National Library of Energy BETA

Sample records for fuel oil sulfur

  1. Distillate Fuel Oil Sales for Residential Use

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use/ Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate Commercial - No. 2 Distillate Commercial - No. 2 Fuel Oil Commercial - Ultra Low Sulfur Diesel Commercial - Low Sulfur Diesel Commercial - High Sulfur Diesel Commercial - No. 4 Fuel Oil Commercial - Residual Fuel Oil Commercial - Kerosene Industrial - Distillate Fuel Oil Industrial - No. 1 Distillate Industrial - No. 2

  2. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  3. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  4. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  5. Adjusted Distillate Fuel Oil Sales for Residential Use

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use/ Product: Residential - Distillate Fuel Oil Residential - No. 1 Residential - No. 2 Residential - Kerosene Commercial - Distillate Fuel Oil Commercial - No. 1 Distillate Commercial - No. 2 Distillate Commercial - No. 2 Fuel Oil Commercial - Ultra Low Sulfur Diesel Commercial - Low Sulfur Diesel Commercial - High Sulfur Diesel Commercial - No. 4 Fuel Oil Commercial - Residual Fuel Oil Commercial - Kerosene Industrial - Distillate Fuel Oil Industrial - No. 1 Distillate Industrial - No. 2

  6. U.S. Residual Fuel Oil Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Residual Fuel Oil Residual F.O., Sulfur < 1% Residual F.O., Sulfur > 1% No. 4 Fuel Oil Download Series History Download Series History Definitions, Sources & Notes ...

  7. Residual Fuel Oil Sales to End Users Refiner Sales Volumes

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Residual Fuel Oil Residual F.O., Sulfur < 1% Residual F.O., Sulfur > 1% No. 4 Fuel Oil Period-Unit: Monthly - Thousand Gallons per Day Annual - Thousand Gallons per Day ...

  8. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  9. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  10. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  11. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  12. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  13. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Fuel Oil Consumption and Expenditures for Non-Mall Buildings, 2003" ,"All Buildings* Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  14. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Total Fuel Oil Consumption and Expenditures for All Buildings, 2003" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  15. LOW SULFUR HOME HEATING OIL DEMONSTRATION PROJECT SUMMARY REPORT.

    SciTech Connect (OSTI)

    BATEY, J.E.; MCDONALD, R.J.

    2005-06-01

    This project was funded by NYSERDA and has clearly demonstrated many advantages of using low sulfur content heating oil to provide thermal comfort in homes. Prior laboratory research in the United States and Canada had indicated a number of potential benefits of using lower sulfur (0.05%) heating oil. However, this prior research has not resulted in the widespread use of low sulfur fuel oil in the marketplace. The research project described in this report was conducted with the assistance of a well-established fuel oil marketer in New York State (NYS) and has provided clear proof of the many real-world advantages of marketing and using low sulfur content No. 2 fuel oil. The very positive experience of the participating marketer over the past three years has already helped to establish low sulfur heating oil as a viable option for many other fuel marketers. In large part, based on the initial findings of this project and the experience of the participating NYS oilheat marketer, the National Oilheat Research Alliance (NORA) has already fully supported a resolution calling for the voluntary use of low sulfur (0.05 percent) home heating oil nationwide. The NORA resolution has the goal of converting eighty percent of all oil-heated homes to the lower sulfur fuel (0.05 percent by weight) by the year 2007. The Oilheat Manufacturers Association (OMA) has also passed a resolution fully supporting the use of lower sulfur home heating oil in the equipment they manufacture. These are important endorsements by prominent national oil heat associations. Using lower sulfur heating oil substantially lowers boiler and furnace fouling rates. Laboratory studies had indicated an almost linear relationship between sulfur content in the oil and fouling rates. The completed NYSERDA project has verified past laboratory studies in over 1,000 occupied residential homes over the course of three heating seasons. In fact, the reduction in fouling rates so clearly demonstrated by this project is almost the same as predicted by past laboratory studies. Fouling deposition rates are reduced by a factor of two to three by using lower sulfur oil. This translates to a potential for substantial service cost savings by extending the interval between labor-intensive cleanings of the internal surfaces of the heating systems in these homes. In addition, the time required for annual service calls can be lowered, reducing service costs and customer inconvenience. The analyses conducted as part of this field demonstration project indicates that service costs can be reduced by up to $200 million a year nationwide by using lower sulfur oil and extending vacuum cleaning intervals depending on the labor costs and existing cleaning intervals. The ratio of cost savings to added fuel costs is economically attractive based on past fuel price differentials for the lower sulfur product. The ratio of cost savings to added costs vary widely as a function of hourly service rates and the additional cost for lower sulfur oil. For typical values, the expected benefit is a factor of two to four higher than the added fuel cost. This means that for every dollar spent on higher fuel cost, two to four dollars can be saved by lowered vacuum cleaning costs when the cleaning intervals are extended. Information contained in this report can be used by individual oil marketers to estimate the benefit to cost ratio for their specific applications. Sulfur oxide and nitrogen oxide air emissions are reduced substantially by using lower sulfur fuel oil in homes. Sulfur oxides emissions are lowered by 75 percent by switching from fuel 0.20 percent to 0.05 percent sulfur oil. This is a reduction of 63,000 tons a year nationwide. In New York State, sulfur oxide emissions are reduced by 13,000 tons a year. This translates to a total value of $12 million a year in Sulfur Oxide Emission Reduction Credits for an emission credit cost of $195 a ton. While this ''environmental cost'' dollar savings is smaller than the potential service costs reduction, it is very significant. It represents an important reduction in air pollutants that contribute directly to acid rain and other adverse impacts in the United States. When all air emissions are included, low sulfur content home heating oil and utility gas are virtually equal in their environmental impacts.

  16. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  17. Ultra Low Sulfur Home Heating Oil Demonstration Project

    SciTech Connect (OSTI)

    Batey, John E.; McDonald, Roger

    2015-09-30

    This Ultra Low Sulfur (ULS) Home Heating Oil Demonstration Project was funded by the New York State Energy Research and Development Authority (NYSERDA) and has successfully quantified the environmental and economic benefits of switching to ULS (15 PPM sulfur) heating oil. It advances a prior field study of Low Sulfur (500 ppm sulfur) heating oil funded by NYSERDA and laboratory research conducted by Brookhaven National Laboratory (BNL) and Canadian researchers. The sulfur oxide and particulate matter (PM) emissions are greatly reduced as are boiler cleaning costs through extending cleaning intervals. Both the sulfur oxide and PM emission rates are directly related to the fuel oil sulfur content. The sulfur oxide and PM emission rates approach near-zero levels by switching heating equipment to ULS fuel oil, and these emissions become comparable to heating equipment fired by natural gas. This demonstration project included an in-depth review and analysis of service records for both the ULS and control groups to determine any difference in the service needs for the two groups. The detailed service records for both groups were collected and analyzed and the results were entered into two spreadsheets that enabled a quantitative side-by-side comparison of equipment service for the entire duration of the ULS test project. The service frequency for the ULS and control group were very similar and did indicate increased service frequency for the ULS group. In fact, the service frequency with the ULS group was slightly less (7.5 percent) than the control group. The only exception was that three burner fuel pump required replacement for the ULS group and none were required for the control group.

  18. Fuel Oil Use in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    logo Return to: Manufacturing Home Page Fuel Oil Facts Oil Price Effect Fuel Switching Actual Fuel Switching Storage Capacity Fuel Oil Use in Manufacturing Why Look at Fuel Oil?...

  19. Vegetable oil fuel

    SciTech Connect (OSTI)

    Bartholomew, D.

    1981-04-01

    In this article, the future role of renewable agricultural resources in providing fuel is discussed. it was only during this century that U.S. farmers began to use petroleum as a fuel for tractors as opposed to forage crop as fuel for work animals. Now farmers may again turn to crops as fuel for agricultural production - the possible use of sunflower oil, soybean oil and rapeseed oil as substitutes for diesel fuel is discussed.

  20. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  1. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  2. Vegetable oil as fuel

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    A review is presented of various experiments undertaken over the past few years in the U.S. to test the performance of vegetable oils in diesel engines, mainly with a view to on-farm energy self-sufficiency. The USDA Northern Regional Research Center in Peoria, Illinois, is screening native U.S. plant species as potential fuel oil sources.

  3. Fuel-rich sulfur capture in a combustion environment

    SciTech Connect (OSTI)

    Lindgren, E.R.; Pershing, D.W.; Kirchgessner, D.A.; Drehmel, D.C.

    1992-01-01

    The paper discusses the use of a refactory-lined, natural gas furnace to study the fuel-rich sulfur capture reactions of calcium sorbents under typical combustion conditions. The fuel-rich sulfur species hydrogen sulfide and carbonyl sulfide were monitored in a nearly continuous fashion using a gas chromatograph equiped with a flame photometric detector and an automatic system that sampled every 30 seconds. Below the fuel-rich zone, 25% excess air was added, and the ultimate fuel-lean capture was simultaneously measured using a continuous sulfur dioxide monitor. Under fuel-rich conditions, high levels of sulfur capture were obtained, and calcium utilization increased with sulfur concentration. The ultimate lean capture was found to be weakly dependent on sulfur concentration and independent of the sulfur capture level obtained in the fuel-rich zone.

  4. Emissions characteristics of ethyl and methyl ester of rapeseed oil compared with low sulfur diesel control fuel in a chassis dynamometer test of a pickup truck

    SciTech Connect (OSTI)

    Peterson, C.; Reece, D.

    1996-05-01

    Comprehensive tests were performed on an on-road vehicle in cooperation with the Los Angeles County Metropolitan Transit Authority emissions test facility. All tests were with a transient chassis dynamometer. Tests included both a double arterial cycle of 768 s duration and an EPA heavy duty vehicle cycle of 1,060 s duration. The test vehicle was a 1994 pickup truck with a 5.9-L turbocharged and intercooled, direct injection diesel engine. Rapeseed methyl (RME) and ethyl esters (REE) and blends were compared with low sulfur diesel control fuel. Emissions data include all regulated emissions: hydrocarbons (HC), carbon monoxide (CO), carbon dioxide (CO{sub 2}), oxides of nitrogen (NO{sub x}), and particulate matter (PM). In these tests the average of 100% RME and 100% REE reduced HC (52.4%), CO (47.6%), NO{sub x} (10.0%), and increases in CO{sub 2} (0.9%) and PM (9.9%) compared to the diesel control fuel. Also, 100% REE reduced HC (8.7%), CO (4.3%), and NO{sub x} (3.4%) compared to 100% RME. 33 refs., 1 figs., 8 tabs.

  5. Sulfur capture by oil shale ashes under atmospheric and pressurized FBC conditions

    SciTech Connect (OSTI)

    Yrjas, K.P.; Hupa, M. [Aabo Akademi Univ., Turku (Finland). Dept. of Chemical Engineering; Kuelaots, I.; Ots, A. [Tallinn Technical Univ. (Estonia). Thermal Engineering Dept.

    1995-12-31

    When oil shale contains large quantities of limestone, a significant auto-absorption of sulfur is possible under suitable conditions. The sulfur capture by oil shale ashes has been studied using a pressurized thermogravimetric apparatus. The chosen experimental conditions were typical for atmospheric and pressurized fluidized bed combustion. The Ca/S molar ratios in the two oil shales studied were 8 (Estonian) and 10 (Israeli). The samples were first burned in a gas atmosphere containing O{sub 2} and N{sub 2} (and CO{sub 2} if pressurized). After the combustion step, SO{sub 2} was added and sulfation started. The results with the oil shales were compared to those obtained with an oil shale cyclone ash from the Narva power plant in Estonia. In general, the results from the sulfur capture experiments under both atmospheric and pressurized conditions showed that the oil shale cannot only capture its own sulfur but also significant amounts of additional sulfur of another fuel if the fuels are mixed together. For example from the runs at atmospheric pressure, the conversion of CaO to CaSO{sub 4} was about 70% for Israeli oil shale and about 55% for Estonian oil shale (850 C). For the cyclone ash the corresponding conversion was about 20%. In comparison it could be mentioned that under the same conditions the conversions of natural limestones are about 30%. The reason the cyclone ash was a poor sulfur absorbent was probably due to its temperature history. In Narva the oil shale was burned at a significantly higher temperature (1,400 C) than was used in the experiments (750 C and 850 C). This caused the ash to sinter and the reactive surface area of the cyclone ash was therefore decreased.

  6. DOE Will Convert Northeast Home Heating Oil Reserve to Ultra Low Sulfur Distillate

    Broader source: Energy.gov [DOE]

    The current inventory of the Northeast Home Heating Oil Reserve will be converted to cleaner burning ultra low sulfur distillate to comply with new, more stringent fuel standards by some Northeastern states, the U.S. Department of Energy said today.

  7. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G

    2013-08-13

    A system for adding sulfur to a reformate stream feeding a fuel cell stack, having a sulfur source for providing sulfur to the reformate stream and a metering device in fluid connection with the sulfur source and the reformate stream. The metering device injects sulfur from the sulfur source to the reformate stream at a predetermined rate, thereby providing a conditioned reformate stream to the fuel cell stack. The system provides a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  8. Compare All CBECS Activities: Fuel Oil Use

    Gasoline and Diesel Fuel Update (EIA)

    Fuel Oil Use Compare Activities by ... Fuel Oil Use Total Fuel Oil Consumption by Building Type Commercial buildings in the U.S. used a total of approximately 1.3 billion gallons...

  9. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    in this table do not include enclosed malls and strip malls. In the 1999 CBECS, total fuel oil consumption in malls was not statistically significant. (*)Value rounds to zero...

  10. Removal of nitrogen and sulfur from oil-shale

    SciTech Connect (OSTI)

    Olmstead, W.N.

    1986-01-28

    This patent describes a process for enhancing the removal of nitrogen and sulfur from oil-shale. The process consists of: (a) contacting the oil-shale with a sufficient amount of an aqueous base solution comprised of at least a stoichiometric amount of one or more alkali metal or alkaline-earth metal hydroxides based on the total amount of nitrogen and sulfur present in the oil-shale. Also necessary is an amount sufficient to form a two-phase liquid, solid system, a temperature from about 50/sup 0/C to about 350/sup 0/C., and pressures sufficient to maintain the solution in liquid form; (b) separating the effluents from the treated oil-shale, wherein the resulting liquid effluent contains nitrogen moieties and sulfur moieties from the oil-shale and any resulting gaseous effluent contains nitrogen moieties from the oil-shale, and (c) converting organic material of the treated oil-shale to shale-oil at a temperature from about 450/sup 0/C to about 550/sup 0/C.

  11. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  12. System for adding sulfur to a fuel cell stack system for improved fuel cell stability

    DOE Patents [OSTI]

    Mukerjee, Subhasish; Haltiner, Jr., Karl J; Weissman, Jeffrey G.

    2012-03-06

    A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

  13. U.S. Sales to End Users Refiner Residual Fuel Oil and No. 4 Fuel Sales

    U.S. Energy Information Administration (EIA) Indexed Site

    Volumes 4,546.1 3,741.4 4,403.1 3,994.1 4,103.1 4,101.4 1983-2016 Sulfur Less Than or Equal to 1% W NA W W W NA 1983-2016 Sulfur Greater Than 1% W 2,878.7 W W W 3,613.7 1983-2016 No. 4 Fuel Oil W - - - W -

  14. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  15. "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas...

    U.S. Energy Information Administration (EIA) Indexed Site

    7.4;" " Unit: Percents." " ",," "," ",," "," " ,,"Residual","Distillate",,"LPG and" "Economic","Electricity","Fuel Oil","Fuel Oil(b)","Natural Gas(c)","NGL(d)","Coal" ...

  16. Process for removal of sulfur compounds from fuel gases

    DOE Patents [OSTI]

    Moore, Raymond H.; Stegen, Gary E.

    1978-01-01

    Fuel gases such as those produced in the gasification of coal are stripped of sulfur compounds and particulate matter by contact with molten metal salt. The fuel gas and salt are intimately mixed by passage through a venturi or other constriction in which the fuel gas entrains the molten salt as dispersed droplets to a gas-liquid separator. The separated molten salt is divided into a major and a minor flow portion with the minor flow portion passing on to a regenerator in which it is contacted with steam and carbon dioxide as strip gas to remove sulfur compounds. The strip gas is further processed to recover sulfur. The depleted, minor flow portion of salt is passed again into contact with the fuel gas for further sulfur removal from the gas. The sulfur depleted, fuel gas then flows through a solid absorbent for removal of salt droplets. The minor flow portion of the molten salt is then recombined with the major flow portion for feed to the venturi.

  17. Oil Shale and Other Unconventional Fuels Activities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Reserves Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on ...

  18. Fuel oil and kerosene sales 1997

    SciTech Connect (OSTI)

    1998-08-01

    The Fuel Oil and Kerosene Sales 1997 report provides information, illustrations and state-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. 24 tabs.

  19. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  20. Fuel oil and kerosene sales 1996

    SciTech Connect (OSTI)

    1997-08-01

    The Fuel Oil and Kerosene Sales 1996 report provides information, illustrations and State-level statistical data on end-use sales of kerosene; No. 1, No. 2, and No. 4 distillate fuel oil; and residual fuel oil. State-level kerosene sales include volumes for residential, commercial, industrial, farm, and all other uses. State-level distillate sales include volumes for residential, commercial, industrial, oil company, railroad, vessel bunkering, military, electric utility, farm, on-highway, off highway construction, and other uses. State-level residual fuel sales include volumes for commercial, industrial, oil company, vessel bunkering, military, electric utility, and other uses. The Petroleum Marketing Division, Office of Oil and Gas, Energy Information Administration ensures the accuracy, quality, and confidentiality of the published data in the Fuel Oil and Kerosene Sales 1996. 24 tabs.

  1. U.S. Sales for Resale Refiner Residual Fuel Oil and No. 4 Fuel Sales

    U.S. Energy Information Administration (EIA) Indexed Site

    Volumes 8,143.0 8,165.8 8,005.5 8,881.1 9,292.6 9,209.8 1983-2016 Sulfur Less Than or Equal to 1% 899.6 1,177.6 1,165.0 557.6 977.1 1,152.2 1983-2016 Sulfur Greater Than 1% 7,243.4 6,988.2 6,840.5 8,323.5 8,315.6 8,057.6 1983-2016 No. 4 Fuel Oil 141.3 W W 128.8 166.0 W

  2. Straight Vegetable Oil as a Diesel Fuel?

    SciTech Connect (OSTI)

    2014-01-01

    Biodiesel, a renewable fuel produced from animal fats or vegetable oils, is popular among many vehicle owners and fleet managers seeking to reduce emissions and support U.S. energy security. Questions sometimes arise about the viability of fueling vehicles with straight vegetable oil (SVO), or waste oils from cooking and other processes, without intermediate processing. But SVO and waste oils differ from biodiesel (and conventional diesel) in some important ways and are generally not considered acceptable vehicle fuels for large-scale or long-term use.

  3. Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.; Hawk, Jeffrey A.

    2005-01-01

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

  4. Straight Vegetable Oil as a Diesel Fuel? (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-05-01

    Discusses the use of straight vegetable oil as a diesel fuel and the use of biodiesel as a transportation fuel.

  5. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1997 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  6. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    Content, Sales Type, and PAD District 242 Energy Information Administration Petroleum Marketing Annual 1996 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  7. Fuel oil and kerosene sales 1995

    SciTech Connect (OSTI)

    1996-09-01

    This publication contains the 1995 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the seventh year that the survey data have appeared in a separate publication. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the product supplied volumes published in the Petroleum Supply Annual (PSA). 24 tabs.

  8. Fuel Oil and Kerosene Sales 2007

    U.S. Energy Information Administration (EIA) Indexed Site

    national level are provided in summary tables. For Fuel Oil and Kerosene Sales on the Internet, access EIA's home page at http:www.eia.doe.gov. Internet Addresses: E-Mail:...

  9. Fuel oil and kerosene sales 1993

    SciTech Connect (OSTI)

    Not Available

    1994-10-03

    This publication contains the 1993 survey results of the ``Annual Fuel Oil and Kerosene, Sales Report`` (Form EIA-821). This is the fifth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA) for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1993 edition marks the 10th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the products supplied volumes published in the Petroleum Supply Annual (PSA).

  10. Fuel oil and kerosene sales 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29

    This publication contains the 1992 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the fourth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA) for reference year 1988 and the Petroleum Marketing Monthly (PMM for reference years 1984 through 1987. The 1992 edition marks the ninth annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Except for the kerosene and on-highway diesel information, data presented in Tables 1 through 12 (Sales of Fuel Oil and Kerosene) present results of the EIA-821 survey. Tables 13 through 24 (Adjusted Sales of Fuel Oil and Kerosene) include volumes that are based on the EIA-821 survey but have been adjusted to equal the products supplied volumes published in the Petroleum Supply Annual (PSA).

  11. Fuel oil and kerosene sales 1994

    SciTech Connect (OSTI)

    1995-09-27

    This publication contains the 1994 survey results of the ``Annual Fuel Oil and Kerosene Sales Report`` (Form EIA-821). This is the sixth year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA)for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. The 1994 edition marks the 11th annual presentation of the results of the ongoing ``Annual Fuel Oil and Kerosene Sales Report`` survey. Distillate and residual fuel oil sales continued to move in opposite directions during 1994. Distillate sales rose for the third year in a row, due to a growing economy. Residual fuel oil sales, on the other hand, declined for the sixth year in a row, due to competitive natural gas prices, and a warmer heating season than in 1993. Distillate fuel oil sales increased 4.4 percent while residual fuel oil sales declined 1.6 percent. Kerosene sales decreased 1.4 percent in 1994.

  12. Oil Shale and Other Unconventional Fuels Activities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Reserves » Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. It is generally agreed that worldwide petroleum supply will eventually reach its productive limit, peak, and begin a

  13. Rocky Mountain (PADD 4) Total Crude Oil and Products Imports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate ... Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur ...

  14. Peanut varieties: potential for fuel oil

    SciTech Connect (OSTI)

    Hammons, R.O.

    1981-01-01

    Research is beginning in farm crushing of peanuts into fuel oil, the high-protein residue being used as livestock feed. Thirty peanut genotypes were investigated for oil and protein yields in field trials in Georgia. For 11 varieties in an irrigated test, mean oil contents (dry base) were in the 49.7-52.7% range, and the level of protein was in the 22.60-26.70% range. Wider variations in oil and protein contents were found in 19 other genotypes selected for possible use as an oil crop. Breeding for high oil yield has not been practiced in US peanut breeding programs. Convergent improvement to attain higher levels of oil content, shell-out percentage, and stable yield will require 6-10 generations of crossing, backcrossing, selection, and testing.

  15. Method of burning sulfur-containing fuels in a fluidized bed boiler

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A method of burning a sulfur-containing fuel in a fluidized bed of sulfur oxide sorbent wherein the overall utilization of sulfur oxide sorbent is increased by comminuting the bed drain solids to a smaller average particle size, preferably on the order of 50 microns, and reinjecting the comminuted bed drain solids into the bed. In comminuting the bed drain solids, particles of spent sulfur sorbent contained therein are fractured thereby exposing unreacted sorbent surface. Upon reinjecting the comminuted bed drain solids into the bed, the newly-exposed unreacted sorbent surface is available for sulfur oxide sorption, thereby increasing overall sorbent utilization.

  16. Table 4b. Relative Standard Errors for Total Fuel Oil Consumption...

    Gasoline and Diesel Fuel Update (EIA)

    4b. Relative Standard Errors for Total Fuel Oil Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Fuel Oil (thousand) Total Fuel Oil...

  17. Table 4a. Total Fuel Oil Consumption per Effective Occupied Square...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Table 4a. Total Fuel Oil Consumption per Effective Occupied Square Foot, 1992 Building Characteristics All Buildings Using Fuel Oil (thousand) Total Fuel Oil Consumption (trillion...

  18. Fuel Oil and Kerosene Sales 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Oil and Kerosene Sales 2014 December 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Fuel Oil and Kerosene Sales 2014 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of approval by any other officer or employee of the United States

  19. "Code(a)","End Use","for Electricity(b)","Fuel Oil","Diesel Fuel...

    U.S. Energy Information Administration (EIA) Indexed Site

    "," ",,,"Fuel Oil",,,"Coal" "NAICS"," ","Net Demand","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End Use","for Electricity(b)","Fuel Oil","Diesel Fuel(c)","Natural ...

  20. "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    ,,,"Distillate" ,,,"Fuel Oil",,,"Coal" ,"Net Demand","Residual","and",,"LPG and","(excluding Coal" "End Use","for Electricity(a)","Fuel Oil","Diesel Fuel(b)","Natural ...

  1. EIA Estimates of Crude Oil and Liquid Fuels Supply Disruptions

    Reports and Publications (EIA)

    2013-01-01

    Short-Term Energy Outlook Supplement: Energy Information Administration estimates of crude oil and liquid fuels supply disruptions

  2. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    57.8 42.0 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1998 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  3. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    62.6 47.4 See footnotes at end of table. 200 Energy Information AdministrationPetroleum Marketing Annual 1999 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  4. Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales...

    U.S. Energy Information Administration (EIA) Indexed Site

    51.8 See footnotes at end of table. 242 Energy Information Administration Petroleum Marketing Annual 1995 Table 41. No. 2 Diesel Fuel Prices by Sulfur Content, Sales Type,...

  5. Demand, Supply, and Price Outlook for Low-Sulfur Diesel Fuel

    Reports and Publications (EIA)

    1993-01-01

    The Clean Air Act Amendments of 1990 established a new, sharply lower standard for the maximum sulfur content of on-highway diesel fuel, to take effect October 1, 1993.

  6. Fuel oil and kerosene sales, 1990

    SciTech Connect (OSTI)

    Not Available

    1991-10-10

    Sales data is presented for kerosene and fuel oils. This is the second year that the survey data have appeared in a separate publication. Prior to the 1989 report, the statistics appeared in the Petroleum Marketing Annual (PMA) for reference year 1988 and the Petroleum Marketing Monthly (PMM) for reference years 1984 through 1987. 4 figs., 24 tabs.

  7. Residual Fuel Oil Prices, Average - Sales to End Users

    U.S. Energy Information Administration (EIA) Indexed Site

    Product/Sales Type: Residual Fuel, Average - Sales to End Users Residual Fuel, Average - Sales for Resale Sulfur Less Than or Equal to 1% - Sales to End Users Sulfur Less Than or Equal to 1% - Sales for Resale Sulfur Greater Than 1% - Sales to End Users Sulfur Greater Than 1% - Sales for Resale Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product/Sales Type Area Sep-15 Oct-15 Nov-15 Dec-15

  8. Vegetable oils as fuel alternatives - symposium overview

    SciTech Connect (OSTI)

    Pryde, E.H.

    1984-10-01

    Several encouraging statements can be made about the use of vegetable oil products as fuel as a result of the information presented in these symposium papers. Vegetable oil ester fuels have the greatest promise, but further engine endurance tests will be required. These can be carried out best by the engine manufacturers. Microemulsions appear to have promise, but more research and engine testing will be necessary before performance equivalent to the ester fuels can be developed. Such research effort can be justified because microemulsification is a rather uncomplicated physical process and might be adaptable to on-farm operations, which would be doubtful for the more involved transesterfication process. Although some answers have been provided by this symposium, others are still not available; engine testing is continuing throughout the world particularly in those countries that do not have access to petroleum. 9 references.

  9. Update on Transition to Ultra-Low-Sulfur Diesel Fuel (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    On November 8, 2005, the Environmental Protection Agency (EPA) Administrator signed a direct final rule that will shift the retail compliance date for offering ultra-low sulfur diesel (ULSD) for highway use from September 1, 2006, to October 15, 2006. The change will allow more time for retail outlets and terminals to comply with the new 15 parts per million (ppm) sulfur standard, providing time for entities in the diesel fuel distribution system to flush higher sulfur fuel out of the system during the transition. Terminals will have until September 1, 2006, to complete their transitions to ULSD. The previous deadline was July 15, 2006.

  10. ,"Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities...

    U.S. Energy Information Administration (EIA) Indexed Site

    Weighted Average Refinery Crude Oil Input Qualities",16,"Monthly","22016","1151985" ,"Release Date:","4292016" ,"Next Release Date:","5312016" ,"Excel File ...

  11. Diesel Emission Control -- Sulfur Effects (DECSE) Program; Phase I Interim Date Report No. 3: Diesel Fuel Sulfur Effects on Particulate Matter Emissions

    SciTech Connect (OSTI)

    DOE; ORNL; NREL; EMA; MECA

    1999-11-15

    The Diesel Emission Control-Sulfur Effects (DECSE) is a joint government/industry program to determine the impact of diesel fuel sulfur levels on emission control systems whose use could lower emissions of nitrogen oxides (NO{sub x}) and particulate matter (PM) from on-highway trucks in the 2002--2004 model years. Phase 1 of the program was developed with the following objectives in mind: (1) evaluate the effects of varying the level of sulfur content in the fuel on the emission reduction performance of four emission control technologies; and (2) measure and compare the effects of up to 250 hours of aging on selected devices for multiple levels of fuel sulfur content. This interim report covers the effects of diesel fuel sulfur level on particulate matter emissions for four technologies.

  12. Major Fuels","Electricity","Natural Gas","Fuel Oil","District...

    U.S. Energy Information Administration (EIA) Indexed Site

    (million square feet)","Total of Major Fuels","Electricity","Natural Gas","Fuel Oil","District Heat" "All Buildings ...",4657,67338,81552,66424,10...

  13. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  14. Major Fuels","Electricity",,"Natural Gas","Fuel Oil","District

    U.S. Energy Information Administration (EIA) Indexed Site

    of Buildings (thousand)","Floorspace (million square feet)","Sum of Major Fuels","Electricity",,"Natural Gas","Fuel Oil","District Heat" ,,,,"Primary","Site" "All Buildings...

  15. Method to improve lubricity of low-sulfur diesel and gasoline fuels

    DOE Patents [OSTI]

    Erdemir, Ali

    2004-08-31

    A method for providing lubricity in fuels and lubricants includes adding a boron compound to a fuel or lubricant to provide a boron-containing fuel or lubricant. The fuel or lubricant may contain a boron compound at a concentration between about 30 ppm and about 3,000 ppm and a sulfur concentration of less than about 500 ppm. A method of powering an engine to minimize wear, by burning a fuel containing boron compounds. The boron compounds include compound that provide boric acid and/or BO.sub.3 ions or monomers to the fuel or lubricant.

  16. Sulfur dioxide capture in the combustion of mixtures of lime, refuse-derived fuel, and coal

    SciTech Connect (OSTI)

    Churney, K.L.; Buckley, T.J. . Center for Chemical Technology)

    1990-06-01

    Chlorine and sulfur mass balance studies have been carried out in the combustion of mixtures of lime, refuse-derived fuel, and coal in the NIST multikilogram capacity batch combustor. The catalytic effect of manganese dioxide on the trapping of sulfur dioxide by lime was examined. Under our conditions, only 4% of the chlorine was trapped in the ash and no effect of manganese dioxide was observed. Between 42 and 14% of the total sulfur was trapped in the ash, depending upon the lime concentration. The effect of manganese dioxide on sulfur capture was not detectable. The temperature of the ash was estimated to be near 1200{degrees}C, which was in agreement with that calculated from sulfur dioxide capture thermodynamics. 10 refs., 12 figs., 10 tabs.

  17. Ultra-low Sulfur Reduction Emission Control Device/Development of an On-board Fuel Sulfur Trap

    SciTech Connect (OSTI)

    Rohrbach, Ron; Barron, Ann

    2008-07-31

    Honeywell has completed working on a multiyear program to develop and demonstrate proof-of-concept for an 'on-vehicle' desulfurization fuel filter for both light duty and heavy-duty diesel engines. Integration of the filter into the vehicle fuel system will reduce the adverse effects sulfur has on post combustion emission control devices such as NOx adsorbers. The NOx adsorber may be required to meet the proposed new EPA Tier II and '2007-Rule' emission standards. The proposed filter concept is based on Honeywell's reactive filtration technology and experience in liquids handling and conditioning. A regeneration and recycling plan for the spent filters was also examined. We have chosen to develop and demonstrate this technology based on criteria set forth for a heavy duty CIDI engine system because it represents a more challenging set of conditions of service intervals and overall fuel usage over light duty systems. In the second phase of the program a light duty diesel engine test was also demonstrated. Further, technology developed under this proposal would also have application for the use of liquid based fuels for fuel cell power generation. The program consisted of four phases. Phase I focused on developing a concept design and analysis and resolution of technical barriers concerning removal of sulfur-containing species in low sulfur fuels. In Phase II concentrated on prototype filter design and preparation followed by qualification testing of this component in a fuel line application. Phase III studied life cycle and regeneration options for the spent filter. Phase IV focused on efficacy and benefits in the desulfation steps of a NOx adsorber on both a heavy and light duty engine. The project team included a number of partners, with Honeywell International as the prime contractor. The partners include an emission control technology developer (Honeywell International), a fuel technology developer (Marathon Ashland Petroleum), a catalyst technology developer (Johnson Matthey), a CIDI engine manufacturer (Navistar Inc. (formerly International Truck & Engine Corporation) and Mack Trucks Inc.), and filter recycler (American Wastes Industries).

