Powered by Deep Web Technologies
Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

Disclosed are a porous sintered cathode for a molten carbonate fuel cell and method of making same. The cathode includes a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell. The cathode has a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, T.D.; Mrazek, F.C.

1986-04-25T23:59:59.000Z

2

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1990-01-01T23:59:59.000Z

3

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

4

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

5

Cathode-preparation method for molten-carbonate fuel cell  

DOE Green Energy (OSTI)

A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

Smith, J.L.; Sim, J.W.; Kucera, E.H.

1982-01-28T23:59:59.000Z

6

Cathode porous transport irreversibility model for PEM fuel cell design  

Science Conference Proceedings (OSTI)

The influence is studied of slip-irreversibility at the interface between the gas diffusion layer, also referred to here as the porous transport layer, and the catalyst layer of a proton exchange membrane fuel cell (PEMFC). A two-dimensional cathode ... Keywords: catalyst layer, exergy, gas diffusion layer, slip flow irreversibility

E. O. B. Ogedengbe; M. A. Rosen

2009-02-01T23:59:59.000Z

7

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

8

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, further measurements of the oxygen deficient double perovskite PrBaCo{sub 2}O{sub 5.5+{delta}} are reported. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. Preliminary measurements in symmetric cells have shown low ASR values at 600 C. Here we describe the first complete cell measurements on Ni/CGO/CGO/PBCO/CGO cells.

Allan J. Jacobson

2006-06-30T23:59:59.000Z

9

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode--electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, the oxygen exchange kinetics of a P2 composition are described in detail. The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) have been determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells.

Allan J. Jacobson

2005-11-17T23:59:59.000Z

10

Lithium-ferrate-based cathodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at approximately 650 degrees Centigrade. These cathodes are based on lithium ferrate (LiFeO[sub 2]) which is attractive because of its very low solubility in the molten (Li,K)[sub 2]CO[sub 3] electrolyte. Because of its high resistivity, LiFeO[sub 2] cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. The effect of cation substitution on the resistivity and deformation of LiFeO[sub 2] was determined. The substitutes were chosen because their respective oxides as well as LiFeO[sub 2] crystallize with the rock-salt structure.

Lanagan, M.T.; Wolfenstine, J. [Argonne National Lab., IL (United States). Energy Technology Div.; Bloom, I.; Kaun, T.D.; Krumpelt, M. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-12-31T23:59:59.000Z

11

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Catalysts and Cathode Catalysts and Supports for PEM Fuel Cells DE-FG36-07GO17007 Mark K. Debe 3M Company Feb. 13, 2007 2007 DOE HFCIT Kick-off Meeting This presentation does not contain any proprietary or confidential information Overview Advanced Cathode Catalysts and Supports for PEM FC's - 2007 DOE HFCIT Kick-off, Feb. 13-14, 2007 2 3 Barriers A. Electrode and MEA Durability B. Stack Material & Mfg Cost C. Electrode and MEA Performance DOE Technical Targets Electrocatalyst (2010, 2015) * Durability w/cycling: hrs < 80 o C - (5000, 5000) > 80 o C - (2000, 5000) * Cost: $/kW (5,4) * Mass activity: A/mg ( 0.44, 0.44) * PGM Total, g/ kW rated: (0.3, 0.2) MEA (2010, 2015) * Cost: $/kW (10,5) * Performance: W/cm 2 at Rated Pwr. (1,1) ; 0.8V (0.25, 0.25) Budget * Total Project funding $10.43MM

12

Development of improved cathodes for solid oxide fuel cells  

DOE Green Energy (OSTI)

The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{sub 3} compositions were developed and found to be more stable than La{sub .8}Sr{sub .2}MnO{sub 3} towards reduction. Their conductivity at 1000{degrees}C ranged between 30 to 60 S/cm. Compositions within the (Y,Ca)(Cr,Co,Mn)O{sub 3} system were developed and found to have higher electrical conductivity than La{sub .8}Sr{sub .2}MnO{sub 3} and preliminary results suggest that their stability towards reduction is superior.

Anderson, H.U.

1991-03-01T23:59:59.000Z

13

NEW CATHODE MATERIALS FOR INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELLS  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and of Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} samples are reported and compared with results from previous studies. Studies of the crystallization of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are reported. Such studies are a preliminary to the combinatorial synthesis approach described in the first report.

Allan J. Jacobson

2004-05-11T23:59:59.000Z

14

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode - electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on additional compositions in the La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} series are presented in this report. Studies of the inter-diffusion of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} bilayer films prepared by pulsed laser deposition are described. Such studies are a preliminary to the combinatorial synthesis approach discussed in previous reports.

Allan J. Jacobson

2004-07-23T23:59:59.000Z

15

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

16

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

17

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study were perovskite oxides based on substituted LaFeO{sub 3} (P1 compositions), where significant data in single cell tests exist at PNNL for example, for La{sub 0.8}Sr{sub 0.2}FeO{sub 3} cathodes on both YSZ and CSO/YSZ. The materials selection was then extended to La{sub 2}NiO{sub 4} compositions (K1 compositions), and then in a longer range task we evaluated the possibility of completely unexplored group of materials that are also perovskite related, the ABM{sub 2}O{sub 5+{delta}}. A key component of the research strategy was to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. In the initial phase, we did this in parallel with the perovskite compositions that were being investigated at PNNL, in order to assess the relative importance of the intrinsic properties such as oxygen ion diffusion and surface exchange rates as predictors of performance in cell tests. We then used these measurements to select new materials for scaled up synthesis and performance evaluation in single cell tests. The results of the single cell tests than provided feedback to the materials synthesis and selection steps. In this summary, the following studies are reported: (1) Synthesis, characterization, and DC conductivity measurements of the P1 compositions La{sub 0.8}Sr{sub 0.2}FeO{sub 3-x} and La{sub 0.7}Sr{sub 0.3}FeO{sub 3-x} were completed. A combinational approach for preparing a range P1 (La,Sr)FeO{sub 3} compositions as thin films was investigated. Synthesis and heat treatment of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are described. (2) Oxygen transport properties of K1 compositions La{sub x}Pr{sub 2-x}NiO{sub 4+d} (x =2.0, 1.9, 1.2, 1.0 and 0) measured by electrical conductivity relaxation are presented in this report. Area specific resistances determined by ac impedance measurements for La{sub 2}NiO{sub 4+{delta}} and Pr{sub 2}NiO{sub 4+{delta}} on CGO are encouraging and suggest that further optimization of the electrode microstructure will enable the target to be reached. (3) The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) were determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. The first complete cell measurements were performed on Ni/CGO/CGO/PBCO/CGO cells. (4) The oxygen exchange kinetics of highly epitaxial thin films of PrBaCo{sub 2}O{sub 5.5+{delta}} (PBCO) has been determined by electrical conductivity relaxation and isotope exchange and depth profiling and confirm the high electronic conductivit

Allan J. Jacobson

2006-09-30T23:59:59.000Z

18

Cathode Improvements in Microbial Fuel Cell (MFC): from the Platinum-based Cathode to the Bio-cathode.  

E-Print Network (OSTI)

?? Microbial fuel cell is a promising technology to clean wastewater and generate environmentally-friend electricity. Microbial fuel cells (MFCs) had several problems that hindered the (more)

Santoro, Carlo

2013-01-01T23:59:59.000Z

19

MANGANESE OXIDE AS A NEW CATHODE CATALYST IN MICROBIAL FUEL CELLS (MFCs).  

E-Print Network (OSTI)

??This study focused on manganese oxides with a cryptomelane-type octahedral molecular sieve (OMS-2) structure to replace platinum as a cathode catalyst in microbial fuel cells (more)

Li, Xiang

2011-01-01T23:59:59.000Z

20

Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality  

Science Conference Proceedings (OSTI)

The effect of carbon functionality on the electrocatalytic performance of carbon black-supported, Pt-based, direct methanol fuel cell cathodes was investigated. Polarization data show that cathodes with nitrogen and sulfur functionality have enhanced catalytic activity toward oxygen reduction. Transmission electron microscopy results indicate that this behavior may be ascribed to a platinum particle size effect.

Roy, S.C.; Christensen, P.A.; Hamnett, A.; Thomas, K.M.; Trapp, V. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1996-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Quantum Mechanics Evaluation of Solid Oxide Fuel Cell Cathode ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Energy Conversion/Fuel Cells. Presentation Title, Quantum Mechanics...

22

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

2008-04-30T23:59:59.000Z

23

Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative and Durable High Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Development of Alternative and Durable High Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Performance Cathode Supports for PEM Fuel Cells PNNL: Yong Wang Conrad Zhang Vilayanur Viswanath Yuehe Lin Jun Liu Project kick Project kick - - off meeting off meeting Feb 13 Feb 13 - - 14, 2007 14, 2007 Ballard Power Systems: Stephen Campbell University of Delaware: Jingguang Chen ORNL: Sheng Dai 2 Technical Issues and Objective Technical Issues and Objective Current technical issues z Carbon support „ Susceptible to oxidation under fuel cell operating conditions. „ Oxidation further catalyzed by Pt „ Corrosion leads to Pt migration and agglomeration

24

A comparative study of PtCo/C Alloys and Pt/C as cathode catalysts for fuel cell applications.  

E-Print Network (OSTI)

??Commercialisation of fuel cells for automotive applications requires catalysts with both improved activity, particularly for the cathodic oxygen reduction reaction (ORR), and stability over commercial (more)

Burton, Sarah

2009-01-01T23:59:59.000Z

25

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes  

Science Conference Proceedings (OSTI)

Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385C for 2 h, and subsequently creep-flattened at 1350C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500C to 750C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

2010-05-08T23:59:59.000Z

26

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

DOE Green Energy (OSTI)

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

27

Quantifying the Water Content in the Cathode of Enzyme Fuel Cells via Neutron Imaging  

SciTech Connect

Neutron imaging was used to study cathode water content over time in a three-dimensional-cathode enzyme fuel cell (EFC). A porous carbon felt cathode allowed air to flow through the electrode. A solution with laccase and a mediator formed an aqueous layer on the electrode surface. Water loss was observed in situ via neutron imaging for varying experimental conditions, including flow rates of hydrogen and air, cathode inlet humidity, volume of enzyme solution, and its composition. Cathode water loss occurred for all experimental conditions, but the loss rate was noticeably reduced when a high-salt-concentration enzyme solution was used in the cathode in conjunction with increased humidity in the air feed stream. Results from neutron imaging and power density analysis were used in analyzing the causes that could contribute to EFC water loss. An increase in temperature due to the exothermic cathode reaction is considered a plausible cause of cathode water loss via evaporation. This is the first reported application of neutron imaging as a technique to study EFC water management. The results suggest that neutron imaging can be employed to provide a better understanding of EFC phenomena and thereby contribute to design and operational improvements of EFCs.

Aaron, D [Georgia Institute of Technology; Borole, Abhijeet P [ORNL; Hussey (NIST), Daniel [National Institute of Standards and Technology (NIST); Jacobson, David [National Institute of Standards and Technology (NIST); Yiacoumi, Sotira [Georgia Institute of Technology; Tsouris, Costas [ORNL

2011-01-01T23:59:59.000Z

28

Microsoft Word - Fuel Cell Cathode Report_WhiteBurke_v09 050713.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Recent Solid Oxide Fuel Cell Recent Solid Oxide Fuel Cell Cathode Studies Tools, Results, and Novel Concepts for Making Better Cells May 9, 2013 DOE/NETL-2013/1618 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process

29

Composite Cathode for High-Power Density Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Reduction of solid oxide fuel cell (SOFC) operating temperature will play a key role in reducing the stack cost by allowing the use of low-cost metallic interconnects and new approaches to sealing, while making applications such as transportation more feasible. Reported results for anode-supported SOFCs show that cathode polarization resistance is the primary barrier to achieving high power densities at operating temperatures of 700 C and lower. This project aims to identify and develop composite cathodes that could reduce SOFC operating temperatures below 700 C. This effort focuses on study and use of (La,Sr)(Co,Fe)O{sub 3} (LSCF) based composite cathodes, which have arguably the best potential to substantially improve on the currently-used, (La,Sr)MnO{sub 3}-Yttria-stabilized Zirconia. During this Phase I, it was successfully demonstrated that high performances can be achieved with LSCF/Gadolinium-Doped Ceria composite cathodes on Ni-based anode supported cells operating at 700 C or lower. We studied electrochemical reactions at LSCF/Yttria-stabilized Zirconia (YSZ) interfaces, and observed chemical reactions between LSCF and YSZ. By using ceria electrolytes or YSZ electrolytes with ceria diffusion barrier layers, the chemical reactions between LSCF and electrolytes were prevented under cathode firing conditions necessary for the optimal adhesion of the cathodes. The protection provided by ceria layer is expected to be adequate for stable long-term cathode performances, but more testing is needed to verify this. Using ceria-based barrier layers, high performance Ni-YSZ anode supported cells have been demonstrated with maximum power densities of 0.8W/cm2 at 700 C and 1.6W/cm{sup 2} at 800 C. Ni-SDC anode supported cells with SDC electrolytes yielded >1W/cm{sup 2} at 600 C. We speculate that the power output of Ni-YSZ anode supported cell at 700 C and lower, was limited by the quality of the Ceria and Ceria YSZ interface. Improvements in the low-temperature performances are expected based on further development of barrier layer fabrication processes and optimization of cathode microstructure.

Ilwon Kim; Scott Barnett; Yi Jiang; Manoj Pillai; Nikkia McDonald; Dan Gostovic; Zhongryang Zhan; Jiang Liu

2004-01-31T23:59:59.000Z

30

Continuum and Quantum-Chemical Modeling of Oxygen Reduction on the Cathode in a Solid Oxide Fuel Cell  

DOE Green Energy (OSTI)

Solid oxide fuel cells (SOFCs) have several advantages over other types of fuels cells such as high-energy efficiency and excellent fuel flexibility. To be economically competitive, however, new materials with extraordinary transport and catalytic properties must be developed to dramatically improve the performance while reducing the cost. This article reviews recent advancements in understanding oxygen reduction on various cathode materials using phenomenological and quantum chemical approaches in order to develop novel cathode materials with high catalytic activity toward oxygen reduction. We summarize a variety of results relevant to understanding the interactions between O2 and cathode materials at the molecular level as predicted using quantum-chemical cal-culations and probed using in situ surface vibrational spectroscopy. It is hoped that this in-depth understanding may provide useful insights into the design of novel cath-ode materials for a new generation of SOFCs.

Choi, Yongman; Mebane, David S.; Wang, Jeng-Han; Liu, Meilin

2009-10-08T23:59:59.000Z

31

Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Ultra-low Platinum Alloy Development of Ultra-low Platinum Alloy C th d C t l t f PEM F l C ll Cathode Catalyst for PEM Fuel Cells 2010 DOE Hydrogen Program Fuel Cell Project Kick-Off P I : Branko N Popov P. I.: Branko N. Popov Center for Electrochemical Engineering University of South Carolina Columbia SC 29208. September 28, 2010 This presentation does not contain any proprietary, confidential, or otherwise restricted information Center for Electrochemical Engineering, University of South Carolina 1 Overview Timeline * S Start d date: J June 01 2010 01 2010 * End date: Nov 30 2012 (Phase I) : May 31 2014 (Phase II) Budget * Total project funding ¾ DOE share: $ 4 400 000 ¾ DOE share: $ 4,400,000 ¾ Contractor share: $1,100,000 * Incremental funding received in FY10: $750,000

32

Final Report - Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

Science Conference Proceedings (OSTI)

The principal objectives of the program were development of a durable, low cost, high performance cathode electrode (catalyst and support), that is fully integrated into a fuel cell membrane electrode assembly with gas diffusion media, fabricated by high volume capable processes, and is able to meet or exceed the 2015 DOE targets. Work completed in this contract was an extension of the developments under three preceding cooperative agreements/grants Nos. DE-FC-02-97EE50473, DE-FC-99EE50582 and DE-FC36- 02AL67621 which investigated catalyzed membrane electrode assemblies for PEM fuel cells based on a fundamentally new, nanostructured thin film catalyst and support system, and demonstrated the feasibility for high volume manufacturability.

Mark Debe

2012-09-28T23:59:59.000Z

33

Development of improved cathodes for solid oxide fuel cells. Final report  

DOE Green Energy (OSTI)

The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{sub 3} compositions were developed and found to be more stable than La{sub .8}Sr{sub .2}MnO{sub 3} towards reduction. Their conductivity at 1000{degrees}C ranged between 30 to 60 S/cm. Compositions within the (Y,Ca)(Cr,Co,Mn)O{sub 3} system were developed and found to have higher electrical conductivity than La{sub .8}Sr{sub .2}MnO{sub 3} and preliminary results suggest that their stability towards reduction is superior.

Anderson, H.U.

1991-03-01T23:59:59.000Z

34

Final Scientific Report : Development of Transition Metal/ Chalcogen Based Cathode Catalysts for PEM Fuel Cells  

DOE Green Energy (OSTI)

The aim of this project was to investigate the potential for using base metal sulfides and selenides as low cost replacements for precious metal catalysts, such as platinum, currently being used in PEM fuel cells. The approach was to deposit thin films of the materials to be evaluated onto inert electrodes and evaluate their activity for the cathode reaction (oxygen reduction) as well as ex-situ structural and compositional characterization. The most active materials identified are CoS2 and the 50:50 solid solution (Co,Ni)S2. However, the OCP of these materials is still considered too low, at 0.83V and 0.89V vs. RHE respectively, for testing in fuel cells. The methods employed here were necessary to compare with the activity of platinum as, when nano-dispersed on carbon supports, the active surface area of these materials is difficult to measure, making comparisons inaccurate. This research adds to the knowledge of potential candidates for platinum replacement in order to reduce the cost of PEM fuel cell technology and promote commercialization. Although the fabrication methods employed here are strictly experimental, methods were also developed to produce nano-dispersed catalysts with similar compositions, structure and activity. Cycling of these catalysts to highly oxidizing potentials resulted in an increase of the open circuit voltage to approach that of platinum, however, it proved difficult to determine why using these dispersed materials. The potential for non-precious, non-metallic, low cost, compound catalysts for PEM fuel cells has been investigated and demonstrated.

Campbell, Stephen, A.

2008-02-29T23:59:59.000Z

35

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Two approaches have been adopted to get a stable cathode material. First approach is the use of LiNi{sub 0.8}Co{sub 0.2}O{sub 2}, a commercially available lithium battery cathode material and the second is the use of tape cast electrodes prepared from cobalt coated nickel powders. The morphology and the structure of LiNi{sub 0.8}Co{sub 0.2}O{sub 2} and tape cast Co coated nickel powder electrodes were studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance of the two materials was investigated by electrochemical impedance spectroscopy and polarization studies. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. The model gives a good fit to the experimental data. The model has been used to analyze MCFC cathode performance under a wide range of operating conditions.

Dr. Ralph E. White; Dr. Branko N. Popov

2002-04-01T23:59:59.000Z

36

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

This project focused on addressing the two main problems associated with state of art Molten Carbonate Fuel Cells, namely loss of cathode active material and stainless steel current collector deterioration due to corrosion. We followed a dual approach where in the first case we developed novel materials to replace the cathode and current collector currently used in molten carbonate fuel cells. In the second case we improved the performance of conventional cathode and current collectors through surface modification. States of art NiO cathode in MCFC undergo dissolution in the cathode melt thereby limiting the lifetime of the cell. To prevent this we deposited cobalt using an electroless deposition process. We also coated perovskite (La{sub 0.8}Sr{sub 0.2}CoO{sub 3}) in NiO thorough a sol-gel process. The electrochemical oxidation behavior of Co and perovskites coated electrodes is similar to that of the bare NiO cathode. Co and perovskite coatings on the surface decrease the dissolution of Ni into the melt and thereby stabilize the cathode. Both, cobalt and provskites coated nickel oxide, show a higher polarization compared to that of nickel oxide, which could be due to the reduced surface area. Cobalt substituted lithium nickel oxide (LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) and lithium cobalt oxide were also studied. LiNi{sub x}Co{sub 1-x}O{sub 2} was synthesized by solid-state reaction procedure using lithium nitrate, nickel hydroxide and cobalt oxalate precursor. LiNi{sub x}Co{sub 1-x}O{sub 2} showed smaller dissolution of nickel than state of art nickel oxide cathode. The performance was comparable to that of nickel oxide. The corrosion of the current collector in the cathode side was also studied. The corrosion characteristics of both SS304 and SS304 coated with Co-Ni alloy were studied. This study confirms that surface modification of SS304 leads to the formation of complex scales with better barrier properties and better electronic conductivity at 650 C. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode and the complete fuel cell. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. This approach can be used to model porous electrodes as it represents the real system much better than the conventional agglomerate model. Using the homogeneous model the polarization characteristics of the MCFC cathode and fuel cell were studied under different operating conditions. Both the cathode and the full cell model give good fits to the experimental data.

Hector Colonmer; Prabhu Ganesan; Nalini Subramanian; Dr. Bala Haran; Dr. Ralph E. White; Dr. Branko N. Popov

2002-09-01T23:59:59.000Z

37

Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells  

Science Conference Proceedings (OSTI)

A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

2011-06-01T23:59:59.000Z

38

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

39

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Lithium cobalt oxide coating onto the porous nickel electrode has been adopted to modify the conventional MCFC cathode which is believed to increase the stability of the cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. Lithium Cobalt oxide was coated on Ni cathode by a sol-gel coating. The morphology and the LiCoO{sub 2} formation of LiCoO{sub 2} coated NiO was studied using scanning electron microscopy and X-Ray diffraction studies respectively. The electrochemical performance lithium cobalt oxide coated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. Dissolution of nickel into the molten carbonate melt was less in case of lithium cobalt oxide coated nickel cathodes. LiCoO{sub 2} coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, lithium cobalt oxide coated nickel shows similar polarization characteristics as nickel oxide. Conventional theoretical models for the molten carbonate fuel cell cathode are based on the thin film agglomerate model. The principal deficiency of the agglomerate model, apart from the simplified pore structure assumed, is the lack of measured values for film thickness and agglomerate radius. Both these parameters cannot be estimated appropriately. Attempts to estimate the thickness of the film vary by two orders of magnitude. To avoid these problems a new three phase homogeneous model has been developed using the volume averaging technique. The model considers the potential and current variation in both liquid and solid phases. Using this approach, volume averaged concentrations of both gaseous and liquid phase reactants are obtained separately. The polarization characteristics of the electrode have been studied for different electrode parameters. The effect of different design parameters on the electrode performance has also been analyzed. Finally, the model has been used to analyze the impedance response of the MCFC cathode.

Dr. Ralph E. White; Dr. Branko N. Popov

2001-10-01T23:59:59.000Z

40

Resistivity of bipolar plate materials at the cathode interface in molten carbonate fuel cells.  

DOE Green Energy (OSTI)

Measurements of oxide scale resistivity for prospective bipolar plate materials in the molten carbonate fuel cell (MCFC) are coupled with observations of microstructural/compositional change over time. This work searches for a compromise to the high corrosion rate of Type 316L and the high oxide scale resistance of Type 310S. We tested a group of materials having chromium content ranging from 16 to 31 wt%, including Nitronic 50 and NKK, a Ni-Cr-Fe alloy. Chromium content was found to be the primary determinant of oxide scale composition. In the MCFC cathode compartment, stainless steels generally formed a duplex structure with an inner Cr-rich layer and an outer, Fe-rich layer. The composition of the inner Cr-rich layer was related to the base alloy and had a controlling effect on scale resistivity. Oxide scale resistivity was measured for two electrolyte compositions: Li/K and Li/Na carbonates. Changes in the physical/mechanical properties (spallation/cracking) in the oxide scale of Type 316L provided an understanding of its resistivity fluctuations over time.

Kaun, T. D.

1998-11-18T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

OPTIMIZATION OF THE CATHODE LONG TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The cathode materials for molten carbonate fuel cells (MCFCs) must have low dissolution rate, high structural strength and good electrical conductivity. Currently available cathodes are made of lithiated NiO which have acceptable structural strength and conductivity. However a study carried out by Orfeld et al. and Shores et al. indicated that the nickel cathodes dissolved, then precipitated and reformed as dendrites across the electrolyte matrix. This results in a decrease in cell utilization and eventually leads to shorting of the cell. The solubility of NiO was found to depend upon the acidity/basicity of the melt (basicity is directly proportional to log P{sub CO2}), carbonate composition, H{sub 2}O partial pressure and temperature. Urushibata et al. found that the dissolution of the cathode is a primary life limiting constraint of MCFCs, particularly in pressurized operation. With currently available NiO cathodes, the goal of 40,000 hours for the lifetime of MCFC appears achievable with cell operation at atmospheric pressure. However, the cell life at 10 atm and higher cell pressures is in the range between 5,000 to 10,000 hours. The overall objective of this research is to develop a superior cathode for MCFC's with improved catalytic ability, enhanced corrosion resistance with low ohmic losses, improved electronic conductivity. We also plan to understand the corrosion processes occurring at the cathode/molten carbonate interface. The following cathode materials will be subjected to detailed electrochemical, performance, structural and corrosion studies. (i) Passivated NiO alloys using chemical treatment with yttrium ion implantation and anodic yttrium molybdate treatment; (ii) Novel composite materials based on NiO and nanosized Ce, Yt, Mo; (iii) Co doped LiNiO{sub 2} LiNiO{sub 2} doped with 10 to 20% Co (LiCo{sub 0.2}NiO{sub 2}) and NiO cathodes; and (iv) CoO as a replacement for NiO. Passivation treatments will inhibit corrosion and increase the stability of the cathode at high temperatures. Deposition of refractory metals (Mo, W, Li{sub 2}NiCrO{sub 4}) will impart stability to the cathode at high temperatures. Further it will also increase the electrocatalytic activity and corrosion resistance of the cathode. Doping with Co will decrease the alloy dissolution and increase the cycle life of the cathode. In the reporting period the oxidation behavior of Ni and Co in Li + Na carbonate eutectic was investigated under oxidizing environment using cyclic voltammetry, electrochemical impedance spectroscopy and potentiodynamic technique. The open circuit potential was monitored as a function of time in order to evaluate the material's reactivity in the melt.

Anand Durairajan; Bala Haran; Branko N. Popov; Ralph E. White

2000-05-01T23:59:59.000Z

42

Evaluation of Cathode Materials for Low Temperature (500-700C) Solid Oxide Fuel Cells.  

E-Print Network (OSTI)

?? Solid oxide fuel cells (SOFC) have gained a great deal of interest, due to their potential for high efficiency power generation and ability to (more)

Lassman, Alexander M

2011-01-01T23:59:59.000Z

43

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells. I. Cross Validation of Polarization Measurements by Impedance Spectroscopy and Current-Potential Sweep  

DOE Green Energy (OSTI)

The aim of this paper is to address three issues in solid oxide fuel cells: (1) cross-validation of the polarization of a single cell measured using both dc and ac approaches, (2) the precise determination of the total areal specific resistance (ASR), and (3) understanding cathode polarization with LSCF cathodes. The ASR of a solid oxide fuel cell is a dynamic property, meaning that it changes with current density. The ASR measured using ac impedance spectroscopy (low frequency interception with real Z axis of ac impedance spectrum) matches with that measured from a dc IV sweep (the tangent of dc i-V curve). Due to the dynamic nature of ASR, we found that an ac impedance spectrum measured under open circuit voltage or on a half cell may not represent cathode performance under real operating conditions, particularly at high current density. In this work, the electrode polarization was governed by the cathode activation polarization; the anode contribution was negligible.

Zhou, Xiao Dong; Pederson, Larry R.; Templeton, Jared W.; Stevenson, Jeffry W.

2009-12-09T23:59:59.000Z

44

Hydrogen & Fuel Cells - Fuel Cell - Solid Oxide  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrolyzer Research and Development Solid Oxide Fuel Cells Solid oxide diagram In an SOFC, oxygen from air is reduced to ions at the cathode, which diffuse through the...

