thermodynamics of microstructure evolution: grain growth Victor L. Berdichevsky Mechanical thermodynamic parameters, entropy of microstructure and temperature of microstruc- ture. It was claimed that there is "one more law of thermodynamics": entropy of microstructure must decay in isolated thermodynamic stable
Montana State University EMEC320 Thermodynamics I1 EMEC 320: THERMODYNAMICS I
Dyer, Bill
Montana State University EMEC320 Thermodynamics I1 EMEC 320: THERMODYNAMICS I (UPDATED AUG 27, 2011 thermodynamic concepts, first and second laws, open and closed systems, properties of ideal and real substances.E. and Borgnakke, C. ISBN 0-471-15232-3 "Fundamentals of Thermodynamics" COORDINATING INSTRUCTOR: Dr. Sarah Codd
Thermodynamics -Past, Present and Future Werner Ebeling
Ebeling, Werner
Thermodynamics - Past, Present and Future Werner Ebeling Institute of Physics, Humboldt, Clausius, Nernst and Einstein. We underline the key role of thermodynamic ideas in the scientific fundamental laws Thermodynamics as a branch of science was established in the 19th century by Sadi Carnot
THERMODYNAMICS Molecular Simulation of Multicomponent Reaction
Lisal, Martin
THERMODYNAMICS Molecular Simulation of Multicomponent Reaction and Phase Equilibria in MTBE Ternary System Martin Lisal´ E. Hala Laboratory of Thermodynamics, Institute of Chemical Process Fundamentals N1G 2W1, Canada Ivo Nezbeda E. Hala Laboratory of Thermodynamics, Institute of Chemical Process
NONEQUILIBRIUM QUANTUM STATISTICAL MECHANICS AND THERMODYNAMICS #
NONEQUILIBRIUM QUANTUM STATISTICAL MECHANICS AND THERMODYNAMICS # Walid K. Abou Salem + Institut f recent progress in deriving the fundamental laws of thermodynamics (0 th , 1 st and 2 nd Âlaw) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and di#erent reversible
Ronnie Kosloff
2013-05-10T23:59:59.000Z
Quantum thermodynamics addresses the emergence of thermodynamical laws from quantum mechanics. The link is based on the intimate connection of quantum thermodynamics with the theory of open quantum systems. Quantum mechanics inserts dynamics into thermodynamics giving a sound foundation to finite-time-thermodynamics. The emergence of the 0-law I-law II-law and III-law of thermodynamics from quantum considerations is presented. The emphasis is on consistence between the two theories which address the same subject from different foundations. We claim that inconsistency is the result of faulty analysis pointing to flaws in approximations.
Thermodynamic estimation: Ionic materials
Glasser, Leslie, E-mail: l.glasser@curtin.edu.au
2013-10-15T23:59:59.000Z
Thermodynamics establishes equilibrium relations among thermodynamic parameters (“properties”) and delineates the effects of variation of the thermodynamic functions (typically temperature and pressure) on those parameters. However, classical thermodynamics does not provide values for the necessary thermodynamic properties, which must be established by extra-thermodynamic means such as experiment, theoretical calculation, or empirical estimation. While many values may be found in the numerous collected tables in the literature, these are necessarily incomplete because either the experimental measurements have not been made or the materials may be hypothetical. The current paper presents a number of simple and relible estimation methods for thermodynamic properties, principally for ionic materials. The results may also be used as a check for obvious errors in published values. The estimation methods described are typically based on addition of properties of individual ions, or sums of properties of neutral ion groups (such as “double” salts, in the Simple Salt Approximation), or based upon correlations such as with formula unit volumes (Volume-Based Thermodynamics). - Graphical abstract: Thermodynamic properties of ionic materials may be readily estimated by summation of the properties of individual ions, by summation of the properties of ‘double salts’, and by correlation with formula volume. Such estimates may fill gaps in the literature, and may also be used as checks of published values. This simplicity arises from exploitation of the fact that repulsive energy terms are of short range and very similar across materials, while coulombic interactions provide a very large component of the attractive energy in ionic systems. Display Omitted - Highlights: • Estimation methods for thermodynamic properties of ionic materials are introduced. • Methods are based on summation of single ions, multiple salts, and correlations. • Heat capacity, entropy, lattice energy, enthalpy, Gibbs energy values are available.
Electrochemical thermodynamic measurement system
Reynier, Yvan (Meylan, FR); Yazami, Rachid (Los Angeles, CA); Fultz, Brent T. (Pasadena, CA)
2009-09-29T23:59:59.000Z
The present invention provides systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and electrochemical energy storage and conversion systems. Systems and methods of the present invention are configured for simultaneously collecting a suite of measurements characterizing a plurality of interconnected electrochemical and thermodynamic parameters relating to the electrode reaction state of advancement, voltage and temperature. Enhanced sensitivity provided by the present methods and systems combined with measurement conditions that reflect thermodynamically stabilized electrode conditions allow very accurate measurement of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and electrochemical systems, such as the energy, power density, current rate and the cycle life of an electrochemical cell.
EMEC 320: THERMODYNAMICS I Updated: June 27, 2012
Dyer, Bill
EMEC 320: THERMODYNAMICS I Updated: June 27, 2012 CATALOG DATA: Spring, 3 cr. Basic thermodynamic., Fundamentals of Thermodynamics, 7th ed., Wiley, ISBN 0-470-04192-7 INSTRUCTOR: Dr. Sarah Codd, 201 Roberts Hall of thermodynamics to engineering problems involving closed and open systems. · effectively apply and understand
Christian Frřnsdal
2014-08-22T23:59:59.000Z
Thermodynamics, when formulated as a dynamic action principle, allows a simple and effective integration into the General Theory of Gravitation.
Quantum thermodynamic cooling cycle
Jose P. Palao; Ronnie Kosloff; Jeffrey M. Gordon
2001-06-08T23:59:59.000Z
The quantum-mechanical and thermodynamic properties of a 3-level molecular cooling cycle are derived. An inadequacy of earlier models is rectified in accounting for the spontaneous emission and absorption associated with the coupling to the coherent driving field via an environmental reservoir. This additional coupling need not be dissipative, and can provide a thermal driving force - the quantum analog of classical absorption chillers. The dependence of the maximum attainable cooling rate on temperature, at ultra-low temperatures, is determined and shown to respect the recently-established fundamental bound based on the second and third laws of thermodynamics.
Quantum thermodynamic cooling cycle
Palao, J P; Gordon, J M; Palao, Jose P.; Kosloff, Ronnie; Gordon, Jeffrey M.
2001-01-01T23:59:59.000Z
The quantum-mechanical and thermodynamic properties of a 3-level molecular cooling cycle are derived. An inadequacy of earlier models is rectified in accounting for the spontaneous emission and absorption associated with the coupling to the coherent driving field via an environmental reservoir. This additional coupling need not be dissipative, and can provide a thermal driving force - the quantum analog of classical absorption chillers. The dependence of the maximum attainable cooling rate on temperature, at ultra-low temperatures, is determined and shown to respect the recently-established fundamental bound based on the second and third laws of thermodynamics.
Thermodynamics of Fractal Universe
Ahmad Sheykhi; Zeinab Teimoori; Bin Wang
2013-01-12T23:59:59.000Z
We investigate the thermodynamical properties of the apparent horizon in a fractal universe. We find that one can always rewrite the Friedmann equation of the fractal universe in the form of the entropy balance relation $ \\delta Q=T_h d{S_h}$, where $ \\delta Q $ and $ T_{h} $ are the energy flux and Unruh temperature seen by an accelerated observer just inside the apparent horizon. We find that the entropy $S_h$ consists two terms, the first one which obeys the usual area law and the second part which is the entropy production term due to nonequilibrium thermodynamics of fractal universe. This shows that in a fractal universe, a treatment with nonequilibrium thermodynamics of spacetime may be needed. We also study the generalized second law of thermodynamics in the framework of fractal universe. When the temperature of the apparent horizon and the matter fields inside the horizon are equal, i.e. $T=T_h$, the generalized second law of thermodynamics can be fulfilled provided the deceleration and the equation of state parameters ranges either as $-1 \\leq q thermodynamics can be secured in a fractal universe by suitably choosing the fractal parameter $\\beta$.
Irreversibility and the second law of thermodynamics
Seevinck, Michiel
Irreversibility and the second law of thermodynamics Jos Uffink July 5, 2001 1 INTRODUCTION The second law of thermodynamics has a curious status. Many modern physicists regard it as an obsolete relic thermodynamics, in which the state does not con- tain velocity-like parameters, one may take R to be the identity
Toward understanding the thermodynamics of TALSPEAK process. Medium effects on actinide complexation
Peter R Zalupski; Leigh R Martin; Ken Nash; Yoshinobu Nakamura; Masahiko Yamamoto
2009-07-01T23:59:59.000Z
The ingenious combination of lactate and diethylenetriamine-N,N,N’,N”,N”-pentaacetic acid (DTPA) as an aqueous actinide-complexing medium forms the basis of the successful separation of americium and curium from lanthanides known as the TALSPEAK process. While numerous reports in the prior literature have focused on the optimization of this solvent extraction system, considerably less attention has been devoted to the understanding of the basic thermodynamic features of the complex fluids responsible for the separation. The available thermochemical information of both lactate and DTPA protonation and metal complexation reactions are representative of the behavior of these ions under idealized conditions. Our previous studies of medium effects on lactate protonation suggest that significant departures from the speciation predicted based on reported thermodynamic values should be expected in the TALSPEAK aqueous environment. Thermodynamic parameters describing the separation chemistry of this process thus require further examination at conditions significantly removed from conventional ideal systems commonly employed in fundamental solution chemistry. Such thermodynamic characterization is the key to predictive modelling of TALSPEAK. Improved understanding will, in principle, allow process technologists to more efficiently respond to off-normal conditions during large scale process operation. In this report, the results of calorimetric and potentiometric investigations of the effects of aqueous electrolytes on the thermodynamic parameters for lactate protonation and lactate complexation of americium and neodymium will be presented. Studies on the lactate protonation equilibrium will clearly illustrate distinct thermodynamic variations between strong electrolyte aqueous systems and buffered lactate environment.
ChE 210A M. F. Doherty Thermodynamics
Bigelow, Stephen
ChE 210A M. F. Doherty Thermodynamics Instructor: Michael F. Doherty (mfd@engineering.ucsb.edu, 893 is an introduction to the fundamentals of classical and statistical thermodynamics. We focus on equilibrium are formulated using either classical or statistical thermodynamics, and these methods have found wide
Thermodynamics of Statistical Inference by Cells Alex H. Lang,1,*
Mora, Thierry
Thermodynamics of Statistical Inference by Cells Alex H. Lang,1,* Charles K. Fisher,1 Thierry Mora June 2014; published 3 October 2014) The deep connection between thermodynamics, computation that thermodynamics also places fundamental constraints on statistical estimation and learning. To do so, we
Krebs, M. E.
1990-01-01T23:59:59.000Z
FUNDAMENTAL DESICCANTS MARK E. KREBS Gas Utllizatlon Engineer Southern Unlon Gas Company Austln. Texas ABSTRACT The purpose of this paper is to familiarize the mainstream HVAC and facility management community with the technical concepts... for traditional HVAC (heating, ventilation and air conditioning) systems. Control air impurity level required for health and/or process requirements Dust. pollen, bacteria, viruses and radon gas are naturally occurring impurities in the air we breath. Air may...
Thermodynamics of error correction
Sartori, Pablo
2015-01-01T23:59:59.000Z
Information processing at the molecular scale is limited by thermal fluctuations. This can cause undesired consequences in copying information since thermal noise can lead to errors that can compromise the functionality of the copy. For example, a high error rate during DNA duplication can lead to cell death. Given the importance of accurate copying at the molecular scale, it is fundamental to understand its thermodynamic features. In this paper, we derive a universal expression for the copy error as a function of entropy production and dissipated work of the process. Its derivation is based on the second law of thermodynamics, hence its validity is independent of the details of the molecular machinery, be it any polymerase or artificial copying device. Using this expression, we find that information can be copied in three different regimes. In two of them, work is dissipated to either increase or decrease the error. In the third regime, the protocol extracts work while correcting errors, reminiscent of a Max...
Friedmann Thermodynamics and the Geometry of the Universe
Selcuk S. Bayin
2008-04-01T23:59:59.000Z
In a recent article we have introduced Friedmann thermodynamics, where certain geometric parameters in Friedmann models are treated like their thermodynamic counterparts (temperature, entropy, Gibbs potential etc.). This model has the advantage of allowing us to determine the geometry of the universe by thermodynamic stability arguments. In this article we review connections between thermodynamics, geometry and cosmology.
Thermodynamic laws beyond free energy relations
Matteo Lostaglio; David Jennings; Terry Rudolph
2014-12-11T23:59:59.000Z
Recent studies have developed fundamental limitations on nanoscale thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state we arrive at an additional, independent set of thermodynamic laws, that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilard engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to thermodynamic work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between thermodynamics and entanglement theory.
Local non-equilibrium thermodynamics
Jinwoo, Lee
2015-01-01T23:59:59.000Z
Local Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics over a finite time interval for small scale systems. However, given that entropy is an ensemble property, it has never been clear how one can assign such a quantity locally. Given such a fundamental omission in our knowledge, we construct a new ensemble composed of trajectories reaching an individual microstate, and show that locally defined entropy, information, and free energy are properties of the ensemble, or trajectory-independent true thermodynamic potentials. We find that the Boltzmann-Gibbs distribution and Landauer's principle can be generalized naturally as properties of the ensemble, and that trajectory-free state functions of the ensemble govern the exact mechanism of non-equilibrium relaxation.
Local non-equilibrium thermodynamics
Lee Jinwoo; Hajime Tanaka
2015-01-16T23:59:59.000Z
Local Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics over a finite time interval for small scale systems. However, given that entropy is an ensemble property, it has never been clear how one can assign such a quantity locally. Given such a fundamental omission in our knowledge, we construct a new ensemble composed of trajectories reaching an individual microstate, and show that locally defined entropy, information, and free energy are properties of the ensemble, or trajectory-independent true thermodynamic potentials. We find that the Boltzmann-Gibbs distribution and Landauer's principle can be generalized naturally as properties of the ensemble, and that trajectory-free state functions of the ensemble govern the exact mechanism of non-equilibrium relaxation.
Thermodynamics of error correction
Pablo Sartori; Simone Pigolotti
2015-04-24T23:59:59.000Z
Information processing at the molecular scale is limited by thermal fluctuations. This can cause undesired consequences in copying information since thermal noise can lead to errors that can compromise the functionality of the copy. For example, a high error rate during DNA duplication can lead to cell death. Given the importance of accurate copying at the molecular scale, it is fundamental to understand its thermodynamic features. In this paper, we derive a universal expression for the copy error as a function of entropy production and dissipated work of the process. Its derivation is based on the second law of thermodynamics, hence its validity is independent of the details of the molecular machinery, be it any polymerase or artificial copying device. Using this expression, we find that information can be copied in three different regimes. In two of them, work is dissipated to either increase or decrease the error. In the third regime, the protocol extracts work while correcting errors, reminiscent of a Maxwell demon. As a case study, we apply our framework to study a copy protocol assisted by kinetic proofreading, and show that it can operate in any of these three regimes. We finally show that, for any effective proofreading scheme, error reduction is limited by the chemical driving of the proofreading reaction.
Z. Fodor
2007-11-02T23:59:59.000Z
Recent results on QCD thermodynamics are presented. The nature of the T>0 transition is determined, which turns out to be an analytic cross-over. The absolute scale for this transition is calculated. The temperature dependent static potential is given. The results were obtained by using a Symanzik improved gauge and stout-link improved fermionic action. In order to approach the continuum limit four different sets of lattice spacings were used with temporal extensions N_t=4, 6, 8 and 10 (they correspond to lattice spacings a \\sim 0.3, 0.2, 0.15 and 0.12 fm). A new technique is presented, which --in contrast to earlier methods-- enables one to determine the equation of state at very large temperatures.
Thermodynamics Review and Relations
Thermodynamics Review and Relations Review · Gas filled piston Motivation Thermodynamics the efficiency of steam engine. Only macroscopic continues states of matter are con- sidered. Thermodynamics of thermodynamics is essential since it easily to statistical mechanics. Definitions and Convention Signs The sign
Sandia National Laboratories: correct thermodynamic parameters
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Sandia received funding for its "Mechanistic Modeling Framework for Predicting Extreme Battery Response: Coupled Hierarchical Models for Thermal, Mechanical, Electrical and...
Adsorption Thermodynamics and Intrinsic Activation Parameters for
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About Become agovEducationWelcome
Thermodynamics of an accelerated expanding universe
Bin Wang; Yungui Gong; Elcio Abdalla
2005-11-10T23:59:59.000Z
We investigate the laws of thermodynamics in an accelerating universe driven by dark energy with a time-dependent equation of state. In the case we consider that the physically relevant part of the Universe is that envelopped by the dynamical apparent horizon, we have shown that both the first law and second law of thermodynamics are satisfied. On the other hand, if the boundary of the Universe is considered to be the cosmological event horizon the thermodynamical description based on the definitions of boundary entropy and temperature breaks down. No parameter redefinition can rescue the thermodynamics laws from such a fate, rendering the cosmological event horizon unphysical from the point of view of the laws of thermodynamics.
THERMODYNAMICS AND MECHANISMS OF SINTERING
Pask, J.A.
2011-01-01T23:59:59.000Z
E. Hoge and Joseph A. Pask, "Thermodynamics of So:!.id StateJoseph A. Pask, "Thermodynamics and Geometric Considerations8419 r- ,y / ( /)~; - - I THERMODYNAMICS AND MECHANISMS OF
Qualitative insights on fundamental mechanics
G. N. Mardari
2006-11-10T23:59:59.000Z
The gap between classical mechanics and quantum mechanics has an important interpretive implication: the Universe must have an irreducible fundamental level, which determines the properties of matter at higher levels of organization. We show that the main parameters of any fundamental model must be theory-independent. They cannot be predicted, because they cannot have internal causes. However, it is possible to describe them in the language of classical mechanics. We invoke philosophical reasons in favor of a specific model, which treats particles as sources of real waves. Experimental considerations for gravitational, electromagnetic, and quantum phenomena are outlined.
Rigorous and General Definition of Thermodynamic Entropy
Gian Paolo Beretta; Enzo Zanchini
2010-10-05T23:59:59.000Z
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology, materials science, energy engineering, etc. --- require understanding thermodynamic entropy beyond the equilibrium realm of its traditional definition. This paper presents a rigorous logical scheme that provides a generalized definition of entropy free of the usual unnecessary assumptions which constrain the theory to the equilibrium domain. The scheme is based on carefully worded operative definitions for all the fundamental concepts employed, including those of system, property, state, isolated system, environment, process, separable system, system uncorrelated from its environment, and parameters of a system. The treatment considers also systems with movable internal walls and/or semipermeable walls, with chemical reactions and/or external force fields, and with small numbers of particles. The definition of reversible process is revised by introducing the new concept of scenario. The definition of entropy involves neither the concept of heat nor that of quasistatic process; it applies to both equilibrium and nonequilibrium states. The role of correlations on the domain of definition and on the additivity of energy and entropy is discussed: it is proved that energy is defined and additive for all separable systems, while entropy is defined and additive only for separable systems uncorrelated from their environment; decorrelation entropy is defined. The definitions of energy and entropy are extended rigorously to open systems. Finally, to complete the discussion, the existence of the fundamental relation for stable equilibrium states is proved, in our context, for both closed and open systems.
Cambridge, University of
I Masters thesis Thermodynamics of Solutes in Cementite Using First-Principles Calculations JangFirst-PrinciplesCalculations Jang,JaeHoon #12;III cementite Thermodynamics of Solutes in Cementite Using First-Principles Calculations #12;IV Thermodynamics of Solutes in Cementite Using First-Principles Calculations By Jang, Jae
Climate Sciences: Atmospheric Thermodynamics
Russell, Lynn
1 Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http://aerosol.ucsd.edu/courses.html Text: Curry & Webster Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 Energy Climate Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http
Atmospheric Thermodynamics Composition
Russell, Lynn
1 Atmospheric Thermodynamics Ch1 Composition Ch2 Laws Ch3 Transfers Ch12 EnergyBalance Ch4 Water Ch Sciences: Atmospheric Thermodynamics Instructor: Lynn Russell, NH343 http #12;2 Review from Ch. 1 · Thermodynamic quantities · Composition · Pressure · Density · Temperature
Kostic, Milivoje M.
SECOND LAW OF THERMODYNAMICS: STATUS AND CHALLENGES San Diego, California, USA 14 15 June 2011 The First Law of energy conservation was even known (Joule 1843) and long before Thermodynamic concepts were, including this one. The Laws of Thermodynamics have much wider, including philosophical significance
Virginia Tech
Spring 2014 Thermodynamics - 1 Consider an insulated (adiabatic) piston and cylinder arrangement. Confirm this statement using the second law of thermodynamics. (b) (20) She now wants to calculate the work done by the air on the piston by using the first law of thermodynamics. Do this. Draw a T
Computational Reality X Thermodynamics
Berlin,Technische Universität
Computational Reality X Thermodynamics B. Emek Abali @ LKM - TU Berlin Abstract After solving energy density. This is actually a branch of thermodynamics, though this question never gets its full answer in a thermodynamics' class. Here we will show one possibility of deriving the energy formulation
Particle Production and Universal Thermodynamics
Subhajit Saha; Subenoy Chakraborty
2014-12-21T23:59:59.000Z
In the present work, particle creation mechanism is employed to the Universe as a thermodynamical system. The universe is considered to be spatially flat FRW model and cosmic fluid is chosen as perfect fluid with barotropic equation of state: p=(\\gamma -1)\\rho . By proper choice of the particle creation rate, entropy and temperature will be determined at various stages of evolution of the Universe. Finally, using the deceleration parameter as a function of the redshift parameter based on recent observations, particle creation rate will be evaluated and its variation at different epochs will be shown graphically.
Particle Production and Universal Thermodynamics
Subhajit Saha; Subenoy Chakraborty
2015-07-06T23:59:59.000Z
In the present work, particle creation mechanism has been employed to the Universe as a thermodynamical system. The Universe is considered to be a spatially flat FRW model and cosmic fluid is chosen as a perfect fluid with a barotropic equation of state -- $p = (\\gamma -1)\\rho$. By proper choice of the particle creation rate, expressions for the entropy and temperature have been determined at various stages of evolution of the Universe. Finally, using the deceleration parameter $q$ as a function of the redshift parameter $z$ based on recent observations, the particle creation rate has been evaluated and its variation at different epochs have been shown graphically.
Thermodynamics and scale relativity
Robert Carroll
2011-10-13T23:59:59.000Z
It is shown how the fractal paths of scale relativity (following Nottale) can be introduced into a thermodynamical context (following Asadov-Kechkin).
Introduction Systems Engineering Fundamentals ENGINEERING
Rhoads, James
Introduction Systems Engineering Fundamentals i SYSTEMS ENGINEERING FUNDAMENTALS January 2001;Systems Engineering Fundamentals Introduction ii #12;Introduction Systems Engineering Fundamentals iii ............................................................................................................................................. iv PART 1. INTRODUCTION Chapter 1. Introduction to Systems Engineering Management
Addressing the Crisis in Fundamental Physics
Christopher W. Stubbs
2007-12-18T23:59:59.000Z
I present the case for fundamental physics experiments in space playing an important role in addressing the current "dark energy'' crisis. If cosmological observations continue to favor a value of the dark energy equation of state parameter w=-1, with no change over cosmic time, then we will have difficulty understanding this new fundamental physics. We will then face a very real risk of stagnation unless we detect some other experimental anomaly. The advantages of space-based experiments could prove invaluable in the search for the a more complete understanding of dark energy. This talk was delivered at the start of the Fundamental Physics Research in Space Workshop in May 2006.
ON THE THERMODYNAMICS AND KINETICS OF THE COOPERATIVE BINDING OF BACTERIOPHAGE T4-
Kowalczykowski, Stephen C.
ON THE THERMODYNAMICS AND KINETICS OF THE COOPERATIVE BINDING OF BACTERIOPHAGE T4- CODED GENE 32 of thermodynamic, and preliminary kinetic, studies on the molecular details and specificity of interaction of phage into the molecular origins of binding cooperativity is obtained by determining these thermodynamic parameters also
The Fundamental Plane of Quasars
Timothy S. Hamilton; Stefano Casertano; David A. Turnshek
2005-11-17T23:59:59.000Z
We present results from an archival study of 70 medium-redshift QSOs observed with the Wide Field Planetary Camera 2 on board the Hubble Space Telescope. The QSOs have magnitudes M_V < -23 (total nuclear plus host light) and redshifts 0.06 < z < 0.46. A close relationship between QSO host and nucleus is found by examining multiple parameters at once. A principal components analysis shows that 3 nuclear and host properties are related in a kind of fundamental plane: nuclear luminosity and the size and effective surface magnitude of the bulge. Using optical nuclear luminosity, this relationship explains 95.9% of the variance in the overall sample, while 94.9% of the variance is accounted for if we use x-ray nuclear luminosity. The form of this QSO fundamental plane shows similarities to the well-studied fundamental plane of elliptical galaxies, and we examine the possible relationship between them as well as the difficulties involved in establishing this connection. The key to the relationship might lie in the fueling mechanism of the central black hole.
Prof. Kostic's Research & Scholarly Interests and Activities Fundamentals and Application of Energy
Kostic, Milivoje M.
and heat transfer fundamentals; the second law of thermodynamics and entropy; energy efficiency-Emission and Propagation: Steady-state, mass-energy transfer is depicted through heat conduction plate (right processes (or changes), thus indivisible from time. Actually, energy is "the building block" and fundamental
From Quantum Mechanics to Thermodynamics?
Steinhoff, Heinz-Jürgen
From Quantum Mechanics to Thermodynamics? Dresden, 22.11.2004 Jochen Gemmer Universit¨at Osnabr to thermodynamical behavior · Quantum approach to thermodynamical behavior · The route to equilibrium · Summary of thermodynamical behavior entirely on the basis of Hamilton models and Schr¨odinger-type quantum dynamics. · define
Extensivity and Relativistic Thermodynamics
J. Dunning-Davies
2007-06-27T23:59:59.000Z
The mathematical properties associated with the widely accepted concept of the extensivity of many of the common thermodynamic variables are examined and some of their consequences considered. The possible conflict between some of these and currently accepted results of special relativistic thermodynamics is highlighted. Although several questions are raised, answers are not advanced as this seems an area demanding calm, widespread reflection which could conceivably lead to radical revision of part, or parts, of theoretical physics.
Stochastic equations for thermodynamics
Tsekov, R
2015-01-01T23:59:59.000Z
The applicability of stochastic differential equations to thermodynamics is considered and a new form, different from the classical Ito and Stratonovich forms, is introduced. It is shown that the new presentation is more appropriate for the description of thermodynamic fluctuations. The range of validity of the Boltzmann-Einstein principle is also discussed and a generalized alternative is proposed. Both expressions coincide in the small fluctuation limit, providing a normal distribution density.
Thermodynamics of N-dimensional quantum walks
Alejandro Romanelli; Raul Donangelo; Renato Portugal; Franklin L. Marquezino
2014-08-22T23:59:59.000Z
The entanglement between the position and coin state of a $N$-dimensional quantum walker is shown to lead to a thermodynamic theory. The entropy, in this thermodynamics, is associated to the reduced density operator for the evolution of chirality, taking a partial trace over positions. From the asymptotic reduced density matrix it is possible to define thermodynamic quantities, such as the asymptotic entanglement entropy, temperature, Helmholz free energy, etc. We study in detail the case of a $2$-dimensional quantum walk, in the case of two different initial conditions: a non-separable coin-position initial state, and a separable one. The resulting entanglement temperature is presented as function of the parameters of the system and those of the initial conditions.
Black Hole Thermodynamics in Modified Gravity
Jonas R. Mureika; John W. Moffat; Mir Faizal
2015-03-03T23:59:59.000Z
We analyze the thermodynamics of a non-rotating and rotating black hole in a modified theory of gravity that includes scalar and vector modifications to general relativity, which results in a modified gravitational constant $G = G_N(1+\\alpha)$ and a new gravitational charge $Q = \\sqrt{\\alpha G_N}M$. The influence of the parameter $\\alpha$ alters the non-rotating black hole's lifetime, temperature and entropy profiles from the standard Schwarzschild case. The thermodynamics of a rotating black hole is analyzed and it is shown to possess stable, cold remnants. The thermodynamic properties of a vacuum solution regular at $r=0$ are investigated and the solution without a horizon called a "gray hole" is not expected to possess an information loss problem.
EWONAP Procurement Fundamentals
Office of Energy Efficiency and Renewable Energy (EERE)
HUD's Eastern Woodlands Office of Native American Programs in collaboration with the Seminole Tribe of Florida Native Learning Center invites you to attend the Procurement Fundamentals training instructed by Vince Franco, Compliance & Resource Development Director of the Native Learning Center in Atlanta, Georgia on September 8-9, 2014.
Mirkin, Sergei
DNA Topology: Fundamentals Sergei M Mirkin, University of Illinois at Chicago, Illinois, USA Topological characteristics of DNA and specifically DNA supercoiling influence all major DNA transactions in living cells. DNA supercoiling induces the formation of unusual secondary structure by specific DNA
Description of quantum coherence in thermodynamic processes requires constraints beyond free energy
Matteo Lostaglio; David Jennings; Terry Rudolph
2015-03-16T23:59:59.000Z
Recent studies have developed fundamental limitations on nanoscale thermodynamics, in terms of a set of independent free energy relations. Here we show that free energy relations cannot properly describe quantum coherence in thermodynamic processes. By casting time-asymmetry as a quantifiable, fundamental resource of a quantum state we arrive at an additional, independent set of thermodynamic constraints that naturally extend the existing ones. These asymmetry relations reveal that the traditional Szilard engine argument does not extend automatically to quantum coherences, but instead only relational coherences in a multipartite scenario can contribute to thermodynamic work. We find that coherence transformations are always irreversible. Our results also reveal additional structural parallels between thermodynamics and the theory of entanglement.
Thermodynamics of Ideal Gas in Cosmology
Ying-Qiu Gu
2009-10-04T23:59:59.000Z
The equation of state and the state functions for the gravitational source are necessary conditions for solving cosmological model and stellar structure. The usual treatments are directly based on the laws of thermodynamics, and the physical meanings of some concepts are obscure. This letter show that, we can actually derive all explicit fundamental state functions for the ideal gas in the context of cosmology via rigorous dynamical and statistical calculation. These relations have clear physical meanings, and are valid in both non-relativistic and ultra-relativistic cases. Some features of the equation of state are important for a stable structure of a star with huge mass.
From Thermodynamics to the Bound on Viscosity
Shahar Hod
2009-07-07T23:59:59.000Z
We show that the generalized second law of thermodynamics may shed much light on the mysterious Kovtun-Son-Starinets (KSS) bound on the ratio of viscosity to entropy density. In particular, we obtain the lower bound $\\eta/s +O(\\eta^3/s^3)\\geq 1/4\\pi$. Furthermore, for conformal field theories we obtain a new fundamental bound on the value of the relaxation coefficient $\\tau_{\\pi}$ of causal hydrodynamics, which has been the focus of much recent attention: $(\\tau_{\\pi}T)^2\\geq {{(\\sqrt{3}-1)}/{2\\pi^2}}$.
Masses of Fundamental Particles
Hidezumi Terazawa
2014-06-11T23:59:59.000Z
In the original paper entitled, "Masses of Fundamental Particles"(arXiv:1109.3705v5, 10 Feb 2012), not only the masses of fundamental particles including the weak bosons, Higgs boson, quarks, and leptons, but also the mixing angles of quarks and those of neutrinos are all explained and/or predicted in the unified composite models of quarks and leptons successfully. In this addendum entitled, "Higgs Boson Mass in the Minimal Unified Subquark Model", it is emphasized that the Higgs boson mass is predicted to be about 130Gev in the minimal unified subquark model, which agrees well with the experimental values of 125-126GeV recently found by the ATLAS and CMS Collaborations at the LHC.
Thermodynamics of electroweak matter
A. Gynther
2006-09-21T23:59:59.000Z
This paper is a slightly modified version of the introductory part of a PhD thesis, also containing the articles hep-ph/0303019, hep-ph/0510375 and hep-ph/0512177. We provide a short history of the research of electroweak thermodynamics and a brief introduction to the theory as well as to the necessary theoretical tools needed to work at finite temperatures. We then review computations regarding the pressure of electroweak matter at high temperatures (the full expression of the perturbative expansion of the pressure is given in the appendix) and the electroweak phase diagram at finite chemical potentials. Finally, we compare electroweak and QCD thermodynamics.
Jeremy Dunning-Davies; David Sands
2011-05-17T23:59:59.000Z
For a long time now, confusion has existed in the minds of many over the meaning of various concepts in thermodynamics. Recently, this point has been brought to people's attention by two articles appearing on the well-known archive (arxiv) web site. The content of these two pieces serves to illustrate many of the problems and has occasioned the construction of this answer to at least some of them. The position of the axiom proposed by Carath\\'eodory is central in this matter and here its position is clarified and secured within the framework of thermodynamics. In particular, its relation to the First Law is examined and justified.
Zeroth Law compatibility of non-additive thermodynamics
T. S. Biró; P. Ván
2011-06-02T23:59:59.000Z
Non-extensive thermodynamics was criticized among others by stating that the Zeroth Law cannot be satisfied with non-additive composition rules. In this paper we determine the general functional form of those non-additive composition rules which are compatible with the Zeroth Law of thermodynamics. We find that this general form is additive for the formal logarithms of the original quantities and the familiar relations of thermodynamics apply to these. Our result offers a possible solution to the longstanding problem about equilibrium between extensive and non-extensive systems or systems with different non-extensivity parameters.
Methods for thermodynamic evaluation of battery state of health
Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T
2013-05-21T23:59:59.000Z
Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.
Thermodynamical description of the ghost dark energy model
Honarvaryan, M; Moradpour, H
2015-01-01T23:59:59.000Z
In this paper, we point out thermodynamical description of ghost dark energy and its generalization to the early universe. Thereinafter, we find expressions for the entropy changes of these dark energy candidates. In addition, considering thermal fluctuations, thermodynamics of the dark energy component interacting with a dark matter sector is addressed. {We will also find the effects of considering the coincidence problem on the mutual interaction between the dark sectors, and thus the equation of state parameter of dark energy.} Finally, we derive a relation between the mutual interaction of the dark components of the universe, accelerated with the either ghost dark energy or its generalization, and the thermodynamic fluctuations.
Sparks, Donald L.
Thermodynamics of Potassium Exchange in Soil Using a Kinetics Approach1 D. L. SPARKS AND P. M. JARDINEZ ABSTRACT Thermodynamics of potassium (K) exchange using a kinetics ap- proach was investigated that more energy was needed to desorb K than to adsorb K. Thermodynamic and pseudother- modynamic parameters
Stretch Efficiency - Thermodynamic Analysis of New Combustion...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037) Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037)...
Fundamental experiments in velocimetry
Briggs, Matthew Ellsworth [Los Alamos National Laboratory; Hull, Larry [Los Alamos National Laboratory; Shinas, Michael [Los Alamos National Laboratory
2009-01-01T23:59:59.000Z
One can understand what velocimetry does and does not measure by understanding a few fundamental experiments. Photon Doppler Velocimetry (PDV) is an interferometer that will produce fringe shifts when the length of one of the legs changes, so we might expect the fringes to change whenever the distance from the probe to the target changes. However, by making PDV measurements of tilted moving surfaces, we have shown that fringe shifts from diffuse surfaces are actually measured only from the changes caused by the component of velocity along the beam. This is an important simplification in the interpretation of PDV results, arising because surface roughness randomizes the scattered phases.
Thermodynamics and gravitational collapse
Daniele Malafarina; Pankaj S. Joshi
2011-06-19T23:59:59.000Z
It is known now that a typical gravitational collapse in general relativity, evolving from regular initial data and under physically reasonable conditions would end in either a black hole or a naked singularity final state. An important question that needs to be answered in this connection is, whether the analogues of the laws of thermodynamics, as formulated for relativistic horizons are respected by the dynamical spacetimes for collapse that end in the formation of a naked singularity. We investigate here the thermodynamical behaviour of the dynamical horizons that form in spherically symmetric gravitational collapse and we show that the first and second laws of black hole thermodynamics, as extended to dynamical spacetimes in a suitable manner, are not violated whether the collapse ends in a black hole or a naked singularity. We then make a distinction between the naked singularities that result from gravitational collapse, and those that exist in solutions of Einstein equations in vacuum axially symmetric and stationary spacetimes, and discuss their connection with thermodynamics in view of the cosmic censorship conjecture and the validity of the third law of black hole mechanics.
