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1

Alternative Fuels Data Center: Low Carbon Fuel Standard  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Low Carbon Fuel Low Carbon Fuel Standard to someone by E-mail Share Alternative Fuels Data Center: Low Carbon Fuel Standard on Facebook Tweet about Alternative Fuels Data Center: Low Carbon Fuel Standard on Twitter Bookmark Alternative Fuels Data Center: Low Carbon Fuel Standard on Google Bookmark Alternative Fuels Data Center: Low Carbon Fuel Standard on Delicious Rank Alternative Fuels Data Center: Low Carbon Fuel Standard on Digg Find More places to share Alternative Fuels Data Center: Low Carbon Fuel Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Low Carbon Fuel Standard Low Carbon Fuel Standard California's Low Carbon Fuel Standard (LCFS) Program requires a reduction in the carbon intensity of transportation

2

Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Low Carbon Fuels Low Carbon Fuels Standard Collaboration to someone by E-mail Share Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on Facebook Tweet about Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on Twitter Bookmark Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on Google Bookmark Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on Delicious Rank Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on Digg Find More places to share Alternative Fuels Data Center: Low Carbon Fuels Standard Collaboration on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Low Carbon Fuels Standard Collaboration The New Hampshire Department of Environmental Services may engage in

3

Carbon fuel particles used in direct carbon conversion fuel cells  

SciTech Connect

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F.; Cherepy, Nerine

2012-10-09T23:59:59.000Z

4

Carbon fuel particles used in direct carbon conversion fuel cells  

SciTech Connect

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

2012-01-24T23:59:59.000Z

5

Carbon fuel particles used in direct carbon conversion fuel cells  

Science Conference Proceedings (OSTI)

A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

Cooper, John F. (Oakland, CA); Cherepy, Nerine (Oakland, CA)

2011-08-16T23:59:59.000Z

6

Carbonate fuel cell matrix  

DOE Patents (OSTI)

A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

Farooque, M.; Yuh, C.Y.

1996-12-03T23:59:59.000Z

7

Carbonate fuel cell matrix  

DOE Patents (OSTI)

A carbonate fuel cell matrix comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles.

Farooque, Mohammad (Huntington, CT); Yuh, Chao-Yi (New Milford, CT)

1996-01-01T23:59:59.000Z

8

Global Fossil Fuel Carbon Emissions - Graphics  

NLE Websites -- All DOE Office Websites (Extended Search)

Fossil-Fuel CO2 Emissions Global Graphics Global Fossil-Fuel Carbon Emissions - Graphics Carbon Emission Estimates image image Global Per Capita Carbon Emission Estimates...

9

Carbon fuel cells with carbon corrosion suppression  

Science Conference Proceedings (OSTI)

An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

Cooper, John F. (Oakland, CA)

2012-04-10T23:59:59.000Z

10

Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Low Carbon Fuel and Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement to someone by E-mail Share Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on Facebook Tweet about Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on Twitter Bookmark Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on Google Bookmark Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on Delicious Rank Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on Digg Find More places to share Alternative Fuels Data Center: Low Carbon Fuel and Fuel-Efficient Vehicle Acquisition Requirement on AddThis.com...

11

Low Carbon Fuel Standards  

E-Print Network (OSTI)

land-use changes. When biofuel production increases, land ison carbon releases. If biofuel production does not result in

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

12

Low Carbon Fuel Standards  

E-Print Network (OSTI)

cap would be placed on oil refineries and would require themwith the fuels. The refineries would be able to tradeto improve the efficiency of refineries and introduce low-

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

13

Low Carbon Fuel Standards  

E-Print Network (OSTI)

emissions for fuels such as biofuels, electric- ity, andcould, for instance, sell biofuels or buy credits fromthat 36 billion gallons of biofuels be sold annu- ally by

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

14

Molten carbonate fuel cell separator  

DOE Patents (OSTI)

In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

Nickols, Richard C. (East Hartford, CT)

1986-09-02T23:59:59.000Z

15

Molten carbonate fuel cell separator  

DOE Patents (OSTI)

In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

Nickols, R.C.

1984-10-17T23:59:59.000Z

16

Direct Carbon Fuel Cell Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Direct Carbon Fuel Cell Workshop Direct Carbon Fuel Cell Workshop July 30, 2003 Table of Contents Disclaimer Papers and Presentations Carbon Anode Electrochemistry Carbon Conversion Fuel Cells Coal Preprocessing Prior to Introduction Into the Fuel Cell Potential Market Applications for Direct Carbon Fuel Cells Discussion of Key R&D Needs Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

17

Molten carbonate fuel cell  

DOE Patents (OSTI)

A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

Kaun, Thomas D. (New Lenox, IL); Smith, James L. (Lemont, IL)

1987-01-01T23:59:59.000Z

18

Molten carbonate fuel cell  

DOE Patents (OSTI)

A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

Kaun, T.D.; Smith, J.L.

1986-07-08T23:59:59.000Z

19

Global Fossil Fuel Carbon Emissions - Graphics  

NLE Websites -- All DOE Office Websites (Extended Search)

Fossil-Fuel CO2 Emissions Global Graphics Global Fossil-Fuel Carbon Emissions - Graphics Data graphic Data (ASCII, Fixed Format) Data graphic Data (ASCII, Comma-delimited)...

20

Assessment of Direct Carbon Fuel Cells  

Science Conference Proceedings (OSTI)

Fuel cells have been under development for stationary power applications because of their high fuel efficiency and low emission characteristics. Research and development of direct carbon fuel cells (DCFC) that can use carbon as a fuel have been identified as an emerging option that needs further assessment and test validation. This project is one of several EPRI fuel cell projects that is investigating the technical and performance characteristics of fuel cells and their potential to impact electric util...

2005-02-16T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Carbonate fuel cell matrix strengthening  

DOE Green Energy (OSTI)

The present baseline electrolyte matrix is a porous ceramic powder bed impregnated with alkali carbonate electrolyte. The matrix provides both ionic conduction and gas sealing. During fuel cell stack operation, the matrix experiences both mechanical and thermal stresses. Different mechanical characteristics of active and wet seal areas generate stress. Thermal stress is generated by nonuniform temperature distribution and thermal cycling. A carbonate fuel cell generally may experience planned and unplanned thermal cycles between 650 C and room temperature during its 40,000h life. During the cycling, the electrolyte matrix expands and contracts at a different rate from other cell components. Furthermore, the change in electrolyte volume associated with freezing/melting may generate additional thermal stress. Strengthening of the matrix may be beneficial for longer-term stability of the carbonate fuel cell with respect to repeated thermal cycling. Several promising strengtheners with improved chemical and mechanical stabilities were identified. Fibers provide the highest strengthening effect, followed by particulates. Matrix fabrication technique was successfully modified for uniformly incorporating the advanced strengtheners, maintaining the desired aspect ratio. Enhanced gas sealing demonstrated using the advanced matrices.

Yuh, C.Y.; Haung, C.M.; Johnsen, R.

1995-12-31T23:59:59.000Z

22

Carbon-based Fuel Cell  

DOE Green Energy (OSTI)

The direct use of coal in the solid oxide fuel cell to generate electricity is an innovative concept for power generation. The C-fuel cell (carbon-based fuel cell) could offer significant advantages: (1) minimization of NOx emissions due to its operating temperature range of 700-1000 C, (2) high overall efficiency because of the direct conversion of coal to CO{sub 2}, and (3) the production of a nearly pure CO{sub 2} exhaust stream for the direct CO{sub 2} sequestration. The objective of this project is to determine the technical feasibility of using a highly active anode catalyst in a solid oxide fuel for the direct electrochemical oxidation of coal to produce electricity. Results of this study showed that the electric power generation from Ohio No 5 coal (Lower Kittanning) Seam, Mahoning County, is higher than those of coal gas and pure methane on a solid oxide fuel cell assembly with a promoted metal anode catalyst at 950 C. Further study is needed to test the long term activity, selectivity, and stability of anode catalysts.

Steven S. C. Chuang

2005-08-31T23:59:59.000Z

23

Pyrolytic carbon-coated nuclear fuel  

DOE Patents (OSTI)

An improved nuclear fuel kernel having at least one pyrolytic carbon coating and a silicon carbon layer is provided in which extensive interaction of fission product lanthanides with the silicon carbon layer is avoided by providing sufficient UO.sub.2 to maintain the lanthanides as oxides during in-reactor use of said fuel.

Lindemer, Terrence B. (Oak Ridge, TN); Long, Jr., Ernest L. (Oak Ridge, TN); Beatty, Ronald L. (Wurlingen, CH)

1978-01-01T23:59:59.000Z

24

Carbonate Fuel Cell Materials and Endurance Results  

Science Conference Proceedings (OSTI)

Abstract Scope, The high-temperature carbonate fuel cell is an ultra-clean and ... Hot Section Corrosion Issues in Microturbines Operating on B100 Bio-Diesel.

25

Electrolyte reservoir for carbonate fuel cells  

DOE Patents (OSTI)

An electrode for a carbonate fuel cell and method of making same are described wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

Iacovangelo, C.D.; Shores, D.A.

1984-05-23T23:59:59.000Z

26

Electrolyte reservoir for carbonate fuel cells  

DOE Patents (OSTI)

An electrode for a carbonate fuel cell and method of making same wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

Iacovangelo, Charles D. (Schenectady, NY); Shores, David A. (Minneapolis, MN)

1985-01-01T23:59:59.000Z

27

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

Disclosed are a porous sintered cathode for a molten carbonate fuel cell and method of making same. The cathode includes a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell. The cathode has a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, T.D.; Mrazek, F.C.

1986-04-25T23:59:59.000Z

28

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1990-01-01T23:59:59.000Z

29

Fuel Type Fuel Treated as of  

E-Print Network (OSTI)

This report was prepared by the Department of Energy (DOE) in response to Congressional direction included in the Energy and Water Development Appropriations Act for FY 2006. The Congressional language states “The Committee directs the Department to undertake a study to evaluate and propose a disposal solution for the entire 62 tons of sodium-bonded spent nuclear fuel (SNF) and to consider what minimal amount of fuel is needed for future experiments under the Advanced Fuel Cycle Initiative (AFCI).” The inventory of sodium-bonded spent fuel is stored in Idaho or planned for shipment to Idaho. Because DOE is committed to meeting its agreement with the State (Settlement and Consent order issued on October 17, 1995, in the actions of Public Service Co. of Colorado v. Batt, No. CV 91-0035-S-EJL [D. Id.] and United States v. Batt, No. CV 91-0054-EJL [D. Id]), all spent fuel, including sodium-bonded spent fuel, must leave Idaho by 2035. Sodium-bonded fuel was principally used in three different reactors: Experimental Breeder Reactor (EBR-II), Enrico Fermi Atomic Power Plant (Fermi-1), and Fast Flux Test Facility (FFTF). The quantity of fuel from each reactor, along with a small quantity that is at Sandia National Laboratory, is shown in the table below.

Fftf Driver

2005-01-01T23:59:59.000Z

30

Progress in carbonate fuel cells  

DOE Green Energy (OSTI)

Our objective is to increase both the life and power of the molten carbonate fuel (MCFC) by developing improved components and designs. Current activities are as follows: (1)Development of LiFeO{sub 2} and LiCoO{sub 2} cathodes for extended MCFC life, particularly in pressurized operation, where the present cathode, NiO, provides insufficient life (2) Development of distributed-manifold MCFC designs for increased volumetric power density and decreased temperature gradients (and, therefore, increased life) (3) Development of components and designs appropriate for high-power density operation (>2 kW/m{sup 2}and >100 kW/m{sup 3}in an integrated MCFC system) (4)Studies of pitting corrosion of the stainless-steel interconnects and aluminized seals now being employed in the MCFC (alternative components will also be studied). Each of these activities has the potential to reduce the MCFC system cost significantly. Progress in each activity will be presented during the poster session.

Myles, K.M.; Krumpelt, M.; Roche, M.F. [and others

1995-12-31T23:59:59.000Z

31

Novel carbon-ion fuel cells  

DOE Green Energy (OSTI)

This report details acitvities by the Duke University Department of Mechanical Engineering and Material Science on the Novel Carbon-Ion Fuel Cells for the Department of Energy Advanced Coal Research Program grant for the third quarter of 1995.

Cocks, F.H.; LaViers, H.

1995-10-03T23:59:59.000Z

32

Synthetic fuels, carbon dioxide and climate  

Science Conference Proceedings (OSTI)

The observed increase in atmospheric carbon dioxide (CO2) has been attributed to the use of fossil fuels. There is concern that the generation and use of synthetic fuels derived from oil shale and coal will accelerate the increase of CO2.

Alex R. Sapre; John R. Hummel; Ruth A. Reck

1982-01-01T23:59:59.000Z

33

Molten carbonate fuel cell research at ORNL  

DOE Green Energy (OSTI)

The activities at ORNL during the period July 1976 to February 1977 on the molten carbonate fuel cell program, funded by the ERDA Division of Conservation Research and Technology, are summarized. This period marks the initiation of molten carbonate fuel cell research at ORNL, making use of the extensive background of expertise and facilities in molten salt research. The activities described include a literature survey on molten carbonates, design, acquisition and installation of apparatus for experimental studies of molten carbonates, initial experiments on materials compatibility with molten carbonates, electrolysis experiments for the determination of transference numbers, and theoretical studies of transport behavior and the coupling of mass flows in molten carbonate mixtures. Significant accomplishments were the theoretical prediction of a possibly appreciable change in the alkali ion ratio at molten carbonate fuel cell electrodes, operated at high current densities, as a result of mobility differences of the alkali ions; design, construction and assembly of an electrolysis cell, and initiation of measurements of composition profiles in mixed alkali carbonate electrolytes; initiation of differential scanning calorimetry of pure alkali carbonates for quantitative measurement of transition enthalpies, eventually leading to new, more reliable values of the enthalpies and free energies of formation of the pure and mixed carbonates.

Braunstein, J.; Bronstein, H. R.; Cantor, S.; Heatherly, D.; Vallet, C. E.

1977-05-01T23:59:59.000Z

34

Effect of carbon coating on scuffing performance in diesel fuels  

DOE Green Energy (OSTI)

Low-sulfur and low-aromatic diesel fuels are being introduced in order to reduce various types of emissions in diesel engines to levels in compliance with current and impending US federal regulations. The low lubricity of these fuels, however, poses major reliability and durability problems for fuel injection components that depend on diesel fuel for their lubrication. In the present study, the authors evaluated the scuff resistance of surfaces in regular diesel fuel containing 500 ppm sulfur and in Fischer-Tropsch synthetic diesel fuel containing no sulfur or aromatics. Tests were conducted with the high frequency reciprocating test rig (HFRR) using 52100 steel balls and H-13 tool-steel flats with and without Argonne's special carbon coatings. Test results showed that the sulfur-containing fuels provide about 20% higher scuffing resistance than does fuel without sulfur. Use of the carbon coating on the flat increased scuffing resistance in both regular and synthetic fuels by about ten times, as measured by the contact severity index at scuffing. Scuffing failure in tests conducted with coated surfaces did not occur until the coating had been removed by the two distinct mechanisms of spalling and wear.

Ajayi, O. O.; Alzoubi, M. F.; Erdemir, A.; Fenske, G. R.

2000-06-29T23:59:59.000Z

35

Status of Molten Carbonate Fuel Cell Technology  

Science Conference Proceedings (OSTI)

Fuel cell technology development and commercialization continues to be a major thrust in the alternative energy sector of distributed generation (DG). Second generation, molten carbonate fuel cell technology (MCFC) is now entering a critical commercialization phase. Given recent MCFC developments and advances in other distributed generation technologies, an assessment and update on the prospects for MCFC power systems is needed to guide future utility investments.

2003-01-22T23:59:59.000Z

36

Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems  

SciTech Connect

Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power generation in the range of 0.5 to 50 MW is small engines fueled with natural gas or liquid fuels or in the bulk power markets supplied usually by remote central station power plants with capacities of 250-1250 MW that deliver electricity to customers via the transmission and distribution grid. New power generation technology must be able to offer a significant cost advantage over existing technologies serving the same market to attract the interest of investors that are needed to provide funding for the development, demonstration, and commercialization of the technology. That path is both lengthy and expensive. One of the key drivers for any new power generation technology is the relative amount of pollutant emissions of all types, particularly those that are currently regulated or may soon be regulated. The new focus on greenhouse gas emissions offers a window of opportunity to DCFC technology because of its much higher conversion efficiency and the production of a very concentrated stream of CO{sub 2} in the product gas. This should offer a major competitive advantage if CO{sub 2} emissions are constrained by regulation in the future. The cost of CO{sub 2} capture, liquefaction, and pressurization has the potential to be much less costly with DCFC technology compared to other currently available forms of fossil fuel power generation.

Wolk, R

2004-04-23T23:59:59.000Z

37

Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems  

DOE Green Energy (OSTI)

Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power generation in the range of 0.5 to 50 MW is small engines fueled with natural gas or liquid fuels or in the bulk power markets supplied usually by remote central station power plants with capacities of 250-1250 MW that deliver electricity to customers via the transmission and distribution grid. New power generation technology must be able to offer a significant cost advantage over existing technologies serving the same market to attract the interest of investors that are needed to provide funding for the development, demonstration, and commercialization of the technology. That path is both lengthy and expensive. One of the key drivers for any new power generation technology is the relative amount of pollutant emissions of all types, particularly those that are currently regulated or may soon be regulated. The new focus on greenhouse gas emissions offers a window of opportunity to DCFC technology because of its much higher conversion efficiency and the production of a very concentrated stream of CO{sub 2} in the product gas. This should offer a major competitive advantage if CO{sub 2} emissions are constrained by regulation in the future. The cost of CO{sub 2} capture, liquefaction, and pressurization has the potential to be much less costly with DCFC technology compared to other currently available forms of fossil fuel power generation.

Wolk, R

2004-04-23T23:59:59.000Z

38

Molten carbonate fuel cell programs in the United States  

DOE Green Energy (OSTI)

The environmental, performance, and economic aspects of molten carbonate fuel cell power plants are discussed. Design, components, and operation of molten carbonate fuel cells are discussed, and US research is outlined. (WHK)

Ackerman, J.P.

1980-01-01T23:59:59.000Z

39

An Analysis of Fuel Demand and Carbon Emissions in China  

E-Print Network (OSTI)

Under the Kyoto Protocol to the United Nations Framework Convention on Climate Change, targets have been set for various developed countries to reduce their carbon emissions. China's share of carbon emissions ranked the second highest in the world in 1996, only after the United States. Although China was not formally required to achieve a reduction in its carbon emissions under the protocol, pressures were mounting, especially from the United States, for China to address the issue seriously. Some recent research on China's carbon emissions has largely been carried out in the framework of computable general equilibrium models. For example, Fisher-Vanden (2003) used such models to assess the impact of market reforms on shaping the level and composition of carbon emissions; Garbaccio et al. (1999) and Zhang (1998) studied macroeconomic and sectoral effects of policies and instruments, such as, a carbon tax, on achieving predefined targets of carbon emissions. A common omission in these studies is the role of fuel price changes in determining the amount of carbon emissions. This paper first shows China's total CO2 emissions from burning all types of fossil fuels over the 50 years or so to 2001, with those from burning coal singled out for the purpose of illustrating coal as the major CO2 emitter. Then, using annual data for the period 1985-2000, the study investigates whether changes in the relative prices of various fuels reduce coal consumption. Four sectors in the Chinese economy are selected for the study, namely, the chemical industry, the metal industry, the non-metal materials industry and the residential sector, which are top energy as well as top coal consumers. Five fuels are considered, namely, coal, crude oil, electricity, natural gas and petroleum products, ...

Baiding Hu Department; Baiding Hu

2004-01-01T23:59:59.000Z

40

MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT  

DOE Green Energy (OSTI)

The program efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program is designed to advance the carbonate fuel cell technology from full-size field test to the commercial design. FuelCell Energy, Inc. (FCE) is in the later stage of the multiyear program for development and verification of carbonate fuel cell based power plants supported by DOE/NETL with additional funding from DOD/DARPA and the FuelCell Energy team. FCE has scaled up the technology to full-size and developed DFC{reg_sign} stack and balance-of-plant (BOP) equipment technology to meet product requirements, and acquired high rate manufacturing capabilities to reduce cost. FCE has designed submegawatt (DFC300A) and megawatt (DFC1500 and DFC3000) class fuel cell products for commercialization of its DFC{reg_sign} technology. A significant progress was made during the reporting period. The reforming unit design was optimized using a three-dimensional stack simulation model. Thermal and flow uniformities of the oxidant-In flow in the stack module were improved using computational fluid dynamics based flow simulation model. The manufacturing capacity was increased. The submegawatt stack module overall cost was reduced by {approx}30% on a per kW basis. An integrated deoxidizer-prereformer design was tested successfully at submegawatt scale using fuels simulating digester gas, coal bed methane gas and peak shave (natural) gas.

H.C. Maru; M. Farooque

2003-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT  

DOE Green Energy (OSTI)

The carbonate fuel cell promises highly efficient, cost-effective and environmentally superior power generation from pipeline natural gas, coal gas, biogas, and other gaseous and liquid fuels. FuelCell Energy, Inc. has been engaged in the development of this unique technology, focusing on the development of the Direct Fuel Cell (DFC{reg_sign}). The DFC{reg_sign} design incorporates the unique internal reforming feature which allows utilization of a hydrocarbon fuel directly in the fuel cell without requiring any external reforming reactor and associated heat exchange equipment. This approach upgrades waste heat to chemical energy and thereby contributes to a higher overall conversion efficiency of fuel energy to electricity with low levels of environmental emissions. Among the internal reforming options, FuelCell Energy has selected the Indirect Internal Reforming (IIR)--Direct Internal Reforming (DIR) combination as its baseline design. The IIR-DIR combination allows reforming control (and thus cooling) over the entire cell area. This results in uniform cell temperature. In the IIR-DIR stack, a reforming unit (RU) is placed in between a group of fuel cells. The hydrocarbon fuel is first fed into the RU where it is reformed partially to hydrogen and carbon monoxide fuel using heat produced by the fuel cell electrochemical reactions. The reformed gases are then fed to the DIR chamber, where the residual fuel is reformed simultaneously with the electrochemical fuel cell reactions. FuelCell Energy plans to offer commercial DFC power plants in various sizes, focusing on the subMW as well as the MW-scale units. The plan is to offer standardized, packaged DFC power plants operating on natural gas or other hydrocarbon-containing fuels for commercial sale. The power plant design will include a diesel fuel processing option to allow dual fuel applications. These power plants, which can be shop-fabricated and sited near the user, are ideally suited for distributed power generation, industrial cogeneration, marine applications and uninterrupted power for military bases. FuelCell Energy operated a 1.8 MW plant at a utility site in 1996-97, the largest fuel cell power plant ever operated in North America. This proof-of-concept power plant demonstrated high efficiency, low emissions, reactive power control, and unattended operation capabilities. Drawing on the manufacture, field test, and post-test experience of the full-size power plant; FuelCell Energy launched the Product Design Improvement (PDI) program sponsored by government and the private-sector cost-share. The PDI efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program was initiated in December 1994. Year 2000 program accomplishments are discussed in this report.

H.C. Maru; M. Farooque

2002-02-01T23:59:59.000Z

42

MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT  

DOE Green Energy (OSTI)

The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction, leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where the fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report.

H.C. Maru; M. Farooque

2004-08-01T23:59:59.000Z

43

Affordable, Low-Carbon Diesel Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Affordable, Low-Carbon Diesel Fuel Affordable, Low-Carbon Diesel Fuel from Domestic Coal and Biomass January 14, 2009 DOE/NETL-2009/1349 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement,

44

Molten Carbonate Fuel Cell Product Design Improvement  

DOE Green Energy (OSTI)

This annual report provides results of Energy Research Corporation`s technical approach to performing the program `Molten Carbonate Fuel Cell (MCFC) Product Design Improvement` covered under the DOE-ERC Cooperative Agreement DE-FC21-95MC31184. This work is supported by DOE/METC and DOD/DARPA as well as ERC Team funds. The objective of the DOE-sponsored program is to advance the direct carbonate fuel cell technology to a level suitable for commercial entry for civilian applications. The overall objective of the DOD/DARPA initiative is to adapt the civilian 2 MW-Class fuel cell power plant for dual fuel DOD applications. This program is designed to advance the carbonate fuel cell technology from the power plant demonstration status to the commercial entry early production unit design stage. The specific objectives which will allow attainment of these overall program goals are: (1) Provide environmental information to support DOE evaluation with respect to the National Environmental Policy Act (NEPA), (2) Define market-responsive power plant requirements and specifications, (3) Establish design for multifuel, low-cost, modular, market-responsive power plant, (4) Resolve power plant manufacturing issues and define the design for the commercial manufacturing facility, (5) Acquire capabilities to support developmental testing of 0370 stacks and BOP equipment as required to prepare for commercial design, and (6) Resolve stack and BOP equipment technology issues and design, build, and field test a modular commercial prototype power plant to demonstrate readiness of the power plant for commercial entry.

NONE

1996-03-01T23:59:59.000Z

45

Fuels for fuel cells: Fuel and catalyst effects on carbon formation  

DOE Green Energy (OSTI)

The goal of this research is to explore the effects of fuels, fuel constituents, additives and impurities on the performance of on-board hydrogen generation devices and consequently on the overall performance of fuel cell systems using reformed hydrocarbon fuels. Different fuels and components have been tested in automotive scale, adiabatic autothermal reactors to observe their relative reforming characteristics with various operating conditions. Carbon formation has been modeled and was experimentally monitored in situ during operation by laser measurements of the effluent reformate. Ammonia formation was monitored, and conditions varied to observe under what conditions N H 3 is made.

Borup, R. L. (Rodney L.); Inbody, M. A. (Michael A.); Perry, W. L. (William Lee); Parkinson, W. J. (William Jerry),

2002-01-01T23:59:59.000Z

46

MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT  

DOE Green Energy (OSTI)

The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations or in distributed locations near the customer, including hospitals, schools, universities, hotels and other commercial and industrial applications. FuelCell Energy has designed three different fuel cell power plant models (DFC300, DFC1500 and DFC3000). FCE's power plants are based on its patented Direct FuelCell technology, where the fuel is directly fed to fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating, and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report. FCE's DFC products development has been carried out under a joint public-private effort with DOE being the major contributor. Current funding is primarily under a Cooperative Agreement with DOE.

H. C. Maru; M. Farooque

2003-12-19T23:59:59.000Z

47

Production of CO{sub 2} from fossil fuel burning by fuel type, 1860-1982  

SciTech Connect

Carbon dioxide emission calculations resulting from fossil fuel useage for the years 1860-1982 are presented.

Rotty, R.M.; Marland, G. [Oak Ridge Associated Universities, TN (United States). Institute for Energy Analysis

1984-09-01T23:59:59.000Z

48

Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels  

DOE Green Energy (OSTI)

This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

Turgut Gur

2010-04-30T23:59:59.000Z

49

MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT  

DOE Green Energy (OSTI)

The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the program period in the areas of technology, manufacturing processes, cost reduction and balance-of-plant equipment designs is discussed in this report.

H.C. Maru; M. Farooque

2005-03-01T23:59:59.000Z

50

MODELING AND DESIGN FOR A DIRECT CARBON FUEL CELL WITH ENTRAINED FUEL AND OXIDIZER  

DOE Green Energy (OSTI)

The novel molten carbonate fuel cell design described in this report uses porous bed electrodes. Molten carbonate, with carbon fuel particles and oxidizer entrained, is circulated through the electrodes. Carbon may be reacted directly, without gasification, in a molten carbonate fuel cell. The cathode reaction is 2CO{sub 2} + O{sub 2} 4e{sup -} {yields} 2CO{sub 3}{sup =}, while the anode reaction can be either C + 2CO{sub 3}{sup =} {yields} 3CO{sub 2} + 4e{sup -} or 2C + CO{sub 3}{sup =} {yields} 3CO + 2e{sup -}. The direct carbon fuel cell has an advantage over fuel cells using coal-derived synthesis gas in that it provides better overall efficiency and reduces equipment requirements. Also, the liquid electrolyte provides a means for transporting the solid carbon. The porous bed cell makes use of this carbon transport ability of the molten salt electrolyte. A one-dimensional model has been developed for predicting the performance of this cell. For the cathode, dependent variables are superficial O{sub 2} and CO{sub 2} fluxes in the gas phase, superficial O{sub 2} and CO{sub 2} fluxes in the liquid phase, superficial current density through the electrolyte, and electrolyte potential. The variables are related by correlations, from the literature, for gas-liquid mass transfer, liquid-solid mass transfer, cathode current density, electrode overpotential, and resistivity of a liquid with entrained gas. For the anode, dependent variables are superficial CO{sub 2} flux in the gas phase, superficial CO{sub 2} flux in the liquid phase, superficial C flux, superficial current density through the electrolyte, and electrolyte potential. The same types of correlations relate the variables as in the cathode, with the addition of a correlation for resistivity of a fluidized bed. CO production is not considered, and axial dispersion is neglected. The model shows behavior typical of porous bed electrodes used in electrochemical processes. Efficiency is comparable to that of membrane electrode fuel cells. Effective bed depths are on the order of 1-5 centimeter, giving power/volume lower than for membrane electrode cells. The porous bed design, however, uses less expensive materials and is more resistant to fouling by coal impurities. The model will be used in the second phase of the project to design a laboratory-scale prototype cell. The prototype cell will demonstrate the concept and provide experimental data for improving the model.

Alan A. Kornhauser; Ritesh Agarwal

2005-04-01T23:59:59.000Z

51

Development of internal reforming carbonate fuel cell stack technology  

DOE Green Energy (OSTI)

Activities under this contract focused on the development of a coal-fueled carbonate fuel cell system design and the stack technology consistent with the system design. The overall contract effort was divided into three phases. The first phase, completed in January 1988, provided carbonate fuel cell component scale-up from the 1ft{sup 2} size to the commercial 4ft{sup 2} size. The second phase of the program provided the coal-fueled carbonate fuel cell system (CGCFC) conceptual design and carried out initial research and development needs of the CGCFC system. The final phase of the program emphasized stack height scale-up and improvement of stack life. The results of the second and third phases are included in this report. Program activities under Phase 2 and 3 were designed to address several key development areas to prepare the carbonate fuel cell system, particularly the coal-fueled CFC power plant, for commercialization in late 1990's. The issues addressed include: Coal-Gas Related Considerations; Cell and Stack Technology Improvement; Carbonate Fuel Cell Stack Design Development; Stack Tests for Design Verification; Full-Size Stack Design; Test Facility Development; Carbonate Fuel Cell Stack Cost Assessment; and Coal-Fueled Carbonate Fuel Cell System Design. All the major program objectives in each of the topical areas were successfully achieved. This report is organized along the above-mentioned topical areas. Each topical area has been processed separately for inclusion on the data base.

Farooque, M.

1990-10-01T23:59:59.000Z

52

The effect of fuel type in unsaturated spent fuel tests  

Science Conference Proceedings (OSTI)

Two well-characterized types of spent nuclear fuel (ATM-103 and ATM-106) were tested under simulated unsaturated conditions with simulated groundwater at 90{degree}C. The actinides present in the leachate were measured after periods of approximately 60, 120, and 275 days. The vessels were acid stripped after 120 and 275 days. Both colloidal and soluble actinide species were detected in the leachates which had pHs ranging from 4 to 7. Alpha spectroscopy studies of filtered and unfiltered leachates showed that large amounts of actinides may be bound in colloids. The uranium phases identified in the colloids were schoepite and soddyite. The actinide release behavior of the two fuels appears to be different. The ATM-106 fuel began to release actinides later than the ATM-103 fuel, but after 275 days, it had released more. The amount of americium released from the two fuels was a higher percentage of the maximum amount of americium present than was the percentage of the simultaneous amount of uranium released.

Finn, P.A.; Gong, M.; Bates, J.K.; Emery, J.W.; Hoh, J.C.

1994-04-01T23:59:59.000Z

53

Idaho Kerosene-Type Jet Fuel Retail Sales by Refiners ...  

U.S. Energy Information Administration (EIA)

Referring Pages: Idaho Kerosene-Type Jet Fuel Refiner Sales Volumes; Idaho Sales to End Users Refiner Sales Volumes of Aviation Fuels, Kerosene, ...

54

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

55

Integration of carbonate fuel cells with advanced coal gasification systems  

DOE Green Energy (OSTI)

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

56

Molten carbonate fuel cell technology improvement  

DOE Green Energy (OSTI)

This report summarizes the work performed under Department of Energy Contract DEAC21-87MC23270, Molten Carbonate Fuel Cell Technology Improvement.'' This work was conducted over a three year period and consisted of three major efforts. The first major effort was the power plant system study which reviewed the competitive requirements for a coal gasifier/molten carbonate fuel cell power plant, produced a conceptual design of a CG/MCFC, and defined the technology development requirements. This effort is discussed in Section 1 of the report. The second major effort involved the design and development of a new MCFC cell configuration which reduced the material content of the cell to a level competitive with competing power plants, simplified the cell configuration to make the components more manufacturable and adaptable to continuous low cost processing techniques, and introduced new-low-pressure drop flow fields for both reactant gases. The new flow fields permitted the incorporation of recirculation systems in both reactant gas systems, permitting simplified cooling techniques and the ability to operate on both natural gas and a wide variety of gasifier fuels. This cell technology improvement is discussed in Section 2. The third major effort involved the scaleup of the new cell configuration to the full-area, 8-sq-ft size and resulted in components used for a 25-kW, 20-cell stack verification test. The verification test was completed with a run of 2200 hours, exceeding the goal of 2000 hours and verifying the new cell design. TWs test, in turn, provided the confidence to proceed to a 100-kW demonstration which is the goal of the subsequent DOE program. The scaleup and stack verification tests are discussed in Sections 3, 4, 5, and 6 of this report.

Not Available

1991-06-01T23:59:59.000Z

57

World Energy Consumption by Fuel Type, 1970-2020  

Gasoline and Diesel Fuel Update (EIA)

Energy Consumption by Fuel Type, 1970-2020 Energy Consumption by Fuel Type, 1970-2020 Source: EIA, International Energy Outlook 2000 Previous slide Next slide Back to first slide View graphic version Notes: Natural gas is projected to be the fastest-growing component of primary world energy consumption, more than doubling between 1997 and 2020. Gas accounts for the largest increment in electricity generation (41 percent of the total increment of energy used for electricity generation). Combined-cycle gas turbine power plants offer some of the highest commercially available plant efficiencies, and natural gas is environmentally attractive because it emits less sulfur dioxide, carbon dioxide, and particulate matter than does oil or coal. In the IEO2000 projection, world natural gas consumption reaches the level of coal by

58

Coal derived fuel gases for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Product streams from state-of-the-art and future coal gasification systems are characterized to guide fuel cell program planners and researchers in establishing performance goals and developing materials for molten carbonate fuel cells that will be compatible with gasifier product gases. Results are presented on: (1) the range of gasifier raw-gas compositions available from the major classes of coal gasifiers; (2) the degree of gas clean-up achievable with state-of-the-art and future gas clean-up systems; and (3) the energy penalties associated with gas clean-up. The study encompasses fixed-bed, fluid-bed, entrained-bed, and molten salt gasifiers operating with Eastern bituminous and Western subbituminous coals. Gasifiers operating with air and oxygen blowing are evaluated, and the coal gasification product streams are characterized with respect to: (1) major gas stream constituents, e.g., CO, H/sub 2/, CO/sub 2/, CH/sub 4/, N/sub 2/, H/sub 2/O; (2) major gas stream contaminants, e.g., H/sub 2/S, COS, particulates, tars, etc.; and (3) trace element contaminants, e.g., Na, K, V, Cl, Hg, etc.

