National Library of Energy BETA

Sample records for fuels solvent deasphalting

  1. Conserve Energy: Modernize Your Solvent Deasphalting Unit 

    E-Print Network [OSTI]

    Lambert, J. S.; Gleitsmann, J. W.

    1983-01-01

    Deasphalting units provide high quality feedstocks for lube oil manufacture, fluid catalytic cracking, or hydrocracking, and can reduce the 'Bottom of the Barrel' by up to 90%. Older units built when energy was less expensive can be easily remodeled...

  2. New Catalyst Might Expand Bio-Ethanol's Possible uses: fuel additives, rubber and solvents

    E-Print Network [OSTI]

    and solvents RESULTS To turn bio-ethanol into chemicals that are typically made from petroleum, re- searchers-boosting gas and fuel ad- ditives, bio-based rubber for tires and a safer solvent for the chemicals industry Univer- sity have potentially found a renewable path to fuel additives, rubber and solvents. Scientists

  3. Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC

    DOE Patents [OSTI]

    Roberts, George W. (Emmaus, PA); Tao, John C. (Perkiomenville, PA)

    1985-01-01

    In this invention, a process is disclosed characterized by heating a slurry of coal in the presence of a process-derived recycle solvent and passing same to a dissolver zone, separating the resultant gases and liquid/solid products therefrom, vacuum distilling the liquid/solids products, separating the portions of the liquid/solids vacuum distillation effluent into a solid ash, unconverted coal particles and SRC material having a boiling point above 850.degree. F. and subjecting same to a critical solvent deashing step to provide an ash-free SRC product. The lighter liquid products from the vacuum distillation possess a boiling point below 850.degree. F. and are passed through a distillation tower, from which recycled solvent is recovered in addition to light distillate boiling below 400.degree. F. (overhead). The ash-free SRC product in accompanyment with at least a portion of the process derived solvent is passed in combination to a hydrotreating zone containing a hydrogenation catalyst and in the presence of hydrogen is hydroprocessed to produce a desulfurized and denitrogenized low-sulfur, low-ash boiler fuel and a process derived recycle solvent which is recycled to slurry the coal in the beginning of the process before heating.

  4. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

    1998-05-19

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

  5. In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents

    DOE Patents [OSTI]

    Taylor, Robert T. (Livermore, CA); Jackson, Kenneth J. (San Leandro, CA); Duba, Alfred G. (Livermore, CA); Chen, Ching-I (Danville, CA)

    1998-01-01

    An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

  6. SOLVENT EXTRACTION RESEARCH AND DEVELOPMENT IN THE U.S. FUEL CYCLE PROGRAM

    SciTech Connect (OSTI)

    Terry A. Todd

    2011-10-01

    Treatment or processing of used nuclear fuel to recycle uranium and plutonium has historically been accomplished using the well known PUREX process. The PUREX process has been used on an industrial scale for over 60 years in the nuclear industry. Research is underway to develop advanced separation methods for the recovery of other used fuel components, such as the minor actinides (Np, Am, Cm) for possible transmutation in fast spectrum reactors, or other constituents (e.g. Cs, Sr, transition metals, lanthanides) to help facilitate effective waste management options. This paper will provide an overview of new solvent extraction processes developed for advanced nuclear fuel cycles, and summarize recent experimental results. This will include the utilization of new extractants for selective separation of target metals and new processes developed to selectively recover one or more elements from used fuel.

  7. Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass

    E-Print Network [OSTI]

    Cai, Charles Miao-Zi

    2014-01-01

    THF is a promising green solvent that is relatively non-is a biomass-sourced green solvent with catalytic qualities

  8. Development of a novel solvent for the simultaneous separation of strontium and cesium from dissolved Spent Nuclear Fuel solutions

    SciTech Connect (OSTI)

    Catherine L. Riddle; John D. Baker; Jack D. Law; Christopher A. McGrath; David H. Meikrantz; Bruce J. Mincher; Dean R. Peterman; Terry A. Todd

    2004-10-01

    The recovery of Cs and Sr from acidic solutions by solvent extraction has been investigated. The goal of this project was to develop an extraction process to remove Cs and Sr from high-level waste in an effort to reduce the heat loading in storage. Solvents for the extraction of Cs and Sr separately have been used on both caustic and acidic spent nuclear fuel waste in the past. The objective of this research was to find a suitable solvent for the extraction of both Cs and Sr simultaneously from acidic nitrate media. The solvents selected for this research possess good stability and extraction behavior when mixed together. The extraction experiments were performed with 4 ,4,(5 )-Di-(tbutyldicyclohexano)- 18-crown-6 {DtBuCH18C6}, Calix[4]arene-bis-(tert-octylbenzocrown-6) {BOBCalixC6} and 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol {Cs-7SB modifier} in a branched aliphatic kerosene {Isopar® L}. The BOBCalixC6 and Cs-7SB modifier were developed at Oak Ridge National Laboratory (ORNL) by Bonnesen et al. [1]. The values obtained from the SREX solvent for DSr in 1 M nitric acid ranged from 0.7 to 2.2 at 25oC and 10oC respectively. The values for DCs in 1 M nitric acid with the CSSX solvent ranged from 8.0 to 46.0 at 25oC and 10oC respectively. A new mixed solvent, developed at the Idaho National Engineering and Environmental Laboratory (INEEL) by Riddle et al. [2], showed distributions for Sr ranging from 8.8 to 17.4 in 1 M nitric acid at 25oC and 10oC respectively. The DCs for the mixed solvent ranged from 7.7 to 20.2 in 1 M nitric acid at 25oC to 10oC respectively. The unexpectedly high distributions for Sr at both 25oC and 10oC show a synergy in the mixed solvent. The DCs, although lower than with CSSX solvent, still showed good extraction behavior.

  9. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W. (Marietta, GA)

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  10. The radiation chemistry of CCD-PEG, a solvent-extraction process for Cs and Sr from dissolved nuclear fuel

    SciTech Connect (OSTI)

    Mincher, B.J.; Herbst, R.S.; Tillotson, R.D.; Mezyk, S.P.

    2008-07-01

    Cobalt dicarbollide and polyethylene glycol in phenyl-trifluoromethyl sulfone (HCCD/PEG in FS- 13) is currently under consideration for use in the process-scale selective extraction of fission- product cesium and strontium from dissolved nuclear fuel. This solvent will be exposed to high radiation doses during use and has not been adequately investigated for radiation stability. Here, HCCD/PEG was y-irradiated to various absorbed doses, to a maximum of 432 kGy, using {sup 60}Co. Irradiations were performed for the neat organic phase and also for the organic phase in contact with 1 M-nitric acid mixed by air sparging. Post-irradiation solvent-extraction measurements showed that Cs distribution ratios were unaffected; however, Sr extraction efficiency decreased with absorbed dose under both conditions and was greater when in contact with the aqueous phase. Stripping performance was not affected. A mechanism, initiated by direct radiolysis of the sulfone diluent, is proposed. (authors)

  11. Solvent wash solution

    DOE Patents [OSTI]

    Neace, James C. (Blackville, SC)

    1986-01-01

    Process for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 volume percent of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  12. Solvent wash solution

    DOE Patents [OSTI]

    Neace, J.C.

    1984-03-13

    A process is claimed for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 vol % of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

  13. Requirements for a Dynamic Solvent Extraction Module to Support...

    Office of Scientific and Technical Information (OSTI)

    FUELS; PERFORMANCE; SAFEGUARDS; SAFETY; SECURITY; SIMULATION; SOLVENT EXTRACTION; SOLVENTS; WASTE FORMS dynamic; model; solvent extraction Word Cloud More Like This Full Text...

  14. Development of a Conceptual Process for Selective CO{sub 2} Capture from Fuel Gas Streams Using [hmim][Tf2N] Ionic Liquid as a Physical Solvent

    SciTech Connect (OSTI)

    Basha, Omar M.; Keller, Murphy J.; Luebke, David R.; Resnik, Kevin; P Morsi, Badie I.

    2013-07-01

    The Ionic Liquid (IL) [hmim][Tf2N] was used as a physical solvent in an Aspen Plus simulation, employing the Peng-Robinson Equation of State (P-R EOS) with Boston-Mathias (BM) alpha function and standard mixing rules, to develop a conceptual process for CO{sub 2} capture from a shifted warm fuel gas stream produced from Pittsburgh # 8 coal for a 400 MWe power plant. The physical properties of the IL, including density, viscosity, surface tension, vapor pressure and heat capacity were obtained from literature and modeled as a function of temperature. Also, available experimental solubility values for CO{sub 2}, H{sub 2}, H{sub 2}S, CO, and CH{sub 4} in this IL were compiled and their binary interaction parameters ({delta}{sub ij} and l{sub ij}) were optimized and correlated as functions of temperature. The Span-Wager Equation-of-State EOS was also employed to generate CO{sub 2} solubilities in [hmim][Tf2N] at high pressures (up to 10 MPa) and temperatures (up to 510 K). The conceptual process developed consisted of 4 adiabatic absorbers (2.4 m ID, 30 m high) arranged in parallel and packed with Plastic Pall Rings of 0.025 m for CO{sub 2} capture; 3 flash drums arranged in series for solvent (IL) regeneration with the pressure-swing option; and a pressure-intercooling system for separating and pumping CO{sub 2} up to 153 bar to the sequestration sites. The compositions of all process streams, CO{sub 2} capture efficiency, and net power were calculated using Aspen Plus simulator. The results showed that, based on the composition of the inlet gas stream to the absorbers, 95.67 mol% of CO{sub 2} was captured and sent to sequestration sites; 99.5 mol% of H{sub 2} was separated and sent to turbines; the solvent exhibited a minimum loss of 0.31 mol%; and the net power balance of the entire system was 30.81 MW. These results indicated that [hmim][Tf2N] IL could be used as a physical solvent for CO{sub 2} capture from warm shifted fuel gas streams with high efficiency.

  15. Solvent substitution

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The DOE Environmental Restoration and Waste Management Office of Technology Development and the Air Force Engineering and Services Center convened the First Annual International Workshop on Solvent Substitution on December 4--7, 1990. The primary objectives of this joint effort were to share information and ideas among attendees in order to enhance the development and implementation of required new technologies for the elimination of pollutants associated with industrial use of hazardous and toxic solvents; and to aid in accelerating collaborative efforts and technology transfer between government and industry for solvent substitution. There were workshop sessions focusing on Alternative Technologies, Alternative Solvents, Recovery/Recycling, Low VOC Materials and Treatment for Environmentally Safe Disposal. The 35 invited papers presented covered a wide range of solvent substitution activities including: hardware and weapons production and maintenance, paint stripping, coating applications, printed circuit boards, metal cleaning, metal finishing, manufacturing, compliance monitoring and process control monitoring. This publication includes the majority of these presentations. In addition, in order to further facilitate information exchange and technology transfer, the US Air Force and DOE solicited additional papers under a general Call for Papers.'' These papers, which underwent review and final selection by a peer review committee, are also included in this combined Proceedings/Compendium. For those involved in handling, using or managing hazardous and toxic solvents, this document should prove to be a valuable resource, providing the most up-to-date information on current technologies and practices in solvent substitution. Individual papers are abstracted separated.

  16. Sorption of selected volatile organic constituents of jet fuels and solvents on natural sorbents from gas and solutions phases. Final report, April 1985-September 1987

    SciTech Connect (OSTI)

    Rao, P.S.; Rhue, R.D.; Johnson, C.T.; Oguada, R.A.

    1988-08-01

    Sorption of selected volatile organic constituents (VOC) of jet fuels and solvents on several natural sorbents from the gas and aqueous phases was investigated. The sorbates studied were: trans-1,2-dichloroethylene; 1,2-dichloroethane; trichloroethylene; 1,1,2,2-tetrachloroethane; toluene; ethylbenzene; p-xylene; o-xylene; and cyclohexane. The sorbents used included clays (kaolin, montmorillonite, SAz-1), soils (Webster and Oldsmar), and aquifer materials (Borden and Lula). Sorption from the vapor phase was studied using three techniques; the headspace analysis method, dynamic-flow method, and a gas chromatographic method. Sorption of VOC on anhydrous sorbents and sorbents in equilibrium with water at different relative humidities was examined. The energetics of sorption were characterized by measuring VOC sorption at several temperatures.

  17. A combined Cyanex-923/HEH[EHP]/Dodecane solvent for recovery of transuranic elements from used nuclear fuel

    SciTech Connect (OSTI)

    Johnson, A.; Nash, K.L. [Department of Chemistry, Washington State University, PO Box 644630, Pullman, WA 99164-4630 (United States)

    2013-07-01

    The separation of minor actinides from fission product lanthanides remains a primary challenge for enabling the recycle of used nuclear fuel. To minimize the complexity of materials handling, combining extractant processes has become an increasingly attractive option. Unfortunately, combined processes sometimes suffer reduced utility due to strong dipole-dipole interactions between the extractants. The results reported here describe a system based on a combination of commercially available extractants Cyanex-923 and HEH[EHP]. In contrast to other combined extractant systems, these extractant molecules exhibit comparatively weak interactions, reducing the impact of secondary interactions. In this process, mixtures containing equal ratios of Cyanex-923 and HEH[EHP] were seen to co-extract americium and the lanthanides from nitric acid solutions. Stripping of An(III) was effectively achieved through contact with an aqueous phase comprised of glycine (for pH control) and a polyamino-poly-carboxylate stripping reagent that selectively removes An(III) from the extractant phase. The lanthanides can then be stripped from the loaded organic phase contacting with high nitric acid concentrations. Extraction of fission products zirconium and molybdenum was also investigated and potential strategies for their management have been identified. The work presented demonstrates the feasibility of combining Cyanex-923 and HEH[EHP] for separating and recovering the transuranic elements from the Ln(III). (authors)

  18. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  19. Solvents: Theory and Application

    E-Print Network [OSTI]

    Yoo, S. J. Ben

    Solvents: Theory and Application Revised: 2007-03-02 Source: www.microchemicals.eu/technical-information Photoresists, developers, remover, adhesion promoters, etchants, and solvents ... Phone: +49 731 36080-409 Fax of solvents can be explained, and which solvent is (un)suited for your purpose. Interaction Between Molecules

  20. Solvent recovery targeting

    SciTech Connect (OSTI)

    Ahmad, B.S.; Barton, P.I.

    1999-02-01

    One of the environmental challenges faced by the pharmaceutical and specialty chemical industries is the widespread use of organic solvents. With a solvent-based chemistry, the solvent necessarily has to be separated from the product. Chemical species in waste-solvent streams typically form multicomponent azeotropic mixtures, and this often complicates separation and, hence, recovery of solvents. A design approach is presented whereby process modifications proposed by the engineer to reduce the formation of waste-solvent streams can be evaluated systematically. This approach, called solvent recovery targeting, exploits a recently developed algorithm for elucidating the separation alternatives achievable when applying batch distillation to homogeneous multicomponent mixtures. The approach places the composition of the waste-solvent mixture correctly in the relevant residue curve map and computes the maximum amount of pure material that can be recovered via batch distillation. Solvent recovery targeting is applied to two case studies derived from real industrial processes.

  1. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  2. Mixed Solvent Electrolyte Model

    Broader source: Energy.gov [DOE]

    With assistance from AMO, OLI Systems, Inc., developed the mixed-solvent electrolyte model, a comprehensive physical property package that can predict the properties of electrolyte systems ranging...

  3. fuel

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4)9 Federal RegisterStorm1 3446 YEAR/%2Afissile4/%2A en

  4. Fuel

    SciTech Connect (OSTI)

    NONE

    1999-10-01

    Two subjects are covered in this section. They are: (1) Health effects of possible contamination at Paducah Gaseous Diffusion Plant to be studied; and (2) DOE agrees on test of MOX fuel in Canada.

  5. Continuous countercurrent membrane column for the separation of solute/solvent and solvent/solvent systems

    DOE Patents [OSTI]

    Nerad, Bruce A. (Longmont, CO); Krantz, William B. (Boulder, CO)

    1988-01-01

    A reverse osmosis membrane process or hybrid membrane - complementary separator process for producing enriched product or waste streams from concentrated and dilute feed streams for both solvent/solvent and solute/solvent systems is described.

  6. Halogenated solvent remediation

    DOE Patents [OSTI]

    Sorenson, Jr., Kent S. (Windsor, CO)

    2008-11-11

    Methods for enhancing bioremediation of ground water contaminated with nonaqueous halogenated solvents are disclosed. An illustrative method includes adding an electron donor for microbe-mediated anaerobic reductive dehalogenation of the halogenated solvents, which electron donor enhances mass transfer of the halogenated solvents from residual source areas into the aqueous phase of the ground water. Illustrative electron donors include C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, salts thereof, esters of C.sub.2-C.sub.4 carboxylic acids and hydroxy acids, and mixtures thereof, of which lactic acid, salts of lactic acid--such as sodium lactate, lactate esters, and mixtures thereof are particularly illustrative. The microbes are either indigenous to the ground water, or such microbes can be added to the ground water in addition to the electron donor.

  7. Halogenated solvent remediation

    DOE Patents [OSTI]

    Sorenson, Kent S.

    2004-08-31

    Methods for enhancing bioremediation of ground water contaminated with nonaqueous halogenated solvents are disclosed. A preferred method includes adding a composition to the ground water wherein the composition is an electron donor for microbe-mediated reductive dehalogenation of the halogenated solvents and enhances mass transfer of the halogenated solvents from residual source areas into the aqueous phase of the ground water. Illustrative compositions effective in these methods include surfactants such as C.sub.2 -C.sub.4 carboxylic acids and hydroxy acids, salts thereof, esters of C.sub.2 -C.sub.4 carboxylic acids and hydroxy acids, and mixtures thereof. Especially preferred compositions for use in these methods include lactic acid, salts of lactic acid, such as sodium lactate, lactate esters, and mixtures thereof. The microbes are either indigenous to the ground water, or such microbes can be added to the ground water in addition to the composition.

  8. Safe battery solvents

    DOE Patents [OSTI]

    Harrup, Mason K. (Idaho Falls, ID); Delmastro, Joseph R. (Idaho Falls, ID); Stewart, Frederick F. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID)

    2007-10-23

    An ion transporting solvent maintains very low vapor pressure, contains flame retarding elements, and is nontoxic. The solvent in combination with common battery electrolyte salts can be used to replace the current carbonate electrolyte solution, creating a safer battery. It can also be used in combination with polymer gels or solid polymer electrolytes to produce polymer batteries with enhanced conductivity characteristics. The solvents may comprise a class of cyclic and acyclic low molecular weight phosphazenes compounds, comprising repeating phosphorus and nitrogen units forming a core backbone and ion-carrying pendent groups bound to the phosphorus. In preferred embodiments, the cyclic phosphazene comprises at least 3 phosphorus and nitrogen units, and the pendent groups are polyethers, polythioethers, polyether/polythioethers or any combination thereof, and/or other groups preferably comprising other atoms from Group 6B of the periodic table of elements.

  9. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    E.A. , "Viscosity of Coal Liquids - The Effect of CharacterOF SOLVENT REFINED COAL TO LIQUID PRODUCTS Kylan I. Tanner*for Conversion of Coal to Liquid Fuels: Basic and Ex-

  10. Solvent Immersion Imprint Lithography

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Wilkins, Michael J.; Grate, Jay W.; Kelly, Ryan T.; Konopka, Allan; Xantheas, Sotiris S.; Chang, M. T.

    2014-06-21

    The mechanism of polymer disolution was explored for polymer microsystem prototyping, including microfluidics and optofluidics. Polymer films are immersed in a solvent, imprinted and finally brought into contact with a non-modified surface to permanently bond. The underlying polymer-solvent interactions were experimentally and theoretically investigated, and enabled rapid polymer microsystem prototyping. During imprinting, small molecule integration in the molded surfaces was feasible, a principle applied to oxygen sensing. Polystyrene (PS) was employed for microbiological studies at extreme environmental conditions. The thermophile anaerobe Clostridium Thermocellum was grown in PS pore-scale micromodels, revealing a double mean generation lifetime than under ideal culture conditions. Microsystem prototyping through directed polymer dissolution is simple and accessible, while simultaneous patterning, bonding, and surface/volume functionalization are possible in less than one minute.

  11. SOLvent | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, NewMichigan:Roxbury,RushS.K EnterpriseTwoSKG

  12. Solvent Blending Strategy to Upgrade MCU CSSX Solvent to Equivalent Next-Generation CSSX Solvent

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Moyer, Bruce A

    2012-12-01

    The results of the present study have validated an equal-volume blending strategy for upgrading freshly prepared CSSX solvent to a blended solvent functionally equivalent to NG-CSSX solvent. It is shown that blending fresh CSSX solvent as currently used in MCU with an equal volume of an NG-CSSX solvent concentrate of appropriate composition yields a blended solvent composition (46.5 mM of MaxCalix, 3.5 mM of BOBCalixC6, 0.5 M of Cs-7SB, 3 mM of guanidine suppressor, and 1.5 mM of TOA in Isopar L) that exhibits equivalent batch ESS performance to that of the NG-CSSX solvent containing 50 mM of MaxCalix, 0.5 M of Cs-7SB, and 3 mM of guanidine suppressor in Isopar L. The solvent blend composition is robust to third-phase formation. Results also show that a blend containing up to 60% v/v of CSSX solvent could be accommodated with minimal risk. Extraction and density data for the effect of solvent concentration mimicking diluent evaporation or over-dilution of the equal-volume blended solvent are also given, providing input for setting operational limits. Given that the experiments employed all pristine chemicals, the results do not qualify a blended solvent starting with actual used MCU solvent, which can be expected to have undergone some degree of degradation. Consequently, further work should be considered to evaluate this risk and implement appropriate remediation if needed.

  13. Solvent reorganization energy of electron-transfer reactions in polar solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent reorganization energy of electron-transfer reactions in polar solvents Dmitry V. Matyushova theory of solvent reorganization energy in polar molecular solvents is developed. The theory represents the solvent response as a combination of the density and polarization fluctuations of the solvent given

  14. Correlation of radioactive-waste-treatment costs and the environmental impact of waste effluents in the nuclear fuel cycle: conversion of yellow cake to uranium hexafluoride. Part II. The solvent extraction-fluorination process

    SciTech Connect (OSTI)

    Sears, M.B.; Etnier, E.L.; Hill, G.S.; Patton, B.D.; Witherspoon, J.P.; Yen, S.N.

    1983-03-01

    A cost/benefit study was made to determine the cost and effectiveness of radioactive waste (radwaste) treatment systems for decreasing the release of radioactive materials and chemicals from a model uranium hexafluoride (UF/sub 6/) production plant using the solvent extraction-fluorination process, and to evaluate the radiological impact (dose commitment) of the release materials on the environment. The model plant processes 10,000 metric tons of uranium per year. Base-case waste treatment is the minimum necessary to operate the process. Effluents meet the radiological requirements listed in the Code of Federal Regulations, Title 10, Part 20 (10 CFR 20), Appendix B, Table II, but may not be acceptable chemically at all sites. Additional radwaste treatment techniques are applied to the base-case plant in a series of case studies to decrease the amounts of radioactive materials released and to reduce the amounts of radioactive materials released and to reduce the radiological dose commitment to the population in the surrounding area. The costs for the added waste treatment operations and the corresponding dose committment are correlated with the annual cost for treatment of the radwastes. The status of the radwaste treatment methods used in the case studies is discussed. Much of the technology used in the advanced cases will require development and demonstration, or else is proprietary and unavailable for immediate use. The methodology and assumptions for the radiological doses are found in ORNL-4992.

  15. Coal liquefaction process with enhanced process solvent

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Kang, Dohee (Macungie, PA)

    1984-01-01

    In an improved coal liquefaction process, including a critical solvent deashing stage, high value product recovery is improved and enhanced process-derived solvent is provided by recycling second separator underflow in the critical solvent deashing stage to the coal slurry mix, for inclusion in the process solvent pool.

  16. Proceedings of ISEC 2008, International Solvent Extraction Conference - Solvent Extraction: Fundamentals to Industrial Applications

    SciTech Connect (OSTI)

    Moyer, Bruce A.