45

Soft X-Ray Spectroscopic Study of Dense Strontium-Doped Lanthanum Manganite Cathodes for Solid Oxide Fuel Cell Applications  

Science Conference Proceedings (OSTI)

The evolution of the Mn charge state, chemical composition, and electronic structure of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSMO) cathodes during the catalytic activation of solid oxide fuel cell (SOFC) has been studies using X-ray spectroscopy of as-processed, exposed, and activated dense thin LSMO films. Comparison of O K-edge and Mn L{sub 3,2}-edge X-ray absorption spectra from the different stages of LSMO cathodes revealed that the largest change after the activation occurred in the Mn charge state with little change in the oxygen environment. Core-level X-ray photoemission spectroscopy and Mn L{sub 3} resonant photoemission spectroscopy studies of exposed and as-processed LSMO determined that the SOFC environment (800 C ambient pressure of O{sub 2}) alone results in La deficiency (severest near the surface with Sr doping >0.55) and a stronger Mn{sup 4+} contribution, leading to the increased insulating character of the cathode prior to activation. Meanwhile, O K-edge X-ray absorption measurements support Sr/La enrichment nearer the surface, along with the formation of mixed Sr{sub x}Mn{sub y}O{sub z} and/or passive MnO{sub x} and SrO species.

L Piper; A Preston; S Cho; A DeMasi; J Laverock; K Smith; L Miara; J Davis; S Basu; et al.

2011-12-31T23:59:59.000Z

46

Mechanical and electrochemical performance of composite cathode contact materials for solid oxide fuel cells  

Science Conference Proceedings (OSTI)

The feasibility of adding glass or inorganic binder to conventional SOFC cathode contact materials (CCM) in order to improve bonding to adjacent materials in the cell stack is assessed. Two glasses (SEM-COM SCZ-8 and Schott GM31107) and one inorganic binder (Aremco 644A) are mixed with LSM particles to produce composite CCM pastes. These are used to bond Mn1.5Co1.5O4-coated stainless steel mesh current collectors to anode-supported button cells. The cells are operated at 800 C for about 1000 h. The cell with SCZ-8 addition to the CCM displays quite stable operation (3.9%/1000 h degradation), whereas the other additives lead to somewhat higher degradation rate. Bonding of the CCM to coated stainless steel coupons is also assessed. Interfacial fracture toughness is determined using a four-point bend test. The fracture toughness for LSM Schott glass (12.3 N mm 1), LSM SCZ-8 glass (6.8 N mm 1) and LSM 644A binder (5.4 N mm 1) are significantly improved relative to pure LSM (1.7 N mm 1). Indeed, addition of binder or glass is found to improve bonding of the CCM layer without sacrificing cell performance.

Tucker, Michael C. [Lawrence Berkeley National Laboratory (LBNL); Dejonghe, Lutgard C. [Lawrence Berkeley National Laboratory (LBNL); Garcia-Negron, Valerie [Material Science and Technology Division, Oak Ridge National Laboratory; Trejo, Rosa M [ORNL; Lara-Curzio, Edgar [ORNL

2013-01-01T23:59:59.000Z

47

Development of Ultra-Low Platinum Alloy Cathode Catalyst for PEM Fuel Cells - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Branko N. Popov University of South Carolina (USC) 301 Main Street Columbia, SC 29208 Phone: (803) 777-7314 Email: popov@cec.sc.edu DOE Managers HQ: Donna Lee Ho Phone: (202) 586-8000 Email: Donna.Ho@ee.doe.gov GO: David Peterson Phone: (720) 356-1747 Email: David.Peterson@go.doe.gov Technical Advisor Thomas Benjamin Phone: (630) 252-1632 Email: benjamin@anl.gov Contract Number: DE-EE0000460 Subcontractor: Dr. Hansung Kim (Co-PI) Yonsei University, S. Korea. Project Start Date: September 1, 2010 Project End Date: May 31, 2014 Objectives Develop low-cost and durable hybrid cathode catalyst * (HCC). Develop Pt alloy/activated graphitic carbon catalyst. * Develop corrosion resistant supports. *

48

Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes  

Science Conference Proceedings (OSTI)

Platinum monolayers can act as shells for palladium nanoparticles to lead to electrocatalysts with high activities and an ultralow platinum content, but high platinum utilization. The stability derives from the core protecting the shell from dissolution. In fuel-cell tests, no loss of platinum was observed in 200,000 potential cycles, whereas loss of palladium was significant.

K Sasaki; H Naohara; Y Cai; Y Choi; P Liu; M Vukmirovic; J Wang; R Adzic

2011-12-31T23:59:59.000Z

49

Exploratory fuel-cell research: I. Direct-hydrocarbon polymer-electrolyte fuel cell. II. Mathematical modeling of fuel-cell cathodes  

DOE Green Energy (OSTI)

A strong need exists today for more efficient energy-conversion systems. Our reliance on limited fuel resources, such as petroleum for the majority of our energy needs makes it imperative that we utilize these resources as efficiently as possible. Higher-efficiency energy conversion also means less pollution, since less fuel is consumed and less exhaust created for the same energy output. Additionally, for many industrialized nations, such as the United States which must rely on petroleum imports, it is also imperative from a national-security standpoint to reduce the consumption of these precious resources. A substantial reduction of U.S. oil imports would result in a significant reduction of our trade deficit, as well as costly military spending to protect overseas petroleum resources. Therefore, energy-conversion devices which may utilize alternative fuels are also in strong demand. This paper describes research on fuel cells for transportation.

Perry, M.L.; McLarnon, F.R.; Newman, J.S.; Cairns, E.J.

1996-12-01T23:59:59.000Z

50

Electrical Contacts between Cathodes and Metallic Interconnects in Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

To minimize electrical resistance, contact layers are often included between interconnects and electrodes during construction of a SOFC stack. In this work, simulated cathode/interconnect structures were used to investigate the effects of different contact materials on the contact resistance between a LSF cathode and a Crofer22 APU interconnect.. The results from the resistance measurements are reported and correlated to interfacial interactions occurring between the metallic interconnect and the contact materials, particularly perovskites. The materials requirements for the contact layers between cathodes and metallic interconnects in intermediate temperature SOFCs are also discussed.

Yang, Z Gary; Xia, Gordon; Singh, Prabhakar; Stevenson, Jeffry W.

2006-04-21T23:59:59.000Z

51

Fuel cell with internal flow control  

SciTech Connect

A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

Haltiner, Jr., Karl J. (Fairport, NY); Venkiteswaran, Arun (Karnataka, IN)

2012-06-12T23:59:59.000Z

52

Methanol-tolerant cathode catalyst composite for direct methanol fuel cells  

oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the ...

53

Effect of Cathode Pore Volume on PEM Fuel Cell Cold Start Ashis Nandy,a  

E-Print Network (OSTI)

of the intraelectrode ice formation theory,5 which explains ice formation in the cathode catalyst layer CCL as the key with resulting tem- perature rise and water production or ice formation in the CCL. Ice formation in the CCL mainly through back-diffusion into the membrane and through vapor-phase transport from CCL

54

The Orientation Distributions of Lines, Surfaces, and Interfaces Around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes  

Science Conference Proceedings (OSTI)

Three-dimensional electron backscatter diffraction was used to measure the crystallographic distribution of the electrochemically relevant triple phase boundary lines and surfaces near them in SOFC cathodes made up of a porous mixture of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild electrochemical loading. All distributions were observed to be nearly isotropic, but non-random textures above the detection threshold were observed. The distributions differ between the two cells, as do the phase fractions and the electrochemical history. The different distributions are interpreted as evidence that steady-state distributions vary locally with phase fractions or that they evolve during the initial operation of the fuel cell. The rates at which triple lines, pore surfaces, and interface boundaries in the porous mixture approach a steady-state value appear to decrease with the average amount of mass transport required to reorient that specific feature. This work provides initial insights into the crystallography of interfaces in a multiphase ceramic material.

Dillon, Shen; Helmick, Lam; Miller, Herbert M.; Johnson, Christopher; Wilson, Lane; Gemmen, Randall; Petrova, Rumyana; Barmak, Katayun; Gerdes, Kirk; Rohrer, Gregory S.; Salvador, Paul A.

2011-11-01T23:59:59.000Z

55

Fuel cell system combustor  

DOE Patents (OSTI)

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode and cathode effluents. The combustor includes a turbulator section at its input end for intimately mixing the anode and cathode effluents before they contact the combustors primary catalyst bed. The turbulator comprises at least one porous bed of mixing media that provides a tortuous path therethrough for creating turbulent flow and intimate mixing of the anode and cathode effluents therein.

Pettit, William Henry (Rochester, NY)

2001-01-01T23:59:59.000Z

56

Micro fuel cell  

SciTech Connect

An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

1998-12-31T23:59:59.000Z

57

How Fuel Cells Work  

NLE Websites -- All DOE Office Websites (Extended Search)

How Fuel Cells Work How Fuel Cells Work Diagram: How a PEM fuel cell works. 1. Hydrogen fuel is channeled through field flow plates to the anode on one side of the fuel cell, while oxygen from the air is channeled to the cathode on the other side of the cell. 2. At the anode, a platinum catalyst causes the hydrogen to split into positive hydrogen ions (protons) and negatively charged electrons. 3. The Polymer Electrolyte Membrane (PEM) allows only the positively charged ions to pass through it to the cathode. The negatively charged electrons must travel along an external circuit to the cathode, creating an electrical current. 4. At the cathode, the electrons and positively charged hydrogen ions combine with oxygen to form water, which flows out of the cell.

58

Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials  

Science Conference Proceedings (OSTI)

Commonly, SOFCs are operated at high temperatures (above 800C). At these temperatures expensive housing is needed to contain an operating stack as well as coatings to contain the oxidation of the metallic interconnects. Lowering the temperature of an operating device would allow for more conventional materials to be used, thus lowering overall cost. Understanding the surface chemical states of cations in the surface of the SOFC cathode is vital to designing a system that will perform well at lower temperatures. The samples studied were grown by pulsed laser deposition (PLD) at the Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory (PNNL). 20% strontium doped lanthanum manganite (LSM-20) was grown on YSZ and NGO (neodymium gallate). The films on YSZ have a fiber texture. LSM-20 on NGO is heteroepitaxial. Lanthanum strontium cobalt ferrite (LSCF-6428) films were grown on LAO and YSZ with a GDC barrier layer. Total X-ray Reflection Fluorescence (TXRF) was used to depth profile the samples. In a typical experiment, the angle of the incident beam is varied though the critical angle. Below the critical angle, the x-ray decays as an evanescent wave and will only penetrate the top few nanometers. TXRF experiments done on LSM films have suggested strontium segregates to the surface and form strontium enriched nanoparticles (1). It should be pointed out that past studies have focused on 30% strontium A-site doping, but this project uses 20% strontium doped lanthanum manganite. XANES and EXAFS data were taken as a function of incoming angle to probe composition as a function of depth. XANES spectra can be difficult to analyze fully. For other materials density functional theory calculations compared to near edge measurements have been a good way to understand the 3d valence electrons (2).

Davis, Jacob N.; Miara, Lincoln J.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Gopalan, Srikanth; Pal, Uday B.; Woicik, Joseph C.; Basu, Soumendra N.; Ludwig, Karl F.

2012-12-01T23:59:59.000Z

59

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

DOE Green Energy (OSTI)

This report summarizes the work done during the fifth quarter of the project. Effort was directed in two areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge region. (2) Fabrication of porous samaria-doped ceria (SDC) and investigation of the effect of thermal treatment on its conductivity. The model developed accounts for transport through three regions: (a) Transport through the bulk of the grain, RI, which includes parallel transport through space charge region. (b) Transport through the space charge region adjacent to the neck (grain boundary), RII. (c) Transport through the structural part of the neck (grain boundary), RIII. The work on the model development involves calculation RI, RII, RIII, and the sum of these three terms, which is the total resistance, as a function of the grain radius ranging between 0.5 and 5 microns and as a function of the relative neck size, described in terms of the angle theta, ranging between 5 and 45{sup o}. Three values of resistivity of the space charge region were chosen; space charge resistivity greater than grain resistivity, equal to grain resistivity, and lower than grain resistivity. Experimental work was conducted on samaria (Sm{sub 2}O{sub 3})-doped ceria (SDC) samples of differing porosity levels, before and after thermal treatment at 1200 C. The conductivity in the annealed samples was lower, consistent with enhanced Debye length. This shows the important role of space charge on ionic transport, and its implications concerning cathode polarization.

Anil V. Virkar

2004-03-08T23:59:59.000Z

60

Microsoft Word - Fuel Cell Cathode Report_WhiteBurke_v09 050713...  

NLE Websites -- All DOE Office Websites (Extended Search)

Studies Tools, Results, and Novel Concepts for Making Better Cells May 9, 2013 DOENETL-20131618 Disclaimer This report was prepared as an account of work sponsored by an agency...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

REACTIVE FORCE FIELDS FOR Y-DOPED BaZrO3 ELECTROLYTE AND NI-ANODE. POTENTIAL CATHODE MATERIALS FOR APPLICATION IN PROTON CERAMIC FUEL CELLS  

DOE Green Energy (OSTI)

Based on quantum mechanical data obtained for the Y-doped BaZrO{sub 3} electrolyte and Ni-anode Reactive Force Field parameters have been developed for further molecular dynamics simulations of the proton diffusion and electrode/electrolyte interfaces. Electronic and atomic structures of different terminations of the (001) BaZrO{sub 3} surface have been studied using first-principles calculations. Several potential cathode materials for the Y-doped BaZrO{sub 3} system were synthesized via glycine nitrate combustion method. Of the five potential cathode materials examined BaZr{sub 0.40}Pr{sub 0.40}Gd{sub 0.20}O{sub 3} and BaZr{sub 0.60}Y{sub 0.20}Co{sub 0.20}O{sub 3} appear to be the most promising for further applications in proton ceramic fuel cells. Fuel cell test of a Y-doped BaZrO{sub 3} thin film using platinum ink for both electrodes have been performed. The obtained results shows that a robust method for fabricating crack-free thin membranes, as well as methods for sealing anode and cathode chambers, have successfully been developed.

Boris Merinov; Adri van Duin; Sossina Haile; William A. Goddard III

2004-10-30T23:59:59.000Z

62

Overcoming phase instability of RBaCo2O5+ (R = Y and Ho) by Sr substitution for application as cathodes in solid oxide fuel cells  

Science Conference Proceedings (OSTI)

Phase instabilities of the RBaCo2O5+ (R = Y and Ho) layered-perovskites and their decompositions into RCoO3 and BaCoO3-z at 800 oC in air were investigated. This will restrict their high temperature applications such as cathodes in solid oxide fuel cell (SOFC). However, appropriate amount of Sr substitution ( 60 % for R = Y and 70 % for R = Ho) for Ba successfully stabilized the R(Ba1-xSrx)Co2O5+ phase at elevated temperatures. This can be explained by decreasing oxygen vacancies at R-O layer, decreasing R-O bonding length, and consequent improvement of structural integrity. In addition, the Sr substitution (x = 0.6 - 1.0) for Ba provided added benefit with respect to the chemical stability against Ce0.8Gd0.2O1.9 (GDC) electrolyte, which is a critical requirement for the cathodes in SOFC. Among the various compositions investigated, the Y(Ba0.3Sr0.7)Co2O5+ + GDC composite cathode delivered the optimum electrochemical performances with a stable phase demonstrating the potential as a cathode in SOFC.

Kim, Jung-Hyun [ORNL; Young Nam, Kim [University of Texas at Austin; Bi, Zhonghe [ORNL; Manthiram, Arumugam [University of Texas at Austin; Paranthaman, Mariappan Parans [ORNL; Huq, Ashfia [ORNL

2013-01-01T23:59:59.000Z

63

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol...  

NLE Websites -- All DOE Office Websites (Extended Search)

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells A direct methanol fuel cell...

64

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium and a mixture of uranium and plutonium for use as a fresh blanket and core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped cathode is disposed about the outer anodic dissolution baskets. Uranium is deposited from the anode baskets in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium collection efficiency enhanced by increasing the electrode area and reducing the anode-cathode spacing for enhanced trapping and recovery of uranium dendrites scraped off of the cylindrical cathodes which may be greater in number than two.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1995-12-31T23:59:59.000Z

65

(Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells  

Science Conference Proceedings (OSTI)

(Y0.5In0.5)BaCo4-xZnxO7 (1.0 x 2.0) oxides crystallizing in a trigonal P31c structure have been synthesized and explored as cathode materials for solid oxide fuel cells (SOFC). At a given Zn content, the (Y0.5In0.5)BaCo4-xZnxO7 sample with 50 % Y and 50 % In exhibits much improved phase stability at intermediate temperatures (600 - 800 oC) compared to the samples with 100 % Y or In. However, the substitution of Zn for Co in (Y0.5In0.5)Ba(Co4-xZnx)O7 (1.0 x 2.0) decreases the amount of oxygen loss on heating, total electrical conductivity, and cathode performance in SOFC while providing good long-term phase stability at high temperatures. Among the various chemical compositions investigated in the (Y0.5In0.5)Ba(Co4-xZnx)O7 system, the (Y0.5In0.5)BaCo3ZnO7 sample offers a combination of good electrochemical performance and low thermal expansion coefficient (TEC) while maintaining superior phase stability at 600 800 oC for 100 h. Fuel cell performances of the (Y0.5In0.5)Ba(Co3Zn)O7 + Ce0.8Gd0.2O1.9 (GDC) (50 : 50 wt. %) composite cathodes collected with anode-supported single cell reveal a maximum power density value of 521 mW cm-2 at 700 oC.

Young Nam, Kim [University of Texas, Austin; Kim, Jung-Hyun [ORNL; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas, Austin; Huq, Ashfia [ORNL

2012-01-01T23:59:59.000Z

66

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network (OSTI)

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and Technology of Ceramic Fuel Cells, p. 209, Elsevier, NewI. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

67

Dry Barrier Mix in Reduction Cell Cathodes  

Science Conference Proceedings (OSTI)

Presentation Title, Dry Barrier Mix in Reduction Cell Cathodes ... successfully tested as a replacement for barrier bricks in several reduction cell technology types...

68

Corrosion free phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell with an electrolyte fuel system which supplies electrolyte via a wick disposed adjacent a cathode to an absorbent matrix which transports the electrolyte to portions of the cathode and an anode which overlaps the cathode on all sides to prevent corrosion within the cell.

Wright, Maynard K. (Bethel Park, PA)

1990-01-01T23:59:59.000Z

69

Cathode Connector For Aluminum Low Temperature Smelting Cell  

DOE Patents (OSTI)

Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2003-07-16T23:59:59.000Z

70

Chalcogen catalysts for polymer electrolyte fuel cell  

DOE Patents (OSTI)

A methanol-tolerant cathode catalyst and a membrane electrode assembly for fuel cells that includes such a cathode catalyst. The cathode catalyst includes a support having at least one transition metal in elemental form and a chalcogen disposed on the support. Methods of making the cathode catalyst and membrane electrode assembly are also described.

Zelenay, Piotr (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Alonso-Vante, Nicolas (France, FR); Wieckowski, Andrzej (Champaign, IL); Cao, Dianxue (Urbana, IL)

2010-08-24T23:59:59.000Z

71

Fuel cell gas management system  

SciTech Connect

A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

DuBose, Ronald Arthur (Marietta, GA)

2000-01-11T23:59:59.000Z

72

Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes  

E-Print Network (OSTI)

Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated Pt[subscript 3]Co catalyst particles in a H[subscript ...

Chen, Shuo

73

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Nenad M. Markovic (Primary Contact) and Vojislav R. Stamenkovic Argonne National Laboratory (ANL) Argonne, IL 60439 Phone: (630) 252-5181 Email: nmmarkovic@anl.gov DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Subcontractors: * Karren More, Oak Ridge National Laboratory, Oak Ridge, TN * Charles Hays, Jet Propulsion Laboratory, Pasadena, CA * Shuoheng Sun, Brown University, Providence, RI * Guofeng Wang, University of Pittsburgh, Pittsburgh, PA * Radoslav Atanasoski, 3M Company, Saint Paul, MN

74

Fuel cell generator with fuel electrodes that control on-cell fuel reformation  

Science Conference Proceedings (OSTI)

A fuel cell for a fuel cell generator including a housing including a gas flow path for receiving a fuel from a fuel source and directing the fuel across the fuel cell. The fuel cell includes an elongate member including opposing first and second ends and defining an interior cathode portion and an exterior anode portion. The interior cathode portion includes an electrode in contact with an oxidant flow path. The exterior anode portion includes an electrode in contact with the fuel in the gas flow path. The anode portion includes a catalyst material for effecting fuel reformation along the fuel cell between the opposing ends. A fuel reformation control layer is applied over the catalyst material for reducing a rate of fuel reformation on the fuel cell. The control layer effects a variable reformation rate along the length of the fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA); Zhang, Gong (Murrysville, PA)

2011-10-25T23:59:59.000Z

75

Microstructure Design of Solid Oxide Fuel Cell  

Science Conference Proceedings (OSTI)

The porous heterogeneous cathode microstructure of solid Oxide fuel cells ... Computer Simulations of Realistic Multi-Phase Three-Dimensional Microstructures.

76

Compact fuel cell  

DOE Patents (OSTI)

A novel electrochemical cell which may be a solid oxide fuel cell (SOFC) is disclosed where the cathodes (144, 140) may be exposed to the air and open to the ambient atmosphere without further housing. Current collector (145) extends through a first cathode on one side of a unit and over the unit through the cathode on the other side of the unit and is in electrical contact via lead (146) with housing unit (122 and 124). Electrical insulator (170) prevents electrical contact between two units. Fuel inlet manifold (134) allows fuel to communicate with internal space (138) between the anodes (154 and 156). Electrically insulating members (164 and 166) prevent the current collector from being in electrical contact with the anode.

Jacobson, Craig (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA); Lu, Chun (Richland, WA)

2010-10-19T23:59:59.000Z

77

Fuel Cell 101  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell 101 Fuel Cell 101 Don Hoffman Don Hoffman Ship Systems & Engineering Research Division March 2011 Distribution Statement A: Approved for public release; distribution is unlimited. Fuel Cell Operation * A Fuel Cell is an electrochemical power source * It supplies electricity by combining hydrogen and oxygen electrochemically without combustion. * It is configured like a battery with anode and cathode. * Unlike a battery, it does not run down or require recharging and will produce electricity and will produce electricity, heat and water as long as fuel is supplied. 2H + + 2e - O 2 + 2H + + 2e - 2H 2 O H 2 Distribution Statement A: Approved for public release; distribution is unlimited. 2 FUEL FUEL CONTROLS Fuel Cell System HEAT & WATER CLEAN CLEAN EXHAUST EXHAUST

78

Fuel Cell Technologies Office: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Cells Search Search Help Fuel Cells EERE Fuel Cell Technologies Office Fuel Cells Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Fuel...

79

Cell properties for modified PTMA cathodes of organic radical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Cell properties for modified PTMA cathodes of organic radical batteries Title Cell properties for modified PTMA cathodes of organic radical batteries Publication Type Journal...

80

Palladium-based electrocatalysts and fuel cells employing such electrocatalysts  

DOE Patents (OSTI)

A direct organic fuel cell includes a fluid fuel comprising formic acid, an anode having an electrocatalyst comprising palladium nanoparticles, a fluid oxidant, a cathode electrically connected to the anode, and an electrolyte interposed between the anode and the cathode.

Masel; Richard I. (Champaign, IL), Zhu; Yimin (Urbana, IL), Larsen; Robert T. (Champaign, IL)

2010-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

www.mdpi.com/journal/ijms A Single-Chamber Microbial Fuel Cell without an Air Cathode  

E-Print Network (OSTI)

treatment with electricity production. Electricity generation with simultaneous nitrate reduction in a single-chamber MFC without air cathode was studied, using glucose (1 mM) as the carbon source and nitrate (1 mM) as the final electron acceptor employed by Bacillus subtilis under anaerobic conditions. Increasing current as a function of decreased nitrate concentration and an increase in biomass were observed with a maximum current of 0.4 mA obtained at an external resistance (Rext) of 1 K? without a platinum catalyst of air cathode. A decreased current with complete nitrate reduction, with further recovery of the current immediately after nitrate addition, indicated the dependence of B. subtilis on nitrate as an electron acceptor to efficiently produce electricity. A power density of 0.0019 mW/cm 2 was achieved at an Rext of 220 ?. Cyclic voltammograms (CV) showed direct electron transfer with the involvement of mediators in the MFC. The low coulombic efficiency (CE)

Vanita Roshan Nimje; Chien-cheng Chen; Hau-ren Chen; Chien-yen Chen; Min-jen Tseng; Kai-chien Cheng; Ruey-chyuan Shih; Young-fo Chang

2012-01-01T23:59:59.000Z

82

Carbon fuel cells with carbon corrosion suppression  

Science Conference Proceedings (OSTI)

An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

Cooper, John F. (Oakland, CA)

2012-04-10T23:59:59.000Z

83

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

SS 304 was encapsulated with thin layers of Co-Ni by an electroless deposition process. The corrosion behavior of SS304 and Co-Ni-SS304 was investigated in molten carbonate under cathode gas atmosphere with electrochemical and surface characterization tools. Surface modification of SS304 reduced the dissolution of chromium and nickel into the molten carbonate melt. Composition of the corrosion scale formed in case of Co-Ni-SS304 is different from SS304 and shows the presence of Co and Ni oxides while the latter shows the presence of lithium ferrite. Polarization resistance for oxygen reduction reaction and conductivity of corrosion values for the corrosion scales were obtained using impedance analysis and current-potential plots. The results indicated lower polarization resistance for oxygen reduction reaction in the case of Co-Ni-SS304 when compared to SS304. Also, the conductivity of the corrosion scales was considerably higher in case of Co-Ni-SS304 than the SS304. This study shows that modifying the current collector surface with Co-Ni coatings leads to the formation of oxide scales with improved barrier properties and electronic conductivity.

Dr. Ralph E. White

2001-03-31T23:59:59.000Z

84

Fuel Cell Technologies Office: Fuel Cells  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cells Search Search Help Fuel Cells EERE Fuel Cell Technologies Office Fuel Cells...

85

Solid oxide fuel cell with single material for electrodes and interconnect  

DOE Patents (OSTI)

A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

McPheeters, Charles C. (Naperville, IL); Nelson, Paul A. (Wheaton, IL); Dees, Dennis W. (Downers Grove, IL)

1994-01-01T23:59:59.000Z

86

Fuel Cell Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Basics Basics Fuel Cell Basics August 14, 2013 - 2:09pm Addthis Photo of two hydrogen fuel cells. Fuel cells are an emerging technology that can provide heat and electricity for buildings and electrical power for vehicles and electronic devices. How Fuel Cells Work Fuel cells work like batteries, but they do not run down or need recharging. They produce electricity and heat as long as fuel is supplied. A fuel cell consists of two electrodes-a negative electrode (or anode) and a positive electrode (or cathode)-sandwiched around an electrolyte. A fuel, such as hydrogen, is fed to the anode, and air is fed to the cathode. Activated by a catalyst, hydrogen atoms separate into protons and electrons, which take different paths to the cathode. The electrons go through an external circuit, creating a flow of electricity. The protons

87

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Converting chemical energy of hydrogenated fuels into electricity Project Description Invented in 1839, fuels cells powered the Gemini and Apollo space missions, as well as the space shuttle. Although fuel cells have been successfully used in such applications, they have proven difficult to make more cost-effective and durable for commercial applications, particularly for the rigors of daily transportation. Since the 1970s, scientists at Los Alamos have managed to make various scientific breakthroughs that have contributed to the development of modern fuel cell systems. Specific efforts include the following: * Finding alternative and more cost-effective catalysts than platinum. * Enhancing the durability of fuel cells by developing advanced materials and

88

Fuel Cell Technologies Office: Fuel Cell Animation  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Animation to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Animation on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Animation on...

