National Library of Energy BETA

Sample records for fundamental thermodynamic parameters

  1. Adsorption Thermodynamics and Intrinsic Activation Parameters...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adsorption Thermodynamics and Intrinsic Activation Parameters for Monomolecular Cracking of n-Alkanes on Bronsted Acid Sites in Zeolites Previous Next List Amber Janda, Bess...

  2. FUNDAMENTAL PARAMETERS AND CHEMICAL COMPOSITION OF ARCTURUS

    SciTech Connect (OSTI)

    Ramirez, I. [Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Allende Prieto, C., E-mail: ivan@obs.carnegiescience.edu, E-mail: callende@iac.es [Instituto de Astrofisica de Canarias, 38205 La Laguna, Tenerife (Spain)

    2011-12-20

    We derive a self-consistent set of atmospheric parameters and abundances of 17 elements for the red giant star Arcturus: T{sub eff} = 4286 {+-} 30 K, log g = 1.66 {+-} 0.05, and [Fe/H] = -0.52 {+-} 0.04. The effective temperature was determined using model atmosphere fits to the observed spectral energy distribution from the blue to the mid-infrared (0.44 to 10 {mu}m). The surface gravity was calculated using the trigonometric parallax of the star and stellar evolution models. A differential abundance analysis relative to the solar spectrum allowed us to derive iron abundances from equivalent width measurements of 37 Fe I and 9 Fe II lines, unblended in the spectra of both Arcturus and the Sun; the [Fe/H] value adopted is derived from Fe I lines. We also determine the mass, radius, and age of Arcturus: M = 1.08 {+-} 0.06 M{sub Sun }, R = 25.4 {+-} 0.2 R{sub Sun }, and {tau} = 7.1{sup +1.5}{sub -1.2} Gyr. Finally, abundances of the following elements are measured from an equivalent width analysis of atomic features: C, O, Na, Mg, Al, Si, K, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, and Zn. We find the chemical composition of Arcturus typical of that of a local thick-disk star, consistent with its kinematics.

  3. Fundamental Thermodynamics of Actinide-Bearing Mineral Waste Forms - Final Report

    SciTech Connect (OSTI)

    Williamson, Mark A.; Ebbinghaus, Bartley B.; Navrotsky, Alexandra

    2001-03-01

    The end of the Cold War raised the need for the technical community to be concerned with the disposition of excess nuclear weapon material. The plutonium will either be converted into mixed-oxide fuel for use in nuclear reactors or immobilized in glass or ceramic waste forms and placed in a repository. The stability and behavior of plutonium in the ceramic materials as well as the phase behavior and stability of the ceramic material in the environment is not well established. In order to provide technically sound solutions to these issues, thermodynamic data are essential in developing an understanding of the chemistry and phase equilibria of the actinide-bearing mineral waste form materials proposed as immobilization matrices. Mineral materials of interest include zircon, zirconolite, and pyrochlore. High temperature solution calorimetry is one of the most powerful techniques, sometimes the only technique, for providing the fundamental thermodynamic data needed to establish optimum material fabrication parameters, and more importantly understand and predict the behavior of the mineral materials in the environment. The purpose of this project is to experimentally determine the enthalpy of formation of actinide orthosilicates, the enthalpies of formation of actinide substituted zirconolite and pyrochlore, and develop an understanding of the bonding characteristics and stabilities of these materials.

  4. DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.

  5. DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 1

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.

  6. DOE Fundamentals Handbook: Thermodynamics, Heat Transfer, and Fluid Flow, Volume 3

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Thermodynamics, Heat Transfer, and Fluid Flow Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the thermal sciences. The handbook includes information on thermodynamics and the properties of fluids; the three modes of heat transfer -- conduction, convection, and radiation; and fluid flow, and the energy relationships in fluid systems. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility fluid systems.

  7. Synthesis, characterization, and thermodynamic parameters of vanadium dioxide

    SciTech Connect (OSTI)

    Qi Ji [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China); Department of Chemical Engineering, Dalian Life Science College, Dalian Nationalities University, 18 Laohe West Road, Dalian 116600 (China); Ning Guiling [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)], E-mail: ninggl@dlut.edu.cn; Lin Yuan [Department of Chemical Engineering of Material, School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012 (China)

    2008-08-04

    A novel process was developed for synthesizing pure thermochromic vanadium dioxide (VO{sub 2}) by thermal reduction of vanadium pentoxide (V{sub 2}O{sub 5}) in ammonia gas. The process of thermal reduction of V{sub 2}O{sub 5} was optimized by both experiments and modeling of thermodynamic parameters. The product VO{sub 2} was characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectrometry (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TG), and differential scanning calorimetry (DSC). The experimental results indicated that pure thermochromic VO{sub 2} crystal particles were successfully synthesized. The phase transition temperature of the VO{sub 2} is approximately 342.6 K and the enthalpy of phase transition is 44.90 J/g.

  8. An electromagnetic and thermodynamic lumped parameter model of an explosively driven regenerative magnetohydrodynamic generator

    SciTech Connect (OSTI)

    Morrison, J.L.

    1992-12-01

    The objective of this research is to develop a simple, yet accurate, lumped parameter mathematical model for an explosively driven magnetohydrodynamic generator that can predict the pulse power variables of voltage and current from startup through regenerative operation. The inputs to the model will be the plasma properties entering the generator as predicted by the explosive shock model of Reference [1]. The strategy used was to simplify electromagnetic and thermodynamic three dimensional effects into a zero dimensional model. The model will provide a convenient tool for researchers to optimize designs to be used in pulse power applications. The model is validated using experimental data of Reference [1]. An overview of the operation of the explosively driven generator is first presented. Then a simplified electrical circuit model that describes basic performance of the device is developed. Then a lumped parameter model that incorporates the coupled electromagnetic and thermodynamic effects that govern generator performance is described and developed. The model is based on fundamental physical principles and parameters that were either obtained directly from design data or estimated from experimental data. The model was used to obtain parameter sensitivities and predict beyond the limits observed in the experiments to the levels desired by the potential Department of Defense sponsors. The model identifies process limitations that provide direction for future research.

  9. Fundamental

    Office of Scientific and Technical Information (OSTI)

    TID-267 11-P2 '4 ' Fundamental Aspects of Nuclear Reactor Fuel Elements Solutions to Problems Donald R. Olander Department - of Nuclear Engineering University of Cacfornia, ...

  10. DOE-HDBK-1012/1-92; DOE Fundamentals Handbook Thermodynamics, Heat Transfer, and Fluid Flow Volume 1 of 3

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1-92 JUNE 1992 DOE FUNDAMENTALS HANDBOOK THERMODYNAMICS, HEAT TRANSFER, AND FLUID FLOW Volume 1 of 3 U.S. Department of Energy FSC-6910 Washington, D.C. 20585 Distribution Statement A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information. P. O. Box 62, Oak Ridge, TN 37831; (615) 576-8401. Available to the public from the National

  11. DOE-HDBK-1012/2-92; DOE Fundamentals Handbook Thermodynamics, Heat Transfer, and Fluid Flow Volume 2 of 3

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2-92 JUNE 1992 DOE FUNDAMENTALS HANDBOOK THERMODYNAMICS, HEAT TRANSFER, AND FLUID FLOW Volume 2 of 3 U.S. Department of Energy FSC-6910 Washington, D.C. 20585 Distribution Statement A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information. P. O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576- 8401. FTS 626-8401.

  12. DOE-HDBK-1012/3-92; DOE Fundamentals Handbook Thermodynamics, Heat Transfer, and Fluid Flow Volume 3 of 3

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3-92 JUNE 1992 DOE FUNDAMENTALS HANDBOOK THERMODYNAMICS, HEAT TRANSFER, AND FLUID FLOW Volume 3 of 3 U.S. Department of Energy FSC-6910 Washington, D.C. 20585 Distribution Statement A. Approved for public release; distribution is unlimited. This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Technical Information. P. O. Box 62, Oak Ridge, TN 37831; prices available from (615) 576- 8401. FTS 626-8401.

  13. A MACHINE-LEARNING METHOD TO INFER FUNDAMENTAL STELLAR PARAMETERS FROM PHOTOMETRIC LIGHT CURVES

    SciTech Connect (OSTI)

    Miller, A. A.; Bloom, J. S.; Richards, J. W.; Starr, D. L.; Lee, Y. S.; Butler, N. R.; Tokarz, S.; Smith, N.; Eisner, J. A.

    2015-01-10

    A fundamental challenge for wide-field imaging surveys is obtaining follow-up spectroscopic observations: there are >10{sup 9} photometrically cataloged sources, yet modern spectroscopic surveys are limited to ∼few× 10{sup 6} targets. As we approach the Large Synoptic Survey Telescope era, new algorithmic solutions are required to cope with the data deluge. Here we report the development of a machine-learning framework capable of inferring fundamental stellar parameters (T {sub eff}, log g, and [Fe/H]) using photometric-brightness variations and color alone. A training set is constructed from a systematic spectroscopic survey of variables with Hectospec/Multi-Mirror Telescope. In sum, the training set includes ∼9000 spectra, for which stellar parameters are measured using the SEGUE Stellar Parameters Pipeline (SSPP). We employed the random forest algorithm to perform a non-parametric regression that predicts T {sub eff}, log g, and [Fe/H] from photometric time-domain observations. Our final optimized model produces a cross-validated rms error (RMSE) of 165 K, 0.39 dex, and 0.33 dex for T {sub eff}, log g, and [Fe/H], respectively. Examining the subset of sources for which the SSPP measurements are most reliable, the RMSE reduces to 125 K, 0.37 dex, and 0.27 dex, respectively, comparable to what is achievable via low-resolution spectroscopy. For variable stars this represents a ≈12%-20% improvement in RMSE relative to models trained with single-epoch photometric colors. As an application of our method, we estimate stellar parameters for ∼54,000 known variables. We argue that this method may convert photometric time-domain surveys into pseudo-spectrographic engines, enabling the construction of extremely detailed maps of the Milky Way, its structure, and history.

  14. Gradient Theory simulations of pure fluid interfaces using a generalized expression for influence parameters and a Helmholtz energy equation of state for fundamentally consistent two-phase calculations

    SciTech Connect (OSTI)

    Dahms, Rainer N.

    2014-12-31

    The fidelity of Gradient Theory simulations depends on the accuracy of saturation properties and influence parameters, and require equations of state (EoS) which exhibit a fundamentally consistent behavior in the two-phase regime. Widely applied multi-parameter EoS, however, are generally invalid inside this region. Hence, they may not be fully suitable for application in concert with Gradient Theory despite their ability to accurately predict saturation properties. The commonly assumed temperature-dependence of pure component influence parameters usually restricts their validity to subcritical temperature regimes. This may distort predictions for general multi-component interfaces where temperatures often exceed the critical temperature of vapor phase components. Then, the calculation of influence parameters is not well defined. In this paper, one of the first studies is presented in which Gradient Theory is combined with a next-generation Helmholtz energy EoS which facilitates fundamentally consistent calculations over the entire two-phase regime. Illustrated on pentafluoroethane as an example, reference simulations using this method are performed. They demonstrate the significance of such high-accuracy and fundamentally consistent calculations for the computation of interfacial properties. These reference simulations are compared to corresponding results from cubic PR EoS, widely-applied in combination with Gradient Theory, and mBWR EoS. The analysis reveals that neither of those two methods succeeds to consistently capture the qualitative distribution of obtained key thermodynamic properties in Gradient Theory. Furthermore, a generalized expression of the pure component influence parameter is presented. This development is informed by its fundamental definition based on the direct correlation function of the homogeneous fluid and by presented high-fidelity simulations of interfacial density profiles. As a result, the new model preserves the accuracy of previous

  15. Gradient Theory simulations of pure fluid interfaces using a generalized expression for influence parameters and a Helmholtz energy equation of state for fundamentally consistent two-phase calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dahms, Rainer N.

    2014-12-31

    The fidelity of Gradient Theory simulations depends on the accuracy of saturation properties and influence parameters, and require equations of state (EoS) which exhibit a fundamentally consistent behavior in the two-phase regime. Widely applied multi-parameter EoS, however, are generally invalid inside this region. Hence, they may not be fully suitable for application in concert with Gradient Theory despite their ability to accurately predict saturation properties. The commonly assumed temperature-dependence of pure component influence parameters usually restricts their validity to subcritical temperature regimes. This may distort predictions for general multi-component interfaces where temperatures often exceed the critical temperature of vapor phasemore » components. Then, the calculation of influence parameters is not well defined. In this paper, one of the first studies is presented in which Gradient Theory is combined with a next-generation Helmholtz energy EoS which facilitates fundamentally consistent calculations over the entire two-phase regime. Illustrated on pentafluoroethane as an example, reference simulations using this method are performed. They demonstrate the significance of such high-accuracy and fundamentally consistent calculations for the computation of interfacial properties. These reference simulations are compared to corresponding results from cubic PR EoS, widely-applied in combination with Gradient Theory, and mBWR EoS. The analysis reveals that neither of those two methods succeeds to consistently capture the qualitative distribution of obtained key thermodynamic properties in Gradient Theory. Furthermore, a generalized expression of the pure component influence parameter is presented. This development is informed by its fundamental definition based on the direct correlation function of the homogeneous fluid and by presented high-fidelity simulations of interfacial density profiles. As a result, the new model preserves the accuracy of

  16. Thermodynamic Metrics and Optimal Paths

    SciTech Connect (OSTI)

    Sivak, David; Crooks, Gavin

    2012-05-08

    A fundamental problem in modern thermodynamics is how a molecular-scale machine performs useful work, while operating away from thermal equilibrium without excessive dissipation. To this end, we derive a friction tensor that induces a Riemannian manifold on the space of thermodynamic states. Within the linear-response regime, this metric structure controls the dissipation of finite-time transformations, and bestows optimal protocols with many useful properties. We discuss the connection to the existing thermodynamic length formalism, and demonstrate the utility of this metric by solving for optimal control parameter protocols in a simple nonequilibrium model.

  17. On equivalence of high temperature series expansion and coupling parameter series expansion in thermodynamic perturbation theory of fluids

    SciTech Connect (OSTI)

    Sai Venkata Ramana, A.

    2014-04-21

    The coupling parameter series expansion and the high temperature series expansion in the thermodynamic perturbation theory of fluids are shown to be equivalent if the interaction potential is pairwise additive. As a consequence, for the class of fluids with the potential having a hardcore repulsion, if the hard-sphere fluid is chosen as reference system, the terms of coupling parameter series expansion for radial distribution function, direct correlation function, and Helmholtz free energy follow a scaling law with temperature. The scaling law is confirmed by application to square-well fluids.

  18. Electrochemical thermodynamic measurement system

    DOE Patents [OSTI]

    Reynier, Yvan; Yazami, Rachid; Fultz, Brent T.

    2009-09-29

    The present invention provides systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and electrochemical energy storage and conversion systems. Systems and methods of the present invention are configured for simultaneously collecting a suite of measurements characterizing a plurality of interconnected electrochemical and thermodynamic parameters relating to the electrode reaction state of advancement, voltage and temperature. Enhanced sensitivity provided by the present methods and systems combined with measurement conditions that reflect thermodynamically stabilized electrode conditions allow very accurate measurement of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and electrochemical systems, such as the energy, power density, current rate and the cycle life of an electrochemical cell.

  19. Precision Plutonium Thermodynamics (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    This presentation discusses some of the fundamental characteristics of a solid and how they can be used to observe thermodynamic changes. Authors: Migliori, Albert 1 + Show ...

  20. Actinide Thermodynamics at Elevated Temperatures

    SciTech Connect (OSTI)

    Friese, Judah I.; Rao, Linfeng; Xia, Yuanxian; Bachelor, Paula P.; Tian, Guoxin

    2007-11-16

    The postclosure chemical environment in the proposed Yucca Mountain repository is expected to experience elevated temperatures. Predicting migration of actinides is possible if sufficient, reliable thermodynamic data on hydrolysis and complexation are available for these temperatures. Data are scarce and scattered for 25 degrees C, and nonexistent for elevated temperatures. This collaborative project between LBNL and PNNL collects thermodynamic data at elevated temperatures on actinide complexes with inorganic ligands that may be present in Yucca Mountain. The ligands include hydroxide, fluoride, sulfate, phosphate and carbonate. Thermodynamic parameters of complexation, including stability constants, enthalpy, entropy and heat capacity of complexation, are measured with a variety of techniques including solvent extraction, potentiometry, spectrophotometry and calorimetry

  1. Exact solution of the thermodynamics and size parameters of a polymer confined to a lattice of finite size: Large chain limit

    SciTech Connect (OSTI)

    Snyder, Chad R. Guttman, Charles M.; Di Marzio, Edmund A.

    2014-01-21

    We extend the exact solutions of the Di Marzio-Rubin matrix method for the thermodynamic properties, including chain density, of a linear polymer molecule confined to walk on a lattice of finite size. Our extensions enable (a) the use of higher dimensions (explicit 2D and 3D lattices), (b) lattice boundaries of arbitrary shape, and (c) the flexibility to allow each monomer to have its own energy of attraction for each lattice site. In the case of the large chain limit, we demonstrate how periodic boundary conditions can also be employed to reduce computation time. Advantages to this method include easy definition of chemical and physical structure (or surface roughness) of the lattice and site-specific monomer-specific energetics, and straightforward relatively fast computations. We show the usefulness and ease of implementation of this extension by examining the effect of energy variation along the lattice walls of an infinite rectangular cylinder with the idea of studying the changes in properties caused by chemical inhomogeneities on the surface of the box. Herein, we look particularly at the polymer density profile as a function of temperature in the confined region for very long polymers. One particularly striking result is the shift in the critical condition for adsorption due to surface energy inhomogeneities and the length scale of the inhomogeneities; an observation that could have important implications for polymer chromatography. Our method should have applications to both copolymers and biopolymers of arbitrary molar mass.

