National Library of Energy BETA

Sample records for fuel type carbon

  1. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR

  2. Carbon-Type Analysis and Comparison of Original and Reblended FACE Diesel Fuels (FACE 2, FACE 4, and FACE 7)

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.; O'Hagan, Molly J.

    2012-10-01

    This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of Fuels for Advanced Combustion Engines (FACE) diesel blends, FD-2B, FD 4B, and FD-7B, and makes comparison of the new blends with the original FACE diesel blends, FD 2A, FD 4A, and FD-7A, respectively. Generally, FD-2A and FD-2B are more similar than the A and B blends of FD-4 and FD-7. The aromatic carbon content is roughly equivalent, although the new FACE blends have decreased monoaromatic content and increased di- and tri-cycloaromatic content, as well as a higher overall aromatic content, than the original FACE blends. The aromatic components of the new FACE blends generally have a higher alkyl substitution with longer alkyl substituents. The naphthenic and paraffinic contents remained relatively consistent. Based on aliphatic methyl and methylene carbon ratios, cetane numbers for FD-2A and -2B, and FD-7A and -7B are predicted to be consistent, while the cetane number for FD-4B is predicted to be higher than FD-4A. Overall, the new FACE fuel blends are fairly consistent with the original FACE fuel blends, but there are observable differences. In addition to providing important comparative compositional information on reformulated FACE diesel blends, this report also provides important information about the capabilities of the team at Pacific Northwest National Laboratory in the use of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  3. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  4. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  5. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  6. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  7. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, Mohammad; Yuh, Chao-Yi

    1996-01-01

    A carbonate fuel cell matrix comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles.

  8. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  9. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  10. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  11. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F.

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  12. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, Richard C.

    1986-09-02

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  13. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, R.C.

    1984-10-17

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  14. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Smith, James L.

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  15. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  16. Molten carbonate fuel cell matrices

    DOE Patents [OSTI]

    Vogel, Wolfgang M.; Smith, Stanley W.

    1985-04-16

    A molten carbonate fuel cell including a cathode electrode of electrically conducting or semiconducting lanthanum containing material and an electrolyte containing matrix of an electrically insulating lanthanum perovskite. In addition, in an embodiment where the cathode electrode is LaMnO.sub.3, the matrix may include LaAlO.sub.3 or a lithium containing material such as LiAlO.sub.2 or Li.sub.2 TiO.sub.3.

  17. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:July 2016 past issues All Issues » submit Greening up fossil fuels with carbon sequestration Researchers make progress fighting climate change by capturing carbon dioxide from power plants and storing it deep underground in geological reservoirs March 25, 2013 Greening up fossil fuels with carbon sequestration Most of the world's existing energy supply is stored underground in

  18. Types of Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells » Types of Fuel Cells Types of Fuel Cells Fuel cells are classified primarily by the kind of electrolyte they employ. This classification determines the kind of electro-chemical reactions that take place in the cell, the kind of catalysts required, the temperature range in which the cell operates, the fuel required, and other factors. These characteristics, in turn, affect the applications for which these cells are most suitable. There are several types of fuel cells currently under

  19. Pyrolytic carbon-coated nuclear fuel

    DOE Patents [OSTI]

    Lindemer, Terrence B.; Long, Jr., Ernest L.; Beatty, Ronald L.

    1978-01-01

    An improved nuclear fuel kernel having at least one pyrolytic carbon coating and a silicon carbon layer is provided in which extensive interaction of fission product lanthanides with the silicon carbon layer is avoided by providing sufficient UO.sub.2 to maintain the lanthanides as oxides during in-reactor use of said fuel.

  20. IMPROVED TYPE OF FUEL ELEMENT

    DOE Patents [OSTI]

    Monson, H.O.

    1961-01-24

    A radiator-type fuel block assembly is described. It has a hexagonal body of neutron fissionable material having a plurality of longitudinal equal- spaced coolant channels therein aligned in rows parallel to each face of the hexagonal body. Each of these coolant channels is hexagonally shaped with the corners rounded and enlarged and the assembly has a maximum temperature isothermal line around each channel which is approximately straight and equidistant between adjacent channels.

  1. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  2. Hydrothermal synthesis of nanocubes of sillenite type compounds for photovoltaic applications and solar energy conversion of carbon dioxide to fuels

    DOE Patents [OSTI]

    Subramanian, Vaidyanathan; Murugesan, Sankaran

    2014-04-29

    The present invention relates to formation of nanocubes of sillenite type compounds, such as bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, via a hydrothermal synthesis process, with the resulting compound(s) having multifunctional properties such as being useful in solar energy conversion, environmental remediation, and/or energy storage, for example. In one embodiment, a hydrothermal method is disclosed that transforms nanoparticles of TiO.sub.2 to bismuth titanate, i.e., Bi.sub.12TiO.sub.20, nanocubes, optionally loaded with palladium nanoparticles. The method includes reacting titanium dioxide nanotubes with a bismuth salt in an acidic bath at a temperature sufficient and for a time sufficient to form bismuth titanate crystals, which are subsequently annealed to form bismuth titanate nanocubes. After annealing, the bismuth titanate nanocubes may be optionally loaded with nano-sized metal particles, e.g., nanosized palladium particles.

  3. Electrolyte reservoir for carbonate fuel cells

    DOE Patents [OSTI]

    Iacovangelo, Charles D. (Schenectady, NY); Shores, David A. (Minneapolis, MN)

    1985-01-01

    An electrode for a carbonate fuel cell and method of making same wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

  4. Cathode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D.; Mrazek, Franklin C.

    1990-01-01

    A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

  5. Electrode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D.; Zarnoch, Kenneth P.

    1983-01-01

    A sintered porous electrode useful for a molten carbonate fuel cell is produced which is composed of a plurality of 5 wt. % to 95 wt. % nickel balance copper alloy encapsulated ceramic particles sintered together by the alloy.

  6. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gap Analysis | Department of Energy Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis This report describes the technical and cost gap analysis performed to identify pathways for reducing the costs of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell (PAFC) stationary fuel cell power plants. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells:

  7. Low-Carbon Fuels Perspectives

    Broader source: Energy.gov (indexed) [DOE]

    Presentation by Tom Zawodzinski to DOE's Fuel Cell Operations at Sub-Freezing Temperatures Workshop held February 1-5, 2005 in Phoenix, Arizona. 06_zawodzinski_proton.pdf (204.95 KB) More Documents & Publications Fuel Cells for Transportation - FY 2001 Progress Report DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 2: MEAs, Components, and Integration Minutes of the High Temperature Membrane Working Group Meeting, Monday, May 18, 2009 Energy

    This overview of GTP's Low

  8. Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) (Conference...

    Office of Scientific and Technical Information (OSTI)

    Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) Citation Details In-Document Search Title: Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) Paul Alivisatos, LBNL Director...

  9. Effect of carbon coating on scuffing performance in diesel fuels

    SciTech Connect (OSTI)

    Ajayi, O. O.; Alzoubi, M. F.; Erdemir, A.; Fenske, G. R.

    2000-06-29

    Low-sulfur and low-aromatic diesel fuels are being introduced in order to reduce various types of emissions in diesel engines to levels in compliance with current and impending US federal regulations. The low lubricity of these fuels, however, poses major reliability and durability problems for fuel injection components that depend on diesel fuel for their lubrication. In the present study, the authors evaluated the scuff resistance of surfaces in regular diesel fuel containing 500 ppm sulfur and in Fischer-Tropsch synthetic diesel fuel containing no sulfur or aromatics. Tests were conducted with the high frequency reciprocating test rig (HFRR) using 52100 steel balls and H-13 tool-steel flats with and without Argonne's special carbon coatings. Test results showed that the sulfur-containing fuels provide about 20% higher scuffing resistance than does fuel without sulfur. Use of the carbon coating on the flat increased scuffing resistance in both regular and synthetic fuels by about ten times, as measured by the contact severity index at scuffing. Scuffing failure in tests conducted with coated surfaces did not occur until the coating had been removed by the two distinct mechanisms of spalling and wear.

  10. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  11. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    Open Energy Info (EERE)

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  12. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview...

    Broader source: Energy.gov (indexed) [DOE]

    This report describes the technical and cost gap analysis performed to identify pathways for reducing the costs of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell ...

  13. Direct Carbon Fuel Cells: Assessment of their Potential as Solid Carbon Fuel Based Power Generation Systems

    SciTech Connect (OSTI)

    Wolk, R

    2004-04-23

    Small-scale experimental work at Lawrence Livermore National Laboratory (LLNL) has confirmed that a direct carbon fuel cell (DCFC) containing a molten carbonate electrolyte completely reacts solid elemental carbon with atmospheric oxygen contained in ambient air at a temperature of 650-800 C. The efficiency of conversion of the chemical energy in the fuel to DC electricity is 75-80% and is a result of zero entropy change for this reaction and the fixed chemical potentials of C and CO{sub 2}. This is about twice as efficient as other forms power production processes that utilize solid fuels such as petroleum coke or coal. These range from 30-40% for coal fired conventional subcritical or supercritical boilers to 38-42% for IGCC plants. A wide range of carbon-rich solids including activated carbons derived from natural gas, petroleum coke, raw coal, and deeply de-ashed coal have been evaluated with similar conversion results. The rate of electricity production has been shown to correlate with disorder in the carbon structure. This report provides a preliminary independent assessment of the economic potential of DCFC for competitive power generation. This assessment was conducted as part of a Director's Research Committee Review of DCFC held at Lawrence Livermore National Laboratory (LLNL) on April 9, 2004. The key question that this assessment addresses is whether this technology, which appears to be very promising from a scientific standpoint, has the potential to be successfully scaled up to a system that can compete with currently available power generation systems that serve existing electricity markets. These markets span a wide spectrum in terms of the amount of power to be delivered and the competitive cost in that market. For example, DCFC technology can be used for the personal power market where the current competition for delivery of kilowatts of electricity is storage batteries, for the distributed generation market where the competition for on-site power

  14. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu; Yuh, Chao-Yi

    2011-03-29

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La.sub.0.8Sr.sub.0.2CoO.sub.3) and lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1).

  15. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2003-03-01

    The program efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program is designed to advance the carbonate fuel cell technology from full-size field test to the commercial design. FuelCell Energy, Inc. (FCE) is in the later stage of the multiyear program for development and verification of carbonate fuel cell based power plants supported by DOE/NETL with additional funding from DOD/DARPA and the FuelCell Energy team. FCE has scaled up the technology to full-size and developed DFC{reg_sign} stack and balance-of-plant (BOP) equipment technology to meet product requirements, and acquired high rate manufacturing capabilities to reduce cost. FCE has designed submegawatt (DFC300A) and megawatt (DFC1500 and DFC3000) class fuel cell products for commercialization of its DFC{reg_sign} technology. A significant progress was made during the reporting period. The reforming unit design was optimized using a three-dimensional stack simulation model. Thermal and flow uniformities of the oxidant-In flow in the stack module were improved using computational fluid dynamics based flow simulation model. The manufacturing capacity was increased. The submegawatt stack module overall cost was reduced by {approx}30% on a per kW basis. An integrated deoxidizer-prereformer design was tested successfully at submegawatt scale using fuels simulating digester gas, coal bed methane gas and peak shave (natural) gas.

  16. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2002-02-01

    The carbonate fuel cell promises highly efficient, cost-effective and environmentally superior power generation from pipeline natural gas, coal gas, biogas, and other gaseous and liquid fuels. FuelCell Energy, Inc. has been engaged in the development of this unique technology, focusing on the development of the Direct Fuel Cell (DFC{reg_sign}). The DFC{reg_sign} design incorporates the unique internal reforming feature which allows utilization of a hydrocarbon fuel directly in the fuel cell without requiring any external reforming reactor and associated heat exchange equipment. This approach upgrades waste heat to chemical energy and thereby contributes to a higher overall conversion efficiency of fuel energy to electricity with low levels of environmental emissions. Among the internal reforming options, FuelCell Energy has selected the Indirect Internal Reforming (IIR)--Direct Internal Reforming (DIR) combination as its baseline design. The IIR-DIR combination allows reforming control (and thus cooling) over the entire cell area. This results in uniform cell temperature. In the IIR-DIR stack, a reforming unit (RU) is placed in between a group of fuel cells. The hydrocarbon fuel is first fed into the RU where it is reformed partially to hydrogen and carbon monoxide fuel using heat produced by the fuel cell electrochemical reactions. The reformed gases are then fed to the DIR chamber, where the residual fuel is reformed simultaneously with the electrochemical fuel cell reactions. FuelCell Energy plans to offer commercial DFC power plants in various sizes, focusing on the subMW as well as the MW-scale units. The plan is to offer standardized, packaged DFC power plants operating on natural gas or other hydrocarbon-containing fuels for commercial sale. The power plant design will include a diesel fuel processing option to allow dual fuel applications. These power plants, which can be shop-fabricated and sited near the user, are ideally suited for distributed power

  17. Thermal Analysis of Ball Type Fuel Element for PBR. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Thermal Analysis of Ball Type Fuel Element for PBR. Citation Details In-Document Search Title: Thermal Analysis of Ball Type Fuel Element for PBR. Authors: ...

  18. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2004-08-01

    The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction, leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where the fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report.

  19. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H. C. Maru; M. Farooque

    2003-12-19

    The ongoing program is designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE) for stationary power plant applications. The program efforts are focused on technology and system optimization for cost reduction leading to commercial design development and prototype system field trials. FCE, Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations or in distributed locations near the customer, including hospitals, schools, universities, hotels and other commercial and industrial applications. FuelCell Energy has designed three different fuel cell power plant models (DFC300, DFC1500 and DFC3000). FCE's power plants are based on its patented Direct FuelCell technology, where the fuel is directly fed to fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating, and air conditioning. Several FCE sub-megawatt power plants are currently operating in Europe, Japan and the US. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the reporting period in the areas of technology, manufacturing processes, cost reduction and balance of plant equipment designs is discussed in this report. FCE's DFC

  20. Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels

    SciTech Connect (OSTI)

    Turgut Gur

    2010-04-30

    This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2

  1. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste

  2. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu; Yuh, Chao-Yi

    2011-04-05

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO.sub.3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1) and X-doped LiMeO.sub.2, wherein X is one of Mg, Ca, and Co.

  3. Anode composite for molten carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D.; Zarnoch, Kenneth P.

    1983-01-01

    An anode composite useful for a molten carbonate fuel cell comprised of a porous sintered metallic anode component having a porous bubble pressure barrier integrally sintered to one face thereof, said barrier being comprised of metal coated ceramic particles sintered together and to said anode by means of said metal coating, said metal coating enveloping said ceramic particle and being selected from the group consisting of nickel, copper and alloys thereof, the median pore size of the barrier being significantly smaller than that of the anode.

  4. Liquid fuels perspective on ultra low carbon vehicles | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy fuels perspective on ultra low carbon vehicles Liquid fuels perspective on ultra low carbon vehicles Fuels challenges in the evolving global energy market deer11_simnick.pdf (572.51 KB) More Documents & Publications Green Racing Initiative: Accelerating the Use of Advanced Technologies & Renewable Fuels Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Vehicle Technologies Office Merit Review 2014: VTO Analysis Portfolio

  5. Protection of porous carbon fuel particles from boudouard corrosion

    DOE Patents [OSTI]

    Cooper, John F.

    2015-05-26

    A system for producing energy that includes infusing porous carbon particles produced by pyrolysis of carbon-containing materials with an off-eutectic salt composition thus producing pore-free carbon particles, and reacting the carbon particles with oxygen in a fuel cell according to the reaction C+O.sub.2=CO.sub.2 to produce electrical energy.

  6. Thermal Hydraulic Characteristics of Fuel Defects in Plate Type...

    Office of Scientific and Technical Information (OSTI)

    in Plate Type Nuclear Research Reactors Citation Details In-Document Search Title: Thermal Hydraulic Characteristics of Fuel Defects in Plate Type Nuclear Research Reactors ...

  7. Electrolyte paste for molten carbonate fuel cells

    DOE Patents [OSTI]

    Bregoli, Lawrance J.; Pearson, Mark L.

    1995-01-01

    The electrolyte matrix and electrolyte reservoir plates in a molten carbonate fuel cell power plant stack are filled with electrolyte by applying a paste of dry electrolyte powder entrained in a dissipatable carrier to the reactant flow channels in the current collector plate. The stack plates are preformed and solidified to final operating condition so that they are self sustaining and can be disposed one atop the other to form the power plant stack. Packing the reactant flow channels with the electrolyte paste allows the use of thinner electrode plates, particularly on the anode side of the cells. The use of the packed electrolyte paste provides sufficient electrolyte to fill the matrix and to entrain excess electrolyte in the electrode plates, which also serve as excess electrolyte reservoirs. When the stack is heated up to operating temperatures, the electrolyte in the paste melts, the carrier vaporizes, or chemically decomposes, and the melted electrolyte is absorbed into the matrix and electrode plates.

  8. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    Unknown

    2000-01-01

    The FCE PDI program is designed to advance the carbonate fuel cell technology from the current full-size field test to the commercial design. The specific objectives selected to attain the overall program goal are: Define power plant requirements and specifications; Establish the design for a multifuel, low-cost, modular, market-responsive power plant; Resolve power plant manufacturing issues and define the design for the commercial-scale manufacturing facility; Define the stack and balance-of-plant (BOP) equipment packaging arrangement, and module designs; Acquire capability to support developmental testing of stacks and critical BOP equipment to prepare for commercial design; and Resolve stack and BOP equipment technology issues, and design, build and field test a modular prototype power plant to demonstrate readiness for commercial entry.

  9. Fuel assembly transfer basket for pool type nuclear reactor vessels

    DOE Patents [OSTI]

    Fanning, Alan W.; Ramsour, Nicholas L.

    1991-01-01

    A fuel assembly transfer basket for a pool type, liquid metal cooled nuclear reactor having a side access loading and unloading port for receiving and relinquishing fuel assemblies during transfer.