2, 15151615, 2005 Thermodynamic
Paris-Sud XI, Université de
- tions of the standard molal thermodynamic properties of ionized proteins as a func- tion of temperature and T at high temperature were taken from the recent literature, which ensures an internally consistent revision, pressure, composition and intra- and extracellular chemical potentials of O2, H2, NH3, H2PO4 and CO2. 1516
Thermodynamics CHE 361, 4 credits
Fuchs, Alan
Thermodynamics CHE 361, 4 credits Spring Semester 2006 Tuesday and Thursday, 11:00 12:15PM, LME Chemical Engineering Thermodynamics", Prentice Hall PTR, 1999. Prerequisites Calculus III (Math 283 of this course, students will understand the first and second laws, PVT properties of fluids, thermodynamic
Phenomenological thermodynamics in a nutshell
Neumaier, Arnold
Phenomenological thermodynamics in a nutshell Arnold Neumaier FakultÂ¨at fÂ¨ur Mathematik, Universit of phenomeno- logical equilibrium thermodynamics for single-phase systems in the absence of chemical reactions-known thermodynamics book the basic concepts by means of a few postulates from which every- thing else follows. His
Kinetic equilibrium and relativistic thermodynamics
P. Ván
2011-02-01T23:59:59.000Z
Relativistic thermodynamics is treated from the point of view of kinetic theory. It is shown that the generalized J\\"uttner distribution suggested in [1] is compatible with kinetic equilibrium. The requirement of compatibility of kinetic and thermodynamic equilibrium reveals several generalizations of the Gibbs relation where the velocity field is an independent thermodynamic variable.
Contact Symmetries and Hamiltonian Thermodynamics
A. Bravetti; C. S. Lopez-Monsalvo; F. Nettel
2015-02-22T23:59:59.000Z
It has been shown that contact geometry is the proper framework underlying classical thermodynamics and that thermodynamic fluctuations are captured by an additional metric structure related to Fisher's Information Matrix. In this work we analyze several unaddressed aspects about the application of contact and metric geometry to thermodynamics. We consider here the Thermodynamic Phase Space and start by investigating the role of gauge transformations and Legendre symmetries for metric contact manifolds and their significance in thermodynamics. Then we present a novel mathematical characterization of first order phase transitions as equilibrium processes on the Thermodynamic Phase Space for which the Legendre symmetry is broken. Moreover, we use contact Hamiltonian dynamics to represent thermodynamic processes in a way that resembles the classical Hamiltonian formulation of conservative mechanics and we show that the relevant Hamiltonian coincides with the irreversible entropy production along thermodynamic processes. Therefore, we use such property to give a geometric definition of thermodynamically admissible fluctuations according to the Second Law of thermodynamics. Finally, we show that the length of a curve describing a thermodynamic process measures its entropy production.
Fundamental Physics Explored with High Intensity Laser
T. Tajima; K. Homma
2012-09-13T23:59:59.000Z
Over the last Century the method of particle acceleration to high energies has become the prime approach to explore the fundamental nature of matter in laboratory. It appears that the latest search of the contemporary accelerator based on the colliders shows a sign of saturation (or at least a slow-down) in increasing its energy and other necessary parameters to extend this frontier. We suggest two pronged approach enabled by the recent progress in high intensity lasers.
Harlan H. Bengtson; Harlan H. Bengtson
Solar energy travels from the sun to the earth in the form of electromagnetic radiation. In this course properties of electromagnetic radiation will be discussed and basic calculations for electromagnetic radiation will be described. Several solar position parameters will be discussed along with means of calculating
Thermodynamics of Chaplygin gas
Yun Soo Myung
2011-05-11T23:59:59.000Z
We clarify thermodynamics of the Chaplygin gas by introducing the integrability condition. All thermal quantities are derived as functions of either volume or temperature. Importantly, we find a new general equation of state, describing the Chaplygin gas completely. We confirm that the Chaplygin gas could show a unified picture of dark matter and energy which cools down through the universe expansion without any critical point (phase transition).
Gravity, Dimension, Equilibrium, & Thermodynamics
Jerome Perez
2006-03-30T23:59:59.000Z
Is it actually possible to interpret gravitation as space's property in a pure classical way. Then, we note that extended self-gravitating system equilibrium depends directly on the number of dimension of the space in which it evolves. Given those precisions, we review the principal thermodynamical knowledge in the context of classical gravity with arbitrary dimension of space. Stability analyses for bounded 3D systems, namely the Antonov instability paradigm, are then rapproched to some amazing properties of globular clusters and galaxies.
Classical QGP : IV. Thermodynamics
Sungtae Cho; Ismail Zahed
2008-12-09T23:59:59.000Z
We construct the equation of a state of the classical QGP valid for all values of Gamma=V/K, the ratio of the mean Coulomb to kinetic energy. By enforcing the Gibbs relations, we derive the pertinent pressure and entropy densities for all Gamma. For the case of an SU(2) classical gluonic plasma our results compare well with lattice simulations. We show that the strongly coupled component of the classical QGP contributes significantly to the bulk thermodynamics across T_c.
Neven Bilic
2010-09-27T23:59:59.000Z
Thermodynamic properties of dark energy are discussed assuming that dark energy is described in terms of a selfinteracting complex scalar. We first show that, under certain assumptions, selfinteracting complex scalar field theories are equivalent to purely kinetic k-essence models. Then we analyze the themal properties of k-essence and in particular we show that dark-energy in the phantom regime does not necessarily yield negative entropy.
Thermodynamic modeling for organic solid precipitation
Chung, T.H.
1992-12-01T23:59:59.000Z
A generalized predictive model which is based on thermodynamic principle for solid-liquid phase equilibrium has been developed for organic solid precipitation. The model takes into account the effects of temperature, composition, and activity coefficient on the solubility of wax and asphaltenes in organic solutions. The solid-liquid equilibrium K-value is expressed as a function of the heat of melting, melting point temperature, solubility parameter, and the molar volume of each component in the solution. All these parameters have been correlated with molecular weight. Thus, the model can be applied to crude oil systems. The model has been tested with experimental data for wax formation and asphaltene precipitation. The predicted wax appearance temperature is very close to the measured temperature. The model not only can match the measured asphaltene solubility data but also can be used to predict the solubility of asphaltene in organic solvents or crude oils. The model assumes that asphaltenes are dissolved in oil in a true liquid state, not in colloidal suspension, and the precipitation-dissolution process is reversible by changing thermodynamic conditions. The model is thermodynamically consistent and has no ambiguous assumptions.
Thermodynamics of free Domain Wall fermions
R. V. Gavai; Sayantan Sharma
2008-11-19T23:59:59.000Z
Studying various thermodynamic quantities for the free domain wall fermions for both finite and infinite fifth dimensional extent N_5, we find that the lattice corrections are minimum for $N_T\\geq10$ for both energy density and susceptibility, for its irrelevant parameter M in the range 1.45-1.50. The correction terms are, however, quite large for small lattice sizes of $N_T\\leq8$. We propose modifications of the domain wall operator, as well as the overlap operator, to reduce the finite cut-off effects to within 10% of the continuum results of the thermodynamic quantities for the currently used N_T=6-8 lattices. Incorporating chemical potential, we show that \\mu^2 divergences are absent for a large class of such domain wall fermion actions although the chiral symmetry is broken for $\\mu\
Thermodynamics and Spectroscopy of Schwarzschild black hole surrounded by Quintessence
R Tharanath; V C Kuriakose
2013-01-11T23:59:59.000Z
The thermodynamic and spectroscopic behaviour of Schwarzschild black hole surrounded by quintessence are studied. We have derived the thermodynamic quantities and studied their behaviour for different values of quintessence parameter. We put the background space-time into the Kruskal-like coordinate to find the period with respect to Elucidean time. Also assuming that the adiabatic invariant obeys Bohr-Sommerfeld quantization rule, detailed study of area spectrum and entropy spectrum have been done for special cases of the quintessece state parameter. We find that the spectra are equally spaced.
Thermodynamics of scalar-tensor theory with non-minimally derivative coupling
Yumei Huang; Yungui Gong; Dicong Liang; Zhu Yi
2015-04-06T23:59:59.000Z
With the usual definitions for the entropy and the temperature associated with the apparent horizon, we show that the unified first law on the apparent horizon is equivalent to the Friedmann equation for the scalar-tensor theory with non-minimally derivative coupling. The second law of thermodynamics on the apparent horizon is also satisfied. The results support a deep and fundamental connection between gravitation, thermodynamics and quantum theory.
Thermodynamics of scalar-tensor theory with non-minimally derivative coupling
Huang, Yumei; Liang, Dicong; Yi, Zhu
2015-01-01T23:59:59.000Z
With the usual definitions for the entropy and the temperature associated with the apparent horizon, we show that the unified first law on the apparent horizon is equivalent to the Friedmann equation for the scalar-tensor theory with non-minimally derivative coupling. The second law of thermodynamics on the apparent horizon is also satisfied. The results support a deep and fundamental connection between gravitation, thermodynamics and quantum theory.
CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II
Zhang, Yuanlin
CH E 2421 Chemical Engineering Thermodynamics I CH E 3322 Chemical Engineering Thermodynamics II CH E 3330 Engineering Materials Science CH E 4342 Polymer Physics Engineering Thermodynamics I M E 3311 Materials Science M E 3322 Engineering Thermodynamics II M
Entropy In The Present And Early Universe: New Small Parameters And Dark Energy Problem
A. E. Shalyt-Margolin
2010-04-16T23:59:59.000Z
It is demonstrated that entropy and its density play a significant role in solving the problem of the vacuum energy density (cosmological constant) of the Universe and hence the dark energy problem. Taking this in mind, two most popular models for dark energy - Holographic Dark Energy Model and Agegraphic Dark Energy Model - are analyzed. It is shown that the fundamental quantities in the first of these models may be expressed in terms of a new small dimensionless parameter. It is revealed that this parameter is naturally occurring in High Energy Gravitational Thermodynamics and Gravitational Holography (UV-limit). On this basis the possibility of a new approach to the problem of Quantum Gravity is discussed. Besides, the results obtained on the uncertainty relation of the pair "cosmological constant - volume of space-time", where the cosmological constant is a dynamic quantity, are reconsidered and generalized up to the Generalized Uncertainty Relation.
Fundamentals and Techniques of Nonimaging
O'Gallagher, J. J.; Winston, R.
2003-07-10T23:59:59.000Z
This is the final report describing a long term basic research program in nonimaging optics that has led to major advances in important areas, including solar energy, fiber optics, illumination techniques, light detectors, and a great many other applications. The term ''nonimaging optics'' refers to the optics of extended sources in systems for which image forming is not important, but effective and efficient collection, concentration, transport, and distribution of light energy is. Although some of the most widely known developments of the early concepts have been in the field of solar energy, a broad variety of other uses have emerged. Most important, under the auspices of this program in fundamental research in nonimaging optics established at the University of Chicago with support from the Office of Basic Energy Sciences at the Department of Energy, the field has become very dynamic, with new ideas and concepts continuing to develop, while applications of the early concepts continue to be pursued. While the subject began as part of classical geometrical optics, it has been extended subsequently to the wave optics domain. Particularly relevant to potential new research directions are recent developments in the formalism of statistical and wave optics, which may be important in understanding energy transport on the nanoscale. Nonimaging optics permits the design of optical systems that achieve the maximum possible concentration allowed by physical conservation laws. The earliest designs were constructed by optimizing the collection of the extreme rays from a source to the desired target: the so-called ''edge-ray'' principle. Later, new concentrator types were generated by placing reflectors along the flow lines of the ''vector flux'' emanating from lambertian emitters in various geometries. A few years ago, a new development occurred with the discovery that making the design edge-ray a functional of some other system parameter permits the construction of whole new classes of devices with greatly expanded capabilities compared to conventional approaches. These ''tailored edge-ray'' designs have dramatically broadened the range of geometries in which nonimaging optics can provide a significant performance improvement. Considerable progress continues to be made in furthering the incorporation of nonimaging secondaries into practical high concentration and ultra-high concentration solar collector systems. In parallel with the continuing development of nonimaging geometrical optics, our group has been working to develop an understanding of certain fundamental physical optics concepts in the same context. In particular, our study of the behavior of classical radiance in nonimaging systems, has revealed some fundamentally important new understandings that we have pursued both theoretically and experimentally. The field is still relatively new and is rapidly gaining widespread recognition because it fuels many industrial applications. Because of this, during the final years of the project, our group at Chicago has been working more closely with a team of industrial scientists from Science Applications International Corporation (SAIC) at first informally, and later more formally, beginning in 1998, under a formal program initiated by the Department of Energy and incrementally funded through this existing grant. This collaboration has been very fruitful and has led to new conceptual breakthroughs which have provided the foundation for further exciting growth. Many of these concepts are described in some detail in the report.
Thermodynamics of cuticular transpiration Allen G. Gibbs *
Ahmad, Sajjad
Review Thermodynamics of cuticular transpiration§ Allen G. Gibbs * School of Life Sciences, 4505 S . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1067 4. Thermodynamics of transport processes Accepted 6 May 2011 Keywords: Cuticle Humidity Thermodynamics Transpiration Water vapor A B S T R A C
Thermodynamics in Loop Quantum Cosmology
Li-Fang Li; Jian-Yang Zhu
2008-12-18T23:59:59.000Z
Loop quantum cosmology (LQC) is very powerful to deal with the behavior of early universe. And the effective loop quantum cosmology gives a successful description of the universe in the semiclassical region. We consider the apparent horizon of the Friedmann-Robertson-Walker universe as a thermodynamical system and investigate the thermodynamics of LQC in the semiclassical region. The effective density and effective pressure in the modified Friedmann equation from LQC not only determine the evolution of the universe in LQC scenario but are actually also found to be the thermodynamic quantities. This result comes from the energy definition in cosmology (the Misner-Sharp gravitational energy) and is consistent with thermodynamic laws. We prove that within the framework of loop quantum cosmology, the elementary equation of equilibrium thermodynamics is still valid.
THERMODYNAMICS Unified Model for Nonideal Multicomponent
Firoozabadi, Abbas
THERMODYNAMICS Unified Model for Nonideal Multicomponent Molecular Diffusion Coefficients Alana and a rigorous descrip- tion of mixture nonideality in the framework of irreversible thermodynamics. Molecular
Thermodynamics and cement science
Damidot, D., E-mail: damidot@ensm-douai.fr [Universite Lille Nord de France (France); EM Douai, LGCgE-MPE-GCE, Douai (France); Lothenbach, B. [Empa, Lab. Concrete and Construction Chemistry, Duebendorf (Switzerland); Herfort, D. [Cementir Holding (Denmark); Glasser, F.P. [Chemistry Department, University of Aberdeen, Aberdeen (United Kingdom)
2011-07-15T23:59:59.000Z
Thermodynamics applied to cement science has proved to be very valuable. One of the most striking findings has been the extent to which the hydrate phases, with one conspicuous exception, achieve equilibrium. The important exception is the persistence of amorphous C-S-H which is metastable with respect to crystalline calcium silicate hydrates. Nevertheless C-S-H can be included in the scope of calculations. As a consequence, from comparison of calculation and experiment, it appears that kinetics is not necessarily an insuperable barrier to engineering the phase composition of a hydrated Portland cement. Also the sensitivity of the mineralogy of the AFm and AFt phase compositions to the presence of calcite and to temperature has been reported. This knowledge gives a powerful incentive to develop links between the mineralogy and engineering properties of hydrated cement paste and, of course, anticipates improvements in its performance leading to decreasing the environmental impacts of cement production.
Thermodynamics of clusterized matter
Ad. R. Raduta; F. Gulminelli
2009-08-26T23:59:59.000Z
Thermodynamics of clusterized matter is studied in the framework of statistical models with non-interacting cluster degrees of freedom. At variance with the analytical Fisher model, exact Metropolis simulation results indicate that the transition from homogeneous to clusterized matter lies along the $\\rho=\\rho_0$ axis at all temperatures and the limiting point of the phase diagram is not a critical point even if the surface energy vanishes at this point. Sensitivity of the inferred phase diagram to the employed statistical framework in the case of finite systems is discussed by considering the grand-canonical and constant-pressure canonical ensembles. A Wigner-Seitz formalism in which the fragment charge is neutralized by an uniform electron distribution allows to build the phase diagram of neutron star matter.
Michaelian, K
2009-01-01T23:59:59.000Z
Understanding the thermodynamic function of life may shed light on its origin. Out of equilibrium structuring in space and time is contingent on continuous entropy production. Entropy production is a measure of the rate of the natural tendency of Nature to explore all available microstates. The process producing the greatest amount of entropy in the biosphere is the absorption and transformation of sunlight, leading to the transpiration of water by plants and cyanobacteria. Here we hypothesize that life began, and exists today, as a dynamic catalyst for the absorption and transformation of sunlight into heat, which could then be efficiently harvested by the water cycle, hurricanes, and ocean and wind currents. RNA and DNA are the most efficient of all known molecules for absorbing the ultraviolet light that could have penetrated the dense early atmosphere, and are extremely rapid in transforming this light into heat that can be readily absorbed by liquid water. The origin and evolution of life was thus driven...
Tribal Energy NEPA Fundamentals Workshop
Office of Energy Efficiency and Renewable Energy (EERE)
The Tribal Energy NEPA Fundamentals Workshop is a three-day workshop for tribes to understand how to manage the National Environmental Policy Act (NEPA) process and implement the Council on...
QCD Thermodynamics with Improved Actions
Karsch, Frithjof; Engels, J; Joswig, R; Laermann, E; Peikert, A; Petersson, B
1996-01-01T23:59:59.000Z
The thermodynamics of the SU(3) gauge theory has been analyzed with tree level and tadpole improved Symanzik actions. A comparison with the continuum extrapolated results for the standard Wilson action shows that improved actions lead to a drastic reduction of finite cut-off effects already on lattices with temporal extent $N_\\tau=4$. Results for the pressure, the critical temperature, surface tension and latent heat are presented. First results for the thermodynamics of four-flavour QCD with an improved staggered action are also presented. They indicate similarly large improvement factors for bulk thermodynamics.
Christoph Fritsch; Thomas Buchert
1999-03-10T23:59:59.000Z
We discuss implications of the fundamental plane parameters of clusters of galaxies derived from combined optical and X-ray data of a sample of 78 nearby clusters. In particular, we investigate the dependence of these parameters on the dynamical state of the cluster. We introduce a new concept of allocation of the fundamental plane of clusters derived from their intrinsic morphological properties, and put some theoretical implications of the existence of a fundamental plane into perspective.
Physical Meteorology I: Thermodynamics (METR 3213)
Fedorovich, Evgeni
instability. Buoyancy. Part VI. Second law of thermodynamics. Carnot cycle. Reversible and irreversible
ME 326 Thermodynamics ABET EC2000 syllabus
Ben-Yakar, Adela
ME 326 Thermodynamics Page 1 ABET EC2000 syllabus ME 326 Thermodynamics Summer 2009 Required or Elective: Required 2008-2010 Catalog Data: Properties, heat and work, first and second laws, thermodynamic, and Physics 303K with a grade of at least C in each. Textbook(s): Thermodynamics: An Integrated Learning
MMAE 320 Thermodynamics Illinois Institute of Technology
Heller, Barbara
MMAE 320 Thermodynamics Fall 2011 Illinois Institute of Technology Instructor: Professor Shawn C of Engineering Thermodynamics, 7th Yes, you will probably be fine with an earlier edition, please buy and read. Work and Heat 4. First Law of Thermodynamics 5. Second Law of Thermodynamics 6. Entropy 7
Nonequilibrium Thermodynamics of Porous Electrodes
Ferguson, Todd Richard
We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic ...
Thermodynamics of regular black hole
Yun Soo Myung; Yong-Wan Kim; Young-Jai Park
2008-09-21T23:59:59.000Z
We investigate thermodynamics for a magnetically charged regular black hole (MCRBH), which comes from the action of general relativity and nonlinear electromagnetics, comparing with the Reissner-Norstr\\"om (RN) black hole in both four and two dimensions after dimensional reduction. We find that there is no thermodynamic difference between the regular and RN black holes for a fixed charge $Q$ in both dimensions. This means that the condition for either singularity or regularity at the origin of coordinate does not affect the thermodynamics of black hole. Furthermore, we describe the near-horizon AdS$_2$ thermodynamics of the MCRBH with the connection of the Jackiw-Teitelboim theory. We also identify the near-horizon entropy as the statistical entropy by using the AdS$_2$/CFT$_1$ correspondence.
On the Mathematics of Thermodynamics
J. B. Cooper; T. Russell
2011-02-08T23:59:59.000Z
We show that the mathematical structure of Gibbsian thermodynamics flows from the following simple elements: the state space of a thermodynamical substance is a measure space together with two orderings (corresponding to "warmer than" and "adiabatically accessible from") which satisfy certain plausible physical axioms and an area condition which was introduced by Paul Samuelson. We show how the basic identities of thermodynamics, in particular the Maxwell relations, follow and so the existence of energy, free energy, enthalpy and the Gibbs potential function. We also discuss some questions which we have not found dealt with in the literature, such as the amount of information required to reconstruct the equations of state of a substance and a systematic approach to thermodynamical identities.
Relativisticlike structure of classical thermodynamics
Hernando Quevedo; Alberto Sanchez; Alejandro Vazquez
2014-10-26T23:59:59.000Z
We analyze in the context of geometrothermodynamics a Legendre invariant metric structure in the equilibrium space of an ideal gas. We introduce the concept of thermodynamic geodesic as a succession of points, each corresponding to a state of equilibrium, so that the resulting curve represents a quasi-static process. A rigorous geometric structure is derived in which the thermodynamic geodesics at a given point split the equilibrium space into two disconnected regions separated by adiabatic geodesics. This resembles the causal structure of special relativity, which we use to introduce the concept of adiabatic cone for thermodynamic systems. This result might be interpreted as an alternative indication of the inter-relationship between relativistic physics and classical thermodynamics.
Thermodynamics of Modified Chaplygin Gas and Tachyonic Field
Samarpita Bhattacharya; Ujjal Debnath
2010-12-26T23:59:59.000Z
Here we generalize the results of the work of ref. [10] in modified Chaplygin gas model and tachyonic field model. Here we have studied the thermodynamical behaviour and the equation of state in terms of volume and temperature for both models. We have used the solution and the corresponding equation of state of our previous work [12] for tachyonic field model. We have also studied the thermodynamical stability using thermal equation of state for the tachyonic field model and have shown that there is no critical points during thermodynamical expansion. The determination of $T_{*}$ due to expansion for the tachyonic field have been discussed by assuming some initial conditions. Here, the thermal quantities have been investigated using some reduced parameters.
Thermodynamics of topological nonlinear charged Lifshitz black holes
Zangeneh, M Kord; Dehghani, M H
2015-01-01T23:59:59.000Z
In this paper, we construct a new class of analytic topological Lifshitz black holes with constant curvature horizon in the presence of power-law Maxwell field in four and higher dimensions. We find that in order to obtain these exact Lifshitz solutions, we need a dilaton and at least three electromagnetic fields. Interestingly enough, we find that the reality of the charge of the electromagnetic field which is needed for having solutions with curved horizon rules out black holes with hyperbolic horizon. Next, we study the thermodynamics of these nonlinear charged Lifshitz black holes with spherical and flat horizons by calculating all the conserved and thermodynamic quantities of the solutions. Furthermore, we obtain a generalized Smarr formula and show that the first law of thermodynamics is satisfied. Finally, we perform a stability analysis in both canonical and grand-canonical ensembles. We find that the solutions are thermally stable in a proper ranges of the metric parameters.
Thermodynamical approaches to efficient sympathetic cooling in ultracold Fermi-Bose atomic mixtures
Presilla, Carlo
mainly due to fundamental obstacles in adapting cooling techniques successfully used for bosonic species degeneracy. This issue has been circumvented by developing two cooling techniques, namely mutual evaporativeThermodynamical approaches to efficient sympathetic cooling in ultracold Fermi-Bose atomic mixtures
Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates
Chaka, Anne M.; Felmy, Andrew R.
2014-03-28T23:59:59.000Z
An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.
Office of Scientific and Technical Information (OSTI)
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem Not Found Item Not Found The itemAIR57451DOE/SC0002390 Technical9'S-0041
Energy Literacy: Essential Principles and Fundamental Concepts...
Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy...
Thermodynamic aspects of reformulation of automotive fuels
Zudkevitch, D. [Columbia Univ., New York, NY (United States); Murthy, A.K.S. [BOC Gases, Murray Hill, NJ (United States); Gmehling, J. [Univ. Oldenburg (Germany)
1995-09-01T23:59:59.000Z
A study of procedures for measuring and predicting the RVP and the initial vapor emissions of reformulated gasoline blends which contain one or more oxygenated compounds, viz., Ethanol, MTBE, ETBE, and TAME is discussed. Two computer simulation methods were programmed and tested. In one method, Method A, the D-86 distillation data on the blend are used for predicting the blend`s RVP from a simulation of the Mini RVPE (RVP Equivalent) experiment. The other method, Method B, relies on analytical information (PIANO analyzes) on the nature of the base gasoline and utilizes classical thermodynamics for simulating the same RVPE, Mini experiment. Method B, also, predicts the composition and other properties of the initial vapor emission from the fuel. The results indicate that predictions made with both methods agree very well with experimental values. The predictions with Method B illustrate that the admixture of an oxygenate to a gasoline blend changes the volatility of the blend and, also, the composition of the vapor emission. From the example simulations, a blend with 10 vol % ethanol increases the RVP by about 0.8 psi. The accompanying vapor emission will contain about 15% ethanol. Similarly, the vapor emission of a fuel blend with 11 vol % MTBE was calculated to contain about 11 vol % MTBE. Predictions of the behavior of blends with ETBE and ETBE+Ethanol are also presented and discussed. Recognizing that quite some efforts have been invested in developing empirical correlations for predicting RVP, the writers consider the purpose of this paper to be pointing out that the methods of classical thermodynamics are adequate and that there is a need for additional work in developing certain fundamental data that are still lacking.
Distinguished rheological models in the framework of a thermodynamical internal variable theory
Asszonyi, Cs; Ván, P
2014-01-01T23:59:59.000Z
We present and analyze a thermodynamical theory of rheology with single internal variable. The universality of the model is ensured as long as the mesoscopic and/or microscopic background processes satisfy the applied thermodynamical principles, which are the second law, the basic balances and the existence of an additional-tensorial-state variable. The resulting model, which we suggest to call the Kluitenberg-Verh\\'as body, is the Poynting-Thomson-Zener body with an additional inertial element, or, in other words, is the extension of Jeffreys model to solids. We argue that this Kluitenberg-Verh\\'as body is the natural thermodynamical building block of rheology. An important feature of the presented methodology is that nontrivial inequality-type restrictions arise for the four parameters of the model. We compare these conditions and other aspects to those of other known thermodynamical approaches, like Extended Irreversible Thermodynamics or the original theory of Kluitenberg.
Thermodynamics and Ionic Conductivity of Block Copolymer Electrolytes
Wanakule, Nisita Sidra
2010-01-01T23:59:59.000Z
2.3 REFERENCES Flory, P.J. , Thermodynamics of high polymerBlock Copolymer Thermodynamics - Theory And Experiment.on block copolymer thermodynamics by measuring the changes
Thermodynamics, Entropy, Information and the Efficiency of Solar Cells
Abrams, Zeev R.
2012-01-01T23:59:59.000Z
and P.T. Landsberg, Thermodynamics and reciprocity of solar59. E. Yablonovitch, Thermodynamics of the fluorescentC. 139. E. Yablonovitch, Thermodynamics of the fluorescent
Thermodynamics of Nanoscale Calcium and Strontium Titanate Perovskites
Sahu, Sulata Kumari
2013-01-01T23:59:59.000Z
and A. Navrotsky, “Thermodynamics of Nanoscale Lead Titanate2007. A. Navrotsky, “Thermodynamics of Solid Electrolytesand Y. Fei, “The Thermodynamics of Ordered Perovskites on
Thermodynamics of Neptunium (V) Complexes with Phosphate at Elevated Temperatures
Xia, Yuanxian
2009-01-01T23:59:59.000Z
VITORGE, H. WANNER, Chemical Thermodynamics of Neptunium andData Bank, Chemical Thermodynamics 4, Elsevier, New York 4.Thermodynamics of Neptunium (V) Complexes with Phosphate at
A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power A Revolutionary Hybrid Thermodynamic...
Cognitive Radio: Fundamentals and Opportunities
Morelos-Zaragoza, Robert H.
Cognitive Radio: Fundamentals and Opportunities Robert H. Morelos-Zaragoza Department of Electrical Engineering San Jose State University October 12, 2007 #12;Cognitive Radio - RHMZ - 2007 Slide 2 of 18 Outline 1. Software-defined radio (SDR) a) Black-box approach b) Components and attributes (Mitola) 2
Plasmons in Graphene: Fundamental Properties
SoljaĂ¨iĂ¦, Marin
INVITED P A P E R Plasmons in Graphene: Fundamental Properties and Potential Applications in graphene have intriguing fundamen- tal properties and hold great potential for applications. They enable via gate voltage, providing an advantage for graphene's plasmons over surface plasmons (SPs
REACHING AGREEMENT A Fundamental Task--
Schneider, Fred B.
REACHING AGREEMENT A Fundamental Task-- Even in Distributed Computer Systems by Fred B. Schneider consists of a collection of computers interconnected by communication channels. The computers are usually that will achieve ByzantineAgreement: Agreement. All nontraitorous generals execute the same action. Validity
AlfĂ¨, Dario
Hugoniot curves cross the melting line, and the sound speed and GruÂ¨neisen parameter along the HugoniotIron under Earth's core conditions: Liquid-state thermodynamics and high-pressure melting curve-augmented-wave implementation are used to calculate the free energy and a range of other thermodynamic properties of liquid iron
Expected Behavior of Quantum Thermodynamic Machines with Prior Information
George Thomas; Ramandeep S. Johal
2012-04-14T23:59:59.000Z
We estimate the expected behavior of a quantum model of heat engine when we have incomplete information about external macroscopic parameters, like magnetic field controlling the intrinsic energy scales of the working medium. We explicitly derive the prior probability distribution for these unknown parameters, $a_i, (i=1,2)$. Based on a few simple assumptions, the prior is found to be of the form $\\Pi(a_i) \\propto 1/a_i$. By calculating the expected values of various physical quantities related to this engine, we find that the expected behavior of the quantum model exhibits thermodynamic-like features. This leads us to a surprising proposal that incomplete information quantified as appropriate prior distribution can lead us to expect classical thermodynamic behavior in quantum models.
Horizon thermodynamics and composite metrics
Lorenzo Sindoni
2012-11-12T23:59:59.000Z
We examine the conditions under which the thermodynamic behaviour of gravity can be explained within an emergent gravity scenario, where the metric is defined as a composite operator. We show that due to the availability of a boundary of a boundary principle for the quantum effective action, Clausius-like relations can always be constructed. Hence, any true explanation of the thermodynamic nature of the metric tensor has to be referred to an equilibration process, associated to the presence of an H-theorem, possibly driven by decoherence induced by the pregeometric degrees of freedom, and their entanglement with the geometric ones.
The thermodynamics of creating correlations: Limitations and optimal protocols
David Edward Bruschi; Martí Perarnau-Llobet; Nicolai Friis; Karen V. Hovhannisyan; Marcus Huber
2015-03-11T23:59:59.000Z
We establish a rigorous connection between fundamental resource theories at the quantum scale. Correlations and entanglement constitute indispensable resources for numerous quantum information tasks. However, their establishment comes at the cost of energy, the resource of thermodynamics, and is limited by the initial entropy. Here, the optimal conversion of energy into correlations is investigated. Assuming the presence of a thermal bath, we establish general bounds for arbitrary systems and construct a protocol saturating them. The amount of correlations, quantified by the mutual information, can increase at most linearly with the available energy, and we determine where the linear regime breaks down. We further consider the generation of genuine quantum correlations, focusing on the fundamental constituents of our universe: fermions and bosons. For fermionic modes, we find the optimal entangling protocol. For bosonic modes, we show that while Gaussian operations can be outperformed in creating entanglement, their performance is optimal for high energies.
Methods and systems for thermodynamic evaluation of battery state of health
Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T
2014-12-02T23:59:59.000Z
Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.
DOE Fundamentals Handbook: Classical Physics
Not Available
1992-06-01T23:59:59.000Z
The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton`s Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.
DOE Fundamentals Handbook: Classical Physics
Not Available
1992-06-01T23:59:59.000Z
The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton's Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.
Optimal control in thermodynamic systems with sources of finite capacity
Kuznetsov, A.G.; Rudenko, A.V.; Tsirlin, A.M.
1985-11-10T23:59:59.000Z
This paper considers problems of optimal control of thermodynamic processes of heat and mass transfer on contact of two systems. The control signal is a vector of the temperatures and concentrations of one system, the parameters of the second being variable at a rate proportional to the heat and material flows. The limiting efficiency of the heat machine is found when the cycle duration and source capacities are bounded.
Quantum measurement and its role in thermodynamics
Philipp Kammerlander; Janet Anders
2015-02-09T23:59:59.000Z
A central goal of the research effort in quantum thermodynamics is the extension of standard thermodynamics to include small-scale and quantum effects. Here we lay out consequences of seeing measurement, one of the central pillars of quantum theory, not merely as a mathematical projection but as a thermodynamic process. We uncover that measurement, a component of any experimental realisation, is accompanied by work and heat contributions and that these are distinct in classical and quantum thermodynamics. Implications are far-reaching, giving a thermodynamic interpretation to quantum coherence, extending the link between thermodynamics and information theory, and providing key input for the construction of a future quantum thermodynamic framework. Repercussions for existing quantum thermodynamic relations that omitted the role of measurement are discussed, including quantum work fluctuation relations and single-shot approaches.
Thermodynamic Efficiency of Heat Exchange Devices
Witte, L. C.; Shamsundar, N.
1982-01-01T23:59:59.000Z
irreversibilities. The reclamation of what was formerly 'waste heat' by using additional, or more efficient, equipment has become not only economically feasible, but sometimes essential. A thermodynamic efficiency based on the second law of thermodynamics...
Moisés Santillán
2011-05-27T23:59:59.000Z
In this work we study, at the single molecular level, the thermodynamic and dynamic characteristics of an enzymatic reaction comprising a rate limiting step. We investigate how the stability of the enzyme-state stationary probability distribution, the reaction velocity, and its efficiency of energy conversion depend on the system parameters. We employ in this study a recently introduced formalism for performing a multiscale thermodynamic analysis in continuous-time discrete-state stochastic systems.
Kinetic Modeling and Thermodynamic Closure Approximation of ...
2007-10-03T23:59:59.000Z
Oct 5, 2007 ... Kinetic Modeling and Thermodynamic Closure. Approximation of Liquid Crystal Polymers. Haijun Yu. Program in Applied and Computational ...
Hawking Emission and Black Hole Thermodynamics
Don N. Page
2006-12-18T23:59:59.000Z
A brief review of Hawking radiation and black hole thermodynamics is given, based largely upon hep-th/0409024.
Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...
Equilibrium Thermodynamics of Lattice QCD
D. K. Sinclair
2007-02-03T23:59:59.000Z
Lattice QCD allows us to simulate QCD at non-zero temperature and/or densities. Such equilibrium thermodynamics calculations are relevant to the physics of relativistic heavy-ion collisions. I give a brief review of the field with emphasis on our work.
On Noncommutative Black Holes Thermodynamics
Faizal, Mir; Ulhoa, S C
2015-01-01T23:59:59.000Z
In this paper, we will analyze noncommutative deformation of the Schwarzschild black holes and Kerr black holes. We will perform our analysis by relating the commutative and the noncommutative metrics using an Moyal product. We will also analyze the thermodynamics of these noncommutative black hole solutions. We will explicitly derive expression for the corrected entropy and temperature of these black hole solutions.
Thermodynamics and timeaverages October 13, 2004
Carati, Andrea
Thermodynamics and timeÂaverages A. Carati October 13, 2004 ABSTRACT For a dynamical system farÂaverages, and the main problem is then how to formulate an appropriate statistical thermodynamics. The com- mon answer: Thermodynamics and timeÂaverages Universit`a di Milano, Dipartimento di Matematica Via Saldini 50, 20133 Milano
Thermodynamics and Mass Transport in Multicomponent,
Manga, Michael
Thermodynamics and Mass Transport in Multicomponent, Multiphase H2O Systems of Planetary Interest, cryogenic systems, thermodynamics, fluid dynamics, clathrates, Mars, Enceladus, sound speed Abstract Heat of the noncondensible components can greatly alter the thermodynamic properties of the phases and their flow properties
Thermodynamics for single-molecule stretching experiments
Kjelstrup, Signe
Thermodynamics for single-molecule stretching experiments J.M. Rubi,a D. Bedeauxb and S. Kjelstrupb, Trondheim, 7491-Norway May 3, 2006 Abstract We show how to construct non-equilibrium thermodynamics for systems too small to be considered thermodynamically in a traditional sense. Through the use of a non
Thermodynamics of a Nonlocal PNJL Model
Weise, Wolfram
Thermodynamics of a Nonlocal PNJL Model Thomas Hell, Simon Rößner and Wolfram Weise Physik Th. Hell Thermodynamics of a Nonlocal NJL-type Model #12;Outline 1 The Nonlocal Nambu Approximation Dynamical Quark Mass 2 Thermodynamics of the Nonlocal PNJL Model Coupling Quarks and Polyakov Loop
Thermodynamics of a Nonlocal PNJL Model
Weise, Wolfram
Thermodynamics of a Nonlocal PNJL Model Thomas Hell, Simon Rößner and Wolfram Weise Physik Darmstadt, March 14th 2008 T. Hell Thermodynamics of a Nonlocal NJL-type Model #12;Outline 1 The Nonlocal Model Mean Field Approximation Dynamical Quark Mass 2 Thermodynamics of the Nonlocal PNJL Model Coupling
Thermodynamics of viscoelastic fluids: the temperature equation.
