National Library of Energy BETA

Sample records for fuels batteries chemicals

  1. Depletion Aggregation > Batteries & Fuel Cells > Research > The...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries & Fuel Cells In This Section Battery Anodes Battery Cathodes Depletion Aggregation Membranes Depletion Aggregation We are exploring a number of synthetic strategies to ...

  2. Tobias Hanrath > Research Thrust Leader - Fuel Cells and Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hanrath Research Thrust Leader - Fuel Cells and Batteries Assistant Professor Chemical and Biomolecular Engineering Research Group Webpage th358@cornell.edu Research There is a...

  3. Electric Fuel Battery Corporation | Open Energy Information

    Open Energy Info (EERE)

    Fuel Battery Corporation Jump to: navigation, search Name: Electric Fuel Battery Corporation Place: Auburn, Alabama Zip: 36832 Product: Develops and manufactures BA-8180U high...

  4. Batteries & Fuel Cells > Research > The Energy Materials Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries & Fuel Cells Here are the details of what we're doing in the labs to improve battery & fuel cell technology. Battery Anodes Battery Cathodes Depletion Aggregation ...

  5. Membranes > Batteries & Fuel Cells > Research > The Energy Materials Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at Cornell Batteries & Fuel Cells In This Section Battery Anodes Battery Cathodes Depletion Aggregation Membranes Membranes Fig. 1 PEM Fuel Cell Fuel cells are highly efficient devices that convert the chemical energy stored in a fuel directly intoelectricity. Within a fuel cell, the polymer electrolyte membrane (PEM) serves as the conducting interface between the anode and cathode, transporting the ions (Figure 1). As a result, the PEM is a central, and often performance-limiting,

  6. Georgia Tech Center for Innovative Fuel Cell and Battery Technologies...

    Open Energy Info (EERE)

    Innovative Fuel Cell and Battery Technologies Jump to: navigation, search Name: Georgia Tech Center for Innovative Fuel Cell and Battery Technologies Place: Georgia Product: The...

  7. Fuel Cell and Battery Electric Vehicles Compared | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Battery Electric Vehicles Compared Fuel Cell and Battery Electric Vehicles Compared Presented by Sandy Thomas at the National Hydrogen Assocation Conference and Hydrogen Expo thomas_fcev_vs_battery_evs.pdf (281 KB) More Documents & Publications An Energy Evolution:Alternative Fueled Vehicle Comparisons Fuel Cell and Battery Electric Vehicles Compared INFOGRAPHIC: The Fuel Cell Electric Vehicle Asia/ITS

  8. Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    for Solar Power Yellowstone Park Recycles Vehicle Batteries for Solar Power to someone by E-mail Share Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Facebook Tweet about Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Twitter Bookmark Alternative Fuels Data Center: Yellowstone Park Recycles Vehicle Batteries for Solar Power on Google Bookmark Alternative Fuels Data Center: Yellowstone Park Recycles

  9. Frank DiSalvo > Research Thrust Leader - Fuel Cells and Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Frank DiSalvo Research Thrust Leader - Fuel Cells and Batteries John A. Newman Professor of Physical Science Chemistry and Chemical Biology Research Group Webpage fjd3@cornell.edu...

  10. Fuel Cell and Battery Electric Vehicles Compared

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Level PHEVs Fuel Cell and Battery Electric Vehicles Compared By C. E. (Sandy) Thomas, Ph.D., President H 2 Gen Innovations, Inc. Alexandria, Virginia Thomas@h2gen.com 1.0 Introduction Detailed computer simulations demonstrate that all-electric vehicles will be required to meet our energy security and climate change reduction goals 1 . As shown in Figure 1, hybrid electric vehicles (HEV's) and plug-in hybrid electric vehicles (PHEV's) both reduce greenhouse gas (GHG) emissions, but neither of

  11. Fuels and Chemicals from Lignocellulosic Biomass: Valorization...

    Office of Scientific and Technical Information (OSTI)

    Fuels and Chemicals from Lignocellulosic Biomass: Valorization of Lignin. Citation Details In-Document Search Title: Fuels and Chemicals from Lignocellulosic Biomass: Valorization ...

  12. Hydrogen and Fuel Cell Activities: 5th International Conference on Polymer Batteries and Fuel Cells

    Broader source: Energy.gov [DOE]

    Plenary presentation by Sunita Satyapal at the 5th International Conference on Polymer Batteries and Fuel Cells on August 4, 2011.

  13. DOE/EA-1760 Final Environmental Assessment for FutureFuel Chemical Company

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 Final Environmental Assessment for FutureFuel Chemical Company Electric Drive Vehicle Battery and Component Manufacturing Initiative Project Batesville, AR August 2010 Prepared for: Department of Energy National Energy Technology Laboratory Electric Drive Vehicle Battery and DOE/EA-1760 Component Manufacturing Initiative Project Environmental Assessment FutureFuel Chemical Company, Batesville, AR August 2010 National Environmental Policy Act (NEPA) Compliance Cover Sheet Proposed Action: The

  14. An overviewFunctional nanomaterials for lithium rechargeable batteries, supercapacitors, hydrogen storage, and fuel cells

    SciTech Connect (OSTI)

    Liu, Hua Kun

    2013-12-15

    Graphical abstract: Nanomaterials play important role in lithium ion batteries, supercapacitors, hydrogen storage and fuel cells. - Highlights: Nanomaterials play important role for lithium rechargeable batteries. Nanostructured materials increase the capacitance of supercapacitors. Nanostructure improves the hydrogenation/dehydrogenation of hydrogen storage materials. Nanomaterials enhance the electrocatalytic activity of the catalysts in fuel cells. - Abstract: There is tremendous worldwide interest in functional nanostructured materials, which are the advanced nanotechnology materials with internal or external dimensions on the order of nanometers. Their extremely small dimensions make these materials unique and promising for clean energy applications such as lithium ion batteries, supercapacitors, hydrogen storage, fuel cells, and other applications. This paper will highlight the development of new approaches to study the relationships between the structure and the physical, chemical, and electrochemical properties of functional nanostructured materials. The Energy Materials Research Programme at the Institute for Superconducting and Electronic Materials, the University of Wollongong, has been focused on the synthesis, characterization, and applications of functional nanomaterials, including nanoparticles, nanotubes, nanowires, nanoporous materials, and nanocomposites. The emphases are placed on advanced nanotechnology, design, and control of the composition, morphology, nanostructure, and functionality of the nanomaterials, and on the subsequent applications of these materials to areas including lithium ion batteries, supercapacitors, hydrogen storage, and fuel cells.

  15. Alternative Fuels Data Center: Batteries for Hybrid and Plug-In Electric

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicles Batteries for Hybrid and Plug-In Electric Vehicles to someone by E-mail Share Alternative Fuels Data Center: Batteries for Hybrid and Plug-In Electric Vehicles on Facebook Tweet about Alternative Fuels Data Center: Batteries for Hybrid and Plug-In Electric Vehicles on Twitter Bookmark Alternative Fuels Data Center: Batteries for Hybrid and Plug-In Electric Vehicles on Google Bookmark Alternative Fuels Data Center: Batteries for Hybrid and Plug-In Electric Vehicles on Delicious Rank

  16. Chemical Kinetic Modeling of Advanced Transportation Fuels

    SciTech Connect (OSTI)

    PItz, W J; Westbrook, C K; Herbinet, O

    2009-01-20

    Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

  17. Fuels and Chemicals from Lignocellulosic Biomass: Valorization...

    Office of Scientific and Technical Information (OSTI)

    Biomass: Valorization of Lignin Mike Kent Deconstruction Division Joint BioEnergy Institute Outline 1. Introduction: -fuels and chemicals from Ngnocellulosic biomass -need ...

  18. Excellence in biotechnology for fuels and chemicals

    SciTech Connect (OSTI)

    Neufeld, S.

    1999-04-23

    The Biotechnology Center for Fuels and Chemicals (BCFC) leads a national effort, in cooperation with industry, to develop innovative, market-driven biotechnologies for producing fuels and chemicals from renewable resources. The BCFC researchers focus on using bioprocesses to convert renewable biomass feedstocks into valuable products.

  19. NREL Uses Fuel Cells to Increase the Range of Battery Electric Vehicles (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01

    NREL analysis identifies potential cost-effective scenarios for using small fuel cell power units to increase the range of medium-duty battery electric vehicles.

  20. Graphene-based Electrochemical Energy Conversion and Storage: Fuel cells, Supercapacitors and Lithium Ion Batteries

    SciTech Connect (OSTI)

    Hou, Junbo; Shao, Yuyan; Ellis, Michael A.; Moore, Robert; Yi, Baolian

    2011-09-14

    Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

  1. Chemical Shuttle Additives in Lithium Ion Batteries

    SciTech Connect (OSTI)

    Patterson, Mary

    2013-03-31

    than NMC) and the DDB is useful for lithium ion cells with LFP cathodes (potential that is lower than NMC). A 4.5 V class redox shuttle provided by Argonne National Laboratory was evaluated which provides a few cycles of overcharge protection for lithium ion cells containing NMC cathodes but it is not stable enough for consideration. Thus, a redox shuttle with an appropriate redox potential and sufficient chemical and electrochemical stability for commercial use in larger format lithium ion cells with NMC cathodes was not found. Molecular imprinting of the redox shuttle molecule during solid electrolyte interphase (SEI) layer formation likely contributes to the successful reduction of oxidized redox shuttle species at carbon anodes. This helps to understand how a carbon anode covered with an SEI layer, that is supposed to be electrically insulating, can reduce the oxidized form of a redox shuttle.

  2. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  3. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  4. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  6. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  7. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  8. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  9. Alternative fuels and chemicals from synthesis gas

    SciTech Connect (OSTI)

    Unknown

    1998-08-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  10. Production of chemicals and fuels from biomass

    DOE Patents [OSTI]

    Woods, Elizabeth; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

    2015-12-15

    Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  11. Multi-layered, chemically bonded lithium-ion and lithium/air batteries

    DOE Patents [OSTI]

    Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

    2014-05-13

    Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

  12. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    1998-12-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE�s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  13. Predicting Chemical Pathways for Li-O2 Batteries - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 6, 2014, Research Highlights Predicting Chemical Pathways for Li-O2 Batteries ... figure) and (LiO2)6 (red curve, upper figure) to Li2O2 using quantum chemical theory. ...

  14. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  15. Correlation of Lithium-Ion Battery Performance with Structural and Chemical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformations | Stanford Synchrotron Radiation Lightsource Correlation of Lithium-Ion Battery Performance with Structural and Chemical Transformations Wednesday, April 30, 2014 Chemical evolution and structural transformations in a material directly influence characteristics relevant to a wide range of prominent applications including rechargeable batteries for energy storage. Structural and/or chemical rearrangements at surfaces determine the way a material interacts with its environment,

  16. Chemical Kinetics Research on HCCI and Diesel Fuels

    Broader source: Energy.gov [DOE]

    Discusses detailed chemical kinetics mechanisms for complex hydrocarbon fuels and computationally efficiecnt, accurate methodologies for modeling advanced combustion strategies.

  17. New materials for batteries and fuel cells. Materials Research Society symposium proceedings, Volume 575

    SciTech Connect (OSTI)

    Doughty, D.H.; Nazar, L.F.; Arakawa, Masayasu; Brack, H.P.; Naoi, Katsuhiko

    2000-07-01

    This proceedings volume is organized into seven sections that reflect the materials systems and issues of electrochemical materials R and D in batteries, fuel cells, and capacitors. The first three parts are largely devoted to lithium ion rechargeable battery materials since that electrochemical system has received much of the attention from the scientific community. Part 1 discusses cathodes for lithium ion rechargeable batteries as well as various other battery systems. Part 2 deals with electrolytes and cell stability, and Part 3 discusses anode developments, focusing on carbon and metal oxides. Part 4 focuses on another rechargeable system that has received substantial interest, nickel/metal hydride battery materials. The next two parts discuss fuel cells--Part 5 deals with Proton Exchange Membrane (PEM) fuel cells, and Part 6 discusses oxide materials for solid oxide fuel cells. The former has the benefit of operating around room temperature, whereas the latter has the benefit of operating with a more diverse (non-hydrogen) fuel source. Part 7 presents developments in electrochemical capacitors, termed Supercapacitors. These devices are receiving renewed interest and have shown substantial improvements in the past few years. In all, the results presented at this symposium gave a deeper understanding of the relationship between synthesis, properties, and performance of power source materials. Papers are processed separately for inclusion on the data base.

  18. Battery Anodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center at Cornell Anodes Introduction The anode is the negative electrode of a primary cell and is always associated with the oxidation or the release of electrons into the external circuit. In a rechargeable cell, the anode is the negative pole during discharge and the positive pole during charge. Lithium Anode The anode in the battery deserves an equal say in the overall performance of a battery. For an effective development of a high energy density battery, the use of high capacity

  19. Battery Cathodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center at Cornell Cathodes Figure 1. Acceleration of DMcT Oxidation and Reduction at PEDOT-Modified Electrode Research on new cathodes for lithium-ion batteries has long been directed towards crystalline metal oxide-based materials, with charge stored by lithium insertion into the material matrix. Research in the Energy Frontier Research Center is pursuing an alternate approach to battery cathodes based on the reaction of lithium with naturally abundant, light-weight, and amorphous organic

  20. Mild, Nontoxic Production of Fuels and Chemicals from Biomass...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil fuel resources supply almost 90 percent of the world's energy and the vast majority of its organic chemicals. This dependency is insupportable in light of rising emissions, ...

  1. 37th Symposium on Biotechnology for Fuels and Chemicals

    Broader source: Energy.gov [DOE]

    The 37th Symposium on Biotechnology for Fuels and Chemicals will be held from April 27–30, 2015 in San Diego, California.

  2. Photosynthetic Conversion of CO2 to Fuels and Chemicals using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthetic Conversion of CO 2 to Fuels and Chemicals using Cyanobacteria Accelerating Innovation Webinar August 8, 2012 Jianping Yu, Ph.D., Senior Scientist * Many eukaryotic ...

  3. Fuel Cell Animation- Chemical Process (Text Version)

    Broader source: Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  4. CNEEC - Batteries Tutorial by Prof. Cui

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries

  5. Membrane Durability in PEM Fuel Cells: Chemical Degradation | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Durability in PEM Fuel Cells: Chemical Degradation Membrane Durability in PEM Fuel Cells: Chemical Degradation Presentation at the 2008 High Temperature Membrane Working Group Meeting held June 9, 2008, in Washington, DC motupally_htmwg_2008.pdf (962.33 KB) More Documents & Publications Highly Dispersed Alloy Cathode Catalyst for Durability Fundamental Study of the Mechanical Strength Degradation Mechanisms of PFSA Membranes and MEAs New Membranes for PEM Fuel Cells

  6. South Carolina Nuclear Profile - All Fuels

    U.S. Energy Information Administration (EIA) Indexed Site

    solid waste, batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, tire-derived fuel, and miscellaneous technologies." "Other Renewable: Wood, black liquor, other wood ...

  7. Chemical Kinetic Research on HCCI & Diesel Fuels

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. Chemical Kinetic Research on HCCI & Diesel Fuels

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  9. Chemical Kinetic Research on HCCI & Diesel Fuels

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Micropower chemical fuel-to-electric conversion : a "regenerative flip" hydrogen concentration cell promising near carnot efficiency.

    SciTech Connect (OSTI)

    Wally, Karl

    2006-05-01

    Although battery technology is relatively mature, power sources continue to impose serious limitations for small, portable, mobile, or remote applications. A potentially attractive alternative to batteries is chemical fuel-to-electric conversion. Chemical fuels have volumetric energy densities 4 to 10 times those of batteries. However, realizing this advantage requires efficient chemical fuel-to-electric conversion. Direct electrochemical conversion would be the ideal, but, for most fuels, is generally not within the state-of-the-science. Next best, chemical-to-thermal-to-electric conversion can be attractive if efficiencies can be kept high. This small investigative project was an exploration into the feasibility of a novel hybrid (i.e., thermal-electrochemical) micropower converter of high theoretical performance whose demonstration was thought to be within near-term reach. The system is comprised of a hydrogen concentration electrochemical cell with physically identical hydrogen electrodes as anode and cathode, with each electrode connected to physically identical hydride beds each containing the same low-enthalpy-of-formation metal hydride. In operation, electrical power is generated by a hydrogen concentration differential across the electrochemical cell. This differential is established via coordinated heating and passive cooling of the corresponding hydride source and sink. Heating is provided by the exothermic combustion (i.e., either flame combustion or catalytic combustion) of a chemical fuel. Upon hydride source depletion, the role of source and sink are reversed, heating and cooling reversed, electrodes commutatively reversed, cell operation reversed, while power delivery continues unchanged. This 'regenerative flip' of source and sink hydride beds can be cycled continuously until all available heating fuel is consumed. Electricity is efficiently generated electrochemically, but hydrogen is not consumed, rather the hydrogen is regeneratively cycled as

  11. Batteries

    Broader source: Energy.gov [DOE]

    From consumer electronics to laptops to vehicles, batteries are an important part of our everyday life. Learn about the Energy Department's innovative research and development in different energy storage options.

  12. Zinc air refuelable battery: alternative zinc fuel morphologies and cell behavior

    SciTech Connect (OSTI)

    Cooper, J.F.; Krueger, R.