  10. California Low Carbon Fuels Infrastructure Investment Initiative

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  11. Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel

    U.S. Energy Information Administration (EIA) Indexed Site

    District and State (Cents per Gallon Excluding Taxes) - Continued Geographic Area Month Aviation Gasoline Kerosene-Type Jet Fuel Kerosene Sales to End Users Sales for Resale...

  12. High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation

    SciTech Connect (OSTI)

    Steinberg, M; Cooper, J F; Cherepy, N

    2002-01-02

    Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power

  13. Recovery of Technetium and Iodine from Spent ATW TRISO Type Fuels.

    SciTech Connect (OSTI)

    Schroeder, N. C.; Attrep, Moses

    2001-01-01

    The Accelerator Transmutation of Waste (ATW) program is being developed to determine the feasibility of separating and transmutating the transactinides (Pu-Cm) and long-lived fission product (99Tc and 129I) from spent LWR fuel. Several types of ATW fuels have been suggested to transmutate the Pu-Cm fraction including TRISO type fuels. An ATW TRISO fuel would consist of a Pu-Cm oxide kernel surrounded by several layers of pyrolytic carbon, a layer of SiC, and an outer layer of pyrolytic carbon. Processing of the spent ATW fuel would involve the crush, burn, and leach approach used on normal TRISO fuels. This report describes experiments that determine the potential behavior of the two long-lived fission products, 99Tc and 129I, in this processing. Iodine can be removed and trapped during the burning of the carbon from the fuel. Some technetium may volatilize in the latter stages of the burn but the bulk of it will have to be recovered after dissolution of the oxide residue.

  14. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, R.G.

    1984-08-31

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine is disclosed which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  15. Air blast type coal slurry fuel injector

    DOE Patents [OSTI]

    Phatak, Ramkrishna G.

    1986-01-01

    A device to atomize and inject a coal slurry in the combustion chamber of an internal combustion engine, and which eliminates the use of a conventional fuel injection pump/nozzle. The injector involves the use of compressed air to atomize and inject the coal slurry and like fuels. In one embodiment, the breaking and atomization of the fuel is achieved with the help of perforated discs and compressed air. In another embodiment, a cone shaped aspirator is used to achieve the breaking and atomization of the fuel. The compressed air protects critical bearing areas of the injector.

  16. Method of making molten carbonate fuel cell ceramic matrix tape

    DOE Patents [OSTI]

    Maricle, Donald L.; Putnam, Gary C.; Stewart, Jr., Robert C.

    1984-10-23

    A method of making a thin, flexible, pliable matrix material for a molten carbonate fuel cell is described. The method comprises admixing particles inert in the molten carbonate environment with an organic polymer binder and ceramic particle. The composition is applied to a mold surface and dried, and the formed compliant matrix material removed.

  17. Coated powder for electrolyte matrix for carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D.; Browall, Kenneth W.

    1985-01-01

    A plurality of electrolyte carbonate-coated ceramic particle which does not differ significantly in size from that of the ceramic particle and wherein no significant portion of the ceramic particle is exposed is fabricated into a porous tape comprised of said coated-ceramic particles bonded together by the coating for use in a molten carbonate fuel cell.

  18. Fast Reactor Fuel Type and Reactor Safety Performance

    SciTech Connect (OSTI)

    R. Wigeland; J. Cahalan

    2009-09-01

    Fast Reactor Fuel Type and Reactor Safety Performance R. Wigeland , Idaho National Laboratory J. Cahalan, Argonne National Laboratory The sodium-cooled fast neutron reactor is currently being evaluated for the efficient transmutation of the highly-hazardous, long-lived, transuranic elements that are present in spent nuclear fuel. One of the fundamental choices that will be made is the selection of the fuel type for the fast reactor, whether oxide, metal, carbide, nitride, etc. It is likely that a decision on the fuel type will need to be made before many of the related technologies and facilities can be selected, from fuel fabrication to spent fuel reprocessing. A decision on fuel type should consider all impacts on the fast reactor system, including safety. Past work has demonstrated that the choice of fuel type may have a significant impact on the severity of consequences arising from accidents, especially for severe accidents of low probability. In this paper, the response of sodium-cooled fast reactors is discussed for both oxide and metal fuel types, highlighting the similarities and differences in reactor response and accident consequences. Any fast reactor facility must be designed to be able to successfully prevent, mitigate, or accommodate all consequences of potential events, including accidents. This is typically accomplished by using multiple barriers to the release of radiation, including the cladding on the fuel, the intact primary cooling system, and most visibly the reactor containment building. More recently, this has also included the use of inherent safety concepts to reduce or eliminate the potential for serious damage in some cases. Past experience with oxide and metal fuel has demonstrated that both fuel types are suitable for use as fuel in a sodium-cooled fast reactor. However, safety analyses for these two fuel types have also shown that there can be substantial differences in accident consequences due to the neutronic and thermophysical

  19. Dynamic simulation of a direct carbonate fuel cell power plant

    SciTech Connect (OSTI)

    Ernest, J.B.; Ghezel-Ayagh, H.; Kush, A.K.

    1996-12-31

    Fuel Cell Engineering Corporation (FCE) is commercializing a 2.85 MW Direct carbonate Fuel Cell (DFC) power plant. The commercialization sequence has already progressed through construction and operation of the first commercial-scale DFC power plant on a U.S. electric utility, the 2 MW Santa Clara Demonstration Project (SCDP), and the completion of the early phases of a Commercial Plant design. A 400 kW fuel cell stack Test Facility is being built at Energy Research Corporation (ERC), FCE`s parent company, which will be capable of testing commercial-sized fuel cell stacks in an integrated plant configuration. Fluor Daniel, Inc. provided engineering, procurement, and construction services for SCDP and has jointly developed the Commercial Plant design with FCE, focusing on the balance-of-plant (BOP) equipment outside of the fuel cell modules. This paper provides a brief orientation to the dynamic simulation of a fuel cell power plant and the benefits offered.

  20. California Low Carbon Fuels Infrastructure Investment Initiative...

    Broader source: Energy.gov (indexed) [DOE]

    12 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting arravt082tibowen2012o.pdf (647.19 KB) More Documents & ...

  1. Novel Application of Carbonate Fuel Cell for Capturing Carbon...

    Office of Scientific and Technical Information (OSTI)

    the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. ... testingmore of an ECM-based CO2 separation and purification system. less ...

  2. A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells

    SciTech Connect (OSTI)

    Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

    2013-01-01

    The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

  3. Molten carbonate fuel cell reduction of nickel deposits

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Zwick, Stanley A. (Darien, IL)

    1987-01-01

    A molten carbonate fuel cell with anode and cathode electrodes and an eleolyte formed with two tile sections, one of the tile sections being adjacent the anode and limiting leakage of fuel gas into the electrolyte with the second tile section being adjacent the cathode and having pores sized to permit the presence of oxygen gas in the electrolyte thereby limiting the formation of metal deposits caused by the reduction of metal compositions migrating into the electrolyte from the cathode.

  4. Carbonate fuel cell and components thereof for in-situ delayed addition of carbonate electrolyte

    SciTech Connect (OSTI)

    Johnsen, Richard; Yuh, Chao-Yi; Farooque, Mohammad

    2011-05-10

    An apparatus and method in which a delayed carbonate electrolyte is stored in the storage areas of a non-electrolyte matrix fuel cell component and is of a preselected content so as to obtain a delayed time release of the electrolyte in the storage areas in the operating temperature range of the fuel cell.

  5. Cathode preparation method for molten carbonate fuel cell

    DOE Patents [OSTI]

    Smith, James L.; Sim, James W.; Kucera, Eugenia H.

    1988-01-01

    A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

  6. All ceramic structure for molten carbonate fuel cell

    DOE Patents [OSTI]

    Smith, James L.; Kucera, Eugenia H.

    1992-01-01

    An all-ceramic molten carbonate fuel cell having a composition formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The structure includes an anode and cathode separated by an electronically conductive interconnect. The electrodes and interconnect are compositions ceramic materials. Various combinations of ceramic compositions for the anode, cathode and interconnect are disclosed. The fuel cell exhibits stability in the fuel gas and oxidizing environments. It presents reduced sealing and expansion problems in fabrication and has improved long-term corrosion resistance.

  7. An Innovative Carbonate Fuel Cell Matrix, Abstract #188

    SciTech Connect (OSTI)

    Hilmi, Abdelkader; Surendranath, Arun; Yuh, Chao-Yi

    2015-05-28

    The electrolyte matrix in direct carbonate fuel cell (DFC) is a microporous ceramic structure sandwiched between the electrodes to isolate the fuel from the oxidant, store electrolyte and facilitate ionic transport. FCE has advanced DFC electrolyte matrix over the years and demonstrated that the matrix meets the requirements for greater than 5 year life based on accelerated tests and field stack operations. However, development of advanced designs and materials that can further increase the performance and extend cell life will enable accelerated MCFC deployment. This paper will report the progress on the development of an unique and innovative matrix design that offers numerous benefits to the carbonate fuel cell performance and durability. In addition, this paper will also review parameters that affect matrix material stability and approaches to extend cell life.

  8. Fact #576: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 6: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel Fact #576: June 22, 2009 Carbon Dioxide from Gasoline and Diesel Fuel The amount of carbon dioxide released into the atmosphere by a vehicle is primarily determined by the carbon content of the fuel. However, there is a small portion of the fuel that is not oxidized into carbon dioxide when the fuel is burned. The Environmental Protection Agency (EPA) has published information on carbon dioxide emissions from

  9. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells. Overview and Gap Analysis

    SciTech Connect (OSTI)

    Remick, Robert; Wheeler, Douglas

    2010-09-01

    This report details technical and cost gap analyses of molten carbonate fuel cell and phosphoric acid fuel cell stationary fuel cell power plants and identifies pathways for reducing costs.

  10. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis

    SciTech Connect (OSTI)

    Remick, R.; Wheeler, D.

    2010-09-01

    This report describes the technical and cost gap analysis performed to identify pathways for reducing the costs of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell (PAFC) stationary fuel cell power plants.

  11. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis

    Fuel Cell Technologies Publication and Product Library (EERE)

    This report details technical and cost gap analyses of molten carbonate fuel cell and phosphoric acid fuel cell stationary fuel cell power plants and identifies pathways for reducing costs.

  12. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  13. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, Chao M.; Yuh, Chao-Yi

    1999-01-01

    A matrix for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 .mu.m to 20 .mu.m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling.

  14. Electrolyte matrix for molten carbonate fuel cells

    DOE Patents [OSTI]

    Huang, C.M.; Yuh, C.Y.

    1999-02-09

    A matrix is described for a carbonate electrolyte including a support material and an additive constituent having a relatively low melting temperature and a relatively high coefficient of thermal expansion. The additive constituent is from 3 to 45 weight percent of the matrix and is formed from raw particles whose diameter is in a range of 0.1 {micro}m to 20 {micro}m and whose aspect ratio is in a range of 1 to 50. High energy intensive milling is used to mix the support material and additive constituent during matrix formation. Also disclosed is the use of a further additive constituent comprising an alkaline earth containing material. The further additive is mixed with the support material using high energy intensive milling. 5 figs.

  15. Molten carbonate fuel cell product design improvement

    SciTech Connect (OSTI)

    P. Voyentzie; T. Leo; A. Kush; L. Christner; G. Carlson; C. Yuh

    1998-12-20

    Drawing on the manufacture, field test, and post-test experience of the sixteen Santa Clara Demonstration Project (SCDP) stacks, ERC is finalizing the next generation commercial entry product design. The second generation cells are 50% larger in area, 40% lighter on equal geometric area basis, and 30% thinner than the earlier design. These improvements have resulted in doubling of the full-height stack power. A low-cost and high-strength matrix has also been developed for improving product ruggedness. The low-cost advanced cell design incorporating these improvements has been refined through six short stack tests. Power production per cell of two times the SCDP maximum power operation, over ten thermal cycles, and overall operating flexibility with respect to load and thermal changes have been demonstrated in these short stack tests. An internally insulated stack enclosure has been designed and fabricated to eliminate the need for an inert gas environment during operation. ERC has acquired the capability for testing 400kW full-height direct fuel ceil (DFC) stack and balance-of-plant equipment. With the readiness of the power plant test facility, the cell package design, and the stack module, full-height stack testing has begun. The first full- height stack incorporating the post-SCDP second generation design was completed. The stack reached a power level of 253 kW, setting a world record for the highest power production from the advanced fuel cell system. Excellent performance uniformity at this power level affirmed manufacturing reproducibility of the components at the factory. This unoptimized small size test has achieved pipeline natural gas to DC electricity conversion efficiency of 47% (based on lower heating value - LHV) including the parasitic power consumed by the BOP equipment; that should translate to more than 50% efficiency in commercial operation, before employing cogeneration. The power plant system also operated smoothly. With the success of this

  16. Molten carbonate fuel cell cathode with mixed oxide coating

    DOE Patents [OSTI]

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  17. NAS Miramar Molten Carbonate Fuel Cell demonstration status

    SciTech Connect (OSTI)

    Scroppo, J.A.

    1996-12-31

    Part of M-C Power`s Technology Development Program, this MCFC power plant is designed to supply 250 kW of electricity to Naval Air Station (NAS) Miramar. It also cogenerates steam for the district heating system. The power plant is a fully integrated unit incorporating an advanced design fuel cell based on years of laboratory tests and a prior field test. This demonstration incorporates many innovative features, one of which is the plate type reformer which processes the natural gas fuel for use in the fuel cell. M-C Power Corp. has completed the design, fabrication, and conditioning of a 250-cell fuel cell stack, which was shipped to the site where it will be installed, tested, and evaluated as a 250 kW Proof-of-Concept MCFC Power Plant. (Originally going to Kaiser Permanente`s Sand Diego Medical Center, it was relocated to Miramar.)

  18. Generation and Solid Oxide Fuel Cell Carbon Sequestration in Northwest Indiana

    SciTech Connect (OSTI)

    Kevin Peavey; Norm Bessette

    2007-09-30

    The objective of the project is to develop the technology capable of capturing all carbon monoxide and carbon dioxide from natural gas fueled Solid Oxide Fuel Cell (SOFC) system. In addition, the technology to electrochemically oxidize any remaining carbon monoxide to carbon dioxide will be developed. Success of this R&D program would allow for the generation of electrical power and thermal power from a fossil fuel driven SOFC system without the carbon emissions resulting from any other fossil fueled power generationg system.

  19. Norwegian carbon taxes and their implication for fossil fuels

    SciTech Connect (OSTI)

    Kaarstad, O.

    1995-12-31

    The Scandinavian countries, and in particular Norway and Sweden, have since 1990/91 taxed CO{sub 2}-emissions with carbon tax of about US $150 per ton of CO{sub 2}. One may therefore say that these countries have placed themselves in a role as {open_quotes}carbon tax laboratories{close_quotes}. These very high CO{sub 2}-taxes have been in place for about four years and the first lessons from this experience are reported. In general it would seem as if the taxation mechanism is less efficient than economists have expected. The CO{sub 2}-emissions are increasing in both Norway and Sweden and the stabilization goal to the year 2000 will not be achieved in spite of the high taxation. The fossil fuel industry will have to learn to live with the climate change question which is inherently hostile to fossil fuels. It is argued that a more informed and active participation by the fossil fuel industry is needed in the climate change discussion. In addition the image of fossil fuels will benefit from showing real and potential improvement in the area of greenhouse gas emissions in the whole energy chain from production to combustion. The R&D effort being done into CO{sub 2}-capture and -disposal is creating such an option for the future. It is argued that the image of the entire fossil fuel industry will benefit from the creation of a {open_quotes}CO{sub 2}-free{close_quote} option or vision for oil, gas and coal. A number of examples are shown where today (or in the near future) actual CO{sub 2}-disposal in underground formations are taking place.

  20. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    The Vulcan Project is a NASA/DOE funded effort under the North American Carbon Program (NACP) to quantify North American fossil fuel carbon dioxide (CO2) emissions at space and time scales much finer than has been achieved in the past. The purpose is to aid in quantification of the North American carbon budget, to support inverse estimation of carbon sources and sinks, and to support the demands posed by higher resolution CO2 observations (in situ and remotely sensed). The detail and scope of the Vulcan CO2 inventory has also made it a valuable tool for policymakers, demographers, social scientists and the public at large. The Vulcan project has achieved the quantification of the 2002 U.S. fossil fuel CO2 emissions at the scale of individual factories, powerplants, roadways and neighborhoods on an hourly basis. The entire inventory was built on a common 10 km x 10 km grid to facilitate atmospheric modeling. In addition to improvement in space and time resolution, Vulcan is quantified at the level of fuel type, economic sub-sector, and county/state identification. Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  1. FABRICATION OF TUBE TYPE FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Loeb, E.; Nicklas, J.H.

    1959-02-01

    A method of fabricating a nuclear reactor fuel element is given. It consists essentially of fixing two tubes in concentric relationship with respect to one another to provide an annulus therebetween, filling the annulus with a fissionablematerial-containing powder, compacting the powder material within the annulus and closing the ends thereof. The powder material is further compacted by swaging the inner surface of the inner tube to increase its diameter while maintaining the original size of the outer tube. This process results in reduced fabrication costs of powdered fissionable material type fuel elements and a substantial reduction in the peak core temperatures while materially enhancing the heat removal characteristics.

  2. Pyrochlore-type catalysts for the reforming of hydrocarbon fuels

    DOE Patents [OSTI]

    Berry, David A.; Shekhawat, Dushyant; Haynes, Daniel; Smith, Mark; Spivey, James J.

    2012-03-13

    A method of catalytically reforming a reactant gas mixture using a pyrochlore catalyst material comprised of one or more pyrochlores having the composition A.sub.2-w-xA'.sub.wA''.sub.xB.sub.2-y-zB'.sub.yB''.sub.zO.sub.7-.DELTA.. Distribution of catalytically active metals throughout the structure at the B site creates an active and well dispersed metal locked into place in the crystal structure. This greatly reduces the metal sintering that typically occurs on supported catalysts used in reforming reactions, and reduces deactivation by sulfur and carbon. Further, oxygen mobility may also be enhanced by elemental exchange of promoters at sites in the pyrochlore. The pyrochlore catalyst material may be utilized in catalytic reforming reactions for the conversion of hydrocarbon fuels into synthesis gas (H.sub.2+CO) for fuel cells, among other uses.