    2008-07-01

    The North American industry has employed major solvent-extraction processes to support a wide range of separations including but not limited to chemical, metallurgical, nuclear, biochemical, pharmaceutical, and petroleum applications. The knowledge enabling these separations has been obtained through fundamental studies in academe, government and industry. The International Solvent Extraction Conferences have been and continue to be a major gathering of scientists, engineers, operators, and vendors from around the world, who present new findings since the last meeting, exchange ideas, make business contacts, and conduct collegial discussions. The ISEC 2008 program emphasizes fundamentals to industrial applications of solvent extraction, particularly how this broad spectrum of activities is interconnected and has led to the implementation of novel processes. The oral and poster sessions have been organized into seven topics: Fundamentals; Novel Reagents, Materials and Techniques; Nuclear Fuel Reprocessing; Hydrometallurgy and Metals Extraction; Analytical and Preparative Applications; Biotechnology, Pharmaceuticals, Life-Science Products, and Organic Products; and Process Chemistry and Engineering. Over 350 abstracts were received, resulting in more than 260 manuscripts published in these proceedings. Five outstanding plenary presentations have been identified, with five parallel sessions for oral presentations and posters. In recognition of the major role solvent extraction (SX) plays in the hydrometallurgical and nuclear industries, these proceedings begin with sections focusing on hydrometallurgy, process chemistry, and engineering. More fundamental topics follow, including sections on novel reagents, materials, and techniques, featuring novel applications in analytical and biotechnology areas. Despite the diversity of topics and ideas represented, however, the primary focus of the ISEC community continues to be metals extraction. Four papers from these proceedings have been entered already in INIS in the form of individual reports. Among the remaining papers, 60 have been selected from the following sessions: Plenary Lectures, Hydrometallurgy and Metals Extraction, Nuclear Fuel Reprocessing, Analytical and Preparative Applications, Fundamentals, and Novel Reagents, Materials, and Techniques.

  17. Industrial application of GNEP solvent-extraction processes

    SciTech Connect (OSTI)

    Arm, S.T.; Phillips, C.; Dobson, A.

    2008-07-01

    EnergySolutions is currently studying the feasibility of commercially recycling spent nuclear fuel in the USA as part of the Global Nuclear Energy Partnership. Uranium, plutonium, and neptunium recycling are accomplished by employing well-established solvent-extraction technology based on the tributylphosphate extractant and acetohydroxamic complexant stripping in a commercially demonstrated configuration. Americium and curium recycling is best achieved by employing the TRUEX and TALSPEAK solvent-extraction processes or a simplified variant of them. Facility design is not predicated on performing any research and development a priori. Process development and demonstration will proceed in parallel with design by proven design-management techniques. (authors)

  18. Replacement solvents for use in chemical synthesis

    DOE Patents [OSTI]

    Molnar, Linda K. (Philadelphia, PA); Hatton, T. Alan (Sudbury, MA); Buchwald, Stephen L. (Newton, MA)

    2001-05-15

    Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.

  19. Solvent-extraction purification of neptunium

    SciTech Connect (OSTI)

    Kyser, E.A.; Hudlow, S.L.

    2008-07-01

    The Savannah River Site (SRS) has recovered {sup 237}Np from reactor fuel that is currently being processed into NpO{sub 2} for future production of {sup 238}Pu. Several purification flowsheets have been utilized. An oxidizing solvent-extraction (SX) flowsheet was used to remove Fe, sulfate ion, and Th while simultaneously {sup 237}Np, {sup 238}Pu, u, and nonradioactive Ce(IV) was extracted into the tributyl phosphate (TBP) based organic solvent. A reducing SX flowsheet (second pass) removed the Ce and Pu and recovered both Np and U. The oxidizing flowsheet was necessary for solutions that contained excessive amounts of sulfate ion. Anion exchange was used to perform final purification of Np from Pu, U, and various non-actinide impurities. The Np(IV) in the purified solution was then oxalate-precipitated and calcined to an oxide for shipment to other facilities for storage and future target fabrication. Performance details of the SX purification and process difficulties are discussed. (authors)

  20. SOLVENT EXTRACTION OF PHENOLS FROM WATER

    E-Print Network [OSTI]

    Greminger, Douglas C.

    2012-01-01

    Waste Water Treatment by Solvent Extraction," Canadian J.A.F. Preuss, "Extraction of Phenol from Water with a Liquid1980 SOLVENT EXTRACTION OF PHENOLS FROM WATER LP,WRENCE BERv

  1. Dipolar correlations in structured solvents under nanoconfinement

    E-Print Network [OSTI]

    Sahin Buyukdagli; Ralf Blossey

    2014-05-26

    We study electrostatic correlations in structured solvents confined to nanoscale systems. We derive variational equations of Netz-Orland type for a model liquid composed of finite size dipoles. These equations are solved for both dilute solvents and solvents at physiological concentrations in a slit nanopore geometry. Correlation effects are of major importance for the dielectric reduction and anisotropy of the solvent resulting from dipole image interactions and also lead to a reduction of van der Waals attractions between low dielectric bodies. Finally, by comparison with other recently developed self-consistent theories and experiments, we scrutinize the effect of solvent-membrane interactions on the differential capacitance of the charged liquid in contact with low dielectric substrates. The interfacial solvent depletion driven by solvent-image interactions plays the major role in the observed low values of the experimental capacitance data, while non-locality associated with the extended charge structure of solvent molecules only brings a minor contribution.

  2. Wash solvent reuse in paint production

    SciTech Connect (OSTI)

    Parsons, A.B.; Heater, K.J.; Olfenbuttel, R.F.

    1994-04-01

    The project evaluated solvent used to clean paint manufacture equipment for its utility in production of subsequent batches of solvent-borne paint. Reusing wash solvent would reduce the amount of solvent disposed of as waste. The evaluation of this wash-solvent recovery technology was conducted by Battelle Memorial Institute for the Pollution Prevention Research Branch of the U.S. Environmental Protection Agency. The evaluation was conducted with the cooperation and assistance of Vanex Color, Inc. The product quality, waste reduction/pollution prevention, and economic impacts of this technology change, as it has been implemented by Vanex, were examined. Two batches of a solvent-borne alkyd house paint were prepared at Vanex--one batch made with 100%-new solvent and the other with 30%-wash solvent--and sampled for laboratory analysis at Battelle.

  3. Solvent-induced forces in protein folding

    SciTech Connect (OSTI)

    Ben-Naim, A. (Hebrew Univ., Jerusalem (Israel))

    1990-08-23

    The solvent-induced forces between various groups on the protein are examined. It is found that the intramolecular hydrophilic forces are likely to be the strongest forces mediated through the solvent. It is argued that these are probably the most important solvent-induced driving forces in the process of protein folding.

  4. Solvent dramatically affects protein structure refinement

    E-Print Network [OSTI]

    Summa, Christopher M.

    Solvent dramatically affects protein structure refinement Gaurav Chopraa , Christopher M. Summab, fold and function in aqueous solution in vivo and in vitro. In this work, we study the role of solvent explicit and implicit solvent were performed on a set of 75 native proteins to test the various energy

  5. COMMUNICATION Phosphorylation Causes Subtle Changes in Solvent

    E-Print Network [OSTI]

    Komives, Elizabeth A.

    COMMUNICATION Phosphorylation Causes Subtle Changes in Solvent Accessibility at the Interdomain transiently phosphorylated enzyme with a lifetime of approximately two seconds. Solvent accessibility changes. No changes in solvent accessibility were seen in the regulatory domain upon phosphorylation of Asp56, but two

  6. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

    1986-01-01

    An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

  7. Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Solvent Reorganization Entropy of Electron Transfer in Polar Solvents Pradip K. Ghorai and Dmitry V Form: February 2, 2006 We report the results of molecular dynamics simulations of the solvent of a positive reorganization entropy in polar solvents. The results of simulations are analyzed in terms

  8. sition from a localized solvent-bound ground state to the continuum of the solvent conduc-

    E-Print Network [OSTI]

    Wong, Joyce

    sition from a localized solvent-bound ground state to the continuum of the solvent conduc- tion species account for es in the immediate and solvent-separated contact pairs. The ET reaction being of two well-defined configurations, an immediate or solvent-separated contact pair. Both configura- tions

  9. Preferential Solvent Partitioning within Asphaltenic Aggregates Dissolved in Binary Solvent Mixtures

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Preferential Solvent Partitioning within Asphaltenic Aggregates Dissolved in Binary Solvent on asphaltenes from Hondo crude oil dissolved in binary solvent mixtures of toluene with n-heptane, decalin, or 1 data, and subsequent calculations of minimum error were performed to ascertain the entrained solvent

  10. Solvent cleaning system and method for removing contaminants from solvent used in resin recycling

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06

    A two step solvent and carbon dioxide based system that produces essentially contaminant-free synthetic resin material and which further includes a solvent cleaning system for periodically removing the contaminants from the solvent so that the solvent can be reused and the contaminants can be collected and safely discarded in an environmentally safe manner.

  11. Reciprocal-space solvent flattening

    SciTech Connect (OSTI)

    Terwilliger, Thomas C., E-mail: terwilliger@lanl.gov [Structural Biology Group, Mail Stop M888, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    1999-11-01

    A procedure is described for improvement of crystallographic phases by reciprocal-space maximization of a likelihood function including experimental phases and characteristics of the electron-density map. Solvent flattening is a powerful tool for improving crystallographic phases for macromolecular structures obtained at moderate resolution, but uncertainties in the optimal weighting of experimental phases and modified phases make it difficult to extract all the phase information possible. Solvent flattening is essentially an iterative method for maximizing a likelihood function which consists of (i) experimental phase information and (ii) information on the likelihood of various arrangements of electron density in a map, but the likelihood function is generally not explicitly defined. In this work, a procedure is described for reciprocal-space maximization of a likelihood function based on experimental phases and characteristics of the electron-density map. The procedure can readily be applied to phase improvement based on solvent flattening and can potentially incorporate information on a wide variety of other characteristics of the electron-density map.

  12. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Quentin C. Berg; Stephen P. Carpenter; Dady Dadyburjor; Jason C. Hissam; Manoj Katakdaunde; Liviu Magean; Abha Saddawi; Alfred H. Stiller; John W. Zondlo

    2006-03-07

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of carbon electrodes for Direct Carbon Fuel Cells (DCFC), and on carbon foam composites used in ballistic armor, as well as the hydrotreatment of solvents used in the basic solvent extraction process. A major goal is the production of 1500 pounds of binder pitch, corresponding to about 3000 pounds of hydrotreated solvent.

  13. Batch extracting process using magneticparticle held solvents

    DOE Patents [OSTI]

    Nunez, Luis (Elmhurst, IL); Vandergrift, George F. (Bolingbrook, IL)

    1995-01-01

    A process for selectively removing metal values which may include catalytic values from a mixture containing same, wherein a magnetic particle is contacted with a liquid solvent which selectively dissolves the metal values to absorb the liquid solvent onto the magnetic particle. Thereafter the solvent-containing magnetic particles are contacted with a mixture containing the heavy metal values to transfer metal values into the solvent carried by the magnetic particles, and then magnetically separating the magnetic particles. Ion exchange resins may be used for selective solvents.

  14. SOLVENT DISPERSION AND FLOW METER CALCULATION RESULTS

    SciTech Connect (OSTI)

    Nash, C.; Fondeur, F.; Peters, T.

    2013-06-21

    Savannah River National Laboratory (SRNL) found that the dispersion numbers for the six combinations of CSSX:Next Generation Solvent (NGS) “blend” and pure NGS versus salt solution, caustic wash, and strip aqueous solutions are all good. The dispersion numbers are indications of processability with centrifugal contactors. A comparison of solvent physical and thermal properties shows that the Intek™ solvent flow meter in the plant has a reading biased high versus calibrated flow when NGS is used, versus the standard CSSX solvent. The flow meter, calibrated for CSSX solvent, is predicted to read 2.8 gpm of NGS in a case where the true flow of NGS is 2.16 gpm.

  15. Electrostatic interactions in critical solvents

    E-Print Network [OSTI]

    Markus Bier; Andrea Gambassi; Martin Oettel; S. Dietrich

    2011-04-29

    The subtle interplay between critical phenomena and electrostatics is investigated by considering the effective force acting on two parallel walls confining a near-critical binary liquid mixture with added salt. The ion-solvent coupling can turn a non-critical repulsive electrostatic force into an attractive one upon approaching the critical point. However, the effective force is eventually dominated by the critical Casimir effect, the universal properties of which are not altered by the presence of salt. This observation allows a consistent interpretation of recent experimental data.

  16. Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Zhang, Sheng-Shui (Tucson, AZ); Xu, Kang (Tempe, AZ)

    1998-01-01

    The present invention relates to electrolyte solvents for use in liquid or rubbery electrolyte solutions. Specifically, this invention is directed to boron-containing electrolyte solvents and boron-containing electrolyte solutions.

  17. Dynamics around solutes and solutesolvent complexes in mixed solvents

    E-Print Network [OSTI]

    Fayer, Michael D.

    Dynamics around solutes and solute­solvent complexes in mixed solvents Kyungwon Kwak, Sungnam Park-IR spectroscopy of the hydroxyl stretch of phenol-OD in three solvents, CCl4, mesitylene (1, 3, 5 trimethyl- benzene), and the mixed solvent of mesitylene and CCl4 (0.83 mole fraction CCl4), are used to study solute-solvent

  18. Hydrogen donor solvent coal liquefaction process

    DOE Patents [OSTI]

    Plumlee, Karl W. (Baytown, TX)

    1978-01-01

    An indigenous hydrocarbon product stream boiling within a range of from about C.sub.1 -700.degree. F., preferably C.sub.1 -400.degree. F., is treated to produce an upgraded hydrocarbon fuel component and a component which can be recycled, with a suitable donor solvent, to a coal liquefaction zone to catalyze the reaction. In accordance therewith, a liquid hydrocarbon fraction with a high end boiling point range up to about 700.degree. F., preferably up to about 400.degree. F., is separated from a coal liquefaction zone effluent, the separated fraction is contacted with an alkaline medium to provide a hydrocarbon phase and an aqueous extract phase, the aqueous phase is neutralized, and contacted with a peroxygen compound to convert indigenous components of the aqueous phase of said hydrocarbon fraction into catalytic components, such that the aqueous stream is suitable for recycle to the coal liquefaction zone. Naturally occurring phenols and alkyl substituted phenols, found in the aqueous phase, are converted, by the addition of hydroxyl constituents to phenols, to dihydroxy benzenes which, as disclosed in copending Application Ser. Nos. 686,813 now U.S. Pat. No. 4,049,536; 686,814 now U.S. Pat. No. 4,049,537; 686,827 now U.S. Pat. No. 4,051,012 and 686,828, K. W. Plumlee et al, filed May 17, 1976, are suitable hydrogen transfer catalysts.

  19. CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION MODELING IN GROUNDWATER

    E-Print Network [OSTI]

    Boyer, Edmond

    CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION MODELING IN GROUNDWATER F. QUIOT1 , C.Goblet@ensmp.fr Keywords : numerical model, groundwater contamination, chlorinated solvents, natural atténuation atténuation models to predict transport and fate of chlorinated solvents in saturated groundwater Systems

  20. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G; Eckert, Charles A; Liotta, Charles L; Heldebrant, David J

    2014-04-29

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  1. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G. (Kingston, CA); Eckert, Charles A. (Atlanta, GA); Liotta, Charles L. (Atlanta, GA); Heldebrant, David J. (Richland, WA)

    2011-07-19

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  2. Switchable solvents and methods of use thereof

    DOE Patents [OSTI]

    Jessop, Philip G.; Eckert, Charles A.; Liotta, Charles L.; Heldebrant, David J.

    2013-08-20

    A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

  3. Mechanism of paint removing by organic solvents

    SciTech Connect (OSTI)

    Del Nero, V.; Siat, C.; Marti, M.J.; Aubry, J.M.; Lallier, J.P.; Dupuy, N.; Huvenne, J.P.

    1996-01-01

    The mechanism of paint removing has been studied by comparing the stripping efficiency of a given solvent with its ability to swell the film. The most effective solvents have a Hildebrand{close_quote}s parameter, {delta}{sub H}, ranging from 10.5 to 12 and a Dimroth parameter, ET{sub (30)}, ranging from 0.25 to 0.4. The synergy observed with the mixtures DMSO/non polar solvent is explained by a dissociation of the DMSO clusters into individual molecules which diffuse more easily. {copyright} {ital 1996 American Institute of Physics.}

  4. Test Plan for Solvent Extraction Data Acquisition to Support...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Test Plan for Solvent Extraction Data Acquisition to Support Modeling Efforts Citation Details In-Document Search Title: Test Plan for Solvent Extraction Data...

  5. Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Breakout Session 1-D: The Pitch Renewable,...

  6. Vibrational spectroscopy for online monitoring of extraction solvent degradation products

    SciTech Connect (OSTI)

    Peterson, J.; Robinson, T.; Bryan, S.A.; Levitskaia, T.G. [Pacific Northwest National Laboratory, 902 Battelle Blvd, PO Box 999, MSIN P7-25 Richland, WA 99352 (United States)

    2013-07-01

    In our research, we are exploring the potential of online monitoring of the organic solvents for the flowsheets relevant to the used nuclear fuel reprocessing and tributyl phosphate (TBP)- based extraction processes in particular. Utilization of vibrational spectroscopic techniques permits the discrimination of the degradation products from the primary constituents of the loaded extraction solvent. Multivariate analysis of the spectral data facilitates development of the regression models for their quantification in real time and potentially enables online implementation of a monitoring system. Raman and FTIR spectral databases were created and used to develop the regression partial least squares (PLS) chemometric models for the quantitative prediction of HDBP (dibutyl phosphoric acid) degradation product, TBP, and UO{sub 2}{sup 2+} extraction organic product phase. It was demonstrated that both these spectroscopic techniques are suitable for the quantification of the Purex solvent components in the presence of UO{sub 2}(NO{sub 3}){sub 2}. Developed PLS models successfully predicted HDBP and TBP organic concentrations in simulated Purex solutions.

  7. Optimizing injected solvent fraction in stratified reservoirs 

    E-Print Network [OSTI]

    Moon, Gary Michael

    1993-01-01

    Waterflooding has become standard practice for extending the productive life of many solution gas drive reservoirs, but has the disadvantage of leaving a substantial residual oil volume in the reservoir. Solvent flooding has been offered as a...

  8. Brayton Solvent Recovery Heat Pump Technology Update 

    E-Print Network [OSTI]

    Enneking, J. C.

    1993-01-01

    The Brayton cycle technology was developed to reduce the temperature of gas streams containing solvents in order to condense and recover them. While the use of turbo compressor/expander machinery in conjunction with an energy recuperator...

  9. Accelerated solvent extraction of petroleum contaminated sediments 

    E-Print Network [OSTI]

    Bauguss, Jeffery Lynn

    1997-01-01

    Attempts have been made in recent years to find acceptable alternatives to classical soxhlet extraction of petroleum contaminated sediments. One such method that is very promising is accelerated solvent extraction also ...

  10. Advanced Water Removal via Membrane Solvent Extraction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Removal via Membrane Solvent Extraction Reduction in energy and water use for the ethanol industry Ethanol is the leading biofuel in the U.S. with 13 Billion gallons produced...

  11. Process for solvent refining of coal using a denitrogenated and dephenolated solvent

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1984-01-01

    A process is disclosed for the solvent refining of non-anthracitic coal at elevated temperatures and pressure in a hydrogen atmosphere using a hydrocarbon solvent which before being recycled in the solvent refining process is subjected to chemical treatment to extract substantially all nitrogenous and phenolic constituents from the solvent so as to improve the conversion of coal and the production of oil in the solvent refining process. The solvent refining process can be either thermal or catalytic. The extraction of nitrogenous compounds can be performed by acid contact such as hydrogen chloride or fluoride treatment, while phenolic extraction can be performed by caustic contact or contact with a mixture of silica and alumina.

  12. Optimization of a Solvent Extraction Desalination Plant 

    E-Print Network [OSTI]

    Beighle, Phillip Lew

    1969-01-01

    , a dynamic mathematical model was developed embodying the solvent extraction principles to find a set of flow rates and temper- atures consistent. with the specifications. The model was subjected to the physical restrictions normally associated... temperature, feed temperature, and feed rate, a set of feasible solutions was calculated. Another set of feasible solutions was then calculated using t. he previous set by allowing the solvent recycle temperature, product temperature, and steam rate...

  13. Method of stripping metals from organic solvents

    DOE Patents [OSTI]

    Todd, Terry A. (Aberdeen, ID); Law, Jack D. (Pocatello, ID); Herbst, R. Scott (Idaho Falls, ID); Romanovskiy, Valeriy N. (St. Petersburg, RU); Smirnov, Igor V. (St.-Petersburg, RU); Babain, Vasily A. (St-Petersburg, RU); Esimantovski, Vyatcheslav M. (St-Petersburg, RU)

    2009-02-24

    A new method to strip metals from organic solvents in a manner that allows for the recycle of the stripping agent. The method utilizes carbonate solutions of organic amines with complexants, in low concentrations, to strip metals from organic solvents. The method allows for the distillation and reuse of organic amines. The concentrated metal/complexant fraction from distillation is more amenable to immobilization than solutions resulting from current practice.

  14. CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION

    SciTech Connect (OSTI)

    Fondeur, F.; Fink, S.

    2011-12-08

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

  15. Method for reprocessing and separating spent nuclear fuels

    DOE Patents [OSTI]

    Krikorian, Oscar H. (Danville, CA); Grens, John Z. (Livermore, CA); Parrish, Sr., William H. (Walnut Creek, CA)

    1983-01-01

    Spent nuclear fuels, including actinide fuels, volatile and non-volatile fission products, are reprocessed and separated in a molten metal solvent housed in a separation vessel made of a carbon-containing material. A first catalyst, which promotes the solubility and permeability of carbon in the metal solvent, is included. By increasing the solubility and permeability of the carbon in the solvent, the rate at which actinide oxides are reduced (carbothermic reduction) is greatly increased. A second catalyst, included to increase the affinity for nitrogen in the metal solvent, is added to increase the rate at which actinide nitrides form after carbothermic reduction is complete.

  16. Method for reprocessing and separating spent nuclear fuels. [Patent application

    DOE Patents [OSTI]

    Krikorian, O.H.; Grens, J.Z.; Parrish, W.H. Sr.

    1982-01-19

    Spent nuclear fuels, including actinide fuels, volatile and nonvolatile fission products, are reprocessed and separated in a molten metal solvent housed in a separation vessel made of a carbon-containing material. A first catalyst, which promotes the solubility and permeability of carbon in the metal solvent, is included. By increasing the solubility and permeability of the carbon in the solvent, the rate at which actinide oxides are reduced (carbothermic reduction) is greatly increased. A second catalyst, included to increase the affinity for nitrogen in the metal solvent, is added to increase the rate at which actinide nitrides form after carbothermic reduction is complete.

  17. Simple Model of Membrane Proteins Including Solvent

    E-Print Network [OSTI]

    D. L. Pagan; A. Shiryayev; T. P. Connor; J. D. Gunton

    2006-03-04

    We report a numerical simulation for the phase diagram of a simple two dimensional model, similar to one proposed by Noro and Frenkel [J. Chem. Phys. \\textbf{114}, 2477 (2001)] for membrane proteins, but one that includes the role of the solvent. We first use Gibbs ensemble Monte Caro simulations to determine the phase behavior of particles interacting via a square-well potential in two dimensions for various values of the interaction range. A phenomenological model for the solute-solvent interactions is then studied to understand how the fluid-fluid coexistence curve is modified by solute-solvent interactions. It is shown that such a model can yield systems with liquid-liquid phase separation curves that have both upper and lower critical points, as well as closed loop phase diagrams, as is the case with the corresponding three dimensional model.

  18. Solvent-resistant microporous polymide membranes

    DOE Patents [OSTI]

    Miller, Warren K. (Bend, OR); McCray, Scott B. (Bend, OR); Friesen, Dwayne T. (Bend, OR)

    1998-01-01

    An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

  19. Solvent-resistant microporous polymide membranes

    DOE Patents [OSTI]

    Miller, W.K.; McCray, S.B.; Friesen, D.T.

    1998-03-10

    An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

  20. Catalog solvent extraction: anticipate process adjustments

    SciTech Connect (OSTI)

    Campbell, S.G.; Brass, E.A.; Brown, S.J.; Geeting, M.W.