  2. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  3. Fundamentals of preparative and nonlinear chromatography

    SciTech Connect (OSTI)

    Guiochon, Georges A; Felinger, Attila; Katti, Anita; Shirazi, Dean G

    2006-02-01

    The second edition of Fundamentals of Preparative and Nonlinear Chromatography is devoted to the fundamentals of a new process of purification or extraction of chemicals or proteins widely used in the pharmaceutical industry and in preparative chromatography. This process permits the preparation of extremely pure compounds satisfying the requests of the US Food and Drug Administration. The book describes the fundamentals of thermodynamics, mass transfer kinetics, and flow through porous media that are relevant to chromatography. It presents the models used in chromatography and their solutions, discusses the applications made, describes the different processes used, their numerous applications, and the methods of optimization of the experimental conditions of this process.

  4. Thermodynamic States in Explosion Fields

    SciTech Connect (OSTI)

    Kuhl, A L

    2010-03-12

    We investigate the thermodynamic states occurring in explosion fields from condensed explosive charges. These states are often modeled with a Jones-Wilkins-Lee (JWL) function. However, the JWL function is not a Fundamental Equation of Thermodynamics, and therefore cannot give a complete specification of such states. We use the Cheetah code of Fried to study the loci of states of the expanded detonation products gases from C-4 charges, and their combustion products air. In the Le Chatelier Plane of specific-internal-energy versus temperature, these loci are fit with a Quadratic Model function u(T), which has been shown to be valid for T < 3,000 K and p < 1k-bar. This model is used to derive a Fundamental Equation u(v,s) for C-4. Given u(v,s), one can use Maxwell's Relations to derive all other thermodynamic functions, such as temperature: T(v,s), pressure: p(v,s), enthalpy: h(v,s), Gibbs free energy: g(v,s) and Helmholz free energy: f(v,s); these loci are displayed in figures for C-4. Such complete equations of state are needed for numerical simulations of blast waves from explosive charges, and their reflections from surfaces.

  5. HCCI/SCCI Fundamentals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HCCISCCI Fundamentals - Sandia Energy Energy Search Icon Sandia Home Locations ... Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ...

  6. Adsorption Thermodynamics and Intrinsic Activation Parameters...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    values of Hads-H+ and Sads-H+, agree well with values obtained independently from quantum mechanicsmolecular mechanics calculations. Application of our method of analysis...

  7. Fundamental Science Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fundamental Science Applications Fundamental Science Applications Supporing research to understand, predict and ultimately control matter and energy at the electronic, atomic, and molecular levels. Contact thumbnail of Business Development Executive Don Hickmott Business Development Executive Richard P. Feynman Center for Innovation (505) 667-8753 Email Fundamental Science Applications The DOE Basic Energy Science (BES) program supports research to understand, predict and ultimately control

  8. Thermodynamics of geothermal fluids

    SciTech Connect (OSTI)

    Rogers, P.S.Z.

    1981-03-01

    A model to predict the thermodynamic properties of geothermal brines, based on a minimum amount of experimental data on a few key systems, is tested. Volumetric properties of aqueous sodium chloride, taken from the literature, are represented by a parametric equation over the range 0 to 300{sup 0}C and 1 bar to 1 kbar. Density measurements at 20 bar needed to complete the volumetric description also are presented. The pressure dependence of activity and thermal properties, derived from the volumetric equation, can be used to complete an equation of state for sodium chloride solutions. A flow calorimeter, used to obtain heat capacity data at high temperatures and pressures, is described. Heat capacity measurements, from 30 to 200{sup 0}C and 1 bar to 200 bar, are used to derive values for the activity coefficient and other thermodynamic properties of sodium sulfate solutions as a function of temperature. Literature data on the solubility of gypsum in mixed electrolyte solutions have been used to evaluate model parameters for calculating gypsum solubility in seawater and natural brines. Predictions of strontium and barium sulfate solubility in seawater also are given.

  9. Thermodynamics: Frontiers and Foundations.

    Energy Science and Technology Software Center (OSTI)

    2009-07-27

    Version 00 Dr. J.D. Lewins has now released the following new book for free distribution: Thermodynamics: Frontiers and Foundations, Preface by Sir Alan Cottrell Introduction 1. Four-Square Foundations: The Laws of Thermodynamics 2. Maximum Entropy and Minimum Energy: The Master Functions and Equations 3. Ideal Gases and their Applications 4. Real Fluids and Some Applications 5. Van der Waals: A Model for Real Fluids 6. Surface Tension: Bubbles and Drops 7. Inert and Reactive Mixtures;more » An introduction to Chemical Thermodynamics 8. Radiation Thermodynamics: Solar Power Potential 9. Outposts of the Empire 10. A Glimpse into Statistical Thermodynamics Envoi« less

  10. Fundamental Mechanisms of Transient States in Materials Quantified by DTEM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geoffrey Campbell is the Principal Investigator for Fundamental Mechanisms of Transient States in Materials Quantified by DTEM. Fundamental Mechanisms of Transient States in Materials Quantified by DTEM Research We study the coupled dynamics of phase transformation nucleation and growth, microstructure, and thermodynamics in nanoscale systems evolving on nanosecond to microsecond time scales using time resolved in situ microscopy (and other) techniques. DTEM enables in situ characterization of

  11. CNEEC - TRG1: Nanoscale Control of Thermodynamic Potentials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TRG1: Nanoscale Control of Thermodynamic Potentials TRG1 Leaders: Bruce Clemens and David Goldhaber-Gordon Energy storage and conversion involve charge transport, charge storage and conversion of materials from one phase to another. At the nanometer regime, size can have a dramatic effect on these processes and properties. Our program develops fundamental understanding of the effect of size on thermodynamics, kinetic processes, electronic structure and charge transport. Material systems

  12. EWONAP Procurement Fundamentals

    Broader source: Energy.gov [DOE]

    HUD's Eastern Woodlands Office of Native American Programs in collaboration with the Seminole Tribe of Florida Native Learning Center invites you to attend the Procurement Fundamentals training instructed by Vince Franco, Compliance & Resource Development Director of the Native Learning Center in Atlanta, Georgia on September 8-9, 2014.

  13. Thermodynamic States in Explosion Fields

    SciTech Connect (OSTI)

    Kuhl, A L

    2009-10-16

    Here we investigate the thermodynamic states occurring in explosion fields from the detonation of condensed explosives in air. In typical applications, the pressure of expanded detonation products gases is modeled by a Jones-Wilkins-Lee (JWL) function: P{sub JWL} = f(v,s{sub CJ}); constants in that function are fit to cylinder test data. This function provides a specification of pressure as a function of specific volume, v, along the expansion isentrope (s = constant = s{sub CJ}) starting at the Chapman-Jouguet (CJ) state. However, the JWL function is not a fundamental equation of thermodynamics, and therefore gives an incomplete specification of states. For example, explosions inherently involve shock reflections from surfaces; this changes the entropy of the products, and in such situations the JWL function provides no information on the products states. In addition, most explosives are not oxygen balanced, so if hot detonation products mix with air, they after-burn, releasing the heat of reaction via a turbulent combustion process. This raises the temperature of explosion products cloud to the adiabatic flame temperature ({approx}3,000K). Again, the JWL function provides no information on the combustion products states.

  14. HCCI/SCCI Fundamentals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HCCI/SCCI Fundamentals - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  15. Fundamental experiments in velocimetry

    SciTech Connect (OSTI)

    Briggs, Matthew Ellsworth; Hull, Larry; Shinas, Michael

    2009-01-01

    One can understand what velocimetry does and does not measure by understanding a few fundamental experiments. Photon Doppler Velocimetry (PDV) is an interferometer that will produce fringe shifts when the length of one of the legs changes, so we might expect the fringes to change whenever the distance from the probe to the target changes. However, by making PDV measurements of tilted moving surfaces, we have shown that fringe shifts from diffuse surfaces are actually measured only from the changes caused by the component of velocity along the beam. This is an important simplification in the interpretation of PDV results, arising because surface roughness randomizes the scattered phases.

  16. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  17. Cyclic Thermodynamics with Open Flow

    SciTech Connect (OSTI)

    Reid, R.S.; Ward, W.C.; Swift, G.W.

    1998-05-01

    Some general features of a new class of thermodynamic device combining a thermodynamic cycle with the externally applied steady flow of an open thermodynamic process are discussed and experimentally demonstrated in the context of a thermoacoustic refrigerator. {copyright} {ital 1998} {ital The American Physical Society}

  18. Thermodynamic Evaluation of Low-GWP Refrigerants

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization Fluid Modeling Cycle Modeling Final Candidates Optimum Thermo Parameters Thermodynamic Evaluation of Low-GWP Refrigerants 2014 Building Technologies Office Peer Review Piotr A. Domanski National Institute of Standards and Technology piotr.domanski@nist.gov Project Summary Timeline: Start date: February 1, 2011 Planned end date: March 31, 2015 Key Milestones 1. Selection of top 20 candidate low-GWP fluids; Sep 30, 2014 2. Complete simulations of top 20 candidate fluids February 28,

  19. Methods for thermodynamic evaluation of battery state of health

    DOE Patents [OSTI]

    Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

    2013-05-21

    Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

  20. Handbook of heat transfer fundamentals

    SciTech Connect (OSTI)

    Rohsenow, W.M.; Hartnett, J.P.; Ganic, E.N.

    1985-01-01

    This handbook is on the fundamentals of heat transfer. It provides coverage on conduction, convection, and radiation and on thermophysical properties of materials.

  1. Fundamentals of gas measurement II

    SciTech Connect (OSTI)

    Smith, J.P.

    1995-12-01

    A knowledge of the Fundamentals of Gas Measurement is essential for all technicians and engineers that are called upon to perform gas volume calculations. These same people must have at least a working knowledge of the fundamentals to perform their everyday jobs including equipment calibrations, specific gravity tests, collecting gas samples, etc. To understand the fundamentals, one must be familiar with the definitions of the terms that are used in day-to- day gas measurement operations. They also must know how to convert some values from one quantity as measured to another quantity that is called for in the gas purchase or sales contracts or transportation agreements.

  2. Sandia Energy - HCCI/SCCI Engine Fundamentals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HCCISCCI Engine Fundamentals Home Transportation Energy Predictive Simulation of Engines Engine Combustion Automotive HCCISCCI Engine Fundamentals HCCISCCI Engine...

  3. Sandia Energy - HCCI/SCCI Engine Fundamentals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HCCISCCI Engine Fundamentals Home Transportation Energy Predictive Simulation of Engines Engine Combustion Heavy Duty HCCISCCI Engine Fundamentals HCCISCCI Engine...

  4. Tribal Energy NEPA Fundamentals Workshop

    Broader source: Energy.gov [DOE]

    The Tribal Energy NEPA Fundamentals Workshop is a three-day workshop for tribes to understand how to manage the National Environmental Policy Act (NEPA) process and implement the Council on...

  5. Thermodynamics and cement science

    SciTech Connect (OSTI)

    Damidot, D.; Lothenbach, B.; Herfort, D.; Glasser, F.P.

    2011-07-15

    Thermodynamics applied to cement science has proved to be very valuable. One of the most striking findings has been the extent to which the hydrate phases, with one conspicuous exception, achieve equilibrium. The important exception is the persistence of amorphous C-S-H which is metastable with respect to crystalline calcium silicate hydrates. Nevertheless C-S-H can be included in the scope of calculations. As a consequence, from comparison of calculation and experiment, it appears that kinetics is not necessarily an insuperable barrier to engineering the phase composition of a hydrated Portland cement. Also the sensitivity of the mineralogy of the AFm and AFt phase compositions to the presence of calcite and to temperature has been reported. This knowledge gives a powerful incentive to develop links between the mineralogy and engineering properties of hydrated cement paste and, of course, anticipates improvements in its performance leading to decreasing the environmental impacts of cement production.

  6. DOE fundamentals handbook: Chemistry. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  7. Adiabatic calorimeter: Fundamentals and application in thermal hazard evaluation

    SciTech Connect (OSTI)

    Yin, Fandong

    1995-12-31

    General equations of kinetics and heat of reaction for an ideal adiabatic calorimeter are developed from fundamental principles with an emphasis on elucidating the critical assumptions associated with these equations. Understanding of the assumptions is of critical importance for correctly applying the equations to an actual adiabatic calorimeter. Utilization of the equations without justifying the assumptions can lead to significant uncertainties in the thermodynamic and kinetic information acquired. In addition, the physical concept of adiabaticity is introduced and defined from the fundamental principles. Its difference and relationship with the thermal inertia ({Phi} factor) are further elucidated in details. Application of the adiabaticity to characterize the degree of achieving adiabatic conditions for both plant-scale reactors and bench-scale calorimeters is discussed. Scale-up of experimental data from the bench-scale adiabatic calorimeters to the plant-scale batch reactors is presented for simple as well as complex reaction systems. 12 refs., 2 figs., 6 tabs.

  8. Thermodynamic properties of indan: Experimental and computational...

    Office of Scientific and Technical Information (OSTI)

    Thermodynamic properties of indan: Experimental and computational results This content will become publicly available on March 13, 2018 Prev Next Title: Thermodynamic ...

  9. Practical Thermodynamic Quantities for Aqueous Vanadium- and...

    Office of Scientific and Technical Information (OSTI)

    Practical Thermodynamic Quantities for Aqueous Vanadium- and Iron-Based Flow Batteries. Citation Details In-Document Search Title: Practical Thermodynamic Quantities for Aqueous...

  10. Thermodynamical description of stationary, asymptotically flat solutions with conical singularities

    SciTech Connect (OSTI)

    Herdeiro, Carlos; Rebelo, Carmen; Radu, Eugen

    2010-05-15

    We examine the thermodynamical properties of a number of asymptotically flat, stationary (but not static) solutions having conical singularities, with both connected and nonconnected event horizons, using the thermodynamical description recently proposed in [C. Herdeiro, B. Kleihaus, J. Kunz, and E. Radu, Phys. Rev. D 81, 064013 (2010).]. The examples considered are the double-Kerr solution, the black ring rotating in either S{sup 2} or S{sup 1}, and the black Saturn, where the balance condition is not imposed for the latter two solutions. We show that not only the Bekenstein-Hawking area law is recovered from the thermodynamical description, but also the thermodynamical angular momentum is the Arnowitt-Deser-Misner angular momentum. We also analyze the thermodynamical stability and show that, for all these solutions, either the isothermal moment of inertia or the specific heat at constant angular momentum is negative, at any point in parameter space. Therefore, all these solutions are thermodynamically unstable in the grand canonical ensemble.

  11. CRC handbook of applied thermodynamics

    SciTech Connect (OSTI)

    Palmer, D.A. . Research and Development Dept.)

    1987-01-01

    This book feature an overview of the importance of physical properties and thermodynamics; and the use of thermodynamics to predict the extent of reaction in proposed new chemical combinations. The use of special types of data and prediction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalist with the types of data measured by each, methods for measuring equilibrium data, and thermodynamic concepts to carry out process optimization are also featured.

  12. Fundamentals of materials accounting for nuclear safeguards ...

    Office of Scientific and Technical Information (OSTI)

    Fundamentals of materials accounting for nuclear safeguards Citation Details In-Document Search Title: Fundamentals of materials accounting for nuclear safeguards You are ...

  13. Energy Literacy: Essential Principles and Fundamental Concepts...

    Energy Savers [EERE]

    Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy...

  14. Hydrogen Embrittlement Fundamentals, Modeling, and Experiment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamentals, Modeling, and Experiment Hydrogen Embrittlement Fundamentals, Modeling, and Experiment Embrittlement, under static load could be a result of the synergistic action of ...

  15. Energy Literacy: Essential Principles and Fundamental Concepts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy ...

  16. DOE Fundamentals Handbook: Classical Physics

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton`s Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.

  17. DOE Fundamentals Handbook: Classical Physics

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Classical Physics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of physical forces and their properties. The handbook includes information on the units used to measure physical properties; vectors, and how they are used to show the net effect of various forces; Newton's Laws of motion, and how to use these laws in force and motion applications; and the concepts of energy, work, and power, and how to measure and calculate the energy involved in various applications. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility systems and equipment.

  18. Fundamental neutron physics at LANSCE

    SciTech Connect (OSTI)

    Greene, G.

    1995-10-01

    Modern neutron sources and science share a common origin in mid-20th-century scientific investigations concerned with the study of the fundamental interactions between elementary particles. Since the time of that common origin, neutron science and the study of elementary particles have evolved into quite disparate disciplines. The neutron became recognized as a powerful tool for studying condensed matter with modern neutron sources being primarily used (and justified) as tools for neutron scattering and materials science research. The study of elementary particles has, of course, led to the development of rather different tools and is now dominated by activities performed at extremely high energies. Notwithstanding this trend, the study of fundamental interactions using neutrons has continued and remains a vigorous activity at many contemporary neutron sources. This research, like neutron scattering research, has benefited enormously by the development of modern high-flux neutron facilities. Future sources, particularly high-power spallation sources, offer exciting possibilities for continuing this research.

  19. Fundamental Interactions - Research - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fundamental Interactions Production of 46V with MARS. Energy loss versus position on Y axis. The Standard Model, which unifies the strong, electromagnetic and weak forces, has been remarkably successful in describing the interactions of quarks and leptons. However, the model is incomplete, and it is the goal of this research program to sensitively probe its limits. Though in most cases we use the nucleus as a micro-laboratory for testing the Standard Model, the implications of the results extend

  20. Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates

    SciTech Connect (OSTI)

    Chaka, Anne M.; Felmy, Andrew R.

    2014-03-28

    An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

  1. Non-hermitian quantum thermodynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gardas, Bartłomiej; Deffner, Sebastian; Saxena, Avadh

    2016-03-22

    Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the Jarzynski equality holds true for all non-hermitian quantum systems with real spectrum. This equality expresses the second law of thermodynamics for isothermal processes arbitrarily far from equilibrium. In the quasistatic limit however, the second law leads to the Carnot bound which is fulfilled even if some eigenenergies are complex provided they appear in conjugate pairs. Lastly, we propose two setups to test our predictions,more » namely with strongly interacting excitons and photons in a semiconductor microcavity and in the non-hermitian tight-binding model.« less

  2. Calculation of the thermodynamic properties of fuel-vapor species from spectroscopic data

    SciTech Connect (OSTI)

    Green, D.W.