Wapperom, Peter
Thermodynamics of viscoelastic fluids: the temperature equation. Peter Wapperom Martien A. Hulsen and Hydrodynamics Rotterdamseweg 145 2628 AL Delft (The Netherlands) Abstract From the thermodynamics with internal. The well- known stress differential models that fit into the thermodynamic theory will be treated
Thermodvnamics Thermodynamics of Wax Precipitation in
Firoozabadi, Abbas
Thermodvnamics Thermodynamics of Wax Precipitation in Petroleum Mixtures C. Lira-Galeana and A, Berkeley, CIA 94720 A thermodynamic pamework is developed for calculating wax precipitation in petroleum only recently have attempts been made to develop a thermodynamic description. Published methods
International Scholarly Research Network ISRN Thermodynamics
Tailleux, Remi
International Scholarly Research Network ISRN Thermodynamics Volume 2012, Article ID 609701, 15 pages doi:10.5402/2012/609701 Research Article Thermodynamics/Dynamics Coupling in Weakly Compressible the thermodynamics from the dynamics, this paper reviews recent results and derive new ones that show
ADVANCES IN ENVIRONMENTAL REACTION KINETICS AND THERMODYNAMICS
Sparks, Donald L.
1262 ADVANCES IN ENVIRONMENTAL REACTION KINETICS AND THERMODYNAMICS: LONG-TERM FATE thermodynamic and kinetic data is available with regard to the formation of these mixed metal precipitate phases to six months from the initial addition of aqueous nickel. Additionally, we have determined thermodynamic
Particles, maps and Irreversible Thermodynamics { I
Rondoni, Lamberto
Particles, maps and Irreversible Thermodynamics { I E. G. D. Cohen The Rockefeller University New Thermodynamics from deterministic dynamics. We #12;nd that these models do not posses the crucial property of local thermodynamic equilibrium, since they rep- resent noninteracting particles systems. Hence
CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings
Sherrill, David
CHEM 6471 CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings 9:35 10:55 am, Tuesday and Thursday of October 22-26 Textbooks Molecular Thermodynamics by D.A McQuarrie and J.D. Simon, University Science Books the laws of classical thermodynamics and some of their chemical applications. It also covers basic
Perform Thermodynamics Measurements on Fuel Cycle Case Study Systems
Leigh R. Martin
2014-09-01T23:59:59.000Z
This document was prepared to meet FCR&D level 3 milestone M3FT-14IN0304022, “Perform Thermodynamics Measurements on Fuel Cycle Case Study Systems.” This work was carried out under the auspices of the Thermodynamics and Kinetics FCR&D work package. This document reports preliminary work in support of determining the thermodynamic parameters for the ALSEP process. The ALSEP process is a mixed extractant system comprised of a cation exchanger 2-ethylhexyl-phosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) and a neutral solvating extractant N,N,N’,N’-tetraoctyldiglycolamide (TODGA). The extractant combination produces complex organic phase chemistry that is challenging for traditional measurement techniques. To neutralize the complexity, temperature dependent solvent extraction experiments were conducted with neat TODGA and scaled down concentrations of the ALSEP formulation to determine the enthalpies of extraction for the two conditions. A full set of thermodynamic data for Eu, Am, and Cm extraction by TODGA from 3.0 M HNO3 is reported. These data are compared to previous extraction results from a 1.0 M HNO3 aqueous medium, and a short discussion of the mixed HEH[EHP]/TODGA system results is offered.
Fundamental Limits to Cellular Sensing
Pieter Rein ten Wolde; Nils B. Becker; Thomas E. Ouldridge; A. Mugler
2015-05-25T23:59:59.000Z
In recent years experiments have demonstrated that living cells can measure low chemical concentrations with high precision, and much progress has been made in understanding what sets the fundamental limit to the precision of chemical sensing. Chemical concentration measurements start with the binding of ligand molecules to receptor proteins, which is an inherently noisy process, especially at low concentrations. The signaling networks that transmit the information on the ligand concentration from the receptors into the cell have to filter this noise extrinsic to the cell as much as possible. These networks, however, are also stochastic in nature, which means that they will also add noise to the transmitted signal. In this review, we will first discuss how the diffusive transport and binding of ligand to the receptor sets the receptor correlation time, and then how downstream signaling pathways integrate the noise in the receptor state; we will discuss how the number of receptors, the receptor correlation time, and the effective integration time together set a fundamental limit on the precision of sensing. We then discuss how cells can remove the receptor noise while simultaneously suppressing the intrinsic noise in the signaling network. We describe why this mechanism of time integration requires three classes of resources---receptors and their integration time, readout molecules, energy---and how each resource class sets a fundamental sensing limit. We also briefly discuss the scheme of maximum-likelihood estimation, the role of receptor cooperativity, and how cellular copy protocols differ from canonical copy protocols typically considered in the computational literature, explaining why cellular sensing systems can never reach the Landauer limit on the optimal trade-off between accuracy and energetic cost.
Holographic Viscosity of Fundamental Matter
David Mateos; Robert C. Myers; Rowan M. Thomson
2006-10-16T23:59:59.000Z
A holographic dual of a finite-temperature SU(N_c) gauge theory with a small number of flavours N_f viscosity to entropy ratio in these theories saturates the conjectured universal bound eta/s >= 1/4\\pi. The contribution of the fundamental matter eta_fund is therefore enhanced at strong 't Hooft coupling lambda; for example, eta_fund ~ lambda N_c N_f T^3 in four dimensions. Other transport coefficients are analogously enhanced. These results hold with or without a baryon number chemical potential.
Kostic, Milivoje M.
and heat transfer fundamentals; the second law of thermodynamics and entropy; energy efficiency for forced, directional displacement of mass-energy in space and time, thus governs all processes in nature-`intelligent' templates, DNAs, etc.). However, the mass-energy flow (transfer) within those structures will always
FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS
Li, Baochun
FUNDAMENTAL PERFORMANCE LIMITS OF WIRELESS SENSOR NETWORKS ZHIHUA HU, BAOCHUN LI Abstract. Understanding the fundamental performance limits of wireless sensor networks is critical towards. Key words. Wireless sensor networks, network capacity, network lifetime. 1. Introduction. When
Thermodynamics of the PNJL model
C. Ratti; S. Roessner; M. A. Thaler; W. Weise
2006-09-21T23:59:59.000Z
QCD thermodynamics is investigated by means of the Polyakov-loop-extended Nambu Jona-Lasinio (PNJL) model, in which quarks couple simultaneously to the chiral condensate and to a background temporal gauge field representing Polyakov loop dynamics. The behaviour of the Polyakov loop as a function of temperature is obtained by minimizing the thermodynamic potential of the system. A Taylor series expansion of the pressure is performed. Pressure difference and quark number density are then evaluated up to sixth order in quark chemical potential, and compared to the corresponding lattice data. The validity of the Taylor expansion is discussed within our model, through a comparison between the full results and the truncated ones.
Thermodynamical instability of black holes
V. V. Kiselev
2012-08-07T23:59:59.000Z
In contrast to Hawking radiation of black hole with a given spacetime structure, we consider a competitive transition due to a heat transfer from a hotter inner horizon to a colder outer horizon of Kerr black hole, that results in a stable thermodynamical state of extremal black hole. In this process, by supposing an emission of gravitational quanta, we calculate the mass of extremal black hole in the final state of transition.
Breaking information-thermodynamics link
Robert Alicki
2014-06-23T23:59:59.000Z
The information-thermodynamics link is revisited, going back to the analysis of Szilard's engine. It is argued that instead of equivalence rather complementarity of physical entropy and information theoretical one is a correct concept. Famous Landauer's formula for a minimal cost of information processing is replaced by a new one which takes into account accuracy and stability of information encoding. Two recent experiments illustrating the information-energy conversion are critically discussed.
Dark Energy: A Crisis for Fundamental Physics
Christopher Stubb
2010-09-01T23:59:59.000Z
Stubbs discusses the astrophysical observations that show that the current picture of fundamental physics is far from complete.
Collective excitations and thermodynamics of disordered state: new insights into an old problem
V. V. Brazhkin; K. Trachenko
2014-08-27T23:59:59.000Z
Disorder has been long considered as a formidable foe of theoretical physicists in their attempts to understand system's behavior. Here, we review recently accumulated data and propose that from the point of view of calculating thermodynamic properties, the problem of disorder may not be as severe as has been hitherto assumed. We particularly emphasize that contrary to the long-held view, collective excitations do not decay in disordered systems. We subsequently discuss recent experimental, theoretical and modelling results related to collective excitations in disordered media, and show how these results pave the way to understanding thermodynamics of disordered systems: glasses, liquids, supercritical fluids and spin glasses. An interesting insight from the recent work is the realization that most important changes of thermodynamic properties of the disordered system are governed only by its fundamental length, the interatomic separation. We discuss how the proposed theory relates to the previous approaches based on general many-body statistical mechanics framework.
Ma, Yi-An
2015-01-01T23:59:59.000Z
We revisit the Ornstein-Uhlenbeck (OU) process as the fundamental mathematical description of linear irreversible phenomena, with fluctuations, near an equilibrium. By identifying the underlying circulating dynamics in a stationary process as the natural generalization of classical conservative mechanics, a bridge between a family of OU processes with equilibrium fluctuations and thermodynamics is established through the celebrated Helmholtz theorem. The Helmholtz theorem provides an emergent macroscopic "equation of state" of the entire system, which exhibits a universal ideal thermodynamic behavior. Fluctuating macroscopic quantities are studied from the stochastic thermodynamic point of view and a non-equilibrium work relation is obtained in the macroscopic picture, which may facilitate experimental study and application of the equalities due to Jarzynski, Crooks, and Hatano and Sasa.
Fundamental enabling issues in nanotechnology :
Floro, Jerrold Anthony; Foiles, Stephen Martin; Hearne, Sean Joseph; Hoyt, Jeffrey John; Seel, Steven Craig; Webb, Edmund Blackburn,; Morales, Alfredo Martin; Zimmerman, Jonathan A.
2007-10-01T23:59:59.000Z
To effectively integrate nanotechnology into functional devices, fundamental aspects of material behavior at the nanometer scale must be understood. Stresses generated during thin film growth strongly influence component lifetime and performance; stress has also been proposed as a mechanism for stabilizing supported nanoscale structures. Yet the intrinsic connections between the evolving morphology of supported nanostructures and stress generation are still a matter of debate. This report presents results from a combined experiment and modeling approach to study stress evolution during thin film growth. Fully atomistic simulations are presented predicting stress generation mechanisms and magnitudes during all growth stages, from island nucleation to coalescence and film thickening. Simulations are validated by electrodeposition growth experiments, which establish the dependence of microstructure and growth stresses on process conditions and deposition geometry. Sandia is one of the few facilities with the resources to combine experiments and modeling/theory in this close a fashion. Experiments predicted an ongoing coalescence process that generates signficant tensile stress. Data from deposition experiments also supports the existence of a kinetically limited compressive stress generation mechanism. Atomistic simulations explored island coalescence and deposition onto surfaces intersected by grain boundary structures to permit investigation of stress evolution during later growth stages, e.g. continual island coalescence and adatom incorporation into grain boundaries. The predictive capabilities of simulation permit direct determination of fundamental processes active in stress generation at the nanometer scale while connecting those processes, via new theory, to continuum models for much larger island and film structures. Our combined experiment and simulation results reveal the necessary materials science to tailor stress, and therefore performance, in nanostructures and, eventually, integrated nanocomponents.
Gravitationally Induced Particle Production: Thermodynamics and Kinetic Theory
J. A. S. Lima; I. P. Baranov
2014-11-24T23:59:59.000Z
A relativistic kinetic description for the irreversible thermodynamic process of gravitationally induced particle production is proposed in the context of an expanding Friedmann-Robertson-Walker (FRW) geometry. We show that the covariant thermodynamic treatment referred to as "adiabatic" particle production provoked by the cosmic time-varying gravitational field has a consistent kinetic counterpart. The variation of the distribution function is associated to a non-collisional kinetic term of quantum-gravitational origin which is proportional to the ratio $\\Gamma/H$, where $\\Gamma$ is the gravitational particle production rate and H is the Hubble parameter. For $\\Gamma production process. The macroscopic temperature evolution law is also kinetically derived for massive and massless particles. The present approach points to the possibility of an exact (semi-classical) quantum-gravitational kinetic treatment by incorporating back-reaction effects in the cosmic background.
Thermodynamics of SU(3) gauge theory at fixed lattice spacing
T. Umeda; S. Ejiri; S. Aoki; T. Hatsuda; K. Kanaya; Y. Maezawa; H. Ohno
2008-10-09T23:59:59.000Z
We study thermodynamics of SU(3) gauge theory at fixed scales on the lattice, where we vary temperature by changing the temporal lattice size N_t=(Ta_t)^{-1}. In the fixed scale approach, finite temperature simulations are performed on common lattice spacings and spatial volumes. Consequently, we can isolate thermal effects in observables from other uncertainties, such as lattice artifact, renormalization factor, and spatial volume effect. Furthermore, in the EOS calculations, the fixed scale approach is able to reduce computational costs for zero temperature subtraction and parameter search to find lines of constant physics, which are demanding in full QCD simulations. As a test of the approach, we study the thermodynamics of the SU(3) gauge theory on isotropic and anisotropic lattices. In addition to the equation of state, we calculate the critical temperature and the static quark free energy at a fixed scale.
Thermodynamics of Evolving Lorentzian Wormhole at Apparent and Event Horizons
Ujjal Debnath; Mubasher Jamil; R. Myrzakulov; M. Akbar
2012-04-06T23:59:59.000Z
We have investigated the non-static Lorentzian Wormhole model in presence of anisotropic pressure. We have presented some exact solutions of Einstein equations for anisotropic pressure case. Introducing two EoS parameters we have shown that these solutions give very rich dynamics of the universe yielding to the different expansion history of it in the $r$ - direction and in the $T$ - direction. The corresponding explicit forms of the shape function $b(r)$ is presented.We have shown that the Einstein's field equations and unified first law are equivalent for the dynamical wormhole model. The first law of thermodynamics has been derived by using the Unified first law. The physical quantities including surface gravity and the temperature are derived for the wormhole. Here we have obtained all the results without any choice of the shape function. The validity of generalized second law (GSL) of thermodynamics has been examined at apparent and event horizons for the evolving Lorentzian wormhole.
Simulation of the thermodynamic properties of organic extraction solutions
Kolker, A.R.
1986-05-01T23:59:59.000Z
A method is proposed for the simulation of the activity coefficients of the components, the excess volume, the heat of mixing, and other excess thermodynamic functions of organic extraction solutions. The method is based on a search in an assigned region for parameters of the NRTL equations of local composition for which the state of the solution satisfies the requirements of chemical thermodynamics, as well as the assigned recovery criteria. The following binary systems of the solvent-extractant, and solvent-solvate types have been simulated according to the program developed on an ES-1033 computer: C6H/sub 14/-TBP, CHC1/sub 3/-TBP, CC1/sub 4/-TBP, UO/sub 2/(NO/sub 3/)/sub 2/ X 2TBP-TBP, and CC1/sub 4/-UO/sub 2/(NO/sub 3/)/sub 2/ X 2TBP.
Electromagnetics close beyond the critical state: thermodynamic prospect
MajĂłs, Antonio BadĂa
-called critical current density is the single material parameter of the theory, and characterizes the balance in material characterization as well as in more fundamental studies. In brief, the CSM postulates equation between magnetic and intrinsic pinning forces: J Ă? B = Fp. The transition between different
Generalized Second Law of Thermodynamics in $f(T,T_{G})$ gravity
Zubair, M
2015-01-01T23:59:59.000Z
An equilibrium picture of thermodynamics is discussed at the apparent horizon of FRW universe in $f(T,T_G)$ gravity, where $T$ represents the torsion invariant and $T_G$ is the teleparallel equivalent of the Gauss-Bonnet term. It is found that one can translate the Friedmann equations to the standard form of first law of thermodynamics. We discuss GSLT in the locality of assumption that temperature of matter inside the horizon is similar to that of horizon. Finally, we consider particular models in this theory and generate constraints on the coupling parameter for the validity of GSLT in terms of recent cosmic parameters and power law solutions.
Nuclear and fundamental physics instrumentation for the ANS project
Robinson, S.J. [Tennessee Technological Univ., Cookeville, TN (United States). Dept. of Physics; Raman, S.; Arterburn, J.; McManamy, T.; Peretz, F.J. [Oak Ridge National Lab., TN (United States); Faust, H. [Institut Laue-Langevin, 38 - Grenoble (France); Piotrowski, A.E. [Soltan Inst. for Nuclear Studies, Otwock-Swierk (Poland)
1996-05-01T23:59:59.000Z
This report summarizes work carried out during the period 1991-1995 in connection with the refinement of the concepts and detailed designs for nuclear and fundamental physics research instrumentation at the proposed Advanced Neutron source at Oak Ridge National Laboratory. Initially, emphasis was placed on refining the existing System Design Document (SDD-43) to detail more accurately the needs and interfaces of the instruments that are identified in the document. The conceptual designs of these instruments were also refined to reflect current thinking in the field of nuclear and fundamental physics. In particular, the on-line isotope separator (ISOL) facility design was reconsidered in the light of the development of interest in radioactive ion beams within the nuclear physics community. The second stage of this work was to define those instrument parameters that would interface directly with the reactor systems so that these parameters could be considered for the ISOL facility and particularly for its associated ion source. Since two of these options involved ion sources internal to the long slant beam tube, these were studied in detail. In addition, preliminary work was done to identify the needs for the target holder and changing facility to be located in the tangential through-tube. Because many of the planned nuclear and fundamental physics instruments have similar needs in terms of detection apparatus, some progress was also made in defining the parameters for these detectors. 21 refs., 32 figs., 2 tabs.
Fourier expansions for a logarithmic fundamental solution of the polyharmonic equation
Howard S. Cohl
2012-02-08T23:59:59.000Z
In even-dimensional Euclidean space for integer powers of the Laplacian greater than or equal to the dimension divided by two, a fundamental solution for the polyharmonic equation has logarithmic behavior. We give two approaches for developing a Fourier expansion of this logarithmic fundamental solution. The first approach is algebraic and relies upon the construction of two-parameter polynomials. We describe some of the properties of these polynomials, and use them to derive the Fourier expansion for a logarithmic fundamental solution of the polyharmonic equation. The second approach depends on the computation of parameter derivatives of Fourier series for a power-law fundamental solution of the polyharmonic equation. The resulting Fourier series is given in terms of sums over associated Legendre functions of the first kind. We conclude by comparing the two approaches and giving the azimuthal Fourier series for a logarithmic fundamental solution of the polyharmonic equation in rotationally-invariant coordinate systems.
Geometric description of BTZ black holes thermodynamics
Hernando Quevedo; Alberto Sanchez
2008-11-15T23:59:59.000Z
We study the properties of the space of thermodynamic equilibrium states of the Ba\\~nados-Teitelboim-Zanelli (BTZ) black hole in (2+1)-gravity. We use the formalism of geometrothermodynamics to introduce in the space of equilibrium states a $2-$dimensional thermodynamic metric whose curvature is non-vanishing, indicating the presence of thermodynamic interaction, and free of singularities, indicating the absence of phase transitions. Similar results are obtained for generalizations of the BTZ black hole which include a Chern-Simons term and a dilatonic field. Small logarithmic corrections of the entropy turn out to be represented by small corrections of the thermodynamic curvature, reinforcing the idea that thermodynamic curvature is a measure of thermodynamic interaction.
Stretch Efficiency - Thermodynamic Analysis of New Combustion...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
Stretch Efficiency - Thermodynamic Analysis of New Combustion Regimes (Agreement 10037) C. Stuart Daw, Josh A. Pihl, A. Lou Qualls, V. Kalyana Chakravarthy, Johney B. Green, Jr.,...
Thermodynamic Advantages of Low Temperature Combustion Engines...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use...
On the Thermodynamic Geometry of Hot QCD
Stefano Bellucci; Vinod Chandra; Bhupendra Nath Tiwari
2010-10-07T23:59:59.000Z
We study the nature of the covariant thermodynamic geometry arising from the free energy of hot QCD. We systematically analyze the underlying equilibrium thermodynamic configurations of the free energy of 2- and 3-flavor hot QCD with or without including thermal fluctuations in the neighborhood of the QCD transition temperature. We show that there exists a well-defined thermodynamic geometric notion for QCD thermodynamics. The geometry thus obtained has no singularity as an intrinsic Riemannian manifold. We further show that there is a close connection of this geometric approach with the existing studies of correlations and quark number susceptibilities in hot QCD.
On the Thermodynamic Geometry of Hot QCD
Bellucci, Stefano; Tiwari, Bhupendra Nath
2008-01-01T23:59:59.000Z
We study the nature of the covariant thermodynamic geometry arising from the free energy of hot QCD. We systematically analyze the underlying equilibrium thermodynamic configurations of the free energy of 2- and 3-flavor hot QCD with or without including thermal fluctuations in the neighborhood of the QCD transition temperature. We show that there exists a well-defined thermodynamic geometric notion for QCD thermodynamics. The geometry thus obtained has no singularity as an intrinsic Riemannian manifold. We further show that there is a close connection of this geometric approach with the existing studies of correlations and quark number susceptibilities in hot QCD.
Thermodynamics of Lemaitre-Tolman-Bondi Model
Subenoy Chakraborty; Nairwita Mazumder; Ritabrata Biswas
2010-06-13T23:59:59.000Z
Here we consider our universe as inhomogeneous spherically symmetric Lemaitre-Tolman-Bondi Model and analyze the thermodynamics of this model of the universe. The trapping horizon is calculated and is found to coincide with the apparent horizon. The Einstein field equations are shown to be equivalent with the unified first law of thermodynamics. Finally assuming the first law of thermodynamics validity of the generalized second law of thermodynamics is examined at the apparent horizon for the perfect fluid and at the event horizon for holographic dark energy.
5.60 Thermodynamics & Kinetics, Spring 2007
Bawendi, Moungi Gabriel, 1961-
This subject deals primarily with equilibrium properties of macroscopic systems, basic thermodynamics, chemical equilibrium of reactions in gas and solution phase, and rates of chemical reactions.
The thermodynamics of general anesthesia
Heimburg, T; Heimburg, Thomas; Jackson, Andrew D.
2006-01-01T23:59:59.000Z
It is known that the action of general anesthetics is proportional to their partition coefficient in lipid membranes (Meyer-Overton rule). This solubility is, however, directly related to the depression of the temperature of the melting transition found close to body temperature in biomembranes. We propose a thermodynamic extension of the Meyer-Overton rule which is based on free energy changes in the system and thus automatically incorporates the effects of melting point depression. This model provides a quantitative explanation of the pressure reversal of anesthesia. Further, it explains why inflammation and the addition of divalent cations reduce the effectiveness of anesthesia.
Thermodynamics of discrete quantum processes
Janet Anders; Vittorio Giovannetti
2012-11-01T23:59:59.000Z
We define thermodynamic configurations and identify two primitives of discrete quantum processes between configurations for which heat and work can be defined in a natural way. This allows us to uncover a general second law for any discrete trajectory that consists of a sequence of these primitives, linking both equilibrium and non-equilibrium configurations. Moreover, in the limit of a discrete trajectory that passes through an infinite number of configurations, i.e. in the reversible limit, we recover the saturation of the second law. Finally, we show that for a discrete Carnot cycle operating between four configurations one recovers Carnot's thermal efficiency.
Thermodynamics of tubelike flexible polymers
Thomas Vogel; Thomas Neuhaus; Michael Bachmann; Wolfhard Janke
2009-07-17T23:59:59.000Z
In this work we present the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling methods to simulate small bead-stick polymer models with Lennard-Jones interaction among non-bonded monomers. We analyze energetic fluctuations and structural quantities to classify conformational pseudophases. We find that the tube thickness influences the thermodynamic behavior of simple tubelike polymers significantly, i.e., for given temperature, the formation of secondary structures strongly depends on the tube thickness.
Thermodynamic data for uranium fluorides
Leitnaker, J.M.
1983-03-01T23:59:59.000Z
Self-consistent thermodynamic data have been tabulated for uranium fluorides between UF/sub 4/ and UF/sub 6/, including UF/sub 4/ (solid and gas), U/sub 4/F/sub 17/ (solid), U/sub 2/F/sub 9/ (solid), UF/sub 5/ (solid and gas), U/sub 2/F/sub 10/ (gas), and UF/sub 6/ (solid, liquid, and gas). Included are thermal function - the heat capacity, enthalpy, and free energy function, heats of formation, and vaporization behavior.
Thermodynamic Properties of Supported Catalysts
Gorte, Raymond J.
2014-03-26T23:59:59.000Z
The goals of this work were to develop Coulometric Titration as a method for characterizing the thermodynamic redox properties of oxides and to apply this technique to the characterization of ceria- and vanadia-based catalysts. The redox properties of ceria and vanadia are a major part of what makes these materials catalytically active but their properties are also dependent on their structure and the presence of other oxides. Quantifying these properties through the measurement of oxidation energetics was the goal of this work.
Fundamental mechanisms of micromachine reliability
DE BOER,MAARTEN P.; SNIEGOWSKI,JEFFRY J.; KNAPP,JAMES A.; REDMOND,JAMES M.; MICHALSKE,TERRY A.; MAYER,THOMAS K.
2000-01-01T23:59:59.000Z
Due to extreme surface to volume ratios, adhesion and friction are critical properties for reliability of Microelectromechanical Systems (MEMS), but are not well understood. In this LDRD the authors established test structures, metrology and numerical modeling to conduct studies on adhesion and friction in MEMS. They then concentrated on measuring the effect of environment on MEMS adhesion. Polycrystalline silicon (polysilicon) is the primary material of interest in MEMS because of its integrated circuit process compatibility, low stress, high strength and conformal deposition nature. A plethora of useful micromachined device concepts have been demonstrated using Sandia National Laboratories' sophisticated in-house capabilities. One drawback to polysilicon is that in air the surface oxidizes, is high energy and is hydrophilic (i.e., it wets easily). This can lead to catastrophic failure because surface forces can cause MEMS parts that are brought into contact to adhere rather than perform their intended function. A fundamental concern is how environmental constituents such as water will affect adhesion energies in MEMS. The authors first demonstrated an accurate method to measure adhesion as reported in Chapter 1. In Chapter 2 through 5, they then studied the effect of water on adhesion depending on the surface condition (hydrophilic or hydrophobic). As described in Chapter 2, they find that adhesion energy of hydrophilic MEMS surfaces is high and increases exponentially with relative humidity (RH). Surface roughness is the controlling mechanism for this relationship. Adhesion can be reduced by several orders of magnitude by silane coupling agents applied via solution processing. They decrease the surface energy and render the surface hydrophobic (i.e. does not wet easily). However, only a molecular monolayer coats the surface. In Chapters 3-5 the authors map out the extent to which the monolayer reduces adhesion versus RH. They find that adhesion is independent of RH up to a threshold value, depending on the coating chemistry. The mechanism for the adhesion increase beyond this threshold value is that the coupling agent reconfigures from a surface to a bulk phase (Chapter 3). To investigate the details of how the adhesion increase occurs, the authors developed the mechanics for adhesion hysteresis measurements. These revealed that near-crack tip compression is the underlying cause of the adhesion increase (Chapter 4). A vacuum deposition chamber for silane coupling agent deposition was constructed. Results indicate that vapor deposited coatings are less susceptible to degradation at high RH (Chapter 5). To address issues relating to surfaces in relative motion, a new test structure to measure friction was developed. In contrast to other surface micromachined friction test structures, uniform apparent pressure is applied in the frictional contact zone (Chapter 6). The test structure will enable friction studies over a large pressure and dynamic range. In this LDRD project, the authors established an infrastructure for MEMS adhesion and friction metrology. They then characterized in detail the performance of hydrophilic and hydrophobic films under humid conditions, and determined mechanisms which limit this performance. These studies contribute to a fundamental understanding for MEMS reliability design rules. They also provide valuable data for MEMS packaging requirements.
Fundamental Mechanisms of Interface Roughness
Randall L. Headrick
2009-01-06T23:59:59.000Z
Publication quality results were obtained for several experiments and materials systems including: (i) Patterning and smoothening of sapphire surfaces by energetic Ar+ ions. Grazing Incidence Small Angle X-ray Scattering (GISAXS) experiments were performed in the system at the National Synchrotron Light Source (NSLS) X21 beamline. Ar+ ions in the energy range from 300 eV to 1000 eV were used to produce ripples on the surfaces of single-crystal sapphire. It was found that the ripple wavelength varies strongly with the angle of incidence of the ions, which increase significantly as the angle from normal is varied from 55° to 35°. A smooth region was found for ion incidence less than 35° away from normal incidence. In this region a strong smoothening mechanism with strength proportional to the second derivative of the height of the surface was found to be responsible for the effect. The discovery of this phase transition between stable and unstable regimes as the angle of incidence is varied has also stimulated new work by other groups in the field. (ii) Growth of Ge quantum dots on Si(100) and (111). We discovered the formation of quantum wires on 4° misoriented Si(111) using real-time GISAXS during the deposition of Ge. The results represent the first time-resolved GISAXS study of Ge quantum dot formation. (iii) Sputter deposition of amorphous thin films and multilayers composed of WSi2 and Si. Our in-situ GISAXS experiments reveal fundamental roughening and smoothing phenomena on surfaces during film deposition. The main results of this work is that the WSi2 layers actually become smoother during deposition due to the smoothening effect of energetic particles in the sputter deposition process.
Velocity Distributions from Nonextensive Thermodynamics
Eric I. Barnes; Liliya L. R. Williams; Arif Babul; Julianne J. Dalcanton
2006-10-05T23:59:59.000Z
There is no accepted mechanism that explains the equilibrium structures that form in collisionless cosmological N-body simulations. Recent work has identified nonextensive thermodynamics as an innovative approach to the problem. The distribution function that results from adopting this framework has the same form as for polytropes, but the polytropic index is now related to the degree of nonextensiveness. In particular, the nonextensive approach can mimic the equilibrium structure of dark matter density profiles found in simulations. We extend the investigation of this approach to the velocity structures expected from nonextensive thermodynamics. We find that the nonextensive and simulated N-body rms-velocity distributions do not match one another. The nonextensive rms-velocity profile is either monotonically decreasing or displays little radial variation, each of which disagrees with the rms-velocity distributions seen in simulations. We conclude that the currently discussed nonextensive models require further modifications in order to corroborate dark matter halo simulations. (adapted from TeX)
Thermodynamic properties of bulk and confined water
Mallamace, Francesco, E-mail: francesco.mallamace@unime.it [Dipartimento di Fisica e Scienza della Terra Universitŕ di Messina and CNISM, I-98168 Messina (Italy); Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Center for Polymer Studies and Department of Physics, Boston University, Boston, Massachusetts 02215 (United States); Corsaro, Carmelo [Dipartimento di Fisica e Scienza della Terra Universitŕ di Messina and CNISM, I-98168 Messina (Italy); Mallamace, Domenico [Dipartimento di Scienze dell'Ambiente, della Sicurezza, del Territorio, degli Alimenti e della Salute, Universitŕ di Messina, I-98166 Messina (Italy); Vasi, Sebastiano; Vasi, Cirino [IPCF-CNR, I-98166 Messina (Italy); Stanley, H. Eugene [Center for Polymer Studies and Department of Physics, Boston University, Boston, Massachusetts 02215 (United States)
2014-11-14T23:59:59.000Z
The thermodynamic response functions of water display anomalous behaviors. We study these anomalous behaviors in bulk and confined water. We use nuclear magnetic resonance (NMR) to examine the configurational specific heat and the transport parameters in both the thermal stable and the metastable supercooled phases. The data we obtain suggest that there is a behavior common to both phases: that the dynamics of water exhibit two singular temperatures belonging to the supercooled and the stable phase, respectively. One is the dynamic fragile-to-strong crossover temperature (T{sub L} ? 225 K). The second, T{sup *} ? 315 ± 5 K, is a special locus of the isothermal compressibility K{sub T}(T, P) and the thermal expansion coefficient ?{sub P}(T, P) in the P–T plane. In the case of water confined inside a protein, we observe that these two temperatures mark, respectively, the onset of protein flexibility from its low temperature glass state (T{sub L}) and the onset of the unfolding process (T{sup *})
Thermodynamics of topological black holes in $R^{2}$ gravity
Cognola, Guido; Vanzo, Luciano; Zerbini, Sergio
2015-01-01T23:59:59.000Z
We study topological black hole solutions of the simplest quadratic gravity action and we find that two classes are allowed. The first is asymptotically flat and mimics the Reissner-Nordstr\\"om solution, while the second is asymptotically de Sitter or anti-de Sitter. In both classes, the geometry of the horizon can be spherical, toroidal or hyperbolic. We focus in particular on the thermodynamical properties of the asymptotically anti-de Sitter solutions and we compute the entropy and the internal energy with Euclidean methods. We find that the entropy is positive-definite for all horizon geometries and this allows to formulate a consistent generalized first law of black hole thermodynamics, which keeps in account the presence of two arbitrary parameters in the solution. The two-dimensional thermodynamical state space is fully characterized by the underlying scale invariance of the action and it has the structure of a projective space. We find a kind of duality between black holes and other objects with the s...
Out-of-equilibrium Thermodynamics of Quantum Optomechanical Systems
M. Brunelli; A. Xuereb; A. Ferraro; G. De Chiara; N. Kiesel; M. Paternostro
2014-12-15T23:59:59.000Z
We address the out-of-equilibrium thermodynamics of an isolated quantum system consisting of a cavity optomechanical device. We explore the dynamical response of the system when driven out of equilibrium by a sudden quench of the coupling parameter and compute analytically the full distribution of the work generated by the process. We consider linear and quadratic optomechanical coupling, where the cavity field is parametrically coupled to either the position or the square of the position of a mechanical oscillator, respectively. In the former case we find that the average work generated by the quench is zero, whilst the latter leads to a non-zero average value. Through fluctuations theorems we access the most relevant thermodynamical figures of merit, such as the free energy difference and the amount of irreversible work generated. We thus provide a full characterization of the out-of-equilibrium thermodynamics in the quantum regime for nonlinearly coupled bosonic modes. Our study is the first due step towards the construction and full quantum analysis of an optomechanical machine working fully out of equilibrium.
THERMODYNAMICS OF SOLID AND LIQUID GROUP III-V ALLOYS
Anderson, T.J.
2011-01-01T23:59:59.000Z
D.A. Stevenson, J. Chern. Thermodynamics, J.V. Smith, D.J.P. Bros, J. Chern. Thermodynamics, z, R. Hultgren, P.D.J.M. Prausnitz, Molecular Thermodynamics of Fluid-Phase
Julie N. Howat & Colin S. Howat Kurata Thermodynamics Laboratory
Howat, Colin S. "Chip"
at KTL Kurata Thermodynamics Laboratory Department of Chemical & Petroleum Engineering UniversityJulie N. Howat & Colin S. Howat Kurata Thermodynamics Laboratory Department of Chemical & Petroleum Total Pressure Method , xsat #12;Kurata Thermodynamics Laboratory Department of Chemical & Petroleum
Modeling of Geothermal Reservoirs: Fundamental Processes, Computer...
Reservoirs: Fundamental Processes, Computer Simulation and Field Applications Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Modeling of...
"Fundamental Challenges in Solar Energy Conversion" workshop...
Office of Science (SC) Website
Fundamental Challenges in Solar Energy Conversion" workshop hosted by LMI-EFRC Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events...
A linear nonequilibrium thermodynamics approach to optimization of thermoelectric devices
Ouerdane, H; Apertet, Y; Michot, A; Abbout, A
2013-01-01T23:59:59.000Z
Improvement of thermoelectric systems in terms of performance and range of applications relies on progress in materials science and optimization of device operation. In this chapter, we focuse on optimization by taking into account the interaction of the system with its environment. For this purpose, we consider the illustrative case of a thermoelectric generator coupled to two temperature baths via heat exchangers characterized by a thermal resistance, and we analyze its working conditions. Our main message is that both electrical and thermal impedance matching conditions must be met for optimal device performance. Our analysis is fundamentally based on linear nonequilibrium thermodynamics using the force-flux formalism. An outlook on mesoscopic systems is also given.