    2008-07-01

    The Modular Caustic-Side Solvent Extraction Unit (MCU) utilizes commercially available centrifugal contactors to facilitate removal of radioactive cesium from highly alkaline salt solutions. During the fabrication of the contactor assembly, demonstrations revealed a higher propensity for foaming than was initially expected. A task team performed a series of single-phase experiments that revealed that the shape of the bottom vanes and the outer diameter of those vanes are key to the successful deployment of commercial contactors in the Caustic-Side Solvent Extraction Process. (authors)

  1. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

    1989-01-01

    There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

  2. Gas separation by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1989-04-25

    There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

  3. Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics -7541C. Temperature and energy MostTheEnergySolvent Tuning of

  4. Novel Solvent System for Post Combustion CO{sub 2} Capture (Technical

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report: AchievementsTemperatures Year 6Report) | SciTech Connect Novel Solvent

  5. solvents-co2-capture-pitt | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnalCarbon AbsorberSolvents for CO2

  6. Solvent treatment of coal for improved liquefaction

    DOE Patents [OSTI]

    Appell, Herbert R. (Pitcairn, PA); Narain, Nand K. (Bethel Park, PA); Utz, Bruce R. (Pittsburgh, PA)

    1986-05-06

    Increased liquefaction yield is obtained by pretreating a slurry of solid carbonaceous material and a liquid hydrocarbonaceous solvent at a temperature above 200.degree. C. but below 350.degree. C. for a period of 10 minutes to four hours prior to exposure to liquefaction temperatures.

  7. ROSE Process Offers Energy Savings for Solvent Extraction 

    E-Print Network [OSTI]

    Gearheart, J. A.; Nelson, S. R.

    1983-01-01

    Kerr-McGee has developed and commercialized an energy-efficient solvent extraction process known as ROSE (Residuum Oil Supercritical Extraction) in which the extraction solvent is recovered as a supercritical fluid. The energy requirement...

  8. Construction of prototype system for directional solvent extraction desalination

    E-Print Network [OSTI]

    Fowler, Michael James

    2012-01-01

    Directional solvent extraction has been demonstrated as a low temperature, membrane free desalination process. This method dissolves the water into an inexpensive, benign directional solvent, rejects the contaminants, then ...

  9. Integrating Safety Issues in Optimizing Solvent Selection and Process Design 

    E-Print Network [OSTI]

    Patel, Suhani Jitendra

    2011-10-21

    Incorporating consideration for safety issues while designing solvent processes has become crucial in light of the chemical process incidents involving solvents that have taken place in recent years. The implementation of inherently safer design...

  10. The Role of Solvent Heterogeneity in Determining the Dispersion...

    Office of Scientific and Technical Information (OSTI)

    density resonse of a solvent to a surface in conjunction with the Clausius-Mossotti equation, we present a simple theory relating the discrete nature of solvent to dispersion...

  11. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    NONE

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  12. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

    1986-01-01

    A process for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal.

  13. Catalytic coal liquefaction with treated solvent and SRC recycle

    DOE Patents [OSTI]

    Garg, D.; Givens, E.N.; Schweighardt, F.K.

    1986-12-09

    A process is described for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal. 2 figs.

  14. How to use Solvent Purification System A brief manual

    E-Print Network [OSTI]

    d'Alarcao, Marc

    1 How to use Solvent Purification System A brief manual By V. Azev. SPS (Figure 1) can be used to collect dry oxygen free solvents into two different types of containers. One of them is a syringe. Syringes are filled with a solvent in a usual manner using a septum port on the flask (Figure 2

  15. Solvent structure and hydrodynamic effects in photoinduced electron transfer

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent structure and hydrodynamic effects in photoinduced electron transfer S. F. Swallen, Kristin to account for realistic finite-volume solvent effects. This work introduces physically important effects caused by the solvent which fundamentally affect the rates and spatial distribution of charge transfer

  16. Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems

    E-Print Network [OSTI]

    Tisseur, Francoise

    Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems Peter Lancaster and Fran ISSN 1749-9097 #12;Hermitian Quadratic Matrix Polynomials: Solvents and Inverse Problems$ Peter with prescribed spectral data (eigenvalues and eigenvectors) it is natural to prescribe a right solvent

  17. PROCEEDINGS Open Access Building Markov state models with solvent

    E-Print Network [OSTI]

    Guibas, Leonidas J.

    PROCEEDINGS Open Access Building Markov state models with solvent dynamics Chen Gu1 , Huang timescale dynamics. However, the solvent information in molecular simulations are often ignored in current methods, because of the large number of solvent molecules in a system and the indistinguishability

  18. Solvent Accessibility of the Thrombin-thrombomodulin Interface

    E-Print Network [OSTI]

    Komives, Elizabeth A.

    Solvent Accessibility of the Thrombin- thrombomodulin Interface Jeffrey G. Mandell1 , Abel Baerga Characterization RIKEN 2-1 Hirosawa, Wako, Saitama 351-01, Japan The kinetics of solvent accessibility exchange due to solvent accessibility at the interface from H/2 H exchange due to complex dissociation

  19. Production of biodiesel using expanded gas solvents

    SciTech Connect (OSTI)

    Ginosar, Daniel M; Fox, Robert V; Petkovic, Lucia M

    2009-04-07

    A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

  20. Alternative solvents/technologies for paint stripping

    SciTech Connect (OSTI)

    Tsang, M.N.; Harris, T.L.

    1990-01-01

    Paint stripping is a necessary part of maintenance at US Air Force Air Logistics Centers. The Waste from Air Force paint stripping operations contains toxic chemicals that require special handling and disposal at considerable cost. Solvent emissions of volatile organic compounds (VOCs) into the atmosphere are another source of pollution. These wastes are hazardous to the environment and to operating personnel, and are now regulated by the US Environmental Protection Agency, which can impose fines for discharges that exceed the established limits. This report describes the research project titled Alternative Solvents/Technologies for Paint Stripping being conducted by the Idaho National Engineering Laboratory for the Engineering and Services Center at Tyndall Air Force Base. This report also includes the results obtained in Phase 1. 8 refs., 3 tabs.

  1. Coal liquefaction process wherein jet fuel, diesel fuel and/or ASTM No. 2 fuel oil is recovered

    DOE Patents [OSTI]

    Bauman, Richard F. (Houston, TX); Ryan, Daniel F. (Friendswood, TX)

    1982-01-01

    An improved process for the liquefaction of coal and similar solid carbonaceous materials wherein a hydrogen donor solvent or diluent derived from the solid carbonaceous material is used to form a slurry of the solid carbonaceous material and wherein the naphthenic components from the solvent or diluent fraction are separated and used as jet fuel components. The extraction increases the relative concentration of hydroaromatic (hydrogen donor) components and as a result reduces the gas yield during liquefaction and decreases hydrogen consumption during said liquefaction. The hydrogenation severity can be controlled to increase the yield of naphthenic components and hence the yield of jet fuel and in a preferred embodiment jet fuel yield is maximized while at the same time maintaining solvent balance.

  2. Solvent extraction of Southern US tar sands

    SciTech Connect (OSTI)

    Penney, W.R.

    1990-01-01

    The Department of Chemical Engineering at the University of Arkansas, in association with Diversified Petroleum Recovery, Inc. (DPR) of Little Rock, Arkansas, has been developing a solvent extraction process for the recovery of bitumen from tar sands for the past five years. The unique feature of the process is that the bitumen is recovered from the solvent by contacting with a co-solvent, which causes the bitumen to precipitate. The overall purpose of this project is to study both the technical and economic feasibility of applying this technology for recovery of bitumen from tar sands by (1) investigating the socioeconmic factors which affect (a) plant siting and (b) the market value of recovered bitumen; (2) operating a process demonstration unit at the rate of 1 lb/hr recovered bitumen while producing clean sand and recyclable solvents; and (3) determine the economic conditions which will make a bitumen recovery project economical. DPR has analyzed the historical trends of domestic production, consumption, discoveries and reserves of crude oil. They have started an investigation of the volatility in the price of crude oil and of gasoline prices and of the differential between gasoline and crude oil. DPR continues to analyze the geographical movement and demand for asphalt products. Utah does not appear economically attractive as a site for a bitumen from tar sands asphalt plant. Oklahoma sites are now being studied. This report also contains the quarterly progress report from a University of Nevada study to determine bitumen composition, oxygen uptake rates, and viscosities of Alabama and Utah bitumens. Both reports have been indexed separately for inclusion on the data base.

  3. A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    A Failure of Continuum Theory: Temperature Dependence of the Solvent Reorganization Energy of Electron Transfer in Highly Polar Solvents Peter Vath and Matthew B. Zimmt* Department of Chemistry, Brown ReceiVed: February 9, 1999; In Final Form: April 26, 1999 The temperature dependence of the solvent

  4. Batch extracting process using magnetic particle held solvents

    DOE Patents [OSTI]

    Nunez, L.; Vandergrift, G.F.

    1995-11-21

    A process is described for selectively removing metal values which may include catalytic values from a mixture containing same, wherein a magnetic particle is contacted with a liquid solvent which selectively dissolves the metal values to absorb the liquid solvent onto the magnetic particle. Thereafter the solvent-containing magnetic particles are contacted with a mixture containing the heavy metal values to transfer metal values into the solvent carried by the magnetic particles, and then magnetically separating the magnetic particles. Ion exchange resins may be used for selective solvents. 5 figs.

  5. An Effective Solvent Theory Connecting the Underlying Mechanisms of Osmolytes and Denaturants for Protein Stability

    E-Print Network [OSTI]

    Plotkin, Steven S.

    An Effective Solvent Theory Connecting the Underlying Mechanisms of Osmolytes and Denaturants solvent, using a single, contact-based interaction energy between protein and solvent particles or repulsive. A statistical mechanical equiv- alence is demonstrated between this effective solvent model

  6. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, J.M.; Simandl, R.F.; Thompson, L.M.

    1993-05-04

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140 F and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140 F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  7. Nonhazardous solvent composition and method for cleaning metal surfaces

    DOE Patents [OSTI]

    Googin, John M. (Oak Ridge, TN); Simandl, Ronald F. (Farragut, TN); Thompson, Lisa M. (Knoxville, TN)

    1993-01-01

    A solvent composition for displacing greasy and oily contaminants as well as water and/or aqueous residue from metallic surfaces, especially surfaces of radioactive materials so that such surfaces can be wiped clean of the displaced contaminants, water and/or aqueous residue. The solvent composition consists essentially of a blend of nonpolar aliphatic hydrocarbon solvent having a minimum flash point of about 140.degree. F. and 2 to 25 volume percent of a polar solvent having a flash point sufficiently high so as to provide the solvent composition with a minimum flash point of at least 140.degree. F. The solvent composition is nonhazardous so that when it is used to clean the surfaces of radioactive materials the waste in the form of paper or cloth wipes, lab coats and the like used in the cleaning operation is not considered to be mixed waste composed of a hazardous solvent and a radioactive material.

  8. Demixing of colloid-polymer mixtures in poor solvents

    E-Print Network [OSTI]

    Matthias Schmidt; Alan R. Denton

    2002-04-15

    The influence of poor solvent quality on fluid demixing of a model mixture of colloids and nonadsorbing polymers is investigated using density functional theory. The colloidal particles are modelled as hard spheres and the polymer coils as effective interpenetrating spheres that have hard interactions with the colloids. The solvent is modelled as a two-component mixture of a primary solvent, regarded as a background theta-solvent for the polymer, and a cosolvent of point particles that are excluded from both colloids and polymers. Cosolvent exclusion favors overlap of polymers, mimicking the effect of a poor solvent by inducing an effective attraction between polymers. For this model, a geometry-based density functional theory is derived and applied to bulk fluid phase behavior. With increasing cosolvent concentration (worsening solvent quality), the predicted colloid-polymer binodal shifts to lower colloid concentrations, promoting demixing. For sufficiently poor solvent, a reentrant demixing transition is predicted at low colloid concentrations.

  9. Single Stage Contactor Testing Of The Next Generation Solvent Blend

    SciTech Connect (OSTI)

    Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

    2014-01-06

    The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

  10. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

    2006-08-01

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

  11. Method of making straight fuel cell tubes

    DOE Patents [OSTI]

    Borglum, Brian P. (Edgewood, PA)

    2001-01-01

    A method and an apparatus for making straight fuel cell tubes are disclosed. Extruded tubes comprising powders of fuel cell material and a solvent are dried by rotating the extruded tubes. The rotation process provides uniform circumferential drying which results in uniform linear shrinkage of the tubes. The resultant dried tubes are very straight, thereby eliminating subsequent straightening steps required with conventional processes. The method is particularly useful for forming inner air electrode tubes of solid oxide fuel cells.

  12. Polymer Translocation Induced by a Bad Solvent

    E-Print Network [OSTI]

    Christopher Lorscher; Tapio Ala-Nissila; Aniket Bhattacharya

    2010-06-08

    We employ 3D Langevin Dynamics simulations to study the dynamics of polymer chains translocating through a nanopore in presence of asymmetric solvent conditions. Initially a large fraction ($>$ 50%) of the chain is placed at the \\textit{cis} side in a good solvent while the $trans$ segments are placed in a bad solvent that causes the chain to collapse and promotes translocation from the $cis$ to the $trans$ side. In particular, we study the ratcheting effect of a globule formed at the \\textit{trans} side created by the translocated segment, and how this ratchet drives the system towards faster translocation. Unlike in the case of unbiased or externally forced translocation where the mean first passage time $\\langle \\tau \\rangle $ is often characterized by algebraic scaling as a function of the chain length $N$ with a single scaling exponent $\\alpha$, and the histogram of the mean first passage time $P(\\tau/\\langle\\tau \\rangle)$ exhibits scaling, we find that scaling is not well obeyed. For relatively long chains we find $\\langle \\tau \\rangle \\sim N^\\alpha$ where $\\alpha \\approx 1$ for $\\varepsilon/k_{B}T > 1$. In this limit, we also find that translocation proceeds with a nearly constant velocity of the individual beads(monomers), which is attributed to the coiling of the globule. We provide an approximate theory assuming rotat ional motion restricted on a 2D disc to demonstrate that there is a crossover from diffusive behavior of the center of mass for short chains to a single file translocation for long chains, where the average translocation time scales linearly with the chain length $N$.

  13. Scenarios Evaluation Tool for Chlorinated Solvent MNA

    SciTech Connect (OSTI)

    Vangelas, Karen; Michael J. Truex; Charles J. Newell; Brian Looney

    2007-02-28

    Over the past three decades, much progress has been made in the remediation of chlorinated solvents from the subsurface. Yet these pervasive contaminants continue to present a significant challenge to the U.S. Department of Energy (DOE), other federal agencies, and other public and private organizations. The physical and chemical properties of chlorinated solvents make it difficult to rapidly reach the low concentrations typically set as regulatory limits. These technical challenges often result in high costs and long remediation time frames. In 2003, the DOE through the Office of Environmental Management funded a science-based technical project that uses the U.S. Environmental Protection Agency's technical protocol (EPA, 1998) and directives (EPA, 1999) on Monitored Natural Attenuation (MNA) as the foundation on which to introduce supporting concepts and new scientific developments that will support remediation of chlorinated solvents based on natural attenuation processes. This project supports the direction in which many site owners want to move to complete the remediation of their site(s), that being to complete the active treatment portion of the remedial effort and transition into MNA. The overarching objective of the effort was to examine environmental remedies that are based on natural processes--remedies such as Monitored Natural Attenuation (MNA) or Enhanced Attenuation (EA). The research program did identify several specific opportunities for advances based on: (1) mass balance as the central framework for attenuation based remedies, (2) scientific advancements and achievements during the past ten years, (3) regulatory and policy development and real-world experience using MNA, and (4) exploration of various ideas for integrating attenuation remedies into a systematic set of ''combined remedies'' for contaminated sites. These opportunities are summarized herein and are addressed in more detail in referenced project documents and journal articles, as well as in the technical and regulatory documents being developed within the ITRC.

  14. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect (OSTI)

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States). EMS Energy Institute

    2009-09-15

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  15. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

    1988-06-14

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  16. Membrane separation of hydrocarbons using cycloparaffinic solvents

    DOE Patents [OSTI]

    Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

    1988-01-01

    Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

  17. INVESTIGATION OF PLUTONIUM AND URANIUM UPTAKE INTO MCU SOLVENT AND NEXT GENERATION SOLVENT

    SciTech Connect (OSTI)

    Peters, T.; Fink, S.

    2012-01-06

    At the request of the Savannah River Remediation (SRR) customer, the Savannah River National Laboratory (SRNL) examined the plutonium (Pu) and uranium (U) uptake into the Next Generation Solvent (NGS) that will be used at the Salt Waste Processing Facility (SWPF). SRNL examined archived samples of solvent used in Extraction-Scrub-Strip (ESS) tests, as well as samples from new tests designed explicitly to examine the Pu and U uptake. Direct radiocounting for Pu and U provided the best results. Using the radiocounting results, we found that in all cases there were <3.41E-12 g Pu/g of NGS and <1.17E-05 g U/g of NGS in multiple samples, even after extended contact times and high aqueous:organic volume phase ratios. These values are conservative as they do not allow for release or removal of the actinides by scrub, strip, or solvent wash processes. The values do not account for extended use or any increase that may occur due to radiolytic damage of the solvent.

  18. Fourier Transform Infrared Spectroscopy and Multivariate Analysis for Online Monitoring of Dibutyl Phosphate Degradation Product in Tributyl Phosphate /n-Dodecane/Nitric Acid Solvent

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Peterson, James M.; Campbell, Emily L.; Casella, Amanda J.; Peterman, Dean; Bryan, Samuel A.

    2013-11-05

    In liquid-liquid extraction separation processes, accumulation of organic solvent degradation products is detrimental to the process robustness and frequent solvent analysis is warranted. Our research explores feasibility of online monitoring of the organic solvents relevant to used nuclear fuel reprocessing. This paper describes the first phase of developing a system for monitoring the tributyl phosphate (TBP)/n-dodecane solvent commonly used to separate used nuclear fuel. In this investigation, the effect of extraction of nitric acid from aqueous solutions of variable concentrations on the quantification of TBP and its major degradation product dibutyl phosphoric acid (HDBP) was assessed. Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy was used to discriminate between HDBP and TBP in the nitric acid-containing TBP/n-dodecane solvent. Multivariate analysis of the spectral data facilitated the development of regression models for HDBP and TBP quantification in real time, enabling online implementation of the monitoring system. The predictive regression models were validated using TBP/n-dodecane solvent samples subjected to the high dose external gamma irradiation. The predictive models were translated to flow conditions using a hollow fiber FTIR probe installed in a centrifugal contactor extraction apparatus demonstrating the applicability of the FTIR technique coupled with multivariate analysis for the online monitoring of the organic solvent degradation products.

  19. Fourier Transform Infrared Spectroscopy and Multivariate Analysis for Online Monitoring of Dibutyl Phosphate Degradation Product in Tributyl Phosphate/n-Dodecane/Nitric Acid Solvent

    SciTech Connect (OSTI)

    Tatiana G. Levitskaia; James M. Peterson; Emily L. Campbell; Amanda J. Casella; Dean R. Peterman; Samuel A. Bryan

    2013-12-01

    In liquid–liquid extraction separation processes, accumulation of organic solvent degradation products is detrimental to the process robustness, and frequent solvent analysis is warranted. Our research explores the feasibility of online monitoring of the organic solvents relevant to used nuclear fuel reprocessing. This paper describes the first phase of developing a system for monitoring the tributyl phosphate (TBP)/n-dodecane solvent commonly used to separate used nuclear fuel. In this investigation, the effect of extraction of nitric acid from aqueous solutions of variable concentrations on the quantification of TBP and its major degradation product dibutylphosphoric acid (HDBP) was assessed. Fourier transform infrared (FTIR) spectroscopy was used to discriminate between HDBP and TBP in the nitric acid-containing TBP/n-dodecane solvent. Multivariate analysis of the spectral data facilitated the development of regression models for HDBP and TBP quantification in real time, enabling online implementation of the monitoring system. The predictive regression models were validated using TBP/n-dodecane solvent samples subjected to high-dose external ?-irradiation. The predictive models were translated to flow conditions using a hollow fiber FTIR probe installed in a centrifugal contactor extraction apparatus, demonstrating the applicability of the FTIR technique coupled with multivariate analysis for the online monitoring of the organic solvent degradation products.

  20. Process to prepare stable trifluorostyrene containing compounds grafted to base polymers using a solvent/water mixture

    DOE Patents [OSTI]

    Roelofs, Mark Gerrit; Yang, Zhen-Yu; Han, Amy Qi

    2010-06-15

    A fluorinated ion exchange polymer is prepared by grafting at least one grafting monomer derived from trifluorostyrene on to at least one base polymer in a organic solvent/water mixture. These ion exchange polymers are useful in preparing catalyst coated membranes and membrane electrode assemblies used in fuel cells.

  1. NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2011-09-29

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

  2. Non-Ideal Behavior in Solvent Extraction

    SciTech Connect (OSTI)

    Peter Zalupski

    2011-09-01

    This report presents a summary of the work performed to meet FCR&D level 3 milestone M31SW050801, 'Complete the year-end report summarizing FY11 experimental and modeling activities.' This work was carried out under the auspices of the Non-Ideality in Solvent Extraction Systems FCR&D work package. The report summarizes our initial considerations of potential influences that non-ideal chemistry may impose on computational prediction of outcomes in solvent extraction systems. The report is packaged into three separate test cases where a robustness of the prediction by SXFIT program is under scrutiny. The computational exercises presented here emphasize the importance of accurate representation of both an aqueous and organic mixtures when modeling liquid-liquid distribution systems. Case No.1 demonstrates that non-ideal behavior of HDEHP in aliphatic diluents, such as n-dodecane, interferes with the computation. Cases No.2 and No.3 focus on the chemical complexity of aqueous electrolyte mixtures. Both exercises stress the need for an improved thermodynamic model of an aqueous environment present in the europium distribution experiments. Our efforts for year 2 of this project will focus on the improvements of aqueous and non-aqueous solution models using fundamental physical properties of mixtures acquired experimentally in our laboratories.

  3. Acid gas scrubbing by composite solvent-swollen membranes

    DOE Patents [OSTI]

    Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

    1988-04-12

    A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorus and sulfur, and having a boiling point of at least 100 C and a solubility parameter of from about 7.5 to about 13.5 (cal/cm[sup 3]-atm)[sup 1/2]. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes. 3 figs.

  4. Method for destroying halocarbon compositions using a critical solvent

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Fox, Robert V.; Janikowski, Stuart K.

    2006-01-10

    A method for destroying halocarbons. Halocarbon materials are reacted in a dehalogenation process wherein they are combined with a solvent in the presence of a catalyst. A hydrogen-containing solvent is preferred which functions as both a solvating agent and hydrogen donor. To augment the hydrogen donation capacity of the solvent if needed (or when non-hydrogen-containing solvents are used), a supplemental hydrogen donor composition may be employed. In operation, at least one of the temperature and pressure of the solvent is maintained near, at, or above a critical level. For example, the solvent may be in (1) a supercritical state; (2) a state where one of the temperature or pressure thereof is at or above critical; or (3) a state where at least one of the temperature and pressure thereof is near-critical. This system provides numerous benefits including improved reaction rates, efficiency, and versatility.

  5. Alcohols as hydrogen-donor solvents for treatment of coal

    DOE Patents [OSTI]

    Ross, David S. (Palo Alto, CA); Blessing, James E. (Menlo Park, CA)

    1981-01-01

    A method for the hydroconversion of coal by solvent treatment at elevated temperatures and pressure wherein an alcohol having an .alpha.-hydrogen atom, particularly a secondary alcohol such as isopropanol, is utilized as a hydrogen donor solvent. In a particular embodiment, a base capable of providing a catalytically effective amount of the corresponding alcoholate anion under the solvent treatment conditions is added to catalyze the alcohol-coal reaction.

  6. Solvent and Process for Recovery of Hydroxide from Aqueous Mixtures

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Chambliss, C. Kevin; Bonnesen, Peter V.; Keever, Tamara J.

    1999-09-13

    Hydroxide values and associated alkali metal may be recovered from alkaline aqueous solutions using classes of fluorinated alcohols in a water immiscible solvent. The alcohols are characterized by fluorine substituents which are proximal to the acidic alcohol protons and are located to adjust the acidity of the extractant and the solubility of the extractant in the solvent. A method for stripping the extractant and solvent to regenerate the extractant and purified aqueous hydroxide solution is described.

  7. Solvent and process for recovery of hydroxide from aqueous mixtures

    DOE Patents [OSTI]

    Moyer, Bruce A. (Oak Ridge, TN); Chambliss, C. Kevin (Macon, GA); Bonnesen, Peter V. (Knoxville, TN); Keever, Tamara J. (Oak Ridge, TN)

    2001-01-01

    Hydroxide values and associated alkali metal may be recovered from alkaline aqueous solutions using classes of fluorinated alcohols in a water immiscible solvent. The alcohols are characterized by fluorine substituents which are proximal to the acidic alcohol protons and are located to adjust the acidity of the extractant and the solubility of the extractant in the solvent. A method for stripping the extractant and solvent to regenerate the extractant and purified aqueous hydroxide solution is described.