  3. Fabrication of catalytic electrodes for molten carbonate fuel cells

    DOE Patents [OSTI]

    Smith, James L.

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  4. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, George; Meyers, Steven J.; Lee, Arthur

    1996-01-01

    A fuel cell system employing a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell.

  5. A new leaf: Scientists turn carbon dioxide back into fuel | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Argonne postdoctoral researcher Cong Liu and chemists Larry Curtiss and Peter Zapol discuss their recent research results on converting carbon dioxide into usable fuel. Photo by Wes Agresta. Argonne postdoctoral researcher Cong Liu and chemists Larry Curtiss and Peter Zapol discuss their recent research results on converting carbon dioxide into usable fuel. Photo by Wes Agresta. A new leaf: Scientists turn carbon dioxide back into fuel July 29, 2016 Tweet EmailPrint As

  6. Development of a Monolithic Research Reactor Fuel Type at Argonne National Laboratory

    SciTech Connect (OSTI)

    Clark, C.R.; Briggs, R.J.

    2004-10-06

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been tasked with the conversion of research reactors from highly enriched to low-enriched uranium (LEU). To convert several high power reactors, monolithic fuel, a new fuel type, is being developed. This fuel type replaces the standard fuel dispersion with a fuel alloy foil, which allows for fuel densities far in excess of that found in dispersion fuel. The single-piece fuel foil also contains a significantly lower interface area between the fuel and the aluminum in the plate than the standard fuel type, limiting the amount of detrimental fuel-aluminum interaction that can occur. Implementation of monolithic fuel is dependant on the development of a suitable fabrication method as traditional roll-bonding techniques are inadequate.

  7. ,"Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes...

    U.S. Energy Information Administration (EIA) Indexed Site

    Kerosene-Type Jet Fuel Sales to End Users Refiner Sales Volumes" ,"Click worksheet name or ... Data for" ,"Data 1","Kerosene-Type Jet Fuel Sales to End Users Refiner Sales ...

  8. Fission rate measurements in fuel plate type assembly reactor cores

    SciTech Connect (OSTI)

    Rogers, J.W.

    1988-01-01

    The methods, materials and equipment have been developed to allow extensive and precise measurement of fission rate distributions in water moderated, U-Al fuel plate assembly type reactor cores. Fission rate monitors are accurately positioned in the reactor core, the reactor is operated at a low power for a short time, the fission rate monitors are counted with detectors incorporating automated sample changers and the measurements are converted to fission rate distributions. These measured fission rate distributions have been successfully used as baseline information related to the operation of test and experimental reactors with respect to fission power and distribution, fuel loading and fission experiments for approximately twenty years at the Idaho National Engineering Laboratory (INEL). 7 refs., 8 figs.

  9. Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    Type, PAD District, and Selected States Energy Information Administration Petroleum Marketing Annual 1996 233 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District,...

  10. Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    Type, PAD District, and Selected States Energy Information Administration Petroleum Marketing Annual 1997 233 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District,...

  11. Solar Reforming of Carbon Dioxide to Produce Diesel Fuel

    SciTech Connect (OSTI)

    Dennis Schuetzle; Robert Schuetzle

    2010-12-31

    This project focused on the demonstration of an innovative technology, referred to as the Sunexus CO2 Solar Reformer, which utilizes waste CO2 as a feedstock for the efficient and economical production of synthetic diesel fuel using solar thermal energy as the primary energy input. The Sunexus technology employs a two stage process for the conversion of CO2 to diesel fuel. A solar reforming system, including a specially designed reactor and proprietary CO2 reforming catalyst, was developed and used to convert captured CO2 rich gas streams into syngas (primarily hydrogen and carbon monoxide) using concentrated solar energy at high conversion efficiencies. The second stage of the system (which has been demonstrated under other funding) involves the direct conversion of the syngas into synthetic diesel fuel using a proprietary catalyst (Terra) previously developed and validated by Pacific Renewable Fuels and Chemicals (PRFC). The overall system energy efficiency for conversion of CO2 to diesel fuel is 74%, due to the use of solar energy. The results herein describe modeling, design, construction, and testing of the Sunexus CO2 Solar Reformer. Extensive parametric testing of the solar reformer and candidate catalysts was conducted and chemical kinetic models were developed. Laboratory testing of the Solar Reformer was successfully completed using various gas mixtures, temperatures, and gas flow rates/space velocities to establish performance metrics which can be employed for the design of commercial plants. A variety of laboratory tests were conducted including dry reforming (CO2 and CH{sub 4}), combination dry/steam reforming (CO2, CH{sub 4} & H{sub 2}O), and tri-reforming (CO2, CH{sub 4}, H{sub 2}O & O{sub 2}). CH{sub 4} and CO2 conversions averaged 95-100% and 50-90% per reformer cycle, respectively, depending upon the temperatures and gas space velocities. No formation of carbon deposits (coking) on the catalyst was observed in any of these tests. A 16 ft. diameter

  12. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, G.; Meyers, S.J.; Lee, A.

    1996-09-10

    A fuel cell system is described which employs a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell. 2 figs.

  13. Novel Application of Carbonate Fuel Cell for Capturing Carbon Dioxide from Flue Gas Streams

    SciTech Connect (OSTI)

    Jolly, Stephen; Ghezel-Ayagh, Hossein; Willman, Carl; Patel, Dilip; DiNitto, M.; Marina, Olga A.; Pederson, Larry R.; Steen, William A.

    2015-09-30

    To address concerns about climate change resulting from emission of CO2 by coal-fueled power plants, FuelCell Energy, Inc. has developed the Combined Electric Power and Carbon-dioxide Separation (CEPACS) system concept. The CEPACS system utilizes Electrochemical Membrane (ECM) technology derived from the Company’s Direct FuelCell® products. The system separates the CO2 from the flue gas of other plants and produces electric power using a supplementary fuel. FCE is currently evaluating the use of ECM to cost effectively separate CO2 from the flue gas of Pulverized Coal (PC) power plants under a U.S. Department of Energy contract. The overarching objective of the project is to verify that the ECM can achieve at least 90% CO2 capture from the flue gas with no more than 35% increase in the cost of electricity. The project activities include: 1) laboratory scale operational and performance tests of a membrane assembly, 2) performance tests of the membrane to evaluate the effects of impurities present in the coal plant flue gas, in collaboration with Pacific Northwest National Laboratory, 3) techno-economic analysis for an ECM-based CO2 capture system applied to a 550 MW existing PC plant, in partnership with URS Corporation, and 4) bench scale (11.7 m2 area) testing of an ECM-based CO2 separation and purification system.

  14. ,"U.S. Residual Fuel Oil Prices by Sales Type"

    U.S. Energy Information Administration (EIA) Indexed Site

    Data for" ,"Data 1","Residual Fuel Oil Average",2,"Monthly","52016","115... AM" "Back to Contents","Data 1: Residual Fuel Oil Average" "Sourcekey","EMAEPPRPTANUS...

  15. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Mr. Paul Chin; Dr. Xiaolei Sun; Professor George W. Roberts; Professor James J. Spivey; Mr. Amornmart Sirijarhuphan; Dr. James G. Goodwin, Jr.; Dr. Richard W. Rice

    2002-12-31

    Several different catalytic reactions must be carried out in order to convert hydrocarbons (or alcohols) into hydrogen for use as a fuel for polyelectrolyte membrane (PEM) fuel cells. Each reaction in the fuel-processing sequence has a different set of characteristics, which influences the type of catalyst support that should be used for that particular reaction. A wide range of supports are being evaluated for the various reactions in the fuel-processing scheme, including porous and non-porous particles, ceramic and metal straight-channel monoliths, and ceramic and metal monolithic foams. These different types of support have distinctly different transport characteristics. The best choice of support for a given reaction will depend on the design constraints for the system, e.g., allowable pressure drop, and on the characteristics of the reaction for which the catalyst is being designed. Three of the most important reaction characteristics are the intrinsic reaction rate, the exothermicity/endothermicity of the reaction, and the nature of the reaction network, e.g., whether more than one reaction takes place and, in the case of multiple reactions, the configuration of the network. Isotopic transient kinetic analysis was used to study the surface intermediates. The preferential oxidation of low concentrations of carbon monoxide in the presence of high concentrations of hydrogen (PROX) is an important final step in most fuel processor designs. Data on the behavior of straight-channel monoliths and foam monolith supports will be presented to illustrate some of the factors involved in choosing a support for this reaction.

  16. Carbonate fuel cell system with integrated carbon dioxide/thermal management

    SciTech Connect (OSTI)

    Paetsch, L.; Ding, J.; Hunt, J.

    1995-12-31

    Upon successful completion of Phase 1, the Phase 2 activities were initiated in July 1994 to define the stack design and system requirements for a commercial-scale burnerless carbonate fuel cell stack with an integrated carbon dioxide management system. The major goals of this program are to define the stack design and the system requirements of the integrated design. The approach taken was to maximize the similarities of this stack with ERC`s proven baseline stack design and power plant system. Recent accomplishments include a detailed stack design which retains all the essential elements of the baseline stack as well as the power plant system designs. All the auxiliary hardware and external flow patterns remain unchanged, only the internal flow configurations are modified.

  17. EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    County, WY | Department of Energy 2: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY Documents Available for Download November 27, 2009 EIS-0432: Notice of Intent to Prepare an Environmental Impact Statement Federal Loan Guarantee to Support the Construction and Startup of the Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, Wyoming December 16, 2009

  18. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.'' This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft[sup 2] cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  19. Simulated Coal-Gas-Fueled Molten Carbonate Fuel Cell Development Program. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-08-01

    This final report summarizes the technical work performed under Department of Energy Contract DE-AC21-91MC27393, ``Simulated Coal- Gas-Fueled Molten Carbonate Fuel Cell Development Program.`` This work consists of five major tasks and their respective subtasks as listed below. A brief description of each task is also provided. The Stack Design Requirements task focused on requirements and specification for designing, constructing, and testing a nominal 100-kilowatt integrated stack and on requirements for the balance-of-plant equipment to support a 1000-kilowatt integrated stack demonstrator. The Stack Design Preparation task focused on the mechanical design of a 100-kilowatt stack comprised of 8-ft{sup 2} cells incorporating the new cell configuration and component technology improvements developed in the previous DOE MCFC contract. Electrode Casting focused on developing a faster drying solvent for use in the electrode tape casting process. Electrode Heat Treatment was directed at scaling up the laboratory continuous debinding process to a new full-size IFC debinding oven coupled to a continuous belt furnace that will both debind and sinter the electrodes in one continuous process train. Repeat Part Quality Assurance and Testing provided the appropriate effort to ensure consistent, high-quality, reproducible and comparable repeat parts.

  20. Landfill gas cleanup for carbonate fuel cell power generation. Final report

    SciTech Connect (OSTI)

    Steinfield, G.; Sanderson, R.

    1998-02-01

    Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

  1. Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance

    SciTech Connect (OSTI)

    Patel, Anant; Artyushkova, Kateryna; Atanassov, Plamen; Colbow, Vesna; Dutta, Monica; Harvey, Davie; Wessel, Silvia

    2012-04-01

    Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 #2;C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

  2. Investigating the effects of proton exchange membrane fuel cell conditions on carbon supported platinum electrocatalyst composition and performance

    SciTech Connect (OSTI)

    A. Patel; K. Artyushkova; P. Atanassov; V. Colbow; M. Dutta; D. Harvey; S. Wessel

    2012-04-30

    Changes that carbon-supported platinum electrocatalysts undergo in a proton exchange membrane fuel cell environment were simulated by ex situ heat treatment of catalyst powder samples at 150 C and 100% relative humidity. In order to study modifications that are introduced to chemistry, morphology, and performance of electrocatalysts, XPS, HREELS and three-electrode rotating disk electrode experiments were performed. Before heat treatment, graphitic content varied by 20% among samples with different types of carbon supports, with distinct differences between bulk and surface compositions within each sample. Following the aging protocol, the bulk and surface chemistry of the samples were similar, with graphite content increasing or remaining constant and Pt-carbide decreasing for all samples. From the correlation of changes in chemical composition and losses in performance of the electrocatalysts, we conclude that relative distribution of Pt particles on graphitic and amorphous carbon is as important for electrocatalytic activity as the absolute amount of graphitic carbon present

  3. Carbon-based composite electrocatalysts for low temperature fuel cells

    DOE Patents [OSTI]

    Popov, Branko N.; Lee, Jog-Won; Subramanian, Nalini P.; Kumaraguru, Swaminatha P.; Colon-Mercado, Hector R.; Nallathambi, Vijayadurga; Li, Xuguang; Wu, Gang

    2009-12-08

    A process for synthesis of a catalyst is provided. The process includes providing a carbon precursor material, oxidizing the carbon precursor material whereby an oxygen functional group is introduced into the carbon precursor material, and adding a nitrogen functional group into the oxidized carbon precursor material.

  4. Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type

    Gasoline and Diesel Fuel Update (EIA)

    "Resellers'Retailers' Monthly Petroleum Product Sales Report." 16. U.S. No. 2 Diesel Fuel Prices by Sales Type 30 Energy Information Administration Petroleum Marketing Annual...

  5. Thermal Hydraulic Characteristics of Fuel Defects in Plate Type...

    Office of Scientific and Technical Information (OSTI)

    fuel plate using the Multi-physics code COMSOL. Simulation outcomes are compared with experimental data from the Advanced Neutron Source Reactor Thermal Hydraulic Test Loop. ...

  6. Formulating Energy Policies Related to Fossil Fuel Use: Critical Uncertainties in the Global Carbon Cycle

    DOE R&D Accomplishments [OSTI]

    Post, W. M.; Dale, V. H.; DeAngelis, D. L.; Mann, L. K.; Mulholland, P. J.; O`Neill, R. V.; Peng, T. -H.; Farrell, M. P.

    1990-02-01

    The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Four reservoirs can be identified, including the atmosphere, terrestrial biosphere, oceans, and sediments. Atmospheric CO{sub 2} concentration is determined by characteristics of carbon fluxes among major reservoirs of the global carbon cycle. The objective of this paper is to document the knowns, and unknowns and uncertainties associated with key questions that if answered will increase the understanding of the portion of past, present, and future atmospheric CO{sub 2} attributable to fossil fuel burning. Documented atmospheric increases in CO{sub 2} levels are thought to result primarily from fossil fuel use and, perhaps, deforestation. However, the observed atmospheric CO{sub 2} increase is less than expected from current understanding of the global carbon cycle because of poorly understood interactions among the major carbon reservoirs.

  7. A New Leaf: Scientists Turn Carbon Dioxide Back Into Fuel

    Broader source: Energy.gov [DOE]

    Researchers at Argonne National Laboratory found a way to recycle CO2 back into fuel, much the same way plants absorb and convert it.

  8. Electrocatalytic Activity of Transition Metal Oxide-Carbon Composites for Oxygen Reduction in Alkaline Batteries and Fuel Cells

    SciTech Connect (OSTI)

    Malkhandi, S; Trinh, P; Manohar, AK; Jayachandrababu, KC; Kindler, A; Prakash, GKS; Narayanan, SR

    2013-06-07

    Conductive transition metal oxides (perovskites, spinels and pyrochlores) are attractive as catalysts for the air electrode in alkaline rechargeable metal-air batteries and fuel cells. We have found that conductive carbon materials when added to transition metal oxides such as calcium-doped lanthanum cobalt oxide, nickel cobalt oxide and calcium-doped lanthanum manganese cobalt oxide increase the electrocatalytic activity of the oxide for oxygen reduction by a factor of five to ten. We have studied rotating ring-disk electrodes coated with (a) various mass ratios of carbon and transition metal oxide, (b) different types of carbon additives and (c) different types of transition metal oxides. Our experiments and analysis establish that in such composite catalysts, carbon is the primary electro- catalyst for the two-electron electro-reduction of oxygen to hydroperoxide while the transition metal oxide decomposes the hydroperoxide to generate additional oxygen that enhances the observed current resulting in an apparent four-electron process. These findings are significant in that they change the way we interpret previous reports in the scientific literature on the electrocatalytic activity of various transition metal oxide- carbon composites for oxygen reduction, especially where carbon is assumed to be an additive that just enhances the electronic conductivity of the oxide catalyst. (C) 2013 The Electrochemical Society. All rights reserved.

  9. Estimating Source Terms for Diverse Spent Nuclear Fuel Types

    SciTech Connect (OSTI)

    Brett Carlsen; Layne Pincock

    2004-11-01

    The U.S. Department of Energy (DOE) National Spent Nuclear Fuel Program is responsible for developing a defensible methodology for determining the radionuclide inventory for the DOE spent nuclear fuel (SNF) to be dispositioned at the proposed Monitored Geologic Repository at the Yucca Mountain Site. SNF owned by DOE includes diverse fuels from various experimental, research, and production reactors. These fuels currently reside at several DOE sites, universities, and foreign research reactor sites. Safe storage, transportation, and ultimate disposal of these fuels will require radiological source terms as inputs to safety analyses that support design and licensing of the necessary equipment and facilities. This paper summarizes the methodology developed for estimating radionuclide inventories associated with DOE-owned SNF. The results will support development of design and administrative controls to manage radiological risks and may later be used to demonstrate conformance with repository acceptance criteria.

  10. A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA (Journal...

    Office of Scientific and Technical Information (OSTI)

    A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA Citation Details In-Document Search Title: A STUDY OF CARBON FEATURES IN TYPE Ia SUPERNOVA SPECTRA One of the major ...

  11. Engineering Bacteria for Efficient Fuel Production: Novel Biological Conversion of Hydrogen and Carbon Dioxide Directly into Free Fatty Acids

    SciTech Connect (OSTI)

    2010-07-12

    Electrofuels Project: OPX Biotechnologies is engineering a microorganism currently used in industrial biotechnology to directly produce a liquid fuel from hydrogen and carbon dioxide (CO2). The microorganism has the natural ability to use hydrogen and CO2 for growth. OPX Biotechnologies is modifying the microorganism to divert energy and carbon away from growth and towards the production of liquid fuels in larger, commercially viable quantities. The microbial system will produce a fuel precursor that can be chemically upgraded to various hydrocarbon fuels.