    1997-01-01

    Multicell zinc/air batteries have been tested previously in the laboratory and as part of the propulsion system of an electric bus; cut zinc wire was used as the anode material. This battery is refueled by a hydraulic transport of 0.5-1 mm zinc particles into hoppers above each cell. We report an investigation concerning alternative zinc fuel morphologies, and energy losses associated with refueling and with overnight or prolonged standby. Three types of fuel pellets were fabricated, tested and compared with results for cut wire: spheres produced in a fluidized bed electrolysis cell; elongated particles produced by gas-atomization; and pellets produced by chopping 1 mm porous plates made of compacted zinc fines. Relative sizes of the particles and cell gap dimensions are critical. All three types transported within the cell 1553 and showed acceptable discharge characteristics, but a fluidized bed approach appears especially attractive for owner/user recovery operations.

  13. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 13159553.pdf (405 KB) Technology Marketing Summary This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen

  14. SBIR/STTR FY15 Phase 1 Release 2 Awards Announced—Includes Fuel Cell-Battery Electric Hybrid Truck and Fuel Cell Manufacturing Quality Control Processes

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy has announced the 2015 Small Business Innovation Research and Small Business Technology Transfer (SBIR/STTR) Phase I Release 2 Awards, including projects demonstrating fuel cell-battery electric hybrid trucks and developing a real-time, in-line optical detector for the measurement of fuel cell membrane thickness.

  15. Chemically Etched Silicon Nanowires as Anodes for Lithium-Ion Batteries

    SciTech Connect (OSTI)

    West, Hannah Elise

    2015-08-01

    This study focused on silicon as a high capacity replacement anode for Lithium-ion batteries. The challenge of silicon is that it expands ~270% upon lithium insertion which causes particles of silicon to fracture, causing the capacity to fade rapidly. To account for this expansion chemically etched silicon nanowires from the University of Maine were studied as anodes. They were built into electrochemical half-cells and cycled continuously to measure the capacity and capacity fade.

  16. US Department of Energy Hybrid Vehicle Battery and Fuel Economy Testing

    SciTech Connect (OSTI)

    Donald Karner; J.E. Francfort

    2005-09-01

    The Advanced Vehicle Testing Activity (AVTA), part of the U.S. Department of Energy’s FreedomCAR and Vehicle Technologies Program, has conducted testing of advanced technology vehicles since August, 1995 in support of the AVTA goal to provide benchmark data for technology modeling, and research and development programs. The AVTA has tested over 200 advanced technology vehicles including full size electric vehicles, urban electric vehicles, neighborhood electric vehicles, and hydrogen internal combustion engine powered vehicles. Currently, the AVTA is conducting significant tests of hybrid electric vehicles (HEV). This testing has included all HEVs produced by major automotive manufacturers and spans over 1.3 million miles. The results of all testing are posted on the AVTA web page maintained by the Idaho National Laboratory. Through the course of this testing, the fuel economy of HEV fleets has been monitored and analyzed to determine the "real world" performance of their hybrid energy systems, particularly the battery. While the initial "real world" fuel economy of these vehicles has typically been less than that evaluated by the manufacturer and varies significantly with environmental conditions, the fuel economy and, therefore, battery performance, has remained stable over vehicle life (160,000 miles).

  17. battery electrode percolating network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    battery electrode percolating network - Sandia Energy Energy Search Icon Sandia Home ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  18. Overcoming the Range Limitation of Medium-Duty Battery Electric Vehicles through the use of Hydrogen Fuel-Cells

    SciTech Connect (OSTI)

    Wood, E.; Wang, L.; Gonder, J.; Ulsh, M.

    2013-10-01

    Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption. This analysis employs real-world vocational data and near-term economic assumptions to (1) identify optimal component configurations for minimizing lifecycle costs, (2) benchmark economic performance relative to both battery electric and conventional powertrains, and (3) understand how the optimal design and its competitiveness change with respect to duty cycle and economic climate. It is found that small fuel-cell power units provide extended range at significantly lower capital and lifecycle costs than additional battery capacity alone. And while fuel-cell range-extended vehicles are not deemed economically competitive with conventional vehicles given present-day economic conditions, this paper identifies potential future scenarios where cost equivalency is achieved.

  19. Co-Optima Fuel Property Team; Part 1 - Fuel Properties and Chemical Kinetics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Co-Optima Fuel Property Team Part 1 - Fuel Properties and Chemical Kinetics June 9, 2016 1 This presentation does not contain any proprietary, confidential, or otherwise restricted information FT038 - Part 1 Co-Optimization of Fuels and Engines Fuel Property Team Robert L. McCormick, 1 Gina Fioroni, 1 Jim Szybist, 2 Tim Bays, 3 Paul Miles, 4 Matt McNenly, 5 Bill Pitz, 5 Jon Luecke, 1 Matt Ratcliff, 1 Brad Zigler, 1 Scott Goldsborough 6 1. National Renewable Energy Laboratory 2. Oak Ridge

  20. Chemical Kinetic Reaction Mechanisms for Combustion of Hydrocarbon and Other Types of Chemical Fuels

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The central feature of the Combustion Chemistry project at LLNL is the development, validation, and application of detailed chemical kinetic reaction mechanisms for the combustion of hydrocarbon and other types of chemical fuels. For the past 30 years, LLNL's Chemical Sciences Division has built hydrocarbon mechanisms for fuels from hydrogen and methane through much larger fuels including heptanes and octanes. Other classes of fuels for which models have been developed include flame suppressants such as halons and organophosphates, and air pollutants such as soot and oxides of nitrogen and sulfur. Reaction mechanisms have been tested and validated extensively through comparisons between computed results and measured data from laboratory experiments (e.g., shock tubes, laminar flames, rapid compression machines, flow reactors, stirred reactors) and from practical systems (e.g., diesel engines, spark-ignition engines, homogeneous charge, compression ignition (HCCI) engines). These kinetic models are used to examine a wide range of combustion systems.

  1. Identification and quantification of organic chemicals in supplemental fuel blends

    SciTech Connect (OSTI)

    Salter, F.

    1996-12-31

    Continental Cement Company, Inc. (Continental) burns waste fuels to supplement coal in firing the kiln. It is to be expected that federal and state agencies want an accounting of the chemicals burned. As rules and regulations become more plentiful, a company such as Continental must demonstrate that it has made a reasonable attempt to identify and quantify many specific organic compounds. The chemicals on the SARA 313 list can change frequently. Also the number and concentrations of compounds that can disqualify a material from consideration as a supplemental fuel at Continental continues to change. A quick and reliable method of identifying and quantifying organics in waste fuel blends is therefore crucial. Using a Hewlett-Packard 5972 GC/MS system Continental has developed a method of generating values for the total weight of compounds burned. A similar procedure is used to verify that waste streams meet Continental`s acceptance criteria.

  2. Alternative fuel and chemicals from synthesis gas

    SciTech Connect (OSTI)

    1996-05-01

    Development of a reliable and cost-effective method of wax/catalyst separation is a key step toward a commercially viable slurry reactor process with iron oxide-based catalyst for Fischer-Tropsch (F-T) synthesis of hydrocarbon transportation fuels. Although a variety of suitable catalysts (including, for example, cobalt-based catalysts) are available, iron oxide-based catalysts are preferred for coal-derived, CO-rich syngas because, in addition to catalyzing the F-T reaction, they simultaneously catalyze the reaction stifling CO to H{sub 2}, obviating a separate shift process block and associated costs. Because of the importance of development of this wax/catalyst separation, a study was initiated in February 1991. P. Z. Zhou of Burns and Roe reviewed the status of F-T wax/catalyst separation techniques. This led to the selection of a filtration system for the separation. Pilot tests were conducted by Mott Porous Metal Products in 1992 to develop this system. Initial results were good, but problems were encountered in follow-up testing. As a result of the testing, a filter was selected for use on the pilot plant. In LaPorte, Texas, APCI has been operating a pilot plant for the development of various synthesis gas technologies with DOE and industry support. The APCI F-T program builds on the DOE-sponsored laboratory-scale work by Mobil, reported in the mid-1980s, which used an iron oxide catalyst to produce high-quality F-T liquids in relatively compact reactors. Separation of the catalyst solids from the wax still represents a challenge. In the summer of 1992, testing of the selected filter was begun as part of the pilot plant testing. The filter performed poorly. Separation of the catalyst was primarily by sedimentation. It was recommended that the wax/catalyst separation be developed further.

  3. 38th Symposium on Biotechnology for Fuels and Chemicals

    Broader source: Energy.gov [DOE]

    The 38th Symposium on Biotechnology for Fuels and Chemicals will be hosted in Baltimore, Maryland, from April 25–28, 2016 and will be hosted by the Oak Ridge National Laboratory. The conference will center on the development of a wide variety of renewable biobased fuels and products. Many members of the Bioenergy Technologies Office will be in attendance, including Deputy Director Valerie Reed and Advanced Algal Systems and Feedstocks Program Manger Alison Goss Eng, as well as Technology Managers Christine English, Jay Fitzgerald, Prasad Gupte, Ian Rowe, and Steve Thomas.

  4. Battery-free Wireless Sensor Network For Advanced Fossil-Fuel Based Power Generation

    SciTech Connect (OSTI)

    Yi Jia

    2011-02-28

    This report summarizes technical progress achieved during the project supported by the Department of Energy under Award Number DE-FG26-07NT4306. The aim of the project was to conduct basic research into battery-free wireless sensing mechanism in order to develop novel wireless sensors and sensor network for physical and chemical parameter monitoring in a harsh environment. Passive wireless sensing platform and five wireless sensors including temperature sensor, pressure sensor, humidity sensor, crack sensor and networked sensors developed and demonstrated in our laboratory setup have achieved the objective for the monitoring of various physical and chemical parameters in a harsh environment through remote power and wireless sensor communication, which is critical to intelligent control of advanced power generation system. This report is organized by the sensors developed as detailed in each progress report.

  5. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1995-01-01

    A compact, hermetic feedthrough apparatus comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance.

  6. Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

    2012-04-16

    Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

  7. Chemical Kinetic Research on HCCI & Diesel Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory Chemical Kinetic Research on HCCI & Diesel Fuels William J. Pitz (PI), Charles K. Westbrook, Marco Mehl, M. Lee Davisson Lawrence Livermore National Laboratory May 12, 2009 DOE National Laboratory Advanced Combustion Engine R&D Merit Review and Peer Evaluation Washington, DC This presentation does not contain any proprietary or confidential information This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under

  8. Evaluation of battery converters based on 4. 8-MW fuel cell demonstrator inverter. Final report. [Contains brief glossary

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    Electrical power conditioning is a critical element in the development of advanced electrochemical energy storage systems. This program evaluates the use of existing self-commutated converter technology (as developed by the Power Systems Division of United Technologies for the 4.8-MW Fuel Cell Demonstrator) with modification for use in battery energy storage systems. The program consists of three parts: evaluation of the cost and performance of a self-commutated converter modified to maintain production commonality between battery and fuel cell power conditioners, demonstration of the principal characteristics required for the battery application in MW-scale hardware, and investigation of the technical requirements of operation isolated from the utility system. A power-conditioning system consisting of a self-commutated converter augmented with a phase-controlled rectifier was selected and a preliminary design, prepared. A principal factor in this selection was production commonality with the fuel cell inverter system. Additional types of augmentation, and the use of a self-commutated converter system without augmentation, were also considered. A survey of advanced battery manufacturers was used to establish the dc interface characteristics. The principal characteristics of self-commutated converter operation required for battery application were demonstrated with the aid of an available 0.5-MW development system. A survey of five REA and municipal utilities and three A and E firms was conducted to determine technical requirements for operation in a mode isolated from the utility. Definitive requirements for this application were not established because of the limited scope of this study. 63 figures, 37 tables.

  9. Consortium for Advanced Battery Simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Battery Simulation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  10. Chemical and Electrochemical Lithiation of LiVOPO4 Cathodes for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Harrison, Katharine L; Bridges, Craig A; Segre, C; VernadoJr, C Daniel; Applestone, Danielle; Bielawski, Christopher W; Paranthaman, Mariappan Parans; Manthiram, Arumugam

    2014-01-01

    The theoretical capacity of LiVOPO4 could be increased from 159 to 318 mAh/g with the insertion of a second Li+ ion into the lattice to form Li2VOPO4, significantly enhancing the energy density of lithium-ion batteries. The changes accompanying the second Li+ insertion into -LiVOPO4 and -LiVOPO4 are presented here at various degrees of lithiation, employing both electrochemical and chemical lithiation. Inductively coupled plasma, X-ray absorption spectroscopy, and Fourier transform spectroscopy measurements indicate that a composition of Li2VOPO4 could be realized with an oxidation state of V3+ by the chemical lithiation process. The accompanying structural changes are evidenced by X-ray and neutron powder diffraction. Spectroscopic and diffraction data collected with the chemically lithiated samples as well as diffraction data on the electrochemically lithiated samples reveal that significant amount of lithium can be inserted into -LiVOPO4 before a more dramatic structural change occurs. In contrast, lithiation of -LiVOPO4 is more consistent with the formation of a two-phase mixture throughout most of the lithiation range. The phases observed with the ambient-temperature lithiation processes presented here are significantly different from those reported in the literature.

  11. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced from any one of a

  12. Process for converting cellulosic materials into fuels and chemicals

    DOE Patents [OSTI]

    Scott, Charles D.; Faison, Brendlyn D.; Davison, Brian H.; Woodward, Jonathan

    1994-01-01

    A process for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attritor and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system.

  13. Chemical Kinetic Research on HCCI & Diesel Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemical Kinetic Research on HCCI & Diesel Fuels Chemical Kinetic Research on HCCI & Diesel Fuels 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_13_pitz.pdf (1.42 MB) More Documents & Publications Multidimensional simulation and chemical kinetics development for high efficiency clean combustion engines Chemical Kinetic Research on HCCI & Diesel Fuels Vehicle Technologies Office

  14. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone ...

  15. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone...

  16. Research and development of a phosphoric acid fuel cell/battery power source integrated in a test-bed bus. Final report

    SciTech Connect (OSTI)

    1996-05-30

    This project, the research and development of a phosphoric acid fuel cell/battery power source integrated into test-bed buses, began as a multi-phase U.S. Department of Energy (DOE) project in 1989. Phase I had a goal of developing two competing half-scale (25 kW) brassboard phosphoric acid fuel cell systems. An air-cooled and a liquid-cooled fuel cell system were developed and tested to verify the concept of using a fuel cell and a battery in a hybrid configuration wherein the fuel cell supplies the average power required for operating the vehicle and a battery supplies the `surge` or excess power required for acceleration and hill-climbing. Work done in Phase I determined that the liquid-cooled system offered higher efficiency.

  17. Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications.

    SciTech Connect (OSTI)

    Swain; Greg M.

    2009-04-13

    The original funding under this project number was awarded for a period 12/1999 until 12/2002 under the project title Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications. The project was extended until 06/2003 at which time a renewal proposal was awarded for a period 06/2003 until 06/2008 under the project title Metal/Diamond Composite Thin-Film Electrodes: New Carbon Supported Catalytic Electrodes. The work under DE-FG02-01ER15120 was initiated about the time the PI moved his research group from the Department of Chemistry at Utah State University to the Department of Chemistry at Michigan State University. This DOE-funded research was focused on (i) understanding structure-function relationships at boron-doped diamond thin-film electrodes, (ii) understanding metal phase formation on diamond thin films and developing electrochemical approaches for producing highly dispersed electrocatalyst particles (e.g., Pt) of small nominal particle size, (iii) studying the electrochemical activity of the electrocatalytic electrodes for hydrogen oxidation and oxygen reduction and (iv) conducting the initial synthesis of high surface area diamond powders and evaluating their electrical and electrochemical properties when mixed with a Teflon binder.

  18. An investigation of synthetic fuel production via chemical looping

    SciTech Connect (OSTI)

    Frank Zeman; Marco Castaldi

    2008-04-15

    Producing liquid hydrocarbon fuels with a reduced greenhouse gas emissions profile would ease the transition to a carbon-neutral energy sector with the transportation industry being the immediate beneficiary followed by the power industry. Revolutionary solutions in transportation, such as electricity and hydrogen, depend on the deployment of carbon capture and storage technologies and/or renewable energy systems. Additionally, high oil prices may increase the development of unconventional sources, such as tar sands, that have a higher emissions profile. One process that is gaining interest is a system for producing reduced carbon fuels though chemical looping technologies. An investigation of the implications of such a process using methane and carbon dioxide that is reformed to yield methanol has been done. An important aspect of the investigation is the use of off-the-shelf technologies to achieve the results. The ability of the process to yield reduced emissions fuels depends on the source for the feed and process heat. For the range of conditions considered, the emissions profile of methanol produced in this method varies from 0.475 to 1.645 moles carbon dioxide per mole methanol. The thermal load can be provided by methane, coal or carbon neutral (biogas). The upper bound can be lowered to 0.750 by applying CCS and/or using nonfossil heat sources for the reforming. The process provides an initial pathway to incorporate CO{sub 2} into fuels independent of electrolytic hydrogen or developments in other sectors of the economy. 22 refs., 1 fig., 3 tabs.