  8. Vacuum pyrolyzed tire oil as a coal solvent

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Y.; Ji, Q.

    1995-12-31

    Coal liquefaction is highly dependent upon the type of coal liquefaction solvent used. The solvent must readily solubilize the coal and must act as an effective hydrogen donor or shuttler. Oil derived from the vacuum pyrolysis of used rubber tires has recently been used as a coal solvent with good conversion of coal to liquids in a hydrogen atmosphere. All experiments were completed in shaken tubing reactors at 450{degrees}C utilizing a bituminous coal. Results show the effectiveness of the pyrolyzed tire oil as a coal liquefaction solvent depends upon hydrogen pressure. Electron probe microanalysis data reveal good dispersion of the molybdenum catalyst in coal particles taken from liquefaction experiments.

  9. Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers

    Broader source: Energy.gov [DOE]

    Breakout Session 1-D: The Pitch Renewable, Non-Toxic and Cost Competitive Solvents and Plasticizers Len Rand, Chief Executive Officer, Chairman, xF Technologies

  10. The Air or Brayton Cycle Solvent Recovery System 

    E-Print Network [OSTI]

    Fox, B. J.

    1986-01-01

    it suitable for solvent recovery. Thi s unit util i zes ai r foil beari ngs. to recover the heat for useful purposes. It is easy Over the past several years they have sold. these for the air cycle system to return the solvent lean uni ts to condense... CYCLE SOLVENT RECOVERY SYSTEM Bryce J. Fox 3M Company St. Paul, ABSTRACT The required temperature and technique for condensing common industrial solvents from the exhaust air of drying ovens is explained. ?:The benefits of the Air Cycle...

  11. Recovery of sugars from ionic liquid biomass liquor by solvent...

    Office of Scientific and Technical Information (OSTI)

    Patent: Recovery of sugars from ionic liquid biomass liquor by solvent extraction Citation Details In-Document Search Title: Recovery of sugars from ionic liquid biomass liquor by...

  12. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, Robert N. (Allentown, PA)

    1986-01-01

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  13. Electrostatic Free Energy and its Variations in Implicit Solvent Models

    E-Print Network [OSTI]

    Li, Bo

    Electrostatic Free Energy and its Variations in Implicit Solvent Models Jianwei Che , Joachim. The unique set of such concentrations that minimize this free energy are given by the usual Boltzmann. The variation of the electrostatic free energy with respect to the location change of solute-solvent interfaces

  14. CO-SOLVENT SELECTION AND RECOVERY Angelo Lucia* and Erik J. Finger

    E-Print Network [OSTI]

    Lucia, Angelo

    1 CO-SOLVENT SELECTION AND RECOVERY Angelo Lucia* and Erik J. Finger Department of Chemical and recovery of two or more solvents (i.e., co-solvents) are studied because of their importance present difficulties in solvent selection while the volatile components give rise to solvent recovery

  15. Solvent Selection For Enhanced Bioproduction of 3-methylcatechol in a Two-Phase

    E-Print Network [OSTI]

    Daugulis, Andrew J.

    ARTICLE Solvent Selection For Enhanced Bioproduction of 3-methylcatechol in a Two for the identification of an appro- priate organic solvent and they included solvent toxicity, bioavailability of the solvent as well as solvent affinity for 3MC. The critical log P (log Pcrit) of the biocatalyst was found

  16. Wide Electrochemical Window Solvents - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricNCubicthe FOIA? The FOIA,DepartmentWhoWhy: TheWideWide

  17. solvent-battelle | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnal

  18. solvent-neumann | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnalCarbon Absorber Retrofit

  19. solvent-novozymes | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnalCarbon Absorber

  20. Radiation chemistry in solvent etxraction: FY2011 research

    SciTech Connect (OSTI)

    Bruce J. Mincher; Stephen P. Mezyk; Leigh R. Martin

    2011-09-01

    This report summarizes work accomplished under the Fuel Cycle Research and Development (FCR&D) program in the area of radiation chemistry during FY 2011. The tasks assigned during FY 2011 included: (1) Continue measurements free radical reaction kinetics in the organic phase; (2) Continue development of an alpha-radiolysis program and compare alpha and gamma radiolysis for CMPO; (3) Initiate an effort to understand dose rate effects in radiation chemistry; and (4) Continued work to characterize TALSPEAK radiation chemistry, including the examination of metal complexed ligand kinetics. Progress made on each of these tasks is reported here. Briefly, the method developed to measure the kinetics of the reactions of the NO3 radical with solvent extraction ligands in organic solution during FY10 was extended here to a number of compounds to better understand the differences between radical reactions in the organic versus aqueous phases. The alpha-radiolysis program in FY11 included irradiations of CMPO solutions with 244Cm, 211At and the He ion beam, for comparison to gamma irradiations, and a comparison of the gamma irradiation results for CMPO at three different gamma dose rates. Finally, recent results for TALSPEAK radiolysis are reported, summarizing the latest in an effort to understand how metal complexation to ligands affects their reaction kinetics with free radicals.

  1. Future nuclear fuel cycles: prospects and challenges

    SciTech Connect (OSTI)

    Boullis, Bernard

    2008-07-01

    Solvent extraction has played, from the early steps, a major role in the development of nuclear fuel cycle technologies, both in the front end and back end. Today's stakes in the field of energy enhance further than before the need for a sustainable management of nuclear materials. Recycling actinides appears as a main guideline, as much for saving resources as for minimizing the final waste impact, and many options can be considered. Strengthened by the important and outstanding performance of recent PUREX processing plants, solvent-extraction processes seem a privileged route to meet the new and challenging requirements of sustainable future nuclear systems. (author)

  2. Fuel pin

    DOE Patents [OSTI]

    Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

    1987-11-24

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  3. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Karnesky, Richard A. (Richland, WA); Leggett, Robert D. (Richland, WA); Baker, Ronald B. (Richland, WA)

    1989-01-01

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  4. Greener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from the flue gases of coal-fired power plants would alleviate concerns

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    to remove CO2 from dilute gas streams because they have very high affinity for CO2. Unfortunately high solvents that balance high affinity for CO2 with ease of solvent recovery and reuse. Because the numberGreener Solvent Selection and Solvent Recycling for CO2 Capture Economically removing CO2 from

  5. Apparatus and method for reprocessing and separating spent nuclear fuels. [Patent application

    DOE Patents [OSTI]

    Krikorian, O.H.; Grens, J.Z.; Parrish, W.H. Sr.; Coops, M.S.

    1982-01-19

    A method and apparatus for separating and reprocessing spent nuclear fuels includes a separation vessel housing a molten metal solvent in a reaction region, a reflux region positioned above and adjacent to the reaction region, and a porous filter member defining the bottom of the separation vessel in a supporting relationship with the metal solvent. Spent fuels are added to the metal solvent. A nonoxidizing nitrogen-containing gas is introduced into the separation vessel, forming solid actinide nitrides in the metal solvent from actinide fuels, while leaving other fission products in solution. A pressure of about 1.1 to 1.2 atm is applied in the reflux region, forcing the molten metal solvent and soluble fission products out of the vessel, while leaving the solid actinide nitrides in the separation vessel.

  6. SCENARIOS EVALUATION TOOL FOR CHLORINATED SOLVENT MNA

    SciTech Connect (OSTI)

    Vangelas, K; Brian02 Looney, B; Michael J. Truex; Charles J. Newell

    2006-08-16

    Over the past three decades, much progress has been made in the remediation of chlorinated solvents from the subsurface. Yet these pervasive contaminants continue to present a significant challenge to the U.S. Department of Energy (DOE), other federal agencies, and other public and private organizations. The physical and chemical properties of chlorinated solvents make it difficult to rapidly reach the low concentrations typically set as regulatory limits. These technical challenges often result in high costs and long remediation time frames. In 2003, the DOE through the Office of Environmental Management funded a science-based technical project that uses the U.S. Environmental Protection Agency's technical protocol (EPA, 1998) and directives (EPA, 1999) on Monitored Natural Attenuation (MNA) as the foundation on which to introduce supporting concepts and new scientific developments that will support remediation of chlorinated solvents based on natural attenuation processes. This project supports the direction in which many site owners want to move to complete the remediation of their site(s), that being to complete the active treatment portion of the remedial effort and transition into MNA. The overarching objective of the effort was to examine environmental remedies that are based on natural processes--remedies such as Monitored Natural Attenuation (MNA) or Enhanced Attenuation (EA). The research program did identify several specific opportunities for advances based on: (1) mass balance as the central framework for attenuation based remedies, (2) scientific advancements and achievements during the past ten years, (3) regulatory and policy development and real-world experience using MNA, and (4) exploration of various ideas for integrating attenuation remedies into a systematic set of ''combined remedies'' for contaminated sites. These opportunities are summarized herein and are addressed in more detail in referenced project documents and journal articles, as well as in the technical and regulatory documents being developed within the ITRC. Three topic areas were identified for development during this project. These areas are: mass balance, Enhanced Attenuation (EA), and new characterization and monitoring tools and approaches to support MNA and EA. Each of these topics is documented in stand alone reports, WSRC-STI-2006-00082, WSRC-STI-2006-00083, and WSRC-STI-2006-00084, respectively. In brief, the mass balance efforts are examining methods and tools to allow a site to be evaluated in terms of a system where the inputs and processes within the system are compared to the outputs from the system, as well as understanding what attenuation processes may be occurring and how likely they are to occur within a system. Enhanced Attenuation is a new concept that is a transition step between primary treatments and MNA, when the natural attenuation processes are not sufficient to allow direct transition from the primary treatment to MNA. EA technologies are designed to either boost the level of the natural attenuation processes or decrease the loading of contaminants to the system for a period of time sufficient to allow the remedial goals to be met over the long-term. For characterization and monitoring, a phased approach based on documenting the site specific mass balance was developed. Tools and techniques to support the approach included direct measures of the biological processes and various tools to support cost-effective long-term monitoring of systems where the natural attenuation processes are the main treatment remedies. The effort revealed opportunities for integrating attenuation mechanisms into a systematic set of ''combined remedies'' for contaminated sites.

  7. Molten carbonate fuel cell cathode with mixed oxide coating

    SciTech Connect (OSTI)

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  8. Apparatus and method for reprocessing and separating spent nuclear fuels. [Patent application

    DOE Patents [OSTI]

    Krikorian, O.H.; Grens, J.Z.; Parrish, W.H. Sr.

    1982-01-19

    Spent nuclear fuels, including actinide fuels, volatile and non-volatile fission products, are reprocessed and separated in a molten metal solvent housed in the reaction region of a separation vessel which includes a reflux region positioned above the molten tin solvent. The reflux region minimizes loss of evaporated solvent during the separation of the actinide fuels from the volatile fission products. Additionally, inclusion of the reflux region permits the separation of the more volatile fission products (noncondensable) from the less volatile ones (condensable).

  9. Solvent Mediated Assembly of Nanoparticles Confined in Mesoporous Alumina

    E-Print Network [OSTI]

    Kyle J. Alvine; Diego Pontoni; Oleg G. Shpyrko; Peter S. Pershan; David J. Cookson; Kyusoon Shin; Thomas P. Russell; Markus Brunnbauer; Francesco Stellacci; Oleg Gang

    2006-03-24

    The controlled self-assembly of thiol stabilized gold nanocrystals in a mediating solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering. The evolution of the self-assembly process was controlled reversibly via regulated changes in the amount of solvent condensed from an undersaturated vapor. Analysis indicated that the nanoparticles self-assembled into cylindrical monolayers within the porous template. Nanoparticle nearest-neighbor separation within the monolayer increased and the ordering decreased with the controlled addition of solvent. The process was reversible with the removal of solvent. Isotropic clusters of nanoparticles were also observed to form temporarily during desorption of the liquid solvent and disappeared upon complete removal of liquid. Measurements of the absorption and desorption of the solvent showed strong hysteresis upon thermal cycling. In addition, the capillary filling transition for the solvent in the nanoparticle-doped pores was shifted to larger chemical potential, relative to the liquid/vapor coexistence, by a factor of 4 as compared to the expected value for the same system without nanoparticles.

  10. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, F.K.

    1986-07-29

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process. 4 figs.

  11. Integrated process for the solvent refining of coal

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1983-01-01

    A process is set forth for the integrated liquefaction of coal by the catalytic solvent refining of a feed coal in a first stage to liquid and solid products and the catalytic hydrogenation of the solid product in a second stage to produce additional liquid product. A fresh inexpensive, throw-away catalyst is utilized in the second stage hydrogenation of the solid product and this catalyst is recovered and recycled for catalyst duty in the solvent refining stage without any activation steps performed on the used catalyst prior to its use in the solvent refining of feed coal.

  12. Automated process for solvent separation of organic/inorganic substance

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1986-01-01

    There is described an automated process for the solvent separation of organic/inorganic substances that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In the process, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control apparatus. The mixture in the filter is agitated by ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  13. Acetone as a solvent for extraction of cottonseed oil 

    E-Print Network [OSTI]

    Hui, In-Wai

    1950-01-01

    ACETONE AS A SOLVENT FOR EXTRACTION GP COTTONSEED OIL A Thesis In-Wai Hui June 1950 Approval as to style and content recommended c t Head oi' the Department of Chemical Engineering ACETONE AS A SOLVENT FOR EXT "ACTION OF COTTONSEED OIL A... Thesis In-Nai Hui June 1950 ACETONE AS A SOLVENT FOR EXTRACTION QF COTTONSEED OIL A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas Partis1 Fulfillment of the Recuirements for the Degree of Master of Science...

  14. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  15. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

    2006-05-12

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

  16. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)Forthcoming UpgradesArea: PADD 1 to PADDFuelFuelFuel

  17. CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS

    E-Print Network [OSTI]

    Tanner, K.I.

    2010-01-01

    I. Solvent Refined Coal II. Catalysts III. Purpose andSondreal, E.A. , "Viscosity of Coal Liquids - The Effect ofAnthraxylon - Kinetics of Coal Hydrogenation," Ind. and Eng.

  18. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  19. A Monte Carlo study of spectroscopy in nanoconfined solvents

    E-Print Network [OSTI]

    Thompson, Ward H.

    2002-09-26

    The absorption and fluorescence spectra of a model diatomic molecule with a charge-transfer electronic transition are simulated. The effect of confining the solvent in which the diatomic molecule is dissolved is examined by comparing results...

  20. Solvent-mediated interactions between nanoparticles at fluid interfaces

    E-Print Network [OSTI]

    F. Bresme; H. Lehle; M. Oettel

    2009-04-03

    We investigate the solvent mediated interactions between nanoparticles adsorbed at a liquid-vapor interface in comparison to the solvent mediated interactions in the bulk liquid and vapor phases of a Lennard-Jones solvent. Molecular dynamics simulation data for the latter are in good agreement with results from integral equations in the reference functional approximation and a simple geometric approximation. Simulation results for the solvent mediated interactions at the interface differ markedly from the interactions of the particles in the corresponding bulk phases. We find that at short interparticle distances the interactions are considerably more repulsive than those in either bulk phase. At long interparticle distances we find evidence for a long-ranged attraction. We discuss these observations in terms of interfacial interactions, namely, the three-phase line tension that would operate at short distances, and capillary wave interactions for longer interparticle distances.

  1. Nuclear Magnetic Resonance Quantum Computing Using Liquid Crystal Solvents

    E-Print Network [OSTI]

    Costantino S. Yannoni; Mark H. Sherwood; Lieven M. K. Vandersypen; Dolores C. Miller; Mark G. Kubinec; Isaac L. Chuang

    1999-12-12

    Liquid crystals offer several advantages as solvents for molecules used for nuclear magnetic resonance quantum computing (NMRQC). The dipolar coupling between nuclear spins manifest in the NMR spectra of molecules oriented by a liquid crystal permits a significant increase in clock frequency, while short spin-lattice relaxation times permit fast recycling of algorithms, and save time in calibration and signal-enhancement experiments. Furthermore, the use of liquid crystal solvents offers scalability in the form of an expanded library of spin-bearing molecules suitable for NMRQC. These ideas are demonstrated with the successful execution of a 2-qubit Grover search using a molecule ($^{13}$C$^{1}$HCl$_3$) oriented in a liquid crystal and a clock speed eight times greater than in an isotropic solvent. Perhaps more importantly, five times as many logic operations can be executed within the coherence time using the liquid crystal solvent.

  2. Proteins in Mixed Solvents: A Molecular-level Perspective

    E-Print Network [OSTI]

    Baynes, Brian M.

    We present a statistical mechanical approach for quantifying thermodynamic properties of proteins in mixed solvents. This approach, based on molecular dynamics simulations which incorporate all atom models and the theory ...

  3. Arsenic Speciation of Solvent-Extracted Leachate from

    E-Print Network [OSTI]

    Florida, University of

    and quantify arsenic species leaching from new and weathered CCA-treated wood and CCA-treated wood ash. Solvent process. CCA-treated wood ash leached more arsenic than unburned wood using the SPLP and TCLP, and ash

  4. Solvent for urethane adhesives and coatings and method of use

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Holt, Jerrid S. (Knoxville, TN)

    2010-08-03

    A solvent for urethane adhesives and coatings, the solvent having a carbaldehyde and a cyclic amide as constituents. In some embodiments the solvent consists only of miscible constituents. In some embodiments the carbaldehyde is benzaldehyde and in some embodiments the cyclic amide is N-methylpyrrolidone (M-pyrole). An extender may be added to the solvent. In some embodiments the extender is miscible with the other ingredients, and in some embodiments the extender is non-aqueous. For example, the extender may include isopropanol, ethanol, tetrahydro furfuryl alcohol, benzyl alcohol, Gamma-butyrolactone or a caprolactone. In some embodiments a carbaldehyde and a cyclic amide are heated and used to separate a urethane bonded to a component.

  5. Renewable, Nontoxic, and Cost-Competitive Solvents and Plasticizers...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - Befer than leading "green" candidates TURI Test xF solvents Compared s olvents Paint Stripping MF and EF DCM, NMP, Green AlternaKve Degreasing MF and EF TCE, NPB, Green...

  6. Apparatus and method for removing solvent from carbon dioxide in resin recycling system

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06

    A two-step resin recycling system and method solvent that produces essentially contaminant-free synthetic resin material. The system and method includes one or more solvent wash vessels to expose resin particles to a solvent, the solvent contacting the resin particles in the one or more solvent wash vessels to substantially remove contaminants on the resin particles. A separator is provided to separate the solvent from the resin particles after removal from the one or more solvent wash vessels. The resin particles are next exposed to carbon dioxide in a closed loop carbon dioxide system. The closed loop system includes a carbon dioxide vessel where the carbon dioxide is exposed to the resin, substantially removing any residual solvent remaining on the resin particles after separation. A separation vessel is also provided to separate the solvent from the solvent laden carbon dioxide. Both the carbon dioxide and the solvent are reused after separation in the separation vessel.

  7. A study of a solvent extraction desalination process 

    E-Print Network [OSTI]

    McFerrin, Arthur Ransom

    1969-01-01

    to separate salt from water has been known for decades, it was not investigated for use in desalination until 1953 (21). Since 1953, the Office of Saline Water, Department of Interior has supported an exhaustive study of the solvent extractjon desalinat... water to produce a solvent phase containing considerable water but little salt, and a water phase of increased salt content. The amine has a lower consolute temperature with water, and the fresh ~ster is recovered by heating the extract to a higher...

  8. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, R.N.

    1986-10-14

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  9. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  10. Initiate test loop irradiations of ALSEP process solvent

    SciTech Connect (OSTI)

    Peterman, Dean R. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Olson, Lonnie G. [Idaho National Lab. (INL), Idaho Falls, ID (United States); McDowell, Rocklan G. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-09-01

    This report describes the initial results of the study of the impacts of gamma radiolysis upon the efficacy of the ALSEP process and is written in completion of milestone M3FT-14IN030202. Initial irradiations, up to 100 kGy absorbed dose, of the extraction section of the ALSEP process have been completed. The organic solvent used for these experiments contained 0.05 M TODGA and 0.75 M HEH[EHP] dissolved in n-dodecane. The ALSEP solvent was irradiated while in contact with 3 M nitric acid and the solutions were sparged with compressed air in order to maintain aerated conditions. The irradiated phases were used for the determination of americium and europium distribution ratios as a function of absorbed dose for the extraction and stripping conditions. Analysis of the irradiated phases in order to determine solvent composition as a function of absorbed dose is ongoing. Unfortunately, the failure of analytical equipment necessary for the analysis of the irradiated samples has made the consistent interpretation of the analytical results difficult. Continuing work will include study of the impacts of gamma radiolysis upon the extraction of actinides and lanthanides by the ALSEP solvent and the stripping of the extracted metals from the loaded solvent. The irradiated aqueous and organic phases will be analyzed in order to determine the variation in concentration of solvent components with absorbed gamma dose. Where possible, radiolysis degradation product will be identified.

  11. Fuel Economy

    Broader source: Energy.gov [DOE]

    The Energy Department is investing in groundbreaking research that will make cars weigh less, drive further and consume less fuel.

  12. Evidence for Complex Molecular Architectures for Solvent-Extracted Lignins

    SciTech Connect (OSTI)

    Rials, Timothy G [ORNL; Urban, Volker S [ORNL; Langan, Paul [Los Alamos National Laboratory (LANL)

    2012-01-01

    Lignin, an abundant, naturally occurring biopolymer, is often considered 'waste' and used as a simple fuel source in the paper-making process. However, lignin has emerged as a promising renewable resource for engineering materials, such as carbon fibers. Unfortunately, the molecular architecture of lignin (in vivo and extracted) is still elusive, with numerous conflicting reports in the literature, and knowledge of this structure is extremely important, not only for materials technologies, but also for production of biofuels such as cellulosic ethanol due to biomass recalcitrance. As such, the molecular structures of solvent-extracted (sulfur-free) lignins, which have been modified using various acyl chlorides, have been probed using small-angle X-ray (SAXS) and neutron (SANS) scattering in tetrahydrofuran (THF) solution along with hydrodynamic characterization using dilute solution viscometry and gel permeation chromatography (GPC) in THF. Mass spectrometry shows an absolute molecular weight {approx}18-30 kDa ({approx}80-140 monomers), while GPC shows a relative molecular weight {approx}3 kDa. A linear styrene oligomer (2.5 kDa) was also analyzed in THF using SANS. Results clearly show that lignin molecular architectures are somewhat rigid and complex, ranging from nanogels to hyperbranched macromolecules, not linear oligomers or physical assemblies of oligomers, which is consistent with previously proposed delignification (extraction) mechanisms. Future characterization using the methods discussed here can be used to guide extraction processes as well as genetic engineering technologies to convert lignin into value added materials with the potential for high positive impact on global sustainability.

  13. Fuels Technologies

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping intoand DavidEnergyVirginiaEnergy|Fuels

  14. Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Impulsive solvent heating probed by picosecond x-ray diffraction M. Cammarata European Synchrotron, the solute-solvent cross term, and the solvent-only term. The last term is very sensitive to the thermodynamic state of the bulk solvent, which may change during a chemical reaction due to energy transfer from

  15. Mechanistic Origins of Hierarchical Order in Organic Monolayers Deposited From Liquid Crystal Solvents

    E-Print Network [OSTI]

    Patrick, David L.

    Solvents Nick E. Gislason, Calvin Murphy, and David L. Patrick* Department of Chemistry, Western Washington two oriented liquid crystal solvents and one isotropic solvent using a sacrificial template method in which a solvent film applied in a first deposition step is displaced by BOC in a second deposition step

  16. WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other

    E-Print Network [OSTI]

    Haimovich, Alexander

    WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other solvents indicates that these solvents can be customized with the chemical muscle to dissolve almost any material are a groundbreaking green alternative to highly toxic solvents capable of causing signifi- cant environmental harm

  17. Solvent-Promoted Self-Healing Epoxy Materials Mary M. Caruso, David A. Delafuente, Victor Ho,

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Solvent-Promoted Self-Healing Epoxy Materials Mary M. Caruso, David A. Delafuente, Victor Ho, Nancy of a solvent to a polymer matrix. Solvents such as ethanol and methanol were used to seal the cracks.15-17 Raman and Palmese found that solvent molecules can influence the epoxy-amine reaction chemistry

  18. Solvent Quality Changes the Structure of G8 PAMAM Dendrimer, a Disagreement with Some Experimental Interpretations

    E-Print Network [OSTI]

    Goddard III, William A.