Not Available

1979-11-01T23:59:59.000Z

59

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

UCD—ITS—RR—07—07 A Low-Carbon Fuel Standard for CaliforniaEnergy Commission. A Low Carbon Fuel Standard For CaliforniaCalifornia, Davis. A Low Carbon Fuel Standard For California

Farrell, Alexander; Sperling, Daniel

2007-01-01T23:59:59.000Z

60

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

A Low-Carbon Fuel Standard for California Part 1: TechnicalOrder S-01-07: Low Carbon Fuel Standard. Sacramento, CA.California, Davis. A Low Carbon Fuel Standard For California

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Electrolyte paste for molten carbonate fuel cells  

DOE Patents (OSTI)

The electrolyte matrix and electrolyte reservoir plates in a molten carbonate fuel cell power plant stack are filled with electrolyte by applying a paste of dry electrolyte powder entrained in a dissipatable carrier to the reactant flow channels in the current collector plate. The stack plates are preformed and solidified to final operating condition so that they are self sustaining and can be disposed one atop the other to form the power plant stack. Packing the reactant flow channels with the electrolyte paste allows the use of thinner electrode plates, particularly on the anode side of the cells. The use of the packed electrolyte paste provides sufficient electrolyte to fill the matrix and to entrain excess electrolyte in the electrode plates, which also serve as excess electrolyte reservoirs. When the stack is heated up to operating temperatures, the electrolyte in the paste melts, the carrier vaporizes, or chemically decomposes, and the melted electrolyte is absorbed into the matrix and electrode plates.

Bregoli, Lawrance J. (Southwick, MA); Pearson, Mark L. (New London, CT)

1995-01-01T23:59:59.000Z

62

FUEL PROCESSING FOR FUEL CELLS: EFFECTS ON CATALYST DURABILITY AND CARBON FORMATION  

DOE Green Energy (OSTI)

On-board production of hydrogen for fuel cells for automotive applications is a challenging developmental task. The fuel processor must show long term durability and under challenging conditions. Fuel processor catalysts in automotive fuel processors will be exposed to large thermal variations, vibrations, exposure to uncontrolled ambient conditions, and various impurities from ambient air and from fuel. For the commercialization of fuel processors, the delineation of effects on catalyst activity and durability are required. We are studying fuels and fuel constituent effects on the fuel processor system as part of the DOE Fuel Cells for Transportation program. Pure fuel components are tested to delineate the fuel component effect on the fuel processor and fuel processor catalysts. Component blends are used to simulate ''real fuels'', with various fuel mixtures being examined such as reformulated gasoline and naptha. The aliphatic, napthenic, olefin and aromatic content are simulated to represent the chemical kinetics of possible detrimental reactions, such as carbon formation, during fuel testing. Testing has examined the fuel processing performance of different fuel components to help elucidate the fuel constituent effects on fuel processing performance and upon catalyst durability. Testing has been conducted with vapor fuels, including natural gas and pure methane. The testing of pure methane and comparable testing with natural gas (97% methane) have shown some measurable differences in performance in the fuel processor. Major gasoline fuel constituents, such as aliphatic compounds, napthanes, and aromatics have been compared for their effect on the fuel processing performance. Experiments have been conducted using high-purity compounds to observe the fuel processing properties of the individual components and to document individual fuel component performance. The relative carbon formation of different fuel constituents have been measured by monitoring carbon via in situ laser optics, and by monitoring carbon buildup on the catalyst surface. The fuel processing performance of the individual components is compared with the fuel processing performance of blended fuel components and the reformulated gasoline to examine synergistic or detrimental effects the fuel components have in a real fuel blend.

R. BORUP; M. INBODY; B. MORTON; L. BROWN

2001-05-01T23:59:59.000Z

63

Novel carbon-ion fuel cells. Quarterly technical report, April--June 1996  

DOE Green Energy (OSTI)

This report presents research to develop a new type of of fuel cell using a solid electrolyte that transports carbon ions. This new class of fuel cell would use solid C dissolved in molten metal (carbide) as a fuel reservoir and anode; thus expensive gas or liquid fuel would not be required. Thermodynamic efficiency of carbon-ion fuel cells is reviewed, as are electrolyte crystal structures (oxide and fluorite carbides). The sequence of laboratory research procedures for developing a solid C-ion electrolyte and to determine the ionic conductivity of C ions therein is outlined; results of the laboratory research to date are summarized, including XRD analysis of crystal structures and transition temperatures of carbides (La, Ce, Be, Al) and SIMS of carbon isotopes.

Cocks, F.H.

1996-11-01T23:59:59.000Z

64

Production of CO2 from Fossil Fuel Burning by Fuel Type, 1860...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fossil Fuel CO2 Emissions Historical Global Estimates Production of CO2 from Fossil Fuel Burning by Fuel Type, 1860-1982 (NDP-006) DOI: 10.3334CDIACffe.ndp006 image Data image...

65

U.S. Exports of Kerosene-Type Jet Fuel (Thousand Barrels per Day)  

U.S. Energy Information Administration (EIA)

Kerosene-Type Jet Fuel Exports; Kerosene-Type Jet Fuel Exports by Destination; Kerosene-Type Jet Fuel Supply and Disposition ...

66

Carbon Monoxide in type II supernovae  

E-Print Network (OSTI)

Infrared spectra of two type II supernovae 6 months after explosion are presented. The spectra exhibit a strong similarity to the observations of SN 1987A and other type II SNe at comparable epochs. The continuum can be fitted with a cool black body and the hydrogen lines have emissivities that are approximately those of a Case B recombination spectrum. The data extend far enough into the thermal region to detect emission by the first overtone of carbon monoxide. The molecular emission is modeled and compared with that in the spectra of SN 1987A. It is found that the flux in the CO first overtone is comparable to that found in SN 1987A. We argue that Carbon Monoxide forms in the ejecta of all type II SNe during the first year after explosion.

J. Spyromilio; B. Leibundgut; R. Gilmozzi

2001-07-16T23:59:59.000Z

67

Direct Conversion of Carbon Fuels in a Molten Carbonate Fuel Cell  

DOE Green Energy (OSTI)

Anodes of elemental carbon may be discharged in a galvanic cell using a molten carbonate electrolyte, a nickel-foam anode-current collector, and a porous nickel air cathode to achieve power densities of 40-100 mW/cm{sup 2}. We report cell and anode polarization, surface area, primary particle size and a crystallization index for nine particulate carbon samples derived from fuel oil, methane, coal, charred biological material and petroleum coke. At 800 C, current densities of 50-125 mA/cm{sup 2} were measured at a representative cell voltage of 0.8 V. Power densities for cells with two carbon-anode materials were found to be nearly the same on scales of 2.8- and 60 cm{sup 2} active area. Constant current operation of a small cell was accompanied by constant voltage during multiple tests of 10-30 hour duration. Cell voltage fell off after the carbon inventory was consumed. Three different cathode structures are compared, indicating that an LLNL fabricated porous nickel electrode with <10 {micro}m pores provides improved rates compared with nickel foam with 100-300 {micro}m pores. Petroleum coke containing substantial sulfur and ash discharges at a slightly lower rate than purified petroleum coke. The sulfur leads to degradation of the anode current collector over time. A conceptual model for electrochemical reactivity of carbon is presented which indicates the importance of (1) bulk lattice disorder, which continually provides surface reactive sites during anodic dissolution and (2) electrical conductivity, which lowers the ohmic component of anode polarization.

Cherepy, N J; Fiet, K J; Krueger, R; Jankowski, A F; Cooper, J F

2004-01-28T23:59:59.000Z

68

Fuel assembly transfer basket for pool type nuclear reactor vessels  

DOE Patents (OSTI)

A fuel assembly transfer basket for a pool type, liquid metal cooled nuclear reactor having a side access loading and unloading port for receiving and relinquishing fuel assemblies during transfer.

Fanning, Alan W. (San Jose, CA); Ramsour, Nicholas L. (San Jose, CA)

1991-01-01T23:59:59.000Z

69

Carbon Capture by Fossil Fuel Power Plants: An Economic Analysis  

Science Conference Proceedings (OSTI)

For fossil fuel power plants to be built in the future, carbon capture and storage (CCS) technologies offer the potential for significant reductions in carbon dioxide (CO2) emissions. We examine the break-even value for CCS adoptions, that ... Keywords: accounting, cost--benefit analysis, energy, energy policies, environment, government, natural resources, pollution

Özge ??legen; Stefan Reichelstein

2011-01-01T23:59:59.000Z

70

Ex-situ and In-situ Stability Studies of PEM Fuel Cell Catalysts: the effect of carbon type and humidification on the thermal degradation of carbon supported catalysts  

DOE Green Energy (OSTI)

One of the most significant challenges for proton exchange membrane fuel cells in stationary power generation systems is lifetime, where 40,000 hours of operation with less than 10% decay in performance is desired. There are several different membrane electrode assembly (MEA) associated degradation mechanisms inhibiting MEAs from obtaining their desired lifetime targets. The focus of this research is on the loss of cathode surface area over time, which results in MEA performance losses, since MEA performance is proportional to cathode catalyst surface area. Two proposed mechanisms, support oxidation and platinum dissolution, are studied using different accelerated tests. These results are compared to cathode catalyst surface area loss data from real-time fuel cell tests in order to decouple the two degradation mechanisms.

Haugen, G. M.; Stevens, D. A.; Hicks, M. T.; Dahn, J. R.

2005-11-01T23:59:59.000Z

71

High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation  

SciTech Connect

Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power generation cycles are: (1) increased efficiency by a factor of up to 2 over many conventional fossil fuel steam plants, (2) reduced power generation cost, especially for increasing fossil fuel cost, (3) reduced CO2 emission per kWh, and (4) direct sequestration or reuse (e.g., in enhanced oil or NG recovery) of the CO{sub 2} product.

Steinberg, M; Cooper, J F; Cherepy, N

2002-01-02T23:59:59.000Z

72

Demonstration of a Carbonate Fuel Cell on Coal Derived Gas  

E-Print Network (OSTI)

Several studies indicate that carbonate fuel cell systems have the potential to offer efficient, cost competitive, and environmentally preferred power plants operating on natural gas or coal derived gas (“syn-gas”). To date, however, no fuel cell system has run on actual syn-gas. Consequently, the Electric Power Research Institute (“EPRI”) has sponsored a 20 kW carbonate fuel cell pilot plant that will begin operating in March at Destec Energy’s coal gasification plant in Plaquemine, Louisiana. The primary purpose of the test is to determine the effect of syn-gas contaminants on the performance and life of the carbonate fuel cell. This paper will describe the project objectives, design aspects of the pilot facility, and the status of the project.

Rastler, D. M.; Keeler, C. G.; Chi, C. V.

1993-03-01T23:59:59.000Z

73

Oxygen electrode reaction in molten carbonate fuel cells  

DOE Green Energy (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

74

Spectroelectrochemical study of the role played by carbon functionality in fuel cell electrodes  

Science Conference Proceedings (OSTI)

X-ray absorption spectroscopy was used to identify specific types of nitrogen and sulfur-based carbon functionality present in the carbon black supports of fuel cell anodes and cathodes. The effects of these functional groups on the electrocatalytic performance of small platinum particles, dispersed on the carbon, during methanol oxidation and oxygen reduction were assessed. Electrodes functionalized with nitrogen had enhanced catalytic activities toward oxygen reduction and methanol oxidation relative to untreated electrodes. Although electrodes with sulfur functionality had higher oxygen reduction activities than untreated carbons, the activity of these electrodes toward methanol oxidation was found to be lower than electrodes manufactured from untreated carbon. It was found that carbon supports functionalized with both nitrogen and sulfur initiated the formation of Pt particles smaller in size than those observed on untreated carbon supports.

Roy, S.C.; Harding, A.W.; Russell, A.E.; Thomas, K.M. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1997-07-01T23:59:59.000Z

75

Recovery of Technetium and Iodine from Spent ATW TRISO Type Fuels.  

SciTech Connect

The Accelerator Transmutation of Waste (ATW) program is being developed to determine the feasibility of separating and transmutating the transactinides (Pu-Cm) and long-lived fission product (99Tc and 129I) from spent LWR fuel. Several types of ATW fuels have been suggested to transmutate the Pu-Cm fraction including TRISO type fuels. An ATW TRISO fuel would consist of a Pu-Cm oxide kernel surrounded by several layers of pyrolytic carbon, a layer of SiC, and an outer layer of pyrolytic carbon. Processing of the spent ATW fuel would involve the crush, burn, and leach approach used on normal TRISO fuels. This report describes experiments that determine the potential behavior of the two long-lived fission products, 99Tc and 129I, in this processing. Iodine can be removed and trapped during the burning of the carbon from the fuel. Some technetium may volatilize in the latter stages of the burn but the bulk of it will have to be recovered after dissolution of the oxide residue.

Schroeder, N. C. (Norman C.); Attrep, Moses

2001-01-01T23:59:59.000Z

76

Figure 77. Electricity generation capacity additions by fuel type ...  

U.S. Energy Information Administration (EIA)

Sheet3 Sheet2 Sheet1 Figure 77. Electricity generation capacity additions by fuel type, including combined heat and power, 2012-2040 (gigawatts) Coal

77

A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells  

SciTech Connect

The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

2013-01-01T23:59:59.000Z

78

Tracing Fuel Component Carbon in the Emissions from Diesel Engines  

DOE Green Energy (OSTI)

The addition of oxygenates to diesel fuel can reduce particulate emissions, but the underlying chemical pathways for the reductions are not well understood. While measurements of particulate matter (PM), unburned hydrocarbons (HC), and carbon monoxide (CO) are routine, determining the contribution of carbon atoms in the original fuel molecules to the formation of these undesired exhaust emissions has proven difficult. Renewable bio-derived fuels (ethanol or bio-diesel) containing a universal distribution of contemporary carbon are easily traced by accelerator mass spectrometry (AMS). These measurements provide general information about the emissions of bio-derived fuels. Another approach exploits synthetic organic chemistry to place {sup 14}C atoms in a specific bond position in a specific fuel molecule. The highly labeled fuel molecule is then diluted in {sup 14}C-free petroleum-derived stock to make a contemporary petroleum fuel suitable for tracing. The specific {sup 14}C atoms are then traced through the combustion event to determine whether they reside in PM, HC, CO, CO{sub 2}, or other emission products. This knowledge of how specific molecular structures produce certain emissions can be used to refine chemical-kinetic combustion models and to optimize fuel composition to reduce undesired emissions. Due to the high sensitivity of the technique and the lack of appreciable {sup 14}C in fossil fuels, fuels for AMS experiments can be labeled with modern levels of {sup 14}C and still produce a strong signal. Since the fuel is not radioactive, emission tests can be conducted in any conventional engine lab, dynamometer facility, or on the open road.

Buchholz, B A; Mueller, C J; Martin, G C; Cheng, A S E; Dibble, R W; Frantz, B R

2002-10-14T23:59:59.000Z

79

Multi-criteria comparison of fuel policies: Renewable fuel mandate, fuel emission-standards, and fuel carbon tax  

E-Print Network (OSTI)

comparison of fuel policies: Renewable fuel mandate, fuelcomparison of fuel policies: Renewable fuel mandate, fuel121, 2011. C. Fischer. Renewable Portfolio Standards: When

Rajagopal, Deepak; Hochman, G.; Zilberman, D.

2012-01-01T23:59:59.000Z

80

Air blast type coal slurry fuel injector  

SciTech Connect

A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

Phatak, Ramkrishna G. (San Antonio, TX)

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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81

Air blast type coal slurry fuel injector  

DOE Patents (OSTI)

A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

Phatak, R.G.

1984-08-31T23:59:59.000Z

82

Fast Reactor Fuel Type and Reactor Safety Performance  

Science Conference Proceedings (OSTI)

Fast Reactor Fuel Type and Reactor Safety Performance R. Wigeland , Idaho National Laboratory J. Cahalan, Argonne National Laboratory The sodium-cooled fast neutron reactor is currently being evaluated for the efficient transmutation of the highly-hazardous, long-lived, transuranic elements that are present in spent nuclear fuel. One of the fundamental choices that will be made is the selection of the fuel type for the fast reactor, whether oxide, metal, carbide, nitride, etc. It is likely that a decision on the fuel type will need to be made before many of the related technologies and facilities can be selected, from fuel fabrication to spent fuel reprocessing. A decision on fuel type should consider all impacts on the fast reactor system, including safety. Past work has demonstrated that the choice of fuel type may have a significant impact on the severity of consequences arising from accidents, especially for severe accidents of low probability. In this paper, the response of sodium-cooled fast reactors is discussed for both oxide and metal fuel types, highlighting the similarities and differences in reactor response and accident consequences. Any fast reactor facility must be designed to be able to successfully prevent, mitigate, or accommodate all consequences of potential events, including accidents. This is typically accomplished by using multiple barriers to the release of radiation, including the cladding on the fuel, the intact primary cooling system, and most visibly the reactor containment building. More recently, this has also included the use of ‘inherent safety’ concepts to reduce or eliminate the potential for serious damage in some cases. Past experience with oxide and metal fuel has demonstrated that both fuel types are suitable for use as fuel in a sodium-cooled fast reactor. However, safety analyses for these two fuel types have also shown that there can be substantial differences in accident consequences due to the neutronic and thermophysical properties of the fuel and their compatibility with the reactor coolant, with corresponding differences in the challenges presented to the reactor developers. Accident phenomena are discussed for the sodium-cooled fast reactor based on the mechanistic progression of conditions from accident initiation to accident termination, whether a benign state is achieved or more severe consequences are expected. General principles connecting accident phenomena and fuel properties are developed from the oxide and metal fuel safety analyses, providing guidelines that can be used as part of the evaluation for selection of fuel type for the sodium-cooled fast reactor.

R. Wigeland; J. Cahalan

2009-09-01T23:59:59.000Z

83

Program plan for molten carbonate fuel-cell systems development  

DOE Green Energy (OSTI)

The purpose of this document is to describe in both programmatic and technical terms the methodology that the US Department of Energy will use to commercialize a molten carbonate fuel cell power plant. Responsibility for the planning and management of the program resides in the molten carbonate fuel cell program office at the Argonne National Laboratory which reports to the Assistant Director for Fuel Cells in the Division of Fossil Fuel utilization of DOE/FE. The actual development of technology is carried out by selected contractors. The technology development phase of the program will culminate with the construction and operation of two demonstration power plants. The first power plant will be an industrial cogeneration plant which will be completed in 1987. The other power plant will be a baseload electric power plant to be completed in 1989.

Not Available

1978-10-27T23:59:59.000Z

84

King County Carbonate Fuel Cell Demonstration Project: 2005 Update  

Science Conference Proceedings (OSTI)

This case study documents the ongoing demonstration experiences of a 1-MW carbonate fuel cell system operating on anaerobic digester gas at a wastewater treatment plant in King County, Washington. This is a follow-up to a previous EPRI report on the same project, 1011472, and summarizes operational experience and performance data obtained in 2005. The case study is one of several fuel cell project case studies under research by the EPRI Distributed Energy Resources Program. This case study is designed to...

2006-03-07T23:59:59.000Z

85

Carbon composite for a PEM fuel cell bipolar plate  

DOE Green Energy (OSTI)

The current major cost component for proton exchange membrane fuel cells is bipolar plate. An option being explored for replacing the current, nominal machined graphite component is a molded carbon fiber material. One face and the volume of the component will be left porous, while the opposite surface and sides are hermetically sealed via chemical vapor infiltration of carbon. This paper will address initial work on the concept.

Besmann, T.M.; Klett, J.W.; Burchell, T.D.

1997-12-01T23:59:59.000Z

86

High efficiency carbonate fuel cell/turbine hybrid power cycles  

SciTech Connect

Carbonate fuel cells developed in commercial 2.85 MW size, have an efficiency of 57.9%. Studies of higher efficiency hybrid power cycles were conducted to identify an economically competitive system and an efficiency over 65%. A hybrid power cycle was identified that includes a direct carbonate fuel cell, a gas turbine, and a steam cycle, which generates power at a LHV efficiency over 70%; it is called a Tandem Technology Cycle (TTC). In a TTC operating on natural gas fuel, 95% of the fuel is mixed with recycled fuel cell anode exhaust, providing water for reforming the fuel, and flows to a direct carbonate fuel cell system which generates 72% of the power. The portion of fuel cell anode exhaust not recycled, is burned and heat is transferred to compressed air from a gas turbine, heating it to 1800 F. The stream is then heated to 2000 F in gas turbine burner and expands through the turbine generating 13% of the power. Half the gas turbine exhaust flows to anode exhaust burner and the rest flows to the fuel cell cathodes providing the O2 and CO2 needed in the electrochemical reaction. Studies of the TTC for 200 and 20 MW size plants quantified performance, emissions and cost-of-electricity, and compared the TTC to gas turbine combined cycles. A 200-MW TTC plant has an efficiency of 72.6%; estimated cost of electricity is 45.8 mills/kWhr. A 20-MW TTC plant has an efficiency of 65.2% and a cost of electricity of 50 mills/kWhr.

Steinfeld, G.

1996-12-31T23:59:59.000Z

87

Hypergolic fuel detection using individual single walled carbon nanotube networks  

SciTech Connect

Accurate and reliable detection of hypergolic fuels such as hydrazine (N{sub 2}H{sub 4}) and its derivatives is vital to missile defense, aviation, homeland security, and the chemical industry. More importantly these sensors need to be capable of operation at low temperatures (below room temperature) as most of the widely used chemical sensors operate at high temperatures (above 300 deg. C). In this research a simple and highly sensitive single walled carbon nanotube (SWNT) network sensor was developed for real time monitoring of hydrazine leaks to concentrations at parts per million levels. Upon exposure to hydrazine vapor, the resistance of the air exposed nanotubes (p-type) is observed to increase rapidly while that of the vacuum-degassed nanotubes (n-type) is observed to decrease. It was found that the resistance of the sample can be recovered through vacuum pumping and exposure to ultraviolet light. The experimental results support the electrochemical charge transfer mechanism between the oxygen redox couple of the ambient and the Fermi level of the SWNT. Theoretical results of the hydrazine-SWNT interaction are compared with the experimental observations. It was found that a monolayer of water molecules on the SWNT is necessary to induce strong interactions between hydrazine and the SWNT by way of introducing new occupied states near the bottom of the conduction band of the SWNT.

Desai, S. C.; Willitsford, A. H. [Department of Electrical and Computer Engineering, University of Louisville, Louisville, Kentucky 40292 (United States); Sumanasekera, G. U. [Department of Electrical and Computer Engineering, University of Louisville, Louisville, Kentucky 40292 (United States); Department of Physics and Astronomy, University of Louisville, Louisville, Kentucky 40292 (United States); Yu, M.; Jayanthi, C. S.; Wu, S. Y. [Department of Physics and Astronomy, University of Louisville, Louisville, Kentucky 40292 (United States); Tian, W. Q. [State Key Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023 (China)

2010-06-15T23:59:59.000Z

88

Cathode-preparation method for molten-carbonate fuel cell  

DOE Green Energy (OSTI)

A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

Smith, J.L.; Sim, J.W.; Kucera, E.H.

1982-01-28T23:59:59.000Z

89

All ceramic structure for molten carbonate fuel cell  

DOE Patents (OSTI)

An all-ceramic molten carbonate fuel cell having a composition formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The structure includes an anode and cathode separated by an electronically conductive interconnect. The electrodes and interconnect are compositions ceramic materials. Various combinations of ceramic compositions for the anode, cathode and interconnect are disclosed. The fuel cell exhibits stability in the fuel gas and oxidizing environments. It presents reduced sealing and expansion problems in fabrication and has improved long-term corrosion resistance.

Smith, J.L.; Kucera, E.H.

1991-01-01T23:59:59.000Z

90

High efficiency carbonate fuel cell/turbine hybrid power cycle  

Science Conference Proceedings (OSTI)

The hybrid power cycle studies were conducted to identify a high efficiency, economically competitive system. A hybrid power cycle which generates power at an LHV efficiency > 70% was identified that includes an atmospheric pressure direct carbonate fuel cell, a gas turbine, and a steam cycle. In this cycle, natural gas fuel is mixed with recycled fuel cell anode exhaust, providing water for reforming fuel. The mixed gas then flows to a direct carbonate fuel cell which generates about 70% of the power. The portion of the anode exhaust which is not recycled is burned and heat transferred through a heat exchanger (HX) to the compressed air from a gas turbine. The heated compressed air is then heated further in the gas turbine burner and expands through the turbine generating 15% of the power. Half the exhaust from the turbine provides air for the anode exhaust burner. All of the turbine exhaust eventually flows through the fuel cell cathodes providing the O2 and CO2 needed in the electrochemical reaction. Exhaust from the cathodes flows to a steam system (heat recovery steam generator, staged steam turbine generating 15% of the cycle power). Simulation of a 200 MW plant with a hybrid power cycle had an LHV efficiency of 72.6%. Power output and efficiency are insensitive to ambient temperature, compared to a gas turbine combined cycle; NOx emissions are 75% lower. Estimated cost of electricity for 200 MW is 46 mills/kWh, which is competitive with combined cycle where fuel cost is > $5.8/MMBTU. Key requirement is HX; in the 200 MW plant studies, a HX operating at 1094 C using high temperature HX technology currently under development by METC for coal gassifiers was assumed. A study of a near term (20 MW) high efficiency direct carbonate fuel cell/turbine hybrid power cycle has also been completed.

Steinfeld, G.; Maru, H.C. [Energy Research Corp., Danbury, CT (United States); Sanderson, R.A. [Sanderson (Robert) and Associates, Wethersfield, CT (United States)

1996-07-01T23:59:59.000Z

91

Oxygen electrode in molten carbonate fuel cells  

DOE Green Energy (OSTI)

The oxygen reduction reaction on a gold electrode in lithium carbonate melt was investigated to determine the influence of partial pressure of carbon dioxide and temperature on electrode kinetics and oxygen solubility by using cyclic Voltammetry and impedance analysis techniques. During this quarter, the impedance data were analyzed by a Complex Nonlinear Least Square (CNLS) Parameter estimation program to determine the kinetic and the mass transfer related parameters such as charge transfer resistance, double layer capacitance, solution resistance, and Warburg coefficient. The estimated parameters were used to obtain the C0{sub 2} reaction orders and apparent activation energies for the exchange current density and the mass transfer parameter (D{sub o}{sup {1/2}}C{sub o}*).

Dave, B.B.; Srinivasan, S.; White, R.E.; Appleby, A.J.

1989-01-01T23:59:59.000Z

92

Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis  

Fuel Cell Technologies Publication and Product Library (EERE)

This report details technical and cost gap analyses of molten carbonate fuel cell and phosphoric acid fuel cell stationary fuel cell power plants and identifies pathways for reducing costs.

93

Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis  

DOE Green Energy (OSTI)

This report describes the technical and cost gap analysis performed to identify pathways for reducing the costs of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell (PAFC) stationary fuel cell power plants.

Remick, R.; Wheeler, D.

2010-09-01T23:59:59.000Z

94

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

E-Print Network (OSTI)

Can the envisaged reductions of fossil fuel CO2 emissions beGoulden. 2008. Where do Fossil Fuel Carbon Dioxide Emissionsof season-averaged fossil fuel CO 2 emissions (Riley et

de la Rue du Can, Stephane

2010-01-01T23:59:59.000Z

95

Fossil fuel derivatives with reduced carbon. Phase I final report  

Science Conference Proceedings (OSTI)

This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

1999-06-30T23:59:59.000Z

96

Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel  

Gasoline and Diesel Fuel Update (EIA)

Gallon Excluding Taxes) - Continued Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Sales to End Users Sales for Resale Sales to End Users Sales for Resale...

97

Fuel Ethanol Total Stocks Stocks by Type  

U.S. Energy Information Administration (EIA)

Stock Type: Download Series History: Definitions, Sources & Notes: Show Data By: Product: Stock Type: Area: Feb-13 Mar-13 Apr-13 May-13 Jun-13 Jul-13 View History; U ...

98

Search by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Vehicle Type Select Year... 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000...

99

Case Studies of 250-kW Carbonate Fuel Cells: Demonstration of Three FuelCell Energy Systems at LADWP  

Science Conference Proceedings (OSTI)

This case study documents the demonstration experiences and lessons learned from the purchase, installation, and operation of three carbonate fuel cell systems built by FuelCell Energy and deployed by the Los Angeles Department of Water and Power (LADWP). These projects are among several fuel cell project case studies under research by EPRI's Distributed Energy Resources Program. They are designed to help utilities and other interested parties understand the early applications of carbonate fuel cells to ...

2005-03-31T23:59:59.000Z

100

Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Austin Lays Plans for Austin Lays Plans for Carbon-Neutral City Fleet to someone by E-mail Share Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on Facebook Tweet about Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on Twitter Bookmark Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on Google Bookmark Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on Delicious Rank Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on Digg Find More places to share Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral City Fleet on AddThis.com... Jan. 15, 2011 Austin Lays Plans for Carbon-Neutral City Fleet L earn how Austin, Texas, is planning to build a carbon-neutral city fleet

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

S. Denning, C. B. A Low Carbon Fuel Standard for California227-241. E4Tech. 2007. Carbon Reporting under the Renewablepatterns and mechanisms of carbon exchange by terrestrial

Sperling, Daniel; Farrell, Alexander

2007-01-01T23:59:59.000Z

102

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

S. Denning, C. B. A Low Carbon Fuel Standard for California227-241. E4Tech. 2007. Carbon Reporting under the Renewablepatterns and mechanisms of carbon exchange by terrestrial

2007-01-01T23:59:59.000Z

103

Comparison of platinum deposit methods on carbon aerogels used in Proton Exchange Membrane Fuel Cells (PEMFC)  

E-Print Network (OSTI)

Comparison of platinum deposit methods on carbon aerogels used in Proton Exchange Membrane Fuel: carbon aerogel, platinum, Strong Electrostatic Adsorption, chemical reduction, UV With the rarefaction the diffusive phenomena limiting electrochemical performances. By contrast, carbon aerogels present

Paris-Sud XI, Université de

104

Electrolyte matrix for molten carbonate fuel cells  

DOE Patents (OSTI)

A matrix for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 .mu.m to 20 .mu.m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling.

Huang, Chao M. (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

1999-01-01T23:59:59.000Z

105

Electrolyte matrix for molten carbonate fuel cells  

DOE Patents (OSTI)

A matrix is described for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 {micro}m to 20 {micro}m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling. 5 figs.

Huang, C.M.; Yuh, C.Y.

1999-02-09T23:59:59.000Z

106

DOE Hydrogen and Fuel Cells Program Record 5003: Carbon Displacement Using Net-Zero Carbon Sources  

NLE Websites -- All DOE Office Websites (Extended Search)

3 Date: January 4, 2006 3 Date: January 4, 2006 Title: Carbon Displacement Using Net-Zero Carbon Sources Originator: Elvin Yuzugullu Approved by: JoAnn Milliken Date: April 4, 2006 Item: "... if 175 billion kWh of grid electricity (10% of the growth of the electric generation market in 2025) is replaced by fuel cells operating on hydrogen at 50% LHV efficiency, about 10.5 million tons of hydrogen would be needed. If this hydrogen were made from a non-carbon (e.g. nuclear) or net-zero carbon (e.g. biomass, coal with carbon sequestration) source, then it could potentially displace about 27.5 million tons of carbon." Calculations/References: Analysis by TIAX for DOE, August 24, 2005: * "10.5 million tons of hydrogen" Required H 2 = 175 billion kWhe

107

Molten carbonate fuel cell product design improvement  

DOE Green Energy (OSTI)

Drawing on the manufacture, field test, and post-test experience of the sixteen Santa Clara Demonstration Project (SCDP) stacks, ERC is finalizing the next generation commercial entry product design. The second generation cells are 50% larger in area, 40% lighter on equal geometric area basis, and 30% thinner than the earlier design. These improvements have resulted in doubling of the full-height stack power. A low-cost and high-strength matrix has also been developed for improving product ruggedness. The low-cost advanced cell design incorporating these improvements has been refined through six short stack tests. Power production per cell of two times the SCDP maximum power operation, over ten thermal cycles, and overall operating flexibility with respect to load and thermal changes have been demonstrated in these short stack tests. An internally insulated stack enclosure has been designed and fabricated to eliminate the need for an inert gas environment during operation. ERC has acquired the capability for testing 400kW full-height direct fuel ceil (DFC) stack and balance-of-plant equipment. With the readiness of the power plant test facility, the cell package design, and the stack module, full-height stack testing has begun. The first full- height stack incorporating the post-SCDP second generation design was completed. The stack reached a power level of 253 kW, setting a world record for the highest power production from the advanced fuel cell system. Excellent performance uniformity at this power level affirmed manufacturing reproducibility of the components at the factory. This unoptimized small size test has achieved pipeline natural gas to DC electricity conversion efficiency of 47% (based on lower heating value - LHV) including the parasitic power consumed by the BOP equipment; that should translate to more than 50% efficiency in commercial operation, before employing cogeneration. The power plant system also operated smoothly. With the success of this test confirming the full-height stack basic design and with the completion of SCDP stacks post-test feedback, manufacture of the full-height stack representing the commercial prototype design has been completed and system demonstration is planned to start in the first quarter of 1999. These developments as well as manufacturing advances are discussed in this report.

P. Voyentzie; T. Leo; A. Kush; L. Christner; G. Carlson; C. Yuh

1998-12-20T23:59:59.000Z

108

Determination of optimum electrolyte composition for molten carbonate fuel cells  

DOE Green Energy (OSTI)

The objective of this study is to determine the optimum electrolyte composition for molten carbonate fuel cells. To accomplish this, the contractor will provide: (1) Comprehensive reports of on-going efforts to optimize carbonate composition. (2) A list of characteristics affected by electrolyte composition variations (e.g. ionic conductivity, vapor pressure, melting range, gas solubility, exchange current densities on NiO, corrosion and cathode dissolution effects). (3) Assessment of the overall effects that these characteristics have on state-of-the-art cell voltage and lifetime.

Yuh, C.Y.; Pigeaud, A.

1987-01-01T23:59:59.000Z

109

Missouri Kerosene-Type Jet Fuel Wholesale/Resale Volume by ...  

U.S. Energy Information Administration (EIA)

Referring Pages: Kerosene-Type Jet Fuel Sales for Resale Refiner Sales Volumes; Missouri Kerosene-Type Jet Fuel Refiner Sales Volumes; Missouri Sales for Resale ...

110

New Mexico Kerosene-Type Jet Fuel Wholesale/Resale Volume by ...  