  19. Recent Advances in Detailed Chemical Kinetic Models for Large Hydrocarbon and Biodiesel Transportation Fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Herbinet, O; Mehl, M

    2009-03-30

    n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for these two primary reference fuels for diesel, a new capability is now available to model diesel fuel ignition. Also, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. Methyl decanoate and methyl stearate are large methyl esters that are closely related to biodiesel fuels, and kinetic models for these molecules have also been developed. These chemical kinetic models are used to predict the effect of the fuel molecule size and structure on ignition characteristics under conditions found in internal combustion engines.

  20. Better batteries to break dependence on fossil fuels > EMC2 News...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EMC2 News Latest News Prof. Hctor Abrua wins Electrochimica Acta Gold Medal award Pastore wins Bauer Scholarship Award Room-temperature lithium metal battery closer to ...

  1. Chemical degradation mechanisms of membranes for alkaline membrane fuel cells

    SciTech Connect (OSTI)

    Choe, Yoong-Kee; Henson, Neil J.; Kim, Yu Seung

    2015-12-31

    Chemical degradation mechanisms of membranes for alkaline membrane fuel cells have been investigated using density functional theory (DFT). We have elucidated that the aryl-ether moiety of membranes is one of the weakest site against attack of hydroxide ions. The results of DFT calculations for hydroxide initiated aryl-ether cleavage indicated that the aryl-ether cleavage occurred prior to degradation of cationic functional group. Such a weak nature of the aryl-ether group arises from the electron deficiency of the aryl group as well as the low bond dissociation energy. The DFT results suggests that removal of the aryl-ether group in the membrane should enhance the stability of membranes under alkaline conditions. In fact, an ether fee poly(phenylene) membrane exhibits excellent stability against the attack from hydroxide ions.

  2. Process for converting cellulosic materials into fuels and chemicals

    DOE Patents [OSTI]

    Scott, C.D.; Faison, B.D.; Davison, B.H.; Woodward, J.

    1994-09-20

    A process is described for converting cellulosic materials, such as waste paper, into fuels and chemicals utilizing enzymatic hydrolysis of the major constituent of paper, cellulose. A waste paper slurry is contacted by cellulase in an agitated hydrolyzer. The cellulase is produced from a continuous, columnar, fluidized-bed bioreactor utilizing immobilized microorganisms. An attrition mill and a cellobiase reactor are coupled to the agitated hydrolyzer to improve reaction efficiency. The cellulase is recycled by an adsorption process. The resulting crude sugars are converted to dilute product in a fluidized-bed bioreactor utilizing microorganisms. The dilute product is concentrated and purified by utilizing distillation and/or a biparticle fluidized-bed bioreactor system. 1 fig.

  3. Production of fuels and chemicals from apple pomace

    SciTech Connect (OSTI)

    Hang, Y.D.

    1987-03-01

    Nearly 36 million tons of apples are produced annually in the US. Approximately 45% of the total US apple production is used for processing purposes. The primary by-product of apple processing is apple pomace. It consists of the presscake resulting from pressing apples for juice or cider, including the presscake obtained in pressing peel and core wastes generated in the manufacture of apple sauce or slices. More than 500 food processing plants in the US produce a total of about 1.3 million metric tons of apple pomace each year, and it is likely that annual disposal fees exceed $10 million. Apple pomace has the potential to be used for the production of fuels (ethanol and biogas containing 60% methane) and food-grade chemicals. These uses will be reviewed in this article.

  4. Hydrogen fuel cells in chemical industry: The assemini project

    SciTech Connect (OSTI)

    Caserza, G.; Bozzoni, T.; Porcino, G.; Pasquinucci, A.

    1996-12-31

    Chemical and petrochemical industries generate large quantities of hydrogen-rich streams, in the range 50%-100% H{sub 2} concentration by volume, as by-products of electrochemical or dehydrogenation processes, or exhausts/purging in hydrogenation processes. Due to safety aspects, and because of the low density, which makes difficult transportation and storage, such streams often constitute a problem for plant managers. In most cases recycling within the plant processes is not possible, and transportation to other sites, generally by truck after compression in cylinders, is not economical. Many of these streams arc therefore simply co-burned in plant boilers, and in some cases even wasted by venting or flaring. Their value ranges from zero (if vented), to the value of the fuel used in the boiler, where they are co-burned.

  5. Leading experts to speak at battery & energy storage technology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including: new battery chemistries, battery longevity and performance, energy storage in electric grid applications and the latest developments in fuel cells and flow batteries. ...

  6. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    capable of automatic, safe, reliable, efficient, and low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. ...

  7. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    low-emission operation across a broad range of fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas. PDF icon Displacing Natural Gas Consumption and...

  8. Breakthrough Flow Battery Cell Stack: Transformative Electrochemical Flow Storage System (TEFSS)

    SciTech Connect (OSTI)

    2010-09-09

    GRIDS Project: UTRC is developing a flow battery with a unique design that provides significantly more power than today's flow battery systems. A flow battery is a cross between a traditional battery and a fuel cell. Flow batteries store their energy in external tanks instead of inside the cell itself. Flow batteries have traditionally been expensive because the battery cell stack, where the chemical reaction takes place, is costly. In this project, UTRC is developing a new stack design that achieves 10 times higher power than today’s flow batteries. This high power output means the size of the cell stack can be smaller, reducing the amount of expensive materials that are needed. UTRC’s flow battery will reduce the cost of storing electricity for the electric grid, making widespread use feasible.

  9. NREL Uses Fuel Cells to Increase the Range of Battery Electric Vehicles (Fact Sheet), NREL Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL analysis identifies potential cost-effective scenarios for using small fuel cell power units to increase the range of medium-duty battery electric vehicles. Battery electric vehicles (BEVs) offer great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Charac- terized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations such as parcel delivery are well

  10. Analysis of environmental factors impacting the life cycle cost analysis of conventional and fuel cell/battery-powered passenger vehicles. Final report

    SciTech Connect (OSTI)

    1995-01-31

    This report presents the results of the further developments and testing of the Life Cycle Cost (LCC) Model previously developed by Engineering Systems Management, Inc. (ESM) on behalf of the U.S. Department of Energy (DOE) under contract No. DE-AC02-91CH10491. The Model incorporates specific analytical relationships and cost/performance data relevant to internal combustion engine (ICE) powered vehicles, battery powered electric vehicles (BPEVs), and fuel cell/battery-powered electric vehicles (FCEVs).

  11. Chemical Dynamics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  12. CONVERSION OF LIGNOCELLULOSIC MATERIAL TO CHEMICALS AND FUELS

    SciTech Connect (OSTI)

    Edwin S. Olson

    2001-06-30

    A direct conversion of cellulosic wastes, including resin-bonded furniture and building waste, to levulinate esters is being investigated with the view to producing fuels, solvents, and chemical intermediates as well as other useful by-products in an inexpensive process. The acid-catalyzed reaction of cellulosic materials with ethanol or methanol at 200 C gives good yields of levulinate and formate esters, as well as useful by-products, such as a solid residue (charcoal) and a resinous lignin residue. An initial plant design showed reasonable rates of return for production of purified ethyl levulinate and by-products. In this project, investigations have been performed to identify and develop reactions that utilize esters of levulinic acid produced during the acid-catalyzed ethanolysis reaction. We wish to develop uses for levulinate esters that allow their marketing at prices comparable to inexpensive polymer intermediates. These prices will allow a sufficient rate of return to justify building plants for utilizing the waste lignocellulosics. If need is demonstrated for purified levulinate, the initial plant design work may be adequate, at least until further pilot-scale work on the process is performed.

  13. Chemical Kinetic Modeling of Non-Petroleum Based Fuels

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  14. Chemical Kinetic Modeling of Non-Petroleum Based Fuels

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  15. electrochemical battery stress-induced degradation mechanisms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electrochemical battery stress-induced degradation mechanisms - Sandia Energy Energy ... Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ...

  16. Epitaxial Single Crystal Nanostructures for Batteries & PVs ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  17. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  18. Battery cell feedthrough apparatus

    DOE Patents [OSTI]

    Kaun, T.D.

    1995-03-14

    A compact, hermetic feedthrough apparatus is described comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance. 8 figs.

  19. Apparatus and method for solid fuel chemical looping combustion

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V; Weber, Justin M

    2015-04-14

    The disclosure provides an apparatus and method utilizing fuel reactor comprised of a fuel section, an oxygen carrier section, and a porous divider separating the fuel section and the oxygen carrier section. The porous divider allows fluid communication between the fuel section and the oxygen carrier section while preventing the migration of solids of a particular size. Maintaining particle segregation between the oxygen carrier section and the fuel section during solid fuel gasification and combustion processes allows gases generated in either section to participate in necessary reactions while greatly mitigating issues associated with mixture of the oxygen carrier with char or ash products. The apparatus and method may be utilized with an oxygen uncoupling oxygen carrier such as CuO, Mn.sub.3O.sub.4, or Co.sub.3O.sub.4, or utilized with a CO/H.sub.2 reducing oxygen carrier such as Fe.sub.2O.sub.3.

  20. Fuel cells: A handbook (Revision 3)

    SciTech Connect (OSTI)

    Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

    1994-01-01

    Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

  1. Converting biomass to fuels and high-value chemicals | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Converting biomass to fuels and high-value chemicals The goal of this research is to develop low cost catalysts based on graphene-derived nanomaterials, and use them to improve the...

  2. Eighteenth symposium on biotechnology for fuels and chemicals: Program and abstracts

    SciTech Connect (OSTI)

    1996-12-31

    This volume provides the proceedings for the Eighteenth Symposium on Biotechnology for Fuels and Chemicals held May 5-9, 1996 in Gatlinburg, Tennessee. The proceedings contains abstracts for oral and poster presentations.

  3. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS. FINAL QUARTERLY STATUS REPORT NO. 10

    SciTech Connect (OSTI)

    1998-11-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  4. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS. FINAL QUARTERLY STATUS REPORT

    SciTech Connect (OSTI)

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. Synthetic Design Microorganisms for Lignin Fuels and Chemicals Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Synthetic Design Microorganisms for Lignin Fuels and Chemicals 3/26/2015 Synthetic Biology Joshua S. Yuan Associate Professor and Director Texas A&M University This presentation does contain proprietary information 1 Project Goal: Design of Microorganisms for Lignin Fuel * The proposed research aims to address one of the most challenging issues in biofuel production: the utilization of lignin for fungible fuels. * Project Outcome: A viable biological platform for conversion of lignin into

  6. Processes for converting biomass-derived feedstocks to chemicals and liquid fuels

    DOE Patents [OSTI]

    Held, Andrew; Woods, Elizabeth; Cortright, Randy; Gray, Matthew

    2016-07-05

    The present invention provides processes, methods, and systems for converting biomass-derived feedstocks to liquid fuels and chemicals. The method generally includes the reaction of a hydrolysate from a biomass deconstruction process with hydrogen and a catalyst to produce a reaction product comprising one of more oxygenated compounds. The process also includes reacting the reaction product with a condensation catalyst to produce C.sub.4+ compounds useful as fuels and chemicals.

  7. Vehicle Technologies Office Merit Review 2014: Overview and Progress of the Batteries for Advanced Transportation Technologies (BATT) Activity

    Broader source: Energy.gov [DOE]

    Presentation given by the Department of Energy's Energy Storage area at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the research area that is examining new battery materials and addressing fundamental chemical and mechanical instability issues in batteries.

  8. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    2010-06-01

    Funded by the American Recovery and Reinvestment Act of 2009 ENVIRON International Corporation, in collaboration with Callidus Technologies by Honeywell and Shell Global Solutions, Inc., will develop and demonstrate a full-scale fuel blending and combustion system. This system will allow a broad range of opportunity fuel compositions, including syngas, biogas, natural gas, and refinery fuel gas, to be safely, cost-effectively, and efficiently utilized while generating minimal emissions of criteria pollutants. The project will develop a commercial technology for application in refinery and chemical plant process heaters where opportunity fuels are used.

  9. Seventeenth symposium on biotechnology for fuels and chemicals. Program and abstracts

    SciTech Connect (OSTI)

    1995-05-01

    This volume contains the abstracts of oral and poster presentations made at the Seventeenth Symposium on Biotechnology for Fuels and Chemicals. Session titles include Thermal, Chemical, and Biological Processing; Applied Biological Research; Bioprocessing Research; Special Topics Discussion Groups; Process Economics and Commercialization; and Environmental Biotechnology.

  10. Fuel Cell/Battery Powered Bus System. Final Report for period August 1987 - December 31, 1997

    SciTech Connect (OSTI)

    Wimmer, R.

    1999-01-01

    Today, fuel cell systems are getting much attention from the automotive industry as a future replacement for the internal combustion engine (ICE). Every US automobile manufacturer and most foreign firms have major programs underway to develop fuel cell engines for transportation. The objective of this program was to investigate the feasibility of using fuel cells as an alternative to the ICE. Three such vehicles (30-foot buses) were introduced beginning in 1994. Extensive development and operational testing of fuel cell systems as a vehicle power source has been accomplished under this program. The development activity investigated total systems configuration and effectiveness for vehicle operations. Operational testing included vehicle performance testing, road operations, and extensive dynamometer emissions testing.

  11. Chemical overcharge protection of lithium and lithium-ion secondary batteries

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M.; Rohan, James F.; Foo, Conrad C.; Pasquariello, David M.

    1999-01-01

    This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

  12. Chemical overcharge protection of lithium and lithium-ion secondary batteries

    DOE Patents [OSTI]

    Abraham, K.M.; Rohan, J.F.; Foo, C.C.; Pasquariello, D.M.

    1999-01-12

    This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn{sub 2}O{sub 4} positive electrode (cathode). 8 figs.

  13. Accelerating the Computation of Detailed Chemical Reaction Kinetics for Simulating Combustion of Complex Fuels

    SciTech Connect (OSTI)

    Grout, Ray W

    2012-01-01

    Combustion of hydrocarbon fuels has been a very challenging scientific and engineering problem due to the complexity of turbulent flows and hydrocarbon reaction kinetics. There is an urgent need to develop an efficient modeling capability to accurately predict the combustion of complex fuels. Detailed chemical kinetic models for the surrogates of fuels such as gasoline, diesel and JP-8 consist of thousands of chemical species and Arrhenius reaction steps. Oxygenated fuels such as bio-fuels and heavier hydrocarbons, such as from newer fossil fuel sources, are expected to have a much more complex chemistry requiring increasingly larger chemical kinetic models. Such models are beyond current computational capability, except for homogeneous or partially stirred reactor type calculations. The advent of highly parallel multi-core processors and graphical processing units (GPUs) promises a steep increase in computational performance in the coming years. This paper will present a software framework that translates the detailed chemical kinetic models to high- performance code targeted for GPU accelerators.

  14. Fuels for Advanced Combustion Engines Research Diesel Fuels: Analysis of Physical and Chemical Properties

    SciTech Connect (OSTI)

    Gallant, Tom; Franz, Jim; Alnajjar, Mikhail; Storey, John Morse; Lewis Sr, Samuel Arthur; Sluder, Scott; Cannella, William C; Fairbridge, Craig; Hager, Darcy; Dettman, Heather; Luecke, Jon; Ratcliff, Matthew A.; Zigler, Brad

    2009-01-01

    The CRC Fuels for Advanced Combustion Engines working group has worked to identify a matrix of research diesel fuels for use in advanced combustion research applications. Nine fuels were specified and formulated to investigate the effects of cetane number aromatic content and 90% distillation fraction. Standard ASTM analyses were performed on the fuels as well as GC/MS and /u1H//u1/u3C NMR analyses and thermodynamic characterizations. Details of the actual results of the fuel formulations compared with the design values are presented, as well as results from standard analyses, such as heating value, viscosity and density. Cetane number characterizations were accomplished by using both the engine method and the Ignition Quality Tester (IQT/sT) apparatus.

  15. Batteries and energy systems

    SciTech Connect (OSTI)

    Mantell, C.L.

    1982-01-01

    A historical review of the galvanic concept and a brief description of the theory of operation of batteries are followed by chapters on specific types of batteries and energy systems. Chapters contain a section on basic theory, performance and applications. Secondary cells discussed are: SLI batteries, lead-acid storage batteries, lead secondary cells, alkaline secondary cells, nickel and silver-cadmium systems and solid electrolyte systems. Other chapters discuss battery charging, regenerative electrochemical systems, solar cells, fuel cells, electric vehicles and windmills. (KAW)

  16. HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model

    SciTech Connect (OSTI)

    Andrae, J.C.G.; Head, R.A.

    2009-04-15

    Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature and high intake pressure and less resistant to autoignition for high intake temperature and low intake pressure. A sensitivity analysis shows that at high intake temperature the chemistry of the fuels ethanol, toluene and diisobutylene helps to advance ignition. This is consistent with the trend that fuels with the least Negative Temperature Coefficient (NTC) behavior show the highest octane sensitivity, and become less resistant to autoignition at high intake temperatures. For high intake pressure the sensitivity analysis shows that fuels in the fuel blend with no NTC behavior consume OH radicals and acts as a radical scavenger for the fuels with NTC behavior. This is consistent with the observed trend of an increase in RON and fuel sensitivity. With data from shock tube experiments in the literature and HCCI modeling in this work, a correlation between the reciprocal pressure exponent on the ignition delay to the fuel sensitivity and volume percentage of single-stage ignition fuel in the fuel blend was found. Higher fuel

  17. Disposal of defense spent fuel and HLW at the Idaho Chemical Processing Plant

    SciTech Connect (OSTI)

    Ermold, L.F.; Loo, H.H.; Klingler, R.D.; Herzog, J.D.; Knecht, D.A.