    1980-09-01

    Measured spectroscopic data, estimated molecular parameters, and a densty-of-states model for electronic structure have been used to calculate thermodynamic functions for gaseous ThO, ThO/sub 2/, UO, UO/sub 2/, UO/sub 3/, PuO, and PuO/sub 2/. Various methods for estimating parameters have been considered and numerically evaluated. The sensitivity of the calculated thermodynamic functions to molecular parameters has been examined quantitatively. New values of the standard enthalpies of formation at 298.15/sup 0/K have been derived from the best available ..delta..G/sup 0//sub f/ equations and the calculated thermodynamic functions. Estimates of the uncertainties have been made for measured and estimated data as well as for various mathematical and physical approximations. Tables of the thermodynamic functions to 6000/sup 0/K are recommended for gaseous thorium, uranium, and plutonium oxides.

  3. CRC handbook of applied thermodynamics

    SciTech Connect (OSTI)

    Palmer, D.A. . Research and Development Dept.)

    1987-01-01

    The emphasis of this book is on applied thermodynamics, featuring the stage of development of a process rather than the logical development of thermodynamic principles. It is organized according to the types of problems encountered in industry, such as probing research, process assessment, and process development. The applied principles presented can be used in most areas of industry including oil and gas production and processing, chemical processing, power generation, polymer production, food processing, synthetic fuels production, specialty chemicals and pharmaceuticals production, bioengineered processes, etc.

  4. Fundamental base closure environmental principles

    SciTech Connect (OSTI)

    Yim, R.A.

    1994-12-31

    Military base closures present a paradox. The rate, scale and timing of military base closures is historically unique. However, each base itself typically does not present unique problems. Thus, the challenge is to design innovative solutions to base redevelopment and remediation issues, while simultaneously adopting common, streamlined or pre-approved strategies to shared problems. The author presents six environmental principles that are fundamental to base closure. They are: remediation not clean up; remediation will impact reuse; reuse will impact remediation; remediation and reuse must be coordinated; environmental contamination must be evaluated as any other initial physical constraint on development, not as an overlay after plans are created; and remediation will impact development, financing and marketability.

  5. Fundamental studies of polymer filtration

    SciTech Connect (OSTI)

    Smith, B.F.; Lu, M.T.; Robison, T.W.; Rogers, Y.C.; Wilson, K.V.

    1998-12-31

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The objectives of this project were (1) to develop an enhanced fundamental understanding of the coordination chemistry of hazardous-metal-ion complexation with water-soluble metal-binding polymers, and (2) to exploit this knowledge to develop improved separations for analytical methods, metals processing, and waste treatment. We investigated features of water-soluble metal-binding polymers that affect their binding constants and selectivity for selected transition metal ions. We evaluated backbone polymers using light scattering and ultrafiltration techniques to determine the effect of pH and ionic strength on the molecular volume of the polymers. The backbone polymers were incrementally functionalized with a metal-binding ligand. A procedure and analytical method to determine the absolute level of functionalization was developed and the results correlated with the elemental analysis, viscosity, and molecular size.

  6. Dabasinksas: Thermodynamics and Energy Transfer

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    later. G E F F B D A C Internal Energy (Joules) t t t t t t t t First Law of Thermodynamics: UQ+W for a closed system Q h t i t d W k i t +Q heat input and +W ...

  7. Transposed critical temperature Rankine thermodynamic cycle

    SciTech Connect (OSTI)

    Pope, W.L.; Doyle, P.A.

    1980-04-01

    The transposed critical temperature (TPCT) is shown to be an extremely important thermodynamic property in the selection of the working fluid and turbine states for optimized geothermal power plants operating on a closed organic (binary) Rankine cycle. When the optimum working fluid composition and process states are determined for given source and sink conditions (7 parameter optimization), turbine inlet states are found to be consistently adjacent to the low pressure side of the working fluids' TPCT line on pressure-enthalpy coordinates. Although the TPCT concepts herein may find numerous future applications in high temperature, advanced cycles for fossil or nuclear fired steam power plants and in supercritical organic Rankine heat recovery bottoming cycles for Diesel engines, this discussion is limited to moderate temperature (150 to 250/sup 0/C) closed simple organic Rankine cycle geothermal power plants. Conceptual design calculations pertinent to the first geothermal binary cycle Demonstration Plant are included.

  8. Government Contracting Fundamentals | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Services » Funding » Small Business Program » Government Contracting Fundamentals Government Contracting Fundamentals EERE's Government Contracting Fundamentals lists useful government contracting resource links and descriptions for small businesses. Government Contracting Fundamentals (382.97 KB) More Documents & Publications Top 10 Tips for Contracting with the DOE Doing Business with the Office of Energy Efficiency and Renewable Energy: Frequently Asked Questions U.S. Department of

  9. Methods and systems for thermodynamic evaluation of battery state of health

    SciTech Connect (OSTI)

    Yazami, Rachid; McMenamin, Joseph; Reynier, Yvan; Fultz, Brent T

    2014-12-02

    Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

  10. Fundamental mechanisms of micromachine reliability

    SciTech Connect (OSTI)

    DE BOER,MAARTEN P.; SNIEGOWSKI,JEFFRY J.; KNAPP,JAMES A.; REDMOND,JAMES M.; MICHALSKE,TERRY A.; MAYER,THOMAS K.

    2000-01-01

    Due to extreme surface to volume ratios, adhesion and friction are critical properties for reliability of Microelectromechanical Systems (MEMS), but are not well understood. In this LDRD the authors established test structures, metrology and numerical modeling to conduct studies on adhesion and friction in MEMS. They then concentrated on measuring the effect of environment on MEMS adhesion. Polycrystalline silicon (polysilicon) is the primary material of interest in MEMS because of its integrated circuit process compatibility, low stress, high strength and conformal deposition nature. A plethora of useful micromachined device concepts have been demonstrated using Sandia National Laboratories' sophisticated in-house capabilities. One drawback to polysilicon is that in air the surface oxidizes, is high energy and is hydrophilic (i.e., it wets easily). This can lead to catastrophic failure because surface forces can cause MEMS parts that are brought into contact to adhere rather than perform their intended function. A fundamental concern is how environmental constituents such as water will affect adhesion energies in MEMS. The authors first demonstrated an accurate method to measure adhesion as reported in Chapter 1. In Chapter 2 through 5, they then studied the effect of water on adhesion depending on the surface condition (hydrophilic or hydrophobic). As described in Chapter 2, they find that adhesion energy of hydrophilic MEMS surfaces is high and increases exponentially with relative humidity (RH). Surface roughness is the controlling mechanism for this relationship. Adhesion can be reduced by several orders of magnitude by silane coupling agents applied via solution processing. They decrease the surface energy and render the surface hydrophobic (i.e. does not wet easily). However, only a molecular monolayer coats the surface. In Chapters 3-5 the authors map out the extent to which the monolayer reduces adhesion versus RH. They find that adhesion is independent of

  11. Perform Thermodynamics Measurements on Fuel Cycle Case Study Systems

    SciTech Connect (OSTI)

    Leigh R. Martin

    2014-09-01

    This document was prepared to meet FCR&D level 3 milestone M3FT-14IN0304022, Perform Thermodynamics Measurements on Fuel Cycle Case Study Systems. This work was carried out under the auspices of the Thermodynamics and Kinetics FCR&D work package. This document reports preliminary work in support of determining the thermodynamic parameters for the ALSEP process. The ALSEP process is a mixed extractant system comprised of a cation exchanger 2-ethylhexyl-phosphonic acid mono-2-ethylhexyl ester (HEH[EHP]) and a neutral solvating extractant N,N,N,N-tetraoctyldiglycolamide (TODGA). The extractant combination produces complex organic phase chemistry that is challenging for traditional measurement techniques. To neutralize the complexity, temperature dependent solvent extraction experiments were conducted with neat TODGA and scaled down concentrations of the ALSEP formulation to determine the enthalpies of extraction for the two conditions. A full set of thermodynamic data for Eu, Am, and Cm extraction by TODGA from 3.0 M HNO3 is reported. These data are compared to previous extraction results from a 1.0 M HNO3 aqueous medium, and a short discussion of the mixed HEH[EHP]/TODGA system results is offered.

  12. thermodynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power ...

  13. "Fundamental Challenges in Solar Energy Conversion" workshop...

    Office of Science (SC) Website

    Fundamental Challenges in Solar Energy Conversion" workshop hosted by LMI-EFRC Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events ...

  14. Fundamental Electroweak Studies using Trapped Ions & Atoms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    collaboration performs fundamental electroweak studies on trapped ions & atoms. We use neutral atom and ion trapping techniques at radioactive ion beam facilities here and...

  15. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    fundamental barrier, other than cation hydration, exists that prevents Mgsup 2+ and ... of water give us a first direct proof to support and quantify the cation hydration effect. ...

  16. Modeling of Geothermal Reservoirs: Fundamental Processes, Computer...

    Open Energy Info (EERE)

    of Geothermal Reservoirs: Fundamental Processes, Computer Simulation and Field Applications Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  17. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  18. Thermodynamic Properties of Supported Catalysts

    SciTech Connect (OSTI)

    Gorte, Raymond J.

    2014-03-26

    The goals of this work were to develop Coulometric Titration as a method for characterizing the thermodynamic redox properties of oxides and to apply this technique to the characterization of ceria- and vanadia-based catalysts. The redox properties of ceria and vanadia are a major part of what makes these materials catalytically active but their properties are also dependent on their structure and the presence of other oxides. Quantifying these properties through the measurement of oxidation energetics was the goal of this work.

  19. Thermodynamic Database Population Software (DBCreate) - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Geothermal Geothermal Energy Analysis Energy Analysis Find More Like This Return to Search Thermodynamic Database Population Software (DBCreate) DOE Grant Recipients Contact GRANT About This Technology <span id="Caption"><span id="ctl00_MainContentHolder_zoomimage_defaultCaption">Geochemical modeling relies on accurate and up to date thermodynamic databases.</span></span> Geochemical modeling relies on accurate and up to date thermodynamic

  20. Thermodynamic assessment of the Pr-O system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system frommore » 298 K to melting.« less

  1. Thermodynamic assessment of the Pr-O system

    SciTech Connect (OSTI)

    McMurray, Jake W.

    2015-12-24

    We found that the Calphad method was used to perform a thermodynamic assessment of the Pr–O system. Compound energy formalism representations were developed for the fluorite α-PrO 2–x and bixbyite σ-Pr 3 O 5 ± x solid solutions while the two-sublattice liquid model was used to describe the binary melt. The series of phases between Pr 2 O 3 and PrO 2 were taken to be stoichiometric. Moreover, the equilibrium oxygen pressure, phase equilibria, and enthalpy data were used to optimize the adjustable parameters of the models for a self-consistent representation of the thermodynamic behavior of the Pr–O system from 298 K to melting.

  2. Phase Field model elucidates competing thermodynamic effects...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... suggest that nanocrystalline metals can be thermodynamically stabilized by the free energy gain associated with the segregation of solute atoms to the grain boundary which ...

  3. Thermodynamic Advantages of Low Temperature Combustion Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use ...

  4. Light particles A window to fundamental physics

    SciTech Connect (OSTI)

    Jaeckel, Joerg

    2010-08-30

    In these proceedings we illustrate that light, very weakly interacting particles can arise naturally from physics which is fundamentally connected to very high energy scales. Searching for them therefore may give us interesting new insights into the structure of fundamental physics. The prime example is the axion.

  5. Thermodynamic properties of bulk and confined water

    SciTech Connect (OSTI)

    Mallamace, Francesco; Corsaro, Carmelo; Mallamace, Domenico; Vasi, Sebastiano; Vasi, Cirino; Stanley, H. Eugene

    2014-11-14

    The thermodynamic response functions of water display anomalous behaviors. We study these anomalous behaviors in bulk and confined water. We use nuclear magnetic resonance (NMR) to examine the configurational specific heat and the transport parameters in both the thermal stable and the metastable supercooled phases. The data we obtain suggest that there is a behavior common to both phases: that the dynamics of water exhibit two singular temperatures belonging to the supercooled and the stable phase, respectively. One is the dynamic fragile-to-strong crossover temperature (T{sub L} ? 225K). The second, T{sup *} ? 315 5K, is a special locus of the isothermal compressibility K{sub T}(T, P) and the thermal expansion coefficient ?{sub P}(T, P) in the PT plane. In the case of water confined inside a protein, we observe that these two temperatures mark, respectively, the onset of protein flexibility from its low temperature glass state (T{sub L}) and the onset of the unfolding process (T{sup *})

  6. Thermodynamic characterization of new palladium alloy tritides

    SciTech Connect (OSTI)

    Hoelder, J.S.; Wermer, J.R.

    1994-08-09

    The decay of tritium in a metal tritide generates {sup 3}He in the lattice which tends to degrade the performance of the material over time. It is desired to develop a material which minimizes the tritium aging effects and may be tailored to a particular tritium processing application. Pd alloys with Ni and Co have been investigated, as Pd tritide is known to be resistant to tritium aging effects and alloying provides a means for adjusting the plateau pressure of the metal tritide. Sets of tritium desorption isotherms were acquired at temperatures between 273 and 338 K over the pressure range of 1 to 900 kPa. The thermodynamic parameters of {Delta}H and {Delta}S for the {beta}-{alpha} phase transition of the metal tritides were determined across the plateau regions of the P-C-T curves. The average values of {Delta}H (kJ/mol{center_dot}T) and {Delta}S (J/K/mol{center_dot}T) were found to be 15.8 and 50.1 for Pd(2.8 wt. %)Ni, 13.7 and 50.3 for Pd(5.2 wt. %)Ni, 15.9 and 51.3 for Pd(2.8 wt. %)Co, and 13.6 and 51.8 for Pd(5.2 wt. %)Co, respectively.

  7. Thermodynamic properties of uranium dioxide

    SciTech Connect (OSTI)

    Fink, J.K.; Chasanov, M.G.; Leibowitz, L.

    1981-04-01

    In order to provide reliable and consistent data on the thermophysical properties of reactor materials for reactor safety studies, this revision is prepared for the thermodynamic properties of the uranium dioxide portion of the fuel property section of the report Properties for LMFBR Safety Analysis. Since the original report was issued in 1976, there has been international agreement on a vapor pressure equation for the total pressure over UO/sub 2/, new methods have been suggested for the calculation of enthalpy and heat capacity, and a phase change at 2670 K has been proposed. In this report, an electronic term is used in place of the Frenkel defect term in the enthalpy and heat capacity equation and the phase transition is accepted.

  8. Eugene Wigner and Fundamental Symmetry Principles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Eugene Wigner and Fundamental Symmetry Principles Patents * Resources with Additional Information * Wigner Honored "[Eugene P.] Wigner's great contribution to science, for which he won the Nobel Prize in Physics in 1963, was his insight into the fundamental mathematics and physics of quantum mechanics. He applied and extended the mathematical theory of groups to the quantum world of the atom; specifically, he used group theory to organize the quantum energy levels of electrons in atoms in a

  9. Overview of NASA supported Stirling thermodynamic loss research

    SciTech Connect (OSTI)

    Tew, R.C.; Geng, S.M.

    1994-09-01

    The National Aeronautics and Space Administration (NASA) is funding research to characterize Stirling machine thermodynamic losses. NASA`s primary goal is to improve Stirling design codes to support engine development for space and terrestrial power. However, much of the fundamental data is applicable to Stirling cooler and heat pump applications. The research results are reviewed. Much has been learned about oscillating-flow hydrodynamics, including laminar/turbulent transition, and tabulated data has been documented for further analysis. Now, with a better understanding of the oscillator-flow field, it is time to begin measuring the effects of oscillating flow and oscillating pressure level on heat transfer in heat exchanger flow passages and in cylinders. This critical phase of the work is just beginning.

  10. Thermodynamics Student Guide (6 Activities) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Student Guide (6 Activities) Thermodynamics Student Guide (6 Activities) Information about Thermodynamics, six student activities on energy basics for grades 5-8 and 9-12....

  11. Thermodynamic Guidelines for the Prediction of Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures Thermodynamic Guidelines for the Prediction of ...

  12. Measurements and non-local thermodynamic equilibrium modeling...

    Office of Scientific and Technical Information (OSTI)

    thermodynamic equilibrium modeling of mid-Z plasma emission Citation Details In-Document Search Title: Measurements and non-local thermodynamic equilibrium modeling of mid-Z ...

  13. DOE fundamentals handbook: Nuclear physics and reactor theory

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.

  14. DOE fundamentals handbook: Nuclear physics and reactor theory. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.

  15. DOE fundamentals handbook: Nuclear physics and reactor theory. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Nuclear Physics and Reactor Theory Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of nuclear physics and reactor theory. The handbook includes information on atomic and nuclear physics; neutron characteristics; reactor theory and nuclear parameters; and the theory of reactor operation. This information will provide personnel with a foundation for understanding the scientific principles that are associated with various DOE nuclear facility operations and maintenance.

  16. Thermodynamic universality of quantum Carnot engines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gardas, Bartłomiej; Deffner, Sebastian

    2015-10-12

    The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for quantum devices with efficiencies larger than the Carnot efficiency. The present study shows that this is not permitted by the laws of thermodynamic —independent of the model. We will show that rather the definition of heat has to be modified to account for the thermodynamic cost of maintaining non-Gibbsian equilibrium states. As a result, our theoretical findings are illustrated for two experimentallymore » relevant examples.« less

  17. Thermodynamic universality of quantum Carnot engines

    SciTech Connect (OSTI)

    Gardas, Bart?omiej; Deffner, Sebastian

    2015-10-12

    The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for quantum devices with efficiencies larger than the Carnot efficiency. The present study shows that this is not permitted by the laws of thermodynamic independent of the model. We will show that rather the definition of heat has to be modified to account for the thermodynamic cost of maintaining non-Gibbsian equilibrium states. As a result, our theoretical findings are illustrated for two experimentally relevant examples.

  18. Theoretical investigation of thermodynamic stability and mobility...

    Office of Scientific and Technical Information (OSTI)

    The thermodynamic stability and the migration energy barriers of oxygen vacancies in ThO2 ... conditions, respectively, while its migration energy barrier is 1.97 eV. The addition ...

  19. Thermodynamic assessment and experimental verification of reactive...

    Office of Scientific and Technical Information (OSTI)

    thermodynamic analysis of etch chemistries for Co, Fe, and Ni using a combination of hydrogen, oxygen, and halogen gases suggested that a single etchant does not work at 300 K;...