U.S. Energy Information Administration (EIA)

Referring Pages: Kerosene-Type Jet Fuel Sales for Resale Refiner Sales Volumes; New Mexico Kerosene-Type Jet Fuel Refiner Sales Volumes; New Mexico Sales for Resale ...

111

Monthly, global emissions of carbon dioxide from fossil fuel consumption  

Science Conference Proceedings (OSTI)

This paper examines available data, develops a strategy and presents a monthly, global time series of fossil-fuel carbon dioxide emissions for the years 1950 2006. This monthly time series was constructed from detailed study of monthly data from the 21 countries that account for approximately 80% of global total emissions. These data were then used in a Monte Carlo approach to proxy for all remaining countries. The proportional-proxy methodology estimates by fuel group the fraction of annual emissions emitted in each country and month. Emissions from solid, liquid and gas fuels are explicitly modelled by the proportional-proxy method. The primary conclusion from this study is the global monthly time series is statistically significantly different from a uniform distribution throughout the year. Uncertainty analysis of the data presented show that the proportional-proxy method used faithfully reproduces monthly patterns in the data and the global monthly pattern of emissions is relatively insensitive to the exact proxy assignments used. The data and results presented here should lead to a better understanding of global and regional carbon cycles, especially when the mass data are combined with the stable carbon isotope data in atmospheric transport models.

Andres, Robert Joseph [ORNL; Gregg, JS [Riso National Laboratory, Roskilde, Denmark; Losey, London M [ORNL; Marland, Gregg [ORNL; Boden, Thomas A [ORNL

2011-01-01T23:59:59.000Z

112

SPECIFICATIONS AND FABRICATION PROCEDURES FOR TYPE 3 FUEL ELEMENTS  

SciTech Connect

Process and product requirements to be met in the fabrication of Type 3 fuel elements are presented. The fuel elements specified consist of thin plates of a dispersion of highly enriched UO/sub 2/ and ZrB/sub 2/ in a stainless steel matrix which is clad with stainless steel on all surfaces. Quality assurance provisions are discussed. Process and material specifications and packaging and packing for shipment are described. Sample calculations and drawings are included. (M.C.G.)

Edgar, E.C.; Clayton, H.R.

1962-04-27T23:59:59.000Z

113

NAS Miramar Molten Carbonate Fuel Cell demonstration status  

DOE Green Energy (OSTI)

Part of M-C Power`s Technology Development Program, this MCFC power plant is designed to supply 250 kW of electricity to Naval Air Station (NAS) Miramar. It also cogenerates steam for the district heating system. The power plant is a fully integrated unit incorporating an advanced design fuel cell based on years of laboratory tests and a prior field test. This demonstration incorporates many innovative features, one of which is the plate type reformer which processes the natural gas fuel for use in the fuel cell. M-C Power Corp. has completed the design, fabrication, and conditioning of a 250-cell fuel cell stack, which was shipped to the site where it will be installed, tested, and evaluated as a 250 kW Proof-of-Concept MCFC Power Plant. (Originally going to Kaiser Permanente`s Sand Diego Medical Center, it was relocated to Miramar.)

Scroppo, J.A.

1996-12-31T23:59:59.000Z

114

Generation and Solid Oxide Fuel Cell Carbon Sequestration in Northwest Indiana  

DOE Green Energy (OSTI)

The objective of the project is to develop the technology capable of capturing all carbon monoxide and carbon dioxide from natural gas fueled Solid Oxide Fuel Cell (SOFC) system. In addition, the technology to electrochemically oxidize any remaining carbon monoxide to carbon dioxide will be developed. Success of this R&D program would allow for the generation of electrical power and thermal power from a fossil fuel driven SOFC system without the carbon emissions resulting from any other fossil fueled power generationg system.

Kevin Peavey; Norm Bessette

2007-09-30T23:59:59.000Z

115

Solar Power To Help Convert Carbon Dioxide Into Fuel : Renewable Energy News  

E-Print Network (OSTI)

Solar Power To Help Convert Carbon Dioxide Into Fuel : Renewable Energy News TUESDAY 25 MAY, 2010 | | Solar Power To Help Convert Carbon Dioxide Into Fuel by Energy Matters Microbiologist Derek Lovley dioxide into transportation fuels, with the help of special micro-organisms and solar power. The team

Lovley, Derek

116

Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2  

Open Energy Info (EERE)

Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions Jump to: navigation, search Tool Summary Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions Agency/Company /Organization: Oak Ridge National Laboratory Sector: Energy, Climate Topics: GHG inventory, Background analysis Resource Type: Dataset Website: cdiac.ornl.gov/trends/emis/meth_reg.html Country: United States, Canada, Mexico, Argentina, Brazil, Chile, Colombia, Ecuador, Peru, Venezuela, Austria, Azerbaijan, Belarus, Belgium, Luxembourg, Bulgaria, Czech Republic, Denmark, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Kazakhstan, Lithuania, Netherlands, Norway, Poland, Portugal, Romania, Russia, Slovakia, Spain, Sweden, Switzerland, Turkey, Turkmenistan, Ukraine, United Kingdom, Uzbekistan, Iran, Kuwait, Qatar, Saudi Arabia, United Arab Emirates, Algeria, Egypt, South Africa, Australia, Bangladesh, China, India, Indonesia, Japan, Malaysia, New Zealand, Pakistan, Philippines, Singapore, South Korea, Taiwan, Thailand

117

Survey of Landfill Gas Generation Potential: 2-MW Molten Carbonate Fuel Cell  

Science Conference Proceedings (OSTI)

Molten carbonate fuel cells can operate almost as efficiently on landfill gas as on natural gas. This study identified 749 landfills in the United States having the potential to support a total of nearly 3000 2-MW fuel cells.

1992-10-01T23:59:59.000Z

118

Carbon Ionic Conductors for use in Novel Carbon-Ion Fuel Cells  

DOE Green Energy (OSTI)

Carbon-consuming fuel cells have many potential advantages, including increased efficiency and reduced pollution in power generation from coal. A large amount of work has already been done on coal fuel cells that utilize yttria-stabilized zirconium carbide as an oxygen-ion superionic membrane material. But high-temperature fuel cells utilizing yttria-stabilized zirconium require partial combustion of coal to carbon monoxide before final oxidation to carbon dioxide occurs via utilization of the oxygen- ion zirconia membrane. A carbon-ion superionic membrane material would enable an entirely new class of carbon fuel cell to be developed, one that would use coal directly as the fuel source, without any intervening combustion process. However, a superionic membrane material for carbon ions has not yet been found. Because no partial combustion of coal would be required, a carbon-ion superionic conductor would allow the direct conversion of coal to electricity and pure CO{sub 2} without the formation of gaseous pollutants. The objective of this research was to investigate ionic lanthanide carbides, which have an unusually high carbon-bond ionicity as potential superionic carbide-ion conductors. A first step in this process is the stabilization of these carbides in the cubic structure, and this stabilization has been achieved via the preparation of pseudobinary lanthanide carbides. The diffusion rates of carbon have been measured in these carbides as stabilized to preserve the high temperature cubic structure down to room temperature. To prepare these new compounds and measure these diffusion rates, a novel, oxide-based preparation method and a new C{sup 13}/C{sup 12} diffusion technique have been developed. The carbon diffusion rates in La{sup 0.5}Er{sup 0.5}C{sub 2}, Ce{sup 0.5}Er{sup 0.5}C{sub 2}, and La{sup 0.5}Y{sup 0.5}C{sub 2}, and Ce{sup 0.5}Tm0.5C{sub 2} modified by the addition of 5 wt %Be{sub 2}C, have been determined at temperatures from 850 C to 1150 C. The resulting diffusion constants as measured were all less than 10{sup -11} cm{sup 2}/sec, and therefore these compounds are not superionic. However, there remain a large number of potentially superionic pseudobinary lanthanide compounds and a number of alternate ionic carbides which might act as dopants to produce vacancies on the carbon-ion sublattice and thereby increase carbon-ion diffusion rates. The discovery of a superionic carbon conductor would usher in a truly revolutionary new coal technology, and could dramatically improve the way in which we generate electricity from coal. The work completed to date is a promising first step towards this end.

Franklin H. Cocks; W. Neal Simmons; Paul A. Klenk

2005-11-01T23:59:59.000Z

119

Fabrication of catalytic electrodes for molten carbonate fuel cells  

DOE Patents (OSTI)

A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

Smith, James L. (Lemont, IL)

1988-01-01T23:59:59.000Z

120

Carbonate fuel cell endurance: Hardware corrosion and electrolyte management status  

DOE Green Energy (OSTI)

Endurance tests of carbonate fuel cell stacks (up to 10,000 hours) have shown that hardware corrosion and electrolyte losses can be reasonably controlled by proper material selection and cell design. Corrosion of stainless steel current collector hardware, nickel clad bipolar plate and aluminized wet seal show rates within acceptable limits. Electrolyte loss rate to current collector surface has been minimized by reducing exposed current collector surface area. Electrolyte evaporation loss appears tolerable. Electrolyte redistribution has been restrained by proper design of manifold seals.

Yuh, C.; Johnsen, R.; Farooque, M.; Maru, H.

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Carbonate fuel cell endurance: Hardware corrosion and electrolyte management status  

DOE Green Energy (OSTI)

Endurance tests of carbonate fuel cell stacks (up to 10,000 hours) have shown that hardware corrosion and electrolyte losses can be reasonably controlled by proper material selection and cell design. Corrosion of stainless steel current collector hardware, nickel clad bipolar plate and aluminized wet seal show rates within acceptable limits. Electrolyte loss rate to current collector surface has been minimized by reducing exposed current collector surface area. Electrolyte evaporation loss appears tolerable. Electrolyte redistribution has been restrained by proper design of manifold seals.

Yuh, C.; Johnsen, R.; Farooque, M.; Maru, H.

1993-05-01T23:59:59.000Z

122

New Zealand Energy Data: Electricity Generation by Fuel Type...  

Open Energy Info (EERE)

South Island and New Zealand (2009). The fuel types include: hydro, geothermal, biogas, wind, oil, coal, and gas.
2011-01-26T00:20:13Z 2011-01-27T19:47:20Z http:...

123

Strategic power plant investment planning under fuel and carbon price uncertainty.  

E-Print Network (OSTI)

??The profitability of power plant investments depends strongly on uncertain fuel and carbon prices. In this doctoral thesis, we combine fundamental electricity market models with… (more)

Geiger, Ansgar

2011-01-01T23:59:59.000Z

124

Sorption of Carbon Dioxide from Oxy-fuel Combustion by Lithium ...  

Science Conference Proceedings (OSTI)

Symposium, Materials for CO2 Capture and Conversion. Presentation Title, Sorption of Carbon Dioxide from Oxy-fuel Combustion by Lithium Orthosilicate.

125

Carbonate fuel cell system with thermally integrated gasification  

DOE Patents (OSTI)

A fuel cell system employing a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell.

Steinfeld, George (Southbury, CT); Meyers, Steven J. (Huntington Beach, CA); Lee, Arthur (Fishkill, NY)

1996-01-01T23:59:59.000Z

126

Carbon capture technology: future fossil fuel use and mitigating climate change  

E-Print Network (OSTI)

Carbon capture technology: future fossil fuel use and mitigating climate change DR N FloRiN aND DR P FeNNell executive summary What is carbon capture and storage? Carbon Capture and Storage (CCS) refers to the set of technologies devel- oped to capture carbon dioxide (CO2) gas from the exhausts

127

Arkansas Kerosene-Type Jet Fuel Retail Sales by Refiners (Thousand ...  

U.S. Energy Information Administration (EIA)

Referring Pages: Arkansas Kerosene-Type Jet Fuel Refiner Sales Volumes; Arkansas Sales to End Users Refiner Sales Volumes of Aviation Fuels, Kerosene, Propane, No.1 ...

128

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

DOE Patents (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

129

Pyrochlore-type catalysts for the reforming of hydrocarbon fuels  

Science Conference Proceedings (OSTI)

A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

Berry, David A. (Morgantown, WV); Shekhawat, Dushyant (Morgantown, WV); Haynes, Daniel (Morgantown, WV); Smith, Mark (Morgantown, WV); Spivey, James J. (Baton Rouge, LA)

2012-03-13T23:59:59.000Z

130

FABRICATION OF TUBE TYPE FUEL ELEMENT FOR NUCLEAR REACTORS  

DOE Patents (OSTI)

A method of fabricating a nuclear reactor fuel element is given. It consists essentially of fixing two tubes in concentric relationship with respect to one another to provide an annulus therebetween, filling the annulus with a fissionablematerial-containing powder, compacting the powder material within the annulus and closing the ends thereof. The powder material is further compacted by swaging the inner surface of the inner tube to increase its diameter while maintaining the original size of the outer tube. This process results in reduced fabrication costs of powdered fissionable material type fuel elements and a substantial reduction in the peak core temperatures while materially enhancing the heat removal characteristics.

Loeb, E.; Nicklas, J.H.

1959-02-01T23:59:59.000Z

131

Molten carbonate fuel cell technology improvement. Final report  

DOE Green Energy (OSTI)

This report summarizes the work performed under Department of Energy Contract DEAC21-87MC23270, ``Molten Carbonate Fuel Cell Technology Improvement.`` This work was conducted over a three year period and consisted of three major efforts. The first major effort was the power plant system study which reviewed the competitive requirements for a coal gasifier/molten carbonate fuel cell power plant, produced a conceptual design of a CG/MCFC, and defined the technology development requirements. This effort is discussed in Section 1 of the report. The second major effort involved the design and development of a new MCFC cell configuration which reduced the material content of the cell to a level competitive with competing power plants, simplified the cell configuration to make the components more manufacturable and adaptable to continuous low cost processing techniques, and introduced new-low-pressure drop flow fields for both reactant gases. The new flow fields permitted the incorporation of recirculation systems in both reactant gas systems, permitting simplified cooling techniques and the ability to operate on both natural gas and a wide variety of gasifier fuels. This cell technology improvement is discussed in Section 2. The third major effort involved the scaleup of the new cell configuration to the full-area, 8-sq-ft size and resulted in components used for a 25-kW, 20-cell stack verification test. The verification test was completed with a run of 2200 hours, exceeding the goal of 2000 hours and verifying the new cell design. TWs test, in turn, provided the confidence to proceed to a 100-kW demonstration which is the goal of the subsequent DOE program. The scaleup and stack verification tests are discussed in Sections 3, 4, 5, and 6 of this report.

Not Available

1991-06-01T23:59:59.000Z

132

Status of molten-carbonate fuel-cell program  

DOE Green Energy (OSTI)

The Department of Energy (DOE) is sponsoring a program to develop molten-carbonate fuel cells. These advanced fuel cells promise coal-to-bus-bar efficiencies of about 50% and are environmentally very attractive. Although oil and gas can be used as fuel with up to 60% efficiency, the main application is anticipated in conjunction with coal gasifiers. DOE's strategy is to help industrial corporations to develop the basic hardware to a point where users and vendors can undertake the risk of commercialization. At present, stacks of small (about .1 m/sup 2/) cells have been run and commercial scale (1.4 m/sup 2/) electrolyte structures have been fabricated. Commercial-size cells are scheduled to run in 1981, with short stacks of cells in 1982 and full commercial size stacks in 1984. Power-plant systems have been defined to guide development. Cogeneration applications are being planned. Component costs and cell-life are nearing the goal required for commercial applications.

Krumpelt, M.; Ackerman, J.

1981-01-01T23:59:59.000Z

133

Large historical changes of fossil-fuel black carbon aerosols  

SciTech Connect

Anthropogenic emissions of fine black carbon (BC) particles, the principal light-absorbing atmospheric aerosol, have varied during the past century in response to changes of fossil-fuel utilization, technology developments, and emission controls. We estimate historical trends of fossil-fuel BC emissions in six regions that represent about two-thirds of present day emissions and extrapolate these to global emissions from 1875 onward. Qualitative features in these trends show rapid increase in the latter part of the 1800s, the leveling off in the first half of the 1900s, and the re-acceleration in the past 50 years as China and India developed. We find that historical changes of fuel utilization have caused large temporal change in aerosol absorption, and thus substantial change of aerosol single scatter albedo in some regions, which suggests that BC may have contributed to global temperature changes in the past century. This implies that the BC history needs to be represented realistically in climate change assessments.

Novakov, T.; Ramanathan, V.; Hansen, J.E.; Kirchstetter, T.W.; Sato, M.; Sinton, J.E.; Sathaye, J.A.

2002-09-26T23:59:59.000Z

134

Landfill Gas Cleanup for Carbonate Fuel Cell Power Generation: Final Report  

DOE Green Energy (OSTI)

Landfill gas represents a significant fuel resource both in the United States and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

135

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

natural gas generation A Low Carbon Fuel Standard for California Part II: PolicyNatural Gas Industries .. 88 A Low Carbon Fuel Standard for California Part II: PolicyPolicy Analysis Page 88 Appendix A: Structure of the California Oil, Electricity, and Natural Gas

2007-01-01T23:59:59.000Z

136

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

natural gas generation A Low Carbon Fuel Standard for California Part II: PolicyNatural Gas Industries .. 88 A Low Carbon Fuel Standard for California Part II: PolicyPolicy Analysis Page 88 Appendix A: Structure of the California Oil, Electricity, and Natural Gas

Sperling, Daniel; Farrell, Alexander

2007-01-01T23:59:59.000Z

137

|Archives| Charts| Companies/Links| Conferences| How A Fuel Cell Works | Patents| | Types of Fuel Cells | The Basics | Fuel Cell News | Basics on Hydrogen | Search|  

E-Print Network (OSTI)

on large fuel cells to generate electricity and power vehicles. If the feat in miniaturization Lilliputian bedeviled scientists at MIT and other energy-research laboratories. The first generation of fuel cell|Archives| Charts| Companies/Links| Conferences| How A Fuel Cell Works | Patents| | Types of Fuel

Lovley, Derek

138

Lithium-ferrate-based cathodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at approximately 650 degrees Centigrade. These cathodes are based on lithium ferrate (LiFeO[sub 2]) which is attractive because of its very low solubility in the molten (Li,K)[sub 2]CO[sub 3] electrolyte. Because of its high resistivity, LiFeO[sub 2] cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. The effect of cation substitution on the resistivity and deformation of LiFeO[sub 2] was determined. The substitutes were chosen because their respective oxides as well as LiFeO[sub 2] crystallize with the rock-salt structure.

Lanagan, M.T.; Wolfenstine, J. [Argonne National Lab., IL (United States). Energy Technology Div.; Bloom, I.; Kaun, T.D.; Krumpelt, M. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-12-31T23:59:59.000Z

139

A Micro-Computer-Based Fuel Optimization System Utilizing In-Situ Measurement of Carbon Monoxide  

E-Print Network (OSTI)

A microcomputer-based control system utilizing a distributed intelligence architecture has been developed to control combustion in hydrocarbon fuel-fired boilers and heaters to significantly reduce fuel usage. The system incorporates a unique flue gas analyzer that mounts directly in the flue or stack to continuously measure carbon monoxide, unburned hydrocarbons, opacity and temperature. The control console interfaces directly with the boiler's existing analog control system to provide precise air fuel ratio control based on carbon monoxide measurements. Significant decreases in excess air result in reduced fuel usage while meeting steam demand. Actual performance on industrial boilers shows increases in efficiency of from 1% to 3% with substantial fuel savings.

DeVivo, D. G.

1980-01-01T23:59:59.000Z

140

Carbon monoxide sensor for PEM fuel cell systems Christopher T. Holta,*  

E-Print Network (OSTI)

environment; Copper-halide 1. Introduction The use of hydrocarbon fuels for generating power for cars for both transportation and residential power systems. PEM fuel cells operate on hydro- gen. However, the infrastructure for hydrogen that will support large markets is decades away. The use of hydro- carbon fuels (e

Dutta, Prabir K.

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Carbonate fuel cell system with integrated carbon dioxide/thermal management  

DOE Green Energy (OSTI)

Upon successful completion of Phase 1, the Phase 2 activities were initiated in July 1994 to define the stack design and system requirements for a commercial-scale burnerless carbonate fuel cell stack with an integrated carbon dioxide management system. The major goals of this program are to define the stack design and the system requirements of the integrated design. The approach taken was to maximize the similarities of this stack with ERC`s proven baseline stack design and power plant system. Recent accomplishments include a detailed stack design which retains all the essential elements of the baseline stack as well as the power plant system designs. All the auxiliary hardware and external flow patterns remain unchanged, only the internal flow configurations are modified.

Paetsch, L.; Ding, J.; Hunt, J.

1995-12-31T23:59:59.000Z

142

South Carolina Kerosene-Type Jet Fuel All Sales/Deliveries by ...  

U.S. Energy Information Administration (EIA)

South Carolina Kerosene-Type Jet Fuel All Sales/Deliveries by Prime Supplier (Thousand Gallons per Day)

143

Carbonate fuel cell system with thermally integrated gasification  

DOE Patents (OSTI)

A fuel cell system is described which employs a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell. 2 figs.

Steinfeld, G.; Meyers, S.J.; Lee, A.

1996-09-10T23:59:59.000Z

144

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

DOE Green Energy (OSTI)

Several different catalytic reactions must be carried out in order to convert hydrocarbons (or alcohols) into hydrogen for use as a fuel for polyelectrolyte membrane (PEM) fuel cells. Each reaction in the fuel-processing sequence has a different set of characteristics, which influences the type of catalyst support that should be used for that particular reaction. A wide range of supports are being evaluated for the various reactions in the fuel-processing scheme, including porous and non-porous particles, ceramic and metal straight-channel monoliths, and ceramic and metal monolithic foams. These different types of support have distinctly different transport characteristics. The best choice of support for a given reaction will depend on the design constraints for the system, e.g., allowable pressure drop, and on the characteristics of the reaction for which the catalyst is being designed. Three of the most important reaction characteristics are the intrinsic reaction rate, the exothermicity/endothermicity of the reaction, and the nature of the reaction network, e.g., whether more than one reaction takes place and, in the case of multiple reactions, the configuration of the network. Isotopic transient kinetic analysis was used to study the surface intermediates. The preferential oxidation of low concentrations of carbon monoxide in the presence of high concentrations of hydrogen (PROX) is an important final step in most fuel processor designs. Data on the behavior of straight-channel monoliths and foam monolith supports will be presented to illustrate some of the factors involved in choosing a support for this reaction.

Mr. Paul Chin; Dr. Xiaolei Sun; Professor George W. Roberts; Professor James J. Spivey; Mr. Amornmart Sirijarhuphan; Dr. James G. Goodwin, Jr.; Dr. Richard W. Rice

2002-12-31T23:59:59.000Z

145

Corrosion of 1018 carbon steel in fuel/seawater incubations  

Science Conference Proceedings (OSTI)

... Workshop on Alternative Fuels and Materials ... O 2 Transition across fuel/seawater interface in ... JP5 Camelina/Marinobacter (~4x105 cells per mL ) ...

2013-08-28T23:59:59.000Z

146

King County Carbonate Fuel Cell Demonstration Project: Case Study of a 1MW Fuel Cell Power Plant Fueled by Digester Gas  

Science Conference Proceedings (OSTI)

This case study documents the first-year demonstration experiences of a 1-MW carbonate fuel cell system operating on anaerobic digester gas at a wastewater treatment plant in King County, Washington. The case study is one of several fuel cell project case studies under research by the EPRI Distributed Energy Resources Program. This case study is designed to help utilities and other interested parties understand the early applications of fuel cell systems to help them in their resource planning efforts an...

2005-03-30T23:59:59.000Z

147

Task 1. 0, Development of improved molten carbonate fuel cell  

DOE Green Energy (OSTI)

The overall objective of this task was to develop an improved cell configuration for molten carbonate fuel cells which has improved performance, meets a 40,000 hour projected life, maintains existing cell cost, and is adaptable to a range of power plant applications. A new cell configuration designed to be manufactured using conventional and available equipment and processes was developed and verified in subscale single cells. This cell configuration is adaptable to a broad range of fuels without redesign, operating on very weak low Btu coal gas as well as high Btu gas and natural gas. The success of this program has provided the confidence to proceed with a scale-up to 8-ft{sup 2} cells and a stack verification in a 20-cell, 25 kW stack test. Design requirements and specifications for components in an improved cell design were defined. Electrolyte requirements for the cell components were established, the estimated time-to-short was updated, and a design operating point and gas composition for single cell testing was defined. Four anode, four cathode, five matrix configurations, and three end-cell reservoirs were defined. A total of 54 single cell tests were conducted to evaluate the performance of individual improvements and combinations of improved configurations. Anodes were successfully fabricated by tape casting. A new tape cast cathode for improved electrolyte sharing, new tape cast matrix materials and matrix reinforcement, and an end-cell reservoir configuration using conductive material were developed. Reports on the separate subtasks have been processed for inclusion on the data base.

Johnson, W.H.

1990-10-01T23:59:59.000Z

148

Landfill gas cleanup for carbonate fuel cell power generation. Final report  

DOE Green Energy (OSTI)

Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

Steinfield, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

149

Molten carbonate fuel cell technology improvement. [25 kW  

DOE Green Energy (OSTI)

This report summarizes the work performed under Department of Energy Contract AC21-87MC23270 during the period March 1, through May 30, 1990. The overall objective of this program is to define a competitive CG/MCFC power plant and the associated technology development requirements and to develop an improved cell configuration for molten carbonate fuel cells which has improved performance, has reduced cell creep and electrolyte management consistent with 40,000 hour projected life, reduces existing cell cost, and is adaptable to a range of power plant applications. The 8-ft{sup 2} 20-cell, 25-kW stack assembly and installation in the test facility were completed. Testing of the stack was started and 896 hours of test time were reached. Manifold seal development focused on a seal to reduce electrolyte transport and test rigs were initiated for shunt current and seal leakage evaluation. Development on sheet metal parts was initiated with focus on improved aluminization for separator plate corrosion protection and nickel clad stainless steel for the anode current collector. Development of porous parts was initiated with focus on an alternative binder for the electrodes. Design of a laboratory scale continuous debinding oven was completed. Development of an improved material blend for the matrix was also initiated. 19 figs., 2 tabs.

Not Available

1990-09-01T23:59:59.000Z

150

Simulated coal-gas-fueled molten carbonate fuel cell development program  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

151

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

152

Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program. Final report  

DOE Green Energy (OSTI)

This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, ``Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.`` This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft{sup 2} cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

Not Available

1992-08-01T23:59:59.000Z

153

Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program  

DOE Green Energy (OSTI)

This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.'' This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft[sup 2] cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

Not Available

1992-08-01T23:59:59.000Z

154

Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance  

SciTech Connect

Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 #2;C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

Patel, Anant; Artyushkova, Kateryna; Atanassov, Plamen; Colbow, Vesna; Dutta, Monica; Harvey, Davie; Wessel, Silvia

2012-04-01T23:59:59.000Z

155

Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance  

DOE Green Energy (OSTI)

Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

A. Patel; K. Artyushkova; P. Atanassov; V. Colbow; M. Dutta; D. Harvey; S. Wessel

2012-04-30T23:59:59.000Z

156

Simulated coal-gas fueled carbonate fuel cell power plant system verification. Final report, September 1990--June 1995  

DOE Green Energy (OSTI)

This report summarizes work performed under U.S. Department of Energy, Morgantown Energy Technology Center (DOE/METC) Contract DE-AC-90MC27168 for September 1990 through March 1995. Energy Research Corporation (ERC), with support from DOE, EPRI, and utilities, has been developing a carbonate fuel cell technology. ERC`s design is a unique direct fuel cell (DFC) which does not need an external fuel reformer. An alliance was formed with a representative group of utilities and, with their input, a commercial entry product was chosen. The first 2 MW demonstration unit was planned and construction begun at Santa Clara, CA. A conceptual design of a 10OMW-Class dual fuel power plant was developed; economics of natural gas versus coal gas use were analyzed. A facility was set up to manufacture 2 MW/yr of carbonate fuel cell stacks. A 100kW-Class subscale power plant was built and several stacks were tested. This power plant has achieved an efficiency of {approximately}50% (LHV) from pipeline natural gas to direct current electricity conversion. Over 6,000 hours of operation including 5,000 cumulative hours of stack operation were demonstrated. One stack was operated on natural gas at 130 kW, which is the highest carbonate fuel cell power produced to date, at 74% fuel utilization, with excellent performance distribution across the stack. In parallel, carbonate fuel cell performance has been improved, component materials have been proven stable with lifetimes projected to 40,000 hours. Matrix strength, electrolyte distribution, and cell decay rate have been improved. Major progress has been achieved in lowering stack cost.

NONE

1995-03-01T23:59:59.000Z

157

Resistivity of bipolar plate materials at the cathode interface in molten carbonate fuel cells.  

DOE Green Energy (OSTI)

Measurements of oxide scale resistivity for prospective bipolar plate materials in the molten carbonate fuel cell (MCFC) are coupled with observations of microstructural/compositional change over time. This work searches for a compromise to the high corrosion rate of Type 316L and the high oxide scale resistance of Type 310S. We tested a group of materials having chromium content ranging from 16 to 31 wt%, including Nitronic 50 and NKK, a Ni-Cr-Fe alloy. Chromium content was found to be the primary determinant of oxide scale composition. In the MCFC cathode compartment, stainless steels generally formed a duplex structure with an inner Cr-rich layer and an outer, Fe-rich layer. The composition of the inner Cr-rich layer was related to the base alloy and had a controlling effect on scale resistivity. Oxide scale resistivity was measured for two electrolyte compositions: Li/K and Li/Na carbonates. Changes in the physical/mechanical properties (spallation/cracking) in the oxide scale of Type 316L provided an understanding of its resistivity fluctuations over time.

Kaun, T. D.

1998-11-18T23:59:59.000Z

158

>Carbon Dioxide Emission Estimates from Fossil-Fuel Burning, Hydraulic  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Dioxide Emission Estimates from Fossil-Fuel Burning, Hydraulic Carbon Dioxide Emission Estimates from Fossil-Fuel Burning, Hydraulic Cement Production, and Gas Flaring for 1995 on a One Degree Grid Cell Basis (NDP-058a) Prepared by Antoinette L. Brenkert Carbon Dioxide Information Analysis Center Oak Ridge National Laboratory Oak Ridge, Tennessee 37831-6290 Date Published: February 1998 (Revised for the Web: 2003) CONTENTS Abstract Documentation file for Data Base NDP-058a (2-1998) Data Base NDP-058a (2-1998) Abstract Carbon Dioxide Emission Estimates from Fossil-Fuel Burning, Hydraulic Cement Production, and Gas Flaring for 1995 on a One Degree Grid Cell Basis. (March 1998) Antoinette L. Brenkert DOI: 10.3334/CDIAC/ffe.ndp058.2003 This data package presents the gridded (one degree latitude by one degree longitude) summed emissions from fossil-fuel burning, hydraulic cement

159

Fabrication of carbon-aerogel electrodes for use in phosphoric acid fuel cells  

E-Print Network (OSTI)

An experiment was done to determine the ability to fabricate carbon aerogel electrodes for use in a phosphoric acid fuel cell (PAFC). It was found that the use of a 25% solution of the surfactant Cetyltrimethylammonium ...

Tharp, Ronald S

2005-01-01T23:59:59.000Z

160

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

A. Miller (1980). "Oil Shales and Carbon Dioxide." Sciencefor CO2 evolved from oil shale." Fuel Processing TechnologyCTLs, or CTL synfuels), and oil shale-based synthetic crude

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

A. Miller (1980). "Oil Shales and Carbon Dioxide." Sciencefor CO2 evolved from oil shale." Fuel Processing TechnologyCTLs, or CTL synfuels), and oil shale-based synthetic crude

2007-01-01T23:59:59.000Z

162

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

for CO2 evolved from oil shale." Fuel Processing TechnologyT. and G. A. Miller (1980). "Oil Shales and Carbon Dioxide."oil, coal, tar sands, oil shale Natural gas, biomass Natural

Farrell, Alexander; Sperling, Daniel

2007-01-01T23:59:59.000Z

163

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

for CO2 evolved from oil shale." Fuel Processing TechnologyT. and G. A. Miller (1980). "Oil Shales and Carbon Dioxide."oil, coal, tar sands, oil shale Natural gas, biomass Natural

2007-01-01T23:59:59.000Z

164

Solar Reforming of Carbon Dioxide to Produce Diesel Fuel  

SciTech Connect

This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter, concentrating solar dish was modified to accommodate the Sunexus CO2 Solar Reformer and the integrated system was installed at the Pacific Renewable Fuels and Chemicals test site at McClellan, CA. Several test runs were conducted without catalyst during which the ceramic heat exchanger in the Sunexus Solar Reformer reached temperatures between 1,050 F (566 C) and 2,200 F (1,204 C) during the test period. A dry reforming mixture of CO2/CH{sub 4} (2.0/1.0 molar ratio) was chosen for all of the tests on the integrated solar dish/catalytic reformer during December 2010. Initial tests were carried out to determine heat transfer from the collimated solar beam to the catalytic reactor. The catalyst was operated successfully at a steady-state temperature of 1,125 F (607 C), which was sufficient to convert 35% of the 2/1 CO2/CH{sub 4} mixture to syngas. This conversion efficiency confirmed the results from laboratory testing of this catalyst which provided comparable syngas production efficiencies (40% at 1,200 F [650 C]) with a resulting syngas composition of 20% CO, 16% H{sub 2}, 39% CO2 and 25% CH{sub 4}. As based upon the laboratory results, it is predicted that 90% of the CO2 will be converted to syngas in the solar reformer at 1,440 F (782 C) resulting in a syngas composition of 50% CO: 43% H{sub 2}: 7% CO2: 0% CH{sub 4}. Laboratory tests show that the higher catalyst operating temperature of 1,440 F (782 C) for efficient conversion of CO2 can certainly be achieved by optimizing solar reactor heat transfer, which would result in the projected 90% CO2-to-syngas conversion efficiencies. Further testing will be carried out during 2011, through other funding support, to further optimize the solar dish CO2 reformer. Additional studies carried out in support of this project and described in this report include: (1) An Assessment of Potential Contaminants in Captured CO2 from Various Industrial Processes and Their Possible Effect on Sunexus CO2 Reforming Catalysts; (2) Recommended Measurement Methods for Assessing Contaminant Levels in Captured CO2 Streams; (3) An Asse

Dennis Schuetzle; Robert Schuetzle

2010-12-31T23:59:59.000Z

165

Molten Carbonate Fuel Cell (MCFC) Product Development Test. Second annual report  

DOE Green Energy (OSTI)

This is the second annual report covering progress made under DOE cooperative agreement DE-FC21-92MC29237, Molten Carbonate Fuel Cell Product Development Test. The project is for the design, construction, and testing of a 2MW carbonate fuel cell power plant in the City of Santa Clara, California. The report is divided into sections which describe the progress in various program activities, and provides an overview of the program, including the project objectives, site location, and schedule.

Not Available

1994-12-15T23:59:59.000Z

166

BSA 01-07: Carbon Monoxide Tolerant Fuel Cell Electrocatalyst  

This fuel cell anode includes an electrocatalyst that has a conductive support material, ... Brookhaven National Laboratory conducts research in the ...