    1993-06-01

    Irradiated nuclear fuel has been reprocessed at the Idaho Chemical Processing Plant (ICPP) since 1953 to recover uranium-235 and krypton-85 for the US Department of Energy (DOE). The resulting acidic high-level radioactive waste (HLW) has been solidified to a calcine since 1963 and stored in stainless steel underground bins enclosed by concrete vaults. Several different types of unprocessed irradiated DOE-owned fuels are also in storage at the ICPP. In April, 1992, DOE announced that spent fuel would no longer be reprocessed to recover enriched uranium and called for a shutdown of the reprocessing facilities at the ICPP. A new Spent Fuel and HLW Technology Development program was subsequently initiated to develop technologies for immobilizing ICPP spent fuels and HLW for disposal, in accordance with the Nuclear Waste Policy Act. The Program elements include Systems Analysis, Graphite Fuel Disposal, Other Spent Fuel Disposal, Sodium-Bearing Liquid Waste Processing, Calcine Immobilization, and Metal Recycle/Waste Minimization. This paper presents an overview of the ICPP radioactive wastes and current spent fuels, with an emphasis on the description of HLW and spent fuels requiring repository disposal.

  18. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery...

  19. Battery of short-term tests in laboratory animals to corroborate the detection of human population exposures to genotoxic chemicals

    SciTech Connect (OSTI)

    Pereira, M.A.; Chang, L.W.; McMillan, L.; Ward, J.B.; Legator, M.S.

    1982-02-01

    The authors are conducting a battery of short-term tests in laboratory animals for comparison to a series of monitoring test they are evaluating for the detection of human population exposures to genotoxic chemicals. The human monitoring tests are described in a separate abstract. These assays include (1) hemoglobin (Hb) alkylation, (2) cytogenetic effects in bone marrow cells including chromosomal structural aberrations, sister chromatid exchange and micronucleus production, (3) DNA damage in bone marrow cells, (4) sperm morphology and (5) urine analysis for mutagens. Formaldehyde and methanol a metabolic precursor, are being evaluated in animals. The results are as follows: Hb Alkylation: the oral administration of carbon-14 radiolabeled formaldehyde or methanol to rats resulted in their covalent binding to Hb. Adducts to amino acids were separated after acid hydrolysis by an amino acid analyzer. The binding of both chemicals exhibited a linear relationship to dose between 10 and 100 umole/kg. The extent of methanol binding to Hb was greater than formaldehyde. Cytogenetic Analyses: the oral administration in mice of formaldehyde (100 mg/kg) or methanol (lg/kg) increased the incidence of chromosomal aberrations particularly aneuploidy and exchanges and the incidence of micronuclei in polychromatic erythrocytes. Results of the Hb alkylation and cytogenetic analyses will be compared to the results obtained in the human monitors studies with formaldehyde.

  20. Argonne partners with Strem Chemicals to deliver next-gen battery materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to industry | Argonne National Laboratory You may also like Argonne theorists solve a long-standing fundamental problem August 30, 2016 Energy Department awards five new Argonne-business collaborations under Small Business Vouchers pilot August 23, 2016 New silicon structures could make better biointerfaces August 1, 2016 A new leaf: Scientists turn carbon dioxide back into fuel July 29, 2016 Physicists show trilayer metal oxide's true stripes July 26, 2016 Argonne partners with Strem

  1. Electrocatalytic Activity of Transition Metal Oxide-Carbon Composites for Oxygen Reduction in Alkaline Batteries and Fuel Cells

    SciTech Connect (OSTI)

    Malkhandi, S; Trinh, P; Manohar, AK; Jayachandrababu, KC; Kindler, A; Prakash, GKS; Narayanan, SR

    2013-06-07

    Conductive transition metal oxides (perovskites, spinels and pyrochlores) are attractive as catalysts for the air electrode in alkaline rechargeable metal-air batteries and fuel cells. We have found that conductive carbon materials when added to transition metal oxides such as calcium-doped lanthanum cobalt oxide, nickel cobalt oxide and calcium-doped lanthanum manganese cobalt oxide increase the electrocatalytic activity of the oxide for oxygen reduction by a factor of five to ten. We have studied rotating ring-disk electrodes coated with (a) various mass ratios of carbon and transition metal oxide, (b) different types of carbon additives and (c) different types of transition metal oxides. Our experiments and analysis establish that in such composite catalysts, carbon is the primary electro- catalyst for the two-electron electro-reduction of oxygen to hydroperoxide while the transition metal oxide decomposes the hydroperoxide to generate additional oxygen that enhances the observed current resulting in an apparent four-electron process. These findings are significant in that they change the way we interpret previous reports in the scientific literature on the electrocatalytic activity of various transition metal oxide- carbon composites for oxygen reduction, especially where carbon is assumed to be an additive that just enhances the electronic conductivity of the oxide catalyst. (C) 2013 The Electrochemical Society. All rights reserved.

  2. Vehicle Battery Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Basics Vehicle Battery Basics November 22, 2013 - 1:58pm Addthis Vehicle Battery Basics Batteries are essential for electric drive technologies such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and all-electric vehicles (AEVs). WHAT IS A BATTERY? A battery is a device that stores chemical energy and converts it on demand into electrical energy. It carries out this process through an electrochemical reaction, which is a chemical reaction involving the

  3. USABC Development of Advanced High-Performance Batteries for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of Advanced High-Performance Batteries for EV Applications USABC Development of Advanced High-Performance Batteries for EV Applications 2012 DOE Hydrogen and Fuel Cells ...

  4. Development of Polymer Electrolytes for Advanced Lithium Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polymer Electrolytes for Advanced Lithium Batteries Development of Polymer Electrolytes for Advanced Lithium Batteries 2013 DOE Hydrogen and Fuel Cells Program and Vehicle...

  5. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  6. CHEMICAL SENSOR AND FIELD SCREENING TECHNOLOGY DEVELOPMENT: FUELS IN SOILS FIELD SCREENING METHOD VALIDATION

    SciTech Connect (OSTI)

    Susan S. Sorini; John F. Schabron

    1997-04-01

    A new screening method for fuel contamination in soils was recently developed as American Society for Testing and Materials (ASTM) Method D-583 1-95, Standard Test Method for Screening Fuels in Soils. This method uses low-toxicity chemicals and can be used to screen organic-rich soils. In addition, it is fast, easy, and inexpensive to perform. The screening method calls for extracting a sample of soil with isopropyl alcohol following treatment with calcium oxide. The resulting extract is filtered, and the ultraviolet absorbance of the extract is measured at 254 nm. Depending on the available information concerning the contaminant fuel type and availability of the contaminant fuel for calibration, the method can be used to determine the approximate concentration of fuel contamination, an estimated value of fuel contamination, or an indication of the presence or absence of fuel contamination. Fuels containing aromatic compounds, such as diesel fuel and gasoline, as well as other aromatic-containing hydrocarbon materials, such as motor oil, crude oil, and coal oil, can be determined. The screening method for fuels in soils was evaluated by conducting a collaborative study on the method and by using the method to screen soil samples at an actual field site. In the collaborative study, a sand and an organic soil spiked with various concentrations of diesel fuel were tested. Data from the collaborative study were used to determine the reproducibility (between participants) and repeatability (within participant) precision of the method for screening the test materials. The collaborative study data also provide information on the performance of portable field equipment versus laboratory equipment for performing the screening method and a comparison of diesel concentration values determined using the screening method versus a laboratory method. Data generated using the method to screen soil samples in the field provide information on the performance of the method in

  7. Chemical Kinetic Simulation of the Combustion of Bio-based Fuels

    SciTech Connect (OSTI)

    Ashen, Ms. Refuyat; Cushman, Ms. Katherine C.

    2007-10-01

    Due to environmental and economic issues, there has been an increased interest in the use of alternative fuels. However, before widespread use of biofuels is feasible, the compatibility of these fuels with specific engines needs to be examined. More accurate models of the chemical combustion of alternative fuels in Homogeneous Charge Compression Ignition (HCCI) engines are necessary, and this project evaluates the performance of emissions models and uses the information gathered to study the chemical kinetics involved. The computer simulations for each alternative fuel were executed using the Chemkin chemical kinetics program, and results from the runs were compared with data gathered from an actual engine that was run under similar conditions. A new heat transfer mechanism was added to the existing model's subroutine, and simulations were then conducted using the heat transfer mechanism. Results from the simulation proved to be accurate when compared with the data taken from the actual engine. The addition of heat transfer produced more realistic temperature and pressure data for biodiesel when biodiesel's combustion was simulated in an HCCI engine. The addition of the heat transfer mechanism essentially lowered the peak pressures and peak temperatures during combustion of all fuels simulated in this project.

  8. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  9. Membrane process designs in the recovery of bio-fuels and bio-chemicals

    SciTech Connect (OSTI)

    Leeper, S.A.

    1990-01-01

    In this presentation, the emerging membrane unit operations and process designs that can be used in recovery of fuels and organic chemicals produced via bioconversion are briefly summarized. Product recovery costs are a major barrier to increased use of bioconversion for the production of fuels and chemicals. The integration of developing membrane unit operations into product recovery schemes may reduce process energy requirements and cost. Membrane unit operations that are used or studied in recovery of bio-fuels and organic chemicals include pervaporation (PV), vapor permeation (VPe), reverse osmosis (RO), membrane extraction, and electrodialysis (ED). Although it can be argued that ultrafiltration (UF) is used to purify bio-fuels and bio-chemicals, UF is not included in this survey for two reasons: (1) the primary uses of UF in bioprocessing are to clarify fermentation broth and to retain cells/enzymes in bioreactors and (2) the literature on UF in biotechnology is expansive. Products of bioconversion for which data are compiled include ethanol, acetone, butanol, glycerol, isopropanol, ethyl acetate, fusel oils, acetaldehyde, acetic acid, butyric acid, citric acid, propionic acid, succinic acid, and tartaric acid. 13 refs.

  10. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters

    SciTech Connect (OSTI)

    Benson, Charles; Wilson, Robert

    2014-04-30

    This project culminated in the demonstration of a full-scale industrial burner which allows a broad range of “opportunity” gaseous fuels to be cost-effectively and efficiently utilized while generating minimal emissions of criteria air pollutants. The burner is capable of maintaining a stable flame when the fuel composition changes rapidly. This enhanced stability will contribute significantly to improving the safety and reliability of burner operation in manufacturing sites. Process heating in the refining and chemicals sectors is the primary application for this burner. The refining and chemical sectors account for more than 40% of total industrial natural gas use. Prior to the completion of this project, an enabling technology did not exist that would allow these energy-intensive industries to take full advantage of opportunity fuels and thereby reduce their natural gas consumption. Opportunity gaseous fuels include biogas (from animal and agricultural wastes, wastewater plants, and landfills) as well as syngas (from the gasification of biomass, municipal solid wastes, construction wastes, and refinery residuals). The primary challenge to using gaseous opportunity fuels is that their composition and combustion performance differ significantly from those of conventional fuels such as natural gas and refinery fuel gas. An effective fuel-flexible burner must accept fuels that range widely in quality and change in composition over time, often rapidly. In Phase 1 of this project, the team applied computational fluid dynamics analysis to optimize the prototype burner’s aerodynamic, combustion, heat transfer, and emissions performance. In Phase 2, full-scale testing and refinement of two prototype burners were conducted in test furnaces at Zeeco’s offices in Broken Arrow, OK. These tests demonstrated that the full range of conventional and opportunity fuels could be utilized by the project’s burner while achieving robust flame stability and very low levels of

  11. Twelfth symposium on biotechnology for fuels and chemicals: Program and abstracts

    SciTech Connect (OSTI)

    Scheitlin, F.M.

    1990-01-01

    This report is the program and abstracts of the twelfth symposium on biotechnology for fuels and chemicals, held on May 7--11, 1990, at Gatlinburg, Tennessee. The symposium, sponsored by the Department of Energy, Oak Ridge National Laboratory, Solar Energy Research Institute, Badger Engineers, Inc., Gas Research Institute, and American Chemical Society, consists of five sessions: Session 1, thermal, chemical, and biological processing; Session 2 and 3, applied biological research; Session 4, bioengineering research; and Session 5, biotechnology, bioengineering, and the solution of environmental problems. It also consists of a poster session of the same five subject categories.

  12. Fuel-cladding chemical interaction correlation for mixed-oxide fuel pins

    SciTech Connect (OSTI)

    Lawrence, L.A.

    1986-10-01

    A revised wastage correlation was developed for FCCI with fabrication and operating parameters. The expansion of the data base to 305 data sets provided sufficient data to employ normal statistical techniques for calculation of confidence levels without unduly penalizing predictions. The correlation based on 316 SS cladding also adequately accounts for limited measured depths of interaction for fuel pins with D9 and HTq cladding.

  13. Solid Fuels Conversion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  14. Clean Fuels/Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  15. Biotechnology for producing fuels and chemicals from biomass. Volume II. Fermentation chemicals from biomass

    SciTech Connect (OSTI)

    Villet, R.

    1981-02-01

    The technological and economic feasibility of producing some selected chemicals by fermentation is discussed: acetone, butanol, acetic acid, citric acid, 2,3-butanediol, and propionic acid. The demand for acetone and butanol has grown considerably. They have not been produced fermentatively for three decades, but instead by the oxo and aldol processes. Improved cost of fermentative production will hinge on improving yields and using cellulosic feedstocks. The market for acetic acid is likely to grow 5% to 7%/yr. A potential process for production is the fermentation of hydrolyzed cellulosic material to ethanol followed by chemical conversion to acetic acid. For about 50 years fermentation has been the chief process for citric acid production. The feedstock cost is 15% to 20% of the overall cost of production. The anticipated 5%/yr growth in demand for citric acid could be enhanced by using it to displace phosphates in detergent manufacture. A number of useful chemicals can be derived from 2,3-butanediol, which has not been produced commercially on a large scale. R and D are needed to establish a viable commercial process. The commercial fermentative production of propionic acid has not yet been developed. Recovery and purification of the product require considerable improvement. Other chemicals such as lactic acid, isopropanol, maleic anhydride, fumarate, and glycerol merit evaluation for commercial fermentative production in the near future.

  16. Chemical Reactivity Testing for the National Spent Nuclear Fuel Program. Quality Assurance Project Plan

    SciTech Connect (OSTI)

    Newsom, H.C.

    1999-01-24

    This quality assurance project plan (QAPjP) summarizes requirements used by Lockheed Martin Energy Systems, Incorporated (LMES) Development Division at Y-12 for conducting chemical reactivity testing of Department of Energy (DOE) owned spent nuclear fuel, sponsored by the National Spent Nuclear Fuel Program (NSNFP). The requirements are based on the NSNFP Statement of Work PRO-007 (Statement of Work for Laboratory Determination of Uranium Hydride Oxidation Reaction Kinetics.) This QAPjP will utilize the quality assurance program at Y-12, QA-101PD, revision 1, and existing implementing procedures for the most part in meeting the NSNFP Statement of Work PRO-007 requirements, exceptions will be noted.

  17. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes

    SciTech Connect (OSTI)

    Ott, Kevin; Linehan, Sue; Lipiecki, Frank; Aardahl, Christopher L.

    2008-08-24

    The DOE Hydrogen Storage Program is focused on identifying and developing viable hydrogen storage systems for onboard vehicular applications. The program funds exploratory research directed at identifying new materials and concepts for storage of hydrogen having high gravimetric and volumetric capacities that have the potential to meet long term technical targets for onboard storage. Approaches currently being examined are reversible metal hydride storage materials, reversible hydrogen sorption systems, and chemical hydrogen storage systems. The latter approach concerns materials that release hydrogen in endothermic or exothermic chemical bond-breaking processes. To regenerate the spent fuels arising from hydrogen release from such materials, chemical processes must be employed. These chemical regeneration processes are envisioned to occur offboard the vehicle.

  18. Alternative fuels and chemicals from synthesis gas. Quarterly report, April 1--June 30, 1995

    SciTech Connect (OSTI)

    1995-12-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts. The paper reports the progress on the following tasks: engineering and modifications: AFDU shakedown, operations, deactivation and disposal; and research and development on new processes for DME, chemistry and catalyst development, and oxygenates via synthesis gas.

  19. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Cao, Yan

    2012-11-30

    Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked reactions are the oxidation of oxygen carriers in the air reactor using air, and the reduction of oxygen carriers in the fuel reactor using fuels (i.e. coal). Generally metal/metal oxides are used as oxygen carriers and operated in a cyclic mode. Chemical looping combustion significantly improves the energy conversion efficiency, in terms of the electricity generation, because it improves the reversibility of the fuel combustion process through two linked parallel processes, compared to the conventional combustion process, which is operated far away from its thermo-equilibrium. Under the current carbon-constraint environment, it has been a promising carbon capture technology in terms of fuel combustion for power generation. Its disadvantage is that it is less mature in terms of technological commercialization. In this DOE-funded project, accomplishment is made by developing a series of advanced copper-based oxygen carriers, with properties of the higher oxygen-transfer capability, a favorable thermodynamics to generate high purity of CO{sub 2}, the higher reactivity, the attrition-resistance, the thermal stability in red-ox cycles and the achievement of the auto-thermal heat balance. This will be achieved into three phases in three consecutive years. The selected oxygen carriers with final-determined formula were tested in a scaled-up 10kW coal-fueled chemical looping combustion facility. This scaled-up evaluation tests (2-day, 8-hour per day) indicated that, there was no tendency of agglomeration of copper-based oxygen carriers. Only trace-amount of coke or carbon deposits on the copper-based oxygen carriers in the fuel reactor. There was also no evidence to show the sulphidization of oxygen

  20. Thermal conversion of biomass to valuable fuels, chemical feedstocks and chemicals

    DOE Patents [OSTI]

    Peters, William A.; Howard, Jack B.; Modestino, Anthony J.; Vogel, Fredreric; Steffin, Carsten R.