  18. Evaluation of Gas, Oil and Wood Pellet Fueled Residential Heating System Emissions Characteristics

    SciTech Connect (OSTI)

    McDonald, R.

    2009-12-01

    This study has measured the emissions from a wide range of heating equipment burning different fuels including several liquid fuel options, utility supplied natural gas and wood pellet resources. The major effort was placed on generating a database for the mass emission rate of fine particulates (PM 2.5) for the various fuel types studied. The fine particulates or PM 2.5 (less than 2.5 microns in size) were measured using a dilution tunnel technique following the method described in US EPA CTM-039. The PM 2.5 emission results are expressed in several units for the benefit of scientists, engineers and administrators. The measurements of gaseous emissions of O{sub 2}, CO{sub 2}, CO, NO{sub x} and SO{sub 2} were made using a combustion analyzer based on electrochemical cells These measurements are presented for each of the residential heating systems tested. This analyzer also provides a steady state efficiency based on stack gas and temperature measurements and these values are included in the report. The gaseous results are within the ranges expected from prior emission studies with the enhancement of expanding these measurements to fuels not available to earlier researchers. Based on measured excess air levels and ultimate analysis of the fuel's chemical composition the gaseous emission results are as expected and fall within the range provided for emission factors contained in the US-EPA AP 42, Emission Factors Volume I, Fifth Edition. Since there were no unexpected findings in these gaseous measurements, the bulk of the report is centered on the emissions of fine particulates, or PM 2.5. The fine particulate (PM 2.5) results for the liquid fuel fired heating systems indicate a very strong linear relationship between the fine particulate emissions and the sulfur content of the liquid fuels being studied. This is illustrated by the plot contained in the first figure on the next page which clearly illustrates the linear relationship between the measured mass of fine particulate per unit of energy, expressed as milligrams per Mega-Joule (mg/MJ) versus the different sulfur contents of four different heating fuels. These were tested in a conventional cast iron boiler equipped with a flame retention head burner. The fuels included a typical ASTM No. 2 fuel oil with sulfur below 0.5 percent (1520 average ppm S), an ASTM No. 2 fuel oil with very high sulfur content (5780 ppm S), low sulfur heating oil (322 ppm S) and an ultra low sulfur diesel fuel (11 ppm S). Three additional oil-fired heating system types were also tested with normal heating fuel, low sulfur and ultralow sulfur fuel. They included an oil-fired warm air furnace of conventional design, a high efficiency condensing warm air furnace, a condensing hydronic boiler and the conventional hydronic boiler as discussed above. The linearity in the results was observed with all of the different oil-fired equipment types (as shown in the second figure on the next page). A linear regression of the data resulted in an Rsquared value of 0.99 indicating that a very good linear relationship exits. This means that as sulfur decreases the PM 2.5 emissions are reduced in a linear manner within the sulfur content range tested. At the ultra low sulfur level (15 ppm S) the amount of PM 2.5 had been reduced dramatically to an average of 0.043 mg/MJ. Three different gas-fired heating systems were tested. These included a conventional in-shot induced draft warm air furnace, an atmospheric fired hydronic boiler and a high efficiency hydronic boiler. The particulate (PM 2.5) measured ranged from 0.011 to 0.036 mg/MJ. depending on the raw material source used in their manufacture. All three stoves tested were fueled with premium (low ash) wood pellets obtained in a single batch to provide for uniformity in the test fuel. Unlike the oil and gas fired systems, the wood pellet stoves had measurable amounts of particulates sized above the 2.5-micron size that defines fine particulates (less than 2.5 microns). The fine particulate emissions rates ranged from 22 to 30 mg/ MJ with an average value

  19. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  20. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    U.S. Energy Information Administration (EIA) Indexed Site

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  1. ,,"Distillate Fuel Oil",,,"Alternative Energy Sources(b)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Standard Errors for Table 10.8;" " Unit: Percents." ,,"Distillate Fuel Oil",,,"Alternative Energy Sources(b)" ,,,..."Coal Coke" "NAICS"," ","Total"," ","Not","Electricity","Nat...

  2. ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)"

    U.S. Energy Information Administration (EIA) Indexed Site

    Errors for Table 10.9;" " Unit: Percents." ,,"Distillate Fuel Oil(b)",,,"Alternative Energy Sources(c)" ,,,..."Coal Coke" "NAICS"," ","Total"," ","Not","Electricity","Nat...

  3. Comparing liquid fuel costs: grain alcohol versus sunflower oil

    SciTech Connect (OSTI)

    Reining, R.C.; Tyner, W.E.

    1983-08-01

    This paper compares the technical and economic feasibility of small-scale production of fuel grade grain alcohol with sunflower oil. Three scales of ethanol and sunflower oil production are modeled, and sensitivity analysis is conducted for various operating conditions and costs. The general conclusion is that sunflower oil costs less to produce than alcohol. Government subsidies for alcohol, but not sunflower oil, could cause adoption of more expensive alcohol in place of cheaper sunflower oil. However, neither sunflower oil nor alcohol are competitive with diesel fuel. 7 references.

  4. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. ); Gidaspow, D.; Gupta, R.; Wasan, D.T. ); Pfister, R.M.: Krieger, E.J. )

    1992-05-01

    This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  5. Combined process for heavy oil, upgrading and synthetic fuel production

    SciTech Connect (OSTI)

    Polomski, R.E.

    1984-06-05

    A process for upgrading heavy oil to fuel products comprises deasphalting the heavy oil with an oxygenated solvent and simultaneously converting the oxygenated solvent and deasphalted oil over a ZSM-5 type catalyst to produce gasoline and distillate boiling range hydrocarbons.

  6. Deliveries of fuel oil and kerosene in 1980

    SciTech Connect (OSTI)

    Not Available

    1982-02-11

    This report contains numerical data on deliveries of distillate fuel oil, residual fuel oil, and kerosene which will be helpful to federal and state agencies, industry, and trade associations in trend analysis, policy/decision making, and forecasting. The data for 1979 and 1980 are tabulated under the following headings: all uses, residential, commercial, industrial, oil companies, electric utilities, transportation, military, and farm use. The appendix contains product and end-use descriptions. (DMC)

  7. Process for Converting Algal Oil to Alternative Aviation Fuel - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Process for Converting Algal Oil to Alternative Aviation Fuel Los Alamos National Laboratory Contact LANL About This Technology The conversion process uses a Kolbe-based method of converting the fatty acids from the algal lipid triglycerides to fuel. The conversion process uses a Kolbe-based method of converting the fatty acids from the algal lipid triglycerides to fuel. Technology Marketing Summary Conversion of triglyceride oils extracted from algae-derived lipids into

  8. Stocks of Distillate Fuel Oil 15 ppm Sulfur and Under

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    128,930 135,683 2004-2016 PADD 1 48,011 47,644 49,624 47,947 48,127 49,490 2004-2016 New England 3,841 4,379 4,534 4,438 5,029 5,888 2004-2016 Central Atlantic 31,859 30,793...

  9. Stocks of Distillate Fuel Oil Greater Than 500 ppm Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    15,747 15,675 15,436 1993-2016 PADD 1 9,594 10,156 10,022 10,045 9,893 9,629 1993-2016 New England 3,108 3,131 2,948 3,290 3,055 3,284 1993-2016 Central Atlantic 5,474 5,933...

  10. "End Use","Total","Electricity(a)","Fuel Oil","Diesel Fuel(b...

    U.S. Energy Information Administration (EIA) Indexed Site

    for Table 5.6;" " Unit: Percents." " "," ",," ","Distillate"," "," ",," " " ",,,,"Fuel Oil",,,"Coal" " "," ","Net","Residual","and",,"LPG and","(excluding Coal"," " "End ...

  11. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  12. Recycled waste oil: A fuel for medium speed diesel engines?

    SciTech Connect (OSTI)

    Cheng, A.B.L.; Poynton, W.A.; Howard, J.G.

    1996-12-31

    This paper describes the exploratory engine trials that Mirrlees Blackstone has undertaken to investigate the effect of fueling an engine using waste oil derived from used lubricants. The effect on the engine`s mechanical components, and thermal performance are examined, and the steps taken to overcome problems are discussed. The proposed engine is sited within the Research and Development facilities, housed separately from the manufacturing plant. The unit is already capable of operating on two different types of fuel with single engine set up. It is a 3 cylinder, 4-stroke turbocharged direct injection engine mounted on an underbase and it operates at 600 rpm, 15.0 bar B.M.E.P. (Brake Mean Effective Pressure). It is a mature engine, built {approximately} 20 years previously, and used for emergency stand-by duties in the company`s powerhouse. The test engine is coupled to an alternator and the electricity generated is fed to the national grid. Initial samples of treated fuel oil, analyzed by an independent oil analysis consultant, indicated that the fuel oil does not correspond to a normal fuel oil. They contained high concentrations of trace elements (i.e. calcium, phosphorus, lead, aluminum and silicon) which was consistent with sourcing from waste lubricating oils. The fuel oil was considered to be too severe for use in an engine.

  13. ,"U.S. Adjusted Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Consumers (Thousand Gallons)","U.S. Residual Fuel Oil Adj SalesDeliveries to Oil Company Consumers (Thousand Gallons)","U.S. Residual Fuel Oil Adj SalesDeliveries to Elect. ...

  14. ,"U.S. Total Sales of Residual Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    to Oil Company Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to Electric Utility Consumers (Thousand Gallons)","U.S. Residual Fuel Oil SalesDeliveries to...

  15. SULFUR HEXAFLUORIDE TREATMENT OF USED NUCLEAR FUEL TO ENHANCE SEPARATIONS

    SciTech Connect (OSTI)

    Gray, J.; Torres, R.; Korinko, P.; Martinez-Rodriguez, M.; Becnel, J.; Garcia-Diaz, B.; Adams, T.

    2012-09-25

    Reactive Gas Recycling (RGR) technology development has been initiated at Savannah River National Laboratory (SRNL), with a stretch-goal to develop a fully dry recycling technology for Used Nuclear Fuel (UNF). This approach is attractive due to the potential of targeted gas-phase treatment steps to reduce footprint and secondary waste volumes associated with separations relying primarily on traditional technologies, so long as the fluorinators employed in the reaction are recycled for use in the reactors or are optimized for conversion of fluorinator reactant. The developed fluorination via SF{sub 6}, similar to the case for other fluorinators such as NF{sub 3}, can be used to address multiple fuel forms and downstream cycles including continued processing for LWR via fluorination or incorporation into a aqueous process (e.g. modified FLUOREX) or for subsequent pyro treatment to be used in advanced gas reactor designs such metal- or gas-cooled reactors. This report details the most recent experimental results on the reaction of SF{sub 6} with various fission product surrogate materials in the form of oxides and metals, including uranium oxides using a high-temperature DTA apparatus capable of temperatures in excess of 1000{deg}C . The experimental results indicate that the majority of the fission products form stable solid fluorides and sulfides, while a subset of the fission products form volatile fluorides such as molybdenum fluoride and niobium fluoride, as predicted thermodynamically. Additional kinetic analysis has been performed on additional fission products. A key result is the verification that SF{sub 6} requires high temperatures for direct fluorination and subsequent volatilization of uranium oxides to UF{sub 6}, and thus is well positioned as a head-end treatment for other separations technologies, such as the volatilization of uranium oxide by NF{sub 3} as reported by colleagues at PNNL, advanced pyrochemical separations or traditional full recycle approaches. Based on current results of the research at SRNL on SF{sub 6} fluoride volatility for UNF separations, SF{sub 6} treatment renders all anticipated volatile fluorides studied to be volatile, and all non-volatile fluorides studied to be non-volatile, with the notable exception of uranium oxides. This offers an excellent opportunity to use this as a head-end separations treatment process because: 1. SF{sub 6} can be used to remove volatile fluorides from a UNF matrix while leaving behind uranium oxides. Therefore an agent such as NF{sub 3} should be able to very cleanly separate a pure UF{sub 6} stream, leaving compounds in the bottoms such as PuF{sub 4}, SrF{sub 2} and CsF after the UNF matrix has been pre-treated with SF{sub 6}. 2. Due to the fact that the uranium oxide is not separated in the volatilization step upon direct contact with SF{sub 6} at moderately high temperatures (? 1000{deg}C), this fluoride approach may be wellsuited for head-end processing for Gen IV reactor designs where the LWR is treated as a fuel stock, and it is not desired to separate the uranium from plutonium, but it is desired to separate many of the volatile fission products. 3. It is likely that removal of the volatile fission products from the uranium oxide should simplify both traditional and next generation pyroprocessing techniques. 4. SF{sub 6} treatment to remove volatile fission products, with or without treatment with additional fluorinators, could be used to simplify the separations of traditional aqueous processes in similar fashion to the FLUOREX process. Further research should be conducted to determine the separations efficiency of a combined SF{sub 6}/NF{sub 3} separations approach which could be used as a stand-alone separations technology or a head-end process.

  16. Distillate Fuel Oil Assessment for Winter 1996-1997

    Reports and Publications (EIA)

    1997-01-01

    This article describes findings of an analysis of the current low level of distillate stocks which are available to help meet the demand for heating fuel this winter, and presents a summary of the Energy Information Administration's distillate fuel oil outlook for the current heating season under two weather scenarios.

  17. Verifying a Simplified Fuel Oil Field Measurement Protocol

    SciTech Connect (OSTI)

    Henderson, Hugh; Dentz, Jordan; Doty, Chris

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  18. Verifying a Simplified Fuel Oil Flow Field Measurement Protocol

    SciTech Connect (OSTI)

    Henderson, H.; Dentz, J.; Doty, C.

    2013-07-01

    The Better Buildings program is a U.S. Department of Energy program funding energy efficiency retrofits in buildings nationwide. The program is in need of an inexpensive method for measuring fuel oil consumption that can be used in evaluating the impact that retrofits have in existing properties with oil heat. This project developed and verified a fuel oil flow field measurement protocol that is cost effective and can be performed with little training for use by the Better Buildings program as well as other programs and researchers.

  19. Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996

    SciTech Connect (OSTI)

    Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

    1996-12-01

    The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

  20. Enhanced Oil Recovery to Fuel Future Oil Demands | GE Global...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the fascinating things of my job is contemplating questions like: What will the future energy mix look like? This is difficult to predict but it is fair to argue that oil will...

  1. ,"for Electricity(a)","Fuel Oil","Diesel Fuel(b)","(billion"...

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Relative Standard Errors for Table 5.7;" " Unit: Percents." ,,,"Distillate",,,"Coal" ,,,"Fuel Oil",,,"(excluding Coal" ,"Net Demand","Residual","and","Natural Gas(c)","LPG ...

  2. ,,,,"Reasons that Made Residual Fuel Oil Unswitchable"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... storage of usable alternative fuels is not available due to the potential" "environmental impact of storage tanks." " NFNo applicable RSE rowcolumn factor." " * Estimate less ...

  3. ,,,,"Reasons that Made Distillate Fuel Oil Unswitchable"

    U.S. Energy Information Administration (EIA) Indexed Site

    ... storage of usable alternative fuels is not available due to the potential" "environmental impact of storage tanks." " NFNo applicable RSE rowcolumn factor." " * Estimate less ...

  4. Fuel Oil and Kerosene Sales - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    ‹ See All Petrolem Reports Fuel Oil and Kerosene Sales With Data for 2014 | Release Date: December 22, 2015 | Next Release Date: November 2016 Previous Issues Year: 2014 2013 2012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 Go EIA is considering changes to the survey Form EIA-821, "Annual Fuel Oil and Kerosene Sales Report," such as deleting kerosene and adding propane. If you would like to participate in a discussion on these proposed changes

  5. Crude oil and finished fuel storage stability: An annotated review

    SciTech Connect (OSTI)

    Whisman, M.L.; Anderson, R.P.; Woodward, P.W.; Giles, H.N.

    1991-01-01

    A state-of-the-art review and assessment of storage effects on crude oil and product quality was undertaken through a literature search by computer accessing several data base sources. Pertinent citations from that literature search are tabulated for the years 1980 to the present. This 1990 revision supplements earlier reviews by Brinkman and others which covered stability publications through 1979 and an update in 1983 by Goetzinger and others that covered the period 1952--1982. For purposes of organization, citations are listed in the current revision chronologically starting with the earliest 1980 publications. The citations have also been divided according to primary subject matter. Consequently 11 sections appear including: alternate fuels, gasoline, distillate fuel, jet fuel, residual fuel, crude oil, biodegradation, analyses, reaction mechanisms, containment, and handling and storage. Each section contains a brief narrative followed by all the citations for that category.

  6. Miscible, multi-component, diesel fuels and methods of bio-oil transformation

    DOE Patents [OSTI]

    Adams, Thomas; Garcia, Manuel; Geller, Dan; Goodrum, John W.; Pendergrass, Joshua T.

    2010-10-26

    Briefly described, embodiments of this disclosure include methods of recovering bio-oil products, fuels, diesel fuels, and the like are disclosed.

  7. Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award August 19, 2013 - 5:07pm Addthis ...

  8. Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award August 19, 2013 - 5:07pm Addthis...

  9. RECS Fuel Oil Usage Form_v1 (Draft).xps

    U.S. Energy Information Administration (EIA) Indexed Site

    fuel oil usage for this delivery address between September 2008 and April 2010. Delivery ... Form EIA 457G OMB No. 1905-0092 Expires 13113 2009 RECS Fuel Oil and Kerosene Usage Form ...

  10. EERE Success Story-Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award EERE Success Story-Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award August 19, 2013 - ...

  11. Rape oil methyl ester (RME) and used cooking oil methyl ester (UOME) as alternative fuels

    SciTech Connect (OSTI)

    Hohl, G.H.

    1995-12-31

    The author presents a review about the fleet tests carried out by the Austrian Armed Forces concerning the practical application of a vegetable oil, i.e Rape Oil Methyl Ester (RME) and Used Cooking Oil Methyl Ester (UOME) as alternative fuels for vehicles under military conditions, and reviews other research results carried out in Austria. As a result of over-production in Western European agriculture, the increase in crop yields has led to tremendous surpluses. Alternative agricultural products have been sought. One alternative can be seen in biological fuel production for tractors, whereby the farmer is able to produce his own fuel supply as was the case when he previously provided self-made feed for his horses. For the market introduction different activities were necessary. A considerable number of institutes and organizations including the Austrian Armed Forces have investigated, tested and developed these alternative fuels. The increasing disposal problems of used cooking oil have initiated considerations for its use. The recycling of this otherwise waste product, and its preparation for use as an alternative fuel to diesel oil, seems to be most promising.

  12. Secure Fuels from Domestic Resources - Oil Shale and Tar Sands | Department

    Energy Savers [EERE]

    of Energy Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development PDF icon Profiles of Companies Engaged in Domestic Oil Shale and Tar Sands Resource and Technology Development More Documents & Publications Oil Shale RD&D Leases in the United States National Strategic Unconventional Resource Model Oil Shale

  13. Distillate Fuel Oil Days of Supply

    Gasoline and Diesel Fuel Update (EIA)

    Randall Luthi, President www.noia.org National Ocean Industries Association The Future of OCS After Macondo 2011 EIA Conference Washington, DC April 26, 2011 NOIA represents the full spectrum of U.S. businesses that produce energy offshore Last year's view through the crystal ball was far different than today's * A year ago, the off shore oil and gas industry was poised to come out of the economic doldrums * Spurred by earlier deep water discoveries, the future looked promising * The Obama

  14. ?Aceite Vegetal Puro Como Combustible Diesel? (Straight Vegetable Oil as a Diesel Fuel? Spanish Version) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01

    Discusses the use of straight vegetable oil as a diesel fuel and the use of biodiesel as a transportation fuel.

  15. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 6, January--March 1996

    SciTech Connect (OSTI)

    Pan, W.P.; Riley, J.T.; Lloyd, W.G.

    1996-02-29

    The objectives for this quarter of study on the co-firing of high sulfur coals with refuse derived fuels were two-fold. First, the effects of different experimental parameters such as temperature, flow rates and reaction times on the formation of chlorinated organic compounds were studied using the tubular furnace as a reactor followed by GC/MS analysis. Secondly, the effect of fuel/air ratio on the flue gas composition and combustion efficiency were studied with the AFBC system.

  16. Total Adjusted Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 55,664,448 58,258,830 59,769,444 57,512,994 58,675,008 61,890,990 1984-2014 East Coast (PADD 1) 18,219,180 17,965,794 17,864,868 16,754,388

  17. Total Adjusted Sales of Residual Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Commercial Industrial Oil Company Electric Power Vessel Bunkering Military All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 7,835,436 8,203,062 7,068,306 5,668,530 4,883,466 3,942,750 1984-2014 East Coast (PADD 1) 3,339,162 3,359,265 2,667,576 1,906,700 1,699,418 1,393,068 1984-2014 New England (PADD 1A) 318,184

  18. Total Sales of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Residential Commercial Industrial Oil Company Farm Electric Power Railroad Vessel Bunkering On-Highway Military Off-Highway All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 54,100,092 56,093,645 57,082,558 57,020,840 58,107,155 60,827,930 1984-2014 East Coast (PADD 1) 17,821,973 18,136,965 17,757,005 17,382,566

  19. Total Sales of Residual Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    End Use: Total Commercial Industrial Oil Company Electric Power Vessel Bunkering Military All Other Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: End Use Area 2009 2010 2011 2012 2013 2014 View History U.S. 6,908,028 7,233,765 6,358,120 6,022,115 5,283,350 4,919,255 1984-2014 East Coast (PADD 1) 2,972,575 2,994,245 2,397,932 2,019,294 1,839,237 1,724,167 1984-2014 New England (PADD 1A) 281,895

  20. Product Supplied for Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    Product Guide Category Prices Volumes Crude oil Refiner acqusistion cost 1,1A - Domestic first purchases 1 - from selected states 18 - by API gravity 20 - for selected crude streams 19 - Imports F.O.B. cost 1 - from selected states 21 - by API gravity 23 - for selected crude streams 26 - Landed costs 1 - from selected states 22 - by API gravity 24 - for selected crude streams 27 - Percentage by gravity band 25 - - Motor gasoline all sellers 28 - refiners 2,4,6,31 3,5,7,39,40 prime suppliers - 45

  1. Identification of sulfur heterocycles in coal liquids and shale oils. Technical progress report, August 1, 1980-May 1, 1981

    SciTech Connect (OSTI)

    Lee, M. L.; Castle, R. N.

    1981-01-01

    The sulfur heterocycle separation scheme which was described in the last progress report was evaluated for quantitative recovery of individual components. The results indicate that recoveries can range from 10% to approx. 30% depending on the structure of the compound. During this period, 23 unsubstituted sulfur-containing heterocyclic ring systems were synthesized in oder to confirm GC/MS identifications and for biological testing. The four possible 3-ring heterocycles and the thirteen possible 4-ring heterocycles were tested for mutagenic activity in the histidine reversion (Ames assay) system. One of the 3-ring isomers, naphtho(1,2-b)-thiophene, and six of the 4-ring isomers induced mutations in Salmonella test strains. One of these compounds, phenanthro(3,4-b)thiophene, displayed approximately the same mutagenic activity as benzo(a)pyrene. A two-step adsorption chromatographic procedure was developed in order to fractionate synthetic fuels into various chemical-type classes for studying the relative concentrations and mutagenic activities of the various types. An SRC-II Heavy Distillate was fractionated into aliphatic hydrocarbons, polycyclic aromatic hydrocarbons, sulfur heterocycles, indoles and carbazoles, azaarenes, and amino polycyclic aromatic hydrocarbons. It was found that the amino-PAH fraction contained most of the mutagenic activity. A survey was made for compounds containing both nitrogen and sulfur heteroatoms in their structures. A number of these compounds were detected by GC using nitrogen- and sulfur-selective detection.

  2. Comparison of thermodynamics of nitrogen and sulfur removal in heavy oil upgrading: Part 1, Acyclic and monocyclic compounds

    SciTech Connect (OSTI)

    Steele, W.V.; Archer, D.G.; Chirico, R.D.; Strube, M.M.

    1989-06-01

    This report is the first in a series detailing the equilibrium thermodynamics associated with hydrodesulfurization and hydrodenitrogenation reactions for organic compounds present as contaminants in crude fossil fuels. In this report acyclic and monocyclic aromatic and nonaromatic compounds are considered. Results for nitrogen and sulfur compounds are compared and contrasted using available thermodynamic data from the literature. Details of all calculations are provided, and all data sources are documented. 38 refs., 8 figs., 14 tabs.

  3. Table 10.24 Reasons that Made Distillate Fuel Oil Unswitchable, 2006;

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Reasons that Made Distillate Fuel Oil Unswitchable, 2006; Level: National Data; Row: NAICS Codes; Column: Reasons that Made Quantity Unswitchable; Unit: Million barrels. Total Amount of Total Amount of Equipment is Not Switching Unavailable Long-Term Unavailable Combinations of NAICS Distillate Fuel Oil Unswitchable Distillate Capable of Using Adversely Affects Alternative Environmenta Contract Storage for Another Columns F, G, Code(a) Subsector and Industry Consumed as a Fue Fuel Oil Fuel Use

  4. Table 10.25 Reasons that Made Residual Fuel Oil Unswitchable, 2006;

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Reasons that Made Residual Fuel Oil Unswitchable, 2006; Level: National Data; Row: NAICS Codes; Column: Reasons that Made Quantity Unswitchable; Unit: Million barrels. Total Amount of Total Amount of Equipment is Not Switching Unavailable Long-Term Unavailable Combinations of NAICS Residual Fuel Oil Unswitchable ResiduaCapable of Using Adversely Affects Alternative Environmental Contract Storage for Another Columns F, G, Code(a) Subsector and Industry Consumed as a Fue Fuel Oil Fuel Use

  5. Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award

    Broader source: Energy.gov [DOE]

    Developed jointly by Da Vinci Emissions Services Ltd., Cummins Inc., and Oak Ridge National Laboratory (ORNL), the Da Vinci Fuel-in-Oil (DAFIO) technology uses a fiber optic probe to obtain real-time measurements of oil in an operating engine to quantify the fuel dissolved in the lubricant oil.

  6. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established “reburning” chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  7. Experimental plan for the fuel-oil study

    SciTech Connect (OSTI)

    Ternes, M.P.; Levins, W.P.; Brown, M.A.

    1992-01-01

    An up-to-date assessment of the Weatherization Assistance Program (WAP) is being performed by the US Department of Energy WAP Division and the Oak Ridge National Laboratory. Five studies form the evaluation. Major goals of the Fuel-Oil Study are to estimate the fuel oil saved by the WAP in the Northeast during the 1990 and 1991 program years, identify and quantify non-energy impacts of the WAP, assess the cost effectiveness of the WAP within this submarket, and assess factors which may cause savings and cost effectiveness to vary. The study will only analyze single-family houses in the nine states in the Northeast census region and will be carried out over two heating seasons (1990 and 1991 WAP program years). A split-winter, pre- and post-weatherization experimental design with a control group will be used. Houses will be monitored over one winter. Energy conservation measures will be installed in the weatherized houses in January of each winter by the local WAP subgrantee. One hundred twenty five weatherized houses and 75 control houses will be monitored over the 1990--1991 winter; a different set of 200 houses will be monitored over the 1991--1992 winter. The houses will be evenly distributed among 25 subgrantees. Space-heating fuel-oil consumption, indoor temperature, and outdoor temperature data will be collected for all houses. Fuel-oil delivery data will be collected for each house monitored over the 1990--1991 winter for at least a year before weatherization. The delivery data will be analyzed to determine if the accuracy of the study can be improved by collecting fuel-oil delivery data on a larger sample of houses over the 1991--1992 winter. Detailed survey information will be obtained on all the houses. This information includes descriptive details of the house and its mechanical systems, details on household size and other demographics, and occupant answers to questions regarding comfort, safety, and operation of their space-heating system and house.

  8. "Characteristic(a)","Electricity","Fuel Oil","Fuel Oil(b)","Natural...

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 7.5;" " Unit: Percents." " ",," "," ",," "," " "Economic",,"Residual","Distillate",,"LPG and" "Characteristic(a)","Electricity","Fuel ...

  9. Vegetable oils as an on the farm diesel fuel substitute: the North Carolina situation. Final report

    SciTech Connect (OSTI)

    Harwood, H.J.

    1981-06-01

    The state-of-the-art of using vegetable oil as a diesel fuel alternative is reviewed. Particular emphasis has been placed on using vegetable oil in farm vehicles as an emergency fuel which may be produced on-farm. The following are reviewed: the mechanical feasibility, on-farm fuel production, and economic analysis.

  10. West Coast (PADD 5) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha for Petrochem. Feed. Use Other Oils for Petrochem. Feed.

  11. On-farm production of soybean oil and its properties as a fuel

    SciTech Connect (OSTI)

    Suh, S.R.

    1983-01-01

    This study presents the design of a system for on-farm production of soybean oil for use as a fuel in compression ignition engines. The soybean oil production system consists of a heat exchanger to heat the beans with the exhaust gas of an engine, a screw press and a system for water degumming and drying the expressed crude oil. Optimum parameters of the oil production system were found. The rheological properties of soybean oil, ester of soybean oil and blends of the above with diesel fuel and diesel fuel additives are given. Data on soybean temperature, outlet gas temperature and thermal efficiency were obtained from a developed mathematical model of the heat exchanger. Chemical analyses show that crude oil from the press is similar to that of commercially degummed oil. The degumming process is not needed for the crude oil to be used as a fuel in compression ignition engines. Rheological properties of the soybean oil and soybean oil diesel fuel mixture show that the fluids have viscosities of time independent characteristics and are Newtonian fluids. Diesel fuel additives having low viscosities can be used to lower the viscosity of soybean oil and blends with diesel fuel but the effect is insignificant.

  12. Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC

    DOE Patents [OSTI]

    Roberts, George W.; Tao, John C.

    1985-01-01

    In this invention, a process is disclosed characterized by heating a slurry of coal in the presence of a process-derived recycle solvent and passing same to a dissolver zone, separating the resultant gases and liquid/solid products therefrom, vacuum distilling the liquid/solids products, separating the portions of the liquid/solids vacuum distillation effluent into a solid ash, unconverted coal particles and SRC material having a boiling point above 850.degree. F. and subjecting same to a critical solvent deashing step to provide an ash-free SRC product. The lighter liquid products from the vacuum distillation possess a boiling point below 850.degree. F. and are passed through a distillation tower, from which recycled solvent is recovered in addition to light distillate boiling below 400.degree. F. (overhead). The ash-free SRC product in accompanyment with at least a portion of the process derived solvent is passed in combination to a hydrotreating zone containing a hydrogenation catalyst and in the presence of hydrogen is hydroprocessed to produce a desulfurized and denitrogenized low-sulfur, low-ash boiler fuel and a process derived recycle solvent which is recycled to slurry the coal in the beginning of the process before heating.

  13. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 245 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  14. Table 42. Residual Fuel Oil Prices by PAD District and State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Information AdministrationPetroleum Marketing Annual 1998 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  15. Rocky Mountain (PADD 4) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Conventional Gasoline Blend. Comp. Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur Residual F.O., Greater than 1% Sulfur Naphtha

  16. Laser-induced fluorescence fiber optic probe measurement of oil dilution by fuel

    DOE Patents [OSTI]

    Parks, II, James E [Knoxville, TN; Partridge, Jr., William P [Oak Ridge, TN

    2010-11-23

    Apparatus for detecting fuel in oil includes an excitation light source in optical communication with an oil sample for exposing the oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state and a spectrally selective device in optical communication with the oil sample for detecting light emitted from the oil sample as the oil sample returns from the excited state to a non-excited state to produce spectral indicia that can be analyzed to determine the presence of fuel in the oil sample. A method of detecting fuel in oil includes the steps of exposing a oil sample to excitation light in order to excite the oil sample from a non-excited state to an excited state, as the oil sample returns from the excited state to a non-excited state, detecting light emitted from the oil sample to produce spectral indicia; and analyzing the spectral indicia to determine the presence of fuel in the oil sample.

  17. The Northeast heating fuel market: Assessment and options

    SciTech Connect (OSTI)

    2000-07-01

    In response to a Presidential request, this study examines how the distillate fuel oil market (and related energy markets) in the Northeast behaved in the winter of 1999-2000, explains the role played by residential, commercial, industrial, and electricity generation sector consumers in distillate fuel oil markets and describes how that role is influenced by the structure of tie energy markets in the Northeast. In addition, this report explores the potential for nonresidential users to move away from distillate fuel oil and how this might impact future prices, and discusses conversion of distillate fuel oil users to other fuels over the next 5 years. Because the President's and Secretary's request focused on converting factories and other large-volume users of mostly high-sulfur distillate fuel oil to other fuels, transportation sector use of low-sulfur distillate fuel oil is not examined here.

  18. Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

    1996-05-31

    The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

  19. Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification

    SciTech Connect (OSTI)

    Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M.; Gidaspow, D.; Gupta, R.; Wasan, D.T.; Pfister, R.M.: Krieger, E.J.

    1992-05-01

    This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

  20. Midwest (PADD 2) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur

  1. Midwest (PADD 2) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31 to 1% Sulfur

  2. Transition to Ultra-Low-Sulfur Diesel Fuel: Effects on Prices and Supply, The

    Reports and Publications (EIA)

    2001-01-01

    This report discusses the implications of the new regulations for vehicle fuel efficiency and examines the technology, production, distribution, and cost implications of supplying diesel fuel to meet the new standards.