89

Hydrogen & Fuel Cells - Fuel Cell - Polymer Electrolyte  

NLE Websites -- All DOE Office Websites (Extended Search)

Polymer Electrolyte Fuel Cell Research Polymer Electrolyte Fuel Cell Research Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. One of the main barriers to the commercialization of polymer electrolyte fuel cell (PEFC) systems, especially for automotive use, is the high cost of the platinum electrocatalysts. Aside from the cost of the precious metal, concern has also been raised over the adequacy of the world supply of platinum, if fuel cell vehicles were to make a significant penetration into the global automotive fleet. At Argonne, chemists are working toward the development of low-cost nonplatinum electrocatalysts for the oxygen reduction reaction--durable materials that would be stable in the fuel

90

Separator plate for a fuel cell  

DOE Patents (OSTI)

A separator plate is described for a fuel cell comprising an anode current collector, a cathode current collector and a main plate, the main plate disposed between the anode current collector and the cathode current collector. The anode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the anode side of the separator plate and the cathode current collector forms a flattened peripheral wet seal structure and manifold wet seal structure on the cathode side of the separator plate. In this manner, the number of components required to manufacture and assemble a fuel cell stack is reduced. 9 figs.

Petri, R.J.; Meek, J.; Bachta, R.P.; Marianowski, L.G.

1996-04-02T23:59:59.000Z

91

Cathode for an electrochemical cell  

SciTech Connect

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

92

Low temperature aluminum reduction cell using hollow cathode  

DOE Patents (OSTI)

A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2002-08-20T23:59:59.000Z

93

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per

94

Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

Fuel cells are an emerging technology that can provide heat and electricity for buildings and electrical power for vehicles and electronic devices.

95

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells Fuel Cells Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electrochemical Devices Email Fernando Garzon Sensors & Electrochemical Devices Email Piotr Zelenay Sensors & Electrochemical Devices Email Rod Borup Sensors & Electrochemical Devices Email Karen E. Kippen Experimental Physical Sciences Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

96

Polymer Electrolyte Fuel Cell Lifetime Limitations: The Role...  

NLE Websites -- All DOE Office Websites (Extended Search)

of polymer electrolyte membrane fuel cell (PEMFC) performance, Establish dominant catalyst and cathode degradation * mechanisms for Pt, Pt-Co alloys, and Pt 3 Sc, Identify key...

97

Ambient pressure fuel cell system  

DOE Patents (OSTI)

An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

Wilson, Mahlon S. (Los Alamos, NM)

2000-01-01T23:59:59.000Z

98

Annular feed air breathing fuel cell stack  

DOE Patents (OSTI)

A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

Wilson, Mahlon S. (Los Alamos, NM)

1996-01-01T23:59:59.000Z

99

Cathode composition for electrochemical cell  

DOE Patents (OSTI)

A high-temperature, secondary electrochemical cell includes a negative electrode containing an alkali metal such as lithium, an electrolyte of molten salt containing ions of that alkali metal and a positive electrode containing a mixture of metallic sulfides. The positive electrode composition is contained within a porous structure that permits permeation of molten electrolyte and includes a mixture of about 5% to 30% by weight Cu.sub.2 S in FeS.

Steunenberg, Robert K. (Naperville, IL); Martin, Allan E. (Woodridge, IL); Tomczuk, Zygmunt (Palos Hills, IL)

1976-01-01T23:59:59.000Z

100

High Specific Power, Direct Methanol Fuel Cell Stack  

NLE Websites -- All DOE Office Websites (Extended Search)

High Specific Power, Direct Methanol Fuel Cell Stack High Specific Power, Direct Methanol Fuel Cell Stack High Specific Power, Direct Methanol Fuel Cell Stack The present invention is a fuel cell stack including at least one direct methanol fuel cell. Available for thumbnail of Feynman Center (505) 665-9090 Email High Specific Power, Direct Methanol Fuel Cell Stack The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Fuel cell system  

DOE Patents (OSTI)

A fuel cell system is comprised of a fuel cell module including sub-stacks of series-connected fuel cells, the sub-stacks being held together in a stacked arrangement with cold plates of a cooling means located between the sub-stacks to function as electrical terminals. The anode and cathode terminals of the sub-stacks are connected in parallel by means of the coolant manifolds which electrically connect selected cold plates. The system may comprise a plurality of the fuel cell modules connected in series. The sub-stacks are designed to provide a voltage output equivalent to the desired voltage demand of a low voltage, high current DC load such as an electrolytic cell to be driven by the fuel cell system. This arrangement in conjunction with switching means can be used to drive a DC electrical load with a total voltage output selected to match that of the load being driven. This arrangement eliminates the need for expensive voltage regulation equipment.

Early, Jack (Perth Amboy, NJ); Kaufman, Arthur (West Orange, NJ); Stawsky, Alfred (Teaneck, NJ)

1982-01-01T23:59:59.000Z

102

Cathode Contact Materials for Anode-Supported Cell Development - Lawrence Berkeley National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Contact Materials for Anode- Cathode Contact Materials for Anode- Supported Cell Development- Lawrence Berkeley National Laboratory Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

103

Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} (x=0, 0.3): New cobaltite materials as cathodes for proton conducting solid oxide fuel cell  

Science Conference Proceedings (OSTI)

Misfit-type Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} (x=0, 0.3) oxides were synthesised to be evaluated as possible cathode materials for proton conducting fuel cells (PCFCs) based on BaCe{sub 0.9}Y{sub 0.1}O{sub 3-{delta}} (BCY10) dense ceramic electrolyte. The electrical conductivity value of Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}} ({sigma}{approx}53 S cm{sup -1} at 600 deg. C) is in the range of usually required value for a cathode application (about 50-100 S cm{sup -1}). In order to test the performance of each compound as cathode material, impedance measurements were carried out on Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}}/BaCe{sub 0.9}Y{sub 0.1}O{sub 3-{delta}}/Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} symmetrical half cells over the temperature range 400-800 deg. C under wet air. A promising electrocatalytic activity has been observed with both compounds Ca{sub 3}Co{sub 4}O{sub 9+{delta}} and Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}}. Factually, the area specific resistance obtained was about 2.2 {Omega} cm{sup 2} at 600 deg. C. - Graphical abstract: Arrehnius plots of the ASR for Ca{sub 3}Co{sub 4}O{sub 9+{delta}} and Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}}.

Ben Yahia, Hamdi [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France); Mauvy, Fabrice, E-mail: mauvy@icmcb-bordeaux.cnrs.f [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France); Grenier, Jean Claude [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France)

2010-03-15T23:59:59.000Z

104

Fuel cell membrane humidification  

DOE Patents (OSTI)

A polymer electrolyte membrane fuel cell assembly has an anode side and a cathode side separated by the membrane and generating electrical current by electrochemical reactions between a fuel gas and an oxidant. The anode side comprises a hydrophobic gas diffusion backing contacting one side of the membrane and having hydrophilic areas therein for providing liquid water directly to the one side of the membrane through the hydrophilic areas of the gas diffusion backing. In a preferred embodiment, the hydrophilic areas of the gas diffusion backing are formed by sewing a hydrophilic thread through the backing. Liquid water is distributed over the gas diffusion backing in distribution channels that are separate from the fuel distribution channels.

Wilson, Mahlon S. (Los Alamos, NM)

1999-01-01T23:59:59.000Z

105

Cathode/Anode Selection and Full Cell Performance for Stationary ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cathode/Anode Selection and Full Cell Performance for Stationary Li-ion Battery System. Author(s), Daiwon Choi, Donghai Wang, Vilayanur...

106

Air Breathing Direct Methanol Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Breathing Direct Methanol Fuel Cell Air Breathing Direct Methanol Fuel Cell Air Breathing Direct Methanol Fuel Cell An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Available for thumbnail of Feynman Center (505) 665-9090 Email Air Breathing Direct Methanol Fuel Cell An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol

107

Annular feed air breathing fuel cell stack  

DOE Patents (OSTI)

A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

Wilson, Mahlon S. (Los Alamos, NM); Neutzler, Jay K. (Peoria, AZ)

1997-01-01T23:59:59.000Z

108

Generation of electricity with fuel cell using alcohol fuel  

Science Conference Proceedings (OSTI)

This patent describes a method for generating electricity in a fuel cell, the fuel cell comprising a cathode, an electrolyte, an anode comprising a first, fluid-permeable face and a second face in contact with the electrolyte, and an external circuit connecting the cathode and the anode. It comprises bringing a lower primary alcohol into contact with the first fluid-permeable face of the anode, thereby permitting the lower primary alcohol to penetrate into the cross-section of the anode toward the second face; oxidizing the lower primary alcohol essentially to carbon dioxide and water at the second face of the anode, reducing a reducible gas at the cathode, and obtaining electricity from the fuel cell.

Reddy, N.R.K.V.; Taylor, E.J.

1992-07-21T23:59:59.000Z

109

Catalytic membranes for fuel cells  

DOE Patents (OSTI)

A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

2011-04-19T23:59:59.000Z

110

PEM fuel cell monitoring system  

DOE Patents (OSTI)

Method and apparatus are disclosed for monitoring the performance of H{sub 2}--O{sub 2} PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H{sub 2} sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken. 2 figs.

Meltser, M.A.; Grot, S.A.

1998-06-09T23:59:59.000Z

111

PEM fuel cell monitoring system  

DOE Patents (OSTI)

Method and apparatus for monitoring the performance of H.sub.2 --O.sub.2 PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H.sub.2 sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken.

Meltser, Mark Alexander (Pittsford, NY); Grot, Stephen Andreas (West Henrietta, NY)

1998-01-01T23:59:59.000Z

112

Fuel Cell Technologies Office: Fuel Cell Animation  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME ABOUT...

113

Energy Basics: Fuel Cells  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Basics Renewable Energy Printable Version Share this resource Biomass Geothermal Hydrogen Hydrogen Fuel Fuel Cells Hydropower Ocean Solar Wind Fuel Cells Photo of...

114

Intermediate Temperature Solid Oxide Fuel Cell Development  

DOE Green Energy (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600 C than conventional manganite or cobaltite cathodes.

S. Elangovan; Scott Barnett; Sossina Haile

2008-06-30T23:59:59.000Z

115

Fuel cell system with combustor-heated reformer  

DOE Patents (OSTI)

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

116

Combinatorial Discovery of Fuel Cell Electrocatalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Discovery of Fuel Cell Discovery of Fuel Cell Electrocatalysts Eugene S. Smotkin University of Puerto Rico @ Rio Piedras Non-Platinum Electrocatalysts Workshop March 21, 2003 Marriot courtyard - Convention Center New Orleans, Louisiana Combinatorial Discovery of Fuel Cell Electrocatalysts Eugene S. Smotkin University of Puerto Rico @ Rio Piedras Non-Platinum Electrocatalysts Workshop March 21, 2003 Marriot courtyard - Convention Center New Orleans, Louisiana Overview „ Parallel Screening methods „ Optical Screening method „ Array fuel cell „ Array synthetic methods „ Partial review of non-Pt cathode work Overview „ Parallel Screening methods „ Optical Screening method „ Array fuel cell „ Array synthetic methods „ Partial review of non-Pt cathode work Optical Screening of Electrocatalyst Libraries

117

Fuel Cell Technologies Office: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

offering cleaner, more-efficient alternatives to the combustion of gasoline and other fossil fuels. Fuel cells have the potential to replace the internal-combustion engine in...

118

Fuel Cell Links  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Links Fuel Cell Links The links below are provided as additional resources for fuel-cell-related information. Most of the linked sites are not part of, nor affiliated with, fueleconomy.gov. We do not endorse or vouch for the accuracy of the information found on such sites. Fuel Cell Vehicles and Manufacturers Chevrolet General Motors press release about the Chevrolet Fuel Cell Equinox Ford Ford overview of their hydrogen fuel cell vehicles Honda FCX Clarity official site Hyundai Hyundai press release announcing the upcoming Tucson Fuel Cell Mercedes-Benz Ener-G-Force Fuel-cell-powered concept SUV Nissan Nissan TeRRA concept SUV Toyota Overview of Toyota fuel cell technology Hydrogen- and Fuel-Cell-Related Information and Tools Fuel Cell Vehicles Brief overview of fuel cell vehicles provided by DOE's Alternative Fuels Data Center (AFDC)

119

NETL: Fuel Cells - Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel CellsSolid State Energy Conversion Alliance (SECA) Contacts For information on the Fuel CellsSECA program, contact: Fuel Cells Technology Manager: Shailesh Vora 412-386-7515...

120

Energy Basics: Fuel Cells  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

EERE: Energy Basics Fuel Cells Photo of two hydrogen fuel cells. Fuel cells are an emerging technology that can provide heat and electricity for buildings and electrical power for...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hydrogen Fuel Cell Vehicles  

E-Print Network (OSTI)

Operation of a Solid Polymer Fuel Cell: A Parametric Model,"1991). G. Bronoel, "Hydrogen-Air Fuel Cells Without PreciousG. Abens, "Development of a Fuel Cell Power Source for Bus,"

Delucchi, Mark

1992-01-01T23:59:59.000Z

122

Polarization Resistance of La0.85Ca0.15MnO3 Cathodes for Solid Oxide Fuel Cells (SOFCs) Measured Using Patterned Electrodes  

SciTech Connect

Patterned cathodes of calcium-doped lanthanum manganite (LCM) were fabricated on polycrystalline yttria-stabilized zirconia (YSZ) substrates by RF magnetron sputtering and photolithographic techniques. Samples were generated with a constant electrode/electrolyte contact area but different three phase boundary (TPB) lengths (lTPB's). Electrochemical impedance spectroscopy (EIS) was performed in the oxygen partial pressure (pO2) and temperature range of 10-3 atm to 1.00 atm and 600-800 C respectively. The area specific polarization resistance, Rp, was found to scale linearly with the inverse of lTPB, suggesting that the TPB is the active region for oxygen reduction. The resistivity decreased with increased temperature and pO2 and showed an activation energy of 1.17 +/- 0.03 eV.

Miara, Lincoln J.; Yoon, Kyung J.; Topping, Stephen; Saraf, Laxmikant V.; Pal, Uday B.; Gopalan, Srikanth

2010-04-25T23:59:59.000Z

123

Advanced Cathode Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Research 1 HFCIT Program Kick-off Meeting, Arlington, VA, February 13-14, 2007 Program Kick-off Meeting Arlington, Virginia, February 13-14, 2007 Advanced Cathode...

124

Fuel Cell Technologies Office: Glossary  

NLE Websites -- All DOE Office Websites (Extended Search)

Glossary Glossary This glossary contains terms and acronyms related to hydrogen and fuel cell technologies. A B C D E F G H I J K L M N O P Q R S T U V W X Y Z - Acronyms A AC Generator (or Alternator) An electric device that produces an electric current that reverses direction many times per second. Also called a synchronous generator. Adsorption The adhesion of the molecules of gases, dissolved substances, or liquids to the surface of the solids or liquids with which they are in contact. Air The mixture of oxygen, nitrogen, and other gases that, with varying amounts of water vapor, forms the atmosphere of the earth. Alkaline Fuel Cell (AFC) A type of hydrogen/oxygen fuel cell in which the electrolyte is concentrated potassium hydroxide (KOH) and the hydroxide ions (OH-) are transported from the cathode to the anode.

125

Water injected fuel cell system compressor  

DOE Patents (OSTI)

A fuel cell system including a dry compressor for pressurizing air supplied to the cathode side of the fuel cell. An injector sprays a controlled amount of water on to the compressor's rotor(s) to improve the energy efficiency of the compressor. The amount of water sprayed out the rotor(s) is controlled relative to the mass flow rate of air inputted to the compressor.

Siepierski, James S. (Williamsville, NY); Moore, Barbara S. (Victor, NY); Hoch, Martin Monroe (Webster, NY)

2001-01-01T23:59:59.000Z

126

Regenerative fuel cell engineering - FY99  

Science Conference Proceedings (OSTI)

The authors report the work conducted by the ESA-EPE Fuel Cell Engineering Team at Los Alamos National Laboratory during FY99 on regenerative fuel cell system engineering. The work was focused on the evaluation of regenerative fuel cell system components obtained through the RAFCO program. These components included a 5 kW PEM electrolyzer, a two-cell regenerative fuel cell stack, and samples of the electrolyzer membrane, anode, and cathode. The samples of the electrolyzer membrane, anode, and cathode were analyzed to determine their structure and operating characteristics. Tests were conducted on the two-cell regenerative fuel cell stack to characterize its operation as an electrolyzer and as a fuel cell. The 5 kW PEM electrolyzer was tested in the Regenerative Fuel Cell System Test Facility. These tests served to characterize the operation of the electrolyzer and, also, to verify the operation of the newly completed test facility. Future directions for this work in regenerative fuel cell systems are discussed.

Michael A. Inbody; Rodney L. Borup; James C. Hedstrom; Jose Tafoya; Byron Morton; Lois Zook; Nicholas E. Vanderborgh

2000-01-01T23:59:59.000Z

127

Fabrication of Yttria stabilized zirconia thin films on porous substrates for fuel cell applications  

E-Print Network (OSTI)

on Solid Oxide Fuel Cells (SOFC-V). Stimming, U. , Singhal,on Solid Oxide Fuel Cells (SOFC-IV), Pennington, NJ, USA:M. Characterization of Composite SOFC Cathodes by Impedance

Leming, Andres

2003-01-01T23:59:59.000Z

128

Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

Solid oxide fuel cell (SOFC) technology, which offers many advantages over traditional energy conversion systems including low emission and high efficiency, has become increasingly attractive to the utility, automotive, and defense industries (as shown in Figure 1). As an all solid-state energy conversion device, the SOFC operates at high temperatures (700-1,000 C) and produces electricity by electrochemically combining the fuel and oxidant gases across an ionically conducting oxide membrane. To build up a useful voltage, a number of cells or PENs (Positive cathode-Electrolyte-Negative anode) are electrically connected in series in a stack through bi-polar plates, also known as interconnects. Shown in Figure 2 (a) is a schematic of the repeat unit for a planar stack, which is expected to be a mechanically robust, high power-density and cost-effective design. In the stack (refer to Figure 2 (b)), the interconnect is simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing (fuels such as hydrogen or natural gas) environment on the anode side for thousands of hours at elevated temperatures (700-1,000 C). Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain sulfide impurities. Also, the interconnect must be stable towards any sealing materials with which it is in contact, under numerous thermal cycles. Furthermore, the interconnect must also be stable towards electrical contact materials that are employed to minimize interfacial contact resistance, and/or the electrode materials. Considering these service environments, the interconnect materials should possess the following properties: (1) Good surface stability (resistance to oxidation and corrosion) in both cathodic (oxidizing) and anodic (reducing) atmospheres. (2) Thermal expansion matching to the ceramic PEN and other adjacent components, all of which typically have a coefficient of thermal expansion (CTE) in the range of 10.5-12.0 x 10{sup -6} K{sup -1}. (3) High electrical conductivity through both the bulk material and in-situ formed oxide scales. (4) Satisfactory bulk and interfacial mechanical/thermomechanical reliability and durability at the SOFC operating temperatures. (5) Good compatibility with other materials in contact with interconnects such as seals and electrical contact materials. Until recently, the leading candidate material for the interconnect was doped lanthanum chromite (LaCrO3), which is a ceramic material which can easily withstand the traditional 1000 C operating temperature. However, the high cost of raw materials and fabrication, difficulties in obtaining high-density chromite parts at reasonable sintering temperatures, and the tendency of the chromite interconnect to partially reduce at the fuel gas/interconnect interface, causing the component to warp and the peripheral seal to break, have plagued the commercialization of planar SOFCs for years. The recent trend in developing lower temperature, more cost-effective cells which utilize anode-supported, several micron-thin electrolytes and/or new electrolytes with improved conductivity make it feasible for lanthanum chromite to be supplanted by metals or alloys as the interconnect materials. Compared to doped lanthanum chromite, metals or alloys offer significantly lower raw material and fabrication costs.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2003-06-15T23:59:59.000Z

129

Fuel Cell Technologies Office: Reversible Fuel Cells Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Reversible Fuel Cells Reversible Fuel Cells Workshop to someone by E-mail Share Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Facebook Tweet about Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Twitter Bookmark Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Google Bookmark Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Delicious Rank Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Digg Find More places to share Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings

130

FCT Fuel Cells: Fuel Cell R&D Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell R&D Activities to someone by E-mail Share FCT Fuel Cells: Fuel Cell R&D Activities on Facebook Tweet about FCT Fuel Cells: Fuel Cell R&D Activities on Twitter Bookmark...

131

Solid oxide fuel cell with single material for electrodes and interconnect  

DOE Patents (OSTI)

A solid oxide fuel cell is described having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed there between, and the anode, cathode and interconnect elements are comprised of substantially one material. 9 figs.

McPheeters, C.C.; Nelson, P.A.; Dees, D.W.

1994-07-19T23:59:59.000Z

132

Fuel Cell Technologies Office: Fuel Cell Technical Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Cell Technical Cell Technical Publications to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technical Publications on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technical Publications on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technical Publications on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technical Publications on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technical Publications on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technical Publications on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards Market Analysis Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings

133

Fuel-cell engine stream conditioning system  

SciTech Connect

A stream conditioning system for a fuel cell gas management system or fuel cell engine. The stream conditioning system manages species potential in at least one fuel cell reactant stream. A species transfer device is located in the path of at least one reactant stream of a fuel cell's inlet or outlet, which transfer device conditions that stream to improve the efficiency of the fuel cell. The species transfer device incorporates an exchange media and a sorbent. The fuel cell gas management system can include a cathode loop with the stream conditioning system transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell related to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

DuBose, Ronald Arthur (Marietta, GA)

2002-01-01T23:59:59.000Z

134

Polyaniline-derived non-precious catalyst for the polymer electrolyte fuel cathode  

Science Conference Proceedings (OSTI)

A novel polyaniline (PANI)-derived non-precious cathode catalyst was developed in this work, exhibiting remarkable activity (onset potential: 0.9 V, half-wave potential: 0.77 V) and selectivity (0.4 % H20 2 at 0.4 V). As a result, the generated current densities at high voltages associated with electrochemically kinetic activity can be achieved to 0.04 Acm-2 for 0.80V and 0.21 Acm-2 for 0.6 V, when air was used in fuel cell tests. MEA life test at a constant voltage of 0.4 V demonstrated a promising stability up to 450 hours, without obvious degradation. The current density during the test was measured around 0.32 A cm-2, a respectable performance for a cell with non-precious cathode, operated on air rather than oxygen. The possible active sites, related to pyridine- and pyrrole-like metal species were discussed according to presented XPS and XRD analysis.

Wu, Gang [Los Alamos National Laboratory; Chen, Zhongwei [Los Alamos National Laboratory; Garzon, Fernando [Los Alamos National Laboratory; Zelenay, Piotr [Los Alamos National Laboratory

2008-01-01T23:59:59.000Z

135

Magnetron cathodes in plasma electrode pockels cells  

DOE Patents (OSTI)

Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

Rhodes, Mark A. (Pleasanton, CA)

1995-01-01T23:59:59.000Z

136

A fuel cell overview  

SciTech Connect

This paper is an overview of the fuel cell as an efficient and environmentally benign energy conversion technology. The topics of the paper include their physical arrangement, types of fuel cells, status of commercial development, applications of the fuel cell power plants and comparison with existing alternatives, and good design practice for fuel cell safety.

Krumpelt, M. [Argonne National Lab., IL (United States); Reiser, C.

1994-10-01T23:59:59.000Z

137

Air breathing direct methanol fuel cell  

DOE Patents (OSTI)

An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source.

Ren, Xiaoming (Los Alamos, NM)

2002-01-01T23:59:59.000Z

138

Fuel cells seminar  

SciTech Connect

This year`s meeting highlights the fact that fuel cells for both stationary and transportation applications have reached the dawn of commercialization. Sales of stationary fuel cells have grown steadily over the past 2 years. Phosphoric acid fuel cell buses have been demonstrated in urban areas. Proton-exchange membrane fuel cells are on the verge of revolutionizing the transportation industry. These activities and many more are discussed during this seminar, which provides a forum for people from the international fuel cell community engaged in a wide spectrum of fuel cell activities. Discussions addressing R&D of fuel cell technologies, manufacturing and marketing of fuel cells, and experiences of fuel cell users took place through oral and poster presentations. For the first time, the seminar included commercial exhibits, further evidence that commercial fuel cell technology has arrived. A total of 205 papers is included in this volume.

1996-12-01T23:59:59.000Z

139

Fuel cell membranes and crossover prevention  

DOE Patents (OSTI)

A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

Masel, Richard I. (Champaign, IL); York, Cynthia A. (Newington, CT); Waszczuk, Piotr (White Bear Lake, MN); Wieckowski, Andrzej (Champaign, IL)

2009-08-04T23:59:59.000Z

140

Solid polymer MEMS-based fuel cells  

DOE Patents (OSTI)

A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Pleasant Hill, CA)

2008-04-22T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents (OSTI)

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

McElroy, James F. (Hamilton, MA); Chludzinski, Paul J. (Swampscott, MA); Dantowitz, Philip (Peabody, MA)

1987-01-01T23:59:59.000Z

142

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents (OSTI)

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

1987-04-14T23:59:59.000Z

143

FCT Fuel Cells: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Fuel Cells: Basics on Facebook Tweet about FCT Fuel Cells: Basics on Twitter Bookmark FCT Fuel Cells: Basics on Google Bookmark FCT Fuel Cells: Basics on Delicious Rank FCT Fuel Cells: Basics on Digg Find More places to share FCT Fuel Cells: Basics on AddThis.com... Home Basics Current Technology DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of a fuel cell stack A fuel cell uses the chemical energy of hydrogen to cleanly and efficiently produce electricity with water and heat as byproducts. (How much water?) Fuel cells are unique in terms of the variety of their potential applications; they can provide energy for systems as large as a utility

144

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

November 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: November 2012 on Facebook Tweet about Fuel Cell Technologies...

145

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Newsletter Archives to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter Archives on Facebook Tweet about Fuel Cell Technologies...

146

Fuel Cell Technologies Office: Subscribe to the Fuel Cell Technologies...  

NLE Websites -- All DOE Office Websites (Extended Search)

Subscribe to the Fuel Cell Technologies Office Newsletter to someone by E-mail Share Fuel Cell Technologies Office: Subscribe to the Fuel Cell Technologies Office Newsletter on...

147

Fuel Cell Technologies Office: Fuel Cells for Portable Power...  

NLE Websites -- All DOE Office Websites (Extended Search)

for Portable Power Workshop to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cells for Portable Power Workshop on Facebook Tweet about Fuel Cell Technologies...

148

Preparation and characterization of solid electrolytes for solid oxide fuel cells. Quarterly report, January 1, 1997--June 30, 1997  

DOE Green Energy (OSTI)

During this period, attempts were made to measure the surface and electrochemical properties of rare-earth dopants in ceria for solid oxide fuel cells and cathodic electrodes.

Rambabu, B.

1997-08-01T23:59:59.000Z

149

Fuel Cell Technologies Office: News  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies Office: News on Twitter Bookmark Fuel Cell Technologies Office: News on Google Bookmark Fuel Cell Technologies Office: News on Delicious Rank Fuel Cell Technologies...

150

Fuel Cell Technologies Office: Webinars  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Webinars to someone by E-mail Share Fuel Cell Technologies Office: Webinars on Facebook Tweet about Fuel Cell Technologies Office: Webinars on Twitter Bookmark Fuel Cell...

151

Electrolysis cell for reprocessing plutonium reactor fuel  

DOE Patents (OSTI)

An electrolytic cell for refining a mixture of metals including spent fuel containing U and Pu contaminated with other metals is claimed. The cell includes a metallic pot containing a metallic pool as one anode at a lower level, a fused salt as the electrolyte at an intermediate level and a cathode and an anode basket in spaced-apart positions in the electrolyte with the cathode and anode being retractable to positions above the electrolyte during which spent fuel may be added to the anode basket. The anode basket is extendable into the lower pool to dissolve at least some metallic contaminants; the anode basket contains the spent fuel acting as a second anode when in the electrolyte.