167

Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality  

Science Conference Proceedings (OSTI)

The effect of carbon functionality on the electrocatalytic performance of carbon black-supported, Pt-based, direct methanol fuel cell cathodes was investigated. Polarization data show that cathodes with nitrogen and sulfur functionality have enhanced catalytic activity toward oxygen reduction. Transmission electron microscopy results indicate that this behavior may be ascribed to a platinum particle size effect.

Roy, S.C.; Christensen, P.A.; Hamnett, A.; Thomas, K.M.; Trapp, V. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1996-10-01T23:59:59.000Z

168

ENHANCING CARBON SEQUESTRATION AND RECLAMATION OF DEGRADED LANDS WITH FOSSIL-FUEL COMBUSTION BYPRODUCTS  

E-Print Network (OSTI)

represents an opportunity to couple carbon sequestration with the utilization of fossil fuel #12;and energy of fossil energy byproducts to stimulate carbon sequestration in those terrestrial ecosystems. GOALS C sequestration through optimal utilization of fossil energy byproducts and management of degraded

169

Direct electrochemical conversion of carbon: systems for efficient conversion of fossil fuels to electricity  

DOE Green Energy (OSTI)

The direct electrochemical conversion of carbon involves discharge of suspensions of reactive carbon particles in a molten salt electrolyte against an oxygen (air) cathode. (Figure 1). The free energy and the enthalpy of the oxidation reaction are nearly identical. This allows theoretical efficiencies ({Delta}G(T)/{Delta}H) to approach 100% at temperatures from 500 to 800 C. Entropy heat losses are therefore negligible. The activities of the elemental carbon and of the carbon dioxide product are uniform throughout the fuel cell and constant over discharge time. This stabilizes cell EMF and allows full utilization of the carbon fuel in a single pass. Finally, the energy cost for pyrolysis of hydrocarbons is generally very low compared with that of steam reforming or water gas reactions. Direct electrochemical conversion of carbon might be compared with molten carbonate fuel cell using carbon rather than hydrogen. However, there are important differences. There is no hydrogen involved (except from trace water contamination). The mixture of molten carbonate and carbon is not highly flammable. The carbon is introduced in as a particulate, rather than as a high volume flow of hydrogen. At the relatively low rates of discharge (about 1 kA/m{sup 2}), the stoichiometric requirements for carbon dioxide by the cathodic reaction may be met by diffusion across the thin electrolyte gap. We report recent experimental work at LLNL using melt slurries of reactive carbons produced by the thermal decomposition of hydrocarbons. We have found that anodic reactivity of carbon in mixed carbonate melts depends strongly on form, structure and nano-scale disorder of the materials, which are fixed by the hydrocarbon starting material and the conditions of pyrolysis. Thus otherwise chemically pure carbons made by hydrocarbon pyrolysis show rates at fixed potentials that span an order of magnitude, while this range lies 1-2 orders of magnitude higher than the current density of graphite plate electrodes. One carbon materials was identified which delivered anode current densities of 1 kA/m{sup 2} at 0.8 V (i.e., 80% efficiency, based on the standard enthalpy of carbon/oxygen reaction, and assuming full conversion), which we believe to be sufficiently great to allow practical application in fuel cell arrays. Since the hydrocarbon starting materials are ''ash free,'' entrainment of ash into the melt is not limiting. Finally, the use of fine carbon particulates in slurries avoids cost and logistics of carbon electrode manufacture and distribution.

Cooper, J F; Cherepy, N; Krueger, R

2000-08-10T23:59:59.000Z

170

DISPERSIONS OF URANIUM CARBIDES IN ALUMINUM PLATE-TYPE RESEARCH REACTOR FUEL ELEMENTS  

DOE Green Energy (OSTI)

The technical feasibility of employing uranium carbide aluminun dispersions in aluminum-base research reactor fuel elements was investigated This study was motivated by the need to obtain higher uranium loadings in these fuel elements. Although toe MTR-type unit, containing a 13 18 wt% U-Al alloy is a proven reactor component, fabrication problems of considerable magnitude arise when attempts are made to increase the uranium investment in the alloy to more than 25 wt.%. Au approach to these fabrication difficulties is to select a compound with significantly higher density tban UAl/sub 4/ or UAl/sub 3/ compounds of the alloy system which when dispersed in aluminum powder, will reduce the volume occupied by the brittle, fissile phase. The uranium carbides, with densities ranging from 11.68 to 13.63 g/cm/sup 3/), appear to be suited for this application and were selected for development as a fuel material for aluminum-base dispersions. Studies were conducted at 580 to 620 deg C to determine the chemical compatibility of carbides with aluminum in sub-size cold- pressed comparts as well as in full-size fabricated fuel plates. Procedures were also developed to prepare uranium carbides, homogernously disperse the compounds in aluminum, roll clad the dispersions to form composite plates, and braze the plates into fuel assemblies. Corrosion tests of the fuel material were conducted in 20 and 60 deg C water to determine the integrity of the fuel material in the event of sin inadventent cladding failure. In addition, specimens were prepared to evaluate penformance under extensive irradiation Prior to studying the uranium carbide-aluminum system, methods for preparing the carbides were investigated. Are melting uranium and carnon was satisfactory for obtaining small quantities of various carbides. Later, reaction of graphite with UO/sub 2/ was successfully employed in the preparation of large quantities of UC/sub 2/, Studies of the chemical compatibility of cold-pressed compacts containing 50 wt% uranium carbide dispersed in aluminum revealed a marked trend toward stebifity as the carbon content of the uranium carbide increased from 446 to 9.20% C. Severe volume increases occurred in monocarbide dispersions with attendant formation of large quantities of the uranium-allumnim inter-metallic compounds. Dicarbide dispersions, on the other band, exhibited negligible reaction with aluminum after extended periods at 580 and 620 deg C. However, it was demonstrated that hydrogen can promote a reaction in UC/sub 2/-Al compacts. The hydrogen appears to reduce the UC/sub 2/ to UC which can subsequently react with aluminum producing the previously noted deleterious effects. A growth study at 605 deg C of composite fuel plates containing 59 wt.% UC/sub 2/ revealed insignificant changes within processing periods envisioned for fuel element processing. However, plate elongations as high as 2.5% were observed after 100 hr at this temperature. Severe blistering which occurred on fuel plates fabricated in the initial stages of the investigation was attributed to gaseous hydrocarbons, and the condition was ellminated by vacuum degasification of cold-pressed compacts. With the exception of the degasification requirement, procedures for manufacturing UC- bearing fuel elements were identical to those specified for the Geneva Conference Reactor fuel elements. Dispersions of uranium dicarbide corroded catastrophically in 20 and 60 deg C water, thus limiting the application of this material However, spocimens were prepared and insented in the MTR to evaluate the irradiation behavior of this fuel because of its potential application in onganic- cooled reactors. (auth)

Thurber, W.C.; Beaver, R.J.

1959-11-19T23:59:59.000Z

171

Non-Kinetic Losses Caused by Electrochemical Carbon Corrosion in PEM Fuel Cells  

SciTech Connect

This paper presented non-kinetic losses in PEM fuel cells under an accelerated stress test of catalyst support. The cathode with carbon-supported Pt catalyst was prepared and characterized with potential hold at 1.2 V vs. SHE in PEM fuel cells. Irreversible losses caused by carbon corrosion were evaluated using a variety of electrochemical characterizations including cyclic voltammetry, linear sweep voltammetry, electrochemical impedance spectroscopy, and polarization technique. Ohmic losses at the cathode with potential hold were determined using its capacitive responses. Concentration losses in PEM fuel cells were analyzed in terms of Tafel behavior and thin film/flooded-agglomerate dynamics.

Park, Seh Kyu; Shao, Yuyan; Viswanathan, Vilayanur V.; Liu, Jun; Wang, Yong

2012-05-01T23:59:59.000Z

172

Corrosion and Cracking of Carbon Steel in Fuel Grade Ethanol  

Science Conference Proceedings (OSTI)

Environmentally Assisted Cracking of Carbon Steel in High Temperature Geothermal Well · Evaluation of the Susceptibility to Hydrogen Assisted Cracking in ...

173

Oxygen electrode reaction in molten carbonate fuel cells. Final report, September 15, 1987--September 14, 1990  

DOE Green Energy (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

174

Multi-criteria comparison of fuel policies: Renewable fuel mandate, fuel emission-standards, and fuel carbon tax  

E-Print Network (OSTI)

types of crude oil and multiple sources of biofuels, we areand synthetic crude oil from sources such as oil sands (OS),the more GHG-intensive source of oil, namely oil sands from

Rajagopal, Deepak; Hochman, G.; Zilberman, D.

2012-01-01T23:59:59.000Z

175

Hardware Materials in Carbonate Fuel Cell - Programmaster.org  

Science Conference Proceedings (OSTI)

Metallic materials are extensively utilized in fuel-cell module hardware (current ... A Study on the Hot Corrosion Resistance of Metal-cemet-glass Coating on ...

176

Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...  

Gasoline and Diesel Fuel Update (EIA)

Information Administration Petroleum Marketing Annual 1995 233 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District, and Selected States (Cents per Gallon...

177

Search for Model Year 2014 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Vehicle Type Model Year: 2014 Select Class... Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Plug-in Hybrid Vehicles...

178

Light-Duty Vehicle Energy Consumption by Fuel Type from EIA AEO...  

Open Energy Info (EERE)

Linked Data Search Share this page on Facebook icon Twitter icon Light-Duty Vehicle Energy Consumption by Fuel Type from EIA AEO 2011 Early Release Dataset Summary...

179

Tribological behavior of near-frictionless carbon coatings in high- and low-sulfur diesel fuels.  

DOE Green Energy (OSTI)

The sulfur content in diesel fuel has a significant effect on diesel engine emissions, which are currently subject to environmental regulations. It has been observed that engine particulate and gaseous emissions are directly proportional to fuel sulfur content. With the introduction of low-sulfur fuels, significant reductions in emissions are expected. The process of sulfur reduction in petroleum-based diesel fuels also reduces the lubricity of the fuel, resulting in premature failure of fuel injectors. Thus, another means of preventing injector failures is needed for engines operating with low-sulfur diesel fuels. In this study, the authors evaluated a near-frictionless carbon (NFC) coating (developed at Argonne National Laboratory) as a possible solution to the problems associated with fuel injector failures in low-lubricity fuels. Tribological tests were conducted with NFC-coated and uncoated H13 and 52100 steels lubricated with high- and low- sulfur diesel fuels in a high-frequency reciprocating test machine. The test results showed that the NFC coatings reduced wear rates by a factor of 10 over those of uncoated steel surfaces. In low-sulfur diesel fuel, the reduction in wear rate was even greater (i.e., by a factor of 12 compared to that of uncoated test pairs), indicating that the NFC coating holds promise as a potential solution to wear problems associated with the use of low-lubricity diesel fuels.

Alzoubi, M. F.; Ajayi, O. O.; Eryilmaz, O. L.; Ozturk, O.; Erdemir, A.; Fenske, G.

2000-01-19T23:59:59.000Z

180

Effects of coal-derived trace species on performance of molten carbonate fuel cells. Final report  

DOE Green Energy (OSTI)

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Not Available

1992-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
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181

Effects of coal-derived trace species on performance of molten carbonate fuel cells  

DOE Green Energy (OSTI)

The Carbonate Fuel Cell is a very promising option for highly efficient generation of electricity from many fuels. If coal-gas is to be used, the interactions of coal-derived impurities on various fuel cell components need to be understood. Thus the effects on Carbonate Fuel Cell performance due to ten different coal-derived contaminants viz., NH{sub 3}, H{sub 2}S, HC{ell}, H{sub 2}Se, AsH{sub 3}, Zn, Pb, Cd, Sn, and Hg, have been studied at Energy Research Corporation. Both experimental and theoretical evaluations were performed, which have led to mechanistic insights and initial estimation of qualitative tolerance levels for each species individually and in combination with other species. The focus of this study was to investigate possible coal-gas contaminant effects on the anode side of the Carbonate Fuel Cell, using both out-of-cell thermogravimetric analysis by isothermal TGA, and fuel cell testing in bench-scale cells. Separate experiments detailing performance decay in these cells with high levels of ammonia contamination (1 vol %) and with trace levels of Cd, Hg, and Sn, have indicated that, on the whole, these elements do not affect carbonate fuel cell performance. However, some performance decay may result when a number of the other six species are present, singly or simultaneously, as contaminants in fuel gas. In all cases, tolerance levels have been estimated for each of the 10 species and preliminary models have been developed for six of them. At this stage the models are limited to isothermal, benchscale (300 cm{sup 2} size) single cells. The information obtained is expected to assist in the development of coal-gas cleanup systems, while the contaminant performance effects data will provide useful basic information for modeling fuel cell endurance in conjunction with integrated gasifier/fuel-cell systems (IGFC).

Not Available

1992-05-01T23:59:59.000Z

182

Direct electrochemical conversion of carbon anode fuels in molton salt media  

DOE Green Energy (OSTI)

We are conducting research into the direct electrochemical conversion of reactive carbons into electricity--with experimental evidence of total efficiencies exceeding 80% of the heat of combustion of carbon. Together with technologies for extraction of reactive carbons from broad based fossil fuels, direct carbon conversion addresses the objectives of DOE's ''21st Century Fuel Cell'' with exceptionally high efficiency (>70% based on standard heat of reaction, {Delta}H{sub std}), as well as broader objectives of managing CO{sub 2} emissions. We are exploring the reactivity of a wide range of carbons derived from diverse sources, including pyrolyzed hydrocarbons, petroleum cokes, purified coals and biochars, and relating their electrochemical reactivity to nano/microstructural characteristics.

Cherepy, N; Krueger, R; Cooper, J F

2001-01-17T23:59:59.000Z

183

Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids  

SciTech Connect

Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

2010-07-12T23:59:59.000Z

184

Non-segregating electrolytes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Current MCFCs use a Li/K carbonate mixture; the segregation increases the K concentration near the cathode, leading to increase cathode solubility and performance decline. ANL is developing molten carbonates that have minimal segregation; the approach is using Li-Na carbonates. In screening tests, fully developed potential distributions were obtained for 4 Li/Na compositions, and performance data were used to compare these.

Krumpelt, M.; Kaun, T.; Lanagan, M.

1996-08-01T23:59:59.000Z

185

Selection and preparation of activated carbon for fuel gas storage  

DOE Green Energy (OSTI)

Increasing the surface acidity of active carbons can lead to an increase in capacity for hydrogen adsorption. Increasing the surface basicity can facilitate methane adsorption. The treatment of carbons is most effective when the carbon source material is selected to have a low ash content i.e., below about 3%, and where the ash consists predominantly of alkali metals alkali earth, with only minimal amounts of transition metals and silicon. The carbon is washed in water or acid and then oxidized, e.g. in a stream of oxygen and an inert gas at an elevated temperature.

Schwarz, James A. (Fayetteville, NY); Noh, Joong S. (Syracuse, NY); Agarwal, Rajiv K. (Las Vegas, NV)

1990-10-02T23:59:59.000Z

186

A synthesis of carbon dioxide emissions from fossil-fuel combustion  

SciTech Connect

This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

Andres, Robert Joseph [ORNL; Boden, Thomas A [ORNL; Breon, F.-M. [CEA/DSM/LSCE, Gif sur Yvette, France; Ciais, P. [LSCE/CEA, Gif-sur-Yvette, France; Davis, S. [Carnegie Institution of Washington; Erickson, D [Oak Ridge National Laboratory (ORNL); Gregg, J. S. [Riso National Laboratory, Roskilde, Denmark; Jacobson, Andrew [NOAA ESRL and CIRES; Marland, Gregg [Appalachian State University; Miller, J. [NOAA ESRL and CIRES; Oda, T [NOAA ESRL/Boulder, CO/Cooperative Institute for Research in the Atmosphere, Colorado State Univ.; Oliver, J. G. J. [PBL Netherlands Environmental Assessment Agency, Bilthoven, The Netherlands; Raupach, Michael [CSIRO Marine and Atmospheric Research; Rayner, P [University of Melbourne, Australia; Treanton, K. [Energy Statistics Division, International Energy Agency, Paris, France

2012-01-01T23:59:59.000Z

187

The Temporal and Spatial Distribution of Carbon Dioxide Emissions from Fossil-Fuel Use in North America  

Science Conference Proceedings (OSTI)

Refinements in the spatial and temporal resolution of North American fossil-fuel carbon dioxide (CO2) emissions provide additional information about anthropogenic aspects of the carbon cycle. In North America, the seasonal and spatial patterns ...

J. S. Gregg; L. M. Losey; R. J. Andres; T. J. Blasing; G. Marland

2009-12-01T23:59:59.000Z

188

Novel carbon-ion fuel cells. Quarterly technical report No. 10, January 1, 1996--March 31, 1996  

DOE Green Energy (OSTI)

This report presents research to develop an entirely new, fundamentally different class of fuel cell using a solid electrolyte that transports carbon ions. This fuel cell would use solid carbon dissolved in molten metal as a fuel reservoir and anode; expensive gaseous or liquid fuel would not be required. A high temperature fuel cell based on a carbon ion membrane/electrolyte would operate in a way like yttria-doped zirconia solid oxide fuel cells; however, the fuel cell would transport the C ion from a fuel source to O{sub 2} in the atmosphere. Such fuel cells, operating above 1000 C, would produce an exhaust gas that could be fed directly into existing boilers, and could thus act as ``topping cycles`` to existing power plant steam cycles.

Cocks, F.H.

1996-08-01T23:59:59.000Z

189

Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity  

DOE Green Energy (OSTI)

We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

2001-03-07T23:59:59.000Z

190

Bipolar plate materials in molten carbonate fuel cells. Final CRADA report.  

DOE Green Energy (OSTI)

Advantages of implementation of power plants based on electrochemical reactions are successfully demonstrated in the USA and Japan. One of the msot promising types of fuel cells (FC) is a type of high temperature fuel cells. At present, thanks to the efforts of the leading countries that develop fuel cell technologies power plants on the basis of molten carbonate fuel cells (MCFC) and solid oxide fuel cells (SOFC) are really close to commercialization. One of the problems that are to be solved for practical implementation of MCFC and SOFC is a problem of corrosion of metal components of stacks that are assembled of a number of fuel cells. One of the major components of MCFC and SOFC stacks is a bipolar separator plate (BSP) that performs several functions - it is separation of reactant gas flows sealing of the joints between fuel cells, and current collection from the surface of electrodes. The goal of Task 1 of the project is to develop new cost-effective nickel coatings for the Russian 20X23H18 steel for an MCFC bipolar separator plate using technological processes usually implemented to apply corrosion stable coatings onto the metal parts for products in the defense. There was planned the research on production of nickel coatings using different methods, first of all the galvanic one and the explosion cladding one. As a result of the works, 0.4 x 712 x 1296 mm plates coated with nickel on one side were to be made and passed to ANL. A line of 4 galvanic baths 600 liters was to be built for the galvanic coating applications. The goal of Task 2 of the project is the development of a new material of an MCFC bipolar separator plate with an upgraded corrosion stability, and development of a technology to produce cold roll sheets of this material the sizes of which will be 0.8 x 712x 1296 mm. As a result of these works, a pilot batch of the rolled material in sheets 0.8 x 712 x 1296 mm in size is to be made (in accordance with the norms and standards of the Russian metallurgical industry) and supplied to the partner for tests in a stack of fuel cells. A feasibility study on the cost of the Russian material for a BSP is to be done on Tasks 1, 2 in case the annual order makes up 400,000 sheets. The goal of Task 3 of the project is to research on possible implementation of cermet compositions on the basis of LiAlO{sub 2}, TiN, B{sub 4}C, ceramics with Ni and Ni-Mo binders. BaCeO{sub 3} conductive ceramics with metal binders of Ni, Ni-Cr etc. were also planned to be studied. As a result of these works, a pilot batch of samples is to be made and passed to FCE for tests. The goal of Task 4 of the Project is development of a new alloy or alloys with a ceramic coating that will have upgraded corrosion stability in operation within a SOFC. A new alloy was to be worked out by the way of modification of compositions of industrial alloys. Ceramic coatings are to be applied onto ferrite steel produced serially by iron and steel industry of Russia as sheet iron.

Krumpelt, M.

2004-06-01T23:59:59.000Z

191

Greenhouse Gas Reductions Under Low Carbon Fuel Standards?  

E-Print Network (OSTI)

to equate the marginal production cost of each fuel across ?e.g. , gasoline, has production costs C H (q) with C H > 0ethanol or hydrogen, has production costs C L (q) with C L >

Holland, Stephen P.; Knittel, Christopher R; Hughes, Jonathan E.

2007-01-01T23:59:59.000Z

192

Novel carbon-ion fuel cells. Quarterly technical report No. 9, October 1, 1995--December 31, 1995  

DOE Green Energy (OSTI)

This report presents research to develop an entirely new, fundamentally different class of fuel cell using a solid electrolyte that transports carbon ions. This fuel cell would use solid carbon dissolved in molten metal as a fuel reservoir and anode; expensive gaseous or liquid fuel would not be required. Thermodynamic factors favor a carbon-ion fuel cell over other fuel cell designs: a combination of enthalpy, entropy, and Gibbs free energy makes the reaction of solid carbon and oxygen very efficient, and the entropy change allows this efficiency to slightly increase at high temperatures. The high temperature exhaust of the fuel cell would make it useful as a ``topping cycle``, to be followed by conventional steam turbine systems.

Cocks, F.H.

1995-12-31T23:59:59.000Z

193

Effects of coal-derived trace species on the performance of molten carbonate fuel cells  

DOE Green Energy (OSTI)

The overall objective of the present study was to determine in detail the interaction effects of 10 simultaneously present, coal-gas contaminants, both on each other and on components of the Carbonate Fuel Cell. The primary goal was to assess underlying chemistries and reaction mechanisms which may cause decay in fuel cell performance or endurance as a result of both physics-chemical and/or mechanical interactions with the cell components and internal fuel cell parts. It was found, both from theory and cell test evidence, that trace contaminant interactions may occur with: Fuel-cell Electrodes (e.g., in this study with the Ni-anode), Lithium/Potassium Carbonate Electrolyte, Nickel and SS-Hardware, and by Mechanical Obstruction of Gas Flow in the Anode Plenum.

Pigeaud, A.

1991-10-01T23:59:59.000Z

194

Fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Goals > Fuels Goals > Fuels XMAT for nuclear fuels XMAT is ideally suited to explore all of the radiation processes experienced by nuclear fuels.The high energy, heavy ion accleration capability (e.g., 250 MeV U) can produce bulk damage deep in the sample, achieving neutron type depths (~10 microns), beyond the range of surface sputtering effects. The APS X-rays are well matched to the ion beams, and are able to probe individual grains at similar penetrations depths. Damage rates to 25 displacements per atom per hour (DPA/hr), and doses >2500 DPA can be achieved. MORE» Fuels in LWRs are subjected to ~1 DPA per day High burn-up fuel can experience >2000 DPA. Traditional reactor tests by neutron irradiation require 3 years in a reactor and 1 year cool down. Conventional accelerators (>1 MeV/ion) are limited to <200-400 DPAs, and

195

Carbon dioxide emission index as a mean for assessing fuel quality  

Science Conference Proceedings (OSTI)

Carbon dioxide emission index, defined as the amount of CO{sub 2} released per unit of energy value, was used to rate gaseous, liquid and solid fuels. The direct utilization of natural gas is the most efficient option. The conversion of natural gas to synthesis gas for production of liquid fuels represents a significant decrease in fuel value of the former. The fuel value of liquids, such as gasoline, diesel oil, etc. is lower than that of natural gas. Blending gasoline with ethanol obtained either from bio-mass or via synthesis may decrease fuel value of the blend when CO{sub 2} emissions produced during the production of ethanol are included in total emissions. The introduction of liquid fuels produced by pyrolysis and liquefaction of biomass would result in the increase in the CO{sub 2} emissions. The CO{sub 2} emissions from the utilization of coal and petroleum coke are much higher than those from gaseous and liquid fuels. However, for petroleum coke, this is offset by the high value gaseous and liquid fuels that are simultaneously produced during coking. Conversion of low value fuels such as coal and petroleum coke to a high value chemicals via synthesis gas should be assessed as means for replacing natural gas and making it available for fuel applications.

Furimsky, E. [IMAF Group, Ottawa, ON (Canada)

2008-07-01T23:59:59.000Z

196

Near-frictionless carbon coatings for use in fuel injectors and pump systems operating with low-sulfur diesel fuels  

DOE Green Energy (OSTI)

While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO{sub 2} emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. This research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems. The lubricity of various diesel fuels (i.e., high-sulfur, 500 ppm; low sulfur, 140 ppm; ultra-clean, 3 ppm; and synthetic diesel or Fischer-Tropsch, zero sulfur) were tested by using both uncoated and NFC-coated 52100 steel specimens in a ball-on-three-disks and a high-frequency reciprocating wear-test rig. The test program was expanded to include some gasoline fuels as well (i.e., regular gasoline and indolene) to further substantiate the usefulness of the NFC coatings in low-sulfur gasoline environments. The results showed that the NFC coating was extremely effective in reducing wear and providing lubricity in low-sulfur or sulfur-free diesel and gasoline fuels. Specifically, depending on the wear test rig, test pair, and test media, the NFC films were able to reduce wear rates of balls and flats by factors of 8 to 83. These remarkable reductions in wear rates raise the prospect for using the ultra slick carbon coatings to alleviate problems that will be caused by the use of low sulfur diesel and gasoline fuels. Surfaces of the wear scars and tracks were characterized by optical and scanning electron microscopy, and by Raman spectroscopy.

Erdemir, A.; Ozturk, O.; Alzoubi, M.; Woodford, J.; Ajayi, L.; Fenske, G.

2000-01-19T23:59:59.000Z

197

High Strength Carbon Fibers - DOE Hydrogen and Fuel Cells Program...  

NLE Websites -- All DOE Office Websites (Extended Search)

System and yielding 15 Msi modulus and 150 ksi. Technical Barriers High-strength carbon fibers account for approximately 65% of the cost of the high-pressure storage tanks....

198

Novel carbon-ion fuel cells. Second quarter 1995 technical progress report, April 1995--June 1995  

DOE Green Energy (OSTI)

Research continued on carbon-ion fuel cells. This period, the project is proceeding with the construction of an apparatus to create a solid electrolyte in the form of castings, or highly pressed and sintered pellets of CeC{sub 2} and LaC{sub 2} and to test the castings or pellets for the ionic conduction of carbon-ions across the electrolyte.

LaViers, H.

1995-06-30T23:59:59.000Z

199

Porous electrolyte retainer for molten carbonate fuel cell. [lithium aluminate  

DOE Patents (OSTI)

A porous tile for retaining molten electrolyte within a fuel cell is prepared by sintering particles of lithium aluminate into a stable structure. The tile is assembled between two porous metal plates which serve as electrodes with fuels gases such as H/sub 2/ and CO opposite to oxidant gases such as O/sub 2/ and CO/sub 2/. The tile is prepared with a porosity of 55 to 65% and a pore size distribution selected to permit release of sufficient molten electrolyte to wet but not to flood the adjacent electrodes.

Singh, R.N.; Dusek, J.T.

1979-12-27T23:59:59.000Z

200

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

DOE Green Energy (OSTI)

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

DOE Green Energy (OSTI)

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-01-01T23:59:59.000Z

202

Development of molten-carbonate fuel cells for power generation. Quarterly progress report, 15 November 1978-15 February 1979  

DOE Green Energy (OSTI)

Molten carbonate fuel cell research and development at General Electric Company during the three month period beginning 15 November 1978 and ending 15 February 1979 is described. The objectives of this Phase I effort include the development of promising concepts to circumvent a number of outstanding technical challenges in molten carbonate fuel cell technology and the better definition of the operating limits of molten carbonate fuel cells and power plant based thereupon. During this quarter of the program, principal activities have been the operation of experimental molten carbonate fuel cells using pure and H/sub 2/S- and HCl-contaminated fuels which simulate coal-derived fuels, the development of synthesis and fabrication techniques to prepare electrolyte tiles, the diagnostic analysis of new and used electrolyte tiles, the quantification of anode sintering, the fabrication of a 10 in. x 10 in. scaled-up single cell, and design activities leading to a stackable 10 in. x 10 in. cell.

Not Available

1979-03-01T23:59:59.000Z

203

Photo-Ignition of Liquid Fuel Spray and Solid Fuel by Carbon ...  

Science Conference Proceedings (OSTI)

3D Multiwall Carbon Nanotubes (MWCNTs) for Li-Ion Battery Anode ... Applications of TiO2 Nanotubular Arrays by Atomic Layer Deposition and Nanotemplating.

204

SPOUTED BED ELECTRODES (SBE) FOR DIRECT UTILIZATION OF CARBON IN FUEL CELLS  

DOE Green Energy (OSTI)

This Phase I project was focused on an investigation of spouted bed particulate electrodes for the direct utilization of solid carbon in fuel cells. This approach involves the use of a circulating carbon particle/molten carbonate slurry in the cell that provides a few critical functions: it (1) fuels the cell continuously with entrained carbon particles; (2) brings particles to the anode surfaces hydrodynamically; (3) removes ash from the anode surfaces and the cell hydrodynamically; (4) provides a facile means of cell temperature control due to its large thermal capacitance; (5) provides for electrolyte maintenance and control in the electrode separator(s); and (6) can (potentially) improve carbon conversion rates by ''pre-activating'' carbon particle surfaces via formation of intermediate oxygen surface complexes in the bulk molten carbonate. The approach of this scoping project was twofold: (1) adaptation and application of a CFD code, originally developed to simulate particle circulation in spouted bed electrolytic reactors, to carbon particle circulation in DCFC systems; and (2) experimental investigation of the hydrodynamics of carbon slurry circulation in DCFC systems using simulated slurry mixtures. The CFD model results demonstrated that slurry recirculation can be used to hydrodynamically feed carbon particles to anode surfaces. Variations of internal configurations were investigated in order to explore effects on contacting. It was shown that good contacting with inclined surfaces could be achieved even when the particles are of the same density as the molten carbonate. The use of CO{sub 2} product gas from the fuel cell as a ''lift-gas'' to circulate the slurry was also investigated with the model. The results showed that this is an effective method of slurry circulation; it entrains carbon particles more effectively in the draft duct and produces a somewhat slower recirculation rate, and thus higher residence times on anode surfaces, and can be controlled completely via pressure balance. Experimental investigations in a rectangular spouted vessel hydrodynamics apparatus (SVHA) showed that hydrodynamics can be used to control the circulation, residence time, and distribution of carbon within the spouted bed, as well as provide good particle contact with anode surfaces. This was shown to be a function of viscosity, carbon loading, and particle size, as well as relative densities. Higher viscosities and smaller particle sizes favor more efficient particle entrainment in the draft duct, and particle recirculation. Both the computational and experimental results are consistent with each another and exhibit the same general qualitative behavior. Based upon this work, a design of a prototype SBE/DCFC cell was developed and is presented.

J.M. Calo

2004-12-01T23:59:59.000Z

205

Creep resistant, metal-coated LiFeO[sub 2] anodes for molten carbonated fuel cells  

DOE Patents (OSTI)

A porous, creep-resistant, metal-coated, LiFeO[sub 2] ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well. 11 figs.

Khandkar, A.C.

1994-08-23T23:59:59.000Z

206

Creep resistant, metal-coated LiFeO.sub.2 anodes for molten carbonated fuel cells  

DOE Patents (OSTI)

A porous, creep-resistant, metal-coated, LiFeO.sub.2 ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well.

Khandkar, Ashok C. (Salt Lake City, UT)

1994-01-01T23:59:59.000Z

207

Molten carbonate fuel cell (MCFC) product development test. Annual report, October 1994--September 1995  

DOE Green Energy (OSTI)

This report summarizes the technical progress that has occurred in conjunction with Cooperative Agreement No. DE-FC21-92MC28065, Molten Carbonate Fuel Cell Product Development Test (PDT) during the period of October 1, 1994 through September 30, 1995. Information is presented on stack design, manufacturing, stack assembly, procurement, site preparation, and test plan.

NONE

1996-01-01T23:59:59.000Z

208

Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report  

DOE Green Energy (OSTI)

The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

209

A carbon riveted Pt/Graphene catalyst with high stability for direct methanol fuel cell  

Science Conference Proceedings (OSTI)

Pt/Graphene catalyst was prepared by microwave-assisted polyol process, and carbonization was riveted onto the catalyst surface to enhance the catalyst stability. The physical properties of the obtained catalysts were characterized by X-ray diffraction ... Keywords: Direct methanol fuel cell, Methanol electrooxidation, Pt/Graphene, Stability

Xiaowei Liu, Jialin Duan, Hailong Chen, Yufeng Zhang, Xuelin Zhang

2013-10-01T23:59:59.000Z

210

Carbon Supported Polyaniline as Anode Catalyst: Pathway to Platinum-Free Fuel Cells  

E-Print Network (OSTI)

The effectiveness of carbon supported polyaniline as anode catalyst in a fuel cell (FC) with direct formic acid electrooxidation is experimentally demonstrated. A prototype FC with such a platinum-free composite anode exhibited a maximum room-temperature specific power of about 5 mW/cm2

Zabrodskii, A G; Malyshkin, V G; Sapurina, I Y

2006-01-01T23:59:59.000Z

211

Ranking of enabling technologies for oxy-fuel based carbon capture  

Science Conference Proceedings (OSTI)

The USDOE National Energy Technology Laboratory (NETL) has begun a process to identify and rank enabling technologies that have significant impacts on pulverized coal oxy-fuel systems. Oxy-fuel combustion has been identified as a potential method for effectively capturing carbon in coal fired power plants. Presently there are a number of approaches for carbon capture via oxy-fuel combustion and it is important to order those approaches so that new research can concentrate on those technologies with high potentials to substantially lower the cost of reduced carbon electricity generation. NETL evaluates these technologies using computer models to determine the energy use of each technology and the potential impact of improvements in the technologies on energy production by a power plant. Near-term sub-critical boiler technologies are targeted for this analysis because: • most of the world continues to build single reheat sub-critical plants; • the overwhelming number of coal fired power plants requiring retrofit for CO2 capture are sub-critical plants. In addition, even in the realm of new construction, subcritical plants are common because they are well understood, easy to operate and maintain, fuel tolerant, and reliable. Following the initial investigation into sub-critical oxy-fuel technology, future investigations will move into the supercritical range.

Ochs, T.L.; Oryshchyn, D.L.; Ciferno, J.P.

