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Sample records for fuel cells electrodes

  1. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Durable Fuel Cell Membrane Electrode Assembly (MEA) Durable Fuel Cell Membrane Electrode Assembly (MEA) A revolutionary method of building a membrane electrode assembly (MEA) for...

  2. Fuel cell electrodes

    DOE Patents [OSTI]

    Strmcnik, Dusan; Cuesta, Angel; Stamenkovic, Vojislav; Markovic, Nenad

    2015-06-23

    A process includes patterning a surface of a platinum group metal-based electrode by contacting the electrode with an adsorbate to form a patterned platinum group metal-based electrode including platinum group metal sites blocked with adsorbate molecules and platinum group metal sites which are not blocked.

  3. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

    1999-01-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

  4. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal and J.create connected nanostructured SOFC electrodes is reviewed.of Solid Oxide Fuel Cells (SOFC) to directly and efficiently

  5. Sintered electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Warner, K.A.

    1999-06-01

    A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

  6. Electrode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D. (Schenectady, NY); Zarnoch, Kenneth P. (Clifton Park, NY)

    1983-01-01

    A sintered porous electrode useful for a molten carbonate fuel cell is produced which is composed of a plurality of 5 wt. % to 95 wt. % nickel balance copper alloy encapsulated ceramic particles sintered together by the alloy.

  7. Nanostructured Solid Oxide Fuel Cell Electrodes

    SciTech Connect (OSTI)

    Sholklapper, Tal Zvi

    2007-12-15

    The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

  8. Fuel cell electrode and method of preparation

    DOE Patents [OSTI]

    Kaun, T.D

    1984-03-02

    A fuel cell having good resistance to compressive creep includes electrodes having a superstructure of porous electrically conductive foam with surface sections adjacent to opposing surfaces of an electrolyte matrix impregnated with electrode catalyst materials. The catalyst materials are affixed in sections contiguous to an inner major surface by sinter bonding, electrochemical bonding or restrictive interstitial spacing. The outer sections of the porous plaque thickness are reserved for gas distribution to the electrode catalyst. Oxidant and fuel gases can be separately manifolded into alternate sides of a fuel cell stack by sealing opposing edges of the porous plaques containing the anode material in one set of opposing side surfaces and sealing opposing edges of the porous plaque containing cathode material in alternate side surfaces of the stack.

  9. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S

    2014-02-25

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  10. Advanced membrane electrode assemblies for fuel cells

    DOE Patents [OSTI]

    Kim, Yu Seung; Pivovar, Bryan S.

    2012-07-24

    A method of preparing advanced membrane electrode assemblies (MEA) for use in fuel cells. A base polymer is selected for a base membrane. An electrode composition is selected to optimize properties exhibited by the membrane electrode assembly based on the selection of the base polymer. A property-tuning coating layer composition is selected based on compatibility with the base polymer and the electrode composition. A solvent is selected based on the interaction of the solvent with the base polymer and the property-tuning coating layer composition. The MEA is assembled by preparing the base membrane and then applying the property-tuning coating layer to form a composite membrane. Finally, a catalyst is applied to the composite membrane.

  11. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  12. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene (Coram, NY)

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  13. Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode

    E-Print Network [OSTI]

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-01-01

    Infiltrated Solid Oxide Fuel Cell Electrode Tal Z.SOFC (Solid Oxide Fuel Cell) electrodes can significantly

  14. Fuel cell generator with fuel electrodes that control on-cell fuel reformation

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA); Zhang, Gong (Murrysville, PA)

    2011-10-25

    A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

  15. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    that fuel cells are superior from an efficiency standpointefficiency is only The theoretical voltage obtained from fuel cellof the efficiency vs. rate power for fuel cells is compared

  16. Electrode electrolyte interlayers containing cerium oxide for electrochemical fuel cells

    DOE Patents [OSTI]

    Borglum, Brian P. (Edgewood, PA); Bessette, Norman F. (N. Huntingdon, PA)

    2000-01-01

    An electrochemical cell is made having a porous fuel electrode (16) and a porous air electrode (13), with solid oxide electrolyte (15) therebetween, where the air electrode surface opposing the electrolyte has a separate, attached, dense, continuous layer (14) of a material containing cerium oxide, and where electrolyte (16) contacts the continuous oxide layer (14), without contacting the air electrode (13).

  17. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and Technology of Ceramic Fuel Cells, p. 209, Elsevier, NewI. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal

  18. Morphological Analyses of Polymer Electrolyte Fuel Cell Electrodes with

    E-Print Network [OSTI]

    Litster, Shawn

    fuel cell (PEFC) electrodes, which are often referred to as catalyst layers. Due to the combination of automo- tive PEFC stacks [3]. Typical PEFC electrodes consist of a network of carbon black aggregates for a polymer elec- trolyte fuel cell (PEFC) catalyst layer. The 3D structure of the platinum

  19. Method of improving fuel cell performance by removing at least one metal oxide contaminant from a fuel cell electrode

    DOE Patents [OSTI]

    Kim, Yu Seung (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2009-08-18

    A method of removing contaminants from a fuel cell catalyst electrode. The method includes providing a getter electrode and a fuel cell catalyst electrode having at least one contaminant to a bath and applying a voltage sufficient to drive the contaminant from the fuel cell catalyst electrode to the getter electrode. Methods of removing contaminants from a membrane electrode assembly of a fuel cell and of improving performance of a fuel cell are also provided.

  20. Fuel cell with Pt/Pd electrocatalyst electrode

    DOE Patents [OSTI]

    Stonehart, Paul (Madison, CT)

    1983-01-01

    An electrode for use in a phosphoric acid fuel cell comprising a graphitized or partially graphitized carbon support having a platinum/palladium electrocatalyst thereon. Preferably, the platinum/palladium catalyst comprises 20 to 65 weight percent palladium.

  1. Durable Fuel Cell Membrane Electrode Assembly (MEA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalentLaboratory |Sectorfor $1.14 Per1-E WholesaleDurable Fuel Cell

  2. Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Vora, Shailesh D. (Monroeville, PA)

    2001-01-01

    A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.

  3. Solid Oxide Fuel Cell Technologies: Improved Electrode-Electrode Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effect Photovoltaics -7541C. Temperature and energy Most basically,Processes -for

  4. Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode

    E-Print Network [OSTI]

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-01-01

    catalysts infiltrated into SOFC (Solid Oxide Fuel Cell)the demanding environment of SOFC electrodes. Introductioninfiltrated into already formed SOFC electrodes to enhance

  5. Fabrication of catalytic electrodes for molten carbonate fuel cells

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL)

    1988-01-01

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

  6. The design of a microfabricated air electrode for liquid electrolyte fuel cells

    E-Print Network [OSTI]

    Pierre, Fritz, 1977-

    2007-01-01

    In this dissertation, the microfabricated electrode (MFE) concept was applied to the design of an air electrode for liquid electrolyte fuel cells. The catalyst layer of the electrode is envisioned to be fabricated by using ...

  7. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, Lewis (Monroeville, PA); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell.

  8. Air electrode composition for solid oxide fuel cell

    DOE Patents [OSTI]

    Kuo, L.; Ruka, R.J.; Singhal, S.C.

    1999-08-03

    An air electrode composition for a solid oxide fuel cell is disclosed. The air electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO{sub 3}. The A-site of the air electrode composition comprises a mixed lanthanide in combination with rare earth and alkaline earth dopants. The B-site of the composition comprises Mn in combination with dopants such as Mg, Al, Cr and Ni. The mixed lanthanide comprises La, Ce, Pr and, optionally, Nd. The rare earth A-site dopants preferably comprise La, Nd or a combination thereof, while the alkaline earth A-site dopant preferably comprises Ca. The use of a mixed lanthanide substantially reduces raw material costs in comparison with compositions made from high purity lanthanum starting materials. The amount of the A-site and B-site dopants is controlled in order to provide an air electrode composition having a coefficient of thermal expansion which closely matches that of the other components of the solid oxide fuel cell. 3 figs.

  9. Different electrode configurations to optimize performance of multi-electrode microbial fuel cells for generating power or treating

    E-Print Network [OSTI]

    Different electrode configurations to optimize performance of multi- electrode microbial fuel cells a b s t r a c t Scaling-up of microbial fuel cells (MFCs) for practical applications requires compact. Introduction Microbial fuel cells (MFCs) are an emerging method for achieving sustainable wastewater treatment

  10. Fabrication of fuel cell electrodes and other catalytic structures

    DOE Patents [OSTI]

    Smith, J.L.

    1987-02-11

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.

  11. Automated catalyst processing for cloud electrode fabrication for fuel cells

    DOE Patents [OSTI]

    Goller, Glen J. (West Springfield, MA); Breault, Richard D. (Coventry, CT)

    1980-01-01

    A process for making dry carbon/polytetrafluoroethylene floc material, particularly useful in the manufacture of fuel cell electrodes, comprises of the steps of floccing a co-suspension of carbon particles and polytetrafluoroethylene particles, filtering excess liquids from the co-suspension, molding pellet shapes from the remaining wet floc solids without using significant pressure during the molding, drying the wet floc pellet shapes within the mold at temperatures no greater than about 150.degree. F., and removing the dry pellets from the mold.

  12. Analysis of Pt/C electrode performance in a flowing-electrolyte alkaline fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Analysis of Pt/C electrode performance in a flowing- electrolyte alkaline fuel cell Fikile R cell Electrode characterization X-ray micro-computed tomography Microfluidic fuel cell Carbonates a b a microfluidic H2/O2 fuel cell as an analytical platform. Both anodes and cathodes were investigated

  13. Polymer electrolyte fuel cell electrodes grown by vapor deposition techniques Pascal Brault*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Polymer electrolyte fuel cell electrodes grown by vapor deposition techniques Pascal Brault Abstract: Polymer fuel cell electrode growth using vapor deposition techniques is reviewed. The supports process: sputtering, CVD, PECVD, MOCVD. In each case, up-to-date fuel cell performances are highlighted

  14. Development of high-power electrodes for a liquid-feed direct methanol fuel cell

    E-Print Network [OSTI]

    Development of high-power electrodes for a liquid-feed direct methanol fuel cell C. Lim, C.Y. Wang for a liquid-feed direct methanol fuel cell (DMFC) were fabricated by using a novel method of modi®ed Na.V. All rights reserved. Keywords: Direct methanol fuel cells; Membrane-electrode assembly (MEA); Polymer

  15. Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs M. D. Gasda,a

    E-Print Network [OSTI]

    Gall, Daniel

    Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs Layers M. D. Gasda,a R. Teki,b T.-M. Lu as cathode electrodes in proton exchange membrane PEM fuel cells using Nafion 1135 membranes and Teflon, 2009. Published March 24, 2009. Polymer electrolyte membrane or proton exchange membrane PEM fuel cells

  16. A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE

    E-Print Network [OSTI]

    Stockie, John

    A SHARP INTERFACE REDUCTION FOR MULTIPHASE TRANSPORT IN A POROUS FUEL CELL ELECTRODE KEITH exchange membrane fuel cell is a highly porous material which acts to distribute reactant gases uniformly perturbation, fuel cell electrodes, free surface. AMS subject classifications. 35B40, 35K55, 76R99, 76S05 1

  17. The performance of fluidized beds, packed beds, and screens as fuel cell electrodes

    E-Print Network [OSTI]

    Ruflin, Justin, 1981-

    2006-01-01

    At present, most fuel cells employ porous gas diffusion (PGD) electrodes. Although much effort has been spent on their development, the performance and cost of PGD electrodes are still major obstacles to the successful ...

  18. Influence of electrode stress on proton exchange membrane fuel cell performance : experimental characterization and power optimization

    E-Print Network [OSTI]

    Gallant, Betar M. (Betar Maurkah)

    2008-01-01

    Compressive stress applied to the electrode area of a Proton Exchange Membrane (PEM) fuel cell is known to significantly affect power output. In practice, electrode stress arises during operation due to the clamping force ...

  19. The effects of chemical pressurization on screen electrode fuel cells

    E-Print Network [OSTI]

    Ahmed, Ali, S.B. Massachusetts Institute of Technology

    2007-01-01

    A large amount of fuel cell research focuses on porous gas diffusion (PGD) fuel cells which currently produce the best power density. However, this sect of fuel cell technology has many obstacles to overcome before becoming ...

  20. Synthesis and Stability of a Nanoparticle-Infiltrated Solid OxideFuel Cell Electrode

    SciTech Connect (OSTI)

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-11-20

    Nanoparticulate catalysts infiltrated into SOFC (Solid OxideFUel Cell) electrodes can significantly enhance the cell performance, butthe stability of these electrodes has been an open issue. An infiltrationprocedure is reported that leads to a stable scandia-stablized zirconia(SSZ) cathode electrode performance.

  1. Design of high-ionic conductivity electrodes for direct methanol fuel cells

    E-Print Network [OSTI]

    Schrauth, Anthony J

    2011-01-01

    Carbon-supported porous electrodes are used in low-temperature fuel cells to provide maximum catalyst surface area, while taking up little volume and using minimum catalyst material. In Direct Methanol Fuel Cells (DMFCs), ...

  2. Battery and fuel cell electrodes containing stainless steel charging additive

    DOE Patents [OSTI]

    Zuckerbrod, David (Pittsburgh, PA); Gibney, Ann (Monroeville, PA)

    1984-01-01

    An electrode for use in electrochemical energy cells is made, comprising a hydrophilic layer and a hydrophobic layer, where the hydrophilic layer comprises a hydrophilic composite which includes: (i) carbon particles; (ii) stainless steel particles; (iii) a nonwetting agent; and (iv) a catalyst, where at least one current collector contacts said composite.

  3. An Investigation of Different Methods of Fabricating Membrane Electrode Assemblies for Methanol Fuel Cells

    E-Print Network [OSTI]

    Hall, Kwame (Kwame J.)

    2009-01-01

    Methanol fuel cells are electrochemical conversion devices that produce electricity from methanol fuel. The current process of fabricating membrane electrode assemblies (MEAs) is tedious and if it is not sufficiently ...

  4. High Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    fuel cells currently used in cars have a resource efficiency of 1 or 2 kW gPt -1 . The high amount of platinum makes commercial fuel cells reliable but the resource efficiency is far too low to provideHigh Performance Plasma Sputtered PdPt Fuel Cell Electrodes with Ultra Low Loading M. Mougenot1, 2

  5. High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low catalytic metal Loadings

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 High Performance Plasma Sputtered Fuel Cell Electrodes with Ultra Low catalytic metal Loadings C in plasma fuel cell deposition devices. Pt loadings lower than 0.01 mg cm-2 have been realized. The Pt density of 250 kW gPt -1 . 1-Introduction The great potential for the fuel cell technology to overcome

  6. High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes S Cuynet1 as a cathode of a proton exchange membrane fuel cell. An increase of 80 % at 0.65 V of the PEMFC power density) 272001" #12;2 Proton exchange membrane fuel cells (PEMFC) have the potential to provide

  7. The Effect of Electrode Morphology on Solid Oxide Fuel Cell Performance J.G. Pharoaha

    E-Print Network [OSTI]

    Schmidt, Volker

    The Effect of Electrode Morphology on Solid Oxide Fuel Cell Performance J.G. Pharoaha , L. Handl b and V. Schmidtb a Queen's-RMC Fuel Cell Research Centre, Queen's University, Kingston, ON, K7L 4T5 transport calculations. Introduction Solid oxide fuel cells are often made with two distinct solid materials

  8. Phase-field modeling of three-phase electrode microstructures in solid oxide fuel cells

    E-Print Network [OSTI]

    Chen, Long-Qing

    Phase-field modeling of three-phase electrode microstructures in solid oxide fuel cells Qun Li, mechanical deformation, and heterogeneous damage accumulation in solid oxide fuel cell anodes J. Appl. Phys oxide fuel cell/gas turbine cycle J. Renewable Sustainable Energy 4, 043115 (2012) Electric

  9. Performance of plasma sputtered Fuel Cell electrodes with ultra-low Pt M. Cavarroca

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Performance of plasma sputtered Fuel Cell electrodes with ultra-low Pt loadings M. Cavarroca , A. Abstract Ultra-low Pt content PEMFC electrodes have been manufactured using magnetron co- sputtering cell; Plasma sputtering deposition; ultra low platinum loading * Corresponding author: Fax: +33 2 38 41

  10. Fabrication of carbon-aerogel electrodes for use in phosphoric acid fuel cells

    E-Print Network [OSTI]

    Tharp, Ronald S

    2005-01-01

    An experiment was done to determine the ability to fabricate carbon aerogel electrodes for use in a phosphoric acid fuel cell (PAFC). It was found that the use of a 25% solution of the surfactant Cetyltrimethylammonium ...

  11. HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana

    E-Print Network [OSTI]

    Sethuraman, Vijay A.

    HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana , L. A. Wiseb , S for the poisoning kinetics of hydrogen sulfide (H2S) on composite solid polymer electrolyte Pt (SPE-Pt) electrode, total recovery with neat hydrogen was not possible and a partial recovery was possible by a potential

  12. Method of preparing a dimensionally stable electrode for use in a molten carbonate fuel cell

    DOE Patents [OSTI]

    Swarr, T.E.; Wnuck, W.G.

    1986-01-29

    A method is disclosed for preparing a dimensionally stable electrode structure, particularly nickel-chromium anodes, for use in a molten carbonate fuel cell stack. A low-chromium to nickel alloy is provided and oxidized in a mildly oxidizing gas of sufficient oxidation potential to oxidize chromium in the alloy structure. Typically, a steam/H/sub 2/ gas mixture in a ratio of about 100/1 and at a temperature below 800/sup 0/C is used as the oxidizing medium. This method permits the use of less than 5 wt % chromium in nickel alloy electrodes while obtaining good resistance to creep in the electrodes of a fuel cell stack.

  13. Method for sintering fuel cell electrodes using a carrier

    SciTech Connect (OSTI)

    Donelson, R.; Bryson, E.S.

    1995-03-28

    A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  14. Coated metal sintering carriers for fuel cell electrodes

    DOE Patents [OSTI]

    Donelson, R.; Bryson, E.S.

    1998-11-10

    A carrier is described for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a water-based carbon paint, the water-based carbon paint comprising water, powdered graphite, an organic binder, a wetting agent, a dispersing agent and a defoaming agent.

  15. Method for sintering fuel cell electrodes using a carrier

    DOE Patents [OSTI]

    Donelson, Richard (Victoria, AU); Bryson, E. S. (Downers Grove, IL)

    1995-01-01

    A carrier for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a carbon-based paint, the carbon-based paint comprising an organic binder. The carbon-based paint may be an alcohol or a solvent-based paint or a water-based paint.

  16. Coated metal sintering carriers for fuel cell electrodes

    DOE Patents [OSTI]

    Donelson, Richard (Glen Waverly, AU); Bryson, E. S. (Downers Grove, IL)

    1998-01-01

    A carrier for conveying components of a fuel cell to be sintered through a sintering furnace. The carrier comprises a metal sheet coated with a water-based carbon paint, the water-based carbon paint comprising water, powdered graphite, an organic binder, a wetting agent, a dispersing agent and a defoaming agent.

  17. Copper-substituted perovskite compositions for solid oxide fuel cell cathodes and oxygen reduction electrodes in other electrochemical devices

    DOE Patents [OSTI]

    Rieke, Peter C. (Pasco, WA); Coffey, Gregory W. (Richland, WA); Pederson, Larry R. (Kennewick, WA); Marina, Olga A. (Richland, WA); Hardy, John S. (Richland, WA); Singh, Prabhaker (Richland, WA); Thomsen, Edwin C. (Richland, WA)

    2010-07-20

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells. Also provided are electrochemical devices that include active oxygen reduction electrodes, such as solid oxide fuel cells, sensors, pumps and the like. The compositions comprises a copper-substituted ferrite perovskite material. The invention also provides novel methods for making and using the electrode compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having cathodes comprising the compositions.

  18. Modified cermet fuel electrodes for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Churchill Boro, PA); Spengler, Charles J. (Murrysville, PA)

    1991-01-01

    An exterior porous electrode (10), bonded to a solid oxygen ion conducting electrolyte (13) which is in contact with an interior electrode (14), contains coarse metal particles (12) of nickel and/or cobalt, having diameters from 3 micrometers to 35 micrometers, where the coarse particles are coated with a separate, porous, multiphase layer (17) containing fine metal particles of nickel and/or cobalt (18), having diameters from 0.05 micrometers to 1.75 micrometers and conductive oxide (19) selected from cerium oxide, doped cerium oxide, strontium titanate, doped strontium titanate and mixtures thereof.

  19. Optimization design of electrodes for anode-supported solid oxide fuel cells via genetic algorithm

    SciTech Connect (OSTI)

    Shi, J.; Xue, X.

    2011-01-01

    Porous electrode is the critical component of solid-oxide fuel cells (SOFCs) and provides a functional material backbone for multi-physicochemical processes. Model based electrode designs could significantly improve SOFC performance. This task is usually performed via parameter studies for simple case and assumed property distributions for graded electrodes. When nonlinearly coupled multiparameters of electrodes are considered, it could be very difficult for the model based parameter study method to effectively and systematically search the design space. In this research, the optimization approach with a genetic algorithm is demonstrated for this purpose. An anode-supported proton conducting SOFC integrated with a fuel supply system is utilized as a physical base for the model development and the optimization design. The optimization results are presented, which are difficult to obtain for parametric study method.

  20. Gas Diffusion Electrodes for Fuel Cells - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)ForthcomingGENERALProblems I n Q

  1. Enhancement of water retention in the membrane electrode assembly for direct methanol fuel cells operating with neat

    E-Print Network [OSTI]

    Zhao, Tianshou

    al. [10], assuming the overall efficiency of the fuel cell system is 20%, the specific energyEnhancement of water retention in the membrane electrode assembly for direct methanol fuel cells 31 July 2010 Keywords: Fuel cell Direct methanol fuel cell (DMFC) Neat-methanol operation Water

  2. Durable Fuel Cell Membrane Electrode Assembly (MEA) - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalentLaboratory |Sectorfor $1.14 Per1-E WholesaleDurable Fuel

  3. BIOENERGY AND BIOFUELS A multi-electrode continuous flow microbial fuel cell

    E-Print Network [OSTI]

    BIOENERGY AND BIOFUELS A multi-electrode continuous flow microbial fuel cell with separator this separator with the cathode. The maximum power density was 975 mW/m2 , with an overall chemical oxygen demand densities, the recovery of elec- trons as current [coulombic efficiency (CE)], and energy recovery while

  4. Simplified process for leaching precious metals from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ)

    2009-12-22

    The membrane electrode assemblies of fuel cells are recycled to recover the catalyst precious metals from the assemblies. The assemblies are cryogenically embrittled and pulverized to form a powder. The pulverized assemblies are then mixed with a surfactant to form a paste which is contacted with an acid solution to leach precious metals from the pulverized membranes.

  5. Core-Shell Fuel Cell Electrodes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit the followingConcentratingPortalCool MagneticCopper

  6. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

    2012-06-26

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  7. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Kuo, Lewis (Monroeville, PA); Li, Baozhen (Essex Junction, VT)

    1999-01-01

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO.sub.3. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La.sub.w Ca.sub.x Ln.sub.y Ce.sub.z MnO.sub.3, wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics.

  8. Lanthanum manganite-based air electrode for solid oxide fuel cells

    DOE Patents [OSTI]

    Ruka, R.J.; Kuo, L.; Li, B.

    1999-06-29

    An air electrode material for a solid oxide fuel cell is disclosed. The electrode material is based on lanthanum manganite having a perovskite-like crystal structure ABO[sub 3]. The A-site of the air electrode material preferably comprises La, Ca, Ce and at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd. The B-site of the electrode material comprises Mn with substantially no dopants. The ratio of A:B is preferably slightly above 1. A preferred air electrode composition is of the formula La[sub w]Ca[sub x]Ln[sub y]Ce[sub z]MnO[sub 3], wherein Ln comprises at least one lanthanide selected from Sm, Gd, Dy, Er, Y and Nd, w is from about 0.55 to about 0.56, x is from about 0.255 to about 0.265, y is from about 0.175 to about 0.185, and z is from about 0.005 to about 0.02. The air electrode material possesses advantageous chemical and electrical properties as well as favorable thermal expansion and thermal cycle shrinkage characteristics. 10 figs.