  20. FP-LAPW study of the fundamental properties of the cubic spinel CdAl{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Bouhemadou, A.; Zerarga, F.; Almuhayya, A.; Bin-Omran, S.

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Fundamental properties of CdAl{sub 2}O{sub 4} are investigated. Black-Right-Pointing-Pointer Results obtained for energy band gaps using EV-GGA are larger than that within PBE-GGA. Black-Right-Pointing-Pointer The decomposition of the dielectric function into individual band-to-band contributions is calculated. Black-Right-Pointing-Pointer The effective charge-carrier masses are estimated from the band structure. Black-Right-Pointing-Pointer Pressure and temperature dependences of some macroscopic parameters are obtained. -- Abstract: We have investigated the structural, elastic, electronic, optical and thermodynamic properties of the cubic spinel CdAl{sub 2}O{sub 4} using accurate ab initio calculations. Computed equilibrium structural parameters are in good agreement with the available experimental data. Single-crystals elastic parameters are calculated for pressure up to 30 GPa using a conserving-volume total energy-strain method. Isotropic elastic parameters for ideal polycrystalline CdAl{sub 2}O{sub 4} aggregates are computed in the framework of the Voigt-Reuss-Hill approximation. Result for band structure using the Engel-Vosko scheme of the GGA shows a significant improvement over the common GGA functionals. Optical spectra have been calculated for the energy range 0-30 eV. The peaks and structures in the optical spectra are assigned to interband transitions. Pressure dependence of the band gaps, static dielectric constant and static refractive index are also investigated. Pressure and thermal effects on some macroscopic properties are predicted using the quasi-harmonic Debye model.

  1. DOE Fundamentals Handbook: Mathematics, Volume 1

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Mathematics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mathematics and its application to facility operation. The handbook includes a review of introductory mathematics and the concepts and functional use of algebra, geometry, trigonometry, and calculus. Word problems, equations, calculations, and practical exercises that require the use of each of the mathematical concepts are also presented. This information will provide personnel with a foundation for understanding and performing basic mathematical calculations that are associated with various DOE nuclear facility operations.

  2. DOE Fundamentals Handbook: Mathematics, Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Mathematics Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mathematics and its application to facility operation. The handbook includes a review of introductory mathematics and the concepts and functional use of algebra, geometry, trigonometry, and calculus. Word problems, equations, calculations, and practical exercises that require the use of each of the mathematical concepts are also presented. This information will provide personnel with a foundation for understanding and performing basic mathematical calculations that are associated with various DOE nuclear facility operations.

  3. Dark Energy: A Crisis for Fundamental Physics

    ScienceCinema (OSTI)

    Stubbs, Christopher [Harvard University, Cambridge, Massachusetts, USA

    2010-09-01

    Astrophysical observations provide robust evidence that our current picture of fundamental physics is incomplete. The discovery in 1998 that the expansion of the Universe is accelerating (apparently due to gravitational repulsion between regions of empty space!) presents us with a profound challenge, at the interface between gravity and quantum mechanics. This "Dark Energy" problem is arguably the most pressing open question in modern fundamental physics. The first talk will describe why the Dark Energy problem constitutes a crisis, with wide-reaching ramifications. One consequence is that we should probe our understanding of gravity at all accessible scales, and the second talk will present experiments and observations that are exploring this issue.

  4. DOE Fundamentals Handbook: Electrical Science, Volume 4

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive transformers; and electrical test components; batteries; AC and DC voltage regulators; instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.

  5. DOE Fundamentals Handbook: Electrical Science, Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.

  6. DOE Fundamentals Handbook: Electrical Science, Volume 3

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.

  7. DOE Fundamentals Handbook: Electrical Science, Volume 1

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Electrical Science Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of electrical theory, terminology, and application. The handbook includes information on alternating current (AC) and direct current (DC) theory, circuits, motors, and generators; AC power and reactive components; batteries; AC and DC voltage regulators; transformers; and electrical test instruments and measuring devices. This information will provide personnel with a foundation for understanding the basic operation of various types of DOE nuclear facility electrical equipment.

  8. Finite-time thermodynamic analysis of the Stirling engine

    SciTech Connect (OSTI)

    Ibrahim, O.M.; Ladas, H.G.

    1995-12-31

    This paper presents a finite-time thermodynamic analysis of the Stirling engine cycle. A lumped-parameter thermodynamic model is used to describe the dynamic behavior of the Stirling engine. The mathematical formulation of this model is based on mass and energy balances with associated heat transfer rate equations. These governing equations are formulated into a set of ordinary differential equations, which are then solved numerically to obtain the dynamic behavior of the Stirling engine. Close inspection of the governing equations reveals that the time to complete on cycle, {tau} and the engine time constant, {tau}{sub c} always appear together in a dimensionless ratio. This ratio, {tau}/{tau}{sub c}, is defined here as the Finite-Time Parameter, FTP. The effects of FTP upon power output and efficiency, are studied. The results show that there exists an optimum power output for a given engine design, based on engine speed and heat-transfer contact time. The results also provide an engineering evaluation procedure to improve the efficiency and power output of Stirling engines.

  9. Thermodynamic modelling of growth-restriction effects in aluminium alloys

    SciTech Connect (OSTI)

    Quested, T.E. . E-mail: teq20@cam.ac.uk; Dinsdale, A.T.; Greer, A.L.

    2005-03-01

    The amount and type of alloying elements in aluminium affect the as-cast microstructure through the dependence of solidified fraction on undercooling. This can be quantified by the growth-restriction parameter Q. Phase-diagram calculations using the CALPHAD method show the effects of thermodynamic parameters on Q. In binary systems, the deviation from linear dependence of Q on solute concentration is assessed. In ternary alloys, model systems elucidate the role of solute interaction in the liquid and solid, and can be used to interpret the behaviour in actual systems. Growth restriction is discussed in relation to solidification modelling and the attainment of a fine, equiaxed microstructure in wrought and shape-casting alloys.

  10. Prequantum Classical Statistical Field Theory: Fundamentals

    SciTech Connect (OSTI)

    Khrennikov, Andrei

    2011-03-28

    We present fundamentals of a prequantum model with hidden variables of the classical field type. In some sense this is the comeback of classical wave mechanics. Our approach also can be considered as incorporation of quantum mechanics into classical signal theory. All quantum averages (including correlations of entangled systems) can be represented as classical signal averages and correlations.

  11. Properties of hadronic systems according to the non-extensive self-consistent thermodynamics

    SciTech Connect (OSTI)

    Deppman, A.

    2014-11-11

    The non-extensive self-consistent theory describing the thermodynamics of hadronic systems at high temperatures is used to derive some thermodynamical quantities, as pressure, entropy, speed of sound and trace-anomaly. The calculations are free of fitting parameters, and the results are compared to lattice QCD calculations, showing a good agreement between theory and data up to temperatures around 175 MeV. Above this temperature the effects of a singularity in the partition function at T{sub o} = 192 MeV results in a divergent behaviour in respect with the lattice calculation.

  12. Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of Lean NOx Traps Pre-Competitive Catalysis Research: Fundamental SulfationDesulfation Studies of...

  13. Fundamental aspects of nuclear reactor fuel elements: solutions...

    Office of Scientific and Technical Information (OSTI)

    Fundamental aspects of nuclear reactor fuel elements: solutions to problems Citation Details In-Document Search Title: Fundamental aspects of nuclear reactor fuel elements: ...

  14. Fundamental aspects of nuclear reactor fuel elements (Technical...

    Office of Scientific and Technical Information (OSTI)

    Fundamental aspects of nuclear reactor fuel elements Citation Details In-Document Search Title: Fundamental aspects of nuclear reactor fuel elements You are accessing a document ...

  15. Ultra-cold neutron fundamental physics experiments at LANSCE...

    Office of Scientific and Technical Information (OSTI)

    Ultra-cold neutron fundamental physics experiments at LANSCE Citation Details In-Document Search Title: Ultra-cold neutron fundamental physics experiments at LANSCE Authors: Saunders, ...

  16. Vehicle Technologies Office Merit Review 2014: Fundamental Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Studies of Lithium-Sulfur Cell Chemistry Vehicle Technologies Office Merit Review 2014: Fundamental Studies of Lithium-Sulfur Cell Chemistry Presentation given by...

  17. Toward A Fundamental Understanding Of Nuclear Reactions And Exotic...

    Office of Scientific and Technical Information (OSTI)

    Conference: Toward A Fundamental Understanding Of Nuclear Reactions And Exotic Nuclei Citation Details In-Document Search Title: Toward A Fundamental Understanding Of Nuclear ...

  18. Nanoscale imaging of fundamental Li battery chemistry: solid...

    Office of Scientific and Technical Information (OSTI)

    Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase ... Citation Details In-Document Search Title: Nanoscale imaging of fundamental Li battery ...

  19. fundamental Modeling and Experimental Studies of Acicular Mullite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate Filters fundamental Modeling and Experimental Studies of Acicular Mullite Diesel Particulate ...

  20. Fundamentals of Monte Carlo (Technical Report) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Fundamentals of Monte Carlo Citation Details In-Document Search Title: Fundamentals of Monte Carlo Authors: Wollaber, Allan Benton 1 + Show Author Affiliations Los Alamos ...

  1. EERE Success Story-Fundamental Studies in Catalysis Enabled the...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Studies in Catalysis Enabled the use of Efficient "Lean-Burn" Engines for Vehicle Transportation EERE Success Story-Fundamental Studies in Catalysis Enabled the use of ...

  2. Fundamental New Insight Into Material for Optical-Switching ...

    Office of Science (SC) Website

    Fundamental New Insight Into Material for Optical-Switching Basic Energy Sciences (BES) ... Fundamental New Insight Into Material for Optical-Switching A triple point, where three ...

  3. Wall of fundamental constants (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Wall of fundamental constants Citation Details In-Document Search Title: Wall of fundamental constants Authors: Olive, Keith A. ; Peloso, Marco ; Uzan, Jean-Philippe Publication ...

  4. Kinetic and thermodynamic study of the liquid-phase etherification of isoamylenes with methanol

    SciTech Connect (OSTI)

    Piccoli, R.L. ); Lovisi, H.R. )

    1995-02-01

    The kinetics and thermodynamics of liquid-phase etherification of isoamylenes with methanol on ion exchange catalyst (Amberlyst 15) were studied. Thermodynamic properties and rate data were obtained in a batch reactor operating under 1,013 kPa and 323--353 K. The kinetic equation was modeled following the Langmuir-Hinshelwood-Hougen-Watson formalism according to a proposed surface mechanism where the rate-controlling step is the surface reaction. According to the experimental results, methanol adsorbs very strongly on the active sites, covering them completely, and thus the reaction follows an apparent first-order behavior. The isoamylenes, according to the proposed mechanism, adsorb simultaneously on the same single active center already occupied by methanol, migrating through the liquid layer formed by the alcohol around the catalyst to react in the acidic site. From the proposed mechanism a model was suggested and the kinetic and thermodynamic parameters were obtained using nonlinear estimation methods.

  5. Fundamental Challenges in Solar to Fuel Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ager, NERSC, 2/4/14 - 1 Fundamental Challenges in Solar to Fuel Conversion aka Improving on Photosynthesis Joel Ager Joint Center for Artificial Photosynthesis Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA February 4, 2014 NERSC User Meeting Berkeley, CA The Joint Center for Artificial Photosynthesis is a DOE Energy Innovation Hub, supported by the Office of Science of the U.S. Department of Energy Ager, NERSC, 2/4/14 - 2 What is "artificial

  6. DOE fundamentals handbook: Material science. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the structure and properties of metals. This volume contains the two modules: structure of metals (bonding, common lattic types, grain structure/boundary, polymorphis, alloys, imperfections in metals) and properties of metals (stress, strain, Young modulus, stress-strain relation, physical properties, working of metals, corrosion, hydrogen embrittlement, tritium/material compatibility).

  7. DOE fundamentals handbook: Material science. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Mechanical Science Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mechanical components and mechanical science. The handbook includes information on diesel engines, heat exchangers, pumps, valves, and miscellaneous mechanical components. This information will provide personnel with a foundation for understanding the construction and operation of mechanical components that are associated with various DOE nuclear facility operations and maintenance.

  8. DOE fundamentals handbook: Mechanical science. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Mechanical Science Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of mechanical components and mechanical science. The handbook includes information diesel engines, heat exchangers, pumps, valves, and miscellaneous mechanical components. This information will provide personnel with a foundation for understanding the construction and operation of mechanical components that are associated with various DOE nuclear facility operations and maintenance.

  9. Cantera and Cantera Electrolyte Thermodynamics Objects

    SciTech Connect (OSTI)

    John Hewson, Harry Moffat

    2015-10-19

    Cantera is a suite of object-oriented software tools for problems involving chemical kinetics, thermodynamics, and/or transport processes. It is a multi-organizational effort to create and formulate high quality 0D and 1D constitutive modeling tools for reactive transport codes.Institutions involved with the effort include Sandia, MIT, Colorado School of Mines, U. Texas, NASA, and Oak Ridge National Labs. Specific to Sandia’s contributions, the Cantera Electrolyte Thermo Objects (CETO) packages is comprised of add-on routines for Cantera that handle electrolyte thermochemistry and reactions within the overall Cantera package. Cantera is a C++ Cal Tech code that handles gas phase species transport, reaction, and thermodynamics. With this addition, Cantera can be extended to handle problems involving liquid phase reactions and transport in electrolyte systems, and phase equilibrium problemsinvolving concentrated electrolytes and gas/solid phases. A full treatment of molten salt thermodynamics and transport has also been implemented in CETO. The routines themselves consist of .cpp and .h files containing C++ objects that are derived from parent Cantera objects representing thermodynamic functions. They are linked unto the main Cantera libraries when requested by the user. As an addendum to the main thermodynamics objects, several utility applications are provided. The first is multiphase Gibbs free energy minimizer based on the vcs algorithm, called vcs_cantera. This code allows for the calculation of thermodynamic equilibrium in multiple phases at constant temperature and pressure. Note, a similar code capability exists already in Cantera. This version follows the same algorithm, but gas a different code-base starting point, and is used as a research tool for algorithm development. The second program, cttables, prints out tables of thermodynamic and kinetic information for thermodynamic and kinetic objects within Cantera. This program serves as a “Get the numbers

  10. Cantera and Cantera Electrolyte Thermodynamics Objects

    Energy Science and Technology Software Center (OSTI)

    2015-10-19

    Cantera is a suite of object-oriented software tools for problems involving chemical kinetics, thermodynamics, and/or transport processes. It is a multi-organizational effort to create and formulate high quality 0D and 1D constitutive modeling tools for reactive transport codes.Institutions involved with the effort include Sandia, MIT, Colorado School of Mines, U. Texas, NASA, and Oak Ridge National Labs. Specific to Sandia’s contributions, the Cantera Electrolyte Thermo Objects (CETO) packages is comprised of add-on routines for Canteramore » that handle electrolyte thermochemistry and reactions within the overall Cantera package. Cantera is a C++ Cal Tech code that handles gas phase species transport, reaction, and thermodynamics. With this addition, Cantera can be extended to handle problems involving liquid phase reactions and transport in electrolyte systems, and phase equilibrium problemsinvolving concentrated electrolytes and gas/solid phases. A full treatment of molten salt thermodynamics and transport has also been implemented in CETO. The routines themselves consist of .cpp and .h files containing C++ objects that are derived from parent Cantera objects representing thermodynamic functions. They are linked unto the main Cantera libraries when requested by the user. As an addendum to the main thermodynamics objects, several utility applications are provided. The first is multiphase Gibbs free energy minimizer based on the vcs algorithm, called vcs_cantera. This code allows for the calculation of thermodynamic equilibrium in multiple phases at constant temperature and pressure. Note, a similar code capability exists already in Cantera. This version follows the same algorithm, but gas a different code-base starting point, and is used as a research tool for algorithm development. The second program, cttables, prints out tables of thermodynamic and kinetic information for thermodynamic and kinetic objects within Cantera. This program serves as a “Get the

  11. Local thermodynamics of a magnetized, anisotropic plasma

    SciTech Connect (OSTI)

    Hazeltine, R. D.; Mahajan, S. M.; Morrison, P. J.

    2013-02-15

    An expression for the internal energy of a fluid element in a weakly coupled, magnetized, anisotropic plasma is derived from first principles. The result is a function of entropy, particle density and magnetic field, and as such plays the role of a thermodynamic potential: it determines in principle all thermodynamic properties of the fluid element. In particular it provides equations of state for the magnetized plasma. The derivation uses familiar fluid equations, a few elements of kinetic theory, the MHD version of Faraday's law, and certain familiar stability and regularity conditions.

  12. Quantum stochastic thermodynamic on harmonic networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deffner, Sebastian

    2016-01-04

    Fluctuation theorems are symmetry relations for the probability to observe an amount of entropy production in a finite-time process. In a recent paper Pigeon et al (2016 New. J. Phys. 18 013009) derived fluctuation theorems for harmonic networks by means of the large deviation theory. Furthermore, their novel approach is illustrated with various examples of experimentally relevant systems. As a main result, however, Pigeon et al provide new insight how to consistently formulate quantum stochastic thermodynamics, and provide new and robust tools for the study of the thermodynamics of quantum harmonic networks.

  13. Cosmic acceleration without dark energy: background tests and thermodynamic analysis

    SciTech Connect (OSTI)

    Lima, J.A.S.; Graef, L.L.; Pavn, D.; Basilakos, Spyros E-mail: leilagraef@usp.br E-mail: svasil@academyofathens.gr

    2014-10-01

    A cosmic scenario with gravitationally induced particle creation is proposed. In this model the Universe evolves from an early to a late time de Sitter era, with the recent accelerating phase driven only by the negative creation pressure associated with the cold dark matter component. The model can be interpreted as an attempt to reduce the so-called cosmic sector (dark matter plus dark energy) and relate the two cosmic accelerating phases (early and late time de Sitter expansions). A detailed thermodynamic analysis including possible quantum corrections is also carried out. For a very wide range of the free parameters, it is found that the model presents the expected behavior of an ordinary macroscopic system in the sense that it approaches thermodynamic equilibrium in the long run (i.e., as it nears the second de Sitter phase). Moreover, an upper bound is found for the GibbonsHawking temperature of the primordial de Sitter phase. Finally, when confronted with the recent observational data, the current 'quasi'-de Sitter era, as predicted by the model, is seen to pass very comfortably the cosmic background tests.