    Solvent Quality Changes the Structure of G8 PAMAM Dendrimer, a Disagreement with Some Experimental on the solvent quality, but recently a disagreement concerning the magnitude and sign has arisen.7,8 Small that with decreasing solvent quality (decrease of the polarity of the solvent) the radius of gyration of PAMAM

  19. Solvent Entrainment in and Flocculation of Asphaltenic Aggregates Probed by Small-Angle Neutron Scattering

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Articles Solvent Entrainment in and Flocculation of Asphaltenic Aggregates Probed by Small solvents in which a broad spectrum of solute and solvent chemical compositions was represented. Fits of solvent entrainment from 30 to 50% (v/v) within the aggregates that were consistent with previous

  20. Corpus Callosum Volume in Railroad Workers With Chronic Exposure to Solvents

    E-Print Network [OSTI]

    Corpus Callosum Volume in Railroad Workers With Chronic Exposure to Solvents Marc W. Haut, Ph reported after long-term exposure to solvents. Solvents are hypothesized to affect brain white matter to solvents. Methods: We manually traced (blind to group membership) the volume of the corpus callosum in 31

  1. CHBE 484 Solvent Recovery Project Group Department of Chemical and Biological Engineering

    E-Print Network [OSTI]

    CHBE 484 Solvent Recovery Project Group Department of Chemical and Biological Engineering Vancouver, B.C. Canada V6T 1Z1 Dear Mr. Craig Smith: RE: Solvent Recovery Report for CHBE 484 Green Engineering The UBC solvent recovery program has been successful in recovering solvents such as acetone

  2. Effect of Solvent Evaporation on Fiber Morphology in Rotary Jet Holly McIlwee Golecki,,

    E-Print Network [OSTI]

    Parker, Kevin Kit

    and solvent evaporation enables production of nanoscale polymer fibers. RJS surpasses the electrospinning

  3. Solvent extraction and recovery of the transuranic elements from waste solutions using the TRUEX process

    SciTech Connect (OSTI)

    Horwitz, E.P.; Schulz, W.W.

    1985-01-01

    High-level liquid waste is produced during the processing of irradiated nuclear fuel by the PUREX process. In some cases the treatment of metallurgical scrap to recover the plutonium values also generates a nitric acid waste solution. Both waste solutions contain sufficient concentrations of transuranic elements (mostly /sup 241/Am) to require handling and disposal as a TRU waste. This paper describes a recently developed solvent extraction/recovery process called TRUEX (transuranium extraction) which is designed to reduce the TRU concentration in nitric waste solutions to <100 nCi/g of disposed form (1,2). (In the USA, non-TRU waste is defined as <100 nCi of TRU/g of disposed form.) The process utilizes PUREX process solvent (TBP in a normal paraffinic hydrocarbon or carbon tetrachloride) modified by a small concentration of octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (abbrev. CMPO). The presence of CMPO enables the modified PUREX process solvent to extract trivalent actinides as well as tetra- and hexavalent actinides. A major feature of the TRUEX process is that is is applicable to waste solutions containing a wide range of nitric acid, salt, and fission product concentrations and at the same time is very compatible with existing liquid-liquid extraction technology as usually practiced in a fuel reprocessing plant. To date the process has been tested on two different types of synthetic waste solutions. The first solution is a typical high-level nitric acid waste and the second a typical waste solution generated in metallurgical scrap processing. Results are discussed. 4 refs., 1 fig., 4 tabs.

  4. Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent

    SciTech Connect (OSTI)

    Ginosar, Daniel M.; Wendt, Daniel S.; Petkovic, Lucia M.

    2014-06-10

    A method of removing a nonpolar solvent from a fluid volume that includes at least one nonpolar compound, such as a fat, an oil or a triglyceride, is provided. The method comprises contacting a fluid volume with an expanding gas to expand the nonpolar solvent and form a gas-expanded solvent. The gas-expanded solvent may have a substantially reduced density in comparison to the at least one nonpolar compound and/or a substantially reduced capacity to solubilize the nonpolar compound, causing the nonpolar compounds to separate from the gas-expanded nonpolar solvent into a separate liquid phase. The liquid phase including the at least one nonpolar compound may be separated from the gas-expanded solvent using conventional techniques. After separation of the liquid phase, at least one of the temperature and pressure may be reduced to separate the nonpolar solvent from the expanding gas such that the nonpolar solvent may be recovered and reused.

  5. Transportation Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired SolarAbout / Transforming Y-12Capacity-Forum

  6. Renewable Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners *ReindustrializationEnergyWind Energy Wind Energy Renewable

  7. fuel cells

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4)9 Federal RegisterStorm1 3446 YEAR/%2Afissile4/%2A en

  8. Essential roles of protein-solvent many-body correlation in solvent-entropy

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article) | SciTech(Journal(Patent)pressure in Ba ( Fe 1 - x Co x ) 2 Aseffect

  9. Development of Effective Solvent Modifiers for the Solvent Extraction of Cesium from Alkaline High-Level Tank Waste.

    SciTech Connect (OSTI)

    Bonnesen, Peter V.; Delmau, Laetitia H.; Moyer, Bruce A.; Lumetta, Gregg J. )

    2003-01-01

    A series of novel alkylphenoxy fluorinated alcohols were prepared and investigated for their effectiveness as modifiers in solvents containing calix[4]arene-bis-(tert-octylbenzo)-crown-6 for extracting cesium from alkaline nitrate media. A modifier that contained a terminal 1,1,2,2-tetrafluoroethoxy group was found to decompose following long-term exposure to warm alkaline solutions. However, replacement of the tetrafluoroethoxy group with a 2,2,3,3-tetrafluoropropoxy group led to a series of modifiers that possessed the alkaline stability required for a solvent extraction process. Within this series of modifiers, the structure of the alkyl substituent (tert-octyl, tert-butyl, tert-amyl, and sec-butyl) of the alkylphenoxy moiety was found to have a profound impact on the phase behavior of the solvent in liquid-liquid contacting experiments, and hence on the overall suitability of the modifier for a solvent extraction process. The sec-butyl derivative[1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol] (Cs-7SB) was found to possess the best overall balance of properties with respect to third phase and coalescence behavior, cleanup following degradation, resistance to solids formation, and cesium distribution behavior. Accordingly, this modifier was selected for use as a component of the solvent employed in the Caustic-Side Solvent Extraction (CSSX) process for removing cesium from high level nuclear waste (HLW) at the U.S. Department of Energy?s (DOE) Savannah River Site. In batch equilibrium experiments, this solvent has also been successfully shown to extract cesium from both simulated and actual solutions generated from caustic leaching of HLW tank sludge stored in tank B-110 at the DOE?s Hanford Site.

  10. Fuel injector

    DOE Patents [OSTI]

    Lambeth, Malcolm David Dick (Bromley, GB)

    2001-02-27

    A fuel injector comprises first and second housing parts, the first housing part being located within a bore or recess formed in the second housing part, the housing parts defining therebetween an inlet chamber, a delivery chamber axially spaced from the inlet chamber, and a filtration flow path interconnecting the inlet and delivery chambers to remove particulate contaminants from the flow of fuel therebetween.

  11. Fuel rail

    SciTech Connect (OSTI)

    Haigh, M.; Herbert, J.D.; O'Leary, J.J.

    1988-09-20

    This patent describes a fuel rail for a V-configuration automotive type internal combustion engine having a throttle body superimposed over an intake manifold. The throttle body has an air plenum above an induction channel aligned with a throttle bore passage in the manifold for flow or air to the engine cylinders. The rail includes a spacer body mounted sealingly between the throttle body and the manifold of the engine and having air induction passages therethrough to connect the throttle body channels and the manifold, the spacer body having at least on longitudinal bore defining a fuel passage extending through the spacer body, and a fuel injector receiving cups projecting from and communicating with the fuel passage. The spacer body consists of a number of separated spacer members, and rail member means through which the fuel passage runs joining the spacer members together.

  12. Ion Exchange and Solvent Extraction: Supramolecular Aspects of Solvent Exchange Volume 21

    SciTech Connect (OSTI)

    Gloe, Karsten [Technischen Universität Dresden] [Technischen Universität Dresden; Tasker, Peter A [ORNL] [ORNL; Oshima, Tatsuya [University of Miyazaki] [University of Miyazaki; Watarai, Hitoshi [Institute for NanoScience Design at Osaka University] [Institute for NanoScience Design at Osaka University; Nilsson, Mikael [University of California, Irvine] [University of California, Irvine

    2013-01-01

    Preface The theme of supramolecular chemistry (SC), entailing the organization of multiple species through noncovalent interactions, has permeated virtually all aspects of chemical endeavor over the past several decades. Given that the observed behavior of discrete molecular species depends upon their weak interactions with one another and with matrix components, one would have to conclude that SC must indeed form part of the fabric of chemistry itself. A vast literature now serves to categorize SC phenomena within a body of consistent terminology. The word supramolecular itself appears in the titles of dozens of books, several journals, and a dedicated encyclopedia. Not surprisingly, the theme of SC also permeates the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. It is attempted in the six chapters of this volume to identify both how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the current direction of SX. Researchers and practitioners have long dealt with supramolecular interactions in SX. Indeed, the use of polar extractant molecules in nonpolar media virtually assures that aggregative interactions will dominate the solution behavior of SX. Analytical chemists working in the 1930s to the 1950s with simple mono- and bidentate chelating ligands as extractants noted that extraction of metal ions obeyed complicated mass-action equilibria involving complex stoichiometries. As chemists and engineers developed processes for nuclear and hydrometallurgical applications in the 1950s and 1960s, the preference for aliphatic diluents only enhanced the complexity and supramolecular nature of extraction chemistry. Use of physical techniques such as light scattering and vapor-pressure measurements together with various spectroscopic methods revealed organic-phase aggregates from well-defined dimers to small aggregates containing a few extractant molecules to large inverse micelles swollen with water molecules. Extraction systems involving long-chain cations such as alkylammonium species or long-chain anions such as sulfonates or carboxylates proved especially prone to extensive aggregate formation. The related phenomenon of third-phase formation in SX systems, long misunderstood, is now yielding to spectroscopic and scattering techniques showing extensive long-range organization. Over the last 50 years, tools for studying the structure and thermodynamics of aggregation have grown increasingly sophisticated, leading to a rich and detailed understanding of what we can now recognize as SC phenomena in SX. In the 1970s and 1980s, the rapid growth of SC elicited a paradigm shift in SX. The influence of SC principles had two major effects on the course of SX research. First, it provided a framework for understanding the supramolecular behavior that was already well appreciated in the field of SX, though earlier without the SC terminology. Second, it provided the conceptual tools to control supramolecular behavior in SX, direct it for intended functionality, and to simplify it. Extraction by designed reagents has been steadily progressing ever since, with commercial applications emerging to successfully validate this approach. With the discovery of crown ethers in the late 1960s, the advancement of extractant design has fruitfully employed the concept of inclusion. While considerable initial progress occurred with such molecules, especially because of their affinity and selectivity for alkali and alkaline earth metals, other molecular platforms such as calixarenes have proven more versatile. Multidentate receptors for partial to full inclusion of cations, anions, ion pairs, as well as neutral species, have now become commonplace for selective extraction. This volume of Ion Exchange and Solvent Extraction examines how the principles of SC are being employed both in advancing the design of new highly selective SX systems and in understanding aggregation phenomena in SX systems. Chapter 1 discusses the nature and definition of SC

  13. Development of novel contactor for nuclear solvent extraction

    SciTech Connect (OSTI)

    Kumar, Shekhar; Kumar, Rajnish; Sivakumar, D.; Balamurugan, M.; Koganti, S.B.

    2008-07-01

    For current designs of radiochemical plants, solvent-extraction contactors with no periodic maintenance like pulse column are the first choice. In addition, as costs of specialty solvents for nuclear extraction are quite high, there is a demand for operation at extreme phase ratios. Recently a novel mixer-settler was visualized and developed for this kind of service. The mixer of the novel contactor is based on rotated helical tubes and does not involve any mechanical moving part. Mass-transfer runs were carried out with aqueous nitric acid and 30% TBP solvent at A/O of 0.25-200 (in extraction) and A/O of 0.25-10 (in back-extraction mode). The developed contactor exhibited nearly 100% efficiency for all the cases. (authors)

  14. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  15. Degradation problems with the solvent extraction organic at Roessing uranium

    SciTech Connect (OSTI)

    Munyungano, Brodrick; Feather, Angus; Virnig, Michael

    2008-07-01

    Roessing Uranium Ltd recovers uranium from a low-grade ore in Namibia. Uranium is recovered and purified from an ion-exchange eluate in a solvent-extraction plant. The solvent-extraction plant uses Alamine 336 as the extractant for uranium, with isodecanol used as a phase modifier in Sasol SSX 210, an aliphatic hydrocarbon diluent. Since the plant started in the mid 1970's, there have been a few episodes where the tertiary amine has been quickly and severely degraded when the plant was operated outside certain operating parameters. The Rossing experience is discussed in more detail in this paper. (authors)

  16. Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass

    E-Print Network [OSTI]

    Cai, Charles Miao-Zi

    2014-01-01

    estimated capital expenses (CapEx) for the major equipmentas this and the additional CapEx for each subsequent reactor

  17. Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass

    E-Print Network [OSTI]

    Cai, Charles Miao-Zi

    2014-01-01

    Streams." Energy & Environmental Science 6, no. 1 Pace,Industries." Energy & Environmental Science 4, no. 6 (2011):Chemistry." Energy & Environmental Science 4, no. 4

  18. Fuel economizer

    SciTech Connect (OSTI)

    Zwierzelewski, V.F.

    1984-06-26

    A fuel economizer device for use with an internal combustion engine fitted with a carburetor is disclosed. The fuel economizer includes a plate member which is mounted between the carburetor and the intake portion of the intake manifold. The plate member further has at least one aperture formed therein. One tube is inserted through the at least one aperture in the plate member. The one tube extends longitudinally in the passage of the intake manifold from the intake portion toward the exit portion thereof. The one tube concentrates the mixture of fuel and air from the carburetor and conveys the mixture of fuel and air to a point adjacent but spaced away from the inlet port of the internal combustion engine.

  19. Study of the combustion of various alternate fuels

    SciTech Connect (OSTI)

    Barfield, B.F.; Acker, G.J. Jr.; Lindsay, M.H.

    1984-01-01

    This research project used two methods for studying the problems facing alternate fuels. The first method studied the use of chemicals to improve fuel characteristics without changing the basic engine design. The second method was to make engine modifications to suit characteristics of the alternate fuel. The result of the two methods studied is a two-part report. Alcohols, solvent-refined coal (SRC-II), vegetable oils, and mixtures of these with diesel fuels and with each other are the alternative fuels discussed and tested. 21 references, 4 figures, 10 tables.

  20. Treatment of Chlorinated Solvents by Nitrogen-Fixing and

    E-Print Network [OSTI]

    Chu, Kung-Hui "Bella"

    ). Therefore, effective contaminant destruction approaches such as in-situ vadose zone bioremediation or above of ground- water contaminants including aliphatic, aromatic, and halogenated hydrocarbons (3 bioremediation for the treatment of chlorinated solvents at Savannah River (6, 7). At this site, nitrogen

  1. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    of the requirements of the Degree of Doctor of Philosophy in Chemical Engineering Practice Abstract In the light1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman B. Chem. Eng. Institute of Chemical Technology, University of Mumbai, 2005 M.S. Chemical Engineering

  2. Solvent Size vs Cohesive Energy as the Origin of Hydrophobicity

    E-Print Network [OSTI]

    Lazaridis, Themis

    of Chemistry, City College of CUNY, Convent Avenue & 138th Street, New York, New York 10031 Received March 22Solvent Size vs Cohesive Energy as the Origin of Hydrophobicity THEMIS LAZARIDIS* Department of water's properties and report a detailed decomposition of the solvation free energy, enthalpy, entropy

  3. Photolysis of RDX and HMX in aqueous and organic solvents 

    E-Print Network [OSTI]

    Choi, Jihyun

    2000-01-01

    the model had a significant amount of lack-of-fit when it was applied to empirical data. Using the selected kinetic model, solvent parameters and the initial concentration of HEs were studied to see their effects on the photolysis rate. Solution pH, buffers...

  4. Electrostatic interactions in charged nanoslits within an explicit solvent theory

    E-Print Network [OSTI]

    Sahin Buyukdagli

    2015-07-23

    Within a dipolar Poisson-Boltzmann theory including electrostatic correlations, we consider the effect of explicit solvent structure on solvent and ion partition confined to charged nanopores. We develop a relaxation scheme for the solution of this highly non-linear integro-differential equation for the electrostatic potential. The scheme is an extension of the approach previously introduced for simple planes (S. Buyukdagli and Ralf Blossey, J. Chem. Phys. 140, 234903 (2014)) to nanoslit geometry. We show that the reduced dielectric response of solvent molecules at the membrane walls gives rise to an electric field significantly stronger than the field of the classical Poisson-Boltzmann equation. This peculiarity associated with non-local electrostatic interactions results in turn in an interfacial counterion adsorption layer absent in continuum theories. The observation of this enhanced counterion affinity in the very close vicinity of the interface may have important impacts on nanofludic transport through charged nanopores. Our results indicate the quantitative inaccuracy of solvent implicit nanofiltration theories in predicting the ionic selectivity of membrane nanopores.

  5. Filming the Birth of Molecules and Accompanying Solvent Rearrangement

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    the products. As a result, the properties of the solvent significantly affect the energy landscape, rates of Chemistry, Technical University of Denmark, Kemitorvet 207, 2800 Kgs. Lyngby, Denmark # Synchrotron Soleil Supporting Information ABSTRACT: Molecules are often born with high energy and large-amplitude vibrations

  6. MODELING OF CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION IN GROUNDWATER

    E-Print Network [OSTI]

    Boyer, Edmond

    1 MODELING OF CHLORINATED SOLVENTS TRANSPORT AND NATURAL ATTENUATION IN GROUNDWATER QUIOT Fabrice1 performed by 4 teams (ANTEA, ENSMP, ENVIROS and INERIS) to simulate a contamination of groundwater is the evaluation of the fate of pollutants in groundwaters and soils. This knowledge is based on the result

  7. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  8. NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)

    SciTech Connect (OSTI)

    Fondeur, F.; Peters, T.; Fink, S.

    2012-01-17

    The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and with the exception of CPVC, no leachate was observed in the NGS from any of the polymers studied. The testing shows no major concerns for compatibility over the short duration of these tests but does indicate that longer duration exposure studies are warranted, especially for Tefzel. However, the physical changes experienced by Tefzel in the improved solvent were comparable to the physical changes obtained when Tefzel is placed in CSSX baseline solvent. Therefore, there is no effect of the improved solvent beyond those observed in CSSX baseline solvent.

  9. Method for sintering fuel cell electrodes using a carrier

    SciTech Connect (OSTI)

    Donelson, R.; Bryson, E.S.

    1995-03-28

    A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  10. Method for sintering fuel cell electrodes using a carrier

    DOE Patents [OSTI]

    Donelson, Richard (Victoria, AU); Bryson, E. S. (Downers Grove, IL)

    1995-01-01

    A carrier for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  11. THE COMBUSTION OF SOLVENT REPINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME

    E-Print Network [OSTI]

    Chin, W.K.

    2011-01-01

    R.F. (1977). Combustion of coal in an opposed flow diffusionpulverized, solvent-refined coal. ASME Paper No. 76-WA/FU-6.OF SOLVENT REFINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME*

  12. Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control January 13, 2015 - 11:20am...

  13. Strategies for the aerobic co-metabolism of chlorinated solvents CURRENT OPINION IN BIOTECHNOLOGY

    E-Print Network [OSTI]

    Semprini, Lewis

    Strategies for the aerobic co-metabolism of chlorinated solvents Semprini L CURRENT OPINION for aerobic co- metabolism of chlorinated solvents. Different co-metabolic substrates and different methods

  14. Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from

    E-Print Network [OSTI]

    California at Riverside, University of

    Co-solvent Pretreatment Reduces Costly Enzyme Requirements for High Sugar and Ethanol Yields from limits potential sugar yields.[7] Thus, it is desirable We introduce a new pretreatment called co-solvent

  15. Simulations of time-dependent fluorescence in nano-confined solvents

    E-Print Network [OSTI]

    Thompson, Ward H.

    2004-04-13

    The time-dependent fluorescence of a model diatomic molecule with a charge-transfer electronic transition in confined solvents has been simulated. The effect of confining the solvent is examined by comparing results for solutions contained within...

  16. Simultaneous sweetening and dehydration of natural gas using a mixed solvent solution 

    E-Print Network [OSTI]

    Garza, Jaime Javier

    1997-01-01

    Mixed solvent solutions of Solvent X in TEG at various concentrations were developed to simultaneously sweeten and dehydrate a wet, sour natural gas stream. An experimental apparatus consisting of a high pressure gas circulation loop and a low...

  17. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  18. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S.

    2012-07-24

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  19. Densities in the Liquid Hydrogen Chloride Solvent System Heather Brooks Shapiro and Donald R. Sadoway*

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    Densities in the Liquid Hydrogen Chloride Solvent System Heather Brooks Shapiro and Donald R in the hydrogen chloride solvent system over the normal liquid range of the solvent. In addition to pure hydrogen to be insoluble in liquid hydrogen chloride. Solutions were prepared by condensing hydrogen chloride over solute

  20. Scientific Correspondence Are Natural Deep Eutectic Solvents the Missing Link in

    E-Print Network [OSTI]

    Galis, Frietson

    and deep eutectic solvents (DES) have been revisited by chemical engineering, because such solvents canScientific Correspondence Are Natural Deep Eutectic Solvents the Missing Link in Understanding that the metabolites that occur in large amounts in cells may form a third type of liquid, one separate from water

  1. Dynamical Arrest of Electron Transfer in Liquid Crystalline Solvents Vitaliy Kapko and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Dynamical Arrest of Electron Transfer in Liquid Crystalline Solvents Vitaliy Kapko and Dmitry V Form: May 3, 2006 We argue that electron transfer reactions in slowly relaxing solvents proceed in the nonergodic regime, making the reaction activation barrier strongly dependent on the solvent dynamics

  2. Heme-Solvent Coupling: A Mo ssbauer Study of Myoglobin in Sucrose H. Lichtenegger,* W. Doster,#

    E-Print Network [OSTI]

    Lichtenegger, Helga C.

    Heme-Solvent Coupling: A Mo¨ ssbauer Study of Myoglobin in Sucrose H. Lichtenegger,* W. Doster,# T% sucrose/water, a protein-stabilizing solvent, to vibrational and diffusive modes of the heme iron of CO the iron is fully exposed in the same solvent. The temperature dependence of the Mo¨ ssbauer parameters

  3. Solvent Quality Dependent Continuum van der Waals Attraction and Phase Behavior for Colloids Bearing

    E-Print Network [OSTI]

    Chan, Derek Y C

    Solvent Quality Dependent Continuum van der Waals Attraction and Phase Behavior for Colloids dispersion as a function of solvent quality and particle volume fraction is compared with theoretical.5 M NaCl as a function of temperature, which controls solvent quality for the adsorbed Pluronic

  4. PESTICIDES AND SOLVENTS Modern pesticides include a diverse number of compounds, grouped according to

    E-Print Network [OSTI]

    Radcliffe, David

    PESTICIDES AND SOLVENTS Modern pesticides include a diverse number of compounds, grouped according in groundwater today. Solvents include a number of organic liquids that are used in a variety of house- hold products such as paint, cleaners, degreasers, and other applications. The most dangerous solvents often

  5. Collapse transition of a hydrophobic self avoiding random walk in a coarse-grained model solvent

    E-Print Network [OSTI]

    Vinals, Jorge

    Collapse transition of a hydrophobic self avoiding random walk in a coarse-grained model solvent in a lattice model of a solvent. As expected, hydrophobic interactions lead to an attractive potential of mean force among chain segments. As a consequence, the random walk in solvent undergoes a collapse transition

  6. Modeling of electrochemomechanical response of ionic polymer-metal composites with various solvents

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Modeling of electrochemomechanical response of ionic polymer-metal composites with various solvents and the amount of solvent uptake, the morphology of the electrodes, the composition of the backbone ionomer variations of the applied potential. Our most recent experimental results show that solvents can have

  7. Reorganization energy of intermolecular electron transfer in solvents near isotropicnematic transition

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Reorganization energy of intermolecular electron transfer in solvents near isotropic of orientational isotropic/ nematic phase transition. These data are used to calculate the solvent reorganization.1063/1.1580107 I. INTRODUCTION The effect of a condensed-phase solvent on the kinetics of electron transfer ET

  8. Effects of Knots on Ring Polymers in Solvents of Varying Quality Arturo Narros,*,

    E-Print Network [OSTI]

    Likos, Christos N.