Hessian structures, Euler vector fields, and thermodynamics
M. Á. García-Ariza
2015-03-02T23:59:59.000Z
In this paper, a geometric structure which generalizes that of thermodynamics is presented; spaces of equilibrium states are portrayed as a particular case of the former. For this end, concepts like Euler vector field and extensive function, which are usual in thermodynamics, are introduced in a wider context.
Loop expansion in Yang-Mills thermodynamics
Ralf Hofmann
2009-11-05T23:59:59.000Z
We argue that a selfconsistent spatial coarse-graining, which involves interacting (anti)calorons of unit topological charge modulus, implies that real-time loop expansions of thermodynamical quantities in the deconfining phase of SU(2) and SU(3) Yang-Mills thermodynamics are, modulo 1PI resummations, determined by a finite number of connected bubble diagrams.
Zevenhoven, Ron
EngineeringThermodynamicsThermodynamics coursecourse # 424304.0# 424304.0 v.v. 20132013 Solar energy (thermal, PV)gy ( , ) Ron Zevenhoven ĹĹbo Akademi 2/52 #12;Potential Solar energy could within one hour provide the energy that is used in all human acitivities in a year. Drawbacks are relatively low energy (exergy) density Pic: IEA08 (exergy) density
Thermodynamics of Protein Folding Erik Sandelin
Sandelin, Erik
Thermodynamics of Protein Folding and Design Erik Sandelin Department of Theoretical Physics Lund Sölvegatan 14A 223 62 LUND September 2000 Erik Sandelin Thermodynamics of Protein Folding and Design The protein folding and protein design problems are addressed, using coarse-grained models with only two types
NUCLEAR THERMODYNAMIC DATABASE MOX-TDB
Paris-Sud XI, Université de
NUCLEAR THERMODYNAMIC DATABASE « MOX-TDB » Ba-Fe-La-O-Pu-Ru-Sr-U-Zr + Ar-H Version 2006-01 6 rue du hal-00160137,version1-5Jul2007 #12;MOX-TDB Nuclear Thermodynamic Database Version 2006-01 developed examined and rechecked before final conclusions are drawn. hal-00160137,version1-5Jul2007 #12;MOX
Thermodynamic and quantum bounds on nonlinear DC thermoelectric transport
Robert S. Whitney
2013-03-05T23:59:59.000Z
I consider the non-equilibrium DC transport of electrons through a quantum system with a thermoelectric response. This system may be any nanostructure or molecule modeled by the nonlinear scattering theory which includes Hartree-like electrostatic interactions exactly, and certain dynamic interaction effects (decoherence and relaxation) phenomenologically. This theory is believed to be a reasonable model when single-electron charging effects are negligible. I derive three fundamental bounds for such quantum systems coupled to multiple macroscopic reservoirs, one of which may be superconducting. These bounds affect nonlinear heating (such as Joule heating), work and entropy production. Two bounds correspond to the first law and second law of thermodynamics in classical physics. The third bound is quantum (wavelength dependent), and is as important as the thermodynamic ones in limiting the capabilities of mesoscopic heat-engines and refrigerators. The quantum bound also leads to Nernst's unattainability principle that the quantum system cannot cool a reservoir to absolute zero in a finite time, although it can get exponentially close.
The Mathematical Structure of the Second Law of Thermodynamics
Elliott H. Lieb; Jakob Yngvason
2003-02-07T23:59:59.000Z
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose increase characterizes the possible state changes under adiabatic conditions. It is one of the few really fundamental physical laws (in the sense that no deviation, however tiny, is permitted) and its consequences are far reaching. This principle is independent of models, statistical mechanical or otherwise, and can be understood without recourse to Carnot cycles, ideal gases and other assumptions about such things as `heat', `temperature', `reversible processes', etc., as is usually done. Also the well known formula of statistical mechanics, S = -\\sum p log p, is not needed for the derivation of the entropy principle. This contribution is partly a summary of our joint work (Physics Reports, Vol. 310, 1--96 (1999)) where the existence and uniqueness of S is proved to be a consequence of certain basic properties of the relation of adiabatic accessibility among equilibrium states. We also present some open problems and suggest directions for further study.
Solid-State Hydrogen Storage: Storage Capacity,Thermodynamics...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Hydrogen Storage: Storage Capacity,Thermodynamics and Kinetics. Solid-State Hydrogen Storage: Storage Capacity,Thermodynamics and Kinetics. Abstract: Solid-state reversible...
Thermodynamic Investigations of Lithium- and Manganese-Rich Transition...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides 2013 DOE...
Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Abstract: Molecular simulation techniques...
Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A Predictive Model through Computations. Comprehensive Thermodynamics of Nickel Hydride Bis(Diphosphine) Complexes: A...
Thermodynamics of Sorption and Distribution of Water in Nafion
Victoria, University of
Thermodynamics of Sorption and Distribution of Water in Nafion by Gwynn Johan Elfring B Thermodynamics of Sorption 20 2.1 System
Benzene Dimer: Dynamic Structure and Thermodynamics Derived from...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Benzene Dimer: Dynamic Structure and Thermodynamics Derived from On-the-Fly ab initio DFT-D Molecular Dynamic Simulations. Benzene Dimer: Dynamic Structure and Thermodynamics...
The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer
Brewer, Leo
2010-01-01T23:59:59.000Z
No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric
Thermodynamic Guidelines for the Prediction of Hydrogen Storage...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures Thermodynamic Guidelines for the Prediction of...
Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants...
Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants - 2013 Peer Review Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants - 2013 Peer Review...
Supriya Pan; Subenoy Chakraborty
2015-04-12T23:59:59.000Z
The paper deals with non-equilibrium thermodynamics based on adiabatic particle creation mechanism with the motivation of considering it as an alternative choice to explain the recent observed accelerating phase of the universe. Using Friedmann equations, it is shown that the deceleration parameter ($q$) can be obtained from the knowledge of the particle production rate ($\\Gamma$). Motivated from thermodynamical point of view, cosmological solutions are evaluated for the particle creation rates in three cosmic phases, namely, inflation, matter dominated and present late time acceleration. The deceleration parameter ($q$) is expressed as a function of the redshift parameter ($z$), and its variation is presented graphically. Also, statefinder analysis has been presented graphically in three different phases of the universe. Finally, two non-interacting fluids with different particle creation rates are considered as cosmic substratum, and deceleration parameter ($q$) is evaluated. It is examined whether more than one transition of $q$ is possible or not by graphical representations.
Light particles A window to fundamental physics
Jaeckel, Joerg [Institute for Particle Physics Phenomenology, Durham University, Durham DH1 3LE (United Kingdom)
2010-08-30T23:59:59.000Z
In these proceedings we illustrate that light, very weakly interacting particles can arise naturally from physics which is fundamentally connected to very high energy scales. Searching for them therefore may give us interesting new insights into the structure of fundamental physics. The prime example is the axion.
Thermodynamics of asymptotically safe theories
Rischke, Dirk H
2015-01-01T23:59:59.000Z
We investigate the thermodynamic properties of a novel class of gauge-Yukawa theories that have recently been shown to be completely asymptotically safe, because their short-distance behaviour is determined by the presence of an interacting fixed point. Not only do all the coupling constants freeze at a constant and calculable value in the ultraviolet, their values can even be made arbitrarily small for an appropriate choice of the ratio $N_c/N_f$ of fermion colours and flavours in the Veneziano limit. Thus, a perturbative treatment can be justified. We compute the pressure, entropy density, and thermal degrees of freedom of these theories to next-to-next-to-leading order in the coupling constants.
Thermodynamics of decaying vacuum cosmologies
Lima, J.A. [Physics Department, Brown University, Providence, Rhode Island 02912 (United States)] [Physics Department, Brown University, Providence, Rhode Island 02912 (United States); [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970, Natal, RN (Brazil)
1996-08-01T23:59:59.000Z
The thermodynamic behavior of decaying vacuum cosmologies is investigated within a manifestly covariant formulation. Such a process corresponds to a continuous, irreversible energy flow from the vacuum component to the created matter constituents. It is shown that if the specific entropy per particle remains constant during the process, the equilibrium relations are preserved. In particular, if the vacuum decays into photons, the energy density {rho} and average number density of photons {ital n} scale with the temperature as {rho}{approximately}{ital T}{sup 4} and {ital n}{approximately}{ital T}{sup 3}. The temperature law is determined and a generalized Planckian-type form of the spectrum, which is preserved in the course of the evolution, is also proposed. Some consequences of these results for decaying vacuum FRW-type cosmologies as well as for models with {open_quote}{open_quote}adiabatic{close_quote}{close_quote} photon creation are discussed. {copyright} {ital 1996 The American Physical Society.}
Thermodynamics, Optical Properties and Coordination Modes of Np(V) with Dipicolinic Acid
Tian, Guoxin
2010-01-01T23:59:59.000Z
Thermodynamics, Optical Properties and Coordination Modes ofacid, complexation, thermodynamics, coordination mode 1.
Jeff Schulte; Patrick Kreitzberg; Chris Haglund; David Roundy
2012-08-31T23:59:59.000Z
We investigate the value of the correlation function of an inhomogeneous hard-sphere fluid at contact. This quantity plays a critical role in Statistical Associating Fluid Theory (SAFT), which is the basis of a number of recently developed classical density functionals. We define two averaged values for the correlation function at contact, and derive formulas for each of them from the White Bear version of the Fundamental Measure Theory functional, using an assumption of thermodynamic consistency. We test these formulas, as well as two existing formulas against Monte Carlo simulations, and find excellent agreement between the Monte Carlo data and one of our averaged correlation functions.
The Department of Energy's National Security Information Fundamental...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
The Department of Energy's National Security Information Fundamental Classification Guidance Review The Department of Energy's National Security Information Fundamental...
Thermodynamics for Single-Molecule Stretching Experiments J. M. Rubi,*, D. Bedeaux, and S. Kjelstrup
Kjelstrup, Signe
Thermodynamics for Single-Molecule Stretching Experiments J. M. Rubi,*, D. Bedeaux, and S to construct nonequilibrium thermodynamics for systems too small to be considered thermodynamically be viewed as a large thermodynamic system, we discuss the validity of nonequilibrium thermodynamics
On the dynamics and thermodynamics of small Markov-type material systems
Andrzej Trzesowski
2015-05-21T23:59:59.000Z
The collective properties of small material systems considered as semidynamical systems revealing the Markov-type irreversible evolution, are investigated. It is shown that these material systems admit their treatment as thermodynamic systems in diathermal and isothermal conditions. A kinetic equation describing statistical regularities of the Markov-type material systems and constrained by the compatibility condition with the first and second laws of thermodynamics and with the relaxation postulate, is proposed. The influence of external parameters on the Gibbs distribution of small material systems is discussed.
Christoph Junghans; Michael Bachmann; Wolfhard Janke
2007-12-06T23:59:59.000Z
We employ a mesoscopic model for studying aggregation processes of protein-like hydrophobic-polar heteropolymers. By means of multicanonical Monte Carlo computer simulations, we find strong indications that peptide aggregation is a phase separation process, in which the microcanonical entropy exhibits a convex intruder due to nonnegligible surface effects of the small systems. We analyze thermodynamic properties of the conformational transitions accompanying the aggregation process from the multicanonical, canonical, and microcanonical perspective. It turns out that the microcanonical description is particularly advantageous as it allows for unraveling details of the phase-separation transition in the thermodynamic region, where the temperature is not a suitable external control parameter anymore.
Finite-time thermodynamic analysis of the Stirling engine
Ibrahim, O.M. [Univ. of Rhode Island, Kingston, RI (United States). Mechanical Engineering Dept.; Ladas, H.G. [Environmental Engineering Corp., North Kingstown, RI (United States)
1995-12-31T23:59:59.000Z
This paper presents a finite-time thermodynamic analysis of the Stirling engine cycle. A lumped-parameter thermodynamic model is used to describe the dynamic behavior of the Stirling engine. The mathematical formulation of this model is based on mass and energy balances with associated heat transfer rate equations. These governing equations are formulated into a set of ordinary differential equations, which are then solved numerically to obtain the dynamic behavior of the Stirling engine. Close inspection of the governing equations reveals that the time to complete on cycle, {tau} and the engine time constant, {tau}{sub c} always appear together in a dimensionless ratio. This ratio, {tau}/{tau}{sub c}, is defined here as the Finite-Time Parameter, FTP. The effects of FTP upon power output and efficiency, are studied. The results show that there exists an optimum power output for a given engine design, based on engine speed and heat-transfer contact time. The results also provide an engineering evaluation procedure to improve the efficiency and power output of Stirling engines.
DOE fundamentals handbook: Nuclear physics and reactor theory. Volume 2
Not Available
1993-01-01T23:59:59.000Z
The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.
DOE fundamentals handbook: Nuclear physics and reactor theory
Not Available
1993-01-01T23:59:59.000Z
The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.
DOE fundamentals handbook: Nuclear physics and reactor theory. Volume 1
Not Available
1993-01-01T23:59:59.000Z
The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.
Modeling of fundamental phenomena in welds
Zacharia, T.; Vitek, J.M. [Oak Ridge National Lab., TN (United States); Goldak, J.A. [Carleton Univ., Ottawa, Ontario (Canada); DebRoy, T.A. [Pennsylvania State Univ., University Park, PA (United States); Rappaz, M. [Ecole Polytechnique Federale de Lausanne (Switzerland); Bhadeshia, H.K.D.H. [Cambridge Univ. (United Kingdom)
1993-12-31T23:59:59.000Z
Recent advances in the mathematical modeling of fundamental phenomena in welds are summarized. State-of-the-art mathematical models, advances in computational techniques, emerging high-performance computers, and experimental validation techniques have provided significant insight into the fundamental factors that control the development of the weldment. The current status and scientific issues in the areas of heat and fluid flow in welds, heat source metal interaction, solidification microstructure, and phase transformations are assessed. Future research areas of major importance for understanding the fundamental phenomena in weld behavior are identified.
Gauge field and geometric control of quantum-thermodynamic engine
Sumiyoshi Abe
2011-09-14T23:59:59.000Z
The problem of extracting the work from a quantum-thermodynamic system driven by slowly varying external parameters is discussed. It is shown that there naturally emerges a gauge-theoretic structure. The field strength identically vanishes if the system is in an equilibrium state, i.e., the nonvanishing field strength implies that the system is in a nonequilibrium quasi-stationary state. The work done through a cyclic process in the parameter space is given in terms of the flux of the field. This general formalism is applied to an example of a single spin in a varying magnetic field, and the maximum power output is discussed in a given finite-time cyclic process.
Spacetime thermodynamics of the glass transition Mauro Merolle
Chandler, David
Spacetime thermodynamics of the glass transition Mauro Merolle , Juan P. Garrahan , and David thermodynamic sense. Nevertheless, the phenom- enon is relatively precipitous, and the thermodynamic conditions an explanation of this behavior in terms of a thermodynamics of trajectory space. Our considerations seem
EK424 THERMODYNAMICS AND STATISTICAL MECHANICS Boston University
EK424 THERMODYNAMICS AND STATISTICAL MECHANICS Boston University Fall 2012 Thermodynamics of energy. A thermodynamic system is a collection of matter, defined by some macroscopic variables in a piston. Thermodynamics is the study of processes done on the system, and explains how the macroscopic
Predicting Improved Chiller Performance Through Thermodynamic Modeling
Figueroa, I. E.; Cathey, M.; Medina, M. A.; Nutter, D. W.
This paper presents two case studies in which thermodynamic modeling was used to predict improved chiller performance. The model predicted the performance (COP and total energy consumption) of water-cooled centrifugal chillers as a function...
Process Engineering Thermodynamics 424304 E (4 sp)
Zevenhoven, Ron
Process Engineering Thermodynamics 424304 E (4 sp) Exam 20-3-2013 All support material is allowed for the pump in the turbine cycle may be neglected). a. What is the electric power output of this OTEC plant
QCD Thermodynamics on the Lattice: Recent Results
Carleton DeTar
2010-12-31T23:59:59.000Z
I give a brief introduction to the goals, challenges, and technical difficulties of lattice QCD thermodynamics and present some recent results from the HotQCD collaboration for the crossover temperature, equation of state, and other observables.
Linear Thermodynamics of Rodlike DNA Filtration
Li, Zirui
Linear thermodynamics transportation theory is employed to study filtration of rodlike DNA molecules. Using the repeated nanoarray consisting of alternate deep and shallow regions, it is demonstrated that the complex ...
Thermodynamics in NJL-like models
A. V. Friesen; Yu. L. Kalinovsky; V. D. Toneev
2011-03-11T23:59:59.000Z
Thermodynamic behavior of conventional Nambu-Jona-Lasinio and Polyakov-loop-extended Nambu-Jona-Lasinio models is compared. A particular attention is paid to the phase diagram in the ($T -\\mu$) plane.
Quantum thermodynamics of general quantum processes
Felix C. Binder; Sai Vinjanampathy; Kavan Modi; John Goold
2015-03-27T23:59:59.000Z
Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to arbitrary quantum states. We formulate an operational thermodynamics suitable for application to an open quantum system undergoing quantum evolution under a general quantum process by which we mean a completely-positive and trace-preserving map. We derive an operational first law of thermodynamics for such processes and show consistency with the second law. We show that heat, from the first law, is positive when the input state of the map majorises the output state. Moreover, the change in entropy is also positive for the same majorisation condition. This makes a strong connection between the two operational laws of thermodynamics.
Some Fundamental Limitations for Cognitive Radio
Sahai, Anant
' & $ % Some Fundamental Limitations for Cognitive Radio Anant Sahai Wireless Foundations, UCB EECS program November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Outline 1. Why cognitive radios? 2 November 1 at BWRC Cognitive Radio Workshop #12;' & $ % Apparent spectrum allocations Â· Traditional
Tables of thermodynamic properties of sodium
Fink, J.K.
1982-06-01T23:59:59.000Z
The thermodynamic properties of saturated sodium, superheated sodium, and subcooled sodium are tabulated as a function of temperature. The temperature ranges are 380 to 2508 K for saturated sodium, 500 to 2500 K for subcooled sodium, and 400 to 1600 K for superheated sodium. Tabulated thermodynamic properties are enthalpy, heat capacity, pressure, entropy, density, instantaneous thermal expansion coefficient, compressibility, and thermal pressure coefficient. Tables are given in SI units and cgs units.
Thermodynamics of (2+1)-flavor QCD
C. Schmidt; T. Umeda
2006-09-21T23:59:59.000Z
We report on the status of our QCD thermodynamics project. It is performed on the QCDOC machine at Brookhaven National Laboratory and the APEnext machine at Bielefeld University. Using a 2+1 flavor formulation of QCD at almost realistic quark masses we calculated several thermodynamical quantities. In this proceeding we show the susceptibilites of the chiral condensate and the Polyakov loop, the static quark potential and the spatial string tension.
Theory and practice in engineering thermodynamics
Polak, P.
1983-01-01T23:59:59.000Z
The book is a new approach to engineering thermodynamics for students of mechanical engineering at diploma and degree levels. There is an explanation of the basic principles of thermodynamics, followed by several chapters illustrating these principles as applied to piston engines, the gas turbine, steam power, and refrigerators and heat pumps. The book aims to introduce some key features of theory and current practice in a way that students will find interesting.
Ch 15. Thermodynamics Liu UCD Phy1B 2012 1
Yoo, S. J. Ben
Ch 15. Thermodynamics Liu UCD Phy1B 2012 1 #12;I The First Law of ThermodynamicsI. The First Law of Thermodynamics Closed system: U=Q-Wy Q U Internal energy: all the energy of the moleculesgy gy for an ideal gas1B 2012 2 #12;Thermodynamic ProcessesThermodynamic Processes Isothermal: T=0, U=0, Q=W Adiabatic: Q
Thermodynamics of quantum jump trajectories in systems driven by classical fluctuations
Adrian A. Budini
2010-12-03T23:59:59.000Z
The large-deviation method can be used to study the measurement trajectories of open quantum systems. For optical arrangements this formalism allows to describe the long time properties of the (non-equilibrium) photon counting statistics in the context of a (equilibrium) thermodynamic approach defined in terms of dynamical phases and transitions between them in the trajectory space [J.P. Garrahan and I. Lesanovsky, Phys. Rev. Lett. 104, 160601 (2010)]. In this paper, we study the thermodynamic approach for fluorescent systems coupled to complex reservoirs that induce stochastic fluctuations in their dynamical parameters. In a fast modulation limit the thermodynamics corresponds to that of a Markovian two-level system. In a slow modulation limit, the thermodynamic properties are equivalent to those of a finite system that in an infinite-size limit is characterized by a first-order transition. The dynamical phases correspond to different intensity regimes, while the size of the system is measured by the transition rate of the bath fluctuations. As a function of a dimensionless intensive variable, the first and second derivative of the thermodynamic potential develop an abrupt change and a narrow peak respectively. Their scaling properties are consistent with a double-Gaussian probability distribution of the associated extensive variable.
Thermodynamic Relationships for Bulk Crystalline and Liquid Phases in the Phase-Field Crystal Model
Victor W. L. Chan; Nirand Pisutha-Arnond; Katsuyo Thornton
2015-02-06T23:59:59.000Z
We present thermodynamic relationships between the free energy of the phase-field crystal (PFC) model and thermodynamic state variables for bulk phases under hydrostatic pressure. This relationship is derived based on the thermodynamic formalism for crystalline solids of Larch\\'e and Cahn [Larch\\'e and Cahn, Acta Metallurgica, Vol. 21, 1051 (1973)]. We apply the relationship to examine the thermodynamic processes associated with varying the input parameters of the PFC model: temperature, lattice spacing, and the average value of the PFC order parameter, $\\bar{n}$. The equilibrium conditions between bulk crystalline solid and liquid phases are imposed on the thermodynamic relationships for the PFC model to obtain a procedure for determining solid-liquid phase coexistence. The resulting procedure is found to be in agreement with the method commonly used in the PFC community, justifying the use of the common-tangent construction to determine solid-liquid phase coexistence in the PFC model. Finally, we apply the procedure to an eighth-order-fit (EOF) PFC model that has been parameterized to body-centered-cubic ($bcc$) Fe [Jaatinen et al., Physical Review E 80, 031602 (2009)] to demonstrate the procedure as well as to develop physical intuition about the PFC input parameters. We demonstrate that the EOF-PFC model parameterization does not predict stable $bcc$ structures with positive vacancy densities. This result suggests an alternative parameterization of the PFC model, which requires the primary peak position of the two-body direct correlation function to shift as a function of $\\bar{n}$.
Thermodynamics of neptunium(V) fluoride and sulfate at elevated temperatures
Rao, Linfeng; Tian, Guoxin; Xia, Yuanxian; Friese, Judah I.
2006-01-01T23:59:59.000Z
Rao, O. Tochiyama; “Chemical Thermodynamics of Compounds andUpdate on the chemical thermodynamics of uranium, neptunium,Thermodynamics of Neptunium(V) Fluoride and Sulfate at
THERMODYNAMICS OF LOW-TEMPERATURE (700-850oC) HOT CORROSION
Misra, A.K.
2013-01-01T23:59:59.000Z
Ref. 2). J. Lumsden, Thermodynamics of molten salt mixtures,R. Defay, Chemical thermodynamics, Longmans Green and Co. ,Electrochemical Society THERMODYNAMICS OF LOW-TEMPERATURE {
Correlating structure and thermodynamics of hydrophobicâ??hydrophilic ion pairs in water
Benjamin, Ilan
2015-01-01T23:59:59.000Z
Correlating Structure and Thermodynamics of Hydrophobic-hydration structure and thermodynamics associated with thefunction) with the thermodynamics (potential of mean force
Silvester, Leonard F.
2011-01-01T23:59:59.000Z
09 THERMODYNAMICS OFELECI'ROLYTES. X'rights. r'-" e. ct THERMODYNAMICS OF ELECTROLYTES. X.Coefficient, Electrolyte, Thermodynamics v ~p , I J ! l
Thermodynamics and the role of allostery in the thrombin- thrombomodulin interaction
Beach, Muneera Aina
2008-01-01T23:59:59.000Z
64 Chapter IV Using Thermodynamics to Probe the Allosteric81 Table 4.3. Thermodynamics of isotherms atOF CALIFORNIA, SAN DIEGO Thermodynamics and the Role of
Thermodynamic properties of a magnetically modulated graphene
SK Firoz Islam; Naveen K. Singh; Tarun Kanti Ghosh
2011-09-12T23:59:59.000Z
The effect of magnetic modulation on thermodynamic properties of a graphene monolayer in presence of a constant perpendicular magnetic field is reported here. One-dimensional spatial electric or magnetic modulation lifts the degeneracy of the Landau levels and converts into bands and their band width oscillates with magnetic field leading to Weiss-type oscillation in the thermodynamic properties. The effect of magnetic modulation on thermodynamic properties of a graphene sheet is studied and then compared with electrically modulated graphene and magnetically modulated conventional two-dimensional electron gas (2DEG). We observe Weiss-type and de Haas-van Alphen (dHvA) oscillations at low and high magnetic field, respectively. There is a definite phase difference in Weiss-type oscillations in thermodynamic quantities of magnetically modulated graphene in compare to electrically modulated graphene. On the other hand, the phase remains same and amplitude of the oscillation is large when compared with the magnetically modulated 2DEG. Explicit asymptotic expressions of density of states and the Helmholtz free energy are provided to understand the phase and amplitude of the Weiss-type oscillations qualitatively. We also study thermodynamic properties when both electric and magnetic modulations are present. The Weiss-type oscillations still exist when the modulations are out-of-phase.
Design of a robust superhydrophobic surface: thermodynamic and kinetic analysis
Anjishnu Sarkar; Anne-Marie Kietzig
2014-12-17T23:59:59.000Z
The design of a robust superhydrophobic surface is a widely pursued topic.While many investigations are limited to applications with high impact velocities (for raindrops of the order of a few m/s), the essence of robustness is yet to be analyzed for applications involving quasi-static liquid transfer.To achieve robustness with high impact velocities, the surface parameters (geometrical details, chemistry) have to be selected from a narrow range of permissible values, which often entail additional manufacturing costs.From the dual perspectives of thermodynamics and mechanics, we analyze the significance of robustness for quasi-static drop impact, and present the range of permissible surface characteristics.For surfaces with a Youngs contact angle greater than 90{\\deg} and square micropillar geometry, we show that robustness can be enforced when an intermediate wetting state (sagged state) impedes transition to a wetted state (Wenzel state).From the standpoint of mechanics, we use available scientific data to prove that a surface with any topology must withstand a pressure of 117 Pa to be robust.Finally, permissible values of surface characteristics are determined, which ensure robustness with thermodynamics (formation of sagged state) and mechanics (withstanding 117 Pa).
DOE Fundamentals Handbook: Mathematics, Volume 2
Not Available
1992-06-01T23:59:59.000Z
The Mathematics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mathematics and its application to facility operation. The handbook includes a review of introductory mathematics and the concepts and functional use of algebra, geometry, trigonometry, and calculus. Word problems, equations, calculations, and practical exercises that require the use of each of the mathematical concepts are also presented. This information will provide personnel with a foundation for understanding and performing basic mathematical calculations that are associated with various DOE nuclear facility operations.
DOE Fundamentals Handbook: Electrical Science, Volume 2
Not Available
1992-06-01T23:59:59.000Z
The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.
DOE Fundamentals Handbook: Mathematics, Volume 1
Not Available
1992-06-01T23:59:59.000Z
The Mathematics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mathematics and its application to facility operation. The handbook includes a review of introductory mathematics and the concepts and functional use of algebra, geometry, trigonometry, and calculus. Word problems, equations, calculations, and practical exercises that require the use of each of the mathematical concepts are also presented. This information will provide personnel with a foundation for understanding and performing basic mathematical calculations that are associated with various DOE nuclear facility operations.
DOE Fundamentals Handbook: Electrical Science, Volume 4
Not Available
1992-06-01T23:59:59.000Z
The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive transformers; and electrical test components; batteries; AC and DC voltage regulators; instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.
DOE Fundamentals Handbook: Electrical Science, Volume 3
Not Available
1992-06-01T23:59:59.000Z
The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.
DOE Fundamentals Handbook: Electrical Science, Volume 1
Not Available
1992-06-01T23:59:59.000Z
The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.
NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement #10049 ...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
(Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) NOx Adsorber (Lean NOx Trap) Fundamentals (Agreement 10049 - PNNL Project 47120) Presentation from the U.S....
Lunar geophysics: The Moon's fundamental shape and paleomagnetism studies
Perera, Viranga
2014-01-01T23:59:59.000Z
Tectonics. Reviews of Geophysics and Space Physics SANTA CRUZ Lunar geophysics: The Moon’s fundamental shapeViranga Perera Lunar geophysics: The Moon’s fundamental
Fundamentals of Traveling Wave Ion Mobility Spectrometry. | EMSL
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Fundamentals of Traveling Wave Ion Mobility Spectrometry. Fundamentals of Traveling Wave Ion Mobility Spectrometry. Abstract: Traveling-wave ion mobility spectrometry (TW IMS) is a...
SciTech Connect: Fundamental aspects of nuclear reactor fuel...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Fundamental aspects of nuclear reactor fuel elements Citation Details In-Document Search Title: Fundamental aspects of nuclear reactor fuel elements You are accessing a document...
Developments in Petroleum Science, 6 FUNDAMENTALS OF NUMERICAL
Santos, Juan
Developments in Petroleum Science, 6 FUNDAMENTALS OF NUMERICAL RESERVOIR SIMULATION DONALD WCongressCatalogingin PublicationData Peaceman, Donald W Fundamentals of numerical reservoir simulation. (develrpents in petroleum
The thermodynamics of general and local anesthesia
Graesboll, Kaare; Heimburg, Thomas
2014-01-01T23:59:59.000Z
General anesthetics are known to cause depression of the freezing point of transitions in biomembranes. This is a consequence of ideal mixing of the anesthetic drugs in the membrane fluid phase and exclusion from the solid phase. Such a generic law provides physical justification of the famous Meyer-Overton rule. We show here that general anesthetics, barbiturates and local anesthetics all display the same effect on melting transitions. Their effect is reversed by hydrostatic pressure. Thus, the thermodynamic behavior of local anesthetics is very similar to that of general anesthetics. We present a detailed thermodynamic analysis of heat capacity profiles of membranes in the presence of anesthetics. This analysis is able to describe experimentally observed calorimetric profiles and permits prediction of the anesthetic features of arbitrary molecules. In addition, we discuss the thermodynamic origin of the cutoff-effect of long-chain alcohols and the additivity of the effect of general and local anesthetics.
Quantum Thermodynamic Cycles and quantum heat engines
H. T. Quan; Yu-xi Liu; C. P. Sun; Franco Nori
2007-04-03T23:59:59.000Z
In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quantum thermodynamic cycles. We find that there is no violation of the second law, even in the existence of such a demon, when the demon is included correctly as part of the working substance of the heat engine.
A microscopic perspective on stochastic thermodynamics
Bernhard Altaner; Jürgen Vollmer
2015-05-18T23:59:59.000Z
We consider stochastic thermodynamics as a theory of statistical inference for experimentally observed fluctuating time-series. To that end, we introduce a general framework for quantifying the knowledge about the dynamical state of the system on two scales: a fine-grained or microscopic, deterministic and a coarse-grained or mesoscopic, stochastic level of description. For a generic model dynamics, we show how the mathematical expressions for fluctuating entropy changes used in Markovian stochastic thermodynamics emerge naturally. Our ideas are conceptional approaches towards (i) connecting entropy production and its fluctuation relations in deterministic and stochastic systems and (ii) providing a complementary information-theoretic picture to notions of entropy and entropy production in stochastic thermodynamics.
Towards a 'Thermodynamics' of Active Matter
Sho C. Takatori; John F. Brady
2014-11-21T23:59:59.000Z
Self-propulsion allows living systems to display unusual collective behavior. Unlike passive systems in thermal equilibrium, active matter systems are not constrained by conventional thermodynamic laws. A question arises however as to what extent, if any, can concepts from classical thermodynamics be applied to nonequilibrium systems like active matter. Here we use the new swim pressure perspective to develop a simple theory for predicting phase separation in active matter. Using purely mechanical arguments we generate a phase diagram with a spinodal and critical point, and define a nonequilibrium chemical potential to interpret the "binodal." We provide a generalization of thermodynamic concepts like the free energy and temperature for nonequilibrium active systems. Our theory agrees with existing simulation data both qualitatively and quantitatively and may provide a framework for understanding and predicting the behavior of nonequilibrium active systems.
Thermodynamics of pairing in mesoscopic systems
Tony Sumaryada; Alexander Volya
2007-06-12T23:59:59.000Z
Using numerical and analytical methods implemented for different models we conduct a systematic study of thermodynamic properties of pairing correlation in mesoscopic nuclear systems. Various quantities are calculated and analyzed using the exact solution of pairing. An in-depth comparison of canonical, grand canonical, and microcanonical ensemble is conducted. The nature of the pairing phase transition in a small system is of a particular interest. We discuss the onset of discontinuity in the thermodynamic variables, fluctuations, and evolution of zeros of the canonical and grand canonical partition functions in the complex plane. The behavior of the Invariant Correlational Entropy is also studied in the transitional region of interest. The change in the character of the phase transition due to the presence of magnetic field is discussed along with studies of superconducting thermodynamics.
Black Hole Thermodynamics Based on Unitary Evolutions
Feng, Yu-Lei
2015-01-01T23:59:59.000Z
In this paper, we try to construct black hole thermodynamics based on the fact that, the formation and evaporation of a black hole can be described by quantum unitary evolutions. First, we show that the Bekenstein-Hawking entropy $S_{BH}$ cannot be a Boltzmann or thermal entropy. To confirm this statement, we show that the original black hole's "first law" cannot be treated as the first law of thermodynamics formally, due to some missing metric perturbations caused by matter. Then, by including those (quantum) metric perturbations, we show that the black hole formation and evaporation can be described in a unitary manner effectively, through a quantum channel between the exterior and interior of the event horizon. In this way, the paradoxes of information loss and firewall can be resolved effectively. Finally, we show that black hole thermodynamics can be constructed in an ordinary way, by constructing statistical mechanics.