  14. Hydrogen Production: Fundamentals and Case Study Summaries (Presentation)

    SciTech Connect (OSTI)

    Harrison, K.; Remick, R.; Hoskin, A.; Martin, G.

    2010-05-19

    This presentation summarizes hydrogen production fundamentals and case studies, including hydrogen to wind case studies.

  15. Model for the Prediction of the Hydriding Thermodynamics of Pd-Rh-Co Ternary Alloys

    SciTech Connect (OSTI)

    Teter, D.F.; Thoma, D.J.

    1999-03-01

    A dilute solution model (with respect to the substitutional alloying elements) has been developed, which accurately predicts the hydride formation and decomposition thermodynamics and the storage capacities of dilute ternary Pd-Rh-Co alloys. The effect of varying the rhodium and cobalt compositions on the thermodynamics of hydride formation and decomposition and hydrogen capacity of several palladium-rhodium-cobalt ternary alloys has been investigated using pressure-composition (PC) isotherms. Alloying in the dilute regime (<10 at.%) causes the enthalpy for hydride formation to linearly decrease with increasing alloying content. Cobalt has a stronger effect on the reduction in enthalpy than rhodium for equivalent alloying amounts. Also, cobalt reduces the hydrogen storage capacity with increasing alloying content. The plateau thermodynamics are strongly linked to the lattice parameters of the alloys. A near-linear dependence of the enthalpy of hydride formation on the lattice parameter was observed for both the binary Pd-Rh and Pd-Co alloys, as well as for the ternary Pd-Rh-Co alloys. The Pd-5Rh-3Co (at. %) alloy was found to have similar plateau thermodynamics as a Pd-10Rh alloy, however, this ternary alloy had a diminished hydrogen storage capacity relative to Pd-10Rh.

  16. Fundamental bioprocessing research for coal applications

    SciTech Connect (OSTI)

    Kaufman, E.N.

    1996-06-01

    The purpose of this program is to gain a fundamental understanding and sound scientific technical basis for evaluating the potential roles of innovative bioprocessing concepts for the utilization and conversion of coal. The aim is to explore the numerous ways in which advanced biological processes and techniques can open new opportunities for coal utilization or can replace more conventional techniques by use of milder conditions with less energy consumption or loss. There are several roles where biotechnology is likely to be important in coal utilization and conversion. These include potential bioprocessing systems such.

  17. DOE fundamentals handbook: Chemistry. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  18. DOE fundamentals handbook: Material science. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of the structure and properties of metals. This volume contains the following modules: thermal shock (thermal stress, pressurized thermal shock), brittle fracture (mechanism, minimum pressurization-temperature curves, heatup/cooldown rate limits), and plant materials (properties considered when selecting materials, fuel materials, cladding and reflectors, control materials, nuclear reactor core problems, plant material problems, atomic displacement due to irradiation, thermal and displacement spikes due to irradiation, neutron capture effect, radiation effects in organic compounds, reactor use of aluminum).

  19. Thermodynamics Teacher and Student Guides (6 Activities)

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    This is a hands-on laboratory unit exploring the concepts of heat and movement. Teachers set up six laboratory stations that will introduce students to the basic concepts of thermodynamics, including atomic structure, atomic and molecular motion, states of matter, heat transfer, thermal expansion, specific heat, and heats of fusion and vaporization. It also includes a unit exam and teacher demonstrations.

  20. Compound hybrid geothermal-fossil power plants: thermodynamic...

    Office of Scientific and Technical Information (OSTI)

    SUPERHEATING; THERMODYNAMICS; WELL TEMPERATURE; WELLHEADS; WESTERN REGION; HEATING; HYDROGEN COMPOUNDS; NORTH AMERICA; OXYGEN COMPOUNDS; POWER PLANTS; RESERVOIR TEMPERATURE;...

  1. Fundamentals of fluidized bed chemical processes

    SciTech Connect (OSTI)

    Yates, J.G.

    1983-01-01

    Chemical processes based on the use of fluidized solids, although widely used on an industrial scale for some four decades, are currently increasing in importance as industry looks for improved methods for handling and reacting solid materials. This book provides background necessary for an understanding of the technique of gas-solid fluidization. Contents: Some Fundamental Aspects of Fluidization-General Features of Gas-Solid Fluidization; Minimum Fluidization Velocity; Inter-particle forces; Liquid-Solid Fluidization; Bubbles; Slugging; Entrainment and Elutriation; Particle Movement; Bed Viscosity; Fluidization Under Pressure. Fluidized-Bed Reactor Models-ome Individual Models; Model Comparisons; Multiple Region Models. Catalytic Cracking-Process Developments Riser Cracking; Catalysis; Process Chemistry; Kinetics; Process Models. Combustion and Gasification-Plant Developments; Oil and Gas Combustion; Desulphurization; No/sub x/ Emissions; Coal Gassification. Miscellaneous Processes-Phthalic Anhydride (1,3-isobezofurandione); Acrylonitrile (prop-3-enenitrile); Vinyl Chloride (chloroethene); Titanium Dioxide; Uranium Processing; Sulphide Roasting; Indexes.

  2. Folding and insertion thermodynamics of the transmembrane WALP peptide

    SciTech Connect (OSTI)

    Bereau, Tristan; Bennett, W. F. Drew; Pfaendtner, Jim; Deserno, Markus; Karttunen, Mikko

    2015-12-28

    The anchor of most integral membrane proteins consists of one or several helices spanning the lipid bilayer. The WALP peptide, GWW(LA){sub n} (L)WWA, is a common model helix to study the fundamentals of protein insertion and folding, as well as helix-helix association in the membrane. Its structural properties have been illuminated in a large number of experimental and simulation studies. In this combined coarse-grained and atomistic simulation study, we probe the thermodynamics of a single WALP peptide, focusing on both the insertion across the water-membrane interface, as well as folding in both water and a membrane. The potential of mean force characterizing the peptide’s insertion into the membrane shows qualitatively similar behavior across peptides and three force fields. However, the Martini force field exhibits a pronounced secondary minimum for an adsorbed interfacial state, which may even become the global minimum—in contrast to both atomistic simulations and the alternative PLUM force field. Even though the two coarse-grained models reproduce the free energy of insertion of individual amino acids side chains, they both underestimate its corresponding value for the full peptide (as compared with atomistic simulations), hinting at cooperative physics beyond the residue level. Folding of WALP in the two environments indicates the helix as the most stable structure, though with different relative stabilities and chain-length dependence.

  3. Improved Engine Design Concepts Using the Second Law of Thermodynamics

    SciTech Connect (OSTI)

    2009-09-30

    This project was aimed at developing and using numerical tools which incorporate the second law of thermodynamics to better understand engine operation and particularly the combustion process. A major activity of this project was the continual enhancement and use of an existing engine cycle simulation to investigate a wide range of engine parameters and concepts. The major motivation of these investigations was to improve engine efficiency. These improvements were examined from both the first law and second law perspective. One of the most important aspects of this work was the identification of the combustion irreversibilities as functions of engine design and operating parameters. The combustion irreversibility may be quantified in a number of ways but one especially useful way is by determining the destruction of exergy (availability) during the combustion process. This destruction is the penalty due to converting the fuel exergy to thermal energy for producing work. The engine cycle simulation was used to examine the performance of an automotive (5.7 liter), V-8 spark-ignition engine. A base case was defined for operation at 1400 rpm, stoichiometric, MBT spark timing with a bmep of 325 kPa. For this condition, the destruction of exergy during the combustion process was 21.0%. Variations of many engine parameters (including speed, load, and spark timing) did not alter the level of destruction very much (with these variations, the exergy destruction was within the range of 20.5-21.5%). Also, the use of turbocharging or the use of an over-expanded engine design did not significantly change the exergy destruction. The exergy destruction during combustion was most affected by increased inlet oxygen concentration (which reduced the destruction due to the higher combustion temperatures) and by the use of cooled EGR (which increased the destruction). This work has demonstrated that, in general, the exergy destruction for conventional engines is fairly constant ({approx

  4. LCLS Parameters Update | Linac Coherent Light Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LCLS Parameters Update The Linac Coherent Light Source (LCLS) has demonstrated FEL operations over the energy range 280 eV to 11.2 keV using the fundamental with pulse energies of at least 1-3 mJ depending on the pulse duration and photon energy (please note that operation above 10 keV requires special accelerator conditions that may not be available at all times). Third harmonic radiation is available up to 25 keV at about 1% of the fundamental pulse energy. The pulse length can be varied from

  5. Fundamental Mechanisms Driving the Amorphous to Crystalline Phase Transformation

    SciTech Connect (OSTI)

    Reed, B W; Browning, N D; Santala, M K; LaGrange, T; Gilmer, G H; Masiel, D J; Campbell, G H; Raoux, S; Topuria, T; Meister, S; Cui, Y

    2011-01-04

    Phase transformations are ubiquitous, fundamental phenomena that lie at the heart of many structural, optical and electronic properties in condensed matter physics and materials science. Many transformations, especially those occurring under extreme conditions such as rapid changes in the thermodynamic state, are controlled by poorly understood processes involving the nucleation and quenching of metastable phases. Typically these processes occur on time and length scales invisible to most experimental techniques ({micro}s and faster, nm and smaller), so our understanding of the dynamics tends to be very limited and indirect, often relying on simulations combined with experimental study of the ''time infinity'' end state. Experimental techniques that can directly probe phase transformations on their proper time and length scales are therefore key to providing fundamental insights into the whole area of transformation physics and materials science. LLNL possesses a unique dynamic transmission electron microscope (DTEM) capable of taking images and diffraction patterns of laser-driven material processes with resolution measured in nanometers and nanoseconds. The DTEM has previously used time-resolved diffraction patterns to quantitatively study phase transformations that are orders of magnitude too fast for conventional in situ TEM. More recently the microscope has demonstrated the ability to directly image a reaction front moving at {approx}13 nm/ns and the nucleation of a new phase behind that front. Certain compound semiconductor phase change materials, such as Ge{sub 2}Sb{sub 2}Te{sub 5} (GST), Sb{sub 2}Te and GeSb, exhibit a technologically important series of transformations on scales that fall neatly into the performance specifications of the DTEM. If a small portion of such material is heated above its melting point and then rapidly cooled, it quenches into an amorphous state. Heating again with a less intense pulse leads to recrystallization into a vacancy

  6. Thermodynamics of metal-organic frameworks

    SciTech Connect (OSTI)

    Wu, Di; Navrotsky, Alexandra

    2015-03-15

    Although there have been extensive studies over the past decade in the synthesis and application of metal-organic frameworks (MOFs), investigation of their thermodynamic stability and of the energetics of guest–host interactions has been much more limited. This review summarizes recent progress in experimental (calorimetric) determination of the thermodynamics of MOF materials. The enthalpies of MOFs relative to dense phase assemblages suggest only modest metastability, with a general increase of enthalpy with increasing molar volume, which becomes less pronounced at higher porosity. The energy landscape of nanoporous materials (inorganic and hybrid) consists of a pair of parallel patterns within a fairly narrow range of metastability of 5–30 kJ per mole of tetrahedra in zeolites and mesoporous silicas or per mole of metal in MOFs. Thus strong thermodynamic instability does not seem to limit framework formation. There are strong interactions within the chemisorption range for small molecule–MOF interactions with defined chemical binding at the metal centers or other specific locations. Coexistence of surface binding and confinement can lead to much stronger guest–host interactions. - Graphical abstract: Energy landscape of inorganic and hybrid porous materials. - Highlights: • Thermochemical data on various MOF structures were experimentally determined. • MOFs are moderately unstable relative to their dense phase assemblage. • Overall energetic landscape of porous materials was revealed. • Guest–host interactions in MOFs were evaluated directly using calorimetry. • Confinement effect and defined chemical binding lead to strong interactions.

  7. Standard Model thermodynamics across the electroweak crossover

    SciTech Connect (OSTI)

    Laine, M.; Meyer, M.

    2015-07-22

    Even though the Standard Model with a Higgs mass m{sub \\tiny H}=125 GeV possesses no bulk phase transition, its thermodynamics still experiences a “soft point” at temperatures around T=160 GeV, with a deviation from ideal gas thermodynamics. Such a deviation may have an effect on precision computations of weakly interacting dark matter relic abundances if their mass is in the few TeV range, or on leptogenesis scenarios operating in this temperature range. By making use of results from lattice simulations based on a dimensionally reduced effective field theory, we estimate the relevant thermodynamic functions across the crossover. The results are tabulated in a numerical form permitting for their insertion as a background equation of state into cosmological particle production/decoupling codes. We find that Higgs dynamics induces a non-trivial “structure” visible e.g. in the heat capacity, but that in general the largest radiative corrections originate from QCD effects, reducing the energy density by a couple of percent from the free value even at T>160 GeV.

  8. Thermodynamics of Sultana-Dyer black hole

    SciTech Connect (OSTI)

    Majhi, Bibhas Ranjan

    2014-05-01

    The thermodynamical entities on the dynamical horizon are not naturally defined like the usual static cases. Here I find the temperature, Smarr formula and the first law of thermodynamics for the Sultana-Dyer metric which is related to the Schwarzschild spacetime by a time dependent conformal factor. To find the temperature (T), the chiral anomaly expressions for the two dimensional spacetime are used. This shows an application of the anomaly method to study Hawking effect for a dynamical situation. Moreover, the analysis singles out one expression for temperature among two existing expressions in the literature. Interestingly, the present form satisfies the first law of thermodynamics. Also, it relates the Misner-Sharp energy (Ē) and the horizon entropy ( S-bar ) by an algebraic expression Ē = 2 S-bar T which is the general form of the Smarr formula. This fact is similar to the usual static black hole cases in Einstein's gravity where the energy is identified as the Komar conserved quantity.

  9. Local equilibrium and the second law of thermodynamics for irreversible systems with thermodynamic inertia

    SciTech Connect (OSTI)

    Glavatskiy, K. S.

    2015-10-28

    Validity of local equilibrium has been questioned for non-equilibrium systems which are characterized by delayed response. In particular, for systems with non-zero thermodynamic inertia, the assumption of local equilibrium leads to negative values of the entropy production, which is in contradiction with the second law of thermodynamics. In this paper, we address this question by suggesting a variational formulation of irreversible evolution of a system with non-zero thermodynamic inertia. We introduce the Lagrangian, which depends on the properties of the normal and the so-called “mirror-image” systems. We show that the standard evolution equations, in particular, the Maxwell-Cattaneo-Vernotte equation, can be derived from the variational procedure without going beyond the assumption of local equilibrium. We also argue that the second law of thermodynamics in non-equilibrium should be understood as a consequence of the variational procedure and the property of local equilibrium. For systems with instantaneous response this leads to the standard requirement of the local instantaneous entropy production being always positive. However, if a system is characterized by delayed response, the formulation of the second law of thermodynamics should be altered. In particular, the quantity, which is always positive, is not the instantaneous entropy production, but the entropy production averaged over a proper time interval.

  10. Fundamental Scientific Problems in Magnetic Recording

    SciTech Connect (OSTI)

    Schulthess, T.C.; Miller, M.K.

    2007-06-27

    Magnetic data storage technology is presently leading the high tech industry in advancing device integration--doubling the storage density every 12 months. To continue these advancements and to achieve terra bit per inch squared recording densities, new approaches to store and access data will be needed in about 3-5 years. In this project, collaboration between Oak Ridge National Laboratory (ORNL), Center for Materials for Information Technology (MINT) at University of Alabama (UA), Imago Scientific Instruments, and Seagate Technologies, was undertaken to address the fundamental scientific problems confronted by the industry in meeting the upcoming challenges. The areas that were the focus of this study were to: (1) develop atom probe tomography for atomic scale imaging of magnetic heterostructures used in magnetic data storage technology; (2) develop a first principles based tools for the study of exchange bias aimed at finding new anti-ferromagnetic materials to reduce the thickness of the pinning layer in the read head; (3) develop high moment magnetic materials and tools to study magnetic switching in nanostructures aimed at developing improved writers of high anisotropy magnetic storage media.

  11. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases

  12. Fundamentals of metals joining with lasers

    SciTech Connect (OSTI)

    Jellison, J.L.

    1991-01-01

    The intrinsic characteristic of a laser as a metals joining heat source is high intensity (high irradiance). Other advantages stem from the ability to optically manipulate the beam and the inertness of light. Optimal application of laser technology to metals joining is supported by a fundamental understanding of the physics of the process. The interaction of the laser beam with metals is highly materials and process dependent. Metals joining with lasers in a absence of an understanding of beam-materials interactions would appear to be a highly unpredictable process. This is because of the complexity of beam-material interactions. For example, absorptivity varies by more than an order of magnitude as a function of alloy, temperature, oxide thickness, and laser wavelength. Also, in most laser welding and brazing processing, evaporation of metal creates a significant plume, and beam-plume interactions can markedly alter the spatial distribution of energy at the plume-metal interface. The probability of the beam being absorbed by the plume increases with the square of the wavelength, whereas the propensity for scattering of the beam by particles in the beam is inversely proportional to wavelength. Also, the beam can be refracted due to thermal and compositional gradients in the plume. In selecting a laser process for a given application, understanding each of these physical effects and others is helpful. In many ways, the physics of metals joining with lasers is only qualitatively understood at the present time. This paper overviews the present understanding of the process and identifies areas where research is required to clarify our process understanding.

  13. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn S. Lighty; Geoffrey Silcox; Andrew Fry; Joseph Helble; Balaji Krishnakumar

    2006-07-31

    The objective of this project is to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involves both experimental and modeling efforts. The team is comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective is to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters to be studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. This report summarizes Year 3 results for the experimental and modeling tasks. Experiments have been completed on the effects of chlorine. However, the experiments with sulfur dioxide and NO, in the presence of water, suggest that the wet-chemistry analysis system, namely the impingers, is possibly giving erroneous results. Future work will investigate this further and determine the role of reactions in the impingers on the oxidation results. The solid-phase experiments have not been completed and it is anticipated that only preliminary work will be accomplished during this study.

  14. Thermodynamics of rotating solutions in Gauss-Bonnet-Maxwell gravity and the counterterm method

    SciTech Connect (OSTI)

    Dehghani, M. H.; Bordbar, G. H.; Shamirzaie, M.