  3. VARIABLE FIRING RATE OIL BURNER USING PULSE FUEL FLOW CONTROL.

    SciTech Connect (OSTI)

    KRISHNA,C.R.; BUTCHER,T.A.; KAMATH,B.R.

    2004-10-01

    The residential oil burner market is currently dominated by the pressure-atomized retention head burner, which has an excellent reputation for reliability and efficiency. In this burner, oil is delivered to a fuel nozzle at pressures from 100 to 150 psi. In addition, to atomizing the fuel, the small, carefully controlled size of the nozzle exit orifice serves to control the burner firing rate. Burners of this type are currently available at firing rates of more than 0.5 gallons-per-hour (70,000 Btu/hr). Nozzles have been made for lower firing rates, but experience has shown that such nozzles suffer rapid fouling of the necessarily small passages, leading to bad spray patterns and poor combustion performance. Also, traditionally burners and the nozzles are oversized to exceed the maximum demand. Typically, this is figured as follows. The heating load of the house on the coldest day for the location is considered to define the maximum heat load. The contractor or installer adds to this to provide a safety margin and for future expansion of the house. If the unit is a boiler that provides domestic hot water through the use of a tankless heating coil, the burner capacity is further increased. On the contrary, for a majority of the time, the heating system is satisfying a much smaller load, as only rarely do all these demands add up. Consequently, the average output of the heating system has to be much less than the design capacity and this is accomplished by start and stop cycling operation of the system so that the time-averaged output equals the demand. However, this has been demonstrated to lead to overall efficiencies lower than the steady-state efficiency. Therefore, the two main reasons for the current practice of using oil burners much larger than necessary for space heating are the unavailability of reliable low firing rate oil burners and the desire to assure adequate input rate for short duration, high draw domestic hot water loads. One approach to solve this problem is to develop a burner, which can operate at two firing rates, with the lower rate being significantly lower than 0.5 gallons per hour. This paper describes the initial results of adopting this approach through a pulsed flow nozzle. It has been shown that the concept of flow modulation with a small solenoid valve is feasible. Especially in the second configuration tested, where the Lee valve was integrated with the nozzle, reasonable modulation in flow of the order of 1.7 could be achieved. For this first prototype, the combustion performance is still not quite satisfactory. Improvements in operation, for example by providing a sharp and positive shut-off so that there is no flow under low pressures with consequent poor atomization could lead to better combustion performance. This could be achieved by using nozzles that have shut off or check valves for example. It is recommended that more work in cooperation with the valve manufacturer could produce a technically viable system. Marketability is of course a far more complex problem to be addressed once a technically viable product is available.

  4. Liquid fuels from co-processing coal with bitumen or heavy oil: A review

    SciTech Connect (OSTI)

    Moschopedis, S.E.; Hepler, L.G.

    1987-01-01

    Coal, bitumen and heavy oil (and various pitches, resids, etc.) are similar in that they require more substantial treatment than does conventional light oil to yield useful liquid fuels. The authors provide a brief and selective review of technologies for liquefying coal, followed by consideration of co-processing coal with bitumen/heavy oil. Such co-processing may be considered as use of bitumen/heavy oil as a solvent and/or hydrogen donor in liquefaction of coal, or as the use of coal to aid upgrading bitumen/heavy oil.

  5. Conversion of crop seed oils to jet fuel and associated methods

    DOE Patents [OSTI]

    Ginosar, Daniel M.; Petkovic, Lucia M.; Thompson, David N.

    2010-05-18

    Aspects of the invention include methods to produce jet fuel from biological oil sources. The method may be comprised of two steps: hydrocracking and reforming. The process may be self-sufficient in heat and hydrogen.

  6. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  7. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    55.1 47.1 W W 55.1 46.2 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  8. Table 42. Residual Fuel Oil Prices by PAD District and State

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    45.5 49.2 W W 44.5 45.4 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  9. "Code(a)","End Use","Total","Electricity(b)","Fuel Oil","Diesel...

    U.S. Energy Information Administration (EIA) Indexed Site

    Relative Standard Errors for Table 5.2;" " Unit: Percents." ,,,,,"Distillate" ,,,,,"Fuel Oil",,,"Coal" "NAICS",,,"Net","Residual","and",,"LPG and","(excluding Coal" "Code(a)","End ...

  10. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for"...

  11. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C.

    1983-01-01

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  12. EERE Success Story—Tennessee: Da Vinci Fuel-in-Oil Reduces Emissions, Wins R&D 100 Award

    Broader source: Energy.gov [DOE]

    Developed jointly by Da Vinci Emissions Services Ltd., Cummins Inc., and Oak Ridge National Laboratory (ORNL), the Da Vinci Fuel-in-Oil (DAFIO™) technology uses a fiber optic probe to obtain real-time measurements of oil in an operating engine to quantify the fuel dissolved in the lubricant oil.

  13. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh/SiO2 and Pt/Al2O3 catalysts.

  14. New Technology for Hydroprocessing Bio-oils to Fuels Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalytic Upgrading of Biomass Pyrolysis Oils In A.V. Bridgwater (Ed.), Research in Thermochemical Biomass Conversion (p 893). Netherlands: Springer. Quad Chart Overview 3 Award: ...

  15. Production and fuel characteristics of vegetable oil from oilseed crops in the Pacific Northwest

    SciTech Connect (OSTI)

    Auld, D.L.; Bettis, B.L.; Peterson, C.L.

    1982-01-01

    The purpose of this research was to evaluate the potential yield and fuel quality of various oilseed crops adapted to the Pacific Northwest as a source of liquid fuel for diesel engines. The seed yield and oil production of three cultivars of winter rape (Brassica napus L.), two cultivars of safflower (Carthamus tinctorius L.) and two cultivars of sunflower (Helianthus annuus L.) were evaluated in replicated plots at Moscow. Additional trials were conducted at several locations in Idaho, Oregon and Washington. Sunflower, oleic and linoleic safflower, and low and high erucic acid rapeseed were evaluated for fatty acid composition, energy content, viscosity and engine performance in short term tests. During 20 minute engine tests power output, fuel economy and thermal efficiency were compared to diesel fuel. Winter rape produced over twice as much farm extractable oil as either safflower or sunflower. The winter rape cultivars, Norde and Jet Neuf had oil yields which averaged 1740 and 1540 L/ha, respectively. Vegetable oils contained 94 to 95% of the KJ/L of diesel fuel, but were 11.1 to 17.6 times more viscous. Viscosity of the vegetable oils was closely related to fatty acid chain length and number of unsaturated bonds (R/sup 2/=.99). During short term engine tests all vegetable oils produced power outputs equivalent to diesel, and had thermal efficiencies 1.8 to 2.8% higher than diesel. Based on these results it appears that species and cultivars of oilseed crops to be utilized as a source of fuel should be selected on the basis of oil yield. 1 figure, 5 tables.

  16. Estimating household fuel oil/kerosine, natural gas, and LPG prices by census region

    SciTech Connect (OSTI)

    Poyer, D.A.; Teotia, A.P.S.

    1994-08-01

    The purpose of this research is to estimate individual fuel prices within the residential sector. The data from four US Department of Energy, Energy Information Administration, residential energy consumption surveys were used to estimate the models. For a number of important fuel types - fuel oil, natural gas, and liquefied petroleum gas - the estimation presents a problem because these fuels are not used by all households. Estimates obtained by using only data in which observed fuel prices are present would be biased. A correction for this self-selection bias is needed for estimating prices of these fuels. A literature search identified no past studies on application of the selectivity model for estimating prices of residential fuel oil/kerosine, natural gas, and liquefied petroleum gas. This report describes selectivity models that utilize the Dubin/McFadden correction method for estimating prices of residential fuel oil/kerosine, natural gas, and liquefied petroleum gas in the Northeast, Midwest, South, and West census regions. Statistically significant explanatory variables are identified and discussed in each of the models. This new application of the selectivity model should be of interest to energy policy makers, researchers, and academicians.

  17. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  18. SUSTAINABLE DEVELOPMENT IN KAZAKHASTAN: USING OIL AND GAS PRODUCTION BY-PRODUCT SULFUR FOR COST-EFFECTIVE SECONDARY END-USE PRODUCTS.

    SciTech Connect (OSTI)

    KALB, P.D.; VAGIN, S.; BEALL, P.W.; LEVINTOV, B.L.

    2004-09-25

    The Republic of Kazakhstan is continuing to develop its extensive petroleum reserves in the Tengiz region of the northeastern part of the Caspian Sea. Large quantities of by-product sulfur are being produced as a result of the removal of hydrogen sulfide from the oil and gas produced in the region. Lack of local markets and economic considerations limit the traditional outlets for by-product sulfur and the buildup of excess sulfur is a becoming a potential economic and environmental liability. Thus, new applications for re-use of by-product sulfur that will benefit regional economies including construction, paving and waste treatment are being developed. One promising application involves the cleanup and treatment of mercury at a Kazakhstan chemical plant. During 19 years of operation at the Pavlodar Khimprom chlor-alkali production facility, over 900 tons of mercury was lost to the soil surrounding and beneath the buildings. The Institute of Metallurgy and Ore Benefication (Almaty) is leading a team to develop and demonstrate a vacuum-assisted thermal process to extract the mercury from the soil and concentrate it as pure, elemental mercury, which will then be treated using the Sulfur Polymer Stabilization/Solidification (SPSS) process. The use of locally produced sulfur will recycle a low-value industrial by-product to treat hazardous waste and render it safe for return to the environment, thereby helping to solve two problems at once. SPSS chemically stabilizes mercury to mercuric sulfide, which has a low vapor pressure and low solubility, and then physically encapsulates the material in a durable, monolithic solid sulfur polymer matrix. Thus, mercury is placed in a solid form very much like stable cinnabar, the form in which it is found in nature. Previous research and development has shown that the process can successfully encapsulate up to 33 wt% mercury in the solid form, while still meeting very strict regulatory standards for leachable mercury (0.025 mg/l in the Toxicity Characteristic Leaching Procedure). The research and development to deploy Kazakhstan recycled sulfur for secondary applications described in this paper is being conducted with support from the International Science and Technology Center (ISTC) and the U.S. Department of Energy Initiatives for Proliferation Prevention (DOE IPP).

  19. Rapid engine test to measure injector fouling in diesel engines using vegetable oil fuels

    SciTech Connect (OSTI)

    Korus, R.A.; Jaiduk, J.; Peterson, C.L.

    1985-11-01

    Short engine tests were used to determine the rate of carbon deposition on direct injection diesel nozzles. Winter rape, high-oleic and high-linoleic safflower blends with 50% diesel were tested for carbon deposit and compared to that with D-2 Diesel Control Fuel. Deposits were greatest with the most unsaturated fuel, high-linoleic safflower, and least with winter rape. All vegetable oil blends developed power similar to diesel fueled engines with a 6 to 8% greater fuel consumption. 8 references.

  20. Refiner and Blender Net Production of Distillate Fuel Oil 15 ppm Sulfur and

    Gasoline and Diesel Fuel Update (EIA)

    Under 4,524 4,453 4,428 4,359 4,338 4,251 2004-2016 PADD 1 235 270 326 336 332 270 2004-2016 PADD 2 951 899 879 850 931 947 2004-2016 PADD 3 2,570 2,562 2,482 2,453 2,402 2,349 2004-2016 PADD 4 182 178 178 177 158 179 2004-2016 PADD 5 587 543 564 543 515 507 2004

  1. Refiner and Blender Net Production of Distillate Fuel Oil > 500 ppm Sulfur

    Gasoline and Diesel Fuel Update (EIA)

    Weekly 4-Week Average Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 04/01/16 04/08/16 04/15/16 04/22/16 04/29/16 05/06/16 View History U.S. 174 151 103 139 123 209 1993-2016 PADD 1 34 22 -3 7 16 35 1993-2016 PADD 2 -12 14 6 2 6 14 1993-2016 PADD 3 133 113 90 119 87 142 1993-2016 PADD 4 1 0 0 -2 0 0 1993-2016 PADD 5 18 3 9 13 14 18 1993

  2. Economics of on-farm production and use of vegetable oils for fuel

    SciTech Connect (OSTI)

    McIntosh, C.S.; Withers, R.V.; Smith, S.M.

    1982-01-01

    The technology of oilseed processing, on a small scale, is much simpler than that for ethanol production. This, coupled with the fact that most energy intensive farm operations use diesel powered equipment, has created substantial interest in vegetable oils as an alternative source of liquid fuel for agriculture. The purpose of this study was to estimate the impact on gross margins resulting from vegetable oil production and utilization in two case study areas, Latah and Power Counties, in Iadho. The results indicate that winter rape oil became a feasible alternative to diesel when the price of diesel reached $0.84 per liter in the Latah County model. A diesel price of $0.85 per liter was required in the Power County model before it became feasible to produce sunflower oil for fuel. 5 tables.

  3. A nuclear wind/solar oil-shale system for variable electricity and liquid fuels production

    SciTech Connect (OSTI)

    Forsberg, C.

    2012-07-01

    The recoverable reserves of oil shale in the United States exceed the total quantity of oil produced to date worldwide. Oil shale contains no oil, rather it contains kerogen which when heated decomposes into oil, gases, and a carbon char. The energy required to heat the kerogen-containing rock to produce the oil is about a quarter of the energy value of the recovered products. If fossil fuels are burned to supply this energy, the greenhouse gas releases are large relative to producing gasoline and diesel from crude oil. The oil shale can be heated underground with steam from nuclear reactors leaving the carbon char underground - a form of carbon sequestration. Because the thermal conductivity of the oil shale is low, the heating process takes months to years. This process characteristic in a system where the reactor dominates the capital costs creates the option to operate the nuclear reactor at base load while providing variable electricity to meet peak electricity demand and heat for the shale oil at times of low electricity demand. This, in turn, may enable the large scale use of renewables such as wind and solar for electricity production because the base-load nuclear plants can provide lower-cost variable backup electricity. Nuclear shale oil may reduce the greenhouse gas releases from using gasoline and diesel in half relative to gasoline and diesel produced from conventional oil. The variable electricity replaces electricity that would have been produced by fossil plants. The carbon credits from replacing fossil fuels for variable electricity production, if assigned to shale oil production, results in a carbon footprint from burning gasoline or diesel from shale oil that may half that of conventional crude oil. The U.S. imports about 10 million barrels of oil per day at a cost of a billion dollars per day. It would require about 200 GW of high-temperature nuclear heat to recover this quantity of shale oil - about two-thirds the thermal output of existing nuclear reactors in the United States. With the added variable electricity production to enable renewables, additional nuclear capacity would be required. (authors)

  4. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  5. Impacts of the Weatherization Assistance Program in fuel-oil heated houses

    SciTech Connect (OSTI)

    Levins, W.P.; Ternes, M.P.

    1994-10-01

    In 1990, the US Department of Energy (DOE) initiated a national evaluation of its lowincome Weatherization Assistance Program. This report, which is one of five parts of that evaluation, evaluates the energy savings and cost-effectiveness of the Program as it had been applied to single-family houses heated primarily by fuel-oil. The study was based upon a representative sample (41 local weatherization agencies, 222 weatherized and 115 control houses) from the nine northeastern states during 1991 and 1992 program years. Dwelling-specific and agency-level data on measures installed, costs, and service delivery procedures were collected from the sampled agencies. Space-heating fuel-oil consumption, indoor temperature, and outdoor temperature were monitored at each house. Dwelling characteristics, air-leakage measurements, space-heating system steady-state efficiency measurements, safety inspections, and occupant questionnaires were also collected or performed at each monitored house. We estimate that the Program weatherized a total of 23,400 single-family fuel-oil heated houses in the nine northeastern states during program years 1991 and 1992. Annual fuel-oil savings were calculated using regression techniques to normalize the savings to standard weather conditions. For the northeast region, annual net fuel-oil savings averaged 160 gallons per house, or 17.7% of pre-weatherization consumption. Although indoor temperatures changed in individual houses following weatherization, there was no average change and no significant difference as compared to the control houses; thus, there was no overall indoor temperature takeback effect influencing fuel-oil savings. The weatherization work was performed cost effectively in these houses from the Program perspective, which included both installation costs and overhead and management costs but did not include non-energy benefits (such as employment and environmental).

  6. ,"New Mexico Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales of Distillate Fuel Oil by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Sales of Distillate Fuel Oil by End Use",13,"Annual",2014,"6/30/1984" ,"Release Date:","12/22/2015" ,"Next Release Date:","Last Week of November 2016" ,"Excel

  7. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Adjusted Sales of Distillate Fuel Oil by End Use",13,"Annual",2014,"6/30/1984" ,"Release Date:","12/22/2015" ,"Next Release Date:","Last Week of November 2016" ,"Excel File

  8. Progress report Idaho on-road test with vegetable oil as a diesel fuel

    SciTech Connect (OSTI)

    Reece, D.; Peterson, C.L.

    1993-12-31

    Biodiesel is among many biofuels being considered in the US for alternative fueled vehicles. The use of this fuel can reduce US dependence on imported oil and help improve air quality by reducing gaseous and particulate emissions. Researchers at the Department of Agricultural Engineering at the University of Idaho have pioneered rapeseed oil as a diesel fuel substitute. Although UI has conducted many laboratory and tractor tests using raw rapeseed oil and rape methyl ester (RME), these fuels have not been proven viable for on-road applications. A biodiesel demonstration project has been launched to show the use of biodiesel in on-road vehicles. Two diesel powered pickups are being tested on 20 percent biodiesel and 80 percent diesel. One is a Dodge 3/4-ton pickup powered by a Cummins 5.9 liter turbocharged and intercooled engine. This engine is direct injected and is being run on 20 percent RME and 80 percent diesel. The other pickup is a Ford, powered by a Navistar 7.3 liter, naturally aspirated engine. This engine has a precombustion chamber and is being operated on 20 percent raw rapeseed oil and 80 percent diesel. The engines themselves are unmodified, but modifications have been made to the vehicles for the convenience of the test. In order to give maximum vehicle range, fuel mixing is done on-board. Two tanks are provided, one for the diesel and one for the biodiesel. Electric fuel pumps supply fuel to a combining chamber for correct proportioning. The biodiesel fuel tanks are heated with a heat exchanger which utilizes engine coolant circulation.

  9. Nonresidential buildings energy consumption survey: 1979 consumption and expenditures. Part 2. Steam, fuel oil, LPG, and all fuels

    SciTech Connect (OSTI)

    Patinkin, L.

    1983-12-01

    This report presents data on square footage and on total energy consumption and expenditures for commercial buildings in the contiguous United States. Also included are detailed consumption and expenditures tables for fuel oil or kerosene, liquid petroleum gas (LPG), and purchased steam. Commercial buildings include all nonresidential buildings with the exception of those where industrial activities occupy more of the total square footage than any other type of activity. 7 figures, 23 tables.

  10. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  11. Oil shale, tar sands, and related materials

    SciTech Connect (OSTI)

    Stauffer, H.C.

    1981-01-01

    This sixteen-chapter book focuses on the many problems and the new methodology associated with the commercialization of the oil shale and tar sand industry. Topics discussed include: an overview of the Department of Energy's oil shale R, D, and D program; computer simulation of explosive fracture of oil shale; fracturing of oil shale by treatment with liquid sulfur dioxide; chemistry of shale oil cracking; hydrogen sulfide evolution from Colorado oil shale; a possible mechanism of alkene/alkane production in oil shale retorting; oil shale retorting kinetics; kinetics of oil shale char gasification; a comparison of asphaltenes from naturally occurring shale bitumen and retorted shale oils: the influence of temperature on asphaltene structure; beneficiation of Green River oil shale by density methods; beneficiation of Green River oil shale pelletization; shell pellet heat exchange retorting: the SPHER energy-efficient process for retorting oil shale; retorted oil shale disposal research; an investigation into the potential economics of large-scale shale oil production; commercial scale refining of Paraho crude shale oil into military specification fuels; relation between fuel properties and chemical composition; chemical characterization/physical properties of US Navy shale-II fuels; relation between fuel properties and chemical composition: stability of oil shale-derived jet fuel; pyrolysis of shale oil residual fractions; synfuel stability: degradation mechanisms and actual findings; the chemistry of shale oil and its refined products; the reactivity of Cold Lake asphaltenes; influence of thermal processing on the properties of Cold Lake asphaltenes: the effect of distillation; thermal recovery of oil from tar sands by an energy-efficient process; and hydropyrolysis: the potential for primary upgrading of tar sand bitumen.

  12. Environmental benefits of replacing fuel oil by natural gas in the metropolitan region of Sao Paulo, Brazil

    SciTech Connect (OSTI)

    Kondo, S.; Assuncao, J.V. de

    1998-12-31

    The Metropolitan Region of Sao Paulo (Brazil) has a population 16.322 million people (1995 estimate) living in an area of 8,051 km2 with most of them concentrated in the city of Sao Paulo with 9.8 million people and 4.6 million cars. Although with an air quality better than some other Latin American megacities such as Mexico and Santiago do Chile, the air quality still exceeds the national air quality standards. In 2/17/1993 Brazilian Petroleum Company (PETROBRAS) and the Bolivian Petroleum Company (Yacimientos Petroliferos Fiscales Bolivianos -- YPFB) signed an agreement to bring natural gas from Bolivia to the south and southeast of Brazil. The end of the construction of the gas pipeline will be in 1999, and it will deliver 4 million Nm3/day of natural gas to COMGAS Sao Paulo State Gas Company. This amount will increase to 8.1 million Nm3/day by the year 2006, that will be sufficient to supply the Sao Paulo Metropolitan Region market need at that time. In this study an estimate of the influence in the air quality was performed supposing the substitution of fuel oil by natural gas in industry and also in diesel buses. The results showed that there will be benefits in relation to sulfur dioxide, PM10, greenhouse gases and trace elements, and negligible effects in relation to NO{sub x}, NMTOC and carbon monoxide.

  13. Winters fuels report

    SciTech Connect (OSTI)

    1995-10-27

    The outlook for distillate fuel oil this winter is for increased demand and a return to normal inventory patterns, assuming a resumption of normal, cooler weather than last winter. With industrial production expected to grow slightly from last winter`s pace, overall consumption is projected to increase 3 percent from last winter, to 3.4 million barrels per day during the heating season (October 1, 1995-March 31, 1996). Much of the supply win come from stock drawdowns and refinery production. Estimates for the winter are from the Energy Information Administration`s (EIA) 4th Quarter 1995 Short-Tenn Energy Outlook (STEO) Mid-World Oil Price Case forecast. Inventories in place on September 30, 1995, of 132 million barrels were 9 percent below the unusually high year-earlier level. Inventories of high-sulfur distillate fuel oil, the principal type used for heating, were 13 percent lower than a year earlier. Supply problems are not anticipated because refinery production and the ready availability of imports should be adequate to meet demand. Residential heating off prices are expected to be somewhat higher than last winter`s, as the effects of lower crude oil prices are offset by lower distillate inventories. Heating oil is forecast to average $0.92 per gallon, the highest price since the winter of 1992-93. Diesel fuel (including tax) is predicted to be slightly higher than last year at $1.13 per gallon. This article focuses on the winter assessment for distillate fuel oil, how well last year`s STEO winter outlook compared to actual events, and expectations for the coming winter. Additional analyses include regional low-sulfur and high-sulfur distillate supply, demand, and prices, and recent trends in distillate fuel oil inventories.

  14. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  15. Method to upgrade bio-oils to fuel and bio-crude

    DOE Patents [OSTI]

    Steele, Philip H; Pittman, Jr., Charles U; Ingram, Jr., Leonard L; Gajjela, Sanjeev; Zhang, Zhijun; Bhattacharya, Priyanka

    2013-12-10

    This invention relates to a method and device to produce esterified, olefinated/esterified, or thermochemolytic reacted bio-oils as fuels. The olefinated/esterified product may be utilized as a biocrude for input to a refinery, either alone or in combination with petroleum crude oils. The bio-oil esterification reaction is catalyzed by addition of alcohol and acid catalyst. The olefination/esterification reaction is catalyzed by addition of resin acid or other heterogeneous catalyst to catalyze olefins added to previously etherified bio-oil; the olefins and alcohol may also be simultaneously combined and catalyzed by addition of resin acid or other heterogeneous catalyst to produce the olefinated/esterified product.

  16. A Damage Model for Degradation in the Electrodes of solid oxide fuel cells: Modeling the effects of sulfur and antimony in the anode

    SciTech Connect (OSTI)

    Ryan, Emily M.; Xu, Wei; Sun, Xin; Khaleel, Mohammad A.

    2012-07-15

    Over their designed lifetime, high temperature electrochemical devices, such as solid oxide fuel cells (SOFCs), can experience degradation in their electrochemical performance due to environmental conditions, operating conditions, contaminants, and other factors. Understanding the different degradation mechanisms in SOFCs and other electrochemical devices is essential to reducing performance degradation and increasing the lifetime of these devices. In this paper SOFC degradation mechanisms are discussed and a damage model is presented which describes performance degradation in SOFCs due to damage or degradation in the electrodes of the SOFC. A degradation classification scheme is presented that divides the various SOFC electrode degradation mechanisms into categories based on their physical effects on the SOFC. The application of the damage model and the classification method is applied to sulfur poisoning and antimony poisoning which occur in the anode of SOFCs. For sulfur poisoning the model is able to predict the degradation in SOFC performance based on the operating temperature and voltage of the fuel cell and the concentration of gaseous sulfur species in the anode. For antimony poisoning the effects of nickel removal from the anode matrix is investigated.

  17. ,"U.S. Sales for Resale Refiner Residual Fuel Oil and No. 4 Fuel...

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Fuel Sales Volumes",4,"Monthly","22016","1151983" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefresdnusvwrmgalpdm.xls" ...

  18. Major Fuels","Electricity",,"Natural Gas","Fuel Oil","District

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Energy Consumption by Major Fuel for Non-Mall Buildings, 2003" ,"All Buildings*",,"Total Energy Consumption (trillion Btu)" ,"Number of Buildings (thousand)","Floorspace...

  19. Major Fuels","Site Electricity","Natural Gas","Fuel Oil","District...

    U.S. Energy Information Administration (EIA) Indexed Site

    C1. Total Energy Consumption by Major Fuel, 1999" ,"All Buildings",,"Total Energy Consumption (trillion Btu)",,,,,"Primary Electricity (trillion Btu)" ,"Number of Buildings...

  20. Swedish tests on rape-seed oil as an alternative to diesel fuel

    SciTech Connect (OSTI)

    Johansson, E.; Nordstroem, O.

    1982-01-01

    The cheapest version of Swedish rape-seed oil was chosen. First the rape-seed oil was mixed in different proportions with regular diesel fuel. A mixture of 1/3 rape-seed oil and 2/3 regular diesel fuel (R 33) was then selected for a long-term test. A Perkins 4.248 diesel engine was used for laboratory tests. Four regular farm tractors, owned and operated by farmers, and two tractors belonging to the Institute have been running on R 33. Each tractor was calibrated on a dynamometer according to Swedish and ISO-standards before they were operated on R 33. Since then the tractors have been regularly recalibrated. The test tractors have been operated on R 33 for more than 3400 h. An additional 1200 h have been covered by the laboratory test engine. None of the test tractors have hitherto required repairs due to the use of R 33, but some fuel filters have been replaced. Some fuel injectors have been cleaned due to deposits on the nozzles. 4 figures, 1 table.

  1. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    SciTech Connect (OSTI)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  2. Economics of sunflower oil as an extender or substitute for diesel fuel

    SciTech Connect (OSTI)

    Helgeson, D.L.; Schaffner, L.W.

    1982-05-01

    The economics of sunflower oil as an extender or substitute for diesel fuel in US agriculture, with particular emphasis on North Dakota, is examined. A study of the spot market prices indicates that crude sunflower oil has moved closer competitively with bulk diesel prices. On the question of energy efficiency, it is estimated, that using current production and processing estimates, there is a positive net energy ratio of 5.78 to 1. Processing can take place at the commercial leveL, in intermediate sized plants or on-farm. Costs were analyzed for three sizes of farm presses. (Refs. 6).

  3. Impacts of the Weatherization Assistance Program in Fuel-Oil Heated Houses

    SciTech Connect (OSTI)

    Levins, W.P.

    1994-01-01

    In 1990, the U.S. Department of Energy (DOE) initiated a national evaluation of its low-income Weatherization Assistance Program. This report, which is one of five parts of that evaluation, evaluates the energy savings and cost-effectiveness of the Program as it had been applied to single-family houses heated primarily by fuel-oil. The study was based upon a representative sample (41 local weatherization agencies, 222 weatherized and 115 control houses) from the nine northeastern states during 1991 and 1992 program years. Dwelling-specific and agency-level data on measures installed, costs, and service delivery procedures were collected from the sampled agencies. Space-heating fuel-oil consumption, indoor temperature, and outdoor temperature were monitored at each house. Dwelling characteristics, air-leakage measurements, space-heating system steady-state efficiency measurements, safety inspections, and occupant questionnaires were also collected or performed at each monitored house. We estimate that the Program weatherized a total of 23,400 single-family fuel-oil heated houses in the nine northeastern states during program years 1991 and 1992. Annual fuel-oil savings were calculated using regression techniques to normalize the savings to standard weather conditions. For the northeast region, annual net fuel-oil savings averaged 160 gallons per house, or 17.7% of pre-weatherization consumption. Although indoor temperatures changed in individual houses following weatherization, there was no average change and no significant difference as compared to the control houses; thus, there was no overall indoor temperature takeback effect influencing fuel-oil savings. The weatherization work was performed cost effectively in these houses from the Program perspective, which included both installation costs and overhead and management costs but did not include non-energy benefits (such as employment and environmental). Total average costs were $1819 per house ($1192 for installation labor and materials, and $627 for overhead and management), and the benefit-to-cost ratio was 1.48. A general trend toward higher-than-average fuel-oil savings was observed in houses with high pre-weatherization fuel-oil consumption. Program savings could likely be increased by targeting higher energy consumers for weatherization, although equity issues would have to be considered. Weatherization measures associated with higher-than-average savings were use of a blower door for air-sealing, attic and wall insulation, and replacement space-heating systems. Space-heating system tune-ups were not particularly effective at improving the steady-state efficiency of systems, although other benefits such as improved seasonal efficiency, and system safety and reliability may have resulted. The Program should investigate methods of improving the selection and/or application of space-heating system tune-ups and actively promote improved tune-up procedures that have been developed as a primary technology transfer activity. Houses were more air-tight following weatherization, but still leakier than what is achievable. Additional technology transfer effort is recommended to increase the use of blower doors considering that only half the weatherized houses used a blower door during air sealing. A guidebook developed by a committee of experts and covering a full range of blower-door topics might be a useful technology transfer and training document. Weatherization appeared to make occupants feel better about their house and house environment.

  4. Louisiana Sales of Distillate Fuel Oil by End Use

    U.S. Energy Information Administration (EIA) Indexed Site

    514,474 1,744,771 1,873,769 1,488,986 1,405,392 1,375,580 1984-2014 Residential 1,036 140 34 53 84 89 1984-2014 Commercial 59,689 38,695 39,659 36,840 17,590 21,197 1984-2014 Industrial 21,826 26,063 20,770 33,052 31,744 33,670 1984-2014 Oil Company 243,789 319,394 364,261 245,303 183,801 178,810 1984-2014 Farm 42,624 44,027 49,985 48,462 40,785 46,134 1984-2014 Electric Power 4,321 4,775 5,464 2,733 4,610 4,826 1984-2014 Railroad 18,345 25,425 32,515 28,110 39,578 45,790 1984-2014 Vessel

  5. Mississippi Sales of Distillate Fuel Oil by End Use

    U.S. Energy Information Administration (EIA) Indexed Site

    835,855 800,065 771,577 830,756 806,396 819,763 1984-2014 Residential 5 5 4 7 7 8 1984-2014 Commercial 26,641 23,713 26,383 26,386 24,019 28,803 1984-2014 Industrial 21,853 18,362 15,450 20,153 21,186 19,595 1984-2014 Oil Company 3,955 4,262 4,058 6,226 7,450 6,419 1984-2014 Farm 41,080 57,087 52,559 81,878 84,753 79,443 1984-2014 Electric Power 3,796 3,393 2,019 1,674 2,223 1,921 1984-2014 Railroad 24,727 17,936 37,741 29,848 32,550 35,578 1984-2014 Vessel Bunkering 141,302 93,384 58,285 58,505

  6. New Mexico Sales of Distillate Fuel Oil by End Use

    U.S. Energy Information Administration (EIA) Indexed Site

    09,709 554,352 574,557 608,490 621,430 669,923 1984-2014 Residential 55 46 37 27 72 53 1984-2014 Commercial 11,030 9,435 9,609 9,145 9,112 12,114 1984-2014 Industrial 33,804 24,429 27,110 31,316 32,029 32,917 1984-2014 Oil Company 9,871 1,705 2,127 5,857 11,218 27,016 1984-2014 Farm 11,278 14,821 10,955 12,816 15,784 11,752 1984-2014 Electric Power 4,321 4,000 1,689 5,155 4,816 3,826 1984-2014 Railroad 245 1,780 1,707 19,123 38,543 45,446 1984-2014 Vessel Bunkering 0 0 0 0 0 0 1984-2014

  7. Alabama Sales of Distillate Fuel Oil by End Use

    U.S. Energy Information Administration (EIA) Indexed Site

    987,571 1,038,133 1,094,359 1,132,711 1,047,981 1,027,777 1984-2014 Residential 3,971 4,895 432 750 639 722 1984-2014 Commercial 39,802 46,009 48,475 46,654 30,536 27,874 1984-2014 Industrial 90,659 77,542 81,120 120,347 77,119 65,322 1984-2014 Oil Company 0 328 1,035 2,640 2,929 2,985 1984-2014 Farm 17,882 19,881 24,518 24,503 24,651 20,459 1984-2014 Electric Power 8,276 10,372 22,490 9,375 6,514 10,071 1984-2014 Railroad 44,546 42,465 97,177 125,439 63,570 56,873 1984-2014 Vessel Bunkering

  8. Florida Sales of Distillate Fuel Oil by End Use

    U.S. Energy Information Administration (EIA) Indexed Site

    840,100 2,027,012 1,914,621 1,918,039 2,023,650 2,038,923 1984-2014 Residential 1,551 1,820 1,085 572 451 728 1984-2014 Commercial 126,292 113,313 100,791 104,860 113,873 110,082 1984-2014 Industrial 36,512 43,088 35,652 32,087 31,458 42,894 1984-2014 Oil Company 236 2,255 4,038 4,359 4,427 3,802 1984-2014 Farm 86,642 204,866 109,177 103,325 122,563 98,418 1984-2014 Electric Power 31,161 43,675 35,577 16,137 16,244 12,182 1984-2014 Railroad 33,651 42,353 46,461 66,711 93,844 92,435 1984-2014

  9. The effect of fuel sulfur level on the HC, CO and NOX conversion efficiencies of PD/RH, PT/RH, PD-only and tri-metal catalysts

    SciTech Connect (OSTI)

    DiCircco, D.M.; Adamczyk, A.A.; Patel, K.S.