2007-06-01T23:59:59.000Z

212

ANALYTIC APPROXIMATION OF CARBON CONDENSATION ISSUES IN TYPE II SUPERNOVAE  

SciTech Connect

I present analytic approximations for some issues related to condensation of graphite, TiC, and silicon carbide in oxygen-rich cores of supernovae of Type II. Increased understanding, which mathematical analysis can support, renders researchers more receptive to condensation in O-rich supernova gases. Taking SN 1987A as typical, my first analysis shows why the abundance of CO molecules reaches an early maximum in which free carbon remains more abundant than CO. This analysis clarifies why O-rich gas cannot oxidize C if {sup 56}Co radioactivity is as strong as in SN 1987A. My next analysis shows that the CO abundance could be regarded as being in chemical equilibrium if the CO molecule is given an effective binding energy rather than its laboratory dissociation energy. The effective binding energy makes the thermal dissociation rate of CO equal to its radioactive dissociation rate. This preserves possible relevance for the concept of chemical equilibrium. My next analysis shows that the observed abundances of CO and SiO molecules in SN 1987A rule out frequent suggestions that equilibrium condensation of SUNOCONs has occurred following atomic mixing of the He-burning shell with more central zones in such a way as to reproduce roughly the observed spectrum of isotopes in SUNOCONs while preserving C/O > 1. He atoms admixed along with the excess carbon would destroy CO and SiO molecules, leaving their observed abundances unexplained. The final analysis argues that a chemical quasiequilibrium among grains (but not gas) may exist approximately during condensation, so that its computational use is partially justified as a guide to which mineral phases would be stable against reactions with gas. I illustrate this point with quasiequilibrium calculations by Ebel and Grossman that have shown that graphite is stable even when O/C >1 if prominent molecules are justifiably excluded from the calculation of chemical equilibrium.

Clayton, Donald D., E-mail: claydonald@gmail.com [Department of Physics and Astronomy, Clemson University, Clemson, SC (United States)

2013-01-01T23:59:59.000Z

213

Combined Power Generation and Carbon Sequestration Using Direct FuelCell  

DOE Green Energy (OSTI)

The unique chemistry of carbonate fuel cell offers an innovative approach for separation of carbon dioxide from greenhouse gases (GHG). The carbonate fuel cell system also produces electric power at high efficiency. The simultaneous generation of power and sequestration of greenhouse gases offer an attractive scenario for re-powering the existing coal-fueled power plants, in which the carbonate fuel cell would separate the carbon dioxide from the flue gas and would generate additional pollutant-free electric power. Development of this system is concurrent with emergence of Direct FuelCell{reg_sign} (DFC{reg_sign}) technology for generation of electric power from fossil fuels. DFC is based on carbonate fuel cell featuring internal reforming. This technology has been deployed in MW-scale power plants and is readily available as a manufactured product. This final report describes the results of the conceptualization study conducted to assess the DFC-based system concept for separation of CO2 from GHG. Design and development studies were focused on integration of the DFC systems with coal-based power plants, which emit large amounts of GHG. In parallel to the system design and simulation activities, operation of laboratory scale DFC verified the technical concept and provided input to the design activity. The system was studied to determine its effectiveness in capturing more than ninety percent of CO2 from the flue gases. Cost analysis was performed to estimate the change in cost of electricity for a 200 MW pulverized coal boiler steam cycle plant retrofitted with the DFC-based CO2 separation system producing an additional 127 MW of electric power. The cost increments as percentage of levelized cost of electricity were estimated for a range of separation plant installations per year and a range of natural gas cost. The parametric envelope meeting the goal (<20% increase in COE) was identified. Results of this feasibility study indicated that DFC-based separation systems have the potential for capturing at least 90% of the emissions from the greenhouse gases generated by power plants and other industrial exhaust streams, and yet entail in less than 20% increase in the cost of energy services for long-term deployment (beyond 2012). The anticipated cost of energy increase is in line with DOE's goal for post-combustion systems as outlined in the ''Carbon Capture and Sequestration Systems Analysis Guidelines'', published by NETL, April 2005. During the course of this study certain enabling technologies were identified and the needs for further research and development were discussed.

Hossein Ghezel-Ayagh

2006-03-01T23:59:59.000Z

214

Geographic Patterns of Carbon Dioxide Emissions from Fossil-Fuel Burning,  

NLE Websites -- All DOE Office Websites (Extended Search)

Fossil Fuel CO2 Emissions » Gridded Estimates for Benchmark Years Fossil Fuel CO2 Emissions » Gridded Estimates for Benchmark Years Geographic Patterns of Carbon Dioxide Emissions from Fossil-Fuel Burning, Hydraulic Cement Production, and Gas Flaring on a One Degree by One Degree Grid Cell Basis: 1950 to 1990 (NDP-058) data Data image ASCII Text Documentation PDF file PDF file Contributors R. J. Andres, G. Marland, I. Fung, and E. Matthews (contributors) DOI DOI: 10.3334/CDIAC/ffe.ndp058 This data package presents data sets recording 1° latitude by 1° longitude CO2 emissions in units of thousand metric tons of carbon per year from anthropogenic sources for 1950, 1960, 1970, 1980, and 1990. Detailed geographic information on CO2 emissions can be critical in understanding the pattern of the atmospheric and biospheric response to these emissions.

215

Mobility and Carbon: The Blind Side of Transport Fuel Demand in the  

NLE Websites -- All DOE Office Websites (Extended Search)

Mobility and Carbon: The Blind Side of Transport Fuel Demand in the Mobility and Carbon: The Blind Side of Transport Fuel Demand in the Developed and Developing World Speaker(s): Lee Schipper Date: February 15, 2011 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Anita Estner James McMahon A new "Great Wall" has emerged in China, this one a string of miles of cars stuck in traffic. Emissions from road transport in developing countries are expected to rise sharply in the coming decades if current trends continue. Projections of passenger and freight activity, vehicle use, and CO2 emissions push up overall CO2 emissions by a factor of three in Latin American and five in Asia by 2030, even with fuel economy improvements. The increase in car use is in part a result of growing incomes and economic activity, but it also reflects the poor quality of transit and

216

Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 data Data image Documentation Contributors R.J. Andres, T.A. Boden, and G. Marland The 2012 revision of this database contains estimates of the annual, global mean value of δ 13C of CO2 emissions from fossil-fuel consumption and cement manufacture for 1751-2009. These estimates of the carbon isotopic signature account for the changing mix of coal, petroleum, and natural gas being consumed and for the changing mix of petroleum from various producing areas with characteristic isotopic signatures. This time series of global fossil-fuel del 13C signature provides an additional constraint for balancing the sources and sinks of the global carbon cycle and complements the atmospheric δ 13C measurements that are used to partition the uptake of fossil carbon emissions among the ocean, atmosphere, and terrestrial

217

Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 data Data image Documentation Contributors R.J. Andres, T.A. Boden, and G. Marland The 2013 revision of this database contains estimates of the annual, global mean value of δ 13C of CO2 emissions from fossil-fuel consumption and cement manufacture for 1751-2010. These estimates of the carbon isotopic signature account for the changing mix of coal, petroleum, and natural gas being consumed and for the changing mix of petroleum from various producing areas with characteristic isotopic signatures. This time series of global fossil-fuel del 13C signature provides an additional constraint for balancing the sources and sinks of the global carbon cycle and complements the atmospheric δ 13C measurements that are used to partition the uptake of fossil carbon emissions among the ocean, atmosphere, and terrestrial

218

Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 data Data image Documentation Contributors R.J. Andres, T.A. Boden, and G. Marland The 2011 revision of this database contains estimates of the annual, global mean value of del 13C of CO2 emissions from fossil-fuel consumption and cement manufacture for 1751-2008. These estimates of the carbon isotopic signature account for the changing mix of coal, petroleum, and natural gas being consumed and for the changing mix of petroleum from various producing areas with characteristic isotopic signatures. This time series of global fossil-fuel del 13C signature provides an additional constraint for balancing the sources and sinks of the global carbon cycle and complements the atmospheric del 13C measurements that are used to partition the uptake of fossil carbon emissions among the ocean, atmosphere, and terrestrial

219

Table 2. 2010 state energy-related carbon dioxide emissions by fuel  

U.S. Energy Information Administration (EIA) Indexed Site

2010 state energy-related carbon dioxide emissions by fuel " 2010 state energy-related carbon dioxide emissions by fuel " "million metric tons of carbon dioxide" ,,,,,," Shares " "State","Coal","Petroleum","Natural Gas ","Total","Coal","Petroleum","Natural Gas" "Alabama",67.81545193,35.95576449,28.97505976,132.7462762,0.5108651925,0.2708608145,0.218273993 "Alaska",1.364880388,19.58916888,17.77313443,38.72718369,0.03524347131,0.5058247724,0.4589317562 "Arizona",43.2377726,34.82066125,17.85460129,95.91303514,0.4508018387,0.3630440972,0.1861540641 "Arkansas",27.72445786,23.82768621,14.56726112,66.11940519,0.4193089424,0.3603735717,0.2203174859 "California",5.157135123,241.2575077,123.3955377,369.8101805,0.01394535736,0.6523820067,0.3336726359

220

Reactions of the Carbon Anode in Alternative Battery and Fuel Cell Configurations  

Science Conference Proceedings (OSTI)

A model is formulated by combining carbonate dissociation with pre-existing anode mechanisms involving heterogeneous reaction kinetics. The proposed model accounts for both the observed preponderance of CO{sub 2} evolution and dependence of rate on carbon anode microstructure. Implications of the model for the design of carbon batteries and fuel cells are discussed, and the laboratory cells used in earlier research are described. High coulombic efficiencies for the net reaction C + O{sub 2} = CO{sub 2} require severely limiting the thickness of paste anodes in powder-fed fuel cells while the unreacting surfaces of solid prismatic anodes must be isolated from the CO{sub 2} product atmosphere to prevent Boudouard corrosion, according to C + CO{sub 2} = 2CO.

Cooper, J F; Krueger, R

2003-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Design and Test of a Carbon-Tolerant Alkaline Fuel Cell  

E-Print Network (OSTI)

This paper presents new results which may constitute a breakthrough in the effort to develop fuel cells truly suitable for use in cars and trucks. For decades, researchers have known that the alkaline fuel cell (AFC) is much cheaper to make, more efficient and more durable than the more popular PEM fuel cell; however, "carbon poisoning" (either from CO2 in air or from contaminants in reformed methanol) causes big problems in the kind of oxygen-hydrogen AFC commonly used in space. This paper reports successful tests of a technique for coating the electrodes with polystyrene which, in conjunction with older common-sense techniques, appears to solve the problem. This kind of design is applicable to cars run on hydrogen fuel, on reformed methanol or even direct methanol. Developing a test methodology was a major part of the work. A foreword by one of the sponsors at NSF discusses the larger importance of this work for energy security and the environment.

Urquidi-Macdonald, M; Grimes, P; Tewari, A; Sambhy, V; Urquidi-Macdonald, Mirna; Sen, Ayusman; Grimes, Patrick; Tewari, Ashutosh; Sambhy, Varun

2005-01-01T23:59:59.000Z

222

The potential application of fuel cell cogeneration systems in petroleum refineries. [Phosphoric acid, molten carbonate and solid oxide fuel cells  

Science Conference Proceedings (OSTI)

The market potential for fuel cell cogeneration systems within the petroleum refinery industry is evaluated. Phosphoric acid (PAFC), molten carbonate (MCFC), and solid oxide (SOFC) fuel cells were considered. Conventional competitive systems now available including purchased power plus boiler-generated steam, gas turbine combined cycle, and a relatively new coke fluidized bed-boiler were characterized. Refineries use large quantities of steam at pressures ranging from about 15 to 650 psig. PAFCs can only meet a limited number of steam requirements because of their relatively low operating temperature. The high temperature MCFC and SOFC are technically much more attractive for this application. However, current estimates of their capital costs are too large to make the technologies competitive. The capital costs of MCFCs and SOFCs would have to decrease approx.50% from their present estimated $1300/kWe. If costs could be decreased to give a 10% energy cost advantage to fuel cells, the industry projects that fuel cells might supply about 300 MWe by the year 2000, and modules in the 5- to 20-MWe size would be of interest. The market opportunities in refineries are varied - the industry is large, each plant is unique, thermal energy consumption is large, and both domestic and international competitiveness is intense. 10 refs., 26 figs., 17 tabs.

Altseimer, J.H.; Roach, F.; Anderson, J.M.; Krupka, M.C.

1987-08-01T23:59:59.000Z

223

Transportation Sector Energy Use by Fuel Type Within a Mode from...  

Open Energy Info (EERE)

Transportation Sector Energy Use by Fuel Type Within a Mode from EIA AEO 2011 Early Release Supplemental Table 46 of EIA AEO 2011 Early Release
2011-02-23T15:55:10Z...

224

U.S. Product Supplied of Kerosene-Type Jet Fuel (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Product Supplied of Kerosene-Type Jet Fuel (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9; 1980's: 295,460 ...

225

U.S. Exports to Italy of Kerosene-Type Jet Fuel (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Exports to Italy of Kerosene-Type Jet Fuel (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 2005: 2: 2008: 23: 9: 18: 2009: 89: 2010: 10 ...

226

New Jersey Kerosene-Type Jet Fuel All Sales/Deliveries by Prime ...  

U.S. Energy Information Administration (EIA)

New Jersey Kerosene-Type Jet Fuel All Sales/Deliveries by Prime Supplier (Thousand Gallons per Day) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8

227

U.S. Kerosene-Type Jet Fuel All Sales/Deliveries by Prime Supplier ...  

U.S. Energy Information Administration (EIA)

U.S. Kerosene-Type Jet Fuel All Sales/Deliveries by Prime Supplier (Thousand Gallons per Day) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1983: 30,535.1 ...

228

Postcombustion measures for cleaner solid fuels combustion: activated carbons for toxic pollutants removal from flue gases  

SciTech Connect

In this work the efficiency of postcombustion measures (i.e., activated carbon utilization) to achieve cleaner solid fuels combustion was evaluated. Thus, two commercial activated carbons (Calgon F400 and RWE active coke) were tested for removing toxic polluting compounds (Hg, PCBs, PCDD/Fs) from the gas phase. The effects of the pore structure and surface chemistry of the activated carbons tested were investigated, along with the sorption temperature and sulfur addition in carbon matrix. Experiments were realized in a bench-scale adsorption unit and in a commercial solid fuels-fired hot water boiler. The results showed that both activated carbons tested are suitable for the removal of toxic compounds (i.e., Hg, PCBs, PCDD/Fs) from the gas phase. Due to differences in Hg adsorptive capacity and adsorption rate, which are attributed to the diversified pore structure and surface chemistry of the activated carbons, RWE active coke is, presumably, more suitable for continuous Hg removal (i.e., activated carbon injection), while Calgon F400 is more suitable for batch one (packed column). For both activated carbons, Hg adsorption capacity was reduced with temperature increase, while it was enhanced by the presence of sulfur. Oxygen surface functional groups seem to be involved in Hg adsorption mechanism. Lactones are believed to act as potential active sites for mercury adsorption, while phenols may act as inhibitors. The removal of PCBs and PCDD/Fs from the gas phase seems not to be a problem for the activated carbons tested, regardless of their pore structure or surface chemistry. 61 refs., 23 figs., 8 tabs.

G. Skodras; I. Diamantopoulou; P. Natas; A. Palladas; G.P. Sakellaropoulos [Aristotle University of Thessaloniki, Thessaloniki (Greece). Chemical Process Engineering Laboratory, Department of Chemical Engineering

2005-12-01T23:59:59.000Z

229

Residual Fuel Oil Bulk Terminal Stocks by Type  

U.S. Energy Information Administration (EIA)

Stock Type: Download Series History: Definitions, Sources & Notes: Show Data By: Product: Stock Type: Area: Jan-13 Feb-13 Mar-13 Apr-13 May-13 Jun-13 View History; U ...

230

Electrolyte matrix in a molten carbonate fuel cell stack  

DOE Patents (OSTI)

A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack. 6 figs.

Reiser, C.A.; Maricle, D.L.

1987-04-21T23:59:59.000Z

231

Electrolyte matrix in a molten carbonate fuel cell stack  

DOE Patents (OSTI)

A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack.

Reiser, Carl A. (Glastonbury, CT); Maricle, Donald L. (Glastonbury, CT)

1987-04-21T23:59:59.000Z

232

Electrolyte matrix in a molten carbonate fuel cell stack  

DOE Patents (OSTI)

A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack to the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack.

Reiser, C.A.; Maricle, D.L.

1986-05-27T23:59:59.000Z

233

Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios  

DOE Green Energy (OSTI)

Achieving the Department of Energy target of an 80% reduction in greenhouse gas emissions by 2050 depends on transportation-related strategies combining technology innovation, market adoption, and changes in consumer behavior. This study examines expanding low-carbon transportation fuel infrastructure to achieve deep GHG emissions reductions, with an emphasis on fuel production facilities and retail components serving light-duty vehicles. Three distinct low-carbon fuel supply scenarios are examined: Portfolio: Successful deployment of a range of advanced vehicle and fuel technologies; Combustion: Market dominance by hybridized internal combustion engine vehicles fueled by advanced biofuels and natural gas; Electrification: Market dominance by electric drive vehicles in the LDV sector, including battery electric, plug-in hybrid, and fuel cell vehicles, that are fueled by low-carbon electricity and hydrogen. A range of possible low-carbon fuel demand outcomes are explored in terms of the scale and scope of infrastructure expansion requirements and evaluated based on fuel costs, energy resource utilization, fuel production infrastructure expansion, and retail infrastructure expansion for LDVs. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored transportation-related strategies for abating GHGs and reducing petroleum dependence.

Melaina, M. W.; Heath, G.; Sandor, D.; Steward, D.; Vimmerstedt, L.; Warner, E.; Webster, K. W.

2013-04-01T23:59:59.000Z

234

Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.  

DOE Green Energy (OSTI)

The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is compatible with much of the existing fuel infrastructure.

Allendorf, Mark D. (Sandia National Laboratories, Livermore, CA); Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

2009-01-01T23:59:59.000Z

235

Method of preparing a dimensionally stable electrode for use in a molten carbonate fuel cell  

DOE Patents (OSTI)

A method is disclosed for preparing a dimensionally stable electrode structure, particularly nickel-chromium anodes, for use in a molten carbonate fuel cell stack. A low-chromium to nickel alloy is provided and oxidized in a mildly oxidizing gas of sufficient oxidation potential to oxidize chromium in the alloy structure. Typically, a steam/H/sub 2/ gas mixture in a ratio of about 100/1 and at a temperature below 800/sup 0/C is used as the oxidizing medium. This method permits the use of less than 5 wt % chromium in nickel alloy electrodes while obtaining good resistance to creep in the electrodes of a fuel cell stack.

Swarr, T.E.; Wnuck, W.G.

1986-01-29T23:59:59.000Z

236

The U.S. molten carbonate fuel-cell development and commercialization effort  

SciTech Connect

The authors discuss the status of molten carbonate fuel-cell (MCFC) development in the U.S., including the role of the U.S. Department of Energy (DOE) in commercializing MCFC power-plant products for use by gas utility and electric power industries. They describe major fundamental stack research issues, as well as MCF power-plant network and system issues, that need to be resolved before MCFC technology can be commercialized. A significant initiative in MCFC research is the spatial configuration of MCFC stacks into networks in a fuel-cell power plant.

Williams, M.C.; Parsons, E.L. Jr.; Mayfield, M.J.

1994-09-01T23:59:59.000Z

237

The U.S. molten carbonate fuel-cell development and commercialization effort  

SciTech Connect

The authors discuss the status of molten carbonate fuel-cell (MCFC) development in the US, including the role of the US Department of Energy (DOE) in commercializing MCFC power-plant products for use by gas utility and electric power industries. The authors describe major fundamental stack research issues, as well as MCFC power-plant network and system issues, that need to be resolved before MCFC technology can be commercialized. A significant initiative in MCFC research is the spatial configuration of MCFC stacks into networks in a fuel-cell power plant.

Williams, M.C.; Parsons, E.L. Jr.; Mayfield, M.J.

1995-03-01T23:59:59.000Z

238

OPTIMIZED FUEL INJECTOR DESIGN FOR MAXIMUM IN-FURNACE NOx REDUCTION AND MINIMUM UNBURNED CARBON  

SciTech Connect

Reaction Engineering International (REI) has established a project team of experts to develop a technology for combustion systems which will minimize NO x emissions and minimize carbon in the fly ash. This much need technology will allow users to meet environmental compliance and produce a saleable by-product. This study is concerned with the NO x control technology of choice for pulverized coal fired boilers, ?in-furnace NO x control,? which includes: staged low-NO x burners, reburning, selective non-catalytic reduction (SNCR) and hybrid approaches (e.g., reburning with SNCR). The program has two primary objectives: 1) To improve the performance of ?in-furnace? NO x control processes. 2) To devise new, or improve existing, approaches for maximum ?in-furnace? NO x control and minimum unburned carbon. The program involves: 1) fundamental studies at laboratory- and bench-scale to define NO reduction mechanisms in flames and reburning jets; 2) laboratory experiments and computer modeling to improve our two-phase mixing predictive capability; 3) evaluation of commercial low-NO x burner fuel injectors to develop improved designs, and 4) demonstration of coal injectors for reburning and low-NO x burners at commercial scale. The specific objectives of the two-phase program are to: 1 Conduct research to better understand the interaction of heterogeneous chemistry and two phase mixing on NO reduction processes in pulverized coal combustion. 2 Improve our ability to predict combusting coal jets by verifying two phase mixing models under conditions that simulate the near field of low-NO x burners. 3 Determine the limits on NO control by in-furnace NO x control technologies as a function of furnace design and coal type. 5 Develop and demonstrate improved coal injector designs for commercial low-NO x burners and coal reburning systems. 6 Modify the char burnout model in REI?s coal combustion code to take account of recently obtained fundamental data on char reactivity during the late stages of burnout. This will improve our ability to predict carbon burnout with low-NO x firing systems.

A.F. SAROFIM; BROWN UNIVERSITY. R.A. LISAUSKAS; D.B. RILEY, INC.; E.G. EDDINGS; J. BROUWER; J.P. KLEWICKI; K.A. DAVIS; M.J. BOCKELIE; M.P. HEAP; REACTION ENGINEERING INTERNATIONAL. D.W. PERSHING; UNIVERSITY OF UTAH. R.H. HURT

1998-01-01T23:59:59.000Z

239

Method of evaluating the integrity of the outer carbon layer of triso-coated reactor fuel particles  

DOE Patents (OSTI)

This invention relates to a method for determining defective final layers of carbon on triso-coated fuel particles and the like. Samples of the particles are subjected to a high temperature treatment with gaseous chlorine and thereafter radiographed. The chlorine penetrates through any defective carbon layer and reacts with the underlying silicon carbide resulting in the volatilization of the silicon as SiCl.sub.4 leaving carbon as a porous layer. This porous carbon layer is easily detected by the radiography.

Caputo, Anthony J. (Knoxville, TN); Costanzo, Dante A. (Oak Ridge, TN); Lackey, Jr., Walter J. (Oak Ridge, TN); Layton, Frank L. (Clinton, TN); Stinton, David P. (Knoxville, TN)

1980-01-01T23:59:59.000Z

240

Transportation Sector Energy Use by Fuel Type Within a Mode from EIA AEO  

Open Energy Info (EERE)

Sector Energy Use by Fuel Type Within a Mode from EIA AEO Sector Energy Use by Fuel Type Within a Mode from EIA AEO 2011 Early Release Dataset Summary Description Supplemental Table 46 of EIA AEO 2011 Early Release Source EIA Date Released December 08th, 2010 (3 years ago) Date Updated Unknown Keywords AEO Annual Energy Outlook EIA Energy Information Administration Fuel mode TEF transportation Transportation Energy Futures Data text/csv icon Transportation_Sector_Energy_Use_by_Fuel_Type_Within_a_Mode.csv (csv, 144.3 KiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset Usefulness of the metadata Average vote Your vote Usefulness of the dataset Average vote Your vote

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Multi-objective fuel policies: Renewable fuel standards versus Fuel greenhouse gas intensity standards  

E-Print Network (OSTI)

under Low Carbon Fuel Standards? American Economic Journal:the Low Carbon Fuel Standard, Volume I Sta? Report: Initialpolicies: Renewable fuel standards versus Fuel greenhouse

Rajagopal, Deepak

2010-01-01T23:59:59.000Z

242

Novel carbon-ion fuel cells. Final report, October 1, 1993--September 30, 1996  

DOE Green Energy (OSTI)

Mixed lanthanide dicarbides having the fluorite crystal structure have been synthesized using the elemental lanthanide metals and elemental carbon that was 99.9% pure carbon-13 isotope. A two step process of first, arc furnace melting of the components, followed by an annealing step in a high vacuum furnace, was adopted as the standard method of fabricating small cast ingots of the dicarbides. The crystal structure of the various lanthanide dicarbides produced were confirmed by x-ray diffraction under protective atmospheres at both room temperature at Duke University and at high temperature at Oak Ridge National Laboratory. After more than 15 combinations of cerium or lanthanum with dopants were tried, low temperature x-ray diffraction showed that Ce{sub .5}Er{sub .5}C{sub 2} had been successfully stabilized and had the desired fluorite crystal structure at room temperature. The fluorite crystal structure lanthanide dicarbide cast ingots were further prepared by having flat and clean surfaces ground onto their surfaces by high-speed milling machines inside argon gas atmosphere gloveboxes. The surfaces thus created were then coated with carbon-12 by the arc evaporation method under low pressure argon gas. The coated ingots were then allowed to have carbon diffusion occur from the surface coating of carbon-12 into the ingot of dicarbide that had been synthesized from carbon-13. After the diffusion run, the cast ingots were slit down the axis perpendicular to the carbon coating. The fracture surface created was then squared and polished by high,speed milling in a glove box with a argon atmosphere. The high diffusion co-efficient of carbon in lanthanide dicarbides having the fluorite crystal structure would make possible the manufacture of a carbon-ion electrolyte for use in a battery or a fuel cell that could consume solid carbon as it`s feedstock.

Cocks, F.H.

1997-01-01T23:59:59.000Z

243

Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

9072 9072 September 2010 Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis Robert Remick National Renewable Energy Laboratory Douglas Wheeler DJW Technology, LLC National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Operated by the Alliance for Sustainable Energy, LLC Contract No. DE-AC36-08-GO28308 Technical Report NREL/TP-560-49072 September 2010 Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis Robert Remick National Renewable Energy Laboratory Douglas Wheeler DJW Technology, LLC Prepared under Task No. H278.7210

244

Electrochemistry of . . . ELECTRODES WITH APPLICATIONS TO FUEL CELLS AND CARBON DIOXIDE CONVERSION DEVICES  

E-Print Network (OSTI)

There is a growing awareness of the need for basic and applied energy research due to the environmental impact of energy use and limitations in the supply of energy sources. In this work, electrochemical research is reported for fuel cells and carbon dioxide reduction, with the aim of reducing the environmental footprint of global energy use. In studies of the formic acid fuel cell, it is reported here that an increase in the formic acid fuel pH increases the rate of formic acid oxidation on palladium and platinum. It is also shown that an increase in fuel pH decreases the potential at which the catalyst poison is removed from the electrode surface. This poison is detrimental to fuel cell operation. This work reports the first such studies in an electrochemical cell on high surface area platinum and palladium nanoparticles. New catalyst formulations were developed via electrochemical surface modification in attempt to eliminate the catalyst poisoning and improve performance of the formic acid fuel cell. Electrochemical studies showed substantial improvement to the rate of formic acid oxidation by a combination of high surface area palladium with tin,

John Leonard Haan

2010-01-01T23:59:59.000Z

245

Fuel cell separator plate with bellows-type sealing flanges  

DOE Patents (OSTI)

A fuel cell separator includes a rectangular flat plate having two unitary upper sealing flanges respectively comprising opposite marginal edges of the plate folded upwardly and back on themselves and two lower sealing flanges respectively comprising the other two marginal edges of the plate folded downwardly and back on themselves. Each of the sealing flanges includes a flat wall spaced from the plate and substantially parallel thereto and two accordion-pleated side walls, one of which interconnects the flat wall with the plate and the other of which steps just short of the plate, these side walls affording resilient compressibility to the sealing flange in a direction generally normal to the plane of the plate. Four corner members close the ends of the sealing flanges. An additional resiliently compressible reinforcing member may be inserted in the passages formed by each of the sealing flanges with the plate.

Louis, G.A.

1984-05-29T23:59:59.000Z

246

Case Study of a 250-kW Molten Carbonate Fuel Cell: LADWP Demonstration of a FuelCell Energy Power Plant: Phase 1  

Science Conference Proceedings (OSTI)

In August 2001, the Los Angeles Department of Water and Power (LADWP) installed a 250-kW pre-commercial molten carbonate fuel cell (MCFC) system manufactured by FuelCell Energy (FCE) at its headquarters building in downtown Los Angeles. At the time, the FCE Direct FuelCell 300A was only the second such system deployed in the United States, although several DFC systems had been deployed in Europe by FCE's partner, MTU. The purpose of the field trial was to gain experience with emerging fuel cell technolog...

2004-03-25T23:59:59.000Z

247

Molted carbonate fuel cell product design and improvement - 4th quarter, 1995. Quarterly report, October 1, 1995--December 31, 1995  

DOE Green Energy (OSTI)

The primary objective of this project is to establish the commercial readiness of MW-class IMHEX Molten Carbonate Fuel Cell power plants. Progress is described on marketing, systems design and analysis, product options and manufacturing.

NONE

1998-04-01T23:59:59.000Z

248

Molecular gas in early-type galaxies: Fuel for residual star formation  

E-Print Network (OSTI)

Abstract: Molecular gas in early-type galaxies: Fuel for residual star formation Timothy A. Davis Survey 2. The ATLAS3D CARMA Survey 3. Kinematic Misalignments 4. Origin of the molecular gas The ATLAS3D results: - 23% of early-type galaxies have significant molecular gas reservoirs - Detection rate

Bureau, Martin

249

World Energy Consumption by Fuel Type, 1970-2020  

Gasoline and Diesel Fuel Update (EIA)

0 0 Notes: Natural gas is projected to be the fastest-growing component of primary world energy consumption, more than doubling between 1997 and 2020. Gas accounts for the largest increment in electricity generation (41 percent of the total increment of energy used for electricity generation). Combined-cycle gas turbine power plants offer some of the highest commercially available plant efficiencies, and natural gas is environmentally attractive because it emits less sulfur dioxide, carbon dioxide, and particulate matter than does oil or coal. In the IEO2000 projection, world natural gas consumption reaches the level of coal by 2005, and by 2020 gas use exceeds coal by 29 percent. Oil currently provides a larger share of world energy consumption than any other energy source and is expected to remain in that position

250

An overview of alternative fossil fuel price and carbon regulation scenarios  

SciTech Connect

The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices, (3) externally generated oil price forecasts, and (4) the historical difficulty in accurately forecasting oil prices. Overall, a spread between the FE-EERE High Oil Price and Reference scenarios of well over $8/bbl is supported by the literature. We conclude that a wide range of carbon regulation scenarios are possible, especially within the time frame considered by EERE and FE (through 2050). The Working Group's Carbon Cap-and-Trade Scenario is found to be less aggressive than many Kyoto-style targets that have been analyzed, and similar in magnitude to the proposed Climate Stewardship Act. The proposed scenario is more aggressive than some other scenarios found in the literature, however, and ignores carbon banking and offsets and does not allow nuclear power to expand. We are therefore somewhat concerned that the stringency of the proposed carbon regulation scenario in the 2010 to 2025 period will lead to a particularly high estimated cost of carbon reduction. As described in more detail later, we encourage some flexibility in the Working Group's ultimate implementation of the Carbon Cap-and-Trade Scenario. We conclude by identifying additional scenarios that might be considered in future analyses, describing a concern with the proposed specification of the High Fuel Price Scenario, and highlighting the possible difficulty of implementing extreme scenarios with current energy modeling tools.

Wiser, Ryan; Bolinger, Mark

2004-10-01T23:59:59.000Z

251

Efficiency of a hybrid-type plasma-assisted fuel reformation system  

Science Conference Proceedings (OSTI)

The major advantages of a new plasma-assisted fuel reformation system are its cost effectiveness and technical efficiency. Applied Plasma Technologies has proposed its new highly efficient hybrid-type plasma-assisted system for organic fuel combustion and gasification. The system operates as a multimode multipurpose reactor in a wide range of plasma feedstock gases and turndown ratios. This system also has convenient and simultaneous feeding of several reagents in the reaction zone such as liquid fuels, coal, steam, and air. A special methodology has been developed for such a system in terms of heat balance evaluation and optimization. This methodology considers all existing and possible energy streams, which could influence the system's efficiency. The developed hybrid-type plasma system could be suitable for combustion applications, mobile and autonomous small- to mid-size liquid fuel and coal gasification modules, hydrogen-rich gas generators, waste-processing facilities, and plasma chemical reactors.

Matveev, I.B.; Serbin, S.I.; Lux, S.M. [Applied Plasma Technologies, Mclean, VA (USA)

2008-12-15T23:59:59.000Z

252

,"Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes"  

U.S. Energy Information Administration (EIA) Indexed Site

Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes" Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes",60,"Monthly","9/2013","1/15/1983" ,"Release Date:","12/2/2013" ,"Next Release Date:","1/2/2014" ,"Excel File Name:","pet_cons_refoth_a_epjk_vtr_mgalpd_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_cons_refoth_a_epjk_vtr_mgalpd_m.htm" ,"Source:","Energy Information Administration"

253

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2011-01-18T23:59:59.000Z

254

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D.; Dumesic, James A.

2013-04-02T23:59:59.000Z

255

Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions  

DOE Patents (OSTI)

A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2012-04-10T23:59:59.000Z

256

P-Type Doping of Lithium Peroxide with Carbon Sheets  

SciTech Connect

The interaction of lithium peroxide (Li{sub 2}O{sub 2}) with carbon electrodes in Li-air batteries is studied with model systems of graphene-intercalated Li{sub 2}O{sub 2}, using density functional theory (DFT) methods. Although both the Li{sub 2}O{sub 2} bulk and its stoichiometric surface structures (without single O atoms) are insulating, the incorporation of graphene sheets into the Li{sub 2}O{sub 2} introduces hole states in the oxygen orbitals due to the electron transfer from the anti-bonding O{sub 2} orbitals to the graphene sheets. This indicates that carbon sheets not only provide conducting channels by themselves, but they also open new channels in Li{sub 2}O{sub 2}.

Zhao, Y.; Ban, C.; Kang, J.; Santhanagopalan, S.; Kim, G. H.; Wei, S. H.; Dillon, A. C.

2012-07-09T23:59:59.000Z

257

MOLTEN CARBONATE FUEL CELL POWER PLANT LOCATED AT TERMINAL ISLAND WASTEWATER TREATMENT PLANT  

DOE Green Energy (OSTI)

The Los Angeles Department of Water and Power (LADWP) has developed one of the most recognized fuel cell demonstration programs in the United States. In addition to their high efficiencies and superior environmental performance, fuel cells and other generating technologies that can be located at or near the load, offers several electric utility benefits. Fuel cells can help further reduce costs by reducing peak electricity demand, thereby deferring or avoiding expenses for additional electric utility infrastructure. By locating generators near the load, higher reliability of service is possible and the losses that occur during delivery of electricity from remote generators are avoided. The potential to use renewable and locally available fuels, such as landfill or sewage treatment waste gases, provides another attractive outlook. In Los Angeles, there are also many oil producing areas where the gas by-product can be utilized. In June 2000, the LADWP contracted with FCE to install and commission the precommercial 250kW MCFC power plant. The plant was delivered, installed, and began power production at the JFB in August 2001. The plant underwent manufacturer's field trials up for 18 months and was replace with a commercial plant in January 2003. In January 2001, the LADWP contracted with FCE to provide two additional 250kW MCFC power plants. These commercial plants began operations during mid-2003. The locations of these plants are at the Terminal Island Sewage Treatment Plant at the Los Angeles Harbor (for eventual operation on digester gas) and at the LADWP Main Street Service Center east of downtown Los Angeles. All three carbonate fuel cell plants received partial funding through the Department of Defense's Climate Change Fuel Cell Buydown Program. This report covers the technical evaluation and benefit-cost evaluation of the Terminal Island 250kW MCFC power plant during its first year of operation from June 2003 to July 2004.