  9. Effect of electrode configuration and electronic conductivity on current density distribution measurements in PEM fuel cells

    E-Print Network [OSTI]

    Natarajan, Dilip; Van Nguyen, Trung

    2004-09-03

    and pollution free characteristics make them an attractive option for terrestrial applications. Of the various types of fuel cells available, Proton Exchange Membrane (PEMFC) fuel cells are considered to be most suitable for transportation and portable... to the catalyst layer and electrode width along the channel, 2) The ratio of in-plane and through-plane area, 3) The ratio of in-plane and through-plane conductivities of the GDL material and finally, 4) The relative contact resistances between the GDL...

  10. Electrode assembly for use in a solid polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Raistrick, Ian D. (Los Alamos, NM)

    1989-01-01

    A gas reaction fuel cell may be provided with a solid polymer electrolyte membrane. Porous gas diffusion electrodes are formed of carbon particles supporting a catalyst which is effective to enhance the gas reactions. The carbon particles define interstitial spaces exposing the catalyst on a large surface area of the carbon particles. A proton conducting material, such as a perfluorocarbon copolymer or ruthenium dioxide contacts the surface areas of the carbon particles adjacent the interstitial spaces. The proton conducting material enables protons produced by the gas reactions adjacent the supported catalyst to have a conductive path with the electrolyte membrane. The carbon particles provide a conductive path for electrons. A suitable electrode may be formed by dispersing a solution containing a proton conducting material over the surface of the electrode in a manner effective to coat carbon surfaces adjacent the interstitial spaces without impeding gas flow into the interstitial spaces.

  11. Process for recycling components of a PEM fuel cell membrane electrode assembly

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ)

    2012-02-28

    The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

  12. Influence of membrane-electrode interface on long-term performance of direct methanol fuel cells

    SciTech Connect (OSTI)

    Kim, Y. S. (Yu Seung); Pivovar, B. S. (Bryan Scott)

    2004-01-01

    Long-term stability of direct methanol fuel cells (DMFCs) is one of the most critical requirements for the successful launch of this technology to commercial market. When a DMFC is operated for extended periods of time, performance decreases continuously. The performance decay in continuous operation of DMFCs is caused by several different attributes, such as surface oxidation of platinum at the cathode, loss of catalytic active surface area, interfacial failure between membrane and electrode, changing hydrophobicity of backing layers or ruthenium crossover. Among those attributes, the interfacial incompatibility between membrane and electrode becomes more important when alternative polymer electrolyte membranes (PEM) are used with Nafion-bonded electrode. In earlier work, we demonstrated that the direct methanol fuel cells (DMFCs) using alternative fully aromatic hydrocarbon based PEMs initially outperformed the DMFCs using industrial standard Nafion membranes. Nonetheless, the longer-term performance of the alternative system deteriorated rather faster probably due to the interfacial incompatibility. In this presentation, the effect of interfacial incompatibility of membrane electrode assemblies (MEAs) on long-term DMFC performance is presented in a systematic manner. A series of disulfonated poly(arylene ether) copolymers having different ion exchange capacity and fluorine content was prepared. The effects of chemical structure of the PEMs on interfacial compatibility and long-term performance were investigated and compared with Nation control membraneelectrode assembly.

  13. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOE Patents [OSTI]

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-11-23

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  14. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOE Patents [OSTI]

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-03-02

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  15. Polymer sphere lithography for solid oxide fuel cells: a route to functional, well-defined electrode structures

    E-Print Network [OSTI]

    Polymer sphere lithography for solid oxide fuel cells: a route to functional, well. Introduction Dramatic breakthroughs in the materials, particularly electrode materials, for solid oxide fuel cells (SOFCs) have been reported in recent years.1­3 Fundamental understanding of the electro- catalytic

  16. Supporting electrodes for solid oxide fuel cells and other electrochemical devices

    DOE Patents [OSTI]

    Sprenkle, Vincent L. (Richland, WA); Canfield, Nathan L. (Kennewick, WA); Meinhardt, Kerry (Kennewick, WA); Stevenson, Jeffry W. (Richland, WA)

    2008-04-01

    An electrode supported electrolyte membrane includes an electrode layer 630 facing an electrolyte layer 620. The opposing side of the electrode layer 630 includes a backing layer 640 of a material with a thermal expansion coefficient approximately equal to the thermal expansion coefficient of the electrolyte layer 620. The backing layer 640 is in a two dimensional pattern that covers only a portion of the electrolyte layer 630. An electrochemical cell such as a SOFC is formed by providing a cathode layer 610 on an opposing side of the electrolyte layer 620.

  17. Solid oxide fuel cell with single material for electrodes and interconnect

    DOE Patents [OSTI]

    McPheeters, Charles C. (Naperville, IL); Nelson, Paul A. (Wheaton, IL); Dees, Dennis W. (Downers Grove, IL)

    1994-01-01

    A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

  18. Unveiling Structure-Property Relationships in Sr2Fe1.5Mo0.5O6-, an Electrode Material for Symmetric Solid Oxide Fuel Cells

    E-Print Network [OSTI]

    Carter, Emily A.

    Solid Oxide Fuel Cells Ana B. Munoz-García, Daniel E. Bugaris, Michele Pavone,,§ Jason P. Hodges, Ashfia oxide fuel cells (SOFCs) can convert a wide variety of fuels with simpler and cheaper designs than those oxide fuel cell electrode material Sr2Fe1.5Mo0.5O6- (SFMO). Rietveld refinement of powder neutron

  19. Solid oxide fuel cell with single material for electrodes and interconnect

    DOE Patents [OSTI]

    McPheeters, C.C.; Nelson, P.A.; Dees, D.W.

    1994-07-19

    A solid oxide fuel cell is described having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed there between, and the anode, cathode and interconnect elements are comprised of substantially one material. 9 figs.

  20. Electrode design for low temperature direct-hydrocarbon solid oxide fuel cells

    DOE Patents [OSTI]

    Chen, Fanglin; Zhao, Fei; Liu, Qiang

    2015-10-06

    In certain embodiments of the present disclosure, a solid oxide fuel cell is described. The solid oxide fuel cell includes a hierarchically porous cathode support having an impregnated cobaltite cathode deposited thereon, an electrolyte, and an anode support. The anode support includes hydrocarbon oxidation catalyst deposited thereon, wherein the cathode support, electrolyte, and anode support are joined together and wherein the solid oxide fuel cell operates a temperature of 600.degree. C. or less.

  1. Altering Anode Thickness To Improve Power Production in Microbial Fuel Cells with Different Electrode Distances

    E-Print Network [OSTI]

    Altering Anode Thickness To Improve Power Production in Microbial Fuel Cells with Different ABSTRACT: A better understanding of how anode and separator physical properties affect power production is needed to improve energy and power production by microbial fuel cells (MFCs). Oxygen crossover from

  2. In Situ Synchrotron X-ray Spectroscopy of Lanthanum Manganite Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Yildiz, Bilge

    fuel cells (SOFC) under long term cathodic or anodic polarization, termed `current conditioning. Introduction The solid oxide fuel cell (SOFC) has potential to produce energy with high efficiency, especially when used for combined heat and power generation. SOFC using yttria- stabilized zirconia (YSZ

  3. Electrolytic/fuel cell bundles and systems including a current collector in communication with an electrode thereof

    DOE Patents [OSTI]

    Hawkes, Grant L.; Herring, James S.; Stoots, Carl M.; O'Brien, James E.

    2013-03-05

    Electrolytic/fuel cell bundles and systems including such bundles include an electrically conductive current collector in communication with an anode or a cathode of each of a plurality of cells. A cross-sectional area of the current collector may vary in a direction generally parallel to a general direction of current flow through the current collector. The current collector may include a porous monolithic structure. At least one cell of the plurality of cells may include a current collector that surrounds an outer electrode of the cell and has at least six substantially planar exterior surfaces. The planar surfaces may extend along a length of the cell, and may abut against a substantially planar surface of a current collector of an adjacent cell. Methods for generating electricity and for performing electrolysis include flowing current through a conductive current collector having a varying cross-sectional area.

  4. Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode

    E-Print Network [OSTI]

    Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2006-01-01

    a stable scandia-stabilized zirconia (SSZ) cathode electrodeSSZ (scandia- stabilized zirconia) electrodes proved, forin isopropanol, using zirconia balls as the milling medium.

  5. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    E-Print Network [OSTI]

    Weber, A.Z.

    2008-01-01

    electrolyte-fuel-cell (PEFC) membrane electrode assembly (of a high aspect ratio PEFC with an active area of 2.1 x 7.7be considered in future PEFC modeling. The complicated GDL

  6. Low platinum loading electrospun electrodes for proton exchange membrane fuel cells

    E-Print Network [OSTI]

    Singer, Simcha Lev

    2006-01-01

    An experimental study was performed to evaluate the utility of electrospun carbon nanofiber supports for sputtered platinum catalyst in proton exchange membrane fuel cells. The performance of the sputtered nanofiber supports ...

  7. Reference electrode for electrolytic cell

    DOE Patents [OSTI]

    Kessie, R.W.

    1988-07-28

    A reference electrode device is provided for a high temperature electrolytic cell used to electrolytically recover uranium from spent reactor fuel dissolved in an anode pool, the device having a glass tube to enclose the electrode and electrolyte and serve as a conductive membrane with the cell electrolyte, and an outer metal tube about the glass tube to serve as a shield and basket for any glass sections broken by handling of the tube to prevent their contact with the anode pool, the metal tube having perforations to provide access between the bulk of the cell electrolyte and glass membrane. 4 figs.

  8. Electrolytic cell with reference electrode

    DOE Patents [OSTI]

    Kessie, Robert W. (Naperville, IL)

    1989-01-01

    A reference electrode device is provided for a high temperature electrolytic cell used to electrolytically recover uranium from spent reactor fuel dissolved in an anode pool, the device having a glass tube to enclose the electrode and electrolyte and serve as a conductive membrane with the cell electrolyte, and an outer metal tube about the glass tube to serve as a shield and basket for any glass sections broken by handling of the tube to prevent their contact with the anode pool, the metal tube having perforations to provide access between the bulk of the cell electrolyte and glass membrane.

  9. Effects of electrode compression on the performance of a solid polymer electrolyte fuel cell 

    E-Print Network [OSTI]

    Del Campo, Christopher Scott

    1997-01-01

    cathodic reactants--pure oxygen and air--were tested. Results of these experiments were plotted in a manner to illustrate the effect of electrode compression on PEFC performance. Electrode compression was found to have a significant effect...

  10. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, D.F.; Suciu, D.F.; Harris, T.L.; Ingram, J.C.

    1993-04-06

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  11. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, David F. (Idaho Falls, ID); Suciu, Dan F. (Idaho Falls, ID); Harris, Taryl L. (Idaho Falls, ID); Ingram, Jani C. (Idaho Falls, ID)

    1993-01-01

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  12. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Cell Chemistries and Streamlining Optimization of Electrode Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode 2010 DOE Vehicle Technologies...

  13. PEM/SPE fuel cell

    DOE Patents [OSTI]

    Grot, Stephen Andreas (Henrietta, NY)

    1998-01-01

    A PEM/SPE fuel cell including a membrane-electrode assembly (MEA) having a plurality of oriented filament embedded the face thereof for supporting the MEA and conducting current therefrom to contiguous electrode plates.

  14. PEM/SPE fuel cell

    DOE Patents [OSTI]

    Grot, S.A.

    1998-01-13

    A PEM/SPE fuel cell is described including a membrane-electrode assembly (MEA) having a plurality of oriented filament embedded the face thereof for supporting the MEA and conducting current therefrom to contiguous electrode plates. 4 figs.

  15. Double interconnection fuel cell array

    DOE Patents [OSTI]

    Draper, R.; Zymboly, G.E.

    1993-12-28

    A fuel cell array is made, containing number of tubular, elongated fuel cells which are placed next to each other in rows (A, B, C, D), where each cell contains inner electrodes and outer electrodes, with solid electrolyte between the electrodes, where the electrolyte and outer electrode are discontinuous, having two portions, and providing at least two opposed discontinuities which contain at least two oppositely opposed interconnections contacting the inner electrode, each cell having only three metallic felt electrical connectors which contact surrounding cells, where each row is electrically connected to the other. 5 figures.

  16. Double interconnection fuel cell array

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); Zymboly, Gregory E. (Murrysville, PA)

    1993-01-01

    A fuel cell array (10) is made, containing number of tubular, elongated fuel cells (12) which are placed next to each other in rows (A, B, C, D), where each cell contains inner electrodes (14) and outer electrodes (18 and 18'), with solid electrolyte (16 and 16') between the electrodes, where the electrolyte and outer electrode are discontinuous, having two portions, and providing at least two opposed discontinuities which contain at least two oppositely opposed interconnections (20 and 20') contacting the inner electrode (14), each cell (12) having only three metallic felt electrical connectors (22) which contact surrounding cells, where each row is electrically connected to the other.

  17. Improving Fuel Cell Electrodes Two-Steps at a Time > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeat Pumps Heat Pumpsfacility doe logo CH2M-WGIMPACTResearch

  18. Air Breathing Direct Methanol Fuel Cell

    DOE Patents [OSTI]

    Ren; Xiaoming (Los Alamos, NM)

    2003-07-22

    A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

  19. Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through Electrode

    E-Print Network [OSTI]

    Gall, Daniel

    Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through for proton exchange membrane PEM fuel cells. X-ray diffraction and scanning electron microscopy show manuscript received September 17, 2009. Published November 13, 2009. Proton exchange membrane PEM fuel cells

  20. Temperature-Dependent Simulations of Dry Gas Transport in the Electrodes of Proton Exchange Membrane Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Membrane Fuel Cells M. J. Kermani1 J. M. Stockie2 mkermani@unb.ca stockie@unb.ca 1 Post Doctoral Fellow the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically. The di usion to achieve this goal is via proton exchange mem- brane (PEM) fuel cells, which in principle combine oxygen

  1. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1983-01-01

    This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

  2. Electrode for a lithium cell

    SciTech Connect (OSTI)

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2008-10-14

    This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

  3. Improved photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, T.A.

    1983-06-29

    Improved photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  4. Electrochemical photovoltaic cells and electrodes

    DOE Patents [OSTI]

    Skotheim, Terje A. (East Patchogue, NY)

    1984-01-01

    Improved electrochemical photovoltaic cells and electrodes for use therein, particularly electrodes employing amorphous silicon or polyacetylene coating are produced by a process which includes filling pinholes or porous openings in the coatings by electrochemical oxidation of selected monomers to deposit insulating polymer in the openings.

  5. Deterministic contact mechanics model applied to electrode interfaces in polymer electrolyte fuel cells and interfacial water accumulation

    E-Print Network [OSTI]

    Litster, Shawn

    in polymer electrolyte fuel cells (PEFCs) to elucidate the interfacial morphology. The model employs measured Elsevier B.V. All rights reserved. 1. Introduction Polymer electrolyte fuel cells (PEFC) are promising, mathematical models are valuable tools often used in evaluating multiphase transport phenomena in PEFC

  6. Optimization of the performance of polymer electrolyte fuel cell membrane-electrode assemblies : roles of curing parameters on the catalyst and ionomer structures and morphology.

    SciTech Connect (OSTI)

    Bose, A. B.; Shaik, R.; Mawdsley, J.; Chemical Sciences and Engineering Division; Northern Illinois Univ.

    2008-07-15

    In order to understand the origin of performance variations in polymer electrolyte membrane fuel cells (PEMFCs), a series of membrane-electrode assemblies (MEAs) with identical electrode layer compositions were prepared using different electrode curing conditions, their performances were evaluated, and their morphologies determined by scanning electron microscopy (SEM). The polarization curves varied markedly primarily due to differences in morphologies of electrodes, which were dictated by the curing processes. The highest performing MEAs (1.46 W cm{sup -2} peak power density at 3.2 A cm{sup -2} and 80 C) were prepared using a slow curing process at a lower temperature, whereas those MEAs prepared using a faster curing process performed poorly (0.1948 W cm{sup -2} peak power density at 440 mA cm{sup -2} and 80 C). The slowly cured MEAs showed uniform electrode catalyst and ionomer distributions, as revealed in SEM images and elemental maps. The relatively faster cured materials exhibited uneven distribution of ionomer with significant catalyst clustering. Collectively, these results indicate that to achieve optimal performance, factors that affect the dynamics of the curing process, such as rate of solvent evaporation, must be carefully controlled to avoid solvent trapping, minimize catalyst coagulation, and promote even distribution of ionomer.

  7. Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

    SciTech Connect (OSTI)

    Lee, You-Kee; Kim, Jung-Yeul; Lee, Young-Ki; Kim, Insoo; Moon, Hee-Soo; Park, Jong-Wan; Jacobson, Craig P.; Visco, Steven J.

    2002-12-06

    Composite cathodes of 50/50 vol percent LSM-YSZ (La1-xSrxMnO3-yttria stabilized zirconia) were deposited onto dense YSZ electrolytes by a colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and studied by an impedance spectroscopy (IS). Conditioning effects of the LSM-YSZ cathodes were seen, and remedies for these effects were proposed for improving the performance of a solid oxide fuel cell (SOFC). LSM surface contamination and modification, cathode bonding to the YSZ electrolyte, changing Pt electrode and bonding paste, and curvature of sintered YSZ electrolytes led to some changes in microstructure and variability in cell performances.

  8. Electrochemical impedance study of electrode-membrane assemblies in PEM fuel cells. 1: Electro-oxidation of H{sub 2} and H{sub 2}/CO mixtures on Pt-based gas-diffusion electrodes

    SciTech Connect (OSTI)

    Ciureanu, M.; Wang, H.

    1999-11-01

    In situ EIS data are presented on the anodic process in proton exchange membrane (PEM) fuel cells and the influence of CO poisoning of the Pt gas-diffusion electrodes (GDE) is examined. A characterization of the effects of interfacial kinetics in determining polarization losses in the presence of CO is performed by comparing impedance patterns obtained for cells of the type H{sub 2}/H{sub 2} with H{sub 2}/(H{sub 2} + CO). The impedance spectrum of the poisoned electrode is strongly dependent on potential and on the CO concentration in the gas feed. In the range between 0 and 0.3 V the impedance increases rapidly with the potential, while at potentials higher than 0.3 V a pseudoinductive behavior is observed, in which a positive loop at higher frequencies is accompanied by a low frequency (LF) loop in the fourth quadrant. The latter was assigned to a new rate-determining process, the oxidation of CO{sub ads} by Pt-H{sub 2}O{sub ads}. As a critical potential V{sub crit} is attained, the diameters of the two loops become almost equal and the LF limit of the impedance (R{sub o}) approaches the value for unpoisoned electrode, showing that the activity of the electrode activity has been restored. The value of V{sub crit} is 0.43 and 0.58 V for electrodes poisoned with 100 ppm and 2% CO, respectively. At very high potentials, where the oxidizing species are Pt-OH{sub ads}, the impedance pattern is reserved to the second and third quadrants. Stripping voltammetry and polarization curves recorded in situ, are used to support the conclusions obtained from impedance measurements.

  9. NREL: Hydrogen and Fuel Cells Research - Hydrogen and Fuel Cell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adam Phillips, whose study was on membrane electrode assembly defect detection in PEM fuel cells. Phillips said that Ulsh and Bender helped him acclimate not only to NREL but...

  10. Methods of conditioning direct methanol fuel cells

    DOE Patents [OSTI]

    Rice, Cynthia (Newington, CT); Ren, Xiaoming (Menands, NY); Gottesfeld, Shimshon (Niskayuna, NY)

    2005-11-08

    Methods for conditioning the membrane electrode assembly of a direct methanol fuel cell ("DMFC") are disclosed. In a first method, an electrical current of polarity opposite to that used in a functioning direct methanol fuel cell is passed through the anode surface of the membrane electrode assembly. In a second method, methanol is supplied to an anode surface of the membrane electrode assembly, allowed to cross over the polymer electrolyte membrane of the membrane electrode assembly to a cathode surface of the membrane electrode assembly, and an electrical current of polarity opposite to that in a functioning direct methanol fuel cell is drawn through the membrane electrode assembly, wherein methanol is oxidized at the cathode surface of the membrane electrode assembly while the catalyst on the anode surface is reduced. Surface oxides on the direct methanol fuel cell anode catalyst of the membrane electrode assembly are thereby reduced.

  11. A Damage Model for Degradation in the Electrodes of solid oxide fuel cells: Modeling the effects of sulfur and antimony in the anode

    SciTech Connect (OSTI)

    Ryan, Emily M.; Xu, Wei; Sun, Xin; Khaleel, Mohammad A.

    2012-07-15

    Over their designed lifetime, high temperature electrochemical devices, such as solid oxide fuel cells (SOFCs), can experience degradation in their electrochemical performance due to environmental conditions, operating conditions, contaminants, and other factors. Understanding the different degradation mechanisms in SOFCs and other electrochemical devices is essential to reducing performance degradation and increasing the lifetime of these devices. In this paper SOFC degradation mechanisms are discussed and a damage model is presented which describes performance degradation in SOFCs due to damage or degradation in the electrodes of the SOFC. A degradation classification scheme is presented that divides the various SOFC electrode degradation mechanisms into categories based on their physical effects on the SOFC. The application of the damage model and the classification method is applied to sulfur poisoning and antimony poisoning which occur in the anode of SOFCs. For sulfur poisoning the model is able to predict the degradation in SOFC performance based on the operating temperature and voltage of the fuel cell and the concentration of gaseous sulfur species in the anode. For antimony poisoning the effects of nickel removal from the anode matrix is investigated.

  12. Modeling and High-Resolution-Imaging Studies of Water-Content Profiles in a Polymer-Electrolyte-Fuel-Cell Membrane-Electrode Assembly

    SciTech Connect (OSTI)

    Stevenson, Cynthia; Weber, A.Z.; Hickner, M.A.

    2008-03-06

    Water-content profiles across the membrane electrode assembly of a polymer-electrolyte fuel cell were measured using high-resolution neutron imaging and compared to mathematical-modeling predictions. It was found that the membrane held considerably more water than the other membrane-electrode constituents (catalyst layers, microporous layers, and macroporous gas-diffusion layers) at low temperatures, 40 and 60 C. The water content in the membrane and the assembly decreased drastically at 80 C where vapor transport and a heat-pipe effect began to dominate the water removal from the membrane-electrode assembly. In the regimes where vapor transport was significant, the through-plane water-content profile skewed towards the cathode. Similar trends were observed as the relative humidity of the inlet gases was lowered. This combined experimental and modeling approach has been beneficial in rationalizing the results of each and given insight into future directions for new experimental work and refinements to currently available models.

  13. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, W.H.; Payne, J.R.

    1982-09-14

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB[sub 2], for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints. 9 figs.

  14. Scientists teach short course on fuel cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    covering Hydrogen and Lab Safety, the Laboratory's Membrane-and-Electrode Process, Fuel Cell Materials Characterization, Modeling, Durability and Testing. October 8, 2015...

  15. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Payne, J.R.

    1983-09-20

    The invention is directed to an anode-cathode structure for an electrolytic cell for the reduction of alumina wherein the structure is comprised of a carbon anode assembly which straddles a wedge-shaped refractory hard metal cathode assembly having steeply sloped cathodic surfaces, each cathodic surface being paired in essentially parallel planar relationship with an anode surface. The anode-cathode structure not only takes into account the structural weakness of refractory hard metal materials but also permits the changing of the RHM assembly during operation of the cell. Further, the anode-cathode structure enhances the removal of anode gas from the interpolar gap between the anode and cathode surfaces. 10 figs.

  16. Interconnection of bundled solid oxide fuel cells

    DOE Patents [OSTI]

    Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

    2014-01-14

    A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

  17. Fuel cell current collector

    DOE Patents [OSTI]

    Katz, Murray (Newington, CT); Bonk, Stanley P. (West Willington, CT); Maricle, Donald L. (Glastonbury, CT); Abrams, Martin (Glastonbury, CT)

    1991-01-01

    A fuel cell has a current collector plate (22) located between an electrode (20) and a separate plate (25). The collector plate has a plurality of arches (26, 28) deformed from a single flat plate in a checkerboard pattern. The arches are of sufficient height (30) to provide sufficient reactant flow area. Each arch is formed with sufficient stiffness to accept compressive load and sufficient resiliently to distribute the load and maintain electrical contact.