Najmabadi, Farrokh
Flexible CO2 laser system for fundamental research related to an extreme ultraviolet lithography 2009; published online 10 December 2009 A CO2 laser system with flexible parameters was developed 1010 W/cm2 . Utilizing this CO2 MOPA laser system, high conversion efficiency from laser to in-band 2
THE RECONSTRUCTION OF GROUNDWATER PARAMETERS FROM HEAD DATA IN AN
Knowles, Ian W.
ancillary data is fundamental to the process of modelling a groundwater system. In an unconfined aquifer of the unconfined groundwater parameters as the unique minimum of a convex functional. 1. Introduction It is commonTHE RECONSTRUCTION OF GROUNDWATER PARAMETERS FROM HEAD DATA IN AN UNCONFINED AQUIFER IAN KNOWLES
Fundamental Physics at the Intensity Frontier
J. L. Hewett; H. Weerts; R. Brock; J. N. Butler; B. C. K. Casey; J. Collar; A. de Gouvea; R. Essig; Y. Grossman; W. Haxton; J. A. Jaros; C. K. Jung; Z. T. Lu; K. Pitts; Z. Ligeti; J. R. Patterson; M. Ramsey-Musolf; J. L. Ritchie; A. Roodman; K. Scholberg; C. E. M. Wagner; G. P. Zeller; S. Aefsky; A. Afanasev; K. Agashe; C. Albright; J. Alonso; C. Ankenbrandt; M. Aoki; C. A. Arguelles; N. Arkani-Hamed; J. R. Armendariz; C. Armendariz-Picon; E. Arrieta Diaz; J. Asaadi; D. M. Asner; K. S. Babu; K. Bailey; O. Baker; B. Balantekin; B. Baller; M. Bass; B. Batell; J. Beacham; J. Behr; N. Berger; M. Bergevin; E. Berman; R. Bernstein; A. J. Bevan; M. Bishai; M. Blanke; S. Blessing; A. Blondel; T. Blum; G. Bock; A. Bodek; G. Bonvicini; F. Bossi; J. Boyce; R. Breedon; M. Breidenbach; S. J. Brice; R. A. Briere; S. Brodsky; C. Bromberg; A. Bross; T. E. Browder; D. A. Bryman; M. Buckley; R. Burnstein; E. Caden; P. Campana; R. Carlini; G. Carosi; C. Castromonte; R. Cenci; I. Chakaberia; M. C. Chen; C. H. Cheng; B. Choudhary; N. H. Christ; E. Christensen; M. E. Christy; T. E. Chupp; E. Church; D. B. Cline; T. E. Coan; P. Coloma; J. Comfort; L. Coney; J. Cooper; R. J. Cooper; R. Cowan; D. F. Cowen; D. Cronin-Hennessy; A. Datta; G. S. Davies; M. Demarteau; D. P. DeMille; A. Denig; R. Dermisek; A. Deshpande; M. S. Dewey; R. Dharmapalan; J. Dhooghe; M. R. Dietrich; M. Diwan; Z. Djurcic; S. Dobbs; M. Duraisamy; B. Dutta; H. Duyang; D. A. Dwyer; M. Eads; B. Echenard; S. R. Elliott; C. Escobar; J. Fajans; S. Farooq; C. Faroughy; J. E. Fast; B. Feinberg; J. Felde; G. Feldman; P. Fierlinger; P. Fileviez Perez; B. Filippone; P. Fisher; B. T. Flemming; K. T. Flood; R. Forty; M. J. Frank; A. Freyberger; A. Friedland; R. Gandhi; K. S. Ganezer; A. Garcia; F. G. Garcia; S. Gardner; L. Garrison; A. Gasparian; S. Geer; V. M. Gehman; T. Gershon; M. Gilchriese; C. Ginsberg; I. Gogoladze; M. Gonderinger; M. Goodman; H. Gould; M. Graham; P. W. Graham; R. Gran; J. Grange; G. Gratta; J. P. Green; H. Greenlee; R. C. Group; E. Guardincerri; V. Gudkov; R. Guenette; A. Haas; A. Hahn; T. Han; T. Handler; J. C. Hardy; R. Harnik; D. A. Harris; F. A. Harris; P. G. Harris; J. Hartnett; B. He; B. R. Heckel; K. M. Heeger; S. Henderson; D. Hertzog; R. Hill; E. A Hinds; D. G. Hitlin; R. J. Holt; N. Holtkamp; G. Horton-Smith; P. Huber; W. Huelsnitz; J. Imber; I. Irastorza; J. Jaeckel; I. Jaegle; C. James; A. Jawahery; D. Jensen; C. P. Jessop; B. Jones; H. Jostlein; T. Junk; A. L. Kagan; M. Kalita; Y. Kamyshkov; D. M. Kaplan; G. Karagiorgi; A. Karle; T. Katori; B. Kayser; R. Kephart; S. Kettell; Y. K. Kim; M. Kirby; K. Kirch; J. Klein; J. Kneller; A. Kobach; M. Kohl; J. Kopp; M. Kordosky; W. Korsch; I. Kourbanis; A. D. Krisch; P. Krizan; A. S. Kronfeld; S. Kulkarni; K. S. Kumar; Y. Kuno; T. Kutter; T. Lachenmaier; M. Lamm; J. Lancaster; M. Lancaster; C. Lane; K. Lang; P. Langacker; S. Lazarevic; T. Le; K. Lee; K. T. Lesko; Y. Li; M. Lindgren; A. Lindner; J. Link; D. Lissauer; L. S. Littenberg; B. Littlejohn; C. Y. Liu; W. Loinaz; W. Lorenzon; W. C. Louis; J. Lozier; L. Ludovici; L. Lueking; C. Lunardini; D. B. MacFarlane; P. A. N. Machado; P. B. Mackenzie; J. Maloney; W. J. Marciano; W. Marsh; M. Marshak; J. W. Martin; C. Mauger; K. S. McFarland; C. McGrew; G. McLaughlin; D. McKeen; R. McKeown; B. T. Meadows; R. Mehdiyev; D. Melconian; H. Merkel; M. Messier; J. P. Miller; G. Mills; U. K. Minamisono; S. R. Mishra; I. Mocioiu; S. Moed Sher; R. N. Mohapatra; B. Monreal; C. D. Moore; J. G. Morfin; J. Mousseau; L. A. Moustakas; G. Mueller; P. Mueller; M. Muether; H. P. Mumm; C. Munger; H. Murayama; P. Nath; O. Naviliat-Cuncin; J. K. Nelson; D. Neuffer; J. S. Nico; A. Norman; D. Nygren; Y. Obayashi; T. P. O'Connor; Y. Okada; J. Olsen; L. Orozco; J. L. Orrell; J. Osta; B. Pahlka; J. Paley; V. Papadimitriou; M. Papucci; S. Parke; R. H. Parker; Z. Parsa; K. Partyka; A. Patch; J. C. Pati; R. B. Patterson; Z. Pavlovic; G. Paz; G. N. Perdue; D. Perevalov; G. Perez; R. Petti; W. Pettus; A. Piepke; M. Pivovaroff; R. Plunkett; C. C. Polly; M. Pospelov; R. Povey; A. Prakesh; M. V. Purohit; S. Raby; J. L. Raaf; R. Rajendran; S. Rajendran; G. Rameika; R. Ramsey; A. Rashed; B. N. Ratcliff; B. Rebel; J. Redondo; P. Reimer; D. Reitzner; F. Ringer; A. Ringwald; S. Riordan; B. L. Roberts; D. A. Roberts; R. Robertson; F. Robicheaux; M. Rominsky; R. Roser; J. L. Rosner; C. Rott; P. Rubin; N. Saito; M. Sanchez; S. Sarkar; H. Schellman; B. Schmidt; M. Schmitt; D. W. Schmitz; J. Schneps; A. Schopper; P. Schuster; A. J. Schwartz; M. Schwarz; J. Seeman; Y. K. Semertzidis; K. K. Seth; Q. Shafi; P. Shanahan; R. Sharma; S. R. Sharpe; M. Shiozawa; V. Shiltsev; K. Sigurdson; P. Sikivie; J. Singh; D. Sivers; T. Skwarnicki; N. Smith; J. Sobczyk; H. Sobel; M. Soderberg; Y. H. Song; A. Soni; P. Souder; A. Sousa; J. Spitz; M. Stancari; G. C. Stavenga; J. H. Steffen
2012-05-11T23:59:59.000Z
The Proceedings of the 2011 workshop on Fundamental Physics at the Intensity Frontier. Science opportunities at the intensity frontier are identified and described in the areas of heavy quarks, charged leptons, neutrinos, proton decay, new light weakly-coupled particles, and nucleons, nuclei, and atoms.
Fundamental Physics at the Intensity Frontier
Hewett, J L; Brock, R; Butler, J N; Casey, B C K; Collar, J; de Gouvea, A; Essig, R; Grossman, Y; Haxton, W; Jaros, J A; Jung, C K; Lu, Z T; Pitts, K; Ligeti, Z; Patterson, J R; Ramsey-Musolf, M; Ritchie, J L; Roodman, A; Scholberg, K; Wagner, C E M; Zeller, G P; Aefsky, S; Afanasev, A; Agashe, K; Albright, C; Alonso, J; Ankenbrandt, C; Aoki, M; Arguelles, C A; Arkani-Hamed, N; Armendariz, J R; Armendariz-Picon, C; Diaz, E Arrieta; Asaadi, J; Asner, D M; Babu, K S; Bailey, K; Baker, O; Balantekin, B; Baller, B; Bass, M; Batell, B; Beacham, J; Behr, J; Berger, N; Bergevin, M; Berman, E; Bernstein, R; Bevan, A J; Bishai, M; Blanke, M; Blessing, S; Blondel, A; Blum, T; Bock, G; Bodek, A; Bonvicini, G; Bossi, F; Boyce, J; Breedon, R; Breidenbach, M; Brice, S J; Briere, R A; Brodsky, S; Bromberg, C; Bross, A; Browder, T E; Bryman, D A; Buckley, M; Burnstein, R; Caden, E; Campana, P; Carlini, R; Carosi, G; Castromonte, C; Cenci, R; Chakaberia, I; Chen, M C; Cheng, C H; Choudhary, B; Christ, N H; Christensen, E; Christy, M E; Chupp, T E; Church, E; Cline, D B; Coan, T E; Coloma, P; Comfort, J; Coney, L; Cooper, J; Cooper, R J; Cowan, R; Cowen, D F; Cronin-Hennessy, D; Datta, A; Davies, G S; Demarteau, M; DeMille, D P; Denig, A; Dermisek, R; Deshpande, A; Dewey, M S; Dharmapalan, R; Dhooghe, J; Dietrich, M R; Diwan, M; Djurcic, Z; Dobbs, S; Duraisamy, M; Dutta, B; Duyang, H; Dwyer, D A; Eads, M; Echenard, B; Elliott, S R; Escobar, C; Fajans, J; Farooq, S; Faroughy, C; Fast, J E; Feinberg, B; Felde, J; Feldman, G; Fierlinger, P; Perez, P Fileviez; Filippone, B; Fisher, P; Flemming, B T; Flood, K T; Forty, R; Frank, M J; Freyberger, A; Friedland, A; Gandhi, R; Ganezer, K S; Garcia, A; Garcia, F G; Gardner, S; Garrison, L; Gasparian, A; Geer, S; Gehman, V M; Gershon, T; Gilchriese, M; Ginsberg, C; Gogoladze, I; Gonderinger, M; Goodman, M; Gould, H; Graham, M; Graham, P W; Gran, R; Grange, J; Gratta, G; Green, J P; Greenlee, H; Guardincerri, E; Gudkov, V; Guenette, R; Haas, A; Hahn, A; Han, T; Handler, T; Hardy, J C; Harnik, R; Harris, D A; Harris, F A; Harris, P G; Hartnett, J; He, B; Heckel, B R; Heeger, K M; Henderson, S; Hertzog, D; Hill, R; Hinds, E A; Hitlin, D G; Holt, R J; Holtkamp, N; Horton-Smith, G; Huber, P; Huelsnitz, W; Imber, J; Irastorza, I; Jaeckel, J; Jaegle, I; James, C; Jawahery, A; Jensen, D; Jessop, C P; Jones, B; Jostlein, H; Junk, T; Kagan, A L; Kalita, M; Kamyshkov, Y; Kaplan, D M; Karagiorgi, G; Karle, A; Katori, T; Kayser, B; Kephart, R; Kettell, S; Kim, Y K; Kirby, M; Kirch, K; Klein, J; Kneller, J; Kobach, A; Kohl, M; Kopp, J; Kordosky, M; Korsch, W; Kourbanis, I; Krisch, A D; Krizan, P; Kronfeld, A S; Kulkarni, S; Kumar, K S; Kuno, Y; Kutter, T; Lachenmaier, T; Lamm, M; Lancaster, J; Lancaster, M; Lane, C; Lang, K; Langacker, P; Lazarevic, S; Le, T; Lee, K; Lesko, K T; Li, Y; Lindgren, M; Lindner, A; Link, J; Lissauer, D; Littenberg, L S; Littlejohn, B; Liu, C Y; Loinaz, W; Lorenzon, W; Louis, W C; Lozier, J; Ludovici, L; Lueking, L; Lunardini, C; MacFarlane, D B; Machado, P A N; Mackenzie, P B; Maloney, J; Marciano, W J; Marsh, W; Marshak, M; Martin, J W; Mauger, C; McFarland, K S; McGrew, C; McLaughlin, G; McKeen, D; McKeown, R; Meadows, B T; Mehdiyev, R; Melconian, D; Merkel, H; Messier, M; Miller, J P; Mills, G; Minamisono, U K; Mishra, S R; Mocioiu, I; Sher, S Moed; Mohapatra, R N; Monreal, B; Moore, C D; Morfin, J G; Mousseau, J; Moustakas, L A; Mueller, G; Mueller, P; Muether, M; Mumm, H P; Munger, C; Murayama, H; Nath, P; Naviliat-Cuncin, O; Nelson, J K; Neuffer, D; Nico, J S; Norman, A; Nygren, D; Obayashi, Y; O'Connor, T P; Okada, Y; Olsen, J; Orozco, L; Orrell, J L; Osta, J; Pahlka, B; Paley, J; Papadimitriou, V; Papucci, M; Parke, S; Parker, R H; Parsa, Z; Partyka, K; Patch, A; Pati, J C; Patterson, R B; Pavlovic, Z; Paz, G; Perdue, G N; Perevalov, D; Perez, G; Petti, R; Pettus, W; Piepke, A; Pivovaroff, M; Plunkett, R; Polly, C C; Pospelov, M; Povey, R; Prakesh, A; Purohit, M V; Raby, S; Raaf, J L; Rajendran, R; Rajendran, S; Rameika, G; Ramsey, R; Rashed, A; Ratcliff, B N; Rebel, B; Redondo, J; Reimer, P; Reitzner, D; Ringer, F; Ringwald, A; Riordan, S; Roberts, B L; Roberts, D A; Robertson, R; Robicheaux, F; Rominsky, M; Roser, R; Rosner, J L; Rott, C; Rubin, P; Saito, N; Sanchez, M; Sarkar, S; Schellman, H; Schmidt, B; Schmitt, M; Schmitz, D W; Schneps, J; Schopper, A; Schuster, P; Schwartz, A J; Schwarz, M; Seeman, J; Semertzidis, Y K; Seth, K K; Shafi, Q; Shanahan, P; Sharma, R; Sharpe, S R; Shiozawa, M; Shiltsev, V; Sigurdson, K; Sikivie, P; Singh, J; Sivers, D; Skwarnicki, T; Smith, N; Sobczyk, J; Sobel, H; Soderberg, M; Song, Y H; Soni, A; Souder, P; Sousa, A; Spitz, J; Stancari, M; Stavenga, G C; Steffen, J H; Stepanyan, S; Stoeckinger, D; Stone, S; Strait, J; Strassler, M; Sulai, I A; Sundrum, R; Svoboda, R; Szczerbinska, B; Szelc, A; Takeuchi, T; Tanedo, P
2012-01-01T23:59:59.000Z
The Proceedings of the 2011 workshop on Fundamental Physics at the Intensity Frontier. Science opportunities at the intensity frontier are identified and described in the areas of heavy quarks, charged leptons, neutrinos, proton decay, new light weakly-coupled particles, and nucleons, nuclei, and atoms.
Radio Astronomy Fundamentals I John Simonetti
Ellingson, Steven W.
Radio Astronomy Fundamentals I John Simonetti Spring 2012 Radio astronomy provides a very different view of the universe than optical astronomy. Radio astronomers and optical astronomers use different terminology to describe their work. Here I present some basic concepts and terms of radio
Ultra Low Power Bioelectronics Fundamentals, Biomedical Applications,
Sarpeshkar, Rahul
Ultra Low Power Bioelectronics Fundamentals, Biomedical Applications, and Bio-inspired Systems to articulate information-based principles for ultra-low-power design that apply to biology or to electronics of ultra- low-power electronics and bioelectronics is shown in the figure below. Engineering can aid
Fundamental Challenges in Mobile Computing M. Satyanarayanan
and level of technology, but are intrinsic to mobility. Together, they complicate the considerationsFundamental Challenges in Mobile Computing M. Satyanarayanan School of Computer Science Carnegie different about mobile computing?" The paper begins by describing a set of constraints intrinsic to mobile
Elements of $\\mu$-calculus and thermodynamics of $\\mu$-Bose gas model
Rebesh, A P; Gavrilik, A M
2014-01-01T23:59:59.000Z
We review on and give some further details about the thermodynamical properties of the \\mu-Bose gas model (arXiv:1309.1363) introduced by us recently. This model was elaborated in connection with \\mu-deformed oscillators. Here, we present the necessary concepts and tools from the so-called \\mu-calculus. For the high temperatures, we obtain the virial expansion of the equation of state, as well as five virial coefficients. In the regime of low temperatures, the critical temperature of condensation is inferred. We also obtain the specific heat, internal energy, and entropy for a \\mu-Bose gas for both low and high temperatures. All thermodynamical functions depend on the deformation parameter \\mu. The dependences of the entropy and the specific heat on the deformation parameter are visualized.
Altaner, Bernhard; Vollmer, Jürgen
2015-01-01T23:59:59.000Z
Unlike macroscopic engines, the molecular machinery of living cells is strongly affected by fluctuations. Stochastic Thermodynamics uses Markovian jump processes to model the random transitions between the chemical and configurational states of these biological macromolecules. A recently developed theoretical framework [Wachtel, Vollmer, Altaner: "Fluctuating Currents in Stochastic Thermodynamics I. Gauge Invariance of Asymptotic Statistics"] provides a simple algorithm for the determination of macroscopic currents and correlation integrals of arbitrary fluctuating currents. Here, we use it to discuss energy conversion and nonequilibrium response in different models for the molecular motor kinesin. Methodologically, our results demonstrate the effectiveness of the algorithm in dealing with parameter-dependent stochastic models. For the concrete biophysical problem our results reveal two interesting features in experimentally accessible parameter regions: The validity of a non-equilibrium Green--Kubo relation ...
Thermodynamics of Rotating Solutions in Gauss-Bonnet-Maxwell Gravity and the Counterterm Method
Dehghani, M H; Shamirzaie, M
2006-01-01T23:59:59.000Z
We present the $(n+1)$-dimensional charged rotating solutions of Gauss-Bonnet gravity with a complete set of allowed rotation parameters. By a suitable transformation, we show that these charged rotating solutions present black hole solutions with two inner and outer event horizons, extreme black holes or naked singularities provided the parameters of the solutions are chosen suitable. Using the surface terms that make the action well-defined for Gauss-Bonnet gravity and the counterterm method for eliminating the divergences in action and conserved quantities, we compute finite action and conserved quantities of the solutions. We also compute temperature, entropy, charge, and electric potential of the black hole solutions, and find that these quantities satisfy the first law of thermodynamics. Finally, we perform a stability analysis by computing the heat capacity and the determinant of Hessian matrix of mass with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, ...
The thermodynamics of a gravitating vacuum
M. Heyl; H. J. Fahr; M. Siewert
2014-12-09T23:59:59.000Z
In the present days of modern cosmology it is assumed that the main ingredient to cosmic energy presently is vacuum energy with an energy density $\\epsilon_\\mathrm{vac}$ that is constant over the cosmic evolution. In this paper here we show, however, that this assumption of constant vacuum energy density is unphysical, since it conflicts with the requirements of cosmic thermodynamics. We start from the total vacuum energy including the negatively valued gravitational binding energy and show that cosmic thermodynamics then requires that the cosmic vacuum energy density can only vary with cosmic scale $R=R(t)$ according to $\\epsilon _\\mathrm{vac}\\sim R^{-\
Thermodynamics of Dyonic Lifshitz Black Holes
Tobias Zingg
2011-07-15T23:59:59.000Z
Black holes with asymptotic anisotropic scaling are conjectured to be gravity duals of condensed matter system close to quantum critical points with non-trivial dynamical exponent z at finite temperature. A holographic renormalization procedure is presented that allows thermodynamic potentials to be defined for objects with both electric and magnetic charge in such a way that standard thermodynamic relations hold. Black holes in asymptotic Lifshitz spacetimes can exhibit paramagnetic behavior at low temperature limit for certain values of the critical exponent z, whereas the behavior of AdS black holes is always diamagnetic.
Variational thermodynamics of relativistic thin disks
A C Gutiérrez-Pińeres; C S Lopez-Monsalvo; H Quevedo
2014-08-18T23:59:59.000Z
We present a relativistic model describing a thin disk system composed of two fluids. The system is surrounded by a halo in the presence of a non-trivial electromagnetic field. We show that the model is compatible with the variational multi-fluid thermodynamics formalism, allowing us to determine all the thermodynamic variables associated with the matter content of the disk. The asymptotic behaviour of these quantities indicates that the single fluid interpretation should be abandoned in favour of a two-fluid model.
Hard-thermal-loop QED thermodynamics
Nan Su; Jens O. Andersen; Michael Strickland
2009-11-24T23:59:59.000Z
The weak-coupling expansion for thermodynamic quantities in thermal field theories is poorly convergent unless the coupling constant is tiny. We discuss the calculation of the free energy for a hot gas of electrons and photons to three-loop order using hard-thermal-loop perturbation theory (HTLpt). We show that the hard-thermal-loop perturbation reorganization improves the convergence of the successive approximations to the QED free energy at large coupling, e ~ 2. The reorganization is gauge invariant by construction, and due to the cancellations among various contributions, we obtain a completely analytic result for the resummed thermodynamic potential at three loops.
Measurement of thermodynamics using gradient flow
Masakiyo Kitazawa; Masayuki Asakawa; Tetsuo Hatsuda; Takumi Iritani; Etsuko Itou; Hiroshi Suzuki
2014-12-15T23:59:59.000Z
We analyze bulk thermodynamics and correlation functions of the energy-momentum tensor in pure Yang-Mills gauge theory using the energy-momentum tensor defined by the gradient flow and small flow time expansion. Our results on thermodynamic observables are consistent with those obtained by the conventional integral method. The analysis of the correlation function of total energy supports the energy conservation. It is also addressed that these analyses with gradient flow require less statistics compared with the previous methods. All these results suggest that the energy-momentum tensor can be successfully defined and observed on the lattice with moderate numerical costs with the gradient flow.
Fluctuations and the second law of thermodynamics
Denur, Jack Boaz
1976-01-01T23:59:59.000Z
concerned w 1th fluctuations in the Helmholtz free eneray of+ as a whole, A*, away from the min1mum poss1ble value, A*. We will assoc1ate fluctuations 1 n A* away from A" with fluctuations of some other thermodynam 1c property of + , X, away from X... uniform fluid ink is a high dens1ty Abel gas. As a third example, let the uniform fluid 1 n 4 be a substance at its critical po1nt, in thermodynamic equilibrium. In th1s case we have v (hf')N g p (4. 4) Thus, from (2. 7) we have (4. 5) Thus...
Dissipative heat engine is thermodynamically inconsistent
A. M. Makarieva; V. G. Gorshkov
2009-10-05T23:59:59.000Z
A heat engine operating on the basis of the Carnot cycle is considered, where the mechanical work performed is dissipated within the engine at the temperature of the warmer isotherm and the resulting heat is added to the engine together with an external heat input. The resulting work performed by the engine per cycle is increased at the expense of dissipated work produced in the previous cycle. It is shown that such a dissipative heat engine is thermodynamically inconsistent violating the first and second laws of thermodynamics. The existing physical models employing the dissipative heat engine concept, in particular, the heat engine model of hurricane development, are physically invalid.
Implications of interface conventions for morphometric thermodynamics
Andreas Reindl; Markus Bier; S. Dietrich
2015-02-06T23:59:59.000Z
Several model fluids in contact with planar, spherical, and cylindrical walls are investigated for small number densities within density functional theory. The dependence of the solid-fluid interfacial tension on the curvature of spherical and cylindrical walls is examined and compared with the corresponding expression derived within the framework of morphometric thermodynamics. Particular attention is paid to the implications of the choice of the interface location, which underlies the definition of the interfacial tension. We find that morphometric thermodynamics is never exact for the considered systems and that its quality as an approximation depends sensitively on the choice of the interface location.
Irreversible work and inner friction in quantum thermodynamic processes
F. Plastina; A. Alecce; T. J. G. Apollaro; G. Falcone; G. Francica; F. Galve; N. Lo Gullo; R. Zambrini
2014-07-24T23:59:59.000Z
We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed along ideal adiabatic and isothermal transformations. The comparison with the latter leads to the introduction of irreversible work, while that with the former leads to the introduction of inner friction. We show that these two quantities can be treated on equal footing, as both can be linked with the heat exchanged in thermalization processes and both can be expressed as relative entropies. Furthermore, we show that a specific fluctuation relation for the entropy production associated with the inner friction exists, which allows the inner friction to be written in terms of its cumulants.
Lorentz violation and black-hole thermodynamics: Compton scattering process
E. Kant; F. R. Klinkhamer; M. Schreck
2009-11-22T23:59:59.000Z
A Lorentz-noninvariant modification of quantum electrodynamics (QED) is considered, which has photons described by the nonbirefringent sector of modified Maxwell theory and electrons described by the standard Dirac theory. These photons and electrons are taken to propagate and interact in a Schwarzschild spacetime background. For appropriate Lorentz-violating parameters, the photons have an effective horizon lying outside the Schwarzschild horizon. A particular type of Compton scattering event, taking place between these two horizons (in the photonic ergoregion) and ultimately decreasing the mass of the black hole, is found to have a nonzero probability. These events perhaps allow for a violation of the generalized second law of thermodynamics in the Lorentz-noninvariant theory considered.
Fundamental Corrosion Studies in High-Temperature Molten Salt...
Broader source: Energy.gov (indexed) [DOE]
Laboratory April 15, 2013 | Garcia-Diaz * The overall project approach will combine corrosion rate and mechanism characterization, together with thermodynamic and fluid dynamic...
http://w3.pppl.gov/~ Thermodynamics,
Zakharov, Leonid E.
web page: http://w3.pppl.gov/~ zakharov Thermodynamics, science and religion in fusion 1 Leonid E of the goal and with understanding how the second law of thermodynamics works in the scientific society
COURSE TITLE CREDITS A A 260 THERMODYNAMICS 4
COURSE TITLE CREDITS A A 260 THERMODYNAMICS 4 ARCH 310 ARCHITECTURAL DESIGN DRAWING I 3 ARCH 331 THERMODYNAMICS & CLOUD PROCESSES 3 ATM S 358 FUND ATMOS CHEMISTRY 3 ATM S 370 ATMOSPHERIC STRUCTURE & ANALYSIS 5
12.480 Thermodynamics for Geoscientists, Spring 2004
Grove, Timothy L.
Principles of thermodynamics are used to infer the physical conditions of formation and modification of igneous and metamorphic rocks. Includes phase equilibria of homogeneous and heterogeneous systems and thermodynamic ...
Thermodynamic Analysis of Combined Cycle District Heating System
Suresh, S.; Gopalakrishnan, H.; Kosanovic, D.
2011-01-01T23:59:59.000Z
This paper presents a thermodynamic analysis of the University of Massachusetts' Combined Heat and Power (CHP) District Heating System. Energy and exergy analyses are performed based on the first and second laws of thermodynamics for power...
Kais, Sabre
length for one- electron screened Coulomb potentials, the critical nuclear charges for twoQuantum criticality at the infinite complete basis set limit: A thermodynamic analog of the Yang Abstract Finite size scaling for calculations of the critical parameters of the few-body Schro
D. H. E. Gross; J. F. Kenney
2005-03-24T23:59:59.000Z
Microcanonical thermodynamics allows the application of statistical mechanics both to finite and even small systems and also to the largest, self-gravitating ones. However, one must reconsider the fundamental principles of statistical mechanics especially its key quantity, entropy. Whereas in conventional thermostatistics, the homogeneity and extensivity of the system and the concavity of its entropy are central conditions, these fail for the systems considered here. For example, at phase separation, the entropy, S(E), is necessarily convex to make exp[S(E)-E/T] bimodal in E. Particularly, as inhomogeneities and surface effects cannot be scaled away, one must be careful with the standard arguments of splitting a system into two subsystems, or bringing two systems into thermal contact with energy or particle exchange. Not only the volume part of the entropy must be considered. As will be shown here, when removing constraints in regions of a negative heat capacity, the system may even relax under a flow of heat (energy) against a temperature slope. Thus the Clausius formulation of the second law: ``Heat always flows from hot to cold'', can be violated. Temperature is not a necessary or fundamental control parameter of thermostatistics. However, the second law is still satisfied and the total Boltzmann entropy increases. In the final sections of this paper, the general microscopic mechanism leading to condensation and to the convexity of the microcanonical entropy at phase separation is sketched. Also the microscopic conditions for the existence (or non-existence) of a critical end-point of the phase-separation are discussed. This is explained for the liquid-gas and the solid-liquid transition.
D. H. E. Gross
2004-09-21T23:59:59.000Z
Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental principles of Statistical Mechanics especially its key quantity, entropy. Whereas in conventional Thermostatistics the homogeneity and extensivity of the system and the concavity of its entropy S(E) are central conditions, these fail for the systems considered here. E.g. at phase separation the entropy S(E) is necessarily convex to make e^{S(E)-E/T} bimodal in E (the two coexisting phases). This is so even for normal macroscopic systems with short-range coupling. As inhomogeneities and surface effects in particular cannot be scaled away,one has to be careful with the standard arguments of splitting a system into two or bringing two systems into thermal contact. Not only the volume part of the entropy must be considered. When removing an external constraint in regions of a negative heat capacity, the system may even relax under a flow of heat (energy) against the temperature slope. Thus Clausius formulation of the Second Law: "Heat always flows from hot to cold" can be violated. Temperature is not a necessary or fundamental control parameter of Thermostatistics. In the final sections of this paper the general microscopic mechanism leading to condensation and to the convexity of the microcanonical entropy S(E) at phase separation is sketched. Also the microscopic conditions for the existence or non-existence of a critical end-point of the phase-separation are discussed. This is explained for the liquid--gas and the solid--liquid transition.
Baines, Ellyn K
2011-01-01T23:59:59.000Z
We measured the angular diameter of the exoplanet host star epsilon Eridani using the Navy Optical Interferometer. We determined its physical radius, effective temperature, and mass by combining our measurement with the star's parallax, photometry from the literature, and the Yonsei-Yale isochrones (Yi et al. 2001), respectively. We used the resulting stellar mass of 0.82 +/- 0.05 M_Sun plus the mass function from Benedict et al. (2006) to calculate the planet's mass, which is 1.53 +/- 0.22 M_Jupiter. Using our new effective temperature, we also estimated the extent of the habitable zone for the system.
Binding Energy and the Fundamental Plane of Globular Clusters
Dean E. McLaughlin
2000-02-03T23:59:59.000Z
A physical description of the fundamental plane of Galactic globular clusters is developed which explains all empirical trends and correlations in a large number of cluster observables and provides a small but complete set of truly independent constraints on theories of cluster formation and evolution in the Milky Way. Within the theoretical framework of single-mass, isotropic King models, it is shown that (1) 39 regular (non--core-collapsed) globulars with measured core velocity dispersions share a common V-band mass-to-light ratio of 1.45 +/- 0.10, and (2) a complete sample of 109 regular globulars reveals a very strong correlation between cluster binding energy and total luminosity, regulated by Galactocentric position: E_b \\propto (L^{2.05} r_{\\rm gc}^{-0.4}). The observational scatter about either of these two constraints can be attributed fully to random measurement errors, making them the defining equations of a fundamental plane for globular clusters. A third, weaker correlation, between total luminosity and the King-model concentration parameter, c, is then related to the (non-random) distribution of globulars on the plane. The equations of the FP are used to derive expressions for any cluster observable in terms of only L, r_{\\rm gc}, and c. Results are obtained for generic King models and applied specifically to the globular cluster system of the Milky Way.
Optimal distillation using thermodynamic geometry Bjarne Andresen
Salamon, Peter
Optimal distillation using thermodynamic geometry Bjarne Andresen Řrsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler (temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2
An Indicator to Evaluate the Thermodynamic Maturity
Kjelstrup, Signe
process units in the chemical and process industry (i.e., heat exchanger, chemical reactor, distillation column, and paper dry- ing machine). The proposed thermodynamic measure should be of interest, energy ef- ficiency problems in design and optimization of thermal and power systems (i.e., heat
MICROSCOPIC DERIVATION OF AN ISOTHERMAL THERMODYNAMIC TRANSFORMATION
Paris-Sud XI, Université de
they are one of the components of the Carnot cycle. As often in thermodynam- ics, they represent idealized an initial equilibrium to a new equilibrium given by the final tension applied. Quasistatic reversible), satisfy the Clausius inequality F1 - F0 W, with equality satisfied for reversible quasistatic
Thermodynamics of Energy Production from Biomass
Patzek, Tadeusz W.
Thermodynamics of Energy Production from Biomass Tad W. Patzek 1 and David Pimentel 2 1 Department #12;3 Biomass from Tropical Tree Plantations 14 3.1 Scope of the Problem . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 3.2 Environmental Impacts of Industrial Biomass Production . . . . . . . . . . . . . . . 16 3
Chapter 7. Thermodynamic Processes and Thermochemistry
Ihee, Hyotcherl
. The gas is heated slowly, with the piston sliding freely to maintain the pressure of the gas close to 1 or pressure affect the extent of the reaction? · How can the conditions for the reaction be optimized, pressure #12;State · A thermodynamic state is a macroscopic condition of a system whose properties
Perturbative String Thermodynamics near Black Hole Horizons
Thomas G. Mertens; Henri Verschelde; Valentin I. Zakharov
2014-10-29T23:59:59.000Z
We provide further computations and ideas to the problem of near-Hagedorn string thermodynamics near (uncharged) black hole horizons, building upon our earlier work JHEP 1403 (2014) 086. The relevance of long strings to one-loop black hole thermodynamics is emphasized. We then provide an argument in favor of the absence of $\\alpha'$-corrections for the (quadratic) heterotic thermal scalar action in Rindler space. We also compute the large $k$ limit of the cigar orbifold partition functions (for both bosonic and type II superstrings) which allows a better comparison between the flat cones and the cigar cones. A discussion is made on the general McClain-Roth-O'Brien-Tan theorem and on the fact that different torus embeddings lead to different aspects of string thermodynamics. The black hole/string correspondence principle for the 2d black hole is discussed in terms of the thermal scalar. Finally, we present an argument to deal with arbitrary higher genus partition functions, suggesting the breakdown of string perturbation theory (in $g_s$) to compute thermodynamical quantities in black hole spacetimes.
QCD thermodynamics with dynamical overlap fermions
S. Borsanyi; Y. Delgado; S. Durr; Z. Fodor; S. D. Katz; S. Krieg; T. Lippert; D. Nogradi; K. K. Szabo
2012-08-02T23:59:59.000Z
We study QCD thermodynamics using two flavors of dynamical overlap fermions with quark masses corresponding to a pion mass of 350 MeV. We determine several observables on N_t=6 and 8 lattices. All our runs are performed with fixed global topology. Our results are compared with staggered ones and a nice agreement is found.
Thermodynamics of nuclei in thermal contact
Karl-Heinz Schmidt; Beatriz Jurado
2010-10-05T23:59:59.000Z
The behaviour of a di-nuclear system in the regime of strong pairing correlations is studied with the methods of statistical mechanics. It is shown that the thermal averaging is strong enough to assure the application of thermodynamical methods to the energy exchange between the two nuclei in contact. In particular, thermal averaging justifies the definition of a nuclear temperature.
A thermodynamic switch for chromosome colocalization
M. Nicodemi; B. Panning; A. Prisco
2008-09-27T23:59:59.000Z
A general model for the early recognition and colocalization of homologous DNA sequences is proposed. We show, on a thermodynamic ground, how the distance between two homologous DNA sequences is spontaneously regulated by the concentration and affinity of diffusible mediators binding them, which act as a switch between two phases corresponding to independence or colocalization of pairing regions.
On phantom thermodynamics with negative temperature
Yun Soo Myung
2008-12-10T23:59:59.000Z
We discuss the thermodynamic properties of the Friedmann-Robertson-Walker universe with dark energy fluids labelled by $\\omega=p/\\rhotemperature takes on negative values because in that case, there exists at least a condition of keeping physical values for $p$ and $\\rho$
Non-equilibrium thermodynamics of gravitational screens
Laurent Freidel; Yuki Yokokura
2014-05-19T23:59:59.000Z
We study the Einstein gravity equations projected on a timelike surface, which represents the time evolution of what we call a gravitational screen. We show that such a screen possesses a surface tension and an internal energy, and that the Einstein equations reduce to the thermodynamic equations of a viscous bubble. We also provide a complete dictionary between gravitational and thermodynamical variables. In the non-viscous cases there are three thermodynamic equations which characterise a bubble dynamics: These are the first law, the Marangoni flow equation and the Young-Laplace equation. In all three equations the surface tension plays a central role: In the first law it appears as a work term per unit area, in the Marangoni flow its gradient drives a force, and in the Young-Laplace equation it contributes to a pressure proportional to the surface curvature. The gravity equations appear as a natural generalization of these bubble equations when the bubble itself is viscous and dynamical. In particular, it shows that the mechanism of entropy production for the viscous bubble is mapped onto the production of gravitational waves. We also review the relationship between surface tension and temperature, and discuss the usual black-hole thermodynamics from this point of view.
Generalised complex geometry in thermodynamical fluctuation theory
P. Fernandez de Cordoba; J. M. Isidro
2015-05-28T23:59:59.000Z
We present a brief overview of some key concepts in the theory of generalised complex manifolds. This new geometry interpolates, so to speak, between symplectic geometry and complex geometry. As such it provides an ideal framework to analyse thermodynamical fluctuation theory in the presence of gravitational fields.
Strong laser fields as a probe for fundamental physics
Holger Gies
2008-12-03T23:59:59.000Z
Upcoming high-intensity laser systems will be able to probe the quantum-induced nonlinear regime of electrodynamics. So far unobserved QED phenomena such as the discovery of a nonlinear response of the quantum vacuum to macroscopic electromagnetic fields can become accessible. In addition, such laser systems provide for a flexible tool for investigating fundamental physics. Primary goals consist in verifying so far unobserved QED phenomena. Moreover, strong-field experiments can search for new light but weakly interacting degrees of freedom and are thus complementary to accelerator-driven experiments. I review recent developments in this field, focusing on photon experiments in strong electromagnetic fields. The interaction of particle-physics candidates with photons and external fields can be parameterized by low-energy effective actions and typically predict characteristic optical signatures. I perform first estimates of the accessible new-physics parameter space of high-intensity laser facilities such as POLARIS and ELI.