    1995-12-31

    Due to additional requirements imposed by the 1990 amendments to the Clean Air Act, automotive emissions systems must perform at high efficiencies for 100,000 miles. However, fuels containing sulfur, can reduce the efficiency of many modern catalyst formulations. Additionally, the Northeast Ozone Transport Commission (OTC) has petitioned the US Environmental Protection Agency (EPA) to require region-wide adaptation of the California Low-Emission Vehicle standards without the application of California`s reformulated gasoline program which is necessary to keep the level of fuel sulfur low. As will be seen, this will result in reduced catalyst activity in the OTC, since typical gasolines contain sulfur levels which vary considerably. Gasolines containing 50ppmS and 500ppmS only represent the 10th and 75th percentile of US commercial summer fuels. As will be shown, these high levels of fuel sulfur will lower the performance of high activity catalyst formulations and may make compliance with LEV/ULEV emissions levels extremely difficult if not impossible without the adaptation of low-sulfur fuels.

  10. Potential use of California lignite and other alternate fuel for enhanced oil recovery. Phase I and II. Final report. [As alternative fuels for steam generation in thermal EOR

    SciTech Connect (OSTI)

    Shelton, R.; Shimizu, A.; Briggs, A.

    1980-02-01

    The Nation's continued reliance on liquid fossil fuels and decreasing reserves of light oils gives increased impetus to improving the recovery of heavy oil. Thermal enhanced oil recovery EOR techniques, such as steam injection, have generally been the most effective for increasing heavy oil production. However, conventional steam generation consumes a large fraction of the produced oil. The substitution of alternate (solid) fuels would release much of this consumed oil to market. This two-part report focuses on two solid fuels available in California, the site of most thermal EOR - petroleum coke and lignite. Phase I, entitled Economic Analysis, shows detailed cost comparisons between the two candidate fuels and also with Western coal. The analysis includes fuels characterizations, process designs for several combustion systems, and a thorough evaluation of the technical and economic uncertainties. In Phase II, many technical parameters of petroleum coke combustion were measured in a pilot-plant fluidized bed. The results of the study showed that petroleum coke combustion for EOR is feasible and cost effective in a fluidized bed combustor.

  11. Experimental plan for the fuel-oil study. Weatherization Assistance Program: Volume 2

    SciTech Connect (OSTI)

    Ternes, M.P.; Levins, W.P.; Brown, M.A.

    1992-01-01

    An up-to-date assessment of the Weatherization Assistance Program (WAP) is being performed by the US Department of Energy WAP Division and the Oak Ridge National Laboratory. Five studies form the evaluation. Major goals of the Fuel-Oil Study are to estimate the fuel oil saved by the WAP in the Northeast during the 1990 and 1991 program years, identify and quantify non-energy impacts of the WAP, assess the cost effectiveness of the WAP within this submarket, and assess factors which may cause savings and cost effectiveness to vary. The study will only analyze single-family houses in the nine states in the Northeast census region and will be carried out over two heating seasons (1990 and 1991 WAP program years). A split-winter, pre- and post-weatherization experimental design with a control group will be used. Houses will be monitored over one winter. Energy conservation measures will be installed in the weatherized houses in January of each winter by the local WAP subgrantee. One hundred twenty five weatherized houses and 75 control houses will be monitored over the 1990--1991 winter; a different set of 200 houses will be monitored over the 1991--1992 winter. The houses will be evenly distributed among 25 subgrantees. Space-heating fuel-oil consumption, indoor temperature, and outdoor temperature data will be collected for all houses. Fuel-oil delivery data will be collected for each house monitored over the 1990--1991 winter for at least a year before weatherization. The delivery data will be analyzed to determine if the accuracy of the study can be improved by collecting fuel-oil delivery data on a larger sample of houses over the 1991--1992 winter. Detailed survey information will be obtained on all the houses. This information includes descriptive details of the house and its mechanical systems, details on household size and other demographics, and occupant answers to questions regarding comfort, safety, and operation of their space-heating system and house.

  12. Particles of spilled oil-absorbing carbon in contact with water

    DOE Patents [OSTI]

    Muradov, Nazim

    2011-03-29

    Hydrogen generator coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. Carbon particles with surface filaments having a hydrophobic property of oil film absorption, compositions of matter containing those particles, and a system for using the carbon particles for cleaning oil spills.

  13. Decision guide to farm fuel production: ethanol, methanol, or vegetable oils

    SciTech Connect (OSTI)

    Kerstetter, J.D.

    1984-09-01

    The purpose of this paper is to inform farmers of the choices they have today regarding production of motor vehicle fuels. Its intent is to inform farmers of what is involved in producing an alternative fuel, its compatibility with existing engines, the costs involved, and the markets for the fuel and any by-products. This paper is not a how-to-do-it manual or a policy document. Some of the data has been developed from the Appropriate Technology Small Grants Program managed by the Washington State Energy Office. Part One provides background information on Washington's fuel use patterns, highlighting the agricultural sector. In Part Two, general considerations common to all alternative fuels are covered. Part Three contains three detailed discussions of the alternative fuels most favored by Washington farmers for production and use - ethanol, vegetable oils, and methanol. The Appendix contains a brief summary of the 11 ethanol projects in Washington funded as a result of the Appropriate Technology Small Grants Program. 5 references, 12 figures, 2 tables.

  14. Gulf Coast (PADD 3) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31

  15. Gulf Coast (PADD 3) Total Crude Oil and Products Imports

    U.S. Energy Information Administration (EIA) Indexed Site

    MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel (Renewable) Other Renewable Diesel Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., Greater than 500 ppm Distillate F.O., 501 to 2000 ppm Distillate F.O., Greater than 2000 ppm Kerosene Finished Aviation Gasoline Aviation Gasoline Blending Components Kerosene-Type Jet Fuel Special Naphthas Residual Fuel Oil Residual F.O., Less than 0.31% Sulfur Residual F.O., 0.31

  16. Study of the competitive viability of minority fuel oil marketers. Final report

    SciTech Connect (OSTI)

    1981-09-30

    Previous studies on the competitive viability of the fuel oil heating market had addressed some of the unique problems facing minority fuel oil marketers (MFMs) within the total market sector (TMS). This study focused on identifying and developing quantitative information on MFMs in the TMS. The specific objective was to determine whether the business problems experienced by MFMs were directly related to their minority status or were characterstic of any firm in the TMS operating under comparable conditions. As an overall conclusion, thorough investigation of the MFMs considered to constitute the universe of minoriy firms within the TMS did not reveal any evidence of overt discrimination affecting the competitive viability of MFMs. Upon analysis, the problems reported by MFMs could not be reasonably ascribed to discrimination on the basis of their minority business status. The study, however, did point up problems unique to MFMs as the result of typical operational and financial characteristics. For example, MFMs, compared to the TMS norm, have not been in the market as long and are smaller in terms of total assets, number of employees, number of trucks, number of accounts and annual volume of oil delivered. Their primary customers are low-income families in urban areas. Financial indicators suggest that the average MFM does not have long-term financial stability. The basis for this overall conclusion, derived by analyses of information from MFMs, as well as many independent sources, is summarized in three parts: (1) MFM industry profile; (2) financial analyses; and (3) problem analyses.

  17. Coal liquefaction process wherein jet fuel, diesel fuel and/or ASTM No. 2 fuel oil is recovered

    DOE Patents [OSTI]

    Bauman, Richard F.; Ryan, Daniel F.

    1982-01-01

    An improved process for the liquefaction of coal and similar solid carbonaceous materials wherein a hydrogen donor solvent or diluent derived from the solid carbonaceous material is used to form a slurry of the solid carbonaceous material and wherein the naphthenic components from the solvent or diluent fraction are separated and used as jet fuel components. The extraction increases the relative concentration of hydroaromatic (hydrogen donor) components and as a result reduces the gas yield during liquefaction and decreases hydrogen consumption during said liquefaction. The hydrogenation severity can be controlled to increase the yield of naphthenic components and hence the yield of jet fuel and in a preferred embodiment jet fuel yield is maximized while at the same time maintaining solvent balance.

  18. Additive for lubricants and hydrocarbon fuels comprising reaction products of olefins, sulfur, hydrogen sulfide and nitrogen containing polymeric compounds

    SciTech Connect (OSTI)

    Horodysky, A.G.; Law, D.A.

    1987-04-28

    A process is described for making an additive for lubricant compositions comprising co-reacting: a monoolefin selected from the group consisting of butenes, propenes, pentenes, and mixtures of two or more thereof; sulfur; hydrogen sulfide; polymeric nitrogen-containing compound selected from the group consisting of succinimides, amides, imides, polyoxyazoline polymers and alkyl imidazoline compounds; and a catalytic amount of an amine selected from the group consisting of polyethylene amines and hydroxyl-containing amines; at a temperature between about 130/sup 0/C and about 200/sup 0/C and a pressure of about 0 psig to about 900 psig, the reactants being reacted in a molar ratio of olefin, polymeric nitrogen-containing compound, and hydrogen sulfide to sulfur of 2 to 0.5, 0.001 to 0.4, and 0.5 to 0.7, respectively, and the concentration of amine being between 0.5 and 10 percent of the total weight of reactants.

  19. Methods of refining natural oils, and methods of producing fuel compositions

    DOE Patents [OSTI]

    Firth, Bruce E.; Kirk, Sharon E.

    2015-10-27

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent that comprises nitric acid; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  20. Methods of refining natural oils and methods of producing fuel compositions

    DOE Patents [OSTI]

    Firth, Bruce E; Kirk, Sharon E; Gavaskar, Vasudeo S

    2015-11-04

    A method of refining a natural oil includes: (a) providing a feedstock that includes a natural oil; (b) reacting the feedstock in the presence of a metathesis catalyst to form a metathesized product that includes olefins and esters; (c) passivating residual metathesis catalyst with an agent selected from the group consisting of phosphorous acid, phosphinic acid, and a combination thereof; (d) separating the olefins in the metathesized product from the esters in the metathesized product; and (e) transesterifying the esters in the presence of an alcohol to form a transesterified product and/or hydrogenating the olefins to form a fully or partially saturated hydrogenated product. Methods for suppressing isomerization of olefin metathesis products produced in a metathesis reaction, and methods of producing fuel compositions are described.

  1. ,"U.S. Adjusted Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2014,"6/30/1984" ,"Data 2","Commercial",10,"Annual",2014,"6/30/1984" ,"Data

  2. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    Distillate Fuel Oil and Kerosene Sales by End Use" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Residential",4,"Annual",2014,"6/30/1984" ,"Data 2","Commercial",10,"Annual",2014,"6/30/1984" ,"Data

  3. ,"U.S. Residual Fuel Oil Refiner Sales Volumes"

    U.S. Energy Information Administration (EIA) Indexed Site

    Refiner Sales Volumes" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Residual Fuel Oil Refiner Sales Volumes",2,"Monthly","2/2016","1/15/1983" ,"Release Date:","5/2/2016" ,"Next Release Date:","6/1/2016" ,"Excel File

  4. Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

    2011-12-11

    A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

  5. Oil

    Broader source: Energy.gov [DOE]

    The Energy Department works to ensure domestic and global oil supplies are environmentally sustainable and invests in research and technology to make oil drilling cleaner and more efficient.

  6. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 1, [September--November 1994

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1994-11-30

    This project is being coordinated with an ongoing project at Western Kentucky University that is being supported by the Southeastern Regional Biomass Energy Program through the Tennessee Valley Authority. Fluidized bed combustion tests will be performed on municipal solid waste blended with high-sulfur and high-chlorine coals in a laboratory scale combustor. The purpose of the tests is to evaluate combustion performance, the extent of the inorganic acid gases (HCl and SO{sub x}) and chlorinated organic compound formation, the effect of chlorine species on SO{sub 2} removal with a sorbent, and the effect of sulfur species on the formation of chlorinated organic compounds from MSW for a range of bed temperatures, excess air levels, MSW/coal ratios, and S/Cl ratios. Flue gas samples will be collected and analyzed at three locations: free board, cyclone inlet, and cyclone outlet. Analytical methods used will include ion chromatography, gas chromatography, and mass spectrometry. Waste stream ash samples will be collected from the cyclone catch and analyzed for unburned carbon, chlorine, chlorinated benzenes, polychlorinated biphenyls, chlorinated phenols, dioxins, furans, and metal content. Major, minor, and trace elements in the ash will be determined by x-ray fluorescence and inductively coupled plasma-atomic emission spectroscopy. Accomplishments for the first quarter are presented.

  7. EIA-821, Annual Fuel Oil and Kerosene Sales Report Page 1 U.S. DEPARTMENT OF ENERGY

    U.S. Energy Information Administration (EIA) Indexed Site

    EIA-821, Annual Fuel Oil and Kerosene Sales Report Page 1 U.S. DEPARTMENT OF ENERGY U.S. ENERGY INFORMATION ADMINISTRATION Washington, DC 20585 OMB No. 1905-0174 Expiration Date: 09/30/2017 Version No.: 2015.01 FORM EIA-821 ANNUAL FUEL OIL AND KEROSENE SALES REPORT INSTRUCTIONS 1. QUESTIONS? If you have any questions about Form EIA-821 after reading the instructions, please call our toll-free number 1-800-638- 8812. 2. PURPOSE The U.S. Energy Information Administration (EIA) Form EIA- 821,

  8. Co-firing High Sulfur Coal with Refuse Derived Fuels. Technical Progress Report {number_sign}11

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, John T.; Lloyd, William G.

    1997-05-31

    The objective of this quarter of study was to prepare fuel pellets containing PVC, newspaper and plastics to be co-fired with coal in the AFBC combustor. The Western Kentucky University atmospheric fluidized bed combustion system requires the fuel to fall from a bunker into a lock-hopper, and from there into a mixing box where the fuel is auger-fed under pressure into the bottom of the fluidized bed. The fuel must flow freely out of the bunker and through the lock- hopper for proper feeding into the combustor. In order for the fuel to continuously fall through these units and into the mixing box during combustion, the density of the fuel and the size of the particles must meet certain requirements. The particles must be no larger than 3/8 inches in diameter and must have a density approaching that of coal. Loose materials such as sawdust, shredded paper products and most shredded plastics do not feed properly in the WKU AFBC system. Bridging and blockage of feed chutes result, even with constant vibration of parts of the feed mechanism. It is not possible to run the AFBC system powered solely by these loose materials.

  9. Mechanisms of particulate matter formation in spark-ignition engines. 2: Effect of fuel, oil, and catalyst parameters

    SciTech Connect (OSTI)

    Kayes, D.; Hochgreb, S.

    1999-11-15

    A combined experimental and modeling effort was performed in order to understand how particulate matter (PM) is formed in spark-ignition (SI) internal combustion engines. Fuel type and fuel/air ratio strongly affect particle concentrations. PM emissions vary by up to 6 orders of magnitude between fuels at the same fuel/air ratio. Minimum PM concentrations are emitted at a global fuel/air ratio within 10% of stoichiometric, with the exact value depending on the particular fuel. Concentrations can increase by more than 3 orders of magnitude when the fuel/air ratio is either increased or decreased 30% from stoichiometric. Particles derived from oil consumption were found to be between 0 and 40% of the PM concentration for the oils used in the present experiments. Differences in PM emissions with and without the catalytic converter are not statistically significant. Particulate number and mass concentrations plus particle sizes are addressed in this paper, as is the correlation between PM and hydrocarbon (HC) emissions.

  10. Co-firing high sulfur coal with refuse derived fuels. Progress report No. 3, [April--June 1995

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1995-05-31

    The Thermogravimetric Analyzer-Fourier Transform Infrared Spectrometer-Mass Spectrometer (TG-FTIR-MS) system was used to identify molecular chlorine, along with HCl, CO, CO{sub 2}, H{sub 2}O, and various hydrocarbons in the gaseous products of the combustion of PVC resin in air. This is a significant finding that will lead us to examine this combustion step further to look for the formation of chlorinated organic compounds. The combination of TG-FTIR and TG-MS offers complementary techniques for the detection and identification of combustion products from coals PVC, cellulose, shredded newspaper, and various blends of these materials. The pilot atmospheric fluidized bed combustor (AFBC) at Western Kentucky University has been tested. The main purpose of these preliminary AFBC runs were to determine the compatibility of coal and pelletized wood in blends and to explore the effects of flue/air ratio. Our objective is to conduct AFBC burns with 90 percent sulfur capture and more then 96% combustion efficiency.

  11. Fact #824: June 9, 2014 EPA Sulfur Standards for Gasoline | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: June 9, 2014 EPA Sulfur Standards for Gasoline Fact 824: June 9, 2014 EPA Sulfur Standards for Gasoline Sulfur naturally occurs in gasoline and diesel fuel, contributing to ...

  12. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur

    Broader source: Energy.gov (indexed) [DOE]

    Batteries | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es105_liang_2012_p.pdf More Documents & Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Vehicle Technologies Office Merit Review 2014: Development of High Energy Density Lithium-Sulfur Cells

  13. Process for reducing sulfur in coal char

    DOE Patents [OSTI]

    Gasior, Stanley J.; Forney, Albert J.; Haynes, William P.; Kenny, Richard F.

    1976-07-20

    Coal is gasified in the presence of a small but effective amount of alkaline earth oxide, hydroxide or carbonate to yield a char fraction depleted in sulfur. Gases produced during the reaction are enriched in sulfur compounds and the alkaline earth compound remains in the char fraction as an alkaline earth oxide. The char is suitable for fuel use, as in a power plant, and during combustion of the char the alkaline earth oxide reacts with at least a portion of the sulfur oxides produced from the residual sulfur contained in the char to further lower the sulfur content of the combustion gases.

  14. EPA Diesel Rule and the Sulfur Effects (DECSE) Project

    SciTech Connect (OSTI)

    2009-05-08

    The VT program collaborated with industry stakeholders and the EPA (in an effort initiated in 1998 called Diesel Emission Control – Sulfur Effects study, otherwise known as DECSE) to quantify the effects of fuel sulfur on emission control technologies.

  15. Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England

    Broader source: Energy.gov [DOE]

    This report summarizes the results of an information exchange sponsored by the DOE/EERE Bioenergy Technologies Office in Manchester, New Hampshire, on May 9-10, 2012. The participand identifies top challenges regarding feedstocks and production, logistics and compatibility, and operational issues, then prioritized next steps for expanding use of pyrolysis oil as a replacement for home heating oil in the Northeast

  16. Fuel Tables.indd

    Gasoline and Diesel Fuel Update (EIA)

    F8: Distillate Fuel Oil Price and Expenditure Estimates, 2014 State Prices Expenditures ... Where shown, (s) Expenditure value less than 0.05. Notes: Distillate fuel oil estimates ...

  17. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    F7: Distillate Fuel Oil Consumption Estimates, 2014 State Residential Commercial ... value less than 0.05. Notes: Distillate fuel oil estimates include biodiesel blended ...

  18. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1995-11-30

    Studies involving the tubular furnace are in the process of identifying the ideal experimental coal-to-refuse derived fuel(RDF) ratio for use in the AFBC system. A series of experiments with this furnace has been performed to determine the possible chemical pathway for formation of chlorinated organic compounds during the combustion of various RDF sources. Phenol and chlorine appear to be likely reactants necessary for the formation of these compounds. The main goal of these experiment is to determine the exact experimental conditions for the formation of chlorinated organic compounds, as well as methods to inhibit their development. Work on the fluidized bed combustor has involved five combustion runs, in which a combustion efficiency of greater than 96% and with a consistent CO{sub 2} concentration of approximately 13% was obtained. Modifications responsible for these improvements include the addition of the underbed fuel feed system and revision of the flue gas sampling system. New methods of determining combustion efficiency and percentage of SO{sub 2} capture using TG techniques to analyze combustion products are being developed. The current outlook using this TGA/FTIR method is very promising, since previously obscured reactions are being studied. the analysis of combustion products is revealing a more complete picture of the combustion process within the AFBC system.

  19. Cost and quality of fuels for electric utility plants: Energy data report. 1980 annual

    SciTech Connect (OSTI)

    Not Available

    1981-06-25

    In 1980 US electric utilities reported purchasng 594 million tons of coal, 408.5 million barrels of oil and 3568.7 billion ft/sup 3/ of gas. As compared with 1979 purchases, coal rose 6.7%, oil decreased 20.9%, and gas increased for the fourth year in a row. This volume presents tabulated and graphic data on the cost and quality of fossil fuel receipts to US electric utilities plants with a combined capacity of 25 MW or greater. Information is included on fuel origin and destination, fuel types, and sulfur content, plant types, capacity, and flue gas desulfurization method used, and fuel costs. (LCL)

  20. Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 8, July 1996--August 1996

    SciTech Connect (OSTI)

    Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

    1996-08-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GC/MS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  1. Filamentous carbon particles for cleaning oil spills and method of production

    DOE Patents [OSTI]

    Muradov, Nazim

    2010-04-06

    A compact hydrogen generator is coupled to or integrated with a fuel cell for portable power applications. Hydrogen is produced via thermocatalytic decomposition (cracking, pyrolysis) of hydrocarbon fuels in oxidant-free environment. The apparatus can utilize a variety of hydrocarbon fuels, including natural gas, propane, gasoline, kerosene, diesel fuel, crude oil (including sulfurous fuels). The hydrogen-rich gas produced is free of carbon oxides or other reactive impurities, so it could be directly fed to any type of a fuel cell. The catalysts for hydrogen production in the apparatus are carbon-based or metal-based materials and doped, if necessary, with a sulfur-capturing agent. Additionally disclosed are two novel processes for the production of two types of carbon filaments, and a novel filamentous carbon product. The hydrogen generator can be conveniently integrated with high temperature fuel cells to produce an efficient and self-contained source of electrical power.

  2. CONFIRMATORY SURVEY OF THE FUEL OIL TANK AREA HUMBOLDT BAY POWER PLANT EUREKA, CALIFORNIA

    SciTech Connect (OSTI)

    WADE C. ADAMS

    2012-04-09

    During the period of February 14 to 15, 2012, ORISE performed radiological confirmatory survey activities for the former Fuel Oil Tank Area (FOTA) and additional radiological surveys of portions of the Humboldt Bay Power Plant site in Eureka, California. The radiological survey results demonstrate that residual surface soil contamination was not present significantly above background levels within the FOTA. Therefore, it is ORISE’s opinion that the radiological conditions for the FOTA surveyed by ORISE are commensurate with the site release criteria for final status surveys as specified in PG&E’s Characterization Survey Planning Worksheet. In addition, the confirmatory results indicated that the ORISE FOTA survey unit Cs-137 mean concentrations results compared favorably with the PG&E FOTA Cs-137 mean concentration results, as determined by ORISE from the PG&E characterization data. The interlaboratory comparison analyses of the three soil samples analyzed by PG&E’s onsite laboratory and the ORISE laboratory indicated good agreement for the sample results and provided confidence in the PG&E analytical procedures and final status survey soil sample data reporting.

  3. Study of trajectories and combustion of fuel-oil droplets in the combustion chamber of a power-plant boiler with the use of a mathematical model

    SciTech Connect (OSTI)

    Enyakin, Yu.P.; Usman, Yu.M.

    1988-03-01

    A mathematical model was developed to permit study of the behavior of fuel-oil droplets in a combustion chamber, and results are presented from a computer calculation performed for the 300-MW model TGMP-314P boiler of a power plant. The program written to perform the calculations was organized so that the first stage would entail calculation of the combustion (vaporization) of a droplet of liquid fuel. The program then provided for a sudden decrease in the mass of the fuel particle, simulating rupture of the coke shell and ejection of some of the liquid. The program then considered the combustion of a hollow coke particle. Physicochemical parameters characteristic of fuel oil M-100 were introduced in the program in the first stage of computations, while parameters characteristic of the coke particle associated with an unburned fuel-oil droplet were included in the second stage.

  4. The examination of pretreatment and end use technologies for dirty fuels produced from coal gasification, coal pyrolysis, oil shale processing, and heavy oil recovery: Final technology status report

    SciTech Connect (OSTI)

    Raden, D.P.; Page, G.C.

    1987-01-01

    The objective of this study was to identify pretreatment (upgrading) and end use technologies which: (1) reduce environmental, health and safety impacts, (2) reduce pollution control costs, or (3) reduce upgrading costs of ''dirty fuels'' while producing higher value energy products. A comprehensive list of technologies was developed for upgrading the various dirty fuels to higher value and products. Fifty-two process flow concepts were examined and from these four process flow concepts were chosen for further development. These are: heavy oil recovery and in situ hydrotreating; wet air oxidation in a downhole reactor; total raw gas shift; and high density fuels via vacuum devolatilization. Each of these four process flow concepts described exhibit the potential for reducing environmental, health and safety impacts and/or pollution control costs. In addition these concepts utilize dirty fuels to produce an upgraded or higher value energy product. These concepts should be developed and evaluated in greater detail to assess their technical and economical viability. Therefore, it is recommended that a program plan be formulated and a proof-of-concept research program be performed for each process concept. 3 refs., 5 figs., 11 tabs.

  5. APPLICATION OF CERAMICS TO HIGH PRESSURE FUEL SYSTEMS

    SciTech Connect (OSTI)

    Mandler, Jr., William F.

    2000-08-20

    Diesel fuel systems are facing increased demands as engines with reduced emissions are developed. Injection pressures have increased to provide finer atomization of fuel for more efficient combustion, Figure 1. This increases the mechanical loads on the system and requires tighter clearances between plungers and bores to prevent leakage. At the same time, fuel lubricity has decreased as a byproduct of reducing the sulfur levels in fuel. Contamination of fuel by water and debris is an ever-present problem. For oil-lubricated fuel system components, increased soot loading in the oil results in increased wear rates. Additionally, engine manufacturers are lengthening warranty periods for engines and systems. This combination of factors requires the development of new materials to counteract the harsher tribological environment.

  6. Oil and Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  7. Crude Oil | NISAC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oil fields to fuel distribution terminals. Different components of this system (e.g., crude oil import terminals, refineries, transmission pipelines, and tank farms) can be ...

  8. Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils

    SciTech Connect (OSTI)

    Huber, George W; Vispute, Tushar P; Routray, Kamalakanta

    2014-06-03

    Disclosed herein is a method of generating hydrogen from a bio-oil, comprising hydrogenating a water-soluble fraction of the bio-oil with hydrogen in the presence of a hydrogenation catalyst, and reforming the water-soluble fraction by aqueous-phase reforming in the presence of a reforming catalyst, wherein hydrogen is generated by the reforming, and the amount of hydrogen generated is greater than that consumed by the hydrogenating. The method can further comprise hydrocracking or hydrotreating a lignin fraction of the bio-oil with hydrogen in the presence of a hydrocracking catalyst wherein the lignin fraction of bio-oil is obtained as a water-insoluble fraction from aqueous extraction of bio-oil. The hydrogen used in the hydrogenating and in the hydrocracking or hydrotreating can be generated by reforming the water-soluble fraction of bio-oil.

  9. Maintenance and operation of the US Alternative Fuel Center

    SciTech Connect (OSTI)

    Erwin, J.; Ferrill, J.L.; Hetrick, D.L.

    1994-08-01

    The Alternative Fuels Utilization Program (AFUP) of the Office of Energy Efficiency and Renewable Energy has investigated the possibilities and limitations of expanded scope of fuel alternatives and replacement means for transportation fuels from alternative sources. Under the AFUP, the Alternative Fuel Center (AFC) was created to solve problems in the DOE programs that were grappling with the utilization of shale oil and coal liquids for transportation fuels. This report covers the first year at the 3-year contract. The principal objective was to assist the AFUP in accomplishing its general goals with two new fuel initiatives selected for tasks in the project year: (1) Production of low-sulfur, low-olefin catalytically cracked gasoline blendstock; and (2) production of low-reactivity/low-emission gasoline. Supporting goals included maintaining equipment in good working order, performing reformulated gasoline tests, and meeting the needs of other government agencies and industries for fuel research involving custom processing, blending, or analysis of experimental fuels.

  10. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur

    Broader source: Energy.gov (indexed) [DOE]

    Batteries | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es105_liang_2011_o.pdf More Documents & Publications Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Protection of Li Anodes Using Dual Phase Electrolytes

  11. Definition of Non-Conventional Sulfur Utilization in Western Kazakhstan for Sulfur Concrete (Phase 1)

    SciTech Connect (OSTI)

    Kalb, Paul

    2007-05-31

    Battelle received a contract from Agip-KCO, on behalf a consortium of international oil and gas companies with exploration rights in the North Caspian Sea, Kazakhstan. The objective of the work was to identify and help develop new techniques for sulfur concrete products from waste, by-product sulfur that will be generated in large quantitites as drilling operations begin in the near future. BNL has significant expertise in the development and use of sulfur concrete products and has direct experience collaborating with the Russian and Kazakh partners that participated. Feasibility testing was successfully conducted for a new process to produce cost-effective sulfur polymer cement that has broad commerical applications.

  12. Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Barrels) Product: Crude Oil Liquefied Petroleum Gases Distillate Fuel Oil Residual Fuel Oil Still Gas Petroleum Coke Marketable Petroleum Coke Catalyst Petroleum Coke Other Petroleum Products Natural Gas Coal Purchased Electricity Purchased Steam Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2009 2010 2011 2012 2013 2014 View History U.S. 0 0 0 0 0 0 1986-2014 East Coast (PADD 1) 0 0 0 0

  13. Refiner and Blender Net Production of Distillate Fuel Oil > 15 pmm to 500

    Gasoline and Diesel Fuel Update (EIA)

    ppm Sulfur 139 179 181 124 128 150 1993-2016 PADD 1 10 26 20 12 10 8 1993-2016 PADD 2 5 4 4 3 1 2 1993-2016 PADD 3 90 84 139 93 109 110 1993-2016 PADD 4 0 6 3 -2 0 1 1993-2016 PADD 5 33 59 15 18 8 30 1993

  14. Uses of lunar sulfur

    SciTech Connect (OSTI)

    Vaniman, D.T.; Pettit, D.R.; Heiken, G.

    1988-01-01

    Sulfur and sulfur compounds have a wide range of applications for their fluid, electrical, chemical and biochemical properties. Although low in abundance on the Moon (/approximately/0.1% in mare soils), sulfur is surface-correlated and relatively extractable. Co-production of sulfur during oxygen extraction from ilmenite-rich soils could yield sulfur in masses up to 10% of the mass of oxygen produced. Sulfur deserves serious consideration as a lunar resource. 29 refs., 3 figs.

  15. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  16. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  17. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  18. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  19. Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication LBNL Commercial Analysis Report (1,062 KB) Technology Marketing Summary A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed

  20. ,"U.S. Sales to End Users Refiner Residual Fuel Oil and No. 4...

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Fuel Sales Volumes",4,"Monthly","22016","1151983" ,"Release Date:","522016" ,"Next Release Date:","612016" ,"Excel File Name:","petconsrefresdnusvtrmgalpdm.xls" ...

  1. Sulfuric acid-sulfur heat storage cycle

    DOE Patents [OSTI]

    Norman, John H.