  18. Micro Fuel Cells Direct Methanol Fuel Cells

    E-Print Network [OSTI]

    Micro Fuel Cells TM Direct Methanol Fuel Cells for Portable Power A Fuel Cell System Developer-17, 2002 Phoenix, Arizona #12;Micro Fuel Cells Direct Methanol Fuel Cells for Portable Power Outline (1 Energy Content (Wh) Volume(cm^3) Li-Ion Battery DMFC #12;Direct Methanol Fuel Cell Technology

  19. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R. (Murrysville, PA)

    1990-01-01

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

  20. Method of electrode fabrication for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, R.R.

    1990-11-20

    A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

  1. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es028lu2011p.pdf More Documents & Publications Screen Electrode...

  2. Characterization and analysis methods for the examination of the heterogeneous solid oxide fuel cell electrode microstructure: Part 2. Quantitative measurement of the microstructure and contributions to transport losses

    SciTech Connect (OSTI)

    Grew, Kyle N.; Peracchio, Aldo A.; Chiu, W. K. S.

    2010-12-15

    Advanced characterization and analysis of multifunctional materials, such as the materials found in heterogeneous solid oxide fuel cell (SOFC) electrode architectures, can help to provide a qualitative and quantitative understanding of how these structures respond to different manufacturing and operating practices. Dense, opaque materials, which have large X-ray mass absorption coefficients and features on sub-micrometer length scales, can make characterization difficult. Advances in tomographic X-ray imaging can permit this level of detailed characterization, and complement stereographic scanning electron microscope measurements that have also been reported. In this second part of a two-part study, details regarding quantitative characterization methods that have been used to examine the SOFC anode microstructure are reported. The detailed formulation and validation of a phase size distributions for the three constitutive phases, as well as resistive loss microstructure-induced resistive loss distributions in the nickel (Ni) and yttria-stabilized zirconia (YSZ) phases are provided in this section.

  3. Minimal RED Cell Pairs Markedly Improve Electrode Kinetics and Power Production in Microbial Reverse Electrodialysis Cells

    E-Print Network [OSTI]

    improved compared to microbial fuel cells (MFCs) by using ammonium bicarbonate (AmB) solutions in multiple electrodes used in a microbial fuel cell (MFC) are placed on each side of a reverse electrodialysis (RED increasing power production (Acetate: 4.2 W/m2 ; WW: 1.9 W/m2 ). By maintaining near optimal electrode power

  4. Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL)

    2012-03-20

    A membrane electrode assembly (MEA) of the invention comprises an anode and a cathode and a proton conductive membrane therebetween, the anode and the cathode each comprising a patterned sheet of longitudinally aligned transition metal-containing carbon nanotubes, wherein the carbon nanotubes are in contact with and are aligned generally perpendicular to the membrane, wherein a catalytically active transition metal is incorporated throughout the nanotubes.

  5. High Temperature Electrolysis using Electrode-Supported Cells

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots

    2010-07-01

    An experimental study is under way to assess the performance of electrode-supported solid-oxide cells operating in the steam electrolysis mode for hydrogen production. The cells currently under study were developed primarily for the fuel cell mode of operation. Results presented in this paper were obtained from single cells, with an active area of 16 cm2 per cell. The electrolysis cells are electrode-supported, with yttria-stabilized zirconia (YSZ) electrolytes (~10 µm thick), nickel-YSZ steam/hydrogen electrodes (~1400 µm thick), and manganite (LSM) air-side electrodes (~90 µm thick). The purpose of the present study was to document and compare the performance and degradation rates of these cells in the fuel cell mode and in the electrolysis mode under various operating conditions. Initial performance was documented through a series of DC potential sweeps and AC impedance spectroscopy measurements. Degradation was determined through long-duration testing, first in the fuel cell mode, then in the electrolysis mode over more than 500 hours of operation. Results indicate accelerated degradation rates in the electrolysis mode compared to the fuel cell mode, possibly due to electrode delamination. The paper also includes details of the single-cell test apparatus developed specifically for these experiments.

  6. Layered electrode for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Swathy (West Bloomfield, MI); Mikhail, Youssef M. (Sterling Heights, MI)

    2001-01-01

    There is provided an electrode structure comprising a current collector sheet and first and second layers of electrode material. Together, the layers improve catalyst utilization and water management.

  7. Minimizing electrode contamination in an electrochemical cell

    DOE Patents [OSTI]

    Kim, Yu Seung; Zelenay, Piotr; Johnston, Christina

    2014-12-09

    An electrochemical cell assembly that is expected to prevent or at least minimize electrode contamination includes one or more getters that trap a component or components leached from a first electrode and prevents or at least minimizes them from contaminating a second electrode.

  8. Electrolyte reservoir for carbonate fuel cells

    DOE Patents [OSTI]

    Iacovangelo, C.D.; Shores, D.A.

    1984-05-23

    An electrode for a carbonate fuel cell and method of making same are described wherein a substantially uniform mixture of an electrode-active powder and porous ceramic particles suitable for a carbonate fuel cell are formed into an electrode with the porous ceramic particles having pores in the range of from about 1 micron to about 3 microns, and a carbonate electrolyte is in the pores of the ceramic particles.

  9. Fuel cell system for transportation applications

    DOE Patents [OSTI]

    Kumar, Romesh (Naperville, IL); Ahmed, Shabbir (Evanston, IL); Krumpelt, Michael (Naperville, IL); Myles, Kevin M. (Downers Grove, IL)

    1993-01-01

    A propulsion system for a vehicle having pairs of front and rear wheels and a fuel tank. An electrically driven motor having an output shaft operatively connected to at least one of said pair of wheels is connected to a fuel cell having a positive electrode and a negative electrode separated by an electrolyte for producing dc power to operate the motor. A partial oxidation reformer is connected both to the fuel tank and to the fuel cell receives hydrogen-containing fuel from the fuel tank and water and air and for partially oxidizing and reforming the fuel with water and air in the presence of an oxidizing catalyst and a reforming catalyst to produce a hydrogen-containing gas. The hydrogen-containing gas is sent from the partial oxidation reformer to the fuel cell negative electrode while air is transported to the fuel cell positive electrode to produce dc power for operating the electric motor.

  10. Fuel cell system for transportation applications

    DOE Patents [OSTI]

    Kumar, R.; Ahmed, S.; Krumpelt, M.; Myles, K.M.

    1993-09-28

    A propulsion system is described for a vehicle having pairs of front and rear wheels and a fuel tank. An electrically driven motor having an output shaft operatively connected to at least one of said pair of wheels is connected to a fuel cell having a positive electrode and a negative electrode separated by an electrolyte for producing dc power to operate the motor. A partial oxidation reformer is connected both to the fuel tank and to the fuel cell and receives hydrogen-containing fuel from the fuel tank and uses water and air for partially oxidizing and reforming the fuel in the presence of an oxidizing catalyst and a reforming catalyst to produce a hydrogen-containing gas. The hydrogen-containing gas is sent from the partial oxidation reformer to the fuel cell negative electrode while air is transported to the fuel cell positive electrode to produce dc power for operating the electric motor. 3 figures.

  11. Molten carbonate fuel cell matrices

    DOE Patents [OSTI]

    Vogel, Wolfgang M. (Glastonbury, CT); Smith, Stanley W. (Vernon, CT)

    1985-04-16

    A molten carbonate fuel cell including a cathode electrode of electrically conducting or semiconducting lanthanum containing material and an electrolyte containing matrix of an electrically insulating lanthanum perovskite. In addition, in an embodiment where the cathode electrode is LaMnO.sub.3, the matrix may include LaAlO.sub.3 or a lithium containing material such as LiAlO.sub.2 or Li.sub.2 TiO.sub.3.

  12. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  13. Negative electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Vaughey, John T.; Fransson, Linda M.; Thackeray, Michael M.

    2005-02-15

    A negative electrode is disclosed for a non-aqueous electrochemical cell. The electrode has an intermetallic compound as its basic structural unit with the formula M.sub.2 M' in which M and M' are selected from two or more metal elements including Si, and the M.sub.2 M' structure is a Cu.sub.2 Sb-type structure. Preferably M is Cu, Mn and/or Li, and M' is Sb. Also disclosed is a non-aqueous electrochemical cell having a negative electrode of the type described, an electrolyte and a positive electrode. A plurality of cells may be arranged to form a battery.

  14. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Reforming for Molten Carbonate Fuel Cells," Berichte derVan Dijkum, "The Molten Carbonate Fuel Cell Programme in thealkaline, molten carbonate, and solid oxide. (Fuel cells

  15. Modeling of solid oxide fuel cells

    E-Print Network [OSTI]

    Lee, Won Yong, S.M. Massachusetts Institute of Technology

    2006-01-01

    A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

  16. Three-Electrode Metal Oxide Reduction Cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Grove, IL); Ackerman, John P. (Downers Grove, IL)

    2005-06-28

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  17. Three-electrode metal oxide reduction cell

    DOE Patents [OSTI]

    Dees, Dennis W. (Downers Groves, IL); Ackerman, John P. (Downers Grove, IL)

    2008-08-12

    A method of electrochemically reducing a metal oxide to the metal in an electrochemical cell is disclosed along with the cell. Each of the anode and cathode operate at their respective maximum reaction rates. An electrolyte and an anode at which oxygen can be evolved, and a cathode including a metal oxide to be reduced are included as is a third electrode with independent power supplies connecting the anode and the third electrode and the cathode and the third electrode.

  18. Tubular solid oxide fuel cell current collector

    DOE Patents [OSTI]

    Bischoff, Brian L. (Knoxville, TN); Sutton, Theodore G. (Kingston, TN); Armstrong, Timothy R. (Clinton, TN)

    2010-07-20

    An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

  19. Method of fabricating electrode catalyst layers with directionally oriented carbon support for proton exchange membrane fuel cell

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Willow brook, IL)

    2010-07-20

    A method of making a membrane electrode assembly (MEA) having an anode and a cathode and a proton conductive membrane there between. A bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated in the nanotubes forms at least one portion of the MEA and is in contact with the membrane. A combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into a first reaction zone maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is transmitted to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes. The nanotubes are in contact with a portion of the MEA at production or being positioned in contact thereafter. Methods of forming a PEMFC are also disclosed.

  20. Ambient pressure fuel cell system

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    2000-01-01

    An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

  1. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)Forthcoming UpgradesArea: PADD 1 to PADDFuelFuelFuel

  2. Composite electrode for use in electrochemical cells

    DOE Patents [OSTI]

    Vanderborgh, N.E.; Huff, J.R.; Leddy, J.

    1987-10-16

    A porous composite electrode for use in electrochemical cells. The electrode has a first face and a second face defining a relatively thin section therebetween. The electrode is comprised of an ion conducting material, an electron conducting material, and an electrocatalyst. The volume concentration of the ion conducting material is greatest at the first face and is decreased across the section, while the volume concentration of the electron conducting material is greatest at the second face and decreases across the section of the electrode. Substantially all of the electrocatalyst is positioned within the electrode section in a relatively narrow zone where the rate of electron transport of the electrode is approximately equal to the rate of ion transport of the electrode. 4 figs., 1 tab.

  3. Characterization and Analysis Methods for the Examination of the Heterogeneous Solid Oxide Fuel Cell Electrode Microstructure, Part 1: Volumetric Measurements of the Heterogeneous Structure

    SciTech Connect (OSTI)

    Grew, Kyle N.; Peracchio, Aldo A.; Joshi, Abhijit S.; Izzo, Jr., John R.; Chiu, W. K. S.

    2010-12-15

    Advanced imaging and characterization methods have permitted the 3-D and phase-specific reconstruction of dense and opaque samples with features that have a length scale on the order of tens of nanometers and comprised of materials with large X-ray mass absorption coefficients. Engineered materials, like those found in solid oxide fuel cell (SOFC) electrodes, use complex materials that have often limited opportunities to perform 3-D characterization and analysis. Still, characterization and analysis methods are needed to better understand these structures and their functional impact. The development, verification, and validation of methods used by the authors for the characterization and analysis of the heterogeneous SOFC anode are discussed in this work. These methods include the measurement of the volume fractions of the individual phases, contiguity or volumetric connectivity, tortuosity, and interfacial properties. A second and complementary part of this work will examine quantitative methods that provide detailed descriptions of the structure and its relations to the transport processes that it must support. These efforts are intended to describe the formulation of methods developed to provide insight into the SOFC anode nano/microstructure.

  4. (Fuel Cells)(Fuel Cells) William Grove

    E-Print Network [OSTI]

    Chen, Yang-Yuan

    Fuel Cell #12; H2 O2 Power CH4 H2 Toyota H2 H2 #12; H2 ~253 #12; 2. 3. : 1. #12; #12;Fuel Cell #12; (Fuel Cells)(Fuel Cells) 1839 William Grove A H2O2 H2O2 2H; Fuel Cell #12;!! PEMFC DMFC SOFC (60~200) (60~100) (600~1000) #12; Proton

  5. fuel cells

    National Nuclear Security Administration (NNSA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal GasAdministration Medal01 Sandia4)9 Federal RegisterStorm1 3446 YEAR/%2Afissile4/%2A en

  6. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell...

  7. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    OH- ions, and molten carbonate fuel cells, which conduct COfuel cells and electrode corrosion by the molten carbonate

  8. Fuel cell system with separating structure bonded to electrolyte

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

    2010-09-28

    A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

  9. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  10. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-08-17

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  11. Micro-electro-mechanical systems phosphoric acid fuel cell

    DOE Patents [OSTI]

    Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

    2010-12-21

    A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

  12. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Alonso-Vante, Nicolas (Buxerolles, FR); Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

    2009-09-15

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  13. Chalcogen catalysts for polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Alonso-Vante, Nicolas (France, FR); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

    2010-08-24

    A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

  14. Ceramic Fuel Cells (SOFC)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Engineering Argonne National Laboratory Thursday, August 11, 2011 Ceramic Fuel Cells (SOFC) Manufacturing Fuel Cell Manhattan Project: * Joe Bonadies - Delphi * Rick...

  15. Interfacial material for solid oxide fuel cell

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    1999-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  16. DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's Fuel Cell Technologies Office...

  17. Center for Fuel Cells I/UCRC Membership Agreement

    E-Print Network [OSTI]

    Almor, Amit

    Center for Fuel Cells I/UCRC Membership Agreement This agreement is made this _____ day of Proton Exchange Membrane Fuel Cells (PEMFCs) by performing research in (1) fuel cell design; (2) fuel for hydrogen production and the fuel cell electrodes; and (5) motor design and power conditioning

  18. POLYMER ELECTROLYTE FUEL CELLS

    E-Print Network [OSTI]

    Petta, Jason

    POLYMER ELECTROLYTE FUEL CELLS: The Gas Diffusion Layer Johannah Itescu Princeton University PRISM REU #12;PEM FUEL CELLS: A little background information I. What do fuel cells do? Generate electricity through chemical reaction #12;PEM FUEL CELLS: A little background information -+ + eHH 442 2 0244 22 He

  19. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Experience with the German Hydrogen Fuel Project," HydrogenHydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would be

  20. Layered electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Johnson, Christopher S. (Naperville, IL); Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Kahaian, Arthur J. (Chicago, IL); Kim, Jeom-Soo (Naperville, IL)

    2008-04-15

    Lithium metal oxide compounds of nominal formula Li.sub.2MO.sub.2, in which M represents two or more positively charged metal ions, selected predominantly and preferably from the first row of transition metals are disclosed herein. The Li.sub.2MO.sub.2 compounds have a layered-type structure, which can be used as positive electrodes for lithium electrochemical cells, or as a precursor for the in-situ electrochemical fabrication of LiMO.sub.2 electrodes. The Li.sub.2MO.sub.2 compounds of the invention may have additional functions in lithium cells, for example, as end-of-discharge indicators, or as negative electrodes for lithium cells.

  1. Dr. Piotr Zelenay's Professional Bio Dr. Zelenay's expertise is in polymer electrolyte fuel cells, electrocatalysis, surface

    E-Print Network [OSTI]

    of polymer electrolyte fuel cell science and technology, electrocatalysis, and electrode kinetics. PiotrDr. Piotr Zelenay's Professional Bio Dr. Zelenay's expertise is in polymer electrolyte fuel cells

  2. Open end protection for solid oxide fuel cells

    DOE Patents [OSTI]

    Zafred, Paolo R. (Murrysville, PA); Dederer, Jeffrey T. (Valencia, PA); Tomlins, Gregory W. (Pittsburgh, PA); Toms, James M. (Irwin, PA); Folser, George R. (Lower Burrell, PA); Schmidt, Douglas S. (Pittsburgh, PA); Singh, Prabhakar (Export, PA); Hager, Charles A. (Zelienople, PA)

    2001-01-01

    A solid oxide fuel cell (40) having a closed end (44) and an open end (42) operates in a fuel cell generator (10) where the fuel cell open end (42) of each fuel cell contains a sleeve (60, 64) fitted over the open end (42), where the sleeve (60, 64) extends beyond the open end (42) of the fuel cell (40) to prevent degradation of the interior air electrode of the fuel cell by fuel gas during operation of the generator (10).

  3. Method of making straight fuel cell tubes

    DOE Patents [OSTI]

    Borglum, Brian P. (Edgewood, PA)

    2001-01-01

    A method and an apparatus for making straight fuel cell tubes are disclosed. Extruded tubes comprising powders of fuel cell material and a solvent are dried by rotating the extruded tubes. The rotation process provides uniform circumferential drying which results in uniform linear shrinkage of the tubes. The resultant dried tubes are very straight, thereby eliminating subsequent straightening steps required with conventional processes. The method is particularly useful for forming inner air electrode tubes of solid oxide fuel cells.

  4. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

    1980-07-30

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  5. Ternary compound electrode for lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Godshall, Ned A. (Stanford, CA); Huggins, Robert A. (Stanford, CA)

    1982-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

  6. Cells containing solvated electron lithium negative electrodes

    SciTech Connect (OSTI)

    Uribe, F.A.; Semkow, K.W.; Sammells, A.F. (Eltron Research, Incorporated, Aurora, IL (US))

    1989-12-01

    Preliminary work performed on a novel solvated electron lithium negative electrode which may have application in either high energy density secondary or reserve battery systems is discussed. The lithium electrode investigated consisted of lithium initially dissolved in liquid ammonia to give a solvated electron solution. Containment of this liquid negative active material from direct contact with a liquid nonaqueous electrolyte present in the cell positive electrode compartment was addressed via the use of a lithium intercalated electronically conducting ceramic membrane of the general composition Li{sub x}WO{sub 2}(0.1{lt}x{lt} 1.0). Secondary electrochemical cells having the general configuration Li,NH{sub 3}/Li{sub x}WO{sub 2}NAE/TiS{sub 2} using nonaqueous electrolytes (NAE) based upon both propylene carbonate and 2Me-THF. Depending upon initial lithium activity in the negative electrode compartments the cell possessed an initial open-circuit potential (OCP 3.44V). Both cells, which were operated at ambient pressure (low temperature) and ambient temperature (high pressure) showed evidence for electrochemical reversibility.

  7. Validation of Electrode Materials and Cell Chemistries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. Development of alkaline fuel cells.

    SciTech Connect (OSTI)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  9. Proceedings of the Lucerne Fuel Cell Forum 2006 European Solid Oxide Fuel Cell Forum, 3-7 July 2006

    E-Print Network [OSTI]

    Yildiz, Bilge

    Uncertainties in our understanding of the oxygen reduction mechanism (ORR) at solid oxide fuel cell (SOFCProceedings of the Lucerne Fuel Cell Forum 2006 7th European Solid Oxide Fuel Cell Forum, 3-7 July studies have shown that cathodic or anodic dc polarization of the solid oxide fuel cell oxygen electrodes

  10. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuel CellsCells Fuel

  11. Webinar: Fuel Cell Buses

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Fuel Cell Buses, originally presented on September 12, 2013.

  12. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    California, June (1986). General Electric, Direct Energy Conversion Programs, Feasibility Study ofSPE Fuel Cell Power Plants

  13. Preventing CO poisoning in fuel cells

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM)

    1990-01-01

    Proton exchange membrane (PEM) fuel cell performance with CO contamination of the H.sub.2 fuel stream is substantially improved by injecting O.sub.2 into the fuel stream ahead of the fuel cell. It is found that a surface reaction occurs even at PEM operating temperatures below about 100.degree. C. to oxidatively remove the CO and restore electrode surface area for the H.sub.2 reaction to generate current. Using an O.sub.2 injection, a suitable fuel stream for a PEM fuel cell can be formed from a methanol source using conventional reforming processes for producing H.sub.2.

  14. High power density fuel cell comprising an array of microchannels

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Upadhye, Ravindra S.; Spadaccini, Christopher M.; Park, Hyung Gyu

    2013-10-15

    A fuel cell according to one embodiment includes a porous electrolyte support structure defining an array of microchannels, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and oxidant electrodes formed along other of the microchannels. A method of making a fuel cell according to one embodiment includes forming an array of walls defining microchannels therebetween using at least one of molding, stamping, extrusion, injection and electrodeposition; processing the walls to make the walls porous, thereby creating a porous electrolyte support structure; forming anode electrodes along some of the microchannels; and forming cathode electrodes along other of the microchannels. Additional embodiments are also disclosed.

  15. Fuel cells and fuel cell catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Rice, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2006-11-07

    A direct organic fuel cell includes a formic acid fuel solution having between about 10% and about 95% formic acid. The formic acid is oxidized at an anode. The anode may include a Pt/Pd catalyst that promotes the direct oxidation of the formic acid via a direct reaction path that does not include formation of a CO intermediate.

  16. Fuel cells: A handbook (Revision 3)

    SciTech Connect (OSTI)

    Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

    1994-01-01

    Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

  17. Micro fuel cell

    SciTech Connect (OSTI)

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  18. DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...

    Broader source: Energy.gov (indexed) [DOE]

    the cost of automotive polymer electrolyte membrane (PEM) fuel cell systems. DOE Hydrogen and Fuel Cells Program Record 14012 More Documents & Publications DOE Fuel Cell...

  19. Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...

    Broader source: Energy.gov (indexed) [DOE]

    2010 Fuel Cell Seminar and Exposition on October 19, 2010. Hydrogen and Fuel Cell Technologies Update More Documents & Publications DOE Hydrogen and Fuel Cell Overview: 2011...

  20. Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Pete Devlin Fuel Cell Technologies Program United States Department of Energy Federal Utility Partnership...

  1. Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems Presented...

  2. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Smith, James L. (Lemont, IL)

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  3. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  4. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  5. Fuel Cells at NASCAR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen h yFuel Cells

  6. Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells

    E-Print Network [OSTI]

    2002-01-01

    x MnO 3 -Yttria Stabilized Zirconia Electrodes for Thin-FilmMnO 3 -yttria stabilized zirconia) were deposited onto dense1.5 h in acetone, using zirconia milling media. The LSM- YSZ

  7. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuel Cell

  8. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuel CellStates

  9. FUEL CELLS FOR TRANSPORTATION

    E-Print Network [OSTI]

    for Fuel Cells for Transportation Energy Efficiency and Renewable Energy Office of Transportation............................................................................................. 101 A. R&D of a 50-kW, High-Efficiency, High-Power-Density, CO-Tolerant PEM Fuel Cell Stack SystemFUEL CELLS FOR TRANSPORTATION 2 0 0 1 A N N U A L P R O G R E S S R E P O R T U.S. Department

  10. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  11. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    Membrane Fuel Cells and Electrolyzers," Journal of PowerAdvanced Alkaline Electrolyzer for Solar Operation,"requirements are for electrolyzer feedwater. T h e high-

  12. Opportunities with Fuel Cells

    Reports and Publications (EIA)

    1994-01-01

    The concept for fuel cells was discovered in the nineteenth century. Today, units incorporating this technology are becoming commercially available for cogeneration applications.

  13. Fuel Cell Technologies Budget

    SciTech Connect (OSTI)

    EERE

    2012-03-16

    The Fuel Cell Technologies Office receives appropriations from Energy and Water Development. The offices's major activities and budget are outlined in this Web page.

  14. Microcomposite Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Summary of microcomposite fuel cell membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  15. Webinar: Fuel Cell Mobile Lighting

    Broader source: Energy.gov [DOE]

    Video recording of the Fuel Cell Technologies Office webinar, Fuel Cell Mobile Lighting, originally presented on November 13, 2012.