Thermodynamics and Structure of Peptide-Aggregates at Membrane Surfaces
Quake, Stephen R.
Thermodynamics and Structure of Peptide- Aggregates at Membrane Surfaces INAUGURALDISSERTATION zur. Introduction 01 1.1 Thermodynamics of Protein Aggregation 01 1.2 Formation of Protein Aggregates 03 1 and P-glycoprotein: Connecting Thermodynamics and Membrane Structure with Functional Activity 23 3
Thermodynamics and Finite size scaling in Scalar Field Theory
Thermodynamics and Finite size scaling in Scalar Field Theory A thesis submitted to the Tata Research, Mumbai December 2008 #12;ii #12;Synopsis In this work we study the thermodynamics of an interacting 4 theory in 4 space- time dimensions. The expressions for the thermodynamic quantities are worked
Entanglement theory and the second law of thermodynamics
Loss, Daniel
ARTICLES Entanglement theory and the second law of thermodynamics FERNANDO G. S. L. BRAND~AO1 aim to draw from them formal analogies to the second law of thermodynamics; however, whereas relationship with thermodynamics may be established when considering all non-entangling transformations
The Thermodynamics of Confidentiality Pasquale Malacaria, Fabrizio Smeraldi
Malacaria, Pasquale
The Thermodynamics of Confidentiality Pasquale Malacaria, Fabrizio Smeraldi School of Electronic and the 2nd principle of thermodynamics. In particular we show that any deter- ministic computation, where constant and T the system temperature. By contrast, for probabilistic computations thermodynamic work can
SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics
Russell, Lynn
SIO 217a Atmospheric and Climate Sciences I: Atmospheric Thermodynamics Course Syllabus and Lecture Schedule Instructor: Lynn Russell, 343 NH, 534-4852, lmrussell@ucsd.edu Text: Thermodynamics of Atmospheres of Thermodynamics (Work, Heat, First Law, Second Law, Heat Capacity, Adiabatic Processes) 5-Oct F Hurricane Example
Mech 204 Thermodynamics Spring 2013 Assoc. Prof. Metin Muradoglu
Muradoglu, Metin
Mech 204 Thermodynamics Spring 2013 Assoc. Prof. Metin Muradoglu Room: Eng 248; Phone: 1473; E://home.ku.edu.tr/~mmuradoglu/ME204/index.htm Text Book: Thermodynamics: An Engineering Approach, 7th Edition in SI units, by Y: The course is designed to teach students the basic principles of the classical thermodynamics with emphasis
Micro-Thermodynamics Saturation has the most possible
Russell, Lynn
1 Micro-Thermodynamics · Saturation has the most possible dissolved species · Equilibrium means of "phase" (from particle to droplet) Bohren, 1987 Macro-Thermodynamics · Hot air rises · Rising air)! 0.1! 10! Diameter (µm)! dN! dlogD! Diameter (µm)! 0.1! 10! 7.1 Surface Thermodynamics · Surfaces
Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)
Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.
2010-05-19T23:59:59.000Z
This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.
Ching, Dominic Wai Wah
1978-01-01T23:59:59.000Z
of the composition and of the orientation parameter y, The negative values of gG (Table V) obtained from this ex- pression indicate that the polymer dissolves in the solvents at this temperature. Third, the orientation parameter y that was determined did not vary... of the requirement for the degree of MASTER OF SCIENCE August 1978 Major Subjects Chemical Engineering EXPERIMENTAL SOLUTION THERMODYNAMICS OF A TERNARY SOLVENT/POLYMER/SOLVENT SYSTEM BY INVERSE GAS CHROMATOGRAPHY A Thesis DOMINIC WAI WAH CHING Approved...
Thermodynamics of resonances and blurred particles
D. N. Voskresensky
2008-04-10T23:59:59.000Z
Exact and approximate expressions for thermodynamic characteristics of heated matter, which consists of particles with finite mass-widths, are constructed. They are expressed in terms of Fermi/Bose distributions and spectral functions, rather than in terms of more complicated combinations between real and imaginary parts of the self-energies of different particle species. Therefore thermodynamically consistent approximate treatment of systems of particles with finite mass-widths can be performed, provided spectral functions of particle species are known. Approximation of the free resonance gas at low densities is studied. Simple ansatz for the energy dependence of the spectral function is suggested that allows to fulfill thermodynamical consistency conditions. On examples it is shown that a simple description of dense systems of interacting particle species can be constructed, provided some species can be treated in the quasiparticle approximation and others as particles with widths. The interaction affects quasiparticle contributions, whereas particles with widths can be treated as free. Example is considered of a hot gas of heavy fermions strongly interacting with light bosons, both species with zero chemical potentials. The density of blurred fermions is dramatically increased for high temperatures compared to the standard Boltzmann value. The system consists of boson quasiparticles (with effective masses) interacting with fermion -- antifermion blurs. In thermodynamical values interaction terms partially compensate each other. Thereby, in case of a very strong coupling between species thermodynamical quantities of the system, like the energy, pressure and entropy, prove to be such as for the quasi-ideal gas mixture of quasi-free fermion blurs and quasi-free bosons.
DOE fundamentals handbook: Mechanical science. Volume 2
Not Available
1993-01-01T23:59:59.000Z
The Mechanical Science Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mechanical components and mechanical science. The handbook includes information diesel engines, heat exchangers, pumps, valves, and miscellaneous mechanical components. This information will provide personnel with a foundation for understanding the construction and operation of mechanical components that are associated with various DOE nuclear facility operations and maintenance.
DOE fundamentals handbook: Material science. Volume 1
Not Available
1993-01-01T23:59:59.000Z
The Mechanical Science Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mechanical components and mechanical science. The handbook includes information on diesel engines, heat exchangers, pumps, valves, and miscellaneous mechanical components. This information will provide personnel with a foundation for understanding the construction and operation of mechanical components that are associated with various DOE nuclear facility operations and maintenance.
Improved Engine Design Concepts Using the Second Law of Thermodynamics
None
2009-09-30T23:59:59.000Z
This project was aimed at developing and using numerical tools which incorporate the second law of thermodynamics to better understand engine operation and particularly the combustion process. A major activity of this project was the continual enhancement and use of an existing engine cycle simulation to investigate a wide range of engine parameters and concepts. The major motivation of these investigations was to improve engine efficiency. These improvements were examined from both the first law and second law perspective. One of the most important aspects of this work was the identification of the combustion irreversibilities as functions of engine design and operating parameters. The combustion irreversibility may be quantified in a number of ways but one especially useful way is by determining the destruction of exergy (availability) during the combustion process. This destruction is the penalty due to converting the fuel exergy to thermal energy for producing work. The engine cycle simulation was used to examine the performance of an automotive (5.7 liter), V-8 spark-ignition engine. A base case was defined for operation at 1400 rpm, stoichiometric, MBT spark timing with a bmep of 325 kPa. For this condition, the destruction of exergy during the combustion process was 21.0%. Variations of many engine parameters (including speed, load, and spark timing) did not alter the level of destruction very much (with these variations, the exergy destruction was within the range of 20.5-21.5%). Also, the use of turbocharging or the use of an over-expanded engine design did not significantly change the exergy destruction. The exergy destruction during combustion was most affected by increased inlet oxygen concentration (which reduced the destruction due to the higher combustion temperatures) and by the use of cooled EGR (which increased the destruction). This work has demonstrated that, in general, the exergy destruction for conventional engines is fairly constant ({approx}21%) for a range of operating and design parameters. Further, to achieve high efficiency engines requires that the exergy be managed and not necessarily reduced. The overall thermodynamics is the final discriminator regarding high efficiency engines.
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No Significant Impact for Biomass1/4-92
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No Significant Impact for Biomass1/4-922/2-92
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No Significant Impact for Biomass1/4-922/2-923-92 JUNE 1992 DOE
Neutrino Physics: Fundamentals of Neutrino Oscillations
C. W. Kim
1996-07-22T23:59:59.000Z
In this lecture we review some of the basic properties of neutrinos, in particular their mass and the oscillation behavior. First we discuss how to describe the neutrino mass. Then, under the assumption that neutrinos are massive and mixed, the fundamentals of the neutrino oscillations are discussed with emphasis on subtle aspects which have been overlooked in the past. We then review the terrestrial neutrino oscillation experiments in the framework of three generations of neutrinos with the standard mass hierarchy. Finally, a brief summary of the current status of the solar and atmospheric neutrino problems will be given.
Fundamental measure theory of hydrated hydrocarbons
Victor F. Sokolov; Gennady N. Chuev
2006-04-13T23:59:59.000Z
To calculate the solvation of hydrophobic solutes we have developed the method based on the fundamental measure treatment of the density functional theory. This method allows us to carry out calculations of density profiles and the solvation energy for various hydrophobic molecules with a high accuracy. We have applied the method to the hydration of various hydrocarbons (linear, branched and cyclic). The calculations of the entropic and the enthalpic parts are also carried out. We have examined a question about temperature dependence of the entropy convergence. Finally, we have calculated the mean force potential between two large hydrophobic nanoparticles immersed in water.
Fundamental studies of black liquor combustion
Clay, D.T.; Lien, S.J.; Grace, T.M.; Brown, C.A.; Empie, H.L.; Macek, A.; Amin, N.; Charangundla, S.R.
1990-03-01T23:59:59.000Z
The fundamentals of black liquor combustion are being studied in a project being carried out for the US Department of Energy by the Institute of Paper Science Technology (IPST, formerly the Institute of Paper Chemistry) and the National Institute of Science Technology (NIST, formerly the National Bureau of Standards). The project was divided into four phases. This report covers the completion of Phase 1 (in-flight processes), the results of all of the work on Phase 2 (char bed processes), Phase 3 (fume processes), and Phase 4 (furnace simulation). 41 refs., 62 figs., 30 tabs.
Fundamental investigation of duct/ESP phenomena
Brown, C.A. (Radian Corp., Austin, TX (United States)); Durham, M.D. (ADA Technologies, Inc., Englewood, CO (United States)); Sowa, W.A. (California Univ., Irvine, CA (United States). Combustion Lab.); Himes, R.M. (Fossil Energy Research Corp., Laguna Hills, CA (United States)); Mahaffey, W.A. (CHAM of North America, Inc., Huntsville, AL (United States))
1991-10-21T23:59:59.000Z
Radian Corporation was contracted to investigate duct injection and ESP phenomena in a 1.7 MW pilot plant constructed for this test program. This study was an attempt to resolve problems found in previous studies and answer remaining questions for the technology using an approach which concentrates on the fundamental mechanisms of the process. The goal of the study was to obtain a better understanding of the basic physical and chemical phenomena that control: (1) the desulfurization of flue gas by calcium-based reagent, and (2) the coupling of an existing ESP particulate collection device to the duct injection process. Process economics are being studied by others. (VC)
Fundamental & Applied Bioenergy | Clean Energy | ORNL
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof Energy ForrestalPrincetonF2:Bioenergy SHARE Fundamental
Thermodynamics of D-brane Probes
E. Kiritsis; T. R. Taylor
1999-06-05T23:59:59.000Z
We discuss the dynamics and thermodynamics of particle and D-brane probes moving in non-extremal black hole/brane backgrounds. When a probe falls from asymptotic infinity to the horizon, it transforms its potential energy into heat, $TdS$, which is absorbed by the black hole in a way consistent with the first law of thermodynamics. We show that the same remains true in the near-horizon limit, for BPS probes only, with the BPS probe moving from AdS infinity to the horizon. This is a quantitative indication that the brane-probe reaching the horizon corresponds to thermalization in gauge theory. It is shown that this relation provides a way to reliably compute the entropy away from the extremal limit (towards the Schwarzschild limit).
Statistical thermodynamics of supercapacitors and blue engines
René van Roij
2012-11-06T23:59:59.000Z
We study the thermodynamics of electrode-electrolyte systems, for instance supercapacitors filled with an ionic liquid or blue-energy devices filled with river- or sea water. By a suitable mapping of thermodynamic variables, we identify a strong analogy with classical heat engines. We introduce several Legendre transformations and Maxwell relations. We argue that one should distinguish between the differential capacity at constant ion number and at constant ion chemical potential, and derive a relation between them that resembles the standard relation between heat capacity at constant volume and constant pressure. Finally, we consider the probability distribution of the electrode charge at a given electrode potential, the standard deviation of which is given by the differential capacity.
Thermodynamic motivations of spherically symmetric static metrics
H. Moradpour; S. Nasirimoghadam
2015-06-14T23:59:59.000Z
Bearing the thermodynamic arguments together with the two definitions of mass in mind, we try to find metrics with spherical symmetry. We consider the adiabatic condition along with the Gong-Wang mass, and evaluate the $g_{rr}$ element which points to a null hypersurface. In addition, we generalize the thermodynamics laws to this hypersurface to find its temperature and thus the corresponding surface gravity which enables us to get a relation for the $g_{tt}$ element. Finally, we investigate the mathematical and physical properties of the discovered metric in the Einstein relativity framework which shows that the primary mentioned null hypersurface is an event horizon. We also show that if one considers the Misner-Sharp mass in the calculations, the Schwarzschild metric will be got. The relationship between the two mass definitions in each metric is studied. The results of considering the geometrical surface gravity are also addressed.
Thermodynamic motivations of spherically symmetric static metrics
Moradpour, H
2015-01-01T23:59:59.000Z
Bearing the thermodynamic arguments together with the two definitions of mass in mind, we try to find metrics with spherical symmetry. We consider the adiabatic condition along with the Gong-Wang mass, and evaluate the $g_{rr}$ element which points to a null hypersurface. In addition, we generalize the thermodynamics laws to this hypersurface to find its temperature and thus the corresponding surface gravity which enables us to get a relation for the $g_{tt}$ element. Finally, we investigate the mathematical and physical properties of the discovered metric in the Einstein relativity framework which shows that the primary mentioned null hypersurface is an event horizon. We also show that if one considers the Misner-Sharp mass in the calculations, the Schwarzschild metric will be got. The relationship between the two mass definitions in each metric is studied. The results of considering the geometrical surface gravity are also addressed.
Lattice QCD Thermodynamics with Physical Quark Masses
R. A. Soltz; C. DeTar; F. Karsch; Swagato Mukherjee; P. Vranas
2015-02-08T23:59:59.000Z
Over the past few years new physics methods and algorithms as well as the latest supercomputers have enabled the study of the QCD thermodynamic phase transition using lattice gauge theory numerical simulations with unprecedented control over systematic errors. This is largely a consequence of the ability to perform continuum extrapolations with physical quark masses. Here we review recent progress in lattice QCD thermodynamics, focussing mainly on results that benefit from the use of physical quark masses: the crossover temperature, the equation of state, and fluctuations of the quark number susceptibilities. In addition, we place a special emphasis on calculations that are directly relevant to the study of relativistic heavy ion collisions at RHIC and the LHC.
Generalized uncertainty principle and black hole thermodynamics
Sunandan Gangopadhyay; Abhijit Dutta; Anirban Saha
2014-01-08T23:59:59.000Z
We study the Schwarzschild and Reissner-Nordstr\\"{o}m black hole thermodynamics using the simplest form of the generalized uncertainty principle (GUP) proposed in the literature. The expressions for the mass-temperature relation, heat capacity and entropy are obtained in both cases from which the critical and remnant masses are computed. Our results are exact and reveal that these masses are identical and larger than the so called singular mass for which the thermodynamics quantities become ill-defined. The expression for the entropy reveals the well known area theorem in terms of the horizon area in both cases upto leading order corrections from GUP. The area theorem written in terms of a new variable which can be interpreted as the reduced horizon area arises only when the computation is carried out to the next higher order correction from GUP.
Thermodynamic cycle in a cavity optomechanical system
Hou Ian
2014-02-16T23:59:59.000Z
A cavity optomechanical system is initiated by a radiation pressure of a cavity field onto a mirror element acting as a quantum resonator. This radiation pressure can control the thermodynamic character of the mirror to some extent, such as cooling its effective temperature. Here we show that by properly engineering the spectral density of a thermal heat bath that interacts with a quantum system, the evolution of the quantum system can be effectively turned on and off. Inside a cavity optomechanical system, when the heat bath is realized by a multi-mode oscillator modeling of the mirror, this on-off effect translates to infusion or extraction of heat energy in and out of the cavity field, facilitating a four-stroke thermodynamic cycle.
Hamiltonian thermodynamics of three-dimensional dilatonic black holes
Dias, Goncalo A. S.; Lemos, Jose P. S. [Centro Multidisciplinar de Astrofisica-CENTRA, Departamento de Fisica, Instituto Superior Tecnico-IST, Universidade Tecnica de Lisboa-UTL, Avenida Rovisco Pais 1, 1049-001 Lisboa (Portugal)
2008-08-15T23:59:59.000Z
The action for a class of three-dimensional dilaton-gravity theories with a negative cosmological constant can be recast in a Brans-Dicke type action, with its free {omega} parameter. These theories have static spherically symmetric black holes. Those with well formulated asymptotics are studied through a Hamiltonian formalism, and their thermodynamical properties are found out. The theories studied are general relativity ({omega}{yields}{infinity}), a dimensionally reduced cylindrical four-dimensional general relativity theory ({omega}=0), and a theory representing a class of theories ({omega}=-3). The Hamiltonian formalism is set up in three dimensions through foliations on the right region of the Carter-Penrose diagram, with the bifurcation 1-sphere as the left boundary, and anti-de Sitter infinity as the right boundary. The metric functions on the foliated hypersurfaces are the canonical coordinates. The Hamiltonian action is written, the Hamiltonian being a sum of constraints. One finds a new action which yields an unconstrained theory with one pair of canonical coordinates (M,P{sub M}), M being the mass parameter and P{sub M} its conjugate momenta The resulting Hamiltonian is a sum of boundary terms only. A quantization of the theory is performed. The Schroedinger evolution operator is constructed, the trace is taken, and the partition function of the canonical ensemble is obtained. The black hole entropies differ, in general, from the usual quarter of the horizon area due to the dilaton.
Thermodynamics of quantum systems under dynamical control
D. Gelbwaser-Klimovsky; Wolfgang Niedenzu; Gershon Kurizki
2015-03-04T23:59:59.000Z
In this review the debated rapport between thermodynamics and quantum mechanics is addressed in the framework of the theory of periodically-driven/controlled quantum-thermodynamic machines. The basic model studied here is that of a two-level system (TLS), whose energy is periodically modulated while the system is coupled to thermal baths. When the modulation interval is short compared to the bath memory time, the system-bath correlations are affected, thereby causing cooling or heating of the TLS, depending on the interval. In steady state, a periodically-modulated TLS coupled to two distinct baths constitutes the simplest quantum heat machine (QHM) that may operate as either an engine or a refrigerator, depending on the modulation rate. We find their efficiency and power-output bounds and the conditions for attaining these bounds. An extension of this model to multilevel systems shows that the QHM power output can be boosted by the multilevel degeneracy. These results are used to scrutinize basic thermodynamic principles: (i) Externally-driven/modulated QHMs may attain the Carnot efficiency bound, but when the driving is done by a quantum device ("piston"), the efficiency strongly depends on its initial quantum state. Such dependence has been unknown thus far. (ii) The refrigeration rate effected by QHMs does not vanish as the temperature approaches absolute zero for certain quantized baths, e.g., magnons, thous challenging Nernst's unattainability principle. (iii) System-bath correlations allow more work extraction under periodic control than that expected from the Szilard-Landauer principle, provided the period is in the non-Markovian domain. Thus, dynamically-controlled QHMs may benefit from hitherto unexploited thermodynamic resources.
Laws of thermodynamics and game theory
Lev Sakhnovich
2011-05-23T23:59:59.000Z
Using a game theory approach and a new extremal problem, Gibbs formula is proved in a most simple and general way for the classical mechanics case. A corresponding conjecture on the asymptotics of the classical entropy is formulated. For the ordinary quantum mechanics case, the third law of thermodynamics is derived. Some results on the number of ground states and residual entropy are obtained rigorously.
Heterophase liquid states: Thermodynamics, structure, dynamics
A. S. Bakai
2015-01-12T23:59:59.000Z
An overview of theoretical results and experimental data on the thermodynamics, structure and dynamics of the heterophase glass-forming liquids is presented. The theoretical approach is based on the mesoscopic heterophase fluctuations model (HPFM) developed within the framework of the bounded partition function approach. The Fischer cluster phenomenon, glass transition, liquid-liquid transformations, parametric phase diagram, cooperative dynamics and fragility of the glass-forming liquids is considered.
Thermodynamic data bases for multivalent elements: An example for ruthenium
Rard, J.A.
1987-11-01T23:59:59.000Z
A careful consideration and understanding of fundamental chemistry, thermodynamics, and kinetics is absolutely essential when modeling predominance regions and solubility behavior of elements that exhibit a wide range of valence states. Examples of this are given using the ruthenium-water system at 298.15 K, for which a critically assessed thermochemical data base is available. Ruthenium exhibits the widest range of known aqueous solution valence states. Known solid anhydrous binary oxides of ruthenium are crystalline RuO/sub 2/, RuO/sub 4/, and possibly RuO/sub 3/ (thin film), and known hydroxides/hydrated oxides (all amorphous) are Ru(OH)/sub 3/ . H/sub 2/O, RuO/sub 2/ . 2H/sub 2/O, RuO/sub 2/ . H/sub 2/O, and a poorly characterized Ru(V) hydrous oxide. Although the other oxides, hydroxides, and hydrous oxides are generally obtained as precipitates from aqueous solutions, they are thermodynamically unstable with regard to RuO/sub 2/(cr) formation. Characterized aqueous species of ruthenium include RuO/sub 4/ (which slowly oxidizes water and which dissociates as a weak acid), RuO/sub 4//sup -/ and RuO/sub 4//sup 2 -/ (which probably contain lesser amounts of RuO/sub 3/(OH)/sub 2//sup -/ and RuO/sub 3/(OH)/sub 2//sup 2 -/, respectively, and other species), Ru(OH)/sub 2//sup 2 +/, Ru/sub 4/(OH)/sub 12//sup 4 +/, Ru(OH)/sub 4/, Ru/sup 3 +/, Ru(OH)/sup 2 +/, Ru(OH)/sub 2//sup +/, Ru/sup 2 +/, and some hydroxytetramers with formal ruthenium valences of 3.75 greater than or equal to Z greater than or equal to 2.0. Potential pH diagrams of the predominance regions change significantly with concentration due to polymerization/depolymerization reactions. Failure to consider the known chemistry of ruthenium can yield large differences in predicted solubilities.
ZINC MITIGATION INTERIM REPORT - THERMODYNAMIC STUDY
Korinko, P.
2010-12-17T23:59:59.000Z
An experimental program was initiated in order to develop and validate conditions that will effectively trap Zn vapors that are released during extraction. The proposed work is broken down into three tasks. The first task is to determine the effectiveness of various pore sizes of filter elements. The second task is to determine the effect of filter temperature on zinc vapor deposition. The final task is to determine whether the zinc vapors can be chemically bound. The approach for chemically binding the zinc vapors has two subtasks, the first is a review of literature and thermodynamic calculations and the second is an experimental approach using the best candidates. This report details the results of the thermodynamic calculations to determine feasibility of chemically binding the zinc vapors within the furnace module, specifically the lithium trap (1). A review of phase diagrams, literature, and thermodynamic calculations was conducted to determine if there are suitable materials to capture zinc vapor within the lithium trap of the extraction basket. While numerous elements exist that form compounds with zinc, many of these also form compounds with hydrogen or the water that is present in the TPBARs. This relatively comprehensive review of available data indicates that elemental cobalt and copper and molybdenum trioxide (MoO3) may have the requisite properties to capture zinc and yet not be adversely affected by the extraction gases and should be considered for testing.
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Main Parameters APS Storage Ring Parameters M. Borland, G. Decker, L. Emery, W. Guo, K. Harkay, V. Sajaev, C.-Y. Yao Advanced Photon Source September 8, 2010 This document list the...
Development of a new radiometer for the thermodynamic measurement of high temperature fixed points
Dury, M. R.; Goodman, T. M.; Lowe, D. H.; Machin, G.; Woolliams, E. R. [National Physical Laboratory, Teddington (United Kingdom)] [National Physical Laboratory, Teddington (United Kingdom)
2013-09-11T23:59:59.000Z
The National Physical Laboratory (NPL) has developed a new radiometer to measure the thermodynamic melting point temperatures of high temperature fixed points with ultra-low uncertainties. In comparison with the NPL's Absolute Radiation Thermometer (ART), the 'THermodynamic Optical Radiometer' (THOR) is more portable and compact, with a much lower size-of-source effect and improved performance in other parameters such as temperature sensitivity. It has been designed for calibration as a whole instrument via the radiance method, removing the need to calibrate the individual subcomponents, as required by ART, and thereby reducing uncertainties. In addition, the calibration approach has been improved through a new integrating sphere that has been designed to have greater uniformity.
Numerical prediction of the thermodynamic properties of ternary Al-Ni-Hf alloys
Romanowska, Jolanta; Kotowski, S?awomir; Zagula-Yavorska, Maryana [Rzeszów University of Technology (Poland)
2014-10-06T23:59:59.000Z
Thermodynamic properties of ternary Al-Hf-Ni system, such as {sup ex}G, ?{sub Al}, ?{sub Ni} and ?{sub Zr} at 1373K were predicted on the basis of thermodynamic properties of binary systems included in the investigated ternary system. The idea of predicting {sup ex}G values was regarded as the calculation of excess Gibbs energy values inside a certain area (a Gibbs triangle) unless all boundary conditions, that is values of {sup ex}G on all legs of the triangle are known. {sup ex}G and L{sub ijk} ternary interaction parameters in the Muggianu extension of the Redlich-Kister formalism are calculated numerically using Wolfram Mathematica 9 software.
Thermodynamics of black holes in $(n+1)$-dimensional Einstein-Born-Infeld dilaton gravity
A. Sheykhi; N. Riazi
2006-10-08T23:59:59.000Z
We construct a new class of $(n+1)$-dimensional $(n\\geq3)$ black hole solutions in Einstein-Born-Infeld-dilaton gravity with Liouville-type potential for the dilaton field and investigate their properties. These solutions are neither asymptotically flat nor (anti)-de Sitter. We find that these solutions can represent black holes, with inner and outer event horizons, an extreme black hole or a naked singularity provided the parameters of the solutions are chosen suitably. We compute the thermodynamic quantities of the black hole solutions and find that these quantities satisfy the first law of thermodynamics. We also perform stability analysis and investigate the effect of dilaton on the stability of the solutions.
Thermodynamics of black holes in (n+1)-dimensional Einstein-Born-Infeld-dilaton gravity
Sheykhi, A. [Physics Department and Biruni Observatory, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of); Physics Department, Shahid Bahonar University, Kerman (Iran, Islamic Republic of); Riazi, N. [Physics Department and Biruni Observatory, Shiraz University, Shiraz 71454 (Iran, Islamic Republic of)
2007-01-15T23:59:59.000Z
We construct a new class of (n+1)-dimensional (n{>=}3) black hole solutions in Einstein-Born-Infeld-dilaton gravity with Liouville-type potential for the dilaton field and investigate their properties. These solutions are neither asymptotically flat nor (anti)-de Sitter. We find that these solutions can represent black holes, with inner and outer event horizons, an extreme black hole, or a naked singularity provided the parameters of the solutions are chosen suitably. We compute the thermodynamic quantities of the black hole solutions and find that these quantities satisfy the first law of thermodynamics. We also perform a stability analysis and investigate the effect of dilaton on the stability of the solutions.
Focus Research Areas 1. Fundamental Accelerator Physics: Theory
Kemner, Ken
Focus Research Areas 1. Fundamental Accelerator Physics: Theory Importance Accelerator physics aspects. Pursuit of fundamental accelerator physics in this sense has contributed significantly to the advance of the accelerator physics knowledgebase during the last several decades, clarifying
Fundamental Corrosion Studies in High-Temperature Molten Salt...
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Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems - FY13 Q2 Fundamental Corrosion Studies in High-Temperature Molten Salt...
Discovering the New Standard Model: Fundamental Symmetries and Neutrinos
V. Cianciolo; A. B. Balantekin; A. Bernstein; V. Cirigliano; M. D. Cooper; D. J. Dean; S. R. Elliott; B. W. Filippone; S. J. Freedman; G. L. Greene; K. M. Heeger; D. W. Hertzog; B. R. Holstein; P. Huffman; T. Ito; K. Kumar; Z. -T. Lu; J. S. Nico; G. D. Orebi Gann; K. Paschke; A. Piepke; B. Plaster; D. Pocanic; A. W. P. Poon; D. C. Radford; M. J. Ramsey-Musolf; R. G. H. Robertson; G. Savard; K. Scholberg; Y. Semertzidis; J. F. Wilkerson
2012-12-20T23:59:59.000Z
This White Paper describes recent progress and future opportunities in the area of fundamental symmetries and neutrinos.
Discovering the New Standard Model: Fundamental Symmetries and Neutrinos
Cianciolo, V; Bernstein, A; Cirigliano, V; Cooper, M D; Dean, D J; Elliott, S R; Filippone, B W; Freedman, S J; Greene, G L; Heeger, K M; Hertzog, D W; Holstein, B R; Huffman, P; Ito, T; Kumar, K; Lu, Z -T; Nico, J S; Gann, G D Orebi; Paschke, K; Piepke, A; Plaster, B; Pocanic, D; Poon, A W P; Radford, D C; Ramsey-Musolf, M J; Robertson, R G H; Savard, G; Scholberg, K; Semertzidis, Y; Wilkerson, J F
2012-01-01T23:59:59.000Z
This White Paper describes recent progress and future opportunities in the area of fundamental symmetries and neutrinos.
Generalized second law of thermodynamics on the apparent horizon in modified Gauss-Bonnet gravity
Abdolmaleki, A
2015-01-01T23:59:59.000Z
Modified gravity and generalized second law (GSL) of thermodynamics are interesting topics in the modern cosmology. In this regard, we investigate the GSL of gravitational thermodynamics in the framework of modified Gauss-Bonnet gravity or f(G)-gravity. We consider a spatially FRW universe filled with the matter and radiation enclosed by the dynamical apparent horizon with the Hawking temperature. For two viable f(G) models, we first numerically solve the set of differential equations governing the dynamics of f(G)-gravity. Then, we obtain the evolutions of the Hubble parameter, the Gauss-Bonnet curvature invariant term, the density and equation of state parameters as well as the deceleration parameter. In addition, we check the energy conditions for both models and finally examine the validity of the GSL. For the selected f(G) models, we conclude that both models have a stable de Sitter attractor. The equation of state parameters behave quite similar to those of the LCDM model in the radiation/matter dominat...
Thermodynamics and evaporation of the noncommutative black hole
Yun Soo Myung; Yong-Wan Kim; Young-Jai Park
2007-01-21T23:59:59.000Z
We investigate the thermodynamics of the noncommutative black hole whose static picture is similar to that of the nonsingular black hole known as the de Sitter-Schwarzschild black hole. It turns out that the final remnant of extremal black hole is a thermodynamically stable object. We describe the evaporation process of this black hole by using the noncommutativity-corrected Vaidya metric. It is found that there exists a close relationship between thermodynamic approach and evaporation process.
Continuum Thermodynamics of the SU(N) Gauge Theory
Saumen Datta; Sourendu Gupta
2010-12-30T23:59:59.000Z
The thermodynamics of the deconfined phase of the SU(N) gauge theory is studied. Careful study is made of the approach to the continuum limit. The latent heat of the deconfinement transition is studied, for the theories with 3, 4 and 6 colors. Continuum estimates of various thermodynamic quantities are studied, and the approach to conformality investigated. The bulk thermodynamic quantities at different N are compared, to investigate the validity of 't Hooft scaling at these values of N.
Can the fluctuations of a black hole be treated thermodynamically?
Kostyantyn Ropotenko
2008-03-31T23:59:59.000Z
Since the temperature of a typical Schwarzschild black hole is very low, some doubts are raised about whether the fluctuations of the black hole can be treated thermodynamically. It is shown that this is not the case: the thermodynamic fluctuations of a black hole are considerably larger than the corresponding quantum fluctuations. Moreover the ratio of the mean square thermodynamic fluctuation to the corresponding quantum fluctuation can be interpreted as a number of the effective constituents of a black hole.
Thermodynamical description of the interacting new agegraphic dark energy
A. Sheykhi; M. R. Setare
2010-09-30T23:59:59.000Z
We describe the thermodynamical interpretation of the interaction between new agegraphic dark energy and dark matter in a non-flat universe. When new agegraphic dark energy and dark matter evolve separately, each of them remains in thermodynamic equilibrium. As soon as an interaction between them is taken into account, their thermodynamical interpretation changes by a stable thermal fluctuation. We obtain a relation between the interaction term of the dark components and this thermal fluctuation.
Subenoy Chakraborty; Subhajit Saha
2015-07-06T23:59:59.000Z
The paper deals with the mechanism of particle creation in the framework of irreversible thermodynamics. The second order non-equilibrium thermodynamical prescription of Israel and Stewart has been presented with particle creation rate, treated as the dissipative effect. In the background of a flat FRW model, we assume the non-equilibrium thermodynamical process to be isentropic so that the entropy per particle does not change and consequently the dissipative pressure can be expressed linearly in terms of the particle creation rate. Here the dissipative pressure behaves as a dynamical variable having a non-linear inhomogeneous evolution equation and the entropy flow vector satisfies the second law of thermodynamics. Further, using the Friedmann equations and by proper choice of the particle creation rate as a function of the Hubble parameter, it is possible to show (separately) a transition from the inflationary phase to the radiation era and also from matter dominated era to late time acceleration. Also, in analogy to analytic continuation, it is possible to show a continuous cosmic evolution from inflation to late time acceleration by adjusting the parameters. It is found that in the de Sitter phase, the comoving entropy increases exponentially with time, keeping entropy per particle unchanged. Subsequently, the above cosmological scenarios has been described from field theoretic point of view by introducing a scalar field having self interacting potential. Finally, we make an attempt to show the cosmological phenomenon of particle creation as Hawking radiation, particularly during the inflationary era.
Improved Engine Design Concepts Using the Second Law of Thermodynamics...
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More Documents & Publications Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Are There Practical Approaches for...
Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates...
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minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including...
Thermodynamics of Friedmann Equation and Masslike Function in General Braneworld
Tao Zhu; Ji-Rong Ren; Shu-Fan Mo
2009-06-10T23:59:59.000Z
Using the generalized procedure proposed by \\emph{Wu et al}\\cite{wu} recently, we construct the first law of thermodynamics on apparent horizon in a general braneworld model with curvature correction terms on the brane and in the bulk, respectively. The explicit entropy formulary of apparent horizon in the general braneworld is worked out. We also discuss the masslike function which associated with a new type first law of thermodynamics of the general braneworld in detail. We analyze the difference between the conventional thermodynamics and the new type thermodynamics on apparent horizon. At last, the discussions about the physical meanings of the masslike function have also been given.
aqueous thermodynamic properties: Topics by E-print Network
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(arXiv) Summary: Recent observations show that our universe is accelerating by dark energy, so it is important to investigate the thermodynamical properties of it. The...
SciTech Connect: Thermodynamic and transport properties of sodium...
Office of Scientific and Technical Information (OSTI)
of state calculations on thermophysical properties of sodium have been included in this critical assessment. Thermodynamic properties of sodium liquid and vapor that have been...
analysis pathway thermodynamics: Topics by E-print Network
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The multifractal analysis is then given in Section Urbanski, Mariusz 10 Statistical Energy Analysis and the second principle of thermodynamics Physics Websites Summary:...
approaching thermodynamic property: Topics by E-print Network
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systems are studied from the thermodynamical point of view unifying the principle of maximum informational entropy and the hypothesis of relaxation times hierarchy. The result...
Thermodynamics of the Complexation of Uranium(VI) by oxalate in aqueous solution at 10-70oC
Di Bernardo, Plinio
2009-01-01T23:59:59.000Z
O. Tochiyama in Chemical Thermodynamics of Compounds andUpdate on the Chemical Thermodynamics of Uranium, Neptunium,Thermodynamics of the Complexation of Uranium(VI) with
Thermodynamic integration from classical to quantum mechanics
Habershon, Scott [Centre for Computational Chemistry, School of Chemistry, University of Bristol, Bristol BS8 1TS (United Kingdom); Manolopoulos, David E. [Physical and Theoretical Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford OX1 3QZ (United Kingdom)
2011-12-14T23:59:59.000Z
We present a new method for calculating quantum mechanical corrections to classical free energies, based on thermodynamic integration from classical to quantum mechanics. In contrast to previous methods, our method is numerically stable even in the presence of strong quantum delocalization. We first illustrate the method and its relationship to a well-established method with an analysis of a one-dimensional harmonic oscillator. We then show that our method can be used to calculate the quantum mechanical contributions to the free energies of ice and water for a flexible water model, a problem for which the established method is unstable.