Miller, W.E.; Steindler, M.J.; Burris, L.

1985-01-04T23:59:59.000Z

152

Electrolysis cell for reprocessing plutonium reactor fuel  

DOE Patents (OSTI)

An electrolytic cell for refining a mixture of metals including spent fuel containing U and Pu contaminated with other metals, the cell including a metallic pot containing a metallic pool as one anode at a lower level, a fused salt as the electrolyte at an intermediate level and a cathode and an anode basket in spaced-apart positions in the electrolyte with the cathode and anode being retractable to positions above the electrolyte during which spent fuel may be added to the anode basket and the anode basket being extendable into the lower pool to dissolve at least some metallic contaminants, the anode basket containing the spent fuel acting as a second anode when in the electrolyte.

Miller, William E. (Naperville, IL); Steindler, Martin J. (Park Forest, IL); Burris, Leslie (Naperville, IL)

1986-01-01T23:59:59.000Z

153

Powering Cell Phones with Fuel Cells Running on Renewable Fuels  

DOE Green Energy (OSTI)

The major goals of this project were to increase lifetime, increase energy density, and reduce material costs. The combination of identifying corrosion resistant materials and changing catalysts increased lifetimes. Work to increase the energy density included increasing the concentration of the formic acid fuel from 12M (ca. 50 wt%) to 22M (ca. 85 wt%) and decreasing the amount of fuel crossing over. The largest expense of the device is the cathode catalyst. At the beginning of the project Pt loading was over 8 mg/cm2 on our cathodes. Through optimization work we managed to bring down the cathode loading to approximately half of what we started with.

Dr. Ruiming Zhang

2007-01-31T23:59:59.000Z

154

Direct Methanol Fuel Cell for Portable Applications  

E-Print Network (OSTI)

A methanol fuel cell stack has at cl f is being incorporated a portable ions. 1 performance and flow rate for cell Water data, transport mechanisms fuel are discussed. Stack response has Implications slack performance and conditions addressed. Introduction 1 development a methanol fuel is presently pursued at 1 sponsorship from Research (1 A five methanol oxidizing stack has at stack incorporates liquiddirect methanol proton exchange membrane [1, 2], methanol (1 by oxidation an solution methanol at reduction at cathode. `1 focus results out stacks. form a n part of 1 cells have as storage but complicated systems to Upon of the methanol fuel many system simpler than before. In the can oxidized at thus is for fuel With the f mixture, electrolytes always at a of operation free-aqueous acid and thus corrosion issues addressed electrode assemblies consist main catalyzed cathode, and a polymer catalyst is the cathode catalyst is as a polymer `1 current state at the for is V at current d...

Narayanan Frank And; T. Valdez; S. R. Narayanan; H Frank; W. Chun

1997-01-01T23:59:59.000Z

155

Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies to someone by E-mail Share Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Facebook Tweet about Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Twitter Bookmark Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Google Bookmark Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Delicious Rank Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Digg Find More places to share Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on AddThis.com... Early Adoption of Fuel Cells Early Market Applications for Fuel Cells

156

Fuel Cell Technologies Office: DOE Fuel Cell Pre-Solicitation...  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Fuel Cell Pre-Solicitation Workshop to someone by E-mail Share Fuel Cell Technologies Office: DOE Fuel Cell Pre-Solicitation Workshop on Facebook Tweet about Fuel Cell...

157

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: January 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell...

158

Fuel Cell Technologies Office: 2010 New Fuel Cell Projects Meeting  

NLE Websites -- All DOE Office Websites (Extended Search)

2010 New Fuel Cell Projects Meeting to someone by E-mail Share Fuel Cell Technologies Office: 2010 New Fuel Cell Projects Meeting on Facebook Tweet about Fuel Cell Technologies...

159

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

3 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: January 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell...

160

Fuel Cell Technologies Office: 2009 New Fuel Cell Projects Meeting  

NLE Websites -- All DOE Office Websites (Extended Search)

09 New Fuel Cell Projects Meeting to someone by E-mail Share Fuel Cell Technologies Office: 2009 New Fuel Cell Projects Meeting on Facebook Tweet about Fuel Cell Technologies...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Fuel Cell Technologies Office: Biogas and Fuel Cells Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Biogas and Fuel Cells Workshop to someone by E-mail Share Fuel Cell Technologies Office: Biogas and Fuel Cells Workshop on Facebook Tweet about Fuel Cell Technologies Office:...

162

Fuel Cell Technologies Office: Fuel Cells for Buildings Roadmap...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells for Buildings Roadmap Workshop to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cells for Buildings Roadmap Workshop on Facebook Tweet about Fuel Cell...

163

California Fuel Cell Partnership  

NLE Websites -- All DOE Office Websites (Extended Search)

Speaker(s): Bob Knight Date: October 19, 2000 - 12:00pm Location: Bldg. 90 The California Fuel Cell Partnership is a current collaboration among major automakers, fuel cell...

164

Advanced materials for solid oxide fuel cells  

DOE Green Energy (OSTI)

The purpose of this research is to improve the properties of the current state-of-the-art materials used for solid oxide fuel cells (SOFCs). The objectives are to: (1) develop materials based on modifications of the state-of-the-art materials; (2) minimize or eliminate stability problems in the cathode, anode, and interconnect; (3) Electrochemically evaluate (in reproducible and controlled laboratory tests) the current state-of-the-art air electrode materials and cathode/electrolyte interfacial properties; (4) Develop accelerated electrochemical test methods to evaluate the performance of SOFCs under controlled and reproducible conditions; and (5) Develop and test materials for use in low-temperature SOFCs.

Armstrong, T.; Stevenson, J.

1995-12-31T23:59:59.000Z

165

Fuel cell arrangement  

DOE Patents (OSTI)

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1987-05-12T23:59:59.000Z

166

Fuel cell arrangement  

DOE Patents (OSTI)

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber. 3 figs.

Isenberg, A.O.

1987-05-12T23:59:59.000Z

167

Energy Basics: Fuel Cell Vehicles  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Fuels Printable Version Share this resource Fuels Vehicles Electric Vehicles Flexible Fuel Vehicles Fuel Cell Vehicles Hybrid Electric Vehicles Natural Gas Vehicles Propane...

168

Solid oxide fuel cell having monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

Ackerman, J.P.; Young, J.E.

1983-10-12T23:59:59.000Z

169

Power from the Fuel Cell  

E-Print Network (OSTI)

Power for Buildings Using Fuel-Cell Cars, Proceedings ofwell as to drive down fuel-cell system costs through productis most likely to be the fuel-cell vehicle. Fuel cells are

Lipman, Timothy E.

2000-01-01T23:59:59.000Z

170

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Information Resources Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter to someone by E-mail Share Fuel...

171

Fuel Cells Information at NIST  

Science Conference Proceedings (OSTI)

NIST Home > Fuel Cells Information at NIST. Fuel Cells Information at NIST. (the links below are a compilation of programs ...

2010-08-23T23:59:59.000Z

172

Fuel Cell Handbook update  

DOE Green Energy (OSTI)

The objective of this work was to update the 1988 version of DOE`s Fuel Cell Handbook. Significant developments in the various fuel cell technologies required revisions to reflect state-of-the-art configurations and performance. The theoretical presentation was refined in order to make the handbook more useful to both the casual reader and fuel cell or systems analyst. In order to further emphasize the practical application of fuel cell technologies, the system integration information was expanded. In addition, practical elements, such as suggestions and guidelines to approximate fuel cell performance, were provided.

Owens, W.R.; Hirschenhofer, J.H.; Engleman, R.R. Jr.; Stauffer, D.B.

1993-11-01T23:59:59.000Z

173

Solid Oxide Fuel Cell Power Generation Systems  

Science Conference Proceedings (OSTI)

An increasing worldwide demand for premium power, emerging trend towards electric utility deregulation and distributed power generation, global environmental concerns and regulatory controls have accelerated the development of advanced fuel cell based power generation systems. Fuel cells convert chemical energy to electrical energy through electrochemical oxidation of gaseous and/or liquid fuels ranging from hydrogen to hydrocarbons. Electrochemical oxidation of fuels prevents the formation of Nox, while the higher efficiency of the systems reduces carbon dioxide emissions (kg/kWh). Among various fuel cell power generation systems currently being developed for stationary and mobile applications, solid oxide fuel cells (SOFC) offer higher efficiency (up to 80% overall efficiency in hybrid configurations), fuel flexibility, tolerance to CO poisoning, modularity, and use of non-noble construction materials of low strategic value. Tubular, planar, and monolithic cell and stack configurations are currently being developed for stationary and military applications. The current generation of fuel cells uses doped zirconia electrolyte, nickel cermet anode, doped Perovskite cathode electrodes and predominantly ceramic interconnection materials. Fuel cells and cell stacks operate in a temperature range of 800-1000 *C. Low cost ($400/kWe), modular (3-10kWe) SOFC technology development approach of the Solid State Energy Conversion Alliance (SECA) initiative of the USDOE will be presented and discussed. SOFC technology will be reviewed and future technology development needs will be addressed.

Singh, Prabhakar; Pederson, Larry R.; Simner, Steve P.; Stevenson, Jeffry W.; Viswanathan, Vish V.

2001-05-12T23:59:59.000Z

174

All ceramic structure for molten carbonate fuel cell  

DOE Patents (OSTI)

An all-ceramic molten carbonate fuel cell having a composition formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The structure includes an anode and cathode separated by an electronically conductive interconnect. The electrodes and interconnect are compositions ceramic materials. Various combinations of ceramic compositions for the anode, cathode and interconnect are disclosed. The fuel cell exhibits stability in the fuel gas and oxidizing environments. It presents reduced sealing and expansion problems in fabrication and has improved long-term corrosion resistance.

Smith, J.L.; Kucera, E.H.

1991-01-01T23:59:59.000Z

175

NIST: NIF - PEM Fuel Cells  

Science Conference Proceedings (OSTI)

... Fuel cells are operationally equivalent to a battery. The reactants or fuel in a fuel cell can be replaced unlike a standard disposable or rechargeable ...

176

Fuel Cells Team  

NLE Websites -- All DOE Office Websites (Extended Search)

Judith Valerio at one of our 31 single-cell test stands Fuel Cell Team The FC team focus is R&D on polymer electrolyte membrane (PEM) fuel cells for commercial and military applications. Our program has had ongoing funding in the area of polymer electrolyte fuel cells since 1977 and has been responsible for enabling breakthroughs in the areas of thin film electrodes and air bleed for CO tolerance. For more information on the history of fuel cell research at Los Alamos, please click here. Fuel cells are an important enabling technology for the Hydrogen Economy and have the potential to revolutionize the way we power the nation and the world. The FC team is exploring the potential of fuel cells as energy-efficient, clean, and fuel-flexible alternatives that will

177

Fuel cell generator  

DOE Patents (OSTI)

High temperature solid oxide electrolyte fuel cell generators which allow controlled leakage among plural chambers in a sealed housing. Depleted oxidant and fuel are directly reacted in one chamber to combust remaining fuel and preheat incoming reactants. The cells are preferably electrically arranged in a series-parallel configuration.

Isenberg, Arnold O. (Forest Hills, PA)

1983-01-01T23:59:59.000Z

178

Indirect-fired gas turbine dual fuel cell power cycle  

DOE Patents (OSTI)

A fuel cell and gas turbine combined cycle system which includes dual fuel cell cycles combined with a gas turbine cycle wherein a solid oxide fuel cell cycle operated at a pressure of between 6 to 15 atms tops the turbine cycle and is used to produce CO.sub.2 for a molten carbonate fuel cell cycle which bottoms the turbine and is operated at essentially atmospheric pressure. A high pressure combustor is used to combust the excess fuel from the topping fuel cell cycle to further heat the pressurized gas driving the turbine. A low pressure combustor is used to combust the excess fuel from the bottoming fuel cell to reheat the gas stream passing out of the turbine which is used to preheat the pressurized air stream entering the topping fuel cell before passing into the bottoming fuel cell cathode. The CO.sub.2 generated in the solid oxide fuel cell cycle cascades through the system to the molten carbonate fuel cell cycle cathode.

Micheli, Paul L. (Sacramento, CA); Williams, Mark C. (Morgantown, WV); Sudhoff, Frederick A. (Morgantown, WV)

1996-01-01T23:59:59.000Z

179

Fuel Cells publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells » Fuel Cells Publications Fuel Cells publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electorchemical Devices Email Fernando Garzon Sensors & Electorchemical Devices Email Piotr Zelenay Sensors & Electorchemical Devices Email Rod Borup Sensors & Electorchemical Devices Email Karen E. Kippen Chemistry Communications Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

180

Fuel Cells Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage DELIVERY FUEL CELLS STORAGE PRODUCTION TECHNOLOGY VALIDATION CODES & STANDARDS SYSTEMS INTEGRATION / ANALYSES SAFETY EDUCATION RESEARCH & DEVELOPMENT Economy Pat Davis 2 Fuel Cells Technical Goals & Objectives Goal : Develop and demonstrate fuel cell power system technologies for transportation, stationary, and portable applications. 3 Fuel Cells Technical Goals & Objectives Objectives * Develop a 60% efficient, durable, direct hydrogen fuel cell power system for transportation at a cost of $45/kW (including hydrogen storage) by 2010. * Develop a 45% efficient reformer-based fuel cell power system for transportation operating on clean hydrocarbon or alcohol based fuel that meets emissions standards, a start-up time of 30 seconds, and a projected manufactured cost of $45/kW by

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream 1 and spent fuel stream 2. Spent fuel stream 1 is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream 1 and exhaust stream 2, and exhaust stream 1 is vented. Exhaust stream 2 is mixed with spent fuel stream 2 to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells. 1 fig.

Grimble, R.E.

1988-03-08T23:59:59.000Z

182

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Grimble, Ralph E. (Finleyville, PA)

1988-01-01T23:59:59.000Z

183

Fuel Cell Technologies Office: Early Market Applications for Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies to someone by E-mail Share Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Facebook Tweet about Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Twitter Bookmark Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Google Bookmark Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Delicious Rank Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Digg Find More places to share Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on AddThis.com...

184

Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Joint Fuel Cell Bus Joint Fuel Cell Bus Workshop to someone by E-mail Share Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Facebook Tweet about Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Twitter Bookmark Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Google Bookmark Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Delicious Rank Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Digg Find More places to share Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings Webinars

185

Thin-film solid-oxide fuel cells  

DOE Green Energy (OSTI)

Fuel cells are energy conversion devices that would save billions of dollars in fuel costs alone each year in the United States if they could be implemented today for stationary and transportation applications (1-5). There are a wide variety of fuel cells available, e.g. molten carbonate, phosphoric acid, proton exchange membrane and solid-oxide. However, solid-oxide fuel cells (SOFCS) are potentially more efficient and less expensive per kilowatt of power in comparison to other fuel cells. For transportation applications, the energy efficiency of a conventional internal combustion engine would be increased two-fold as replaced with a zero-emission SOFC. The basic unit of a SOFC consists of an anode and cathode separated by an oxygen-ion conducting, electrolyte layer. Manifolded stacks of fuel cells, with electrical interconnects, enable the transport and combination of a fuel and oxidant at elevated temperature to generate electrical current. Fuel cell development has proceeded along different paths based on the configuration of the anode-electrolyte-cathode. Various configurations include the tubular, monolithic and planar geometries. A planar geometry for the anode-electrolyte-cathode accompanied by a reduction in layer thickness offers the potential for high power density. Maximum power densities will require yet additional innovations in the assembly of fuel cell stacks with all of the manifolding stipulations for gas flow and electrical interconnects.

Jankowski, A.F.

1997-05-01T23:59:59.000Z

186

Customizable Fuel Processor Technology Benefits Fuel Cell ...  

Customizable Fuel Processor Technology Benefits Fuel Cell Power Industry (ANL-IN-00-030) Argonne National Laboratory. Contact ANL About This ...

187

NREL: Learning - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Fuel cells and their ability to cleanly produce electricity from hydrogen and oxygen are what make hydrogen attractive as a "fuel" for transportation use particularly, but also as a general energy carrier for homes and other uses, and for storing and transporting otherwise intermittent renewable energy. Fuel cells function somewhat like a battery-with external fuel being supplied rather than stored electricity-to generate power by chemical reaction rather than combustion. Hydrogen fuel cells, for instance, feed hydrogen gas into an electrode that contains a catalyst, such as platinum, which helps to break up the hydrogen molecules into positively charged hydrogen ions and negatively charged electrons. The electrons flow from the electrode to a terminal that

188

NETL: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Coal and Power Systems Fuel Cells SECA Logo Welcome to NETL's Fuel Cells Webpage. In partnership with private industry, educational institutions and national laboratories, we are leading the research, development, and demonstration of high efficiency, fuel flexible solid oxide fuel cells (SOFCs) and coal-based SOFC power generation systems for stationary market large central power plants under the Solid State Energy Conversion Alliance (SECA). The SECA cost reduction goal is to have SOFC systems capable of being manufactured at $400 per kilowatt by 2010. Concurrently, the scale-up, aggregation, and integration of the technology will progress in parallel leading to prototype validation of megawatt (MW)-class fuel flexible products by 2012 and 2015. The SECA coal-based systems goal is the development of large

189

Method of fabricating a monolithic solid oxide fuel cell  

SciTech Connect

In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array.

Minh, Nguyen Q. (Fountain Valley, CA); Horne, Craig R. (Redondo Beach, CA)

1994-01-01T23:59:59.000Z

190

Method of fabricating a monolithic solid oxide fuel cell  

DOE Patents (OSTI)

In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array. 10 figures.

Minh, N.Q.; Horne, C.R.

1994-03-01T23:59:59.000Z

191

Fuels processing for transportation fuel cell systems  

DOE Green Energy (OSTI)

Fuel cells primarily use hydrogen as the fuel. This hydrogen must be produced from other fuels such as natural gas or methanol. The fuel processor requirements are affected by the fuel to be converted, the type of fuel cell to be supplied, and the fuel cell application. The conventional fuel processing technology has been reexamined to determine how it must be adapted for use in demanding applications such as transportation. The two major fuel conversion processes are steam reforming and partial oxidation reforming. The former is established practice for stationary applications; the latter offers certain advantages for mobile systems and is presently in various stages of development. This paper discusses these fuel processing technologies and the more recent developments for fuel cell systems used in transportation. The need for new materials in fuels processing, particularly in the area of reforming catalysis and hydrogen purification, is discussed.

Kumar, R.; Ahmed, S.

1995-07-01T23:59:59.000Z

192

Distributed Energy Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Fuel Cells Energy Fuel Cells DOE Hydrogen DOE Hydrogen and and Fuel Cells Fuel Cells Coordination Meeting Fuel Cell Coordination Meeting June 2-3, 2003 Electricity Users Kathi Epping Kathi Epping Objectives & Barriers Distributed Energy OBJECTIVES * Develop a distributed generation PEM fuel cell system operating on natural gas or propane that achieves 40% electrical efficiency and 40,000 hours durability at $400-750/kW by 2010. BARRIERS * Durability * Heat Utilization * Power Electronics * Start-Up Time Targets and Status Integrated Stationary PEMFC Power Systems Operating on Natural Gas or Propane Containing 6 ppm Sulfur 40,000 30,000 15,000 Hours Durability 750 1,250 2,500 $/kWe Cost 40 32 30 % Electrical Efficiency Large (50-250 kW) Systems 40,000 30,000 >6,000 Hours Durability 1,000 1,500 3,000

193

Fuel cell market applications  

DOE Green Energy (OSTI)

This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

Williams, M.C.

1995-12-31T23:59:59.000Z

194

Molten carbonate fuel cell  

DOE Patents (OSTI)

A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

Kaun, Thomas D. (New Lenox, IL); Smith, James L. (Lemont, IL)

1987-01-01T23:59:59.000Z

195

Molten carbonate fuel cell  

DOE Patents (OSTI)

A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

Kaun, T.D.; Smith, J.L.

1986-07-08T23:59:59.000Z

196

Planar micro-direct methanol fuel cell prototyped by rapid powder blasting  

Science Conference Proceedings (OSTI)

We present a planar micro-direct methanol fuel cell (@m-DMFC) fabricated by rapid prototyping-powder blasting technology. Using an elastomeric mask, we pattern two parallel microfluidic channels in glass. The anode and cathode of the fuel cell are formed ... Keywords: Direct methanol fuel cell, Microchannel, Nafion, Powder blasting

M. Shen; S. Walter; L. Dovat; M. A. M. Gijs

2011-08-01T23:59:59.000Z

197

A Thermal Model to Evaluate Sub-Freezing Startup for a Direct Hydrogen Hybrid Fuel Cell Vehicle Polymer Electrolyte Fuel Cell Stack and System  

E-Print Network (OSTI)

and methods for using water produced by the fuel cells,"the amount of reaction water produced during starvation isalso allows liquid water produced at the cathode to leave

Sundaresan, Meena

2004-01-01T23:59:59.000Z

198

A Thermal Model to Evaluate Sub-Freezing Startup for a Direct Hydrogen Hybrid Fuel Cell Vehicle Polymer Electrolyte Fuel Cell Stack and System  

E-Print Network (OSTI)

and methods for using water produced by the fuel cells,"by ice formed from water produced in the stack reactions.and allows liquid water produced at the cathode to leave the

Sundaresan, Meena

2004-01-01T23:59:59.000Z

199

Modeling & Simulation - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

GCTool Computer Model Helps Focus Fuel Cell Vehicle Research Somewhere near Detroit, an automotive engineer stares at the ceiling, wondering how to squeeze 1% more efficiency out...

200

Opportunities with Fuel Cells  

Reports and Publications (EIA)

The concept for fuel cells was discovered in the nineteenth century. Today, units incorporating this technology are becoming commercially available for cogeneration applications.

Information Center

1994-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Hydrogen Fuel Cells  

Fuel Cell Technologies Publication and Product Library (EERE)

The fuel cell an energy conversion device that can efficiently capture and use the power of hydrogen is the key to making it happen.

202

Fuel Cell Development Status  

NLE Websites -- All DOE Office Websites (Extended Search)

Development Status Michael Short Systems Engineering Manager United Technologies Corporation Research Center Hamilton Sundstrand UTC Power UTC Fire & Security Fortune 50 corporation $52.9B in annual sales in 2009 ~60% of Sales are in building technologies Transportation Stationary Fuel Cells Space & Defense * Fuel cell technology leader since 1958 * ~ 550 employees * 768+ Active U.S. patents, more than 300 additional U.S. patents pending * Global leader in efficient, reliable, and sustainable fuel cell solutions UTC Power About Us PureCell ® Model 400 Solution Process Overview Power Conditioner Converts DC power to high-quality AC power 3 Fuel Cell Stack Generates DC power from hydrogen and air 2 Fuel Processor Converts natural gas fuel to hydrogen

203

Fuel Cell Demonstration Program  

DOE Green Energy (OSTI)

In an effort to promote clean energy projects and aid in the commercialization of new fuel cell technologies the Long Island Power Authority (LIPA) initiated a Fuel Cell Demonstration Program in 1999 with six month deployments of Proton Exchange Membrane (PEM) non-commercial Beta model systems at partnering sites throughout Long Island. These projects facilitated significant developments in the technology, providing operating experience that allowed the manufacturer to produce fuel cells that were half the size of the Beta units and suitable for outdoor installations. In 2001, LIPA embarked on a large-scale effort to identify and develop measures that could improve the reliability and performance of future fuel cell technologies for electric utility applications and the concept to establish a fuel cell farm (Farm) of 75 units was developed. By the end of October of 2001, 75 Lorax 2.0 fuel cells had been installed at the West Babylon substation on Long Island, making it the first fuel cell demonstration of its kind and size anywhere in the world at the time. Designed to help LIPA study the feasibility of using fuel cells to operate in parallel with LIPA's electric grid system, the Farm operated 120 fuel cells over its lifetime of over 3 years including 3 generations of Plug Power fuel cells (Lorax 2.0, Lorax 3.0, Lorax 4.5). Of these 120 fuel cells, 20 Lorax 3.0 units operated under this Award from June 2002 to September 2004. In parallel with the operation of the Farm, LIPA recruited government and commercial/industrial customers to demonstrate fuel cells as on-site distributed generation. From December 2002 to February 2005, 17 fuel cells were tested and monitored at various customer sites throughout Long Island. The 37 fuel cells operated under this Award produced a total of 712,635 kWh. As fuel cell technology became more mature, performance improvements included a 1% increase in system efficiency. Including equipment, design, fuel, maintenance, installation, and decommissioning the total project budget was approximately $3.7 million.

Gerald Brun

2006-09-15T23:59:59.000Z

204

Miniature ceramic fuel cell  

DOE Patents (OSTI)

A miniature power source assembly capable of providing portable electricity is provided. A preferred embodiment of the power source assembly employing a fuel tank, fuel pump and control, air pump, heat management system, power chamber, power conditioning and power storage. The power chamber utilizes a ceramic fuel cell to produce the electricity. Incoming hydro carbon fuel is automatically reformed within the power chamber. Electrochemical combustion of hydrogen then produces electricity.

Lessing, Paul A. (Idaho Falls, ID); Zuppero, Anthony C. (Idaho Falls, ID)

1997-06-24T23:59:59.000Z

205

Fuel Cell Technologies Office: About  

NLE Websites -- All DOE Office Websites (Extended Search)

variety of other fuels, including natural gas and renewable fuels such as methanol or biogas. Hydrogen and fuel cells can provide these benefits and address critical challenges in...

206

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

Di Croce, A.M.; Draper, R.

1993-11-02T23:59:59.000Z

207

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

1993-11-02T23:59:59.000Z

208

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe

209

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

3 to someone by E-mail 3 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

210

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

September 2012 to someone by E-mail September 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications

211

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe Program Presentations

212

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

August 2013 to someone by E-mail August 2013 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

213

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

October 2012 to someone by E-mail October 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications

214

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

April 2012 to someone by E-mail April 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives

215

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

3 to someone by E-mail 3 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe Program Presentations

216

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe

217

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

September/October 2013 to someone by E-mail September/October 2013 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on AddThis.com... Publications

218

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

August 2012 to someone by E-mail August 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

219

Fuel Cell Technologies Office: Hydrogen and Fuel Cell Manufacturing...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen and Fuel Cell Manufacturing R&D Workshop to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen and Fuel Cell Manufacturing R&D Workshop on Facebook Tweet...

220

Fuel Cell Technologies Office: DOE Hydrogen and Fuel Cells Coordinatio...  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells Coordination Meeting to someone by E-mail Share Fuel Cell Technologies Office: DOE Hydrogen and Fuel Cells Coordination Meeting on Facebook Tweet about...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Fuel Cells Vehicle Systems Analysis (Fuel Cell Freeze Investigation)  

DOE Green Energy (OSTI)

Presentation on Fuel Cells Vehicle Systems Analysis (Fuel Cell Freeze Investigation) for the 2005 Hydrogen, Fuel Cells & Infrastructure Technologies Program Annual Review held in Arlington, Virginia on May 23-26, 2005.

Pesaran, A.; Kim, G.; Markel, T.; Wipke, K.

2005-05-01T23:59:59.000Z

222

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and fuel cells offer great  

E-Print Network (OSTI)

and electricity for fuel cell and plug-in hybrid electric vehicles while using proven stationary fuel cell technol vehicles with its own fuel cell technology. Currently, advanced vehicle technologies are being evalu- ated in addition to hydrogen fuel for local demonstration fuel cell vehicles. As advanced vehicles begin to enter

223

Hydrogen Fuel Cell Engines  

E-Print Network (OSTI)

the batteries, and to power accessories like the air condi- tioner and heater. Hybrid electric cars can exceed#12;#12;Hydrogen Fuel Cell Engines MODULE 8: FUEL CELL HYBRID ELECTRIC VEHICLES CONTENTS 8.1 HYBRID ELECTRIC VEHICLES .................................................................................. 8-1 8

224

Low cost fuel cell diffusion layer configured for optimized anode water management  

DOE Patents (OSTI)

A fuel cell comprises a cathode gas diffusion layer, a cathode catalyst layer, an anode gas diffusion layer, an anode catalyst layer and an electrolyte. The diffusion resistance of the anode gas diffusion layer when operated with anode fuel is higher than the diffusion resistance of the cathode gas diffusion layer. The anode gas diffusion layer may comprise filler particles having in-plane platelet geometries and be made of lower cost materials and manufacturing processes than currently available commercial carbon fiber substrates. The diffusion resistance difference between the anode gas diffusion layer and the cathode gas diffusion layer may allow for passive water balance control.