  16. Fuel Cells in Telecommunications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen hfor|Fuel

  17. Fuel Cell Projects Kickoff Meeting September 30th

    E-Print Network [OSTI]

    Fuel Cells Ken Chen, SNL 5:10 Air-Cooled Stack Freeze Tolerance Mike Parsons, Plug Power 5:30 TransportFuel Cell Projects Kickoff Meeting Agenda September 30th , 2009 1:00 Opening Remarks Henry Kelly 1-scale, Three-dimensional Non-Platinum Group Metal Electrodes for Catalysis of Fuel Cell Reactions John Kerr

  18. Pt/Pd electrocatalyst electrons for fuel cells

    DOE Patents [OSTI]

    Stonehart, P.

    1981-11-03

    This invention relates to improved electrochemical cells and to novel electrodes for use therein. In particular, the present invention comprises a fuel cell used primarily for the consumption of impure hydrogen fuels containing carbon monoxide or carbonaceous fuels where the electrode in contact with the fuel is not substantially poisoned by carbon monoxide. The anode of the fuel cell comprises a Pd/Pt alloy supported on a graphitized or partially graphitized carbon material. Fuel cells which comprise as essential elements a fuel electrode, an oxidizing electrode, and an electrolyte between said electrodes are devices for the direct production of electricity through the electrochemical combustion of a fuel and oxidant. These devices are recognized for their high efficiency as energy conversion units, since unlike conventional combustion engines, they are not subject to the limitations of the Carnot heat cycle. It is the primary object of the present invention to provide an electrode having high electrochemical activity for an electrochemical cell. It is another object of the present invention to provide an electrode having an electro-catalyst which is highly resistant to the corrosive environment of an electrochemical cell.

  19. Corrugated Membrane Fuel Cell Structures

    SciTech Connect (OSTI)

    Grot, Stephen President, Ion Power Inc.

    2013-09-30

    One of the most challenging aspects of traditional PEM fuel cell stacks is the difficulty achieving the platinum catalyst utilization target of 0.2 gPt/kWe set forth by the DOE. Good catalyst utilization can be achieved with state-of-the-art catalyst coated membranes (CCM) when low catalyst loadings (<0.3 mg/cm2) are used at a low current. However, when low platinum loadings are used, the peak power density is lower than conventional loadings, requiring a larger total active area and a larger bipolar plate. This results in a lower overall stack power density not meeting the DOE target. By corrugating the fuel cell membrane electrode structure, Ion Power?s goal is to realize both the Pt utilization targets as well as the power density targets of the DOE. This will be achieved by demonstrating a fuel cell single cell (50 cm2) with a twofold increase in the membrane active area over the geometric area of the cell by corrugating the MEA structure. The corrugating structure must be able to demonstrate the target properties of < 10 mOhm-cm2 electrical resistance at > 20 psi compressive strength over the active area, in combination with offering at least 80% of power density that can be achieved by using the same MEA in a flat plate structure. Corrugated membrane fuel cell structures also have the potential to meet DOE power density targets by essentially packaging more membrane area into the same fuel cell volume as compared to conventional stack constructions.

  20. Tubular screen electrical connection support for solid oxide fuel cells

    DOE Patents [OSTI]

    Tomlins, Gregory W. (Pittsburgh, PA); Jaszcar, Michael P. (Murrysville, PA)

    2002-01-01

    A solid oxide fuel assembly is made of fuel cells (16, 16', 18, 24, 24', 26), each having an outer interconnection layer (36) and an outer electrode (28), which are disposed next to each other with rolled, porous, hollow, electrically conducting metal mesh conductors (20, 20') between the fuel cells, connecting the fuel cells at least in series along columns (15, 15') and where there are no metal felt connections between any fuel cells.

  1. Fuel Cells Go Live

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen h y d r o g e

  2. Oxide modified air electrode surface for high temperature electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); Ruka, Roswell J. (Churchill Boro, Allegheny County, PA)

    1992-01-01

    An electrochemical cell is made having a porous cermet electrode (16) and a porous lanthanum manganite electrode (14), with solid oxide electrolyte (15) between them, where the lanthanum manganite surface next to the electrolyte contains a thin discontinuous layer of high surface area cerium oxide and/or praseodymium oxide, preferably as discrete particles (30) in contact with the air electrode and electrolyte.

  3. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

  4. Li-alloy electrode for Li-alloy/metal sulfide cells

    DOE Patents [OSTI]

    Kaun, Thomas D. (320 Willow St., New Lenox, IL 60451)

    1996-01-01

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Lithium, silicon and nickel is alloyed in a prescribed proportion forming an electroactive material, to provide an improved electrode and cell.

  5. Fuel cell water transport

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Hedstrom, James C. (Los Alamos, NM)

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  6. Miniature ceramic fuel cell

    DOE Patents [OSTI]

    Lessing, Paul A. (Idaho Falls, ID); Zuppero, Anthony C. (Idaho Falls, ID)

    1997-06-24

    A miniature power source assembly capable of providing portable electricity is provided. A preferred embodiment of the power source assembly employing a fuel tank, fuel pump and control, air pump, heat management system, power chamber, power conditioning and power storage. The power chamber utilizes a ceramic fuel cell to produce the electricity. Incoming hydro carbon fuel is automatically reformed within the power chamber. Electrochemical combustion of hydrogen then produces electricity.

  7. Air Liquide - Biogas & Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    and the environment PT Loma WWTP, Biogas to Fuel Cell Power BioFuels Energy Biogas to BioMethane to 4.5 MW Fuel Cell Power 3 FCE Fuel Cells 2 via directed...

  8. Fuel cell stack with passive air supply

    DOE Patents [OSTI]

    Ren, Xiaoming; Gottesfeld, Shimshon

    2006-01-17

    A fuel cell stack has a plurality of polymer electrolyte fuel cells (PEFCs) where each PEFC includes a rectangular membrane electrode assembly (MEA) having a fuel flow field along a first axis and an air flow field along a second axis perpendicular to the first axis, where the fuel flow field is long relative to the air flow field. A cathode air flow field in each PEFC has air flow channels for air flow parallel to the second axis and that directly open to atmospheric air for air diffusion within the channels into contact with the MEA.

  9. Fuel cell stack arrangements

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Boro, PA); Somers, Edward V. (Murrysville, PA)

    1982-01-01

    Arrangements of stacks of fuel cells and ducts, for fuel cells operating with separate fuel, oxidant and coolant streams. An even number of stacks are arranged generally end-to-end in a loop. Ducts located at the juncture of consecutive stacks of the loop feed oxidant or fuel to or from the two consecutive stacks, each individual duct communicating with two stacks. A coolant fluid flows from outside the loop, into and through cooling channels of the stack, and is discharged into an enclosure duct formed within the loop by the stacks and seals at the junctures at the stacks.

  10. Reforming of fuel inside fuel cell generator

    DOE Patents [OSTI]

    Grimble, Ralph E. (Finleyville, PA)

    1988-01-01

    Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

  11. Hydrogen Fuel Cell Demonstration ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  12. Method of making chalcogen catalysts for polymer electrolyte fuel cells

    DOE Patents [OSTI]

    Choi, Jong-Ho (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Harabin, CN)

    2010-12-14

    A method of making an electrode catalyst material using aqueous solutions. The electrode catalyst material includes a support comprising at least one transition metal and at least one chalcogen disposed on a surface of the transition metal. The method includes reducing a metal powder, mixing the metal powder with an aqueous solution containing at least one inorganic compound of the chalcogen to form a mixture, and providing a reducing agent to the mixture to form nanoparticles of the electrode catalyst. The electrode catalyst may be used in a membrane electrode assembly for a fuel cell.

  13. Compliant fuel cell system

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY)

    2009-12-15

    A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

  14. Wick-and-pool electrodes for electrochemical cell

    DOE Patents [OSTI]

    Roche, Michael F. (Downers Grove, IL); Faist, Suzan M. (Haddonfield, NJ); Eberhart, James G. (Naperville, IL); Ross, Laurids E. (Naperville, IL)

    1980-01-01

    An electrode system includes a reservoir of liquid-metal reactant, and a wick extending from a submersed location within the reservoir into the molten electrolyte of an electrochemical cell structure. The wick is flooded with the liquid metal and thereby serves as one electrode within the cell. This electrode system has application in high-temperature batteries employing molten alkali metals or their alloys as active material within an electrode submersed within a molten salt electrolyte. It also can be used in electrochemical cells where the purification, separation or electrowinning of liquid metals is accomplished.

  15. Electrocatalysts for Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES Science NetworkMediatorElectrocatalysts for Fuel Cells June

  16. Inactive end cell assembly for fuel cells for improved electrolyte management and electrical contact

    DOE Patents [OSTI]

    Yuh, Chao-Yi (New Milford, CT); Farooque, Mohammad (Danbury, CT); Johnsen, Richard (New Fairfield, CT)

    2007-04-10

    An assembly for storing electrolyte in a carbonate fuel cell is provided. The combination of a soft, compliant and resilient cathode current collector and an inactive anode part including a foam anode in each assembly mitigates electrical contact loss during operation of the fuel cell stack. In addition, an electrode reservoir in the positive end assembly and an electrode sink in the negative end assembly are provided, by which ribbed and flat cathode members inhibit electrolyte migration in the fuel cell stack.

  17. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  18. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  19. Performance Assessment of Single Electrode-Supported Solid Oxide Cells Operating in the Steam Electrolysis Mode

    SciTech Connect (OSTI)

    X. Zhang; J. E. O'Brien; R. C. O'Brien; N. Petigny

    2011-11-01

    An experimental study is under way to assess the performance of electrode-supported solid-oxide cells operating in the steam electrolysis mode for hydrogen production. Results presented in this paper were obtained from single cells, with an active area of 16 cm{sup 2} per cell. The electrolysis cells are electrode-supported, with yttria-stabilized zirconia (YSZ) electrolytes ({approx}10 {mu}m thick), nickel-YSZ steam/hydrogen electrodes ({approx}1400 {mu}m thick), and modified LSM or LSCF air-side electrodes ({approx}90 {mu}m thick). The purpose of the present study is to document and compare the performance and degradation rates of these cells in the fuel cell mode and in the electrolysis mode under various operating conditions. Initial performance was documented through a series of voltage-current (VI) sweeps and AC impedance spectroscopy measurements. Degradation was determined through long-term testing, first in the fuel cell mode, then in the electrolysis mode. Results generally indicate accelerated degradation rates in the electrolysis mode compared to the fuel cell mode, possibly due to electrode delamination. The paper also includes details of an improved single-cell test apparatus developed specifically for these experiments.

  20. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    freezing and about a hundred freeze-thaw cycles, there is no change in fuel cellfuel cell is operating, it generates more than enough heat to prevent water and moisture from freezingfuel cell system, because in the present design the flow fields and manifolds would be damaged by the freezing-

  1. Carbon nanotube-coated macroporous sponge for microbial fuel cell Liangbing Hu,b

    E-Print Network [OSTI]

    Cui, Yi

    Carbon nanotube-coated macroporous sponge for microbial fuel cell electrodes Xing Xie,a Meng Ye to make electrodes and their internal structures significantly affect microbial fuel cell (MFC matter can also drive electron flow. Microbial fuel cells (MFCs) that exploit this understanding have

  2. In-situ measurement of ethanol tolerance in an operating fuel cell

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    In-situ measurement of ethanol tolerance in an operating fuel cell Matt S. Naughton a , Claire E online xxx Keywords: Alkaline fuel cell Gas diffusion electrodes Ag cathode Electrode characterization for direct ethanol fuel cells and as a source for on-demand production of hydrogen in portable applications

  3. Air breathing direct methanol fuel cell

    DOE Patents [OSTI]

    Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

    2002-01-01

    An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Water loss from the cell is minimized by making the conductive cathode assembly hydrophobic and the conductive anode assembly hydrophilic.

  4. Fuel cell with electrolyte matrix assembly

    DOE Patents [OSTI]

    Kaufman, Arthur (West Orange, NJ); Pudick, Sheldon (Sayreville, NJ); Wang, Chiu L. (Edison, NJ)

    1988-01-01

    This invention is directed to a fuel cell employing a substantially immobilized electrolyte imbedded therein and having a laminated matrix assembly disposed between the electrodes of the cell for holding and distributing the electrolyte. The matrix assembly comprises a non-conducting fibrous material such as silicon carbide whiskers having a relatively large void-fraction and a layer of material having a relatively small void-fraction.

  5. Layered method of electrode for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Jensen, Russell R. (Murrysville, PA)

    1991-07-30

    A process for fabricating a fuel electrode comprising: slurry dipping to form layers which are structurally graded from all or mostly all stabilized zirconia at a first layer, to an outer most layer of substantially all metal powder, such an nickel. Higher performaance fuel electrodes may be achieved if sinter active stabilized zirconia doped for electronic conductivity is used.

  6. Fuel cell system

    DOE Patents [OSTI]

    Early, Jack (Perth Amboy, NJ); Kaufman, Arthur (West Orange, NJ); Stawsky, Alfred (Teaneck, NJ)

    1982-01-01

    A fuel cell system is comprised of a fuel cell module including sub-stacks of series-connected fuel cells, the sub-stacks being held together in a stacked arrangement with cold plates of a cooling means located between the sub-stacks to function as electrical terminals. The anode and cathode terminals of the sub-stacks are connected in parallel by means of the coolant manifolds which electrically connect selected cold plates. The system may comprise a plurality of the fuel cell modules connected in series. The sub-stacks are designed to provide a voltage output equivalent to the desired voltage demand of a low voltage, high current DC load such as an electrolytic cell to be driven by the fuel cell system. This arrangement in conjunction with switching means can be used to drive a DC electrical load with a total voltage output selected to match that of the load being driven. This arrangement eliminates the need for expensive voltage regulation equipment.

  7. Formic acid fuel cells and catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Larsen, Robert; Ha, Su Yun

    2010-06-22

    An exemplary fuel cell of the invention includes a formic acid fuel solution in communication with an anode (12, 134), an oxidizer in communication with a cathode (16, 135) electrically linked to the anode, and an anode catalyst that includes Pd. An exemplary formic acid fuel cell membrane electrode assembly (130) includes a proton-conducting membrane (131) having opposing first (132) and second surfaces (133), a cathode catalyst on the second membrane surface, and an anode catalyst including Pd on the first surface.

  8. Fuel Cells as an Emerging Technology 

    E-Print Network [OSTI]

    Jewell, D. M.

    1986-01-01

    electrodes. SOFC Status Very high temperature (l,OOOOC) solid oxide fuel cells might offer greater sulfur tolerance, more systems design options, and cost advantages by not requiring expensive noble metal catalysts. The solid oxide cell offers... stream_source_info ESL-IE-86-06-100.pdf.txt stream_content_type text/plain stream_size 21359 Content-Encoding ISO-8859-1 stream_name ESL-IE-86-06-100.pdf.txt Content-Type text/plain; charset=ISO-8859-1 FUEL CELLS...

  9. Fuel cell membranes and crossover prevention

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); York, Cynthia A. (Newington, CT); Waszczuk, Piotr (White Bear Lake, MN); Wieckowski, Andrzej (Champaign, IL)

    2009-08-04

    A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

  10. Power from the Fuel Cell

    E-Print Network [OSTI]

    Lipman, Timothy E.

    2000-01-01

    Power for Buildings Using Fuel-Cell Cars,” Proceedings ofwell as to drive down fuel-cell system costs through productPower from the Fuel Cell BY TIMOTHY E. LIPMAN A U T O M O B

  11. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    t t 1 | Fuel Cell Technologies Program eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U S D f E Overview U.S....

  12. Electrolyte paste for molten carbonate fuel cells

    DOE Patents [OSTI]

    Bregoli, Lawrance J. (Southwick, MA); Pearson, Mark L. (New London, CT)

    1995-01-01

    The electrolyte matrix and electrolyte reservoir plates in a molten carbonate fuel cell power plant stack are filled with electrolyte by applying a paste of dry electrolyte powder entrained in a dissipatable carrier to the reactant flow channels in the current collector plate. The stack plates are preformed and solidified to final operating condition so that they are self sustaining and can be disposed one atop the other to form the power plant stack. Packing the reactant flow channels with the electrolyte paste allows the use of thinner electrode plates, particularly on the anode side of the cells. The use of the packed electrolyte paste provides sufficient electrolyte to fill the matrix and to entrain excess electrolyte in the electrode plates, which also serve as excess electrolyte reservoirs. When the stack is heated up to operating temperatures, the electrolyte in the paste melts, the carrier vaporizes, or chemically decomposes, and the melted electrolyte is absorbed into the matrix and electrode plates.

  13. Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities Mr. Pete Devlin U.S. Department of Energy Fuel Cell Technologies Program Market Transformation Manager Stationary Fuel Cell Applications First National Bank of Omaha...

  14. Webinar: Fuel Cells at NASCAR

    Broader source: Energy.gov [DOE]

    Video recording and text version of the Fuel Cell Technologies Office webinar "Fuel Cells at NASCAR," originally presented on April 17, 2014.

  15. Solid oxide fuel cell operable over wide temperature range

    DOE Patents [OSTI]

    Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

    2001-01-01

    Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

  16. Fuel cell tubes and method of making same

    DOE Patents [OSTI]

    Borglum, Brian P. (Edgewood, PA)

    1999-11-30

    A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost. A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost.

  17. Fuel cell system combustor

    DOE Patents [OSTI]

    Pettit, William Henry (Rochester, NY)

    2001-01-01

    A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode and cathode effluents. The combustor includes a turbulator section at its input end for intimately mixing the anode and cathode effluents before they contact the combustors primary catalyst bed. The turbulator comprises at least one porous bed of mixing media that provides a tortuous path therethrough for creating turbulent flow and intimate mixing of the anode and cathode effluents therein.

  18. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, Eddie C. (Park Forest, IL); Miller, William E. (Naperville, IL); Laidler, James J. (Burr Ridge, IL)

    1997-01-01

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two.

  19. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, E.C.; Miller, W.E.; Laidler, J.J.

    1997-07-22

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two. 12 figs.

  20. Development of Industrially Viable Battery Electrode Coatings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Industrially Viable Battery Electrode Coatings Development of Industrially Viable Battery Electrode Coatings 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  1. Compact fuel cell

    DOE Patents [OSTI]

    Jacobson, Craig (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA); Lu, Chun (Richland, WA)

    2010-10-19

    A novel electrochemical cell which may be a solid oxide fuel cell (SOFC) is disclosed where the cathodes (144, 140) may be exposed to the air and open to the ambient atmosphere without further housing. Current collector (145) extends through a first cathode on one side of a unit and over the unit through the cathode on the other side of the unit and is in electrical contact via lead (146) with housing unit (122 and 124). Electrical insulator (170) prevents electrical contact between two units. Fuel inlet manifold (134) allows fuel to communicate with internal space (138) between the anodes (154 and 156). Electrically insulating members (164 and 166) prevent the current collector from being in electrical contact with the anode.

  2. California Fuel Cell Partnership: Alternative Fuels Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    research. cafcpinitiativescall.pdf More Documents & Publications The Department of Energy Hydrogen and Fuel Cells Program Plan Vehicle Technologies Office Merit Review 2015:...

  3. Breakthrough Vehicle Development - Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing research and development program for fuel cell power systems for transportation applications.

  4. National Fuel Cell Research Center

    E-Print Network [OSTI]

    Mease, Kenneth D.

    the optimal conditions to operate a molten carbonate fuel cell, can be used to garner fundamental insightNational Fuel Cell Research Center www.nfcrc.uci.edu MOLTEN CARBONATE FUEL CELLS STEADY STATE MODELING OF MOLTEN CARBONATE FUEL CELLS FOR SYSTEM PERFORMANCE ANALYSES OVERVIEW Development of steady

  5. Hydrogen & Fuel Cells -Program Overview -

    E-Print Network [OSTI]

    Analysis Fuel Cells Solid oxide fuel cell (kW-scale) R&D led to 75% weight reduction and >80% volume,000 35,000 2008 2009 2010 2011 2012P (SystemsShipped) Fuel Cell Systems Shipped by Application, World Research Market Growth Fuel cell markets continue to grow 48% increase in global MWs shipped 62% increase

  6. Seventh Edition Fuel Cell Handbook

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

  7. Fuel dissipater for pressurized fuel cell generators

    DOE Patents [OSTI]

    Basel, Richard A.; King, John E.

    2003-11-04

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a pressurized fuel cell generator (10) when the electrical power output of the fuel cell generator is terminated during transient operation, such as a shutdown; where, two electrically resistive elements (two of 28, 53, 54, 55) at least one of which is connected in parallel, in association with contactors (26, 57, 58, 59), a multi-point settable sensor relay (23) and a circuit breaker (24), are automatically connected across the fuel cell generator terminals (21, 22) at two or more contact points, in order to draw current, thereby depleting the fuel inventory in the generator.

  8. Fuel cell generator energy dissipator

    DOE Patents [OSTI]

    Veyo, Stephen Emery (Murrysville, PA); Dederer, Jeffrey Todd (Valencia, PA); Gordon, John Thomas (Ambridge, PA); Shockling, Larry Anthony (Pittsburgh, PA)

    2000-01-01

    An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a fuel cell generator when the electrical power output of the fuel cell generator is terminated. During a generator shut down condition, electrically resistive elements are automatically connected across the fuel cell generator terminals in order to draw current, thereby depleting the fuel

  9. Solid polymer MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Pleasant Hill, CA)

    2008-04-22

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  10. Solid oxide MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  11. Sustainable Power Generation in Microbial Fuel Cells Using

    E-Print Network [OSTI]

    Tullos, Desiree

    Sustainable Power Generation in Microbial Fuel Cells Using Bicarbonate Buffer and Proton Transfer applications, especially for wastewater treatment. Introduction Microbial fuel cell (MFC) technology has drawn of electrodes (6­9), (iii) selection and treatment of membranes (10­12), and (iv) optimization of the MFC design

  12. Fuel Cell Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Systems Fuel Cell Systems The design of fuel cell systems is complex, and can vary significantly depending upon fuel cell type and application. However, several basic...

  13. Fuel Cells Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen fuel cell technology. Fuel Cells More Documents & Publications Hydrogen and Fuel Cell...

  14. 2009 Fuel Cell Market Report

    SciTech Connect (OSTI)

    Vincent, Bill; Gangi, Jennifer; Curtin, Sandra; Delmont, Elizabeth

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  15. Low hydrostatic head electrolyte addition to fuel cell stacks

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Boro, PA)

    1983-01-01

    A fuel cell and system for supply electrolyte, as well as fuel and an oxidant to a fuel cell stack having at least two fuel cells, each of the cells having a pair of spaced electrodes and a matrix sandwiched therebetween, fuel and oxidant paths associated with a bipolar plate separating each pair of adjacent fuel cells and an electrolyte fill path for adding electrolyte to the cells and wetting said matrices. Electrolyte is flowed through the fuel cell stack in a back and forth fashion in a path in each cell substantially parallel to one face of opposite faces of the bipolar plate exposed to one of the electrodes and the matrices to produce an overall head uniformly between cells due to frictional pressure drop in the path for each cell free of a large hydrostatic head to thereby avoid flooding of the electrodes. The bipolar plate is provided with channels forming paths for the flow of the fuel and oxidant on opposite faces thereof, and the fuel and the oxidant are flowed along a first side of the bipolar plate and a second side of the bipolar plate through channels formed into the opposite faces of the bipolar plate, the fuel flowing through channels formed into one of the opposite faces and the oxidant flowing through channels formed into the other of the opposite faces.

  16. Investigation of the performance and water transport of a polymer electrolyte membrane (pem) fuel cell 

    E-Print Network [OSTI]

    Park, Yong Hun

    2009-05-15

    Fuel cell performance was obtained as functions of the humidity at the anode and cathode sites, back pressure, flow rate, temperature, and channel depth. The fuel cell used in this work included a membrane and electrode assembly (MEA) which...