    2006-09-15

    By a suitable transformation, we present the (n+1)-dimensional charged rotating solutions of Gauss-Bonnet gravity with a complete set of allowed rotation parameters which are real in the whole spacetime. We show that these charged rotating solutions present black hole solutions with two inner and outer event horizons, extreme black holes, or naked singularities provided the parameters of the solutions are chosen suitable. Using the surface terms that make the action well defined for Gauss-Bonnet gravity and the counterterm method for eliminating the divergences in action, we compute finite action of the solutions. We compute the conserved and thermodynamical quantities through the use of free energy and the counterterm method, and find that the two methods give the same results. We also find that these quantities satisfy the first law of thermodynamics. Finally, we perform a stability analysis by computing the heat capacity and the determinant of Hessian matrix of mass with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, and show that the system is thermally stable. This is commensurate with the fact that there is no Hawking-Page phase transition for black objects with zero curvature horizon.

  15. Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2013 Peer Review | Department of Energy Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants - 2013 Peer Review Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants - 2013 Peer Review Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review emrgtech13_mclinden_040213.pdf (2.18 MB) More Documents & Publications Credit: National Institute of Standards Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants

  16. Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Their Application to Destabillzed Hydride Mixtures | Department of Energy Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures A presentation demonstrating the development of a set of thermodynamic guidelines aimed at facilitating more-robust screening of candidate storage reactions.

  17. A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power A Revolutionary Hybrid Thermodynamic Cycle for Bianary Geothermal Power presentation at the April 2013 peer review meeting held in Denver, Colorado. hybrid_therm_cycle_peer2013.pdf (571.03 KB) More Documents & Publications Working Fluids and Their Effect on Geothermal Turbines Tailored Working Fluids for Enhanced Binary

  18. Thermodynamics of black holes in (n+1)-dimensional Einstein-Born-Infeld-dilaton gravity

    SciTech Connect (OSTI)

    Sheykhi, A.; Riazi, N.

    2007-01-15

    We construct a new class of (n+1)-dimensional (n{>=}3) black hole solutions in Einstein-Born-Infeld-dilaton gravity with Liouville-type potential for the dilaton field and investigate their properties. These solutions are neither asymptotically flat nor (anti)-de Sitter. We find that these solutions can represent black holes, with inner and outer event horizons, an extreme black hole, or a naked singularity provided the parameters of the solutions are chosen suitably. We compute the thermodynamic quantities of the black hole solutions and find that these quantities satisfy the first law of thermodynamics. We also perform a stability analysis and investigate the effect of dilaton on the stability of the solutions.

  19. Thermodynamics of charged rotating black branes in Brans-Dicke theory with quadratic scalar field potential

    SciTech Connect (OSTI)

    Dehghani, M. H.; Pakravan, J.; Hendi, S. H.

    2006-11-15

    We construct a class of charged rotating solutions in (n+1)-dimensional Maxwell-Brans-Dicke theory with flat horizon in the presence of a quadratic potential and investigate their properties. These solutions are neither asymptotically flat nor (anti)-de Sitter. We find that these solutions can present black brane, with inner and outer event horizons, an extreme black brane or a naked singularity provided the parameters of the solutions are chosen suitably. We compute the finite Euclidean action through the use of counterterm method, and obtain the conserved and thermodynamic quantities by using the relation between the action and free energy in grand-canonical ensemble. We find that these quantities satisfy the first law of thermodynamics, and the entropy does not follow the area law.

  20. Thermodynamics of asymptotically flat charged black holes in third order Lovelock gravity

    SciTech Connect (OSTI)

    Dehghani, M.H.; Shamirzaie, M.

    2005-12-15

    We present a new class of asymptotically flat charge static solutions in third order Lovelock gravity. These solutions present black hole solutions with two inner and outer event horizons, extreme black holes, or naked singularities provided the parameters of the solutions are chosen suitable. We find that the uncharged asymptotically flat solutions can present black holes with two inner and outer horizons. This kind of solution does not exist in Einstein or Gauss-Bonnet gravity, and it is a special effect in third order Lovelock gravity. We compute temperature, entropy, charge, electric potential, and mass of the black hole solutions, and find that these quantities satisfy the first law of thermodynamics. We also perform a stability analysis by computing the determinant of the Hessian matrix of the mass with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, and show that there exists only an intermediate stable phase.

  1. A combined experimental and computational thermodynamic investigation of the U-Th-O system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McMurray, Jake Wesley; Voit, Stewart L.; Besmann, Theodore M.

    2016-03-21

    Here, the thermodynamics of the U–Th–O system have been assessed using the Calphad method. The compound energy formalism (CEF) and a partially ionic two-sublattice liquid model (TSLM) were used for the fluorite U1–yThyO2±x, γ-(U,Th)4O9, and the U–Th–O melt. The O2 activity of fluorite U1–yThyO2±x with temperature and composition was determined by thermogravimetric analysis. Thermodynamic studies for the Th–O binary and U–Th–O ternary available in the open literature were critically reviewed. A self-consistent data set was selected and compiled with the equilibrium oxygen pressures determined by thermogravimetry in order to optimize the adjustable parameters of models selected to represent the phasesmore » in the Th–O and U–Th–O systems.« less

  2. Numerical prediction of the thermodynamic properties of ternary Al-Ni-Hf alloys

    SciTech Connect (OSTI)

    Romanowska, Jolanta; Kotowski, S?awomir; Zagula-Yavorska, Maryana

    2014-10-06

    Thermodynamic properties of ternary Al-Hf-Ni system, such as {sup ex}G, ?{sub Al}, ?{sub Ni} and ?{sub Zr} at 1373K were predicted on the basis of thermodynamic properties of binary systems included in the investigated ternary system. The idea of predicting {sup ex}G values was regarded as the calculation of excess Gibbs energy values inside a certain area (a Gibbs triangle) unless all boundary conditions, that is values of {sup ex}G on all legs of the triangle are known. {sup ex}G and L{sub ijk} ternary interaction parameters in the Muggianu extension of the Redlich-Kister formalism are calculated numerically using Wolfram Mathematica 9 software.

  3. Precision Plutonium Thermodynamics (Technical Report) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 36 MATERIALS SCIENCE Plutonium, ultrasound, thermodynamics ...

  4. Using ARM TWP Nauru Observations to Evaluate a Simple Thermodynamic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using ARM TWP Nauru Observations to Evaluate a Simple Thermodynamic Model of the Subcloud Layer Under Fair-Weather Cumulus Conditions Albrecht, Bruce University of Miami Kollias, ...

  5. Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Credit: National Institute of Standards Thermodynamic Evaluation of Low-Global Warming Potential Refrigerants Research & Development Roadmap: Next-Generation Low Global Warming ...

  6. Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalize...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalized Metal-Organic ... of CO2 on an alkylamine-appended MOF, mmen-Mg2(dobpdc) employing gas ...

  7. Thermodynamic Guidelines for the Prediction of Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Hydrogen Storage & Nanoscale Modeling Group Ford ...

  8. Thermodynamics of Iodide Adsorption at the Instantaneous Air...

    Office of Scientific and Technical Information (OSTI)

    proposed recently by Willard and Chandler.citechandler1 Referring structural and thermodynamic quantities to the instantaneous interface unmasks molecular-scale details that are...

  9. Thermodynamic Investigations of Lithium- and Manganese-Rich Transition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ...

  10. Finite-Temperature Hydrogen Adsorption and Desorption Thermodynamics...

    Office of Scientific and Technical Information (OSTI)

    Finite-Temperature Hydrogen Adsorption and Desorption Thermodynamics Driven by Soft Vibration Modes Citation Details In-Document Search Title: Finite-Temperature Hydrogen ...

  11. Thermodynamic theory of the plasmoelectric effect

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van de Groep, Jorik; Sheldon, Matthew T.; Atwater, Harry A.; Polman, Albert

    2016-03-18

    Resonant metal nanostructures exhibit an optically induced electrostatic potential when illuminated with monochromatic light under off-resonant conditions. This plasmoelectric effect is thermodynamically driven by the increase in entropy that occurs when the plasmonic structure aligns its resonant absorption spectrum with incident illumination by varying charge density. As a result, the elevated steady-state temperature of the nanostructure induced by plasmonic absorption is further increased by a small amount. Here, we study in detail the thermodynamic theory underlying the plasmoelectric effect by analyzing a simplified model system consisting of a single silver nanoparticle. We find that surface potentials as large as 473more » mV are induced under 100 W/m2 monochromatic illumination, as a result of a 11 mK increases in the steady-state temperature of the nanoparticle. Hence, we discuss the applicability of this analysis for realistic experimental geometries, and show that this effect is generic for optical structures in which the resonance is linked to the charge density.« less

  12. Energy Literacy: Essential Principles and Fundamental Concepts for Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education | Department of Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education Energy Literacy: Essential Principles and Fundamental Concepts for Energy Education News and Updates Check out our new Energy Literacy video series! The Energy Literacy Framework is also available in Spanish: Conocimiento de Energía. What is Energy Literacy? Energy Literacy is an understanding of the

  13. Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control the Impact on DPF Performance and Engine Efficiency | Department of Energy Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash

  14. Fundamental Research on Percussion Drilling: Improved rock mechanics...

    Office of Scientific and Technical Information (OSTI)

    Fundamental Research on Percussion Drilling: Improved rock mechanics analysis, advanced simulation technology, and full-scale laboratory investigations Citation Details In-Document...

  15. Vehicle Technologies Office Merit Review 2015: Fundamental Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office Merit Review 2014: Fundamental Studies of Lithium-Sulfur Cell Chemistry Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Vehicle Technologies...

  16. The fundamental solution of the unidirectional pulse propagation equation

    SciTech Connect (OSTI)

    Babushkin, I.; Bergé, L.

    2014-03-15

    The fundamental solution of a variant of the three-dimensional wave equation known as “unidirectional pulse propagation equation” (UPPE) and its paraxial approximation is obtained. It is shown that the fundamental solution can be presented as a projection of a fundamental solution of the wave equation to some functional subspace. We discuss the degree of equivalence of the UPPE and the wave equation in this respect. In particular, we show that the UPPE, in contrast to the common belief, describes wave propagation in both longitudinal and temporal directions, and, thereby, its fundamental solution possesses a non-causal character.

  17. Discovery of the Fundamental Mechanism of Action of Resveratrol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discovery of the Fundamental Mechanism of Action of Resveratrol Thursday, May 28, 2015 Resveratrol is reported to extend lifespan and provide cardio-neuro-protective, ...

  18. Nanoscale imaging of fundamental Li battery chemistry: solid...

    Office of Scientific and Technical Information (OSTI)

    Nanoscale imaging of fundamental Li battery chemistry: solid-electrolyte interphase formation and preferential growth of lithium metal nanoclusters Prev Next Title: Nanoscale ...

  19. The Department of Energy's National Security Information Fundamental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Department of Energy's National Security Information Fundamental Classification Guidance Review The goals of this review process was to evaluate the guidance content, determine ...

  20. COLLOQUIUM: Type II Solar Radio Bursts: From Fundamental Plasma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    distribution functions, the electron beams drive Langmuir waves, and the Langmuir waves couple linearly andor nonlinearly to produce the fundamental and harmonic radio emission. ...

  1. Fundamentals of XAFS (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Fundamentals of XAFS Citation Details In-Document Search Title: ... Publication Date: 2014-08-07 OSTI Identifier: 1149632 Resource Type: Journal Article ...

  2. Transition metals on the (0001) surface of graphite: Fundamental...

    Office of Scientific and Technical Information (OSTI)

    metals on the (0001) surface of graphite: Fundamental aspects of adsorption, diffusion, and morphology Citation Details In-Document Search Title: Transition metals on the...

  3. Fundamental study of the relationship of austenite-ferrite transformat...

    Broader source: Energy.gov (indexed) [DOE]

    Fundamental study of the relationship of austenite-ferrite transformation details to austenite retention in carbon steels FSW & USW Solid State Joining of Magnesium to Steel ...

  4. Fundamental Issues in Subzero PEMFC Startup and Operation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental issues in subzero PEMFC startup and operation Jeremy P. Meyers February 1, 2005 DOE Freeze Workshop Outline of presentation * Motivation * Stack performance * ...

  5. APS Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    next up previous Next: Main Parameters APS Storage Ring Parameters M. Borland, G. Decker, L. Emery, W. Guo, K. Harkay, V. Sajaev, C.-Y. Yao Advanced Photon Source September 8, 2010...

  6. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible)...

  7. Generalized second law of thermodynamics in f(T) gravity

    SciTech Connect (OSTI)

    Karami, K.; Abdolmaleki, A. E-mail: AAbdolmaleki@uok.ac.ir

    2012-04-01

    We investigate the validity of the generalized second law (GSL) of gravitational thermodynamics in the framework of f(T) modified teleparallel gravity. We consider a spatially flat FRW universe containing only the pressureless matter. The boundary of the universe is assumed to be enclosed by the Hubble horizon. For two viable f(T) models containing f(T) = T+?{sub 1}((?T)){sup n} and f(T) = T??{sub 2}T(1?e{sup ?T{sub 0}/T}), we first calculate the effective equation of state and deceleration parameters. Then, (we investigate the null and strong energy conditions and conclude that a sudden future singularity appears in both models. Furthermore, using a cosmographic analysis we check the viability of two models. Finally, we examine the validity of the GSL and find that for both models it) is satisfied from the early times to the present epoch. But in the future, the GSL is violated for the special ranges of the torsion scalar T.

  8. Thermodynamic properties of model CdTe/CdSe mixtures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    van Swol, Frank; Zhou, Xiaowang W.; Challa, Sivakumar R.; Martin, James E.

    2015-02-20

    We report on the thermodynamic properties of binary compound mixtures of model groups II–VI semiconductors. We use the recently introduced Stillinger–Weber Hamiltonian to model binary mixtures of CdTe and CdSe. We use molecular dynamics simulations to calculate the volume and enthalpy of mixing as a function of mole fraction. The lattice parameter of the mixture closely follows Vegard's law: a linear relation. This implies that the excess volume is a cubic function of mole fraction. A connection is made with hard sphere models of mixed fcc and zincblende structures. We found that the potential energy exhibits a positive deviation frommore » ideal soluton behaviour; the excess enthalpy is nearly independent of temperatures studied (300 and 533 K) and is well described by a simple cubic function of the mole fraction. Using a regular solution approach (combining non-ideal behaviour for the enthalpy with ideal solution behaviour for the entropy of mixing), we arrive at the Gibbs free energy of the mixture. The Gibbs free energy results indicate that the CdTe and CdSe mixtures exhibit phase separation. The upper consolute temperature is found to be 335 K. Finally, we provide the surface energy as a function of composition. Moreover, it roughly follows ideal solution theory, but with a negative deviation (negative excess surface energy). This indicates that alloying increases the stability, even for nano-particles.« less

  9. Molecular Dynamics Simulation of Thermodynamic Properties in Uranium Dioxide

    SciTech Connect (OSTI)

    Wang, Xiangyu; Wu, Bin; Gao, Fei; Li, Xin; Sun, Xin; Khaleel, Mohammad A.; Akinlalu, Ademola V.; Liu, L.

    2014-03-01

    In the present study, we investigated the thermodynamic properties of uranium dioxide (UO2) by molecular dynamics (MD) simulations. As for solid UO2, the lattice parameter, density, and enthalpy obtained by MD simulations were in good agreement with existing experimental data and previous theoretical predictions. The calculated thermal conductivities matched the experiment results at the midtemperature range but were underestimated at very low and very high temperatures. The calculation results of mean square displacement represented the stability of uranium at all temperatures and the high mobility of oxygen toward 3000 K. By fitting the diffusivity constant of oxygen with the Vogel-Fulcher-Tamman law, we noticed a secondary phase transition near 2006.4 K, which can be identified as a strong to fragile supercooled liquid or glass phase transition in UO2. By fitting the oxygen diffusion constant with the Arrhenius equation, activation energies of 2.0 and 2.7 eV that we obtained were fairly close to the recommended values of 2.3 to 2.6 eV. Xiangyu Wang, Bin Wu, Fei Gao, Xin Li, Xin Sun, Mohammed A. Khaleel, Ademola V. Akinlalu and Li Liu

  10. Thermodynamics in variable speed of light theories

    SciTech Connect (OSTI)

    Racker, Juan [CONICET, Centro Atomico Bariloche, Avenida Bustillo 9500 (8400), San Carlos De Bariloche (Argentina); Facultad de Ciencias Astronomicas y Geofisicas, Universidad Nacional de La Plata, Paseo del Bosque S/N (1900), La Plata (Argentina); Sisterna, Pablo [Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Mar del Plata, Funes 3350 (7600), Mar del Plata (Argentina); Vucetich, Hector [Facultad de Ciencias Astronomicas y Geofisicas, Universidad Nacional de La Plata, Paseo del Bosque S/N (1900), La Plata (Argentina)

    2009-10-15

    The perfect fluid in the context of a covariant variable speed of light theory proposed by J. Magueijo is studied. On the one hand the modified first law of thermodynamics together with a recipe to obtain equations of state are obtained. On the other hand the Newtonian limit is performed to obtain the nonrelativistic hydrostatic equilibrium equation for the theory. The results obtained are used to determine the time variation of the radius of Mercury induced by the variability of the speed of light (c), and the scalar contribution to the luminosity of white dwarfs. Using a bound for the change of that radius and combining it with an upper limit for the variation of the fine structure constant, a bound on the time variation of c is set. An independent bound is obtained from luminosity estimates for Stein 2015B.

  11. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26

    is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  12. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26

    is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  13. Lagrangian formulation of irreversible thermodynamics and the second law of thermodynamics

    SciTech Connect (OSTI)

    Glavatskiy, K. S.

    2015-05-28

    We show that the equations which describe irreversible evolution of a system can be derived from a variational principle. We suggest a Lagrangian, which depends on the properties of the normal and the so-called “mirror-image” system. The Lagrangian is symmetric in time and therefore compatible with microscopic reversibility. The evolution equations in the normal and mirror-imaged systems are decoupled and describe therefore independent irreversible evolution of each of the systems. The second law of thermodynamics follows from a symmetry of the Lagrangian. Entropy increase in the normal system is balanced by the entropy decrease in the mirror-image system, such that there exists an “integral of evolution” which is a constant. The derivation relies on the property of local equilibrium, which states that the local relations between the thermodynamic quantities in non-equilibrium are the same as in equilibrium.