    1983-12-20

    A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

  2. Evaluation of dense-phase ultrafine coal (DUC) as a fuel alternative for oil- and gas-designed boilers and heaters. Final report

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    Utility and industrial firms currently using oil- and gas-fired boilers have an interest in substitution of coal for oil and gas as the primary boiler fuel. This interest stems from coal`s two main advantages over oil and gas-lower cost and security of supply. Recent efforts in the area of coal conversion have been directed to converting oil- and gas- fired boilers which were originally designed for coal-firing or were designed with some coal-firing capability. Boilers designed exclusively for oil- or gas-firing have not been considered viable candidates for coal conversion because they generally require a significant capacity derating and extensive and costly modifications. As a result, conversion of boilers in this class to coal-firing has generally been considered unattractive. Renewed interest in the prospects for converting boilers designed exclusively for oil- and gas-firing to coal firing has centered around the concept of using ``ultra fine`` coal as opposed to ``conventional grind`` pulverized coal. The main distinction being the finer particle size to which the former is ground. This fuel type may have characteristics which ameliorate many of the boiler problems normally associated with pulverized coal-firing. The overall concept for ultrafine coal utilization is based on a regional large preparation plant with distribution of a ready to fire fuel directly to many small users. This differs from normal practice in which final coal sizing is performed in pulverizers at the user`s site.

  3. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  4. Thermal upgrading of residual oil to light product and heavy residual fuel

    SciTech Connect (OSTI)

    Yan, T.Y.; Shu, P.

    1986-08-05

    The method is described of upgrading residual oil boiling in the range of 1050/sup 0/F+ comprising: thermally cracking the residual oil at a temperature of 650/sup 0/-900/sup 0/F, a pressure of 0-100 psig, and a residence time of 0.1 to 5 hours at the highest severity in the range between about 1,000-18,000 seconds, as expressed in equivalent reaction time at 800/sup 0/F, sufficient to convert at least about 50 wt% of the residual oil to light products, substantially without the formation of solid coke; recovering separate fractions of light product and emulsifiable heavy bottom product which has a fusion temperature below about 150/sup 0/C and a quinoline-insoluble content between about 10 wt% and 30 wt% and wherein the highest severity is determined by a functional relationship between the asphaltene content of the residual oil feedstock and the heavy bottom product yield and quinoline-insoluble content.

  5. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  6. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda; Janiak, Jerzy S.; Turak, Ali A.; Ignasiak, Boleslaw L.

    1990-01-01

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  7. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  8. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  9. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Patent: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Graphene-sulfur nanocomposites for rechargeable ...

  10. Oil ash corrosion; A review of utility boiler experience

    SciTech Connect (OSTI)

    Paul, L.D. ); Seeley, R.R. )

    1991-02-01

    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  11. A Study of the Use of Jatropha Oil Blends in Boilers

    SciTech Connect (OSTI)

    Krishna, C.R.

    2010-10-01

    Executive Summary: This project investigated the combustion performance of blends of unrefined Jatropha oil and its blends in laboratory boilers. Although a very limited amount of testing blends in distillate oil, ASTM No. 2 oil or heating oil was conducted, the primary interest was in testing the performance of blends with residual ASTM No. 6 oil. The basic idea is to provide a renewable fuel option to residual oil used in space heating and in industrial applications. The intent also was to explore the use of non-edible plant oil and one that might be potentially cheaper than biodiesel. The characteristics of No. 6 oil, such as high viscosity at ambient temperature, which requires it to be kept heated, make the blending with such oils feasible. Jatropha oil is one such oil and there is currently considerable interest building up in its use as a source for making biodiesel and jet fuel. A 10% blend of Jatropha oil with heating oil was burned using a standard burner in a residential boiler. Combustion performance was shown to be comparable with that of burning heating oil by itself with some noticeable differences. Typical heating oil has about 2000 ppm of sulfur, while the Jatropha oil has about 50 ppm leading to lower levels of sulphur dioxide emissions. Stack measurements also showed that the NOx emission was lower with the blend. We have previously reported similar reductions in NOx with blends of biodiesel in heating oil as well as slight reductions in PM2.5, particulates below 2.5 microns in size. Long term tests were not part of this project and hence deleterious effects on pumps, seals etc., if any, were not measured. The majority of the work involved testing blends of Jatropha oil with residual oil in a 1.5 million Btu/hr boiler with a burner modified to burn residual oil. Blends of 20 and 60% Jatropha oil and 100% Jatropha oil were burned in the combustion performance tests. The residual oil used had a sulfur content of over 2000 ppm and hence dramatic reductions in sulfur dioxide emissions are measured with the blends. Again, consistent with our past experience with biodiesel blends, significant reductions in nitrogen oxide emissions nearing 50% with 100% Jatropha oil, were also measured. This is in contrast with the use of biodiesel in diesel engines, where the NOx has a tendency to increase. In addition to the gaseous emission measurements, particulate emissions were measured using an EPA CTM-39 system to obtain both particulates, of sizes below 2.5 microns, so-called PM2.5, and of sizes larger than 2.5 microns. The results show that the particulate emissions are lower with the blending of Jatropha oil. Overall, one can conclude that the blending of Jatropha oil with residual oil is a feasible approach to using non-edible plant oil to provide a renewable content to residual oil, with significant benefits in the reduction of pollutant emissions such as sulfur dioxide, nitrogen oxides and particulates.

  12. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  14. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    Stocks by Type Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils, Kerosene & Light Gas Unfinished Oils,

  15. Process for production of synthesis gas with reduced sulfur content

    DOE Patents [OSTI]

    Najjar, Mitri S.; Corbeels, Roger J.; Kokturk, Uygur

    1989-01-01

    A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1800.degree.-2200.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises an iron-containing compound portion and a sodium-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (i) a sulfur-containing sodium-iron silicate phase and (ii) a sodium-iron sulfide phase. The sulfur capture additive may optionally comprise a copper-containing compound portion.

  16. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery

    Office of Scientific and Technical Information (OSTI)

    electrodes (Patent) | SciTech Connect sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the

  17. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fueling the Next Generation of Vehicle Technology Fueling the Next Generation of Vehicle Technology February 6, 2013 - 11:20am Addthis Professor Jack Brouwer, Associate Director and Chief Technology Officer of the National Fuel Cell Research Center, points out the tri-generation facility that uses biogas from Orange County Sanitation District’s wastewater treatment plant to produce hydrogen, heat and power. | Photo courtesy of the Energy Department. Professor Jack Brouwer, Associate

  18. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  19. Biodiesel Fuel Basics

    Broader source: Energy.gov [DOE]

    Biodiesel is a domestically produced, renewable fuel that can be manufactured from vegetable oils, animal fats, or recycled restaurant greases.

  20. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

  1. Deep desulfurization of hydrocarbon fuels

    DOE Patents [OSTI]

    Song, Chunshan; Ma, Xiaoliang; Sprague, Michael J.; Subramani, Velu

    2012-04-17

    The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

  2. Status of Heavy Vehicle Diesel Emission Control Sulfur Effects (DECSE) Test Program

    SciTech Connect (OSTI)

    George Sverdrup

    1999-06-07

    DECSE test program is well under way to providing data on effects of sulfur levels in diesel fuel on performance of emission control technologies.

  3. Heating Oil Reserve | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating Oil Reserve Heating Oil Reserve The Northeast Home Heating Oil Reserve is a one million barrel supply of ultra low sulfur distillate (diesel) that provides protection for homes and businesses in the northeastern United States should a disruption in supplies occur. The Northeast Home Heating Oil Reserve is a one million barrel supply of ultra low sulfur distillate (diesel) that provides protection for homes and businesses in the northeastern United States should a disruption in supplies

  4. Heavy oil. upgrading integrated with steam drive

    SciTech Connect (OSTI)

    Van Driesen, R.; Viens, C.H.; Fornoff, L.L.

    1980-01-01

    A study of the upgrading of heavy oil from a representative Venezuelan Jobo crude (9.2/sup 0/API, 4.1% sulfur, and 500 ppm total metals) from the Orinoco area involved 110 computer simulations based on a modified C-E Lummus Refinery Linear Program model on the assumptions of a 125,000 bbl/day refinery built, starting at 1979 prices, for completion by 1986 near the producing field to supply the fuel oil needed to provide oil field steam. All of the upgrading systems were economically attractive; the per cent return-on-investment (ROI) before taxes for the methods studied were: for Lummus LC-Fining, 135.9%; for Exxon's FLEXICOKING, 132.4%; for delayed coking, 119.2%; and for deasphalting, 106.5%. LC-Fining provided the best over-all combination of flexibility, product yield, product quality, and return on investment. The economics favored upgrading to the maximum extent possible; there was a reduction in the ROI for all the upgrading systems when product specifications were lowered from the premium base case (1.2% SO/sub 2/ emitted per million Btu fired). The premium upgraded heavy crude oils should be worth $3.00-$3.50/bbl more than comparable conventional crude oils, could be of up to 27/sup 0/API, and could be substituted, at up to 50%, for conventional crude oils in a typical U.S. refinery.

  5. Heating Oil and Propane Update

    Gasoline and Diesel Fuel Update (EIA)

    Maps of states participating in Winter Fuels Survey Residential propane PADD map Residential heating oil PADD map...

  6. The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBtu/hour oil fired boiler to pulverized coal

    SciTech Connect (OSTI)

    Zauderer, B.; Fleming, E.S.

    1991-08-30

    The project objective was to demonstrate a technology which can be used to retrofit oil/gas designed boilers, and conventional pulverized coal fired boilers to direct coal firing, by using a patented sir cooled coal combustor that is attached in place of oil/gas/coal burners. A significant part of the test effort was devoted to resolving operational issues related to uniform coal feeding, efficient combustion under very fuel rich conditions, maintenance of continuous slag flow and removal from the combustor, development of proper air cooling operating procedures, and determining component materials durability. The second major focus of the test effort was on environmental control, especially control of SO{sub 2} emissions. By using staged combustion, the NO{sub x} emissions were reduced by around 3/4 to 184 ppmv, with further reductions to 160 ppmv in the stack particulate scrubber. By injection of calcium based sorbents into the combustor, stack SO{sub 2} emissions were reduced by a maximum of of 58%. (VC)

  7. The impact of regulation on fuel quality

    SciTech Connect (OSTI)

    Jones, D.R.

    1985-02-01

    Governmental actions require significantly increased attention to keep pace with frequently changing requirements. These are dictated by environmental or political factors. The 1973 oil embargo is discussed. Both the EPA and the auto industry pay increased attention to gasoline composition factors which may affect potential for particulate reduction by fuel modification. Sulfur removal is likely to be a far more costeffective means of reducing total particulate mass than reduction of aromatics or volatility. The authors conclude that the technology needed to achieve product changes which may be mandated by government is not insurmountable.

  8. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway

    SciTech Connect (OSTI)

    Jones, Susanne B.; Meyer, Pimphan A.; Snowden-Swan, Lesley J.; Padmaperuma, Asanga B.; Tan, Eric; Dutta, Abhijit; Jacobson, Jacob; Cafferty, Kara

    2013-11-01

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  9. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels: Fast Pyrolysis and Hydrotreating Bio-oil Pathway

    SciTech Connect (OSTI)

    Jones, S.; Meyer, P.; Snowden-Swan, L.; Padmaperuma, A.; Tan, E.; Dutta, A.; Jacobson, J.; Cafferty, K.

    2013-11-01

    This report describes a proposed thermochemical process for converting biomass into liquid transportation fuels via fast pyrolysis followed by hydroprocessing of the condensed pyrolysis oil. As such, the analysis does not reflect the current state of commercially-available technology but includes advancements that are likely, and targeted to be achieved by 2017. The purpose of this study is to quantify the economic impact of individual conversion targets to allow a focused effort towards achieving cost reductions.

  10. Turbine fuels from tar sands bitumen and heavy oil. Phase I. Preliminary process analysis. Interim report, 8 July 1983-9 April 1984

    SciTech Connect (OSTI)

    Talbot, A.F.; Elanchenny, V.; Macris, A.; Schwedock, J.P.

    1985-04-09

    The strategic potential of domestic bitumens and heavy crude oils as substitutes for imported crude rests with their efficient conversion into aviation turbine fuels. In this Phase I study, preliminary analyses of several processing schemes were performed. The comparison included both hydrogen-addition and carbon-rejection upgrading processes. Projected JP-4 yields, costs, and thermal efficiencies suggest further exploration of the hydrovisbreaking process. For Phase II, laboratory-scale demonstration of the recommended process is proposed.

  11. Sulfur recovery process

    SciTech Connect (OSTI)

    Hise, R.E.; Cook, W.J.

    1991-06-04

    This paper describes a method for recovering sulfur from a process feed stream mixture of gases comprising sulfur-containing compounds including hydrogen sulfide using the Claus reaction to convert sulfur-containing compounds to elemental sulfur and crystallization to separate sulfur-containing compounds from a tail gas of the Claus reaction for further processing as a recycle stream. It comprises: providing a Claus feed stream containing a stoichiometric excess of hydrogen sulfide, the Claus feed stream including the process feed stream and the recycles stream; introducing the Claus feed stream and an oxidizing agent into a sulfur recovery unit for converting sulfur-containing compounds in the Claus feed stream to elemental sulfur; withdrawing the tail gas from the sulfur recovery unit; separating water from the tail gas to producing a dehydrated tail gas; separating sulfur-containing compounds including carbonyl sulfide from the dehydrated tail gas as an excluded material by crystallization and withdrawing an excluded material-enriched output from the crystallization to produce the recycle stream; and combining the recycle stream with the process feed stream to produce the Claus feed stream.

  12. RTP Green Fuel: A Proven Path to Renewable Heat and Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Fuel Oil - A Commercial Perspective Steve Lupton Technical Information Exchange on Pyrolysis Oil: Potential for a Renewable Heating Oil Substitution Fuel in New ...

  13. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2008-03-31

    The final report summarizes the accomplishments toward project goals during length of the project. The goal of this project was to integrate coal into a refinery in order to produce coal-based jet fuel, with the major goal to examine the products other than jet fuel. These products are in the gasoline, diesel and fuel oil range and result from coal-based jet fuel production from an Air Force funded program. The main goal of Task 1 was the production of coal-based jet fuel and other products that would need to be utilized in other fuels or for non-fuel sources, using known refining technology. The gasoline, diesel fuel, and fuel oil were tested in other aspects of the project. Light cycle oil (LCO) and refined chemical oil (RCO) were blended, hydrotreated to removed sulfur, and hydrogenated, then fractionated in the original production of jet fuel. Two main approaches, taken during the project period, varied where the fractionation took place, in order to preserve the life of catalysts used, which includes (1) fractionation of the hydrotreated blend to remove sulfur and nitrogen, followed by a hydrogenation step of the lighter fraction, and (2) fractionation of the LCO and RCO before any hydrotreatment. Task 2 involved assessment of the impact of refinery integration of JP-900 production on gasoline and diesel fuel. Fuel properties, ignition characteristics and engine combustion of model fuels and fuel samples from pilot-scale production runs were characterized. The model fuels used to represent the coal-based fuel streams were blended into full-boiling range fuels to simulate the mixing of fuel streams within the refinery to create potential 'finished' fuels. The representative compounds of the coal-based gasoline were cyclohexane and methyl cyclohexane, and for the coal-base diesel fuel they were fluorine and phenanthrene. Both the octane number (ON) of the coal-based gasoline and the cetane number (CN) of the coal-based diesel were low, relative to commercial fuels ({approx}60 ON for coal-based gasoline and {approx}20 CN for coal-based diesel fuel). Therefore, the allowable range of blending levels was studied where the blend would achieve acceptable performance. However, in both cases of the coal-based fuels, their ignition characteristics may make them ideal fuels for advanced combustion strategies where lower ON and CN are desirable. Task 3 was designed to develop new approaches for producing ultra clean fuels and value-added chemicals from refinery streams involving coal as a part of the feedstock. It consisted of the following three parts: (1) desulfurization and denitrogenation which involves both new adsorption approach for selective removal of nitrogen and sulfur and new catalysts for more effective hydrotreating and the combination of adsorption denitrogenation with hydrodesulfurization; (2) saturation of two-ring aromatics that included new design of sulfur resistant noble-metal catalysts for hydrogenation of naphthalene and tetralin in middle distillate fuels, and (3) value-added chemicals from naphthalene and biphenyl, which aimed at developing value-added organic chemicals from refinery streams such as 2,6-dimethylnaphthalene and 4,4{prime}-dimethylbiphenyl as precursors to advanced polymer materials. Major advances were achieved in this project in designing the catalysts and sorbent materials, and in developing fundamental understanding. The objective of Task 4 was to evaluate the effect of introducing coal into an existing petroleum refinery on the fuel oil product, specifically trace element emissions. Activities performed to accomplish this objective included analyzing two petroleum-based commercial heavy fuel oils (i.e., No. 6 fuel oils) as baseline fuels and three co-processed fuel oils, characterizing the atomization performance of a No. 6 fuel oil, measuring the combustion performance and emissions of the five fuels, specifically major, minor, and trace elements when fired in a watertube boiler designed for natural gas/fuel oil, and determining the boiler performance when firing the five fuels. Two different co-processed fuel oils were tested: one that had been partially hydrotreated, and the other a product of fractionation before hydrotreating. Task 5 focused on examining refining methods that would utilize coal and produce thermally stable jet fuel, included delayed coking and solvent extraction. Delayed coking was done on blends of decant oil and coal, with the goal to produce a premium carbon product and liquid fuels. Coking was done on bench scale and large laboratory scale cokers. Two coals were examined for co-coking, using Pittsburgh seam coal and Marfork coal product. Reactions in the large, laboratory scaled coker were reproducible in yields of products and in quality of products. While the co-coke produced from both coals was of sponge coke quality, minerals left in the coke made it unacceptable for use as anode or graphite grade filler.

  14. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  15. Determination of alternative fuels combustion products: Phase 3 report

    SciTech Connect (OSTI)

    Whitney, K.A.

    1997-12-01

    This report describes the laboratory efforts to characterize particulate and gaseous exhaust emissions from a passenger vehicle operating on alternative fuels. Tests were conducted at room temperature (nominally 72 F) and 20 F utilizing the chassis dynamometer portion of the FTP for light-duty vehicles. Fuels evaluated include Federal RFG, LPG meeting HD-5 specifications, a national average blend of CNG, E85, and M85. Exhaust particulate generated at room temperature was further characterized to determine polynuclear aromatic content, trace element content, and trace organic constituents. For all fuels except M85, the room temperature particulate emission rate from this vehicle was about 2 to 3 mg/mile. On M85, the particulate emission rate was more than 6 mg/mile. In addition, elemental analysis of particulate revealed an order of magnitude more sulfur and calcium from M85 than any other fuel. The sulfur and calcium indicate that these higher emissions might be due to engine lubricating oil in the exhaust. For RFG, particulate emissions at 20 F were more than six times higher than at room temperature. For alcohol fuels, particulate emissions at 20 F were two to three times higher than at room temperature. For CNG and LPG, particulate emissions were virtually the same at 72 F and 20 F. However, PAH emissions from CNG and LPG were higher than expected. Both gaseous fuels had larger amounts of pyrene, 1-nitropyrene, and benzo(g,h,i)perylene in their emissions than the other fuels.

  16. Total

    U.S. Energy Information Administration (EIA) Indexed Site

    Fuel Kerosene Distillate Fuel Oil Distillate Fuel Oil, 15 ppm Sulfur and Under Distillate Fuel Oil, Greater than 15 ppm to 500 ppm Sulfur Distillate Fuel Oil, Greater than 500 ppm ...

  17. Global Alternative Fuels | Open Energy Information

    Open Energy Info (EERE)

    Alternative Fuels Jump to: navigation, search Name: Global Alternative Fuels Place: El Paso, Texas Zip: 79922 Product: Global Alternative Fuels processes virgin oils (palm,...

  18. Solid oxide fuel cell process and apparatus

    DOE Patents [OSTI]

    Cooper, Matthew Ellis; Bayless, David J.; Trembly, Jason P.

    2011-11-15

    Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H.sub.2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H.sub.2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.

  19. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Gas Efficient recovery of our nation's fossil fuel resources in an environmentally safe manner requires the development and application of new technologies that address the ...

  20. ADVANCED SULFUR CONTROL CONCEPTS

    SciTech Connect (OSTI)

    Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

    2003-01-01

    Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

  1. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  2. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  3. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  4. Microbial desulfurization of Eastern oil shale: Bioreactor studies

    SciTech Connect (OSTI)

    Maka, A.; Akin, C.; Punwani, D.V.; Lau, F.S.; Srivastava, V.J.

    1989-01-01

    The removal of sulfur from Eastern oil shale (40 microns particle size) slurries in bioreactors by mixed microbial cultures was examined. A mixed culture that is able to remove the organic sulfur from model sulfur compounds presenting coal as well as a mixed culture isolated from oil shale enrichments were evaluated. The cultures were grown in aerobic fed-batch bioreactors where the oil shale served as the source of all nutrients except organic carbon. Glucose was added as an auxiliary carbon source. Microbial growth was monitored by plate counts, the pH was checked periodically, and oil shale samples were analyzed for sulfur content. Results show a 24% reduction in the sulfur content of the oil shale after 14 days. The settling characteristics of the oil shale in the bioreactors were examined in the presence of the microbes. Also, the mixing characteristics of the oil shale in the bioreactors were examined. 10 refs., 6 figs., 5 tabs.

  5. Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel

    Office of Scientific and Technical Information (OSTI)

    oil (Patent) | SciTech Connect Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel oil Citation Details In-Document Search Title: Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel oil An improved fuel composition is provided comprising in minor proportion a non-dewatered sewage sludge and in major proportion an organic fuel comprised of a hydrocarbon fuel oil. A method is also provided for the incineration of sewage sludge comprised of providing

  6. Behavior of carbonate-rich fuels in ACFBC and PFBC conditions

    SciTech Connect (OSTI)

    Ots, A.; Arro, H.; Pihu, T.; Prikk, A.

    1999-07-01

    Estonian oil shale is known as one of richest in carbonate fuels. High mineral matter content (60--75% in dry mass), moderate moisture (9--12%) and carbonate carbon dioxide content (17--19%), and low heating value (LHV 8--10 MJ/kg as received) are characteristic for Estonian oil shale. Approximately half of the mineral matter is in the carbonate form, mainly as calcium carbonate. The sulfur content of dry mass is 1.5--1.7% and Ca/S molar ratio is 8--10. Due to limestone present in oil shale, the additional sorbent for sulfur retention during combustion is not needed. The behavior of carbonates as well as the formation of ash at fluidized bed combustion (FBC) was the main topics to study. At Thermal Engineering Department (TED) of Tallinn Technical University a laboratory pressurized combustion facility was used for investigation the decomposition of soil shale carbonates in atmospheric and pressurized burning conditions. The experiments with oil shale were performed at pressures 0.1 MPa and 1.2 MPa and at the temperature 850 C. Based on the carbonate decomposition rate (CDR) 0.3--0.4 established experimentally at pressurized combustion, it may be concluded that the heating value of oil shale increases approximately by 5.5--8% and the carbon dioxide concentration in flue gas decreases by 13--20% compared with the conditions of the complete decomposition of carbonate. Combustion of oil shale was tested in 0.15--1.0 MW{sub th} test facilities. The tests confirmed the suitability of both ACFBC and PFBC technologies to utilize oil shale. The tests showed a nearly complete binding of sulfur by oil shale ash and a limited formation of NO{sub x} at combustion. Oil shale FBC is characterized by the formation of large amounts (40--85% from total) of fine-grained fly ash.

  7. Gasoline and Diesel Fuel Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Even when crude oil prices are stable... read more in Gasoline Explained What causes fluctuations in diesel fuel oil prices? The retail price of a gallon of diesel fuel reflects ...

  8. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  9. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E.; Jalan, Vinod M.

    1984-01-01

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  10. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  11. Bacterial Sulfur Storage Globules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as

  12. MECS Fuel Oil Tables

    U.S. Energy Information Administration (EIA) Indexed Site

    202-586-0018 URL: http:www.eia.govemeuconsumptionbriefsmecsmecsfueloiltables.html For questions about content, please contact the National Energy Information Center:...

  13. MECS Fuel Oil Figures

    U.S. Energy Information Administration (EIA) Indexed Site

    Energy Consumption Survey (MECS): Consumption of Energy; U.S. Department of Commerce, Bureau of the Census, Annual Survey of Manufactures (ASM): Statistics for Industry...

  14. fuel_oil.pdf

    Gasoline and Diesel Fuel Update (EIA)

    (toll free) at 1-888-861-0464. For general information about the survey, visit our Web site at http:www.eia.doe.govemeucbecs. 6. Please use the enclosed self-addre ssed, ...

  15. Biogenic sulfur source strengths

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.; Bamesberger, W.L.

    1981-12-01

    Conclusions are presented from a 4-yr field measurement study of biogenic sulfur gas emissions from soils, and some water and vegetated surfaces, at 35 locales in the eastern and southeastern United States. More than one soil order was examined whenever possible to increase the data base obtained from the 11 major soil orders comprising the study area. Data analysis and emission model development were based upon an (80 x 80)-km/sup 2/ grid system. The measured sulfur fluxes, adjusted for the annual mean temperature for each sampling locale, weigted by the percentage of each soil order within each grid, and averaged for each of the east-west grid tiers from 47/sup 0/N to 25/sup 0/N latitude, showed an exponential north-to-south increase in total sulfur gas flux. Our model predits an additional increase of nearly 25-fold in sulfur flux between 25/sup 0/N and the equator.

  16. Technical Information Exchange on Pyrolysis Oil: Potential for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewab;e Heating Oil Substation Fuel in New England Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England This ...

  17. Separation of sulfur isotopes

    DOE Patents [OSTI]

    DeWitt, Robert; Jepson, Bernhart E.; Schwind, Roger A.

    1976-06-22

    Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    for a pilot program to operate Type II school buses that are retrofitted with an auxiliary fuel tank to enable the use of biodiesel, waste vegetable oil, or straight vegetable oil. ...

  19. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  20. Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution

    Broader source: Energy.gov [DOE]

    Two-day agenda from the workshop: Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution fuel in New England.

  1. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    F9: Residual Fuel Oil Consumption Estimates, 2014 State Commercial Industrial Transportation Electric Power Total Commercial Industrial Transportation Electric Power Total Thousand ...

  2. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    0: Residual Fuel Oil Price and Expenditure Estimates, 2014 State Prices Expenditures Commercial Industrial Transportation Electric Power Total Commercial Industrial Transportation ...

  3. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which assigns a RIN to each gallon of renewable fuel. Entities regulated by RFS include oil refiners, blenders, and gasoline and diesel importers. The volumes required of each...

  4. Further experience for environmental improvement in fossil fuel combustion

    SciTech Connect (OSTI)

    Lazzeri, L.; Santis, R. de

    1998-12-31

    Reburning is a technology which has proven, by plant demonstration, capable of providing compliance with very stringent regulatory emissions requests (less than 90 ppm NO{sub x} firing oil and gas and less than 160--170 ppm firing coal). Designing a Reburn System requires a contemporary control of many parameters like flow rates, local stoichiometries residence times, etc.; it also requires the availability and capability of using complex and sophisticated numerical modeling. Although the system can be adapted to any already installed hardware it should be noted that the availability of reliable LNB`s and of specifically designed OFA`s and Reburn fuel injectors can greatly enhance the system performance. Design of OFA system is a subcase of a Reburn System design, as it implies same concepts of mixing and residence times which are the basis of Reburn System. As shown in the cases previously presented Reburning always provides additional margins to OFA operation specifically when very low emission limits are pursued. Finally it should be noted that the use of Reburning may create problems of unburned specifically when very low local stoichiometries and when very low sulfur oils are used which are often characterized by asphaltene instability especially when STZ oil is the result of blending high and low sulfur oils. A specific know-how has been jointly developed by Ansaldo and ENEL to solve these problems acting on both atomizer type selection and operation.

  5. Method for storing spent nuclear fuel in repositories

    DOE Patents [OSTI]

    Schweitzer, D.G.; Sastre, C.; Winsche, W.

    A method for storing radioactive spent fuel in repositories containing sulfur as the storage medium is disclosed. Sulfur is non-corrosive and not subject to radiation damage. Thus, storage periods of up to 100 years are possible.

  6. Vegetable oils for tractors

    SciTech Connect (OSTI)

    Moroney, M.

    1981-11-14

    Preliminary tests by the Agricultural Institute, show that tractors can be run on a 50:50 rape oil-diesel mixture or on pure rape oil. In fact, engine power actually increased slightly with the 50:50 blend but decreased fractionally with pure rape oil. Research at the North Dakota State University on using sunflower oil as an alternative to diesel fuel is also noted.

  7. untitled

    U.S. Energy Information Administration (EIA) Indexed Site

    a Propane (Consumer Grade) Residual Fuel Oil Sulfur Less Than or Equal to 1 Percent Sulfur Greater Than 1 Percent Total Residual Fuel Oil United States January...

  8. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Mikkor, Mati

    1981-01-01

    This disclosure is directed to an improvement in a sodium sulfur battery construction in which a seal between various battery compartments is made by a structure in which a soft metal seal member is held in a sealing position by holding structure. A pressure applying structure is used to apply pressure on the soft metal seal member when it is being held in sealing relationship to a surface of a container member of the sodium sulfur battery by the holding structure. The improvement comprises including a thin, well-adhered, soft metal layer on the surface of the container member of the sodium sulfur battery to which the soft metal seal member is to be bonded.

  9. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Yun; Yu, Qiquan; Chang, Shih-Ger

    1996-01-01

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

  10. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Poe, R.L.; Morrison, J.L.; Xie, Jianyang; Walsh, P.M.; Schobert, H.H.; Scaroni, A.W.

    1992-05-29

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in an oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels.

  11. Releases from the Heating Oil Reserve

    Broader source: Energy.gov [DOE]

    The Northeast Home Heating Oil Reserve (NEHHOR), a one million barrel supply of ultra low sulfur distillate (diesel), was created to build a buffer to allow commercial companies to compensate for...

  12. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Poe, R.L.; Morrison, J.L.; Xie, J.; Walsh, P.M.; Wincek, R.T.; Clark, D.A.; Scaroni, A.W.

    1993-04-21

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for heavy fuel oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) program expansion (additional 1,000 hours of testing). The boiler testing wig determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting boilers will be identified

  13. Virent is Replacing Crude Oil

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virent 2014 Virent is Replacing Crude Oil. Biomass 2014 July 30, 2014 Randy D. Cortright, ... Plants Partners & Investors Converting plant-based feedstocks to fuels and chemicals 75 ...

  14. Biomass Feedstocks for Renewable Fuel Production: A review of the impacts of feedstock and pretreatment on the yield and product distribution of fast pyrolysis bio-oils and vapors

    SciTech Connect (OSTI)

    Daniel Carpenter; Stefan Czernik; Whitney Jablonski; Tyler L. Westover

    2014-02-01

    Renewable transportation fuels from biomass have the potential to substantially reduce greenhouse gas emissions and diversify global fuel supplies. Thermal conversion by fast pyrolysis converts up to 75% of the starting plant material (and its energy content) to a bio-oil intermediate suitable for upgrading to motor fuel. Woody biomass, by far the most widely-used and researched material, is generally preferred in thermochemical processes due to its low ash content and high quality bio-oil produced. However, the availability and cost of biomass resources, e.g. forest residues, agricultural residues, or dedicated energy crops, vary greatly by region and will be key determinates in the overall economic feasibility of a pyrolysis-to-fuel process. Formulation or blending of various feedstocks, combined with thermal and/or chemical pretreatment, could facilitate a consistent, high-volume, lower-cost biomass supply to an emerging biofuels industry. However, the impact of biomass type and pretreatment conditions on bio-oil yield and quality, and the potential process implications, are not well understood. This literature review summarizes the current state of knowledge regarding the effect of feedstock and pretreatments on the yield, product distribution, and upgradability of bio-oil.

  15. Sodium sulfur battery seal

    DOE Patents [OSTI]

    Topouzian, Armenag

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which a flexible diaphragm sealing elements respectively engage opposite sides of a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  16. SULFUR POLYMER ENCAPSULATION.

    SciTech Connect (OSTI)

    KALB, P.

    2001-08-22

    Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

  17. Process for forming sulfuric acid

    DOE Patents [OSTI]

    Lu, Wen-Tong P.

    1981-01-01

    An improved electrode is disclosed for the anode in a sulfur cycle hydrogen generation process where sulfur dioxie is oxidized to form sulfuric acid at the anode. The active compound in the electrode is palladium, palladium oxide, an alloy of palladium, or a mixture thereof. The active compound may be deposited on a porous, stable, conductive substrate.

  18. Chapter 4. Fuel Economy, Consumption and Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    national concerns about dependence on foreign oil and the deleterious effect on the environment of fossil fuel combustion, residential vehicle fleet fuel consumption was...

  19. AgriFuel Company | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: AgriFuel Company Place: Cranford, New Jersey Sector: Biofuels Product: AgriFuel produces and markets biofuels refined from waste vegetable oil,...