Owejan, Jon P; Nicotera, Paul D; Mench, Matthew M; Evans, Robert E

2013-08-27T23:59:59.000Z

225

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies and Products Supported by the Fuel Cell Technologies Office, finds DOE funding has led to more than 360 hydrogen and fuel cell patents, 36 commercial...

226

NREL: Hydrogen and Fuel Cells Research - Fuel Cell System Contaminants...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell System Contaminants Material Screening Data NREL designed this interactive material selector tool to help fuel cell developers and material suppliers explore the results...

227

Fuel Cell Technologies Office: Reversible Fuel Cells Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reversible Fuel Cell Systems at Proton Energy, Mr. Everett Anderson, PROTON ON SITE Regenerative Fuel Cells for Energy Storage, Mr. Corky Mittelsteadt, Giner Electrochemical...

228

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Research, Development and Demonstration Plan* to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Multi-Year Research, Development and...

229

Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologie...  

NLE Websites -- All DOE Office Websites (Extended Search)

Adoption of Fuel Cell Technologies Federal Facilities Guide Read Procuring Fuel Cells for Stationary Power: A Guide for Federal Facility Decision Makers for step-by-step guidance...

230

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

231

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

offices, including Fuel Cell Technologies. Funding Opportunities SBIRSTTR Phase I Release 1 Technical Topics Announced for FY14-Hydrogen and Fuel Cell Topics Include...

232

Transitioning from Fuel Cells to Redox Flow Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Transitioning From Fuel Cells to Redox Transitioning From Fuel Cells to Redox Flow Cells T. Zawodzinski and Matt Mench University of Tennessee and ORNL Managed by UT-Battelle for the Department of Energy 2 Acknowledgments $$ DOE-OE EPRI GCEP NSF EPSCOR (TN SCORE) UTK Governor's Chair Fund Partner in Crime Matt Mench Managed by UT-Battelle for the Department of Energy 'Peeling the Onion' Personalized History of PEM Fuel Cells We May Recapitulate This for RFBs Catalysis Test System * Small Single Cell * Large Single Cell * Stack * System Layers of the Onion Hot Topic du Jour * Water Management, Membranes * Late '80's, early '90's * Reformate Tolerance, DMFC's * Mid '90's * High Temp Membranes * Late '90's * Durability * Early '00's Modeling * Membrane/ Water * Cathode * Impedance

233

Method for producing electricity from a fuel cell having solid-oxide ionic electrolyte  

DOE Patents (OSTI)

Stabilized quadrivalent cation oxide electrolytes are employed in fuel cells at elevated temperatures with a carbon and/or hydrogen containing fuel anode and an oxygen cathode. The fuel cell is operated at elevated temperatures with conductive metallic coatings as electrodes and desirably having the electrolyte surface blackened. Of particular interest as the quadrivalent oxide is zirconia.

Mason, David M. (Los Altos, CA)

1984-01-01T23:59:59.000Z

234

Fuel cell stack arrangements  

DOE Patents (OSTI)

Arrangements of stacks of fuel cells and ducts, for fuel cells operating with separate fuel, oxidant and coolant streams. An even number of stacks are arranged generally end-to-end in a loop. Ducts located at the juncture of consecutive stacks of the loop feed oxidant or fuel to or from the two consecutive stacks, each individual duct communicating with two stacks. A coolant fluid flows from outside the loop, into and through cooling channels of the stack, and is discharged into an enclosure duct formed within the loop by the stacks and seals at the junctures at the stacks.

Kothmann, Richard E. (Churchill Boro, PA); Somers, Edward V. (Murrysville, PA)

1982-01-01T23:59:59.000Z

235

What's Up With Fuel Cells? | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Up With Fuel Cells? Up With Fuel Cells? What's Up With Fuel Cells? June 8, 2010 - 7:30am Addthis Sean Large Intern with the Office of Energy Efficiency and Renewable Energy We hear a lot about renewables like wind and solar these days, but what's the deal with fuel cells and is there a future in them? The truth is, fuel cells have been around for some time now; the idea originated in the 1840's. Though fuel cells come in a variety of forms, they all work in the same general manner: three sandwiched segments - the anode, the electrolyte and the cathode. At each of these segments two different chemical reactions occur. The net result of the two reactions is that fuel is consumed, and an electrical current is created, which can be used to power electrical devices, normally referred to as the load. The only emissions are water or

236

Enhanced methanol utilization in direct methanol fuel cell  

DOE Patents (OSTI)

The fuel utilization of a direct methanol fuel cell is enhanced for improved cell efficiency. Distribution plates at the anode and cathode of the fuel cell are configured to distribute reactants vertically and laterally uniformly over a catalyzed membrane surface of the fuel cell. A conductive sheet between the anode distribution plate and the anodic membrane surface forms a mass transport barrier to the methanol fuel that is large relative to a mass transport barrier for a gaseous hydrogen fuel cell. In a preferred embodiment, the distribution plate is a perforated corrugated sheet. The mass transport barrier may be conveniently increased by increasing the thickness of an anode conductive sheet adjacent the membrane surface of the fuel cell.

Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM)

2001-10-02T23:59:59.000Z

237

Batteries and Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Collage of electric cars, plug, battery research lab Collage of electric cars, plug, battery research lab Batteries and Fuel Cells EETD researchers study the basic science and development of advanced batteries and fuel cells for transportation, electric grid storage, and other stationary applications. This research is aimed at developing more environmentally friendly technologies for generating and storing energy, including better batteries and fuel cells. Li-Ion and Other Advanced Battery Technologies Research conducted here on battery technology is aimed at developing low-cost rechargeable advanced electrochemical batteries for both automotive and stationary applications. The goal of fuel cell research is to provide the technologies for the successful commercialization of polymer-electrolyte and solid oxide fuel

238

Fuel cells: A handbook (Revision 3)  

SciTech Connect

Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

1994-01-01T23:59:59.000Z

239

Staged venting of fuel cell system during rapid shutdown  

DOE Patents (OSTI)

A venting methodology and system for rapid shutdown of a fuel cell apparatus of the type used in a vehicle propulsion system. H.sub.2 and air flows to the fuel cell stack are slowly bypassed to the combustor upon receipt of a rapid shutdown command. The bypass occurs over a period of time (for example one to five seconds) using conveniently-sized bypass valves. Upon receipt of the rapid shutdown command, the anode inlet of the fuel cell stack is instantaneously vented to a remote vent to remove all H.sub.2 from the stack. Airflow to the cathode inlet of the fuel cell stack gradually diminishes over the bypass period, and when the airflow bypass is complete the cathode inlet is also instantaneously vented to a remote vent to eliminate pressure differentials across the stack.

Clingerman, Bruce J. (Palmyra, NY); Doan, Tien M. (Columbia, MD); Keskula, Donald H. (Webster, NY)

2002-01-01T23:59:59.000Z

240

DOE Fuel Cell Technologies Office  

NLE Websites -- All DOE Office Websites (Extended Search)

500 2007 2013 Cumulative Number of Patents Fuel Cells ProductionDelivery Storage * DOE funding has led to 40 commercial hydrogen and fuel cell technologies and 65 emerging...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Fuel Cell Technologies Office: Multimedia  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

242

Fuel Cell Technologies Office: Budget  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

243

Fuel Cells | Open Energy Information  

Open Energy Info (EERE)

Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon Fuel Cells Jump to: navigation, search TODO: Add description List of Fuel Cells Incentives...

244

Fuel Cell Technologies Office: Education  

NLE Websites -- All DOE Office Websites (Extended Search)

& Local Governments For Early Adopters For Students & Educators Careers in Hydrogen & Fuel Cells Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells...

245

Fuel processing for fuel cell powered vehicles.  

DOE Green Energy (OSTI)

A number of auto companies have announced plans to have fuel cell powered vehicles on the road by the year 2004. The low-temperature polymer electrolyte fuel cells to be used in these vehicles require high quality hydrogen. Without a hydrogen-refueling infrastructure, these vehicles need to convert the available hydrocarbon fuels into a hydrogen-rich gas on-board the vehicle. Earlier analysis has shown that fuel processors based on partial oxidation reforming are well suited to meet the size and weight targets and the other performance-related needs of on-board fuel processors for light-duty fuel cell vehicles (1).

Ahmed, S.; Wilkenhoener, R.; Lee, S. H. D.; Carter, J. D.; Kumar, R.; Krumpelt, M.

1999-01-22T23:59:59.000Z

246

Modeling Low-Platinum-Loading Effects in Fuel-Cell Catalyst Layers  

E-Print Network (OSTI)

Loading Effects in Fuel-Cell Catalyst Layers Wonseok Yoon*CA 94720, USA The cathode catalyst layer within a proton-with low Pt-loading catalyst layers. Model results

Yoon, Wonseok

2013-01-01T23:59:59.000Z

247

Fuel Cell Technologies Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

4/3/2012 4/3/2012 eere.energy.gov Fuel Cell Technologies Overview Flow Cell Workshop Washington, DC Dr. Sunita Satyapal & Dr. Dimitrios Papageorgopoulos U.S. Department of Energy Fuel Cell Technologies Program 3/7/2011 Flow Cells for Energy Storage Workshop Purpose To understand the applied research and development needs and the grand challenges for the use of flow cells as energy-storage devices. Objectives 1. Understand the needs for applied research from stakeholders. 2. Gather input for future development of roadmaps and technical targets for flow cells for various applications. 3. Identify grand challenges and prioritize R&D needs. Flow cells combine the unique advantages of batteries and fuel cells and can offer benefits for multiple energy storage applications.

248

Fuel cell generator energy dissipator  

DOE Patents (OSTI)

An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a fuel cell generator when the electrical power output of the fuel cell generator is terminated. During a generator shut down condition, electrically resistive elements are automatically connected across the fuel cell generator terminals in order to draw current, thereby depleting the fuel

Veyo, Stephen Emery (Murrysville, PA); Dederer, Jeffrey Todd (Valencia, PA); Gordon, John Thomas (Ambridge, PA); Shockling, Larry Anthony (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

249

DOE Hydrogen and Fuel Cells Program: 2005 Annual Progress Report - Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Printable Version 2005 Annual Progress Report VII. Fuel Cells This section of the 2005 Progress Report for the DOE Hydrogen Program focuses on fuel cells. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Fuel Cells Sub-program Overview, Valri Lightner, Department of Energy (PDF 198 KB) A. Membrane Electrode Assemblies (MEA) Integrated Manufacturing for Advanced Membrane Electrode Assemblies, Emory S. De Castro, De Nora N.A., E-TEK Division (PDF 292 KB) Advanced MEAs for Enhanced Operating Conditions, Mark K. Debe, 3M Company (PDF 459 KB) Development of High-temperature Membranes and Improved Cathode Catalysts, Lesia Protsailo, UTC Fuel Cells (PDF 642 KB) Electrocatalyst Supports and Electrode Structures, Eric Brosha, Los

250

DOE Hydrogen and Fuel Cells Program: 2004 Annual Progress Report - Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Printable Version 2004 Annual Progress Report IV. Fuel Cells Each individual technical report is available as an individual Adobe Acrobat PDF for easier use. Download Adobe Reader. Fuel Cells Sub-Program Review, Patrick Davis, DOE (PDF 265 KB) A. MEAs and Catalysts Integrated Manufacturing for Advanced Membrane Electrode Assemblies, Emory DeCastro, De Nora (PDF 486 KB) Development of High-Temperature Membranes and Improved Cathode Catalysts Jeremy Meyers, UTC (PDF 595 KB) Advanced MEAs for Enhanced Operating Conditions, Amenable to High Volume Manufacture, Mark Debe, 3M (PDF 372 KB) Back to Top B. Membranes and MEAs High Temperature Polymer Membranes for Fuel Cells, Tom Zawodzinski, Case West Res. University (PDF 356 KB) Electrodes for Hydrogen-Air PEM Fuel Cells, Francisco Uribe, LANL

251

High Performance Catalytic Heat Exchanger for SOFC Systems - FuelCell Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Heat Catalytic Heat Exchanger for SOFC Systems-FuelCell Energy Background In a typical solid oxide fuel cell (SOFC) power generation system, hot (~900 °C) effluent gas from a catalytic combustor serves as the heat source within a high-temperature heat exchanger, preheating incoming fresh air for the SOFC's cathode. The catalytic combustor and the cathode air heat exchanger together represent the largest opportunity for cost

252

Nondestructive characterization methods for monolithic solid oxide fuel cells  

DOE Green Energy (OSTI)

Monolithic solid oxide fuel cells (MSOFCS) represent a potential breakthrough in fuel cell technology, provided that reliable fabrication methods can be developed. Fabrication difficulties arise in several steps of the processing: First is the fabrication of uniform thin (305 {mu}m) single-layer and trilayer green tapes (the trilayer tapes of anode/electrolyte/cathode and anode/interconnect/cathode must have similar coefficients of thermal expansion to sinter uniformly and to have the necessary electrochemical properties); Second is the development of fuel and oxidant channels in which residual stresses are likely to develop in the tapes; Third is the fabrication of a ``complete`` cell for which the bond quality between layers and the quality of the trilayers must be established; and Last, attachment of fuel and oxidant manifolds and verification of seal integrity. Purpose of this report is to assess nondestructive characterization methods that could be developed for application to laboratory, prototype, and full-scale MSOFCs.

Ellingson, W.A.

1993-01-01T23:59:59.000Z

253

Fuel Cell Technologies Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

States Energy Advisory Board (STEAB) States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3/14/2012 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov * Introduction - Technology and Market Overview * DOE Program Overview - Mission & Structure - R&D Progress - Demonstration & Deployments * State Activities - Examples of potential opportunities Outline 3 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov Fuel cells - convert chemical energy directly into electrical energy, bypassing inefficiencies associated with thermal energy conversion. Available energy is equal to the Gibbs free energy. Combustion Engines - convert chemical energy into thermal energy and

254

Hydrogen & Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy (DOE) is the lead federal agency for applied research and development (R&D) of cutting edge hydrogen and fuel cell technologies. DOE supports R&D that makes it...

255

Hydrogen and Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy (DOE) is the lead federal agency for applied research and development (R&D) of cutting edge hydrogen and fuel cell technologies. DOE supports R&D that makes it...

256

Energy Basics: Fuel Cell Vehicles  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

EERE: Energy Basics Fuel Cell Vehicles Photo of a blue car with 'The Road to Hydrogen' written on it, filling up at a hydrogen fueling station. Fuel cell vehicles, powered by...

257

Fuel Cell Technologies Office: Durability Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

Durability Working Group Durability Working Group The Durability Working Group meets twice per year to exchange information, create synergies, and collaboratively develop both an understanding of and tools for studying degradation mechanisms of polymer electrolyte fuel cell stacks. Its members include principle investigators and supporting personnel from U.S. Department of Energy (DOE)-funded durability projects. More information on DOE durability activities can be found in the Multi-Year Research, Development, and Demonstration Plan. Description Technical Targets Meetings Contacts Description DOE durability targets for stationary and transportation fuel cells are 40,000 hours and 5,000 hours, respectively, under realistic operating conditions. In the most demanding applications, realistic operating conditions include impurities in the fuel and air, starting and stopping, freezing and thawing, and humidity and load cycles that result in stresses on the chemical and mechanical stability of the fuel cell materials, components, and interfaces. Degradation-exacerbating conditions resulting from cyclic operation include hydrogen starvation, differential pressure imbalance, oxidation-reduction cycling, and oxygen ingress to the anode, resulting in high cathode potentials. Significant progress has been made in determining the degradation mechanisms of fuel cell components and developing improved materials. However, as stated in the 2008 DOE Fuel Cell Solicitation, there is a need for further research and development in the following areas:

258

Fuel cell electrode and method of preparation  

DOE Patents (OSTI)

A fuel cell having good resistance to compressive creep includes electrodes having a superstructure of porous electrically conductive foam with surface sections adjacent to opposing surfaces of an electrolyte matrix impregnated with electrode catalyst materials. The catalyst materials are affixed in sections contiguous to an inner major surface by sinter bonding, electrochemical bonding or restrictive interstitial spacing. The outer sections of the porous plaque thickness are reserved for gas distribution to the electrode catalyst. Oxidant and fuel gases can be separately manifolded into alternate sides of a fuel cell stack by sealing opposing edges of the porous plaques containing the anode material in one set of opposing side surfaces and sealing opposing edges of the porous plaque containing cathode material in alternate side surfaces of the stack.

Kaun, T.D

1984-03-02T23:59:59.000Z

259

Rapidly refuelable fuel cell  

DOE Patents (OSTI)

This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

Joy, Richard W. (Santa Clara, CA)

1983-01-01T23:59:59.000Z

260

Composite fuel cell membranes  

DOE Patents (OSTI)

A bilayer or trilayer composite ion exchange membrane is described suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.

Plowman, K.R.; Rehg, T.J.; Davis, L.W.; Carl, W.P.; Cisar, A.J.; Eastland, C.S.

1997-08-05T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES  

DOE Green Energy (OSTI)

A simple, approximate analysis of the effect of differing cathode and anode areas on the measurement of cell performance on anode-supported solid oxide fuel cells, wherein the cathode area is smaller than the anode area, is presented. It is shown that the effect of cathode area on cathode polarization, on electrolyte contribution, and on anode resistance, as normalized on the basis of the cathode area, is negligible. There is a small but measurable effect on anode polarization, which results from concentration polarization. Effectively, it is the result of a greater amount of fuel transported to the anode/electrolyte interface in cases wherein the anode area is larger than the cathode area. Experiments were performed on cells made with differing cathode areas and geometries. Cathodic and anodic overpotentials measured using reference electrodes, and the measured ohmic area specific resistances by current interruption, were in good agreement with expectations based on the analysis presented. At 800 C, the maximum power density measured with a cathode area of {approx}1.1 cm{sup 2} was {approx}1.65 W/cm{sup 2} compared to {approx}1.45 W/cm{sup 2} for cathode area of {approx}2 cm{sup 2}, for anode thickness of {approx}1.3 mm, with hydrogen as the fuel and air as the oxidant. At 750 C, the measured maximum power densities were {approx}1.3 W/cm{sup 2} for the cell with cathode area {approx}1.1 cm{sup 2}, and {approx}1.25 W/cm{sup 2} for the cell with cathode area {approx}2 cm{sup 2}.

Anil V. Virkar

2001-06-21T23:59:59.000Z

262

Seventh Edition Fuel Cell Handbook  

DOE Green Energy (OSTI)

Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

NETL

2004-11-01T23:59:59.000Z

263

Breakthrough Vehicle Development - Fuel Cells  

Fuel Cell Technologies Publication and Product Library (EERE)

Document describing research and development program for fuel cell power systems for transportation applications.

264

FUEL CELL TECHNOLOGIES PROGRAM Technologies  

E-Print Network (OSTI)

.eere.energy.gov/informationcenter hydrogen and electricity for fuel cell and plug-in hybrid electric vehicles while using proven stationary vehicles with its own fuel cell technology. Currently, advanced vehicle technologies are being evalu- ated and fuel cells offer great promise for our energy future. Fuel cell vehicles are not yet commercially

265

Argonne TDC: Fuel Cell Technologies  

Emergency Response. Engineering. Environmental Research. Fuel Cells. Imaging Technology. Material Science. Nanotechnology. Physical Sciences. Sensor ...

266

Fuel Cell Technologies Program Overview  

E-Print Network (OSTI)

Cell TypesFuel Cell Types Note: ITSOFC is intermediate temperature SOFC and TSOFC is tubular SOFC #12

267

Simulated coal-gas-fueled molten carbonate fuel cell development program  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

268

Fuel Cell Technologies Office: Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentations to Presentations to someone by E-mail Share Fuel Cell Technologies Office: Presentations on Facebook Tweet about Fuel Cell Technologies Office: Presentations on Twitter Bookmark Fuel Cell Technologies Office: Presentations on Google Bookmark Fuel Cell Technologies Office: Presentations on Delicious Rank Fuel Cell Technologies Office: Presentations on Digg Find More places to share Fuel Cell Technologies Office: Presentations on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings Webinars Data Records Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells

269

Fuel Cell Technologies Office: Glossary  

NLE Websites -- All DOE Office Websites (Extended Search)

Glossary to someone by Glossary to someone by E-mail Share Fuel Cell Technologies Office: Glossary on Facebook Tweet about Fuel Cell Technologies Office: Glossary on Twitter Bookmark Fuel Cell Technologies Office: Glossary on Google Bookmark Fuel Cell Technologies Office: Glossary on Delicious Rank Fuel Cell Technologies Office: Glossary on Digg Find More places to share Fuel Cell Technologies Office: Glossary on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Webinars Data Records Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Glossary

270

Layed Perovskite PRBA0.5SR0.5CO205 as High Performance Cathode for Solid Oxide Fuels Using Photon Conducting Electrolyte  

DOE Green Energy (OSTI)

The layered perovskite PrBa{sub 0.5}Sr{sub 0.5}Co{sub 2}O{sub 5+{delta}} (PBSC) was investigated as a cathode material for a solid oxide fuel cell using a proton-conducting electrolyte based on BaCe{sub 0.7}Y{sub 0.2}Zr{sub 0.1}O{sub 3-{delta}} (BCYZ). The sintering conditions for the PBSC-BCYZ composite cathode were optimized resulting in the lowest area-specific resistance and apparent activation energy obtained with the cathode sintered at 1200 C for 2h. The maximum power densities of the PBSC-BCYZ/BZCY/NiO-BCYZ cell were 0.179, 0.274, 0.395, and 0.522 Wcm{sup -2} at 550, 600, 650, and 700 C, respectively with a 15{micro}m thick electrolyte. A relatively low cell interfacial polarization resistance of 0.132 {Omega}cm{sup 2} at 700 C indicated that the PBSC-BCYZ could be a good cathode candidate for intermediate temperature SOFCs with proton-conducting electrolyte.

Brinkman, K.

2010-05-05T23:59:59.000Z

271

Biomass Fuel Cell Systems - DOE Hydrogen and Fuel Cells Program...  

NLE Websites -- All DOE Office Websites (Extended Search)

Utilize ceramic microchannel reactor technology for * reforming of natural gas and biogas fuels for subsequent electrochemical oxidation within a solid-oxide fuel cell (SOFC)....

272

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

& & Renewable Energy Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Pete Devlin Fuel Cell Technologies Program United States Department of Energy Federal Utility Partnership Working Group April 14 th , 2010 2 * DOE Fuel Cell Market Transformation Overview * Overview of CHP Concept * Stationary Fuel Cells for CHP Applications * Partnering and Financing (Sam Logan) * Example Project Outline 3 Fuel Cells: Addressing Energy Challenges Energy Efficiency and Resource Diversity  Fuel cells offer a highly efficient way to use diverse fuels and energy sources. Greenhouse Gas Emissions and Air Pollution:  Fuel cells can be powered by emissions-free fuels that are produced from clean, domestic resources. Stationary Power (including CHP & backup power)

273

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cell devices to charge electronics such as cell phones and audio players. EERE funding for hydrogen and fuel cells has led to more than 450 patents, 60 commercial...

274

Solid Oxide Fuel Cells: Technology Status  

Science Conference Proceedings (OSTI)

In its most common configuration, solid oxide fuel cell (SOFC) uses an oxygen ion conducting ceramic electrolyte membrane, perovskite cathode and nickel cermet anode electrode. Cells operate in the 600-1000 C temperature range and utilize metallic or ceramic current collectors for cell-to-cell interconnection. Recent development in engineered electrode architectures, component materials chemistry, cell and stack designs and fabrication processes have led to significant improvement in the electrical performance and performance stability as well as reduction in the operating temperature of such cells. Large kW-size power generation systems have been designed and field demonstrated. This paper reviews the status of SOFC power generation systems with emphasis on cell and stack component materials, electrode reactions, materials reactions and corrosion processes

Singh, Prabhakar; Minh, Nguyen Q.

2004-08-01T23:59:59.000Z

275

Fuel processor for fuel cell power system  

DOE Patents (OSTI)

A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

Vanderborgh, Nicholas E. (Los Alamos, NM); Springer, Thomas E. (Los Alamos, NM); Huff, James R. (Los Alamos, NM)

1987-01-01T23:59:59.000Z

276

2011 DOE Hydrogen and Fuel Cells Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

85 85 FY 2011 Annual Progress Report DOE Hydrogen and Fuel Cells Program 3M Company V.B.1 Effect of System Contaminants on PEMFC Performance and Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . 640 V.C.1 Membranes and MEAs for Dry, Hot Operating Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662 V.C.6 Novel Approaches to Immobilized Heteropoly Acid (HPA) Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 685 V.D.1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 699 V.D.3 Durable Catalysts for Fuel Cell Protection During Transient Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .714

277

Hydrogen Fuel Cell Engines  

E-Print Network (OSTI)

#12;#12;Hydrogen Fuel Cell Engines MODULE 11:GLOSSARY AND CONVERSIONS CONTENTS 11.1 GLOSSARY Cell Engines MODULE 11:GLOSSARY AND CONVERSIONS OBJECTIVES This module is for reference only. Hydrogen MODULE 11: GLOSSARY AND CONVERSIONS PAGE 11-1 11.1 Glossary This glossary covers words, phrases

278

Reactant gas composition for fuel cell potential control  

DOE Patents (OSTI)

A fuel cell (10) system in which a nitrogen (N.sub.2) gas is used on the anode section (11) and a nitrogen/oxygen (N.sub.2 /O.sub.2) gaseous mix is used on the cathode section (12) to maintain the cathode at an acceptable voltage potential during adverse conditions occurring particularly during off-power conditions, for example, during power plant shutdown, start-up and hot holds. During power plant shutdown, the cathode section is purged with a gaseous mixture of, for example, one-half percent (0.5%) oxygen (O.sub.2) and ninety-nine and a half percent (99.5%) nitrogen (N.sub.2) supplied from an ejector (21) bleeding in air (24/28) into a high pressure stream (27) of nitrogen (N.sub.2) as the primary or majority gas. Thereafter the fuel gas in the fuel processor (31) and the anode section (11) is purged with nitrogen gas to prevent nickel (Ni) carbonyl from forming from the shift catalyst. A switched dummy electrical load (30) is used to bring the cathode potential down rapidly during the start of the purges. The 0.5%/99.5% O.sub.2 /N.sub.2 mixture maintains the cathode potential between 0.3 and 0.7 volts, and this is sufficient to maintain the cathode potential at 0.3 volts for the case of H.sub.2 diffusing to the cathode through a 2 mil thick electrolyte filled matrix and below 0.8 volts for no diffusion at open circuit conditions. The same high pressure gas source (20) is used via a "T" juncture ("T") to purge the anode section and its associated fuel processor (31).

Bushnell, Calvin L. (Glastonbury, CT); Davis, Christopher L. (Tolland, CT)

1991-01-01T23:59:59.000Z

279

Hawaii Fuel Cell Test Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Test Facility presented to DOE Hydrogen Codes and Standards Coordinating Committee Fuel Purity Specifications Workshop Renaissance Hollywood Hotel by Rick Rocheleau...