  14. Gyromagnetic factors and atomic clock constraints on the variation of fundamental constants

    SciTech Connect (OSTI)

    Luo Feng; Olive, Keith A.; Uzan, Jean-Philippe

    2011-11-01

    We consider the effect of the coupled variations of fundamental constants on the nucleon magnetic moment. The nucleon g-factor enters into the interpretation of the measurements of variations in the fine-structure constant, {alpha}, in both the laboratory (through atomic clock measurements) and in astrophysical systems (e.g. through measurements of the 21 cm transitions). A null result can be translated into a limit on the variation of a set of fundamental constants, that is usually reduced to {alpha}. However, in specific models, particularly unification models, changes in {alpha} are always accompanied by corresponding changes in other fundamental quantities such as the QCD scale, {Lambda}{sub QCD}. This work tracks the changes in the nucleon g-factors induced from changes in {Lambda}{sub QCD} and the light quark masses. In principle, these coupled variations can improve the bounds on the variation of {alpha} by an order of magnitude from existing atomic clock and astrophysical measurements. Unfortunately, the calculation of the dependence of g-factors on fundamental parameters is notoriously model-dependent.

  15. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01

    is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature

  16. Thermodynamic modeling of lead distribution among matte, slag, and liquid copper

    SciTech Connect (OSTI)

    Degterov, S.A.; Pelton, A.D.

    1999-12-01

    Recently, a thermodynamic database was developed for the calculation of equilibria involved in the production of copper. The present study is concerned with the further development of the thermodynamic models and the database of model parameters for the matte, slag, and blister copper phases with a view to including Pb in the database and phase equilibrium data available in the literature are reviewed, critically assessed, and optimized with the modified quasi-chemical model. When used with the Gibbs energy minimization software and other databases of the FACT thermodynamic computing system, the database developed in the present study can be used for the calculation of matte-slag-copper-gas phase equilibria during copper smelting and converting. The distribution of lead among these phases can be computed. For example, the distribution of lead among matte, silica-saturated slag, and copper has been calculated at metal saturation, or under fixed partial pressure of SO{sub 2}, and has been compared with the available experimental data. The Pb distributions among the equilibrium phases have been calculated under various conditions, which are difficult to study experimentally, such as at magnetite saturation or under various oxygen partial pressures and iron to silica ratios in the slag.

  17. Determination of the molecular area on a liquid surface from thermodynamic functions: Application to alkanes

    SciTech Connect (OSTI)

    Carre, A.; Vial, J. )

    1993-10-15

    A method is proposed to calculate the molecular area on the surface of a liquid from thermodynamic parameters such as the molar internal energy, the surface free energy, and the surface entropy. When the method is applied to the series of normal alkanes, it allows calculation of the area of the molecules on these liquid surfaces and to deduce the orientation of these molecules. Moreover, the molecular areas of the first terms of the alkane series and of hydrogen are also obtained by extrapolation.

  18. Thermodynamics of Taub-NUT/bolt-AdS black holes in Einstein-Gauss-Bonnet gravity

    SciTech Connect (OSTI)

    Khodam-Mohammadi, A.; Monshizadeh, M.

    2009-02-15

    We give a review of the existence of Taub-NUT/bolt solutions in Einstein Gauss-Bonnet gravity with the parameter {alpha} in six dimensions. Although the spacetime with base space S{sup 2}xS{sup 2} has a curvature singularity at r=N, which does not admit NUT solutions, we may proceed with the same computations as in the CP{sup 2} case. The investigation of thermodynamics of NUT/bolt solutions in six dimensions is carried out. We compute the finite action, mass, entropy, and temperature of the black hole. Then the validity of the first law of thermodynamics is demonstrated. It is shown that in NUT solutions all thermodynamic quantities for both base spaces are related to each other by substituting {alpha}{sup CP{sup k}}=[(k+1)/k]{alpha}{sup S{sup 2}}{sup xS{sup 2}}{sup x...S{sub k}{sup 2}}. So, no further information is given by investigating NUT solutions in the S{sup 2}xS{sup 2} case. This relation is not true for bolt solutions. A generalization of the thermodynamics of black holes to arbitrary even dimensions is made using a new method based on the Gibbs-Duhem relation and Gibbs free energy for NUT solutions. According to this method, the finite action in Einstein Gauss-Bonnet is obtained by considering the generalized finite action in Einstein gravity with an additional term as a function of {alpha}. Stability analysis is done by investigating the heat capacity and entropy in the allowed range of {alpha}, {lambda}, and N. For NUT solutions in d dimensions, there exists a stable phase at a narrow range of {alpha}. In six-dimensional bolt solutions, the metric is completely stable for B=S{sup 2}xS{sup 2} and is completely unstable for the B=CP{sup 2} case.

  19. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They

  20. The impact of vertical shear on the sensitivity of tropical cyclogenesis to environmental rotation and thermodynamic state

    SciTech Connect (OSTI)

    Zhou, Wenyu

    2015-11-19

    Here, the impact of vertical wind shear on the sensitivity of tropical cyclogenesis to environmental rotation and thermodynamic state is investigated through idealized cloud-resolving simulations of the intensification of an incipient vortex. With vertical shear, tropical cyclones intensify faster with a higher Coriolis parameter, f, irrespective of the environmental thermodynamic state. The vertical shear develops a vertically tilted vortex, which undergoes a precession process with the midlevel vortices rotating cyclonically around the surface center. With a higher f, the midlevel vortices are able to rotate continuously against the vertical shear, leading to the realignment of the tilted vortex and rapid intensification. With a lower f, the rotation is too slow such that the midlevel vortices are advected away from the surface center and the intensification is suppressed. The parameter, Χb, measuring the effect from the low-entropy downdraft air on the boundary layer entropy, is found to be a good indicator of the environmental thermodynamic favorability for tropical cyclogenesis in vertical shear. Without vertical shear, tropical cyclones are found to intensify faster with a lower f by previous studies. We show this dependency on f is sensitive to the environmental thermodynamic state. The thermodynamical favorability for convection can be measured by Χm, which estimates the time it takes for surface fluxes to moisten the midtroposphere. A smaller Χm not only leads to a faster intensification due to a shorter period for moist preconditioning of the inner region but also neutralizes the faster intensification with a lower f due to enhanced peripheral convection.

  1. The impact of vertical shear on the sensitivity of tropical cyclogenesis to environmental rotation and thermodynamic state

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhou, Wenyu

    2015-11-19

    Here, the impact of vertical wind shear on the sensitivity of tropical cyclogenesis to environmental rotation and thermodynamic state is investigated through idealized cloud-resolving simulations of the intensification of an incipient vortex. With vertical shear, tropical cyclones intensify faster with a higher Coriolis parameter, f, irrespective of the environmental thermodynamic state. The vertical shear develops a vertically tilted vortex, which undergoes a precession process with the midlevel vortices rotating cyclonically around the surface center. With a higher f, the midlevel vortices are able to rotate continuously against the vertical shear, leading to the realignment of the tilted vortex and rapidmore » intensification. With a lower f, the rotation is too slow such that the midlevel vortices are advected away from the surface center and the intensification is suppressed. The parameter, Χb, measuring the effect from the low-entropy downdraft air on the boundary layer entropy, is found to be a good indicator of the environmental thermodynamic favorability for tropical cyclogenesis in vertical shear. Without vertical shear, tropical cyclones are found to intensify faster with a lower f by previous studies. We show this dependency on f is sensitive to the environmental thermodynamic state. The thermodynamical favorability for convection can be measured by Χm, which estimates the time it takes for surface fluxes to moisten the midtroposphere. A smaller Χm not only leads to a faster intensification due to a shorter period for moist preconditioning of the inner region but also neutralizes the faster intensification with a lower f due to enhanced peripheral convection.« less

  2. Proton Dripping Tests a Fundamental Force of Nature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    off, similar to the water in this photo, leaving an oxygen-13 nucleus behind. Like gravity, the strong interaction is a fundamental force of nature. It is the essential "glue"...

  3. Uncovering Fundamental Ash-Formation Mechanisms and Potential...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties deer12kamp.pdf (9.21 MB) ...

  4. Expanding the Fundamental Chemistry of Thorium Through the Synthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Expanding the Fundamental Chemistry of Thorium Through the Synthesis and Reactivity of the First Molecular Complexes of Th(II) and New Classes of Th(III) and Th(IV) August 29, 2016 ...

  5. Fuel-Cell Fundamentals at Low and Subzero Temperatures

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Fundamentals at Low and Subzero Temperatures Adam Z. Weber (PI), John Newman, Clayton Radke LBNL Rangachary Mukundan, Rodney Borup LANL Michael Perry UTRC Mark Debe 3M Chao-Yang Wang PSU This presentation does not contain any proprietary or confidential information Objectives  Fundamental understanding of transport phenomena and water and thermal management at low and subzero temperatures using state-of-the-art materials  Enable optimization strategies to be developed to overcome

  6. Fundamental Study of the Mechanical Strength Degradation Mechanisms of PFSA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Membranes and MEAs | Department of Energy Fundamental Study of the Mechanical Strength Degradation Mechanisms of PFSA Membranes and MEAs Fundamental Study of the Mechanical Strength Degradation Mechanisms of PFSA Membranes and MEAs Presentation at the 2008 High Temperature Membrane Working Group Meeting held June 9, 2008, in Washington, DC huang_htmwg_2008.pdf (2.27 MB) More Documents & Publications Membrane Durability in PEM Fuel Cells: Chemical Degradation Automotive Perspective on PEM

  7. Weatherization Installer/Technician Fundamentals 2.0 - Moisture Barriers |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Moisture Barriers Weatherization Installer/Technician Fundamentals 2.0 - Moisture Barriers Moisture Barriers - Complete (2.34 MB) Lesson Plan: Moisture Barriers (107.22 KB) PowerPoint: Moisture Barriers (2.31 MB) More Documents & Publications Energy Auditor - Single Family 2.0: Moisture Assessment Weatherization Installer/Technician Fundamentals 2.0 - Roofing, Flashing, and Attic Ventilation Installation Needs Energy Auditor - Single Family 2.0: Building Shell

  8. Bridging the Gap between Fundamental Physics and Chemistry and Applied

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Models for HCCI Engines | Department of Energy Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_assanis.pdf (1.42 MB) More Documents & Publications Computationally Efficient Modeling of High-Efficiency Clean Combustion Engines Modeling of HCCI and PCCI

  9. The Department of Energy's National Security Information Fundamental

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Classification Guidance Review | Department of Energy The Department of Energy's National Security Information Fundamental Classification Guidance Review The Department of Energy's National Security Information Fundamental Classification Guidance Review The goals of this review process was to evaluate the guidance content, determine if the guidance conforms to current operational and technical circumstances, determine if the guidance meets the standards for classification under section 1.4

  10. Fundamental Interactions | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fundamental Interactions Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Fundamental Interactions Print Text Size: A A A FeedbackShare Page Research emphasis is placed on structural and dynamical studies of atoms, molecules, and nanostructures, and the description of their

  11. DOE Fundamentals Handbook: Instrumentation and Control, Volume 2

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Instrumentation and Control Fundamentals Handbook personnel, and the technical staff facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of instrumentation and control systems. The handbook includes information on temperature, pressure, flow, and level detection systems; position indication systems; process control systems; and radiation detection principles. This information will provide personnel with an understanding of the basic operation of various types of DOE nuclear facility instrumentation and control systems.

  12. Advancing the Fundamental Understanding of Fission: 2014 LDRD 20120077DR

    Office of Scientific and Technical Information (OSTI)

    Review (Technical Report) | SciTech Connect Advancing the Fundamental Understanding of Fission: 2014 LDRD 20120077DR Review Citation Details In-Document Search Title: Advancing the Fundamental Understanding of Fission: 2014 LDRD 20120077DR Review The following slides were presented as part of the LDRD 20120077DR Progress Appraisal Review held Tuesday, February 4, 2014. This is part of an ongoing project assessment the previous of which was documented in LA-UR-13-21182. This presentation

  13. Project Profile: Fundamental Corrosion Studies in High-Temperature Molten

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Salt Systems for Next-Generation CSP Systems | Department of Energy Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems Project Profile: Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems Savannah River National Laboratory logo -- This project is inactive -- The Savannah River National Laboratory (SRNL), under the National Laboratory R&D competitive funding opportunity, is working with

  14. Caltech announces discovery in fundamental physics | Argonne National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Caltech announces discovery in fundamental physics August 18, 2015 Tweet EmailPrint This press release was originally printed by CalTech. When the transistor was invented in 1947 at Bell Labs, few could have foreseen the future impact of the device. This fundamental development in science and engineering was critical to the invention of handheld radios, led to modern computing, and enabled technologies such as the smartphone. This is one of the values of basic research. In a

  15. DOE Fundamentals Handbook: Instrumentation and Control, Volume 1

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The Instrumentation and Control Fundamentals Handbook was developed to assist nuclear facility operating contractors provide operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of instrumentation and control systems. The handbook includes information on temperature, pressure, flow, and level detection systems; position indication systems; process control systems; and radiation detection principles. This information will provide personnel with an understanding of the basic operation of various types of DOE nuclear facility instrumentation and control systems.

  16. Coal surface structure and thermodynamics. Final report

    SciTech Connect (OSTI)

    Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

    1994-05-01

    Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

  17. Thermodynamic analysis of adsorption refrigeration cycles

    SciTech Connect (OSTI)

    Saha, B.B.; Akisawa, Atsushi; Kashiwagi, Takao

    1997-12-31

    High- and mid-temperature waste heat can be recovered by using existing heat pump technologies. However, heat utilization near environmental temperatures still faces technical hurdles. Silica gel-water adsorption cycles have a distinct advantage over other systems in their ability to be driven by near-ambient temperature heat. Waste heat (above 60 C) can be exploited by using conventional silica gel-water adsorption chiller. The advanced silica gel-water adsorption chiller can operate effectively by utilizing low-grade waste heat ({approximately}50 C) as the driving source with a cooling source of 30 C. In this paper, the effect of operating temperatures on cycle performance is discussed from the thermodynamic viewpoint. The temperature effectiveness and the entropy generation number on cycle time are analyzed. For a comparatively short cycle time, adsorber/desorber heat exchanger temperature effectiveness reaches up to 92% after only 200 sec. The entropy generation number N{sub s} is defined by the ratio between irreversibility generated during a cycle and availability of the heat transfer fluid. The result showed that for the advanced adsorption cycle the entropy generation number N{sub s} is smaller for hot water temperature between 45 to 55 C with a cooling source of 30 C, while for the conventional cycle N{sub s} is smaller for hot water temperature between 65 to 75 C /with the same cooling source temperature.

  18. Thermodynamic behavior of particular f(R,T)-gravity models

    SciTech Connect (OSTI)

    Sharif, M. Zubair, M.

    2013-08-15

    We investigate the thermodynamics at the apparent horizon of the FRW universe in f(R, T) theory in the nonequilibrium description. The laws of thermodynamics are discussed for two particular models of the f(R, T) theory. The first law of thermodynamics is expressed in the form of the Clausius relation T{sub h} dS-circumflex{sub h} = {delta} Q , where {delta}Q is the energy flux across the horizon and dS-circumflex is the entropy production term. Furthermore, the conditions for the generalized second law of thermodynamics to be preserved are established with the constraints of positive temperature and attractive gravity. We illustrate our results for some concrete models in this theory.

  19. Relevance of the second law of thermodynamics to energy conservation

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    An analysis is presented of the potential relevance of the use of analytical tools based on the Second Law of thermodynamics to existing federal programs for energy conservation in the industrial, transportation, buildings, and utility sectors in the US. (LCL)

  20. Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalize...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermodynamic Complexity of Carbon Capture in Alkylamine-Functionalized Metal-Organic Frameworks Previous Next List D. Wu, T. M. McDonald, Z. Quan, S. V. Ushakov, P. Zhang, J. R....

  1. Thermodynamics of Quark Flavors from Lattice QCD | Argonne Leadership...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ian McVicar, University of Glasgow (Courtesy of ALICE and CERN) Thermodynamics of Quark ... that ordinary hadronic matter will undergo a phase transition to quark-gluon plasma (QGP). ...

  2. Thermodynamic Advantages of Low Temperature Combustion Engines Including

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Use of Low Heat Rejection Concepts | Department of Energy Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic Advantages of Low Temperature Combustion Engines Including the Use of Low Heat Rejection Concepts Thermodynamic cycle simulation was used to evaluate low temperature combustion in systematic and sequential fashion to base engine design. deer10_caton.pdf (462.23 KB) More Documents & Publications Boosted HCCI for High

  3. Statistical thermodynamics model and empirical correlations for predicting

    Office of Scientific and Technical Information (OSTI)

    mixed hydrate phase equilibria (Journal Article) | SciTech Connect Statistical thermodynamics model and empirical correlations for predicting mixed hydrate phase equilibria Citation Details In-Document Search Title: Statistical thermodynamics model and empirical correlations for predicting mixed hydrate phase equilibria Authors: Garapati, Nagasree ; Anderson, Brian J Publication Date: 2014-07-01 OSTI Identifier: 1165558 Report Number(s): A-UNIV-PUB-100 Journal ID: ISSN 0378-3812 DOE Contract

  4. Quadractic Model of Thermodynamic States in SDF Explosions

    SciTech Connect (OSTI)

    Kuhl, A L; Khasainov, B

    2007-05-04

    We study the thermodynamic states encountered during Shock-Dispersed-Fuel (SDF) explosions. Such explosions contain up to six components: three fuels (PETN, TNT and Aluminum) and their products corresponding to stoichiometric combustion with air. We establish the loci in thermodynamic state space that correctly describes the behavior of the components. Results are fit with quadratic functions that serve as fast equations of state suitable for 3D numerical simulations of SDF explosions.

  5. Combined thermodynamic study of nickel-base alloys. Progress report

    SciTech Connect (OSTI)

    Brooks, C. R.; Meschter, P. J.