    2009-02-24

    A continuous process for the conversion of biomass to form a chemical feedstock is described. The biomass and an exogenous metal oxide, preferably calcium oxide, or metal oxide precursor are continuously fed into a reaction chamber that is operated at a temperature of at least 1400.degree. C. to form reaction products including metal carbide. The metal oxide or metal oxide precursor is capable of forming a hydrolizable metal carbide. The reaction products are quenched to a temperature of 800.degree. C. or less. The resulting metal carbide is separated from the reaction products or, alternatively, when quenched with water, hydolyzed to provide a recoverable hydrocarbon gas feedstock.

  1. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  2. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  3. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  4. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  5. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Mapping Particle Charges in Battery Electrodes Print Friday, 26 July 2013 14:18 The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how

  6. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mapping Particle Charges in Battery Electrodes Print The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or discharged lithium ions move from one electrode to another, filling and unfilling individual, variably-sized battery particles. The rates of these processes determine how much power a battery can deliver. Despite the technological innovations

  7. Photosynthetic Conversion of CO2 to Fuels and Chemicals using Cyanobacteria

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photosynthetic Conversion of CO 2 to Fuels and Chemicals using Cyanobacteria Accelerating Innovation Webinar August 8, 2012 Jianping Yu, Ph.D., Senior Scientist * Many eukaryotic algae accumulate triacylglycerols (TAG), a biodiesel precursor. * Genetic system in eukaryotic algae lags behind; while cyanobacteria offer good genetic tools that facilitate fundamental understanding and they ability to manipulate pathways. * Harvesting TAG accumulated inside algae cells requires large energy input;

  8. Process Improvement to Biomass Pretreatment for Fuels and Chemicals Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Peer Review Process Improvement to Biomass Pretreatment for Fuels and Chemicals March 24 th 2015 Technology Area Review: Biochemical Conversion Principal investigator: Farzaneh Teymouri Organization: MBI, Lansing MI Tel.: (517) 337-3181, www.mbi.org This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Feedstock supply, including logistics systems and sustainable high quality feedstock, inadequate supply chain

  9. Status Report on the Fabrication of Fuel Cladding Chemical Interaction Test Articles for ATR Irradiations

    SciTech Connect (OSTI)

    Field, Kevin G.; Howard, Richard H.

    2015-09-28

    FeCrAl alloys are a promising new class of alloys for light water reactor (LWR) applications due to their superior oxidation and corrosion resistance in high temperature environments. The current R&D efforts have focused on the alloy composition and processing routes to generate nuclear grade FeCrAl alloys with optimized properties for enhanced accident tolerance while maintaining properties needed for normal operation conditions. Therefore, the composition and processing routes must be optimized to maintain the high temperature steam oxidation (typically achieved by increasing the Cr and Al content) while still exhibiting properties conducive to normal operation in a LWR (such as radiation tolerance where reducing Cr content is favorable). Within this balancing act is the addition of understanding the influence on composition and processing routes on the FeCrAl alloys for fuel-cladding chemical interactions (FCCI). Currently, limited knowledge exists on FCCI for the FeCrAl-UO2 clad-fuel system. To overcome the knowledge gaps on the FCCI for the FeCrAl-UO2 clad-fuel system a series of fueled irradiation tests have been developed for irradiation in the Advanced Test Reactor (ATR) housed at the Idaho National Laboratory (INL). The first series of tests has already been reported. These tests used miniaturized 17x17 PWR fuel geometry rodlets of second-generation FeCrAl alloys fueled with industrial Westinghouse UO2 fuel. These rodlets were encapsulated within a stainless steel housing.To provide high fidelity experiments and more robust testing, a new series of rodlets have been developed deemed the Accident Tolerant Fuel Experiment #1 Oak Ridge National Laboratory FCCI test (ATF-1 ORNL FCCI). The main driving factor, which is discussed in detail, was to provide a radiation environment where prototypical fuel-clad interface temperatures are met while still maintaining constant contact between industrial fuel and the candidate cladding alloys

  10. Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method

    SciTech Connect (OSTI)

    Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng

    2014-02-24

    In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.8439910{sup ?10} and 8.5988810{sup ?10} cm{sup 2} s{sup ?1}, respectively.

  11. Unique battery with an active membrane separator having uniform physico-chemically functionalized ion channels and a method making the same

    DOE Patents [OSTI]

    Gerald, II, Rex E.; Ruscic, Katarina J.; Sears, Devin N.; Smith, Luis J.; Klingler, Robert J.; Rathke, Jerome W.

    2012-02-21

    The invention relates to a unique battery having an active, porous membrane and method of making the same. More specifically the invention relates to a sealed battery system having a porous, metal oxide membrane with uniform, physicochemically functionalized ion channels capable of adjustable ionic interaction. The physicochemically-active porous membrane purports dual functions: an electronic insulator (separator) and a unidirectional ion-transporter (electrolyte). The electrochemical cell membrane is activated for the transport of ions by contiguous ion coordination sites on the interior two-dimensional surfaces of the trans-membrane unidirectional pores. The membrane material is designed to have physicochemical interaction with ions. Control of the extent of the interactions between the ions and the interior pore walls of the membrane and other materials, chemicals, or structures contained within the pores provides adjustability of the ionic conductivity of the membrane.

  12. Test Report : GS battery, EPC power HES RESCU.

    SciTech Connect (OSTI)

    Rose, David Martin; Schenkman, Benjamin L.; Borneo, Daniel R.

    2013-10-01

    The Department of Energy Office of Electricity (DOE/OE), Sandia National Laboratories (SNL) and the Base Camp Integration Lab (BCIL) partnered together to incorporate an energy storage system into a microgrid configured Forward Operating Base to reduce the fossil fuel consumption and to ultimately save lives. Energy storage vendors will be sending their systems to SNL Energy Storage Test Pad (ESTP) for functional testing and then to the BCIL for performance evaluation. The technologies that will be tested are electro-chemical energy storage systems comprising of lead acid, lithium-ion or zinc-bromide. GS Battery and EPC Power have developed an energy storage system that utilizes zinc-bromide flow batteries to save fuel on a military microgrid. This report contains the testing results and some limited analysis of performance of the GS Battery, EPC Power HES RESCU.

  13. Durathon Battery in New Bus | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    step in reducing the cost of clean fuel, zero emission buses, with a vehicle powered by GE's new Durathon(tm) battery in tandem with a lithium battery and a hydrogen fuel cell. ...

  14. Hydrogen Fuel for Material Handling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    p Hydrogen Fuel for Hydrogen Fuel for Material Handling Tom Joseph © Air Products & Chemicals, Inc., 2009 7201 Hamilton Blvd Allentown PA 18195 7201 Hamilton Blvd., Allentown PA 18195 Fuel Cell Packs for MHE Form Fit and Function Battery Replacement Form, Fit and Function Battery Replacement © Air Products & Chemicals, Inc., 2009 Courtesy of Ballard Power Systems 31.1 x 13.2 x 31.6 LWH MHE Classes and Pack size 4kW 9kW 14kW 4kW 9kW 14kW CLASS 1 Forklift 32 x 38.6 x 22.7" LWH CLASS

  15. Correlation of Lithium-Ion Battery Performance with Structural...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Correlation of Lithium-Ion Battery Performance with Structural and Chemical ... Specifically, the surfaces of lithium-ion battery electrodes evolve simultaneously with ...

  16. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect (OSTI)

    Dayton, David C

    2010-03-24

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested

  17. Process for the conversion of and aqueous biomass hydrolyzate into fuels or chemicals by the selective removal of fermentation inhibitors

    DOE Patents [OSTI]

    Hames, Bonnie R.; Sluiter, Amie D.; Hayward, Tammy K.; Nagle, Nicholas J.

    2004-05-18

    A process of making a fuel or chemical from a biomass hydrolyzate is provided which comprises the steps of providing a biomass hydrolyzate, adjusting the pH of the hydrolyzate, contacting a metal oxide having an affinity for guaiacyl or syringyl functional groups, or both and the hydrolyzate for a time sufficient to form an adsorption complex; removing the complex wherein a sugar fraction is provided, and converting the sugar fraction to fuels or chemicals using a microorganism.

  18. An Experimental and Chemical Kinetics Study of the Combustion of Syngas and High Hydrogen Content Fuels

    SciTech Connect (OSTI)

    Santoro, Robers; Dryer, Frederick; Ju, Yiguang

    2013-09-30

    An integrated and collaborative effort involving experiments and complementary chemical kinetic modeling investigated the effects of significant concentrations of water and CO2 and minor contaminant species (methane [CH4], ethane [C2H6], NOX, etc.) on the ignition and combustion of HHC fuels. The research effort specifically addressed broadening the experimental data base for ignition delay, burning rate, and oxidation kinetics at high pressures, and further refinement of chemical kinetic models so as to develop compositional specifications related to the above major and minor species. The foundation for the chemical kinetic modeling was the well validated mechanism for hydrogen and carbon monoxide developed over the last 25 years by Professor Frederick Dryer and his co-workers at Princeton University. This research furthered advance the understanding needed to develop practical guidelines for realistic composition limits and operating characteristics for HHC fuels. A suite of experiments was utilized that that involved a high-pressure laminar flow reactor, a pressure-release type high-pressure combustion chamber and a high-pressure turbulent flow reactor.

  19. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  20. Chemical reactivity testing for the National Spent Nuclear Fuel Program. Revision 2

    SciTech Connect (OSTI)

    Koester, L.W.

    2000-02-08

    This quality assurance project plan (QAPjP) summarizes requirements used by Lockheed Martin Energy Systems, Incorporated (LMES) Development Division at Y-12 for conducting chemical reactivity testing of Department of Energy (DOE) owned spent nuclear fuel, sponsored by the National Spent Nuclear Fuel Program (NSNFP). The requirements are based on the NSNFP Statement of work PRO-007 (Statement of Work for Laboratory Determination of Uranium Hydride Oxidation Reaction Kinetics.) This QAPjP will utilize the quality assurance program at Y-12, Y60-101PD, Quality Program Description, and existing implementing procedures for the most part in meeting the NSNFP Statement of Work PRO-007 requirements, exceptions will be noted. The project consists of conducting three separate series of related experiments, ''Passivation of Uranium Hydride Powder With Oxygen and Water'', '''Passivation of Uranium Hydride Powder with Surface Characterization'', and ''Electrochemical Measure of Uranium Hydride Corrosion Rate''.

  1. Nanoscale Imaging of Fundamental Li Battery Chemistry: Solid...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: catalysis (heterogeneous), solar (fuels), energy storage (including batteries and capacitors), hydrogen and fuel ...

  2. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  3. Soluble Lead Flow Battery: Soluble Lead Flow Battery Technology

    SciTech Connect (OSTI)

    2010-09-01

    GRIDS Project: General Atomics is developing a flow battery technology based on chemistry similar to that used in the traditional lead-acid battery found in nearly every car on the road today. Flow batteries store energy in chemicals that are held in tanks outside the battery. When the energy is needed, the chemicals are pumped through the battery. Using the same basic chemistry as a traditional battery but storing its energy outside of the cell allows for the use of very low cost materials. The goal is to develop a system that is far more durable than today’s lead-acid batteries, can be scaled to deliver megawatts of power, and which lowers the cost of energy storage below $100 per kilowatt hour.

  4. Development of Diffusion barrier coatings and Deposition Technologies for Mitigating Fuel Cladding Chemical Interactions (FCCI)

    SciTech Connect (OSTI)

    Sridharan, Kumar; Allen, Todd; Cole, James

    2013-02-27

    The goal of this project is to develop diffusion barrier coatings on the inner cladding surface to mitigate fuel-cladding chemical interaction (FCCI). FCCI occurs due to thermal and radiation enhanced inter-diffusion between the cladding and fuel materials, and can have the detrimental effects of reducing the effective cladding wall thickness and lowering the melting points of the fuel and cladding. The research is aimed at the Advanced Burner Reactor (ABR), a sodium-cooled fast reactor, in which higher burn-ups will exacerbate the FCCI problem. This project will study both diffusion barrier coating materials and deposition technologies. Researchers will investigate pure vanadium, zirconium, and titanium metals, along with their respective oxides, on substrates of HT-9, T91, and oxide dispersion-strengthened (ODS) steels; these materials are leading candidates for ABR fuel cladding. To test the efficacy of the coating materials, the research team will perform high-temperature diffusion couple studies using both a prototypic metallic uranium fuel and a surrogate—the rare-earth element lanthanum. Ion irradiation experiments will test the stability of the coating and the coating-cladding interface. A critical technological challenge is the ability to deposit uniform coatings on the inner surface of cladding. The team will develop a promising non-line-of-sight approach that uses nanofluids . Recent research has shown the feasibility of this simple yet novel approach to deposit coatings on test flats and inside small sections of claddings. Two approaches will be investigated: 1) modified electrophoretic deposition (MEPD) and 2) boiling nanofluids. The coatings will be evaluated in the as-deposited condition and after sintering.

  5. Battery system

    DOE Patents [OSTI]

    Dougherty, Thomas J; Wood, Steven J; Trester, Dale B; Andrew, Michael G

    2013-08-27

    A battery module includes a plurality of battery cells and a system configured for passing a fluid past at least a portion of the plurality of battery cells in a parallel manner.

  6. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Chemical Reactions That lithium-ion batteries lose their ... Simulation and Experiment Sandia's BATLab is a leading facility for investigating and understanding battery ...

  7. Direct measurement of the chemical reactivity of silicon electrodes with LiPF6-based battery electrolytes

    SciTech Connect (OSTI)

    Veith, Gabriel M; Baggetto, Loic; Sacci, Robert L; Unocic, Raymond R; Tenhaeff, Wyatt E; Browning, Jim

    2014-01-01

    We report the first direct measurement of the chemistry and extent of reactivity between a lithium ion battery electrode surface (Si) and a liquid electrolyte (1.2M LiPF6-3:7 wt% ethylene carbonate:dimethyl carbonate). This layer is estimated to be 3.6 nm thick and partially originates from the consumption of the silicon surface.

  8. Alternative fuels and chemicals from synthesis gas. Quarterly status report number 2, 1 January--31 March 1995

    SciTech Connect (OSTI)

    1995-12-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit. Results are discussed for the following tasks: liquid phase hydrodynamic run; catalyst activation with CO; new processes for DME (dehydration catalyst screening runs, and experiments using Robinson-Mahoney basket internal and pelletized catalysts); new fuels from DME; and new processes for alcohols and oxygenated fuel additives.

  9. Slurry-Based Chemical Hydrogen Storage Systems for Automotive Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Semelsberger, Troy; Simmons, Kevin L.; Van Hassel, Bart A.

    2014-05-30

    In this paper, the system designs for hydrogen storage using chemical hydrogen materials in an 80 kWe fuel cell, light-duty vehicle are described. Ammonia borane and alane are used for these designs to represent the general classes of exothermic and endothermic materials. The designs are then compared to the USDRIVE/DOE developed set of system level targets for on-board storage. While most of the DOE targets are predicted to be achieved based on the modeling, the system gravimetric and volumetric densities were more challenging and became the focus of this work. The resulting system evaluation determined that the slurry is majority of the system mass. Only modest reductions in the system mass can be expected with improvements in the balance of plant components. Most of the gravimetric improvements will require developing materials with higher inherent storage capacity or by increasing the solids loading of the chemical hydrogen storage material in the slurry.

  10. Nanoelectrofuels for Flow Batteries | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoelectrofuels for Flow Batteries Four-page technical brochure about Argonne's high-density rechargeable liquid fuel PDF icon esnanoelectrofuels-broch-tech...

  11. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    Thin-Film Battery with Lithium Anode Courtesy of Oak Ridge National Laboratory, Materials Science and Technology Division Lithium Batteries Resources with Additional Information...

  12. Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Curran, H J; Mehl, M

    2008-12-15

    Detailed chemical kinetic models are needed to simulate the combustion of current and future transportation fuels. These models should represent the various chemical classes in these fuels. Conventional diesel fuels are composed of n-alkanes, iso-alkanes, cycloalkanes and aromatics (Farrell et al. 2007). For future fuels, there is a renewed interest in Fischer-Tropsch (F-T) processes which can be used to synthesize diesel and other transportation fuels from biomass, coal and natural gas. F-T diesel fuels are expected to be similar to F-T jet fuels which are commonly comprised of iso-alkanes with some n-alkanes (Smith and Bruno, 2008). Thus, n-alkanes and iso-alkanes are common chemical classes in these conventional and future fuels. This paper reports on the development of chemical kinetic models of large n-alkanes and iso-alkanes to represent these chemical classes in conventional and future fuels. Two large iso-alkanes are 2,2,4,4,6,8,8-heptamethylnonane, which is a primary reference fuel for diesel, and isooctane, a primary reference fuel for gasoline. Other iso-alkanes are branched alkanes with a single methyl side chain, typical of most F-T fuels. The chemical kinetic models are then used to predict the effect of these fuel components on ignition characteristics under conditions found in internal combustion engines.