William W. Glauz

2004-09-01T23:59:59.000Z

258

Electro-catalytic oxidation device for removing carbon from a fuel reformate  

SciTech Connect

An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

Liu, Di-Jia (Naperville, IL)

2010-02-23T23:59:59.000Z

259

Reducing Our Carbon Footprint: Converting Plants to Fuel (LBNL Science at the Theater)  

DOE Green Energy (OSTI)

Berkeley Lab's Chris Somerville is a leading authority on the structure and function of plant cell walls, which comprise most of the body mass of higher plants. He views the knowledge of cell wall structure and function as furthering the development of plants with improved usefulness: these plants are strong potential sources of renewable materials and biofuel feedstocks. His scientific expertise defines an ideal match of his interest — in the development of cellulosic and other solar-to-fuel science — with his recent appointment as Director of the Energy Biosciences Institute (EBI). With colleagues in biology, physical sciences, engineering, and environmental and the social sciences, he now leads the EBI multidisciplinary teams' research efforts to develop next-generation, carbon-neutral transportation fuels.

Somerville, Chris

2007-11-12T23:59:59.000Z

260

Drum type fossil fueled power plant control based on fuzzy inverse MIMO model  

Science Conference Proceedings (OSTI)

In this paper, a new fuzzy controller is proposed based on inverse model of boiler-turbine system. Gain scheduling scheme is used to keep feedback rule as close as possible to optimal condition while generating plant Input/Output data. Interaction between ... Keywords: ANFIS, drum type fossil fueled power plant (FFPP), interaction, inverse model control, nonlinear model, robustness

Ali Ghaffari; Mansour Nikkhah Bahrami; Hesam Parsa

2006-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Light-Duty Vehicle Energy Consumption by Fuel Type from EIA AEO...  

Open Energy Info (EERE)

Light-Duty Vehicle Energy Consumption by Fuel Type from EIA AEO 2011 Early Release Supplemental Table 47 of EIA AEO 2011 Early Release
2011-02-23T16:04:28Z 2011-03-31T19:33:44Z...

262

U.S. Kerosene-Type Jet Fuel Stocks at Refineries (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Kerosene-Type Jet Fuel Stocks at Refineries (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1993: 13,255: 14,640: 14,907: 15,583: 14,878 ...

263

U.S. Imports of Kerosene-Type Jet Fuel, Bonded (Thousand Barrels)  

U.S. Energy Information Administration (EIA)

U.S. Imports of Kerosene-Type Jet Fuel, Bonded (Thousand Barrels) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec; 1993: 1,406: 1,620: 1,231: 1,388: 1,379: 1,456 ...

264

Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan  

DOE Data Explorer (OSTI)

Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

Gurney, Kevin [PI and spokesperson for the Vulcan Collaboration

265

Landfill gas cleanup for carbonate fuel cell power generation. Final report  

DOE Green Energy (OSTI)

To utilize landfill gas for power generation using carbonate fuel cells, the LFG must be cleaned up to remove sulfur and chlorine compounds. This not only benefits the operation of the fuel cell, but also benefits the environment by preventing the emission of these contaminants to the atmosphere. Commercial technologies for gas processing are generally economical in relatively large sizes (3 MMSCFD or larger), and may not achieve the low levels of contaminants required. To address the issue of LFG clean-up for fuel cell application, a process was developed utilizing commercially available technology. A pilot-scale test facility utilizing this process was built at a landfill site in Anoka, Minnesota using the EPRI fuel cell test facility used for coal gas testing. The pilot plant was tested for 1000 hours, processing 970,000 SCF (27,500 Nm{sup 3}) of landfill gas. Testing indicated that the process could achieve the following concentrations of contaminants in the clean gas: Less than 80 ppbv hydrogen sulfide; less than 1 ppm (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv if any individual chlorinated hydrocarbon; and 1.5 ppm (average) Sulfur Dioxide. The paper describes the LFG composition for bulk and trace compounds; evaluation of various methods to clean landfill gas; design of a LFG cleanup system; field test of pilot-scale gas cleanup process; fuel cell testing on simulated landfill gas; single cell testing on landfill gas contaminants and post test analysis; and design and economic analyses of a full scale gas cleanup system.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

266

Rock Physics-Based Carbonate Reservoir Pore Type Evaluation by Combining Geological, Petrophysical and Seismic Data  

E-Print Network (OSTI)

Pore type variations account for complex velocity-porosity relationship and intensive permeability heterogeneity and consequently low oil and gas recovery in carbonate reservoir. However, it is a challenge for geologist and geophysicist to quantitatively estimate the influences of pore type complexity on velocity variation at a given porosity and porosity-permeability relationship. A new rock physics-based integrated approach in this study was proposed to quantitatively characterize the diversity of pore types and its influences on wave propagation in carbonate reservoir. Based on above knowledge, permeability prediction accuracy from petrophysical data can be improved compared to conventional approach. Two carbonate reservoirs with different reservoir features, one is a shallow carbonate reservoir with average high porosity (>10%) and another one is a supper-deep carbonate reservoir with average low porosity (Permian basin, West Texas. Meanwhile, the complex paleokarst system is explained by using a carbonate platform hydrological model, similar to modern marine hydrological environments within carbonate islands. How to evaluate carbonate reservoir permeability heterogeneity from 3D seismic data has been a dream for reservoir geoscientists, which is a key factor to optimize reservoir development strategy and enhance reservoir recovery. A two-step seismic inversions approach by integrating angle-stack seismic data and rock physics model is proposed to characterize pore-types complexity and further to identify the relative high permeability gas-bearing zones in low porosity reservoir (< 5%) using ChangXing super-deep carbonate reservoir as an example. Compared to the conventional permeability calculation method by best-fit function between porosity and permeability, the results in this study demonstrate that gas zones and non-gas zones in low porosity reservoir can be differentiated by using above integrated permeability characterization method.

Dou, Qifeng

2011-05-01T23:59:59.000Z

267

Conceptual design for a re-entrant type fuel channel for supercritical water-cooled nuclear reactors.  

E-Print Network (OSTI)

??Current CANDU-type nuclear reactors use a once-through fuel-channel with an annulus gas insulating it from the moderator. The current reference design for a CANDU-type SuperCritical… (more)

Samuel, Jeffrey

2011-01-01T23:59:59.000Z

268

MOLTEN CARBONATE FUEL CELL POWER PLANT LOCATED AT LADWP MAIN STREET SERVICE CENTER  

DOE Green Energy (OSTI)

The Los Angeles Department of Water and Power (LADWP) has developed one of the most recognized fuel cell demonstration programs in the United States. In addition to their high efficiencies and superior environmental performance, fuel cells and other generating technologies that can be located at or near the load, offers several electric utility benefits. Fuel cells can help further reduce costs by reducing peak electricity demand, thereby deferring or avoiding expenses for additional electric utility infrastructure. By locating generators near the load, higher reliability of service is possible and the losses that occur during delivery of electricity from remote generators are avoided. The potential to use renewable and locally available fuels, such as landfill or sewage treatment waste gases, provides another attractive outlook. In Los Angeles, there are also many oil producing areas where the gas by-product can be utilized. In June 2000, the LADWP contracted with FCE to install and commission the precommercial 250kW MCFC power plant. The plant was delivered, installed, and began power production at the JFB in August 2001. The plant underwent manufacturer's field trials up for 18 months and was replace with a commercial plant in January 2003. In January 2001, the LADWP contracted with FCE to provide two additional 250kW MCFC power plants. These commercial plants began operations during mid-2003. The locations of these plants are at the Terminal Island Sewage Treatment Plant at the Los Angeles Harbor (for eventual operation on digester gas) and at the LADWP Main Street Service Center east of downtown Los Angeles. All three carbonate fuel cell plants received partial funding through the Department of Defense's Climate Change Fuel Cell Buydown Program. This report covers the technical evaluation and benefit-cost evaluation of the Main Street 250kW MCFC power plant during its first year of operation from September 2003 to August 2004. The data for the month of September 2004 was not available at the time this report was prepared. An addendum to this report will be prepared and transmitted to the Department of Energy once this data becomes available. This fuel cell power plant was originally intended to be installed at an American Airlines facility located at Los Angeles International Airport, however, due to difficulties in obtaining a site, the plant was ultimately installed at the LADWP's Distributed Generation Test Facility at it's Main Street Service Center.

William W. Glauz

2004-09-10T23:59:59.000Z

269

Effects of coal-derived trace species on the performance of molten carbonate fuel cells. Topical report on thermochemical studies  

DOE Green Energy (OSTI)

The overall objective of the present study was to determine in detail the interaction effects of 10 simultaneously present, coal-gas contaminants, both on each other and on components of the Carbonate Fuel Cell. The primary goal was to assess underlying chemistries and reaction mechanisms which may cause decay in fuel cell performance or endurance as a result of both physics-chemical and/or mechanical interactions with the cell components and internal fuel cell parts. It was found, both from theory and cell test evidence, that trace contaminant interactions may occur with: Fuel-cell Electrodes (e.g., in this study with the Ni-anode), Lithium/Potassium Carbonate Electrolyte, Nickel and SS-Hardware, and by Mechanical Obstruction of Gas Flow in the Anode Plenum.

Pigeaud, A.

1991-10-01T23:59:59.000Z

270

Development of molten-carbonate fuel-cell technology. Final report, February-December 1980  

DOE Green Energy (OSTI)

The objective of the work was to focus on the basic technology for producing molten carbonate fuel cell (MCFC) components. This included the development and fabrication of stable anode structures, preparation of lithiated nickel oxide cathodes, synthesis and characterization of a high surface area (gamma-lithium-aluminate) electrolyte support, pressurized cell testing and modeling of the overall electrolyte distribution within a cell to aid performance optimization of the different cell components. The electrode development program is highlighted by two successful 5000 hour bench-scale tests using stabilized anode structures. One of these provided better performance than in any previous state-of-the-art, bench-scale cell (865 mV at 115 mA/cm/sup 2/ under standard conditions). Pressurized testing at 10 atmosphere of a similar stabilized, high surface area, Ni/Co anode structure in a 300 cm/sup 2/ cell showed that the 160 mA/cm/sup 2/ performance goal of 850 mV on low Btu fuel (80% conversion) can be readily met. A study of the H/sub 2/S-effects on molten carbonate fuel cells showed that ERC's Ni/Co anode provided better tolerance than a Ni/Cr anode. Prelithiated nickel oxide plaques were prepared from materials made by a low temperature and a high temperature powder-production process. The methods for fabricating handleable cathodes of various thicknesses were also investigated. In electrolyte matrix development, accelerated out-of-cell and in-cell tests have confirmed the superior stability of ..gamma..-LiAlO/sub 2/.

Not Available

1980-01-01T23:59:59.000Z

271

1990 fuel cell seminar: Program and abstracts  

DOE Green Energy (OSTI)

This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

Not Available

1990-12-31T23:59:59.000Z

272

Influence of Rock Types on Seismic Monitoring of CO2 Sequestration in Carbonate Reservoirs  

E-Print Network (OSTI)

Although carbonates hold more than 60 percent of the world's oil reserves, they, nevertheless, exhibit much lower average recovery factor values than terrigenous sandstone reservoirs. Thus, utilization of advanced enhanced oil recovery (EOR) techniques such as high pressure CO2 injection may normally be required to recover oil in place in carbonate reservoirs. This study addresses how different rock types can influence the seismic monitoring of CO2 sequestration in carbonates. This research utilizes an elastic parameter, defined in a rock physics model of poroelasticity and so-­called as the frame flexibility factor, to successfully quantify the carbonate pore types in core samples available from the Great Bahama Bank (GBB). This study shows that for carbonate samples of a given porosity the lower the frame flexibility factors the higher is the sonic wave velocity. Generally, samples with frame flexibility values of 4 are rocks with intercrystalline and microporosity. Hence, different carbonate pore geometries can be quantitatively predicted using the elastic parameters capable of characterizing the porous media with a representation of their internal structure on the basis of the flexibility of the frame and pore connectivity. In this research, different fluid substitution scenarios of liquid and gaseous CO2 saturations are demonstrated to characterize the variations in velocity for carbonate-specific pore types. The results suggest that the elastic response of CO2 flooded rocks is mostly governed by pore pressure conditions and carbonate rock types. Ultrasonic P-­wave velocities in the liquid-­phase CO2 flooded samples show a marked decrease in the order of 0.6 to 16 percent. On the contrary, samples flooded with gaseous-­phase CO2 constitute an increase in P-­wave velocities for moldic and intraframe porosities, while establishing a significant decrease for samples with intercrystalline and micro-­porosities. Such velocity variations are explained by the stronger effect of density versus compressibility, accounting for the profound effect of pore geometries on the acoustic properties in carbonates. The theoretical results from this research could be a useful guide for interpreting the response of time-­lapse seismic monitoring of carbonate formations following CO2 injection at depth. In particular, an effective rock-­physics model can aid in better discrimination of the profound effects of different pore geometries on seismic monitoring of CO2 sequestration in carbonates.

Mammadova, Elnara

2011-08-01T23:59:59.000Z

273

EIA - International Energy Outlook 2009-Energy-Related Carbon...  

Annual Energy Outlook 2012 (EIA)

Energy Outlook 2009 Figure 80. World Energy-Related Carbon Dioxide Emissions, 2006-2030 Figure 81. World Energy-Related Carbon Dioxide Emissions by Fuel Type, 1990-2030 Figure...

274

Handbook of fuel cell performance  

DOE Green Energy (OSTI)

The intent of this document is to provide a description of fuel cells, their performances and operating conditions, and the relationship between fuel processors and fuel cells. This information will enable fuel cell engineers to know which fuel processing schemes are most compatible with which fuel cells and to predict the performance of a fuel cell integrated with any fuel processor. The data and estimates presented are for the phosphoric acid and molten carbonate fuel cells because they are closer to commercialization than other types of fuel cells. Performance of the cells is shown as a function of operating temperature, pressure, fuel conversion (utilization), and oxidant utilization. The effect of oxidant composition (for example, air versus O/sub 2/) as well as fuel composition is examined because fuels provided by some of the more advanced fuel processing schemes such as coal conversion will contain varying amounts of H/sub 2/, CO, CO/sub 2/, CH/sub 4/, H/sub 2/O, and sulfur and nitrogen compounds. A brief description of fuel cells and their application to industrial, commercial, and residential power generation is given. The electrochemical aspects of fuel cells are reviewed. The phosphoric acid fuel cell is discussed, including how it is affected by operating conditions; and the molten carbonate fuel cell is discussed. The equations developed will help systems engineers to evaluate the application of the phosphoric acid and molten carbonate fuel cells to commercial, utility, and industrial power generation and waste heat utilization. A detailed discussion of fuel cell efficiency, and examples of fuel cell systems are given.

Benjamin, T.G.; Camara, E.H.; Marianowski, L.G.

1980-05-01T23:59:59.000Z

275

Fuel from Bacteria: Bioconversion of Carbon Dioxide to Biofuels by Facultatively Autotrophic Hydrogen Bacteria  

Science Conference Proceedings (OSTI)

Electrofuels Project: Ohio State is genetically modifying bacteria to efficiently convert carbon dioxide directly into butanol, an alcohol that can be used directly as a fuel blend or converted to a hydrocarbon, which closely resembles a gasoline. Bacteria are typically capable of producing a certain amount of butanol before it becomes too toxic for the bacteria to survive. Ohio State is engineering a new strain of the bacteria that could produce up to 50% more butanol before it becomes too toxic for the bacteria to survive. Finding a way to produce more butanol more efficiently would significantly cut down on biofuel production costs and help make butanol cost competitive with gasoline. Ohio State is also engineering large tanks, or bioreactors, to grow the biofuel-producing bacteria in, and they are developing ways to efficiently recover biofuel from the tanks.

None

2010-07-01T23:59:59.000Z

276

Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants  

Science Conference Proceedings (OSTI)

The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025. Other potential benefits of the demonstration include developing a passive technology for water treatment for trace metal and nutrient release reductions, using power plant by-products to improve coal mine land reclamation and carbon sequestration, developing wildlife habitat and green-space around production facilities, generating Total Maximum Daily Load (TMDL) credits for the use of process water, and producing wood products for use by the lumber and pulp and paper industry. Project activities conducted during the five year project period include: Assessing tree cultivation and other techniques used to sequester carbon; Project site assessment; Greenhouse studies to determine optimum plant species and by-product application; Designing, constructing, operating, monitoring, and evaluating the CCWESTRS system; and Reporting (ongoing). The ability of the system to sequester carbon will be the primary measure of effectiveness, measured by accessing survival and growth response of plants within the CCWESTRS. In addition, costs associated with design, construction, and monitoring will be evaluated and compared to projected benefits of other carbon sequestration technologies. The test plan involves the application of three levels each of two types of power plant by-products--three levels of FGD gypsum mulch, and three levels of ash pond irrigation water. This design produces nine treatment levels which are being tested with two species of hardwood trees (sweet gum and sycamore). The project is examining the effectiveness of applications of 0, 8-cm, and 15-cm thick gypsum mulch layers and 0, 13 cm, and 25 cm of coal fly ash water for irrigation. Each treatment combination is being replicated three times, resulting in a total of 54 treatment plots (3 FGD gypsum levels X 3 irrigation water levels x 2 tree species x 3 replicates). Survival and growth response of plant species in terms of sequestering carbon in plant material and soil will be the primary measure of effectiveness of each treatment. Additionally, the ability of the site soils and unsaturated zone subsurface m

P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

2005-08-30T23:59:59.000Z

277

Molten carbonate fuel cell product design & improvement - 2nd quarter, 1995. Quarterly report, April 1--June 30, 1996  

DOE Green Energy (OSTI)

The primary objective of this project is to establish, by 1998, the commercial readiness of MW-class molten carbonate fuel cell power plants for distributed power generation, cogeneration, and compressor station applications. Tasks include system design and analysis, manufacturing, packaging and assembly, test facility development, and technology development, improvement, and verification.

NONE

1997-05-01T23:59:59.000Z

278

Molten carbonate fuel cell product design & improvement - 2nd quarter, 1996. Quarterly report, April 1--June 30, 1996  

DOE Green Energy (OSTI)

The main objective of this project is to establish the commercial readiness of a molten carbonate fuel cell power plant for distributed power generation, cogeneration, and compressor station applications. This effort includes marketing, systems design and analysis, packaging and assembly, test facility development, and technology development, improvement, and verification.

NONE

1997-05-01T23:59:59.000Z

279

Design and Testing of a Landfill Gas Cleanup System for Carbonate Fuel Cell Power Plants: Volume 1: Field Test Results  

Science Conference Proceedings (OSTI)

This report presents results of an effort to develop a low-cost cleanup system that would enable landfill gas to be used in carbonate fuel cells or other power generation devices. The EPRI-developed system is now available for license to commercial applications.

1997-11-26T23:59:59.000Z

280

The symbiosis of carbon-dioxide sequestration and hydrogen fuel: what is its significance for the long-term global energy system. Final progress report July 1998 - July 2000  

DOE Green Energy (OSTI)

This study examined the implications of the ''fuel decarbonization/carbon sequestration'' strategy for the world energy system.

Socolow, Robert H.; Ogden, Joan M.; Williams, Robert H.

2000-09-08T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Molten carbonate fuel cell product design improvement. Annual report, December 20, 1996--December 20, 1997  

DOE Green Energy (OSTI)

This program is designed to advance the carbonate fuel cell technology from the current full-size field test to the commercial design by the turn of the century. The specific objectives selected to attain the overall program goal are: Define power plant requirements and specifications; Establish the design for a multifuel, low-cost, modular, market-responsive power plant; Resolve power plant manufacturing issues and define the design for the commercial-scale manufacturing facility; Define the stack and balance-of-plant (BOP) equipment packaging arrangement and module designs; Acquire capability to support developmental testing of stacks and critical BOP equipment to prepare for commercial design; and Resolve stack and BOP equipment technology issues, and design, build, and field test a modular prototype power plant to demonstrate readiness for commercial entry. ERC is currently in the third year of the multiyear program for development and demonstration of a MW-class power plant. The product definition and specification have been derived with input from potential users, including the Fuel Cell Commercialization Group (FCCG). The baseline power plant final design has been completed. Detailed power plant system and packaging designs are being developed using stack and BOP development results. A MW-scale prototype modular power plant representative of the commercial design is planned. Based on the experience and data generated in the current program, ERC also plans to acquire manufacturing capability for market-entry products through expansion of the existing Torrington production facility.

Maru, H.C.; Farooque, M.

1998-09-01T23:59:59.000Z

282

Contributions of weather and fuel mix to recent declines in U.S.energy and carbon intensity  

SciTech Connect

A recent (1996-2000) acceleration of declines in energy andcarbon intensity in the U.S. remains largely unexplained. This study usesDivisia decomposition and regression to test two candidate explanations -fuel mix and weather. The Divisia method demonstrates that fuel mix doesnot explain the declines in carbon intensity. The fuel mix, both overalland for electricity generation, became slightly more carbon intensiveover the study period (though the slight trend reversed before the end ofthe period). A regression-based correction to the Divisia indices,accounting for variation in heating- and cooling-degree-days, indicatesthat warmer weather accounts for about 30 percent ofthe total declines.This leaves declines of more than 2 percent per year (and an accelerationof more than 1 percent over previous decade) remaining to beexplained.

Davis, W. Bart; Sanstad, Alan H.; Koomey, Jonathan G.

2002-10-20T23:59:59.000Z

283

High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding  

SciTech Connect

Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

2012-09-01T23:59:59.000Z

284

The Cellular Burning Regime in Type Ia Supernova Explosions - I. Flame Propagation into Quiescent Fuel  

E-Print Network (OSTI)

We present a numerical investigation of the cellular burning regime in Type Ia supernova explosions. This regime holds at small scales (i.e. below the Gibson scale), which are unresolved in large-scale Type Ia supernova simulations. The fundamental effects that dominate the flame evolution here are the Landau-Darrieus instability and its nonlinear stabilization, leading to a stabilization of the flame in a cellular shape. The flame propagation into quiescent fuel is investigated addressing the dependence of the simulation results on the specific parameters of the numerical setup. Furthermore, we investigate the flame stability at a range of fuel densities. This is directly connected to the questions of active turbulent combustion (a mechanism of flame destabilization and subsequent self-turbulization) and a deflagration-to-detonation transition of the flame. In our simulations we find no substantial destabilization of the flame when propagating into quiescent fuels of densities down to ~10^7 g/cm^3, corroborating fundamental assumptions of large-scale SN Ia explosion models. For these models, however, we suggest an increased lower cutoff for the flame propagation velocity to take the cellular burning regime into account.

F. K. Roepke; W. Hillebrandt; J. C. Niemeyer

2003-12-03T23:59:59.000Z

285

Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications.  

DOE Green Energy (OSTI)

The original funding under this project number was awarded for a period 12/1999 until 12/2002 under the project title Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications. The project was extended until 06/2003 at which time a renewal proposal was awarded for a period 06/2003 until 06/2008 under the project title Metal/Diamond Composite Thin-Film Electrodes: New Carbon Supported Catalytic Electrodes. The work under DE-FG02-01ER15120 was initiated about the time the PI moved his research group from the Department of Chemistry at Utah State University to the Department of Chemistry at Michigan State University. This DOE-funded research was focused on (i) understanding structure-function relationships at boron-doped diamond thin-film electrodes, (ii) understanding metal phase formation on diamond thin films and developing electrochemical approaches for producing highly dispersed electrocatalyst particles (e.g., Pt) of small nominal particle size, (iii) studying the electrochemical activity of the electrocatalytic electrodes for hydrogen oxidation and oxygen reduction and (iv) conducting the initial synthesis of high surface area diamond powders and evaluating their electrical and electrochemical properties when mixed with a Teflon binder.

Swain; Greg M.

2009-04-13T23:59:59.000Z

286

The effects of halides on the performance of coal gas-fueled molten carbonate fuel cells: Final report, October 1986-October 1987  

DOE Green Energy (OSTI)

This report presents the results of a program to determine the probable tolerable limits of hydrogen chloride and hydrogen fluoride present in the fuel and oxidant streams of molten carbonate fuel cells that are operating on gasified coal. A literature survey and thermodynamic analyses were performed to determine the likely effects of halides on cell performance and materials. Based on the results of these studies, accelerated corrosion experiments and electrode half-cell performance tests were conducted using electrolyte which contained chloride and fluoride. These data and the results of previous in-cell tests were used to develop a computer for predicting the performance decay due to these halides. The tolerable limits were found to be low (less than 1 PPM) and depend on the power plant system configuration, the operating conditions of the fuel cell stack, the cell design and initial electrolyte inventory, and the ability of the cell to scrub low levels of halide from the reactant streams. The primary decay modes were conversion of the electrolyte from pure carbonate to a carbonate-halide mixture and accelerated electrolyte evaporation. 75 figs., 16 tabs.

Magee, T.P.; Kunz, H.R.; Krasij, M.; Cote, H.A.

1987-10-01T23:59:59.000Z

287

Analysis of Strategies of Companies under Carbon Constraint: Relationship between Profit Structure of Companies and Carbon/Fuel Price Uncertainty  

E-Print Network (OSTI)

This paper examines the relationship between future carbon prices and the expected profit of companies by case studies with model companies. As the future carbon price will vary significantly in accordance with the political ...

Hashimoto, Susumu

288

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

in 2020, with the rest being E85 flex-fuel vehicles (5.8%),HEVs, hybrid flex-fuel E85 vehicles, and PHEVs, will be

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

289

An overview of alternative fossil fuel price and carbon regulation scenarios  

E-Print Network (OSTI)

reaction of energy markets to higher fuel prices. Combinedreaction of energy markets to higher fuel prices. Other Highin spot market prices (note California Energy Commission.

Wiser, Ryan; Bolinger, Mark

2004-01-01T23:59:59.000Z

290

Effects of fuel type and equivalence ratios on the flickering of triple flames  

Science Conference Proceedings (OSTI)

An experimental study has been conducted in axisymmetric, co-flowing triple flames with different equivalence ratios of the inner and outer reactant streams (2propane/propane, propane/methane or methane/methane in the inner and outer streams respectively, have been used in the experiments. The structures of the triple flames have been compared for the different fuel combinations and equivalence ratios. The conditions under which triple flames exhibit oscillation have been identified. During the oscillation, the non-premixed flame and the outer lean premixed flame flicker strongly, while the inner rich premixed flame remains more or less stable. The flickering frequency has been evaluated through image processing and fast Fourier transform (FFT) of the average pixel intensity of the image frames. It is observed that, for all the fuel combinations, the frequency decreases with the increase in the outer equivalence ratio, while it is relatively invariant with the change in the inner equivalence ratio. However, an increase in the inner equivalence ratio affects the structure of the flame by increasing the heights of the inner premixed flame and non-premixed flame and also enlarges the yellow soot-laden zone at the tip of the inner flame. A scaling analysis of the oscillating flames has been performed based on the measured parameters, which show a variation of Strouhal number (St) with Richardson number (Ri) as St {proportional_to} Ri{sup 0.5}. The fuel type is found to have no influence on this correlation. (author)

Sahu, K.B.; Kundu, A.; Ganguly, R.; Datta, A. [Department of Power Engineering, Jadavpur University, Salt Lake Campus, Kolkata 700098 (India)

2009-02-15T23:59:59.000Z

291

ATR LEU Monolithic Foil-Type Fuel with Integral Cladding Burnable Absorber – Neutronics Performance Evaluation  

SciTech Connect

The Advanced Test Reactor (ATR), currently operating in the United States, is used for material testing at very high neutron fluxes. Powered with highly enriched uranium (HEU), the ATR has a maximum thermal power rating of 250 MWth. Because of the large test volumes located in high flux areas, the ATR is an ideal candidate for assessing the feasibility of converting HEU driven reactor cores to low-enriched uranium (LEU) cores. The burnable absorber - 10B, was added in the inner and outer plates to reduce the initial excess reactivity, and to improve the peak ratio of the inner/outer heat flux. The present work investigates the LEU Monolithic foil-type fuel with 10B Integral Cladding Burnable Absorber (ICBA) design and evaluates the subsequent neutronics operating effects of this proposed fuel designs. The proposed LEU fuel specification in this work is directly related to both the RERTR LEU Development Program and the Advanced Test Reactor (ATR) LEU Conversion Project at Idaho National Laboratory (INL).

Gray Chang

2012-03-01T23:59:59.000Z

292

Might Carbon-Atmosphere White Dwarfs Harbour a New Type of Pulsating Star?  

E-Print Network (OSTI)

In the light of the recent and unexpected discovery of a brand new type of white dwarfs, those with carbon-dominated atmospheres, we examine the asteroseismological potential of such stars. The motivation behind this is based on the observation that past models of carbon-atmosphere white dwarfs have partially ionized outer layers that bear strong resemblance with those responsible for mode excitation in models of pulsating DB (helium-atmosphere) and pulsating DA (hydrogen-atmosphere) white dwarfs. Our exciting main result is that, given the right location in parameter space, some carbon-atmosphere white dwarfs are predicted to show pulsational instability against gravity modes. We are eagerly waiting the results of observational searches for luminosity variations in these stars.

G. Fontaine; P. Brassard; P. Dufour

2008-03-14T23:59:59.000Z

293

Alternative Fuels Data Center: Emissions Reduction Requirements  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Emissions Reduction Emissions Reduction Requirements to someone by E-mail Share Alternative Fuels Data Center: Emissions Reduction Requirements on Facebook Tweet about Alternative Fuels Data Center: Emissions Reduction Requirements on Twitter Bookmark Alternative Fuels Data Center: Emissions Reduction Requirements on Google Bookmark Alternative Fuels Data Center: Emissions Reduction Requirements on Delicious Rank Alternative Fuels Data Center: Emissions Reduction Requirements on Digg Find More places to share Alternative Fuels Data Center: Emissions Reduction Requirements on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Emissions Reduction Requirements Recognizing the impact of carbon-emitting fuels on climate change and to

294

Molten carbonate fuel cell (MCFC) product development test. Annual report, September 1993--September 1994  

DOE Green Energy (OSTI)

M-C Power Corporation will design, fabricate, install, test and evaluate a 250 kW Proof-of-Concept Molten Carbonate Fuel Cell (MCFC) Power Plant. The plant is to be located at the Naval Air Station Miramar in San Diego, California. This report summarizes the technical progress that has occurred in conjunction with this project in 1994. M-C Power has completed the tape casting and sintering of cathodes and is proceeding with the tape casting and sintering of anodes for the first 250 cell stack. M-C Power and San Diego Gas and Electric relocated the fuel cell demonstration project to an alternate site at the Naval Air Station Miramar. For the new project location at the Naval Air Station Miramar, an Environmental Assessment has been prepared by the Department of Energy in compliance with the National Environmental Policy Act of 1969. The Environmental Assessment resulted in a categorical exclusion of the proposed action from all environmental permit requirements. Bechtel Corporation has completed the reformer process design coordination, a Process Description, the Pipe and Instrumentation Diagrams, a Design Criteria Document and General Project Requirement Document. Bechtel developed the requirements for soils investigation report and issued the following equipment bid packages to the suppliers for bids: Inverter, Reformer, Desulfurization Vessels, Hot Gas Recycle Blower, Heat Recovery Steam Generator, and Recycle Gas Cooler. SDG and E has secured necessary site permits, conducted soils investigations, and is working on the construction plan. They are in final negotiations with the US Navy on a site agreement. Site drawings are required for finalization of the agreement.

NONE

1995-02-01T23:59:59.000Z

295

,"U.S. Residual Fuel Oil Prices by Sales Type"  

U.S. Energy Information Administration (EIA) Indexed Site

Prices by Sales Type" Prices by Sales Type" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Residual Fuel Oil Average",2,"Monthly","9/2013","1/15/1983" ,"Data 2","Sulfur Less Than or Equal to 1%",2,"Monthly","9/2013","1/15/1983" ,"Data 3","Sulfur Greater Than 1%",2,"Monthly","9/2013","1/15/1983" ,"Release Date:","12/2/2013" ,"Next Release Date:","1/2/2014" ,"Excel File Name:","pet_pri_resid_dcu_nus_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pri_resid_dcu_nus_m.htm"

296

Design and Testing of a Landfill Gas Cleanup System for Carbonate Fuel Cell Power Plants: Volume II: Full Scale Landfill Gas Cleanup for Carbonate Fuel Cell Power Plants (Proprietary)  

Science Conference Proceedings (OSTI)

This document is a proprietary version of section 5 of EPRI technical report TR-108043-V1. The volume contains detailed design information and operating conditions for a full-scale, low-cost cleanup system that would enable landfill gas to be used in carbonate fuel cells or other power generation devices. The EPRI-developed system is now available for license to commercial applications.

1998-02-27T23:59:59.000Z

297

The Cellular Burning Regime in Type Ia Supernova Explosions - II. Flame Propagation into Vortical Fuel  

E-Print Network (OSTI)

We investigate the interaction of thermonuclear flames in Type Ia supernova explosions with vortical flows by means of numerical simulations. In our study, we focus on small scales, where the flame propagation is no longer dominated by the turbulent cascade originating from large-scale effects. Here, the flame propagation proceeds in the cellular burning regime, resulting from a balance between the Landau-Darrieus instability and its nonlinear stabilization. The interaction of a cellularly stabilized flame front with a vortical fuel flow is explored applying a variety of fuel densities and strengths of the velocity fluctuations. We find that the vortical flow can break up the cellular flame structure if it is sufficiently strong. In this case the flame structure adapts to the imprinted flow field. The transition from the cellularly stabilized front to the flame structure dominated by vortices of the flow proceeds in a smooth way. The implications of the results of our simulations for Type Ia Supernova explosion models are discussed.

F. K. Roepke; W. Hillebrandt; J. C. Niemeyer

2003-12-08T23:59:59.000Z

298

Determination of optimum electrolyte composition for molten carbonate fuel cells. Quarterly technical progress report, April--June 1987  

DOE Green Energy (OSTI)

The objective of this study is to determine the optimum electrolyte composition for molten carbonate fuel cells. To accomplish this, the contractor will provide: (1) Comprehensive reports of on-going efforts to optimize carbonate composition. (2) A list of characteristics affected by electrolyte composition variations (e.g. ionic conductivity, vapor pressure, melting range, gas solubility, exchange current densities on NiO, corrosion and cathode dissolution effects). (3) Assessment of the overall effects that these characteristics have on state-of-the-art cell voltage and lifetime.

Yuh, C.Y.; Pigeaud, A.