  17. Semitransparent Organic Photovoltaic Cells with Laminated Top Electrode

    E-Print Network [OSTI]

    Cui, Yi

    efficiencies is the use of multijunction cell archi- tectures where several individual cells with different, or when the energy gaps of the materials are not ideal. In multijunction architectures in which the cellsSemitransparent Organic Photovoltaic Cells with Laminated Top Electrode Jung-Yong Lee, Steve T

  18. High power density fuel cell comprising an array of microchannels

    SciTech Connect (OSTI)

    Sopchak, David A; Morse, Jeffrey D; Upadhye, Ravindra S; Kotovsky, Jack; Graff, Robert T

    2014-05-06

    A phosphoric acid fuel cell according to one embodiment includes an array of microchannels defined by a porous electrolyte support structure extending between bottom and upper support layers, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and air electrodes formed along other of the microchannels. A method of making a phosphoric acid fuel cell according to one embodiment includes etching an array of microchannels in a substrate, thereby forming walls between the microchannels; processing the walls to make the walls porous, thereby forming a porous electrolyte support structure; forming anode electrodes along some of the walls; forming cathode electrodes along other of the walls; and filling the porous electrolyte support structure with a phosphoric acid electrolyte. Additional embodiments are also disclosed.

  19. Method of bonding an interconnection layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Pal, U.B.; Isenberg, A.O.; Folser, G.R.

    1992-01-14

    An electrochemical cell containing an air electrode, contacting electrolyte and electronically conductive interconnection layer, and a fuel electrode, has the interconnection layer attached by: (A) applying a thin, closely packed, discrete layer of LaCrO[sub 3] particles, doped with an element selected from the group consisting of Ca, Sr, Co, Ba, Mg and their mixtures on a portion of the air electrode, and then (B) electrochemical vapor depositing a dense skeletal structure between and around the doped LaCrO[sub 3] particles. 2 figs.

  20. Electrochemical sensor for monitoring electrochemical potentials of fuel cell components

    DOE Patents [OSTI]

    Kunz, Harold R. (Vernon, CT); Breault, Richard D. (Coventry, CT)

    1993-01-01

    An electrochemical sensor comprised of wires, a sheath, and a conduit can be utilized to monitor fuel cell component electric potentials during fuel cell shut down or steady state. The electrochemical sensor contacts an electrolyte reservoir plate such that the conduit wicks electrolyte through capillary action to the wires to provide water necessary for the electrolysis reaction which occurs thereon. A voltage is applied across the wires of the electrochemical sensor until hydrogen evolution occurs at the surface of one of the wires, thereby forming a hydrogen reference electrode. The voltage of the fuel cell component is then determined with relation to the hydrogen reference electrode.

  1. Fuel cell CO sensor

    DOE Patents [OSTI]

    Grot, Stephen Andreas (Rochester, NY); Meltser, Mark Alexander (Pittsford, NY); Gutowski, Stanley (Pittsford, NY); Neutzler, Jay Kevin (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY); Weisbrod, Kirk (Los Alamos, NM)

    1999-12-14

    The CO concentration in the H.sub.2 feed stream to a PEM fuel cell stack is monitored by measuring current and/or voltage behavior patterns from a PEM-probe communicating with the reformate feed stream. Pattern recognition software may be used to compare the current and voltage patterns from the PEM-probe to current and voltage telltale outputs determined from a reference cell similar to the PEM-probe and operated under controlled conditions over a wide range of CO concentrations in the H.sub.2 fuel stream. A CO sensor includes the PEM-probe, an electrical discharge circuit for discharging the PEM-probe to monitor the CO concentration, and an electrical purging circuit to intermittently raise the anode potential of the PEM-probe's anode to at least about 0.8 V (RHE) to electrochemically oxidize any CO adsorbed on the probe's anode catalyst.

  2. Carbonate fuel cell matrix

    DOE Patents [OSTI]

    Farooque, M.; Yuh, C.Y.

    1996-12-03

    A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

  3. Method of making MEA for PEM/SPE fuel cell

    DOE Patents [OSTI]

    Hulett, Jay S. (West Henrietta, NY)

    2000-01-01

    A method of making a membrane-electrode-assembly (MEA) for a PEM/SPE fuel cell comprising applying a slurry of electrode-forming material directly onto a membrane-electrolyte film. The slurry comprises a liquid vehicle carrying catalyst particles and a binder for the catalyst particles. The membrane-electrolyte is preswollen by contact with the vehicle before the electrode-forming slurry is applied to the membrane-electrolyte. The swollen membrane-electrolyte is constrained against shrinking in the "x" and "y" directions during drying. Following assembly of the fuel cell, the MEA is rehydrated inside the fuel cell such that it swells in the "z" direction for enhanced electrical contact with contiguous electrically conductive components of the fuel cell.

  4. Fuel cell membrane humidification

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1999-01-01

    A polymer electrolyte membrane fuel cell assembly has an anode side and a cathode side separated by the membrane and generating electrical current by electrochemical reactions between a fuel gas and an oxidant. The anode side comprises a hydrophobic gas diffusion backing contacting one side of the membrane and having hydrophilic areas therein for providing liquid water directly to the one side of the membrane through the hydrophilic areas of the gas diffusion backing. In a preferred embodiment, the hydrophilic areas of the gas diffusion backing are formed by sewing a hydrophilic thread through the backing. Liquid water is distributed over the gas diffusion backing in distribution channels that are separate from the fuel distribution channels.

  5. California Fuel Cell Partnership: Alternative Fuels Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based Fuels| Department ofBusinessCEA90:2:09California EnergyFuel Cell

  6. Magnetron cathodes in plasma electrode Pockels cells

    DOE Patents [OSTI]

    Rhodes, M.A.

    1995-04-25

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal. 5 figs.

  7. Membrane-electrode assemblies for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Sundararajan (Troy, MI); Mikhail, Youssef M. (Sterling Heights, MI)

    1993-01-01

    A combination, unitary, membrane and electrode assembly with a solid polymer electrolyte membrane, and first and second electrodes at least partially embedded in opposed surfaces of the membrane. The electrodes each comprise a respective group of finely divided carbon particles, very finely divided catalytic particles supported on internal and external surfaces of the carbon particles and a proton conductive material intermingled with the catalytic and carbon particles. A first group of finely divided carbon particles forming the first electrode has greater water attraction and retention properties, and is more hydrophilic than a second group of carbon particles forming the second electrode. In a preferred method, the membrane electrode assembly of the invention is prepared by forming a slurry of proton conductive material and at least one group of the carbon and catalyst particles. The slurry is applied to the opposed surfaces of the membrane and heated while being pressed to the membrane for a time and at a temperature and compressive load sufficient to embed at least a portion of the particles into the membrane.

  8. Fuel processor for fuel cell power system

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Springer, Thomas E. (Los Alamos, NM); Huff, James R. (Los Alamos, NM)

    1987-01-01

    A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

  9. Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Download the webinar slides from the U.S. Department...

  10. Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructu...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase...

  11. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-09-05

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  12. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-03-21

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  13. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    a yittria stabilized zirconia (YSZ) electrolyte sandwichedscandia yittria stabilized zirconia (SYSZ) is exchanged forrequirements is stabilized zirconia. Oxygen ion conductivity

  14. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  15. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  16. 2009 Fuel Cell Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  17. Fuel Cell Technical Team Roadmap

    SciTech Connect (OSTI)

    2013-06-01

    The Fuel Cell Technical Team promotes the development of a fuel cell power system for an automotive powertrain that meets the U.S. DRIVE Partnership (United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability) goals.

  18. Cornell Fuel Cell Institute: Materials Discovery to Enable Fuel Cell Technologies

    SciTech Connect (OSTI)

    Abruna, H.D.; DiSalvo, Francis J.

    2012-06-29

    The discovery and understanding of new, improved materials to advance fuel cell technology are the objectives of the Cornell Fuel Cell Institute (CFCI) research program. CFCI was initially formed in 2003. This report highlights the accomplishments from 2006-2009. Many of the grand challenges in energy science and technology are based on the need for materials with greatly improved or even revolutionary properties and performance. This is certainly true for fuel cells, which have the promise of being highly efficient in the conversion of chemical energy to electrical energy. Fuel cells offer the possibility of efficiencies perhaps up to 90 % based on the free energy of reaction. Here, the challenges are clearly in the materials used to construct the heart of the fuel cell: the membrane electrode assembly (MEA). The MEA consists of two electrodes separated by an ionically conducting membrane. Each electrode is a nanocomposite of electronically conducting catalyst support, ionic conductor and open porosity, that together form three percolation networks that must connect to each catalyst nanoparticle; otherwise the catalyst is inactive. This report highlights the findings of the three years completing the CFCI funding, and incudes developments in materials for electrocatalyts, catalyst supports, materials with structured and functional porosity for electrodes, and novel electrolyte membranes. The report also discusses developments at understanding electrocatalytic mechanisms, especially on novel catalyst surfaces, plus in situ characterization techniques and contributions from theory. Much of the research of the CFCI continues within the Energy Materials Center at Cornell (emc2), a DOE funded, Office of Science Energy Frontier Research Center (EFRC).

  19. Fuel Cell Handbook, Fourth Edition

    SciTech Connect (OSTI)

    Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

    1998-11-01

    Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  20. Commercialization of fuel-cells

    SciTech Connect (OSTI)

    Penner, S.S.; Appleby, A.J.; Baker, B.S.; Bates, J.L.; Buss, L.B.; Dollard, W.J.; Farris, P.J.; Gillis, E.A.; Gunsher, J.A.; Khandkar, A.; Krumpelt, M.; O'Sullivan, J.B.; Runte, G.; Savinell, R.F.; Selman, J.R.; Shores, D.A.; Tarman, P.

    1995-03-01

    This report is an abbreviated version of the ''Report of the DOE Advanced Fuel Cell Commercialization Working Group (AFC2WG),'' released January 1995. We describe fuel-cell commercialization for stationary power applications of phosphoric acid, molten carbonate, solid oxide, and polymer electrolyte membrane fuel cells.

  1. National Fuel Cell Research Center

    E-Print Network [OSTI]

    Mease, Kenneth D.

    National Fuel Cell Research Center www.nfcrc.uci.edu SOFC AND PEMFC COMPARISON Efficiency ­ Higher FOR OPTIMIZATION · Fuel Cell · Compressor · Combustor · Turbine · Storage Tank · Heat Exchanger·Battery · Motor of the system. · Operating characteristics of fuel cells at pressures less than 1 atm are largely unknown

  2. Microfluidic Fuel Cells Erik Kjeang

    E-Print Network [OSTI]

    Victoria, University of

    Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeĺ University, 2004 A Dissertation Submitted Supervisory Committee Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeĺ University, 2004 Supervisory University External Examiner Microfluidic fuel cell architectures are presented in this thesis. This work

  3. Performance modelling of a proton exchange membrane fuel cell

    SciTech Connect (OSTI)

    Marr, C.; Li, X.

    1998-12-31

    This paper presents a performance model of a proton exchange membrane fuel cell that has sufficient accuracy for engineering applications with reduced computational requirements. The model includes electrochemical reaction in the catalyst layers and formulation for electrical resistance in the membrane, electrodes and bipolar plates, and employs engineering correlation for the reactant gas transport in the flow channels and through the electrodes. It is shown that the present model predictions are in reasonable agreement with known experimental observations, indicating that the present model can be employed for fuel cell stack and system modeling. The effect of various operating and design parameters on the cell performance has been investigated. It is found that mass transport limitations are the largest cause of performance loss in the cell when graphite is used as the material for bipolar plates and electrodes. If conducting polymers are substituted as construction materials, cell performance is expected to suffer considerably at high current densities due to their reduced electrical conductivity.

  4. Fuel Cell Handbook, Fifth Edition

    SciTech Connect (OSTI)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  5. Pore Formation by In Situ Etching of Nanorod PEM Fuel Cell M. D. Gasda, G. A. Eisman,* and D. Gallz

    E-Print Network [OSTI]

    Gall, Daniel

    Pore Formation by In Situ Etching of Nanorod PEM Fuel Cell Electrodes M. D. Gasda, G. A. Eisman electrolyte membranes for testing as cathode electrodes in fuel cells. The rods were etched within fully, yielding a 400­700% increase in fuel cell output current at low potential. These results suggest

  6. Creep resistant, metal-coated LiFeO[sub 2] anodes for molten carbonated fuel cells

    DOE Patents [OSTI]

    Khandkar, A.C.

    1994-08-23

    A porous, creep-resistant, metal-coated, LiFeO[sub 2] ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well. 11 figs.

  7. Creep resistant, metal-coated LiFeO.sub.2 anodes for molten carbonated fuel cells

    DOE Patents [OSTI]

    Khandkar, Ashok C. (Salt Lake City, UT)

    1994-01-01

    A porous, creep-resistant, metal-coated, LiFeO.sub.2 ceramic electrode for fuel cells is disclosed. The electrode is particularly useful for molten carbonate fuel cells (MCFC) although it may have utilities in solid oxide fuel cells (SOFC) as well.

  8. Fuel cell separator with compressible sealing flanges

    DOE Patents [OSTI]

    Mientek, A.P.

    1984-03-30

    A separator for separating adjacent fuel cells in a stack of such cells includes a flat, rectangular, gas-impermeable plate disposed between adjacent cells and having two opposite side margins thereof folded back over one side of the plate to form two first seal flanges and having the other side margins thereof folded back over the opposite side of the plate to form two second seal flanges, each of the seal flanges cooperating with the plate to define a channel in which is disposed a resiliently compressible stack of thin metal sheets. The two first seal flanges cooperate with the electrolyte matrix of one of the cells to form a gas-impermeable seal between an electrode of the one cell and one of two reactant gas manifolds. The second seal flanges cooperate with the electrolyte matrix of the other cell for forming a gas-impermeable seal between an electrode of the other cell and the other of the two reactant gas manifolds. The seal flanges cooperate with the associated compressible stacks of sheets for maintaining a spacing between the plate and the electrolyte matrices while accommodating variation of that spacing.

  9. Organic fuel cells and fuel cell conducting sheets

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); Ha, Su (Champaign, IL); Adams, Brian (Savoy, IL)

    2007-10-16

    A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

  10. Microbial fuel cells

    DOE Patents [OSTI]

    Nealson, Kenneth H; Pirbazari, Massoud; Hsu, Lewis

    2013-04-09

    A microbial fuel cell includes an anode compartment with an anode and an anode biocatalyst and a cathode compartment with a cathode and a cathode biocatalyst, with a membrane positioned between the anode compartment and the cathode compartment, and an electrical pathway between the anode and the cathode. The anode biocatalyst is capable of catalyzing oxidation of an organic substance, and the cathode biocatalyst is capable of catalyzing reduction of an inorganic substance. The reduced organic substance can form a precipitate, thereby removing the inorganic substance from solution. In some cases, the anode biocatalyst is capable of catalyzing oxidation of an inorganic substance, and the cathode biocatalyst is capable of catalyzing reduction of an organic or inorganic substance.

  11. Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer

    DOE Patents [OSTI]

    Dederer, J.T.; Hager, C.A.

    1998-03-31

    An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier. 10 figs.

  12. Electrochemical fuel cell generator having an internal and leak tight hydrocarbon fuel reformer

    DOE Patents [OSTI]

    Dederer, Jeffrey T. (Valencia, PA); Hager, Charles A. (Mars, PA)

    1998-01-01

    An electrochemical fuel cell generator configuration is made having a generator section which contains a plurality of axially elongated fuel cells, each cell containing a fuel electrode, air electrode, and solid oxide electrolyte between the electrodes, in which axially elongated dividers separate portions of the fuel cells from each other, and where at least one divider also reforms a reformable fuel gas mixture prior to electricity generation reactions, the at least one reformer-divider is hollow having a closed end and an open end entrance for a reformable fuel mixture to pass to the closed end of the divider and then reverse flow and pass back along the hollowed walls to be reformed, and then finally to pass as reformed fuel out of the open end of the divider to contact the fuel cells, and further where the reformer-divider is a composite structure having a gas diffusion barrier of metallic foil surrounding the external walls of the reformer-divider except at the entrance to prevent diffusion of the reformable gas mixture through the divider, and further housed in an outer insulating jacket except at the entrance to prevent short-circuiting of the fuel cells by the gas diffusion barrier.

  13. Nafion-sepiolite composite membranes for improved Proton Exchange Membrane Fuel Cell performance.

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nafion®-sepiolite composite membranes for improved Proton Exchange Membrane Fuel Cell performance, characterized and integrated in Membrane-Electrodes Assembly to be tested in fuel cell operating conditions, mobile or stationary), Proton Exchange Membrane Fuel Cells (PEMFC) are amongst the most studied fuel

  14. Electrical contact structures for solid oxide electrolyte fuel cell

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills, PA)

    1984-01-01

    An improved electrical output connection means is provided for a high temperature solid oxide electrolyte type fuel cell generator. The electrical connection of the fuel cell electrodes to the electrical output bus, which is brought through the generator housing to be connected to an electrical load line maintains a highly uniform temperature distribution. The electrical connection means includes an electrode bus which is spaced parallel to the output bus with a plurality of symmetrically spaced transversely extending conductors extending between the electrode bus and the output bus, with thermal insulation means provided about the transverse conductors between the spaced apart buses. Single or plural stages of the insulated transversely extending conductors can be provided within the high temperatures regions of the fuel cell generator to provide highly homogeneous temperature distribution over the contacting surfaces.

  15. Fuel Station of the Future- Innovative Approach to Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Station of the Future- Innovative Approach to Fuel Cell Technology Unveiled in California Fuel Station of the Future- Innovative Approach to Fuel Cell Technology Unveiled in...

  16. Hydrogen Fueling for Current and Anticipated Fuel Cell Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Download presentation slides from...

  17. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    Sediment microbial fuel cells demonstrating marine (left)Model of hydrogen fuel cell kinetic losses including5 FutureWork 5.1 Microfluidic Microbial Fuel Cell Continued

  18. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    microbial fuel cell applications using dielectrophoresis,”electrochemistry: Application to Fuel Cells. PhD thesis,scale, microbial fuel cells find their application in the

  19. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    on hydrogen fuel cell theoretical efficiency, ? rev , andon hydrogen fuel cell theoretical efficiency, ? rev , andand power and efficiency of PEM fuel cells. In this section,

  20. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    Model of hydrogen fuel cell kinetic losses includingschematic of typical hydrogen fuel cell performancephase factors on hydrogen fuel cell theoretical efficiency,

  1. Sandia Energy - Maritime Hydrogen Fuel Cell Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cell Project Home Transportation Energy Hydrogen Market Transformation Maritime Hydrogen & SF-BREEZE Maritime Hydrogen Fuel Cell Project Maritime Hydrogen Fuel Cell...

  2. Method of forming a plasma sprayed interconnection layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Spengler, Charles J. (Murrysville, PA); Folser, George R. (Lower Burrell, PA); Vora, Shailesh D. (Monroeville, PA); Kuo, Lewis (Monroeville, PA); Richards, Von L. (Anyola, IN)

    1995-01-01

    A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO.sub.3 particles doped with an element selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by plasma spraying doped LaCrO.sub.3 powder, preferably compensated with chromium as Cr.sub.2 O.sub.3 and/or dopant element, preferably by plasma arc spraying; and, (C) heating the doped and compensated LaCrO.sub.3 layer to about 1100.degree. C. to 1300.degree. C. to provide a dense, substantially gas-tight, substantially hydration-free, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the unselected portion of the air electrode, and a fuel electrode can be applied to the solid electrolyte, to provide an electrochemical cell.

  3. Method of forming a plasma sprayed interconnection layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Spengler, C.J.; Folser, G.R.; Vora, S.D.; Kuo, L.; Richards, V.L.

    1995-06-20

    A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an air electrode structure of an electrochemical cell by (A) providing an electrode surface; (B) forming on a selected portion of the electrode surface, a layer of doped LaCrO{sub 3} particles doped with an element selected from Ca, Sr, Ba, Mg, Co, Ni, Al and mixtures thereof by plasma spraying doped LaCrO{sub 3} powder, preferably compensated with chromium as Cr{sub 2}O{sub 3} and/or dopant element, preferably by plasma arc spraying; and, (C) heating the doped and compensated LaCrO{sub 3} layer to about 1100 C to 1300 C to provide a dense, substantially gas-tight, substantially hydration-free, electrically conductive interconnection material bonded to the electrode surface. A solid electrolyte layer can be applied to the unselected portion of the air electrode, and a fuel electrode can be applied to the solid electrolyte, to provide an electrochemical cell. 6 figs.

  4. Li-alloy electrode for Li-alloy/metal sulfide cells

    DOE Patents [OSTI]

    Kaun, T.D.

    1996-07-16

    A method of making a negative electrode is described, the electrode made thereby and a secondary electrochemical cell using the electrode. Lithium, silicon and nickel is alloyed in a prescribed proportion forming an electroactive material, to provide an improved electrode and cell. 7 figs.

  5. Fuel cell with metal screen flow-field

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM); Zawodzinski, Christine (Los Alamos, NM)

    2001-01-01

    A polymer electrolyte membrane (PEM) fuel cell is provided with electrodes supplied with a reactant on each side of a catalyzed membrane assembly (CMA). The fuel cell includes a metal mesh defining a rectangular flow-field pattern having an inlet at a first corner and an outlet at a second corner located on a diagonal from the first corner, wherein all flow paths from the inlet to the outlet through the square flow field pattern are equivalent to uniformly distribute the reactant over the CMA. In a preferred form of metal mesh, a square weave screen forms the flow-field pattern. In a particular characterization of the present invention, a bipolar plate electrically connects adjacent fuel cells, where the bipolar plate includes a thin metal foil having an anode side and a cathode side; a first metal mesh on the anode side of the thin metal foil; and a second metal mesh on the cathode side of the thin metal foil. In another characterization of the present invention, a cooling plate assembly cools adjacent fuel cells, where the cooling plate assembly includes an anode electrode and a cathode electrode formed of thin conducting foils; and a metal mesh flow field therebetween for distributing cooling water flow over the electrodes to remove heat generated by the fuel cells.

  6. Fuel cell with metal screen flow-field

    DOE Patents [OSTI]

    Wilson, M.S.; Zawodzinski, C.

    1998-08-25

    A polymer electrolyte membrane (PEM) fuel cell is provided with electrodes supplied with a reactant on each side of a catalyzed membrane assembly (CMA). The fuel cell includes a metal mesh defining a rectangular flow-field pattern having an inlet at a first corner and an outlet at a second corner located on a diagonal from the first corner, wherein all flow paths from the inlet to the outlet through the square flow field pattern are equivalent to uniformly distribute the reactant over the CMA. In a preferred form of metal mesh, a square weave screen forms the flow-field pattern. In a particular characterization of the present invention, a bipolar plate electrically connects adjacent fuel cells, where the bipolar plate includes a thin metal foil having an anode side and a cathode side; a first metal mesh on the anode side of the thin metal foil; and a second metal mesh on the cathode side of the thin metal foil. In another characterization of the present invention, a cooling plate assembly cools adjacent fuel cells, where the cooling plate assembly includes an anode electrode and a cathode electrode formed of thin conducting foils; and a metal mesh flow field there between for distributing cooling water flow over the electrodes to remove heat generated by the fuel cells. 11 figs.

  7. Hybrid Fuel Cell Technology Overview

    SciTech Connect (OSTI)

    None available

    2001-05-31

    For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

  8. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuelCell|FYIEA

  9. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell Seminar2015ofFuelCell|FYIEA

  10. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Cell Technologies

  11. Integrated fuel cell stack shunt current prevention arrangement

    DOE Patents [OSTI]

    Roche, Robert P. (Cheshire, CT); Nowak, Michael P. (Bolton, CT)

    1992-01-01

    A fuel cell stack includes a plurality of fuel cells juxtaposed with one another in the stack and each including a pair of plate-shaped anode and cathode electrodes that face one another, and a quantity of liquid electrolyte present at least between the electrodes. A separator plate is interposed between each two successive electrodes of adjacent ones of the fuel cells and is unified therewith into an integral separator plate. Each integral separator plate is provided with a circumferentially complete barrier that prevents flow of shunt currents onto and on an outer peripheral surface of the separator plate. This barrier consists of electrolyte-nonwettable barrier members that are accommodated, prior to the formation of the integral separator plate, in corresponding edge recesses situated at the interfaces between the electrodes and the separator plate proper. Each barrier member extends over the entire length of the associated marginal portion and is flush with the outer periphery of the integral separator plate. This barrier also prevents cell-to-cell migration of any electrolyte that may be present at the outer periphery of the integral separator plate while the latter is incorporated in the fuel cell stack.

  12. Fuel Cell Research

    SciTech Connect (OSTI)

    Weber, Peter M.