  12. Non-segregating electrolytes for molten carbonate fuel cells

    SciTech Connect (OSTI)

    Krumpelt, M.; Kaun, T.; Lanagan, M.

    1996-08-01

    Current MCFCs use a Li/K carbonate mixture; the segregation increases the K concentration near the cathode, leading to increase cathode solubility and performance decline. ANL is developing molten carbonates that have minimal segregation; the approach is using Li-Na carbonates. In screening tests, fully developed potential distributions were obtained for 4 Li/Na compositions, and performance data were used to compare these.

  13. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect (OSTI)

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  14. Selection and preparation of activated carbon for fuel gas storage

    DOE Patents [OSTI]

    Schwarz, James A.; Noh, Joong S.; Agarwal, Rajiv K.

    1990-10-02

    Increasing the surface acidity of active carbons can lead to an increase in capacity for hydrogen adsorption. Increasing the surface basicity can facilitate methane adsorption. The treatment of carbons is most effective when the carbon source material is selected to have a low ash content i.e., below about 3%, and where the ash consists predominantly of alkali metals alkali earth, with only minimal amounts of transition metals and silicon. The carbon is washed in water or acid and then oxidized, e.g. in a stream of oxygen and an inert gas at an elevated temperature.

  15. Bipolar plate materials in molten carbonate fuel cells. Final CRADA report.

    SciTech Connect (OSTI)

    Krumpelt, M. Gorelov, A. M.

    2004-06-01

    Advantages of implementation of power plants based on electrochemical reactions are successfully demonstrated in the USA and Japan. One of the msot promising types of fuel cells (FC) is a type of high temperature fuel cells. At present, thanks to the efforts of the leading countries that develop fuel cell technologies power plants on the basis of molten carbonate fuel cells (MCFC) and solid oxide fuel cells (SOFC) are really close to commercialization. One of the problems that are to be solved for practical implementation of MCFC and SOFC is a problem of corrosion of metal components of stacks that are assembled of a number of fuel cells. One of the major components of MCFC and SOFC stacks is a bipolar separator plate (BSP) that performs several functions - it is separation of reactant gas flows sealing of the joints between fuel cells, and current collection from the surface of electrodes. The goal of Task 1 of the project is to develop new cost-effective nickel coatings for the Russian 20X23H18 steel for an MCFC bipolar separator plate using technological processes usually implemented to apply corrosion stable coatings onto the metal parts for products in the defense. There was planned the research on production of nickel coatings using different methods, first of all the galvanic one and the explosion cladding one. As a result of the works, 0.4 x 712 x 1296 mm plates coated with nickel on one side were to be made and passed to ANL. A line of 4 galvanic baths 600 liters was to be built for the galvanic coating applications. The goal of Task 2 of the project is the development of a new material of an MCFC bipolar separator plate with an upgraded corrosion stability, and development of a technology to produce cold roll sheets of this material the sizes of which will be 0.8 x 712x 1296 mm. As a result of these works, a pilot batch of the rolled material in sheets 0.8 x 712 x 1296 mm in size is to be made (in accordance with the norms and standards of the Russian

  16. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; et al

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption andmore » clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).« less

  17. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    SciTech Connect (OSTI)

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; Andres, Robert Joseph; Crawford-Brown, D.; Lin, J.; Zhao, H.; Hong, C.; Boden, Thomas A.; Feng, K.; Peters, Glen P.; Xi, F.; Liu, J.; Li, Y.; Zhao, Y.; Zeng, Ning; He, K.

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).

  18. Fact #586: August 31, 2009 New Vehicle Fuel Economies by Vehicle Type |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 6: August 31, 2009 New Vehicle Fuel Economies by Vehicle Type Fact #586: August 31, 2009 New Vehicle Fuel Economies by Vehicle Type The average fuel economy for new cars climbed to over 30 miles per gallon (mpg) in 2008 while the average for new pickup trucks stayed around 20 mpg. For new vans and sport utility vehicles (SUVs) the average fuel economy has noticeably increased in the last few years. These data are weighted by the number of vehicles sold. New Vehicle

  19. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  20. An option making for nuclear fuel reprocessing by using supercritical carbon dioxide

    SciTech Connect (OSTI)

    Enokida, Youichi; Sawada, Kayo; Shimada, Takashi; Yamamoto, Ichiro

    2007-07-01

    A four-year-research has been completed as a collaborative work by Nagoya University Mitsubishi Heavy Industries Corporation and Japan Atomic Energy Agency (JAEA) in order to develop a super critical carbon dioxide (SF-CO{sub 2}) based technology, 'SUPER-DIREX process', for nuclear fuel reprocessing. As a result obtained in Phase II of the Japan's feasibility Studies on Commercialized Fast Reactor Cycle Systems, this technology was evaluated as one of the alternatives for the advanced Purex process for he future FBR fuel cycle. Although further investigation is required for a scaled-up demonstration of processing spent fuels by SUPER-DIREX process, we could conclude that an option has been made for nuclear fuel reprocessing by using supercritical carbon dioxide. (authors)

  1. Carbon dioxide emission index as a mean for assessing fuel quality

    SciTech Connect (OSTI)

    Furimsky, E.

    2008-07-01

    Carbon dioxide emission index, defined as the amount of CO{sub 2} released per unit of energy value, was used to rate gaseous, liquid and solid fuels. The direct utilization of natural gas is the most efficient option. The conversion of natural gas to synthesis gas for production of liquid fuels represents a significant decrease in fuel value of the former. The fuel value of liquids, such as gasoline, diesel oil, etc. is lower than that of natural gas. Blending gasoline with ethanol obtained either from bio-mass or via synthesis may decrease fuel value of the blend when CO{sub 2} emissions produced during the production of ethanol are included in total emissions. The introduction of liquid fuels produced by pyrolysis and liquefaction of biomass would result in the increase in the CO{sub 2} emissions. The CO{sub 2} emissions from the utilization of coal and petroleum coke are much higher than those from gaseous and liquid fuels. However, for petroleum coke, this is offset by the high value gaseous and liquid fuels that are simultaneously produced during coking. Conversion of low value fuels such as coal and petroleum coke to a high value chemicals via synthesis gas should be assessed as means for replacing natural gas and making it available for fuel applications.

  2. Preface for small-molecule activation: Carbon-containing fuels

    SciTech Connect (OSTI)

    Fujita, Etsuko; Goldman, Alan S.

    2015-06-01

    For millennia, human transportation was fueled largely through the consumption of biomass (by humans or domestic animals) and to a lesser extent by wind. The 19th century saw a major shift to coal-fueled transportation, with trains and ships powered by steam engines. A second major shift in the fueling of transportation occurred in the 20th century, this time to petroleum. Thus, this transition was not driven by the cost or ease of obtaining energy from oil wells vs. coal mines – indeed, the cost of petroleum has always been higher than coal on a per-unit-energy basis – but rather by the tremendous technical advantages of powering engines with liquids, specifically liquid hydrocarbons.

  3. Preface for small-molecule activation: Carbon-containing fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fujita, Etsuko; Goldman, Alan S.

    2015-06-01

    For millennia, human transportation was fueled largely through the consumption of biomass (by humans or domestic animals) and to a lesser extent by wind. The 19th century saw a major shift to coal-fueled transportation, with trains and ships powered by steam engines. A second major shift in the fueling of transportation occurred in the 20th century, this time to petroleum. Thus, this transition was not driven by the cost or ease of obtaining energy from oil wells vs. coal mines – indeed, the cost of petroleum has always been higher than coal on a per-unit-energy basis – but rather bymore » the tremendous technical advantages of powering engines with liquids, specifically liquid hydrocarbons.« less

  4. Preface for small-molecule activation: Carbon-containing fuels

    SciTech Connect (OSTI)

    Fujita, Etsuko; Goldman, Alan S.

    2015-06-01

    For millennia, human transportation was fueled largely through the consumption of biomass (by humans or domestic animals) and to a lesser extent by wind. The 19th century saw a major shift to coal-fueled transportation, with trains and ships powered by steam engines. A second major shift in the fueling of transportation occurred in the 20th century, this time to petroleum. Thus, this transition was not driven by the cost or ease of obtaining energy from oil wells vs. coal mines indeed, the cost of petroleum has always been higher than coal on a per-unit-energy basis but rather by the tremendous technical advantages of powering engines with liquids, specifically liquid hydrocarbons.

  5. Copper clusters capture and convert carbon dioxide to make fuel | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Copper clusters capture and convert carbon dioxide to make fuel By Payal Marathe * August 6, 2015 Tweet EmailPrint Capture and convert-this is the motto of carbon dioxide reduction, a process that stops the greenhouse gas before it escapes from chimneys and power plants into the atmosphere and instead turns it into a useful product. One possible end product is methanol, a liquid fuel and the focus of a recent study conducted at the U.S. Department of Energy's (DOE)

  6. Porous electrolyte retainer for molten carbonate fuel cell

    DOE Patents [OSTI]

    Singh, Raj N.; Dusek, Joseph T.

    1983-06-21

    A porous tile for retaining molten electrolyte within a fuel cell is prepared by sintering particles of lithium aluminate into a stable structure. The tile is assembled between two porous metal plates which serve as electrodes with fuels gases such as H.sub.2 and CO opposite to oxidant gases such as O.sub.2 and CO.sub.2. The tile is prepared with a porosity of 55-65% and a pore size distribution selected to permit release of sufficient molten electrolyte to wet but not to flood the adjacent electrodes.

  7. Porous electrolyte retainer for molten carbonate fuel cell. [lithium aluminate

    DOE Patents [OSTI]

    Singh, R.N.; Dusek, J.T.

    1979-12-27

    A porous tile for retaining molten electrolyte within a fuel cell is prepared by sintering particles of lithium aluminate into a stable structure. The tile is assembled between two porous metal plates which serve as electrodes with fuels gases such as H/sub 2/ and CO opposite to oxidant gases such as O/sub 2/ and CO/sub 2/. The tile is prepared with a porosity of 55 to 65% and a pore size distribution selected to permit release of sufficient molten electrolyte to wet but not to flood the adjacent electrodes.

  8. Humidifier for fuel cell using high conductivity carbon foam

    DOE Patents [OSTI]

    Klett, James W.; Stinton, David P.

    2006-12-12

    A method and apparatus of supplying humid air to a fuel cell is disclosed. The extremely high thermal conductivity of some graphite foams lends itself to enhance significantly the ability to humidify supply air for a fuel cell. By utilizing a high conductivity pitch-derived graphite foam, thermal conductivity being as high as 187 W/m.dot.K, the heat from the heat source is more efficiently transferred to the water for evaporation, thus the system does not cool significantly due to the evaporation of the water and, consequently, the air reaches a higher humidity ratio.

  9. Fact #920: April 11, 2016 Electric Charging Stations are the Fastest Growing Type of Alternative Fueling Station- Dataset

    Broader source: Energy.gov [DOE]

    Excel file and dataset for Electric Charging Stations are the Fastest Growing Type of Alternative Fueling Station

  10. Development of a 200kW multi-fuel type PAFC power plant

    SciTech Connect (OSTI)

    Take, Tetsuo; Kuwata, Yutaka; Adachi, Masahito; Ogata, Tsutomu

    1996-12-31

    Nippon Telegraph and Telephone Corporation (NFT) has been developing a 200 kW multi-fuel type PAFC power plant which can generate AC 200 kW of constant power by switching fuel from pipeline town gas to liquefied propane gas (LPG) and vice versa. This paper describes the outline of the demonstration test plant and test results of its fundamental characteristics.

  11. Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2000-01-01

    A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

  12. Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.4 65.5 51.3 See footnotes at end of table. Energy Information AdministrationPetroleum Marketing Annual 1999 191 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District,...

  13. Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    64.6 54.0 See footnotes at end of table. Energy Information Administration Petroleum Marketing Annual 1995 233 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District,...

  14. Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District...

    U.S. Energy Information Administration (EIA) Indexed Site

    60.4 60.0 45.2 See footnotes at end of table. Energy Information AdministrationPetroleum Marketing Annual 1998 191 Table 40. No. 2 Diesel Fuel Prices by Sales Type, PAD District,...

  15. Creep resistant, metal-coated LiFeO[sub 2] anodes for molten carbonated fuel cells

    DOE Patents [OSTI]

    Khandkar, A.C.

    1994-08-23

    A porous, creep-resistant, metal-coated, LiFeO[sub 2] ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well. 11 figs.

  16. Creep resistant, metal-coated LiFeO.sub.2 anodes for molten carbonated fuel cells

    DOE Patents [OSTI]

    Khandkar, Ashok C. (Salt Lake City, UT)

    1994-01-01

    A porous, creep-resistant, metal-coated, LiFeO.sub.2 ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well.

  17. Evaluation of cast carbon steel and aluminum for rack insert in MCO Mark 1A fuel basket

    SciTech Connect (OSTI)

    Graves, C.E., Fluor Daniel Hanford

    1997-03-21

    This document evaluates the effects ofusing a cast carbon steel or aluminum instead of 3O4L stainless steel in the construction ofthe fuel rack insert for the Spent Nuclear Fuel MCO Mark IA fuel baskets. The corrosion, structural, and cost effects are examined.

  18. Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Alivisatos, Paul

    2011-06-03

    Paul Alivisatos, LBNL Director speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 4, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  19. Molten carbonate fuel cell (MCFC) product development test. Annual report, October 1994--September 1995

    SciTech Connect (OSTI)

    1996-01-01

    This report summarizes the technical progress that has occurred in conjunction with Cooperative Agreement No. DE-FC21-92MC28065, Molten Carbonate Fuel Cell Product Development Test (PDT) during the period of October 1, 1994 through September 30, 1995. Information is presented on stack design, manufacturing, stack assembly, procurement, site preparation, and test plan.

  20. Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report

    SciTech Connect (OSTI)

    Steinfeld, G.; Sanderson, R.

    1998-02-01

    The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

  1. Combined Power Generation and Carbon Sequestration Using Direct FuelCell

    SciTech Connect (OSTI)

    Hossein Ghezel-Ayagh

    2006-03-01

    The unique chemistry of carbonate fuel cell offers an innovative approach for separation of carbon dioxide from greenhouse gases (GHG). The carbonate fuel cell system also produces electric power at high efficiency. The simultaneous generation of power and sequestration of greenhouse gases offer an attractive scenario for re-powering the existing coal-fueled power plants, in which the carbonate fuel cell would separate the carbon dioxide from the flue gas and would generate additional pollutant-free electric power. Development of this system is concurrent with emergence of Direct FuelCell{reg_sign} (DFC{reg_sign}) technology for generation of electric power from fossil fuels. DFC is based on carbonate fuel cell featuring internal reforming. This technology has been deployed in MW-scale power plants and is readily available as a manufactured product. This final report describes the results of the conceptualization study conducted to assess the DFC-based system concept for separation of CO2 from GHG. Design and development studies were focused on integration of the DFC systems with coal-based power plants, which emit large amounts of GHG. In parallel to the system design and simulation activities, operation of laboratory scale DFC verified the technical concept and provided input to the design activity. The system was studied to determine its effectiveness in capturing more than ninety percent of CO2 from the flue gases. Cost analysis was performed to estimate the change in cost of electricity for a 200 MW pulverized coal boiler steam cycle plant retrofitted with the DFC-based CO2 separation system producing an additional 127 MW of electric power. The cost increments as percentage of levelized cost of electricity were estimated for a range of separation plant installations per year and a range of natural gas cost. The parametric envelope meeting the goal (<20% increase in COE) was identified. Results of this feasibility study indicated that DFC-based separation

  2. Fuel cell separator plate with bellows-type sealing flanges

    DOE Patents [OSTI]

    Louis, George A. (West Hartford, CT)

    1986-08-05

    A fuel cell separator includes a rectangular flat plate having two unitary upper sealing flanges respectively comprising opposite marginal edges of the plate folded upwardly and back on themselves and two lower sealing flanges respectively comprising the other two marginal edges of the plate folded downwardly and back on themselves. Each of the sealing flanges includes a flat wall spaced from the plate and substantially parallel thereto and two accordion-pleated side walls, one of which interconnects the flat wall with the plate and the other of which stops just short of the plate, these side walls affording resilient compressibility to the sealing flange in a directiongenerally normal to the plane of the plate. Four corner members close the ends of the sealing flanges. An additional resiliently compressible reinforcing member may be inserted in the passages formed by each of the sealing flanges with the plate.

  3. Solar Fuels and Carbon Cycle 2.0 (Carbon Cycle 2.0) (Conference...

    Office of Scientific and Technical Information (OSTI)

    the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http:carboncycle2.lbl.gov Authors: Alivisatos, Paul...

  4. Electrolyte matrix in a molten carbonate fuel cell stack

    DOE Patents [OSTI]

    Reiser, Carl A.; Maricle, Donald L.

    1987-04-21

    A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack.

  5. Electrolyte matrix in a molten carbonate fuel cell stack

    DOE Patents [OSTI]

    Reiser, C.A.; Maricle, D.L.

    1987-04-21

    A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack. 6 figs.

  6. Transportation Energy Futures Series: Alternative Fuel Infrastructure Expansion: Costs, Resources, Production Capacity, and Retail Availability for Low-Carbon Scenarios

    SciTech Connect (OSTI)

    Melaina, M. W.; Heath, G.; Sandor, D.; Steward, D.; Vimmerstedt, L.; Warner, E.; Webster, K. W.