1987-12-31T23:59:59.000Z

299

VISION Model : description of model used to estimate the impact of highway vehicle technologies and fuels on energy use and carbon emissions to 2050.  

DOE Green Energy (OSTI)

The VISION model has been developed by the U.S. Department of Energy (DOE) to provide estimates of the potential energy use, oil use, and carbon emission impacts to 2050 of advanced light- and heavy-duty highway vehicle technologies and alternative fuels. DOE supports research of advanced transportation technologies (including fuels) and is frequently asked to provide estimates of the potential impacts of successful market penetration of these technologies, sometimes on a relatively quick-turnaround basis. VISION is a spreadsheet model in Microsoft Excel that can be used to respond rapidly to quick-turnaround requests, as well as for longer-term analyses. It uses vehicle survival and age-dependent usage characteristics to project total light and heavy vehicle stock, total vehicle miles of travel (VMT), and total energy use by technology and fuel type by year, given market penetration and vehicle energy efficiency assumptions developed exogenously. Total carbon emissions for on-highway vehicles by year are also estimated because life-cycle carbon coefficients for various fuels are included in VISION. VISION is not a substitute for the transportation component of the Energy Information Administration's (EIA's) National Energy Modeling System (NEMS). NEMS incorporates a consumer choice model to project market penetration of advanced vehicles and alternative fuels. The projections are made within the context of the entire U.S. economy. However, the NEMS model is difficult to use on a quick-turnaround basis and only makes projections to 2025. VISION complements NEMS with its relative ''user-friendliness'' and by extending the time frame of potential analysis. VISION has been used for a wide variety of purposes. For illustration, we have listed some of its most recent and current uses in Table 1.1. Figures 1.1-1.3 illustrate the results of some of those runs. These graphs are not actual model output, but they are based on model results. The main body of this report describes VISION's methodology and data sources. The methodology and data sources used in the light- and heavy-vehicle portions of the model are discussed separately. Some suggestions for future improvements to the model are made. Appendix A provides instructions on how to run the VISION model. Appendix B describes the procedure for updating the model with the latest EIA Annual Energy Outlook (AEO).

Singh, M.; Vyas, A.; Steiner, E.

2004-02-19T23:59:59.000Z

300

SPATIAL AND SEASONAL DISTRIBUTION OF CARBON DIOXIDE EMISSIONS FROM FOSSIL-FUEL COMBUSTION; GLOBAL, REGIONAL, AND NATIONAL POTENTIAL FOR SUSTAINABLE BIOENERGY FROM RESIDUE BIOMASS AND MUNICIPAL SOLID WASTE.  

E-Print Network (OSTI)

??Combustion of fossil fuels releases carbon dioxide (CO2) into the atmosphere, and has led to an increase in the atmospheric concentration of CO2. CO2 is… (more)

Gregg, Jay Sterling

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Role of fuel cells in industrial cogeneration  

SciTech Connect

During the early years (1958 to 1963), three types of fuel cells were under development: phosphoric acid (PAFC), molten carbonate (MCFC), and solid oxide (SOFC) fuel cells. Between 1963 and 1971, the IGT research and development effort concentrated on the phosphoric acid and molten carbonate technologies; since 1971, emphasis has been on the molten carbonate fuel cell. IGT believes MCFC is best suited to meet the goals of the electric industry and the requirements of industrial cogeneration. Through the years, IGT has conducted system studies to evaluate the role that each one of the three fuel cell types can play in industrial cogeneration. This paper briefly discusses the status of the three technologies, the potential industrial cogeneration market, the application of fuel cells to this market, and the potential fuel savings for several industrial categories.

Camara, E.H.

1985-01-01T23:59:59.000Z

302

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

E-Print Network (OSTI)

Fuel use, CO 2 emissions, and CO 2 emission factors of ten largest California electricity generatingFuel use, CO 2 emissions, and CO 2 emission factors of ten largest California electricity generating

de la Rue du Can, Stephane

2010-01-01T23:59:59.000Z

303

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

E-Print Network (OSTI)

residual fuel oil, petroleum coke, and waste and other oil)residual fuel oil, petroleum coke, and waste and other oil22 CHP plants. For petroleum coke, CALEB only reports final

de la Rue du Can, Stephane

2010-01-01T23:59:59.000Z

304

Electro-catalytic oxidation device for removing carbon from a fuel ...  

Electricity Transmission; Energy Analysis; Energy Storage; Geothermal; Hydrogen and Fuel Cell; Hydropower, Wave and Tidal; Industrial Technologies; Solar Photovoltaic;

305

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

fuels (e.g. , compressed natural gas, oil derived from tar20% by volume), compressed natural gas, electricity, and

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

306

Thin graphite bipolar plate with associated gaskets and carbon cloth flow-field for use in an ionomer membrane fuel cell  

DOE Patents (OSTI)

The present invention comprises a thin graphite plate with associated gaskets and pieces of carbon cloth that comprise a flow-field. The plate, gaskets and flow-field comprise a "plate and gasket assembly" for use in an ionomer membrane fuel cell, fuel cell stack or battery.

Marchetti, George A. (Western Springs, IL)

2003-01-03T23:59:59.000Z

307

Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering  

SciTech Connect

Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov [AO Mittal Steel Temirtau, Temirtau (Kazakhstan)

2007-07-01T23:59:59.000Z

308

Alternative Fuels Data Center: Alternative Fuel Promotion  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Alternative Fuel Alternative Fuel Promotion to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Promotion on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Promotion on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Promotion on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Promotion on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Promotion on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Promotion on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Promotion The Missouri Alternative Fuels Commission (Commission) promotes the continued production and use of alternative transportation fuels in

309

Alternative Fuels Data Center: Alternative Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Fuel Definition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Definition The definition of an alternative fuel includes natural gas, liquefied petroleum gas, electricity, hydrogen, fuel mixtures containing not less

310

|Archives| Charts| Companies/Links| Conferences| How A Fuel Cell Works | Patents| | Types of Fuel Cells | The Basics | Fuel Cell News | Basics on Hydrogen | Search|  

E-Print Network (OSTI)

:06-June-2006 01:00 PM US Eastern Timezone Source:ISA Microbe-powered electricity generation to electricity without the need for combustion, and microbial fuel cells work the same way. They usually consist for making the pili, yet the microbes still produced electricity when placed in a fuel cell. The researchers

Lovley, Derek

311

Molten carbonate fuel cell product development test. Final report, September 30, 1992--March 31, 1997  

DOE Green Energy (OSTI)

This report summarizes the work performed for manufacturing and demonstrating the performance of its 250-kW molten carbonate fuel cell (MCFC) stack in an integrated system at the Naval Air Station Miramar (NAS Miramar) located in San Diego, California. The stack constructed for the demonstration test at the NAS Miramar consisted of 250 cells. It was manufactured using M-C Power`s patented Internally Manifolded Heat Exchanger (IMHEX{reg_sign}) stack design. The demonstration test at NAS Miramar was designed to operate the 250-kW MCFC stack in a cogeneration mode. This test represented the first attempt to thermally integrate an MCFC stack in a cogeneration system. The test was started on January 10, 1997, and voluntarily terminated on May 12, 1997, after 2,350 hours of operation at temperatures above 1,100 F and at a pressure of three atmospheres. It produced 160 MWh of d.c. power and 346,000 lbs of 110 psig steam for export during 1,566 hours of on-load operations. The test demonstrated a d.c. power output of 206 kW. Most of the balance of the plant (BOP) equipment operated satisfactorily. However, the off-the-shelf automotive turbocharger used for supplying air to the plant failed on numerous occasions and the hot gas blower developed seal leakage problems which impacted continuous plant operations. Overall the demonstration test at NAS Miramar was successful in demonstrating many critical features of the IMHEX technology. Lessons learned from this test will be very useful for improving designs and operations for future MCFC power plants.

NONE

1997-12-31T23:59:59.000Z

312

Novel Anode Materials For Solid Oxide Fuel Cells Dissertation committee  

E-Print Network (OSTI)

and fabrication of alternative anodes for direct methane oxidation in SOFC". Publisher: Twente University Press, P cells (SOFC). The principles and materials employed for SOFC are described. Emphasis is on the anode (PAFC), · the molten carbonate fuel cell (MCFC), · the solid oxide fuel cell (SOFC). Each type of fuel

Verweij, Henk

313

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

the carbon intensity of biofuels. London: E4tech, ECCM,85 Mathews, John A. 2007. Biofuels: What a Biopact betweenLehman. 2006. Carbon-Negative Biofuels from Low- Input High-

2007-01-01T23:59:59.000Z

314

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

with carbon capture and storage Natural gas combined cyclecarbon capture and storage (CCS) in natural gas applicationsnatural gas sources, as well as other fossil sources with carbon capture and storage.

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

315

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

with carbon capture and storage Natural gas combined cyclecarbon capture and storage (CCS) in natural gas applicationsnatural gas sources, as well as other fossil sources with carbon capture and storage.

2007-01-01T23:59:59.000Z

316

Solar-induced chemical vapor deposition of diamond-type carbon films  

DOE Patents (OSTI)

An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

1994-09-13T23:59:59.000Z

317

Solar-induced chemical vapor deposition of diamond-type carbon films  

DOE Patents (OSTI)

An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

Pitts, J. Roland (Lakewood, CO); Tracy, C. Edwin (Golden, CO); King, David E. (Lakewood, CO); Stanley, James T. (Beaverton, OR)

1994-01-01T23:59:59.000Z

318

Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes  

Science Conference Proceedings (OSTI)

The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

2011-12-11T23:59:59.000Z

319

Carbon dioxide emissions from fossil fuels: A procedure for estimation and results for 1950-1982. Tellus 36B  

E-Print Network (OSTI)

This work briefly discusses four of the current research emphases at Oak Ridge National Laboratory regarding the emission of carbon dioxide (C02) from fossil fuel consumption, natural gas flaring and cement manufacture. These emphases include: 1) updating the 1950 to present time series of C02 emissions from fossil fuel consumption and cement manufacture, 2) extending this time series back to 1751, 3) gridding the data at 1 ' by 1 ' resolution, and 4) estimating the isotopic signature of these emissions. In 1991, global emissions of C02 from fossil fuel and cement increased 1.5 % over 1990 levels to 6188 x lo6 metric tonnes C. The Kuwaiti oil fires can account for all of the increase. Recently published energy data (Etemad et al., 1991) allow extension of the CO emissions time series back to 1751. Preliminary examination shows good agreement wit % two other, but shorter, energy time series. A latitudinal distriiution of carbon emissions is being completed. A southward shift in the major mass of C02 emissions is occurring from European-North American latitudes towards central-southeast Asian latitudes, reflecting the growth of population

Robert J. Andres; Gregg Marl; Tom Boden; Steve Bischof

1984-01-01T23:59:59.000Z

320

Fuel cell research on second-generation molten-carbonate systems. Quarterly technical progress report, October 1-December 31, 1977  

DOE Green Energy (OSTI)

The objectives of the FY 1978 program are to (a) improve the performance and endurance of the molten carbonate fuel cell and (b) develop cost-effective cell components. The required effort is subdivided into three tasks: Task 1 is cell and component development. Improved components and cost-effective fabrication processes will be developed. This will include developing stable anode structures and improved electrolyte structures that can be fabricated by cost-effective processes. Task 2 is directed to fuel cell electrolyte optimization. New melt compositions will be tested in laboratory- and bench-scale cells. Supporting information necessary for electrolyte selection and for understanding the processes occurring in these systems will be obtained by developing models to describe cell performance and by electrochemical measurements. Task 3 involves cell operation at high pressure. Molten carbonate fuel cells will be operated (during the 3rd and 4th Quarters) at high pressure to identify and provide solutions to cell decay mechanisms and to identify problems associated with operating these cells at high pressures. Progress is reported. (WHK)

Not Available

1978-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents (OSTI)

A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-03-27T23:59:59.000Z

322

Oxidation Resistance of Low Carbon Stainless Steel for Applications in Solid Oxide Fuel Cells  

SciTech Connect

Alloys protected from corrosion by Cr2O3 (chromia) are recognized as potential replacements for LaCrO3–based ceramic materials currently used as bipolar separators (interconnects) in solid oxide fuel cells (SOFC). Stainless steels gain their corrosion resistance from the formation of chromia, when exposed to oxygen at elevated temperatures. Materials for interconnect applications must form uniform conductive oxide scales at 600–800o C while simultaneously exposed to air on the cathode side and mixtures of H2 - H2O, and, possibly, CHx and CO - CO2 on the anode side. In addition, they must possess good physical, mechanical, and thermal properties. Type 316L stainless steel was selected for the baseline study and development of an understanding of corrosion processes in complex gas environments. This paper discusses the oxidation resistance of 316L stainless steel exposed to dual SOFC environment for ~100 hours at ~900oK. The dual environment consisted of dry air on the cathode side of the specimen and a mixture of H2 and 3% H2O on the anode side. Post - corrosion surface evaluation involved the use of optical and scanning electron microscopy and x-ray diffraction analyses.

Ziomek-Moroz, Margaret; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Cramer, Stephen D.; Bullard, Sophie J.; Matthes, Steven A.; Dunning, John S.; Alman, David E.; Singh, P. (PNNL)

2003-10-01T23:59:59.000Z

323

Development of molten-carbonate fuel-cell technology. Technical status report, August-October 1980  

DOE Green Energy (OSTI)

Efforts in the development of mechanically stable anodes with more enduring pore structures are being concentrated at present on the powder/metal alloy fabrication process. One of the new alloy compositions being prepared for electrode production concerns a new 50 at. % nickel-copper powder. Another task in the electrode development area is directed at producing low resistance cathodes. The newly developed fabrication procedure of wet-forming thin nickel powder films from aqueous PVA-binder slurries is showing promising results. The relatively low-cost, standard electrolyte of 50Li/50K cation ratio used at ERC is being re-examined for performance level compared to higher lithium content melts. All other cell components and the tile matrix material used in these tests are of exactly the same type so as to be able to positively identify the electrolyte composition effect. A second pressurized, bench-scale (300 cm/sup 2/), cell test has been operated successfully showing that under the demanding conditions of 80% utilization with low-Btu fuel, the performance goal of 850 mV at 160 mA/cm/sup 2/ can be met with 10 atmosphere pressurization. Details are given. (WHK)

Not Available

1980-01-01T23:59:59.000Z

324

Alternative Fuels Data Center: Alternative Fuel and Special Fuel  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel and Fuel and Special Fuel Definitions to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Google Bookmark Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Delicious Rank Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel and Special Fuel Definitions on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel and Special Fuel Definitions

325

Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Motor Fuel Motor Carrier Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Motor Carrier Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Motor Carrier Fuel Tax Effective January 1, 2014, a person who operates a commercial motor vehicle

326

Alternative Fuels Data Center: Alternative Fuel Infrastructure...  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Type Alternative Fuel Infrastructure Development Program The Tennessee Department of Environment and Conservation provides funding for alternative fueling infrastructure...

327

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

must be provided (such as E85 filling stations, dedicatedmodest changes (e.g. , E85 flex-fuel vehicles), but

Farrell, Alexander; Sperling, Daniel

2007-01-01T23:59:59.000Z

328

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

must be provided (such as E85 filling stations, dedicatedmodest changes (e.g. , E85 flex-fuel vehicles), but

2007-01-01T23:59:59.000Z

329

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

existing solid-fuel biomass direct combustion sector stemGasification The partial combustion of biomass in an oxygen-biomass) and energy conversion technologies (combustion,

2007-01-01T23:59:59.000Z

330

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

existing solid-fuel biomass direct combustion sector stemGasification The partial combustion of biomass in an oxygen-biomass) and energy conversion technologies (combustion,

Farrell, Alexander; Sperling, Daniel

2007-01-01T23:59:59.000Z

331

The Challenge of Achieving California’s Low Carbon Fuel Standard  

U.S. Energy Information Administration (EIA)

vehicles (BEVs), fuel cell vehicles (FCVs), plug-in hybrid electric vehicles (PHEVs), and the consumption of significant quantities of low-CI ethanol.[2

332

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

of U.S. croplands for biofuels increases greenhouse gasesthe indirect Effects of Biofuels Production. Renewable FuelsTyner, W. E. ; Birur, D. K. Biofuels for all? Understanding

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

333

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

conversion from soybean to corn ethanol production in theproduced in the US: corn ethanol and soybean biodiesel. USDAdifferent fuels such as corn ethanol, cellulosic ethanol,

Sperling, Daniel; Farrell, Alexander

2007-01-01T23:59:59.000Z

334

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

conversion from soybean to corn ethanol production in theproduced in the US: corn ethanol and soybean biodiesel. USDAdifferent fuels such as corn ethanol, cellulosic ethanol,

2007-01-01T23:59:59.000Z

335

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

GREET Pathway for Corn Ethanol. Version 2.1. Stationarygasoline fuel, 6%from corn ethanol, and 17% from diesel. Webased biofuels including corn ethanol, Brazilian sugarcane

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

336

An overview of alternative fossil fuel price and carbon regulation scenarios  

E-Print Network (OSTI)

3) inclusion of high coal prices within the High Fuel Pricegas prices (as well as coal prices, as substitutes for both

Wiser, Ryan; Bolinger, Mark

2004-01-01T23:59:59.000Z

337

Fuel  

E-Print Network (OSTI)

heavy-water-moderated, light-water-moderated and liquid-metal cooled fast breeder reactors fueled with natural or low-enriched uranium and containing thorium mixed with the uranium or in separate target channels. U-232 decays with a 69-year half-life through 1.9-year half-life Th-228 to Tl-208, which emits a 2.6 MeV gamma ray upon decay. We find that pressurized light-water-reactors fueled with LEU-thorium fuel at high burnup (70 MWd/kg) produce U-233 with U-232 contamination levels of about 0.4 percent. At this contamination level, a 5 kg sphere of U-233 would produce a gammaray dose rate of 13 and 38 rem/hr at 1 meter one and ten years after chemical purification respectively. The associated plutonium contains 7.5 percent of the undesirable heat-generating 88-year half-life isotope Pu-238. However, just as it is possible to produce weapon-grade plutonium in low-burnup fuel, it is also practical to use heavy-water reactors to produce U-233 containing only a few ppm of U-232 if the thorium is segregated in “target ” channels and discharged a few times more frequently than the natural-uranium “driver ” fuel. The dose rate from a 5-kg solid sphere of U-233 containing 5 ppm U-232 could be reduced by a further factor of 30, to about 2 mrem/hr, with a close-fitting lead sphere weighing about 100 kg. Thus the proliferation resistance of thorium fuel cycles depends very much upon how they are implemented. The original version of this manuscript was received by Science & Global Security on

Jungmin Kang A

2001-01-01T23:59:59.000Z

338

HIGH-TEMPERATURE REACTIONS OF TYPE 304 STAINLESS STEEL IN LOW CONCENTRATIONS OF CARBON DIOXIDE AND CARBON MONOXIDE  

SciTech Connect

Compatibility studies of type 304 stainless steel in helium containing low concentrations of CO and CO/sub 2/ were conducted. The oxidation rates were insensitive to impurity concentrations between 0.0006--0.3 vol% in the temperature range 400--1000 deg C when P/sub co2/P/sub co/ was less than 0.66. Ratios above this value resulted initially in a slow oxidation rate, but was followed by an accelerated attack. The incubation period for the break-away varied with the P/sub co2//P/sub co/ ratio and the pressure of the two gases. The oxidation reactions proceeded through a selective depletion of chromium from the alloy which increased the carbon solubility and depletion of nickel which led to the transformation of austenite to ferrite. Parabolic reaction rates were observed for the formation of the protective oxides. Arrhenius plots of rate constants versus 1/T indicated the presence of several oxides which was confirmed by other methods. Carburization or decarburization reactions occurred coincidentally with oxidation and depended upon temperature and (P/sub CO/)/sup 2/ /P/sub CO2/ and the P/sub co2//P /sub CO/. Neither was detected below 600 deg C. Between 600--900 deg C, only carburization occurred and appeared to be mainly dependent on the temperature. Above 900 deg C, both carburization and decarburization occurred depending upon the (P/sub co/)/sup 2//P/sub co2/ and the P/sub co2//P/sub co/. The interactions of the oxidizing and carburization reactions resulted in carbon maxima at a (P/sub co/)/sup 2//P/sub co2/ ratio of 0.227. The results indicate that it may be impractical or unnecessary to reduce impurity gases to levels which do not cause surface reactions. It is concluded that undesirable oxidation and carburization reactions can be eliminated by controlling the ratios of the impurity gases. (auth)

Inouye, H.

1962-08-29T23:59:59.000Z

339

Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell  

DOE Green Energy (OSTI)

The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

Not Available

1991-09-01T23:59:59.000Z

340

Carbon Neutrality of Biomass Fuels: Case Studies of the Influence of Pretreatment Processes and Accounting Methods  

Science Conference Proceedings (OSTI)

Until recently, combustion of biomass to generate electricity was generally presumed to be “carbon neutral,” based on the understanding that biomass accumulates carbon dioxide from the atmosphere during its growth, and then releases carbon dioxide when burned, resulting in no net emissions. Prior to 2010, electric utilities anticipated having the ability to co-fire biomass with coal, or replace coal entirely with biomass in existing coal-fired power plants, to reduce their net emissions ...

2012-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance of the two materials was investigated by electrochemical impedance spectroscopy and polarization studies. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. The model gives a good fit to the experimental data. The model has been used to analyze MCFC cathode performance under a wide range of operating conditions.

Dr. Ralph E. White; Dr. Branko N. Popov

2002-04-01T23:59:59.000Z

342

A Novel Type of Carbon Coated Sulfur Nanoparticles for Li/S Batteries  

Science Conference Proceedings (OSTI)

The SEM image shows that the size of carbon coated sulfur nanoparticles is ... Performances of Nanoporous Carbon Anode for Super Lithium Ion Capacitor.

343

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

both biofuels and electricity to achieve the LCFS targets.biofuels within the western region to achieve the LCFS carbon reduction target.

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

344

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

natural gas price volatility has engendered a resurgence in coal-coal gasification combined cycle with carbon capture and storage Natural gas combined cycle Price

Farrell, Alexander; Sperling, Daniel

2007-01-01T23:59:59.000Z

345

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

natural gas price volatility has engendered a resurgence in coal-coal gasification combined cycle with carbon capture and storage Natural gas combined cycle Price

2007-01-01T23:59:59.000Z

346

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

Electricity Natural gas combined cycle and renewablecoal gasification combined cycle with carbon captureand storage Natural gas combined cycle Price change and

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

347

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

Electricity Natural gas combined cycle and renewablecoal gasification combined cycle with carbon captureand storage Natural gas combined cycle Price change and

2007-01-01T23:59:59.000Z

348

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

the carbon intensity of biofuels. London: E4tech, ECCM,85 Mathews, John A. 2007. Biofuels: What a Biopact betweenPolicy Should Distinguish Biofuels by Differential Global

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

349

Preliminary Study on Utilization of Carbon Dioxide as a Coolant of High Temperature Engineering Test Reactor with MOX and Minor Actinides Fuel  

Science Conference Proceedings (OSTI)

High temperature engineering test reactor (HTTR) is an uranium oxide (UO2) fuel, graphite moderator and helium gas-cooled reactor with 30 MW in thermal output and outlet coolant temperature of 950 deg. C. Instead of using helium gas, we have utilized carbon dioxide as a coolant in the present study. Beside that, uranium and plutonium oxide (mixed oxide, MOX) and minor actinides have been employed as a new fuel type of HTTR. Utilization of plutonium and minor actinide is one of the support system to non-proliferation issue in the nuclear development. The enrichment for uranium oxide has been varied of 6-20% with plutonium and minor actinides concentration of 10%. In this study, burnup period is 1100 days. The reactor cell calculation was performed by using SRAC 2002 code, with nuclear data library was derived from JENDL3.2. Reactor core calculation was done by using CITATION module. The result shows that HTTR can achieve its criticality condition with 14% of {sup 235}U enrichment.

Fauzia, A. F.; Waris, A.; Novitrian [Bosscha Laboratory, Department of Physics, Nuclear Physics and Biophysics Research Group, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, INDONESIA Jl. Ganesa 10 Bandung 40132 (Indonesia)

2010-06-22T23:59:59.000Z

350

Search for Model Year 2001 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

(Propane) Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

351

Search for Model Year 2004 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Vehicles Bifuel (Propane) Compressed Natural Gas Vehicles Diesel Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

352

Search for Model Year 2008 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Class... Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

353

Search for Model Year 2003 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

(Propane) Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

354

Search for Model Year 2002 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

(Propane) Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

355

Search for Model Year 2000 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Vehicles Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

356

Solar fuels : integration of molecular catalysts with p-type semiconductor photocathode  

E-Print Network (OSTI)

Philosophy, University of California, San Diego PUBLICATIONSUNIVERSITY OF CALIFORNIA, SAN DIEGO Solar fuels: IntegrationChair University of California, San Diego iii DEDICATION

Kumar, Bhupendra

2012-01-01T23:59:59.000Z

357

Particles of spilled oil-absorbing carbon in contact with water  

Science Conference Proceedings (OSTI)

Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

Muradov, Nazim (Melbourne, FL)

2011-03-29T23:59:59.000Z

358

Synthesis of Highly Porous Catalytic Layers for Polymer Electrolyte Fuel Cell Based on Carbon Aerogels  

E-Print Network (OSTI)

Aerogels J. Mariea , S. Berthon-Fabrya , P. Acharda , M. Chatenetb , E. Chainetb , R. Pirardc , N. Cornetd and characterized carbon aerogels which exhibit high surface area, high porous volume and adjustable pore carbon aerogels with 2 different Nafion loadings. Finally, we characterized the structure

Paris-Sud XI, Université de

359

Fuel cell market applications  

DOE Green Energy (OSTI)

This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

Williams, M.C.

1995-12-31T23:59:59.000Z

360

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

E-Print Network (OSTI)

1A5) Nat Gas Petroleum Coal Source: CARB, 2007a Note: CodePetroleum and Coal Products Manufac. Refinery Fuel Sourceand total petroleum products. Data Sources In the CALEB

de la Rue du Can, Stephane

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

53 Figure 3-2: Production costs and GHG emissions for fossil58 Figure 3-5: Fuel production costFigure 4-5: Ethanol production costs from MSW with variable

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

362

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

53 Figure 3-2: Production costs and GHG emissions for fossil58 Figure 3-5: Fuel production costFigure 4-5: Ethanol production costs from MSW with variable

2007-01-01T23:59:59.000Z

363

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

for production of Fischer Tropsch liquids and power viahigher value is for Fischer-Tropsch liquids. See Section 4.cellulosic ethanol and Fischer-Tropsch diesel fuel from wood

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

364

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

for production of Fischer Tropsch liquids and power viahigher value is for Fischer-Tropsch liquids. See Section 4.cellulosic ethanol and Fischer-Tropsch diesel fuel from wood

2007-01-01T23:59:59.000Z

365

An assessment of carbon sources for the production of synthetic fuels from nuclear hydrogen  

E-Print Network (OSTI)

In the transportation sector, the current dependence on petroleum to satisfy large transportation fuel demand in the US is unsustainable. Oil resources are finite, and causing heavy US reliance on oil imports. Therefore, ...

Leung, MinWah

2007-01-01T23:59:59.000Z

366

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

in the Manufacture of Corn Ethanol. St. Louis, National CornWetcake” is a form of corn ethanol co-product that requiresTypical dry-grind corn ethanol facilities burn fossil fuels

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

367

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents (OSTI)

Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

Clawson, Lawrence G. (7 Rocky Brook Rd., Dover, MA 02030); Mitchell, William L. (111 Oakley Rd., Belmont, MA 02178); Bentley, Jeffrey M. (20 Landmark Rd., Westford, MA 01886); Thijssen, Johannes H. J. (1 Richdale Ave.#2, Cambridge, MA 02140)

2002-01-01T23:59:59.000Z

368

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

hybrid vehicles (C5) Fuel cell vehicles Battery electric vehicles Low- GHG Biofuel Existing Vehicles and Advancedand Advanced Batteries Plug-in hybrid vehicles (F5, F10) Battery electric

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

369

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

hybrid vehicles (C5) Fuel cell vehicles Battery electric vehicles Low-GHG Biofuel Existing Vehicles and Advancedand Advanced Batteries Plug-in hybrid vehicles (F5, F10) Battery electric

2007-01-01T23:59:59.000Z

370

Use in combustion processes for a new type of gaseous fuel based on hydrogen  

Science Conference Proceedings (OSTI)

The paper approaches a very actual problem worldwide, concerning the replacing, in combustion processes, of classical fossil fuels by clean energy sources, in order to reduce the greenhouse effect gases, as well as for fossil fuels' saving. The experiments ... Keywords: burner, clean energy, energy saving, flame, greenhouse effect gases, hydrogen

Lucian Paunescu; Gheorghe Surugiu; Ion Melinte; Corneliu Dica; Paul Dan Stanescu; Gheorghe Iorga; Horia Necula

2007-05-01T23:59:59.000Z

371

One-dimensional turbulence model simulations of autoignition of hydrogen/carbon monoxide fuel mixtures in a turbulent jet  

Science Conference Proceedings (OSTI)

The autoignition of hydrogen/carbon monoxide in a turbulent jet with preheated co-flow air is studied using the one-dimensional turbulence (ODT) model. The simulations are performed at atmospheric pressure based on varying the jet Reynolds number and the oxidizer preheat temperature for two compositions corresponding to varying the ratios of H{sub 2} and CO in the fuel stream. Moreover, simulations for homogeneous autoignition are implemented for similar mixture conditions for comparison with the turbulent jet results. The results identify the key effects of differential diffusion and turbulence on the onset and eventual progress of autoignition in the turbulent jets. The differential diffusion of hydrogen fuels results in a reduction of the ignition delay relative to similar conditions of homogeneous autoignition. Turbulence may play an important role in delaying ignition at high-turbulence conditions, a process countered by the differential diffusion of hydrogen relative to carbon monoxide; however, when ignition is established, turbulence enhances the overall rates of combustion of the non-premixed flame downstream of the ignition point. (author)

Gupta, Kamlesh G.; Echekki, Tarek [Department of Mechanical and Aerospace Engineering, North Carolina State University, NC (United States)

2011-02-15T23:59:59.000Z

372

Program on Technology Innovation: Systems Assessment of Direct Carbon Fuel Cells Technology  

Science Conference Proceedings (OSTI)

Efficiently using abundant coal resources in a way that limits CO2 emissions is among the toughest challenges facing the power industry. Coal options available include combustion systems such as pulverized coal (PC) and supercritical systems that use the steam Rankin cycle; integrated-gasification-combined-cycle (IGCC) systems that use a gas turbine/steam turbine combined cycle; and advanced gasification fuel cell cycles, which use a combination of high-temperature fuel cells with gas or steam turbine sy...

2008-04-30T23:59:59.000Z

373

N-Type Thermoelectric Performance of Functionalized Carbon Nanotube-Filled Polymer Composites  

E-Print Network (OSTI)

Carbon nanotubes were dispersed and functionalized with polyethylene imine (PEI) before incorporation in a polyvinyl acetate matrix. The resulting samples exhibit air-stable N-type characteristics with electrical conductivities as great as 1600 S/m and thermopowers as high as 100 microV/K. Thermopowers and electrical conductivities correlate, in a reversal of the trend found in typical materials. This phenomenon is believed to be due to the increase in the number of tubes that are evenly coated in a better dispersed sample. Increasing the amount of PEI relative to the other constituents positively affects thermopower but not conductivity. Air exposure reduces both thermopower and conductivity, but a stable value is reached within seven days following film fabrication. The atmospheric effects on the electrical conductivity prove to be reversible. Oxygen is believed to be the primary contributor to the decay.

Freeman, Dallas

2012-05-01T23:59:59.000Z

374

Carbon Cycle  

NLE Websites -- All DOE Office Websites (Extended Search)

Carbon Cycle Carbon Cycle Latest Global Carbon Budget Estimates Including CDIAC Estimates Terrestrial Carbon Management Data Sets and Analyses Carbon Dioxide Emissions from Fossil-Fuel Consumption and Cement Manufacture, (2011) Annual Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Monthly Fossil-Fuel CO2 Emissions: Mass of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) Annual Fossil-Fuel CO2 Emissions: Global Stable Carbon Isotopic Signature (2012) Monthly Fossil-Fuel CO2 Emissions: Isomass (δ 13C) of Emissions Gridded by One Degree Latitude by One Degree Longitude (2012) AmeriFlux - Terrestrial Carbon Dioxide, Water Vapor, and Energy Balance Measurements Estimates of Monthly CO2 Emissions and Associated 13C/12C Values

375

Effects of H/sub 2/S on molten carbonate fuel cells. Progress report, January 1-March 31, 1984  

DOE Green Energy (OSTI)

The overall program objective is to identify the poisoning mechanism(s) responsible for performance losses of molten carbonate fuel cells (MCFC) when operating on sulfur-containing gases. This objective is being addressed by focusing out-of-cell and in-cell experiments on single mechanistic issues, followed by incorporation of the results into a model that correlates cell potential decline to contaminant(s) concentration. When coupled with gas cleanup cost projectons, the model can be used to conduct trade-off studies leading to the selection of optimum feed-gas compositions for MCFC power plants. The importance of this program is that the degree to which H/sub 2/S and other contaminants must be removed from typical MCFC fuels can have a profound effect on the cost of cleaning the fuel gas, especially if contaminant levels lower than 0.1 ppM are required. The anticipated product from the overall program is a justifiable specification for gas cleanup requirements for MCFC power plants. Progress is reported. (WHK)

Remick, R.J.

1984-07-01T23:59:59.000Z

376

POST-IRRADIATION EVALUATION OF A PLATE-TYPE UO$sub 2$ FUEL ELEMENT  

DOE Green Energy (OSTI)

The premature failure of fuel Element M22, which had six compartments of 0.100-in.-thick, 96% TD UO/sub 2/ + 6 wt% ZrO/sub 2/ fuel, was attributed to the large irradiation-induced solid volume swelling of the UO/sub 2/ fuels. This volume swelling was the result of incomplete homogenization during fabrication of the mixed and sintered U/sup E/O/sub 2/ and U/sup N/O/sub 2/ fuel s in Element M22. In addition, heavy hydriding of the Ni-free Zircaloy-2 cladding occurred in the relatively hot areas adjacent to the fuel and to a lesser extent at the external cladding surfaces. By postulation, H/sub 2/ was apparently formed by the radiolytic decomposition of water entrapped between fuel and cladding after formation of the initial cladding defect, and was absorbed by the cladding so rapidly that it could not diffuse adequately down the thermal gradient to the cold side of the cladding. The corrosion behavior of the cladding was as expected and did not contribute to the hydriding. Analysis of the CR-X-3 loop operating history indicates that no abnormal conditions external to Element M22 existed in the loop other than U from inpile intentionally defected fuel elements. (auth)

Meieran, H.B.