280

Handbook of fuel cell performance  

DOE Green Energy (OSTI)

The intent of this document is to provide a description of fuel cells, their performances and operating conditions, and the relationship between fuel processors and fuel cells. This information will enable fuel cell engineers to know which fuel processing schemes are most compatible with which fuel cells and to predict the performance of a fuel cell integrated with any fuel processor. The data and estimates presented are for the phosphoric acid and molten carbonate fuel cells because they are closer to commercialization than other types of fuel cells. Performance of the cells is shown as a function of operating temperature, pressure, fuel conversion (utilization), and oxidant utilization. The effect of oxidant composition (for example, air versus O/sub 2/) as well as fuel composition is examined because fuels provided by some of the more advanced fuel processing schemes such as coal conversion will contain varying amounts of H/sub 2/, CO, CO/sub 2/, CH/sub 4/, H/sub 2/O, and sulfur and nitrogen compounds. A brief description of fuel cells and their application to industrial, commercial, and residential power generation is given. The electrochemical aspects of fuel cells are reviewed. The phosphoric acid fuel cell is discussed, including how it is affected by operating conditions; and the molten carbonate fuel cell is discussed. The equations developed will help systems engineers to evaluate the application of the phosphoric acid and molten carbonate fuel cells to commercial, utility, and industrial power generation and waste heat utilization. A detailed discussion of fuel cell efficiency, and examples of fuel cell systems are given.

Benjamin, T.G.; Camara, E.H.; Marianowski, L.G.

1980-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Internal reforming fuel cell assembly with simplified fuel feed  

DOE Patents (OSTI)

A fuel cell assembly in which fuel cells adapted to internally reform fuel and fuel reformers for reforming fuel are arranged in a fuel cell stack. The fuel inlet ports of the fuel cells and the fuel inlet ports and reformed fuel outlet ports of the fuel reformers are arranged on one face of the fuel cell stack. A manifold sealing encloses this face of the stack and a reformer fuel delivery system is arranged entirely within the region between the manifold and the one face of the stack. The fuel reformer has a foil wrapping and a cover member forming with the foil wrapping an enclosed structure.

Farooque, Mohammad (Huntington, CT); Novacco, Lawrence J. (Brookfield, CT); Allen, Jeffrey P. (Naugatuck, CT)

2001-01-01T23:59:59.000Z

282

Fuel Cells & Renewable Portfolio Standards  

E-Print Network (OSTI)

.....................................................12 SOFC Battery Range Extender Auxiliary Power Unit (SOFC) as Military APU Replacements" (presentation, DOD-DOE Workshop on Fuel Cells in Aviation cell plasma lighting demonstration, a solid oxide fuel cell (SOFC) battery range extender APU

283

Solid oxide fuel cell matrix and modules  

DOE Patents (OSTI)

Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

Riley, Brian (Willimantic, CT)

1990-01-01T23:59:59.000Z

284

Fuel cell with metal screen flow-field  

DOE Patents (OSTI)

A polymer electrolyte membrane (PEM) fuel cell is provided with electrodes supplied with a reactant on each side of a catalyzed membrane assembly (CMA). The fuel cell includes a metal mesh defining a rectangular flow-field pattern having an inlet at a first corner and an outlet at a second corner located on a diagonal from the first corner, wherein all flow paths from the inlet to the outlet through the square flow field pattern are equivalent to uniformly distribute the reactant over the CMA. In a preferred form of metal mesh, a square weave screen forms the flow-field pattern. In a particular characterization of the present invention, a bipolar plate electrically connects adjacent fuel cells, where the bipolar plate includes a thin metal foil having an anode side and a cathode side; a first metal mesh on the anode side of the thin metal foil; and a second metal mesh on the cathode side of the thin metal foil. In another characterization of the present invention, a cooling plate assembly cools adjacent fuel cells, where the cooling plate assembly includes an anode electrode and a cathode electrode formed of thin conducting foils; and a metal mesh flow field there between for distributing cooling water flow over the electrodes to remove heat generated by the fuel cells. 11 figs.

Wilson, M.S.; Zawodzinski, C.

1998-08-25T23:59:59.000Z

285

Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure  

NLE Websites -- All DOE Office Websites (Extended Search)

International Hydrogen International Hydrogen Fuel and Pressure Vessel Forum to someone by E-mail Share Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Facebook Tweet about Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Twitter Bookmark Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Google Bookmark Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Delicious Rank Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Digg Find More places to share Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on AddThis.com... Publications Program Publications Technical Publications

286

Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery and Delivery and Fueling (Text Alternative Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Google Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Delicious Rank Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on AddThis.com... Publications Program Publications

287

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel  

E-Print Network (OSTI)

- tions, distributed power generation, and cogeneration (in which excess heat released during electricity the imported petroleum we currently use in our cars and trucks. Why Fuel Cells? Fuel cells directly convert the chemical energy in hydrogen to electricity, with pure water and potentially useful heat as the only

288

Real-time mass spectrometric study of the methanol crossover in a direct methanol fuel cell  

Science Conference Proceedings (OSTI)

The products of methanol crossover through the acid-doped polybenzimidazole polymer electrolyte membrane (PBI PEM) to the cathode of a prototype direct methanol fuel cell (DMFC) were analyzed using multipurpose electrochemical mass spectrometry (MPEMS) coupled to the cathode exhaust gas outlet. It was found that the methanol crossing over reacts almost quantitatively to CO{sub 2} at the cathode with the platinum of the cathode acting as a heterogeneous catalyst. The cathode open-circuit potential is inversely proportional to the amount of CO{sub 2} formed. A poisoning effect on the oxygen reduction also was found. Methods for the estimation of the methanol crossover rate at operating fuel cells are suggested.

Wang, J.T.; Wasmus, S.; Savinell, R.F. [Case Western Reserve Univ., Cleveland, OH (United States)

1996-04-01T23:59:59.000Z

289

PEM FUEL CELL TURBOCOMPRESSOR  

DOE Green Energy (OSTI)

The objective is to assist the Department of Energy in the development of a low cost, reliable and high performance air compressor/expander. Technical Objective 1: Perform a turbocompressor systems PEM fuel cell trade study to determine the enhanced turbocompressor approach. Technical Objective 2: Using the results from technical objective 1, an enhanced turbocompressor will be fabricated. The design may be modified to match the flow requirements of a selected fuel cell system developer. Technical Objective 3: Design a cost and performance enhanced compact motor and motor controller. Technical Objective 4: Turbocompressor/motor controller development.

Mark K. Gee

2004-04-01T23:59:59.000Z

290

Indirect-fired gas turbine bottomed with fuel cell  

DOE Patents (OSTI)

An indirect-heated gas turbine cycle is bottomed with a fuel cell cycle with the heated air discharged from the gas turbine being directly utilized at the cathode of the fuel cell for the electricity-producing electrochemical reaction occurring within the fuel cell. The hot cathode recycle gases provide a substantial portion of the heat required for the indirect heating of the compressed air used in the gas turbine cycle. A separate combustor provides the balance of the heat needed for the indirect heating of the compressed air used in the gas turbine cycle. Hot gases from the fuel cell are used in the combustor to reduce both the fuel requirements of the combustor and the NOx emissions therefrom. Residual heat remaining in the air-heating gases after completing the heating thereof is used in a steam turbine cycle or in an absorption refrigeration cycle. Some of the hot gases from the cathode can be diverted from the air-heating function and used in the absorption refrigeration cycle or in the steam cycle for steam generating purposes.

Micheli, Paul L. (Morgantown, WV); Williams, Mark C. (Morgantown, WV); Parsons, Edward L. (Morgantown, WV)

1995-01-01T23:59:59.000Z

291

Indirect-fired gas turbine bottomed with fuel cell  

DOE Patents (OSTI)

An indirect-heated gas turbine cycle is bottomed with a fuel cell cycle with the heated air discharged from the gas turbine being directly utilized at the cathode of the fuel cell for the electricity-producing electrochemical reaction occurring within the fuel cell. The hot cathode recycle gases provide a substantial portion of the heat required for the indirect heating of the compressed air used in the gas turbine cycle. A separate combustor provides the balance of the heat needed for the indirect heating of the compressed air used in the gas turbine cycle. Hot gases from the fuel cell are used in the combustor to reduce both the fuel requirements of the combustor and the NOx emissions therefrom. Residual heat remaining in the air-heating gases after completing the heating thereof is used in a steam turbine cycle or in an absorption refrigeration cycle. Some of the hot gases from the cathode can be diverted from the air-heating function and used in the absorption refrigeration cycle or in the steam cycle for steam generating purposes.

Micheli, P.L.; Williams, M.C.; Parsons, E.L.

1993-12-31T23:59:59.000Z

292

Indirect-fired gas turbine bottomed with fuel cell  

DOE Patents (OSTI)

An indirect-heated gas turbine cycle is bottomed with a fuel cell cycle with the heated air discharged from the gas turbine being directly utilized at the cathode of the fuel cell for the electricity-producing electrochemical reaction occurring within the fuel cell. The hot cathode recycle gases provide a substantial portion of the heat required for the indirect heating of the compressed air used in the gas turbine cycle. A separate combustor provides the balance of the heat needed for the indirect heating of the compressed air used in the gas turbine cycle. Hot gases from the fuel cell are used in the combustor to reduce both the fuel requirements of the combustor and the NOx emissions therefrom. Residual heat remaining in the air-heating gases after completing the heating thereof is used in a steam turbine cycle or in an absorption refrigeration cycle. Some of the hot gases from the cathode can be diverted from the air-heating function and used in the absorption refrigeration cycle or in the steam cycle for steam generating purposes. 1 fig.

Micheli, P.L.; Williams, M.C.; Parsons, E.L.

1995-09-12T23:59:59.000Z

293

Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Bus Workshop Fuel Cell Bus Workshop The U.S. Department of Energy (DOE) and the U.S. Department of Transportation (DOT) held a Fuel Cell Bus Workshop on June 7, 2010 in Washington, D.C. in conjunction with the DOE Hydrogen and Fuel Cell Program Annual Merit Review. The workshop plenary and breakout session brought together technical experts from industry, end users, academia, DOE national laboratories, and other government agencies to address the status and technology needs of fuel cell powered buses. Meeting Summary Joint Fuel Cell Bus Workshop Summary Report Presentations Fuel Cell Bus Workshop Overview & Purpose, Dimitrios Papageorgopoulos, DOE Users Perspective on Advanced Fuel Cell Bus Technology, Nico Bouwkamp, CaFCP and Leslie Eudy, NREL Progress and Challenges for PEM Transit Fleet Applications, Tom Madden, UTC Power, LLC

294

DOE Hydrogen and Fuel Cells Program: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office FY2014 Budget Request Briefing on April 12 Apr 9, 2013 The Fuel Cell Technologies Office will hold a budget briefing for stakeholders on Friday, April...

295

Fuel Cell Technologies Office: Hydrogen and Fuel Cell Manufacturing...  

NLE Websites -- All DOE Office Websites (Extended Search)

and Fuel Cell Manufacturing R&D Workshop The National Renewable Energy Laboratory (NREL) hosted a Hydrogen and Fuel Cell Manufacturing R&D Workshop August 11-12, 2011, in...

296

Fuel Cell Technologies Office: Biogas and Fuel Cells Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Biogas and Fuel Cells Workshop The U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory (NREL) held a Biogas and Fuel Cells Workshop June 11-13, 2012, in...

297

Fuel Cell Technologies Office: New Fuel Cell Projects Meeting  

NLE Websites -- All DOE Office Websites (Extended Search)

Agenda (PDF 83 KB) New Fuel Cell Projects Overview (PDF 1.2 MB), P. Davis, DOE New Fuel Cell Projects Overview (PDF 609 KB), N. Garland, DOE Membranes Membranes and MEAs for Dry,...

298

NREL: Hydrogen and Fuel Cells Research - Fuel Cell Electric Vehicle...  

NLE Websites -- All DOE Office Websites (Extended Search)

the cost and increasing the performance of fuel cell propulsion systems, and most major vehicle manufacturers are geared to launch fuel cell electric vehicles in the U.S. market...

299

DOE Hydrogen and Fuel Cells Program: Hydrogen and Fuel Cells...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen and Fuel Cells Program Presents Annual Merit Review Awards May 21, 2013 The U.S. Department of Energy's (DOE's) Hydrogen and Fuel Cells Program presented its annual awards...

300

The Stirred Tank Reactor Polymer Electrolyte Membrane Fuel Cell  

E-Print Network (OSTI)

The design and operation of a differential Polymer Electrolyte Membrane (PEM) fuel cell is described. The fuel cell design is based on coupled Stirred Tank Reactors (STR); the gas phase in each reactor compartment was well mixed. The characteristic times for reactant flow, gas phase diffusion and reaction were chosen so that the gas compositions at both the anode and cathode are uniform. The STR PEM fuel cell is one-dimensional; the only spatial gradients are transverse to the membrane. The STR PEM fuel cell was employed to examine fuel cell start- up, and its dynamic responses to changes in load, temperature and reactant flow rates. Multiple time scales in systems response are found to correspond to water absorption by the membrane, water transport through the membrane and stress-related mechanical changes of the membrane.

Benziger, J; Karnas, E; Moxley, J; Teuscher, C; Kevrekidis, Yu G; Benziger, Jay

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Fuel Cell Technologies Office: Technology Validation  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office: Technology Validation to someone by E-mail Share Fuel Cell Technologies Office: Technology Validation on Facebook Tweet about Fuel Cell Technologies...

302

Hydrogen, Fuel Cells, & Infrastructure - Program Areas - Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cell Welcome> Program Areas> Program Areas Hydrogen, Fuel Cells & Infrastructure Production & Delivery | Storage | Fuel Cell R&D | Systems Integration & Analysis | Safety...

303

Microfluidic Microbial Fuel Cells for Microstructure Interrogations  

E-Print Network (OSTI)

Sediment microbial fuel cells demonstrating marine (left)Model of hydrogen fuel cell kinetic losses including5 FutureWork 5.1 Microfluidic Microbial Fuel Cell Continued

Parra, Erika Andrea

2010-01-01T23:59:59.000Z

304

Canadian Fuel Cell Commercialization Roadmap Update: Progress...  

Open Energy Info (EERE)

Fuel Cell Commercialization Roadmap Update: Progress of Canada's Hydrogen and Fuel Cell Industry Jump to: navigation, search Name Canadian Fuel Cell Commercialization Roadmap...

305

Air Breathing Direct Methanol Fuel Cell  

DOE Patents (OSTI)

A method for activating a membrane electrode assembly for a direct methanol fuel cell is disclosed. The method comprises operating the fuel cell with humidified hydrogen as the fuel followed by running the fuel cell with methanol as the fuel.

Ren; Xiaoming (Los Alamos, NM)

2003-07-22T23:59:59.000Z

306

Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Vehicle Tax Fuel Cell Vehicle Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Google Bookmark Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Delicious Rank Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Vehicle Tax Credit South Carolina residents that claim the federal fuel cell vehicle tax credit are eligible for a state income tax credit equal to 20% of the

307

Journal of Power Sources 140 (2005) 331339 Numerical study of a flat-tube high power density solid oxide fuel cell  

E-Print Network (OSTI)

· Research and development in MCFC, SOFC, PEM and Fuels #12;FuelCell Energy, the FuelCell Energy logo, Direct Electrolyte Anode Cathode Electrolyte FCE SOFC Systems Background SOFC MW Module FCE utilizes VPS (Versa Power Systems) fuel cell technology in FCEs SOFC stack modules and systems. FCE/VPS team is engaged

308

Non-Kinetic Losses Caused by Electrochemical Carbon Corrosion in PEM Fuel Cells  

SciTech Connect

This paper presented non-kinetic losses in PEM fuel cells under an accelerated stress test of catalyst support. The cathode with carbon-supported Pt catalyst was prepared and characterized with potential hold at 1.2 V vs. SHE in PEM fuel cells. Irreversible losses caused by carbon corrosion were evaluated using a variety of electrochemical characterizations including cyclic voltammetry, linear sweep voltammetry, electrochemical impedance spectroscopy, and polarization technique. Ohmic losses at the cathode with potential hold were determined using its capacitive responses. Concentration losses in PEM fuel cells were analyzed in terms of Tafel behavior and thin film/flooded-agglomerate dynamics.

Park, Seh Kyu; Shao, Yuyan; Viswanathan, Vilayanur V.; Liu, Jun; Wang, Yong

2012-05-01T23:59:59.000Z

309

Organic fuel cells and fuel cell conducting sheets  

DOE Patents (OSTI)

A passive direct organic fuel cell includes an organic fuel solution and is operative to produce at least 15 mW/cm.sup.2 when operating at room temperature. In additional aspects of the invention, fuel cells can include a gas remover configured to promote circulation of an organic fuel solution when gas passes through the solution, a modified carbon cloth, one or more sealants, and a replaceable fuel cartridge.

Masel, Richard I. (Champaign, IL); Ha, Su (Champaign, IL); Adams, Brian (Savoy, IL)

2007-10-16T23:59:59.000Z

310

Precious Metal Recovery from Fuel Cell MEA's  

DOE Green Energy (OSTI)

One of the next-generation power sources is the proton exchange membrane (PEM) fuel cell, which runs on pure hydrogen or hydrogen-rich reformate. At the heart of the PEM fuel cell is a membrane electrode assembly (MEA). The MEA is a laminate composed of electrode layers sandwiched between outer layers, fabricated from either carbon fiber or fabric and which control the diffusion of reactant gases, and the inner polymer mebrane. Hydrogen is oxidized at the anode to form protons, which migrate through the membrane and react with oxygen at the cathode to form water. In this type of fuel cell, platinum catalyzes the reactions at both electrodes. Realization of a future that includes ubiquitous use of hydrogen fuel cell-powered vehicles will be partially contingent on a process for recycling components of the fuel cell membrane electrode assemblies. In aggregate, the platinum used for the fuel cell will represent a large pool of this precious metal, and the efficient recycling of Pt from MEA's will be a cost-enabling factor for success of this technology. Care must be taken in the reclamation process because of the presence of fluoropolymers in the MEA. While Pt is normally recovered with high yield, the combustion process commonly applied to remove an organic matrix will also liberate a large volume of HF, a gas which is both toxic and corrosive. Carbonyl fluoride, which has a recommended exposure limit of 2ppmv, is another undesirable product of fluoroploymer combustion. In 2003, the Department of Energy awarded Engelhard Corporation an 80% cost share grant for a five-year project budgeted at $5.9MM. The principal objective is reclaiming platinum from fuel cell MEA's without producing fluorine-containing emissions. Over the last three years, Engelhard has approached the problem from several directions in balancing the two goals: a commercially-viable recycling process and an environmentally favorable one. Working with both fresh and aged fuel cells, it has been shown that precious metals can be liberated at high yield using microwave assisted acid digestion, but exposure of the gas diffusion electrode surfaces is required. A low-cost solvent-stripping process has been identified for two geometries of fuel cell MEA's: GDL and GDE. This paper will detail progress made in realizing a practical, "green" process for recovery of Pt from PEM fuel cell MEA's

Lawrence Shore

2006-11-16T23:59:59.000Z

311

Fuel Cell Technologies Office: Multimedia  

NLE Websites -- All DOE Office Websites (Extended Search)

uses of fuel cell technologies. MotorWeek H2 on the Horizon Video Learn how car makers, energy suppliers, and the government are bringing fuel cell electric vehicles and hydrogen...

312

Fuel Cell Technologies Office: Databases  

NLE Websites -- All DOE Office Websites (Extended Search)

Efficiency and Renewable Energy Fuel Cell Technologies Office Databases The Fuel Cell Technologies Office is developing databases to make it easier for users to find up-to-date...

313

Fuel Cell Projects Kickoff Meeting  

NLE Websites -- All DOE Office Websites (Extended Search)

of Cost-Competitive Fuel Cell Stacks James Cross, Nuvera 4:30 Fuel Cell Fundamentals at Low and Subzero Temperatures Adam Weber, LBNL 4:50 Development and Validation of...

314

Fuel Cell Technologies Office: Events  

NLE Websites -- All DOE Office Websites (Extended Search)

Events Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Events to someone by E-mail Share Fuel Cell Technologies Office: Events on Facebook Tweet...

315

DOE Fuel Cell Subprogram (Presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

* By 2010, develop a fuel cell system for consumer electronics (<50 W) with an energy density of 1,000 WhL. * By 2010, develop a fuel cell system for auxiliary power units (3-30...

316

2009 Fuel Cell Market Report  

Fuel Cell Technologies Publication and Product Library (EERE)

Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

317

Energy Conversion/Fuel Cells  

Science Conference Proceedings (OSTI)

About this Symposium. Meeting, Materials Science & Technology 2011. Symposium, Energy Conversion/Fuel Cells. Sponsorship, MS&T Organization.

318

Fuel Cell Technologies Office: Webinars  

NLE Websites -- All DOE Office Websites (Extended Search)

Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems...

319

Fuel cell sub-assembly  

DOE Patents (OSTI)

A fuel cell sub-assembly comprising a plurality of fuel cells, a first section of a cooling means disposed at an end of the assembly and means for connecting the fuel cells and first section together to form a unitary structure.

Chi, Chang V. (Brookfield, CT)

1983-01-01T23:59:59.000Z

320

Commercialization of fuel-cells  

DOE Green Energy (OSTI)

This report is an abbreviated version of the ''Report of the DOE Advanced Fuel Cell Commercialization Working Group (AFC2WG),'' released January 1995. We describe fuel-cell commercialization for stationary power applications of phosphoric acid, molten carbonate, solid oxide, and polymer electrolyte membrane fuel cells.

Penner, S.S.; Appleby, A.J.; Baker, B.S.; Bates, J.L.; Buss, L.B.; Dollard, W.J.; Farris, P.J.; Gillis, E.A.; Gunsher, J.A.; Khandkar, A.; Krumpelt, M.; O'Sullivan, J.B.; Runte, G.; Savinell, R.F.; Selman, J.R.; Shores, D.A.; Tarman, P.

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Fuel Cell Handbook, Fourth Edition  

SciTech Connect

Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

1998-11-01T23:59:59.000Z

322

Fuel Cell Handbook, Fourth Edition  

DOE Green Energy (OSTI)

sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

1998-11-01T23:59:59.000Z

323

Combined goal gasifier and fuel cell system and method  

DOE Patents (OSTI)

A molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture.

Gmeindl, Frank D. (Morgantown, WV); Geisbrecht, Rodney A. (New Alexandria, PA)

1990-01-01T23:59:59.000Z

324

Combined coal gasifier and fuel cell system and method  

DOE Patents (OSTI)

This report describes a process whereby a molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture. 1 fig.

Gmeindl, F.D.; Geisbrecht, R.A.

1989-06-26T23:59:59.000Z

325

Fuel Cell Handbook, Fifth Edition  

DOE Green Energy (OSTI)

Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Energy and Environmental Solutions

2000-10-31T23:59:59.000Z

326

Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects to someone by E-mail Share Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Facebook Tweet about Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Twitter Bookmark Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Google Bookmark Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Delicious Rank Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Digg Find More places to share Fuel Cell Technologies Office: Financial

327

Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP)  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

National Fuel Cell Bus National Fuel Cell Bus Program (NFCBP) to someone by E-mail Share Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Facebook Tweet about Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Twitter Bookmark Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Google Bookmark Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Delicious Rank Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Digg Find More places to share Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type National Fuel Cell Bus Program (NFCBP) The goal of the NFCBP is to facilitate the development of commercially

328

Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Motor Fuel Cell Motor Vehicle Tax Deduction to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Google Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Delicious Rank Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Motor Vehicle Tax Deduction A taxpayer is eligible for a $2,000 tax deduction for the purchase of a

329

Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen and Fuel Cell Hydrogen and Fuel Cell Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Google Bookmark Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Delicious Rank Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Hydrogen and Fuel Cell Tax Exemption The following are exempt from state sales tax: 1) any device, equipment, or

330

Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Motor Fuel Cell Motor Vehicle Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Google Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Delicious Rank Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Motor Vehicle Tax Credit A tax credit of up to $4,000 is available for the purchase of qualified

331

Layered Nickel Oxide-Based Cathodes for Lithium Cells: Analysis ofPerformance Loss Mechanisms  

DOE Green Energy (OSTI)

Spectroscopic and electrochemical diagnostic measurements are reported for the cell components of a Generation 2 (Gen 2) Li-Ion cell from the US Department of Energy's Advanced Technology Development (ATD) project. The cells are composed of LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} positive electrodes (cathode), carbon graphite anodes and electrolyte consisting of 1.2 M LiPF{sub 6} in EC:EMC 3:7. Fluorophosphates were observed by {sup 19}F and {sup 31}P NMR in the electrolyte obtained from a Gen 2 cell aged 72 weeks at 45 C and presenting 50% power fade. These electrolyte decomposition products were also observed by {sup 31}P solid-state NMR on the surface of the cathode of the same cell. Samples were cut from the aged cathode from the original cell, subjected to different treatments (ultrasonic washing in anhydrous DMC, pressing, ultrasonic washing and pressing), and subsequently reassembled into small lab cells for electrochemical characterization. These treatments recovered the capacity of the electrodes to within a few percent of the original value, with the most improvement being obtained with the washed and pressed cathode. The impedance of the cathodes was also lowered after the ultrasonic washing and pressing treatments. Electron microscopy revealed that the ultrasonic washing of the aged Gen 2 cathode material resulted in the removal of small particles covering the surface of the active cathode. These findings are interpreted in terms of a model whereby capacity loss, and thus power capability, is restored by removing the fluorophosphate deposit and restoring electronic contact to the active cathode material.

Kerlau, Marie; Reimer, Jeffrey A.; Cairns, Elton J.

2004-10-01T23:59:59.000Z

332

Alternative Fuels Data Center: Fuel Cell Electric Vehicles  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Cell Electric Vehicles to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Google Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Delicious Rank Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Electric Vehicles on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations Vehicles Availability Emissions Laws & Incentives Fuel Cell Electric Vehicles

333

Reformate fuel cell system durability  

DOE Green Energy (OSTI)

The goal of this research is to identify the factors limiting the durability of fuel cells and fuel processors. This includes identifying PEM fuel cell durability issues for operating on pure hydrogen, and those that arise from the fuel processing of liquid hydrocarbons (e.g., gasoline) as a function of fuel composition and impurity content. Benchmark comparisons with the durability of fuel cells operating on pure hydrogen are used to identify limiting factors unique to fuel processing. We describe the design, operation and operational results of the durability system, including the operating conditions for the system, fuel processor sub-section operation over 1000 hours, post-mortem characterization of the catalysts in the fuel processor, and single cell operation.

Borup, R. L. (Rodney L.); Inbody, M. A. (Michael A.); Uribe, F. A. (Francisco A.); Tafoya, J. (Jose I.)

2002-01-01T23:59:59.000Z

334

Carbonate fuel cell matrix  

DOE Patents (OSTI)

A carbonate fuel cell matrix is described comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles. 8 figs.

Farooque, M.; Yuh, C.Y.

1996-12-03T23:59:59.000Z

335

Carbonate fuel cell matrix  

DOE Patents (OSTI)

A carbonate fuel cell matrix comprising support particles and crack attenuator particles which are made platelet in shape to increase the resistance of the matrix to through cracking. Also disclosed is a matrix having porous crack attenuator particles and a matrix whose crack attenuator particles have a thermal coefficient of expansion which is significantly different from that of the support particles, and a method of making platelet-shaped crack attenuator particles.

Farooque, Mohammad (Huntington, CT); Yuh, Chao-Yi (New Milford, CT)

1996-01-01T23:59:59.000Z

336

Fuel cell oxygen electrode  

DOE Patents (OSTI)

An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

Shanks, Howard R. (Ames, IA); Bevolo, Albert J. (Ames, IA); Danielson, Gordon C. (Ames, IA); Weber, Michael F. (Wichita, KS)

1980-11-04T23:59:59.000Z

337

Energy Basics: Hydrogen and Fuel Cell Technologies  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Basics Renewable Energy Printable Version Share this resource Biomass Geothermal Hydrogen Hydrogen Fuel Fuel Cells Hydropower Ocean Solar Wind Hydrogen and Fuel Cell...