    2013-04-01

    Achieving the Department of Energy target of an 80% reduction in greenhouse gas emissions by 2050 depends on transportation-related strategies combining technology innovation, market adoption, and changes in consumer behavior. This study examines expanding low-carbon transportation fuel infrastructure to achieve deep GHG emissions reductions, with an emphasis on fuel production facilities and retail components serving light-duty vehicles. Three distinct low-carbon fuel supply scenarios are examined: Portfolio: Successful deployment of a range of advanced vehicle and fuel technologies; Combustion: Market dominance by hybridized internal combustion engine vehicles fueled by advanced biofuels and natural gas; Electrification: Market dominance by electric drive vehicles in the LDV sector, including battery electric, plug-in hybrid, and fuel cell vehicles, that are fueled by low-carbon electricity and hydrogen. A range of possible low-carbon fuel demand outcomes are explored in terms of the scale and scope of infrastructure expansion requirements and evaluated based on fuel costs, energy resource utilization, fuel production infrastructure expansion, and retail infrastructure expansion for LDVs. This is one of a series of reports produced as a result of the Transportation Energy Futures (TEF) project, a Department of Energy-sponsored multi-agency project initiated to pinpoint underexplored transportation-related strategies for abating GHGs and reducing petroleum dependence.

  7. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  8. Method of preparing a dimensionally stable electrode for use in a molten carbonate fuel cell

    DOE Patents [OSTI]

    Swarr, T.E.; Wnuck, W.G.

    1986-01-29

    A method is disclosed for preparing a dimensionally stable electrode structure, particularly nickel-chromium anodes, for use in a molten carbonate fuel cell stack. A low-chromium to nickel alloy is provided and oxidized in a mildly oxidizing gas of sufficient oxidation potential to oxidize chromium in the alloy structure. Typically, a steam/H/sub 2/ gas mixture in a ratio of about 100/1 and at a temperature below 800/sup 0/C is used as the oxidizing medium. This method permits the use of less than 5 wt % chromium in nickel alloy electrodes while obtaining good resistance to creep in the electrodes of a fuel cell stack.

  9. Summary report : direct approaches for recycling carbon dioxide into synthetic fuel.

    SciTech Connect (OSTI)

    Allendorf, Mark D.; Ambrosini, Andrea; Diver, Richard B., Jr.; Siegel, Nathan Phillip; Miller, James Edward; Gelbard, Fred; Evans, Lindsey R.

    2009-01-01

    The consumption of petroleum by the transportation sector in the United States is roughly equivalent to petroleum imports into the country, which have totaled over 12 million barrels a day every year since 2004. This reliance on foreign oil is a strategic vulnerability for the economy and national security. Further, the effect of unmitigated CO{sub 2} releases on the global climate is a growing concern both here and abroad. Independence from problematic oil producers can be achieved to a great degree through the utilization of non-conventional hydrocarbon resources such as coal, oil-shale and tarsands. However, tapping into and converting these resources into liquid fuels exacerbates green house gas (GHG) emissions as they are carbon rich, but hydrogen deficient. Revolutionary thinking about energy and fuels must be adopted. We must recognize that hydrocarbon fuels are ideal energy carriers, but not primary energy sources. The energy stored in a chemical fuel is released for utilization by oxidation. In the case of hydrogen fuel the chemical product is water; in the case of a hydrocarbon fuel, water and carbon dioxide are produced. The hydrogen economy envisions a cycle in which H{sub 2}O is re-energized by splitting water into H{sub 2} and O{sub 2}, by electrolysis for example. We envision a hydrocarbon analogy in which both carbon dioxide and water are re-energized through the application of a persistent energy source (e.g. solar or nuclear). This is of course essentially what the process of photosynthesis accomplishes, albeit with a relatively low sunlight-to-hydrocarbon efficiency. The goal of this project then was the creation of a direct and efficient process for the solar or nuclear driven thermochemical conversion of CO{sub 2} to CO (and O{sub 2}), one of the basic building blocks of synthetic fuels. This process would potentially provide the basis for an alternate hydrocarbon economy that is carbon neutral, provides a pathway to energy independence, and is

  10. Carbon attrition during the circulating fluidized bed combustion of a packaging-derived fuel

    SciTech Connect (OSTI)

    Mastellone, M.L.; Arena, U.

    1999-05-01

    Cylindrical pellets of a market-available packaging-derived fuel, obtained from a mono-material collection of polyethylene terephthalate (PET) bottles, were batchwise fed to a laboratory scale circulating fluidized bed (CFB) combustor. The apparatus, whose riser was 41 mm ID and 4 m high, was operated under both inert and oxidizing conditions to establish the relative importance of purely mechanical attrition and combustion-assisted attrition in generating carbon fines. Silica sand particles of two size distributions were used as inert materials. For each run, carbon load and carbon particle size distribution in the riser and rates of attrited carbon fines escaping the combustor were determined as a function of time. A parallel investigation was carried out with a bubbling fluidized bed (BFB) combustor to point out peculiarities of attrition in CFB combustors. After devolatilization, PET pellets generated fragile aggregates of char and sand, which easily crumbled, leading to single particles, partially covered by a carbon-rich layer. The injected fixed carbon was therefore present in the bed in three phases: an A-phase, made of aggregates of sand and char, an S-phase, made of individual carbon-covered sand particles and an F-phase, made of carbon fines, abraded by the surfaces of the A- and S-phases. The effects of the size of inert material on the different forms under which fixed carbon was present in the bed and on the rate of escape of attrited carbon fines from the combustor were investigated. Features of carbon attrition in CFB and BFB combustors are discussed.

  11. DOE Fuel Cell Technologies Office Record 13010: Onboard Type IV Compressed

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Storage Systems-Current Performance and Cost | Department of Energy Office Record 13010: Onboard Type IV Compressed Hydrogen Storage Systems-Current Performance and Cost DOE Fuel Cell Technologies Office Record 13010: Onboard Type IV Compressed Hydrogen Storage Systems-Current Performance and Cost This record summarizes the current status of the projected capacities and manufacturing costs of Type IV, 350- and 700-bar compressed hydrogen storage systems, storing 5.6 kg of usable

  12. Method of evaluating the integrity of the outer carbon layer of triso-coated reactor fuel particles

    DOE Patents [OSTI]

    Caputo, Anthony J.; Costanzo, Dante A.; Lackey, Jr., Walter J.; Layton, Frank L.; Stinton, David P.

    1980-01-01

    This invention relates to a method for determining defective final layers of carbon on triso-coated fuel particles and the like. Samples of the particles are subjected to a high temperature treatment with gaseous chlorine and thereafter radiographed. The chlorine penetrates through any defective carbon layer and reacts with the underlying silicon carbide resulting in the volatilization of the silicon as SiCl.sub.4 leaving carbon as a porous layer. This porous carbon layer is easily detected by the radiography.

  13. Behavior of carbonate-rich fuels in ACFBC and PFBC conditions

    SciTech Connect (OSTI)

    Ots, A.; Arro, H.; Pihu, T.; Prikk, A.

    1999-07-01

    Estonian oil shale is known as one of richest in carbonate fuels. High mineral matter content (60--75% in dry mass), moderate moisture (9--12%) and carbonate carbon dioxide content (17--19%), and low heating value (LHV 8--10 MJ/kg as received) are characteristic for Estonian oil shale. Approximately half of the mineral matter is in the carbonate form, mainly as calcium carbonate. The sulfur content of dry mass is 1.5--1.7% and Ca/S molar ratio is 8--10. Due to limestone present in oil shale, the additional sorbent for sulfur retention during combustion is not needed. The behavior of carbonates as well as the formation of ash at fluidized bed combustion (FBC) was the main topics to study. At Thermal Engineering Department (TED) of Tallinn Technical University a laboratory pressurized combustion facility was used for investigation the decomposition of soil shale carbonates in atmospheric and pressurized burning conditions. The experiments with oil shale were performed at pressures 0.1 MPa and 1.2 MPa and at the temperature 850 C. Based on the carbonate decomposition rate (CDR) 0.3--0.4 established experimentally at pressurized combustion, it may be concluded that the heating value of oil shale increases approximately by 5.5--8% and the carbon dioxide concentration in flue gas decreases by 13--20% compared with the conditions of the complete decomposition of carbonate. Combustion of oil shale was tested in 0.15--1.0 MW{sub th} test facilities. The tests confirmed the suitability of both ACFBC and PFBC technologies to utilize oil shale. The tests showed a nearly complete binding of sulfur by oil shale ash and a limited formation of NO{sub x} at combustion. Oil shale FBC is characterized by the formation of large amounts (40--85% from total) of fine-grained fly ash.

  14. Molten carbonate fuel cell product development test environmental assessment/protection plan

    SciTech Connect (OSTI)

    Not Available

    1992-11-01

    Objective of proposed action is to conduct a 250-kW product development test of M-C Power Corporation`s molten carbonate fuel cell concept, at the Kaiser Permanente San Diego Medical Center. Review of environmental impacts of this test indicate the following: no impact on solid waste disposal, water quality, noise levels, floodplains, wetlands, ecology, historic areas, or socioeconomic resources. Impact on air quality are expected to be positive.

  15. Molten carbonate fuel cell product development test environmental assessment/protection plan

    SciTech Connect (OSTI)

    Brunton, Jack; Furukawa, Vance; Frost, Grant; Danna, Mike; Figueroa, Al; Scroppo, Joseph

    1992-11-01

    Objective of proposed action is to conduct a 250-kW product development test of M-C Power Corporation's molten carbonate fuel cell concept, at the Kaiser Permanente San Diego Medical Center. Review of environmental impacts of this test indicate the following: no impact on solid waste disposal, water quality, noise levels, floodplains, wetlands, ecology, historic areas, or socioeconomic resources. Impact on air quality are expected to be positive.

  16. The Challenge of Achieving Californias Low Carbon Fuel Standard

    U.S. Energy Information Administration (EIA) Indexed Site

    Author: Peter Gross, peter.gross@eia.doe.gov, (202)586-8822 Disclaimer: Views not necessarily those of the U. S. Energy Information Administration Date: May 15, 2010 Revised: July 16, 2010 The Challenge of Achieving California's Low Carbon Fuel Standard Peter Gross Office of Integrated Analysis and Forecasting U.S. Energy Information Administration This paper is released to encourage discussion and critical comment. The analysis and conclusions expressed here are those of the author and not

  17. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9072 September 2010 Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis Robert Remick National Renewable Energy Laboratory Douglas Wheeler DJW Technology, LLC National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393 303-275-3000 * www.nrel.gov NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Operated by the Alliance for Sustainable Energy, LLC Contract No.

  18. Power conversion and quality of the Santa Clara 2 MW direct carbonate fuel cell demonstration plant

    SciTech Connect (OSTI)

    Skok, A.J.; Abueg, R.Z.; Schwartz, P.

    1996-12-31

    The Santa Clara Demonstration Project (SCDP) is the first application of a commercial-scale carbonate fuel cell power plant on a US electric utility system. It is also the largest fuel cell power plant ever operated in the United States. The 2MW plant, located in Santa Clara, California, utilizes carbonate fuel cell technology developed by Energy Research Corporation (ERC) of Danbury, Connecticut. The ultimate goal of a fuel cell power plant is to deliver usable power into an electrical distribution system. The power conversion sub-system does this for the Santa Clara Demonstration Plant. A description of this sub-system and its capabilities follows. The sub-system has demonstrated the capability to deliver real power, reactive power and to absorb reactive power on a utility grid. The sub-system can be operated in the same manner as a conventional rotating generator except with enhanced capabilities for reactive power. Measurements demonstrated the power quality from the plant in various operating modes was high quality utility grade power.

  19. Chemical Kinetic Reaction Mechanisms for Combustion of Hydrocarbon and Other Types of Chemical Fuels

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The central feature of the Combustion Chemistry project at LLNL is the development, validation, and application of detailed chemical kinetic reaction mechanisms for the combustion of hydrocarbon and other types of chemical fuels. For the past 30 years, LLNL's Chemical Sciences Division has built hydrocarbon mechanisms for fuels from hydrogen and methane through much larger fuels including heptanes and octanes. Other classes of fuels for which models have been developed include flame suppressants such as halons and organophosphates, and air pollutants such as soot and oxides of nitrogen and sulfur. Reaction mechanisms have been tested and validated extensively through comparisons between computed results and measured data from laboratory experiments (e.g., shock tubes, laminar flames, rapid compression machines, flow reactors, stirred reactors) and from practical systems (e.g., diesel engines, spark-ignition engines, homogeneous charge, compression ignition (HCCI) engines). These kinetic models are used to examine a wide range of combustion systems.

  20. An overview of alternative fossil fuel price and carbon regulation scenarios

    SciTech Connect (OSTI)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices

  1. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2013-04-02

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  2. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2011-01-18

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  3. Method for producing bio-fuel that integrates heat from carbon-carbon bond-forming reactions to drive biomass gasification reactions

    DOE Patents [OSTI]

    Cortright, Randy D.; Dumesic, James A.

    2012-04-10

    A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H.sub.2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

  4. MOLTEN CARBONATE FUEL CELL POWER PLANT LOCATED AT TERMINAL ISLAND WASTEWATER TREATMENT PLANT

    SciTech Connect (OSTI)

    William W. Glauz

    2004-09-01

    The Los Angeles Department of Water and Power (LADWP) has developed one of the most recognized fuel cell demonstration programs in the United States. In addition to their high efficiencies and superior environmental performance, fuel cells and other generating technologies that can be located at or near the load, offers several electric utility benefits. Fuel cells can help further reduce costs by reducing peak electricity demand, thereby deferring or avoiding expenses for additional electric utility infrastructure. By locating generators near the load, higher reliability of service is possible and the losses that occur during delivery of electricity from remote generators are avoided. The potential to use renewable and locally available fuels, such as landfill or sewage treatment waste gases, provides another attractive outlook. In Los Angeles, there are also many oil producing areas where the gas by-product can be utilized. In June 2000, the LADWP contracted with FCE to install and commission the precommercial 250kW MCFC power plant. The plant was delivered, installed, and began power production at the JFB in August 2001. The plant underwent manufacturer's field trials up for 18 months and was replace with a commercial plant in January 2003. In January 2001, the LADWP contracted with FCE to provide two additional 250kW MCFC power plants. These commercial plants began operations during mid-2003. The locations of these plants are at the Terminal Island Sewage Treatment Plant at the Los Angeles Harbor (for eventual operation on digester gas) and at the LADWP Main Street Service Center east of downtown Los Angeles. All three carbonate fuel cell plants received partial funding through the Department of Defense's Climate Change Fuel Cell Buydown Program. This report covers the technical evaluation and benefit-cost evaluation of the Terminal Island 250kW MCFC power plant during its first year of operation from June 2003 to July 2004.

  5. Reducing Our Carbon Footprint: Converting Plants to Fuel (LBNL Science at the Theater)

    ScienceCinema (OSTI)

    Somerville, Chris

    2011-04-28

    Berkeley Lab's Chris Somerville is a leading authority on the structure and function of plant cell walls, which comprise most of the body mass of higher plants. He views the knowledge of cell wall structure and function as furthering the development of plants with improved usefulness: these plants are strong potential sources of renewable materials and biofuel feedstocks. His scientific expertise defines an ideal match of his interest - in the development of cellulosic and other solar-to-fuel science - with his recent appointment as Director of the Energy Biosciences Institute (EBI). With colleagues in biology, physical sciences, engineering, and environmental and the social sciences, he now leads the EBI multidisciplinary teams' research efforts to develop next-generation, carbon-neutral transportation fuels.

  6. Electro-catalytic oxidation device for removing carbon from a fuel reformate

    DOE Patents [OSTI]

    Liu, Di-Jia

    2010-02-23

    An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

  7. Fundamental stack and system issues in molten carbonate fuel cell development

    SciTech Connect (OSTI)

    Williams, M.C.; Parsons, E.L. Jr.; Mayfield, M.J.

    1993-12-31

    Stack research and system issues in molten carbonate fuel cell (MCFC) technology development and commercialization are discussed within context of status of MCFC development and commercialization in US. Status of MCFC development is addressed. Major known fundamental stack research issues remaining for the MCFC technology are identified and discussed. The cathode remains a focal point of performance improvement and cost reduction. The various aspects of MCFC power plant network and systems issues are also addressed and discussed. These include cost, heat loss management, startup and shutdown modes, dynamic response, footprint, packaging and integration, parasitic power losses, pressurization and reforming. Potential of MCFC networks is discussed. With the initial demonstration of full-area, fullheight 250-kW to 2-MW MCFC power plants, the spatial configuration of the MCFC stacks into networks in the fuel cell power plant takes on importance for the first time.

  8. Startup, testing, and operation of the Santa Clara 2MW direct carbonate fuel cell demonstration plant

    SciTech Connect (OSTI)

    Skok, A.J.; Leo, A.J.; O`Shea, T.P.

    1996-12-31

    The Santa Clara Demonstration Project (SCDP) is a collaboration between several utility organizations, Fuel Cell Engineering Corporation (FCE), and the U.S. Dept. Of Energy aimed at the demonstration of Energy Research Corporation`s (ERC) direct carbonate fuel cell (DFC) technology. ERC has been pursuing the development of the DFC for commercialization near the end of this decade, and this project is an integral part of the ERC commercialization effort. The objective of the Santa Clara Demonstration Project is to provide the first full, commercial scale demonstration of this technology. The approach ERC has taken in the commercialization of the DFC is described in detail elsewhere. An aggressive core technology development program is in place which is focused by ongoing interaction with customers and vendors to optimize the design of the commercial power plant. ERC has selected a 2.85 MW power plant unit for initial market entry. Two ERC subsidiaries are supporting the commercialization effort: the Fuel Cell Manufacturing Corporation (FCMC) and the Fuel Cell Engineering Corporation (FCE). FCMC manufactures carbonate stacks and multi-stack modules, currently from its production facility in Torrington, CT. FCE is responsible for power plant design, integration of all subsystems, sales/marketing, and client services. FCE is serving as the prime contractor for the design, construction, and testing of the SCDP Plant. FCMC has manufactured the multi-stack submodules used in the DC power section of the plant. Fluor Daniel Inc. (FDI) served as the architect-engineer subcontractor for the design and construction of the plant and provided support to the design of the multi-stack submodules. FDI is also assisting the ERC companies in commercial power plant design.

  9. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  10. Evaluation of the feasibility of ethanol steam reforming in a molten carbonate fuel cell

    SciTech Connect (OSTI)

    Cavallaro, S.; Passalacqua, E.; Maggio, G.; Patti, A.; Freni, S.