1963-01-01T23:59:59.000Z

377

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

Dispensing and Handing E85. ” Office of Energy Efficiency2007. Effects of ethanol (E85) versus gasoline vehicles onof 90 gCO 2 eq. /MJ. The E85 sold to FFVs has a carbon

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

378

Characterization and hydrogen storage of surface-modified multiwalled carbon nanotubes for fuel cell application  

Science Conference Proceedings (OSTI)

The synthesis, identification, and H2 storage of multiwalled carbon nanotubes (MWCNTs) have been investigated in the present work. MWCNTs were produced from the catalytic-assembly solvent (benzene)-thermal (solvothermal) route. Reduction of ...

Kuen-Song Lin, Yao-Jen Mai, Shin-Rung Li, Chia-Wei Shu, Chieh-Hung Wang

2012-01-01T23:59:59.000Z

379

A Low-Carbon Fuel Standard for California Part 1: Technical Analysis  

E-Print Network (OSTI)

M. , T. Howes, et al. (2004). Biofuels For Transport. Paris,the carbon intensity of biofuels. London: E4tech, ECCM,Markets for Green Biofuels. In Transportation Sustainability

2007-01-01T23:59:59.000Z

380

A Low-Carbon Fuel Standard for California, Part 1: Technical Analysis  

E-Print Network (OSTI)

M. , T. Howes, et al. (2004). Biofuels For Transport. Paris,the carbon intensity of biofuels. London: E4tech, ECCM,Markets for Green Biofuels. In Transportation Sustainability

Farrell, Alexander E.; Sperling, Dan

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Assessment of Technologies for Compliance with the Low Carbon Fuel Standard  

E-Print Network (OSTI)

P. Land clearing and the biofuel carbon debt. Science 2008,times for crop-based biofuel expansion in the tropics: theLand Use Impacts of U.S. Biofuel Policies: The Importance of

Yeh, Sonia; Lutsey, Nicholas P.; Parker, Nathan C.

2009-01-01T23:59:59.000Z

382

Criticality Analysis for Proposed Maximum Fuel Loading in a Standardized SNF Canister with Type 1a Baskets  

SciTech Connect

This document represents a summary version of the criticality analysis done to support loading SNF in a Type 1a basket/standard canister combination. Specifically, this engineering design file (EDF) captures the information pertinent to the intact condition of four fuel types with different fissile loads and their calculated reactivities. These fuels are then degraded into various configurations inside a canister without the presence of significant moderation. The important aspect of this study is the portrayal of the fuel degradation and its effect on the reactivity of a single canister given the supposition there will be continued moderation exclusion from the canister. Subsequent analyses also investigate the most reactive ‘dry’ canister in a nine canister array inside a hypothetical transport cask, both dry and partial to complete flooding inside the transport cask. The analyses also includes a comparison of the most reactive configuration to other benchmarked fuels using a software package called TSUNAMI, which is part of the SCALE 5.0 suite of software.

Chad Pope; Larry L. Taylor; Soon Sam Kim

2007-02-01T23:59:59.000Z

383

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Lithium Cobalt oxide was coated on Ni cathode by a sol-gel coating. The morphology and the LiCoO{sub 2} formation of LiCoO{sub 2} coated NiO was studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance lithium cobalt oxide coated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. Dissolution of nickel into the molten carbonate melt was less in case of lithium cobalt oxide coated nickel cathodes. LiCoO{sub 2} coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, lithium cobalt oxide coated nickel shows similar polarization characteristics as nickel oxide. Conventional theoretical models for the molten carbonate fuel cell cathode are based on the thin film agglomerate model. The principal deficiency of the agglomerate model, apart from the simplified pore structure assumed, is the lack of measured values for film thickness and agglomerate radius. Both these parameters cannot be estimated appropriately. Attempts to estimate the thickness of the film vary by two orders of magnitude. To avoid these problems a new three phase homogeneous model has been developed using the volume averaging technique. The model considers the potential and current variation in both liquid and solid phases. Using this approach, volume averaged concentrations of both gaseous and liquid phase reactants are obtained separately. The polarization characteristics of the electrode have been studied for different electrode parameters. The effect of different design parameters on the electrode performance has also been analyzed. Finally, the model has been used to analyze the impedance response of the MCFC cathode.

Dr. Ralph E. White; Dr. Branko N. Popov

2001-10-01T23:59:59.000Z

384

Alternative Fuels Data Center: Alternative Fueling Infrastructure  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Alternative Fueling Alternative Fueling Infrastructure Development to someone by E-mail Share Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Facebook Tweet about Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Twitter Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Google Bookmark Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Delicious Rank Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on Digg Find More places to share Alternative Fuels Data Center: Alternative Fueling Infrastructure Development on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type

385

Search for Model Year 2005 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Year: 2005 Select Class... Compressed Natural Gas Vehicles Diesel Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

386

Search for Model Year 2013 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Class... Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Plug-in Hybrid Vehicles Search by Make Search by Model Search...

387

Search for Model Year 2009 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Year: 2009 Select Class... Compressed Natural Gas Vehicles Diesel Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

388

Search for Model Year 2010 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Year: 2010 Select Class... Compressed Natural Gas Vehicles Diesel Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Search by Make Search by Model Search by EPA Size Class...

389

Search for Model Year 2012 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Class... Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Plug-in Hybrid Vehicles Search by Make Search by Model Search...

390

Search for Model Year 2011 Vehicles by Fuel or Vehicle Type  

NLE Websites -- All DOE Office Websites (Extended Search)

Class... Compressed Natural Gas Vehicles Diesel Vehicles Electric Vehicles Flex-Fuel (E85) Vehicles Hybrid Vehicles Plug-in Hybrid Vehicles Search by Make Search by Model Search...

391

Enhanced air/fuel mixing for automotive stirling engine turbulator-type combustors  

DOE Patents (OSTI)

The invention relates to the improved combustion of fuel in a combustion chamber of a stirling engine and the like by dividing combustion into primary and secondary combustion zones through the use of a diverter plate.

Riecke, George T. (Ballston Spa, NY); Stotts, Robert E. (Newark, NY)

1992-01-01T23:59:59.000Z

392

EFFECT OF FUEL TYPE ON FLAME IGNITION BY TRANSIENT PLASMA Jianbang Liu1,2  

E-Print Network (OSTI)

ABSTRACT Rise and delay times of mixtures of methane, propane, n-butane, iso-butane and iso- octane mixed performance of various fuels including methane, propane, iso-butane, n-butane and iso-octane mixed with air

393

REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS  

DOE Green Energy (OSTI)

Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

2005-06-01T23:59:59.000Z

394

The use of U/sub 3/Si/sub 2/ dispersed in aluminum in plate-type fuel elements for research and test reactors  

SciTech Connect

A high-density fuel based on U/sub 3/Si/sub 2/ dispersed in aluminum has been developed and tested for use in converting plate-type research and test reactors from the use of highly enriched uranium to the use of low-enriched uranium. Results of preirradiation testing and the irradiation and postirradiation examination of miniature fuel plates and full-sized fuel elements are summarized. Swelling of the U/sub 3/Si/sub 2/ fuel particles is a linear function of the fission density in the particle to well beyond the fission density achievable in low-enriched fuels. U/sub 3/Si/sub 2/ particle swelling rate is approximately the same as that of the commonly used UAl/sub x/ fuel particle. The presence of minor amounts of U/sub 3/Si or uranium solid solution in the fuel result in greater, but still acceptable, fuel swelling. Blister threshold temperatures are at least as high as those of currently used fuels. An exothermic reaction occurs near the aluminum melting temperature, but the measured energy releases were low enough not to substantially worsen the consequences of an accident. U/sub 3/Si/sub 2/-aluminum dispersion fuel with uranium densities up to at least 4.8 Mg/m/sup 3/ is a suitable LEU fuel for typical plate-type research and test reactors. 42 refs., 28 figs., 7 tabs.

Snelgrove, J.L.; Domagala, R.F.; Hofman, G.L.; Wiencek, T.C.; Copeland, G.L.; Hobbs, R.W.; Senn, R.L.

1987-10-01T23:59:59.000Z

395

* Corresponding author -kfingerman@berkeley.edu 1 Integrating Water Sustainability into the Low Carbon Fuel Standard  

E-Print Network (OSTI)

(Gleick, 1994) to over 39 gallons for fuel from tar sands or oil shale (Davis and Velikanov, 1979). Nearly requires from 3.4 gallons of water (Gleick, 1994) to over 60 gallons for processing of tar sands or oil shale (Davis and Velikanov, 1979). These figures, however, reflect almost the entirety of the life

Kammen, Daniel M.

396

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

This project focused on addressing the two main problems associated with state of art Molten Carbonate Fuel Cells, namely loss of cathode active material and stainless steel current collector deterioration due to corrosion. We followed a dual approach where in the first case we developed novel materials to replace the cathode and current collector currently used in molten carbonate fuel cells. In the second case we improved the performance of conventional cathode and current collectors through surface modification. States of art NiO cathode in MCFC undergo dissolution in the cathode melt thereby limiting the lifetime of the cell. To prevent this we deposited cobalt using an electroless deposition process. We also coated perovskite (La{sub 0.8}Sr{sub 0.2}CoO{sub 3}) in NiO thorough a sol-gel process. The electrochemical oxidation behavior of Co and perovskites coated electrodes is similar to that of the bare NiO cathode. Co and perovskite coatings on the surface decrease the dissolution of Ni into the melt and thereby stabilize the cathode. Both, cobalt and provskites coated nickel oxide, show a higher polarization compared to that of nickel oxide, which could be due to the reduced surface area. Cobalt substituted lithium nickel oxide (LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) and lithium cobalt oxide were also studied. LiNi{sub x}Co{sub 1-x}O{sub 2} was synthesized by solid-state reaction procedure using lithium nitrate, nickel hydroxide and cobalt oxalate precursor. LiNi{sub x}Co{sub 1-x}O{sub 2} showed smaller dissolution of nickel than state of art nickel oxide cathode. The performance was comparable to that of nickel oxide. The corrosion of the current collector in the cathode side was also studied. The corrosion characteristics of both SS304 and SS304 coated with Co-Ni alloy were studied. This study confirms that surface modification of SS304 leads to the formation of complex scales with better barrier properties and better electronic conductivity at 650 C. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode and the complete fuel cell. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. This approach can be used to model porous electrodes as it represents the real system much better than the conventional agglomerate model. Using the homogeneous model the polarization characteristics of the MCFC cathode and fuel cell were studied under different operating conditions. Both the cathode and the full cell model give good fits to the experimental data.

Hector Colonmer; Prabhu Ganesan; Nalini Subramanian; Dr. Bala Haran; Dr. Ralph E. White; Dr. Branko N. Popov

2002-09-01T23:59:59.000Z

397

Pu-Zr alloy for high-temperature foil-type fuel  

DOE Patents (OSTI)

A nuclear reactor fuel alloy consists essentially of from slightly greater than 7 to about 4 w/o zirconium, balance plutonium, and is characterized in that the alloy is castable and is rollable to thin foils. A preferred embodiment of about 7 w/o zirconium, balance plutonium, has a melting point substantially above the melting point of plutonium, is rollable to foils as thin as 0.0005 inch thick, and is compatible with cladding material when repeatedly cycled to temperatures above 650.degree. C. Neutron reflux densities across a reactor core can be determined with a high-temperature activation-measurement foil which consists of a fuel alloy foil core sandwiched and sealed between two cladding material jackets, the fuel alloy foil core being a 7 w/o zirconium, plutonium foil which is from 0.005 to 0.0005 inch thick.

McCuaig, Franklin D. (LaGrange, IL)

1977-01-01T23:59:59.000Z

398

Investigation of carbon-formation mechanisms and fuel-conversion rates in the adiabatic reformer. Annual report, March 19, 1980-March 19, 1981  

Science Conference Proceedings (OSTI)

Fuel cell power plants may be required to use coal derived liquid fuels or heavy petroleum distillates as fuels. Among the fuel processor candidates, the adiabatic reformer is at the most advanced state of development. The objective of the present program is to establish a reactor model for the adiabatic reformer which will predict process stream compositions and include carbon formation processes. Four subordinate tasks were proposed to achieve the objective. These are: 1) to determine on selected catalysts rate expressions for catalytic reactions occurring in the entrance section of the adiabatic reformer; 2) to determine with microbalance experiments critical conditions for carbon formation on selected catalysts; 3) to establish a reactor model to predict process stream compositions in the adiabatic reformer using data from Task 1 for catalytic reactions and data from the literature for homogeneous gas phase reactions; and 4) to establish a model to predict carbon formation by combination of the model for process stream composition from Task 3 and data for carbon formation from Task 2. Progress is reported. (WHK)

Not Available

1981-01-01T23:59:59.000Z

399

Annual Energy Outlook 2006 with Projections to 2030 - Carbon Dioxide  

Gasoline and Diesel Fuel Update (EIA)

Carbon Dioxide Emissions Carbon Dioxide Emissions Annual Energy Outlook 2006 with Projections to 2030 Higher Energy Consumption Forecast Increases Carbon Dioxide Emissions Figure 107. Carbn dioxide emissions by sector and fuel, 2004 and 2030 (million metric tons). Having problems, call our National Energy Information Center at 202-586-8800 for help. Figure data CO2 emissions from the combustion of fossil fuels are proportional to fuel consumption. Among fossil fuel types, coal has the highest carbon content, natural gas the lowest, and petroleum in between. In the AEO2006 reference case, the shares of these fuels change slightly from 2004 to 2030, with more coal and less petroleum and natural gas. The combined share of carbon-neutral renewable and nuclear energy is stable from 2004 to 2030 at

400

Molten carbonate fuel cell product development test. Annual report, October 1992--September 1993  

DOE Green Energy (OSTI)

Advanced fuel cell active components have been developed and scaled up from laboratory scale to commercial scale. Full width components of both the stabilized nickel cathodes and the low chrome anodes have been successfully cast on M-C Power`s production tape caster. An improved design for a fuel cell separator plate has been developed. The improved design meets the goals of lower cost and manufacturing simplicity, and addresses performance issues of the current commercial area plate. The engineering that the Bechtel Corporation has completed for the MCFC power plant includes a site design, a preliminary site layout, a Process Flow Diagram, and specification for the procurement of some of the major equipment items. Raw materials for anode and cathode components were ordered and received during the first half of 1993. Tape casting of anodes was started in late summer and continued through August. In addition to the technical progress mentioned above, an environment assessment was prepared in compliance with the National Environmental Policy Act of 1969 (NEPA). As a result, the PDT has received a categorical exclusion from the Air Pollution Control District permit requirements. The PDT is configured to demonstrate the viability of natural gas-fueled MCFC for the production of electricity and thermal energy in an environmentally benign manner for use in commercial and industrial applications.

Not Available

1993-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels  

DOE Green Energy (OSTI)

This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

Steven Markovich

2010-06-30T23:59:59.000Z

402

REFORMING PROCESSES FOR MICRO COMBINED HEAT AND POWER SYSTEM BASED ON SOLID OXIDE FUEL CELL  

E-Print Network (OSTI)

and energy balance, different types of fuel reforming including steam reforming, autothermal reforming technologies. Steam reforming, partial oxidation and autothermal reforming are the three major fuel of an activated carbon bed. Prior to enter the SOFC stack, the fuel is pre-reformed (methane is partially

Liso, Vincenzo

403

Cost-effectiveness of controlling emissions for various alternative-fuel vehicle types, with vehicle and fuel price subsidies estimated on the basis of monetary values of emission reductions  

DOE Green Energy (OSTI)

Emission-control cost-effectiveness is estimated for ten alternative-fuel vehicle (AFV) types (i.e., vehicles fueled with reformulated gasoline, M85 flexible-fuel vehicles [FFVs], M100 FFVs, dedicated M85 vehicles, dedicated M100 vehicles, E85 FFVS, dual-fuel liquefied petroleum gas vehicles, dual-fuel compressed natural gas vehicles [CNGVs], dedicated CNGVs, and electric vehicles [EVs]). Given the assumptions made, CNGVs are found to be most cost-effective in controlling emissions and E85 FFVs to be least cost-effective, with the other vehicle types falling between these two. AFV cost-effectiveness is further calculated for various cases representing changes in costs of vehicles and fuels, AFV emission reductions, and baseline gasoline vehicle emissions, among other factors. Changes in these parameters can change cost-effectiveness dramatically. However, the rank of the ten AFV types according to their cost-effectiveness remains essentially unchanged. Based on assumed dollars-per-ton emission values and estimated AFV emission reductions, the per-vehicle monetary value of emission reductions is calculated for each AFV type. Calculated emission reduction values ranged from as little as $500 to as much as $40,000 per vehicle, depending on AFV type, dollar-per-ton emission values, and baseline gasoline vehicle emissions. Among the ten vehicle types, vehicles fueled with reformulated gasoline have the lowest per-vehicle value, while EVs have the highest per-vehicle value, reflecting the magnitude of emission reductions by these vehicle types. To translate the calculated per-vehicle emission reduction values to individual AFV users, AFV fuel or vehicle price subsidies are designed to be equal to AFV emission reduction values. The subsidies designed in this way are substantial. In fact, providing the subsidies to AFVs would change most AFV types from net cost increases to net cost decreases, relative to conventional gasoline vehicles.

Wang, M.Q.

1993-12-31T23:59:59.000Z

404

Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type  

Annual Energy Outlook 2012 (EIA)

... 60.5 64.5 68.5 69.4 65.4 55.2 a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories shown,...

405

Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type  

Annual Energy Outlook 2012 (EIA)

58.8 64.9 67.0 67.7 63.6 54.6 Dash (-) No data reported. a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories shown,...

406

Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type  

Gasoline and Diesel Fuel Update (EIA)

... 51.6 56.2 59.3 60.4 56.2 45.4 a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories shown,...

407

Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type  

Annual Energy Outlook 2012 (EIA)

... 71.1 77.5 78.8 79.6 75.7 66.7 a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories shown,...

408

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

409

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Alternative Fuels Tax Alternative Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax Excise taxes on alternative fuels are imposed on a gasoline gallon equivalent basis. The tax rate for each alternative fuel type is based on the number of motor vehicles licensed in the state that use the specific

410

EXAFS of carbon monoxide oxidation on supported Pt fuel cell electrocatalysts  

Science Conference Proceedings (OSTI)

The potential dependence of the extended X-ray absorption fine structure (EXAFS) obtained at the Pt L{sub III} absorption edge for a carbon supported Pt electrocatalyst exposed to carbon monoxide is presented. The data have been analyzed using the difference file method to separate the dominant contributions of the Pt neighbors from contributions to the EXAFS from the adsorbed species. The presence of adsorbed CO is clearly observed with a Pt-C distance of 1.85 {angstrom} at potentials less than 0.5 V vs. RHE. Increasing the potential above 0.5 V resulted first in the removal of the adsorbed CO and at more positive potentials, e.g., 1.05 V, in the formation of an oxide layer, as evidenced by the presence of a Pt-O coordination shell at 2.00 {angstrom}. These results demonstrate that in situ EXAFS of supported Pt electrocatalysts may be used to probe adsorbate structures.

Maniguet, S.; Mathew, R.J.; Russell, A.E.

2000-03-09T23:59:59.000Z

411

Novel carbon-ion fuel cells. First quarterly technical progress report, January--March 1994  

DOE Green Energy (OSTI)

Apparatuses are being constructed to create pressed and sintered rare-earth carbide pellets for carbon-ion conduction testing. Attempts were made to determined the temperature of crystalline phase transformation of the CeC{sub 2} and LaC{sub 2} where they change from the alpha CaC{sub 2} structure to the beta CaF{sub 2} structure.

Cocks, F.H.; LaViers, H.

1994-04-19T23:59:59.000Z

412

Characterization and Mapping of Fuel Types for the Mediterranean Ecosystems of Pollino National Park in Southern Italy by Using Hyperspectral MIVIS Data  

Science Conference Proceedings (OSTI)

The characterization and mapping of fuel types is one of the most important factors that should be taken into consideration for wildland fire prevention and prefire planning. This research aims to investigate the usefulness of hyperspectral data ...

Rosa Lasaponara; Antonio Lanorte; Stefano Pignatti

2006-05-01T23:59:59.000Z

413

Geophysical consequences of carbon dioxide generation by fossil fuels. [Melting of polar icecaps  

SciTech Connect

The recent National Academy of Sciences Report ''Energy and Climate'' asserts that the greenhouse effect of CO/sub 2/ generated by the burning of fossil fuels would increase the temperature of the earth by 11/sup 0/F. It is argued and calculations have been carried out to show that the principal effect is the complete melting of the polar icecaps in a few centuries; the resulting inundation of the populated land areas and the coastal cities of the world is even more disastrous. The calculated increase of temperature is only 1.4/sup 0/C.

Fong, P.

1978-01-01T23:59:59.000Z

414

Molten carbonate fuel cell product development test at SDG&E  

DOE Green Energy (OSTI)

Design goals of a fuel cell power plant are described. The PDT design objectives will include improved performance at reduced cost compared with the UNOCAL demonstration project. Several specific objectives that differentiate the San Diego Gas & Electric PDT project from the UNOCAL demonstration are the following: packaging designs are more compact in the PDT program; it will also have longer unattended operation and increased reliability. Additionally, the experience gained during the design, construction and start-up of the UNOCAL power plant will be incorporated into the SDG&E design. This power plant is. being designed for compatibility with the SDG&E electrical distribution grid.

Scroppo, J.A.; Laurens, R.M.; Petraglia, V.J.

1995-12-31T23:59:59.000Z

415

Alternative Fuels Data Center: Alternative Fuel License  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Fuel License to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel License on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel License on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel License on Google Bookmark Alternative Fuels Data Center: Alternative Fuel License on Delicious Rank Alternative Fuels Data Center: Alternative Fuel License on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel License on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel License Any person acting as an alternative fuels dealer must hold a valid alternative fuel license and certificate from the Wisconsin Department of Administration. Except for alternative fuels that a dealer delivers into a

416

Alternative Fuels Data Center: Alternative Fuel License  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Fuel License to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel License on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel License on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel License on Google Bookmark Alternative Fuels Data Center: Alternative Fuel License on Delicious Rank Alternative Fuels Data Center: Alternative Fuel License on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel License on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel License Alternative fuel providers, bulk users, and retailers, or any person who fuels an alternative fuel vehicle from a private source that does not pay

417

List of Fuel Cells Incentives | Open Energy Information  

Open Energy Info (EERE)

Incentives Incentives Jump to: navigation, search The following contains the list of 1021 Fuel Cells Incentives. CSV (rows 1-500) CSV (rows 501-1000) CSV (rows 1001-1021) Incentive Incentive Type Place Applicable Sector Eligible Technologies Active 2003 Climate Change Fuel Cell Buy-Down Program (Federal) Federal Grant Program United States Commercial Nonprofit Schools Local Government State Government Fed. Government Fuel Cells No Abatement of Air Pollution: Control of Carbon Dioxide Emissions/Carbon Dioxide Budget Trading Program (Connecticut) Environmental Regulations Connecticut Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential

418

A Low-Carbon Fuel Standard for California, Part 2: Policy Analysis  

E-Print Network (OSTI)

U.S. cellulosic ethanol from wood waste. Feedstock defaultbased feedstock defaults. Under such a system, cellulosicand feedstock type. Examples: gasoline from conventional oil, diesel from coal, corn ethanol, soy biodiesel, cellulosic

Sperling, Daniel; Farrell, Alexander

2007-01-01T23:59:59.000Z

419

A Low-Carbon Fuel Standard for California Part 2: Policy Analysis  

E-Print Network (OSTI)

U.S. cellulosic ethanol from wood waste. Feedstock defaultbased feedstock defaults. Under such a system, cellulosicand feedstock type. Examples: gasoline from conventional oil, diesel from coal, corn ethanol, soy biodiesel, cellulosic

2007-01-01T23:59:59.000Z

420

Fuel Cell Handbook, Fifth Edition  

DOE Green Energy (OSTI)

Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Energy and Environmental Solutions

2000-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "fuel type carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Fuel Cell Handbook, Fourth Edition  

SciTech Connect

Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

1998-11-01T23:59:59.000Z

422

DOE Fuel Cell Technologies Office Record 13010: Onboard Type IV Compressed Hydrogen Storage Systems - Current Performance and Cost  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Fuel Cell Technologies Office Record Record #: 13010 Date: June 11, 2013 Title: Onboard Type IV Compressed Hydrogen Storage Systems - Current Performance and Cost Originators: Scott McWhorter and Grace Ordaz Approved by: Sunita Satyapal Date: July 17, 2013 Item: This record summarizes the current status of the projected capacities and manufacturing costs of Type IV, 350- and 700-bar compressed hydrogen storage systems, storing 5.6 kg of usable hydrogen, for onboard light-duty automotive applications when manufactured at a volume of 500,000 units per year. The current projected performance and cost of these systems are presented in Table 1 against the DOE Hydrogen Storage System targets. These analyses were performed in support of the Hydrogen Storage

423

N-type thermoelectric recycled carbon fibre sheet with electrochemically deposited Bi{sub 2}Te{sub 3}  

SciTech Connect

An N-type thermoelectric recycled carbon fibre sheet with bismuth telluride coating has been successfully synthesised through an electro-deposition technique. The Seebeck coefficient and electrical properties of the combined recycled carbon fibre sheet and bismuth telluride films are reported. Classification of the crystal structure, surface morphology and the elemental composition of the resulting deposits are methodically characterised by XRD, SEM and EDX. Cyclic voltammetry is also carried out in nitric acid solutions to investigate the right range of deposition potential. The synthesis N-type thermoelectric sheet has a highest attainable Seebeck coefficient of -54 {mu}V K{sup -1} and an electrical resistivity of 8.9 Multiplication-Sign 10{sup -5} Ohm-Sign m. The results show slight differences in morphologies and thermoelectric properties for the films deposited at varying deposition potential. The increase in thermoelectrical properties of the recycled carbon fibre is in line with the development of using coated recycled fibre for thermoelectrical applications. - Graphical abstract: SEM image of an N-type thermoelectric recycled carbon fibre sheet with Bi{sub 2}Te{sub 3} coatings. Highlights: Black-Right-Pointing-Pointer N-type thermoelectric sheet is synthesis through the electrodeposition of Bi{sub 2}Te{sub 3}. Black-Right-Pointing-Pointer Bi{sub 2}Te{sub 3} composition can be controlled by varying the deposition voltage. Black-Right-Pointing-Pointer Seebeck coefficient and electrical properties of the combined sheet were reported. Black-Right-Pointing-Pointer Material characterisations of the deposits are done using XRD, SEM and EDX.

Pang, E.J.X. [Division of Materials, Mechanics and Structures, The University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom)] [Division of Materials, Mechanics and Structures, The University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom); Pickering, S.J., E-mail: stephen.pickering@nottingham.ac.uk [Division of Materials, Mechanics and Structures, The University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom); Chan, A. [Division of Materials, Mechanics and Structures, The University of Nottingham Malaysia Campus, Jalan Broga, 43500 Semenyih, Selangor Darul Ehsan (Malaysia)] [Division of Materials, Mechanics and Structures, The University of Nottingham Malaysia Campus, Jalan Broga, 43500 Semenyih, Selangor Darul Ehsan (Malaysia); Wong, K.H. [Division of Materials, Mechanics and Structures, The University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom)] [Division of Materials, Mechanics and Structures, The University of Nottingham, University Park, Nottingham, NG7 2RD (United Kingdom); Lau, P.L. [Division of Materials, Mechanics and Structures, The University of Nottingham Malaysia Campus, Jalan Broga, 43500 Semenyih, Selangor Darul Ehsan (Malaysia)] [Division of Materials, Mechanics and Structures, The University of Nottingham Malaysia Campus, Jalan Broga, 43500 Semenyih, Selangor Darul Ehsan (Malaysia)

2012-09-15T23:59:59.000Z

424

Alternative Fuels Data Center: Alternative Fuel Definition  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Alternative Fuel Alternative Fuel Definition to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Definition on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Definition on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Definition on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Definition on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Definition on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of

425

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax A state excise tax is imposed on the use of alternative fuels. Alternative fuels include liquefied petroleum gas (LPG or propane), compressed natural gas (CNG), and liquefied natural gas (LNG). The current tax rates are as

426

Alternative Fuels Data Center: Renewable Fuel Standard  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Renewable Fuel Renewable Fuel Standard to someone by E-mail Share Alternative Fuels Data Center: Renewable Fuel Standard on Facebook Tweet about Alternative Fuels Data Center: Renewable Fuel Standard on Twitter Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Google Bookmark Alternative Fuels Data Center: Renewable Fuel Standard on Delicious Rank Alternative Fuels Data Center: Renewable Fuel Standard on Digg Find More places to share Alternative Fuels Data Center: Renewable Fuel Standard on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Renewable Fuel Standard RFS Volumes by Year Enlarge illustration The Renewable Fuel Standard (RFS) is a federal program that requires transportation fuel sold in the U.S. to contain a minimum volume of

427

Alternative Fuels Data Center: Alternative Fuel Loans  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Loans Fuel Loans to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Loans on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Loans on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Loans on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Loans on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Loans on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Loans on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Loans The Oregon Department of Energy administers the State Energy Loan Program (SELP) which offers low-interest loans for qualified projects. Eligible alternative fuel projects include fuel production facilities, dedicated

428

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax Alternative fuels are subject to an excise tax at a rate of $0.205 per gasoline gallon equivalent, with a variable component equal to at least 5% of the average wholesale price of the fuel. (Reference Senate Bill 454,

429

Alternative Fuels Data Center: Alternative Fuels Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuels Tax Fuels Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuels Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuels Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuels Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuels Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuels Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuels Tax The excise tax imposed on an alternative fuel distributed in New Mexico is $0.12 per gallon. Alternative fuels subject to the excise tax include liquefied petroleum gas (or propane), compressed natural gas, and liquefied

430

Alternative Fuels Data Center: Alternative Fuel Tax  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Alternative Fuel Tax Alternative Fuel Tax to someone by E-mail Share Alternative Fuels Data Center: Alternative Fuel Tax on Facebook Tweet about Alternative Fuels Data Center: Alternative Fuel Tax on Twitter Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Google Bookmark Alternative Fuels Data Center: Alternative Fuel Tax on Delicious Rank Alternative Fuels Data Center: Alternative Fuel Tax on Digg Find More places to share Alternative Fuels Data Center: Alternative Fuel Tax on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Alternative Fuel Tax The Minnesota Department of Revenue imposes an excise tax on the first licensed distributor that receives E85 fuel products in the state and on distributors, special fuel dealers, or bulk purchasers of other alternative

431

Comparison of Marine Microalgae Culture Systems for Fuels Production and Carbon Sequestration  

DOE Green Energy (OSTI)

The dual problems of global fossil fuels supplies and global warming focus attention on the need to develop technologies that can provide large amounts of renewable fuels without contributing to global warming. The capture of power plant flue gas CO2 using microalgae cultures is one potential technology that could meet this objective. The central R&D issues are the design and operation of low-cost algal mass culture systems and the development of algal strains and cultivation techniques that can achieve very high biomass productivities. The major objective of this project was to develop mass culture techniques that could result in greatly increased biomass productivities, well above the about 50 metric tons per hectare per year (mt/ha/y) currently achievable. In this project, two marine microalgae species, the diatom Cyclotella sp.. and the green alga Tetraselmis sp., were cultivated on seawater in both open ponds and closed photo bioreactors, under a variety of different cultivation conditions. Simultaneous operation of the closed photo bioreactors and open ponds demonstrated similar productivities, under the same operating conditions. Thus the very expensive closed systems do not provide any major or inherent advantages in microalgae production over open ponds. Mutants of Cyclotella sp. were developed that exhibited reduced pigment content, which theoretically would result in greatly increased productivities when grown under full sunlight. However, in open ponds, these mutant strains exhibited similar productivities as the parental strains. The mutant strains all grew relatively slowly, suggesting that additional mutations masked whatever inherent potential for increased productivities may have resulted from the reduced pigment content. Research is still required to develop improved low pigment strains. When open pond cultures were exposed to intermittent sunlight, by partially covering the ponds with slats, solar conversion efficiencies increased dramatically, by over 50%. Although such techniques are not directly applicable to practical processes, the experiments demonstrated the inherent potential of algal mass cultures to achieve very high productivities. Nitrogen limited pond cultures demonstrated that it is possible to produce biomass with a potentially high content of carbohydrates or oils (although these were not directly measured in these experiments), without reducing achievable productivities. This suggested that microalgae biomass suitable for conversion to biofuels (ethanol or biodiesel) could be produced without compromising productivity. Experiments combining both light modulation and nitrogen limitation indicated possibly synergistic effects. The goal of developing practical and economic processes for the sustainable production of renewable fuels with microalgae pond cultures using power plant flue gases as sources of CO2 was advanced by these studies, but requires more work. Most important is the research, development and demonstration in outdoor pond cultures of algal strains with low pigment content. Such strains are the most likely approach to achieve, in combination with the other mass culture techniques investigated in this study, the very high productivities, above 100 mt/ha/y (45 t/acre/y), that are the goal in this field. The projected economics for such a process suggests that, as for higher plant biofuel production, microalgae biofuels production should be developed as a multiproduct process providing additional higher value co-products.

Weissman, Joseph C; Polle, Juergen

2006-05-30T23:59:59.000Z

432

Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California  

Science Conference Proceedings (OSTI)

Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

2008-08-13T23:59:59.000Z

433

Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills  

Science Conference Proceedings (OSTI)

Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal of mercury from simulated flue gas. A business model was generated to summarize anti

J.G. Groppo; T.L. Robl

2005-09-30T23:59:59.000Z

434

Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills  

SciTech Connect

Several sampling techniques were evaluated to recover representative core samples from the ash ponds at Western Kentucky Energy's Coleman Station. The most successful was a combination of continuous-flight augers and specially designed soft-sediment sampling tubes driven by a Hammerhead drill mounted on an amphibious ARGO vehicle. A total of 51 core samples were recovered and analyzed in 3 ft sections and it was determined that there are 1,354,974 tons of ash in Pond C. Of the over 1.35M tons of ash present, 14% or 190K tons can be considered as coarse (+100 mesh). Pond C contains approximately 88K tons of carbon, nearly half of which is coarse and potentially recoverable with spiral concentration while the fine carbon (-100 mesh) is recoverable with froth flotation. There are 1.27M tons of carbon-free ash, 12% of which is coarse and potentially usable as block sand. Spiral concentration testing on bulk samples showed that product grade of 30 to 38% C (4200 to 5500 Btu/lb) was obtainable. When this product was cleaned again in an additional stage of spiral concentration, the product grade was improved to 7200 to 8200 Btu/lb with an accompanying 13 to 29% decrease in yield. Release analysis of hydraulically classified pond ash showed that froth flotation could provide froth products with as high a grade as 9000 Btu/lb with a yield of 5%. Increasing yield to 10% reduced froth grade to 7000 Btu/lb. Batch flotation provided froth grades as high as 6500 Btu/lb with yields of 7% with 1.5 lb/ton SPP and 1 lb/ton frother. Column flotation test results were similar to those achieved in batch flotation in terms of both grade and yield, however, carbon recoveries were lower (<70%). High airflow rate was required to achieve >50% carbon recovery and using wash water improved froth grade. Bottom ash samples were recovered from each of the units at Coleman Station. Characterization confirmed that sufficient quantity and quality of material is generated to produce a marketable lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was d