338

Fuel Cell Technologies Office: About  

NLE Websites -- All DOE Office Websites (Extended Search)

About the Fuel Cell Technologies Office About the Fuel Cell Technologies Office The Fuel Cell Technologies Office conducts comprehensive efforts to overcome the technological, economic, and institutional barriers to the widespread commercialization of hydrogen and fuel cells. The office is aligned with the strategic vision and goals of the U.S. Department of Energy (DOE). The office's efforts will help secure U.S. leadership in clean energy technologies and advance U.S. economic competitiveness and scientific innovation. What We Do DOE is the lead federal agency for directing and integrating activities in hydrogen and fuel cell R&D as authorized in the Energy Policy Act of 2005. The Fuel Cell Technologies Office is responsible for coordinating the R&D activities for DOE's Hydrogen and Fuel Cells Program, which includes activities within four DOE offices (Office of Energy Efficiency and Renewable Energy [EERE], Office of Fossil Energy, Office of Nuclear Energy, and Office of Science).

339

Hydrogen and Fuel Cell Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

8/5/2011 eere.energy.gov 8/5/2011 eere.energy.gov 5 th International Conference on Polymer Batteries & Fuel Cells Argonne, Illinois Hydrogen and Fuel Cell Activities Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager August 4, 2011 2 | Fuel Cell Technologies Program Source: US DOE 8/5/2011 eere.energy.gov Fuel Cells: Benefits & Market Potential The Role of Fuel Cells Key Benefits Very High Efficiency Reduced CO 2 Emissions * 35-50%+ reductions for CHP systems (>80% with biogas) * 55-90% reductions for light- duty vehicles * up to 60% (electrical) * up to 70% (electrical, hybrid fuel cell / turbine) * up to 85% (with CHP) Reduced Oil Use * >95% reduction for FCEVs (vs. today's gasoline ICEVs)

340

Fuel Cell Technologies Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

IEA HIA Hydrogen Safety Stakeholder IEA HIA Hydrogen Safety Stakeholder Workshop Bethesda, Maryland Fuel Cell Technologies Program Overview Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 10/2/2012 2 | Fuel Cell Technologies Program eere.energy.gov Overview Fuel Cells - An Emerging Global Industry Clean Energy Patent Growth Index [1] shows that fuel cell patents lead in the clean energy field with over 950 fuel cell patents issued in 2011. * Nearly double the second place holder, solar, which has ~540 patents. [1] http://cepgi.typepad.com/files/cepgi-4th-quarter-2011-1.pdf United States 46% Germany 7% Korea 7% Canada 3% Taiwan 1% Great Britain 1% France 1% Other 3% Japan 31% Fuel Cell Patents Geographic Distribution 2002-2011 Top 10 companies: GM, Honda, Samsung,

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Proton Conductor based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119  

NLE Websites -- All DOE Office Websites (Extended Search)

based Solid Oxide Fuel Cells based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119 S. (Elango) Elangovan, Joseph Hartvigsen, Insoo Bay, and Feng Zhao High efficiency operation is one of the primary attractions to use solid oxide fuel cells as the energy conversion device. High efficiency requires maximizing of the product of operating voltage and fuel utilization. The maximum possible operating voltage however is limited by the Nernst potential near the fuel exhaust. In oxygen conducting electrolyte based fuel cells (O-SOFC) as the fuel utilization increases, the Nernst potential continues to decrease with the dilution of fuel by the reaction products. In contrast, in a proton conducting electrolyte based fuel cell (P-SOFC) the reaction product is formed on the cathode side allowing for high operating voltage at high fuel

342

Fuel Cell Power Plant Experience Naval Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

clean clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy/ Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC March 29, 2011 FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. *FuelCell Energy, Inc. *Renewable and Liquid Fuels Experience *HTPEM Fuel Cell Stack for Shipboard APU *Solid Oxide Experience and Applications DOE-ONR Workshop FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. FuelCell Energy, Inc. * Premier developer of fuel cell technology - founded in 1969 * Over 50 power installations in North America, Europe, and Asia * Industrial, commercial, utility

343

Engineered Nano-scale Ceramic Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies Technologies Operated by Los Alamos National Security, LLC for NNSA U N C L A S S I F I E D Engineered Nano-scale Ceramic Supports for PEM Fuel Cells Eric L. Brosha, Anthony Burrell, Neil Henson, Jonathan Phillips, and Tommy Rockward Los Alamos National Laboratory Timothy Ward, Plamen Atanassov University of New Mexico Karren More Oak Ridge National Laboratory Fuel Cell Technologies Program Kick-off Meeting September 30 - October 1, 2009 Washington DC Operated by Los Alamos National Security, LLC for NNSA U N C L A S S I F I E D Fuel Cell Technologies Objectives  Develop a ceramic alternative to carbon material supports for a polymer electrolyte fuel cell cathode that exhibits an enhanced resistance to corrosion and Pt coalescence while preserving positive attributes of carbon such as

344

NREL: Hydrogen and Fuel Cells Research - National Fuel Cell Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

National Fuel Cell Technology Evaluation Center National Fuel Cell Technology Evaluation Center The National Fuel Cell Technology Evaluation Center (NFCTEC) at NREL's Energy Systems Integration Facility (ESIF) plays a crucial role in NREL's independent, third-party analysis of hydrogen fuel cell technologies in real-world operation. The NFCTEC is designed for secure management, storage, and processing of proprietary data from industry. Access to the off-network NFCTEC is limited to NREL's Technology Validation Team, which analyzes detailed data and reports on fuel cell technology status, progress, and technical challenges. Graphic representing NREL's Hydrogen Secure Data Center and the variety of applications from which it gathers data, including fuel cell (FC) stacks, FC backup power, FC forklifts, FC cars, FC buses, and FC prime power, and hydrogen infrastructure.

345

Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Delicious Rank Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations

346

Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations

347

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Multi-Year Research, Development and Demonstration Plan* The Fuel Cell Technologies Office Multi-Year Research, Development, and Demonstration (MYRD&D) Plan* describes the goals,...

348

NREL: Hydrogen and Fuel Cells Research - Fuel Cell Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

with a focus on improving the performance and durability and reducing the cost of fuel cell components and systems. Research efforts involve: Developing advanced catalysts,...

349

DOE Hydrogen and Fuel Cells Program: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

portable power and auxiliary power applications in a limited fashion where earlier market entry would assist in the development of a fuel cell manufacturing base. This DOE...

350

Fuel Cell Technologies Office: Alkaline Membrane Fuel Cell Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Renewable Energy Laboratory Anion Exchange Membranes for Fuel Cells, Prof. Andrew Herring, Colorado School of Mines Electrocatalysis in Alkaline Electrolytes, Prof. Sanjeev...

351

NREL: Hydrogen and Fuel Cells Research - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

high conductivity) for this application include tin oxide, indium tin oxide, and zinc oxide. Contact: Bryan Pivovar 303-275-3809 Printable Version Hydrogen & Fuel Cells Research...

352

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

Newsletter: August 2013 The August 2013 issue of the Fuel Cell Technologies Office newsletter includes stories in these categories: In the News Funding Opportunities Webinars and...

353

Fuel Cell Technologies Office: Fuel Cell Technologies Office...  

NLE Websites -- All DOE Office Websites (Extended Search)

hydrogen and fuel cells. This information is provided in documents such as technical and project reports, conference proceedings and journal articles, technical presentations, and...

354

Fuel Cell Technologies Office: Fuel Cells for Portable Power...  

NLE Websites -- All DOE Office Websites (Extended Search)

Session - Fuel Cell Portable Power Perspectives End User Perspective - Industry Consumer Electronics Power (PDF 1.51 MB) Jerry Hallmark, Motorola Portable Power Sources (above...

355

An advanced fuel cell simulator  

E-Print Network (OSTI)

Fuel cell power generation systems provide a clean alternative to the conventional fossil fuel based systems. Fuel cell systems have a high e?ciency and use easily available hydrocarbons like methane. Moreover, since the by-product is water, they have a very low environmental impact. The fuel cell system consists of several subsystems requiring a lot of e?ort from engineers in diverse areas. Fuel cell simulators can provide a convenient and economic alternative for testing the electrical subsystems such as converters and inverters. This thesis proposes a low-cost and an easy-to-use fuel cell simulator using a programmable DC supply along with a control module written in LabVIEW. This simulator reproduces the electrical characteristics of a 5kW solid oxide fuel cell (SOFC) stack under various operating conditions. The experimental results indicate that the proposed simulator closely matches the voltage-current characteristic of the SOFC system under varying load conditions. E?ects of non-electrical parameters like hydrogen ?ow rate are also modeled and these parameters are taken as dynamic inputs from the user. The simulator is customizable through a graphical user interface and allows the user to model other types of fuel cells with the respective voltage-current data. The simulator provides an inexpensive and accurate representation of a solid oxide fuel cell under steady state and transient conditions and can replace an actual fuel cell during testing of power conditioning equipment.

Acharya, Prabha Ramchandra

2004-08-01T23:59:59.000Z

356

Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Financial Opportunities Financial Opportunities Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation to someone by E-mail Share Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Facebook Tweet about Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Twitter Bookmark Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Google Bookmark Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Delicious Rank Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Digg

357

Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles  

E-Print Network (OSTI)

An Indirect Methanol Pem Fuel Cell System, SAE 2001, (paperof automotive PEM fuel cell stacks, SAE 2000 (paper numberParasitic Loads in Fuel Cell Vehicles, International Journal

Zhao, Hengbing; Burke, Andy

2008-01-01T23:59:59.000Z

358

Hybrid Fuel Cell Technology Overview  

SciTech Connect

For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

None available

2001-05-31T23:59:59.000Z

359

MODELING AND DESIGN FOR A DIRECT CARBON FUEL CELL WITH ENTRAINED FUEL AND OXIDIZER  

DOE Green Energy (OSTI)

The novel molten carbonate fuel cell design described in this report uses porous bed electrodes. Molten carbonate, with carbon fuel particles and oxidizer entrained, is circulated through the electrodes. Carbon may be reacted directly, without gasification, in a molten carbonate fuel cell. The cathode reaction is 2CO{sub 2} + O{sub 2} 4e{sup -} {yields} 2CO{sub 3}{sup =}, while the anode reaction can be either C + 2CO{sub 3}{sup =} {yields} 3CO{sub 2} + 4e{sup -} or 2C + CO{sub 3}{sup =} {yields} 3CO + 2e{sup -}. The direct carbon fuel cell has an advantage over fuel cells using coal-derived synthesis gas in that it provides better overall efficiency and reduces equipment requirements. Also, the liquid electrolyte provides a means for transporting the solid carbon. The porous bed cell makes use of this carbon transport ability of the molten salt electrolyte. A one-dimensional model has been developed for predicting the performance of this cell. For the cathode, dependent variables are superficial O{sub 2} and CO{sub 2} fluxes in the gas phase, superficial O{sub 2} and CO{sub 2} fluxes in the liquid phase, superficial current density through the electrolyte, and electrolyte potential. The variables are related by correlations, from the literature, for gas-liquid mass transfer, liquid-solid mass transfer, cathode current density, electrode overpotential, and resistivity of a liquid with entrained gas. For the anode, dependent variables are superficial CO{sub 2} flux in the gas phase, superficial CO{sub 2} flux in the liquid phase, superficial C flux, superficial current density through the electrolyte, and electrolyte potential. The same types of correlations relate the variables as in the cathode, with the addition of a correlation for resistivity of a fluidized bed. CO production is not considered, and axial dispersion is neglected. The model shows behavior typical of porous bed electrodes used in electrochemical processes. Efficiency is comparable to that of membrane electrode fuel cells. Effective bed depths are on the order of 1-5 centimeter, giving power/volume lower than for membrane electrode cells. The porous bed design, however, uses less expensive materials and is more resistant to fouling by coal impurities. The model will be used in the second phase of the project to design a laboratory-scale prototype cell. The prototype cell will demonstrate the concept and provide experimental data for improving the model.

Alan A. Kornhauser; Ritesh Agarwal

2005-04-01T23:59:59.000Z

360

List of Fuel Cells using Renewable Fuels Incentives | Open Energy  

Open Energy Info (EERE)

Fuel Cells using Renewable Fuels Incentives Fuel Cells using Renewable Fuels Incentives Jump to: navigation, search The following contains the list of 192 Fuel Cells using Renewable Fuels Incentives. CSV (rows 1 - 192) Incentive Incentive Type Place Applicable Sector Eligible Technologies Active Advanced Energy Fund (Ohio) Public Benefits Fund Ohio Commercial Industrial Institutional Residential Utility Biomass CHP/Cogeneration Fuel Cells Fuel Cells using Renewable Fuels Geothermal Electric Hydroelectric energy Landfill Gas Microturbines Municipal Solid Waste Photovoltaics Solar Space Heat Solar Thermal Electric Solar Water Heat Wind energy Yes AlabamaSAVES Revolving Loan Program (Alabama) State Loan Program Alabama Commercial Industrial Institutional Building Insulation Doors Energy Mgmt. Systems/Building Controls

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Improved electrolytes for fuel cells  

DOE Green Energy (OSTI)

Present day fuel cells based upon hydrogen and oxygen have limited performance due to the use of phosphoric acid as an electrolyte. Improved performance is desirable in electrolyte conductivity, electrolyte management, oxygen solubility, and the kinetics of the reduction of oxygen. Attention has turned to fluorosulfonic acids as additives or substitute electrolytes to improve fuel cell performance. The purpose of this project is to synthesize and electrochemically evaluate new fluorosulfonic acids as superior alternatives to phosphoric acid in fuel cells. (VC)

Gard, G.L.; Roe, D.K.

1991-06-01T23:59:59.000Z

362

Oxygen electrode reaction in molten carbonate fuel cells  

DOE Green Energy (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

363

Molten carbonate fuel cell separator  

DOE Patents (OSTI)

In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

Nickols, Richard C. (East Hartford, CT)

1986-09-02T23:59:59.000Z

364

Molten carbonate fuel cell separator  

DOE Patents (OSTI)

In a stacked array of molten carbonate fuel cells, a fuel cell separator is positioned between adjacent fuel cells to provide isolation as well as a conductive path therebetween. The center portion of the fuel cell separator includes a generally rectangular, flat, electrical conductor. Around the periphery of the flat portion of the separator are positioned a plurality of elongated resilient flanges which form a gas-tight seal around the edges of the fuel cell. With one elongated flange resiliently engaging a respective edge of the center portion of the separator, the sealing flanges, which are preferably comprised of a noncorrosive material such as an alloy of yttrium, iron, aluminum or chromium, form a tight-fitting wet seal for confining the corrosive elements of the fuel cell therein. This arrangement permits a good conductive material which may be highly subject to corrosion and dissolution to be used in combination with a corrosion-resistant material in the fuel cell separator of a molten carbonate fuel cell for improved fuel cell conductivity and a gas-tight wet seal.

Nickols, R.C.

1984-10-17T23:59:59.000Z

365

LADWP FUEL CELL DEMONSTRATION PROJECT  

SciTech Connect

Los Angeles Department of Water and Power (LADWP) is currently one of the most active power utility companies in researching fuel cell technology. Fuel cells offer many benefits and are now used as an alternative to traditional internal combustion engines in power generation. In continuing it's role as the leader in fuel cell research, LADWP has installed a pre-commercial molten carbonate fuel cell on August 2001 at its headquarter, the John Ferraro Building (JFB). The goal of this project is to learn more about the actual behavior of the fuel cell running under real world conditions. The fuel cell ran smoothly through the first year of operation with very high efficiency, but with some minor setbacks. The JFB fuel cell project is funded by the City of Los Angeles Department of Water and Power with partial grant funding from the Department of Defense's Climate Change Fuel Cell Buydown Program. The technical evaluation and the benefit-cost evaluation of the JFB fuel cell are both examined in this report.

Thai Ta

2003-09-12T23:59:59.000Z

366

Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

as high as 90% is achievable. This high efficiency operation saves money, saves energy, and reduces greenhouse gas emissions. Regenerative or Reversible Fuel Cells This...

367

CLIMATE CHANGE FUEL CELL PROGRAM  

DOE Green Energy (OSTI)

This report discusses the first year of operation of a fuel cell power plant located at the Sheraton Edison Hotel, Edison, New Jersey. PPL EnergyPlus, LLC installed the plant under a contract with the Starwood Hotels & Resorts Worldwide, Inc. A DFC{reg_sign}300 fuel cell, manufactured by FuelCell Energy, Inc. of Danbury, CT was selected for the project. The fuel cell successfully operated from June 2003 to May 2004. This report discusses the performance of the plant during this period.

Steven A. Gabrielle

2004-12-03T23:59:59.000Z

368

Fuel Cell Technologies Office: Education  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Offices | Consumer Information Education Search Search Help Education EERE Fuel Cell Technologies Office Education Printable Version Share this resource Send a link...

369

EERE Fuel Cell Technologies Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Results will be documented in a report by Pacific Northwest National Lab: "Pathways to Commercial Success: Technologies and Products Supported by the Hydrogen, Fuel Cells and...

370

LADWP FUEL CELL DEMONSTRATION PROJECT  

DOE Green Energy (OSTI)

Los Angeles Department of Water and Power (LADWP) is currently one of the most active power utility companies in researching fuel cell technology. Fuel cells offer many benefits and are now used as an alternative to traditional internal combustion engines in power generation. In continuing it's role as the leader in fuel cell research, LADWP has installed a pre-commercial molten carbonate fuel cell on August 2001 at its headquarter, the John Ferraro Building (JFB). The goal of this project is to learn more about the actual behavior of the fuel cell running under real world conditions. The fuel cell ran smoothly through the first year of operation with very high efficiency, but with some minor setbacks. The JFB fuel cell project is funded by the City of Los Angeles Department of Water and Power with partial grant funding from the Department of Defense's Climate Change Fuel Cell Buydown Program. The technical evaluation and the benefit-cost evaluation of the JFB fuel cell are both examined in this report.

Thai Ta

2003-09-12T23:59:59.000Z

371

Fuel Cell Technologies Office: Education  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office - Education Students learn about solar energy. DOE supports demonstrations and commercialization by providing technically accurate and objective...

372

Fuel Cell Power PlantsFuel Cell Power Plants Renewable and Waste Fuels  

E-Print Network (OSTI)

for Safety and Grid Interface Direct Fuel Cell Module: FuelCell Energy, the FuelCell Energy logo, Direct Fuel generation of combined heat andcombined heat and power ­Clean Power with natural gas f lfuel ­Renewable Power with biofuels ·Grid connected power generationgeneration ­High Efficiency Grid support

373

Fuel Cell Technologies Office: News  

NLE Websites -- All DOE Office Websites (Extended Search)

News News Recent news stories and press releases related to the Fuel Cell Technologies Office are presented below. To see past news items, refer to the news archives for 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, and 2003. Subscribe to Fuel Cell Technologies Office updates. January 10, 2014 Upcoming Live Discussion on Energy 101: Fuel Cells Join the Energy Department at 2:00 p.m. ET on Thursday, January 16 for the first Energy 101 Google+ Hangout, which will focus on fuel cells. More January 10, 2014 Help Design the Hydrogen Fueling Station of Tomorrow The Energy Department posted a blog yesterday about the Hydrogen Education Foundation's Hydrogen Student Design Contest. More December 20, 2013 Your Holidays...Brought to You by Fuel Cells

374

Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Compressed Natural Gas Compressed Natural Gas and Hydrogen Fuels Workshop to someone by E-mail Share Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Facebook Tweet about Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Twitter Bookmark Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Google Bookmark Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Delicious Rank Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Digg Find More places to share Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications

375

Fuel Cell Vehicles | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cell Vehicles Fuel Cell Vehicles August 20, 2013 - 9:11am Addthis Photo of a blue car with 'The Road to Hydrogen' written on it, filling up at a hydrogen fueling station. Fuel...

376

Fuel Cell Technologies Program Record 12012: Fuel Cell Bus Targets  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Program Record Fuel Cell Technologies Program Record Record #: 12012 Date: March 2, 2012 Title: Fuel Cell Bus Targets Originator: Jacob Spendelow and Dimitrios Papageorgopoulos Approved by: Sunita Satyapal * Date: September 12, 2012 Item: Performance, cost, and durability targets for fuel cell transit buses are presented in Table 1. These market-driven targets represent technical requirements needed to compete with alternative technologies. They do not represent expectations for the status of the technology in future years. Table 1. Performance, cost, and durability targets for fuel cell transit buses. Units 2012 Status 2016 Target Ultimate Target Bus Lifetime years/miles 5/100,000 1 12/500,000 12/500,000 Power Plant Lifetime 2,3 hours 12,000 18,000 25,000

377

Hydrogen and Fuel Cells R&D  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquids --Hydrogen Storage Materials --Hydrogen Storage Systems Modeling and Analysis --Thermochemical Hydrogen * Fuel Cells --Polymer Electrolyte --Modeling & Analysis --Fuel...

378

A Reversible Planar Solid Oxide Fuel-Fed Electrolysis Cell and Solid Oxide Fuel Cell for Hydrogen and Electricity Production Operating on Natural Gas/Biomass Fuels  

DOE Green Energy (OSTI)

A solid oxide fuel-assisted electrolysis technique was developed to co-generate hydrogen and electricity directly from a fuel at a reduced cost of electricity. Solid oxide fuel-assisted electrolysis cells (SOFECs), which were comprised of 8YSZ electrolytes sandwiched between thick anode supports and thin cathodes, were constructed and experimentally evaluated at various operation conditions on lab-level button cells with 2 cm2 per-cell active areas as well as on bench-scale stacks with 30 cm2 and 100 cm2 per-cell active areas. To reduce the concentration overpotentials, pore former systems were developed and engineered to optimize the microstructure and morphology of the Ni+8YSZ-based anodes. Chemically stable cathode materials, which possess good electronic and ionic conductivity and exhibit good electrocatalytic properties in both oxidizing and reducing gas atmospheres, were developed and materials properties were investigated. In order to increase the specific hydrogen production rate and thereby reduce the system volume and capital cost for commercial applications, a hybrid system that integrates the technologies of the SOFEC and the solid-oxide fuel cell (SOFC), was developed and successfully demonstrated at a 1kW scale, co-generating hydrogen and electricity directly from chemical fuels.

Tao, Greg, G.

2007-03-31T23:59:59.000Z

379

Fuel Cell Technologies Office: Waste-to-Energy using Fuel Cells...  

NLE Websites -- All DOE Office Websites (Extended Search)

Waste-to-Energy using Fuel Cells Workshop to someone by E-mail Share Fuel Cell Technologies Office: Waste-to-Energy using Fuel Cells Workshop on Facebook Tweet about Fuel Cell...

380

Fuel Cell Technologies Office: Waste-to-Energy using Fuel Cells...  

NLE Websites -- All DOE Office Websites (Extended Search)

Waste-to-Energy using Fuel Cells Webinar to someone by E-mail Share Fuel Cell Technologies Office: Waste-to-Energy using Fuel Cells Webinar on Facebook Tweet about Fuel Cell...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Manufacturing Fuel Cell Manhattan Project  

NLE Websites -- All DOE Office Websites (Extended Search)

to to DOE Fuel Cell Manufacturing Workshop 2011 John Christensen, PE NREL Consultant DOE Fuel Cell Market Transformation Support August 11, 2011 Manufacturing Fuel Cell Manhattan Project √ Identify manufacturing cost drivers to achieve affordability √ Identify best practices in fuel cell manufacturing technology √ Identify manufacturing technology gaps √ Identify FC projects to address these gaps MFCMP Objectives Completed Final Report due out Nov 2010 B2PCOE Montana Tech SME's Industry Academia Government FC Consortiums Power ranges * <0.5 kW (man portable / man wearable) * 0.5 kW< Power range < 10 kW (mobile power) Fuels: Hydrogen and reformed hydrocarbons *Packaged Fuels < 0.5 kW * Near term solution * Move through the supply chain like batteries

382

Fuel cell electric power production  

DOE Patents (OSTI)

A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

Hwang, Herng-Shinn (Livingston, NJ); Heck, Ronald M. (Frenchtown, NJ); Yarrington, Robert M. (Westfield, NJ)

1985-01-01T23:59:59.000Z

383

High efficiency carbonate fuel cell/turbine hybrid power cycle  

Science Conference Proceedings (OSTI)

The hybrid power cycle studies were conducted to identify a high efficiency, economically competitive system. A hybrid power cycle which generates power at an LHV efficiency > 70% was identified that includes an atmospheric pressure direct carbonate fuel cell, a gas turbine, and a steam cycle. In this cycle, natural gas fuel is mixed with recycled fuel cell anode exhaust, providing water for reforming fuel. The mixed gas then flows to a direct carbonate fuel cell which generates about 70% of the power. The portion of the anode exhaust which is not recycled is burned and heat transferred through a heat exchanger (HX) to the compressed air from a gas turbine. The heated compressed air is then heated further in the gas turbine burner and expands through the turbine generating 15% of the power. Half the exhaust from the turbine provides air for the anode exhaust burner. All of the turbine exhaust eventually flows through the fuel cell cathodes providing the O2 and CO2 needed in the electrochemical reaction. Exhaust from the cathodes flows to a steam system (heat recovery steam generator, staged steam turbine generating 15% of the cycle power). Simulation of a 200 MW plant with a hybrid power cycle had an LHV efficiency of 72.6%. Power output and efficiency are insensitive to ambient temperature, compared to a gas turbine combined cycle; NOx emissions are 75% lower. Estimated cost of electricity for 200 MW is 46 mills/kWh, which is competitive with combined cycle where fuel cost is > $5.8/MMBTU. Key requirement is HX; in the 200 MW plant studies, a HX operating at 1094 C using high temperature HX technology currently under development by METC for coal gassifiers was assumed. A study of a near term (20 MW) high efficiency direct carbonate fuel cell/turbine hybrid power cycle has also been completed.

Steinfeld, G.; Maru, H.C. [Energy Research Corp., Danbury, CT (United States); Sanderson, R.A. [Sanderson (Robert) and Associates, Wethersfield, CT (United States)

1996-07-01T23:59:59.000Z

384

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

1993-01-01T23:59:59.000Z

385

Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels  

DOE Green Energy (OSTI)

This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

Turgut Gur

2010-04-30T23:59:59.000Z

386

1 | Fuel Cell Technologies Office eere.energy.gov DOE Fuel Cell Technologies Office  

E-Print Network (OSTI)

to demonstrate: World's first tri-generation station World's first fuel cell forklifts World's first fuel cell

387

Bronx Zoo Fuel Cell Project  

DOE Green Energy (OSTI)

A 200 kW Fuel Cell has been installed in the Lion House, Bronx Zoo, NY. The Fuel Cell is a 200 kW phosphoric acid type manufactured by United Technologies Corporation (UTC) and will provide thermal energy at 725,000 Btu/hr.

Hoang Pham

2007-09-30T23:59:59.000Z

388

Heated transportable fuel cell cartridges  

DOE Patents (OSTI)

A fuel cell stack protective system is made where a plurality of fuel cells, each containing liquid electrolyte subject to crystallization, is enclosed by a containing vessel, and where at least one electric heater is placed in the containing vessel and is capable of preventing electrolyte crystallization.

Lance, Joseph R. (N. Huntingdon, PA); Spurrier, Francis R. (Whitehall, PA)

1985-01-01T23:59:59.000Z

389

Through-the-electrode model of a proton exchange membrane fuel cell with independently measured parameters  

DOE Green Energy (OSTI)

A one dimensional model for a proton exchange membrane fuel cell was developed which makes use of independently measured parameters for predicting single cell performance. Optimization of catalyst layer formulation and properties are explored. Impact of temperature and cathode pressure upon system performance was investigated.

Weisbrod, K.R.; Grot, S.A.; Vanderborgh, N.E.

1995-05-01T23:59:59.000Z

390

Through-the-electrode model of a proton exchange membrane fuel cell with independently measured parameters  

DOE Green Energy (OSTI)

A one dimensional model for a proton exchange membrane fuel cell was developed which makes use of independently measured parameters for predicting single cell performance. Optimization of catalyst layer formulation and properties are explored. Impact of temperature and cathode pressure upon system performance is investigated.

Weisbrod, K.R.; Grot, S.A.; Vandergborgh, N.E.