    1996-12-31

    The molten carbonate fuel cells (MCFCs) utilizing traditional fuels represent a suitable technological progress in comparison with pure hydrogen-fed MCFCs. The more investigated fuel for such an application is the methane, which has the advantages of low cost and large availability; besides, several authors demonstrated the feasibility of a methane based MCFC. In particular, the methane steam-reforming allows the conversion of the fuel in hydrogen also inside the cell (internal reforming configuration), utilizing the excess heat to compensate the reaction endothermicity. In this case, however, both the catalyst and the cell materials are subjected to thermal stresses due to the cold spots arising near to the reaction sites MCFC. An alternative, in accordance with the recent proposals of other authors, may be to produce hydrogen from methane by the partial oxidation reaction, rather than by steam reforming. This reaction is exothermic ({Delta}H{degrees}=-19.1 kJ/mol H{sub 2}) and it needs to verify the possibility to obtain an acceptable distribution of the temperature inside the cell. The alcohols and, in particular, methanol shows the gas reformed compositions as a function of the steam/ethanol molar ratio, ranging from 1.0 to 3.5. The hydrogen production enhances with this ratio, but it presents a maximum at S/EtOH of about 2.0. Otherwise, the increase of S/EtOH depresses the production of CO and CH{sub 4}, and ethanol may be a further solution for the hydrogen production inside a MCFC. In this case, also, the reaction in cell is less endothermic compared with the methane steam reforming with the additional advantage of a liquid fuel more easily storable and transportable. Aim of the present work is to perform a comparative evaluation of the different solutions, with particular reference to the use of ethanol.

  11. MOLTEN CARBONATE FUEL CELL POWER PLANT LOCATED AT LADWP MAIN STREET SERVICE CENTER

    SciTech Connect (OSTI)

    William W. Glauz

    2004-09-10

    The Los Angeles Department of Water and Power (LADWP) has developed one of the most recognized fuel cell demonstration programs in the United States. In addition to their high efficiencies and superior environmental performance, fuel cells and other generating technologies that can be located at or near the load, offers several electric utility benefits. Fuel cells can help further reduce costs by reducing peak electricity demand, thereby deferring or avoiding expenses for additional electric utility infrastructure. By locating generators near the load, higher reliability of service is possible and the losses that occur during delivery of electricity from remote generators are avoided. The potential to use renewable and locally available fuels, such as landfill or sewage treatment waste gases, provides another attractive outlook. In Los Angeles, there are also many oil producing areas where the gas by-product can be utilized. In June 2000, the LADWP contracted with FCE to install and commission the precommercial 250kW MCFC power plant. The plant was delivered, installed, and began power production at the JFB in August 2001. The plant underwent manufacturer's field trials up for 18 months and was replace with a commercial plant in January 2003. In January 2001, the LADWP contracted with FCE to provide two additional 250kW MCFC power plants. These commercial plants began operations during mid-2003. The locations of these plants are at the Terminal Island Sewage Treatment Plant at the Los Angeles Harbor (for eventual operation on digester gas) and at the LADWP Main Street Service Center east of downtown Los Angeles. All three carbonate fuel cell plants received partial funding through the Department of Defense's Climate Change Fuel Cell Buydown Program. This report covers the technical evaluation and benefit-cost evaluation of the Main Street 250kW MCFC power plant during its first year of operation from September 2003 to August 2004. The data for the month of

  12. Development of molten-carbonate fuel-cell technology. Final report, February-December 1980

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    The objective of the work was to focus on the basic technology for producing molten carbonate fuel cell (MCFC) components. This included the development and fabrication of stable anode structures, preparation of lithiated nickel oxide cathodes, synthesis and characterization of a high surface area (gamma-lithium-aluminate) electrolyte support, pressurized cell testing and modeling of the overall electrolyte distribution within a cell to aid performance optimization of the different cell components. The electrode development program is highlighted by two successful 5000 hour bench-scale tests using stabilized anode structures. One of these provided better performance than in any previous state-of-the-art, bench-scale cell (865 mV at 115 mA/cm/sup 2/ under standard conditions). Pressurized testing at 10 atmosphere of a similar stabilized, high surface area, Ni/Co anode structure in a 300 cm/sup 2/ cell showed that the 160 mA/cm/sup 2/ performance goal of 850 mV on low Btu fuel (80% conversion) can be readily met. A study of the H/sub 2/S-effects on molten carbonate fuel cells showed that ERC's Ni/Co anode provided better tolerance than a Ni/Cr anode. Prelithiated nickel oxide plaques were prepared from materials made by a low temperature and a high temperature powder-production process. The methods for fabricating handleable cathodes of various thicknesses were also investigated. In electrolyte matrix development, accelerated out-of-cell and in-cell tests have confirmed the superior stability of ..gamma..-LiAlO/sub 2/.

  13. 1990 fuel cell seminar: Program and abstracts

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

  14. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  15. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  16. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  17. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  18. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  19. Fuel from Bacteria: Bioconversion of Carbon Dioxide to Biofuels by Facultatively Autotrophic Hydrogen Bacteria

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: Ohio State is genetically modifying bacteria to efficiently convert carbon dioxide directly into butanol, an alcohol that can be used directly as a fuel blend or converted to a hydrocarbon, which closely resembles a gasoline. Bacteria are typically capable of producing a certain amount of butanol before it becomes too toxic for the bacteria to survive. Ohio State is engineering a new strain of the bacteria that could produce up to 50% more butanol before it becomes too toxic for the bacteria to survive. Finding a way to produce more butanol more efficiently would significantly cut down on biofuel production costs and help make butanol cost competitive with gasoline. Ohio State is also engineering large tanks, or bioreactors, to grow the biofuel-producing bacteria in, and they are developing ways to efficiently recover biofuel from the tanks.

  20. ATR LEU Monolithic Foil-Type Fuel with Integral Cladding Burnable Absorber Neutronics Performance Evaluation

    SciTech Connect (OSTI)

    Gray Chang

    2012-03-01

    The Advanced Test Reactor (ATR), currently operating in the United States, is used for material testing at very high neutron fluxes. Powered with highly enriched uranium (HEU), the ATR has a maximum thermal power rating of 250 MWth. Because of the large test volumes located in high flux areas, the ATR is an ideal candidate for assessing the feasibility of converting HEU driven reactor cores to low-enriched uranium (LEU) cores. The burnable absorber - 10B, was added in the inner and outer plates to reduce the initial excess reactivity, and to improve the peak ratio of the inner/outer heat flux. The present work investigates the LEU Monolithic foil-type fuel with 10B Integral Cladding Burnable Absorber (ICBA) design and evaluates the subsequent neutronics operating effects of this proposed fuel designs. The proposed LEU fuel specification in this work is directly related to both the RERTR LEU Development Program and the Advanced Test Reactor (ATR) LEU Conversion Project at Idaho National Laboratory (INL).

  1. Molten carbonate fuel cell product design & improvement - 2nd quarter, 1996. Quarterly report, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1997-05-01

    The main objective of this project is to establish the commercial readiness of a molten carbonate fuel cell power plant for distributed power generation, cogeneration, and compressor station applications. This effort includes marketing, systems design and analysis, packaging and assembly, test facility development, and technology development, improvement, and verification.

  2. Molten carbonate fuel cell product design & improvement - 2nd quarter, 1995. Quarterly report, April 1--June 30, 1996

    SciTech Connect (OSTI)

    1997-05-01

    The primary objective of this project is to establish, by 1998, the commercial readiness of MW-class molten carbonate fuel cell power plants for distributed power generation, cogeneration, and compressor station applications. Tasks include system design and analysis, manufacturing, packaging and assembly, test facility development, and technology development, improvement, and verification.

  3. The Elephant in the Room: Dealing with Carbon Emissions from Synthetic Transportation Fuels Production

    SciTech Connect (OSTI)

    Parker, Graham B.; Dahowski, Robert T.

    2007-07-11

    Carbon dioxide (CO2), produced by conversion of hydrocarbons to energy, primarily via fossil fuel combustion, is one of the most ubiquitous and significant greenhouse gases (GHGs). Concerns over climate change precipitated by rising atmospheric GHG concentrations have prompted many industrialized nations to begin adopting limits on emissions to inhibit increases in atmospheric CO2 levels. The United Nations Framework Convention on Climate Change states as a key goal the stabilization of atmospheric CO2 at a level that prevents dangerous anthropogenic interference with the planets climate systems. This will require sharply reducing emissions growth rates in developing nations, and reducing CO2 emissions in the industrialized world to half current rates in the next 50 years. And ultimately, stabilization will require that annual emissions drop to almost zero.Recently, there has been interest in producing synthetic transportation fuels via coal-to-liquids (CTL) production, particularly in countries where there is an abundant supply of domestic coal, including the United States. This paper provides an overview of the current state of CTL technologies and deployment, a discussion of costs and technical requirements for mitigating the CO2 impacts associated with a CTL facility, and the challenges facing the CTL industry as it moves toward maturity.

  4. Effects of fuel type and equivalence ratios on the flickering of triple flames

    SciTech Connect (OSTI)

    Sahu, K.B.; Kundu, A.; Ganguly, R.; Datta, A.

    2009-02-15

    An experimental study has been conducted in axisymmetric, co-flowing triple flames with different equivalence ratios of the inner and outer reactant streams (2<{phi}{sub in}<3 and 0{<=}{phi}{sub out}<0.7). Different fuel combinations, like propane/propane, propane/methane or methane/methane in the inner and outer streams respectively, have been used in the experiments. The structures of the triple flames have been compared for the different fuel combinations and equivalence ratios. The conditions under which triple flames exhibit oscillation have been identified. During the oscillation, the non-premixed flame and the outer lean premixed flame flicker strongly, while the inner rich premixed flame remains more or less stable. The flickering frequency has been evaluated through image processing and fast Fourier transform (FFT) of the average pixel intensity of the image frames. It is observed that, for all the fuel combinations, the frequency decreases with the increase in the outer equivalence ratio, while it is relatively invariant with the change in the inner equivalence ratio. However, an increase in the inner equivalence ratio affects the structure of the flame by increasing the heights of the inner premixed flame and non-premixed flame and also enlarges the yellow soot-laden zone at the tip of the inner flame. A scaling analysis of the oscillating flames has been performed based on the measured parameters, which show a variation of Strouhal number (St) with Richardson number (Ri) as St {proportional_to} Ri{sup 0.5}. The fuel type is found to have no influence on this correlation. (author)

  5. Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications.

    SciTech Connect (OSTI)

    Swain; Greg M.

    2009-04-13

    The original funding under this project number was awarded for a period 12/1999 until 12/2002 under the project title Diamond and Hydrogenated Carbons for Advanced Batteries and Fuel Cells: Fundamental Studies and Applications. The project was extended until 06/2003 at which time a renewal proposal was awarded for a period 06/2003 until 06/2008 under the project title Metal/Diamond Composite Thin-Film Electrodes: New Carbon Supported Catalytic Electrodes. The work under DE-FG02-01ER15120 was initiated about the time the PI moved his research group from the Department of Chemistry at Utah State University to the Department of Chemistry at Michigan State University. This DOE-funded research was focused on (i) understanding structure-function relationships at boron-doped diamond thin-film electrodes, (ii) understanding metal phase formation on diamond thin films and developing electrochemical approaches for producing highly dispersed electrocatalyst particles (e.g., Pt) of small nominal particle size, (iii) studying the electrochemical activity of the electrocatalytic electrodes for hydrogen oxidation and oxygen reduction and (iv) conducting the initial synthesis of high surface area diamond powders and evaluating their electrical and electrochemical properties when mixed with a Teflon binder.

  6. Effects of spent fuel types on offsite consequences of hypothetical accidents

    SciTech Connect (OSTI)

    Courtney, J. C.; Dwight, C. C.; Lehto, M. A.

    2000-02-18

    Argonne National Laboratory (ANL) conducts experimental work on the development of waste forms suitable for several types of spent fuel at its facility on the Idaho National Engineering and Environmental Laboratory (INEEL) located 48 km West of Idaho Falls, ID. The objective of this paper is to compare the offsite radiological consequences of hypothetical accidents involving the various types of spent nuclear fuel handled in nonreactor nuclear facilities. The highest offsite total effective dose equivalents (TEDEs) are estimated at a receptor located about 5 km SSE of ANL facilities. Criticality safety considerations limit the amount of enriched uranium and plutonium that could be at risk in any given scenario. Heat generated by decay of fission products and actinides does not limit the masses of spent fuel within any given operation because the minimum time elapsed since fissions occurred in any form is at least five years. At cooling times of this magnitude, fewer than ten radionuclides account for 99% of the projected TEDE at offsite receptors for any credible accident. Elimination of all but the most important nuclides allows rapid assessments of offsite doses with little loss of accuracy. Since the ARF (airborne release fraction), RF (respirable fraction), LPF (leak path fraction) and atmospheric dilution factor ({chi}/Q) can vary by orders of magnitude, it is not productive to consider nuclides that contribute less than a few percent of the total dose. Therefore, only {sup 134}Cs, {sup 137}Cs-{sup 137m}Ba, and the actinides significantly influence the offsite radiological consequences of severe accidents. Even using highly conservative assumptions in estimating radiological consequences, they remain well below current Department of Energy guidelines for highly unlikely accidents.

  7. Molten carbonate fuel cell (MCFC) product development test. Annual report, September 1993--September 1994

    SciTech Connect (OSTI)

    1995-02-01

    M-C Power Corporation will design, fabricate, install, test and evaluate a 250 kW Proof-of-Concept Molten Carbonate Fuel Cell (MCFC) Power Plant. The plant is to be located at the Naval Air Station Miramar in San Diego, California. This report summarizes the technical progress that has occurred in conjunction with this project in 1994. M-C Power has completed the tape casting and sintering of cathodes and is proceeding with the tape casting and sintering of anodes for the first 250 cell stack. M-C Power and San Diego Gas and Electric relocated the fuel cell demonstration project to an alternate site at the Naval Air Station Miramar. For the new project location at the Naval Air Station Miramar, an Environmental Assessment has been prepared by the Department of Energy in compliance with the National Environmental Policy Act of 1969. The Environmental Assessment resulted in a categorical exclusion of the proposed action from all environmental permit requirements. Bechtel Corporation has completed the reformer process design coordination, a Process Description, the Pipe and Instrumentation Diagrams, a Design Criteria Document and General Project Requirement Document. Bechtel developed the requirements for soils investigation report and issued the following equipment bid packages to the suppliers for bids: Inverter, Reformer, Desulfurization Vessels, Hot Gas Recycle Blower, Heat Recovery Steam Generator, and Recycle Gas Cooler. SDG and E has secured necessary site permits, conducted soils investigations, and is working on the construction plan. They are in final negotiations with the US Navy on a site agreement. Site drawings are required for finalization of the agreement.

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Low Carbon Fuel Standard California's Low Carbon Fuel Standard (LCFS) Program requires a reduction in the carbon intensity of transportation fuels that are sold, supplied, or offered for sale in the state by a minimum of 10% by 2020. The California Air Resources Board (ARB) regulations require transportation fuel producers and importers to meet specified average carbon intensity requirements for fuel. In the regulations, carbon intensity reductions are based on reformulated gasoline mixed with

  9. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect (OSTI)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    . Other potential benefits of the demonstration include developing a passive technology for water treatment for trace metal and nutrient release reductions, using power plant by-products to improve coal mine land reclamation and carbon sequestration, developing wildlife habitat and green-space around production facilities, generating Total Maximum Daily Load (TMDL) credits for the use of process water, and producing wood products for use by the lumber and pulp and paper industry. Project activities conducted during the five year project period include: Assessing tree cultivation and other techniques used to sequester carbon; Project site assessment; Greenhouse studies to determine optimum plant species and by-product application; Designing, constructing, operating, monitoring, and evaluating the CCWESTRS system; and Reporting (ongoing). The ability of the system to sequester carbon will be the primary measure of effectiveness, measured by accessing survival and growth response of plants within the CCWESTRS. In addition, costs associated with design, construction, and monitoring will be evaluated and compared to projected benefits of other carbon sequestration technologies. The test plan involves the application of three levels each of two types of power plant by-products--three levels of FGD gypsum mulch, and three levels of ash pond irrigation water. This design produces nine treatment levels which are being tested with two species of hardwood trees (sweet gum and sycamore). The project is examining the effectiveness of applications of 0, 8-cm, and 15-cm thick gypsum mulch layers and 0, 13 cm, and 25 cm of coal fly ash water for irrigation. Each treatment combination is being replicated three times, resulting in a total of 54 treatment plots (3 FGD gypsum levels X 3 irrigation water levels x 2 tree species x 3 replicates). Survival and growth response of plant species in terms of sequestering carbon in plant material and soil will be the primary measure of effectiveness

  10. Cryogenic distillation: a fuel enrichment system for near-term tokamak-type D-T fusion reactors

    SciTech Connect (OSTI)

    Misra, B.; Davis, J.F.

    1980-02-01

    The successful operation and economic viability of deuterium-tritium- (D-T-) fueled tokamak-type commercial power fusion reactors will depend to a large extent on the development of reliable tritium-containment and fuel-recycle systems. Of the many operating steps in the fuel recycle scheme, separation or enrichment of the isotropic species of hydrogen by cryogenic distillation is one of the most important. A parametric investigation was carried out to study the effects of the various operating conditions and the composition of the spent fuel on the degree of separation. A computer program was developed for the design and analysis of a system of interconnected distillation columns for isotopic separation such that the requirements of near-term D-T-fueled reactors are met. The analytical results show that a distillation cascade consisting of four columns is capable of reprocessing spent fuel varying over a wide range of compositions to yield reinjection-grade fuel with essentially unlimited D/T ratio.

  11. Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering

    SciTech Connect (OSTI)

    M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov

    2007-07-01

    Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

  12. Materials issues in solid oxide fuel cell systems

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  13. Thin graphite bipolar plate with associated gaskets and carbon cloth flow-field for use in an ionomer membrane fuel cell

    DOE Patents [OSTI]

    Marchetti, George A.