  20. Straight Vegetable Oil as a Vehicle Fuel? (Fact Sheet), Energy Efficiency & Renewable Energy (EERE), Vehicle Technologies Office (VTO)

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Performance of SVO Research has shown that there are sev- eral technical barriers to widespread use of SVO as a vehicle fuel. The published engineering literature strongly indicates that the use of SVO leads to reduced engine life, 1 caused by the buildup of carbon deposits inside the engine and the buildup of SVO in the engine lubricant. These issues are attributable to SVO's high viscosity and high boiling point relative to the required boiling range for diesel fuel. The carbon buildup doesn't

  1. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  2. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  3. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-05-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  4. Gasoline and Diesel Fuel Update

    Gasoline and Diesel Fuel Update (EIA)

    Procedures, Methodology, and Coefficients of Variation Diesel Fuel Price Data Collection Procedures Every Monday, cash self-serve on-highway diesel prices (including taxes) are collected from a sample of approximately 400 retail diesel outlets in the continental U.S. The sample includes a combination of truck stops and service stations that sell on-highway diesel fuel. The data represent the price of ultra low sulfur diesel (ULSD) which contains less than 15 parts-per-million sulfur. The prices

  5. Development of a 5 kW Prototype Coal-Based Fuel Cell

    SciTech Connect (OSTI)

    Chuang, Steven S.C.; Mirzababaei, Jelvehnaz; Rismanchian, Azadeh

    2014-01-20

    The University of Akron Fuel Cell Laboratory pioneered the development of a laboratory scale coal-based fuel cell, which allows the direct use of high sulfur content coal as fuel. The initial research and coal fuel cell technology development (“Coal-based Fuel Cell,” S. S. C. Chuang, PCT Int. Appl. 2006, i.e., European Patent Application, 35 pp. CODEN: PIXXD2 WO 2006028502 A2 20060316) have demonstrated that it is feasible to electrochemically oxidize carbon to CO2, producing electricity. The key innovative concept of this coal-based fuel cell technology is that carbon in coal can be converted through an electrochemical oxidation reaction into manageable carbon dioxide, efficiently generating electricity without involving coal gasification, reforming, and water-gas shift reaction. This study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reaction. A carbon injection system was developed to inject the solid fuel without bringing air into the anode chamber; a fuel cell stack was developed and tested to demonstrate the feasibility of the fuel cell stack. Further improvement of anode catalyst activity and durability is needed to bring this novel coal fuel cell to a highly efficient, super clean, multi-use electric generation technology, which promises to provide low cost electricity by expanding the utilization of U.S. coal supplies and relieving our dependence on foreign oil.

  6. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  7. Natural Gas and Crude Oil Prices in AEO (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    If oil and natural gas were perfect substitutes in all markets where they are used, market forces would be expected to drive their delivered prices to near equality on an energy-equivalent basis. The price of West Texas Intermediate (WTI) crude oil generally is denominated in terms of barrels, where 1 barrel has an energy content of approximately 5.8 million Btu. The price of natural gas (at the Henry Hub), in contrast, generally is denominated in million Btu. Thus, if the market prices of the two fuels were equal on the basis of their energy contents, the ratio of the crude oil price (the spot price for WTI, or low-sulfur light, crude oil) to the natural gas price (the Henry Hub spot price) would be approximately 6.0. From 1990 through 2007, however, the ratio of natural gas prices to crude oil prices averaged 8.6; and in the Annual Energy Outlook 2009 projections from 2008 through 2030, it averages 7.7 in the low oil price case, 14.6 in the reference case, and 20.2 in the high oil price case.

  8. Technical Information Exchange on Pyrolysis Oil: Potential for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Two-day agenda from the workshop: Technical Information Exchange on Pyrolysis Oil: Potential for a renewable heating oil substitution fuel in New England. PDF icon ...

  9. Providential Energy Corp formerly Providential Oil Gas Inc |...

    Open Energy Info (EERE)

    (formerly Providential Oil & Gas Inc) Place: California Sector: Hydro Product: Focused on natural gas and crude oil; expanding into hydropower, fuel cells, and ethanol. References:...

  10. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to 2.84 per gallon, down 5.4 cents from last week

  11. Fuel Mix and Emissions Disclosure | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    customers the fuel mix of its electricity production and the associated sulfur dioxide, nitrogen oxide, and carbon dioxide emissions emissions, expressed in pounds per 1000...

  12. Superclean coal-water slurry combustion testing in an oil-fired boiler

    SciTech Connect (OSTI)

    Miller, B.G.; Schobert, H.H.

    1990-09-28

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program with the objective of demonstrating the capability of effectively firing SCCWS in industrial boilers designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0% ash and 0.9% sulfur) can effectively be burned in oil-designed industrial boilers without adverse impact on boiler rating, maintainability, reliability and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of three phases: (1) design, permitting, and test planning, (2) construction and start up, and (3) demonstration and evaluation. The boiler testing will determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting and operating boilers will be identified to assess the viability of future oil-to-coal retrofits. Progress is reported. 7 refs., 7 figs., 1 tab.

  13. Estimating Impacts of Diesel Fuel Reformulation with Vector-based Blending

    SciTech Connect (OSTI)

    Hadder, G.R.

    2003-01-23

    The Oak Ridge National Laboratory Refinery Yield Model has been used to study the refining cost, investment, and operating impacts of specifications for reformulated diesel fuel (RFD) produced in refineries of the U.S. Midwest in summer of year 2010. The study evaluates different diesel fuel reformulation investment pathways. The study also determines whether there are refinery economic benefits for producing an emissions reduction RFD (with flexibility for individual property values) compared to a vehicle performance RFD (with inflexible recipe values for individual properties). Results show that refining costs are lower with early notice of requirements for RFD. While advanced desulfurization technologies (with low hydrogen consumption and little effect on cetane quality and aromatics content) reduce the cost of ultra low sulfur diesel fuel, these technologies contribute to the increased costs of a delayed notice investment pathway compared to an early notice investment pathway for diesel fuel reformulation. With challenging RFD specifications, there is little refining benefit from producing emissions reduction RFD compared to vehicle performance RFD. As specifications become tighter, processing becomes more difficult, blendstock choices become more limited, and refinery benefits vanish for emissions reduction relative to vehicle performance specifications. Conversely, the emissions reduction specifications show increasing refinery benefits over vehicle performance specifications as specifications are relaxed, and alternative processing routes and blendstocks become available. In sensitivity cases, the refinery model is also used to examine the impact of RFD specifications on the economics of using Canadian synthetic crude oil. There is a sizeable increase in synthetic crude demand as ultra low sulfur diesel fuel displaces low sulfur diesel fuel, but this demand increase would be reversed by requirements for diesel fuel reformulation.

  14. Total Crude Oil and Petroleum Products Exports

    U.S. Energy Information Administration (EIA) Indexed Site

    Exports Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Unfinished Oils Naphthas and Lighter

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Tax Exemption Biodiesel blends containing at least 20% biodiesel derived from used cooking oil are exempt from the $0.30 per gallon state fuel excise tax. The exemption does not apply to fuel used in vehicles with a gross vehicle weight rating of 26,001 pounds or more, fuel not sold in retail operations, or fuel sold in operations involving fleet fueling or bulk sales. The exemption expires after December 31, 2019. (Reference Oregon Revised Statutes 319.530

  16. Qualification of Alternative Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Qualification of Alternative Fuels May 8, 2012 Pyrolysis Oil Workshop Thomas Butcher Sustainable Energy Technologies Department Applications Baseline - Residential and Light Commercial Pressure-atomized burners with 100-150 psi fuel pressure, no fuel heating; Cyclic operation - to 12,000 cycles per year; Fuel filtration to 90 microns or finer; Storage for periods of 1 year, possibly longer; Storage temperature varied; Visible range flame detection for safety; Nitrile seal materials common; Fuels

  17. Qualification of Alternative Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Qualification of Alternative Fuels Qualification of Alternative Fuels Thomas Butcher presentation on May 8, 2012 at the Pyrolysis Oil Workshop on the qualification of alternative fuels. PDF icon pyrolysis_butcher.pdf More Documents & Publications Technical Information Exchange on Pyrolysis Oil: Potential for a Renewab;e Heating Oil Substation Fuel in New England Biodiesel_Fuel_Management_Best_Practices_Report.pdf Known Challenges Associated with the Production, Transportation, Storage and

  18. Catalyst for the reduction of sulfur dioxide to elemental sulfur

    DOE Patents [OSTI]

    Jin, Y.; Yu, Q.; Chang, S.G.

    1996-02-27

    The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

  19. Turbine fuels from tar sands bitumen and heavy oil. Volume 1. Phase 3. Pilot plant testing, final design, and economics. Final report, 1 June 1985-31 March 1987

    SciTech Connect (OSTI)

    Talbot, A.F.; Carson, T.C.; Magill, L.G.; Swesey, J.R.

    1987-08-01

    Pilot-plant-scale demonstration of an upgrading/refining scheme to convert bitumen or heavy crude oil into high yields of specification-quality aviation turbine fuel was performed. An atmospheric residue from San Ardo (California) crude was converted under hydrovisbreaking conditions to synthetic crude for further refining. Naphtha cuts from the straight run and synthetic crude were combined, catalytically hydrotreated, then hydrocracked. Products from these operations were combined to produce two prototype specification fuels (JP-4 and JP-8) as well as two heavier, variable-quality fuels. An engineering design (Volume II) was developed for a 50,000 BPSD grass-roots refinery, from the pilot-plant operations. Capital investment and operating costs were estimated, and fuel manufacturing costs projected. Conclusions and recommendations for further work are included.

  20. Rheology and stability of SRC residual fuel oils - storage evaluation. SRC-1 quarterly technical report, October-December 1982. Supplement

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-06-01

    In Air Products ongoing study to characterize the rheology and stability of various SRC residual oils, single-phase blends of 50 wt % HSRC and TSL SRC in 1:1 mixtures of 1st- and 2nd-stage process solvents were subjected to storage stability tests at 150/sup 0/F in nitrogen and air atmospheres. Using viscosity as an indicator, it was observed that the blends studied increased in viscosity with storage time in an air atmosphere; the viscosity increase began after a 4-week storage period. The increase in HSRC blend viscosity was significantly greater than that of the TSL SRC blend. A 60-day air-stored blend will require a pumping temperature about 10/sup 0/F higher than that specified for an unaged blend in order to have the same viscosity. The viscosity increase under nitrogen storage was relatively insignificant. Nitrogen blanketing appears to be important in maintaining the specified viscosity characteristics of the blends during storage in the 150/sup 0/F storage condition tested. A loss of volatiles undoubtedly occurs during high-temperature storage under laboratory conditions. Such losses contribute to an increase in the viscosity of the blend. In commercial practice, volatile losses are expected to be significantly lower. Solvent extraction data and analysis of separated fractions suggest that during storage under the above conditions, some oxidative polymerization of pentane-soluble oil components forms higher molecular weight pentane insolubles (asphaltenes and benzene insolubles). Asphaltenes are also involved in the increase in viscosity and do chemically change. 1 reference, 8 figures, 27 tables.

  1. Past, Present, and Future Production of Bio-oil (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Practitioners have at-tempted to utilize raw bio-oil as a fuel; they have also applied many techniques to upgrade bio-oil to a fuel. Attempts to utilize raw bio-oil as a combustion ...

  2. Greenhouse gases, Regulated Emissions, and Energy use in Transportation fuel-cyl

    Energy Science and Technology Software Center (OSTI)

    2000-06-20

    The GREET model estimates the full fuel-cycle energy use and emissions associated with various transportation fuels and advanced vehile technologies applied to motor vehicles. GREET 1.5 includes the following cycles: petroleum to conventional gasoline, reformulated gasoline, conventional diesel, reformulated diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied natural gas, liquefied petroleum gas, methanol, Fischer-Tropsch diesel, dimethyl ether, hydrogen, and electricity; coal to electricity; corn, woody biomass, andmore » herbaceous biomass to ethanol; soybeans to biodiesel; flared gas to methanol, Fischer-Tropsch diesel, and dimethyl ether; and landfill gases to methanol. For a given fuel/transportation technology combination, GREET 1.5 calculates (1) the fuel-cycle consumption of total energy (all energy sources), fossil fuels (petroleum, natural gas, and coal), and petroleum; (2) the fuel-cycle emissions of GHGs -- primarily carbon dioxide (CO2), methane (CH4), and nitrous oxide (N20); and (3) the fuel-cycle emissions of five criteria pollutants: volatile organic compounds (VOCs), carbon monoxide (C0), nitrogen oxides (N0x), sulfur oxides (S0x), and particulate matter with a diameter measuring 10 micrometers or less (PM10). The model is designed to readily allow researchers to input their own assumptions and generate fuel-cycle energy and emission results for specified fuel/technology combinations.« less

  3. Greenhouse gases, Regulated Emissions, and Energy use in Transportation fuel-cyl

    SciTech Connect (OSTI)

    Wang, Michael

    2000-06-20

    The GREET model estimates the full fuel-cycle energy use and emissions associated with various transportation fuels and advanced vehile technologies applied to motor vehicles. GREET 1.5 includes the following cycles: petroleum to conventional gasoline, reformulated gasoline, conventional diesel, reformulated diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied natural gas, liquefied petroleum gas, methanol, Fischer-Tropsch diesel, dimethyl ether, hydrogen, and electricity; coal to electricity; corn, woody biomass, and herbaceous biomass to ethanol; soybeans to biodiesel; flared gas to methanol, Fischer-Tropsch diesel, and dimethyl ether; and landfill gases to methanol. For a given fuel/transportation technology combination, GREET 1.5 calculates (1) the fuel-cycle consumption of total energy (all energy sources), fossil fuels (petroleum, natural gas, and coal), and petroleum; (2) the fuel-cycle emissions of GHGs -- primarily carbon dioxide (CO2), methane (CH4), and nitrous oxide (N20); and (3) the fuel-cycle emissions of five criteria pollutants: volatile organic compounds (VOCs), carbon monoxide (C0), nitrogen oxides (N0x), sulfur oxides (S0x), and particulate matter with a diameter measuring 10 micrometers or less (PM10). The model is designed to readily allow researchers to input their own assumptions and generate fuel-cycle energy and emission results for specified fuel/technology combinations.

  4. Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Oil Upgrading Conversion Technologies for Advanced Biofuels - Bio-Oil Upgrading PNNL report-out at the CTAB webinar on Bio-Oil Upgrading. PDF icon ctab_webinar_bio_oils_upgrading.pdf More Documents & Publications Conversion Technologies for Advanced Biofuels - Bio-Oil Production Thermochemical Conversion Proceeses to Aviation Fuels 2013 Peer Review Presentations-Bio-oil

  5. Evaluation of Sulfur in Syngas

    SciTech Connect (OSTI)

    None

    2006-04-01

    This project will define the options and costs at different scales of technology that can be used to remove sulfur from syngas.

  6. Chemical kinetics and oil shale process design

    SciTech Connect (OSTI)

    Burnham, A.K.

    1993-07-01

    Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

  7. The microbial upgrading of model heavy oils

    SciTech Connect (OSTI)

    Webster, I.A.; Patras, L.E. )

    1988-01-01

    The authors have isolated bacteria and used them to catalyze the removal of sulfur, nitrogen and nickel from model heavy oils and asphaltenes. Their paper will discuss their activity and reactor concepts. The concept of a membrane bioreactor for oil processing is introduced.

  8. AEO Early Release 2013 - oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Growing U.S. oil output and rising vehicle fuel economy to cut U.S. reliance on foreign oil The United States is expected to continue cutting its dependence on petroleum and liquid fuels imports over the rest of this decade because of growing domestic crude oil production and more fuel-efficient vehicles on America's highways. The new long-term outlook from the U.S. Energy Information Administration shows America's dependence on imported petroleum and liquid fuels will decline from 45 percent of

  9. RECENT ADVANCES IN THE DEVELOPMENT OF THE HYBRID SULFUR PROCESS FOR HYDROGEN PRODUCTION

    SciTech Connect (OSTI)

    Hobbs, D.

    2010-07-22

    Thermochemical processes are being developed to provide global-scale quantities of hydrogen. A variant on sulfur-based thermochemical cycles is the Hybrid Sulfur (HyS) Process, which uses a sulfur dioxide depolarized electrolyzer (SDE) to produce the hydrogen. In the HyS Process, sulfur dioxide is oxidized in the presence of water at the electrolyzer anode to produce sulfuric acid and protons. The protons are transported through a cation-exchange membrane electrolyte to the cathode and are reduced to form hydrogen. In the second stage of the process, the sulfuric acid by-product from the electrolyzer is thermally decomposed at high temperature to produce sulfur dioxide and oxygen. The two gases are separated and the sulfur dioxide recycled to the electrolyzer for oxidation. The Savannah River National Laboratory (SRNL) has been exploring a fuel-cell design concept for the SDE using an anolyte feed comprised of concentrated sulfuric acid saturated with sulfur dioxide. The advantages of this design concept include high electrochemical efficiency and small footprint compared to a parallel-plate electrolyzer design. This paper will provide a summary of recent advances in the development of the SDE for the HyS process.

  10. Retrofitting heavy oil processes

    SciTech Connect (OSTI)

    Hamilton, G.L.; Fitzgerald, M.; D'Amico, V.

    1986-01-01

    Refiners, faced with the need to process the bottom end of the heavy high sulfur crude oil barrel in today's uncertain economic environment, are reluctant to commit large amounts of money to expensive upgrading processes. In order to conserve scarce capital while improving operating margins, additional valuable products can be produced by retrofits such as conversion of an idle crude unit to visbreaking, delayed coking or deasphalting service, or conversion of hydrodesulfurizers to mild hydrocracking.

  11. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  12. Process for removing sulfur from sulfur-containing gases

    DOE Patents [OSTI]

    Rochelle, Gary T.; Jozewicz, Wojciech

    1989-01-01

    The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accorda The government may own certain rights in the present invention pursuant to EPA Cooperative Agreement CR 81-1531.

  13. Field performance of a premium heating oil

    SciTech Connect (OSTI)

    Santa, T.; Jetter, S.

    1997-01-01

    As part of ongoing research to provide quality improvements to heating oil, Mobil Oil together with Santa Fuel conducted a field trial to investigate the performance of a new premium heating oil. This premium heating oil contains an additive system designed to minimize sludge related problems in the fuel delivery system of residential home heating systems. The additive used was similar to others reported at this and earlier BNL conferences, but was further developed to enhance its performance in oil heat systems. The premium heating oil was bulk additized and delivered to a subset of the customer base. The performance of this premium heating oil is discussed.

  14. Fuel Additive Strategies for Enhancing the Performance of Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additive Strategies for Enhancing the Performance of Engines and Engine Oils Fuel Additive Strategies for Enhancing the Performance of Engines and Engine Oils 2003 DEER Conference ...

  15. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  16. Production and Upgrading of Infrastructure Compatible Bio-Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Production and Upgrading of Infrastructure Compatible Bio-Oil with VTT March 25, 2015 ... Major Project Objectives: Low-severity hydrotreating (HT) Stabilize bio-oil for fuel oil ...

  17. Quality improvement of pyrolysis oil from waste rubber by adding sawdust

    SciTech Connect (OSTI)

    Wang, Wen-liang; Chang, Jian-min; Cai, Li-ping; Shi, Sheldon Q.

    2014-12-15

    Highlights: • Rubber-pyrolysis oil is difficult to be fuel due to high proportion of PAHs. • The efficiency of pyrolysis was increased as the percentage of sawdust increased. • The adding of sawdust improved pyrolysis oil quality by reducing the PAHs content. • Adding sawdust reduced nitrogen/sulfur in oil and was easier to convert to diesel. - Abstract: This work was aimed at improving the pyrolysis oil quality of waste rubber by adding larch sawdust. Using a 1 kg/h stainless pyrolysis reactor, the contents of sawdust in rubber were gradually increased from 0%, 50%, 100% and 200% (wt%) during the pyrolysis process. Using a thermo-gravimetric (TG) analyzer coupled with Fourier transform infrared (FTIR) analysis of evolving products (TG–FTIR), the weight loss characteristics of the heat under different mixtures of sawdust/rubber were observed. Using the pyrolysis–gas chromatography (GC)–mass spectrometry (Py–GC/MS), the vapors from the pyrolysis processes were collected and the compositions of the vapors were examined. During the pyrolysis process, the recovery of the pyrolysis gas and its composition were measured in-situ at a reaction temperature of 450 °C and a retaining time of 1.2 s. The results indicated that the efficiency of pyrolysis was increased and the residual carbon was reduced as the percentage of sawdust increased. The adding of sawdust significantly improved the pyrolysis oil quality by reducing the polycyclic aromatic hydrocarbons (PAHs) and nitrogen and sulfur compounds contents, resulting in an improvement in the combustion efficiency of the pyrolysis oil.

  18. SOFC cells and stacks for complex fuels

    SciTech Connect (OSTI)

    Edward M. Sabolsky; Matthew Seabaugh; Katarzyna Sabolsky; Sergio A. Ibanez; Zhimin Zhong

    2007-07-01

    Reformed hydrocarbon and coal (syngas) fuels present an opportunity to integrate solid oxide fuel cells into the existing fuel infrastructure. However, these fuels often contain impurities or additives that may lead to cell degradation through sulfur poisoning or coking. Achieving high performance and sulfur tolerance in SOFCs operating on these fuels would simplify system balance of plant and sequestration of anode tail gas. NexTech Materials, Ltd., has developed a suite of materials and components (cells, seals, interconnects) designed for operation in sulfur-containing syngas fuels. These materials and component technologies have been integrated into an SOFC stack for testing on simulated propane, logistic fuel reformates and coal syngas. Details of the technical approach, cell and stack performance is reported.

  19. Winter Heating Fuels - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    Winter Heating Fuels Click on the map to view state specific heating fuels data below | click to reset to U.S. values Click on map above to view state-specific heating fuel data Propane Heating oil Natural gas Electricity For more data on: Heating oil and propane prices - Heating Oil and Propane Update Propane stocks - Weekly Petroleum Status Report Heating oil/distillate stocks - Weekly Petroleum Status Report Natural gas storage - Weekly Natural Gas Storage Report Natural gas prices - Natural

  20. An Evolutionary Arms Race for Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    globally distributed sulfur-oxidizing bacteria in the deep sea carry bacterial genes for the oxidation of elemental sulfur. Although such observations are common in...

  1. Historical Sulfur Dioxide Emissions 1850-2000: Methods and Results

    SciTech Connect (OSTI)

    Smith, Steven J.; Andres, Robert; Conception , Elvira; Lurz, Joshua

    2004-01-25

    A global, self-consistent estimate of sulfur dioxide emissions over the last one and a half century were estimated by using a combination of bottom-up and best available inventory methods including all anthropogenic sources. We find that global sulfur dioxide emissions peaked about 1980 and have generally declined since this time. Emissions were extrapolated to a 1{sup o} x 1{sup o} grid for the time period 1850-2000 at annual resolution with two emission height levels and by season. Emissions are somewhat higher in the recent past in this new work as compared with some comprehensive estimates. This difference is largely due to our use of emissions factors that vary with time to account for sulfur removals from fossil fuels and industrial smelting processes.

  2. Fuel gas desulfurization

    DOE Patents [OSTI]

    Yang, Ralph T.; Shen, Ming-Shing

    1981-01-01

    A method for removing sulfurous gases such as H.sub.2 S and COS from a fuel gas is disclosed wherein limestone particulates containing iron sulfide provide catalytic absorption of the H.sub.2 S and COS by the limestone. The method is effective at temperatures of 400.degree. C. to 700.degree. C. in particular.

  3. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  4. Development of Ni-based Sulfur Resistant Catalyst for Diesel Reforming

    SciTech Connect (OSTI)

    Gunther Dieckmann

    2006-06-30

    In order for diesel fuel to be used in a solid oxide fuel cell auxiliary power unit, the diesel fuel must be reformed into hydrogen, carbon monoxide and carbon dioxide. One of the major problems facing catalytic reforming is that the level of sulfur found in low sulfur diesel can poison most catalysts. This report shows that a proprietary low cost Ni-based reforming catalyst can be used to reform a 7 and 50 ppm sulfur containing diesel fuel for over 500 hours of operation. Coking, which appears to be route of catalyst deactivation due to metal stripping, can be controlled by catalyst modifications, introduction of turbulence, and/or by application of an electromagnetic field with a frequency from {approx}50 kHz to 13.56 MHz with field strength greater than about 100 V/cm and more preferably greater about 500 V/cm.

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2007-03-17

    This report summarizes the accomplishments toward project goals during the no cost extension period of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts for a third round of testing, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Hydrotreating and hydrogenation of the product has been completed, and due to removal of material before processing, yield of the jet fuel fraction has decreased relative to an increase in the gasoline fraction. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. Emission testing indicates that the coal derived material has more trace metals related to coal than petroleum, as seen in previous runs. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. The co-coking of the runs with the new coal have begun, with the coke yield similar to previous runs, but the gas yield is lower and the liquid yield is higher. Characterization of the products continues. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking.

  6. Biomass Derivatives Competitive with Heating Oil Costs.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biomass Derivatives Competitive with Heating Oil Costs Transportation fuel Heat or electricity * Data are from literature, except heating oil is adjusted from 2011 winter average * Fuel costs vary widely based on feedstock, location, and technology option * Retail pellet costs are based on current prices in NE (~$243/ton) * Densifying biomass for heating (e.g. pyrolysis oil or pellets) can be a cost- competitive feedstock for residential heating system * These are not "drop-in" fuels

  7. SMALL SCALE FUEL CELL AND REFORMER SYSTEMS FOR REMOTE POWER

    SciTech Connect (OSTI)

    Dennis Witmer

    2003-12-01

    New developments in fuel cell technologies offer the promise of clean, reliable affordable power, resulting in reduced environmental impacts and reduced dependence on foreign oil. These developments are of particular interest to the people of Alaska, where many residents live in remote villages, with no roads or electrical grids and a very high cost of energy, where small residential power systems could replace diesel generators. Fuel cells require hydrogen for efficient electrical production, however. Hydrogen purchased through conventional compressed gas suppliers is very expensive and not a viable option for use in remote villages, so hydrogen production is a critical piece of making fuel cells work in these areas. While some have proposed generating hydrogen from renewable resources such as wind, this does not appear to be an economically viable alternative at this time. Hydrogen can also be produced from hydrocarbon feed stocks, in a process known as reforming. This program is interested in testing and evaluating currently available reformers using transportable fuels: methanol, propane, gasoline, and diesel fuels. Of these, diesel fuels are of most interest, since the existing energy infrastructure of rural Alaska is based primarily on diesel fuels, but this is also the most difficult fuel to reform, due to the propensity for coke formation, due to both the high vaporization temperature and to the high sulfur content in these fuels. There are several competing fuel cell technologies being developed in industry today. Prior work at UAF focused on the use of PEM fuel cells and diesel reformers, with significant barriers identified to their use for power in remote areas, including stack lifetime, system efficiency, and cost. Solid Oxide Fuel Cells have demonstrated better stack lifetime and efficiency in demonstrations elsewhere (though cost still remains an issue), and procuring a system for testing was pursued. The primary function of UAF in the fuel cell industry is in the role of third party independent testing. In order for tests to be conducted, hardware must be purchased and delivered. The fuel cell industry is still in a pre-commercial state, however. Commercial products are defined as having a fixed set of specifications, fixed price, fixed delivery date, and a warrantee. Negotiations with fuel cell companies over these issues are often complex, and the results of these discussions often reveal much about the state of development of the technology. This work includes some of the results of these procurement experiments. Fuel cells may one day replace heat engines as the source of electrical power in remote areas. However, the results of this program to date indicate that currently available hardware is not developed sufficiently for these environments, and that significant time and resources will need to be committed for this to occur.

  8. Superclean coal-water slurry combustion testing in an oil-fired boiler. Semiannual technical progress report, August 15, 1991--February 15, 1992

    SciTech Connect (OSTI)

    Miller, B.G.; Poe, R.L.; Morrison, J.L.; Xie, Jianyang; Walsh, P.M.; Schobert, H.H.; Scaroni, A.W.

    1992-05-29

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with less than 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in an oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels.

  9. Dynacracking process first commerical application for upgrading heavy oils

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1981-01-01

    The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in the product mix, product quality, and economics.

  10. Pyrochem Catalysts for Diesel Fuel Reforming

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pyrochem Catalysts for Diesel Fuel Reforming Success Story Converting heavy hydrocarbons, such as diesel and coal-based fuels, into hydrogen-rich synthesis gas is a necessary step for fuel cells and other applications. The high sulfur and aromatic content of these fuels poses a major technical challenge since these components can deactivate reforming catalysts. Taking on this challenge, NETL researchers invented a novel fuel-reforming catalyst that overcomes limitations of current catalysts by

  11. DOE Awards Storage Contracts for Northeast Home Heating Oil Reserve

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy today announced that new contracts have been awarded for commercial storage of 650,000 barrels of ultra low sulfur distillate for the Northeast Home Heating Oil Reserve.

  12. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  13. Superclean coal-water slurry combustion testing in an oil-fired boiler. Semiannual technical progress report, August 15, 1992--February 15, 1993

    SciTech Connect (OSTI)

    Miller, B.G.; Pisupati, S.V.; Poe, R.L.; Morrison, J.L.; Xie, J.; Walsh, P.M.; Wincek, R.T.; Clark, D.A.; Scaroni, A.W.

    1993-04-21

    The Pennsylvania State University is conducting a superclean coal-water slurry (SCCWS) program for the United States Department of Energy (DOE) and the Commonwealth of Pennsylvania with the objective of determining the capability of effectively firing SCCWS in an industrial boiler designed for heavy fuel oil. Penn State has entered into a cooperative agreement with DOE to determine if SCCWS (a fuel containing coal with 3.0 wt.% ash and 0.9 wt.% sulfur) can effectively be burned in a heavy fuel oil-designed industrial boiler without adverse impact on boiler rating, maintainability, reliability, and availability. The project will provide information on the design of new systems specifically configured to fire these clean coal-based fuels. The project consists of four phases: (1) design, permitting, and test planning, (2) construction and start up, (3) demonstration and evaluation (1,000-hour demonstration), and (4) program expansion (additional 1,000 hours of testing). The boiler testing wig determine if the SCCWS combustion characteristics, heat release rate, fouling and slagging behavior, corrosion and erosion limits, and fuel transport, storage, and handling characteristics can be accommodated in an oil-designed boiler system. In addition, the proof-of-concept demonstration will generate data to determine how the properties of SCCWS and its parent coal affect boiler performance. Economic factors associated with retrofitting boilers will be identified

  14. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    See footnotes at end of table. 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State 386 Energy Information...

  15. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  16. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    U.S. Energy Information Administration (EIA) Indexed Site

    Marketing Annual 1995 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  17. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  18. Native Village of Teller Addresses Heating Fuel Shortage, Improves...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    utility, which runs its own diesel fuel bulk storage facility for the diesel generators. However, residential heating oil and fuel for all public buildings except the...

  19. Our addiction to foreign oil and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    addiction to foreign oil and fossil fuels puts our economy, our environment, and ultimately our national security at risk. Furthermore, there is a growing recognition of the...

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel is defined as a fuel that is comprised of mono-alkyl esters of long chain fatty acids derived from vegetable oil or animal fats and that meets ASTM D6751. Green diesel is ...

  1. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power

    SciTech Connect (OSTI)

    2009-11-01

    TDA Research Inc., in collaboration with FuelCell Energy, will develop a new, high-capacity sorbent to remove sulfur from anaerobic digester gas. This technology will enable the production of a nearly sulfur-free biogas to replace natural gas in fuel cell power plants while reducing greenhouse gas emissions from fossil fuels.

  2. Final Report for NFE-07-00912: Development of Model Fuels Experimental...

    Office of Scientific and Technical Information (OSTI)

    New fuels include bio-fuels such as ethanol or bio-diesel, drop-in bio-derived fuels and those derived from new crude oil sources such as gas-to-liquids, coal-to-liquids, oil ...

  3. Alvan Blanch Green Fuels joint venture | Open Energy Information

    Open Energy Info (EERE)

    to extract oil from rape and Green Fuels provides the equipment to turn the oil into biodiesel, to allow farmers to produce their own fuel. References: Alvan Blanch - Green...

  4. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  5. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre' Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-09-17

    This report summarizes the accomplishments toward project goals during the second six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts and examination of carbon material, the use of a research gasoline engine to test coal-based gasoline, and modification of diesel engines for use in evaluating diesel produced in the project. At the pilot scale, the hydrotreating process was modified to separate the heavy components from the LCO and RCO fractions before hydrotreating in order to improve the performance of the catalysts in further processing. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. Both gasoline and diesel continue to be tested for combustion performance. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Activated carbons have proven useful to remove the heavy sulfur components, and unsupported Ni/Mo and Ni/Co catalysts have been very effective for hydrodesulfurization. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of the latest fuel oil (the high temperature fraction of RCO from the latest modification) indicates that the fraction is heavier than a No. 6 fuel oil. Combustion efficiency on our research boiler is {approx}63% for the heavy RCO fraction, lower than the combustion performance for previous co-coking fuel oils and No. 6 fuel oil. An additional coal has been procured and is being processed for the next series of delayed co-coking runs. Work continues on characterization of liquids and solids from co-coking of hydrotreated decant oils; liquid yields include more saturated and hydro- aromatics, while the coke quality varies depending on the conditions used. Pitch material is being generated from the heavy fraction of co-coking. Investigation of coal extraction as a method to produce RCO continues; the reactor modifications to filter the products hot and to do multi-stage extraction improve extraction yields from {approx}50 % to {approx}70%. Carbon characterization of co-cokes for use as various carbon artifacts continues.

  6. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  7. Alkali metal/sulfur battery

    DOE Patents [OSTI]

    Anand, Joginder N.

    1978-01-01

    Alkali metal/sulfur batteries in which the electrolyte-separator is a relatively fragile membrane are improved by providing means for separating the molten sulfur/sulfide catholyte from contact with the membrane prior to cooling the cell to temperatures at which the catholyte will solidify. If the catholyte is permitted to solidify while in contact with the membrane, the latter may be damaged. The improvement permits such batteries to be prefilled with catholyte and shipped, at ordinary temperatures.