    Effects of Knots on Ring Polymers in Solvents of Varying Quality Arturo Narros,*, Angel J. Moreno the conformations and the interactions of ring polymers under conditions of worsening solvent quality, in comparison with molecular weight and one based on the dependence of the effective interaction on solvent quality

  9. Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells Harry J. Ploehn,z

    E-Print Network [OSTI]

    Solvent Diffusion Model for Aging of Lithium-Ion Battery Cells Harry J. Ploehn,z Premanand Ramadass model of solvent diffusion describing the growth of solid-electrolyte inter- faces SEIs in Li-ion cells incorporating carbon anodes. The model assumes that a reactive solvent component diffuses through the SEI

  10. Solvent mediated assembly of nanoparticles confined in mesoporous alumina Kyle J. Alvine,1,

    E-Print Network [OSTI]

    Pershan, Peter S.

    Solvent mediated assembly of nanoparticles confined in mesoporous alumina Kyle J. Alvine,1, * Diego solvent and confined within mesoporous alumina was probed in situ with small angle x-ray scattering of solvent condensed from an under- saturated vapor. Analysis indicated that the nanoparticles self

  11. Effects of Solvent Mediated Interactions on Electrolytes and Related Electrostatic Systems

    E-Print Network [OSTI]

    Effects of Solvent Mediated Interactions on Electrolytes and Related Electrostatic Systems Thesis. The first issue is concerned with discrete polar solvents such as water. The main objective is to study the consequences of solvent discreteness, as opposed to a continuous dielectric medium. Ion-ion interactions

  12. On the validity of dielectric continuum models in application to solvation in molecular solvents

    E-Print Network [OSTI]

    Matyushov, Dmitry

    On the validity of dielectric continuum models in application to solvation in molecular solvents simulations of solvation of a point dipole in dipolar­quadrupolar solvents of varying dipole moment and axial of a monotonic increase of the absolute value of the solvation chemical potential p with the solvent dielectric

  13. Molecular simulation study of nanoscale friction between alkyl monolayers on Si,,111... immersed in solvents

    E-Print Network [OSTI]

    Zhang, Luzheng

    in solvents Luzheng Zhanga) and Shaoyi Jiangb) Department of Chemical Engineering, University of Washington monolayers immersed in liquid solvents. Three pairs of interfaces, ranging from hydrophobic CH3 /CH3 to hydrophilic OH/OH, were studied. Three solvents, including water, methanol, and n-decane were used

  14. Solvent Reclaiming by Crystallization of Potassium Sulfate Qing Xu, B. S.

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Copyright by Qing Xu 2008 #12;Solvent Reclaiming by Crystallization of Potassium Sulfate by Qing Xu of Texas at Austin December 2008 #12;Solvent Reclaiming by Crystallization of Potassium Sulfate Approved study. Thank you my friends who are always there for me. December 5th , 2008 #12;vi Abstract Solvent

  15. A Coarse-Grained Protein Model in a Water-like Solvent

    E-Print Network [OSTI]

    Buldyrev, Sergey

    A Coarse-Grained Protein Model in a Water-like Solvent Sumit Sharma1 *, Sanat K. Kumar1 , Sergey V an explicit atom description of proteins in solvent can be computationally expensive. On the other hand, coarse-grained protein models in implicit solvent miss essential features of the hydrophobic effect

  16. A Solvent-Free Thermosponge Nanoparticle Platform for Efficient Delivery of Labile Proteins

    E-Print Network [OSTI]

    von Andrian, Ulrich H.

    A Solvent-Free Thermosponge Nanoparticle Platform for Efficient Delivery of Labile Proteins Won Il a solvent-free polymer thermo-expansion mechanism with clinical potential, capable of effectively delivering biological half-lives and efficacy in vivo. KEYWORDS: Nanoparticles, thermosponge, solvent-free, therapeutic

  17. Consecutive Solvent Evaporation and Co-Rolling Techniques for Polymer Multilayer Hollow Fiber

    E-Print Network [OSTI]

    Skorobogatiy, Maksim

    Consecutive Solvent Evaporation and Co-Rolling Techniques for Polymer Multilayer Hollow Fiber, "Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber preform Layer-by-Layer Solvent Evaporation Process Polymer tube (cladding) Polymer 1 Polymer 2 Drawing Fiber #12

  18. Effect of solvents on the chemical and physical properties of ionic polymer-metal composites

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    Effect of solvents on the chemical and physical properties of ionic polymer-metal composites Sia of solvent uptake, the morphology of the electrodes, the composition of the backbone ionomer, the geometry of the applied potential. With water as the solvent, the applied electric potential must be limited to less than

  19. Influence of Solvent Molecules on the Stereochemical Code of Glycyl Residues in Proteins

    E-Print Network [OSTI]

    Srinivasan, N.

    Influence of Solvent Molecules on the Stereochemical Code of Glycyl Residues in Proteins Narayanan- tions are shown to have highest solvent accessibility in a system of two-linked peptide units high solvent accessibility. Analysis of a subset of nonhomologous structures with very high resolu

  20. Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber preform fabrication

    E-Print Network [OSTI]

    Skorobogatiy, Maksim

    Consecutive solvent evaporation and co-rolling techniques for polymer multilayer hollow fiber photonic fiber preforms were fabricated using consecutive deposition from a solvent phase of two polymers process involved consecutive film deposition by solvent evaporation of polymer solutions on the inside

  1. Solvent Polarization and Kinetic Isotope Effects in Nitroethane Deprotonation and Implications to the Nitroalkane Oxidase Reaction

    E-Print Network [OSTI]

    Minnesota, University of

    Solvent Polarization and Kinetic Isotope Effects in Nitroethane Deprotonation and Implications proton abstraction, and nitroalkane ionization is predicted to have large solvent effects with increased free energy barrier in protic solvents.1,2 The deprotonation of nitroalkanes is catalyzed by the flavo

  2. Anomalous Capacitance Maximum of the Glassy Carbon-Ionic Liquid Interface through Dilution with Organic Solvents

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    with Organic Solvents David J. Bozym, Betul Uralcan, David T. Limmer, Michael A. Pope, Nicholas J. Szamreta liquid with miscible organic solvents on the differential capacitance of the glassy carbon,2-dichloroethane, a low- dielectric constant solvent, yield the largest gains in capacitance near the open circuit

  3. Coarse-graining and phase behavior of model star polymercolloid mixtures in solvents of varying quality

    E-Print Network [OSTI]

    Likos, Christos N.

    Coarse-graining and phase behavior of model star polymer­colloid mixtures in solvents of varying-grained models for mixtures of colloids and linear polymers under good-solvent conditions J. Chem. Phys. 141, 244905 (2014); 10.1063/1.4904392 Surface adsorption of colloidal brushes at good solvents conditions J

  4. Anal. Chem. 1994,66,168-176 Classification of Countercurrent Chromatography Solvent

    E-Print Network [OSTI]

    Wesfreid, José Eduardo

    Anal. Chem. 1994,66,168-176 Classification of Countercurrent Chromatography Solvent Systems Cedex 05, France Solvent systems used for countercurrent chromatography (CCC) have been classified in a countercurrentchromatograph. To achievegoodretentionof one phase of a solvent system when the other one is pumped inthecolumn

  5. Materials SafetyProper Disposal of Waste Contaminated with Hazardous Solvents

    E-Print Network [OSTI]

    Materials SafetyProper Disposal of Waste Contaminated with Hazardous Solvents A M e s s a g e f r o released from solvent-soaked polishing cloths that had been improperly tossed in a general trash can in the hallway. As the janitor removed the bag from the trashcan, she inhaled concentrated solvent vapor

  6. Solvent relaxation effects on the kinetics of photoinduced electron transfer reactions

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent relaxation effects on the kinetics of photoinduced electron transfer reactions J. Najbar formation and recombination of radical- ion pairs limited by solvent dielectric relaxation. The problem). Solvent relaxation moves the system to lower energy on the radical-ion pair surface where crossing

  7. Depletion-induced surface alignment of asymmetric diblock copolymer in selective solvents

    E-Print Network [OSTI]

    Depletion-induced surface alignment of asymmetric diblock copolymer in selective solvents Rong Wang online 31 July 2008 Phase separation of asymmetric diblock copolymer near surfaces in selective solvents. The walls strongly affect the phase separation of block copolymer in selective solvent, and the depletion

  8. Solvent Effects on Methyl Transfer Reactions. 2. The Reaction of Amines with Trimethylsulfonium Salts

    E-Print Network [OSTI]

    Sklenak, Stepan

    Solvent Effects on Methyl Transfer Reactions. 2. The Reaction of Amines with Trimethylsulfonium the effect of cyclohexane and dimethyl sulfoxide as the solvent on the energy changes. The effect of water as the solvent was studied using the Monte Carlo free energy perturbation method. The reaction with both ammonia

  9. Vehicular fuels and additives for the future

    SciTech Connect (OSTI)

    Not Available

    1988-01-01

    Interest in automotive fuel is resurging. Automobile fuels must increasingly deal with clean air regulations and ozone problems. Furthermore, feedstocks become heavier,as refinery production changes, as more unleaded is produced, and as an increasing number of pollution regulations must be satisfied greater attention will be paid to better mixtures, solvents, additives, and neat methanol. BCC report analyzes developments technologies, markets, players and the political/regulations aspects of this important market. Study also assesses the advantages and drawbacks of methanol, ethanol, MTBE and other additives which have their place as octane enhancers and fuel substitutes-all now deeply involved in the gasoline modification battle. Other issues addressed are subsidies, farm lobbying, imports, pricing, economics, Detroit's response, neat fuel testing projects, volatility problems vs. fewer ozone-forming hydrocarbon species, and emission ratings.

  10. Donor solvent coal liquefaction with bottoms recycle at elevated pressure

    DOE Patents [OSTI]

    Bauman, Richard F. (Houston, TX); Taunton, John W. (Seabrook, TX); Anderson, George H. (Houston, TX); Trachte, Ken L. (Baytown, TX); Hsia, Steve J. (Friendswood, TX)

    1982-01-01

    An improved process for liquefying solid carbonaceous materials wherein increased naphtha yields are achieved by effecting the liquefaction at a pressure within the range from about 1750 to about 2800 psig in the presence of recycled bottoms and a hydrogen-donor solvent containing at least 0.8 wt % donatable hydrogen. The liquefaction is accomplished at a temperature within the range from about 700.degree. to about 950.degree. F. The coal:bottoms ratio in the feed to liquefaction will be within the range from about 1:1 to about 5:1 and the solvent or diluent to total solids ratio will be at least 1.5:1 and preferably within the range from about 1.6:1 to about 3:1. The yield of naphtha boiling range materials increases as the pressure increases but generally reaches a maximum at a pressure within the range from about 2000 to about 2500 psig.

  11. Investigation of HNO2 Production in Solvent Extraction Organic Phases

    SciTech Connect (OSTI)

    Leigh R. Martin

    2014-09-01

    This document is a letter report that was prepared to meet FCR&D level 4 milestone M4FT-14IN0304054, “Investigate HNO2 production in solvent extraction organic phases.” This work was carried out under the auspices of the Fundamental Radiation Chemistry FCR&D work package. This document reports on an initial tests performed to follow HNO2 formation in reference flowsheet relevant organic phases.

  12. DEMONSTRATION OF THE NEXT-GENERATION CAUSTIC-SIDE SOLVENT EXTRACTION SOLVENT WITH 2-CM CENTRIGUGAL CONTRACTORS USING TANK 49H WASTE AND WASTE SIMULANT

    SciTech Connect (OSTI)

    Pierce, R.; Peters, T.; Crowder, M.; Pak, D.; Fink, S.; Blessing, R.; Washington, A.; Caldwell, T.

    2011-11-29

    Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet using MaxCalix for the decontamination of high level waste (HLW). The demonstration was completed using a 12-stage, 2-cm centrifugal contactor apparatus at the Savannah River National Laboratory (SRNL). This represents the first CSSX process demonstration of the MaxCalix solvent system with Savannah River Site (SRS) HLW. Two tests lasting 24 and 27 hours processed non-radioactive simulated Tank 49H waste and actual Tank 49H HLW, respectively. A solvent extraction system for removal of cesium from alkaline solutions was developed utilizing a novel solvent invented at the Oak Ridge National Laboratory (ORNL). This solvent consists of a calix[4]arene-crown-6 extractant dissolved in an inert hydrocarbon matrix. A modifier is added to the solvent to enhance the extraction power of the calixarene and to prevent the formation of a third phase. An additional additive is used to improve stripping performance and to mitigate the effects of any surfactants present in the feed stream. The process that deploys this solvent system is known as Caustic Side Solvent Extraction (CSSX). The solvent system has been deployed at the Savannah River Site (SRS) in the Modular CSSX Unit (MCU) since 2008.

  13. Polymeric Assembly of Gluten Proteins in an Aqueous Ethanol Solvent

    E-Print Network [OSTI]

    Mohsen Dahesh; Amélie Banc; Agnès Duri; Marie-Hélène Morel; Laurence Ramos

    2014-09-02

    The supramolecular organization of wheat gluten proteins is largely unknown due to the intrinsic complexity of this family of proteins and their insolubility in water. We fractionate gluten in a water/ethanol (50/50 v/v) and obtain a protein extract which is depleted in gliadin, the monomeric part of wheat gluten proteins, and enriched in glutenin, the polymeric part of wheat gluten proteins. We investigate the structure of the proteins in the solvent used for extraction over a wide range of concentration, by combining X-ray scattering and multi-angle static and dynamic light scattering. Our data show that, in the ethanol/water mixture, the proteins display features characteristic of flexible polymer chains in a good solvent. In the dilute regime, the protein form very loose structures of characteristic size 150 nm, with an internal dynamics which is quantitatively similar to that of branched polymer coils. In more concentrated regimes, data highlight a hierarchical structure with one characteristic length scale of the order of a few nm, which displays the scaling with concentration expected for a semi-dilute polymer in good solvent, and a fractal arrangement at much larger length scale. This structure is strikingly similar to that of polymeric gels, thus providing some factual knowledge to rationalize the viscoelastic properties of wheat gluten proteins and their assemblies.

  14. Fluoroalkyl containing salts combined with fluorinated solvents for electrolytes

    SciTech Connect (OSTI)

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Erickson, Michael Jason

    2015-04-21

    Provided are electrochemical cells and electrolytes used to build such cells. An electrolyte may include a fluoroalkyl-substituted LiPF.sub.6 salt or a fluoroalkyl-substituted LiBF.sub.4 salt. In some embodiments, at least one fluorinated alkyl of the salt has a chain length of from 1 to 8 or, more specifically, between about 2 and 8. These fluorinated alkyl groups, in particular, relatively large fluorinated alkyl groups improve solubility of these salts in fluorinated solvents that are less flammable than, for example, conventional carbonate solvents. At the same time, the size of fluoroalkyl-substituted salts should be limited to ensure adequate concentration of the salt in an electrolyte and low viscosity of the electrolyte. In some embodiments, the concentration of a fluoroalkyl-substituted salt is at least about 0.5M. Examples of fluorinated solvents include various fluorinated esters, fluorinated ethers, and fluorinated carbonates, such a 1-methoxyheptafluoropropane, methyl nonafluorobutyl ether, ethyl nonafluorobutyl ether, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-trifluoromethyl-hexane, and 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)-pentane.

  15. Dielectric anisotropy in polar solvents under external fields

    E-Print Network [OSTI]

    Sahin Buyukdagli

    2015-07-23

    We investigate dielectric saturation and increment in polar liquids under external fields. We couple a previously introduced dipolar solvent model to a uniform electric field and derive the electrostatic kernel of interacting dipoles. This procedure allows an unambiguous definition of the liquid dielectric permittivity embodying non-linear dielectric response and correlation effects.We find that the presence of the external field results in a dielectric anisotropy characterized by a two-component dielectric permittivity tensor. The increase of the electric field amplifies the permittivity component parallel to the field direction, i.e. dielectric increment is observed along the field. However, the perpendicular component is lowered below the physiological permittivity, indicating dielectric saturation perpendicular to the field. By comparison with Molecular Dynamics simulations from the literature, we show that the mean-field level dielectric response theory underestimates dielectric saturation. The inclusion of dipolar correlations at the weak-coupling level intensify the mean-field level dielectric saturation and improves the agreement with simulation data at weak electric fields. The correlation-corrected theory predicts as well the presence of a metastable configuration corresponding to the antiparallel alignment of dipoles with the field. This prediction can be verified by solvent-explicit simulations where solvent molecules are expected to be trapped transiently in this metastable state.

  16. Solvent control of crack dynamics in a reversible hydrogel

    E-Print Network [OSTI]

    Tristan Baumberger; Christiane Caroli; David Martina

    2006-05-16

    The resistance to fracture of reversible biopolymer hydrogels is an important control factor of the cutting/slicing and eating characteristics of food gels. It is also critical for their utilization in tissue engineering, for which mechanical protection of encapsulated components is needed. Its dependence on loading rate and, recently, on the density and strength of cross-links has been investigated. But no attention was paid so far to solvent nor to environment effects. Here we report a systematic study of crack dynamics in gels of gelatin in water/glycerol mixtures. We show on this model system that: (i) increasing solvent viscosity slows down cracks; (ii) soaking with solvent increases markedly gel fragility; (iii) tuning the viscosity of the (miscible) environmental liquid affects crack propagation via diffusive invasion of the crack tip vicinity. The results point toward the fact that fracture occurs by viscoplastic chain pull-out. This mechanism, as well as the related phenomenology, should be common to all reversibly cross-linked (physical) gels.

  17. Review Article: The Effects of Radiation Chemistry on Solvent Extraction 3: A Review of Actinide and Lanthanide Extraction

    SciTech Connect (OSTI)

    Bruce J. Mincher; Giuseppe Modolo; Stephen P. Mezyk

    2009-12-01

    The partitioning of the long-lived ?-emitters and the high-yield fission products from dissolved nuclear fuel is a key component of processes envisioned for the safe recycling of nuclear fuel and the disposition of high-level waste. These future processes will likely be based on aqueous solvent extraction technologies for light water reactor fuel and consist of four main components for the sequential separation of uranium, fission products, group trivalent actinides and lanthanides, and then trivalent actinides from lanthanides. Since the solvent systems will be in contact with highly radioactive solutions, they must be robust toward radiolytic degradation in an irradiated mixed organic, aqueous acidic environment. Therefore, an understanding of their radiation chemistry is important to the design of a practical system. In the first paper in this series we reviewed the radiation chemistry of irradiated aqueous nitric acid and the tributyl phosphate ligand for uranium extraction in the first step of these extractions. In the second, we reviewed the radiation chemistry of the ligands proposed for use in the extraction of cesium and strontium fission products. Here, we review the radiation chemistry of the ligands that might be used in the third step in the series of separations, for the group extraction of the lanthanides and actinides. This includes traditional organophosphorous reagents such as CMPO and HDEHP, as well as novel reagents such as the amides and diamides currently being investigated.

  18. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  19. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  20. Experimental solution thermodynamics of a ternary solvent/polymer/solvent system by inverse gas chromatography / by Dominic Wai Wah Ching 

    E-Print Network [OSTI]

    Ching, Dominic Wai Wah

    1978-01-01

    fraction of solvent vapor i in the gas 1 phase. Solving for p. /w gives p. /w. = ['I /(v N )j (R + pB . Qv) Substituting equation 12 into equation 8 gives (12) T (R+PB JT) exp[2/v(y B. +y B. +Y~B. ~)] ( 2 i2 4 (]3) i%3 V M. 2 + 2 + 2 here B = yi...

  1. Oak Ridge K-25 Site chlorinated solvent pollution prevention opportunity assessment

    SciTech Connect (OSTI)

    Not Available

    1994-08-01

    A pollution prevention opportunity assessment (PPOA) was conducted at the Oak Ridge K-25 Site to identify opportunities to reduce and better manage the use of chlorinated solvents. At the K-25 Site, 67 control areas were examined for their potential use of chlorinated solvents. Of these areas, 27 were found to be using (1) chlorinated solvents for cleaning, degreasing, and lubricating; (2) laboratory standards and solvents; and (3) test medium. Current management practices encourage the identification and use of nonhazardous chemicals, including the use of chlorinated solvents. The main pollution prevention principles are source reduction and recycling, and a number of pollution prevention options based on these principles were identified and evaluated as part of this chlorinated solvent PPOA. Source reduction options evaluated for the K-25 Site include the substitution of chlorinated solvents with nonchlorinated solvents. Recycling was identified for those areas that would benefit most from the reuse of the chlorinated solvents in use. The pollution prevention options that offer the greatest opportunity for success at the K-25 Site are the implementation of substitutes at the 10 control areas using chlorinated solvents for cleaning, degreasing, and lubrication. A change in the process may be all that is needed to eliminate the use of a chlorinated solvent. Once a decision is made to implement a substitution, the information should be communicated to all shops and laboratories. Another option to consider is the installation of recycling units to recycle the large amounts of methylene chloride used in the analytical sampling procedure.

  2. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  3. Supporting Information: GM Giambau et al Ion counting from explicit solvent simulations and 3D-RISM Ion counting from explicit solvent simulations and 3D-RISM

    E-Print Network [OSTI]

    Herschlag, Dan

    Supporting Information: GM Giambau et al Ion counting from explicit solvent simulations and 3D, Stanford University, Stanford, CA 94305 USA; ¶ These authors contributed equally GM Giambau and T Luchko Information: GM Giambau et al Ion counting from explicit solvent simulations and 3D-RISM S02 Numerical

  4. Micro Fuel Cells Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Micro Fuel Cells TM Direct Methanol Fuel Cells for Portable Power A Fuel Cell System Developer-17, 2002 Phoenix, Arizona #12;Micro Fuel Cells Direct Methanol Fuel Cells for Portable Power Outline (1 Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

  5. Experimental Study of Nafion-and Flemion-based Ionic Polymer-metal Composites (IPMCs) with Ethylene Glycol as Solvent

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    ) with Ethylene Glycol as Solvent Sia Nemat-Nasser and Shahram Zamani University of California, San Diego Center dependent on the cations used, the solvent, the amount of solvent uptake, the morphology of the electrodes, and other factors. With water as the solvent, the applied electric potential must be limited to less than 1

  6. PHYSICAL REVIEW E 86, 031503 (2012) Hydration and anomalous solubility of the Bell-Lavis model as solvent

    E-Print Network [OSTI]

    Barbosa, Marcia C. B.

    2012-01-01

    as solvent Marcia M. Szortyka,1,* Carlos E. Fiore,2, Marcia C. Barbosa,3, and Vera B. Henriques4,§ 1 the effect of a small concentration of inert solute on the solvent thermodynamic phases. Solute stabilizes the structure of solvent by the organization of solvent particles around solute particles at low temperatures

  7. Reorganization Energy of Electron Transfer in Viscous Solvents above the Glass Transition Pradip K. Ghorai and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Reorganization Energy of Electron Transfer in Viscous Solvents above the Glass Transition Pradip KVed: September 15, 2005; In Final Form: NoVember 6, 2005 We present a molecular-dynamics study of the solvent arrest of the slow, collective relaxation of the solvent related to Debye relaxation of the solvent

  8. Effects of Solvent and Solute Polarizability on the Reorganization Energy of Electron Shikha Gupta and Dmitry V. Matyushov*

    E-Print Network [OSTI]

    Matyushov, Dmitry

    Effects of Solvent and Solute Polarizability on the Reorganization Energy of Electron Transfer of the effect of solute and solvent polarizability on the solvent reorganization energy of intramolecular electron transfer. In the first set of simulations, the polarizability of the solvent is varied at constant

  9. Ions in Mixed Dielectric Solvents: Density Profiles and Osmotic Pressure between Charged Dan Ben-Yaakov and David Andelman*

    E-Print Network [OSTI]

    Podgornik, Rudolf

    Ions in Mixed Dielectric Solvents: Density Profiles and Osmotic Pressure between Charged Interfaces solvents (binary mixture), the osmotic pressure between charged macromolecules is affected by the binary solvent composition. By adding local solvent composition terms to the free energy, we obtain a general

  10. A solvent system to provide selective removal of sulfur compounds

    SciTech Connect (OSTI)

    Pearce, R.L.; Bacon, T.R.