  13. Detailed Chemical Kinetic Reaction Mechanisms for Primary Reference Fuels for Diesel Cetane Number and Spark-Ignition Octane Number

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Mehl, M; Curran, H J

    2010-03-03

    For the first time, a detailed chemical kinetic reaction mechanism is developed for primary reference fuel mixtures of n-hexadecane and 2,2,4,4,6,8,8-heptamethyl nonane for diesel cetane ratings. The mechanisms are constructed using existing rules for reaction pathways and rate expressions developed previously for the primary reference fuels for gasoline octane ratings, n-heptane and iso-octane. These reaction mechanisms are validated by comparisons between computed and experimental results for shock tube ignition and for oxidation under jet-stirred reactor conditions. The combined kinetic reaction mechanism contains the submechanisms for the primary reference fuels for diesel cetane ratings and submechanisms for the primary reference fuels for gasoline octane ratings, all in one integrated large kinetic reaction mechanism. Representative applications of this mechanism to two test problems are presented, one describing fuel/air autoignition variations with changes in fuel cetane numbers, and the other describing fuel combustion in a jet-stirred reactor environment with the fuel varying from pure 2,2,4,4,6,8,8-heptamethyl nonane (Cetane number of 15) to pure n-hexadecane (Cetane number of 100). The final reaction mechanism for the primary reference fuels for diesel fuel and gasoline is available on the web.

  14. Thermochemical Conversion of Woody Biomass to Fuels and Chemicals Final Report

    SciTech Connect (OSTI)

    Pendse, Hemant P.

    2015-09-30

    Maine and its industries identified more efficient utilization of biomass as a critical economic development issue. In Phase I of this implementation project, a research team was assembled, research equipment was implemented and expertise was demonstrated in pyrolysis, hydrodeoxygenation of pyrolysis oils, catalyst synthesis and characterization, and reaction engineering. Phase II built upon the infrastructure to innovate reaction pathways and process engineering, and integrate new approaches for fuels and chemical production within pulp and paper and other industries within the state. This research cluster brought together chemists, engineers, physicists and students from the University of Maine, Bates College, and Bowdoin College. The project developed collaborations with Oak Ridge National Laboratory and Brookhaven National Laboratory. The specific research projects within this proposal were of critical interest to the DoE - in particular the biomass program within EERE and the catalysis/chemical transformations program within BES. Scientific and Technical Merit highlights of this project included: (1) synthesis and physical characterization of novel size-selective catalyst/supports using engineered mesoporous (1-10 nm diameter pores) materials, (2) advances in fundamental knowledge of novel support/ metal catalyst systems tailored for pyrolysis oil upgrading, (3) a microcalorimetric sensing technique, (4) improved methods for pyrolysis oil characterization, (5) production and characterization of woody biomass-derived pyrolysis oils, (6) development of two new patented bio oil pathways: thermal deoxygenation (TDO) and formate assisted pyrolysis (FASP), and (7) technoeconomics of pyrolysis of Maine forest biomass. This research cluster has provided fundamental knowledge to enable and assess pathways to thermally convert biomass to hydrocarbon fuels and chemicals.

  15. Mapping Particle Charges in Battery Electrodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The deceivingly simple appearance of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion...

  16. Applications of high-temperature solar heat to the production of selected fuels and chemicals

    SciTech Connect (OSTI)

    Beall, S.E. Jr.; Bamberger, C.E.; Goeller, H.A.

    1981-07-01

    An attempt is made to judge whether solar heat in the 500 K to 2500 K temperature range might be economical for some important fuel- and chemical-production processes. Previous work in related areas is reviewed and the chemicals aluminum oxide (and bauxite), calcium sulfate (and gypsum), and calcium oxide (lime) chosen for detailed study. In addition to reviewing the energy needs of the more common bulk chemicals, several innovative processes requiring heat in the 1500 to 2500 K range were investigated. Hydrogen production by several thermochemical means, carbon monoxide production by thermochemical and direct thermal dissociation, and nitrogen fixation by direct thermal reaction of nitrogen and oxygen in air were considered. The engineering feasibility of the processes is discussed. The problem of matching the conventional and innovative processes to a high-temperature solar supply is studied. Some solar-thermal power plants of current designs are examined and several advanced concepts of highly concentrating systems are considered for very high-temperature applications. Conclusions and recommendations are presented.

  17. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2010-05-15

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet-stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines. (author)

  18. Radiant flash pyrolysis of biomass as a source of fuels and chemicals

    SciTech Connect (OSTI)

    Antal, M.J. Jr.; Hofman, L.; Moreira, J.R.

    1980-01-01

    Last year a team of US and French scientists using the Odeillo (France) 1MW/sub th/ solar furnace showed concentrated solar radiation to be an effective means for rapidly volatilizing biomass materials. The results of continuing research in the U.S. on radiant flash pyrolysis of biomass as a source of fluid fuels, industrial feedstocks and chemicals are described. Bench scale sources of intense, visible radiant energy have been used to simulate the concentrated solar flux available at the focus of solar towers. Windowed transport reactors are being developed, which act as cavity receivers for the focused radiant energy and provide a means for direct use of the radiation to rapidly pyrolyze the entering biomass. One of these reactors will be operated at the focus of the Georgia Tech 400kW/sub th/ solar furnace next August. Preliminary results from the bench scale reactor experiments, and plans for the Georgia Tech experiments are detailed.

  19. Process for hydrocracking carbonaceous material to provide fuels or chemical feed stock

    DOE Patents [OSTI]

    Duncan, Dennis A.

    1980-01-01

    A process is disclosed for hydrocracking coal or other carbonaceous material to produce various aromatic hydrocarbons including benzene, toluene, xylene, ethylbenzene, phenol and cresols in variable relative concentrations while maintaining a near constant maximum temperature. Variations in relative aromatic concentrations are achieved by changing the kinetic severity of the hydrocracking reaction by altering the temperature profile up to and quenching from the final hydrocracking temperature. The relative concentration of benzene to the alkyl and hydroxyl aromatics is increased by imposing increased kinetic severity above that corresponding to constant heating rate followed by immediate quenching at about the same rate to below the temperature at which dehydroxylation and dealkylation reactions appreciably occur. Similarly phenols, cresols and xylenes are produced in enhanced concentrations by adjusting the temperature profile to provide a reduced kinetic severity relative to that employed when high benzene concentrations are desired. These variations in concentrations can be used to produce desired materials for chemical feed stocks or for fuels.

  20. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2009-07-21

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

  1. Chemical Engineering Division fuel cycle programs. Quarterly progress report, October-December 1978

    SciTech Connect (OSTI)

    Steindler, M J; Ader, M; Barletta, R E

    1980-01-01

    In the program on pyrochemical and dry processing methods (PDPM) for nuclear fuel, tungsten crucibles were successfully spun for use in laboratory-scale experiments. Corrosion testing of refractory metals and alloys in PDPM environments was done. Ceramic substrates were successfully coated with tungsten. Solubility measurements were made to determine Cd/Mg alloy composition and temperature at which dissolved Th will precipitate. Experiments were started to study the reduction of high-fired ThO/sub 2/ with Ca in a molten metal-molten salt system. Work on the fused salt electrolysis of CaO was started. Equipment for determining phase diagrams for U-Cu-Mg system was set up. The reaction of UO/sub 2/ with molten equimolar NaNO/sub 3/-KNO/sub 3/ was studied as part of a project to identify chemically feasible nonaqueous fuel reprocessing methods. Work was continued on development of a flowsheet for reprocessing actinide oxides by extracting actinides into ammonium chloro-aluminate (and alternative salts) from a bismuth solution. Preparation of Th, U, and Pu nitrides after dissolution of spent fuel elements in molten tin is being studied. Leach rates of glass beads, pulverized beads, and beads encapsulated in a lead matrix with no protective envelope were studied. A method (employing no pressure or vacuum systems) of encapsulating various solid wastes in a lead metal matrix was developed and tested. A preliminary integration was made of earlier data on effects of impacts on metal-matrix waste forms.Leach migration experiments were compared with conventional infiltration experiments as methods of evaluating geologic formations as barriers to nuclide migration. The effect of the streaming potential on the rates of transport of radioactive I/sup -/ and Na/sup +/ through kaolinite columns was measured, as well as adsorption of iodide and iodate by several compounds; implications of the results upon the disposal of radioactive iodine are discussed.

  2. Benefits analysis for the production of fuels and chemicals using solar thermal energy. Final report

    SciTech Connect (OSTI)

    1982-05-01

    Numerous possibilities exist for using high temperature solar thermal energy in the production of various chemicals and fuels (Sun Fuels). Research and development activities have focused on the use of feedstocks such as coal and biomass to provide synthesis gas, hydrogen, and a variety of other end-products. A Decision Analysis technique geared to the analysis of Sun Fuels options was developed. Conventional scoring methods were combined with multi-attribute utility analysis in a new approach called the Multi-Attribute Preference Scoring (MAPS) system. MAPS calls for the designation of major categories of attributes which describe critical elements of concern for the processes being examined. The six major categories include: Process Demonstration; Full-Scale Process, Feedstock; End-Product Market; National/Social Considerations; and Economics. MAPS calls for each attribute to be weighted on a simple scale for all of the candidate processes. Next, a weight is assigned to each attribute, thus creating a multiplier to be used with each individual value to derive a comparative weighting. Last, each of the categories of attributes themselves are weighted, thus creating another multiplier, for use in developing an overall score. With sufficient information and industry input, each process can be ultimately compared using a single figure of merit. After careful examination of available information, it was decided that only six of the 20 candidate processes were adequately described to allow a complete MAPS analysis which would allow direct comparisons for illustrative purposes. These six processes include three synthesis gas processes, two hydrogen and one ammonia. The remaining fourteen processes were subjected to only a partial MAPS assessment.

  3. PHEV Battery Cost Assessment | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Cost Assessment PHEV Battery Cost Assessment 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es111_gallagher_2012_o.pdf (1.1 MB) More Documents & Publications Promises and Challenges of Lithium- and Manganese-Rich Transition-Metal Layered-Oxide Cathodes PHEV Battery Cost Assessment EV Everywhere Grand Challenge - Battery Status and Cost Reduction Prospects

  4. Fifteenth symposium on biotechnology for fuels and chemicals: Program and abstracts

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This collection contains 173 abstracts from presented papers and poster sessions. The five sessions of the conference were on the subjects of: (1) Thermal, Chemical, and Biological Processing, (2) Applied Biological Research, (3) Bioprocessing Research (4), Process Economics and Commercialization, and (5) Environmental Biotechnology. Examples of specific topics in the first session include the kinetics of ripening cheese, microbial liquefaction of lignite, and wheat as a feedstock for fuel ethanol. Typical topics in the second session were synergism studies of bacterial and fungal celluloses, conversion of inulin from jerusalem artichokes to sorbitol and ethanol by saccharomyces cerevisiae, and microbial conversion of high rank coals to methane. The third session entertained topics such as hydrodynamic modeling of a liquid fluidized bed bioreactor for coal biosolubilization, aqueous biphasic systems for biological particle partitioning, and arabinose utilization by xylose-fermenting yeast and fungi. The fourth session included such topics as silage processing of forage biomass to alcohol fuels, economics of molasses to ethanol in India, and production of lactic acid from renewable resources. the final session contained papers on such subjects as bioluminescent detection of contaminants in soils, characterization of petroleum contaminated soils in coral atolls in the south Pacific, and landfill management for methane generation and emission control.

  5. Detailed chemical kinetic models for large n-alkanes and iso-alkanes found in conventional and F-T diesel fuels

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Mehl, M; Curran, H J

    2009-03-09

    n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for both primary reference fuels, a new capability is now available to model diesel fuel ignition. Additionally, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. These chemical kinetic models are used to predict the effect of the aforementioned fuel components on ignition characteristics under conditions found in internal combustion engines.

  6. Lithium-Ion Batteries - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Energy Analysis Energy Analysis Find More Like This Return to Search Lithium-Ion Batteries Predictive computer models for lithium-ion battery performance under standard and potentially abusive conditions National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Design. Build. Test. Break. Repeat. Developing batteries is an expensive and time-intensive process. Testing costs the

  7. Microwave Plasma Chemical Vapor Deposition of Nano-Structured Sn/C Composite Thin-Film Anodes for Li-ion Batteries

    SciTech Connect (OSTI)

    Stevenson, Cynthia; Marcinek, M.; Hardwick, L.J.; Richardson, T.J.; Song, X.; Kostecki, R.

    2008-02-01

    In this paper we report results of a novel synthesis method of thin-film composite Sn/C anodes for lithium batteries. Thin layers of graphitic carbon decorated with uniformly distributed Sn nanoparticles were synthesized from a solid organic precursor Sn(IV) tert-butoxide by a one step microwave plasma chemical vapor deposition (MPCVD). The thin-film Sn/C electrodes were electrochemically tested in lithium half cells and produced a reversible capacity of 440 and 297 mAhg{sup -1} at C/25 and 5C discharge rates, respectively. A long term cycling of the Sn/C nanocomposite anodes showed 40% capacity loss after 500 cycles at 1C rate.

  8. Development of Geothermally Assisted Process for Production of Liquid Fuels and Chemicals from Wheat Straw

    SciTech Connect (OSTI)

    Murphy, V.G.; Linden, J.C.; Moreira, A.R.; Lenz, T.G.

    1981-06-01

    Recently there has been much interest in developing processes for producing liquid fuels from renewable resources. The most logical long term approach in terms of economics derives the carbohydrate substrate for fermentation from the hydrolysis of cellulosic crop and forest residues rather than from grains or other high grade food materials (1,2). Since the presence of lignin is the main barrier to the hydrolysis of cellulose from lignocellulosic materials, delignification processes developed by the wood pulping industry have been considered as possible prehydrolysis treatments. The delignification process under study in our laboratory is envisioned as a synthesis of two recently developed pulping processes. In the first step, called autohydrolysis, hot water is used directly to solubilize hemicellulose and to depolymerize lignin (3). Then, in a second step known as organosolv pulping (4), the autohydrolyzed material is extracted with aqueous alcohol. A s shown in Figure 1, this process can separate the original lignocellulosic material into three streams--hemicellulose in water, lignin in aqueous alcohol, and a cellulose pulp. Without further mechanical milling, delignified cellulose can be enzymatically hydrolyzed at 45-50 C to greater than 80% theoretical yield of glucose using fungal cellulases (5, 6). The resulting glucose syrup can then be fermented by yeast to produce ethanol or by selected bacteria to produce acetone and butanol or acetic and propionic acids (7). One objection to such a process, however, is the large energy input that is required. In order to extend our supplies of liquid fuels and chemicals, it is important that the use of fossil fuels in any lignocellulosic conversion process be minimized. The direct use of geothermal hot water in carrying out the autohydrolysis and extraction operations, therefore, seems especially attractive. On the one hand, it facilitates the conversion of non-food biomass to fuels and chemicals without wasting fossil

  9. Heavy Duty Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel ... Laser enters piston bowl through windows in cylinder wall (not shown) and piston bowl-rim. ...

  10. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    information about thin-film lithium batteries is available in full-text and on the Web. ... Additional Web Pages: Thin Films for Advanced Batteries Thin-Film Rechargeable Lithium, ...

  11. Initial evaluation of dry storage issues for spent nuclear fuels in wet storage at the Idaho Chemical Processing Plant

    SciTech Connect (OSTI)

    Guenther, R.J.; Johnson, A.B. Jr.; Lund, A.L.; Gilbert, E.R.

    1996-07-01

    The Pacific Northwest Laboratory has evaluated the basis for moving selected spent nuclear fuels in the CPP-603 and CPP-666 storage pools at the Idaho Chemical Processing Plant from wet to dry interim storage. This work is being conducted for the Lockheed Idaho Technologies Company as part of the effort to determine appropriate conditioning and dry storage requirements for these fuels. These spent fuels are from 22 test reactors and include elements clad with aluminum or stainless steel and a wide variety of fuel materials: UAl{sub x}, UAl{sub x}-Al and U{sub 3}O{sub 8}-Al cermets, U-5% fissium, UMo, UZrH{sub x}, UErZrH, UO{sub 2}-stainless steel cermet, and U{sub 3}O{sub 8}-stainless steel cermet. The study also included declad uranium-zirconium hydride spent fuel stored in the CPP-603 storage pools. The current condition and potential failure mechanisms for these spent fuels were evaluated to determine the impact on conditioning and dry storage requirements. Initial recommendations for conditioning and dry storage requirements are made based on the potential degradation mechanisms and their impacts on moving the spent fuel from wet to dry storage. Areas needing further evaluation are identified.

  12. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  13. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  14. Physical and chemical comparison of soot in hydrocarbon and biodiesel fuel diffusion flames: A study of model and commercial fuels

    SciTech Connect (OSTI)

    Matti Maricq, M.