  8. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

    SciTech Connect (OSTI)

    Wang, Huamin; Male, Jonathan L.; Wang, Yong

    2013-05-01

    There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

  9. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  10. Crude Oil Domestic Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Crude Oil Domestic Production Refinery Crude Oil Inputs Refinery Gross Inputs Refinery Operable Capacity (Calendar Day) Refinery Percent Operable Utilization Net Inputs of Motor Gasoline Blending Components Net Inputs of RBOB Blending Components Net Inputs of CBOB Blending Components Net Inputs of GTAB Blending Components Net Inputs of All Other Blending Components Net Inputs of Fuel Ethanol Net Production - Finished Motor Gasoline Net Production - Finished Motor Gasoline (Excl.

  11. Assessing historical global sulfur emission patterns for the period 1850--1990

    SciTech Connect (OSTI)

    Lefohn, A.S.; Husar, J.D.; Husar, R.B.; Brimblecombe, P.

    1996-07-19

    Anthropogenic sulfur dioxide emissions from energy-producing and metal production activities have become an important factor in better understanding the relationship between humans and the environment. Concerns about (1) acid rain effects on the environment and (2) anthropogenic aerosols affecting possible global change have prompted interest in the transformation and fate of sulfur in the environment. One step in assessing the importance of sulfur emissions is the development of a reliable regional emission inventory of sulfur as a function of time. The objective of this research effort was to create a homogeneous database for historical sulfur emission estimates for the world. The time from 1850--1990 was selected to include the period of industrialization form the time the main production of fuels and minerals began until the most recent year for which complete production data exist. This research effort attempts to correct some of the deficiencies associated with previous global sulfur emission estimates by (1) identifying those production activities that resulted in sulfur emissions by country and (2) calculating historical emission trends by country across years. An important component of this study was the comparison of the sulfur emission results with those of previous studies.

  12. Residential heating oil prices increase

    U.S. Energy Information Administration (EIA) Indexed Site

    That's down 2.6 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. The price for heating oil in the New England ...

  13. Residential heating oil price decreases

    U.S. Energy Information Administration (EIA) Indexed Site

    fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to 2.90 per gallon, down 10.4 cents from last week. This is Marcela ...

  14. Residential heating oil prices available

    U.S. Energy Information Administration (EIA) Indexed Site

    fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region currently average 2.35 per gallon. This is Marcela Rourk with EIA, in ...

  15. Residential heating oil prices available

    U.S. Energy Information Administration (EIA) Indexed Site

    That's down 32.7 cents from a year ago, based on the U.S. Energy Information Administration's weekly residential heating fuel price survey. Heating oil prices in the New England ...

  16. Residential heating oil prices decline

    U.S. Energy Information Administration (EIA) Indexed Site

    That's down 4.5 cents from a week ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region are ...

  17. ,,,"Electricity","Natural Gas","Fuel Oil","District Heat","District Chilled Water","Propane","Othera"

    U.S. Energy Information Administration (EIA) Indexed Site

    7. Energy Sources, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings","All Buildings Using Any Energy Source","Energy Sources Used (more than one may apply)" ,,,"Electricity","Natural Gas","Fuel Oil","District Heat","District Chilled Water","Propane","Othera" "All Buildings ................",4657,4403,4395,2670,434,117,50,451,153 "Building

  18. ,,,"Electricity","Natural Gas","Fuel Oil","District Heat","District Chilled Water","Propane","Othera"

    U.S. Energy Information Administration (EIA) Indexed Site

    8. Energy Sources, Floorspace, 1999" ,"Total Floorspace (million square feet)" ,"All Buildings","All Buildings Using Any Energy Source","Energy Sources Used (more than one may apply)" ,,,"Electricity","Natural Gas","Fuel Oil","District Heat","District Chilled Water","Propane","Othera" "All Buildings ................",67338,65753,65716,45525,13285,5891,2750,6290,2322

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Support for Growth of Alternative Fuel Sources The Louisiana Legislature urges the U.S. Congress to take actions to promote the growth of domestic alternative fuel sources, such as natural gas, and reduce dependence on foreign oil. (Reference House Concurrent Resolution 132, 2013

  20. Gasoline and Diesel Fuel Update

    Gasoline and Diesel Fuel Update (EIA)

    Methodology For Gasoline and Diesel Fuel Pump Components The components for the gasoline and diesel fuel pumps are calculated in the following manner in cents per gallon and then converted into a percentage: Crude Oil - the monthly average of the composite refiner acquisition cost, which is the average price of crude oil purchased by refiners. Refining Costs & Profits - the difference between the monthly average of the spot price of gasoline or diesel fuel (used as a proxy for the value of

  1. Life-Cycle Assessment of Pyrolysis Bio-Oil Production*

    SciTech Connect (OSTI)

    Steele, Philip; Puettmann, Maureen E.; Penmetsa, Venkata Kanthi; Cooper, Jerome E.

    2012-07-01

    As part ofthe Consortium for Research on Renewable Industrial Materials' Phase I life-cycle assessments ofbiofuels, lifecycle inventory burdens from the production of bio-oil were developed and compared with measures for residual fuel oil. Bio-oil feedstock was produced using whole southern pine (Pinus taeda) trees, chipped, and converted into bio-oil by fast pyrolysis. Input parameters and mass and energy balances were derived with Aspen. Mass and energy balances were input to SimaPro to determine the environmental performance of bio-oil compared with residual fuel oil as a heating fuel. Equivalent functional units of 1 MJ were used for demonstrating environmental preference in impact categories, such as fossil fuel use and global warming potential. Results showed near carbon neutrality of the bio-oil. Substituting bio-oil for residual fuel oil, based on the relative carbon emissions of the two fuels, estimated a reduction in CO2 emissions by 0.075 kg CO2 per MJ of fuel combustion or a 70 percent reduction in emission over residual fuel oil. The bio-oil production life-cycle stage consumed 92 percent of the total cradle-to-grave energy requirements, while feedstock collection, preparation, and transportation consumed 4 percent each. This model provides a framework to better understand the major factors affecting greenhouse gas emissions related to bio-oil production and conversion to boiler fuel during fast pyrolysis.

  2. Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment

    SciTech Connect (OSTI)

    Sayer, J.H.

    1995-06-01

    The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

  3. HYBRID SULFUR PROCESS REFERENCE DESIGN AND COST ANALYSIS

    SciTech Connect (OSTI)

    Gorensek, M.; Summers, W.; Boltrunis, C.; Lahoda, E.; Allen, D.; Greyvenstein, R.

    2009-05-12

    This report documents a detailed study to determine the expected efficiency and product costs for producing hydrogen via water-splitting using energy from an advanced nuclear reactor. It was determined that the overall efficiency from nuclear heat to hydrogen is high, and the cost of hydrogen is competitive under a high energy cost scenario. It would require over 40% more nuclear energy to generate an equivalent amount of hydrogen using conventional water-cooled nuclear reactors combined with water electrolysis compared to the proposed plant design described herein. There is a great deal of interest worldwide in reducing dependence on fossil fuels, while also minimizing the impact of the energy sector on global climate change. One potential opportunity to contribute to this effort is to replace the use of fossil fuels for hydrogen production by the use of water-splitting powered by nuclear energy. Hydrogen production is required for fertilizer (e.g. ammonia) production, oil refining, synfuels production, and other important industrial applications. It is typically produced by reacting natural gas, naphtha or coal with steam, which consumes significant amounts of energy and produces carbon dioxide as a byproduct. In the future, hydrogen could also be used as a transportation fuel, replacing petroleum. New processes are being developed that would permit hydrogen to be produced from water using only heat or a combination of heat and electricity produced by advanced, high temperature nuclear reactors. The U.S. Department of Energy (DOE) is developing these processes under a program known as the Nuclear Hydrogen Initiative (NHI). The Republic of South Africa (RSA) also is interested in developing advanced high temperature nuclear reactors and related chemical processes that could produce hydrogen fuel via water-splitting. This report focuses on the analysis of a nuclear hydrogen production system that combines the Pebble Bed Modular Reactor (PBMR), under development by PBMR (Pty.) Ltd. in the RSA, with the Hybrid Sulfur (HyS) Process, under development by the Savannah River National Laboratory (SRNL) in the US as part of the NHI. This work was performed by SRNL, Westinghouse Electric Company, Shaw, PBMR (Pty) Ltd., and Technology Insights under a Technical Consulting Agreement (TCA). Westinghouse Electric, serving as the lead for the PBMR process heat application team, established a cost-shared TCA with SRNL to prepare an updated HyS thermochemical water-splitting process flowsheet, a nuclear hydrogen plant preconceptual design and a cost estimate, including the cost of hydrogen production. SRNL was funded by DOE under the NHI program, and the Westinghouse team was self-funded. The results of this work are presented in this Final Report. Appendices have been attached to provide a detailed source of information in order to document the work under the TCA contract.

  4. Imports of Distillate Fuel Oil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 175 90 207 126 118 1982-2016 East Coast (PADD 1) 57 173 81 199 120 107 2004-2016 Midwest (PADD 2) 2 2 1 2 3 2 2004-2016 Gulf Coast (PADD 3) 0 0 0 0 0 0 2004-2016 Rocky Mountain ...

  5. Stocks of Distillate Fuel Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    PADD 1 55,591 55,881 56,335 55,188 54,662 55,940 1990-2016 New England 10,015 10,297 10,018 9,115 8,789 8,934 1990-2016 Central Atlantic 31,929 31,468 32,172 33,497 32,550 33,034 ...

  6. Martinez Sulfuric Acid Regeneration Plt Biomass Facility | Open...

    Open Energy Info (EERE)

    Martinez Sulfuric Acid Regeneration Plt Biomass Facility Jump to: navigation, search Name Martinez Sulfuric Acid Regeneration Plt Biomass Facility Facility Martinez Sulfuric Acid...

  7. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur Deactivation on CuZeolite SCR Catalysts in Diesel Application Investigation of Sulfur ...

  8. Method of preparing graphene-sulfur nanocomposites for rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be ...

  9. Fuel-cycle assessment of selected bioethanol production.

    SciTech Connect (OSTI)

    Wu, M.; Wang, M.; Hong, H.; Energy Systems

    2007-01-31

    A large amount of corn stover is available in the U.S. corn belt for the potential production of cellulosic bioethanol when the production technology becomes commercially ready. In fact, because corn stover is already available, it could serve as a starting point for producing cellulosic ethanol as a transportation fuel to help reduce the nation's demand for petroleum oil. Using the data available on the collection and transportation of corn stover and on the production of cellulosic ethanol, we have added the corn stover-to-ethanol pathway in the GREET model, a fuel-cycle model developed at Argonne National Laboratory. We then analyzed the life-cycle energy use and emission impacts of corn stover-derived fuel ethanol for use as E85 in flexible fuel vehicles (FFVs). The analysis included fertilizer manufacturing, corn farming, farming machinery manufacturing, stover collection and transportation, ethanol production, ethanol transportation, and ethanol use in light-duty vehicles (LDVs). Energy consumption of petroleum oil and fossil energy, emissions of greenhouse gases (carbon dioxide [CO{sub 2}], nitrous oxide [N{sub 2}O], and methane [CH{sub 4}]), and emissions of criteria pollutants (carbon monoxide [CO], volatile organic compounds [VOCs], nitrogen oxide [NO{sub x}], sulfur oxide [SO{sub x}], and particulate matter with diameters smaller than 10 micrometers [PM{sub 10}]) during the fuel cycle were estimated. Scenarios of ethanol from corn grain, corn stover, and other cellulosic feedstocks were then compared with petroleum reformulated gasoline (RFG). Results showed that FFVs fueled with corn stover ethanol blends offer substantial energy savings (94-95%) relative to those fueled with RFG. For each Btu of corn stover ethanol produced and used, 0.09 Btu of fossil fuel is required. The cellulosic ethanol pathway avoids 86-89% of greenhouse gas emissions. Unlike the life cycle of corn grain-based ethanol, in which the ethanol plant consumes most of the fossil fuel, farming consumes most of the fossil fuel in the life cycle of corn stover-based ethanol.

  10. The last decade of global anthropogenic sulfur dioxide: 2000-2011 emissions

    SciTech Connect (OSTI)

    Klimont, Z.; Smith, Steven J.; Cofala, Janusz

    2013-01-09

    Evolution of global and regional anthropogenic SO2 emissions in the last decade has been estimated through a bottom-up calculation for recent years. After a strong increase in emissions that peaked about 2006, we estimate a declining trend continuing until 2011. However, there is a strong spatial variability with North America and Europe continuing to reduce emissions with an increasing role of Asia and international shipping. China remains a key contributor but the introduction of stricter emission limits followed by an ambitious program of installing flue gas desulfurization on power plants resulted in significant decline in emissions from energy sector and stabilization of Chinese SO2 emissions. Comparable mitigation strategies are not yet present in several other Asian countries and industrial sectors in general, while emissions from international shipping are expected to start declining soon following agreed reduction of sulfur content of fuel oil. Estimated trends in global SO2 emissions are within the range of RCP projections and uncertainty calculated for the year 2005.

  11. Hydrocarbon Liquid Production from Biomass via Hot-Vapor-Filtered Fast Pyrolysis and Catalytic Hydroprocessing of the Bio-oil

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; French, Richard; Deutch, Steve; Iisa, Kristiina

    2014-08-14

    Hot-vapor filtered bio-oils were produced from two different biomass feedstocks, oak and switchgrass, and the oils were evaluated in hydroprocessing tests for production of liquid hydrocarbon products. Hot-vapor filtering reduced bio-oil yields and increased gas yields. The yields of fuel carbon as bio-oil were reduced by ten percentage points by hot-vapor filtering for both feedstocks. The unfiltered bio-oils were evaluated alongside the filtered bio-oils using a fixed bed catalytic hydrotreating test. These tests showed good processing results using a two-stage catalytic hydroprocessing strategy. Equal-sized catalyst beds, a sulfided Ru on carbon catalyst bed operated at 220°C and a sulfided CoMo on alumina catalyst bed operated at 400°C were used with the entire reactor at 100 atm operating pressure. The products from the four tests were similar. The light oil phase product was fully hydrotreated so that nitrogen and sulfur were below the level of detection, while the residual oxygen ranged from 0.3 to 2.0%. The density of the products varied from 0.80 g/ml up to 0.86 g/ml over the period of the test with a correlated change of the hydrogen to carbon atomic ratio from 1.79 down to 1.57, suggesting some loss of catalyst activity through the test. These tests provided the data needed to assess the suite of liquid fuel products from the process and the activity of the catalyst in relationship to the existing catalyst lifetime barrier for the technology.

  12. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  13. Decontamination performance of selected in situ technologies for jet fuel contamination. Master's thesis

    SciTech Connect (OSTI)

    Chesley, G.D.

    1993-01-01

    Specific study of jet fuel is warranted because of the quantitive and qualitative component differences between jet fuel and other hydrocarbon fuels. Quantitatively, jet fuel contains a larger aliphatic or saturate fraction and a smaller aromatic fraction than other fuels (i.e. heating oil and diesel oil) in the medium-boiling-point-distillate class of fuels. Since the aliphatic and aromatic fractions of fuel are not equally susceptible to biodegradation, jet fuel decontamination using biodegradation may be different from other fuels.

  14. 1985 fuel supply seminar: proceedings

    SciTech Connect (OSTI)

    Prast, W.G.

    1986-09-01

    The major topics were utility fuel demand uncertainty (featuring uncertainty in electricity demand growth prospects), fuel forecasts and assumptions, residual fuel oil and natural gas markets, coal in environmental planning, coal market conditions and implications for procurement, and Canadian energy purchases. Individual papers are processed separately for the data bases. (PSB)

  15. Synthetic fuels handbook: properties, process and performance

    SciTech Connect (OSTI)

    Speight, J.

    2008-07-01

    The handbook is a comprehensive guide to the benefits and trade-offs of numerous alternative fuels, presenting expert analyses of the different properties, processes, and performance characteristics of each fuel. It discusses the concept systems and technology involved in the production of fuels on both industrial and individual scales. Chapters 5 and 7 are of special interest to the coal industry. Contents: Chapter 1. Fuel Sources - Conventional and Non-conventional; Chapter 2. Natural Gas; Chapter 3. Fuels From Petroleum and Heavy Oil; Chapter 4. Fuels From Tar Sand Bitumen; Chapter 5. Fuels From Coal; Chapter 6. Fuels From Oil Shale; Chapter 7. Fuels From Synthesis Gas; Chapter 8. Fuels From Biomass; Chapter 9. Fuels From Crops; Chapter 10. Fuels From Wood; Chapter 11. Fuels From Domestic and Industrial Waste; Chapter 12. Landfill Gas. 3 apps.

  16. Fuel Preprocessor (FPP) for a Solid Oxide Fuel Cell Auxiliary Power Unit

    SciTech Connect (OSTI)

    M. Namazian, S. Sethuraman and G. Venkataraman

    2004-12-31

    Auxiliary Power Units (APUs), driven by truck engines, consume over 800 million gallon of diesel fuel while idling. Use of separate SOFC based APUs are an excellent choice to reduce the cost and pollution associated with producing auxiliary power. However, diesel fuel is a challenging fuel to use in fuel cell systems because it has heavy hydrocarbons that can transform into carbon deposits and gums that can block passages and deactivate fuel reformer and fuel cell reactor elements. The work reported herein addresses the challenges associated with the diesel fuel sulfur and carbon producing contaminants in a Fuel Preprocessor (FPP). FPP processes the diesel fuel onboard and ahead of the reformer to reduce its carbon deposition tendency and its sulfur content, thus producing a fuel suitable for SOFC APU systems. The goal of this DOE supported Invention and Innovation program was to design, develop and test a prototype Fuel Preprocessor (FPP) that efficiently and safely converts the diesel fuel into a clean fuel suitable for a SOFC APU system. The goals were achieved. A 5 kWe FPP was designed, developed and tested. It was demonstrated that FPP removes over 80% of the fuel sulfur and over 90% of its carbon residues and it was demonstrated that FPP performance exceeds the original project goals.

  17. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  18. Collaborative Lubricating Oil Study on Emissions: November 28, 2006 - March 31, 2011

    SciTech Connect (OSTI)

    Carroll, J. N.; Khalek, I. A.; Smith, L. R.; Fujita, E.; Zielinska, B.

    2011-10-01

    The Collaborative Lubricating Oil Study on Emissions (CLOSE) project was a pilot investigation of how fuels and crankcase lubricants contribute to the formation of particulate matter (PM) and semi-volatile organic compounds (SVOC) in vehicle exhaust. As limited vehicles were tested, results are not representative of the whole on-road fleet. Long-term effects were not investigated. Pairs of vehicles (one normal PM emitting, one high-PM emitting) from four categories were selected: light-duty (LD) gasoline cars, medium-duty (MD) diesel trucks, heavy-duty (HD) natural-gas-fueled buses, and HD diesel buses. HD vehicles procured did not exhibit higher PM emissions, and thus were labeled high mileage (HM). Fuels evaluated were non-ethanol gasoline (E0), 10 percent ethanol (E10), conventional low-sulfur TxLED diesel, 20% biodiesel (B20), and natural gas. Temperature effects (20 degrees F, 72 degrees F) were evaluated on LD and MD vehicles. Lubricating oil vintage effects (fresh and aged) were evaluated on all vehicles. LD and MD vehicles were operated on a dynamometer over the California Unified Driving Cycle, while HD vehicles followed the Heavy Duty Urban Dynamometer Driving Schedule. Regulated and unregulated emissions were measured. Chemical markers from the unregulated emissions measurements and a tracer were utilized to estimate the lubricant contribution to PM.

  19. EERE Success Story-Refining Bio-Oil alongside Petroleum | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of technologies that enable the processing of bio-oils in petroleum refineries. ... readily for gasoline, conventional diesel fuel, and jet fuel) brings significant ...

  20. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P.; Lynn, Scott

    1995-01-01

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  1. World Oil Prices in AEO2007 (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01

    Over the long term, the Annual Energy Outlook 2007 (AEO) projection for world oil prices -- defined as the average price of imported low-sulfur, light crude oil to U.S. refiners -- is similar to the AEO2006 projection. In the near term, however, AEO2007 projects prices that are $8 to $10 higher than those in AEO2006.

  2. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Statistical Overview of 5 Years of HCCI Fuel and Engine Data from ORNL Response of Oil Sands Derived Fuels in Diesel HCCI Operation Combustion, Efficiency, and Fuel Effects in a ...

  3. Desulfurization of coal with hydroperoxides of vegetable oils. [Quarterly] report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, Ruozhi; Cheng, Jianjun

    1994-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. Preliminary experiments showed that EBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During this first quarter the requirement of an added photosensitizer has been eliminated, the catalytic effect of coal has been confirmed, and the existence of a complex set of reactions revealed. These reactions between the oxygen, oil, hydroperoxides, and coal are hydroperoxide formation, which is catalyzed by the coal surface and by heat, an unknown coal-hydroperoxide reaction, and oil polymerization. Additionally, diffusion phenomena must be playing a role because oil polymerization occurs, but the importance of diffusion is difficult to assess because less polymerization occurs when coal is present. The first task has been completed and we are now ready to determine the ability of linseed oil hydroperoxides to oxidize organic sulfur in EBC 108 coal.

  4. Sulfur oxidation to sulfate coupled with electron transfer to electrodes by Desulfuromonas strain TZ1

    SciTech Connect (OSTI)

    Zhang, T; Bain, TS; Barlett, MA; Dar, SA; Snoeyenbos-West, OL; Nevin, KP; Lovley, DR

    2014-01-02

    Microbial oxidation of elemental sulfur with an electrode serving as the electron acceptor is of interest because this may play an important role in the recovery of electrons from sulfidic wastes and for current production in marine benthic microbial fuel cells. Enrichments initiated with a marine sediment inoculum, with elemental sulfur as the electron donor and a positively poised (+300 mV versus Ag/AgCl) anode as the electron acceptor, yielded an anode biofilm with a diversity of micro-organisms, including Thiobacillus, Sulfurimonas, Pseudomonas, Clostridium and Desulfuromonas species. Further enrichment of the anode biofilm inoculum in medium with elemental sulfur as the electron donor and Fe(III) oxide as the electron acceptor, followed by isolation in solidified sulfur/Fe(III) medium yielded a strain of Desulfuromonas, designated strain TZ1. Strain TZ1 effectively oxidized elemental sulfur to sulfate with an anode serving as the sole electron acceptor, at rates faster than Desulfobulbus propionicus, the only other organism in pure culture previously shown to oxidize S with current production. The abundance of Desulfuromonas species enriched on the anodes of marine benthic fuel cells has previously been interpreted as acetate oxidation driving current production, but the results presented here suggest that sulfur-driven current production is a likely alternative.

  5. Seal for sodium sulfur battery

    DOE Patents [OSTI]

    Topouzian, Armenag; Minck, Robert W.; Williams, William J.

    1980-01-01

    This invention is directed to a seal for a sodium sulfur battery in which the sealing is accomplished by a radial compression seal made on a ceramic component of the battery which separates an anode compartment from a cathode compartment of the battery.

  6. AltAir Fuels | Open Energy Information

    Open Energy Info (EERE)

    Renewable Energy Product: Seattle-based developer of projects for the production of jet fuel from renewable and sustainable oils. References: AltAir Fuels1 This article is a...

  7. Two stage sorption of sulfur compounds

    DOE Patents [OSTI]

    Moore, William E.

    1992-01-01

    A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

  8. Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005

    SciTech Connect (OSTI)

    John E. Pinkerton

    2007-08-15

    Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

  9. Biomass Derivatives Competitive with Heating Oil Costs. | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Derivatives Competitive with Heating Oil Costs. Biomass Derivatives Competitive with Heating Oil Costs. Presentation at the May 9, 2012, Pyrolysis Oil Workship on biomass derivatives competitive with heating oil costs. PDF icon pyrolysis_levine.pdf More Documents & Publications Challenge # 1. Feedstock & Production Thermochemical Conversion Proceeses to Aviation Fuels A Review of DOE Biofuels Program

  10. Process for demetallizing and desulfurizing heavy crude oil

    SciTech Connect (OSTI)

    Brown, R.E.; Hogan, R.J.; Combs, D.M.; Kukes, S.G.

    1989-12-05

    This patent describes a process for producing a synthetic crude oil of improved properties by desulfurizing, denitrogenating and demetallizing a heavy crude oil feed stock. The feed stock being a crude oil having an average boiling point at least as high as 500{degrees} F., an API gravity at 60{degrees} F. of less than 20, and containing at least about 1 weight percent sulfur.

  11. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  12. Biological Pyrolysis Oil Upgrading Presentation for BETO 2015...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pyrolysis Oil Upgrading WBS 2.3.2.301 2015 DOE BioEnergy Technologies Office (BETO) ... * Tt-J Catalytic Upgrading of Bio-Oil Intermediates to Fuels and Chemicals ...

  13. Unusual refinery boiler tube failures due to corrosion by sulfuric acid induced by steam leaks

    SciTech Connect (OSTI)

    Lopez-Lopez, D.; Wong-Moreno, A.

    1998-12-31

    Corrosion by sulfuric acid in boilers is a low probability event because gas temperature and metal temperature of boiler tubes are high enough to avoid the condensation of sulfuric acid from flue gases. This degradation mechanism is frequently considered as an important cause of air preheaters materials degradation, where flue gases are cooled by heat transfer to the combustion air. Corrosion is associated to the presence of sulfuric acid, which condensates if metal temperature (or gas temperature) is below of the acid dew point. In economizer tubes, sulfuric acid corrosion is an unlikely event because flue gas and tube temperatures are normally over the acid dewpoint. In this paper, the failure analysis of generator tubes (similar to the economizer of bigger boilers) of two small oil-fired subcritical boilers is reported. It is concluded that sulfuric acid corrosion was the cause of the failure. The sulfuric acid condensation was due to the contact of flue gases containing SO{sub 3} with water-steam spray coming from leaks at the interface of rolled tube to the drum. Considering the information gathered from these two cases studied, an analysis of this failure mechanism is presented including a description of the thermodynamics condition of water leaking from the drum, and an analysis of the factors favoring it.

  14. Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1994

    SciTech Connect (OSTI)

    1995-11-01

    The objective of this project is to demonstrate and evaluate commercially available selective catalytic reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. Coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and European gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing al aspects of this project. 1 ref., 69 figs., 45 tabs.

  15. Sulfur Content, Weighted Average Refinery Crude Oil Input Qualities

    U.S. Energy Information Administration (EIA) Indexed Site

    Sep-15 Oct-15 Nov-15 Dec-15 Jan-16 Feb-16 View History U.S. 1.36 1.37 1.44 1.44 1.43 1.38 1985-2016 PADD 1 0.62 0.83 0.75 0.75 0.75 0.63 1985-2016 East Coast 0.51 0.76 0.68 0.67 ...

  16. Proceedings of the 1995 SAE alternative fuels conference. P-294

    SciTech Connect (OSTI)

    1995-12-31

    This volume contains 32 papers and five panel discussions related to the fuel substitution of trucks, automobiles, buses, cargo handling equipment, diesel passenger cars, and pickup trucks. Fuels discussed include liquefied natural gas, natural gas, ethanol fuels, methanol fuels, dimethyl ether, methyl esters from various sources (rape oil, used cooking oils, soya, and canola oils), hydrogen fuels, and biodiesel. Other topics include fuel cell powered vehicles, infrastructure requirements for fuel substitution, and economics. Papers have been processed separately for inclusion on the data base.

  17. Winter fuels report

    SciTech Connect (OSTI)

    Not Available

    1995-02-03

    The Winter Fuels Report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and State and local governments on the following topics: distillate fuel oil net production, imports and stocks on a US level and for all Petroleum Administration for Defense Districts (PADD) and product supplied on a US level; propane net production, imports and stocks on a US level and for PADD`s I, II, and III; natural gas supply and disposition and underground storage for the US and consumption for all PADD`s; as well as selected National average prices; residential and wholesale pricing data for heating oil and propane for those States participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; crude oil and petroleum price comparisons for the US and selected cities; and a 6-10 Day and 30-Day outlook for temperature and precipitation and US total heating degree-days by city.

  18. Winter fuels report

    SciTech Connect (OSTI)

    Not Available

    1995-02-17

    The Winter Fuels Report is intended to provide consise, timely information to the industry, the press, policymakers, consumers, analysts, and State and local governments on the following topics: Distillate fuel oil net production, imports and stocks on a US level and for all Petroleum Administration for Defense Districts (PADD) and product supplied on a US level; Natural gas supply and disposition and underground storage for the US and consumption for all PADD`s as well as selected National average prices; Residential and wholesale pricing data for heating oil and propane for those States participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; Crude oil and petroleum price comparisons for the US and selected cities; and A 6-10 Day and 30-Day outlook for temperature and precipitation and US total heating degree days by city.

  19. Winter fuels report

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    The Winter Fuels Report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and state and local governments on the following topics: distillate fuel oil net production, imports and stocks for all PADD's and product supplied on a US level; propane net product supplied on a US level; propane net production, imports and stocks for Petroleum Administration for Defense Districts (PADD) I, II, and III; natural gas supply and disposition and underground storage for the United States and consumption for all PADD's; residential and wholesale pricing data for propane and heating oil for those states participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; crude oil and petroleum price comparisons for the United States and selected cities; and US total heating degree-days by city. 27 figs, 12 tabs.

  20. Field-to-Fuel Performance Testing of Various Biomass Feedstocks: Production and Catalytic Upgrading of Bio-Oil to Refinery Blendstocks (Presentation)

    SciTech Connect (OSTI)

    Carpenter, D.; Westover, T.; Howe, D.; Evans, R.; French, R.; Kutnyakov, I.

    2014-09-01

    Large-scale, cost-competitive deployment of thermochemical technologies to replace petroleum oil with domestic biofuels will require inclusion of high volumes of low-cost, diverse biomass types into the supply chain. However, a comprehensive understanding of the impacts of feedstock thermo-physical and chemical variability, particularly inorganic matter (ash), on the yield and product distribution

  1. EIS-0083: Final Northeast Regional Environmental Impact Statement; The Potential Conversion of Forty-Two Powerplants From Oil to Coal or Alternate Fuels

    Broader source: Energy.gov [DOE]

    This Economic Regulatory Administration statement assesses the potential for cumulative and interactive environmental impacts resulting from conversion of up to 42 northeastern power plants from oil to coal and from an alternative “Voluntary Conversion” scenario for 27 power plants.

  2. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion...

    Office of Scientific and Technical Information (OSTI)

    chemistry and particulate size measurements. Fuels obtained in late 2011, which will be evaluated in 2012, include a series of oil shale derived fuels from PNNL, green diesel ...

  3. FUSED REACTOR FUELS

    DOE Patents [OSTI]

    Mayer, S.W.

    1962-11-13

    This invention relates to a nuciear reactor fuel composition comprising (1) from about 0.01 to about 50 wt.% based on the total weight of said composition of at least one element selected from the class consisting of uranium, thorium, and plutonium, wherein said eiement is present in the form of at least one component selected from the class consisting of oxides, halides, and salts of oxygenated anions, with components comprising (2) at least one member selected from the class consisting of (a) sulfur, wherein the sulfur is in the form of at least one entity selected irom the class consisting of oxides of sulfur, metal sulfates, metal sulfites, metal halosulfonates, and acids of sulfur, (b) halogen, wherein said halogen is in the form of at least one compound selected from the class of metal halides, metal halosulfonates, and metal halophosphates, (c) phosphorus, wherein said phosphorus is in the form of at least one constituent selected from the class consisting of oxides of phosphorus, metal phosphates, metal phosphites, and metal halophosphates, (d) at least one oxide of a member selected from the class consisting of a metal and a metalloid wherein said oxide is free from an oxide of said element in (1); wherein the amount of at least one member selected from the class consisting of halogen and sulfur is at least about one at.% based on the amount of the sum of said sulfur, halogen, and phosphorus atom in said composition; and wherein the amount of said 2(a), 2(b) and 2(c) components in said composition which are free from said elements of uranium, thorium, arid plutonium, is at least about 60 wt.% based on the combined weight of the components of said composition which are free from said elements of uranium, thorium, and plutonium. (AEC)

  4. Effect of carbon coating on scuffing performance in diesel fuels

    SciTech Connect (OSTI)

    Ajayi, O. O.; Alzoubi, M. F.; Erdemir, A.; Fenske, G. R.

    2000-06-29

    Low-sulfur and low-aromatic diesel fuels are being introduced in order to reduce various types of emissions in diesel engines to levels in compliance with current and impending US federal regulations. The low lubricity of these fuels, however, poses major reliability and durability problems for fuel injection components that depend on diesel fuel for their lubrication. In the present study, the authors evaluated the scuff resistance of surfaces in regular diesel fuel containing 500 ppm sulfur and in Fischer-Tropsch synthetic diesel fuel containing no sulfur or aromatics. Tests were conducted with the high frequency reciprocating test rig (HFRR) using 52100 steel balls and H-13 tool-steel flats with and without Argonne's special carbon coatings. Test results showed that the sulfur-containing fuels provide about 20% higher scuffing resistance than does fuel without sulfur. Use of the carbon coating on the flat increased scuffing resistance in both regular and synthetic fuels by about ten times, as measured by the contact severity index at scuffing. Scuffing failure in tests conducted with coated surfaces did not occur until the coating had been removed by the two distinct mechanisms of spalling and wear.