    2003-01-03

    The present invention comprises a thin graphite plate with associated gaskets and pieces of carbon cloth that comprise a flow-field. The plate, gaskets and flow-field comprise a "plate and gasket assembly" for use in an ionomer membrane fuel cell, fuel cell stack or battery.

  14. Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report

    SciTech Connect (OSTI)

    Sinskey, Anthony J.; Worden, Robert Mark; Brigham, Christopher; Lu, Jingnan; Quimby, John Westlake; Gai, Claudia; Speth, Daan; Elliott, Sean; Fei, John Qiang; Bernardi, Amanda; Li, Sophia; Grunwald, Stephan; Grousseau, Estelle; Maiti, Soumen; Liu, Chole

    2013-12-16

    This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide

  15. DOE Fuel Cell Technologies Office Record 13010: Onboard Type IV Compressed Hydrogen Storage Systems - Current Performance and Cost

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Fuel Cell Technologies Office Record Record #: 13010 Date: June 11, 2013 Title: Onboard Type IV Compressed Hydrogen Storage Systems - Current Performance and Cost Originators: Scott McWhorter and Grace Ordaz Approved by: Sunita Satyapal Date: July 17, 2013 Item: This record summarizes the current status of the projected capacities and manufacturing costs of Type IV, 350- and 700-bar compressed hydrogen storage systems, storing 5.6 kg of usable hydrogen, for onboard light-duty automotive

  16. Molten carbonate fuel cell product development test. Final report, September 30, 1992--March 31, 1997

    SciTech Connect (OSTI)

    1997-12-31

    This report summarizes the work performed for manufacturing and demonstrating the performance of its 250-kW molten carbonate fuel cell (MCFC) stack in an integrated system at the Naval Air Station Miramar (NAS Miramar) located in San Diego, California. The stack constructed for the demonstration test at the NAS Miramar consisted of 250 cells. It was manufactured using M-C Power`s patented Internally Manifolded Heat Exchanger (IMHEX{reg_sign}) stack design. The demonstration test at NAS Miramar was designed to operate the 250-kW MCFC stack in a cogeneration mode. This test represented the first attempt to thermally integrate an MCFC stack in a cogeneration system. The test was started on January 10, 1997, and voluntarily terminated on May 12, 1997, after 2,350 hours of operation at temperatures above 1,100 F and at a pressure of three atmospheres. It produced 160 MWh of d.c. power and 346,000 lbs of 110 psig steam for export during 1,566 hours of on-load operations. The test demonstrated a d.c. power output of 206 kW. Most of the balance of the plant (BOP) equipment operated satisfactorily. However, the off-the-shelf automotive turbocharger used for supplying air to the plant failed on numerous occasions and the hot gas blower developed seal leakage problems which impacted continuous plant operations. Overall the demonstration test at NAS Miramar was successful in demonstrating many critical features of the IMHEX technology. Lessons learned from this test will be very useful for improving designs and operations for future MCFC power plants.

  17. Microbial production of multi-carbon chemicals and fuels from water and carbon dioxide using electric current

    DOE Patents [OSTI]

    Lovley, Derek R; Nevin, Kelly

    2015-11-03

    The invention provides systems and methods for generating organic compounds using carbon dioxide as a source of carbon and electrical current as an energy source. In one embodiment, a reaction cell is provided having a cathode electrode and an anode electrode that are connected to a source of electrical power, and which are separated by a permeable membrane. A biological film is provided on the cathode. The biological film comprises a bacterium that can accept electrons and that can convert carbon dioxide to a carbon-bearing compound and water in a cathode half-reaction. At the anode, water is decomposed to free molecular oxygen and solvated protons in an anode half-reaction. The half-reactions are driven by the application of electrical current from an external source. Compounds that have been produced include acetate, butanol, 2-oxobutyrate, propanol, ethanol, and formate.

  18. Enhanced air/fuel mixing for automotive Stirling engine turbulator-type combustors

    SciTech Connect (OSTI)

    Riecke, G.T.; Stotts, R.E.

    1992-02-25

    This patent describes a combustor for use in a Stirling engine and the like. It comprises: a combustor chamber; a fuel inlet couple to the chamber to inject fuel therein; a turbulator means disposed in the chambers downstream of the fuel inlet means for injecting combustion air into the chamber, the turbulator means being so positioned to cause a mixing of the combustion air and fuel injected in the chamber; diverter means for dividing the combustion air and creating a primary mixing zone downstream fa the primary mixing zone; and wherein the primary mixing zone comprises a fuel rich zone where combustion initiates and the secondary mixing zone has sufficient combustion air to complete combustion of the fuel.

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    State Agency Low Carbon Fuel Use Requirement Beginning January 1, 2017, at least 3% of the aggregate amount of bulk transportation fuel purchased by the state government must be from very low carbon transportation fuel sources. Beginning January 1, 2018, the required amount of very low carbon transportation fuel purchased will increase by 1% annually until January 1, 2024. Some exemptions may apply, as determined by the California Department of General Services (DGS). Very low carbon fuel is

  20. Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2001-01-01

    A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.

  1. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2001-03-27

    A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

  2. Table 2.6 Household End Uses: Fuel Types, Appliances, and Electronics, Selected Years, 1978-2009

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Household End Uses: Fuel Types, Appliances, and Electronics, Selected Years, 1978-2009 Appliance Year Change 1978 1979 1980 1981 1982 1984 1987 1990 1993 1997 2001 2005 2009 1980 to 2009 Total Households (millions) 77 78 82 83 84 86 91 94 97 101 107 111 114 32 Percent of Households<//td> Space Heating - Main Fuel 1 Natural Gas 55 55 55 56 57 55 55 55 53 52 55 52 50 -5 Electricity 2 16 17 18 17 16 17 20 23 26 29 29 30 35 17 Liquefied Petroleum Gases 4 5 5 4 5 5 5 5 5 5 5 5 5 0 Distillate

  3. In-pile post-DNB behavior of a nine-rod PWR-type fuel bundle

    SciTech Connect (OSTI)

    Gunnerson, F.S.; MacDonald, P.E.

    1980-01-01

    The results of an in-pile power-cooling-mismatch (PCM) test designed to investigate the behavior of a nine-rod, PWR-type fuel bundle under intermittent and sustained periods of high temperature film boiling operation are presented. Primary emphasis is placed on the DNB and post-DNB events including rod-to-rod interactions, return to nucleate boiling (RNB), and fuel rod failure. A comparison of the DNB behavior of the individual bundle rods with single-rod data obtained from previous PCM tests is also made.

  4. Alternative Fuels Data Center: Austin Lays Plans for Carbon-Neutral...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    ... GE Showcases Innovation in Alternative Fuel Vehicles July 15, 2015 Photo of a locomotive engine carrying passenger cars. New Hampshire Railway Makes Tracks With Biodiesel June 27, ...

  5. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  6. Impact Analysis of a Dipper-Type and Multi Spring-Type Fuel Rod Support Grid Assemblies in PWR

    SciTech Connect (OSTI)

    Song, K.N.; Yoon, K.H.; Park, K.J.; Park, G.J.; Kang, B.S.

    2002-07-01

    A spacer grid is one of the main structural components in a fuel assembly of a Pressurized light Water Reactor (PWR). It supports fuel rods, guides cooling water, and maintains geometry from external impact loads. A simulation is performed for the strength of a spacer grid under impact load. The critical impact load that leads to plastic deformation is identified by a free-fall test. A finite element model is established for the nonlinear simulation of the test. The simulation model is tuned based on the free-fall test. The model considers the aspects of welding and the contacts between components. Nonlinear finite element analysis is carried out by a software system called LS/DYNA3D. The results are discussed from a design viewpoint. (authors)

  7. Fuel cell market applications

    SciTech Connect (OSTI)

    Williams, M.C.

    1995-12-31

    This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

  8. Electronic Durability of Flexible Transparent Films from Type-Specific Single-Wall Carbon Nanotubes

    SciTech Connect (OSTI)

    Harris, J; Iyer, S; Bernhardt, A; Huh, JY; Hudson, S; Fagan, J; Hobbie, E.

    2011-12-11

    The coupling between mechanical flexibility and electronic performance is evaluated for thin films of metallic and semiconducting single-wall carbon nanotubes (SWCNTs) deposited on compliant supports. Percolated networks of type-purified SWCNTs are assembled as thin conducting coatings on elastic polymer substrates, and the sheet resistance is measured as a function of compression and cyclic strain through impedance spectroscopy. The wrinkling topography, microstructure and transparency of the films are independently characterized using optical microscopy, electron microscopy, and optical absorption spectroscopy. Thin films made from metallic SWCNTs show better durability as flexible transparent conductive coatings, which we attribute to a combination of superior mechanical performance and higher interfacial conductivity.

  9. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J. Roland; Tracy, C. Edwin; King, David E.; Stanley, James T.

    1994-01-01

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp.sup.3 -bonded diamond-type carbon films, comprising: a) providing a volatile hydrocarbon gas/H.sub.2 reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and b) directing a concentrated solar flux of from about 40 to about 60 watts/cm.sup.2 through said reactant mixture to produce substrate temperatures of about 750.degree. C. to about 950.degree. C. to activate deposition of the film on said substrate.

  10. Solar-induced chemical vapor deposition of diamond-type carbon films

    DOE Patents [OSTI]

    Pitts, J.R.; Tracy, C.E.; King, D.E.; Stanley, J.T.

    1994-09-13

    An improved chemical vapor deposition method for depositing transparent continuous coatings of sp[sup 3]-bonded diamond-type carbon films, comprises: (a) providing a volatile hydrocarbon gas/H[sub 2] reactant mixture in a cold wall vacuum/chemical vapor deposition chamber containing a suitable substrate for said films, at pressure of about 1 to 50 Torr; and (b) directing a concentrated solar flux of from about 40 to about 60 watts/cm[sup 2] through said reactant mixture to produce substrate temperatures of about 750 C to about 950 C to activate deposition of the film on said substrate. 11 figs.

  11. OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING

    SciTech Connect (OSTI)

    Dr. Ralph E. White; Dr. Branko N. Popov

    2002-04-01

    The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance of the two materials was investigated by electrochemical impedance spectroscopy and polarization studies. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. The model gives a good fit to the experimental data. The model has been used to analyze MCFC cathode performance under a wide range of operating conditions.

  12. Design criteria for an independent spent fuel storage installation (water pool type)

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This standard is intended to be used by those involved in the ownership and operation of an Independent Spent Fuel Storage Installation (ISFSI) in specifying the design requirements and by the designer in meeting the minimum design requirements of such installations. This standard continues the set of American National Standards on spent fuel storage design. Similar standards are: Design Objectives for Light Water Reactor Spent Fuel Storage Facilities at Nuclear Power Stations, N210-1976 (ANS-57.2); Design Objectives for Highly Radioactive Solid Material Handling and Storage Facilities in a Reprocessing Plant, ANSI N305-1975; and Guidelines for Evaluating Site-Related Parameters for an Independent Spent Fuel Storage Installation, ANSI/ANS-2.19-1981.

  13. Enhanced air/fuel mixing for automotive stirling engine turbulator-type combustors

    DOE Patents [OSTI]

    Riecke, George T.; Stotts, Robert E.

    1992-01-01

    The invention relates to the improved combustion of fuel in a combustion chamber of a stirling engine and the like by dividing combustion into primary and secondary combustion zones through the use of a diverter plate.

  14. Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G.; Mitchell, William L.; Bentley, Jeffrey M.; Thijssen, Johannes H. J.

    2002-01-01

    Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

  15. American National Standard: design criteria for an independent spent-fuel-storage installation (water pool type)

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This standard provides design criteria for systems and equipment of a facility for the receipt and storage of spent fuel from light water reactors. It contains requirements for the design of major buildings and structures including the shipping cask unloading and spent fuel storage pools, cask decontamination, unloading and loading areas, and the surrounding buildings which contain radwaste treatment, heating, ventilation and air conditioning, and other auxiliary systems. It contains requirements and recommendations for spent fuel storage racks, special equipment and area layout configurations, the pool structure and its integrity, pool water cleanup, ventilation, residual heat removal, radiation monitoring, fuel handling equipment, cask handling equipment, prevention of criticality, radwaste control and monitoring systems, quality assurance requirements, materials accountability, and physical security. Such an installation may be independent of both a nuclear power station and a reprocessing facility or located adjacent to any of these facilities in order to share selected support systems. Support systems shall not include a direct means of transferring fuel assemblies from the nuclear facility to the installation.

  16. Particles of spilled oil-absorbing carbon in contact with water

    DOE Patents [OSTI]

    Muradov, Nazim

    2011-03-29

    Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

  17. Pu-Zr alloy for high-temperature foil-type fuel

    DOE Patents [OSTI]

    McCuaig, Franklin D.

    1977-01-01

    A nuclear reactor fuel alloy consists essentially of from slightly greater than 7 to about 4 w/o zirconium, balance plutonium, and is characterized in that the alloy is castable and is rollable to thin foils. A preferred embodiment of about 7 w/o zirconium, balance plutonium, has a melting point substantially above the melting point of plutonium, is rollable to foils as thin as 0.0005 inch thick, and is compatible with cladding material when repeatedly cycled to temperatures above 650.degree. C. Neutron reflux densities across a reactor core can be determined with a high-temperature activation-measurement foil which consists of a fuel alloy foil core sandwiched and sealed between two cladding material jackets, the fuel alloy foil core being a 7 w/o zirconium, plutonium foil which is from 0.005 to 0.0005 inch thick.

  18. Facile synthesis of B-type carbonated nanoapatite with tailored microstructure

    SciTech Connect (OSTI)

    Gualtieri, Magdalena Lassinantti; Romagnoli, Marcello; Hanuskova, Miriam; Fabbri, Elena; Gualtieri, Alessandro F.

    2014-12-15

    Nanolime and a phosphate-based chelating agent were used to synthesize B-type carbonated apatite. Developed Rietveld refinement strategies allowed one to determine process yield, product crystallinity as well as structural (unit cell) and microstructural (size, strain) parameters. The effect of synthesis temperature (20–60 °C) as well as Ca/P ratio (1.5–2.5) and solid content (10–30 wt%) of the starting batch on these properties were investigated. FTIR, TEM and gas adsorption data provided supporting evidence. The process yield was 42–60 wt% and found to be governed by the Ca/P ratio. The purified products had high specific surface area (107–186 m{sup 2}/g) and crystallinity (76–97%). The unit cell parameters, correlated to the degree of structural carbonate, were sensitive to the Ca/P ratio. Instead, temperature governed the microstructural parameters. Less strained and larger crystals were obtained at higher temperatures. Long-term aging up to 6 months at 20 °C compensated for higher crystal growth kinetics at higher temperature. - Graphical abstract: Controlled synthesis of carbonated apatite at moderate temperatures using nanolime and sodiumhexametaphosphate as starting reagent. - Highlights: • Chemical synthesis of nano-sized apatite with tailored microstructure was performed. • Colloidal Ca(OH){sub 2} and a phosphorus-based chelating agents were used as reagents. • The method is simple and reproducible which facilitate industrial process scale-up. • Rietveld refinement strategies for product characterization were developed. • Rietveld analyses provided yield, microstructural and structure information.

  19. Preface: Forum on small molecules related to carbon-containing fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fujita, Etsuko; Goldman, Alan S.

    2015-06-01

    For millennia, human transportation was fueled largely through the consumption of biomass (by humans or domestic animals) and to a lesser extent by wind. The 19th century saw a major shift to coal-fueled transportation, with trains and ships powered by steam engines. A second major shift in the fueling of transportation occurred in the 20th century, this time to petroleum. This transition was not driven by the cost or ease of obtaining energy from oil wells vs. coal mines indeed, the cost of petroleum has always been higher than coal on a per-unit-energy basis but rather by themoretremendous technical advantages of powering engines with liquids, specifically liquid hydrocarbons.less

  20. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

    2005-06-01

    Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

  1. Cost-effectiveness of controlling emissions for various alternative-fuel vehicle types, with vehicle and fuel price subsidies estimated on the basis of monetary values of emission reductions

    SciTech Connect (OSTI)

    Wang, M.Q.

    1993-12-31

    Emission-control cost-effectiveness is estimated for ten alternative-fuel vehicle (AFV) types (i.e., vehicles fueled with reformulated gasoline, M85 flexible-fuel vehicles [FFVs], M100 FFVs, dedicated M85 vehicles, dedicated M100 vehicles, E85 FFVS, dual-fuel liquefied petroleum gas vehicles, dual-fuel compressed natural gas vehicles [CNGVs], dedicated CNGVs, and electric vehicles [EVs]). Given the assumptions made, CNGVs are found to be most cost-effective in controlling emissions and E85 FFVs to be least cost-effective, with the other vehicle types falling between these two. AFV cost-effectiveness is further calculated for various cases representing changes in costs of vehicles and fuels, AFV emission reductions, and baseline gasoline vehicle emissions, among other factors. Changes in these parameters can change cost-effectiveness dramatically. However, the rank of the ten AFV types according to their cost-effectiveness remains essentially unchanged. Based on assumed dollars-per-ton emission values and estimated AFV emission reductions, the per-vehicle monetary value of emission reductions is calculated for each AFV type. Calculated emission reduction values ranged from as little as $500 to as much as $40,000 per vehicle, depending on AFV type, dollar-per-ton emission values, and baseline gasoline vehicle emissions. Among the ten vehicle types, vehicles fueled with reformulated gasoline have the lowest per-vehicle value, while EVs have the highest per-vehicle value, reflecting the magnitude of emission reductions by these vehicle types. To translate the calculated per-vehicle emission reduction values to individual AFV users, AFV fuel or vehicle price subsidies are designed to be equal to AFV emission reduction values. The subsidies designed in this way are substantial. In fact, providing the subsidies to AFVs would change most AFV types from net cost increases to net cost decreases, relative to conventional gasoline vehicles.

  2. Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    58.8 64.9 67.0 67.7 63.6 54.6 Dash (-) No data reported. a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories...

  3. Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 60.5 64.5 68.5 69.4 65.4 55.2 a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories...