    2011-01-15

    Data are presented to compare soot formation in both surrogate and practical fatty acid methyl ester biodiesel and petroleum fuel diffusion flames. The approach here uses differential mobility analysis to follow the size distributions and electrical charge of soot particles as they evolve in the flame, and laser ablation particle mass spectrometry to elucidate their composition. Qualitatively, these soot properties exhibit a remarkably similar development along the flames. The size distributions begin as a single mode of precursor nanoparticles, evolve through a bimodal phase marking the onset of aggregate formation, and end in a self preserving mode of fractal-like particles. Both biodiesel and hydrocarbon fuels yield a common soot composition dominated by C{sub x}H{sub y}{sup +} ions, stabilomer PAHs, and fullerenes in the positive ion mass spectrum, and C{sub x}{sup -} and C{sub 2x}H{sup -} in the negative ion spectrum. These ion intensities initially grow with height in the diffusion flames, but then decline during later stages, consistent with soot carbonization. There are important quantitative differences between fuels. The surrogate biodiesel fuel methyl butanoate substantially reduces soot levels, but soot formation and evolution in this flame are delayed relative to both soy and petroleum fuels. In contrast, soots from soy and hexadecane flames exhibit nearly quantitative agreement in their size distribution and composition profiles with height, suggesting similar soot precursor chemistry. (author)

  15. Battery Charger Efficiency

    Energy Savers [EERE]

    Battery Chargers Marine and RV battery chargers differ from power tool and small appliance chargers CEC Testing assumes all variables are known - battery chemistry, battery size. ...

  16. Life-cycle cost comparisons of advanced storage batteries and fuel cells for utility, stand-alone, and electric vehicle applications

    SciTech Connect (OSTI)

    Humphreys, K.K.; Brown, D.R.

    1990-01-01

    This report presents a comparison of battery and fuel cell economics for ten different technologies. To develop an equitable economic comparison, the technologies were evaluated on a life-cycle cost (LCC) basis. The LCC comparison involved normalizing source estimates to a standard set of assumptions and preparing a lifetime cost scenario for each technology, including the initial capital cost, replacement costs, operating and maintenance (O M) costs, auxiliary energy costs, costs due to system inefficiencies, the cost of energy stored, and salvage costs or credits. By considering all the costs associated with each technology over its respective lifetime, the technology that is most economical to operate over any given period of time can be determined. An analysis of this type indicates whether paying a high initial capital cost for a technology with low O M costs is more or less economical on a lifetime basis than purchasing a technology with a low initial capital cost and high O M costs. It is important to realize that while minimizing cost is important, the customer will not always purchase the least expensive technology. The customer may identify benefits associated with a more expensive option that make it the more attractive over all (e.g., reduced construction lead times, modularity, environmental benefits, spinning reserve, etc.). The LCC estimates presented in this report represent three end-use applications: utility load-leveling, stand-alone power systems, and electric vehicles.

  17. Improving Fuel Cell Electrodes Two-Steps at a Time > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  18. Co-Optimization of Fuels and Engines (Co-Optima) -- Fuel Properties and Chemical Kinetics and Thrust I Engine Projects

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation does not contain any proprietary, confidential, or otherwise restricted information #$%&'"(")*+,"!" Co-Optimization of Fuels and Engines Fuel Property Team -./0+,"12"345.+67489 ! "!"#$%&"'('#") * %+",%-./0"12) 3 %4",%5$/1) 6 %7$89%:"9;1) <% :$=%:>?;#9/) @ %5"99%7"2.) @ %+'#%A8;>B;) * %:$=%C$2>9"D) * %5($E%F"G9;() * %->'=%!'9E10'('8GH I % *J!

  19. Development and Validation of a Slurry Model for Chemical Hydrogen Storage in Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Pires, Richard P.; Simmons, Kevin L.

    2014-07-25

    The US Department of Energy's (DOE) Hydrogen Storage Engineering Center of Excellence (HSECoE) is developing models for hydrogen storage systems for fuel cell-based light duty vehicle applications for a variety of promising materials. These transient models simulate the performance of the storage system for comparison to the DOE’s Technical Targets and a set of four drive cycles. The purpose of this research is to describe the models developed for slurry-based chemical hydrogen storage materials. The storage systems of both a representative exothermic system based on ammonia borane and endothermic system based on alane were developed and modeled in Simulink®. Once complete the reactor and radiator components of the model were validated with experimental data. The model was then run using a highway cycle, an aggressive cycle, cold-start cycle and hot drive cycle. The system design was adjusted to meet these drive cycles. A sensitivity analysis was then performed to identify the range of material properties where these DOE targets and drive cycles could be met. Materials with a heat of reaction greater than 11 kJ/mol H2 generated and a slurry hydrogen capacity of greater than 11.4% will meet the on-board efficiency and gravimetric capacity targets, respectively.

  20. Systems Modeling of Chemical Hydride Hydrogen Storage Materials for Fuel Cell Applications

    SciTech Connect (OSTI)

    Brooks, Kriston P.; Devarakonda, Maruthi N.; Rassat, Scot D.; Holladay, Jamelyn D.

    2011-10-05

    A fixed bed reactor was designed, modeled and simulated for hydrogen storage on-board the vehicle for PEM fuel cell applications. Ammonia Borane (AB) was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to {approx}16% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. The design evaluated consisted of a tank with 8 thermally isolated sections in which H2 flows freely between sections to provide ballast. Heating elements are used to initiate reactions in each section when pressure drops below a specified level in the tank. Reactor models in Excel and COMSOL were developed to demonstrate the proof-of-concept, which was then used to develop systems models in Matlab/Simulink. Experiments and drive cycle simulations showed that the storage system meets thirteen 2010 DOE targets in entirety and the remaining four at greater than 60% of the target.

  1. Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters- Fact Sheet 2014

    Broader source: Energy.gov [DOE]

    Fact sheet summarizing a project to develop and demonstrate a full-scale fuel handling and combustion system

  2. NREL: Hydrogen and Fuel Cells Research - Early Fuel Cell Market

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrations Early Fuel Cell Market Demonstrations Photo of fuel cell backup power system in outdoor setting. Photo of fuel cell forklifts in warehouse setting. Fuel cell backup power systems offer longer continuous runtimes and greater durability than traditional batteries in harsh outdoor environments. For specialty vehicles such as forklifts, fuel cells can be a cost-competitive alternative to traditional lead-acid batteries. Learn More Subscribe to the biannual Fuel Cell and Hydrogen

  3. Battery Charger Efficiency

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Battery Charger Efficiency Issues with Marine and Recreational Vehicle Battery Chargers Marine and RV battery chargers differ from power tool and small appliance chargers CEC Testing assumes all variables are known - battery chemistry, battery size. This is not the case in Marine and RV applications. * The battery charger manufacturer has no influence on the selection of batteries. * The battery charger could be used to charge a single battery, single battery bank, multiple batteries or multiple

  4. Historic American Engineering Record, Idaho National Laboratory, Idaho Chemical Processing Plant, Fuel Reprocessing Complex

    SciTech Connect (OSTI)

    Susan Stacy; Julie Braun

    2006-12-01

    Just as automobiles need fuel to operate, so do nuclear reactors. When fossil fuels such as gasoline are burned to power an automobile, they are consumed immediately and nearly completely in the process. When the fuel is gone, energy production stops. Nuclear reactors are incapable of achieving this near complete burn-up because as the fuel (uranium) that powers them is burned through the process of nuclear fission, a variety of other elements are also created and become intimately associated with the uranium. Because they absorb neutrons, which energize the fission process, these accumulating fission products eventually poison the fuel by stopping the production of energy from it. The fission products may also damage the structural integrity of the fuel elements. Even though the uranium fuel is still present, sometimes in significant quantities, it is unburnable and will not power a reactor unless it is separated from the neutron-absorbing fission products by a method called fuel reprocessing. Construction of the Fuel Reprocessing Complex at the Chem Plant started in 1950 with the Bechtel Corporation serving as construction contractor and American Cyanamid Company as operating contractor. Although the Foster Wheeler Corporation assumed responsibility for the detailed working design of the overall plant, scientists at Oak Ridge designed all of the equipment that would be employed in the uranium separations process. After three years of construction activity and extensive testing, the plant was ready to handle its first load of irradiated fuel.

  5. Catalytic Upgrading of Thermochemical Intermediates to Hydrocarbons: Conversion of Lignocellulosic Feedstocks to Aromatic Fuels and High Value Chemicals

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 May, 2013 Technology Area Review: Thermochemical Conversion Randy Cortright PhD Virent, Inc WBS: 3.3.1.10 This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement Project Goal -Develop and demonstrate integration of Virent's lignocellulosic biomass solvolysis technology with Virent's BioForming® process to generate aromatic-rich hydrocarbon products for use in either fuels or chemicals applications.  Liquefaction of Biomass and

  6. Lithium Batteries

    Office of Scientific and Technical Information (OSTI)

    This greatly expands the potential medical uses of the batteries, including transdermal applications for heart regulation.' -Edited excerpt from Medical Applications of Non-medical ...

  7. Vehicle Technologies Office Merit Review 2015: Battery Safety Testing

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about battery safety...

  8. Vehicle Technologies Office Merit Review 2014: Battery Safety Testing

    Broader source: Energy.gov [DOE]

    Presentation given by Sandia National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about battery safety...

  9. Vehicle Technologies Office Merit Review 2014: Battery Thermal Characterization

    Broader source: Energy.gov [DOE]

    Presentation given by NREL at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about battery thermal characterization.

  10. Vehicle Technologies Office Merit Review 2015: Battery Thermal Characterization

    Broader source: Energy.gov [DOE]

    Presentation given by National Renewable Energy Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about battery...

  11. Batteries for Large Scale Energy Storage

    SciTech Connect (OSTI)

    Soloveichik, Grigorii L.

    2011-07-15

    In recent years, with the deployment of renewable energy sources, advances in electrified transportation, and development in smart grids, the markets for large-scale stationary energy storage have grown rapidly. Electrochemical energy storage methods are strong candidate solutions due to their high energy density, flexibility, and scalability. This review provides an overview of mature and emerging technologies for secondary and redox flow batteries. New developments in the chemistry of secondary and flow batteries as well as regenerative fuel cells are also considered. Advantages and disadvantages of current and prospective electrochemical energy storage options are discussed. The most promising technologies in the short term are high-temperature sodium batteries with β”-alumina electrolyte, lithium-ion batteries, and flow batteries. Regenerative fuel cells and lithium metal batteries with high energy density require further research to become practical.

  12. KAir Battery

    Broader source: Energy.gov [DOE]

    KAir Battery, from Ohio State University, is commercializing highly energy efficient cost-effective potassium air batteries for use in the electrical stationary storage systems market (ESSS). Beyond, the ESSS market potential applications range from temporary power stations and electric vehicle.

  13. Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery

    Broader source: Energy.gov (indexed) [DOE]

    Manufacturing Grants | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es098_johnson_2011_o.pdf (1.22 MB) More Documents & Publications Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grants Vehicle Technologies Office: 2010 Energy Storage R&D Annual Progress Report Perfluoro Aryl Boronic Esters as Chemical Shuttle Additives

  14. Models for Battery Reliability and Lifetime

    SciTech Connect (OSTI)

    Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G. H.; Neubauer, J.; Pesaran, A.

    2014-03-01

    Models describing battery degradation physics are needed to more accurately understand how battery usage and next-generation battery designs can be optimized for performance and lifetime. Such lifetime models may also reduce the cost of battery aging experiments and shorten the time required to validate battery lifetime. Models for chemical degradation and mechanical stress are reviewed. Experimental analysis of aging data from a commercial iron-phosphate lithium-ion (Li-ion) cell elucidates the relative importance of several mechanical stress-induced degradation mechanisms.

  15. Circulating current battery heater

    DOE Patents [OSTI]

    Ashtiani, Cyrus N.; Stuart, Thomas A.

    2001-01-01

    A circuit for heating energy storage devices such as batteries is provided. The circuit includes a pair of switches connected in a half-bridge configuration. Unidirectional current conduction devices are connected in parallel with each switch. A series resonant element for storing energy is connected from the energy storage device to the pair of switches. An energy storage device for intermediate storage of energy is connected in a loop with the series resonant element and one of the switches. The energy storage device which is being heated is connected in a loop with the series resonant element and the other switch. Energy from the heated energy storage device is transferred to the switched network and then recirculated back to the battery. The flow of energy through the battery causes internal power dissipation due to electrical to chemical conversion inefficiencies. The dissipated power causes the internal temperature of the battery to increase. Higher internal temperatures expand the cold temperature operating range and energy capacity utilization of the battery. As disclosed, either fixed frequency or variable frequency modulation schemes may be used to control the network.

  16. Polymers For Advanced Lithium Batteries | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es088_balsara_2011_o.pdf (682.79 KB) More Documents & Publications Development of Polymer Electrolytes for Advanced Lithium Batteries Polymers For Advanced Lithium Batteries Polymer Electrolytes for Advanced Lithium Batteries

  17. Detailed Chemical Kinetic Modeling of Surrogate Fuels for Gasoline and Application to an HCCI Engine

    SciTech Connect (OSTI)

    Naik, C V; Pitz, W J; Sj?berg, M; Dec, J E; Orme, J; Curran, H J; Simmie, J M; Westbrook, C K

    2005-01-07

    Gasoline consists of many different classes of hydrocarbons, such as paraffins, olefins, aromatics, and cycloalkanes. In this study, a surrogate gasoline reaction mechanism is developed, and it has one representative fuel constituent from each of these classes. These selected constituents are iso-octane, n-heptane, 1-pentene, toluene, and methyl-cyclohexane. The mechanism was developed in a step-wise fashion, adding submechanisms to treat each fuel component. Reactions important for low temperature oxidation (<1000K) and cross-reactions among different fuels are incorporated into the mechanism. The mechanism consists of 1214 species and 5401 reactions. A single-zone engine model is used to evaluate how well the mechanism captures autoignition behavior for conditions corresponding to homogeneous charge compression ignition (HCCI) engine operation. Experimental data are available for both how the combustion phasing changes with fueling at a constant intake temperature, and also how the intake temperature has to be changed with pressure in order to maintain combustion phasing for a fixed equivalence ratio. Three different surrogate fuel mixtures are used for the modeling. Predictions are in reasonably good agreement with the engine data. In addition, the heat release rate is calculated and compared to the data from experiments. The model predicts less low-temperature heat release than that measured. It is found that the low temperature heat-release rate depends strongly on engine speed, reactions of RO{sub 2}+HO{sub 2}, fuel composition, and pressure boost.

  18. Evaluation Study for Large Prismatic Lithium-Ion Cell Designs Using Multi-Scale Multi-Dimensional Battery Model (Presentation)

    SciTech Connect (OSTI)

    Kim, G. H.; Smith, K.

    2009-05-01

    Addresses battery requirements for electric vehicles using a model that evaluates physical-chemical processes in lithium-ion batteries, from atomic variations to vehicle interface controls.

  19. Lithium battery

    SciTech Connect (OSTI)

    Ikeda, H.; Nakaido, S.; Narukara, S.

    1983-08-16

    In a lithium battery having a negative electrode formed with lithium as active material and the positive electrode formed with manganese dioxide, carbon fluoride or the like as the active material, the discharge capacity of the negative electrode is made smaller than the discharge capacity of the positive electrode, whereby a drop in the battery voltage during the final discharge stage is steepened, and prevents a device using such a lithium battery as a power supply from operating in an unstable manner, thereby improving the reliability of such device.

  20. Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes - May 2008

    Fuel Cell Technologies Publication and Product Library (EERE)

    Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report: Technical report describing assessment of hydrogen storage materials and progress towards meeting DOE’s hydrogen

  1. Identification of vapor-phase chemical warfare agent simulants and rocket fuels using laser-induced breakdown spectroscopy

    SciTech Connect (OSTI)

    Stearns, Jaime A.; McElman, Sarah E.; Dodd, James A.

    2010-05-01

    Application of laser-induced breakdown spectroscopy (LIBS) to the identification of security threats is a growing area of research. This work presents LIBS spectra of vapor-phase chemical warfare agent simulants and typical rocket fuels. A large dataset of spectra was acquired using a variety of gas mixtures and background pressures and processed using partial least squares analysis. The five compounds studied were identified with a 99% success rate by the best method. The temporal behavior of the emission lines as a function of chamber pressure and gas mixture was also investigated, revealing some interesting trends that merit further study.

  2. Chemicals, fuels and electricity from coal. A proposed tri-generation concept for utilization of CO{sub 2} from power plants

    SciTech Connect (OSTI)

    Song, C.

    1999-07-01

    A tri-generation concept is proposed for the 21st century for making liquid fuels and chemicals along with electricity using CO{sub 2} from flue gases of coal-based electric power plants. The CO{sub 2} from flue gas in the power plant can be converted with CH{sub 4} (natural gas) to form synthesis gas (CO and H{sub 2} mixture) using the waste heat in the power plant. The H{sub 2}O and O{sub 2} in the flue gas will be used as co-reactants and need not be separated from the flue gas. The hot synthesis gas can be used as feedstock for fuel cells for electricity generation (such as MCFC and SOFC). The hot synthesis gas can also be used for gas turbines to generate electricity. The synthesis gas at moderate temperature can be converted into chemicals and fuels, e.g., methanol and mixed alcohols for chemical and fuel uses, dimethylether (DME) and mixed ethers for diesel fuel, dimethyl carbonate and acetic acid for chemicals. The fuels thus produced may be used either for conventional IC engines or in fuel cell-driven vehicles. This concept could also be applied, in principle, for natural gas-based power plants and IGCC power plants.