  5. OXIDATION OF FUELS IN THE COOL FLAME REGIME FOR COMBUSTION AND REFORMING FOR FUEL CELLS.

    SciTech Connect (OSTI)

    NAIDJA,A.; KRISHNA,C.R.; BUTCHER,T.; MAHAJAN,D.

    2002-08-01

    THE REVIEW INTEGRATES RECENT INVESTIGATIONS ON AUTO OXIDATION OF FUEL OILS AND THEIR REFORMING INTO HYDROGEN RICH GAS THAT COULD SERVE AS A FEED FOR FUEL CELLS AND COMBUSTION SYSTEMS.

  6. Biogenic sulfur emissions in the SURE region

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.; Robinson, E.; Pack, M.R.

    1980-09-01

    The objective of this study was to estimate the magnitude of biogenic sulfur emissions from the northeastern United States - defined as the EPRI Sulfate Regional Experiment (SURE) study area. Initial laboratory efforts developed and validated a portable sulfur sampling system and a sensitive, gas chromatographic analytical detection system. Twenty-one separate sites were visited in 1977 to obtain a representative sulfur emission sampling of soil orders, suborders, and wetlands. The procedure determined the quantity of sulfur added to sulfur-free sweep air by the soil flux as the clean air was blown through the dynamic enclosure set over the selected sampling area. This study represents the first systematic sampling for biogenic sulfur over such a wide range of soils and such a large land area. The major impacts upon the measured sulfur flux were found to include soil orders, temperature, sunlight intensity, tidal effects along coastal areas. A mathematical model was developed for biogenic sulfur emissions which related these field variables to the mean seasonal and annual ambient temperatures regimes for each SURE grid and the percentage of each soil order within each grid. This model showed that at least 53,500 metric tons (MT) of biogenic sulfur are emitted from the SURE land surfaces and approximately 10,000 MT are emitted from the oceanic fraction of the SURE grids. This equates to a land sulfur flux of nearly 0.02 gram of sulfur per square meter per yr, or about 0.6% of the reported anthropogenic emissions withn the SURE study area. Based upon these data and the summertime Bermuda high clockwise circulation of maritime air across Florida and the Gulf Coast states northward through the SURE area, the total land biogenic sulfur emission contribution to the SURE area atmospheric sulfur burden might approach 1 to 2.5% of the anthropogenic.

  7. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfurmore » were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.« less

  8. Method of preparing graphene-sulfur nanocomposites for rechargeable

    Office of Scientific and Technical Information (OSTI)

    lithium-sulfur battery electrodes (Patent) | SciTech Connect Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Citation Details In-Document Search Title: Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing

  9. Desulfurization of coal with hydroperoxides of vegetable oils. Technical progress report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, R.; Cheng, J.; Shi, Feng; Gholson, K.L.

    1995-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of solid products. Preliminary experiments showed that IBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During the first quarter the requirement of an added photosensitizer was eliminated, the catalytic effect of coal was confirmed, and the existence of a complex set of reactions was revealed. During the second quarter, working with IBC-108 coal (2.3% organic S, 0.4% pyrite S), the effects of different extraction solvents were examined. A new pretreatment which combines alkali with linseed oil was discovered. Best organic sulfur removal is approximately 26% using alkali pretreatment combined with linseed oil at 100[degrees]C. BTU loses can be kept to a minimum of 3% with proper use of solvents. During this third quarter the effects of different ratios of oil:coal, different temperatures, and different reaction times were completely examined. The effects of alkali on sulfur removal were further investigated. Best organic sulfur removal reaches 34% using ammonia pretreatment, then oil and finally aqNA2CO3 extraction.

  10. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfur were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.

  11. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  12. HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS

    SciTech Connect (OSTI)

    A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

    2003-11-01

    The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

  13. Gasoline and Diesel Fuel Update

    Gasoline and Diesel Fuel Update (EIA)

    Price Data Collection Procedures Every Monday, cash self-serve on-highway diesel prices (including taxes) are collected from a sample of approximately 400 retail diesel outlets in the continental U.S. The sample includes a combination of truck stops and service stations that sell on-highway diesel fuel. The data represent the price of ultra low sulfur diesel (ULSD) which contains less than 15 parts-per-million sulfur. The prices are collected via telephone, fax, email, or the internet from

  14. Orimulsion conversion boosts prospects of `fourth` fossil fuel

    SciTech Connect (OSTI)

    1995-04-01

    This article describes how, by retrofitting a 100-MW oil-fired and a 215-MW coal-fired unit, one utility turned a plant destined for peaking service into a base-load asset with a predictable fuel bill and manageable emissions-even in environmentally sensitive Atlantic Canada. Six years ago, New Brunswick Power Corp (NB Power) found itself on the horns of a dilemma. For years, the utility had been searching for a powerplant fuel with a more stable price than oil, which at the time was fueling one-third of its generating capacity. Buying and burning more domestic coal-even at twice the price of offshore supplies-was the preferred option, because that would also help keep New Brunswick`s coal mines open. But by 1989, federal and provincial legislation had begun to plan for stringent limits on SO{sub 2} emissions that would take the local-coal card out of NB Power`s hand. Containing up to 8% sulfur, New Brunswick coal would be too dirty to burn by itself; emissions from a 200-MW unit would alone use up nearly half of the utility`s system-wide annual quota for SO{sub 2} emissions schedules for imposition in 1994. Enter Bitor America Corp, the Boca Raton (Fla) marketing subsidiary of the world`s third-largest oil company, Petroleos de Venezuela SA (PdVSA). Looking to further the fortunes of Orimulsion, a liquid emulsion of bitumen and water from the Orinoco region of Venezuela, Bitor funded and provided technical support for the first large-scale test burn of the fuel in the 100-MW Unit 1 of NB Power`s Dalhousie station in northern New Brunswick. After making the required modifications, NB Power burned Orimulsion in Unit 1 for two years. By 1991, the utility had cleanly converted more than a million barrels of the fuel to nearly half a million megawatt-hours of electricity-in the process finding few reasons not to commit to permanently converting Dalhousie`s Unit 1, as well as coal fired 215-MW Unit 2, to burn Orimulsion.

  15. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 2 -- Jointly sponsored research program. Final report, October 1986--September 1993

    SciTech Connect (OSTI)

    Smith, V.E.

    1994-09-01

    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  16. Recovery and upgrading of heavy oil analyzed

    SciTech Connect (OSTI)

    Fornoff, L.L.; Van Driesen, R.P.; Viens, C.H.

    1980-10-13

    An analysis has been made of recovery and upgrading of Venezuelan heavy crudes by integrating steam-drive production data with an upgraded computer processing program. A study used 110 computer cases to analyze a project using Venezuelan heavy crude from the Jobo field with gravity of 9.2 API and 4.1% by wt sulfur for the base case. Sensitivity cases used 12.2 API oil from the Lot 9 field, Monagas state, Venezuela, with sulfur content of 2.3%. Four upgrading methods were studied (deasphalting, delayed coking, flexicoking, and LC-fining), all with favorable resulting economics.

  17. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect (OSTI)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  18. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen rangedmore » from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.« less

  19. Biomass fuel use in agriculture under alternative fuel prices

    SciTech Connect (OSTI)

    Bjornstad, D.J.; Hillsman, E.L.; Tepel, R.C.

    1984-11-01

    A linear programming model is used to analyze cost-competitiveness of biomass fuels in agricultural applications for the projected year 1990. With all else held constant, the prices of conventional fuels are increased and analytically compared to prices for biomass fuel products across a variety of end uses. Potential penetration of biomass fuels is measured as the share of each conventional fuel for which cost savings could be realized by substituting biomass fuels. This study examines the cost competitiveness of biomass fuels produced on farms, relative to conventional fuels (diesel, gasoline, natural gas, LPG, fuel oil, and electricity), as the prices of conventional fuels change. The study is targeted at the year 1990 and considers only fuel use in the agricultural sector. The method of analysis is to project fuel demands for ten farm operations in the year 1990 and to match these with biomass fuel substitutes from ten feedstock and nine process alternatives. In all, 61 feedstock/process combinations are possible. The matching of fuel demands and biomass fuels occurs in a linear programming model that seeks to meet fuel demands at minimum cost. Two types of biomass fuel facilities are considered, assuming a decentralized fuel distribution system. The first includes on-farm production units such as oil presses, low-Btu gasifiers, biogas digestors and direct combustion units. The second type of facility would be run by a farm co-operative. The primary data describing the biomass technologies are cost per unit output, where costs are calculated as first-year capital charges, plus al l allocable operating expenses, less any by-products of value. All costs assume commercial purchase of equipment. Homemade or makeshift installations are not considered. 1 reference.

  20. The Naval Petroleum and Oil Shale Reserves | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Naval Petroleum and Oil Shale Reserves The Naval Petroleum and Oil Shale Reserves To ensure sufficient fuel for the fleet, the Government began withdrawing probable oil-bearing lands from the public domain. Between 1909 and 1924, tracts in California, Utah, and Wyoming were set aside that became the Naval Petroleum and Oil Shale Reserves - the oldest component of today's Fossil Energy organization. PDF icon Naval Petroleum & Oil Shale Reserves - 90 Years of Ensuring the Nation's Security

  1. This Week In Petroleum Printer-Friendly Version

    Gasoline and Diesel Fuel Update (EIA)

    no Federal sulfur content restrictions. Several northeastern States are leading a transition to cleaner burning heating fuels by decreasing sulfur content in heating oil. Table...

  2. Total Crude Oil and Petroleum Products Imports by Area of Entry

    U.S. Energy Information Administration (EIA) Indexed Site

    by Area of Entry Product: Total Crude Oil and Petroleum Products Crude Oil Natural Gas Plant Liquids and Liquefied Refinery Gases Pentanes Plus Liquefied Petroleum Gases Ethane Ethylene Propane Propylene Normal Butane Butylene Isobutane Isobutylene Other Liquids Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Oxygenates (excl. Fuel Ethanol) Methyl Tertiary Butyl Ether (MTBE) Other Oxygenates Renewable Fuels (incl. Fuel Ethanol) Fuel Ethanol Biomass-Based Diesel Fuel Other Renewable Diesel Fuel

  3. Proceedings: 1987 fuel supply seminar

    SciTech Connect (OSTI)

    Prast, W.G.

    1988-08-01

    The seventh annual EPRI Fuel Supply Seminar was held in Baltimore, Maryland, from October 6 to 8, 1987. The major emphasis of the meeting was on identifying fuel market risks and planning concerns in order to cope with inherent uncertainties and make informed fuel supply decisions. Sessions dealt with the natural gas markets including the prospects for continued availability of gas as a boiler fuel, the relationship of gas and oil prices and the relevance of different regulatory issues. Other sessions addressed the political dimensions of world oil supply and the role of oil inventories in price dynamics, the interaction of world trade cycles, interest rates and currency fluctuations on utility fuel planning, and the role of strategic fuel planning in various utilities. The changing coal transportation market was the subject of several presentations, concluding with a review of utility experiences in integrating coal transportation and coal supply procurement. Presentations were made by various specialists including EPRI research contractors reporting on the results of ongoing research, speakers drawn from the utility, coal and natural gas industries, and independent consultants. The principal purpose of the seminar continues to be to provide utility fuel planners and fuel procurement managers with data and insights into the structure, operations and uncertainties of the fuel markets, thereby supporting their development of flexible fuel strategies and contributing to integrated utility decision making. Selected papers have been processed separately for inclusion in the energy data base.

  4. Fuel-cycle energy and emissions impacts of tripled fuel economy vehicles

    SciTech Connect (OSTI)

    Mintz, M.M.; Wang, M.Q.; Vyas, A.D.

    1998-12-31

    This paper presents estimates of the full cycle energy and emissions impacts of light-duty vehicles with tripled fuel economy (3X vehicles) as currently being developed by the Partnership for a New Generation of Vehicles (PNGV). Seven engine and fuel combinations were analyzed: reformulated gasoline, methanol, and ethanol in spark-ignition, direct-injection engines; low sulfur diesel and dimethyl ether in compression-ignition, direct-injection engines; and hydrogen and methanol in fuel-cell vehicles. The fuel efficiency gain by 3X vehicles translated directly into reductions in total energy demand, petroleum demand, and carbon dioxide emissions. The combination of fuel substitution and fuel efficiency resulted in substantial reductions in emissions of nitrogen oxide, carbon monoxide, volatile organic compounds, sulfur oxide, and particulate matter smaller than 10 microns, particularly under the High Market Share Scenario.

  5. Cost of Ownership and Well-to-Wheels Carbon Emissions/Oil Use of Alternative Fuels and Advanced Light-Duty Vehicle Technologies

    SciTech Connect (OSTI)

    Elgowainy, Mr. Amgad; Rousseau, Mr. Aymeric; Wang, Mr. Michael; Ruth, Mr. Mark; Andress, Mr. David; Ward, Jacob; Joseck, Fred; Nguyen, Tien; Das, Sujit

    2013-01-01

    The U.S. Department of Energy (DOE), Argonne National Laboratory (Argonne), and the National Renewable Energy Laboratory (NREL) updated their analysis of the well-to-wheels (WTW) greenhouse gases (GHG) emissions, petroleum use, and the cost of ownership (excluding insurance, maintenance, and miscellaneous fees) of vehicle technologies that have the potential to significantly reduce GHG emissions and petroleum consumption. The analyses focused on advanced light-duty vehicle (LDV) technologies such as plug-in hybrid, battery electric, and fuel cell electric vehicles. Besides gasoline and diesel, alternative fuels considered include natural gas, advanced biofuels, electricity, and hydrogen. The Argonne Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) and Autonomie models were used along with the Argonne and NREL H2A models.

  6. A technical and economic assessment of petroleum, heavy oil, shale oil and coal liquid refining

    SciTech Connect (OSTI)

    Sikonia, J.G.; Shah, B.R.; Ulowetz, M.A.

    1983-11-01

    Decreasing availability of conventional crude oil will result in the utilization of alternative raw materials for the production of transportation fuels. Based on currently available processes and as a result of detailed pilot plant studies, the differences in the technical and economic aspects of refining alternative feedstocks of heavy oil, coal liquids and shale oil have indicated that heavy, hydrogen-deficient materials require more complex and costly upgrading techniques. Compared to the base case of Arabian Light crude oil, the Mexican Maya heavy oil is worth about $4.35/B less, the coal liquid about $2.38/B less and the shale oil about $5.98/B less. All of these alternative fuels can be upgraded into high quality transportation fuels.

  7. Net Imports of Total Crude Oil and Products into the U.S. by Country

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Total Crude Oil and Products Crude Oil Products Pentanes Plus Liquefied Petroleum Gases Unfinished Oils Finished Motor Gasoline Reformulated Conventional Motor Gasoline Blending Components Reformulated Gasoline Blend. Comp. Conventional Gasoline Blend. Comp. MTBE (Oxygenate) Other Oxygenates Fuel Ethanol (Renewable) Biomass-Based Diesel Other Renewable Diesel Other Renewable Fuels Distillate Fuel Oil Distillate F.O., 15 ppm and under Distillate F.O., 15 to 500 ppm Distillate F.O., 500

  8. Sustainable Oils Inc | Open Energy Information

    Open Energy Info (EERE)

    producer and marketer of renewable, environmentally clean, and high-value Camelina-based biodiesel fuel. References: Sustainable Oils Inc.1 This article is a stub. You can help...

  9. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    DOE Patents [OSTI]

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  10. LPG fuel shutoff system

    SciTech Connect (OSTI)

    Watanabe, T.; Miyata, K.

    1988-01-26

    An LPG fuel shutoff system for use with a vehicle having an LPG fuel engine and having a solenoid valve to supply and shut off LPG fuel is described including: a relay having a relay contact which is closed when an electric current is fed to a coil of the relay; a pressure switch having a first position and a second position and adapted to be in the first position when engine oil pressure rises above a predetermined level; and an oil lamp adapted to light when the engine oil pressure is below the predetermined level, and wherein a solenoid coil of the solenoid valve is connected at one side to a battery through an ignition switch and a fuel switch. The solenoid coil also is connected, at another side of the solenoid coil, in series to the relay contact and the pressure switch in the second position respectively, the coil of the relay is connected to the solenoid valve side of the ignition switch through a starting switch, the oil lamp is connected between the ignition switch and the pressure switch.

  11. Stabilized sulfur binding using activated fillers

    DOE Patents [OSTI]

    Kalb, Paul D.; Vagin, Vyacheslav P.; Vagin, Sergey P.

    2015-07-21

    A method of making a stable, sulfur binding composite comprising impregnating a solid aggregate with an organic modifier comprising unsaturated hydrocarbons with at least one double or triple covalent bond between adjacent carbon atoms to create a modifier-impregnated aggregate; heating and drying the modifier-impregnated aggregate to activate the surface of the modifier-impregnated aggregate for reaction with sulfur.

  12. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu; King, David L.

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  13. Desulfurization of coal with hydroperoxides of vegetable oils. [Quarterly progress report], December 1, 1994--February 28, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, Ruozhi; Cheng, Jianjun; Shi, Feng; Gholson, K.L.; Ho, K.K.

    1995-12-31

    This project proposes a new method for removing organic sulfur from Illinois coals using readily available farm products. It proposes to use air and vegetable oils to disrupt the coal matrix, oxidize sulfur forms, increase volatiles, and desulfurize coal. This will be accomplished by impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover, the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. Preliminary experiments showed that IBC 104 coal catalyzes the formation of hydroperoxides in safflower oil and that more sulfur is extracted from the treated than untreated coal. During the first quarter the requirement of an added photosensitizer was eliminated, the catalytic effect of coal was confirmed, and the existence of a complex set of reactions was revealed. During this second quarter working with IBC-108 coal (2.3% organic S. 0.4% pyrite S), the effects of different ratios of oil:coal, different extraction solvents, and different temperatures were examined. A new pretreatment which combines alkali with linseed oil was discovered. Best organic sulfur removal is approximately 26% using alkali pretreatment combined with linseed oil at 1OO{degree}C. BTU loses can be kept to a minimum of 3% with proper use of solvents.

  14. Desulfurization of Illinois coals with hydroperoxides of vegetable oils and alkali. Technical report, September 1--November 30, 1995

    SciTech Connect (OSTI)

    Smith, G.V.; Gaston, R.D.; Song, R.; Cheng, J.; Shi, F.; Wang, Y.

    1995-12-31

    Organic sulfur is removed from coals by treatment with aqueous base, air, and vegetable oils with minimal loss of BTU. Such results were revealed during exploratory experiments on an ICCI funded project to remove organic sulfur from Illinois coals with hydroperoxides of vegetable oils. In fact, prewashing IBC-108 coal with dilute alkali prior to treating with linseed oil and air results in 26% removal of sulfur. This new method will be investigated by treating coals with alkali, impregnating coals with polyunsaturated oils, converting the oils to their hydroperoxides, and heating. Since these oils are relatively inexpensive and easily applied, this project could lead to a cost effective method for removing organic sulfur from coals. Moreover the oils are environmentally safe; they will produce no noxious products and will improve burning qualities of the solid products. During this first quarter the selection of base for pretreatment and extraction (Task 1) has been completed. NaOH is better than NH{sub 4}OH for the pretreatment and Na{sub 2}CO{sub 3} is better than NaOH for the oil extraction. About 40% of sulfur is removed from IBC-108 coal using 5% NaOH for pretreatment followed by linseed oil oxidation in air and Na{sub 2}CO{sub 3} extraction.

  15. Phosphorus, Sulfur, and Chlorine in Fuel Gases: Impact on High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transactions 26 (2010) 363-370) *Class I: least volatile and will remain in the ash *Class II: more volatile and will partition between solid and gaseous species *Class III: highly ...

  16. A novel process for upgrading heavy oil emulsions

    SciTech Connect (OSTI)

    Ng, F.T.T.; Rintjema, R.T.

    1994-12-31

    Canada has extensive reserves of high sulfur heavy oils. These heavy oils are recovered primarily by steam injection techniques. As a result, the heavy oils are obtained as emulsions at well-heads. The heavy oils, being high in sulfur and metals, and low in hydrogen to carbon atomic ratio, require upgrading such as desulfurization and hydrocracking before it can be used in conventional refineries. Conventional emulsion treatment and desulfurization technology require multistage processing. Thus, alternative technologies for processing heavy oil emulsions would be attractive. The authors have recently developed a novel single stage process for upgrading emulsions via activation of water to provide hydrogen in situ for catalytic desulfurization and hydrocracking. Current work is focused on the desulfurization aspect of upgrading, using benzothiophene as the model sulfur compound and molybdic acid as the catalyst. At 340 C and a CO loading pressure of 600 psi, up to 86% sulfur removal was obtained. As well, in situ generated H{sub 2} was found to be more active than externally supplied molecular H{sub 2}. A likely pathway for desulfurization of benzothiophene was via the initial hydrogenation of benzothiophene to dihydrobenzothiophene followed by hydrogenolysis to give ethylbenzene and H{sub 2}S.

  17. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 ...

  18. Method of removal of sulfur from coal and petroleum products

    DOE Patents [OSTI]

    Verkade, John G.; Mohan, Thyagarajan; Angelici, Robert J.

    1995-01-01

    A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

  19. Scientists Probe Lithium-Sulfur Batteries in Real Time - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7, 2012, Videos Scientists Probe Lithium-Sulfur Batteries in Real Time Lithium-sulfur batteries are a promising technology that could some day power electric vehicles. Scientists ...

  20. Understanding Lithium-Sulfur Batteries at the Molecular Level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 17, 2015, Accomplishments Understanding Lithium-Sulfur Batteries at the Molecular Level Conceived some 40 years ago, the lithium-sulfur battery can store, in theory, ...

  1. High capacity oil burner

    SciTech Connect (OSTI)

    Pedrosa, O.A. Jr.; Couto, N.C.; Fanqueiro, R.C.C.

    1983-11-01

    The present invention relates to a high capacity oil burner comprising a cylindrical atomizer completely surrounded by a protective cylindrical housing having a diameter from 2 to 3 times greater than the diameter of said atomizer; liquid fuels being injected under pressure into said atomizer and accumulating within said atomizer in a chamber for the accumulation of liquid fuels, and compressed air being injected into a chamber for the accumulation of air; cylindrical holes communicating said chamber for the accumulation of liquid fuels with the outside and cylindrical holes communicating said chamber for the accumulation of air with said cylindrical holes communicating the chamber for the accumulation of liquids with the outside so that the injection of compressed air into said liquid fuel discharge holes atomizes said fuel which is expelled to the outside through the end portions of said discharge holes which are circumferentially positioned to be burnt by a pilot flame; said protecting cylindrical housing having at its ends perforated circular rings into which water is injected under pressure to form a protecting fan-like water curtain at the rear end of the housing and a fan-like water curtain at the flame to reduce the formation of soot; the burning efficiency of said burner being superior to 30 barrels of liquid fuel per day/kg of the apparatus.

  2. Feedstock Supply System Design and Economics for Conversion of Lignocellulosic Biomass to Hydrocarbon Fuels Conversion Pathway: Fast Pyrolysis and Hydrotreating Bio-Oil Pathway "The 2017 Design Case"

    SciTech Connect (OSTI)

    Kevin L. Kenney; Kara G. Cafferty; Jacob J. Jacobson; Ian J. Bonner; Garold L. Gresham; J. Richard Hess; William A. Smith; David N. Thompson; Vicki S. Thompson; Jaya Shankar Tumuluru; Neal Yancey

    2014-01-01

    The U.S. Department of Energy promotes the production of liquid fuels from lignocellulosic biomass feedstocks by funding fundamental and applied research that advances the state of technology in biomass sustainable supply, logistics, conversion, and overall system sustainability. As part of its involvement in this program, Idaho National Laboratory (INL) investigates the feedstock logistics economics and sustainability of these fuels. Between 2000 and 2012, INL quantified and the economics and sustainability of moving biomass from the field or stand to the throat of the conversion process using conventional equipment and processes. All previous work to 2012 was designed to improve the efficiency and decrease costs under conventional supply systems. The 2012 programmatic target was to demonstrate a biomass logistics cost of $55/dry Ton for woody biomass delivered to fast pyrolysis conversion facility. The goal was achieved by applying field and process demonstration unit-scale data from harvest, collection, storage, preprocessing, handling, and transportation operations into INL’s biomass logistics model.

  3. Hydrogen as a fuel for fuel cell vehicles: A technical and economic comparison

    SciTech Connect (OSTI)

    Ogden, J.; Steinbugler, M.; Kreutz, T.

    1997-12-31

    All fuel cells currently being developed for near term use in vehicles require hydrogen as a fuel. Hydrogen can be stored directly or produced onboard the vehicle by reforming methanol, ethanol or hydrocarbon fuels derived from crude oil (e.g., Diesel, gasoline or middle distillates). The vehicle design is simpler with direct hydrogen storage, but requires developing a more complex refueling infrastructure. In this paper, the authors compare three leading options for fuel storage onboard fuel cell vehicles: compressed gas hydrogen storage; onboard steam reforming of methanol; onboard partial oxidation (POX) of hydrocarbon fuels derived from crude oil. Equilibrium, kinetic and heat integrated system (ASPEN) models have been developed to estimate the performance of onboard steam reforming and POX fuel processors. These results have been incorporated into a fuel cell vehicle model, allowing us to compare the vehicle performance, fuel economy, weight, and cost for various fuel storage choices and driving cycles. A range of technical and economic parameters were considered. The infrastructure requirements are also compared for gaseous hydrogen, methanol and hydrocarbon fuels from crude oil, including the added costs of fuel production, storage, distribution and refueling stations. Considering both vehicle and infrastructure issues, the authors compare hydrogen to other fuel cell vehicle fuels. Technical and economic goals for fuel cell vehicle and hydrogen technologies are discussed. Potential roles for hydrogen in the commercialization of fuel cell vehicles are sketched.

  4. Energy Information Administration - Table 2. End Uses of Fuel...

    Gasoline and Diesel Fuel Update (EIA)

    -- -- -- Net Electricity 74 79 76 Residual Fuel Oil 19 * 11 Natural Gas 369 329 272 Machine Drive -- -- -- Net Electricity 68 86 77 Notes 1. The North American Industry...

  5. Designer Catalysts for Next Generation Fuel Synthesis - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    industry's "workhorse" catalysts for upgrading heavy petroleum feed stocks and removing ... Bio-fuel production Hydrogen generation Direct coal liquefaction Oil refining ...

  6. Energy Department to Loan Emergency Fuel to Department of Defense...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Defense Logistics Agency (DLA) will begin drawing down stocks from the heating oil reserve terminal in Groton, Connecticut as early as tomorrow. The fuel, which will be ...

  7. Production Costs of Alternative Transportation Fuels | Open Energy...

    Open Energy Info (EERE)

    ... further results Find Another Tool FIND TRANSPORTATION TOOLS This study examines the production costs of a range of transport fuels and energy carriers under varying crude oil...

  8. Oil shale as an energy source in Israel

    SciTech Connect (OSTI)

    Fainberg, V.; Hetsroni, G. [Technion-Israel Inst. of Tech., Haifa (Israel)

    1996-01-01

    Reserves, characteristics, energetics, chemistry, and technology of Israeli oil shales are described. Oil shale is the only source of energy and the only organic natural resource in Israel. Its reserves of about 12 billion tons will be enough to meet Israel`s requirements for about 80 years. The heating value of the oil shale is 1,150 kcal/kg, oil yield is 6%, and sulfur content of the oil is 5--7%. A method of oil shale processing, providing exhaustive utilization of its energy and chemical potential, developed in the Technion, is described. The principal feature of the method is a two-stage pyrolysis of the oil shale. As a result, gas and aromatic liquids are obtained. The gas may be used for energy production in a high-efficiency power unit, or as a source for chemical synthesis. The liquid products can be an excellent source for production of chemicals.

  9. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.; Thomas, C.P.

    1995-10-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to upgrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  10. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.

    1995-07-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to ungrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  11. Method for cold stable biojet fuel

    DOE Patents [OSTI]

    Seames, Wayne S.; Aulich, Ted

    2015-12-08

    Plant or animal oils are processed to produce a fuel that operates at very cold temperatures and is suitable as an aviation turbine fuel, a diesel fuel, a fuel blendstock, or any fuel having a low cloud point, pour point or freeze point. The process is based on the cracking of plant or animal oils or their associated esters, known as biodiesel, to generate lighter chemical compounds that have substantially lower cloud, pour, and/or freeze points than the original oil or biodiesel. Cracked oil is processed using separation steps together with analysis to collect fractions with desired low temperature properties by removing undesirable compounds that do not possess the desired temperature properties.

  12. Winter fuels report

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    The report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and state and local governments on the following topics: (1) distillate fuel oil net production, imports and stocks for all PADD's and product supplied on a US level; (2) propane net production, imports and stocks for Petroleum Administration for Defense Districts (PADD) I, II, and III; (3) natural gas supply and disposition and underground storage for the United States and consumption for all PADD's; (4) residential and wholesale pricing data for propane and heating oil for those states participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; (5) crude oil and petroleum price comparisons for the United States and selected cities; and (6) US total heating degree-days by city.

  13. D1 Williamson Magor Bio Fuel | Open Energy Information

    Open Energy Info (EERE)

    Magor Bio Fuel Jump to: navigation, search Name: D1 Williamson Magor Bio Fuel Place: Kolkata, West Bengal, India Zip: 700 001 Product: Joint venture between D1 Oils and Williamson...

  14. D1 Fuel Crops Ltd | Open Energy Information

    Open Energy Info (EERE)

    D1 Fuel Crops Ltd Jump to: navigation, search Name: D1 Fuel Crops Ltd Place: London, United Kingdom Zip: SE1 2RE Product: London-based JV between BP and D1 oils focusing on the...

  15. Houston BioFuels Consultants | Open Energy Information

    Open Energy Info (EERE)

    BioFuels Consultants Jump to: navigation, search Name: Houston BioFuels Consultants Place: Kingwood, Texas Zip: 77345 Product: A Houston-based consultancy run by oil industry...

  16. Effect of morphology of sulfurized materials in the retention of mercury from gas streams

    SciTech Connect (OSTI)

    Guijarro, M.I.; Mendioroz, S.; Munoz, V.

    1998-03-01

    Mercury pollution sources are chloralkali industries, metal sulfide ore smelting, gold refining, cement production, industrial applications of metals, and, especially, fossil fuel combustion and incineration of sewage sludge or municipal garbage. The retention of mercury vapor by sulfur supported on sepiolite has been studied, and the utility of sepiolite as a dispersant for the active phase, sulfur, has been thoroughly ascertained. Samples with 10% S supported on sepiolite of varying size and shape have been prepared from powders sulfurized by reaction/deposit, and their efficiency in depurating air streams with 95 ppm mercury has been tested in a dynamic system using a fixed-bed glass reactor and fluid velocities ranging from 3.1 to 18.9 cm/s. From breakthrough curves under various sets of conditions, the importance of mass transfer under the process conditions has been proven. The progress of the reaction is limited by the resistance to reactant diffusion inside the solid through the layer of product formed. Sulfur reaction to HgS is reduced to an external zone of the solid, giving rise to an egg-shell deposit whose extension is related to sulfur dispersion and porosity of the adsorbent. Then, conversion and capacity of the samples are related to their porosity and S/V ratio. The use of SEM helps to confirm those statements. The 10% S samples compare well with the more conventional S/activated carbon, with their use being advantageous for the low price and abundance of the substrate.

  17. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Energy Savers [EERE]

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil)...

  18. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  19. Catalyst for elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Liu, W.

    1995-01-24

    A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

  20. Toxicology Studies on Lewisite and Sulfur Mustard Agents: Subchronic Toxicity of Sulfur Mustard (HD) In Rats Final Report

    SciTech Connect (OSTI)

    Sasser, L. B.; Miller, R. A.; Kalkwarf, D, R.; Buschbom, R. L.; Cushing, J. A.

    1989-06-30

    Occupational health standards have not been established for sulfur mustard [bis(2- chlorethyl)-sulfide], a strong alkylating agent with known mutagenic properties. Seventytwo Sprague-Dawley rats of each sex, 6-7 weeks old, were divided into six groups (12/group/ sex) and gavaged with either 0, 0.003 , 0.01 , 0.03 , 0.1 or 0.3 mg/kg of sulfur mustard in sesame oil 5 days/week for 13 weeks. No dose-related mortality was observed. A significant decrease (P ( 0.05) in body weight was observed in both sexes of rats only in the 0.3 mg/kg group. Hematological evaluations and clinical chemistry measurements found no consistent treatment-related effects at the doses studied. The only treatment-related lesion associated with gavage exposure upon histopathologic evaluation was epithelial hyperplasia of the forestomach of both sexes at 0.3 mg/kg and males at 0.1 mg/kg. The hyperplastic change was minimal and characterized by cellular disorganization of the basilar layer, an apparent increase in mitotic activity of the basilar epithelial cells, and thickening of the epithelial layer due to the apparent increase in cellularity. The estimated NOEL for HD in this 90-day study is 0.1 mg/kg/day when administered orally.