    2014-03-30

    Executive Summary In conjunction with the Brown Energy Initiative, research Projects selected for the fuel cell research grant were selected on the following criteria: ? They should be fundamental research that has the potential to significantly impact the nation’s energy infrastructure. ? They should be scientifically exciting and sound. ? They should synthesize new materials, lead to greater insights, explore new phenomena, or design new devices or processes that are of relevance to solving the energy problems. ? They involve top-caliper senior scientists with a record of accomplishment, or junior faculty with outstanding promise of achievement. ? They should promise to yield at least preliminary results within the given funding period, which would warrant further research development. ? They should fit into the overall mission of the Brown Energy Initiative, and the investigators should contribute as partners to an intellectually stimulating environment focused on energy science. Based on these criteria, fourteen faculty across three disciplines (Chemistry, Physics and Engineering) and the Charles Stark Draper Laboratory were selected to participate in this effort.1 In total, there were 30 people supported, at some level, on these projects. This report highlights the findings and research outcomes of the participating researchers.

  13. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel Cell

  14. Fuel Cell Technologies Office: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information Resources » Fuel Cell

  15. Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterFinancial Opportunities Financialof Energy Cell

  16. Financing Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,Energy 9,UNIVERSITYDepartment of

  17. Fuel Cell Case Study

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy Loftus Global Leader, Sustainable

  18. Fuel cell gas management system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur (Marietta, GA)

    2000-01-11

    A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  19. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, Richard C. (East Hartford, CT)

    1986-09-02

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  20. Molten carbonate fuel cell separator

    DOE Patents [OSTI]

    Nickols, R.C.

    1984-10-17

    In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

  1. Fuel Cell Handbook (Seventh Edition)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Directly to the Local Utility...... 8-37 8.2.6 Power Conditioners for Automotive Fuel Cells ... 8-39 8.2.7 Power Conversion...

  2. Fuel cell system with interconnect

    DOE Patents [OSTI]

    Goettler, Richard; Liu, Zhien

    2015-08-11

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  3. Fuel cell system with interconnect

    SciTech Connect (OSTI)

    Liu, Zhien; Goettler, Richard

    2015-09-29

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  4. Fuel cell system with interconnect

    DOE Patents [OSTI]

    Goettler, Richard; Liu, Zhien

    2015-03-10

    The present invention includes a fuel cell system having a plurality of adjacent electrochemical cells formed of an anode layer, a cathode layer spaced apart from the anode layer, and an electrolyte layer disposed between the anode layer and the cathode layer. The fuel cell system also includes at least one interconnect, the interconnect being structured to conduct free electrons between adjacent electrochemical cells. Each interconnect includes a primary conductor embedded within the electrolyte layer and structured to conduct the free electrons.

  5. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the Bill Financing Tool Fits theSunShot Prize:4 FuelAbout Key Activities

  6. Layered method of electrode for solid oxide electrochemical cells

    SciTech Connect (OSTI)

    Jensen, R.R.

    1991-07-30

    This patent describes a fuel electrode. It comprises a first layer comprising substantially stabilized zirconia; a second layer, in intimate contact with the first layer, comprising a mixture of stabilized zirconia and metal powder selected from the group consisting of nickel, palladium, platinum and cobalt; and a third layer comprising substantially metal powder selected from the group consisting of nickel, palladium, platinum and cobalt.

  7. Efficient process for previous metal recovery from cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence; Matlin, Ramail; Heinz, Robert

    2010-05-04

    A method is provided for recovering a catalytic element from a fuel cell membrane electrode assembly. The method includes grinding the membrane electrode assembly into a powder, extracting the catalytic element by forming a slurry comprising the powder and an acid leachate adapted to dissolve the catalytic element into a soluble salt, and separating the slurry into a depleted powder and a supernatant containing the catalytic element salt. The depleted powder is washed to remove any catalytic element salt retained within pores in the depleted powder and the catalytic element is purified from the salt.

  8. Internal reforming fuel cell assembly with simplified fuel feed

    DOE Patents [OSTI]

    Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

    2001-01-01

    A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

  9. Current Research Activities in Electrode and Cell Prototyping

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  10. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    process for the dual channeled microbial fuel cell. Theprocess for the dual channeled microbial fuel cell. The

  11. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    electrolyte fuel cells (PEFC) is an ongoing challenge.PEFC.electrolyte fuel cell (PEFC) is a device that converts

  12. Sandia Energy - Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen GenerationTechnologiesEnergy ConversionEngine CombustionFuel

  13. Ohio Fuel Cell Initiative

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills and ReduceNovemberDOE'sManagement ofOh, the (Energy-Related) Stories

  14. Fuel Cell Financing Options

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy Loftus Global Leader, Sustainable4IssuesUTC

  15. Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly(diallyldimethylammonium chloride)s

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly to be used in a Solid Alkaline Fuel Cell (SAFC) needs to (i) be insoluble in both aqueous solutions,10% > 320 °C). When used in a fuel cell as a binder in the membrane-electrodes assembly (MEA

  16. Electrochimica Acta 52 (2007) 49424946 High-performance microfluidic vanadium redox fuel cell

    E-Print Network [OSTI]

    Brolo, Alexandre G.

    2007-01-01

    vanadium redox fuel cell Erik Kjeanga,c, Brenton T. Proctora,c, Alexandre G. Brolob,c, David A. Harringtonb a new microfluidic fuel cell design with high-surface area porous carbon electrodes and high aspect-effective and rapid fabrication, and would be applicable to most microfluidic fuel cell architectures. © 2007 Elsevier

  17. Phase field modeling of microstructure evolution of electrocatalyst-infiltrated solid oxide fuel cell cathodes

    E-Print Network [OSTI]

    Chen, Long-Qing

    instability and mechanical damage in solid oxide fuel cell anodes J. Appl. Phys. 114, 183519 (2013); 10-phase electrode microstructures in solid oxide fuel cells Appl. Phys. Lett. 101, 033909 (2012); 10.1063/1.4738230 Synthesis and calorimetric studies of oxide multilayer systems: Solid oxide fuel cell cathode

  18. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

  19. Method of bonding a conductive layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Bowker, J.C.; Singh, P.

    1989-08-29

    A dense, electronically conductive interconnection layer is bonded onto a porous, tubular, electronically conductive air electrode structure, optionally supported by a ceramic support, by (A) providing an air electrode surface, (B) forming on a selected portion of the electrode surface, without the use of pressure, particles of LaCrO[sub 3] doped with an element selected from the group consisting of Sr, Mg, Ca, Ba, Co, and mixtures thereof, where the particles have a deposit on their surface comprising calcium oxide and chromium oxide; (C) heating the particles with the oxide surface deposit in an oxidizing atmosphere at from 1,300 C to 1,550 C, without the application of pressure, to provide a dense, sintered, interconnection material bonded to the air electrode, where calcium and chromium from the surface deposit are incorporated into the structure of the LaCrO[sub 3]. A solid electrolyte layer can be applied to the uncovered portion of the air electrode, and a fuel electrode can be applied to the solid electrolyte, to provide an electrochemical cell. 4 figs.

  20. Hydrogen & Fuel Cells -Program Overview -

    E-Print Network [OSTI]

    and Peer Evaluation Meeting May 14, 2012 #12;Petroleum 37% Natural Gas 25% Coal 21% Nuclear Energy 9% Korea 7% Canada 3% Taiwan 1% Great Britain 1% France 1% Other 3% Japan 31% Fuel Cell Patents Geographic Others. For 2008-2011 All Others Germany South Korea Japan United States Fuel Cell Market Overview

  1. Energy 101: Fuel Cell Technology

    ScienceCinema (OSTI)

    None

    2014-06-06

    Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

  2. Bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2010-06-08

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  3. Energy 101: Fuel Cell Technology

    SciTech Connect (OSTI)

    2014-03-11

    Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

  4. Bronx Zoo Fuel Cell Project

    SciTech Connect (OSTI)

    Hoang Pham

    2007-09-30

    A 200 kW Fuel Cell has been installed in the Lion House, Bronx Zoo, NY. The Fuel Cell is a 200 kW phosphoric acid type manufactured by United Technologies Corporation (UTC) and will provide thermal energy at 725,000 Btu/hr.

  5. Hydrogen & Fuel Cells Program Overview

    E-Print Network [OSTI]

    and Peer Evaluation Meeting May 9, 2011 #12;Enable widespread commercialization of hydrogen and fuel cell: > 300-mile range for vehicles--without compromising interior space or performance #12;Balance of Plant estimate" for 2008 http://hydrogendoedev.nrel.gov/peer_reviews.html Progress ­ Fuel Cell R&D 2010 2007 6

  6. Porous coolant tube holder for fuel cell stack

    DOE Patents [OSTI]

    Guthrie, Robin J. (East Hartford, CT)

    1981-01-01

    A coolant tube holder for a stack of fuel cells is a gas porous sheet of fibrous material adapted to be sandwiched between a cell electrode and a nonporous, gas impervious flat plate which separates adjacent cells. The porous holder has channels in one surface with coolant tubes disposed therein for carrying coolant through the stack. The gas impervious plate is preferably bonded to the opposite surface of the holder, and the channel depth is the full thickness of the holder.

  7. Journal of Power Sources 160 (2006) 10581064 Passive direct formic acid microfabricated fuel cells

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    2006-01-01

    Journal of Power Sources 160 (2006) 1058­1064 Passive direct formic acid microfabricated fuel cells on microscale silicon-based direct formic acid fuel cells (Si-DFAFCs) in which the fuel and the oxidant are supplied to the electrodes in a passive manner. Passive delivery of fuel and oxidant eliminates the need

  8. Automotive Fuel Cell Corporation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits & Inspections Audits & Inspections

  9. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  10. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  11. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

    2006-11-14

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  12. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-13

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  13. Electrochemical cell apparatus having axially distributed entry of a fuel-spent fuel mixture transverse to the cell lengths

    DOE Patents [OSTI]

    Reichner, P.; Dollard, W.J.

    1991-01-08

    An electrochemical apparatus is made having a generator section containing axially elongated electrochemical cells, a fresh gaseous feed fuel inlet, a gaseous feed oxidant inlet, and at least one gaseous spent fuel exit channel, where the spent fuel exit channel passes from the generator chamber to combine with the fresh feed fuel inlet at a mixing apparatus, reformable fuel mixture channel passes through the length of the generator chamber and connects with the mixing apparatus, that channel containing entry ports within the generator chamber, where the axis of the ports is transverse to the fuel electrode surfaces, where a catalytic reforming material is distributed near the reformable fuel mixture entry ports. 2 figures.

  14. Fuel cell electric power production

    DOE Patents [OSTI]

    Hwang, Herng-Shinn (Livingston, NJ); Heck, Ronald M. (Frenchtown, NJ); Yarrington, Robert M. (Westfield, NJ)

    1985-01-01

    A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

  15. Fuel Cells | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpAFlex FuelsEnergyInc| OpenFuMA TechFuel Cells

  16. Fuel Cells in the States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen hfor|Fuelin

  17. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Y.; Meng, W.J.; Swathirajan, S.; Harris, S.J.; Doll, G.L.

    1997-04-29

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell`s operating environment. Stainless steels rich in Cr, Ni, and Mo are particularly effective protective interlayers. 6 figs.

  18. Electrodes including a polyphosphazene cyclomatrix, methods of forming the electrodes, and related electrochemical cells

    DOE Patents [OSTI]

    Gering, Kevin L; Stewart, Frederick F; Wilson, Aaron D; Stone, Mark L

    2014-10-28

    An electrode comprising a polyphosphazene cyclomatrix and particles within pores of the polyphosphazene cyclomatrix. The polyphosphazene cyclomatrix comprises a plurality of phosphazene compounds and a plurality of cross-linkages. Each phosphazene compound of the plurality of phosphazene compounds comprises a plurality of phosphorus-nitrogen units, and at least one pendant group bonded to each phosphorus atom of the plurality of phosphorus-nitrogen units. Each phosphorus-nitrogen unit is bonded to an adjacent phosphorus-nitrogen unit. Each cross-linkage of the plurality of cross-linkages bonds at least one pendant group of one phosphazene compound of the plurality of phosphazene compounds with the at least one pendant group of another phosphazene compound of the plurality of phosphazene compounds. A method of forming a negative electrode and an electrochemical cell are also described.

  19. Nanomaterials for Fuel cells, Batteries, and Supercapacitors Flow Batteries

    E-Print Network [OSTI]

    Dutta, Indranath

    Nanomaterials for Fuel cells, Batteries, and Supercapacitors Flow Batteries 1. Shao Y, X Wang, MH storage in vanadium redox flow batteries." Journal of Power Sources 195(13):4375-4379. 2. Shao Y, MH nanotube electrodes for redox flow batteries." Electrochemistry Communications 11(10):2064-2067. doi:10

  20. Canadian Fuel Cell Commercialization Roadmap Update: Progress...

    Open Energy Info (EERE)

    Canadian Fuel Cell Commercialization Roadmap Update: Progress of Canada's Hydrogen and Fuel Cell Industry Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Canadian Fuel...

  1. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, A.F.; Makowiecki, D.M.; Rambach, G.D.; Randich, E.

    1998-05-19

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated. 8 figs.

  2. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

    1998-01-01

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  3. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

    1999-01-01

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  4. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01

    to produce a unit of bio-energy than is required to producecompared the amount of bio-energy (45 eJ) that could besource (electricity or bio-energy) or the end-use fuel (

  5. Porous electrolyte retainer for molten carbonate fuel cell

    DOE Patents [OSTI]

    Singh, Raj N. (Downers Grove, IL); Dusek, Joseph T. (Downers Grove, IL)

    1983-06-21

    A porous tile for retaining molten electrolyte within a fuel cell is prepared by sintering particles of lithium aluminate into a stable structure. The tile is assembled between two porous metal plates which serve as electrodes with fuels gases such as H.sub.2 and CO opposite to oxidant gases such as O.sub.2 and CO.sub.2. The tile is prepared with a porosity of 55-65% and a pore size distribution selected to permit release of sufficient molten electrolyte to wet but not to flood the adjacent electrodes.

  6. Metal electrode for amorphous silicon solar cells

    DOE Patents [OSTI]

    Williams, Richard (Princeton, NJ)

    1983-01-01

    An amorphous silicon solar cell having an N-type region wherein the contact to the N-type region is composed of a material having a work function of about 3.7 electron volts or less. Suitable materials include strontium, barium and magnesium and rare earth metals such as gadolinium and yttrium.

  7. Navy fuel cell demonstration project.

    SciTech Connect (OSTI)

    Black, Billy D.; Akhil, Abbas Ali

    2008-08-01

    This is the final report on a field evaluation by the Department of the Navy of twenty 5-kW PEM fuel cells carried out during 2004 and 2005 at five Navy sites located in New York, California, and Hawaii. The key objective of the effort was to obtain an engineering assessment of their military applications. Particular issues of interest were fuel cell cost, performance, reliability, and the readiness of commercial fuel cells for use as a standalone (grid-independent) power option. Two corollary objectives of the demonstration were to promote technological advances and to improve fuel performance and reliability. From a cost perspective, the capital cost of PEM fuel cells at this stage of their development is high compared to other power generation technologies. Sandia National Laboratories technical recommendation to the Navy is to remain involved in evaluating successive generations of this technology, particularly in locations with greater environmental extremes, and it encourages their increased use by the Navy.

  8. Climate Change Fuel Cell Program

    SciTech Connect (OSTI)

    Paul Belard

    2006-09-21

    Verizon is presently operating the largest Distributed Generation Fuel Cell project in the USA. Situated in Long Island, NY, the power plant is composed of seven (7) fuel cells operating in parallel with the Utility grid from the Long Island Power Authority (LIPA). Each fuel cell has an output of 200 kW, for a total of 1.4 mW generated from the on-site plant. The remaining power to meet the facility demand is purchased from LIPA. The fuel cell plant is utilized as a co-generation system. A by-product of the fuel cell electric generation process is high temperature water. The heat content of this water is recovered from the fuel cells and used to drive two absorption chillers in the summer and a steam generator in the winter. Cost savings from the operations of the fuel cells are forecasted to be in excess of $250,000 per year. Annual NOx emissions reductions are equivalent to removing 1020 motor vehicles from roadways. Further, approximately 5.45 million metric tons (5 millions tons) of CO2 per year will not be generated as a result of this clean power generation. The project was partially financed with grants from the New York State Energy R&D Authority (NYSERDA) and from Federal Government Departments of Defense and Energy.

  9. Nanostructured Electrode Materials for Supercapacitors

    E-Print Network [OSTI]

    Wu, Shin-Tson

    and batteries/fuel cells. Nanostructured electrode materials have demonstrated superior electrochemical of polymethine dyes electronic spectra is crucial for successful design of the new molecules with optimized

  10. DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...

    Broader source: Energy.gov (indexed) [DOE]

    Results from the analysis were communicated to the FCT Office at the DOE Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation 3 and at a meeting of the...

  11. Fuel Cell Stack Components BipolarPlate

    E-Print Network [OSTI]

    for Metallic Bipolar Plates · Carbon Foam for Fuel Cell Humidification · High Temperature Proton ExchangeFuel Cell Stack Components Fuel Processor BipolarPlate Cathode+ Anode- Electrolyte H+ H+ HYDROGEN Crossover Fuel Cell Stack Components #12;Barriers

  12. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, L.J.H.; Singh, P.; Ruka, R.J.; Vasilow, T.R.; Bratton, R.J.

    1997-11-11

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators. 4 figs.

  13. Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells

    DOE Patents [OSTI]

    Kuo, Lewis J. H. (Monroeville, PA); Singh, Prabhakar (Export, PA); Ruka, Roswell J. (Churchill Boro, PA); Vasilow, Theodore R. (Penn Township, PA); Bratton, Raymond J. (Delmont, PA)

    1997-01-01

    A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators.

  14. High power density solid oxide fuel cells

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2004-10-12

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O (LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  15. Additive Manufacturing for Fuel Cells

    Broader source: Energy.gov [DOE]

    Blake Marshall, AMO's lead for Additive Manufacturing Technologies, will provide an overview of current R&D activities in additive manufacturing and its application to fuel cell prototyping and...

  16. CLIMATE CHANGE FUEL CELL PROGRAM

    SciTech Connect (OSTI)

    Mike Walneuski

    2004-09-16

    ChevronTexaco has successfully operated a 200 kW PC25C phosphoric acid fuel cell power plant at the corporate data center in San Ramon, California for the past two years and seven months following installation in December 2001. This site was chosen based on the ability to utilize the combined heat (hot water) and power generation capability of this modular fuel cell power plant in an office park setting . In addition, this project also represents one of the first commercial applications of a stationary fuel cell for a mission critical data center to assess power reliability benefits. This fuel cell power plant system has demonstrated outstanding reliability and performance relative to other comparably sized cogeneration systems.

  17. Metrology for Fuel Cell Manufacturing

    SciTech Connect (OSTI)

    Stocker, Michael; Stanfield, Eric

    2015-02-04

    The project was divided into three subprojects. The first subproject is Fuel Cell Manufacturing Variability and Its Impact on Performance. The objective was to determine if flow field channel dimensional variability has an impact on fuel cell performance. The second subproject is Non-contact Sensor Evaluation for Bipolar Plate Manufacturing Process Control and Smart Assembly of Fuel Cell Stacks. The objective was to enable cost reduction in the manufacture of fuel cell plates by providing a rapid non-contact measurement system for in-line process control. The third subproject is Optical Scatterfield Metrology for Online Catalyst Coating Inspection of PEM Soft Goods. The objective was to evaluate the suitability of Optical Scatterfield Microscopy as a viable measurement tool for in situ process control of catalyst coatings.

  18. Stationary Fuel Cell Evaluation (Presentation)

    SciTech Connect (OSTI)

    Kurtz, J.; Wipke, K.; Sprik, S.; Ramsden, T.; Ainscough, C.

    2012-05-01

    This powerpoint presentation discusses its objectives: real world operation data from the field and state-of-the-art lab; collection; analysis for independent technology validation; collaboration with industry and end users operating stationary fuel cell systems and reporting on technology status, progress and technical challenges. The approach and accomplishments are: A quarterly data analysis and publication of first technical stationary fuel cell composite data products (data through June 2012).

  19. Variable area fuel cell cooling

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Borough, PA)

    1982-01-01

    A fuel cell arrangement having cooling fluid flow passages which vary in surface area from the inlet to the outlet of the passages. A smaller surface area is provided at the passage inlet, which increases toward the passage outlet, so as to provide more uniform cooling of the entire fuel cell. The cooling passages can also be spaced from one another in an uneven fashion.

  20. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang (Troy, MI); Meng, Wen-Jin (Okemos, MI); Swathirajan, Swathy (West Bloomfield, MI); Harris, Stephen J. (Bloomfield, MI); Doll, Gary L. (Orion Township, Oakland County, MI)

    1997-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  1. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang; Meng, Wen-Jin; Swathirajan, Swathy; Harris, Stephen Joel; Doll, Gary Lynn

    2001-07-17

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  2. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Li, Yang (Troy, MI); Meng, Wen-Jin (Okemos, MI); Swathirajan, Swathy (West Bloomfield, MI); Harris, Stephen Joel (Bloomfield, MI); Doll, Gary Lynn (Orion Township, Oakland County, MI)

    2002-01-01

    The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell's operating environment. Stainless steels rich in CR, Ni, and Mo are particularly effective protective interlayers.

  3. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1985-01-01

    A rapidly refuelable dual cell of an electrochemical type wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  4. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, R.W.

    1982-09-20

    A rapidly refuelable dual cell of an electrochemical type is described wherein a single anode cooperates with two cathodes and wherein the anode has a fixed position and the cathodes are urged toward opposite faces of the anodes at constant and uniform force. The associated cathodes are automatically retractable to permit the consumed anode remains to be removed from the housing and a new anode inserted between the two cathodes.

  5. Fuel Cells for Portable Power: 1. Introduction to DMFCs; 2. Advanced Materials and Concepts for Portable Power Fuel Cells

    SciTech Connect (OSTI)

    Zelenay, Piotr [Los Alamos National Laboratory

    2012-07-16

    Thanks to generally less stringent cost constraints, portable power fuel cells, the direct methanol fuel cell (DMFC) in particular, promise earlier market penetration than higher power polymer electrolyte fuel cells (PEFCs) for the automotive and stationary applications. However, a large-scale commercialization of DMFC-based power systems beyond niche applications already targeted by developers will depend on improvements to fuel cell performance and performance durability as well as on the reduction in cost, especially of the portable systems on the higher end of the power spectrum (100-250 W). In this part of the webinar, we will focus on the development of advanced materials (catalysts, membranes, electrode structures, and membrane electrode assemblies) and fuel cell operating concepts capable of fulfilling two key targets for portable power systems: the system cost of $5/W and overall fuel conversion efficiency of 2.0-2.5 kWh/L. Presented research will concentrate on the development of new methanol oxidation catalysts, hydrocarbon membranes with reduced methanol crossover, and improvements to component durability. Time permitted, we will also present a few highlights from the development of electrocatalysts for the oxidation of two alternative fuels for the direct-feed fuel cells: ethanol and dimethyl ether.

  6. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    Optimization of Fuel Cell System Operating Conditions forOptimization of Fuel Cell System Operating Conditions forOptimization of Fuel Cell System Operating Conditions for

  7. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    R.M. Moore, PEM Fuel Cell System Optimization, ProceedingsInterface of the fuel cell system optimization model Fig. 5hydrogen fuel cell vehicle; optimization model; simulation *

  8. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    and cost [ 1]. Fuel cell applications in automobiles arete d M fuel cell systems for vehicle applications, Journalof the fuel cell for vehicle applications. The air supply

  9. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    simulation tool for hydrogen fuel cell vehicles, Journal ofApplication on Direct Hydrogen Fuel Cell Vehicles, 2008. Accell system for direct hydrogen fuel cell vehicles Fig. 3

  10. Fuel Cell Hybrid Bus Lands at Hickam AFB: Hydrogen Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid Bus Lands at Hickam AFB: Hydrogen Fuel Cell & Infrastructure Technologies Program, Fuel Cell Bus Demonstration Project (Fact Sheet) Fuel Cell Hybrid Bus Lands at Hickam AFB:...