Recent Progress in Lattice QCD Thermodynamics
Carleton DeTar
2008-11-14T23:59:59.000Z
This review gives a critical assessment of the current state of lattice simulations of QCD thermodynamics and what it teaches us about hot hadronic matter. It outlines briefly lattice methods for studying QCD at nonzero temperature and zero baryon number density with particular emphasis on assessing and reducing cutoff effects. It discusses a variety of difficulties with methods for determining the transition temperature. It uses results reported recently in the literature and at this conference for illustration, especially those from a major study carried out by the HotQCD collaboration.
Quark mass thresholds in QCD thermodynamics
M. Laine; Y. Schroder
2006-05-05T23:59:59.000Z
We discuss radiative corrections to how quark mass thresholds are crossed, as a function of the temperature, in basic thermodynamic observables such as the pressure, the energy and entropy densities, and the heat capacity of high temperature QCD. The indication from leading order that the charm quark plays a visible role at surprisingly low temperatures, is confirmed. We also sketch a way to obtain phenomenological estimates relevant for generic expansion rate computations at temperatures between the QCD and electroweak scales, pointing out where improvements over the current knowledge are particularly welcome.
Some remarks on black hole thermodynamics
R. Y. Chiao
2011-02-04T23:59:59.000Z
Two thermodynamic "paradoxes" of black hole physics are re-examined. The first is that there is a thermal instability involving two coupled blackbody cavities containing two black holes, and second is that a classical black hole can swallow up entropy in the form of ambient blackbody photons without increasing its mass. The resolution of the second paradox by Bekenstein and by Hawking is re-visited. The link between Hawking radiation and Wigner's superluminal tunneling time is discussed using two equivalent Feynman diagrams, and Feynman's re-interpretation principle.
Low-temperature thermodynamics with quantum coherence
Varun Narasimhachar; Gilad Gour
2014-10-02T23:59:59.000Z
We find a new characterization of low-temperature processes, which we call "cooling processes", incorporating quantum coherence in the model of thermodynamics for the first time. We derive necessary and sufficient conditions for the feasibility of state transitions under cooling processes. We also rigorously confirm the intuitive robustness of coherence against low-temperature thermal noise. Additionally, we develop the low-temperature "Gibbs-preserving" model, and by comparing our results on the two models, we argue that the latter is a poor approximation to physical processes.
On QCD Thermodynamics with Improved Actions
Karsch, Frithjof
1998-01-01T23:59:59.000Z
We discuss recent advances in the calculation of thermodynamic observables using improved actions. In particular, we discuss the calculation of the equation of state of the SU(3) gauge theory, the critical temperature in units of the string tension, the surface tension and the latent heat at the deconfinement transition. We also present first results from a calculation of the equation of state for four-flavour QCD using an O(a^2) improved staggered fermion action and discuss possible further improvements of the staggered fermion action.
Thermodynamics of Few-Particle Systems
Vasily E. Tarasov
2007-06-23T23:59:59.000Z
We consider the wide class of few-particle systems that have some analog of the thermodynamic laws. These systems are characterized by the distributions that are determined by the Hamiltonian and satisfy the Liouville equation. Few-particle systems of this class are described by a non-holonomic constraint: the power of non-potential forces is directly proportional to the velocity of the elementary phase volume change. The coefficient of this proportionality is determined by the Hamiltonian. In the general case, the examples of the few-particle systems of this class are the constant temperature systems, canonical-dissipative systems, and Fermi-Bose classical systems.
Xu, Wen, 1967-
2001-01-01T23:59:59.000Z
Matched-field methods concern estimation of source location and/or ocean environmental parameters by exploiting full wave modeling of acoustic waveguide propagation. Typical estimation performance demonstrates two fundamental ...
A thermodynamic model of methyldiethanolamine-CO{sub 2}-H{sub 2}S-water
Posey, M.L.; Rochelle, G.T. [Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering] [Univ. of Texas, Austin, TX (United States). Dept. of Chemical Engineering
1997-09-01T23:59:59.000Z
Methyldiethanolamine (MDEA) is one of the favored alkanolamines in acid gas treating. It is receiving increased use due to its lower heat of reaction and lower corrosivity compared to the other amines. The electrolyte-nonrandom two-liquid model has been used to represent the thermodynamic behavior of the system: methyldiethanolamine-CO{sub 2}-H{sub 2}S-water. The Data Regression System (DRS) of Aspen Plus was used to regress parameters of the model to experimental data. pH and conductivity data were utilized to supplement vapor-liquid equilibria (VLE) data and improve confidence in model predictions at low acid gas loadings. Predictions for the mixed acid gas systems can be accurately made from the single acid gas parameter sets without the need to regress additional parameters. VLE data were fit well and the calculated heat absorption matches calorimetric data.
Measurements of Fundamental Fluid Physics of SNF Storage Canisters
Condie, Keith Glenn; Mc Creery, Glenn Ernest; McEligot, Donald Marinus
2001-09-01T23:59:59.000Z
With the University of Idaho, Ohio State University and Clarksean Associates, this research program has the long-term goal to develop reliable predictive techniques for the energy, mass and momentum transfer plus chemical reactions in drying / passivation (surface oxidation) operations in the transfer and storage of spent nuclear fuel (SNF) from wet to dry storage. Such techniques are needed to assist in design of future transfer and storage systems, prediction of the performance of existing and proposed systems and safety (re)evaluation of systems as necessary at later dates. Many fuel element geometries and configurations are accommodated in the storage of spent nuclear fuel. Consequently, there is no one generic fuel element / assembly, storage basket or canister and, therefore, no single generic fuel storage configuration. One can, however, identify generic flow phenomena or processes which may be present during drying or passivation in SNF canisters. The objective of the INEEL tasks was to obtain fundamental measurements of these flow processes in appropriate parameter ranges.
Vajda, Sandor
EK424 THERMODYNAMICS AND STATISTICAL MECHANICS (Fall 2013) Thermodynamics is the study in order to take place? We will study the thermodynamics of two types of processes: mechanical, or the chemical conversion of glucose into useful work), and a good understanding of thermodynamics is essential
Vajda, Sandor
EK424 THERMODYNAMICS AND STATISTICAL MECHANICS (Spring 2013) Thermodynamics is the study in order to take place? We will study the thermodynamics of two types of processes: mechanical, or the chemical conversion of glucose into useful work), and a good understanding of thermodynamics is essential
Conservation-dissipation formalism of irreversible thermodynamics
Yi Zhu; Liu Hong; Zaibao Yang; Wen-An Yong
2014-07-21T23:59:59.000Z
We propose a conservation-dissipation formalism (CDF) for coarse-grained descriptions of irreversible processes. This formalism is based on a stability criterion for non-equilibrium thermodynamics. The criterion ensures that non-equilibrium states tend to equilibrium in long time. As a systematic methodology, CDF provides a feasible procedure in choosing non-equilibrium state variables and determining their evolution equations. The equations derived in CDF have a unified elegant form. They are globally hyperbolic, allow a convenient definition of weak solutions, and are amenable to existing numerics. More importantly, CDF is a genuinely nonlinear formalism and works for systems far away from equilibrium. With this formalism, we formulate novel thermodynamics theories for heat conduction in rigid bodies and non-isothermal compressible Maxwell fluid flows as two typical examples. In these examples, the non-equilibrium variables are exactly the conjugate variables of the heat fluxes or stress tensors. The new theory generalizes Cattaneo's law or Maxwell's law in a regularized and nonlinear fashion.
Molecular thermodynamics of polymer melts at interfaces
Theodorou, D.N.
1988-09-01T23:59:59.000Z
A lattice model is developed for the prediction of structure and thermodynamic properties at free polymer melt surfaces and polymer melt/solid interfaces. Density variations in the interfacial region are taken into account by introducing voids in the lattice, in the spirit of the equation of state theory of Sanchez and Lacombe. Intramolecular energy (chain stiffness) effects are explicitly incorporated. The model is derived through a rigorous statistical mechanical and thermodynamic analysis, which is based on the concept of availability. Two cases are considered: ''full equilibrium,'' whereby the interfacial polymer is taken as free to exchange heat, work and mass with a bulk polymer phase at given temperature and pressure; and ''restricted equilibrium,'' whereby a thin polymer film is allowed to equilibrate locally in response to ambient temperature and pressure, but in which chains do not necessarily have the same chemical potential as in the unconstrained bulk. Techniques are developed for calculating surface tension, adhesion tension, density profiles, chain shape, bond orientation, as well as the distribution of segments of various orders in the interfacial region. 28 refs., 6 figs.
Which Fundamental Constants for CMB and BAO?
Rich, James
2015-01-01T23:59:59.000Z
We study the Cosmic Microwave Background using the three-scale framework of Hu et al. to derive the dependence of the CMB temperature anisotropy spectrum on the fundamental constants. We show that, as expected, the observed spectrum depends only on \\emph{dimensionless} combinations of the constants, and we emphasize the points that make this generally true for cosmological observations. Our analysis suggests that the CMB spectrum shape is mostly determined by $\\alpha^2m_e/m_p$ and the proton-CDM-particle mass ratio, $m_p/\\mchi$, with a sub-dominant dependence on $(G\\mchi m_e/\\hbar c)\\alpha^\\beta$ with $\\beta\\sim -7$. The distance to the last-scattering surface depends on $Gm_p\\mchi/\\hbar c$, so published CMB observational limits on time variations of the constants, besides making assumptions about the form of the dark-energy, implicitly assume the time-independence of this quantity. On the other hand, low-redshift $H_0$, BAO and large-scale structure data can be combined with the \\emph{shape} of the CMB spect...
Fundamentals of materials accounting for nuclear safeguards
Pillay, K.K.S. (comp.)
1989-04-01T23:59:59.000Z
Materials accounting is essential to providing the necessary assurance for verifying the effectiveness of a safeguards system. The use of measurements, analyses, records, and reports to maintain knowledge of the quantities of nuclear material present in a defined area of a facility and the use of physical inventories and materials balances to verify the presence of special nuclear materials are collectively known as materials accounting for nuclear safeguards. This manual, prepared as part of the resource materials for the Safeguards Technology Training Program of the US Department of Energy, addresses fundamental aspects of materials accounting, enriching and complementing them with the first-hand experiences of authors from varied disciplines. The topics range from highly technical subjects to site-specific system designs and policy discussions. This collection of papers is prepared by more than 25 professionals from the nuclear safeguards field. Representing research institutions, industries, and regulatory agencies, the authors create a unique resource for the annual course titled ''Materials Accounting for Nuclear Safeguards,'' which is offered at the Los Alamos National Laboratory.
Generalized second law of thermodynamics in f(T) gravity
Karami, K.; Abdolmaleki, A., E-mail: KKarami@uok.ac.ir, E-mail: AAbdolmaleki@uok.ac.ir [Department of Physics, University of Kurdistan, Pasdaran St., Sanandaj (Iran, Islamic Republic of)
2012-04-01T23:59:59.000Z
We investigate the validity of the generalized second law (GSL) of gravitational thermodynamics in the framework of f(T) modified teleparallel gravity. We consider a spatially flat FRW universe containing only the pressureless matter. The boundary of the universe is assumed to be enclosed by the Hubble horizon. For two viable f(T) models containing f(T) = T+?{sub 1}((?T)){sup n} and f(T) = T??{sub 2}T(1?e{sup ?T{sub 0}/T}), we first calculate the effective equation of state and deceleration parameters. Then, (we investigate the null and strong energy conditions and conclude that a sudden future singularity appears in both models. Furthermore, using a cosmographic analysis we check the viability of two models. Finally, we examine the validity of the GSL and find that for both models it) is satisfied from the early times to the present epoch. But in the future, the GSL is violated for the special ranges of the torsion scalar T.
Analytical thermodynamics of a strongly attractive three-component Fermi gas in one dimension
He Peng [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Yin Xiangguo; Wang Yupeng [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, Murray T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)
2010-11-15T23:59:59.000Z
Ultracold three-component atomic Fermi gases in one dimension are expected to exhibit rich physics due to the presence of trions and different pairing states. Quantum phase transitions from the trion state into a paired phase and a normal Fermi liquid occur at zero temperature. We derive the analytical thermodynamics of strongly attractive three-component one-dimensional fermions with SU(3) symmetry via the thermodynamic Bethe ansatz method in unequal Zeeman splitting fields H{sub 1} and H{sub 2}. We find explicitly that for low temperature the system acts like either a two-component or a three-component Tomonaga-Luttinger liquid dependent on the system parameters. The phase diagrams for the chemical potential and specific heat are presented for illustrative values of the Zeeman splitting. We also demonstrate that crossover between different Tomonaga-Luttinger-liquid phases exhibit singular behavior in specific heat and entropy as the temperature tends to zero. Beyond Tomonaga-Luttinger-liquid physics, we obtain the equation of state which provides a precise description of universal thermodynamics and quantum criticality in three-component, strongly attractive Fermi gases.
Thermodynamics of Rotating Black Branes in Gauss-Bonnet-Born-Infeld Gravity
M. H. Dehghani; S. H. Hendi
2006-11-08T23:59:59.000Z
Considering both the Gauss-Bonnet and the Born-Infeld terms, which are on similar footing with regard to string corrections on the gravity side and electrodynamic side, we present a new class of rotating solutions in Gauss-Bonnet gravity with $k$ rotation parameters in the presence of a nonlinear electromagnetic field. These solutions, which are asymptotically anti-de Sitter in the presence of cosmological constant, may be interpreted as black brane solutions with inner and outer event horizons, an extreme black brane or naked singularity provided the metric parameters are chosen suitably. We calculate the finite action and conserved quantities of the solutions by using the counterterm method, and find that these quantities do not depend on the Gauss-Bonnet parameter. We also compute the temperature, the angular velocities, the electric charge and the electric potential. Then, we calculate the entropy of the black brane through the use of Gibbs-Duhem relation and show that it obeys the area law of entropy. We obtain a Smarr-type formula for the mass as a function of the entropy, the angular momenta and the charge, and show that the conserved and thermodynamic quantities satisfy the first law of thermodynamics. Finally, we perform a stability analysis in both the canonical and grand-canonical ensemble and show that the presence of a nonlinear electromagnetic field has no effect on the stability of the black branes, and they are stable in the whole phase space.
Thermodynamics of finite magnetic two-isomer systems Peter Borrmann, Heinrich Stamerjohanns,a)
Thermodynamics of finite magnetic two-isomer systems Peter Borrmann, Heinrich Stamerjohanns Carlo simulations to investigate the thermodynamical behavior of aggregates consisting of few thermodynamically the nature of the transition between the ring and the chain ``phase.'' © 1999 American Institute
Boyer, Edmond
Thermodynamics based stabilitization of CSTR networks H. Hoang, F. Couenne, Y. Le Gorrec and D. Dochain Abstract-- This paper shows that any potential function fulfilling certain thermodynamic stability the theoretical developments. Keywords. Irreversible thermodynamics, CSTR networks, Port Hamiltonian systems
The Frenkel Line: a direct experimental evidence for the new thermodynamic boundary
Bolmatov, Dima; Zav'yalov, D; Tkachev, S N; Cunsolo, A; Cai, Y Q
2015-01-01T23:59:59.000Z
Supercritical fluids play a significant role in elucidating fundamental aspects of liquid matter under extreme conditions. They have been extensively studied at pressures and temperatures relevant to various industrial applications. However, much less is known about the structural behaviour of supercritical fluids and no structural crossovers have been observed in static compression experiments in any temperature and pressure ranges beyond the critical point. The structure of supercritical state is currently perceived to be uniform everywhere on the phase diagram, and to change only in a monotonic way while moving along any pressure and temperature path beyond the critical point and its neighborhood. Conversely, we observe structural crossovers in a deeply supercritical sample through diffraction measurements in a diamond anvil cell and discover a new thermodynamic boundary on the pressure-temperature diagram. We explain the existence of these crossovers in the framework of the phonon theory of liquids using ...
A thermodynamically consistent Ginzburg-Landau model for superfluid transition in liquid helium
Alessia Berti; Valeria Berti
2012-11-15T23:59:59.000Z
In this paper we propose a thermodynamically consistent model for superfluid-normal phase transition in liquid helium, accounting for variations of temperature and density. The phase transition is described by means of an order parameter, according to the Ginzburg-Landau theory, emphasizing the analogies between superfluidity and superconductivity. The normal component of the velocity is assumed to be compressible and the usual phase diagram of liquid helium is recovered. Moreover, the continuity equation leads to a dependence between density and temperature in agreement with the experimental data.
EXTENDING THE PREDICTION OF THE THERMODYNAMIC PROPERTIES OF CLAY
Paris-Sud XI, Université de
EXTENDING THE PREDICTION OF THE THERMODYNAMIC PROPERTIES OF CLAY MINERALS TO THE TRAPPING OF TRACE The thermodynamic properties of clay minerals, which control the stability of these minerals in solution, are still are parameterised using a given set of minerals. For clay minerals, the latter are mainly composed by Si, Al, Fe
Thermodynamic Analysis of a single chamber Microbial Eric A. Zielke
Thermodynamic Analysis of a single chamber Microbial Fuel Cell Eric A. Zielke May 5, 2006 #12;Microbial Fuel Cell Zielke ii List of Tables 1 First Law Thermodynamic Efficiencies from Experimental Data . . . . . . . 9 #12;Microbial Fuel Cell Zielke iii List of Figures 1 Representation of Anaerobic (anode portion
On thermodynamically consistent schemes for phase field equations
Fife, Paul
and at the phase change front. A somewhat different approach of Charach and Zemel [2] combines bal- ance equationsOn thermodynamically consistent schemes for phase field equations C. Charach and P. C. Fife thermodynamics. The principal applications are to the solidification of a pure material and of a binary alloy
Thermodynamics and the naked singularity in the Gamma-metric
K. Lochan; D. Malafarina; T. P. Singh
2010-09-23T23:59:59.000Z
We investigate a possible way of establishing a parallel between the third law of black hole mechanics, and the strong version of the third law of thermodynamics. We calculate the surface gravity and area for a naked singular null surface in the Gamma-metric and explain in what sense this behaviour violates thermodynamics.
Thermodynamics and Finite size scaling in Scalar Field Theory
Debasish Banerjee; Saumen Datta; Sourendu Gupta
2008-12-05T23:59:59.000Z
In this work we consider the 1-component real scalar $\\phi^4$ theory in 4 space-time dimensions on the lattice and investigate the finite size scaling of thermodynamic quantities to study whether the thermodynamic limit is attained. The results are obtained for the symmetric phase of the theory.
Notes on the Generalised Second Law of Thermodynamics
S. -T. Sung
1997-03-22T23:59:59.000Z
Several comments are given to previous proofs of the generalised second law of thermodynamics: black hole entropy plus ordinary matter entropy never decreases for a thermally closed system. Arguments in favour of its truism are given in the spirit of conventional thermodynamics.
Fundamentals of Mercury Oxidation in Flue Gas
JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar
2008-07-31T23:59:59.000Z
The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.
A definition of thermodynamic entropy valid for non-equilibrium states and few-particle systems
Gian Paolo Beretta; Enzo Zanchini
2014-11-19T23:59:59.000Z
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic entropy well beyond the traditional realm of equilibrium states of macroscopic systems. The new definition is achieved by avoiding to resort to the traditional concepts of "heat" (which restricts $a$ $priori$ the traditional definitions of entropy to the equilibrium domain) and of "thermal reservoir" (which restricts $in$ $practice$ our previous definitions of non-equilibrium entropy to the many-particle domain). The measurement procedure that defines entropy is free from intrinsic limitations and can be applied, $in$ $principle$, even to non-equilibrium states of few-particle systems, provided they are separable and uncorrelated. The construction starts from a previously developed set of carefully worded operational definitions for all the basic concepts. Then, through a new set of fully spelled-out fundamental hypotheses (four postulates and five assumptions) we derive the definitions of energy and entropy of any state, and of temperature of any stable equilibrium state. Finally, we prove the principle of entropy non-decrease, the additivity of entropy differences, the maximum entropy principle, and the impossibility of existence of a thermal reservoir.
The thermodynamics for a hadronic gas of fireballs with internal color structures and chiral fields
Ismail Zakout; Carsten Greiner
2008-08-11T23:59:59.000Z
The thermodynamical partition function for a gas of color-singlet bags consisting of fundamental and adjoint particles in both $U(N_c)$ and $SU(N_c)$ group representations is reviewed in detail. The constituent particle species are assumed to satisfy various thermodynamical statistics. The gas of bags is probed to study the phase transition for a nuclear matter in the extreme conditions. These bags are interpreted as the Hagedorn states and they are the highly excited hadronic states which are produced below the phase transition point to the quark-gluon plasma. The hadronic density of states has the Gross-Witten critical point and exhibits a third order phase transition from a hadronic phase dominated by the discrete low-lying hadronic mass spectrum particles to another hadronic phase dominated by the continuous Hagedorn states. The Hagedorn threshold production is found just above the highest known experimental discrete low-lying hadronic mass spectrum. The subsequent Hagedorn phase undergoes a first order deconfinement phase transition to an explosive quark-gluon plasma. The role of the chiral phase transition in the phases of the discrete low-lying mass spectrum and the continuous Hagedorn mass spectrum is also considered. It is found crucial in the phase transition diagram. Alternate scenarios are briefly discussed for the Hagedorn gas undergoes a higher order phase transition through multi-processes of internal color-flavor structure modification.
Particle absorption by black holes and the generalized second law of thermodynamics
Scott Funkhouser
2010-04-08T23:59:59.000Z
The change in entropy, /DeltaS, associated with the quasi-static absorption of a particle of energy u by a Schwarzschild black hole (ScBH) is approximately (u/T)-s, where T is the Hawking temperature of the black hole and s is the entropy of the particle. Motivated by the statistical interpretation of entropy, it is proposed here that absorption should be suppressed, but not forbidden, when /DeltaSabsorption cross-section to be sensitive to /DeltaS. A purely thermodynamic formulation of the probability for absorption is obtained from the standard relationship between microstates and entropy. If /DeltaS>>1 and s<fundamental physical unity between thermodynamics and quantum mechanics.
Thermodynamic geometry of charged rotating BTZ black holes
Akbar, M. [Center for Advanced Mathematics and Physics, National University of Sciences and Technology, H-12, Islamabad (Pakistan); Quevedo, H. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, AP 70543, Mexico, DF 04510 (Mexico); ICRANet, Dipartimento di Fisica, Universita di Roma La Sapienza, I-00185 Roma (Italy); Saifullah, K. [Department of Mathematics, Quaid-i-Azam University, Islamabad (Pakistan); Sanchez, A. [Departamento de Posgrado, CIIDET, AP 752, Queretaro, QRO 76000 (Mexico); Taj, S. [Center for Advanced Mathematics and Physics, National University of Sciences and Technology, H-12, Islamabad (Pakistan); ICRANet, Dipartimento di Fisica, Universita di Roma La Sapienza, I-00185 Roma (Italy)
2011-04-15T23:59:59.000Z
We study the thermodynamics and the thermodynamic geometries of charged rotating Banados-Teitelboim-Zanelli black holes in (2+1)-gravity. We investigate the thermodynamics of these systems within the context of the Weinhold and Ruppeiner thermodynamic geometries and the recently developed formalism of geometrothermodynamics. Considering the behavior of the heat capacity and the Hawking temperature, we show that Weinhold and Ruppeiner geometries cannot describe completely the thermodynamics of these black holes and of their limiting case of vanishing electric charge. In contrast, the Legendre invariance imposed on the metric in geometrothermodynamics allows one to describe the charged rotating Banados-Teitelboim-Zanelli black holes and their limiting cases in a consistent and invariant manner.
Beyond heat baths II: Framework for generalized thermodynamic resource theories
Nicole Yunger Halpern
2014-09-27T23:59:59.000Z
Cutting-edge experiments, which involve the nano- and quantum scales, have been united with thermodynamics, which describes macroscopic systems, via resource theories. Resource theories have modeled small-scale exchanges of heat and information. Recently, the models were extended to particle exchanges, and a family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilard's engine and Landauer's Principle are generalized, as resourcefulness is shown to be convertible not only between informational and gravitational-energy forms, but also among varied physical degrees of freedom in the thermodynamic limit. Quantum operators associated with extensive variables offer opportunities to explore nonclassical noncommutation. This generalization of thermodynamic resource theories invites the modeling of realistic systems that might be harnessed to test small-scale statistical mechanics experimentally.
Thermodynamics in f(R,T) Theory of Gravity
M. Sharif; M. Zubair
2012-04-11T23:59:59.000Z
A non-equilibrium picture of thermodynamics is discussed at the apparent horizon of FRW universe in $f(R,T)$ gravity, where $R$ is the Ricci scalar and $T$ is the trace of the energy-momentum tensor. We take two forms of the energy-momentum tensor of dark components and demonstrate that equilibrium description of thermodynamics is not achievable in both cases. We check the validity of the first and second law of thermodynamics in this scenario. It is shown that the Friedmann equations can be expressed in the form of first law of thermodynamics $T_hdS'_h+T_hd_{\\jmath}S'=-dE'+W'dV$, where $d_{\\jmath}S'$ is the entropy production term. Finally, we conclude that the second law of thermodynamics holds both in phantom and non-phantom phases.
Rui Wang; Zhen-Gang Wang
2014-06-05T23:59:59.000Z
Using the language of the Flory chi parameter, we develop a theory that unifies the treatment of the single-chain structure and the solution thermodynamics of polymers in poor solvents. The structure of a globule and its melting thermodynamics is examined using the self-consistent filed theory. Our results show that the chain conformation involves three states prior to the globule-to-coil transition: the fully-collapsed globule, the swollen globule and the molten globule, which are distinguished by the core density and the interfacial thickness. By examining the chain-length dependence of the melting of the swollen globule, we find universal scaling behavior in the chain properties near the Theta point. The information of density profile and free energy of the globule is used in the dilute solution thermodynamics to study the phase equilibrium of polymer solution. Our results show different scaling behavior of the solubility of polymers in the dilute solution compared to the F-H theory, both in the chi dependence and the chain-length dependence. From the perspectives of single chain structure and solution thermodynamics, our results verifies the consistency of the Theta point defined by different criteria in the limit of infinite chain length: the disappearance of the second viral coefficient, the abrupt change in chain size and the critical point in the phase diagram of the polymer solution. Our results show the value of chi at the Theta point is 0.5 (for the case of equal monomer and solvent volume), which coincides with the value predicted from the F-H theory.
Fundamentals of Mercury Oxidation in Flue Gas
JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar
2006-07-31T23:59:59.000Z
The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.
Fundamentals of Mercury Oxidation in Flue Gas
JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Constance Senior; Joseph Helble; Balaji Krishnakumar
2005-08-01T23:59:59.000Z
The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 2 results for the experimental and modeling tasks. Experiments in the mercury reactor are underway and interesting results suggested that a more comprehensive look at catalyzed surface reactions was needed. Therefore, much of the work has focused on the heterogeneous reactions. In addition, various chemical kinetic models have been explored in an attempt to explain some discrepancies between this modeling effort and others.
ash fiber fundamental: Topics by E-print Network
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MIT - DSpace Summary: We demonstrate significant shifting of the fundamental bandgap of a hollow-core Bragg fiber by systematically filling the core with liquids of various...
The fundamental solution of the unidirectional pulse propagation equation
Babushkin, I. [Institute of Mathematics, Humboldt University, Rudower Chaussee 25, 12489 Berlin (Germany)] [Institute of Mathematics, Humboldt University, Rudower Chaussee 25, 12489 Berlin (Germany); Bergé, L. [CEA, DAM, DIF, F-91297 Arpajon (France)] [CEA, DAM, DIF, F-91297 Arpajon (France)
2014-03-15T23:59:59.000Z
The fundamental solution of a variant of the three-dimensional wave equation known as “unidirectional pulse propagation equation” (UPPE) and its paraxial approximation is obtained. It is shown that the fundamental solution can be presented as a projection of a fundamental solution of the wave equation to some functional subspace. We discuss the degree of equivalence of the UPPE and the wave equation in this respect. In particular, we show that the UPPE, in contrast to the common belief, describes wave propagation in both longitudinal and temporal directions, and, thereby, its fundamental solution possesses a non-causal character.
Fundamental study of the relationship of austenite-ferrite transformat...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
More Documents & Publications Fundamental study of the relationship of austenite-ferrite transformation details to austenite retention in carbon steels FSW & USW Solid State...
Fundamental study of the relationship of austenite-ferrite transformat...
Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site
More Documents & Publications Fundamental study of the relationship of austenite-ferrite transformation details to austenite retention in carbon steels Vehicle Technologies...
COLLOQUIUM: Type II Solar Radio Bursts: From Fundamental Plasma...
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Auditorium COLLOQUIUM: Type II Solar Radio Bursts: From Fundamental Plasma Physics to Space Weather Research Professor Iver Cairns University of Sydney - School of Physics For...
Fundamental Approach to Electrode Fabrication and Failure Analysis
Broader source: Energy.gov (indexed) [DOE]
Fundamental Approach to Electrode Fabrication and Failure Analysis Vince Battaglia LBNL May 11, 2011 This presentation does not contain any proprietary, confidential, or otherwise...
Chelation: A Fundamental Mechanism of Action of AGE Inhibitors...
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Mechanism of Action of AGE Inhibitors, AGE Breakers, and Other Inhibitors of Diabetes Complications. Chelation: A Fundamental Mechanism of Action of AGE Inhibitors, AGE...
Entanglement Production in Non-Equilibrium Thermodynamics
V. Vedral
2007-06-21T23:59:59.000Z
We define and analyse the concept of entanglement production during the evolution of a general quantum mechanical dissipative system. While it is important to minimise entropy production in order to achieve thermodynamical efficiency, maximising the rate of change of entanglement is important in quantum information processing. Quantitative relations are obtained between entropy and entanglement productions, under specific assumptions detailed in the text. We apply these to the processes of dephasing and decay of correlations between two initially entangled qubits. Both the Master equation treatment as well as the higher Hilbert space analysis are presented. Our formalism is very general and contains as special cases many reported individual instance of entanglement dynamics, such as, for example, the recently discovered notion of the sudden death of entanglement.
Thermodynamics of pairing transition in hot nuclei
Lang Liu; Zhen-Hua Zhang; Peng-Wei Zhao
2014-12-16T23:59:59.000Z
The pairing correlations in hot nuclei $^{162}$Dy are investigated in terms of the thermodynamical properties by covariant density functional theory. The heat capacities $C_V$ are evaluated in the canonical ensemble theory and the paring correlations are treated by a shell-model-like approach, in which the particle number is conserved exactly. A S-shaped heat capacity curve, which agrees qualitatively with the experimental data, has been obtained and analyzed in details. It is found that the one-pair-broken states play crucial roles in the appearance of the S shape of the heat capacity curve. Moreover, due to the effect of the particle-number conservation, the pairing gap varies smoothly with the temperature, which indicates a gradual transition from the superfluid to the normal state.
Halogenation of Imidazolium Ionic Liquids. Thermodynamics Perspective
Chaban, Vitaly V
2015-01-01T23:59:59.000Z
Imidazolium cations are promising for anion exchange membranes, and electrochemical applications and gas capture. They can be chemically modified in many ways including halogenation. Halogenation possibilities of the imidazole ring constitute a particular interest. This work investigates fluorination and chlorination reactions of all symmetrically non-equivalent sites of the imidazolium cation. Halogenation of all carbon atoms is thermodynamically permitted. Out of these, the most favorable site is the first methylene group of the alkyl chain. In turn, the least favorable site is carbon of the imidazole ring. Temperature dependence of enthalpy, entropy, and Gibbs free energy at 1 bar is discussed. The reported results provide an important guidance in functionalization of ionic liquids in search of task-specific compounds.
Thermodynamics in variable speed of light theories
Juan Racker; Pablo Sisterna; Hector Vucetich
2009-11-30T23:59:59.000Z
The perfect fluid in the context of a covariant variable speed of light theory proposed by J. Magueijo is studied. On the one hand the modified first law of thermodynamics together with a recipe to obtain equations of state are obtained. On the other hand the Newtonian limit is performed to obtain the nonrelativistic hydrostatic equilibrium equation for the theory. The results obtained are used to determine the time variation of the radius of Mercury induced by the variability of the speed of light ($c$), and the scalar contribution to the luminosity of white dwarfs. Using a bound for the change of that radius and combining it with an upper limit for the variation of the fine structure constant, a bound on the time variation of $c$ is set. An independent bound is obtained from luminosity estimates for Stein 2015B.
Some Thermodynamic Properties of Colloidal Dispersions
de Thier, Pierre
2013-01-01T23:59:59.000Z
In this paper, some results are derived to describe the out-of-equilibrium thermodynamics of colloidal suspensions. These results are obtained assuming that the properties of the colloids essentially come from their surfaces which are unusually high in comparison to their volume. The dispersion, in the form of a variable, is introduced in such a way as to embody the various changes which could affect those systems. Explicit relations are deduced for the free enthalpy of dispersion which describe two separated phenomena: the peptization/coalescence and the suspension of a colloidal phase. An alternative to the Gibbs' adsorption equation allows to explain how a surface relaxes thanks to adsorptions. Finally, a link between conformational entropy changes and surface entropy production is discussed with the idea to be applied to the well known protein folding problem.
M.S. Gruszkiewiez; D.A. Palmer; R.D. Springer; P. Wang; A. Anderko
2006-09-14T23:59:59.000Z
A comprehensive model has been established for calculating thermodynamic properties of multicomponent aqueous systems containing the Na{sup +}, K{sup +}, Mg{sup 2+}, Ca{sup 2+}, Cl{sup -}, and NO{sub 3}{sup -} ions. The thermodynamic framework is based on a previously developed model for mixed-solvent electrolyte solutions. The framework has been designed to reproduce the properties of salt solutions at temperatures ranging from the freezing point to 300 C and concentrations ranging from infinite dilution to the fused salt limit. The model has been parameterized using a combination of an extensive literature database and new isopiestic measurements for thirteen salt mixtures at 140 C. The measurements have been performed using Oak Ridge National Laboratory's (ORNL) previously designed gravimetric isopiestic apparatus, which makes it possible to detect solid phase precipitation. Water activities are reported for mixtures with a fixed ratio of salts as a function of the total apparent salt mole fraction. The isopiestic measurements reported here simultaneously reflect two fundamental properties of the system, i.e., the activity of water as a function of solution concentration and the occurrence of solid-liquid transitions. The thermodynamic model accurately reproduces the new isopiestic data as well as literature data for binary, ternary and higher-order subsystems. Because of its high accuracy in calculating vapor-liquid and solid-liquid equilibria, the model is suitable for studying deliquescence behavior of multicomponent salt systems.
Selective coupling of optical energy into the fundamental diffusion mode of a scattering medium
Ojambati, Oluwafemi S; Lagendijk, Ad; Mosk, Allard P; Vos, Willem L
2015-01-01T23:59:59.000Z
We demonstrate experimentally that optical wavefront shaping selectively couples light into the fundamental diffusion mode of a scattering medium. The total energy density inside a scattering medium of zinc oxide (ZnO) nanoparticles was probed by measuring the emitted fluorescent power of spheres that were randomly positioned inside the medium. The fluorescent power of an optimized incident wave front is observed to be enhanced compared to a non-optimized incident front. The observed enhancement increases with sample thickness. Based on diffusion theory, we derive a model wherein the distribution of energy density of wavefront-shaped light is described by the fundamental diffusion mode. The agreement between our model and the data is striking not in the least since there are no adjustable parameters. Enhanced total energy density is crucial to increase the efficiency of white LEDs, solar cells, and of random lasers, as well as to realize controlled illumination in biomedical optics.
Plasma-Therm Workshop: Fundamentals of Plasma Processing (Etching & Deposition)
Martin, Jan M.L.