    1986-01-01

    Energy costs and SRU inefficiencies resulting from utilization of low strength MEA technology induced a large refinery to convert to MDEA. One of the seven product streams being treated required extremely low carbonyl sulfide in the treated product. This required careful consideration in making the decision to convert. However, the conclusions were that the advantages outweighed the disadvantages. When the initial converted operations verified a need to improve the carbonyl sulfide removal, GAS/SPEC Tech Service produced an innovative solution which allowed for efficient operation at acceptable COS specification, lower energy utilization, reduced solvent losses, and improved sulfur recovery unit operation.

  11. Conformational transitions of a semiflexible polymer in nematic solvents

    E-Print Network [OSTI]

    Akihiko Matsuyama

    2002-12-05

    Conformations of a single semiflexible polymer chain dissolved in a low molecular weight liquid crystalline solvents (nematogens) are examined by using a mean field theory. We takes into account a stiffness and partial orientational ordering of the polymer. As a result of an anisotropic coupling between the polymer and nematogen, we predict a discontinuous (or continuous) phase transition from a condensed-rodlike conformation to a swollen-one of the polymer chain, depending on the stiffness of the polymer. We also discuss the effects of the nematic interaction between polymer segments.

  12. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a Vehicle Fuel

  13. Alternative Fuels Data Center: Propane Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digglaws-incentivesFuelsPublicationsPlug-InBenefits

  14. Differential Microscopic Mobility of Components within a Deep Eutectic Solvent

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wagle, Durgesh V.; Baker, Gary A.; Mamontov, Eugene

    2015-07-13

    From macroscopic measurements of deep eutectic solvents such as glyceline (1:2 molar ratio of choline chloride to glycerol), the long-range translational diffusion of the larger cation (choline) is known to be slower compared to that of the smaller hydrogen bond donor (glycerol). However, when the diffusion dynamics are analyzed on the subnanometer length scale, we discover that the displacements associated with the localized diffusive motions are actually larger for choline. This counterintuitive diffusive behavior can be understood as follows. The localized diffusive motions confined in the transient cage of neighbor particles, which precede the cage-breaking long-range diffusion jumps, are moremore »spatially constrained for glycerol than for choline because of the stronger hydrogen bonds the former makes with chloride anions. The implications of differential localized mobility of the constituents should be especially important for applications where deep eutectic solvents are confined on the nanometer length scale and their long-range translational diffusion is strongly inhibited (e.g., within microporous media).« less

  15. Solvent-quality dependent contact formation dynamics in proteins

    E-Print Network [OSTI]

    Kundu, Prasanta

    2015-01-01

    The mean time of contact formation between two ends of a protein chain shows power law dependence with respect to the number of residues, $\\tau_{CF} \\sim N^{\\alpha}$. Fluorescence quenching measurements based on triplet-triplet energy transfer show variation in the value of scaling exponent $\\alpha$ for different protein-solvent systems. Here, starting from a non-Markovian diffusion equation supplemented with an exponential sink term that accounts for the energy transfer reaction between donor and acceptor groups, we calculate the mean time of contact formation using the Wilemski-Fixman closure approximation. The non-Markovian diffusion-reaction equation includes the effects of solvent quality and hydrodynamic interaction in a mean-field fashion. It shows that the contact formation dynamics is mainly governed by two time scales, the reciprocal of the intrinsic rate of quenching $(k_0^{ET})^{-1}$, and the relaxation time $\\tau_0 = \\eta b^3/k_B T$ of the coarse-grained residue of an effective size $b$ with solv...

  16. Structure and aggregation of colloids immersed in critical solvents

    E-Print Network [OSTI]

    T. F. Mohry; A. Macio?ek; S. Dietrich

    2012-01-27

    We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of the solvent drive the divergence of the correlation length. Spatial confinements of these critical fluctuations by colloidal solute particles, acting as cavities in the fluctuating medium, restrict and modify the fluctuation spectrum in a way which depends on their relative configuration. This results in effective, so-called critical Casimir forces (CCFs) acting on the confining surfaces. Using the available knowledge about CCFs we study the structure and stability of such colloidal suspensions by employing an approach in terms of effective, one-component colloidal systems. Applying the approximation of pairwise additive CCFs we calculate the radial distribution function of the colloids, which is experimentally accessible. We analyze colloidal aggregation due to CCFs and thus allude to previous experimental studies which are still under debate

  17. Alternative Fuel Implementation Toolkit

    E-Print Network [OSTI]

    ? Alternative Fuels, the Smart Choice: Alternative fuels ­ biodiesel, electricity, ethanol (E85), natural gas

  18. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E. (Finleyville, PA)

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  19. Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability

    SciTech Connect (OSTI)

    Daniel, W. E.

    2013-02-13

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

  20. Processes for preparing carbon fibers using sulfur trioxide in a halogenated solvent

    DOE Patents [OSTI]

    Patton, Jasson T.; Barton, Bryan E.; Bernius, Mark T.; Chen, Xiaoyun; Hukkanen, Eric J.; Rhoton, Christina A.; Lysenko, Zenon

    2015-12-29

    Disclosed here are processes for preparing carbonized polymers (preferably carbon fibers), comprising sulfonating a polymer with a sulfonating agent that comprises SO.sub.3 dissolved in a solvent to form a sulfonated polymer; treating the sulfonated polymer with a heated solvent, wherein the temperature of the solvent is at least 95.degree. C.; and carbonizing the resulting product by heating it to a temperature of 500-3000.degree. C. Carbon fibers made according to these methods are also disclosed herein.

  1. Minnesota Solvent Descriptor Database Paul Winget, Derek M. Dolney, David J. Giesen, Christopher J. Cramer,

    E-Print Network [OSTI]

    Truhlar, Donald G

    1 Minnesota Solvent Descriptor Database Paul Winget, Derek M. Dolney, David J. Giesen, Christopher contains tables of the solvent descriptors (defined below) that are used in the SM5 suite of universal, for which no solvent descriptors are required. The SM5.2R,7 SM5.42R,8­11 SM5.42,12,13 and SM5CR14 models

  2. Modified Yeast with Enhanced Tolerance for GVL Biomass Solvent - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGEMission MissionModeling

  3. RESULTS OF ANALYSIS OF NGS CONCENTRATE DRUM SAMPLES [Next Generation Solvent

    SciTech Connect (OSTI)

    Peters, T.; Williams, M.

    2013-09-13

    Savannah River National Laboratory (SRNL) prepared two drums (50 gallons each in ?Drum#2? and ?Drum#4?) of NGS-MCU (Next Generation Solvent-Modular CSSX Unit) concentrate for future use at MCU in downblending the BOBCalixC6 based solvent to produce NGS-MCU solvent. Samples of each drum were sent for analysis. The results of all the analyses indicate that the blend concentrate is of the correct composition and should produce a blended solvent at MCU of the desired formulation.

  4. INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE

    E-Print Network [OSTI]

    Dorighi, G.P.

    2010-01-01

    conversion of western coals into liquid products. A largeconsist of the coal derived organic liquid, unreacted coal,action of coal with an organic liquid solvent represents a

  5. Alternative Fuels Data Center: Emerging Fuels

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places to

  6. Alternative Fuels Data Center: Flexible Fuel Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places toEthanol PrintableEthanol

  7. Alternative Fuels Data Center: Fuel Prices

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places toEthanolVehicles Printable

  8. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a VehicleNaturalDimethyl

  9. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanol Benefits and

  10. Alternative Fuels Data Center: Biodiesel Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a Vehicle FuelFueling Stations to

  11. Methods for recovering a polar solvent from a fluid stream contaminated with at least one polar impurity

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Wendt, Daniel S.

    2012-11-13

    A method of removing a polar solvent from a fluid volume contaminated with at least one polar impurity, such as a free fatty acid, is provided. The method comprises providing a fluid volume that includes at least one polar impurity dissolved in at least one solvent. The fluid volume is contacted with an expanding gas to remove the at least one solvent. The expanding gas may be dissolved into the at least one solvent in the fluid volume to form a gas-expanded solvent. The immiscibility of the polar impurities in the gas-expanded solvent enables separation of the polar impurities from the gas-expanded solvent. After separation of the polar impurities, at least one of the temperature and pressure may be reduced to separate the solvent from the expanding gas such that the clean solvent may be reused.

  12. Method for cleaning solution used in nuclear fuel reprocessing

    DOE Patents [OSTI]

    Tallent, Othar K. (Oak Ridge, TN); Crouse, David J. (Oak Ridge, TN); Mailen, James C. (Oak Ridge, TN)

    1982-01-01

    Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

  13. Method for cleaning solution used in nuclear fuel reprocessing

    DOE Patents [OSTI]

    Tallent, O.K.; Crouse, D.J.; Mailen, J.C.

    1980-12-17

    Nuclear fuel processing solution consisting of tri-n-butyl phosphate and dodecane, with a complex of uranium, plutonium, or zirconium and with a solvent degradation product such as di-n-butyl phosphate therein, is contacted with an aqueous solution of a salt formed from hydrazine and either a dicarboxylic acid or a hydroxycarboxylic acid, thereby removing the aforesaid complex from the processing solution.

  14. Enhanced sampling and applications in protein folding in explicit solvent

    E-Print Network [OSTI]

    Zhang, Cheng

    2010-01-01

    We report a single-copy tempering method for enhancing sampling in simulating large complex systems. A continuous temperature space random walk is achieved by a Langevin equation, which is guided by a runtime estimate of the thermal average energy through a novel integral identity. We first validated the method in a two-dimensional Ising model and a Lennard-Jones liquid system. Then the method was applied to folding of three small proteins, trpzip2, trp-cage, and villin headpiece in explicit solvent. Within 0.5~1 microsecond, all three systems were folded into atomic accuracy: the alpha carbon root mean square deviation of the best folded conformations from the native states are 0.2 A, 0.4 A, and 0.4 A, for trpzip2, trp-cage, and villin headpiece, respectively.

  15. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Reforming for Molten Carbonate Fuel Cells," Berichte derVan Dijkum, "The Molten Carbonate Fuel Cell Programme in thealkaline, molten carbonate, and solid oxide. (Fuel cells

  16. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01

    regenerative braking, as do Saving Fuel, Reducing Emissionsconditions, the expected savings in fuel costs are notis whether the fuel cost savings over the lifetime of the

  17. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  18. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  19. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  20. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (DNR) has defined. Eligible alternative fuels include natural gas, propane, hydrogen, coal-derived liquid fuels, fuels other than alcohol derived from biological materials, and...

  1. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01

    would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

  2. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  3. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  4. Engineered fuel: Renewable fuel of the future?

    SciTech Connect (OSTI)

    Tomczyk, L.

    1997-01-01

    The power generation and municipal solid waste management industries share an interest in the use of process engineered fuel (PEF) comprised mainly of paper and plastics as a supplement to conventional fuels. PEF is often burned in existing boilers, making PEF an alternative to traditional refuse derived fuels (RDF). This paper describes PEF facilities and makes a comparison of PEF and RDF fuels.

  5. OptFuels: Fuel Treatment Optimization

    E-Print Network [OSTI]

    OptFuels: Fuel Treatment Optimization Scientists a Rocky Mountain Research Station Missoula, MT, scientists at the University of Montana, are developing a tool to help forest managers prioritize forest fuel reduction treatments. Although several computer models analyz stand-level effects of fuel treatments

  6. Syngas into Fuel: Optofluidic Solar Concentrators

    SciTech Connect (OSTI)

    None

    2010-10-01

    Broad Funding Opportunity Announcement Project: Ohio State has developed an iron-based material and process for converting syngas—a synthetic gas mixture—into electricity, H2, and/or liquid fuel with zero CO2 emissions. Traditional carbon capture methods use chemical solvents or special membranes to separate CO2 from the gas exhaust from coal-fired power plants. Ohio State’s technology uses an iron-based oxygen carrier to generate CO2 and H2 from syngas in separate, pure product streams by means of a circulating bed reactor configuration. The end products of the system are H2, electricity, and/or liquid fuel, all of which are useful sources of power that can come from coal or syngas derived from biomass. Ohio State is developing a high-pressure pilot-scale unit to demonstrate this process at the National Carbon Capture Center.

  7. California Fuel Cell Partnership: Alternative Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels| Department ofBusinessCEA90:2:09California EnergyFuel Cell

  8. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanol Benefits andFueling Stations

  9. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas aEthanolAFDCHydrogen PrintableFueling

  10. Tips: Buying and Driving Fuel Efficient and Alternative Fuel...

    Office of Environmental Management (EM)

    & Fuel Vehicles & Fuels Tips: Buying and Driving Fuel Efficient and Alternative Fuel Vehicles Tips: Buying and Driving Fuel Efficient and Alternative Fuel Vehicles...

  11. (Fuel Cells)(Fuel Cells) William Grove

    E-Print Network [OSTI]

    Chen, Yang-Yuan

    Fuel Cell #12; H2 O2 Power CH4 H2 Toyota H2 H2 #12; H2 ~253 #12; 2. 3. : 1. #12; #12;Fuel Cell #12; (Fuel Cells)(Fuel Cells) 1839 William Grove A H2O2 H2O2 2H; Fuel Cell #12;!! PEMFC DMFC SOFC (60~200) (60~100) (600~1000) #12; Proton

  12. "Solvent Usage in Biorefineries Biphasic Dehydration of Xylose to Furfural" Maheen Khan

    E-Print Network [OSTI]

    Mountziaris, T. J.

    to replace THF in this process. Ideally, the solvent would be produced from the biomass as part of an integrated biorefinery. Therefore not relying on external petrochemical supplies and utilizing he renewable of separating the solvent from the furfural. In addition, in the current process the aqueous phase is saturated

  13. Use of Life Cycle Assessment in Evaluating Solvent Recovery Alternatives in Pharmaceutical Manufacture

    E-Print Network [OSTI]

    Savelski, Mariano J.

    Use of Life Cycle Assessment in Evaluating Solvent Recovery Alternatives in Pharmaceutical and purify IPA from the process waste streams. A life cycle assessment was later conducted to measure *Savelski@rowan.edu Keywords: pharmaceutical manufacture, solvent recovery, pervaporation, life cycle

  14. Timedomain MRSI quantitation combining multivoxel processing, FIR based solvent suppression and prior knowledge

    E-Print Network [OSTI]

    Time­domain MRSI quantitation combining multivoxel processing, FIR based solvent suppression and prior knowledge P. Pels#, L. Vanhamme#, S. Van Hu#el#, and P. Van Hecke + # Katholieke Universiteit processing using a FIR filter for solvent suppression. The advantage of this multivoxel approach

  15. Hydrophobic Aided Replica Exchange: an Efficient Algorithm for Protein Folding in Explicit Solvent

    E-Print Network [OSTI]

    Berne, Bruce J.

    Hydrophobic Aided Replica Exchange: an Efficient Algorithm for Protein Folding in Explicit Solvent protein folding in explicit solvent. This method is based on exaggerating the hydrophobic effect understanding of protein folding and misfolding is critical to many problems in computational biology.1 Many

  16. Polymers in poor solvents : loop expansion of irreducible diagrams (II) J. des Cloizeaux

    E-Print Network [OSTI]

    Boyer, Edmond

    761 Polymers in poor solvents : loop expansion of irreducible diagrams (II) J. des Cloizeaux polydispersion. Abstract. 2014 Properties of polymers in poor solvent are found by calculating irreducible. Expressions are given for the osmotic pressure, the size of a polymer in a solution and the density

  17. Chemical equilibrium in supercritical fluids: Solvent effects on the dimerization equilibrium constant

    E-Print Network [OSTI]

    Rabani, Eran

    supercritical sol- vents CO2 , CHF3 , CClF3 , Ar, and Xe across the whole solvent density range, from gasChemical equilibrium in supercritical fluids: Solvent effects on the dimerization equilibrium; accepted 27 February 2002 We study dimerization equilibrium between two dilute solutes in a supercritical

  18. Lithium Diisopropylamide-Mediated Enolizations: Solvent-Dependent Mixed Aggregation Effects

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Diisopropylamide-Mediated Enolizations: Solvent-Dependent Mixed Aggregation Effects Xiufeng spectroscopic investigations of lithium diisopropylamide-mediated ester enolization in THF, t-BuOMe, HMPA that the metalations by lithium diisopropylamide (LDA) homonuclear dimers proceed at nearly solvent-independent rates

  19. J. Phys. A: Math. Gen., Vol. 9. No. 9,1976. Printed in Great Britain. 01976 Configurationalproperties of polymers in a good solvent

    E-Print Network [OSTI]

    Rapaport, Dennis C.

    Configurationalproperties of polymers in a good solvent D C Rapaport Department of Physics, Bar-Ilan University, Ramat-avoiding polymer chains and rings are generated on the FCC lattice by exact enumeration.The effectof the `good'solvent to the type (ii)interaction between pairs of units arise from polymer- polymer, polymer-solvent and solvent-solvent

  20. Critical Oxidation Reactions Optimized with Solvent Swap | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in Actinide SandwichCray era

  1. BioRenewable Chemicals and Solvents - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|Bilayer Graphene Gets aVehicles and

  2. Recovery of Sugars by Solvent Extraction - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts onReal-TimeRecord-SettingActEnhancingDepartmentPolicies

  3. HIGH-PRESSURE SOLVENT EXTRACTION OF METHANE FROM GEOPRESSURED BRINES:

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLED Street LightingFrom the BuildingHASL-258

  4. PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding access to(Conference) |ofPDV workshop(Conference) |(JournalEXTRACTION

  5. PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding access to(Conference) |ofPDV workshop(Conference)

  6. Requirements for a Dynamic Solvent Extraction Module to Support Development

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeedingConnect(Conference)Factory: Linear vs. Circular'and Nanoscopicof

  7. Requirements for a Dynamic Solvent Extraction Module to Support Development

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeedingConnect(Conference)Factory: Linear vs. Circular'and Nanoscopicofof

  8. Test Plan for Solvent Extraction Data Acquisition to Support Modeling

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback SystemGimbaled X-RayChinaNanotube(Journal Article) |Efforts

  9. Test Plan for Solvent Extraction Data Acquisition to Support Modeling

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback SystemGimbaled X-RayChinaNanotube(Journal Article)

  10. Advanced Water Removal via Membrane Solvent Extraction | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A sCOLONY PROJECTRecord4

  11. The Role of Solvent Heterogeneity in Determining the Dispersion Interaction

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)FeedbackProperties ofThe Maximum ValueSciTech ConnectinBetween

  12. novel-solvent-system | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26th AnnualHistoryMIII:National1-2130 1Development

  13. solvent-babcock-wilcox | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnal VariationsSolid-StateDevelopment

  14. A modified Poisson-Boltzmann theory: Effects of co-solvent polarizability

    E-Print Network [OSTI]

    Y. A. Budkov; A. L. Kolesnikov; M. G. Kiselev

    2015-07-27

    In this paper within a field-theoretical approach taking into account explicitly a co-solvent with a nonzero dipole and a polarizability tensor, we derive a modified Poisson-Boltzmann equation. Applying the modified Poisson-Boltzmann equation, we formulate a generalized Gouy-Chapman theory for the case when an electrolyte solution is mixed with a polar co-solvent having a large polarizability. We show that an increase of the co-solvent concentration as well as the co-solvent polarizability lead to a significant increase of differential capacitance at sufficiently high surface potentials of the electrode, whereas the profile of the electrostatic potential becomes considerably more long-ranged. On the contrary, an increase in the permanent dipole of the co-solvent only weakly affects the differential capacitance.

  15. Modeling morphology evolution during solvent-based fabrication of organic solar cells

    E-Print Network [OSTI]

    Wodo, Olga

    2011-01-01

    Solvent-based techniques usually involve preparing dilute blends of electron-donor and electron-acceptor materials dissolved in a volatile solvent. After some form of coating onto a substrate, the solvent evaporates. An initially homogeneous mixture separates into electron-acceptor rich and electron-donor rich regions as the solvent evaporates. Depending on the specifics of the blend and processing conditions different morphologies are typically formed. Experimental evidence consistently confirms that the morphology critically affects device performance. A computational framework that can predict morphology evolution can significantly augment experimental analysis. Such a framework will also allow high throughput analysis of the large phase space of processing parameters, thus yielding insight into the process-structure-property relationships. In this paper, we formulate a computational framework to predict evolution of morphology during solvent-based fabrication of organic thin films. This is accomplished by...

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropaneAlternative FuelNaturalFueling

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropaneAlternative FuelNaturalFuelingVehicle

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropaneAlternative FuelNaturalFuelingVehicleLoans

  19. Advanced Fuel Reformer Development: Putting the 'Fuel' in Fuel Cells |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReportOfficeAcqguide18pt0Department ofHigh2 DOEFactory-Built

  20. Studies on reaction runaways for Urex/Purex solvent-nitric acid and red-oil synthesis

    SciTech Connect (OSTI)

    Kumar, Shekhar; Kumar, Rajnish; Koganti, S.B.

    2008-07-01

    In PUREX/UREX processes for recycling of spent nuclear fuels, 30% TBP solvent is used, This solvent has a small solubility in the aqueous phase. During concentration of the process solutions by an evaporation route, a runaway reaction between TBP and nitric acid is initiated at above 130 deg. C, leading to rapid pressurization and finally containment failure if proper venting is not provided. Red oil was synthesized for the first time in India, and its physical properties as well as thermodynamic parameters for the reaction were determined. It was experimentally established that the presence of metallic nitrates was not essential for red-oil formation as thought earlier. Various experiments have been completed for single-phase as well as two-phase runs. The most important finding of this work was lowering of the limiting acid concentration from the conventional values. In fact, in these experiments, red oil could be formed even at 2 N aqueous acidity. Thus, safety guidelines based on the classical literature are obsolete. New guidelines for the red-oil-safety are required. (authors)

  1. Sample Results From The Extraction, Scrub, And Strip Test For The Blended NGS Solvent

    SciTech Connect (OSTI)

    Washington, A. L. II; Peters, T. B.

    2014-03-03

    This report summarizes the results of the extraction, scrub, and strip testing for the September 2013 sampling of the Next Generation Solvent (NGS) Blended solvent from the Modular Caustic Side-Solvent Extraction Unit (MCU) Solvent Hold Tank. MCU is in the process of transitioning from the BOBCalixC6 solvent to the NGS Blend solvent. As part of that transition, MCU has intentionally created a blended solvent to be processed using the Salt Batch program. This sample represents the first sample received from that blended solvent. There were two ESS tests performed where NGS blended solvent performance was assessed using either the Tank 21 material utilized in the Salt Batch 7 analyses or a simulant waste material used in the V-5/V-10 contactor testing. This report tabulates the temperature corrected cesium distribution, or DCs values, step recovery percentage, and actual temperatures recorded during the experiment. This report also identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. The calculated extraction DCs values using the Tank 21H material and simulant are 59.4 and 53.8, respectively. The DCs values for two scrub and three strip processes for the Tank 21 material are 4.58, 2.91, 0.00184, 0.0252, and 0.00575, respectively. The D-values for two scrub and three strip processes for the simulant are 3.47, 2.18, 0.00468, 0.00057, and 0.00572, respectively. These values are similar to previous measurements of Salt Batch 7 feed with lab-prepared blended solvent. These numbers are considered compatible to allow simulant testing to be completed in place of actual waste due to the limited availability of feed material.

  2. Solvent Hold Tank Sample Results For MCU-15-710-711-712: June 2015 Monthly Sample

    SciTech Connect (OSTI)

    Fondeur, F.; Taylor-Pashow, K.