    1981-02-15

    Achievements during this period are the following: (1) initiation of a high-temperature study of the Ni-Ta system using the galvanic cell technique, (2) emf study of high-temperature thermodynamics in the Ni-Mo system, (3) measured heat capacity data on ordered and disordered Ni/sub 4/Mo, (4) heat capacities of Ni and disordered Ni/sub 3/Fe, and (5) computer correlation of thermodynamic and phase diagram data in binary Ni-base alloys. (MOW)

  6. A thermodynamic model to predict the aqueous solubility of hydrocarbon

    Office of Scientific and Technical Information (OSTI)

    mixtures at two-phase hydrate-liquid water equilibrium (Journal Article) | SciTech Connect Journal Article: A thermodynamic model to predict the aqueous solubility of hydrocarbon mixtures at two-phase hydrate-liquid water equilibrium Citation Details In-Document Search This content will become publicly available on March 30, 2018 Title: A thermodynamic model to predict the aqueous solubility of hydrocarbon mixtures at two-phase hydrate-liquid water equilibrium Authors: Velaga, Srinath C.

  7. Thermodynamics of rotating black branes in (n+1)-dimensional Einstein-Born-Infeld gravity

    SciTech Connect (OSTI)

    Dehghani, M. H.; Sedehi, H. R. Rastegar

    2006-12-15

    We construct a new class of charged rotating solutions of (n+1)-dimensional Einstein-Born-Infeld gravity with cylindrical or toroidal horizons in the presence of cosmological constant and investigate their properties. These solutions are asymptotically (anti)-de Sitter and reduce to the solutions of Einstein-Maxwell gravity as the Born-Infeld parameters goes to infinity. We find that these solutions can represent black branes, with inner and outer event horizons, an extreme black brane or a naked singularity provided the parameters of the solutions are chosen suitably. We compute temperature, mass, angular momentum, entropy, charge and electric potential of the black brane solutions. We obtain a Smarr-type formula and show that these quantities satisfy the first law of thermodynamics. We also perform a stability analysis by computing the heat capacity and the determinant of Hessian matrix of mass of the system with infinite boundary with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, and show that the system is thermally stable in the whole phase space. Also, we find that there exists an unstable phase when the finite size effect is taken into account.

  8. Thermodynamics of rotating charged black branes in third order lovelock gravity and the counterterm method

    SciTech Connect (OSTI)

    Dehghani, M.H.; Mann, R.B.

    2006-05-15

    We generalize the quasilocal definition of the stress-energy tensor of Einstein gravity to the case of third order Lovelock gravity, by introducing the surface terms that make the action well-defined. We also introduce the boundary counterterm that removes the divergences of the action and the conserved quantities of the solutions of third order Lovelock gravity with zero curvature boundary at constant t and r. Then, we compute the charged rotating solutions of this theory in n+1 dimensions with a complete set of allowed rotation parameters. These charged rotating solutions present black hole solutions with two inner and outer event horizons, extreme black holes or naked singularities provided the parameters of the solutions are suitably chosen. We compute temperature, entropy, charge, electric potential, mass and angular momenta of the black hole solutions, and find that these quantities satisfy the first law of thermodynamics. We find a Smarr-type formula and perform a stability analysis by computing the heat capacity and the determinant of Hessian matrix of mass with respect to its thermodynamic variables in both the canonical and the grand-canonical ensembles, and show that the system is thermally stable. This is commensurate with the fact that there is no Hawking-Page phase transition for black objects with zero curvature horizon.

  9. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible) Beam current (all operation is in top-off with ΔI/I ≤ 0.3%) 500 mA in multibunch mode 2 x 17.5 mA in two-bunch mode Filling pattern (multibunch mode) 256-320 bunches; possibility of one or two 5- to 6-mA "camshaft" bunches in filling gaps Bunch spacing: multibunch mode 2 ns Bunch

  10. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    There are small sector-to-sector variations in the parameters for a given source angle because of the distortion in the lattice functions of the superbends and the...

  11. THERMODYNAMICS OF THE COMA CLUSTER OUTSKIRTS

    SciTech Connect (OSTI)

    Simionescu, A.; Werner, N.; Urban, O.; Allen, S. W.; Fabian, A. C.; Sanders, J. S.; Walker, S. A.; Mantz, A.; Matsushita, K.; Sasaki, T.; Sato, T.; Nulsen, P. E. J.; Takei, Y.

    2013-09-20

    We present results from a large mosaic of Suzaku observations of the Coma Cluster, the nearest and X-ray brightest hot ({approx}8 keV), dynamically active, non-cool core system, focusing on the thermodynamic properties of the intracluster medium on large scales. For azimuths not aligned with an infalling subcluster toward the southwest, our measured temperature and X-ray brightness profiles exhibit broadly consistent radial trends, with the temperature decreasing from about 8.5 keV at the cluster center to about 2 keV at a radius of 2 Mpc, which is the edge of our detection limit. The southwest merger significantly boosts the surface brightness, allowing us to detect X-ray emission out to {approx}2.2 Mpc along this direction. Apart from the southwestern infalling subcluster, the surface brightness profiles show multiple edges around radii of 30-40 arcmin. The azimuthally averaged temperature profile, as well as the deprojected density and pressure profiles, all show a sharp drop consistent with an outwardly-propagating shock front located at 40 arcmin, corresponding to the outermost edge of the giant radio halo observed at 352 MHz with the Westerbork Synthesis Radio Telescope. The shock front may be powering this radio emission. A clear entropy excess inside of r{sub 500} reflects the violent merging events linked with these morphological features. Beyond r{sub 500}, the entropy profiles of the Coma Cluster along the relatively relaxed directions are consistent with the power-law behavior expected from simple models of gravitational large-scale structure formation. The pressure is also in agreement at these radii with the expected values measured from Sunyaev-Zel'dovich data from the Planck satellite. However, due to the large uncertainties associated with the Coma Cluster measurements, we cannot yet exclude an entropy flattening in this system consistent with that seen in more relaxed cool core clusters.

  12. Supersymmetry Parameter Analysis: SPA Convention and Project

    SciTech Connect (OSTI)

    Hinchliffe, I.; et al.

    2005-05-05

    High-precision analyses of supersymmetry parameters aim atreconstructing the fundamental supersymmetric theory and its breakingmechanism. A well defined theoretical framework is needed whenhigher-order corrections are included. We propose such a scheme,Supersymmetry Parameter Analysis SPA, based on a consistent set ofconventions and input parameters. A repository for computer programs isprovided which connect parameters in different schemes and relate theLagrangian parameters to physical observables at LHC and high energy e+e-linear collider experiments, i.e., masses, mixings, decay widths andproduction cross sections for supersymmetric particles. In addition,programs for calculating high-precision low energy observables, thedensity of cold dark matter (CDM) in the universe as well as the crosssections for CDM search experiments are included. The SPA scheme stillrequires extended efforts on both the theoretical and experimental sidebefore data can be evaluated in the future at the level of the desiredprecision. We take here an initial step of testing the SPA scheme byapplying the techniques involved to a specific supersymmetry referencepoint.

  13. COLLOQUIUM: Fundamental Physics and the LHC: A Progress Report | Princeton

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plasma Physics Lab 17, 2013, 4:15pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Fundamental Physics and the LHC: A Progress Report Professor Nima Arkani-Hamed The Institute for Advanced Study Presentation: PDF icon WC17APR2013_NAHamed.pdf Last July's discovery of the Higgs particle at the Large Hadron Collider was a triumph for both experiment and theory in fundamental physics. But the Higgs also introduces major conceptual paradoxes that strongly suggest we are missing essential new

  14. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible) Beam current (all operation is in top-off with ΔI/I ≤ 0.3%) 500 mA in multibunch mode 2 x 17.5 mA in two-bunch mode Filling pattern (multibunch mode) 256-320 bunches; possibility of one or two 5- to 6-mA "camshaft" bunches in filling gaps Bunch spacing: multibunch mode 2 ns Bunch spacing: two-bunch mode 328

  15. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible) Beam current (all operation is in top-off with ΔI/I ≤ 0.3%) 500 mA in multibunch mode 2 x 17.5 mA in two-bunch mode Filling pattern (multibunch mode) 256-320 bunches; possibility of one or two 5- to 6-mA "camshaft" bunches in filling gaps Bunch spacing: multibunch mode 2 ns Bunch spacing: two-bunch mode 328

  16. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible) Beam current (all operation is in top-off with ΔI/I ≤ 0.3%) 500 mA in multibunch mode 2 x 17.5 mA in two-bunch mode Filling pattern (multibunch mode) 256-320 bunches; possibility of one or two 5- to 6-mA "camshaft" bunches in filling gaps Bunch spacing: multibunch mode 2 ns Bunch spacing: two-bunch mode 328

  17. Storage Ring Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Ring Parameters Print General Parameters Parameter Value Beam particle electron Beam energy 1.9 GeV (1.0-1.9 GeV possible) Injection energy 1.9 GeV (1.0-1.9 GeV possible) Beam current (all operation is in top-off with ΔI/I ≤ 0.3%) 500 mA in multibunch mode 2 x 17.5 mA in two-bunch mode Filling pattern (multibunch mode) 256-320 bunches; possibility of one or two 5- to 6-mA "camshaft" bunches in filling gaps Bunch spacing: multibunch mode 2 ns Bunch spacing: two-bunch mode 328

  18. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  19. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  20. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  1. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  2. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  3. Photon Source Parameters

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photon Source Parameters Print Summary Graph of Brightness Curves for All Insertion Devices Insertion Device and Bend Magnet Parameters Bend Magnet Superbend Magnet U30 Undulator U50 Undulator U80 Undulator U100 Undulator W114 Wiggler The ALS has six elliptically polarizing undulators, two in straight 4, two in straight 11, and one each in straights 6 and 7. All are arranged with chicanes so that two such devices can be installed to feed two independent beamlines. They can be used in a variety

  4. Dealing with Multipacting in Fundamental Power Couplers for SRF Cavities

    SciTech Connect (OSTI)

    Mircea Stirbet

    2005-03-19

    Multipacting events are well known and bothersome discharge phenomena specific to vacuum and RF exposed surfaces. Left uncontrolled, these events could affect normal machine operation, limiting performance or inducing irreversible damage of critical components such as ceramic windows. Numerical simulations have been developed and their predictions fit fairly well with real multipacting events in coaxial lines or waveguide-type fundamental power couplers. Controlling multipacting must be considered from the design stage, as well as during manufacture of subassemblies or preparation of the coupler for cavity assembly. All fundamental power couplers must be conditioned using a high power RF source, and during this process, restricting multipacting by adequate instrumentation should be considered. After RF conditioning, during beam acceleration, control of multipacting is achieved with field perturbation methods. This paper summarizes our experience in dealing with multipacting in CW or pulsed fundamental power couplers (LEP, LHC, SNS and RIA) for SRF cavities. The SNS fundamental power coupler is used as an example for controlling multipacting during high power RF conditioning.

  5. Emergency Management Fundamentals and the Operational Emergency Base Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides information about the emergency management fundamentals imbedded in the requirements of DOE O 151.1C, as well as acceptable methods of meeting the requirements for the Operational Emergency Base Program, which ensures that all DOE facilities have effective capabilities for all emergency response. Supersedes DOE G 151.1-1, Volume 1.

  6. Thermodynamic model for calorimetric and phase coexistence properties of coal derived fluids. Final technical report

    SciTech Connect (OSTI)

    Kabadi, V.N.

    1992-10-01

    The work on this project was initiated on September 1, 1989. The project consisted of three different tasks. 1. A thermodynamic model to predict VLE and calorimetric properties of coal liquids. 2. VLE measurements at high temperature and high pressure for coal model compounds and 3. Chromatographic characterization of coal liquids for distribution of heteroatoms. The thermodynamic model developed is an extension of the previous model developed for VLE of coal derived fluids (DOE Grant no. FG22-86PC90541). The model uses the modified UNIFAC correlation for the liquid phase. Some unavailable UNIFAC interactions parameters have been regressed from experimental VLE and excess enthalpy data. The model is successful in predicting binary VLE and excess enthalpy data. Further refinements of the model are suggested. An apparatus for the high pressure high temperature VLE data measurements has been built and tested. Tetralin-Quinoline is the first binary system selected for data measurements. The equipment was tested by measuring 325{degree}C isotherm for this system and comparing it with literature data. Additional isotherms at 350{degree}C and 370{degree}C have been measured. The framework for a characterization procedure for coal derived liquids has been developed. A coal liquid is defined by a true molecular weight distribution and distribution of heteroatoms as a function of molecular weights. Size exclusions liquid chromatography, elemental analysis and FTIR spectroscopy methods are used to obtain the molecular weight and hetroatom distributions. Further work in this area should include refinements of the characterization procedure, high temperature high pressure VLE data measurements for selective model compound binary systems, and improvement of the thermodynamic model using the new measured data and consistent with the developments in the characterization procedure.

  7. Thermodynamics of Taub-NUT/bolt black holes in Einstein-Maxwell gravity

    SciTech Connect (OSTI)

    Dehghani, M.H.; Khodam-Mohammadi, A.

    2006-06-15

    First, we construct the Taub-NUT/bolt solutions of (2k+2)-dimensional Einstein-Maxwell gravity, when all the factor spaces of 2k-dimensional base space B have positive curvature. These solutions depend on two extra parameters, other than the mass and the NUT charge. These are electric charge q and electric potential at infinity V. We investigate the existence of Taub-NUT solutions and find that in addition to the two conditions of uncharged NUT solutions, there exist two extra conditions. These two extra conditions come from the regularity of vector potential at r=N and the fact that the horizon at r=N should be the outer horizon of the NUT charged black hole. We find that the NUT solutions in 2k+2 dimensions have no curvature singularity at r=N, when the 2k-dimensional base space is chosen to be CP{sup 2k}. For bolt solutions, there exists an upper limit for the NUT parameter which decreases as the potential parameter increases. Second, we study the thermodynamics of these spacetimes. We compute temperature, entropy, charge, electric potential, action and mass of the black hole solutions, and find that these quantities satisfy the first law of thermodynamics. We perform a stability analysis by computing the heat capacity, and show that the NUT solutions are not thermally stable for even k's, while there exists a stable phase for odd k's, which becomes increasingly narrow with increasing dimensionality and wide with increasing V. We also study the phase behavior of the 4 and 6 dimensional bolt solutions in canonical ensemble and find that these solutions have a stable phase, which becomes smaller as V increases.

  8. Eternal inflation and a thermodynamic treatment of Einstein's equations

    SciTech Connect (OSTI)

    Ghersi, José Tomás Gálvez; Geshnizjani, Ghazal; Shandera, Sarah; Piazza, Federico E-mail: ggeshnizjani@perimeterinstitute.ca E-mail: sshandera@perimeterinstitute.ca

    2011-06-01

    In pursuing the intriguing resemblance of the Einstein equations to thermodynamic equations, most sharply seen in systems possessing horizons, we suggest that eternal inflation of the stochastic type may be a fruitful phenomenon to explore. We develop a thermodynamic first law for quasi-de Sitter space, valid on the horizon of a single observer's Hubble patch and explore consistancy with previous proposals for horizons of various types in dynamic and static situations. We use this framework to demonstrate that for the local observer fluctuations of the type necessary for stochastic eternal inflation fall within the regime where the thermodynamic approach is believed to apply. This scenario is interesting because of suggestive parallels with black hole evaporation.

  9. Nanoscale Molecules Under Thermodynamic Control:" Digestive Ripening" or " Nanomachining"

    SciTech Connect (OSTI)

    Klabunde, Kenneth J.

    2015-06-04

    Overall Research Goals and Specific Objectives: Nanoscale materials are becoming ubiquitous in science and engineering, and are found widely in nature. However, their formation processes and uniquely high chemical reactivities are not understood well, indeed are often mysterious. Over recent years, a number of research teams have described nanoparticle synthesis, and aging, thermal treatment, or etching times have been mentioned. We have used the terms “digestive ripening” and “nanomachining” and have suggested that thermodynamics plays an important part in the size adjustment to monodisperse arrays being formed. Since there is scant theoretical understanding of digestive ripening, the overall goal in our research is to learn what experimental parameters (ligand used, temperature, solvent, time) are most important, how to control nanoparticle size and shape after initial crude nanoparticles have been synthesized, and gain better understanding of the chemical mechanism details. Specific objectives for the past twentynine months since the grant began have been to (1) Secure and train personnel;as of 2011, a postdoc Deepa Jose, female from the Indian Institute of Science in Bangalore, India; Yijun Sun, a second year graduate student, female from China; and Jessica Changstrom, female from the USA, GK12 fellow (program for enhancing teaching ability) are actively carrying out research. (2) Find out what happens to sulfur bound hydrogen of thiol when it interacts with gold nanoparticles. Our findings are discussed in detail later. (3) Determine the effect of particle size, shape, and temperature on dodecyl thiol assited digestive ripening of gold nanoparticles. See our discussions later. (4) To understand in detail the ligand interaction in molecular clusters and nanoparticles (5) Determine the effect of chain length of amines on Au nanoparticle size under digestive ripening conditions (carbon chain length varied from 4-18). (6) Determine the catalytic activity

  10. Molecular Thermodynamics for Swelling of a Mesoscopic Ionomer Gelin 1:1 Salt Solutions

    SciTech Connect (OSTI)

    Victorov, Alexey; Radke, Clayton; Prausnitz,John

    2005-06-15

    For a microphase-separated diblock copolymer ionic gel swollen in salt solution, a molecular-thermodynamic model is based on the self-consistent field theory in the limit of strongly segregated copolymer subchains. The geometry of microdomains is described using the Milner generic wedge construction neglecting the packing frustration. Thermodynamic functions are expressed analytically for gels of lamellar, bicontinuous, cylindrical and spherical morphologies. Molecules are characterized by chain composition, length, rigidity, degree of ionization, and by effective polymer-polymer and polymer-solvent interaction parameters. The model predicts equilibrium solvent uptakes and the equilibrium microdomain spacing for gels swollen in salt solutions. Results are given for details of the gel structure: distribution of mobile ions and polymer segments, and the electric potential across microdomains. Apart from effects obtained by coupling classical Flory-Rehner theory with Donnan equilibria, viz., increased swelling with polyelectrolyte charge and shrinking of gel upon addition of salt, the model predicts the effects of microphase morphology on swelling.