The workshop will focus on the fundamentals of plasma etching and deposition. Lectures will includePlasma-Therm Workshop: Fundamentals of Plasma Processing (Etching & Deposition) Nanofabrication an introduction to vacuum technology, the basics of plasma and plasma reactors and an overview of mechanisms
Ris-R-1336(EN) Fundamentals for Remote Structural
Risř-R-1336(EN) Fundamentals for Remote Structural Health Monitoring of Wind Turbine Blades) Fundamentals for Remote Structural Health Monitoring of Wind Turbine Blades - a Preproject Bent F. Sřrensen for the sensors capability to detect the most important damage types in wind turbine blades. Three different
ON WAVELET FUNDAMENTAL SOLUTIONS TO THE HEAT EQUATION ---HEATLETS
Soatto, Stefano
ON WAVELET FUNDAMENTAL SOLUTIONS TO THE HEAT EQUATION --- HEATLETS JIANHONG SHEN AND GILBERT STRANG Abstract. We present an application of wavelet theory in partial differential equaÂ tions. We study the wavelet fundamental solutions to the heat equation. The heat evolution of an initial wavelet state
Sun, Na; Zhang, Xinyu, E-mail: jiaqianqin@gmail.com; Ning, Jinliang; Zhang, Suhong; Liang, Shunxing; Ma, Mingzhen; Liu, Riping [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Qin, Jiaqian, E-mail: jiaqianqin@gmail.com [Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330 (Thailand)
2014-02-28T23:59:59.000Z
A comprehensive investigation of the structural, elastic, and thermodynamic properties for Laves-phases ZrZn{sub 2} and HfZn{sub 2} are conducted using density functional total energy calculations combined with the quasi-harmonic Debye model. The optimized lattice parameters of ZrZn{sub 2} and HfZn{sub 2} compare well with available experimental values. We estimated the mechanical behaviors of both compounds under compression, including mechanical stability, Young's modulus, Poisson's ratio, ductility, and anisotropy. Additionally, the thermodynamic properties as a function of pressure and temperature are analyzed and found to be in good agreement with the corresponding experimental data.
Thermodynamical properties of graphene in noncommutative phase-space
Victor Santos; R. V. Maluf; C. A. S. Almeida
2014-07-28T23:59:59.000Z
We investigated the thermodynamic properties of graphene in a noncommutative phase-space in the presence of a constant magnetic field. In particular, we determined the behaviour of the main thermodynamical functions: the Helmholtz free energy, the mean energy, the entropy and the specific heat. The high temperature limit is worked out and the thermodynamic quantities, such as mean energy and specific heat, exhibit the same features as the commutative case. Possible connections with the results already established in the literature are discussed briefly.
Thermodynamics on the apparent horizon in generalized gravity theories
Shao-Feng Wu; Bin Wang; Guo-Hong Yang
2008-01-17T23:59:59.000Z
We present a general procedure to construct the first law of thermodynamics on the apparent horizon and illustrate its validity by examining it in some extended gravity theories. Applying this procedure, we can describe the thermodynamics on the apparent horizon in Randall-Sundrum braneworld imbedded in a nontrivial bulk. We discuss the mass-like function which was used to link Friedmann equation to the first law of thermodynamics and obtain its special case which gives the generalized Misner-Sharp mass in Lovelock gravity.
A Study of Universal Thermodynamics in Brane World Scenario
Saugata Mitra; Subhajit Saha; Subenoy Chakraborty
2015-03-25T23:59:59.000Z
A study of Universal thermodynamics is done in the frame work of RSII brane model and DGP brane scenario. The Universe is chosen as FRW model bounded by apparent or event horizon. Assuming extended Hawking temperature on the horizon, the unified first law is examined for perfect fluid (with constant equation of state) and modified Chaplygin gas model. As a result there is a modification of Bekenstein entropy on the horizons. Further the validity of the generalized second law of thermodynamics and thermodynamical equilibrium are also investigated.
Thermodynamics of strong-interaction matter from Lattice QCD
Heng-Tong Ding; Frithjof Karsch; Swagato Mukherjee
2015-04-21T23:59:59.000Z
We review results from lattice QCD calculations on the thermodynamics of strong-interaction matter with emphasis on input these calculations can provide to the exploration of the phase diagram and properties of hot and dense matter created in heavy ion experiments. This review is organized as follows: 1) Introduction, 2) QCD thermodynamics on the lattice, 3) QCD phase diagram at high temperature, 4) Bulk thermodynamics, 5) Fluctuations of conserved charges, 6) Transport properties, 7) Open heavy flavors and heavy quarkonia, 8) QCD in external magnetic fields, 9) Summary.
The role of quantum information in thermodynamics --- a topical review
John Goold; Marcus Huber; Arnau Riera; Lídia del Rio; Paul Skrzypzyk
2015-05-28T23:59:59.000Z
This topical review article gives an overview of the interplay between quantum information theory and thermodynamics of quantum systems. We focus on several trending topics including the foundations of statistical mechanics, resource theories, entanglement in thermodynamic settings, fluctuation theorems and thermal machines. This is not a comprehensive review of the diverse field of quantum thermodynamics; rather, it is a convenient entry point for the thermo-curious information theorist. Furthermore this review should facilitate the unification and understanding of different interdisciplinary approaches emerging in research groups around the world.
A Study of Universal Thermodynamics in Brane World Scenario
Mitra, Saugata; Chakraborty, Subenoy
2015-01-01T23:59:59.000Z
A study of Universal thermodynamics is done in the frame work of RSII brane model and DGP brane scenario. The Universe is chosen as FRW model bounded by apparent or event horizon. Assuming extended Hawking temperature on the horizon, the unified first law is examined for perfect fluid (with constant equation of state) and modified Chaplygin gas model. As a result there is a modification of Bekenstein entropy on the horizons. Further the validity of the generalized second law of thermodynamics and thermodynamical equilibrium are also investigated.
Thermodynamics of strong-interaction matter from Lattice QCD
Ding, Heng-Tong; Mukherjee, Swagato
2015-01-01T23:59:59.000Z
We review results from lattice QCD calculations on the thermodynamics of strong-interaction matter with emphasis on input these calculations can provide to the exploration of the phase diagram and properties of hot and dense matter created in heavy ion experiments. This review is organized as follows: 1) Introduction, 2) QCD thermodynamics on the lattice, 3) QCD phase diagram at high temperature, 4) Bulk thermodynamics, 5) Fluctuations of conserved charges, 6) Transport properties, 7) Open heavy flavors and heavy quarkonia, 8) QCD in external magnetic fields, 9) Summary.
Zaltash, A.
1987-01-01T23:59:59.000Z
Application of thermodynamic analogy to pneumatic transport in 0.0266 m and 0.0504 m systems held at various angles of inclination was investigated. Particles used in these systems included glass particles of 67 ..mu..m, 450 ..mu..m, and 900 ..mu..m weight mean diameter as well as iron ore of 400 ..mu..m weight mean diameter. An equation of state similar to the van der Waals has been suggested for these systems. Measurements in these experimental set-ups included pressure drops, particle velocities, and solids mass flow rates in both the upper and lower halves of the pipe. These measurements were used to describe the phase behavior of the systems studied. It was found that the van der Waals analog is capable of describing the phase behavior of these systems. A method has been proposed to estimate the parameters of the van der Waals analog equation. The incorporation of dimensionless pressure drop into the analysis has been attempted by the use of energy functions in thermodynamics. The effect of inclination angle, pipe diameter, and particle characteristics on basic flow parameters were studied. The ratio of solids flow in the top half to that of the bottom half of the pipe showed that the concentration gradient is influenced by particle characteristics, and by the pipe diameter and orientation. Glass test section was used in these systems for visual observations of the flow patterns. 53 refs., 176 figs., 52 tabs.
Thermodynamics of the six-vertex model in an L-shaped domain
Filippo Colomo; Andrei G. Pronko
2015-01-13T23:59:59.000Z
We consider the six-vertex model in an L-shaped domain of the square lattice, with domain wall boundary conditions. For free-fermion vertex weights the partition function can be expressed in terms of some Hankel determinant, or equivalently as a Coulomb gas with discrete measure and a non-polynomial potential with two hard walls. We use Coulomb gas methods to study the partition function in the thermodynamic limit. We obtain the free energy of the six-vertex model as a function of the parameters describing the geometry of the scaled L-shaped domain. Under variations of these parameters the system undergoes a third-order phase transition. The result can also be considered in the context of dimer models, for the perfect matchings of the Aztec diamond graph with a cut-off corner.
A Synergy of Novel Experiments, Materials Science, Fundamental Physics, and Superconducting Magnets
Godeke, Arno
2007-01-01T23:59:59.000Z
Fundamental Physics Superconducting Magnets Yields: Accuraterecord setting superconducting magnet systems ITER, NMRScience, Fundamental Physics, and Superconducting Magnets
M. Bahrami ENSC 388 (F09) 2nd Law of Thermodynamics 1
Bahrami, Majid
M. Bahrami ENSC 388 (F09) 2nd Law of Thermodynamics 1 The Second Law of Thermodynamics The second law of thermodynamics asserts that processes occur it satisfies both the first and the second laws of thermodynamics. The second law also asserts that energy
Thermodynamics of combined-cycle electric power plants Harvey S. Leffa)
of thermodynamics and technology, modern gas and steam turbines can be coupled, to effect dramatic efficiency
Pavement Thickness Design Parameter
Pavement Thickness Design Parameter Impacts 2012 Municipal Streets Seminar November 14, 2012 Paul D. Wiegand, P.E. #12;Pavement Thickness Design · How do cities decide how thick to build their pavements;Pavement Thickness Design · Correct answer A data-based analysis! · Doesn't have to be difficult and time
aggrecans statistical thermodynamic: Topics by E-print Network
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15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Thermodynamics for Fractal Statistics HEP - Theory (arXiv) Summary: We consider for an anyon gas its...
actinide thermodynamic predictions: Topics by E-print Network
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2012-08-02 289 Coupled thermodynamic-dynamic semi-analytical model of Free Piston Stirling engines CERN Preprints Summary: The study of free piston Stirling engine (FPSE)...
A unifying framework for watershed thermodynamics: balance equations for mass,
Hassanizadeh, S. Majid
A unifying framework for watershed thermodynamics: balance equations for mass, momentum, energy Hassanizadehb a Centre for Water Research, Department of Environmental Engineering, The University of Western Australia, 6907 Nedlands, Australia b Department of Water Management, Environmental and Sanitary Engineering
Dynamics and Thermodynamics of Blackholes and Naked Singularities
Lorenzo Fatibene; Mauro Francaviglia; Roberto Giambo'; Giulio Magli
2005-12-15T23:59:59.000Z
Proceedings of the international Workshop on ``Dynamics and Thermodynamics of Blackholes and Naked Singularities``, that took place at the Department of Mathematics of the Politecnico of Milano from 13 to 15 May 2004.
OBTAINING LAWS OF THERMODYNAMICS FOR IDEAL GASES USING ELASTIC COLLISIONS
Montgomery-Smith, Stephen
momenta. In [3], this work was used to simulate the Carnot cycle. This paper gives a slightly different Newtonian. For example, the motion is reversible, thus demonstrating that the second law of thermodynamics
Lithium-ion battery modeling using non-equilibrium thermodynamics
Ferguson, Todd R. (Todd Richard)
2014-01-01T23:59:59.000Z
The focus of this thesis work is the application of non-equilibrium thermodynamics in lithium-ion battery modeling. As the demand for higher power and longer lasting batteries increases, the search for materials suitable ...
Thermodynamics of a non-commutative fermion gas
F G Scholtz; J Govaerts
2008-10-17T23:59:59.000Z
Building on the recent solution for the spectrum of the non-commutative well in two dimensions, the thermodynamics that follows from it is computed. In particular the focus is put on an ideal fermion gas confined to such a well. At low densities the thermodynamics is the same as for the commutative gas. However, at high densities the thermodynamics deviate strongly from the commutative gas due to the implied excluded area resulting from the non-commutativity. In particular there are extremal macroscopic states, characterized by area, number of particles and angular momentum, that correspond to a single microscopic state and thus have vanishing entropy. When the system size and excluded area are comparable, thermodynamic quantities, such as entropy, exhibit non-extensive features.
Thermodynamics of de Sitter Black Holes: Thermal Cosmological Constant
Yuichi Sekiwa
2006-04-10T23:59:59.000Z
We study the thermodynamic properties associated with the black hole event horizon and the cosmological horizon for black hole solutions in asymptotically de Sitter spacetimes. We examine thermodynamics of these horizons on the basis of the conserved charges according to Teitelboim's method. In particular, we have succeeded in deriving the generalized Smarr formula among thermodynamical quantities in a simple and natural way. We then show that cosmological constant must decrease when one takes into account the quantum effect. These observations have been obtained if and only if cosmological constant plays the role of a thermodynamical state variable. We also touch upon the relation between inflation of our universe and a phase transition of black holes.
Thermodynamic behavior of particular f(R,T)-gravity models
Sharif, M., E-mail: msharif.math@pu.edu.pk; Zubair, M., E-mail: mzubairkk@gmail.com [University of the Punjab Quaid-e-Azam Campus, Department of Mathematics (Pakistan)
2013-08-15T23:59:59.000Z
We investigate the thermodynamics at the apparent horizon of the FRW universe in f(R, T) theory in the nonequilibrium description. The laws of thermodynamics are discussed for two particular models of the f(R, T) theory. The first law of thermodynamics is expressed in the form of the Clausius relation T{sub h} dS-circumflex{sub h} = {delta} Q , where {delta}Q is the energy flux across the horizon and dS-circumflex is the entropy production term. Furthermore, the conditions for the generalized second law of thermodynamics to be preserved are established with the constraints of positive temperature and attractive gravity. We illustrate our results for some concrete models in this theory.
Beyond heat baths II: Framework for generalized thermodynamic resource theories
Nicole Yunger Halpern
2015-06-17T23:59:59.000Z
Thermodynamics, which describes vast systems, has been reconciled with small scales, relevant to single-molecule experiments, in resource theories. Resource theories have been used to model exchanges of energy and information. Recently, particle exchanges were modeled; and an umbrella family of thermodynamic resource theories was proposed to model diverse baths, interactions, and free energies. This paper motivates and details the family's structure and prospective applications. How to model electrochemical, gravitational, magnetic, and other thermodynamic systems is explained. Szilard's engine and Landauer's Principle are generalized, as resourcefulness is shown to be convertible not only between information and gravitational energy, but also among diverse degrees of freedom. Extensive variables are associated with quantum operators that might fail to commute, introducing extra nonclassicality into thermodynamic resource theories. This generalization expands the theories' potential for modeling realistic systems with which small-scale statistical mechanics might be tested experimentally.
Thermodynamic Database for Rare Earth Elements Recycling Process...
Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)
Thermodynamic Database for Rare Earth Elements Recycling Process: Energetics of the REE-X Systems (XA;, Mg, Zn, Si, Sn, Mn, Pb, Fe, Co, Ni) Apr 17 2015 11:00 AM - 12:00 PM In-Ho...
Fermionic Molecular Dynamics for nuclear dynamics and thermodynamics
K. H. O. Hasnaoui; Ph. Chomaz; F. Gulminelli
2008-12-02T23:59:59.000Z
A new Fermionic Molecular Dynamics (FMD) model based on a Skyrme functional is proposed in this paper. After introducing the basic formalism, some first applications to nuclear structure and nuclear thermodynamics are presented
Gravitation and Thermodynamics: The Einstein Equation of State Revisited
Jarmo Makela; Ari Peltola
2008-08-19T23:59:59.000Z
We perform an analysis where Einstein's field equation is derived by means of very simple thermodynamical arguments. Our derivation is based on a consideration of the properties of a very small, spacelike two-plane in a uniformly accelerating motion.
Mechanical and Industrial Engineering 230 Thermodynamics Course Syllabus
Rothstein, Jonathan
cycles Refrigeration and heat pump systems Final Exam (Date and time TBA) Suggested Reading Chapter 1Mechanical and Industrial Engineering 230 Fall 2009 Thermodynamics Course Syllabus Date Week 1 (9
Non-Equilibrium Thermodynamics of Self-Replicating Protocells
Harold Fellermann; Bernat Corominas-Murtra; Per Lyngs Hansen; John Hjort Ipsen; Ricard Solé; Steen Rasmussen
2015-03-16T23:59:59.000Z
We provide a non-equilibrium thermodynamic description of the life-cycle of a droplet based, chemically feasible, system of protocells. By coupling the protocells metabolic kinetics with its thermodynamics, we demonstrate how the system can be driven out of equilibrium to ensure protocell growth and replication. This coupling allows us to derive the equations of evolution and to rigorously demonstrate how growth and replication life-cycle can be understood as a non-equilibrium thermodynamic cycle. The process does not appeal to genetic information or inheritance, and is based only on non-equilibrium physics considerations. Our non-equilibrium thermodynamic description of simple, yet realistic, processes of protocell growth and replication, represents an advance in our physical understanding of a central biological phenomenon both in connection to the origin of life and for modern biology.
.H.H. Hoffmann, V.E. Fortov et al. Phys. Plasmas 9 (2002) 3651. #12;Critical Parameters of Some Metals I. Rosmej3, T. Schlegel1, A. Tauschwitz3 and D.H.H. Hoffmann1,3 Target: Solid (cryogenic) hydrogen
Quadractic Model of Thermodynamic States in SDF Explosions
Kuhl, A L; Khasainov, B
2007-05-04T23:59:59.000Z
We study the thermodynamic states encountered during Shock-Dispersed-Fuel (SDF) explosions. Such explosions contain up to six components: three fuels (PETN, TNT and Aluminum) and their products corresponding to stoichiometric combustion with air. We establish the loci in thermodynamic state space that correctly describes the behavior of the components. Results are fit with quadratic functions that serve as fast equations of state suitable for 3D numerical simulations of SDF explosions.
On the Quantum-Corrected Black Hole Thermodynamics
Kourosh Nozari; S. Hamid Mehdipour
2006-01-15T23:59:59.000Z
Bekenstein-Hawking Black hole thermodynamics should be corrected to incorporate quantum gravitational effects. Generalized Uncertainty Principle(GUP) provides a perturbational framework to perform such modifications. In this paper we consider the most general form of GUP to find black holes thermodynamics in microcanonical ensemble. Our calculation shows that there is no logarithmic pre-factor in perturbational expansion of entropy. This feature will solve part of controversies in literatures regarding existence or vanishing of this pre-factor.
Calculation of the compressibility factor and thermodynamic properties for methane
Dowling, Dennis William
1966-01-01T23:59:59.000Z
of Saturated Vapor Volumes Reported by Bloomer and Parent (5) and Those Calculated in This Work Thermodynamic Properties Calculated by Use of Berlin Equation Thermodynamic Properties Calculated by Use of Benedict-Webb-Rubin Equation 35 36 39 40 48..., and Smith (15), Gardoso (7), and Bloomer and Parent (5) have reported experimental vapor pressure data and values for the saturated liquid density. Cardoso (7) and Bloomer and Parent (5) have also reported values for saturated vapor densities. A critical...
Poker Cash Game: a Thermodynamic Description
Javarone, Marco Alberto
2015-01-01T23:59:59.000Z
Poker is one of the most popular card games, whose rational investigation represents also one of the major challenges in several scientific areas, spanning from information theory and artificial intelligence to game theory and statistical physics. In principle, several variants of Poker can be identified, although all of them make use of money to make the challenge meaningful and, moreover, can be played in two different formats: tournament and cash game. An important issue when dealing with Poker is its classification, i.e., as a `skill game' or as gambling. Nowadays, its classification still represents an open question, having a long list of implications (e.g., legal and healthcare) that vary from country to country. In this study, we analyze Poker challenges, considering the cash game format, in terms of thermodynamics systems. Notably, we propose a framework to represent a cash game Poker challenge that, although based on a simplified scenario, allows both to obtain useful information for rounders (i.e., ...
Coal surface structure and thermodynamics. Final report
Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.
1994-05-01T23:59:59.000Z
Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.
Prediction of new thermodynamically stable aluminum oxides
Liu, Yue; Wang, Shengnan; Zhu, Qiang; Dong, Xiao; Kresse, Georg
2015-01-01T23:59:59.000Z
Recently, it has been shown that under pressure, unexpected and counterintuitive chemical compounds become stable. Laser shock experiments (A. Rode, unpublished) on alumina (Al2O3) have shown non-equilibrium decomposition of alumina with the formation of free Al and a mysterious transparent phase. Inspired by these observations, with have explored the possibility of the formation of new chemical compounds in the system Al-O. Using the variable-composition structure prediction algorithm USPEX, in addition to the well-known Al2O3, we have found two extraordinary compounds Al4O7 and AlO2 to be thermodynamically stable in the pressure range 330-443 GPa and above 332 GPa, respectively. Both of these compounds at the same time contain oxide O2- and peroxide O22- ions, and both are insulating. Peroxo-groups are responsible for gap states, which significantly reduce the electronic band gap of both Al4O7 and AlO2.
Thermodynamic functions of degenerate magnetized electron gas
Skobelev, V. V., E-mail: v.skobelev@inbox.ru [Moscow State Industrial University (Russian Federation)
2011-11-15T23:59:59.000Z
The Fermi energy, pressure, internal energy, entropy, and heat capacity of completely degenerate relativistic electron gas are calculated by numerical methods. It is shown that the maximum admissible magnetic field on the order of 10{sup 9} G in white dwarfs increases the pressure by a factor of 1.06 in the central region, where the electron concentration is {approx}10{sup 33} cm{sup -3}, while the equilibrium radius increases by approximately a factor of 1.03, which obviously cannot be observed experimentally. A magnetic field of {approx}10{sup 8} G or lower has no effect on the pressure and other thermodynamic functions. It is also shown that the contribution of degenerate electron gas to the total pressure in neutron stars is negligible compared to that of neutron gas even in magnetic fields with a maximum induction {approx}10{sup 17} G possible in neutron stars. The neutron beta-decay forbiddeness conditions in a superstrong magnetic field are formulated. It is assumed that small neutron stars have such magnetic fields and that pulsars with small periods are the most probable objects that can have super-strong magnetic fields.
Vitaly V. Bulatov; Yuriy V. Vladimirov
2012-06-26T23:59:59.000Z
In this paper, we consider fundamental problems of the dynamics of internal gravity waves. We present analytical and numerical algorithms for calculating the wave fields for a set of values of the parameters, as observed in the ocean. We show that our mathematical models can describe the wave dynamics of the Arctic Basin, taking into account the actual physical characteristics of sea water, topography of its floor, etc. The numerical and analytical results show that the internal gravity waves have a significant effect on underwater sea objects in the Arctic Basin.
Thermodynamics of Schwarzschild-de Sitter black hole: thermal stability of Nariai black hole
Yun Soo Myung
2008-03-28T23:59:59.000Z
We study thermodynamics of the Schwarzschild-de Sitter black hole in five dimensions by introducing two temperatures based on the standard and Bousso-Hawking normalizations. We use the first-law of thermodynamics to derive thermodynamic quantities. The two temperatures indicate that the Nariai black hole is thermodynamically unstable. However, it seems that black hole thermodynamics favors the standard normalization, and does not favor the Bousso-Hawking normalization.
Fundamentals of Delayed Coking Joint Industry Project
Michael Volk; Keith Wisecarver
2004-09-26T23:59:59.000Z
Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.
Fundamentals of Delayed Coking Joint Industry Project
Michael Volk; Keith Wisecarver
2003-09-26T23:59:59.000Z
Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.
Parameterizing the Deceleration Parameter
Diego Pavón; Ivan Duran; Sergio del Campo; Ramón Herrera
2012-12-31T23:59:59.000Z
We propose and constrain with the latest observational data three parameterizations of the deceleration parameter, valid from the matter era to the far future. They are well behaved and do not diverge at any redshift. On the other hand, they are model independent in the sense that in constructing them the only assumption made was that the Universe is homogeneous and isotropic at large scales.
Fundamentals of Delayed Coking Joint Industry Project
Michael Volk Jr; Keith Wisecarver
2005-10-01T23:59:59.000Z
Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c
Microscale combustion: Technology development and fundamental research Yiguang Ju a
Ju, Yiguang
of micro-thrusters, micro internal combustion engines, and micro chemical reactors summarized. ThirdlyReview Microscale combustion: Technology development and fundamental research Yiguang Ju a , Kaoru Maruta b,* a Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ
Physics 122 Fundamentals of Physics II Syllabus for Fall 2012
Lathrop, Daniel P.
Physics 122 Â Fundamentals of Physics II Syllabus for Fall 2012 Course description The second)-405-4993 Office hours : TBD Website http://elms.umd.edu The syllabus and schedule can be also found at: http
3.012 Fundamentals of Materials Science, Fall 2003
Marzari, Nicola
This subject describes the fundamentals of bonding, energetics, and structure that underpin materials science. From electrons to silicon to DNA: the role of electronic bonding in determining the energy, structure, and ...
Nuclear Facility Safety Basis Fundamentals Self-Study Guide ...
Broader source: Energy.gov (indexed) [DOE]
Oak Ridge Operations Office Nuclear Facility Safety Basis Fundamentals Self-Study Guide Fulfills ORO Safety Basis Competency 1, 2 (Part 1), or 7 (Part 1) November 2002 Nuclear...
Fundamental Scratch Behavior of Styrene-Acrylonitrile Random Copolymers
Browning, Robert Lee
2011-10-21T23:59:59.000Z
The present study employs a standardized progressive load scratch test (ASTM D7027/ISO 19252) to investigate the fundamental physical and mechanistic origins of scratch deformation in styrene-acrylonitrile (SAN) random copolymers. Previous findings...
The fundamental theorem of Galois theory Definition 1. A polynomial ...
2011-11-14T23:59:59.000Z
The fundamental theorem of Galois theory. Definition 1. A polynomial in K[X] (K a field) is separable if it has no multiple roots in any field containing K. An ...
The fundamental properties of current controlled current source amplifiers
Terry, Michael Buford
1978-01-01T23:59:59.000Z
The thesis studies the fundamental properties of current controlled current source (CCCS) amplifiers for use in a wide bandwidth voltage gain application. Theoretical expressions are derived which describe the p'erformance of the CCCS in terms of circuit... of this research was to conduct a theoretical and experimental study of the fundamental properties of Current Controlled Current Source (CCCS) amplifiers. Of particular interest was the bandwidth independence on the closed loop voltage gain of the CCCS used...
DOE Fundamentals Handbook: Instrumentation and Control, Volume 2
Not Available
1992-06-01T23:59:59.000Z
The Instrumentation and Control Fundamentals Handbook personnel, and the technical staff facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of instrumentation and control systems. The handbook includes information on temperature, pressure, flow, and level detection systems; position indication systems; process control systems; and radiation detection principles. This information will provide personnel with an understanding of the basic operation of various types of DOE nuclear facility instrumentation and control systems.
DOE Fundamentals Handbook: Instrumentation and Control, Volume 1
Not Available
1992-06-01T23:59:59.000Z
The Instrumentation and Control Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of instrumentation and control systems. The handbook includes information on temperature, pressure, flow, and level detection systems; position indication systems; process control systems; and radiation detection principles. This information will provide personnel with an understanding of the basic operation of various types of DOE nuclear facility instrumentation and control systems.
Linear harmonic analysis of Stirling engine thermodynamics
Chen, N.C.J.; Griffin, F.P.; West, C.D.
1984-08-01T23:59:59.000Z
The analysis involves linearization of the pressure waveform and represents each term in the conservation equations by a truncated Fourier series, including enthalpy flux discontinuity. Second-Law analysis is presented of four important loss mechanisms that result from adiabatic cylinders, transient heat transfer in semiadiabatic cylinders, pressure drop through the heat exchangers, and gas leakage from the compression space. The four loss mechanisms, all leading to efficiency reduction below the Carnot level, are characterized by irreversible thermodynamic processes that occur when heat is transferred across a finite temperature difference; when gases at two different temperatures are mixed; or when there is a mass flow through a pressure difference. The allocation of each individual loss mechanism is derived precisely in terms of entropy production but evaluated by use of pressure, temperature, and mass oscillations calculated from the linear harmonic approximation. When the theory is applied to an engine of Sunpower's RE-1000 dimensions, it reveals clearly that the adiabatic loss (due to temperature fluctuations in the cylinders) consists of two components: gas mixing and heat transfer across a temperature difference. The theory further shows that the adiabatic effect is more important than the transient heat transfer loss if the gas-to-cylinder heat transfer rate is small (i.e., nearly adiabatic conditions); the reverse is true for intermediate heat transfer rates; and both losses vanish at very high heat transfer rates. In addition, entropy analyses of pressure drop and mass leakage for isothermal cylinders shed some light on coupling between the different individual loss mechanisms.
Li, J.; Zhou, L.; Pan, K.; Jiang, D. [Xi`an Jiaotong Univ. (China); Chae, J.
1995-12-31T23:59:59.000Z
Heat transfer losses in the swirl chamber, throttling losses at the connecting passage and combustion delay in the main chamber are considered as the three factors influencing the thermal efficiency of IDI diesel engines. This paper suggests a thermodynamic model, in which three idealized diesel engines including no passage throttling engine, adiabatic diesel engine for swirl chamber and DI diesel engine are assumed to isolate heat transfer losses, throttling losses and combustion delay in IDI diesel engines. The Second Law analysis is carried out by the thermodynamic state parameters calculated by the cycle simulation of engines based on the First Law. The effects of heat transfer losses in the swirl chamber, throttling losses at the connecting passage and combustion delay in the main chamber on the irreversibilities and availability losses during the engine cycle are analyzed in detail. The relative influences among the three losses are also investigated. The results of First Law analysis indicate that heat transfer losses in the swirl chamber at low load conditions and combustion delay in the main chamber at full load conditions are the main factors impairing the fuel economy of IDI diesel engines. However, the results of further analysis of the Second Law indicate that passage throttling is a key factor affecting the fuel economy of IDI diesel engines at full load conditions. On the basis of thermodynamic analysis, a modified design of connecting passage is made on a single cylinder IDI diesel engine.The modified connecting passage has different inclination angles at both sides of the passage, and reduces throttling losses at the connecting passage, shortens combustion delay and combustion period in the main chamber, and hence reduces the engine fuel consumption and smoke emission.
Force Field Parameter Estimation of Functional Perfluoropolyether Lubricants
Smith, R.; Chung, P.S.; Steckel, J; Jhon, M.S.; Biegler, L.T.
2011-01-01T23:59:59.000Z
The head disk interface in a hard disk drive can be considered to be one of the hierarchical multiscale systems, which require the hybridization of multiscale modeling methods with coarse-graining procedure. However, the fundamental force field parameters are required to enable the coarse-graining procedure from atomistic/molecular scale to mesoscale models. In this paper, we investigate beyond molecular level and perform ab initio calculations to obtain the force field parameters. Intramolecular force field parameters for Zdol and Ztetraol were evaluated with truncated PFPE molecules to allow for feasible quantum calculations while still maintaining the characteristic chemical structure of the end groups. Using the harmonic approximation to the bond and angle potentials, the parameters were derived from the Hessian matrix, and the dihedral force constants are fit to the torsional energy profiles generated by a series of constrained molecular geometry optimization.
Force Field Parameter Estimation of Functional Perfluoropolyether Lubricants
Smith, R.; Chung, P.S.; Steckel, J; Jhon, M.S.; Biegler, L.T.
2011-01-01T23:59:59.000Z
The head disk interface in hard disk drive can be considered one of the hierarchical multiscale systems, which require the hybridization of multiscale modeling methods with coarse-graining procedure. However, the fundamental force field parameters are required to enable the coarse-graining procedure from atomistic/molecular scale to mesoscale models .In this paper, we investigate beyond molecular level and perform ab-initio calculations to obtain the force field parameters. Intramolecular force field parameters for the Zdol and Ztetraol were evaluated with truncated PFPE molecules to allow for feasible quantum calculations while still maintaining the characteristic chemical structure of the end groups. Using the harmonic approximation to the bond and angle potentials, the parameters were derived from the Hessian matrix, and the dihedral force constants are fit to the torsional energy profiles generated by a series of constrained molecular geometry optimization.
Thermodynamics and quark susceptibilities: a Monte-Carlo approach to the PNJL model
M. Cristoforetti; T. Hell; B. Klein; W. Weise
2010-02-11T23:59:59.000Z
The Monte-Carlo method is applied to the Polyakov-loop extended Nambu--Jona-Lasinio (PNJL) model. This leads beyond the saddle-point approximation in a mean-field calculation and introduces fluctuations around the mean fields. We study the impact of fluctuations on the thermodynamics of the model, both in the case of pure gauge theory and including two quark flavors. In the two-flavor case, we calculate the second-order Taylor expansion coefficients of the thermodynamic grand canonical partition function with respect to the quark chemical potential and present a comparison with extrapolations from lattice QCD. We show that the introduction of fluctuations produces only small changes in the behavior of the order parameters for chiral symmetry restoration and the deconfinement transition. On the other hand, we find that fluctuations are necessary in order to reproduce lattice data for the flavor non-diagonal quark susceptibilities. Of particular importance are pion fields, the contribution of which is strictly zero in the saddle point approximation.
Nodal gap structure and order parameter symmetry of the unconventional superconductor UPt 3
DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)
Gannon, W. J.; Halperin, W. P.; Rastovski, C.; Schlesinger, K. J.; Hlevyack, J.; Eskildsen, M. R.; Vorontsov, A. B.; Gavilano, J.; Gasser, U.; Nagy, G.
2015-02-01T23:59:59.000Z
Spanning a broad range of physical systems, complex symmetry breaking is widely recognized as a hallmark of competing interactions. This is exemplified in superfluid 3He which has multiple thermodynamic phases with spin and orbital quantum numbers S = 1 and L = 1, that emerge on cooling from a nearly ferromagnetic Fermi liquid. The heavy fermion compound UPt3 exhibits similar behavior clearly manifest in its multiple superconducting phases. However, consensus as to its order parameter symmetry has remained elusive. Our small angle neutron scattering measurements indicate a linear temperature dependence of the London penetration depth characteristic of nodal structure ofmore »the order parameter. Our theoretical analysis is consistent with assignment of its symmetry to an L = 3 odd parity state for which one of the three thermodynamic phases in non-zero magnetic field is chiral.« less
The energy balancing parameter
Walton R. Gutierrez
2011-05-10T23:59:59.000Z
A parameter method is introduced in order to estimate the relationship among the various variables of a system in equilibrium, where the potential energy functions are incompletely known or the quantum mechanical calculations very difficult. No formal proof of the method is given; instead, a sufficient number of valuable examples are shown to make the case for the method's usefulness in classical and quantum systems. The mathematical methods required are quite elementary: basic algebra and minimization of power functions. This method blends advantageously with a simple but powerful approximate method for quantum mechanics, sidestepping entirely formal operators and differential equations. It is applied to the derivation of various well-known results involving centrally symmetric potentials for a quantum particle such as the hydrogen-like atom, the elastic potential and other cases of interest. The same formulas provide estimates for previously unsolved cases. PACS: 03.65.-w 30.00.00
Work extraction and thermodynamics for individual quantum systems
Paul Skrzypczyk; Anthony J. Short; Sandu Popescu
2014-09-26T23:59:59.000Z
Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage device (essentially a `weight' that can be raised or lowered). We prove that the second law of thermodynamics holds in our framework, and give a simple protocol to extract the optimal amount of work from the system, equal to its change in free energy. Our results apply to any quantum system in an arbitrary initial state, in particular including non-equilibrium situations. The optimal protocol is essentially reversible, similar to classical Carnot cycles, and indeed, we show that it can be used it to construct a quantum Carnot engine.
Thermodynamics of viscous dark energy in an RSII braneworld
M. R. Setare; A. Sheykhi
2011-03-05T23:59:59.000Z
We show that for an RSII braneworld filled with interacting viscous dark energy and dark matter, one can always rewrite the Friedmann equation in the form of the first law of thermodynamics, $dE=T_hdS_h+WdV$, at apparent horizon. In addition, the generalized second law of thermodynamics can fulfilled in a region enclosed by the apparent horizon on the brane for both constant and time variable 5-dynamical Newton's constant $G_5$. These results hold regardless of the specific form of the dark energy. Our study further support that in an accelerating universe with spatial curvature, the apparent horizon is a physical boundary from the thermodynamical point of view.
Quantum coherence, time-translation symmetry and thermodynamics
Matteo Lostaglio; Kamil Korzekwa; David Jennings; Terry Rudolph
2015-04-13T23:59:59.000Z
The first law of thermodynamics imposes not just a constraint on the energy-content of systems in extreme quantum regimes, but also symmetry-constraints related to the thermodynamic processing of quantum coherence. We show that this thermodynamic symmetry decomposes any quantum state into mode operators that quantify the coherence present in the state. We then establish general upper and lower bounds for the evolution of quantum coherence under arbitrary thermal operations, valid for any temperature. We identify primitive coherence manipulations and show that the transfer of coherence between energy levels manifests irreversibility not captured by free energy. Moreover, the recently developed thermo-majorization relations on block-diagonal quantum states are observed to be special cases of this symmetry analysis.
Quantum Collapse and the Second Law of Thermodynamics
Sahand Hormoz
2012-08-11T23:59:59.000Z
A heat engine undergoes a cyclic operation while in equilibrium with the net result of conversion of heat into work. Quantum effects such as superposition of states can improve an engine's efficiency by breaking detailed balance, but this improvement comes at a cost due to excess entropy generated from collapse of superpositions on measurement. We quantify these competing facets for a quantum ratchet comprised of an ensemble of pairs of interacting two-level atoms. We suggest that the measurement postulate of quantum mechanics is intricately connected to the second law of thermodynamics. More precisely, if quantum collapse is not inherently random, then the second law of thermodynamics can be violated. Our results challenge the conventional approach of simply quantifying quantum correlations as a thermodynamic work deficit.