1995-09-01T23:59:59.000Z

391

Fuel Cells for Robots  

NLE Websites -- All DOE Office Websites (Extended Search)

For Robots For Robots Fuel Cells For Robots Pavlo Rudakevych iRobot Pavlo Rudakevych iRobot Product Needs Product Needs * Military/Police/Search and Rescue - PackBot - Gladiator - ThrowBot/UGCV * Industrial and Oil - CoWorker - MicroRig * Military/Police/Search and Rescue - PackBot - Gladiator - ThrowBot/UGCV * Industrial and Oil - CoWorker - MicroRig PackBot PackBot * Mission capable robots * Rugged, portable tools for minimal casualty engagements * Assisting behaviors * Small size and weight * Mission capable robots * Rugged, portable tools for minimal casualty engagements * Assisting behaviors * Small size and weight System Concept System Concept System Concept System Concept System Concept Continued System Concept Continued * Modular payload bays - 3 primary - 1 head - 4 side pods * Each payload socket supports - Ethernet

392

Climate Change Fuel Cell Program  

DOE Green Energy (OSTI)

A 200 kW, natural gas fired fuel cell was installed at the Richard Stockton College of New Jersey. The purpose of this project was to demonstrate the financial and operational suitability of retrofit fuel cell technology at a medium sized college. Target audience was design professionals and the wider community, with emphasis on use in higher education. ''Waste'' heat from the fuel cell was utilized to supplement boiler operations and provide domestic hot water. Instrumentation was installed in order to measure the effectiveness of heat utilization. It was determined that 26% of the available heat was captured during the first year of operation. The economics of the fuel cell is highly dependent on the prices of electricity and natural gas. Considering only fuel consumed and energy produced (adjusted for boiler efficiency), the fuel cell saved $54,000 in its first year of operation. However, taking into account the price of maintenance and the cost of financing over the short five-year life span, the fuel cell operated at a loss, despite generous subsidies. As an educational tool and market stimulus, the fuel cell attracted considerable attention, both from design professionals and the general public.

Alice M. Gitchell

2006-09-15T23:59:59.000Z

393

Evaluation of Stationary Fuel Cell Deployments, Costs, and Fuels (Presentation)  

SciTech Connect

This presentation summarizes NREL's technology validation of stationary fuel cell systems and presents data on number of deployments, system costs, and fuel types.

Ainscough, C.; Kurtz, J.; Peters, M.; Saur, G.

2013-10-01T23:59:59.000Z

394

Fuel Cells using Renewable Fuels | Open Energy Information  

Open Energy Info (EERE)

Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon Fuel Cells using Renewable Fuels Jump to: navigation, search TODO: Add description List of...

395

Fuel Cell Technologies Office: International Partnership for...  

NLE Websites -- All DOE Office Websites (Extended Search)

Partnership for Hydrogen and Fuel Cells in the Economy to someone by E-mail Share Fuel Cell Technologies Office: International Partnership for Hydrogen and Fuel Cells in the...

396

NETL: Fuel Cells/SECA News - Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells/Solid State Energy Conversion Alliance (SECA) Fuel Cells/Solid State Energy Conversion Alliance (SECA) News Archive SECA Workshop Proceedings, Peer Reviews, and Annual Reports 2013 Archive 2012 Archive 2011 Archive Previous Highlights FuelCell Energy's Stack Boosts Power and Minimizes Degradation FuelCell Energy has developed a new solid oxide fuel cell stack design that boosts the overall power output of the fuel cell stack by nearly 50%. FuelCell Energy also achieved a voltage degradation rate of 1.3% per 1000 hours after testing the fuel cells for 26,000 hours of operation. This breakthrough by FuelCell Energy of greater power from the fuel cell stack while minimizing fuel cell degradation pushes it further towards meeting SECA's goal of a market ready, affordable solid oxide fuel cell ready by the year 2010. (5/05)

397

Fuel Cell Today | Open Energy Information  

Open Energy Info (EERE)

Today Jump to: navigation, search Name Fuel Cell Today Place London, United Kingdom Zip EC1N 8EE Product Fuel Cell Today is a online information service for the global fuel cell...

398

Fuel Cell Technologies Office: NewsDetail  

NLE Websites -- All DOE Office Websites (Extended Search)

Office: NewsDetail on Twitter Bookmark Fuel Cell Technologies Office: NewsDetail on Google Bookmark Fuel Cell Technologies Office: NewsDetail on Delicious Rank Fuel Cell...

399

Solar-Hydrogen Fuel-Cell Vehicles  

E-Print Network (OSTI)

LemonsR. A. ( 1990) Fuel Cells for Transportation. Jour- DC,M. A. (1992). Hydrogen Fuel-Cell Vehicles. Re- koebensteinsolid tember. oxide fuel cell development. Journal of

DeLuchi, Mark A.; Ogden, Joan M.

1993-01-01T23:59:59.000Z

400

Characterization of Fuel-Cell Diffusion Media  

E-Print Network (OSTI)

electrolyte membrane fuel cells, 2009. C. Lim and C. Y.directly into full fuel-cell simulations to predictFCgen1020ACS, www.ballard.com/fuel-cell-products, Accessed

Gunterman, Haluna Penelope Frances

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Fuel Cell Markets Ltd | Open Energy Information  

Open Energy Info (EERE)

Fuel Cell Markets Ltd Place Buckinghamshire, United Kingdom Zip SL0 9AQ Sector Hydro, Hydrogen Product Fuel Cell Markets was set up to assist companies in the fuel cell and...

402

Hydrocarbon Reformers for Fuel Cell Systems  

Science Conference Proceedings (OSTI)

Several new or emerging technologies are vying to compete in the distributed resources market; notably, fuel cells and microturbines. Fuel cells represent an idealized power generation technology with tremendous long-term promise. As a hydrogen-fueled system, however, fuel cells need either a hydrogen fuel supply infrastructure or fuel processing (reforming and clean-up) technology to convert conventional fossil fuels to a hydrogen-rich energy source. This report provides an overview of fuel processing t...

2000-11-30T23:59:59.000Z

403

Yttria-stabilized zirconia solid oxide electrolyte fuel cells--- monolithic solid oxide fuel cells  

DOE Green Energy (OSTI)

The monolithic solid oxide fuel cell (MSOFC) is currently under development for a variety of applications including coal-based power generation. The MSOFC is a design concept that places the thin components of a solid oxide fuel cell in lightweight, compact, corrugated structure, and so achieves high efficiency and excellent performance simultaneously with high power density. The MSOFC can be integrated with coal gasification plants and is expected to have high overall efficiency in the conversion of the chemical energy of coal to electrical energy. This report describes work aimed at (1) assessing manufacturing costs for the MSOFC and system costs for a coal-based plant; (2) modifying electrodes and electrode/electrolyte interfaces to improve the electrochemical performance of the MSOFC; and (3) testing the performance of the MSOFC on hydrogen and simulated coal gas. Manufacturing costs for both the coflow and crossflow MSOFC's were assessed based on the fabrication flow charts developed by direct scaleup of tape calendering and other laboratory processes. Integrated coal-based MSOFC systems were investigated to determine capital costs and costs of electricity. Design criteria were established for a coal-fueled 200-Mw power plant. Four plant arrangements were evaluated, and plant performance was analyzed. Interfacial modification involved modification of electrodes and electrode/electrolyte interfaces to improve the MSOFC electrochemical performance. Work in the cathode and cathode/electrolyte interface was concentrated on modification of electrode porosity, electrode morphology, electrode material, and interfacial bonding. Modifications of the anode and anode/electrolyte interface included the use of additives and improvement of nickel distribution. Single cells have been tested for their electrochemical performance. Performance data were typically obtained with humidified H{sub 2} or simulated coal gas and air or oxygen. 68 figs., 29 tabs.

Not Available

1990-10-01T23:59:59.000Z

404

Fuel Cell Technologies Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Fuel Cell Technologies Program Overview Program Overview Richard Farmer Richard Farmer Acting Acting Program Program Manager Manager Acting Acting Program Program Manager Manager 2010 Annual Merit Review and Peer Evaluation Meeting 2010 Annual Merit Review and Peer Evaluation Meeting (7 June 2010) (7 June 2010) The Administration's Clean Energy Goals 9 9 Double Renewable Double Renewable Energy Capacity by 2012 9 Invest $150 billion over ten years i in energy R&D to transition to a clean energy economy clean energy economy 9 Reduce GHG emissions 83% by 2050 2 t t Æ Æ F l ll ff hi hl ffi i di f l d Fuel Cells Address Our Key Energy Challenges Increasing Energy Increasing Energy Ef ficiency and Resource Diversity Efficiency and Resource Diversity Æ Æ Fuel cells offer a highly efficient way to use diverse fuels and energy sources.

405

Navy fuel cell demonstration project.  

DOE Green Energy (OSTI)

This is the final report on a field evaluation by the Department of the Navy of twenty 5-kW PEM fuel cells carried out during 2004 and 2005 at five Navy sites located in New York, California, and Hawaii. The key objective of the effort was to obtain an engineering assessment of their military applications. Particular issues of interest were fuel cell cost, performance, reliability, and the readiness of commercial fuel cells for use as a standalone (grid-independent) power option. Two corollary objectives of the demonstration were to promote technological advances and to improve fuel performance and reliability. From a cost perspective, the capital cost of PEM fuel cells at this stage of their development is high compared to other power generation technologies. Sandia National Laboratories technical recommendation to the Navy is to remain involved in evaluating successive generations of this technology, particularly in locations with greater environmental extremes, and it encourages their increased use by the Navy.

Black, Billy D.; Akhil, Abbas Ali

2008-08-01T23:59:59.000Z

406

DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

XVIII-1 XVIII-1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program 3M Company II.D.5 Low-Cost Large-Scale PEM Electrolysis for Renewable Energy Storage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . II-46 V.D.1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V-84 V.D.3 Durable Catalysts for Fuel Cell Protection during Transient Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V-100 V.D.5 Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V-111 V.F.2 Fuel Cell Fundamentals at Low and Subzero Temperatures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . V-211 Acumentrics Corporation V.J.2 Development of a Low-Cost 3-10 kW Tubular SOFC Power System .

407

fuel cells | OpenEI  

Open Energy Info (EERE)

cells cells Dataset Summary Description Developed for the U.S. Department of Energy's Office of Fuel Cell Technologies by Argonne National Laboratory and RCF Economic and Financial Consulting, Inc., JOBS and economic impacts of Fuel Cells (JOBS FC) is a spreadsheet model that estimates economic impacts from the manufacture and use of select types of fuel cells. Source Argonne Date Released Unknown Date Updated Unknown Keywords fuel cells Job Creation Data application/vnd.openxmlformats-officedocument.spreadsheetml.sheet icon File without Macros. Full version at official link. (xlsx, 2.8 MiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Time Period License License Open Data Commons Attribution License Comment From Argonne National Lab

408

Corrugated Membrane Fuel Cell Structures  

DOE Green Energy (OSTI)

By corrugating the fuel cell membrane electrode structure, Ion Power?s goal is to realize both the Pt utilization targets as well as the power density targets of the DOE. This will be achieved by demonstrating a fuel cell single cell (50 cm2) with a twofold increase in the membrane active area over the geometric area of the cell by corrugating the MEA structure. The corrugating structure must be able to demonstrate the target properties of < 10 mOhm-cm2 electrical resistance at > 20 psi compressive strength over the active area, in combination with offering at least 80% of power density that can be achieved by using the same MEA in a flat plate structure. Corrugated membrane fuel cell structures also have the potential to meet DOE power density targets by essentially packaging more membrane area into the same fuel cell volume as compared to conventional stack constructions.

Grot, Stephen [President, Ion Power Inc.

2013-09-30T23:59:59.000Z

409

Fuel Cell Technologies Office: Market Analysis Reports  

NLE Websites -- All DOE Office Websites (Extended Search)

Information Resources Information Resources Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Market Analysis Reports to someone by E-mail Share Fuel Cell Technologies Office: Market Analysis Reports on Facebook Tweet about Fuel Cell Technologies Office: Market Analysis Reports on Twitter Bookmark Fuel Cell Technologies Office: Market Analysis Reports on Google Bookmark Fuel Cell Technologies Office: Market Analysis Reports on Delicious Rank Fuel Cell Technologies Office: Market Analysis Reports on Digg Find More places to share Fuel Cell Technologies Office: Market Analysis Reports on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards Market Analysis Educational Publications Newsletter

410

DOE Hydrogen and Fuel Cell Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

eere.energy.gov eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U.S. Department of Energy Fuel Cell Technologies Program January 5, 2011 2 | Fuel Cell Technologies Program eere.energy.gov * Overview - Goals & Objectives - Technology Status & Key Challenges * Progress - Research & Development - Deployments - Recovery Act Projects * Budget * Key Publications Agenda: DOE Fuel Cell Technologies Program 3 | Fuel Cell Technologies Program eere.energy.gov Program Mission The mission of the Hydrogen and Fuel Cells Program is to enable the widespread commercialization of a portfolio of hydrogen and fuel cell technologies through basic and applied research, technology development and demonstration, and

411

Fuel Cell Technologies Office: Market Transformation  

NLE Websites -- All DOE Office Websites (Extended Search)

supporting the role that fuel cells play in our nation's energy portfolio. Through its market transformation efforts, the Fuel Cell Technologies Office seeks to accelerate the...

412

Fuel Cell Technologies Office: Systems Integration  

NLE Websites -- All DOE Office Websites (Extended Search)

Systems Integration to someone by E-mail Share Fuel Cell Technologies Office: Systems Integration on Facebook Tweet about Fuel Cell Technologies Office: Systems Integration on...

413

Fuel Cell Technologies Office: Hydrogen Technical Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Information Resources Information Resources Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Hydrogen Technical Publications to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Technical Publications on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Technical Publications on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Technical Publications on Google Bookmark Fuel Cell Technologies Office: Hydrogen Technical Publications on Delicious Rank Fuel Cell Technologies Office: Hydrogen Technical Publications on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Technical Publications on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards

414

NREL: Hydrogen and Fuel Cells Research - Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Projects NREL's hydrogen and fuel cell research projects focus on developing, integrating, and demonstrating advanced hydrogen production, hydrogen storage, and fuel cell...

415

Fuel Cell Technologies Office: Hydrogen Sensor Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

CSA Standards DOE Fuel Cell Technologies Office Element One, Inc. EmersonTherm-O-Disc FM Global Fuel Cell & Hydrogen Energy Association H2scan Honeywell Analytics Intelligent...

416

Fuel Cell Power Electronics Status & Challenges Tejinder ...  

Science Conference Proceedings (OSTI)

... Fuel cell powered critical refrigeration loads, preventing ... Ref. CL&P Connecticut Outage Map for October 2011 Fuel Cells: Power Through the Storm ...

2012-07-27T23:59:59.000Z

417

Joint Fuel Cell Bus Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

equipment is heavy and costly * Slow response time of the fuel cell adversely affects regenerative energy recovery potential and efficiency Barriers to full fuel cell bus...

418

Energy Conversion Devices Fuel Cell Electrocatalyst Development...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell(tm) Texaco Ovonic Fuel Cell Company, LLC non-precious metal catalysts regenerative braking energy absorption capability wide temperature range instant...

419

Fuel Cell Technologies Office: Program Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentations The Fuel Cell Technologies Office staff members give presentations about fuel cells and hydrogen at a variety of conferences. Some of their presentations are below....

420

Fuel Cell Technologies Office: Durability Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Durability Working Group to someone by E-mail Share Fuel Cell Technologies Office:...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Fuel Cell Technologies Office: Past Financial Opportunities  

NLE Websites -- All DOE Office Websites (Extended Search)

used. Technology Solicitation Title Open Date Close Date Hydrogen and Fuel Cells Fuel Cell Hybrid Electric Medium Duty Trucks, Roof-top Backup Power, and Advanced Hydrogen...

422

Fuel Cell Technologies Office: Annual Progress Reports  

NLE Websites -- All DOE Office Websites (Extended Search)

Progress Reports to someone by E-mail Share Fuel Cell Technologies Office: Annual Progress Reports on Facebook Tweet about Fuel Cell Technologies Office: Annual Progress Reports on...

423

Battery-Size Regenerative Fuel Cells  

ORNL 2010-G01073/jcn UT-B ID 201002378 Battery-Size Regenerative Fuel Cells Technology Summary A battery-size regenerative fuel cell with energy ...

424

Fuel Cell Technologies Office: Recovery Act  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

425

Fuel Cell Technologies Office: Hydrogen Infrastructure Market...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

426

Fuel Cell Technologies Office: Market Transformation  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

427

Fuel Cell Technologies Office: Related Financial Opportunities  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

428

Fuel Cell Technologies Office: Technical Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

429

Fuel Cell Technologies Office: 2013 Webinar Archives  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

430

Fuel Cell Technologies Office: Market Analysis Reports  

NLE Websites -- All DOE Office Websites (Extended Search)

of Energy - Energy Efficiency and Renewable Energy Fuel Cell Technologies Office Market Analysis Reports Reports about fuel cell and hydrogen technology market analysis...

431

Fuel Cell Technologies Office: Information Resources  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME...

432

Technology Validation: Fuel Cell Bus Evaluations (Poster)  

DOE Green Energy (OSTI)

Poster discusses hydrogen fuel cell transit bus evaluations conducted for the Hydrogen, Fuel Cells, & Infrastructure Technologies Program (HFCIT). It was presented at the 2006 HFCIT Program Review.

Eudy, L.

2006-05-01T23:59:59.000Z

433

Fuel Cell Technologies Office: IPHE Infrastructure Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

IPHE Infrastructure Workshop to someone by E-mail Share Fuel Cell Technologies Office: IPHE Infrastructure Workshop on Facebook Tweet about Fuel Cell Technologies Office: IPHE...

434

Fuel Cell Technologies Office: Educational Publications  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME ABOUT...

435

EERE: Fuel Cell Technologies Office Home Page  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficiency and Renewable Energy EERE Home | Programs & Offices | Consumer Information Fuel Cell Technologies Office Search Search Help Fuel Cell Technologies Office HOME ABOUT...

436

EERE: Fuel Cell Technologies Office - Webmaster  

NLE Websites -- All DOE Office Websites (Extended Search)

Webmaster Printable Version Share this resource Send a link to EERE: Fuel Cell Technologies Office - Webmaster to someone by E-mail Share EERE: Fuel Cell Technologies Office -...

437

EERE: Fuel Cell Technologies Office - Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Contacts Printable Version Share this resource Send a link to EERE: Fuel Cell Technologies Office - Contacts to someone by E-mail Share EERE: Fuel Cell Technologies Office -...

438

Hydrogen & Fuel Cells Blog | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Blog Hydrogen & Fuel Cells Blog Bioenergy Buildings Geothermal Government Energy Management Homes Hydrogen & Fuel Cells Manufacturing Solar Vehicles Water Wind Blog Archive Recent...

439

Fuel Cell Store Inc | Open Energy Information  

Open Energy Info (EERE)

search Name Fuel Cell Store, Inc Place San Diego, California Zip 92154 Sector Hydro, Hydrogen Product San Diego-based firm selling fuel cell stacks, components, and hydrogen...

440

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Webinar Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol U.S. DOE WEBINAR ON H2 FUELING PROTOCOLS: PARTICIPANTS Rob Burgess Moderator Jesse Schneider TIR J2601,...

442

Fuel Station of the Future- Innovative Approach to Fuel Cell...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

& Fuel Cell Technology Program Imagine pulling-up to a fuel station that supplies your car with clean, renewable fuel. Now imagine that, while you're filling up, this same...

443

Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study  

DOE Green Energy (OSTI)

In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

1991-12-31T23:59:59.000Z

444

Climate Change Fuel Cell Program  

DOE Green Energy (OSTI)

Verizon is presently operating the largest Distributed Generation Fuel Cell project in the USA. Situated in Long Island, NY, the power plant is composed of seven (7) fuel cells operating in parallel with the Utility grid from the Long Island Power Authority (LIPA). Each fuel cell has an output of 200 kW, for a total of 1.4 mW generated from the on-site plant. The remaining power to meet the facility demand is purchased from LIPA. The fuel cell plant is utilized as a co-generation system. A by-product of the fuel cell electric generation process is high temperature water. The heat content of this water is recovered from the fuel cells and used to drive two absorption chillers in the summer and a steam generator in the winter. Cost savings from the operations of the fuel cells are forecasted to be in excess of $250,000 per year. Annual NOx emissions reductions are equivalent to removing 1020 motor vehicles from roadways. Further, approximately 5.45 million metric tons (5 millions tons) of CO2 per year will not be generated as a result of this clean power generation. The project was partially financed with grants from the New York State Energy R&D Authority (NYSERDA) and from Federal Government Departments of Defense and Energy.

Paul Belard

2006-09-21T23:59:59.000Z

445

Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC and LSCF  

E-Print Network (OSTI)

1 Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC cathode materials for Single Chamber Solid Oxide Fuel Cell (SC-SOFC) (La0.8Sr0.2MnO3- (LSM), Ba0.5Sr0.5Co0 Chamber, Solid Oxide Fuel cell, SSC. 1 Introduction Single Chamber Solid Oxide Fuel Cells (SC-SOFC) show

446

Overview of Hydrogen Fuel Cell Budget  

NLE Websites -- All DOE Office Websites (Extended Search)

Budget Budget FUEL CELL TECHNOLOGIES PROGRAM Stakeholders Webinar - Budget Briefing Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager February 24, 2011 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov Fuel Cells: For Diverse Applications 3 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov INTRODUCTION: FY 2012 Budget in Brief Continues New Sub-programs for: * Fuel Cell Systems R&D - Consolidates four sub-programs: Fuel Cell Stack Components R&D, Transportation Fuel Cell Systems, Distributed Energy Fuel Cell Systems, and Fuel Processor R&D - Technology-neutral fuel cell systems R&D for diverse applications * Hydrogen Fuel R&D - Consolidates Hydrogen Production & Delivery and Hydrogen Storage activities

447

Calling All Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

448

Calling All Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

449

Nanostructured thin films for solid oxide fuel cells  

E-Print Network (OSTI)

The goals of this work were to synthesize high performance perovskite based thin film solid oxide fuel cell (TF-SOFC) cathodes by pulsed laser deposition (PLD), to study the structural, electrical and electrochemical properties of these cathodes and to establish structure-property relations for these cathodes in order to further improve their properties and design new structures. Nanostructured cathode thin films with vertically-aligned nanopores (VANP) were processed using PLD. These VANP structures enhance the oxygen-gas phase diffusivity, thus improve the overall TF-SOFC performance. La0.5Sr0.5CoO3 (LSCO) and La0.4Sr0.6Co0.8Fe0.2O3 (LSCFO) were deposited on various substrates (YSZ, Si and pressed Ce0.9Gd0.1O1.95 (CGO) disks). Microstructures and properties of the nanostructured cathodes were characterized by transmission electron microscope (TEM), high resolution TEM (HRTEM), scanning electron microscope (SEM) and electrochemical impedance spectroscopy (EIS) measurements. A thin layer of vertically-aligned nanocomposite (VAN) structure was deposited in between the CGO electrolyte and the thin film LSCO cathode layer for TF-SOFCs. The VAN structure consists of the electrolyte and the cathode materials in the composition of (CGO) 0.5 (LSCO) 0.5. The self-assembled VAN nanostructures contain highly ordered alternating vertical columns formed through a one-step thin film deposition using a PLD technique. These VAN structures significantly increase the interface area between the electrolyte and the cathode as well as the area of active triple phase boundary (TPB), thus improving the overall TF-SOFC performance at low temperatures, as low as 400oC, demonstrated by EIS measurements. In addition, the binary VAN interlayer could act as the transition layer that improves the adhesion and relieves the thermal stress and lattice strain between the cathode and the electrolyte. The microstructural properties and growth mechanisms of CGO thin film prepared by PLD technique were investigated. Thin film CGO electrolytes with different grain sizes and crystal structures were prepared on single crystal YSZ substrates under different deposition conditions. The effect of the deposition conditions such as substrate temperature and laser ablation energy on the microstructural properties of these films are examined using XRD, TEM, SEM, and optical microscope. CGO thin film deposited above 500 C starts to show epitaxial growth on YSZ substrates. The present study suggests that substrate temperature significantly influences the microstructure of the films especially film grain size.

Yoon, Jongsik

2008-12-01T23:59:59.000Z

450

Fuel cell applications for novel metalloporphyrin catalysts  

DOE Green Energy (OSTI)

This project utilized Computer-Aided Molecular Design (CAMD) to develop a new class of metalloporphyrin materials for use as catalysts for two fuel cell reactions. The first reaction is the reduction of oxygen at the fuel cell cathode, and this reaction was the main focus of the research. The second reaction we attempted to catalyze was the oxidation of methanol at the anode. Two classes of novel metalloporphyrins were developed. The first class comprised the dodecaphenylporphyrins whose steric bulk forces them into a non-planar geometry having a pocket where oxygen or methanol is more tightly bound to the porphyrin than it is in the case of planar porphyrins. Significant improvements in the catalytic reduction of oxygen by the dodecaphenyl porphyrins were measured in electrochemical cells. The dodecaphenylporphyrins were further modified by fluorinating the peripheral phenyl groups to varying degrees. The fluorination strongly affected their redox potential, but no effect on their catalytic activity towards oxygen was observed. The second class of porphyrin catalysts was a series of hydrogen-bonding porphyrins whose interaction with oxygen is enhanced. Enhancements in the interaction of oxygen with the porphyrins having hydrogen bonding groups were observed spectroscopically. Computer modeling was performed using Molecular Simulations new CERIUS2 Version 1.6 and a research version of POLYGRAF from Bill Goddard`s research group at the California Institute of Technology. We reoptimized the force field because of an error that was in POLYGRAF and corrected a problem in treatment of the metal in early versions of the program. This improved force field was reported in a J. Am. Chem. Soc. manuscript. Experimental measurements made on the newly developed catalysts included the electrochemical testing in a fuel cell configuration and spectroscopic measurements (UV-Vis, Raman and XPS) to characterize the catalysts.

Ryba, G.; Shelnutt, J.; Doddapaneni, N.; Zavadil, K.

1997-04-01T23:59:59.000Z

451

Progress in carbonate fuel cells  

DOE Green Energy (OSTI)

Our objective is to increase both the life and power of the molten carbonate fuel (MCFC) by developing improved components and designs. Current activities are as follows: (1)Development of LiFeO{sub 2} and LiCoO{sub 2} cathodes for extended MCFC life, particularly in pressurized operation, where the present cathode, NiO, provides insufficient life (2) Development of distributed-manifold MCFC designs for increased volumetric power density and decreased temperature gradients (and, therefore, increased life) (3) Development of components and designs appropriate for high-power density operation (>2 kW/m{sup 2}and >100 kW/m{sup 3}in an integrated MCFC system) (4)Studies of pitting corrosion of the stainless-steel interconnects and aluminized seals now being employed in the MCFC (alternative components will also be studied). Each of these activities has the potential to reduce the MCFC system cost significantly. Progress in each activity will be presented during the poster session.

Myles, K.M.; Krumpelt, M.; Roche, M.F. [and others

1995-12-31T23:59:59.000Z

452

Fuel Cell Technologies Office: DOE Fuel Cell Pre-Solicitation...  

NLE Websites -- All DOE Office Websites (Extended Search)

of the DOE Hydrogen Program (PDF 1.1 MB), JoAnn Milliken, DOE Hydrogen Program Manager SOFC Technology R&D Needs (PDF 1.7 MB), Steven Shaffer, Delphi Chief Engineer, Fuel Cell...

453

NREL: Hydrogen and Fuel Cells Research - Fuel Cell Electric Vehicles...  

NLE Websites -- All DOE Office Websites (Extended Search)

the cost and increasing the performance of fuel cell propulsion systems, and most major vehicle manufacturers are geared to launch FCEVs in the U.S. market between 2015 and 2020....

454

Fuel Cell Technologies Office: Fuel Cells Today: Early Market...  

NLE Websites -- All DOE Office Websites (Extended Search)

Here (music) Hydrogen and fuel cell technologies are beginning to enter the market and learning demonstrations are spreading to various parts of the country. As you begin to see...

455