  4. Table 16. U.S. No. 2 Diesel Fuel Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    ... 51.6 56.2 59.3 60.4 56.2 45.4 a Includes low-sulfur diesel fuel only. b All end-user sales not included in the other end-user categories...

  5. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  6. Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide

    DOE Patents [OSTI]

    Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

    2000-09-26

    A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.

  7. Production and Optimization of Direct Coal Liquefaction derived Low Carbon-Footprint Transportation Fuels

    SciTech Connect (OSTI)

    Steven Markovich

    2010-06-30

    This report summarizes works conducted under DOE Contract No. DE-FC26-05NT42448. The work scope was divided into two categories - (a) experimental program to pretreat and refine a coal derived syncrude sample to meet transportation fuels requirements; (b) system analysis of a commercial scale direct coal liquefaction facility. The coal syncrude was derived from a bituminous coal by Headwaters CTL, while the refining study was carried out under a subcontract to Axens North America. The system analysis included H{sub 2} production cost via six different options, conceptual process design, utilities requirements, CO{sub 2} emission and overall plant economy. As part of the system analysis, impact of various H{sub 2} production options was evaluated. For consistence the comparison was carried out using the DOE H2A model. However, assumptions in the model were updated using Headwaters database. Results of Tier 2 jet fuel specifications evaluation by the Fuels & Energy Branch, US Air Force Research Laboratory (AFRL/RZPF) located at Wright Patterson Air Force Base (Ohio) are also discussed in this report.

  8. Fuel Cell Handbook, Fifth Edition

    SciTech Connect (OSTI)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed

  9. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh

  10. Filamentous carbon particles for cleaning oil spills and method of production

    DOE Patents [OSTI]

    Muradov, Nazim

    2010-04-06

    A compact hydrogen generator is coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. The hydrogen generator can be conveniently integrated with high temperature fuel cells to produce an efficient and self-contained source of electrical power.

  11. Influence of Electronic Type Purity on the Lithiation of Single-Walled Carbon Nanotubes

    SciTech Connect (OSTI)

    Jaber-Ansari, Laila; Iddir, Hakim; Curtiss, Larry A.; Hersam, Mark C.

    2014-03-25

    Single-walled carbon nanotubes (SWCNTs) have emerged as one of the leading additives for high-capacity nanocomposite lithium ion battery electrodes due to their ability to improve electrode conductivity, current collection efficiency, and charge/discharge rate for high power applications. However, since as-grown SWCNTs possess a distribution of physical and electronic structures, it is of high interest to determine which subpopulations of SWCNTs possess the highest lithiation capacity and to develop processing methods that can enhance the lithiation capacity of underperforming SWCNT species. Toward this end, SWCNT electronic type purity is controlled via density gradient ultracentrifugation, enabling a systematic study of the lithiation of SWCNTs as a function of metal versus semiconducting content. Experimentally, vacuum-filtered freestanding films of metallic SWCNTs are found to accommodate lithium with an order of magnitude higher capacity than their semiconducting counterparts, which is consistent with ab initio molecular dynamics and density functional theory calculations in the limit of isolated SWCNTs. In contrast, SWCNT film densification leads to the enhancement of the lithiation capacity of semiconducting SWCNTs to levels comparable to metallic SWCNTs, which is corroborated by theoretical calculations that show increased lithiation of semiconducting SWCNTs in the limit of small SWCNT*SWCNT spacing. Overall, these results will inform ongoing efforts to utilize SWCNTs as conductive additives in nanocomposite lithium ion battery electrodes.

  12. Fuel cell components and systems having carbon-containing electrically-conductive hollow fibers

    SciTech Connect (OSTI)

    Langry, Kevin C; Farmer, Joseph C

    2015-04-28

    A method, according to one embodiment, includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode.

  13. Possibilities of production of smokeless fuel via carbonization of Czech coals

    SciTech Connect (OSTI)

    Buchtele, J.; Straka, P.

    1995-12-01

    It was consumed 48 -51 % of hard coal (total output 28 - 30 Mt/year) in a long period for the production of coke. It appears to be anomaly in comparison with other coke producers in Europe and in the world, it was predeterminated by {open_quotes}steel conception{close_quotes} of state`s economics. The production of coke reached 10-11 Mt/year in former Czechoslovakia in the period 1970-1990. A considerable quantity 1.2 - 1.7 Mt/year of produced coke was utilized for heating. In comparison, 7-5.4 Mt coke/year was it in Poland for the heating. Al coke production is realized on the basis of Czech hard coals mined in the southern part of Upper Silesian Coal District. The coke production is operated in multi-chamber system with full recovery of chemical products (gas, raw tar, raw benzene, amonium etc.). The future trend of smokeless fuel production in Czech Republic makes for to the non-recovery coke oven, it means to two-product processes (coke + reduction gas, coke + electricity and so on). Jewell--Thompson coke oven (hard coal) and Salem oven (ignites) represent nonrecovery nowadays. The possibility of it`s application in Czech Republic are discussed. Jumbo coking reactor system (European project No. 500 to the Eureka programme) produces primarily metallurgical coke. The strong Clean Air Act suspends the production of smokeless fuel in multi-chamber system also in Czech Republic for the future period 2010-2020.

  14. Fuel cell components and systems having carbon-containing electrically-conductive hollow fibers

    DOE Patents [OSTI]

    Langry, Kevin C.; Farmer, Joseph C.

    2014-07-08

    According to one embodiment, a system includes a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst coupled to the hollow fiber, an anode extending along at least part of a length of the structure, and a cathode extending along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode. In another embodiment, a method includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure on an opposite side as the anode.

  15. Temperature modeling for analysis and design of the sintering furnance in HTR fuel type of ball

    SciTech Connect (OSTI)

    Saragi, Elfrida; Setiadji, Moch

    2013-09-09

    One of the factors that determine the safety of the operation of the sintering furnace fuel HTR ball is the temperature distribution in the ceramic tube furnace. The temperature distribution must be determined at design stage. The tube has a temperature of 1600 C at one end and about 40 C at the other end. The outside of the tube was cooled by air through natural convection. The tube is a furnace ceramic tube which its geometry are 0.08, 0.09 and 0.5 m correspondingly for the inner tube diameter, outer tube diameter and tube length. The temperature distribution of the tube is determined by the natural convection coefficient (NCF), which is difficult to be calculated manually. The determination of NCF includes the Grasshoff, Prandtl, and Nusselt numbers which is a function of the temperature difference between the surrounding air with the ceramic tube. If the temperature vary along the tube, the complexity of the calculations increases. Thus the proposed modeling was performed to determine the temperature distribution along the tube and heat transfer coefficient using a self-developed software which permit the design process easier.

  16. Flashback Characteristics of Syngas-Type Fuels Under Steady and Pulsating Conditions

    SciTech Connect (OSTI)

    Tim Lieuwen

    2007-09-30

    The objective of this project was to improve understanding and modeling of flashback, a significant issue in low emissions combustors containing high levels of hydrogen. Experimental studies were performed over a range of fuel compositions, flow velocities, reactant temperatures, and combustor pressures to study the factors leading to flashback. In addition, high speed imaging of the flashback phenomenon was obtained. One of the key conclusions of this study was that there existed multiple mechanisms which lead to flashback, each with different underlying parametric dependencies. Specifically, two mechanisms of 'flashback' were noted: rapid flashback into the premixer, presumably through the boundary layer, and movement of the static flame position upstream along the centerbody. The former and latter mechanisms were observed at high and low hydrogen concentrations. In the latter mechanism, flame temperature ratio, not flame speed, appeared to be the key parameter describing flashback tendencies. We suggested that this was due to an alteration of the vortex breakdown location by the adverse pressure gradient upstream of the flame, similar to the mechanism proposed by Sattelmayer and co-workers [1]. As such, a key conclusion here was that classical flashback scalings derived from, e.g., Bunsen flames, were not relevant for some parameter regimes found in swirling flames. In addition, it was found that in certain situations, pure H2 flames could not be stabilized, i.e., the flame would either flashback or blowout at ignition. This result could have significant implications on the development of future high hydrogen turbine systems.

  17. Comparison of Marine Microalgae Culture Systems for Fuels Production and Carbon Sequestration

    SciTech Connect (OSTI)

    Weissman, Joseph C; Polle, Juergen

    2006-05-30

    The dual problems of global fossil fuels supplies and global warming focus attention on the need to develop technologies that can provide large amounts of renewable fuels without contributing to global warming. The capture of power plant flue gas CO2 using microalgae cultures is one potential technology that could meet this objective. The central R&D issues are the design and operation of low-cost algal mass culture systems and the development of algal strains and cultivation techniques that can achieve very high biomass productivities. The major objective of this project was to develop mass culture techniques that could result in greatly increased biomass productivities, well above the about 50 metric tons per hectare per year (mt/ha/y) currently achievable. In this project, two marine microalgae species, the diatom Cyclotella sp.. and the green alga Tetraselmis sp., were cultivated on seawater in both open ponds and closed photo bioreactors, under a variety of different cultivation conditions. Simultaneous operation of the closed photo bioreactors and open ponds demonstrated similar productivities, under the same operating conditions. Thus the very expensive closed systems do not provide any major or inherent advantages in microalgae production over open ponds. Mutants of Cyclotella sp. were developed that exhibited reduced pigment content, which theoretically would result in greatly increased productivities when grown under full sunlight. However, in open ponds, these mutant strains exhibited similar productivities as the parental strains. The mutant strains all grew relatively slowly, suggesting that additional mutations masked whatever inherent potential for increased productivities may have resulted from the reduced pigment content. Research is still required to develop improved low pigment strains. When open pond cultures were exposed to intermittent sunlight, by partially covering the ponds with slats, solar conversion efficiencies increased dramatically

  18. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  19. Technology for the Recovery of Fuel and Adsorbent Carbons from Coal Burning Utility Ash Ponds and Landfills

    SciTech Connect (OSTI)

    J.G. Groppo; T.L. Robl

    2005-09-30

    lightweight aggregate and recover a high-grade fuel product. Spiral concentration provided acceptable grade lightweight aggregate with yields of only 10 to 20%. Incorporating a sieve bend into the process to recover coarse, porous ash particles from the outside race of the spirals increased aggregate yield to as high as 75%, however, the carbon content of the aggregate also increased. An opening size of 28 mesh on the sieve bend appeared to be sufficient. Lightweight concrete blocks (28 to 32 lbs) were produced from bottom ash and results show that acceptable strength could be attained with a cement/concrete ratio as low as 1/4. A mobile Proof-of-Concept (POC) field unit was designed and fabricated to meet the processing objectives of the project. The POC plant consisted of two trailer-mounted modules and was completely self sufficient with respect to power and water requirements. The POC unit was hauled to Coleman Station and operated at a feed rate of 2 tph. Results showed that the spirals operated similarly to previous pilot-scale operations and a 500 lb composite sample of coarse carbon was collected with a grade of 51.7% C or 7279 Btu/lb. Flotation results compared favorably with release analysis and 500 lbs of composite froth product was collected with a grade of 35% C or 4925 Btu/lb. The froth product was dewatered to 39% moisture with vacuum filtration. Pan pelletization and briquetting were evaluated as a means of minimizing handling concerns. Rotary pan pelletization produced uniform pellets with a compressive strength of 4 lbf without the use of any binder. Briquettes were produced by blending the coarse and fine carbon products at a ratio of 1:10, which is the proportion that the two products would be produced in a commercial operation. Using 3% lime as a binder produced the most desirable briquettes with respect to strength, attrition and drop testing. Additionally, the POC carbon products compared favorably with commercial activated carbon when used for removal

  20. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    SciTech Connect (OSTI)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Höflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; González-Gaitán, S.; Mason, R. E.; Folatelli, G.; Parent, E.; Gall, C.; Amanullah, R.; Anupama, G. C.; Arcavi, I.; Banerjee, D. P. K.; Beletsky, Y.; Blanc, G. A.; Bloom, J. S.; Brown, P. J.; Campillay, A.; Cao, Y.; De Cia, A.; Diamond, T.; Freedman, W. L.; Gonzalez, C.; Goobar, A.; Holmbo, S.; Howell, D. A.; Johansson, J.; Kasliwal, M. M.; Kirshner, R. P.; Krisciunas, K.; Kulkarni, S. R.; Maguire, K.; Milne, P. A.; Morrell, N.; Nugent, P. E.; Ofek, E. O.; Osip, D.; Palunas, P.; Perley, D. A.; Persson, S. E.; Piro, A. L.; Rabus, M.; Roth, M.; Schiefelbein, J. M.; Srivastav, S.; Sullivan, M.; Suntzeff, N. B.; Surace, J.; Woźniak, P. R.; Yaron, O.

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C Iλ1.0693 μm line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though the optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with Δm15(B) = 1.79 ± 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a “transitional” event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II λ0.6355 μm line, implying a long dark phase of ~4 days.

  1. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Höflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; González-Gaitán, S.; Mason, R. E.; et al

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C Iλ1.0693 μm line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though themore » optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with Δm15(B) = 1.79 ± 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a “transitional” event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II λ0.6355 μm line, implying a long dark phase of ~4 days.« less

  2. Strong near-infrared carbon in the Type Ia supernova iPTF13ebh

    SciTech Connect (OSTI)

    Hsiao, E. Y.; Burns, C. R.; Contreras, C.; Hflich, P.; Sand, D.; Marion, G. H.; Phillips, M. M.; Stritzinger, M.; Gonzlez-Gaitn, S.; Mason, R. E.; Folatelli, G.; Parent, E.; Gall, C.; Amanullah, R.; Anupama, G. C.; Arcavi, I.; Banerjee, D. P. K.; Beletsky, Y.; Blanc, G. A.; Bloom, J. S.; Brown, P. J.; Campillay, A.; Cao, Y.; De Cia, A.; Diamond, T.; Freedman, W. L.; Gonzalez, C.; Goobar, A.; Holmbo, S.; Howell, D. A.; Johansson, J.; Kasliwal, M. M.; Kirshner, R. P.; Krisciunas, K.; Kulkarni, S. R.; Maguire, K.; Milne, P. A.; Morrell, N.; Nugent, P. E.; Ofek, E. O.; Osip, D.; Palunas, P.; Perley, D. A.; Persson, S. E.; Piro, A. L.; Rabus, M.; Roth, M.; Schiefelbein, J. M.; Srivastav, S.; Sullivan, M.; Suntzeff, N. B.; Surace, J.; Wo?niak, P. R.; Yaron, O.

    2015-05-22

    We present near-infrared (NIR) time-series spectroscopy, as well as complementary ultraviolet (UV), optical, and NIR data, of the Type Ia supernova (SN Ia) iPTF13ebh, which was discovered within two days from the estimated time of explosion. The first NIR spectrum was taken merely 2.3 days after explosion and may be the earliest NIR spectrum yet obtained of a SN Ia. The most striking features in the spectrum are several NIR C I lines, and the C I?1.0693 ?m line is the strongest ever observed in a SN Ia. Interestingly, no strong optical C II counterparts were found, even though the optical spectroscopic time series began early and is densely cadenced. Except at the very early epochs, within a few days from the time of explosion, we show that the strong NIR C I compared to the weaker optical C II appears to be general in SNe Ia. iPTF13ebh is a fast decliner with ?m15(B) = 1.79 0.01, and its absolute magnitude obeys the linear part of the width-luminosity relation. It is therefore categorized as a transitional event, on the fast-declining end of normal SNe Ia as opposed to subluminous/91bg-like objects. iPTF13ebh shows NIR spectroscopic properties that are distinct from both the normal and subluminous/91bg-like classes, bridging the observed characteristics of the two classes. These NIR observations suggest that composition and density of the inner core are similar to that of 91bg-like events, and that it has a deep-reaching carbon burning layer that is not observed in more slowly declining SNe Ia. Furthermore, there is also a substantial difference between the explosion times inferred from the early-time light curve and the velocity evolution of the Si II ?0.6355 ?m line, implying a long dark phase of ~4 days.

  3. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Paul Chin; George W. Roberts; James J. Spivey

    2003-12-31

    Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal

  4. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  5. Irradiation Performance of U-Mo Alloy Based ‘Monolithic’ Plate-Type Fuel – Design Selection

    SciTech Connect (OSTI)

    A. B. Robinson; G. S. Chang; D. D. Keiser, Jr.; D. M. Wachs; D. L. Porter

    2009-08-01

    A down-selection process has been applied to the U-Mo fuel alloy based monolithic plate fuel design, supported by irradiation testing of small fuel plates containing various design parameters. The irradiation testing provided data on fuel performance issues such as swelling, fuel-cladding interaction (interdiffusion), blister formation at elevated temperatures, and fuel/cladding bond quality and effectiveness. U-10Mo (wt%) was selected as the fuel alloy of choice, accepting a somewhat lower uranium density for the benefits of phase stability. U-7Mo could be used, with a barrier, where the trade-off for uranium density is critical to nuclear performance. A zirconium foil barrier between fuel and cladding was chosen to provide a predictable, well-bonded, fuel-cladding interface, allowing little or no fuel-cladding interaction. The fuel plate testing conducted to inform this selection was based on the use of U-10Mo foils fabricated by hot co-rolling with a Zr foil. The foils were subsequently bonded to Al-6061 cladding by hot isostatic pressing or friction stir bonding.

  6. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    SciTech Connect (OSTI)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D.

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  7. Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons

    DOE Patents [OSTI]

    Muradov, Nazim Z.

    2011-08-23

    A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

  8. Flexible Fuel Vehicles: Providing a Renewable Fuel Choice, Vehicle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    than one type of fuel. FFVs can be fueled with unleaded gasoline, E85, or any combination of the two. Like conventional gasoline vehicles, FFVs have a single fuel tank, fuel ...

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Labeling Requirements Alternative fuel dispensers must be labeled with information to help consumers make informed decisions about fueling a vehicle, including the name of the fuel and the minimum percentage of the main component of the fuel. Labels may also list the percentage of other fuel components. This requirement applies to, but is not limited to, the following fuel types: methanol, denatured ethanol, and/or other alcohols; mixtures containing 85% or more by volume of

  10. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.