    2015-10-07

    Savannah River National Laboratory (SRNL) received one set of Solvent Hold Tank (SHT) samples (MCU-15-710, MCU-15-711, and MCU-15-712), pulled on 06/15/2015 for analysis. The samples were combined and analyzed for composition. Analysis of the composite sample MCU-15-710-711-712 indicated a low concentration (~ 55 % of nominal) of the suppressor (TiDG) and concentrations of the extractant (MaxCalix), and of the modifier (Cs-7SB) in the solvent that were slightly lower than nominal. This analysis confirms the addition of TiDG, MaxCalix, and modifier (92 % of nominal) to the solvent in February 2015. Based on the current monthly sample, the levels of TiDG, MaxCalix, and modifier were sufficient when this solvent sample was collected from MCU. A higher cesium concentration (9.3 E6 dpm/mL) was observed in this sample relative to recent samples. In the past, this level of cesium appeared to correlate with upsets in the MCU operation. It is not known at this time the reason for the higher cesium level in this solvent. No impurities above the 1000 ppm level were found in this solvent by the Semi-Volatile Organic Analysis (SVOA). In addition, the sample contains up to 10.4 micrograms of mercury per gram of solvent (or 8.7 µg/mL). A relatively large cesium concentration (9.3 E 6 dpm/mL) was measured in this solvent and it may indicate poor cesium stripping. The laboratory will continue to monitor the quality of the solvent in particular for any new impurities or degradation of the solvent components.

  3. Microbial process for the preparation of acetic acid, as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.; Ko, Ching-Whan; Wade, Leslie E.; Wikstrom, Carl V.

    2004-06-22

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. Solvent mixtures formed of such a modified solvent with a desired co-solvent, preferably a low boiling hydrocarbon, are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  4. Microbial process for the preparation of acetic acid, as well as solvent for its extraction from the fermentation broth

    DOE Patents [OSTI]

    Gaddy, James L.; Clausen, Edgar C.; Ko, Ching-Whan; Wade, Leslie E.; Wikstrom, Carl V.

    2007-03-27

    A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. Solvent mixtures formed of such a modified solvent with a desired co-solvent, preferably a low boiling hydrocarbon, are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

  5. Enzymatic Digestion in Aqueous-Organic Solvents: A Mass Spectrometry-Based Approach in Monitoring Protein Conformation Changes 

    E-Print Network [OSTI]

    Tuvilla, Mavreen Rose

    2013-05-08

    -organic solvent systems. The technique involved trypsin digestion and generation of peptide mass maps. For cytochrome c, the experiments were done with ethanol, methanol and acetonitrile to gain insights on naturation and denaturation. An apparent solvent effect...

  6. Process Simulation and Evaluation of Alternative Solvents for Jatropha Curcas L. Seed Oil Extraction in Biodiesel Production 

    E-Print Network [OSTI]

    Chiou, Ming-Hao

    2012-10-19

    alternatives for conventional petro-diesel. Currently, hexane is still the most commonly used solvent for commercial oil extraction. However, the increasing price and flammability properties of hexane are motivating industry to seek alternative solvents...

  7. Sequential Processing for Organic Photovoltaics: Design Rules for Morphology Control by Tailored Semi-Orthogonal Solvent Blends

    E-Print Network [OSTI]

    2015-01-01

    solvents for the fullerene-casting solution. By tuning thecan be used: blend casting (BC) [ 18,19 ] and sequentialchoice of the fullerene casting co-solvent yields well-

  8. Experimentation and application of directional solvent extraction for desalination of seawater and shale gas 'frac' flowback water

    E-Print Network [OSTI]

    Kleinguetl, Kevin (Kevin G.)

    2011-01-01

    A recently demonstrated directional solvent technique for desalination of water has been tested for desalting seawater and shale gas 'frac' flowback water. The premise behind directional solvent extraction is that when ...

  9. 1/6TH SCALE STRIP EFFLUENT FEED TANK-MIXING RESULTS USING MCU SOLVENT

    SciTech Connect (OSTI)

    Hansen, E

    2006-02-01

    The purpose of this task was to determine if mixing was an issue for the entrainment and dispersion of the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) solvent in the Defense Waste Processing Facility (DWPF) Strip Effluent Feed Tank (SEFT). The MCU strip effluent stream containing the Cs removed during salt processing will be transferred to the DWPF for immobilization in HLW glass. In lab-scale DWPF chemical process cell testing, mixing of the solvent in the dilute nitric acid solution proved problematic, and the Savannah River National Laboratory (SRNL) was requested to perform scaled SEFT mixing tests to evaluate whether the problem was symptomatic of the lab-scale set-up or of the solvent. The solvent levels tested were 228 and 235 ppm, which represented levels near the estimated DWPF solvent limit of 239 ppm in 0.001M HNO{sub 3} solution. The 239 ppm limit was calculated by Norato in X-CLC-S-00141. The general approach for the mixing investigation was to: (1) Investigate the use of fluorescent dyes to aid in observing the mixing behavior. Evaluate and compare the physical properties of the fluorescent dyed MCU solvents to the baseline Oak Ridge CSSX solvent. Based on the data, use the dyed MCU solvent that best approximates the physical properties. (2) Use approximately a 1/6th linear scale of the SEFT to replicate the internal configuration for DWPF mixing. (3) Determine agitator speed(s) for scaled testing based on the DWPF SEFT mixing speed. (4) Perform mixing tests using the 1/6th SEFT and determine any mixing issues (entrainment/dispersion, accumulation, adhesion) through visual observations and by pulling samples to assess uniformity. The mixing tests used MCU solvent fabricated at SRNL blended with Risk Reactor DFSB-K43 fluorescent dye. This dyed SRNL MCU solvent had equivalent physical properties important to mixing as compared to the Oak Ridge baseline solvent, blended easily with the MCU solvent, and provided an excellent visual aid.

  10. Fuel processor for fuel cell power system

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Springer, Thomas E. (Los Alamos, NM); Huff, James R. (Los Alamos, NM)

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  11. A study of substitution solvents in asphalt fume extraction and the effects of heating duration and temperature 

    E-Print Network [OSTI]

    Curry, Noel Thomas

    1981-01-01

    may be used as substitute solvents for the solvent extraction analytical method for asphalt furres proposed by NlnSH and currently in use by OSHA. Benzene is known to orovide IC0% effic- 1 iency in asphalt fume extraction. The results..., rather than the solvents' effic- iency loss, was responsible for the differences. The importance of the data lies in the fact that the other two test solvents exhibited a consiatency equal to that of benzene. 'Ahile the exact coefficient of any...

  12. Fuel Cycle Subcommittee

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender PumpVehiclesTheAlternative Fuel, Advanced

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home PageBlender PumpVehiclesTheAlternative Fuel,HighHigh

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

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  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeVehicle Replacement Vouchers TheIncentiveAlternative Fuel

  7. Organic solvent soluble oxide supported hydrogenation catalyst precursors

    DOE Patents [OSTI]

    Edlund, David J. (Bend, OR); Finke, Richard G. (Eugene, OR); Saxton, Robert J. (Sunnyvale, CA)

    1992-01-01

    The present invention discloses two polyoxoanion supported metal complexes found to be useful in olefin hydrogenation. The complexes are novel compositions of matter which are soluble in organic solvents. In particular, the compositions of matter comprise A.sub.x [L.sub.n Ir.sup.(I) .multidot.X.sub.2 M.sub.15 M'.sub.3 O.sub.62 ].sup.x- and A.sub.y [L.sub.n Ir.sup.(I) .multidot.X.sub.2 M.sub.9 M'.sub.3 O.sub.40 ].sup.y- where L is a ligand preferably chosen from 1,5-cyclooctadiene (COD), ethylene, cyclooctene, norbornadiene and other olefinic ligands; n=1 or 2 depending upon the number of double bonds present in the ligand L; X is a "hetero" atom chosen from B, Si, Ge, P, As, Se, Te, I, Co, Mn and Cu; M is either W or Mo; M' is preferably Nb or V but Ti, Zr, Ta, Hf are also useful; and A is a countercation preferably selected from tetrabutyl ammonium and alkali metal ions.

  8. Solvent effects on the resonance Raman and electronic absorption spectra of bacteriochlorophyll a cation radical

    SciTech Connect (OSTI)

    Misono, Yasuhito; Itoh, Koichi [Waseda Univ., Tokyo (Japan)] [Waseda Univ., Tokyo (Japan); Limanatara, Leenawaty; Koyama, Yasushi [Kwansei Gakuin Univ., Nishinomiya (Japan)] [Kwansei Gakuin Univ., Nishinomiya (Japan)

    1996-02-08

    Resonance Raman and electronic absorption spectra of bacteriocholrophyll a cation radical (BChl a{sup .+}) were recorded in 14 different kinds of solvents. The frequency of the ring-breathing Raman band of BChl a{sup .+} was in the region of 1596-1599 cm{sup -1} in solvents forming the pentacoordinated state in neutral bacteriochlorophyll a (BChl a), while it was in the region of 1584-1588 cm{sup -1} in solvents forming the hexacoordinated state. BChl a{sup .+} exhibited a key absorption band in the regions 546-554 and 557-563 nm in the above penta- and hexa-coordinating solvents. Therefore, it has been concluded that the penta- and hexa-coordinated states are retained even after conversion of BChl a into BChl a{sup .+} (one-electron oxidization). Application of this rule to the case of 2-propanol solution showed transformation from the penta- to the hexa-coordinated state upon one-electron oxidation in this particular solution. The coordination states of BChl a{sup .+} could be correlated with the donor number(DN) and the Taft parameters, {Beta} and {pi}{sup *}, of the solvent: The hexacoordinated state was formed in solvents with DN >= 18 or {Beta} > 0.5 showing higher electron donating power, while the pentacoordinated state was formed in solvents with {pi}{sup *} > 0.65 showing higher dielectric stabilization. 27 refs., 8 figs., 3 tabs.

  9. Solvent mediated interactions between model colloids and interfaces: A microscopic approach

    E-Print Network [OSTI]

    Paul Hopkins; Andrew J. Archer; Robert Evans

    2009-08-17

    We determine the solvent mediated contribution to the effective potentials for model colloidal or nano- particles dispersed in a binary solvent that exhibits fluid-fluid phase separation. Using a simple density functional theory we calculate the density profiles of both solvent species in the presence of the `colloids', which are treated as external potentials, and determine the solvent mediated (SM) potentials. Specifically, we calculate SM potentials between (i) two colloids, (ii) a colloid and a planar fluid-fluid interface, and (iii) a colloid and a planar wall with an adsorbed wetting film. We consider three different types of colloidal particles: colloid A which prefers the bulk solvent phase rich in species 2, colloid C which prefers the solvent phase rich in species 1, and `neutral' colloid B which has no strong preference for either phase, i.e. the free energies to insert the colloid into either of the coexisting bulk phases are almost equal. When a colloid which has a preference for one of the two solvent phases is inserted into the disfavored phase at statepoints close to coexistence a thick adsorbed `wetting' film of the preferred phase may form around the colloids. The presence of the adsorbed film has a profound influence on the form of the SM potentials.

  10. Solvent Hold Tank Sample Results For MCU-15-750-751-752-: June Monthly Sample

    SciTech Connect (OSTI)

    Fondeur, F.; Taylor-Pashow, K.

    2015-10-07

    Savannah River National Laboratory (SRNL) received one set of Solvent Hold Tank (SHT) samples (MCU-15-750, MCU-15-751, and MCU-15-752), pulled on 06/22/2015 for analysis. The samples were combined and analyzed for composition. Analysis of the composite sample MCU-15-750-751-752 indicated a low concentration (~ 49 % of nominal) of the suppressor (TiDG) and slightly lower than nominal concentrations of the extractant (MaxCalix), and of the modifier (Cs-7SB) in the solvent. This analysis confirms the addition of TiDG, MaxCalix, and modifier to the solvent in February 2015. Based on the current monthly sample, the levels of TiDG, MaxCalix, and modifier are sufficient for continuing operation without adding a trim at this time but it is recommended that an addition of TiDG, modifier and Isopar™L should be made in the near future. No impurities above the 1000 ppm level were found in this solvent by the Semi-Volatile Organic Analysis (SVOA). No impurities were observed in the Hydrogen Nuclear Magnetic Resonance (HNMR). In addition, up to 13.9 micrograms of mercury per gram of solvent (or 11.5 µg/mL) was detected in this sample. The laboratory will continue to monitor the quality of the solvent in particular for any new impurities or degradation of the solvent components.

  11. Solvent Hold Tank Sample Results for MCU-15-556-557-558. March 2015 Monthly Sample

    SciTech Connect (OSTI)

    Fondeur, F.; Taylor-Pashow, K.

    2015-05-04

    Savannah River National Laboratory (SRNL) received one set of Solvent Hold Tank (SHT) samples (MCU-15-556, MCU-15-557, and MCU-15-558), pulled on 03/16/2015 for analysis. The samples were combined and analyzed for composition. Analysis of the composite sample MCU-15-556-557-558 indicated a low concentration (~ 78 % of nominal) of the suppressor (TiDG) and concentrations of the extractant (MaxCalix), and of the modifier (CS-7SB) in the solvent that were slightly lower than nominal. This analysis confirms the addition of TiDG, MaxCalix, and modifier to the solvent in February 2015. Based on the current monthly sample, the levels of TiDG, MaxCalix, and modifier are sufficient for continuing operation without adding a trim at this time. No impurities above the 1000 ppm level were found in this solvent by the Semi-Volatile Organic Analysis (SVOA). However, the p-nut vials that delivered the samples contained small (1 mm) droplets of oxidized modifier and amides (as detected by the FTIR analysis). In addition, up to 21 microgram of mercury per gram of solvent (or 17.4 µg/mL) was detected in this sample. The laboratory will continue to monitor the quality of the solvent in particular for any new impurities or degradation of the solvent components.

  12. Controlled actuation of Nafion-based Ionic Polymer-metal Composites (IPMCs) with Ethylene Glycol as Solvent

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    as Solvent Shahram Zamani and Sia Nemat-Nasser University of California, San Diego Center of Excellence is highly dependent on the cations used, the nature and the amount of solvent uptake, the morphology of tests on Nafion-based IPMCs with ethylene glycol as solvent, actuated under electric potential inputs

  13. Role of Electrical Interactions in the Rotational Motion of a Charged Solute Molecule in a Polar Solvent

    E-Print Network [OSTI]

    Solvent N. V. Brilliantov,*,, N. G. Vostrikova, and O. P. Revokatov Department of Chemistry, Uni in a polar solvent which takes into account dielectric friction, dielectric saturation, and spatial dependence of the solvent viscosity due to electrostriction is developed. The results are obtained from

  14. Solvent-Dependent Molecular Structure of Ionic Species Directly Measured by Ultrafast X-Ray Solution Scattering

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    Solvent-Dependent Molecular Structure of Ionic Species Directly Measured by Ultrafast X often play important roles in chemical reactions occurring in water and other solvents, but it has been elusive to determine the solvent-dependent molecular structure with atomic resolution. The triiodide ion

  15. Valence-bond charge-transfer solvation model for nonlinear optical properties of organic molecules in polar solvents

    E-Print Network [OSTI]

    Goddard III, William A.

    in polar solvents Guanhua Chen,a) Daqi Lu, and William A. Goddard Illb) Materials and Molecular Simulation on the valence-bond charge-transfer (VB-CT) framework, using a continuum description of the solvent), the polarizability (cu), the hyperpolarizabilities (&y,s), and the bond length alternation with only one solvent

  16. Ion distribution around a charged rod in one and two component solvents: Preferential solvation and first order ionization phase transition

    E-Print Network [OSTI]

    Ion distribution around a charged rod in one and two component solvents: Preferential solvation 2009; publisher error corrected 8 September 2009 In one and two component polar solvents, we calculate solvation of the charged particles and the short-range interaction between the rod and the solvent

  17. Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical, 2008 The formation and dissociation kinetics of a series of triethylsilanol/solvent weakly hydrogen with previous observations on eight phenol/solvent complexes with enthalpies of formation from -0.6 to -2.5 kcal

  18. pH control with silicates minerals for in situ bioremediation of chlorinated solventsfor in situ bioremediation of chlorinated solvents

    E-Print Network [OSTI]

    Lenstra, Arjen K.

    bioremediation of chlorinated solvents Elsa Lacroix(1,2), Alessandro Brovelli(2), D.A. Barry(2), Christof, Lausanne, Switzerland Email: elsa.lacroix@epfl.ch Problem21 Background What are chlorinated solvents? PCE (tetrachloroethylene), TCE 21 In situ bioremediation of chlorinated solvents is an acid-generating process. Acidic

  19. Indentation of polydimethylsiloxane submerged in organic solvents School of Engineering and Applied Sciences, Kavli Institute, Harvard University, Cambridge, Massachusetts 02138

    E-Print Network [OSTI]

    Suo, Zhigang

    Indentation of polydimethylsiloxane submerged in organic solvents Yuhang Hu School of Engineering) elastomer submerged in an organic solvent (decane, heptane, pentane, or cyclohexane). An indenter is pressed indicates that the solvent migrates in PDMS by diffusion, rather than by convection. This work confirms

  20. Environ. Sci. Technol. 1993, 27, 2831-2843 Coal Tar Dissolution in Water-Miscible Solvents: Experimental Evaluation

    E-Print Network [OSTI]

    Peters, Catherine A.

    Environ. Sci. Technol. 1993, 27, 2831-2843 Coal Tar Dissolution in Water-Miscible Solvents remediationtechnology is water-miscible solvent extraction, which requires un- derstandingof the effectof water data and Raoult's law assumption for aqueous solubility. For three solvents, n-butylamine,acetone,and 2

  1. Solvent Mode Participation in the Nonradiative Relaxation of the Hydrated Electron Oleg V. Prezhdo and Peter J. Rossky*

    E-Print Network [OSTI]

    Solvent Mode Participation in the Nonradiative Relaxation of the Hydrated Electron Oleg V. Prezhdo simulations are used to analyze the role of different solvent molecular degrees of freedom in the nonradiative theories. Solvent librations and vibrations, and the H2O asymmetric stretch in particular, are found

  2. Solvent Reorganization Energy and Free Energy Change for Donor/Acceptor Electron Transfer at Micelle Surfaces: Theory and Experiment

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent Reorganization Energy and Free Energy Change for Donor/Acceptor Electron TransferVed: April 7, 1998 Theories are presented for calculating the solvent reorganization energy and the free and acceptor. The form of this dependence has been of considerable interest for many years.2-6 Solvents

  3. Fuel dissipater for pressurized fuel cell generators

    DOE Patents [OSTI]

    Basel, Richard A.; King, John E.

    2003-11-04

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a pressurized fuel cell generator (10) when the electrical power output of the fuel cell generator is terminated during transient operation, such as a shutdown; where, two electrically resistive elements (two of 28, 53, 54, 55) at least one of which is connected in parallel, in association with contactors (26, 57, 58, 59), a multi-point settable sensor relay (23) and a circuit breaker (24), are automatically connected across the fuel cell generator terminals (21, 22) at two or more contact points, in order to draw current, thereby depleting the fuel inventory in the generator.

  4. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuel CellsCells Fuel

  5. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell...

  6. Method for the simultaneous recovery of radionuclides from liquid radioactive wastes using a solvent

    DOE Patents [OSTI]

    Romanovskiy, Valeriy Nicholiavich (St. Petersburg, RU); Smirnov, Igor V. (St. Petersburg, RU); Babain, Vasiliy A. (St. Petersburg, RU); Todd, Terry A. (Aberdeen, ID); Brewer, Ken N. (Arco, ID)

    2001-01-01

    The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

  7. Removing oxygen from a solvent extractant in an uranium recovery process

    DOE Patents [OSTI]

    Hurst, Fred J. (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN); Posey, Franz A. (Concord, TN)

    1984-01-01

    An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous and accumulation of complex iron phosphates or cruds.

  8. Ribbon polymers in poor solvents: layering transitions in annular and tubular condensates

    E-Print Network [OSTI]

    Y. Y. Suzuki; D. R. M. Williams

    2008-11-05

    We study the structures of a ribbon or ladder polymer immersed in poor solvents. The anisotropic bending rigidity coupled with the surface tension leads ribbon polymers to spontaneous formation of highly anisotropic condensates in poor solvents. Unlike ordinary flexible polymers these condensates undergo a number of distinct layering transitions as a function of chain length or solvent quality, and the size of condensates becomes non-monotonic function of chain length. We show that the fluctuations of the condensates are in general small and these condensates are stable.

  9. Solvent for the simultaneous recovery of radionuclides from liquid radioactive wastes

    DOE Patents [OSTI]

    Romanovskiy, Valeriy Nicholiavich (St. Petersburg, RU); Smirnov, Igor V. (St. Petersburg, RU); Babain, Vasiliy A. (St. Petersburg, RU); Todd, Terry A. (Aberdeen, ID); Brewer, Ken N. (Arco, ID)

    2002-01-01

    The present invention relates to solvents, and methods, for selectively extracting and recovering radionuclides, especially cesium and strontium, rare earths and actinides from liquid radioactive wastes. More specifically, the invention relates to extracting agent solvent compositions comprising complex organoboron compounds, substituted polyethylene glycols, and neutral organophosphorus compounds in a diluent. The preferred solvent comprises a chlorinated cobalt dicarbollide, diphenyl-dibutylmethylenecarbamoylphosphine oxide, PEG-400, and a diluent of phenylpolyfluoroalkyl sulfone. The invention also provides a method of using the invention extracting agents to recover cesium, strontium, rare earths and actinides from liquid radioactive waste.

  10. Automated apparatus for solvent separation of a coal liquefaction product stream

    DOE Patents [OSTI]

    Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01

    An automated apparatus for the solvent separation of a coal liquefaction product stream that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In use of the apparatus, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control means. The mixture in the filter is agitated by means of ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

  11. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Experience with the German Hydrogen Fuel Project," HydrogenHydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would be

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuels Road Tax Alternative fuels including, but not limited to, natural gas or propane sold by a licensed alternative fuel dealer and used in on-road vehicles is subject to a...

  13. Low Carbon Fuel Standards

    E-Print Network [OSTI]

    Sperling, Dan; Yeh, Sonia

    2009-01-01

    S O N I A YE H Low Carbon Fuel Standards The most direct andalternative transportation fuels is to spur innovation withstandard for upstream fuel producers. hen it comes to energy

  14. Multi-criteria comparison of fuel policies: Renewable fuel mandate, fuel emission-standards, and fuel carbon tax

    E-Print Network [OSTI]

    Rajagopal, Deepak; Hochman, G.; Zilberman, D.

    2012-01-01

    comparison of fuel policies: Renewable fuel mandate, fuelcomparison of fuel policies: Renewable fuel mandate, fuel121, 2011. C. Fischer. Renewable Portfolio Standards: When

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places to share EERE: Alternative

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places to share EERE: AlternativeLocal

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More places to share EERE:

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More placesNaturalStateVehicleTools Printable

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More placesNaturalStateVehicleTools

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More placesNaturalStateVehicleToolsIdle

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find More

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternative

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNational Alternative

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNational AlternativeSmartWay

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNational

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestion Mitigation

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestion

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestionTier 2 and

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestionTier 2

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestionTier

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find MoreAlternativeNationalCongestionTierSchool

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg Find

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USA is an

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USA is

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USA

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USAVoluntary Airport Low

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USAVoluntary Airport

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USAVoluntary

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports USAVoluntaryAftermarket

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean Ports

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean PortsRenewable

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean PortsRenewableIncome

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA Clean

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA CleanAdvanced Technology Vehicle

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA CleanAdvanced Technology

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA CleanAdvanced

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA CleanAdvancedAlternative

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA CleanAdvancedAlternativePayments

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USA

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol Infrastructure Grants and

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol Infrastructure Grants

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol Infrastructure GrantsAmerican

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol Infrastructure

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol InfrastructureImprovement and

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol InfrastructureImprovement

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanol

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanolState Printable Version Share

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanolState Printable Version

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanolState Printable

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPorts USAEthanolState PrintableState

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManual del

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManual delBiodiesel Tax

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManual delBiodiesel

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManual delBiodieselIdle

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManual

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefied Natural Gas (LNG)

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefied Natural Gas

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefied Natural

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefied NaturalLiquefied

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefied

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefiedVehicle and Equipment

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefiedVehicle and

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefiedVehicle

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls onManualLiquefiedVehicleAlternative

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane Rolls

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joined Arkansas, Colorado,

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joined Arkansas, Colorado,Ohio

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joined Arkansas,

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joined Arkansas,Low-Speed

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joined

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joinedPlug-In Electric

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joinedPlug-In

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi joinedPlug-InAlternative

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippi

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural Gas Measurement

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural Gas MeasurementPublic

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural Gas

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural GasNatural Gas

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural GasNatural

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNatural

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNaturalAlternative

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane RollsMississippiNaturalAlternativeAdvanced

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropane

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants The Indiana Office of

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants The Indiana Office

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants The Indiana

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants The IndianaFreight

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants The

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants TheDiesel Emissions

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page onPropanePropane School Bus Grants TheDiesel