  3. Design Concepts for Co-Production of Power, Fuels & Chemicals Via Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Rao, A. D.; Chen, Q.; Samuelsen, G. S.

    2012-09-30

    The overall goal of the program is to develop design concepts, incorporating advanced technologies in areas such as oxygen production, feed systems, gas cleanup, component separations and gas turbines, for integrated and economically viable coal and biomass fed gasification facilities equipped with carbon capture and storage for the following scenarios: (i) coproduction of power along with hydrogen, (ii) coproduction of power along with fuels, (iii) coproduction of power along with petrochemicals, and (iv) coproduction of power along with agricultural chemicals. To achieve this goal, specifically the following objectives are met in this proposed project: (i) identify advanced technology options and innovative preliminary design concepts that synergistically integrate plant subsections, (ii) develop steady state system simulations to predict plant efficiency and environmental signature, (iii) develop plant cost estimates by capacity factoring major subsystems or by major equipment items where required, and then capital, operating and maintenance cost estimates, and (iv) perform techno- economic analyses for the above described coproduction facilities. Thermal efficiencies for the electricity only cases with 90% carbon capture are 38.26% and 36.76% (HHV basis) with the bituminous and the lignite feedstocks respectively. For the coproduction cases (where 50% of the energy exported is in the form of electricity), the electrical efficiency, as expected, is highest for the hydrogen coproduction cases while lowest for the higher alcohols (ethanol) coproduction cases. The electrical efficiencies for Fischer-Tropsch coproduction cases are slightly higher than those for the methanol coproduction cases but it should be noted that the methanol (as well as the higher alcohol) coproduction cases produce the finished coproduct while the Fischer-Tropsch coproduction cases produce a coproduct that requires further processing in a refinery. The cross comparison of the thermal

  4. Flow battery

    DOE Patents [OSTI]

    Lipka, Stephen M.; Swartz, Christopher R.

    2016-02-23

    An electrolyte system for a flow battery has an anolyte including [Fe(CN).sub.6].sup.3- and [Fe(CN).sub.6].sup.4- and a catholyte including Fe.sup.2+ and Fe.sup.3+.

  5. Webinar: Fuzzy Mud and the Future of Alternative Fuels | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    research --Building design ---Construction ... & simulation ---Nuclear fuel cycle ---Reactors -Energy usage --Energy storage ---Batteries ----Lithium-ion ...

  6. Computer-Aided Engineering for Electric Drive Vehicle Batteries (CAEBAT) |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es099_pesaran_2011_p.pdf (1.5 MB) More Documents & Publications Overview of Computer-Aided Engineering of Batteries (CAEBAT) and Introduction to Multi-Scale, Multi-Dimensional (MSMD) Modeling of Lithium-Ion Batteries Battery Thermal Modeling and Testing Progress of Computer-Aided Engineering of Batteries (CAEBAT)

  7. Sandia Researchers Develop Promising Chemical Technology for Energy Storage

    Broader source: Energy.gov [DOE]

    DOE-funded researchers have developed new chemical technology that could lead to batteries able to cost-effectively store three times more energy than today's batteries.

  8. Bipolar battery

    DOE Patents [OSTI]

    Kaun, Thomas D.

    1992-01-01

    A bipolar battery having a plurality of cells. The bipolar battery includes: a negative electrode; a positive electrode and a separator element disposed between the negative electrode and the positive electrode, the separator element electrically insulating the electrodes from one another; an electrolyte disposed within at least one of the negative electrode, the positive electrode and the separator element; and an electrode containment structure including a cup-like electrode holder.

  9. Hydrogen-Bromine Flow Battery: Hydrogen Bromine Flow Batteries for Grid Scale Energy Storage

    SciTech Connect (OSTI)

    2010-10-01

    GRIDS Project: LBNL is designing a flow battery for grid storage that relies on a hydrogen-bromine chemistry which could be more efficient, last longer and cost less than today’s lead-acid batteries. Flow batteries are fundamentally different from traditional lead-acid batteries because the chemical reactants that provide their energy are stored in external tanks instead of inside the battery. A flow battery can provide more energy because all that is required to increase its storage capacity is to increase the size of the external tanks. The hydrogen-bromine reactants used by LBNL in its flow battery are inexpensive, long lasting, and provide power quickly. The cost of the design could be well below $100 per kilowatt hour, which would rival conventional grid-scale battery technologies.

  10. Electric Drive and Advanced Battery and Components Testbed (EDAB) |

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting vss033_carlson_2012_o.pdf (1.13 MB) More Documents & Publications Electric Drive and Advanced Battery and Components Testbed (EDAB) Vehicle Technologies Office Merit Review 2014: Electric Drive and Advanced Battery and Components Testbed (EDAB) Electric Drive and Advanced Battery Department of Energy

    1 DOE Hydrogen and Fuel Cells Program, and

  11. DOE Issues Request for Information on Fuel Cells for Continuous...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Request for Information on Fuel Cells for Continuous On-Board Recharging for Battery Electric Light-Duty Vehicles DOE Issues Request for Information on Fuel Cells for...

  12. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

    2011-03-01

    An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

  13. Self-Regulating, Nonflamable Rechargeable Lithium Batteries

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2010-06-23

    Rechargeable lithium batteries are superior to other rechargeable batteries due to their ability to store more energy per unit size and weight and to operate at higher voltages. The performance of lithium ion batteries available today, however, has been compromised by their tendency to overheat during operation. This condition, called “thermal runaway,” can melt the battery’s lithium metal and, in the most serious cases, result in explosive chemical reactions....

  14. Separation of Corn Fiber and Conversion to Fuels and Chemicals: Pilot-Scale Operation

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project focuses on the development and pilot-scale testing of technologies that will enable the development of a biorefinery capable of economically deriving high-value chemicals and oils from lower value corn fiber.

  15. 2009 Fuel Cell Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  16. Direct Measurement of the Chemical Reactivity of Silicon Electrodes...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: catalysis (heterogeneous), solar (fuels), energy storage (including batteries and capacitors), hydrogen and fuel ...

  17. Microsoft PowerPoint - Chemical Kinetics Studies of Alternative Fuels_Sung_092310

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Studies of Alt ti F l Alternative Fuels Chih-Jen (Jackie) Sung Chih Jen (Jackie) Sung Department of Mechanical Engineering University of Connecticut y Prepared for 2010 MACCCR and CEFRC Conferences 2010 MACCCR and CEFRC Conferences Princeton, NJ September 23, 2010 Accomplishments - Year 1 * * Autoignition Autoignition of of n n- -Butanol Butanol at Low to Intermediate at Low to Intermediate Temperatures and Elevated Pressures* Temperatures and Elevated Pressures* Temperatures and Elevated

  18. Basic mechanisms of photosynthesis and applications to improved production and conversion of biomass to fuels and chemical products

    SciTech Connect (OSTI)

    El-Sayed, M.; Greenbaum, E.; Wasielewski, M.

    1996-09-01

    Natural photosynthesis, the result of 3.5 billion years of evolutionary experimentation, is the best proven, functional solar energy conversion technology. It is responsible for filling the vast majority of humanity`s energy, nutritional, and materials needs. Understanding the basic physical chemical principles underlying photosynthesis as a working model system is vital to further exploitation of this natural technology. These principles can be used to improve or modify natural photosynthesis so that it is more efficient or so that it can produce unusual products such as hydrogen, methane, methanol, ethanol, diesel fuel substitutes, biodegradable materials, or other high value chemical products. Principles garnered from the natural process can also be used to design artificial photosynthetic devices that employ analogs of natural antenna and reaction center function, self-assembly and repair concepts, photoinduced charge transfer processes, photoprotection, and dark reactions that facilitate catalytic action to convert light into, useful chemical or electrical energy. The present broad understanding of many structural and functional aspects of photosynthesis has resulted from rapid recent research progress. X-ray structures of several key photosynthetic reaction centers and antenna systems are available, and the overall principles controlling photoinduced energy and electron transfer are being established.

  19. NREL Joins with A123Systems to Improve Advanced-Vehicle Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Joins with A123Systems to Improve Advanced-Vehicle Batteries Safe, powerful, and long-lasting batteries key to more fuel-efficient cars June 19, 2008 The U.S. Department of ...

  20. RADIOACTIVE BATTERY

    DOE Patents [OSTI]

    Birden, J.H.; Jordan, K.C.

    1959-11-17

    A radioactive battery which includes a capsule containing the active material and a thermopile associated therewith is presented. The capsule is both a shield to stop the radiations and thereby make the battery safe to use, and an energy conventer. The intense radioactive decay taking place inside is converted to useful heat at the capsule surface. The heat is conducted to the hot thermojunctions of a thermopile. The cold junctions of the thermopile are thermally insulated from the heat source, so that a temperature difference occurs between the hot and cold junctions, causing an electrical current of a constant magnitude to flow.

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    By January 1, 2018, the Department of Motor Vehicles (Department) should record the number of EVs registered in Connecticut. An EV is defined as any battery electric, fuel cell, ...

  2. The Structural Evolution and Diffusion During the Chemical Transformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Cobalt to Cobalt Phosphide Nanoparticles > Research Highlights > Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel

  3. Materials cost evaluation report for high-power Li-ion batteries.

    SciTech Connect (OSTI)

    Henriksen, G. L.; Amine, K.; Liu, J.

    2003-01-10

    The U.S. Department of Energy (DOE) is the lead federal agency in the partnership between the U.S. automobile industry and the federal government to develop fuel cell electric vehicles (FCEVs) and hybrid electric vehicles (HEVs) as part of the FreedomCAR Partnership. DOE's FreedomCAR and Vehicle Technologies Office sponsors the Advanced Technology Development (ATD) Program--involving 5 of its national laboratories--to assist the industrial developers of high-power lithium-ion batteries to overcome the barriers of cost, calendar life, and abuse tolerance so that this technology can be rendered practical for use in HEV and FCEV applications under the FreedomCAR Partnership. In the area of cost reduction, Argonne National Laboratory (ANL) is working to identify and develop advanced anode, cathode, and electrolyte components that can significantly reduce the cost of the cell chemistry, while simultaneously extending the calendar life and enhancing the inherent safety of this electrochemical system. The material cost savings are quantified and tracked via the use of a cell and battery design model that establishes the quantity of each material needed in the production of batteries that are designed to meet the requirements of a minimum-power-assist HEV battery or a maximum-power-assist HEV battery for the FreedomCAR Partnership. Similar models will be developed for FEV batteries when the requirements for those batteries are finalized. In order to quantify the material costs relative to the FreedomCAR battery cost goals, ANL uses (1) laboratory cell performance data, (2) its battery design model and (3) battery manufacturing process yields to create battery-level material cost models. Using these models and industry-supplied material cost information, ANL assigns battery-level material costs for different cell chemistries. These costs can then be compared with the battery cost goals to determine the probability of meeting the goals with these cell chemistries. As can be

  4. Chemical reactions during ThO{sub 2} and ThO{sub 2}-UO{sub 2} fuel fabrication

    SciTech Connect (OSTI)

    Clayton, J.C.

    1994-08-01

    The chemical reactions that occur during the fabrication of fuel pellets for the Shipping port Light Water Breeder Reactor are discussed. These include (1) precipitation and pyrolysis of thorium oxalate, (2) precipitation, calcination, and hydrogen reduction of ammonium diuranate, (3) comminution, granulation with an organic binder, and cold compaction of ThO{sub 2} and ThO{sub 2}-UO{sub 2} powders, (4) decarburization of the organic binder in CO{sub 2} at temperature up to 925 C, and (5) sintering in moist hydrogen at temperature up to 1790 C. Thorium oxalate precipitation and pyrolysis temperatures were the primary process variables for controlling the resulting thoria powder properties. Coprecipitated metal sulfates were converted to transition metal sulfides during calcining - the conversion of thorium oxalate to thorium oxide. The critical variable for controlling the urania powder properties was the hydrogen reduction temperature. Thermodynamic analyses showed that the efficiency of carbon removal from cold-compacted ThO{sub 2} and ThO{sub 2}-UO{sub 2} pellets by CO{sub 2} oxidation increases with temperature and, at temperatures around 900 C, substantially complete oxidation of carbon to carbon monoxide gas should occur. The carbon content of the ThO{sub 2} and ThO{sub 2}-UO{sub 2} fuels was further reduced during the initial heating in the hydrogen sintering cycle through the formation of methane gas. Additions of water vapor to the hydrogen sintering atmosphere also aided in carbon removal.

  5. Thermal battery

    SciTech Connect (OSTI)

    Williams, M.T.; Winchester, C.S.; Jolson, J.D.

    1989-06-20

    A thermal battery is described comprising at least one electrochemical cell comprising an anode of alkali metal, alkaline earth metal or alloys thereof, a fusible salt electrolyte, a fluorocarbon polymer or fluorochlorocarbon polymer depolarizer, and means for heating the cell to melt the electrolyte.

  6. Stand Alone Battery Thermal Management System

    SciTech Connect (OSTI)

    Brodie, Brad

    2015-09-30

    The objective of this project is research, development and demonstration of innovative thermal management concepts that reduce the cell or battery weight, complexity (component count) and/or cost by at least 20%. The project addresses two issues that are common problems with current state of the art lithium ion battery packs used in vehicles; low power at cold temperatures and reduced battery life when exposed to high temperatures. Typically, battery packs are “oversized” to satisfy the two issues mentioned above. The first phase of the project was spent making a battery pack simulation model using AMEsim software. The battery pack used as a benchmark was from the Fiat 500EV. FCA and NREL provided vehicle data and cell data that allowed an accurate model to be created that matched the electrical and thermal characteristics of the actual battery pack. The second phase involved using the battery model from the first phase and evaluate different thermal management concepts. In the end, a gas injection heat pump system was chosen as the dedicated thermal system to both heat and cool the battery pack. Based on the simulation model. The heat pump system could use 50% less energy to heat the battery pack in -20°C ambient conditions, and by keeping the battery cooler at hot climates, the battery pack size could be reduced by 5% and still meet the warranty requirements. During the final phase, the actual battery pack and heat pump system were installed in a test bench at DENSO to validate the simulation results. Also during this phase, the system was moved to NREL where testing was also done to validate the results. In conclusion, the heat pump system can improve “fuel economy” (for electric vehicle) by 12% average in cold climates. Also, the battery pack size, or capacity, could be reduced 5%, or if pack size is kept constant, the pack life could be increased by two years. Finally, the total battery pack and thermal system cost could be reduced 5% only if the

  7. Alan MacDiarmid, Conductive Polymers, and Plastic Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alan MacDiarmid, Conductive Polymers, and Plastic Batteries Resources with Additional Information * Patents Alan MacDiarmid ©Alan MacDiarmid/ University of Pennsylvania Photo by Felice Macera Until 1987, the billions of batteries that had been marketed in myriad sizes and shapes all had one thing in common. To make electricity, they depended exclusively upon chemical reactions involving metal components of the battery. But today a revolutionary new type of battery is available commercially. It

  8. Vehicle Technologies Office Merit Review 2016: Co-Optimization of Fuels and Engines (Co-Optima)—Fuel Properties and Chemical Kinetics and Thrust I Engine Projects

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory (ORNL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Fuel & Lubricants

  9. Vehicle Technologies Office Merit Review 2016: Co-Optimization of Fuels and Engines (Co-Optima)-- Fuel Properties and Chemical Kinetics and Thrust I Engine Projects

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory (ORNL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Fuel...

  10. Chemical Engineering Division fuel cycle programs. Quarterly progress report, July-September 1978

    SciTech Connect (OSTI)

    Steindler, M.J.; Ader, M.; Barletta, R.E.

    1980-01-01

    Fuel cycle work included hydraulic performance and extraction efficiency of eight-stage centrifugal contactors, flowsheet for the Aralex process, Ru and Zr extraction in a miniature centrifugal contactor, study of Zr aging in the organic phase and its effect on Zr extraction and hydraulic testing of the 9-cm-ID contactor. Work for predicting accident consequences in LWR fuel processing covered the relation between energy input (to subdivide a solid) and the modes of particle size frequency distribution. In the pyrochemical and dry processing program corrosion-testing materials for containment vessels and equipment for studying carbide reactions in bismuth is under way. Analytical studies have been made of salt-transport processes; efforts to spin tungsten crucibles 13 cm dia continue, and other information on tungsten fabrication is being assembled; the process steps of the chloride volatility process have been demonstrated and the thoria powder product used to produce oxide pellets; solubility of UO/sub 2/, PuO/sub 2/, and fission products in molten alkali nitrates is being investigated; work was continued on reprocessing actinide oxides by extracting the actinides into ammonium chloroaluminate from bismuth; the preparation of thorium-uranium carbide from the oxide is being studied as a means of improving the oxide reactivity; studies are in progress on producing uranium metal and decontaminated ThO/sub 2/ by the reaction of (Th,U)O/sub 2/ solid solution in molten salts containing ThCl/sub 4/ and thorium metal chips. In the molten tin process, no basic thermodynamic or kinetic factors have been found that may limit process development.