  11. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    An Indirect Methanol Pem Fuel Cell System, SAE 2001, (paperof automotive PEM fuel cell stacks, SAE 2000 (paper numberParasitic Loads in Fuel Cell Vehicles, International Journal

  12. Fuel Cell Handbook (Seventh Edition)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvanServicesAmesFourFromFuel Cell Handbook (Seventh

  13. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting es028lu2012o.pdf More Documents & Publications Cell...

  14. Federico Zenith Control of fuel cells

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Federico Zenith Control of fuel cells Doctoral thesis for the degree of philosophić doctor with control of fuel cells, focusing on high-temperature proton- exchange-membrane fuel cells. Fuel cells-wide electric grids. Whereas studies about the design of fuel cell systems and the electrochemical properties

  15. Federico Zenith Control of fuel cells

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Federico Zenith Control of fuel cells Doctoral thesis for the degree of philosophić doctor with control of fuel cells, focusing on high-temperature proton-exchange-membrane fuel cells. Fuel cells-wide electric grids. Whereas studies about the design of fuel cell systems and the electrochemical properties

  16. 1986 fuel cell seminar: Program and abstracts

    SciTech Connect (OSTI)

    1986-10-01

    Ninety nine brief papers are arranged under the following session headings: gas industry's 40 kw program, solid oxide fuel cell technology, phosphoric acid fuel cell technology, molten carbonate fuel cell technology, phosphoric acid fuel cell systems, power plants technology, fuel cell power plant designs, unconventional fuels, fuel cell application and economic assessments, and plans for commerical development. The papers are processed separately for the data base. (DLC)

  17. Molten carbonate fuel cell reduction of nickel deposits

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Zwick, Stanley A. (Darien, IL)

    1987-01-01

    A molten carbonate fuel cell with anode and cathode electrodes and an eleolyte formed with two tile sections, one of the tile sections being adjacent the anode and limiting leakage of fuel gas into the electrolyte with the second tile section being adjacent the cathode and having pores sized to permit the presence of oxygen gas in the electrolyte thereby limiting the formation of metal deposits caused by the reduction of metal compositions migrating into the electrolyte from the cathode.

  18. NREL: Hydrogen and Fuel Cells Research - Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on771/6/14RecentGeospatialReliabilityWorking with UstheCells Photo of

  19. Method for producing electricity from a fuel cell having solid-oxide ionic electrolyte

    DOE Patents [OSTI]

    Mason, David M. (Los Altos, CA)

    1984-01-01

    Stabilized quadrivalent cation oxide electrolytes are employed in fuel cells at elevated temperatures with a carbon and/or hydrogen containing fuel anode and an oxygen cathode. The fuel cell is operated at elevated temperatures with conductive metallic coatings as electrodes and desirably having the electrolyte surface blackened. Of particular interest as the quadrivalent oxide is zirconia.

  20. Binary inorganic salt mixtures as high conductivity liquid electrolytes for .100 uC fuel cells{

    E-Print Network [OSTI]

    Angell, C. Austen

    Binary inorganic salt mixtures as high conductivity liquid electrolytes for .100 uC fuel cells cations (e.g. ammonium) as electrolytes in fuel cells operating in the temperature range 100­200 uC, where cell operating with optimized electrodes in the same temperature range, while open circuit voltages

  1. All ceramic structure for molten carbonate fuel cell

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1992-01-01

    An all-ceramic molten carbonate fuel cell having a composition formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The structure includes an anode and cathode separated by an electronically conductive interconnect. The electrodes and interconnect are compositions ceramic materials. Various combinations of ceramic compositions for the anode, cathode and interconnect are disclosed. The fuel cell exhibits stability in the fuel gas and oxidizing environments. It presents reduced sealing and expansion problems in fabrication and has improved long-term corrosion resistance.

  2. Gene expression and deletion analysis of mechanisms for electron transfer from electrodes to Geobacter sulfurreducens

    E-Print Network [OSTI]

    Lovley, Derek

    transfer to electrodes. Keywords: microbial fuel cell, Geobacter sulfurreducens, cathode, electron donor. Surprisingly, genes for putative cell-electrode connections, such as outer-surface cytochromes and pili, which emerging area in microbe-electrode interactio

  3. Fuel Cells Calendar | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells Calendar Fuel Cells Calendar Upcoming events for the Fuel Cell Technologies Office are listed below. Find past events. June 2015 < prev next > Sun Mon Tue Wed Thu Fri...

  4. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    polymer electrolyte membrane fuel cells, 2009. C. Lim and C.be incorporated directly into full fuel-cell simulations toFCgen1020ACS, www.ballard.com/fuel-cell-products, Accessed

  5. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  6. Aalborg Universitet HTPEM Fuel Cell Impedance

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet HTPEM Fuel Cell Impedance Vang, Jakob Rabjerg Publication date: 2014 Document Citation for published version (APA): Vang, J. R. (2014). HTPEM Fuel Cell Impedance: Mechanistic Modelling #12;HTPEM fuel cell impedance - Mechanistic modelling and experimental characterisation Jakob Rabjerg

  7. Solar-Hydrogen Fuel-Cell Vehicles

    E-Print Network [OSTI]

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01

    264. DeLuchi M. A. (1992). Hydrogen Fuel-Cell Vehicles. Re-or regulation. Solar-Hydrogen Fuel-Cell Vehicles MarkA.Solar-Hydrogen Fuel-Cell Mark Ao DeLuchi Joan M. Ogden

  8. Microfluidic Microbial Fuel Cells for Microstructure Interrogations

    E-Print Network [OSTI]

    Parra, Erika Andrea

    2010-01-01

    5 FutureWork 5.1 Microfluidic Microbial Fuel Cell ContinuedSediment microbial fuel cells demonstrating marine (left)Model of hydrogen fuel cell kinetic losses including

  9. Tubular solid oxide fuel cell prospect

    SciTech Connect (OSTI)

    Veyo, S.E.

    1996-05-01

    Driven by technological achievement and rational projection of commercial product cost, expectations for tubular SOFC commercialization are improving. Tubular SOFCs have surpassed 7 yrs operation and have recently demonstrated remarkable toughness in thermal cycling. Customer-owned systems with 25 kW stacks utilizing air electrode supported (AES) cells continue to operate directly on natural gas without degradation after multiple thermal cycles and over 4000 hrs operation. AES cell operation at elevated pressure corroborates theoretical estimates of performance gain without evidence of deleterious effect. Commercial class AES cell of 22 mm dia and 1500 mm length, is now in production for application to 100 kW, 50% efficient (ac/LHV), atmospheric pressure systems. This same cell applied to pressurized systems in combination with conventional turbo machinery (gas turbines) can yield an efficiency approaching 70% for power plants as small as 5 MW. Total installed system cost for commercial 5 MW SOFC/CT units for distributed power generation and on-site cogeneration should approach $1000/kW. A major challenge is formation of funded projects to demonstrate at the turn of the century prototype MW class SOFC/CT combined cycle power plants and to complete the development of commercial fuel cell manufacturing processes.

  10. Novel Low Temperature Solid State Fuel Cells

    SciTech Connect (OSTI)

    Chen, Chonglin; Nash, Patrick; Liu, Jian; Collins, Gregory

    2009-12-15

    We have successfully fabricated (PrBa)Co{sub 2}O{sub 5+{delta}} and (LaBa)Co{sub 2}O{sub 5+{deleta}} epitaxial thin film on various single crystal substrates. Physical and electrochemical properties characterizations were carried out. Highly conductive oxygen-deficient double perovskite LnBaCo2O5+? thin films were grown on single crystal (001) SrTiO{sub 3} (STO), (001) MgO, (001) LaAlO{sub 3} and (110) NdGaO{sub 3} substrate by pulsed laser deposition. Microstructure studies from synchrotron X-ray diffraction and Transmission electron microscopy. High temperature transport properties was carried in different atmosphere (O{sub 2},Air, N{sub 2}) up to ~900K. Resistance response of (LaBa)Co{sub 2}O{sub 5+{delta}} epitaxial thin film was characterized in oxygen, nitrogen and 4% hydrogen over a wide range of temperature from 400?C up to 800?C. To determine the electrode performance and oxygen exchange kinetics of PrBaCo{sub 2}O{sub 5+{delta}}, multi-layered thin film based half cell was deposited on LaAlO{sub 3}(001) substrate. The temperature dependence of the resistance of this half ?cell structure was characterized by electrochemical impedance spectroscopy (EIS) within different temperature and gas environments. Anode supported fuel cells, with GCO:YSZ multilayer thin film as electrolyte and PBCO thin film as electrode, are fabricated on tape casted NiO/YSZ substrate. Full cell performance is characterized up to 800?C.

  11. DOE Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System...

    Office of Environmental Management (EM)

    Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System Cost - 2014 DOE Hydrogen and Fuel Cells Program Record 14014: Fuel Cell System Cost - 2014 Program record 14014 from...

  12. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich`s solution and analysis.

  13. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

    2008-12-23

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  14. Lithium Metal Oxide Electrodes For Lithium Cells And Batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-20

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  15. PEM fuel cell durability studies

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Ofstad, Axel B [Los Alamos National Laboratory; Xu, Hui [Los Alamos National Laboratory

    2008-01-01

    The durability of polymer electrolyte membrane (PEM) fuel cells is a major barrier to the commercialization for stationary and transportation power applications. For transportation applications, the durability target for fuel cell power systems is a 5,000 hour lifespan and able to function over a range of vehicle operating conditions (-40{sup o} to +40{sup o}C). However, durability is difficult to quantify and improve because of the quantity and duration of testing required, and also because the fuel cell stack contains many components, for which the degradation mechanisms, component interactions and effects of operating conditions are not fully understood. These requirements have led to the development of accelerated testing protocols for PEM fuel cells. The need for accelerated testing methodology is exemplified by the times required for standard testing to reach their required targets: automotive 5,000 hrs = {approx} 7 months; stationary systems 40,000 hrs = {approx} 4.6 years. As new materials continue to be developed, the need for relevant accelerated testing increases. In this investigation, we examine the durability of various cell components, examine the effect of transportation operating conditions (potential cycling, variable RH, shut-down/start-up, freeze/thaw) and evaluate durability by accelerated durability protocols. PEM fuel cell durability testing is performed on single cells, with tests being conducted with steady-state conditions and with dynamic conditions using power cycling to simulate a vehicle drive cycle. Component and single-cell characterization during and after testing was conducted to identify changes in material properties and related failure mechanisms. Accelerated-testing experiments were applied to further examine material degradation.

  16. Fuel Cells in Telecommunications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells in Telecommunications Fuel Cells in Telecommunications Presentation by Joe Blanchard, ReliOn, at the Technology Transition Corporation and U.S. Department of Energy...

  17. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    Characterization of Fuel-Cell Diffusion Media by HalunaFall 2011 Abstract Characterization of Fuel-Cell Diffusionpredictive capabilities. Characterization of DM and their

  18. Fuel Cell Power Plant Experience Naval Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reliable, efficient, ultra-clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC...

  19. Fuel Cell School Buses: Report to Congress

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities, Progress, and Plans: Report to Congress ii December 2008 Fuel Cell School Buses Report to Congress Fuel Cell School Buses: Report to Congress Preface This Department of...

  20. Webinar: National Fuel Cell Technology Evaluation Center

    Broader source: Energy.gov [DOE]

    Video recording and text version of the Fuel Cell Technologies Office webinar titled "National Fuel Cell Technology Evaluation Center (NFCTEC)," originally presented on March 11, 2014.

  1. Characterization of Fuel-Cell Diffusion Media

    E-Print Network [OSTI]

    Gunterman, Haluna Penelope Frances

    2011-01-01

    to take up or eject fluid. Most fuel-cell materials arethe wetting fluid. Therefore, P C for fuel-cell systems is

  2. Pacific Fuel Cell Corporation | Open Energy Information

    Open Energy Info (EERE)

    Fuel Cell Corporation Jump to: navigation, search Name: Pacific Fuel Cell Corporation Address: 26985 Lakeland Blvd. Place: Euclid, Ohio Zip: 44132 Sector: Buildings, Efficiency,...

  3. Fuel Cell Technologies Office Information Resources | Department...

    Energy Savers [EERE]

    Information Resources Fuel Cell Technologies Office Information Resources Learn about hydrogen and fuel cells, find publications and technical information, view and download...

  4. Fuel Cell Animation- Chemical Process (Text Version)

    Broader source: Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  5. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report...

  6. Hydrogen, Fuel Cells and Infrastructure Technologies Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Fuel Cells and Infrastructure Technologies Program FY2003 Merit Review and Peer Evaluation Report Hydrogen, Fuel Cells and Infrastructure Technologies Program FY2003...

  7. Fuel cell with internal flow control

    DOE Patents [OSTI]

    Haltiner, Jr., Karl J. (Fairport, NY); Venkiteswaran, Arun (Karnataka, IN)

    2012-06-12

    A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

  8. LONG-TERM PERFORMANCE OF SOLID OXIDE STACKS WITH ELECTRODE-SUPPORTED CELLS OPERATING IN THE STEAM ELECTROLYSIS MODE

    SciTech Connect (OSTI)

    J. E. O'Brien; R. C. O'Brien; X. Zhang; G. Tao; B. J. Butler

    2011-11-01

    Performance characterization and durability testing have been completed on two five-cell high-temperature electrolysis stacks constructed with advanced cell and stack technologies. The solid oxide cells incorporate a negative-electrode-supported multi-layer design with nickel-zirconia cermet negative electrodes, thin-film yttria-stabilized zirconia electrolytes, and multi-layer lanthanum ferrite-based positive electrodes. The per-cell active area is 100 cm2. The stack is internally manifolded with compliant mica-glass seals. Treated metallic interconnects with integral flow channels separate the cells. Stack compression is accomplished by means of a custom spring-loaded test fixture. Initial stack performance characterization was determined through a series of DC potential sweeps in both fuel cell and electrolysis modes of operation. Results of these sweeps indicated very good initial performance, with area-specific resistance values less than 0.5 ?.cm2. Long-term durability testing was performed with A test duration of 1000 hours. Overall performance degradation was less than 10% over the 1000-hour period. Final stack performance characterization was again determined by a series of DC potential sweeps at the same flow conditions as the initial sweeps in both electrolysis and fuel cell modes of operation. A final sweep in the fuel cell mode indicated a power density of 0.356 W/cm2, with average per-cell voltage of 0.71 V at a current of 50 A.

  9. Fuel Cell Distributed Power Package Unit: Fuel Processing Based On

    E-Print Network [OSTI]

    have been metAll milestones have been met #12;4 Autothermal Cyclic Reforming for PEM Fuel Cell CH4 + H2Fuel Cell Distributed Power Package Unit: Fuel Processing Based On Autothermal Cyclic Reforming-2000) Bread-Board Fuel Processor Development DOE (2001-3) Integrated Fuel Processor Development CEC/ARB (2002

  10. PEM fuel cell monitoring system

    DOE Patents [OSTI]

    Meltser, M.A.; Grot, S.A.

    1998-06-09

    Method and apparatus are disclosed for monitoring the performance of H{sub 2}--O{sub 2} PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H{sub 2} sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken. 2 figs.

  11. PEM fuel cell monitoring system

    DOE Patents [OSTI]

    Meltser, Mark Alexander (Pittsford, NY); Grot, Stephen Andreas (West Henrietta, NY)

    1998-01-01

    Method and apparatus for monitoring the performance of H.sub.2 --O.sub.2 PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H.sub.2 sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken.

  12. Evaluation of Stationary Fuel Cell Deployments, Costs, and Fuels (Presentation)

    SciTech Connect (OSTI)

    Ainscough, C.; Kurtz, J.; Peters, M.; Saur, G.

    2013-10-01

    This presentation summarizes NREL's technology validation of stationary fuel cell systems and presents data on number of deployments, system costs, and fuel types.

  13. Improved Electrodes and Electrolytes for Dye-Based Solar Cells

    SciTech Connect (OSTI)

    Harry R. Allcock; Thomas E. Mallouk; Mark W. Horn

    2011-10-26

    The most important factor in limiting the stability of dye-sensitized solar cells is the use of volatile liquid solvents in the electrolytes, which causes leakage during extended operation especially at elevated temperatures. This, together with the necessary complex sealing of the cells, seriously hampers the industrial-scale manufacturing and commercialization feasibilities of DSSCs. The objective of this program was to bring about a significant improvement in the performance and longevity of dye-based solar cells leading to commercialization. This had been studied in two ways first through development of low volatility solid, gel or liquid electrolytes, second through design and fabrication of TiO2 sculptured thin film electrodes.

  14. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Fronk, Matthew Howard (Honeoye Falls, NY); Borup, Rodney Lynn (East Rochester, NY); Hulett, Jay S. (Rochester, NY); Brady, Brian K. (North Chili, NY); Cunningham, Kevin M. (Romeo, MI)

    2002-01-01

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  15. Corrosion resistant PEM fuel cell

    DOE Patents [OSTI]

    Fronk, Matthew Howard (Honeoye Falls, NY); Borup, Rodney Lynn (East Rochester, NY); Hulett, Jay S. (Rochester, NY); Brady, Brian K. NY); Cunningham, Kevin M. (Romeo, MI)

    2011-06-07

    A PEM fuel cell having electrical contact elements comprising a corrosion-susceptible substrate metal coated with an electrically conductive, corrosion-resistant polymer containing a plurality of electrically conductive, corrosion-resistant filler particles. The substrate may have an oxidizable metal first layer (e.g., stainless steel) underlying the polymer coating.

  16. Combination nickel foam expanded nickel screen electrical connection supports for solid oxide fuel cells

    DOE Patents [OSTI]

    Draper, Robert; Prevish, Thomas; Bronson, Angela; George, Raymond A.

    2007-01-02

    A solid oxide fuel assembly is made, wherein rows (14, 25) of fuel cells (17, 19, 21, 27, 29, 31), each having an outer interconnection (20) and an outer electrode (32), are disposed next to each other with corrugated, electrically conducting expanded metal mesh member (22) between each row of cells, the corrugated mesh (22) having top crown portions and bottom portions, where the top crown portion (40) have a top bonded open cell nickel foam (51) which contacts outer interconnections (20) of the fuel cells, said mesh and nickel foam electrically connecting each row of fuel cells, and where there are no more metal felt connections between any fuel cells.

  17. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, Thomas C. (Berkeley, CA); McLarnon, Frank R. (Orinda, CA); Cairns, Elton J. (Walnut Creek, CA)

    1994-01-01

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.

  18. Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode

    DOE Patents [OSTI]

    Adler, T.C.; McLarnon, F.R.; Cairns, E.J.

    1994-04-12

    An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K[sub 2]CO[sub 3] salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics. 8 figures.

  19. FUEL CELL TECHNOLOGIES PROGRAM Safety, Codes, and

    E-Print Network [OSTI]

    . Many odorants can also contaminate fuel cells. Hydrogen burns very quickly. Under optimal combustionFUEL CELL TECHNOLOGIES PROGRAM Safety, Codes, and Standards Hydrogen and fuel cell technologies, nuclear, natural gas, and coal with carbon sequestration. Fuel cells provide a highly efficient means

  20. Solar-Hydrogen Fuel-Cell Vehicles

    E-Print Network [OSTI]

    DeLuchi, Mark A.; Ogden, Joan M.

    1993-01-01

    fuel cells are being developed: proton-exchange membrane (PEM), phosphoric acid, alkaline, molten carbonate

  1. 2008 FUEL CELL TECHNOLOGIES MARKET REPORT

    E-Print Network [OSTI]

    2008 FUEL CELL TECHNOLOGIES MARKET REPORT JUNE 2010 #12;2008 FUEL CELL TECHNOLOGIES MARKET REPORT i and the fuel cell industry. The authors especially wish to thank Sunita Satyapal, Nancy Garland, and the staff of the U.S. Department of Energy's Fuel Cell Technologies Program for their support and guidance

  2. MEMS-based thin-film fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2003-10-28

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  3. A microfluidic microbial fuel cell fabricated by soft lithography Fang Qian a,b,

    E-Print Network [OSTI]

    A microfluidic microbial fuel cell fabricated by soft lithography Fang Qian a,b, , Zhen He c microfluidic microbial fuel cell (MFC) platform built by soft-lithography tech- niques. The MFC design includes a unique sub-5 lL polydimethylsiloxane soft chamber featuring carbon cloth electrodes and microfluidic

  4. NREL Develops High-Speed Scanner to Monitor Fuel Cell Material Defects

    SciTech Connect (OSTI)

    2015-09-01

    This highlight describes results of recent work in which polymer electrolyte membrane fuel cell electrodes with intentionally introduced known defects were imaged and analyzed using a fuel cell scanner recently developed at NREL. The highlight is being developed for the September 2015 Alliance S&T Board meeting.

  5. Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing investigated and the dual effects of enhanced oxygen reduction reaction activity and improved ionic

  6. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of molten carbonate fuel cell (MCFC) and phosphoric acid fuel cell (PAFC) stationary fuel cell power plants. Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview...

  7. 2009 Fuel Cell Market Report, November 2010

    SciTech Connect (OSTI)

    Not Available

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  8. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  9. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  10. Membrane catalyst layer for fuel cells

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1993-01-01

    A gas reaction fuel cell incorporates a thin catalyst layer between a solid polymer electrolyte (SPE) membrane and a porous electrode backing. The catalyst layer is preferably less than about 10 .mu.m in thickness with a carbon supported platinum catalyst loading less than about 0.35 mgPt/cm.sup.2. The film is formed as an ink that is spread and cured on a film release blank. The cured film is then transferred to the SPE membrane and hot pressed into the surface to form a catalyst layer having a controlled thickness and catalyst distribution. Alternatively, the catalyst layer is formed by applying a Na.sup.+ form of a perfluorosulfonate ionomer directly to the membrane, drying the film at a high temperature, and then converting the film back to the protonated form of the ionomer. The layer has adequate gas permeability so that cell performance is not affected and has a density and particle distribution effective to optimize proton access to the catalyst and electronic continuity for electron flow from the half-cell reaction occurring at the catalyst.

  11. Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels

    E-Print Network [OSTI]

    Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

    2012-01-01

    Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

  12. Method of forming a leak proof plasma sprayed interconnection layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Kuo, Lewis J. H. (Monroeville, PA); Vora, Shailesh D. (Monroeville, PA)

    1995-01-01

    A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an electrode structure of an electrochemical cell by: (A) providing an electrode structure; (B) forming on a selected portion of the electrode surface, an interconnection layer having the general formula La.sub.1-x M.sub.x Cr.sub.1-y N.sub.y O.sub.3, where M is a dopant selected from the group of Ca, Sr, Ba, and mixtures thereof, and where N is a dopant selected from the group of Mg, Co, Ni, Al, and mixtures thereof, and where x and y are each independently about 0.075-0.25, by thermally spraying, preferably plasma arc spraying, a flux added interconnection spray powder, preferably agglomerated, the flux added powder comprising flux particles, preferably including dopant, preferably (CaO).sub.12. (Al.sub.2 O.sub.3).sub.7 flux particles including Ca and Al dopant, and LaCrO.sub.3 interconnection particles, preferably undoped LaCrO.sub.3, to form a dense and substantially gas-tight interconnection material bonded to the electrode structure by a single plasma spraying step; and, (C) heat treating the interconnection layer at from about 1200.degree. to 1350.degree. C. to further densify and heal the micro-cracks and macro-cracks of the thermally sprayed interconnection layer. The result is a substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode structure. The electrode structure can be an air electrode, and a solid electrolyte layer can be applied to the unselected portion of the air electrode, and further a fuel electrode can be applied to the solid electrolyte, to form an electrochemical cell for generation of electrical power.

  13. Method of forming a leak proof plasma sprayed interconnection layer on an electrode of an electrochemical cell

    DOE Patents [OSTI]

    Kuo, L.J.H.; Vora, S.D.

    1995-02-21

    A dense, substantially gas-tight, electrically conductive interconnection layer is formed on an electrode structure of an electrochemical cell by: (A) providing an electrode structure; (B) forming on a selected portion of the electrode surface, an interconnection layer having the general formula La{sub 1{minus}x}M{sub x}Cr{sub 1{minus}y}N{sub y}O{sub 3}, where M is a dopant selected from the group of Ca, Sr, Ba, and mixtures thereof, and where N is a dopant selected from the group of Mg, Co, Ni, Al, and mixtures thereof, and where x and y are each independently about 0.075--0.25, by thermally spraying, preferably plasma arc spraying, a flux added interconnection spray powder, preferably agglomerated, the flux added powder comprising flux particles, preferably including dopant, preferably (CaO){sub 12}(Al{sub 2}O{sub 3}){sub 7} flux particles including Ca and Al dopant, and LaCrO{sub 3} interconnection particles, preferably undoped LaCrO{sub 3}, to form a dense and substantially gas-tight interconnection material bonded to the electrode structure by a single plasma spraying step; and (C) heat treating the interconnection layer at from about 1,200 to 1,350 C to further densify and heal the micro-cracks and macro-cracks of the thermally sprayed interconnection layer. The result is a substantially gas-tight, highly doped, electrically conductive interconnection material bonded to the electrode structure. The electrode structure can be an air electrode, and a solid electrolyte layer can be applied to the unselected portion of the air electrode, and further a fuel electrode can be applied to the solid electrolyte, to form an electrochemical cell for generation of electrical power. 4 figs.

  14. 1990 fuel cell seminar: Program and abstracts

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    This volume contains author prepared short resumes of the presentations at the 1990 Fuel Cell Seminar held November 25-28, 1990 in Phoenix, Arizona. Contained herein are 134 short descriptions organized into topic areas entitled An Environmental Overview, Transportation Applications, Technology Advancements for Molten Carbonate Fuel Cells, Technology Advancements for Solid Fuel Cells, Component Technologies and Systems Analysis, Stationary Power Applications, Marine and Space Applications, Technology Advancements for Acid Type Fuel Cells, and Technology Advancement for Solid Oxide Fuel Cells.

  15. Use of Alternative Fuels in Solid Oxide Fuel Cells Fuel Cells and Solid State Chemistry Department, Ris National Laboratory, Technical

    E-Print Network [OSTI]

    Use of Alternative Fuels in Solid Oxide Fuel Cells Anke Hagen Fuel Cells and Solid State Chemistry on a variety of environmentally benign energy production technologies. Fuel cells can be a key element in this scenario. One of the fuel cells types ­ the solid oxide fuel cell (SOFC) ­ has a number of advantages

  16. Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz

    E-Print Network [OSTI]

    Gall, Daniel

    Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz as cathode electrodes in proton exchange membrane PEM fuel cells. Deposition on flat substrates yields February 4, 2010. Proton exchange membrane PEM fuel cells are promising for future automotive applications

  17. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-11-25

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into the fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  18. Water reactive hydrogen fuel cell power system

    DOE Patents [OSTI]

    Wallace, Andrew P; Melack, John M; Lefenfeld, Michael

    2014-01-21

    A water reactive hydrogen fueled power system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is converted in a fuel cell to provide electricity. The water reactive hydrogen fueled power system includes a fuel cell, a water feed tray, and a fuel cartridge to generate power for portable power electronics. The removable fuel cartridge is encompassed by the water feed tray and fuel cell. The water feed tray is refillable with water by a user. The water is then transferred from the water feed tray into a fuel cartridge to generate hydrogen for the fuel cell which then produces power for the user.

  19. Three-Dimensional Analysis of Solid Oxide Fuel Cell Ni-YSZ Anode Interconnectivity James R. Wilson,a

    E-Print Network [OSTI]

    Kalies, William D.

    of interconnectivity of solid-oxide fuel cell (SOFC) electrode phases. The method was applied to the three cell (SOFC) electrode performance have often been limited by the lack of quantitative data describing + 2e- , (1) that occurs in an SOFC anode, as an example. The H2 and H2O exist in pores, the ions

  20. Expanded nickel screen electrical connection supports for solid oxide fuel cells

    DOE Patents [OSTI]

    Draper, Robert (Pittsburgh, PA); Antol, Ronald F. (North Huntingdon, PA); Zafred, Paolo R. (Murrysville, PA)

    2002-01-01

    A solid oxide fuel assembly is made, wherein rows (14, 24) of fuel cells (16, 18, 20, 26, 28, 30), each having an outer interconnection (36) and an outer electrode (32), are disposed next to each other with corrugated, electrically conducting expanded metal mesh (22) between each row of cells, the corrugated mesh (22) having top crown portions (40) and bottom shoulder portions (42), where the top crown portion (40) contacts outer interconnections (36) of the fuel cells (16, 18, 20) in a first row (14), and the bottom shoulder portions (42) contacts outer electrodes (32) of the fuel cells in a second row (24), said mesh electrically connecting each row of fuel cells, and where there are no metal felt connections between any fuel cells.

  1. An Innovative Carbonate Fuel Cell Matrix, Abstract #188

    SciTech Connect (OSTI)

    Hilmi, Abdelkader; Surendranath, Arun; Yuh, Chao-Yi

    2015-05-28

    The electrolyte matrix in direct carbonate fuel cell (DFC) is a microporous ceramic structure sandwiched between the electrodes to isolate the fuel from the oxidant, store electrolyte and facilitate ionic transport. FCE has advanced DFC electrolyte matrix over the years and demonstrated that the matrix meets the requirements for greater than 5 year life based on accelerated tests and field stack operations. However, development of advanced designs and materials that can further increase the performance and extend cell life will enable accelerated MCFC deployment. This paper will report the progress on the development of an unique and innovative matrix design that offers numerous benefits to the carbonate fuel cell performance and durability. In addition, this paper will also review parameters that affect matrix material stability and approaches to extend cell life.

  2. Fuel cell powered irrigation system

    SciTech Connect (OSTI)

    Jacobi, E.F.; Madden, M.R.

    1982-01-12

    Set out herein is a fuel cell power plant for use with irrigation systems wherein the fuel cell is utilized to generate electric current to drive a pump motor. This pump motor drives a first water pump which receives water for distribution through a traveling irrigation system, the output of the first pump first conveyed into a condenser heat exchanger connected to a steam engine or turbine cycle. The fuel cell itself is contained within a boiler assembly and the heat of production of the electric power is used to generate steam which is sent to the steam engine. In the course of cooling the condenser gases of the steam engine the irrigating water is passed through a second pump driven by the steam engine and it is through this second pump that the pressure is raised sufficiently to allow for the necessary spraying fans. To improve the condenser efficiency part of the condensate or the ullage thereof is connected to one of the spray heads on the irrigation system in a venturi nozzle which thereby lowers the back pressure thereof. The lower portion of the condenser or the liquid part thereof is fed back through yet another condenser pump to the boiler to be regenerated into steam.

  3. Investigation of Fuel Cell System Performance and Operation: A Fuel Cell as a Practical

    E-Print Network [OSTI]

    Investigation of Fuel Cell System Performance and Operation: A Fuel Cell as a Practical Distributed of Fuel Cell System Performance and Operation: A Fuel Cell as a Practical Distributed Generator George Research Center program. This report is of work done under the PSERC project "Investigation of Fuel Cell

  4. Recent progress in tubular solid oxide fuel cell technology

    SciTech Connect (OSTI)

    Singhal, S.C.

    1997-12-31

    The tubular design of solid oxide fuel cells (SOFCs) and the materials used therein have been validated by successful, continuous electrical testing over 69,000 h of early technology cells built on a calcia-stabilized zirconia porous support tube (PST). In the latest technology cells, the PST has been eliminated and replaced by a doped lanthanum manganite air electrode tube. These air electrode supported (AES) cells have shown a power density increase of about 33% with a significantly improved performance stability over the previously used PST type cells. These cells have also demonstrated the ability to thermally cycle over 100 times without any mechanical damage or performance loss. In addition, recent changes in processes used to fabricate these cells have resulted in significant cost reduction. This paper reviews the fabrication and performance of the state-of-the-art AES tubular cells. It also describes the materials and processing studies that are underway to further reduce the cell cost, and summarizes the recently built power generation systems that employed state-of-the-art AES cells.

  5. Fuel Cells in America 2012 September 2012

    E-Print Network [OSTI]

    .S. Department of Energy's Energy Efficiency and Renewable Energy Fuel Cell Technologies Program. About & Efficiency (DSIRE). It is a follow-up to Fuel Cells 2000's 2011 and 2010 reports, State of the States: FuelFuel Cells in America 2012 State OF THE States September 2012 #12;i Authors and Acknowledgements

  6. Analysis of Fuel Cell Systems Rangan Banerjee

    E-Print Network [OSTI]

    Banerjee, Rangan

    Analysis of Fuel Cell Systems Rangan Banerjee Energy Systems Engineering IIT Bombay Lecture in CEP Course on `Fuel Cell' at IIT 14th November 2007 #12;Overview of Talk Energy Crisis ­ Motivation for fuel biological Hydrogen Gasification Fermentation Cracking + Shift Reaction Fuel Cell #12;ENERGY FLOW DIAGRAM

  7. CONTROL OF FUEL CELLS Federico Zenith

    E-Print Network [OSTI]

    Skogestad, Sigurd

    CONTROL OF FUEL CELLS Federico Zenith Department of Chemical Engineering Norwegian University of Science and Technology Trondheim, June 29, 2007 WWW.NTNU.NO FEDERICO ZENITH, CONTROL OF FUEL CELLS #12 STACK TEMPERATURE CONTROL WWW.NTNU.NO FEDERICO ZENITH, CONTROL OF FUEL CELLS #12;3 INTRODUCTION Fuel

  8. Revision Date: October 2014 Fuel Cell Inspection

    E-Print Network [OSTI]

    Chen, Zhongping

    Revision Date: October 2014 Fuel Cell Inspection INTRODUCTION Introduction: Safety concerns associated with fuel cells are generally hazardous interactions when fuel is integrated in such systems, mainly fire, explosion and electrical shock hazards. Per the 2013 California Mechanical Code, fuel cell

  9. Solid oxide fuel cell with transitioned cross-section for improved anode gas management at the open end

    DOE Patents [OSTI]

    Zafred, Paolo R. (Murrysville, PA); Draper, Robert (Pittsburgh, PA)

    2012-01-17

    A solid oxide fuel cell (400) is made having a tubular, elongated, hollow, active section (445) which has a cross-section containing an air electrode (452) a fuel electrode (454) and solid oxide electrolyte (456) between them, where the fuel cell transitions into at least one inactive section (460) with a flattened parallel sided cross-section (462, 468) each cross-section having channels (472, 474, 476) in them which smoothly communicate with each other at an interface section (458).

  10. Encouraging Industrial Demonstrations of Fuel Cell Applications 

    E-Print Network [OSTI]

    Anderson, J. M.

    1986-01-01

    INDUSTRIAL DEMONSTRATIONS OF FUEL CELL APPLICATIONS Joseph M~ Anderson, P.E. INDUSTRIAL FUEL CELL ASSOCIATION Lake Charles, Louisiana ABSTRACT Fuel Cell technology has advanced from a space-age curiosity to near commercial status within the last few... years. Both the electric and the gas utilities in the United States have conducted ambitious programs to oemonstrate the practicality of fuel cell power plants in a number of applications. The Japanese have been equally active in promoting a fuel...

  11. The Onsite Fuel Cell Cogeneration System 

    E-Print Network [OSTI]

    Woods, R. R.; Cuttica, J. J.; Trimble, K. A.

    1986-01-01

    CELL COGENERATION SYSTEM R. Root Woods, John J. Cuttica and Karen A. Trimble Gas Research Institute, Chicago, Illinois ABSTRACT This paper describes the experiences and results of the major field test of forty-six 40kW onsite fuel cell power... acid onsite fuel cell power plants, the gas industry, in cooperation with International Fuel Cells Corporation (formerly the Power Systems Division of United Technologies Corporation), has demonstrated in extensive field tests that onsite fuel cell...

  12. Fuel Cells & Alternative Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006deermckee.pdf More Documents & Publications Testing...

  13. Improving the lifetime performance of ceramic fuel cells Fuel cells generate electricity from fuels more efficiently and with

    E-Print Network [OSTI]

    Rollins, Andrew M.

    2014 Improving the lifetime performance of ceramic fuel cells Fuel cells generate electricity from fuels more efficiently and with fewer emissions per watt than burning fossil fuels. But as fuel cells received an $800,000 Department of Energy grant to study how to make one type of fuel cell--solid oxide

  14. Fuel Cell Seminar, 1992: Program and abstracts

    SciTech Connect (OSTI)

    Not Available

    1992-12-31

    This year`s theme, ``Fuel Cells: Realizing the Potential,`` focuses on progress being made toward commercial manufacture and use of fuel cell products. Fuel cell power plants are competing for market share in some applications and demonstrations of market entry power plants are proceeding for additional applications. Development activity on fuel cells for transportation is also increasing; fuel cell products have potential in energy and transportation industries, with very favorable environmental impacts. This Seminar has the purpose of fostering communication by providing a forum for the international community interested in development, application, and business opportunities related fuel cells. Over 190 technical papers are included, the majority being processed for the data base.

  15. Fuel cell stack monitoring and system control

    DOE Patents [OSTI]

    Keskula, Donald H.; Doan, Tien M.; Clingerman, Bruce J.

    2004-02-17

    A control method for monitoring a fuel cell stack in a fuel cell system in which the actual voltage and actual current from the fuel cell stack are monitored. A preestablished relationship between voltage and current over the operating range of the fuel cell is established. A variance value between the actual measured voltage and the expected voltage magnitude for a given actual measured current is calculated and compared with a predetermined allowable variance. An output is generated if the calculated variance value exceeds the predetermined variance. The predetermined voltage-current for the fuel cell is symbolized as a polarization curve at given operating conditions of the fuel cell.

  16. Electrochemical cell apparatus having axially distributed entry of a fuel-spent fuel mixture transverse to the cell lengths

    DOE Patents [OSTI]

    Reichner, Philip (Plum Borough, PA); Dollard, Walter J. (Churchill Borough, PA)

    1991-01-01

    An electrochemical apparatus (10) is made having a generator section (22) containing axially elongated electrochemical cells (16), a fresh gaseous feed fuel inlet (28), a gaseous feed oxidant inlet (30), and at least one gaseous spent fuel exit channel (46), where the spent fuel exit channel (46) passes from the generator chamber (22) to combine with the fresh feed fuel inlet (28) at a mixing apparatus (50), reformable fuel mixture channel (52) passes through the length of the generator chamber (22) and connects with the mixing apparatus (50), that channel containing entry ports (54) within the generator chamber (22), where the axis of the ports is transverse to the fuel electrode surfaces (18), where a catalytic reforming material is distributed near the reformable fuel mixture entry ports (54).

  17. A three-dimensional numerical model of a micro laminar flow fuel cell with a bridge-shaped microchannel cross-section

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    A three-dimensional numerical model of a micro laminar flow fuel cell with a bridge: Membraneless fuel cell Laminar flow fuel cell Numerical model Convection-diffusion equations Electrode kinetics equations COMSOL a b s t r a c t The operation of a laminar flow fuel cell (LFFC) involves complex interplay

  18. Low contaminant formic acid fuel for direct liquid fuel cell

    DOE Patents [OSTI]

    Masel, Richard I. (Champaign, IL); Zhu, Yimin (Urbana, IL); Kahn, Zakia (Palatine, IL); Man, Malcolm (Vancouver, CA)

    2009-11-17

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  19. In situ PEM fuel cell water measurements

    SciTech Connect (OSTI)

    Borup, Rodney L [Los Alamos National Laboratory; Mukundan, Rangachary [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendalow, Jacob S [Los Alamos National Laboratory

    2008-01-01

    Efficient PEM fuel cell performance requires effective water management. The materials used, their durability, and the operating conditions under which fuel cells run, make efficient water management within a practical fuel cell system a primary challenge in developing commercially viable systems. We present experimental measurements of water content within operating fuel cells. in response to operational conditions, including transients and freezing conditions. To help understand the effect of components and operations, we examine water transport in operating fuel cells, measure the fuel cell water in situ and model the water transport within the fuel cell. High Frequency Resistance (HFR), AC Impedance and Neutron imaging (using NIST's facilities) were used to measure water content in operating fuel cells with various conditions, including current density, relative humidity, inlet flows, flow orientation and variable GDL properties. Ice formation in freezing cells was also monitored both during operation and shut-down conditions.

  20. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    ip t Table 3 Vehicle and fuel cell system parameters (Casekg) Electric Motor (kW) Fuel Cell Stack and Auxiliaries Max.An Indirect Methanol Pem Fuel Cell System, SAE 2001, (paper

  1. Webinar: California Fuel Cell Partnership's Roadmap to the Commercialization of Hydrogen Fuel Cell Electric Vehicles

    Office of Energy Efficiency and Renewable Energy (EERE)

    Video recording of the Fuel Cell Technologies Office webinar, California Fuel Cell Partnership's Roadmap to the Commercialization of Hydrogen Fuel Cell Electric Vehicles, originally presented on October 16, 2013.

  2. Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2008-01-01

    H. Peng, Control of Fuel Cell Power Systems, Springer, 2004.May 2002, pp.3117-3122. te d M fuel cell systems for vehicleHutchenreuther, Control of a Fuel Cell Air Supply Module (

  3. Power conversion efficiency, electrode separation, and overpotential in the ferricyanide/ferrocyanide thermogalvanic cell

    SciTech Connect (OSTI)

    Mua, Y.; Quickenden, T.I. [Univ. of Western Australia, Nedlands, Western Australia (Australia). Dept. of Chemistry

    1996-08-01

    Thermogalvanic cells are electrochemical cells in which thermal energy is converted to electrical energy by maintaining the two (usually identical) electrodes at different temperatures. The effect of electrode separation on the power conversion efficiency of a ferricyanide/ferrocyanide thermogalvanic cell containing platinum electrodes was studied at electrode separations up to 150 cm, using the ``cold-above-hot`` electrode configuration. The open-circuit potential difference is almost independent of electrode separation, but the short-circuit current density falls continuously with increasing electrode separation, while the power conversion efficiency increases asymptotically to a plateau value of ca. 0.04% at a separation near 150 cm. This corresponds to an efficiency of ca. 0.6% relative to that of a Carnot engine operating between the temperatures of 293.1 and 313.1 K used in the present study. A separation of 10 cm provides efficiencies which are ca. 83% of the plateau value and is a convenient separation to use if minimal cell volume is required. The power conversion efficiency of the cell was largely limited by ohmic overpotential. Measured exchange current densities showed that activation overpotential has negligible effect on cell current. Mass transport does not limit the cell current because of the beneficial convection caused by the ``cold-above-hot`` electrode configuration.

  4. Fuel cell with interdigitated porous flow-field

    DOE Patents [OSTI]

    Wilson, Mahlon S. (Los Alamos, NM)

    1997-01-01

    A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers.

  5. Fuel cell with interdigitated porous flow-field

    DOE Patents [OSTI]

    Wilson, M.S.

    1997-06-24

    A polymer electrolyte membrane (PEM) fuel cell is formed with an improved system for distributing gaseous reactants to the membrane surface. A PEM fuel cell has an ionic transport membrane with opposed catalytic surfaces formed thereon and separates gaseous reactants that undergo reactions at the catalytic surfaces of the membrane. The fuel cell may also include a thin gas diffusion layer having first and second sides with a first side contacting at least one of the catalytic surfaces. A macroporous flow-field with interdigitated inlet and outlet reactant channels contacts the second side of the thin gas diffusion layer for distributing one of the gaseous reactants over the thin gas diffusion layer for transport to an adjacent one of the catalytic surfaces of the membrane. The porous flow field may be formed from a hydrophilic material and provides uniform support across the backside of the electrode assembly to facilitate the use of thin backing layers. 9 figs.

  6. Fuel Cell Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information Resources » Fuel CellDepartmentFuel Cell

  7. Moving toward a commercial market for hydrogen fuel cell vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Moving toward a commercial market for hydrogen fuel cell vehicles Moving toward a commercial market for hydrogen fuel cell vehicles Fuel cell vehicles and fueling stations...

  8. Optimum Performance of Direct Hydrogen Hybrid Fuel Cell Vehicles

    E-Print Network [OSTI]

    Zhao, Hengbing; Burke, Andy

    2009-01-01

    etc. , Control of Fuel Cell Power Systems, Springer, 2004. [transient power. The fuel cell power command is calculatedavoiding low fuel cell output power region. Keywords: fuel

  9. EERE Announces Notice of Intent to Issue Fuel Cell Technologies...

    Broader source: Energy.gov (indexed) [DOE]

    its Fuel Cell Technologies Office, a Funding Opportunity Announcement (FOA) entitled "Fuel Cell Technologies Incubator: Innovations in Fuel Cell and Hydrogen Fuel Technologies."...

  10. Method for fabrication of electrodes

    DOE Patents [OSTI]

    Jankowski, Alan F.; Morse, Jeffrey D.; Barksdale, Randy

    2004-06-22

    Described herein is a method to fabricate porous thin-film electrodes for fuel cells and fuel cell stacks. Furthermore, the method can be used for all fuel cell electrolyte materials which utilize a continuous electrolyte layer. An electrode layer is deposited on a porous host structure by flowing gas (for example, Argon) from the bottomside of the host structure while simultaneously depositing a conductive material onto the topside of the host structure. By controlling the gas flow rate through the pores, along with the process conditions and deposition rate of the thin-film electrode material, a film of a pre-determined thickness can be formed. Once the porous electrode is formed, a continuous electrolyte thin-film is deposited, followed by a second porous electrode to complete the fuel cell structure.

  11. Cooling assembly for fuel cells

    DOE Patents [OSTI]

    Kaufman, Arthur (West Orange, NJ); Werth, John (Princeton, NJ)

    1990-01-01

    A cooling assembly for fuel cells having a simplified construction whereby coolant is efficiently circulated through a conduit arranged in serpentine fashion in a channel within a member of such assembly. The channel is adapted to cradle a flexible, chemically inert, conformable conduit capable of manipulation into a variety of cooling patterns without crimping or otherwise restricting of coolant flow. The conduit, when assembled with the member, conforms into intimate contact with the member for good thermal conductivity. The conduit is non-corrodible and can be constructed as a single, manifold-free, continuous coolant passage means having only one inlet and one outlet.

  12. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

    2011-04-19

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  13. 2007 Fuel Cell Technologies Market Report

    SciTech Connect (OSTI)

    McMurphy, K.

    2009-07-01

    The fuel cell industry, which has experienced continued increases in sales, is an emerging clean energy industry with the potential for significant growth in the stationary, portable, and transportation sectors. Fuel cells produce electricity in a highly efficient electrochemical process from a variety of fuels with low to zero emissions. This report describes data compiled in 2008 on trends in the fuel cell industry for 2007 with some comparison to two previous years. The report begins with a discussion of worldwide trends in units shipped and financing for the fuel cell industry for 2007. It continues by focusing on the North American and U.S. markets. After providing this industry-wide overview, the report identifies trends for each of the major fuel cell applications -- stationary power, portable power, and transportation -- including data on the range of fuel cell technologies -- polymer electrolyte membrane fuel cell (PEMFC), solid oxide fuel cell (SOFC), alkaline fuel cell (AFC), molten carbonate fuel cell (MCFC), phosphoric acid fuel cell (PAFC), and direct-methanol fuel cell (DMFC) -- used for these applications.

  14. 2008 Fuel Cell Technologies Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  15. Fuel Cell Handbook - Seventh Edition (DOE FE)

    Fuel Cell Technologies Publication and Product Library (EERE)

    This handbook is a technical explanation of the science of the fuel cell. Descriptions and explanations of the many different types of fuel cells are also included. Explanations of the chemistry, phys

  16. Biogas Impurities and Cleanup for Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    Biogas Impurities and Cleanup for Fuel Cells Dennis Papadias and Shabbir Ahmed Argonne National Laboratory Presented at the Biogas and Fuel Cells Workshop Golden, CO June 11-13,...

  17. Fuel Cell Systems Annual Progress Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Efficiency and Renewable Energy Office of Transportation Technologies TRANSPORTATION FUEL CELL POWER SYSTEMS TRANSPORTATION FUEL CELL POWER SYSTEMS A C K N O W L E D G E M E N T...

  18. Fuel-cell engine stream conditioning system

    DOE Patents [OSTI]

    DuBose, Ronald Arthur (Marietta, GA)

    2002-01-01

    A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

  19. Fuel Cell Technologies Researcher Lightens Green Fuel Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information Resources » Fuel CellDepartment of

  20. Combined goal gasifier and fuel cell system and method

    DOE Patents [OSTI]

    Gmeindl, Frank D. (Morgantown, WV); Geisbrecht, Rodney A. (New Alexandria, PA)

    1990-01-01

    A molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture.