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1

Advanced Cathode Catalysts and Supports for PEM Fuel Cells |...  

Energy Savers (EERE)

Advanced Cathode Catalysts and Supports for PEM Fuel Cells Advanced Cathode Catalysts and Supports for PEM Fuel Cells 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

2

Degradation of Ionic Pathway in PEM Fuel Cell Cathode. | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Degradation of Ionic Pathway in PEM Fuel Cell Cathode. Degradation of Ionic Pathway in PEM Fuel Cell Cathode. Abstract: The degradation of the ionic pathway throughout the catalyst...

3

Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance Alkaline Fuel Cell Membranes Improving Fuel Cell...

4

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on advanced cathode catalysts and supports for PEM fuel cells, was given by Mark Debe of 3M at a February 2007 meeting on new fuel cell projects.

5

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

6

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

7

Nanofiber Scaffold for Cathode of Solid Oxide Fuel Cell  

SciTech Connect

A high performance solid oxide fuel cell cathode using the yttria-stabilized zirconia (YSZ) nanofibers scaffold with the infiltrated La1-xSrxMnO3 (LSM) shows an enhanced catalytic activity toward oxygen reduction. Such a cathode offers a continuous path for charge transport and an increased number of triple-phase boundary sites.

Mingjia Zhi; Nicholas Mariani; Randall Gemmen; Kirk Gerdes; Nianqiang Wu

2010-10-01T23:59:59.000Z

8

Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells  

Science Journals Connector (OSTI)

Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells ... The optimum amount of graphite fibers needed for these brush electrodes has not yet been optimized, and the cathode remains the greatest challenge for MFC designs. ... Different catalyst locations (inside versus outside) and loadings, specific surface areas, and solution chemistry (solution conductivity) were examined to optimize performance. ...

Yi Zuo; Shaoan Cheng; Bruce E. Logan

2008-08-13T23:59:59.000Z

9

Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on cathode supports for PEM fuel cells, was given by Yong Wang of PNNL at a February 2007 meeting on new fuel cell projects.

10

Cathode porous transport irreversibility model for PEM fuel cell design  

Science Journals Connector (OSTI)

The influence is studied of slip-irreversibility at the interface between the gas diffusion layer, also referred to here as the porous transport layer, and the catalyst layer of a proton exchange membrane fuel cell (PEMFC). A two-dimensional cathode ... Keywords: catalyst layer, exergy, gas diffusion layer, slip flow irreversibility

E. O. B. Ogedengbe; M. A. Rosen

2009-02-01T23:59:59.000Z

11

Degradation characteristics of air cathode in zinc air fuel cells  

Science Journals Connector (OSTI)

Abstract The zinc air fuel cell (ZAFC) is a promising candidate for electrical energy storage and electric vehicle propulsion. However, its limited durability has become a major obstacle for its successful commercialization. In this study, 2-cell stacks, 25cm cells and three-electrode half-cells are constructed to experimentally investigate the degradation characteristics of the air cathode. The results of electrochemical tests reveal that the peak power density for the 25cm2 cell with a new air cathode is 454mWcm?2, which is twice as the value of the used air cathode. The electrochemical impedance analysis shows that both the charge transfer resistance and the mass transfer resistance of the used air cathodes have increased, suggesting that the catalyst surface area and gas diffusion coefficient have decreased significantly. Additionally, the microstructure and morphology of the catalytic layer (CL) and gas diffusion layer (GDL) are characterized by scanning electron microscopes (SEM). SEM results confirm that the micropores in CL and GDL of the used air cathode are seriously clogged, and many catalyst particles are lost. Therefore, the performance degradation is mainly due to the clogging of micropores and loss of catalyst particles. Furthermore, hypotheses of degradation mechanism and mitigation strategies for GDL and CL are discussed briefly.

Ze Ma; Pucheng Pei; Keliang Wang; Xizhong Wang; Huachi Xu; Yongfeng Liu; Guanlin peng

2015-01-01T23:59:59.000Z

12

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

13

Heterogeneous electrocatalysis in porous cathodes of solid oxide fuel cells  

E-Print Network (OSTI)

A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas dissociative adsorption and surface diffusion of the oxygen intermediate to the triple phase boundary, where charge transfer occurs. The model accurately captures the Gerischer-like frequency dependence and the oxygen partial pressure dependence of the impedance of symmetric cathode cells. Digital image analysis of the microstructure of the cathode functional layer in four different cells directly confirms the predicted connection between geometrical properties and the impedance response. As in classical catalysis, the electrocatalytic activity is controlled by an effective Thiele modulus, which is the ratio of the surface diffusion length (mean distance from an adsorption site to the triple phase boundary) to the surface boundary layer length (square root of surface diffusivity div...

Fu, Y; Bertei, A; Qi, C; Mohanram, A; Pietras, J D; Bazant, M Z

2014-01-01T23:59:59.000Z

14

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect

One primary suspected cause of long-term performance degradation of solid oxide fuels (SOFCs) is the accumulation of chromium (Cr) species at or near the cathode/electrolyte interface due to reactive Cr molecules originating from Cr-containing components (such as the interconnect) in fuel cell stacks. To date, considerable efforts have been devoted to the characterization of cathodes exposed to Cr sources; however, little progress has been made because a detailed understanding of the chemistry and electrochemistry relevant to the Cr-poisoning processes is still lacking. This project applied multiple characterization methods - including various Raman spectroscopic techniques and various electrochemical performance measurement techniques - to elucidate and quantify the effect of Cr-related electrochemical degradation at the cathode/electrolyte interface. Using Raman microspectroscopy the identity and location of Cr contaminants (SrCrO{sub 4}, (Mn/Cr){sub 3}O{sub 4} spinel) have been observed in situ on an LSM cathode. These Cr contaminants were shown to form chemically (in the absence of current flowing through the cell) at temperatures as low as 625 C. While SrCrO{sub 4} and (Mn/Cr){sub 3}O{sub 4} spinel must preferentially form on LSM, since the LSM supplies the Sr and Mn cations necessary for these compounds, LSM was also shown to be an active site for the deposition of Ag{sub 2}CrO{sub 4} for samples that also contained silver. In contrast, Pt and YSZ do not appear to be active for formation of Cr-containing phases. The work presented here supports the theory that Cr contamination is predominantly chemically-driven and that in order to minimize the effect, cathode materials should be chosen that are free of cations/elements that could preferentially react with chromium, including silver, strontium, and manganese.

Harry Abernathy; Meilin Liu

2006-12-31T23:59:59.000Z

15

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Catalysts and Cathode Catalysts and Supports for PEM Fuel Cells DE-FG36-07GO17007 Mark K. Debe 3M Company Feb. 13, 2007 2007 DOE HFCIT Kick-off Meeting This presentation does not contain any proprietary or confidential information Overview Advanced Cathode Catalysts and Supports for PEM FC's - 2007 DOE HFCIT Kick-off, Feb. 13-14, 2007 2 3 Barriers A. Electrode and MEA Durability B. Stack Material & Mfg Cost C. Electrode and MEA Performance DOE Technical Targets Electrocatalyst (2010, 2015) * Durability w/cycling: hrs < 80 o C - (5000, 5000) > 80 o C - (2000, 5000) * Cost: $/kW (5,4) * Mass activity: A/mg ( 0.44, 0.44) * PGM Total, g/ kW rated: (0.3, 0.2) MEA (2010, 2015) * Cost: $/kW (10,5) * Performance: W/cm 2 at Rated Pwr. (1,1) ; 0.8V (0.25, 0.25) Budget * Total Project funding $10.43MM

16

Modeling Studies of a Cylindrical Polymer Electrolyte Membrane Fuel Cell Cathode  

Science Journals Connector (OSTI)

The cathode catalyst layer is modeled using spherical agglomerate characterization. ... (16-19) In the present work, we have developed a two-dimensional (2-D) steady-state model of a cylindrical PEMFC cathode under air-breathing and pressurized conditions. ... We adopt an agglomerate catalyst layer model and recast it into a compact form for optimization of polymer electrolyte fuel cell cathodes. ...

Srinivasarao Modekurti; Brian Bullecks; Debangsu Bhattacharyya; Raghunathan Rengaswamy

2012-03-12T23:59:59.000Z

17

Impact of salinity on cathode catalyst performance in microbial fuel cells (MFCs)  

E-Print Network (OSTI)

not been previously examined. Three different types of cathode materials were tested here with increasingly of catalyst used with more saline wastewaters. While Pt oxygen reduction activity is reduced, CoTMPP cathodeImpact of salinity on cathode catalyst performance in microbial fuel cells (MFCs) Xi Wang

18

Challenges and Constraints of Using Oxygen Cathodes in Microbial Fuel Cells  

Science Journals Connector (OSTI)

Challenges and Constraints of Using Oxygen Cathodes in Microbial Fuel Cells ... The optimization of the cathode preparation (the choice of binder (5), the binder/catalyst ratio, the catalyst processing etc.) was beyond the scope of this study and should be the focus of further, technological investigations. ... Optimized cathode preparation procedures will most likely help increasing this factor and result in a further improved cathode performance at lower catalyst loads. ...

Feng Zhao; Falk Harnisch; Uwe Schrder; Fritz Scholz; Peter Bogdanoff; Iris Herrmann

2006-05-25T23:59:59.000Z

19

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

20

SWNT?MWNT Hybrid Architecture for Proton Exchange Membrane Fuel Cell Cathodes  

Science Journals Connector (OSTI)

SWNT?MWNT Hybrid Architecture for Proton Exchange Membrane Fuel Cell Cathodes ... A thin film of single-wall carbon nanotubes (SWNTs) and SWNT?multiwall carbon nanotube (MWNT) hybrids loaded with Pt have been evaluated as the cathode catalyst layer in proton exchange membrane fuel cells. ... Hydrogen, Fuel Cells & Infrastructure Technologies Program: Multi-Year Research, Development and Demonstration Plan: Planned Program Activities for 2003?2010; U.S. Department of Energy: Energy Efficiency and Renewable Energy: January 21, 2005. ...

Palanisamy Ramesh; Mikhail E. Itkis; Jason M. Tang; Robert C. Haddon

2008-05-28T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

SciTech Connect

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

22

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network (OSTI)

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights to drive fast ionic transport. 1. Introduction The interest in Solid Oxide Fuel Cell (SOFC) technology. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediate

Yildiz, Bilge

23

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform  

E-Print Network (OSTI)

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R of hydrogen H2 and oxygen O2 . Operating fuel cells in alkaline media, as opposed to acidic media, has on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing

Kenis, Paul J. A.

24

A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode  

SciTech Connect

Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D. (Chemical Sciences and Engineering Division); (National Institute of Advanced Industrial Science and Technology)

2012-01-01T23:59:59.000Z

25

Hydrous oxide species as inhibitors of oxygen reduction at platinum activated fuel cell cathodes  

Science Journals Connector (OSTI)

The successful development of a methanol/air fuel cell requires optimum performance of the air/ oxygen cathode at about 0.8 V vs RHE. ... oxygen gas reduction on platinum (the best electrocatalyst for this reacti...

L. D. Burke; J. K. Casey; J. A. Morrissey

1994-01-01T23:59:59.000Z

26

Composite cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells  

Science Journals Connector (OSTI)

Composites consisting of silver and yttria stabilized bismuth oxide (YSB) have been investigated as cathodes for low-temperature honeycomb solid oxide fuel cells with stabilized zirconia as electrolytes. At 600? C the interfacial polarization resistances of a porous YSBAg cathode is about 0.3??? cm 2 more than one order of magnitude smaller than those of other reported cathodes on stabilized zirconia. For example the interfacial resistances of a traditional YSZlanthanum maganites composite cathode is about 11.4??? cm 2 at 600? C . Impedance analysis indicated that the performance of an YSBAg composite cathode fired at 850? C for 2 h is severely limited by gas transport due to insufficient porosity. The high performance of the YSBAg cathodes is very encouraging for developing honeycomb fuel cells to be operated at temperatures below 600? C .

Changrong Xia; Yuelan Zhang; Meilin Liu

2003-01-01T23:59:59.000Z

27

Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell  

E-Print Network (OSTI)

. Researchers all over the world are focusing on optimizing this system to be cost competitive with energy conversion devices currently available. It is a well known fact that the cathode of the PEM fuel cell is the performance limiting component due...THREE DIMENSIONAL EFFECTS OF LIQUID WATER FLOODING IN THE CATHODE OF A PEM FUEL CELL by Dilip Natarajan and Trung Van Nguyen* Department of Chemical and Petroleum Engineering University of Kansas Lawrence, KS 66045, USA Submitted...

Natarajan, Dilip; Van Nguyen, Trung

2003-03-27T23:59:59.000Z

28

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black  

E-Print Network (OSTI)

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black-based materials that have good catalytic activity, but the electrical conductivity of the AC is poor compared as a binder, as opposed to Nafion with Pt, which greatly reduces the cost of the cathode materials. AC

29

Electricity generation from sediment microbial fuel cells with algae-assisted cathodes  

Science Journals Connector (OSTI)

Abstract One major limiting factor for sediment microbial fuel cells (SMFC) is the low oxygen reduction rate in the cathode. The use of the photosynthetic process of the algae is an effective strategy to increase the oxygen availability to the cathode. In this study, \\{SMFCs\\} were constructed by introducing the algae (Chlorella vulgaris) to the cathode, in order to generate oxygen in situ. Cyclic voltammetry and dissolved oxygen analysis confirmed that C. vulgaris in the cathode can increase the dissolved oxygen concentration and the oxygen reduction rate. We showed that power generation of SMFC with algae-assisted cathode was 21mWm?2 and was further increased to 38mWm?2 with additional carbon nanotube coating in the cathode, which was 2.4 fold higher than that of the SMFC with bare cathode. This relatively simple method increases the oxygen reduction rate at a low cost and can be applied to improve the performance of SMFCs.

De-Bin Wang; Tian-Shun Song; Ting Guo; Qinglu Zeng; Jingjing Xie

2014-01-01T23:59:59.000Z

30

Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz  

E-Print Network (OSTI)

Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz as cathode electrodes in proton exchange membrane PEM fuel cells. Deposition on flat substrates yields February 4, 2010. Proton exchange membrane PEM fuel cells are promising for future automotive applications

Gall, Daniel

31

Mechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Cathode  

Science Journals Connector (OSTI)

The efficiency of the oxygen reduction reaction (ORR), 4H+ + 4e + O2 ? 2H2O, at the cathode of a polymer electrolyte membrane fuel cell (PEMFC) is a critical issue for commercial application of this type of fuel cells. ... This agrees with the volcano-like trend for ORR catalysts,(7, 31, 32) when the activity first increases and then decreases as the catalyst d-band center shifts downward. ... Improved Non-Pt Alloys for the Oxygen Reduction Reaction at Fuel Cell Cathodes Predicted from Quantum Mechanics ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2012-09-04T23:59:59.000Z

32

Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative and Durable High Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Development of Alternative and Durable High Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Performance Cathode Supports for PEM Fuel Cells PNNL: Yong Wang Conrad Zhang Vilayanur Viswanath Yuehe Lin Jun Liu Project kick Project kick - - off meeting off meeting Feb 13 Feb 13 - - 14, 2007 14, 2007 Ballard Power Systems: Stephen Campbell University of Delaware: Jingguang Chen ORNL: Sheng Dai 2 Technical Issues and Objective Technical Issues and Objective Current technical issues z Carbon support „ Susceptible to oxidation under fuel cell operating conditions. „ Oxidation further catalyzed by Pt „ Corrosion leads to Pt migration and agglomeration

33

Recent advances in cathode electrocatalysts for PEM fuel cells  

Science Journals Connector (OSTI)

Great progress has been made in the past two decades in the development of the electrocatalysts for proton exchange membrane fuel cells (PEMFCs). This review article is focused on recent advances made in the k...

Junliang Zhang

2011-06-01T23:59:59.000Z

34

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes  

SciTech Connect

Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385C for 2 h, and subsequently creep-flattened at 1350C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500C to 750C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

2010-05-08T23:59:59.000Z

35

Influence of NaCl on cathode performance of solid oxide fuel cells  

Science Journals Connector (OSTI)

Degradation induced by sodium chloride in air was...0.8Sr0.2)0.98MnO3(LSM) and La0.6Sr0.4Co0.2Fe0.8O3(LSCF) cathodes in solid oxide fuel cells(SOFC). Cell performance was measured by volatilizing NaCl to...2...fo...

Run-ru Liu; De-jun Wang; Jing Leng

2013-08-01T23:59:59.000Z

36

Carbon Nanotube Film by Filtration as Cathode Catalyst Support for Proton-Exchange Membrane Fuel Cell  

Science Journals Connector (OSTI)

Carbon Nanotube Film by Filtration as Cathode Catalyst Support for Proton-Exchange Membrane Fuel Cell ... 1-10 Some early investigations found that by using the normal paste method and simply replacing carbon black particles with disordered multiwalled CNTs as the support for Pt catalyst nanoparticles higher PEMFC and DMFC performances were achieved. ... activity of the CNT cathode catalysts was measured in a direct methanol fuel cell by use of a Pt-Ru/C anode, and use of a Nafion-115 membrane. ...

Wenzhen Li; Xin Wang; Zhongwei Chen; Mahesh Waje; Yushan Yan

2005-09-08T23:59:59.000Z

37

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

SciTech Connect

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

38

Improved Non-Pt Alloys for the Oxygen Reduction Reaction at Fuel Cell Cathodes Predicted from Quantum Mechanics  

E-Print Network (OSTI)

the hypothesis that improved alloy catalysts for the oxygen reduction reaction (ORR) at fuel cell cathodes should catalysts for polymer electrolyte mem- brane fuel cell (PEMFC) than pure Pt, while maintaining or improving the surface under FC operating conditions.9 To determine new alloy candidates for PEMFC cathodes, we

Goddard III, William A.

39

The Orientation Distributions of Lines, Surfaces, and Interfaces around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes  

E-Print Network (OSTI)

in Solid Oxide Fuel Cell Cathodes Shen J. Dillon, Lam Helmick,§,¶ Herbert M. Miller,§ Lane Wilson in a multiphase ceramic material. I. Introduction THE active cathode regions of many solid oxide fuel cells (SOFCs of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild

Rohrer, Gregory S.

40

Comparison of electrogenic capabilities of microbial fuel cell with different light power on algae grown cathode  

Science Journals Connector (OSTI)

Electricity generation capabilities of microbial fuel cell with different light power on algae grown cathode were compared. Results showed that microbial fuel cell with 6 and 12W power of light always produced higher voltage and power density than with 18 and 26W. Similarly, microbial fuel cell with 6 and 12W of light power always displayed higher Coulombic efficiency and specific power than the one with 18 and 26W. The results also showed that microbial fuel cell with covered anodic chamber always displayed higher voltage, power density, Coulombic efficiency and specific power than the one without covered anodic chamber. Binary quadratic equations can be used to express the relationships between the light power and the voltage, power density, Coulombic efficiency and specific power. Although lower power of light on algae grown cathode and covering anodic chamber will increase systems electricity production, they will not significantly reduce its internal resistance.

D.F. Juang; C.H. Lee; S.C. Hsueh

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Approaches to methanol-tolerant air cathodes for methanol-air fuel cells  

SciTech Connect

The achievement of truly methanol-tolerant oxygen cathodes will greatly assist the development of direct methanol-air fuel cells, because the cathode performance will not be affected by the presence of methanol or its oxidation products, which can diffuse across the cell from the anode. In addition, methanol will not be consumed at the cathode. Although platinum-based oxygen cathodes can continue to perform well in the presence of methanol under certain conditions, methanol can be consumed rapidly at such electrodes. Oxygen electrocatalysts were examined in the present work which are largely inactive for methanol oxidation and are also not affected significantly by the presence of methanol. These included heat-treated transition metal macrocycles and hydrated ruthenium dioxide. The most promising electrocatalyst examines thus far is heat-treated iron tetramethoxyphenylporphyrin supported on high area carbon.

Tryk, D.A.; Gupta, S.L.; Aldred, W.H.; Yeager, E.B. [Case Western Reserve Univ., Cleveland, OH (United States)

1994-12-31T23:59:59.000Z

42

Supporting Information Power generation by packed-bed air-cathode microbial fuel cells  

E-Print Network (OSTI)

1 Supporting Information Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan b a State Key Joint Laboratory of Environment Simulation and Pollution Control, THU­ VEOLIA Informatics, China University of Mining and Technology, Xuzhou 221116, PR China * Corresponding author: E

43

Portable power source based on air-hydrogen fuel cells with free-breathing cathodes  

Science Journals Connector (OSTI)

Portable power source based on air-hydrogen fuel cells (FCs) operating in a free-breathing cathode regime has been developed. At a volume of 100 cm3, the source has a power capacity of 8.5 W h and generates a pow...

S. A. Gurevich; E. I. Terukov; O. I. Konkov; A. A. Tomasov

2011-05-01T23:59:59.000Z

44

Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes  

DOE Patents (OSTI)

Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

2014-01-28T23:59:59.000Z

45

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through Electrode  

E-Print Network (OSTI)

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through for proton exchange membrane PEM fuel cells. X-ray diffraction and scanning electron microscopy show manuscript received September 17, 2009. Published November 13, 2009. Proton exchange membrane PEM fuel cells

Gall, Daniel

46

Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts  

DOE Patents (OSTI)

Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

2014-08-12T23:59:59.000Z

47

Microsoft Word - Fuel Cell Cathode Report_WhiteBurke_v09 050713.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Recent Solid Oxide Fuel Cell Recent Solid Oxide Fuel Cell Cathode Studies Tools, Results, and Novel Concepts for Making Better Cells May 9, 2013 DOE/NETL-2013/1618 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process

48

Microbial fuel cell with an algae-assisted cathode: A preliminary assessment  

Science Journals Connector (OSTI)

Abstract A microbial fuel cell (MFC) with an algae-assisted cathode, i.e., a system where the oxygen required by the cathode is not provided by aeration but by the photosynthetic process of the algae (Chlorella vulgaris), has been studied. The cathode was illuminated for 12h each day (from 8:00h to 20:00h). 25 days was necessary to achieve steady state conditions. The time evolution of dissolved oxygen and cell voltage were assessed over the course of each day. As expected, the dissolved oxygen values were not constant throughout the day, reaching maximum values between 14:00h and 20:00h when dark phase reactions began and the algae started to consume oxygen. Cell voltage (Rext 120?) followed the same trend as the oxygen profile. The supply of CO2 in the cathode was also studied, and half an hour was enough time to get the system working properly. During the acclimation stage, power density increased up to 13.5mWm?2 at steady state conditions. However, impedance analysis showed that polarization resistance was higher at the cathode than at the anode. Nevertheless, it canbe concluded that the studied system is a feasible method to treat wastewater in a self-sustainable way.

Araceli Gonzlez del Campo; Pablo Caizares; Manuel A. Rodrigo; Francisco J. Fernndez; Justo Lobato

2013-01-01T23:59:59.000Z

49

Optimization of the Cathode Catalyst Layer Composition of a PEM Fuel Cell Using a Novel 2-Step Preparation Method  

E-Print Network (OSTI)

For good performance and high durability PEM fuel cells run at high water saturation levels. However, excess liquid water generated by the oxygen reduction reaction at the cathode can block pores in the catalyst layer so ...

Friedmann, Roland

2009-03-05T23:59:59.000Z

50

Mass transport in gas-diffusion electrodes: A diagnostic tool for fuel-cell cathodes  

SciTech Connect

Two mathematical models of gas-diffusion electrodes, one for liquid electrolytes and one for ion-exchange polymer electrolytes, are presented to investigate the effects of mass-transport limitations on the polarization characteristics of a reaction obeying Tafel kinetics. The focus is on low-temperature fuel-cell cathodes, and in particular, contrasting two limiting cases that may be encountered at high current densities: control by kinetics and dissolved oxygen mass transport vs. control by kinetics and ionic mass transport. It is shown that two distinct double Tafel slopes may arise from these two limiting cases. The former is first order, and the latter is half-order with respect to oxygen concentration. How the modeling results may be applied to diagnose the performance of fuel-cell cathodes is also presented. Since the ionic-mass-transport-limited case has generally been neglected in previous gas-diffusion electrode models, specific examples of fuel-cell cathode data from the literature which display the behavior predicted by the models in this case are given and briefly discussed.

Perry, M.L.; Newman, J.; Cairns, E.J. [Lawrence Berkeley National Lab., CA (United States). Energy and Environment Div.]|[Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering

1998-01-01T23:59:59.000Z

51

Composite Cathode for High-Power Density Solid Oxide Fuel Cells  

SciTech Connect

Reduction of solid oxide fuel cell (SOFC) operating temperature will play a key role in reducing the stack cost by allowing the use of low-cost metallic interconnects and new approaches to sealing, while making applications such as transportation more feasible. Reported results for anode-supported SOFCs show that cathode polarization resistance is the primary barrier to achieving high power densities at operating temperatures of 700 C and lower. This project aims to identify and develop composite cathodes that could reduce SOFC operating temperatures below 700 C. This effort focuses on study and use of (La,Sr)(Co,Fe)O{sub 3} (LSCF) based composite cathodes, which have arguably the best potential to substantially improve on the currently-used, (La,Sr)MnO{sub 3}-Yttria-stabilized Zirconia. During this Phase I, it was successfully demonstrated that high performances can be achieved with LSCF/Gadolinium-Doped Ceria composite cathodes on Ni-based anode supported cells operating at 700 C or lower. We studied electrochemical reactions at LSCF/Yttria-stabilized Zirconia (YSZ) interfaces, and observed chemical reactions between LSCF and YSZ. By using ceria electrolytes or YSZ electrolytes with ceria diffusion barrier layers, the chemical reactions between LSCF and electrolytes were prevented under cathode firing conditions necessary for the optimal adhesion of the cathodes. The protection provided by ceria layer is expected to be adequate for stable long-term cathode performances, but more testing is needed to verify this. Using ceria-based barrier layers, high performance Ni-YSZ anode supported cells have been demonstrated with maximum power densities of 0.8W/cm2 at 700 C and 1.6W/cm{sup 2} at 800 C. Ni-SDC anode supported cells with SDC electrolytes yielded >1W/cm{sup 2} at 600 C. We speculate that the power output of Ni-YSZ anode supported cell at 700 C and lower, was limited by the quality of the Ceria and Ceria YSZ interface. Improvements in the low-temperature performances are expected based on further development of barrier layer fabrication processes and optimization of cathode microstructure.

Ilwon Kim; Scott Barnett; Yi Jiang; Manoj Pillai; Nikkia McDonald; Dan Gostovic; Zhongryang Zhan; Jiang Liu

2004-01-31T23:59:59.000Z

52

Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Ultra-low Platinum Alloy Development of Ultra-low Platinum Alloy C th d C t l t f PEM F l C ll Cathode Catalyst for PEM Fuel Cells 2010 DOE Hydrogen Program Fuel Cell Project Kick-Off P I : Branko N Popov P. I.: Branko N. Popov Center for Electrochemical Engineering University of South Carolina Columbia SC 29208. September 28, 2010 This presentation does not contain any proprietary, confidential, or otherwise restricted information Center for Electrochemical Engineering, University of South Carolina 1 Overview Timeline * S Start d date: J June 01 2010 01 2010 * End date: Nov 30 2012 (Phase I) : May 31 2014 (Phase II) Budget * Total project funding ¾ DOE share: $ 4 400 000 ¾ DOE share: $ 4,400,000 ¾ Contractor share: $1,100,000 * Incremental funding received in FY10: $750,000

53

Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b  

E-Print Network (OSTI)

Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b , Juan Shi c Laboratory of Environment Simulation and Pollution Control, THU­VEOLIA Environment Joint Research Center Park, PA 16802, USA c School of Environment Science and Spatial Informatics, China University of Mining

54

Combined Theoretical and Experimental Analysis of Processes Determining Cathode Performance in Solid Oxide Fuel Cells  

SciTech Connect

Solid oxide fuel cells (SOFC) are under intensive investigation since the 1980s as these devices open the way for ecologically clean direct conversion of the chemical energy into electricity, avoiding the efficiency limitation by Carnots cycle for thermochemical conversion. However, the practical development of SOFC faces a number of unresolved fundamental problems, in particular concerning the kinetics of the electrode reactions, especially oxygen reduction reaction. We review recent experimental and theoretical achievements in the current understanding of the cathode performance by exploring and comparing mostly three materials: (La,Sr)MnO3 (LSM), (La,Sr)(Co,Fe)O3 (LSCF) and (Ba,Sr)(Co,Fe)O3 (BSCF). Special attention is paid to a critical evaluation of advantages and disadvantages of BSCF, which shows the best cathode kinetics known so far for oxides. We demonstrate that it is the combined experimental and theoretical analysis of all major elementary steps of the oxygen reduction reaction which allows us to predict the rate determining steps for a given material under specific operational conditions and thus control and improve SOFC performance.

Kukla, Maija M.; Kotomin, Eugene Alexej; Merkle, R.; Mastrikov, Yuri; Maier, J.

2013-02-11T23:59:59.000Z

55

A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications  

E-Print Network (OSTI)

Fuel Cell Applications Fikile R. Brushett, Matthew S. Thorum, Nicholas S. Lioutas, Matthew S. Naughton-tri/C) is investigated as a cathode material using an alkaline microfluidic H2/O2 fuel cell. The absolute Cu be realized by optimizing catalyst and electrode preparation procedures. Fuel cell-based systems hold promise

Kenis, Paul J. A.

56

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the third quarter of the project. Effort was directed in two areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries, and its relationship to cathode polarization. Included indirectly through the grain boundary effect is the effect of space charge. (2) Synthesis of LSC + SDC composite cathode powders by combustion synthesis. (3) Fabrication and testing of anode-supported single cells made using synthesized LSC + ScDC composite cathodes.

Anil V. Virkar

2003-11-03T23:59:59.000Z

57

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect

This project focused on addressing the two main problems associated with state of art Molten Carbonate Fuel Cells, namely loss of cathode active material and stainless steel current collector deterioration due to corrosion. We followed a dual approach where in the first case we developed novel materials to replace the cathode and current collector currently used in molten carbonate fuel cells. In the second case we improved the performance of conventional cathode and current collectors through surface modification. States of art NiO cathode in MCFC undergo dissolution in the cathode melt thereby limiting the lifetime of the cell. To prevent this we deposited cobalt using an electroless deposition process. We also coated perovskite (La{sub 0.8}Sr{sub 0.2}CoO{sub 3}) in NiO thorough a sol-gel process. The electrochemical oxidation behavior of Co and perovskites coated electrodes is similar to that of the bare NiO cathode. Co and perovskite coatings on the surface decrease the dissolution of Ni into the melt and thereby stabilize the cathode. Both, cobalt and provskites coated nickel oxide, show a higher polarization compared to that of nickel oxide, which could be due to the reduced surface area. Cobalt substituted lithium nickel oxide (LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) and lithium cobalt oxide were also studied. LiNi{sub x}Co{sub 1-x}O{sub 2} was synthesized by solid-state reaction procedure using lithium nitrate, nickel hydroxide and cobalt oxalate precursor. LiNi{sub x}Co{sub 1-x}O{sub 2} showed smaller dissolution of nickel than state of art nickel oxide cathode. The performance was comparable to that of nickel oxide. The corrosion of the current collector in the cathode side was also studied. The corrosion characteristics of both SS304 and SS304 coated with Co-Ni alloy were studied. This study confirms that surface modification of SS304 leads to the formation of complex scales with better barrier properties and better electronic conductivity at 650 C. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode and the complete fuel cell. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. This approach can be used to model porous electrodes as it represents the real system much better than the conventional agglomerate model. Using the homogeneous model the polarization characteristics of the MCFC cathode and fuel cell were studied under different operating conditions. Both the cathode and the full cell model give good fits to the experimental data.

Hector Colonmer; Prabhu Ganesan; Nalini Subramanian; Dr. Bala Haran; Dr. Ralph E. White; Dr. Branko N. Popov

2002-09-01T23:59:59.000Z

58

Carbon-Supported Pt?Co Catalysts Prepared by a Modified Polyol Process as Cathodes for PEM Fuel Cells  

Science Journals Connector (OSTI)

Among others, the conversion of chemical energy into electricity in proton exchange membrane fuel cells (PEMFC) requires the development of better electrocatalyst to improve the cell performance. ... However, to further reduce the voltage losses associated to the cathode performance, it is necessary to develop ORR electrocatalysts more active than platinum. ... In the so-called polyol process, developed by Fievet et al.,36 a diol or polyalcohol (ethylene glycol or diethylene glycol) is used as both solvent and reducing agent of metallic precursors. ...

Elisabete I. Santiago; Laudemir C. Varanda; H. Mercedes Villullas

2007-02-01T23:59:59.000Z

59

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the first quarter of the project. Effort was directed in three areas: (1) The determination of the role of ionic conductor morphology, used in composite cathodes, on the ionic conductivity of the ionic conductor. It was shown that if the particles are not well sintered, the necks formed between particles will be very narrow, and the resulting conductivity will be too low (resistivity will be too high). Specifically, a mathematical equation was derived to demonstrate the singular nature of conductivity. (2) Nanosize powders of Sc-doped CeO{sub 2} were prepared by combustion synthesis. The rationale is that the particle size of the composite electrode must be as small as possible to ensure a high ionic conductivity--and resulting in high performance in fuel cells. Di-gluconic acid (DGA) was used as fuel. The process led to the formation of nanosize Sc-doped CeO{sub 2}. The powder was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). (3) Samples were sintered to form materials containing various levels of porosity, from {approx}3% to {approx}43%. Conductivity was measured over a range of temperatures by four probe DC method. It was observed that in highly porous samples, the conductivity was far lower than can be expected purely based on total porosity. The difference could be rationalized on the basis of the theoretical model developed.

Professor Anil V. Virkar

2003-04-14T23:59:59.000Z

60

Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells  

SciTech Connect

A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

2011-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

62

Modeling the cathode compartment of polymer electrolyte fuel cells: Dead and active reaction zones  

SciTech Connect

A two-dimensional model of the cathode compartment of a polymer electrolyte fuel cell has been developed. The existence of gas channels in the current collector is taken into account. The model is based on continuity equations for concentrations of the gases and Poisson's equations for potentials of membrane and carbon phase, coupled by Tafel relation for reaction kinetics. Stefan-Maxwell and Knudsen diffusion of gases are taken into account. The simulations were performed for high and low values of carbon phase conductivity. The results revealed (i) for a low value of carbon phase conductivity, a dead zone in the active layer in front of the gas channel is formed, where the reaction rate is small. The catalyst may be removed from this zone without significant loss in cell performance; (ii) For a high carbon phase conductivity value, such a zone is absent, but removal of the catalyst from the same part of the active layer forces the reaction to proceed more rapidly in the remaining parts, with only marginal losses in performance. This conclusion is valid for high diffusivity of oxygen. For low diffusivity, dead zones are formed in front of the current collector, so that catalyst can be removed from these zones. The results, thus, show the possibilities for a considerable reduction of the amount of catalyst.

Kulikovsky, A.A.; Divisek, J.; Kornyshev, A.A.

1999-11-01T23:59:59.000Z

63

A model and simulation of cathode flooding and drying on unsteady proton exchange membrane fuel cell  

Science Journals Connector (OSTI)

A water balance has a significant impact on the overall system performance in proton exchange membrane fuel cell. An actual fuel cell application has a dynamic electrical load which means also dynamic electrical ...

A. Bakhtiar; Young-Bok Kim; Jin-Kwang You

2012-09-01T23:59:59.000Z

64

Extended reaction zone of La0.6Sr0.4Co0.2Fe0.8O3 cathode for solid oxide fuel cell  

SciTech Connect

The oxygen reduction reaction at the cathode of solid oxide fuel cell (SOFC) is a complicated process which involves the interaction of oxygen molecules, electrons, and oxygen ions. Therefore, it can only proceed at locations where gas, electronic conductor, and an oxygen ion conductor meet. Although the extension of the reaction zone beyond the traditional so-called triple-phase-boundary (TPB) is widely accepted for a mixed ionically and electronically conductive cathode, work in this area has yet to reach a consensus on how far the reaction zone can be extended. In this study, anode-supported fuel cells with a variety of LSCF cathode thicknesses were fabricated and tested in two cathode environments, flowing oxygen and flowing air. In flowing oxygen, the cell performance increased with LSCF cathode thickness over the entire range investigated (from 5 to 33 ?m). In flowing air, the cell performance also increased with the LSCF cathode thickness from 5 to 13 ?m, but then remained almost constant with further increase in cathode thickness. In flowing oxygen, since there was no concentration polarization related to oxygen diffusion, the polarization resistance of oxygen reduction decreased with the LSCF cathode thickness because of the increased number of reaction sites. A linear relationship was established between the reciprocal of the polarization resistance and the cathode thickness, which was explained by a model developed for aqueous gas diffusion electrodes.

Lu, Zigui; Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

2012-01-03T23:59:59.000Z

65

Ordered Hierarchical Nanostructured Carbon as a Highly Efficient Cathode Catalyst Support in Proton Exchange Membrane Fuel Cell  

Science Journals Connector (OSTI)

Ordered hierarchical nanostructured carbon (OHNC) has been fabricated through inverse replication of silica template and explored for the first time to support high loading of Pt nanoparticles as cathode catalyst in proton exchange membrane fuel cells (PEMFC). ... Ordered porous carbon materials with three-dimensionally interconnected pore structures and highly developed porosity have a variety of potential applications such as catalyst supports in low temperature fuel cells,(1, 2) electrode materials for electric double-layer capacitors(3, 4) and for lithium ion batteries,(5) adsorbents, and hydrogen storage materials. ... Carbon black Vulcan XC-72 (VC) is widely used as an electrocatalyst support in the PEMFCs due to its relatively large surface area and excellent chemical stability in the fuel cell environment. ...

Baizeng Fang; Jung Ho Kim; Minsik Kim; Jong-Sung Yu

2009-02-04T23:59:59.000Z

66

Aerosol Jet Printing of LSCF-CGO Cathode for Solid Oxide Fuel Cells.  

E-Print Network (OSTI)

??Solid oxide fuel cell (SOFC) technology has attracted great attention due to advantages such as low emissions and high efficiency. In this work, solid oxide (more)

Gardner, Paul

2011-01-01T23:59:59.000Z

67

Low platinum, high limiting current density of the PEMFC (proton exchange membrane fuel cell) based on multilayer cathode catalyst approach  

Science Journals Connector (OSTI)

Abstract Novel multilayer cathode electrodes structures for PEMFC (proton exchange membrane fuel cell) based on sputtering technique were developed to provide high performance with low loading Pt of 0.05mg/cm compared to the standard MEA (membrane electrode assembly) cathode (?0.20.3mg/cm). Different configurations of cathode catalyst layer were made by altering Pt and CN (CarbonNafion) ink carefully prepared on gas diffusion layer containing MPL (micro porous layer). The performances of PEMFC containing the multilayer electrodes were compared based on their measured polarization curves. Higher limiting current densities were achieved compared to standard MEA with platinum loading of 0.2mg/cm both at the cathode and the anode sides. Limiting current densities over 1.1A/cm2, 1.2A/cm2 and 1.4A/cm2 were reached whereas maximum powers were in the range of 500mW/cm at 600mW/cm. The good performances obtained can be due to the structural improvement which has contributed to a better catalyst utilization compared to conventional methods. A CN loading inferior to 0.24mg/cm between each layer is preferred for multilayer electrode.

Daouda Fofana; Sadesh Kumar Natarajan; Jean Hamelin; Pierre Benard

2014-01-01T23:59:59.000Z

68

Power Generation Capabilities of Microbial Fuel Cells with Different Oxygen Supplies in the Cathodic Chamber  

Science Journals Connector (OSTI)

Two microbial fuel cells (MFCs) inoculated with activated sludge ... whereas it was obtained by the photosynthesis of algae in the other. Electrogenic capabilities of both ... power output than the one with photo...

Der-Fong Juang; Chao-Hsien Lee; Shu-Chun Hsueh

2012-06-01T23:59:59.000Z

69

Oxygen Reduction Kinetics on Electrodeposited PtCo as a Model Catalyst for Proton Exchange Membrane Fuel Cell Cathodes: Stability as a Function of PtCo Composition  

Science Journals Connector (OSTI)

Oxygen Reduction Kinetics on Electrodeposited PtCo as a Model Catalyst for Proton Exchange Membrane Fuel Cell Cathodes: Stability as a Function of PtCo Composition ... When the focus is at reducing cost and improving durability, the PEMFC cathode deserves special attention. ... (4-7) Mukerjee et al. investigated various Pt bimetallic alloys supported on carbon and found a 2?3-fold increase in the oxygen reduction reaction (ORR) activity for the alloy catalysts under PEMFC operating conditions. ...

Kaushik Jayasayee; Van Anh T. Dam; Tiny Verhoeven; Serdar Celebi; Frank A. de Bruijn

2009-11-02T23:59:59.000Z

70

Fuel cell with internal flow control  

SciTech Connect

A fuel cell stack is provided with a plurality of fuel cell cassettes where each fuel cell cassette has a fuel cell with an anode and cathode. The fuel cell stack includes an anode supply chimney for supplying fuel to the anode of each fuel cell cassette, an anode return chimney for removing anode exhaust from the anode of each fuel cell cassette, a cathode supply chimney for supplying oxidant to the cathode of each fuel cell cassette, and a cathode return chimney for removing cathode exhaust from the cathode of each fuel cell cassette. A first fuel cell cassette includes a flow control member disposed between the anode supply chimney and the anode return chimney or between the cathode supply chimney and the cathode return chimney such that the flow control member provides a flow restriction different from at least one other fuel cell cassettes.

Haltiner, Jr., Karl J. (Fairport, NY); Venkiteswaran, Arun (Karnataka, IN)

2012-06-12T23:59:59.000Z

71

Carbonized Hemoglobin Functioning as a Cathode Catalyst for Polymer Electrolyte Fuel Cells  

Science Journals Connector (OSTI)

development, i.e., (a) transition from poly(styrenesulfonic acid) to Nafion-type membranes; (b) a 10- to 100-fold redn. in the platinum loading in electrode by using nanosize electrocatalyst particles supported on high surface area carbon and impregnation of the proton conducting electrolyte into the active layer of the electrode; (c) optimization of structure of electrode and of membrane and electrode assembly to enhance power densities to 0.5-0.7 W/cm2 at desirable efficiencies; and (d) using Nafion-type membranes for direct methanol fuel cells instead of liq. ... Preparative procedures were optimized to enhance the performance of these nanocomposites as anode electrocatalysts in direct methanol fuel cells. ... To improve the performance of proton-exchange membrane fuel cells (PEMFCs), it is necessary to optimize the structure of the interface between polymer electrolyte and catalyst particles in the electrodes of PEMFCs. ...

Jun Maruyama; Ikuo Abe

2006-02-09T23:59:59.000Z

72

Development of Ultra-Low Platinum Alloy Cathode Catalyst for PEM Fuel Cells - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Branko N. Popov University of South Carolina (USC) 301 Main Street Columbia, SC 29208 Phone: (803) 777-7314 Email: popov@cec.sc.edu DOE Managers HQ: Donna Lee Ho Phone: (202) 586-8000 Email: Donna.Ho@ee.doe.gov GO: David Peterson Phone: (720) 356-1747 Email: David.Peterson@go.doe.gov Technical Advisor Thomas Benjamin Phone: (630) 252-1632 Email: benjamin@anl.gov Contract Number: DE-EE0000460 Subcontractor: Dr. Hansung Kim (Co-PI) Yonsei University, S. Korea. Project Start Date: September 1, 2010 Project End Date: May 31, 2014 Objectives Develop low-cost and durable hybrid cathode catalyst * (HCC). Develop Pt alloy/activated graphitic carbon catalyst. * Develop corrosion resistant supports. *

73

Exploratory fuel-cell research: I. Direct-hydrocarbon polymer-electrolyte fuel cell. II. Mathematical modeling of fuel-cell cathodes  

SciTech Connect

A strong need exists today for more efficient energy-conversion systems. Our reliance on limited fuel resources, such as petroleum for the majority of our energy needs makes it imperative that we utilize these resources as efficiently as possible. Higher-efficiency energy conversion also means less pollution, since less fuel is consumed and less exhaust created for the same energy output. Additionally, for many industrialized nations, such as the United States which must rely on petroleum imports, it is also imperative from a national-security standpoint to reduce the consumption of these precious resources. A substantial reduction of U.S. oil imports would result in a significant reduction of our trade deficit, as well as costly military spending to protect overseas petroleum resources. Therefore, energy-conversion devices which may utilize alternative fuels are also in strong demand. This paper describes research on fuel cells for transportation.

Perry, M.L.; McLarnon, F.R.; Newman, J.S.; Cairns, E.J.

1996-12-01T23:59:59.000Z

74

Mechanical and electrochemical performance of composite cathode contact materials for solid oxide fuel cells  

SciTech Connect

The feasibility of adding glass or inorganic binder to conventional SOFC cathode contact materials (CCM) in order to improve bonding to adjacent materials in the cell stack is assessed. Two glasses (SEM-COM SCZ-8 and Schott GM31107) and one inorganic binder (Aremco 644A) are mixed with LSM particles to produce composite CCM pastes. These are used to bond Mn1.5Co1.5O4-coated stainless steel mesh current collectors to anode-supported button cells. The cells are operated at 800 C for about 1000 h. The cell with SCZ-8 addition to the CCM displays quite stable operation (3.9%/1000 h degradation), whereas the other additives lead to somewhat higher degradation rate. Bonding of the CCM to coated stainless steel coupons is also assessed. Interfacial fracture toughness is determined using a four-point bend test. The fracture toughness for LSM Schott glass (12.3 N mm 1), LSM SCZ-8 glass (6.8 N mm 1) and LSM 644A binder (5.4 N mm 1) are significantly improved relative to pure LSM (1.7 N mm 1). Indeed, addition of binder or glass is found to improve bonding of the CCM layer without sacrificing cell performance.

Tucker, Michael C. [Lawrence Berkeley National Laboratory (LBNL); Dejonghe, Lutgard C. [Lawrence Berkeley National Laboratory (LBNL); Garcia-Negron, Valerie [Material Science and Technology Division, Oak Ridge National Laboratory; Trejo, Rosa M [ORNL; Lara-Curzio, Edgar [ORNL

2013-01-01T23:59:59.000Z

75

Study of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2  

E-Print Network (OSTI)

to oxygen dissociation and diffusion process.26 KEYWORDS: Solid oxide fuel cell; Silver infiltrationStudy of oxygen reduction mechanism on Ag modified1 Sm1.8Ce0.2CuO4 cathode for solid oxide fuel cell2 3 4 Li-Ping Sun1 -- Hui Zhao1 -- Qiang Li1 -- Li-Hua Huo1 -- Jean-Paul Viricelle*2 --5 Christophe

Paris-Sud XI, Université de

76

Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes  

SciTech Connect

Platinum monolayers can act as shells for palladium nanoparticles to lead to electrocatalysts with high activities and an ultralow platinum content, but high platinum utilization. The stability derives from the core protecting the shell from dissolution. In fuel-cell tests, no loss of platinum was observed in 200,000 potential cycles, whereas loss of palladium was significant.

K Sasaki; H Naohara; Y Cai; Y Choi; P Liu; M Vukmirovic; J Wang; R Adzic

2011-12-31T23:59:59.000Z

77

Low Loading Pt Cathode Catalysts for Direct Methanol Fuel Cell Derived from the Particle Size Effect  

Science Journals Connector (OSTI)

Recent results have shown that with sputtered Pt cathode catalysts, the metal loading in PEMFC can be reduced to cathode metal loading in PEMFC, less attention has been paid to DMFC. ... The long-term performance of catalyst Pt14-050 in DMFC was examined to explore the stability of the small-sized Pt catalysts. ...

Fei Wen; Ulrich Simon

2007-06-16T23:59:59.000Z

78

Prediction of O2 Dissociation Kinetics on LaMnO3-Based Cathode Materials for Solid Oxide Fuel Cells  

SciTech Connect

First-principles and statistical-theory calculations were applied to examine the interactions between oxygen molecules and the (100) surfaces of LaMnO3 and La0.5Sr0.5MnO2.75, one of the most-used cathode materials in solid oxide fuel cells (SOFCs). To predict the rate constants for the interactions between O2 and LaMnO3 or La0.5Sr0.5MnO2.75, potential energy profiles were constructed using the nudged elastic band (NEB) method. Predicted rate constants for the dissociation of adsorbed oxygen species on LaMnO3 (lm) and La0.5Sr0.5MnO2.75 (lsm) can be expressed as kdiss,lm ) 2.35 1012 exp(-0.50 eV/RT) s-1 and kdiss,lsm ) 2.15 1012 exp(-0.23 eV/RT) s-1, respectively, in the temperature range of 873-1273 K at 1 atm. Because the activation energy for oxygen dissociation on La0.5Sr0.5MnO2.75 (0.23 eV) is much smaller than that on LaMnO3 (0.50 eV), oxygen vacancies greatly enhance O2 dissociation kinetics. The kinetic and mechanistic studies for the interactions at the molecular level are imperative to gaining a fundamental understanding of oxygen reduction kinetics on cathode materials and to providing important insight into the rational design of more catalytically active cathode materials for SOFCs.

Choi, Yongman; Lynch, Matthew E.; Lin, M. C.; Liu, Meilin

2009-04-30T23:59:59.000Z

79

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the sixth quarter of the project. Effort was directed in three areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge region. (2) Calculation of the effect of space charge and morphology of porous bodies on the effective charge transfer resistance of porous composite cathodes. (3) The investigation of the three electrode system for the measurement of cathodic polarization using amperometric sensors.

Anil V. Virkar

2004-05-17T23:59:59.000Z

80

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells: III. Role of volatile boron species on LSM/YSZ and LSCF  

SciTech Connect

Boron oxide is a key component to tailor the softening temperature and viscosity of the sealing glass for solid oxide fuel cells. The primary concern regarding the use of boron containing sealing glasses is the volatility of boron species, which possibly results in cathode degradation. In this paper, we report the role of volatile boron species on the electrochemical performance of LSM/YSZ and LSCF cathodes at various SOFC operation temperatures. The transport rate of boron, ~ 3.2410-12 g/cm2sec was measured at 750C with air saturated with 2.8% moisture. A reduction in power density was observed in cells with LSM/YSZ cathodes after introduction of the boron source to the cathode air stream. Partial recovery of the power density was observed after the boron source was removed. Results from post-test secondary ion mass spectroscopy (SIMS) analysis the partial recovery in power density correlated with partil removal of the deposited boron by the clean air stream. The presence of boron was also observed in LSCF cathodes by SIMS analysis, however the effect of boron on the electrochemical performance of LSCF cathode was negligible. Coverage of triple phase boundaries in LSM/YSZ was postulated as the cause for the observed reduction in electrochemical performance.

Zhou, Xiao Dong; Templeton, Jared W.; Zhu, Zihua; Chou, Y. S.; Maupin, Gary D.; Lu, Zigui; Brow, R. K.; Stevenson, Jeffry W.

2010-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Effect of current density on poisoning rate of Co-containing fuel cell cathodes by chromium  

Science Journals Connector (OSTI)

Variation of electrochemical performance of a La0.58Sr0.4Co0.2Fe0.8O3 (LSCF) cathode due to chromium gas-phase deposition has been studied at 800C. The highest degradation rate is observed under open circuit con...

E. Yu. Konysheva

2014-07-01T23:59:59.000Z

82

A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications  

Science Journals Connector (OSTI)

Furthermore, at a commercially relevant potential, the measured mass activity of an unoptimized Cu-tri/C-based cathode was significantly greater than that of similar Pt/C- and Ag/C-based cathodes. ... Figure 2 compares the cathode performance of the Cu-tri/C catalyst with known ORR catalysts, Pt/C and Ag/C, in a microfluidic H2/O2 fuel cell with a flowing electrolyte of 1 M KOH (pH ?14). ... Presently, directly comparing the Cu-tri/C performance to that of other Pt-free catalysts is difficult as these studies are performed either in an electrochemical cell(6, 11, 16) or embedded in a GDE within an operating acidic PEMFC. ...

Fikile R. Brushett; Matthew S. Thorum; Nicholas S. Lioutas; Matthew S. Naughton; Claire Tornow; Huei-Ru Molly Jhong; Andrew A. Gewirth; Paul J. A. Kenis

2010-08-17T23:59:59.000Z

83

How Fuel Cells Work  

NLE Websites -- All DOE Office Websites (Extended Search)

How Fuel Cells Work How Fuel Cells Work Diagram: How a PEM fuel cell works. 1. Hydrogen fuel is channeled through field flow plates to the anode on one side of the fuel cell, while oxygen from the air is channeled to the cathode on the other side of the cell. 2. At the anode, a platinum catalyst causes the hydrogen to split into positive hydrogen ions (protons) and negatively charged electrons. 3. The Polymer Electrolyte Membrane (PEM) allows only the positively charged ions to pass through it to the cathode. The negatively charged electrons must travel along an external circuit to the cathode, creating an electrical current. 4. At the cathode, the electrons and positively charged hydrogen ions combine with oxygen to form water, which flows out of the cell.

84

Development of ternary alloy cathode catalysts for phosphoric acid fuel cells: Final report  

SciTech Connect

The overall objective of the program was the identification development and incorporation of high activity platinum ternary alloys on corrosion resistant supports, for use in advanced phosphoric acid fuel cells. Two high activity ternary alloys, Pr-Cr-Ce and Pt-Ni-Co, both supported on Vulcan XC-72, were identified during the course of the program. The Pr-Ni-Co system was selected for optimization, including preparation and evaluation on corrosion resistant supports such as 2700/degree/C heat-treated Vulcan XC-72 and 2700/degree/ heat-treated Black Pearls 2000. A series of tests identified optimum metal ratios, heat-treatment temperatures and heat-treatment atmospheres for the Pr-Ni-Co system. During characterization testing, it was discovered that approximately 50% of the nickel and cobalt present in the starting material could be removed, subsequent to alloy formation, without degrading performance. Extremely stable full cell performance was observed for the Pt-Ni-Co system during a 10,000 hour atmosphere pressure life test. Several theories are proposed to explain the enhancement in activity due to alloy formation. Recommendations are made for future research in this area. 62 refs., 23 figs., 27 tabs.

Not Available

1988-11-01T23:59:59.000Z

85

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the second quarter of the project. Effort is directed in two areas: (1) The use of a novel method to achieve a given porosity level with high contiguity and thus conductivity. (2) Relate the measured conductivity to porosity and contiguity. The rationale for these experiments was to develop cathodes with high ionic conductivity, so that the effective polarization resistance will be concomitantly lowered.

Anil V. Virkar

2003-10-11T23:59:59.000Z

86

PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL  

SciTech Connect

State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratorys Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

Phelan, B.T.; Myers, D.J.; Smith, M.C.

2009-01-01T23:59:59.000Z

87

The Orientation Distributions of Lines, Surfaces, and Interfaces Around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes  

SciTech Connect

Three-dimensional electron backscatter diffraction was used to measure the crystallographic distribution of the electrochemically relevant triple phase boundary lines and surfaces near them in SOFC cathodes made up of a porous mixture of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild electrochemical loading. All distributions were observed to be nearly isotropic, but non-random textures above the detection threshold were observed. The distributions differ between the two cells, as do the phase fractions and the electrochemical history. The different distributions are interpreted as evidence that steady-state distributions vary locally with phase fractions or that they evolve during the initial operation of the fuel cell. The rates at which triple lines, pore surfaces, and interface boundaries in the porous mixture approach a steady-state value appear to decrease with the average amount of mass transport required to reorient that specific feature. This work provides initial insights into the crystallography of interfaces in a multiphase ceramic material.

Dillon, Shen; Helmick, Lam; Miller, Herbert M.; Johnson, Christopher; Wilson, Lane; Gemmen, Randall; Petrova, Rumyana; Barmak, Katayun; Gerdes, Kirk; Rohrer, Gregory S.; Salvador, Paul A.

2011-11-01T23:59:59.000Z

88

Single crystalline La0.5Sr0.5MnO3 microcubes as cathode of solid oxide fuel cell  

SciTech Connect

The efficiency of solid oxide fuel cells (SOFCs) is heavily dependent on the electrocatalytic activity of the cathode toward the oxygen reduction reaction (ORR). In order to achieve better cathode performance, single crystalline La0.5Sr0.5MnO3 (LSM) microcubes with the {200} facets have been synthesized by the hydrothermal method. It is found that the LSM microcubes exhibit lower polarization resistance than the conventional polycrystalline La0.8Sr0.2MnO3 powder in air from 700 #2;C to 900 #2;C. The ORR activation energy of the LSM microcubes is lower than that of the conventional powder. The ORR kinetics for the microcubes is limited by the charge transfer step while that for the conventional powder is dominated by the oxygen adsorption and dissociation on the cathode surface.

Mingjia Zhi; Guangwen Zhou; Zhanglian Hong; Jin Wang; Randall Gemmen; Kirk Gerdes; Ayyakkannu Manivannan; Dongling Mae; Nianqiang Wu

2010-09-13T23:59:59.000Z

89

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the fourth quarter of the project. Effort was directed in two areas, namely, continued further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge, and its relationship to cathode polarization; and fabrication of samaria-doped ceria porous (SDC). The work on the model development involves calculation of the effect of space charge on transport through porous bodies. Three specific cases have been examined: (1) Space charge resistivity greater than the grain resistivity, (2) Space charge resistivity equal to the grain resistivity, and (3) Space charge resistivity lower than the grain resistivity. The model accounts for transport through three regions: the bulk of the grain, the space charge region, and the structural part of the grain boundary. The effect of neck size has been explicitly incorporated. In future work, the effective resistivity will be incorporated into the effective cathode polarization resistance. The results will then be compared with experiments.

Anil V. Virkar

2003-12-12T23:59:59.000Z

90

On the hydrophobicity and hydrophilicity of the cathode gas diffusion layer in a polymer electrolyte fuel cell  

Science Journals Connector (OSTI)

...diffusion layer in a polymer electrolyte fuel cell M. Vynnycky A. Gordon e-mail...layer (GDL) of a polymer electrolyte fuel cell is investigated asymptotically and...experimentally the case. polymer electrolyte fuel cell|gas diffusion layer|hydrophobicity...

2013-01-01T23:59:59.000Z

91

Surface Wettability Impact on Water Management in PEM Fuel Cell.  

E-Print Network (OSTI)

??Excessive water formation inside the polymer electrolyte membrane (PEM) fuel cells structures leads to the flooding of the cathode gas diffusion layer (GDL) and cathode (more)

Al Shakhshir, Saher

2012-01-01T23:59:59.000Z

92

Five percent platinum-tungsten oxide-based electrocatalysts for phosphoric acid fuel cell cathodes  

SciTech Connect

A Pt-tungsten oxide-based electrocatalyst has been fabricated by an inexpensive chemical route for use as an oxygen cathode in 99% phosphoric acid at 180 C. The effect of %WO{sub 3} (wt/wt) on the Pt-tungsten oxide/C-based electrode performance was studied. The electrocatalytic properties for the oxygen reduction reaction (ORR), e.g., exchange current density and mass activity of a 5% Pt-40% WO{sub 3}-based electrode were found to be twice as high as those of 10% Pt, which contains double the amount of platinum. The Tafel slope and specific activity of the two electrodes are similar. It was shown that an increase in its electrochemically active surface area was the only reason for the performance of the 5% Pt-40% WO{sub 3}-based electrode. The electrocatalytic parameters of the 5% Pt-40% WO{sub 3}-based electrode for the ORR were compared to those of the 2% Pt-1% H{sub 2}WO{sub 4}-based electrode.

Savadogo, O.; Beck, P. [Ecole Polytechnique, Montreal, Quebec (Canada). Lab. d`Electrochimie et de Materiaux Energetiques

1996-12-01T23:59:59.000Z

93

Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes for air-cathode microbial fuel cells{  

E-Print Network (OSTI)

Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes materials in order to optimize and extend the lifetime of AC cathodes in MFCs. 1. Introduction A microbial, with the cathode typically limiting power production.5,6 Catalysts can be used to reduce the activation energy

94

Hard X-ray Fluorescence Measurements of Heteroepitaxial Solid Oxide Fuel Cell Cathode Materials  

SciTech Connect

Commonly, SOFCs are operated at high temperatures (above 800C). At these temperatures expensive housing is needed to contain an operating stack as well as coatings to contain the oxidation of the metallic interconnects. Lowering the temperature of an operating device would allow for more conventional materials to be used, thus lowering overall cost. Understanding the surface chemical states of cations in the surface of the SOFC cathode is vital to designing a system that will perform well at lower temperatures. The samples studied were grown by pulsed laser deposition (PLD) at the Environmental Molecular Sciences Laboratory (EMSL) at Pacific Northwest National Laboratory (PNNL). 20% strontium doped lanthanum manganite (LSM-20) was grown on YSZ and NGO (neodymium gallate). The films on YSZ have a fiber texture. LSM-20 on NGO is heteroepitaxial. Lanthanum strontium cobalt ferrite (LSCF-6428) films were grown on LAO and YSZ with a GDC barrier layer. Total X-ray Reflection Fluorescence (TXRF) was used to depth profile the samples. In a typical experiment, the angle of the incident beam is varied though the critical angle. Below the critical angle, the x-ray decays as an evanescent wave and will only penetrate the top few nanometers. TXRF experiments done on LSM films have suggested strontium segregates to the surface and form strontium enriched nanoparticles (1). It should be pointed out that past studies have focused on 30% strontium A-site doping, but this project uses 20% strontium doped lanthanum manganite. XANES and EXAFS data were taken as a function of incoming angle to probe composition as a function of depth. XANES spectra can be difficult to analyze fully. For other materials density functional theory calculations compared to near edge measurements have been a good way to understand the 3d valence electrons (2).

Davis, Jacob N.; Miara, Lincoln J.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Gopalan, Srikanth; Pal, Uday B.; Woicik, Joseph C.; Basu, Soumendra N.; Ludwig, Karl F.

2012-12-01T23:59:59.000Z

95

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect

This report summarizes the work done during the fifth quarter of the project. Effort was directed in two areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge region. (2) Fabrication of porous samaria-doped ceria (SDC) and investigation of the effect of thermal treatment on its conductivity. The model developed accounts for transport through three regions: (a) Transport through the bulk of the grain, RI, which includes parallel transport through space charge region. (b) Transport through the space charge region adjacent to the neck (grain boundary), RII. (c) Transport through the structural part of the neck (grain boundary), RIII. The work on the model development involves calculation RI, RII, RIII, and the sum of these three terms, which is the total resistance, as a function of the grain radius ranging between 0.5 and 5 microns and as a function of the relative neck size, described in terms of the angle theta, ranging between 5 and 45{sup o}. Three values of resistivity of the space charge region were chosen; space charge resistivity greater than grain resistivity, equal to grain resistivity, and lower than grain resistivity. Experimental work was conducted on samaria (Sm{sub 2}O{sub 3})-doped ceria (SDC) samples of differing porosity levels, before and after thermal treatment at 1200 C. The conductivity in the annealed samples was lower, consistent with enhanced Debye length. This shows the important role of space charge on ionic transport, and its implications concerning cathode polarization.

Anil V. Virkar

2004-03-08T23:59:59.000Z

96

Optimization of the Cathode Catalyst Layer Composition of a PEM Fuel Cell Using a Novel 2-Step Preparation Method.  

E-Print Network (OSTI)

??For good performance and high durability PEM fuel cells run at high water saturation levels. However, excess liquid water generated by the oxygen reduction reaction (more)

Friedmann, Roland

2009-01-01T23:59:59.000Z

97

Grain-size effects in nanoscaled electrolyte and cathode thin films for solid oxide fuel cells (SOFC).  

E-Print Network (OSTI)

??Due to their high energy conversion efficiencies and low emissions, Solid Oxide Fuel Cells (SOFCs) show promise as a replacement for combustion-based electrical generators at (more)

Peters, Christoph

2009-01-01T23:59:59.000Z

98

REACTIVE FORCE FIELDS FOR Y-DOPED BaZrO3 ELECTROLYTE AND NI-ANODE. POTENTIAL CATHODE MATERIALS FOR APPLICATION IN PROTON CERAMIC FUEL CELLS  

SciTech Connect

Based on quantum mechanical data obtained for the Y-doped BaZrO{sub 3} electrolyte and Ni-anode Reactive Force Field parameters have been developed for further molecular dynamics simulations of the proton diffusion and electrode/electrolyte interfaces. Electronic and atomic structures of different terminations of the (001) BaZrO{sub 3} surface have been studied using first-principles calculations. Several potential cathode materials for the Y-doped BaZrO{sub 3} system were synthesized via glycine nitrate combustion method. Of the five potential cathode materials examined BaZr{sub 0.40}Pr{sub 0.40}Gd{sub 0.20}O{sub 3} and BaZr{sub 0.60}Y{sub 0.20}Co{sub 0.20}O{sub 3} appear to be the most promising for further applications in proton ceramic fuel cells. Fuel cell test of a Y-doped BaZrO{sub 3} thin film using platinum ink for both electrodes have been performed. The obtained results shows that a robust method for fabricating crack-free thin membranes, as well as methods for sealing anode and cathode chambers, have successfully been developed.

Boris Merinov; Adri van Duin; Sossina Haile; William A. Goddard III

2004-10-30T23:59:59.000Z

99

Interaction between (La, Sr)MnO3 cathode and NiMoCr metallic interconnect with suppressed chromium vaporization for solid oxide fuel cells  

Science Journals Connector (OSTI)

Interaction between (La0.8Sr0.2)0.90MnO3 (LSM) cathode and newly developed NiMoCr metallic interconnect is investigated at 900C under operation conditions of solid oxide fuel cells (SOFCs). The results show that chromium deposition on the LSM cathodes in the presence of NiMoCr interconnect is remarkably reduced as compared to that in the presence of a conventional FeCr metallic interconnect (RA446). In contact with the NiMo-Cr interconnect the overpotential, ?, for the O2 reduction reaction on LSM cathode decreased from 529 to 111mV during the 1200min current passage at 200mA/cm2. In contrast, ? increased from 464 to 561mV for the reaction in the presence of a RA446 interconnect. The decrease in ? clearly indicates that chromium poisoning effect of the NiMoCr interconnect is also significantly suppressed as compared to that with conventional FeCr interconnect materials. The suppressed Cr deposition and poisoning effects observed on the LSM cathodes demonstrate promising potential of the NiMoCr alloy as new interconnect materials with significant suppressed chromium vaporization and deposition for SOFCs.

Xinbing Chen; Bin Hua; Jian Pu; Jian Li; Lan Zhang; San Ping Jiang

2009-01-01T23:59:59.000Z

100

High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells  

SciTech Connect

InBaCo4-xZnxO7 oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo4-xZnxO7 has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 oC and 700 oC for 100 h, and chemical stability against a Gd0.2Ce0.8O1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo4-xZnxO7 (x = 1, 1.5, 2) specimens were determined to be 8.6 10-6 9.6 10-6 /oC in the range of 80 900 oC, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo4-xZnxO7 + GDC (50:50 wt. %) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo4-xZnxO7 cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.

Kim, Jung-Hyun [ORNL; Young Nam, Kim [University of Texas, Austin; Bi, Zhonghe [ORNL; Manthiram, Arumugam [University of Texas, Austin; Paranthaman, Mariappan Parans [ORNL; Huq, Ashfia [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network (OSTI)

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and V. I. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C.Nanostructured Solid Oxide Fuel Cell Electrodes By Tal Zvi

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

102

Enhanced reductive degradation of methyl orange in a microbial fuel cell through cathode modification with redox mediators  

Science Journals Connector (OSTI)

A model azo dye, methyl orange (MO), was reduced through in situ utilization of the electrons derived from the anaerobic conversion of organics in a microbial fuel cell (MFC). The MO reduction process could be...

Rong-Hua Liu; Guo-Ping Sheng; Min Sun

2011-01-01T23:59:59.000Z

103

Corrosion free phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell with an electrolyte fuel system which supplies electrolyte via a wick disposed adjacent a cathode to an absorbent matrix which transports the electrolyte to portions of the cathode and an anode which overlaps the cathode on all sides to prevent corrosion within the cell.

Wright, Maynard K. (Bethel Park, PA)

1990-01-01T23:59:59.000Z

104

Fuel cell gas management system  

DOE Patents (OSTI)

A fuel cell gas management system including a cathode humidification system for transferring latent and sensible heat from an exhaust stream to the cathode inlet stream of the fuel cell; an anode humidity retention system for maintaining the total enthalpy of the anode stream exiting the fuel cell equal to the total enthalpy of the anode inlet stream; and a cooling water management system having segregated deionized water and cooling water loops interconnected by means of a brazed plate heat exchanger.

DuBose, Ronald Arthur (Marietta, GA)

2000-01-11T23:59:59.000Z

105

(Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells  

SciTech Connect

(Y0.5In0.5)BaCo4-xZnxO7 (1.0 x 2.0) oxides crystallizing in a trigonal P31c structure have been synthesized and explored as cathode materials for solid oxide fuel cells (SOFC). At a given Zn content, the (Y0.5In0.5)BaCo4-xZnxO7 sample with 50 % Y and 50 % In exhibits much improved phase stability at intermediate temperatures (600 - 800 oC) compared to the samples with 100 % Y or In. However, the substitution of Zn for Co in (Y0.5In0.5)Ba(Co4-xZnx)O7 (1.0 x 2.0) decreases the amount of oxygen loss on heating, total electrical conductivity, and cathode performance in SOFC while providing good long-term phase stability at high temperatures. Among the various chemical compositions investigated in the (Y0.5In0.5)Ba(Co4-xZnx)O7 system, the (Y0.5In0.5)BaCo3ZnO7 sample offers a combination of good electrochemical performance and low thermal expansion coefficient (TEC) while maintaining superior phase stability at 600 800 oC for 100 h. Fuel cell performances of the (Y0.5In0.5)Ba(Co3Zn)O7 + Ce0.8Gd0.2O1.9 (GDC) (50 : 50 wt. %) composite cathodes collected with anode-supported single cell reveal a maximum power density value of 521 mW cm-2 at 700 oC.

Young Nam, Kim [University of Texas, Austin; Kim, Jung-Hyun [ORNL; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas, Austin; Huq, Ashfia [ORNL

2012-01-01T23:59:59.000Z

106

Deactivation and Regeneration of Oxygen Reduction Reactivity on Double Perovskite Ba2Bi0.1Sc0.2Co1.7O6?x Cathode for Intermediate-Temperature Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Deactivation and Regeneration of Oxygen Reduction Reactivity on Double Perovskite Ba2Bi0.1Sc0.2Co1.7O6?x Cathode for Intermediate-Temperature Solid Oxide Fuel Cells ... Most notably, cathodic polarization treatment, for example, current discharge from BBSC, can be utilized to recover the original ORR performance. ... After evaporation of water at 120 C, a dark purple gel was recovered. ...

Wei Zhou; Jaka Sunarso; Julius Motuzas; Fengli Liang; Zhigang Chen; Lei Ge; Shaomin Liu; Anne Julbe; Zhonghua Zhu

2011-02-28T23:59:59.000Z

107

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two.

Gay, Eddie C. (Park Forest, IL); Miller, William E. (Naperville, IL); Laidler, James J. (Burr Ridge, IL)

1997-01-01T23:59:59.000Z

108

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two. 12 figs.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1997-07-22T23:59:59.000Z

109

Cathode Connector For Aluminum Low Temperature Smelting Cell  

DOE Patents (OSTI)

Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2003-07-16T23:59:59.000Z

110

Evaluation of sterling silver as a contacting material for the cathode chamber of the solid-oxide fuel cell.  

E-Print Network (OSTI)

??This research focuses on the development and testing of contact paste materials for the SOFC, utilizing silver, in a simulated cathode environment. Test specimens were (more)

Sakacsi, John.

2006-01-01T23:59:59.000Z

111

Fuel Cell 101  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell 101 Fuel Cell 101 Don Hoffman Don Hoffman Ship Systems & Engineering Research Division March 2011 Distribution Statement A: Approved for public release; distribution is unlimited. Fuel Cell Operation * A Fuel Cell is an electrochemical power source * It supplies electricity by combining hydrogen and oxygen electrochemically without combustion. * It is configured like a battery with anode and cathode. * Unlike a battery, it does not run down or require recharging and will produce electricity and will produce electricity, heat and water as long as fuel is supplied. 2H + + 2e - O 2 + 2H + + 2e - 2H 2 O H 2 Distribution Statement A: Approved for public release; distribution is unlimited. 2 FUEL FUEL CONTROLS Fuel Cell System HEAT & WATER CLEAN CLEAN EXHAUST EXHAUST

112

High Specific Power, Direct Methanol Fuel Cell Stack  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt...

113

Chelating agent assisted heat treatment of carbon supported cobalt oxide nanoparticle for use as cathode catalyst of polymer electrolyte membrane fuel cell (PEMFC)  

Science Journals Connector (OSTI)

Cobalt-based catalysts for the oxygen reduction reaction (ORR) in polymer electrolyte membrane fuel cell (PEMFC) have been successfully incorporated cobalt oxide (Co3O4) onto Vulcan XC-72 carbon powder by thermal decomposition of Coethylenediamine complex (ethylenediamine, NH2CH2CH2NH2, denoted en) at 850C. The catalysts were prepared by adsorbing the cobalt complexes [Co(en)(H2O)4]3+, [Co(en)2(H2O)2]3+ and [Co(en)3]3+ on commercial XC-72 carbon black supports, loading amount of Co with respect to carbon black was about 2%, the resulting materials have been pyrolyzed under nitrogen atmosphere to create CoOx/C catalysts, donated as E1, E2, and E3, respectively. The composite materials were characterized using X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS). Chemical compositions of prepared catalysts were determined using inductively-coupled plasma-atomic emission spectroscopy (ICP-AES). The catalytic activities for ORR have been analyzed by cyclic voltammetry (CV) and linear sweep voltammetry (LSV). The electrocatalytic activity for oxygen reduction of E2 is superior to that of E1 and E3. Membrane electrode assemblies (MEAs) containing the synthesized CoOx/C cathode catalysts were fabricated and evaluated by single cell tests. The E2 cathode performed better than that of E1 and E3 cathode. This can be attributed to the enhanced activity for ORR, in agreement with the composition of the catalyst that CoO co-existed with Co3O4. The maximum power density 73mWcm?2 was obtained at 0.3V with a current density of 240mAcm?2 for E2 and the normalized power density of E2 is larger than that that of commercial 20wt.% Pt/C-ETEK.

Chia-Hung Huang; Shyh-Jiun Liu; Weng-Sing Hwang

2011-01-01T23:59:59.000Z

114

Compact fuel cell  

DOE Patents (OSTI)

A novel electrochemical cell which may be a solid oxide fuel cell (SOFC) is disclosed where the cathodes (144, 140) may be exposed to the air and open to the ambient atmosphere without further housing. Current collector (145) extends through a first cathode on one side of a unit and over the unit through the cathode on the other side of the unit and is in electrical contact via lead (146) with housing unit (122 and 124). Electrical insulator (170) prevents electrical contact between two units. Fuel inlet manifold (134) allows fuel to communicate with internal space (138) between the anodes (154 and 156). Electrically insulating members (164 and 166) prevent the current collector from being in electrical contact with the anode.

Jacobson, Craig (Moraga, CA); DeJonghe, Lutgard C. (Lafayette, CA); Lu, Chun (Richland, WA)

2010-10-19T23:59:59.000Z

115

Dynamic characteristics of spherical agglomerate for study of cathode catalyst layers in proton exchange membrane fuel cells (PEMFC)  

Science Journals Connector (OSTI)

There has been growing interest in the modeling of proton exchange membrane fuel cells (PEMFC) over the last two decades. While a variety of steady-state models have been proposed, literature is scarce in PEMFC dynamic models and transient studies. Typical dynamic models for PEM fuel cell are empirical currentvoltage relationships. The internal transients associated with reactant and product species and other components are usually neglected. A detailed dynamic model for spherical agglomerate in PEM fuel cell is presented in this work. The dynamic model includes detailed mathematical equations for conservation of oxygen and hydrogen ions inside the agglomerate. The agglomerate dynamic model is simulated for typical operating conditions inside the PEMFC catalyst layer. Simulation studies show that the time scales in which the dynamics of agglomerate potential and concentration of dissolved oxygen respond differ by several orders of magnitude. Transient response of agglomerate current to step changes in surface boundary conditions are also presented. Reasons for the typical characteristics observed in the dynamic behavior of agglomerate current are also highlighted.

R. Madhusudana Rao; R. Rengaswamy

2006-01-01T23:59:59.000Z

116

Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes  

E-Print Network (OSTI)

Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated Pt[subscript 3]Co catalyst particles in a H[subscript ...

Chen, Shuo

117

Microstructured Hydrogen Fuel Cells  

Science Journals Connector (OSTI)

Micro fuel cells ; Polymer electrolyte membrane fuel cells ; Proton exchange membrane fuel cells ...

Luc G. Frechette

2014-05-01T23:59:59.000Z

118

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Nenad M. Markovic (Primary Contact) and Vojislav R. Stamenkovic Argonne National Laboratory (ANL) Argonne, IL 60439 Phone: (630) 252-5181 Email: nmmarkovic@anl.gov DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Subcontractors: * Karren More, Oak Ridge National Laboratory, Oak Ridge, TN * Charles Hays, Jet Propulsion Laboratory, Pasadena, CA * Shuoheng Sun, Brown University, Providence, RI * Guofeng Wang, University of Pittsburgh, Pittsburgh, PA * Radoslav Atanasoski, 3M Company, Saint Paul, MN

119

Development of Cathode Architectures Customized for H2/O2 Metal-Cation-Free Alkaline Membrane Fuel Cells  

Science Journals Connector (OSTI)

A final significant finding was that Pt-free Vulcan XC-72R?only cathodes can produce between 25% and 36% of the power obtained when Pt/C catalysts were used in SPE-AFCs (this is not the case with PEMFCs where carbon is electrokinetically inactive for the oxygen reduction reaction at the cathode); this insight highlights the necessity of recording the background currents, arising from the carbon supports, when testing different catalyst formulations in alkaline media. ... The Ag/C catalyst performed poorly for the hydrogen oxidation reaction (HOR) at the anode of a SPE-AFC and for the ORR at the cathode of a PEMFC. ... MEA E containing the E-Tek-catalyzed carbon paper electrode did not perform as well as MEA A. ...

Christelle Tamain; Simon D. Poynton; Robert C. T. Slade; Bryony Carroll; John R. Varcoe

2007-11-10T23:59:59.000Z

120

Improved Direct Methanol Fuel Cell Stack  

DOE Patents (OSTI)

A stack of direct methanol fuel cells exhibiting a circular footprint. A cathode and anode manifold, tie-bolt penetrations and tie-bolts are located within the circular footprint. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet and outlet cathode manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold, where the serpentine channels of the anode are orthogonal to the serpentine channels of the cathode. Located between the two plates is the fuel cell active region.

Wilson, Mahlon S. (Los Alamos, NM); Ramsey, John C. (Los Alamos, NM)

2005-03-08T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Nickel-Cathoded Perovskite Solar Cells  

Science Journals Connector (OSTI)

Nickel-Cathoded Perovskite Solar Cells ... Current lead halide perovskite solar cells use high work function (?) precious metals, such as gold (? = 5.1 eV), as the back cathode to maximize the attainable photovoltage. ... We report herein a set of perovskite-type solar cells that use nickel (? = 5.04 eV), an earth-abundant element and non-precious metal, as back cathode and achieve the same open-circuit voltage as gold and an efficiency of 10.4%. ...

Qinglong Jiang; Xia Sheng; Bing Shi; Xinjian Feng; Tao Xu

2014-10-22T23:59:59.000Z

122

Solid oxide fuel cell with single material for electrodes and interconnect  

DOE Patents (OSTI)

A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

McPheeters, Charles C. (Naperville, IL); Nelson, Paul A. (Wheaton, IL); Dees, Dennis W. (Downers Grove, IL)

1994-01-01T23:59:59.000Z

123

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Converting chemical energy of hydrogenated fuels into electricity Project Description Invented in 1839, fuels cells powered the Gemini and Apollo space missions, as well as the space shuttle. Although fuel cells have been successfully used in such applications, they have proven difficult to make more cost-effective and durable for commercial applications, particularly for the rigors of daily transportation. Since the 1970s, scientists at Los Alamos have managed to make various scientific breakthroughs that have contributed to the development of modern fuel cell systems. Specific efforts include the following: * Finding alternative and more cost-effective catalysts than platinum. * Enhancing the durability of fuel cells by developing advanced materials and

124

Cells having cathodes containing polycarbon disulfide materials  

DOE Patents (OSTI)

The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS.sub.x).sub.n, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode.

Okamoto, Yoshi (Fort Lee, NJ); Skotheim, Terje A. (Shoreham, NY); Lee, Hung S. (Rocky Point, NY)

1995-08-15T23:59:59.000Z

125

Cells having cathodes containing polycarbon disulfide materials  

DOE Patents (OSTI)

The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS{sub x}){sub n}, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode. 5 figs.

Okamoto, Y.; Skotheim, T.A.; Lee, H.S.

1995-08-15T23:59:59.000Z

126

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per

127

Fuel Cell Basics | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Basics Basics Fuel Cell Basics August 14, 2013 - 2:09pm Addthis Photo of two hydrogen fuel cells. Fuel cells are an emerging technology that can provide heat and electricity for buildings and electrical power for vehicles and electronic devices. How Fuel Cells Work Fuel cells work like batteries, but they do not run down or need recharging. They produce electricity and heat as long as fuel is supplied. A fuel cell consists of two electrodes-a negative electrode (or anode) and a positive electrode (or cathode)-sandwiched around an electrolyte. A fuel, such as hydrogen, is fed to the anode, and air is fed to the cathode. Activated by a catalyst, hydrogen atoms separate into protons and electrons, which take different paths to the cathode. The electrons go through an external circuit, creating a flow of electricity. The protons

128

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust...

129

Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells Fuel Cells Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electrochemical Devices Email Fernando Garzon Sensors & Electrochemical Devices Email Piotr Zelenay Sensors & Electrochemical Devices Email Rod Borup Sensors & Electrochemical Devices Email Karen E. Kippen Experimental Physical Sciences Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

130

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect

SS 304 was encapsulated with thin layers of Co-Ni by an electroless deposition process. The corrosion behavior of SS304 and Co-Ni-SS304 was investigated in molten carbonate under cathode gas atmosphere with electrochemical and surface characterization tools. Surface modification of SS304 reduced the dissolution of chromium and nickel into the molten carbonate melt. Composition of the corrosion scale formed in case of Co-Ni-SS304 is different from SS304 and shows the presence of Co and Ni oxides while the latter shows the presence of lithium ferrite. Polarization resistance for oxygen reduction reaction and conductivity of corrosion values for the corrosion scales were obtained using impedance analysis and current-potential plots. The results indicated lower polarization resistance for oxygen reduction reaction in the case of Co-Ni-SS304 when compared to SS304. Also, the conductivity of the corrosion scales was considerably higher in case of Co-Ni-SS304 than the SS304. This study shows that modifying the current collector surface with Co-Ni coatings leads to the formation of oxide scales with improved barrier properties and electronic conductivity.

Dr. Ralph E. White

2001-03-31T23:59:59.000Z

131

Hydrogen & Fuel Cells - Fuel Cell - Polymer Electrolyte  

NLE Websites -- All DOE Office Websites (Extended Search)

Polymer Electrolyte Fuel Cell Research Polymer Electrolyte Fuel Cell Research Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. Xiaoping Wang measures the stability of a platinum cathode electrocatalyst. One of the main barriers to the commercialization of polymer electrolyte fuel cell (PEFC) systems, especially for automotive use, is the high cost of the platinum electrocatalysts. Aside from the cost of the precious metal, concern has also been raised over the adequacy of the world supply of platinum, if fuel cell vehicles were to make a significant penetration into the global automotive fleet. At Argonne, chemists are working toward the development of low-cost nonplatinum electrocatalysts for the oxygen reduction reaction--durable materials that would be stable in the fuel

132

Nanostructured thin films for solid oxide fuel cells  

E-Print Network (OSTI)

The goals of this work were to synthesize high performance perovskite based thin film solid oxide fuel cell (TF-SOFC) cathodes by pulsed laser deposition (PLD), to study the structural, electrical and electrochemical properties of these cathodes...

Yoon, Jongsik

2009-05-15T23:59:59.000Z

133

Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy novel cathode / alloy...

134

Ambient pressure fuel cell system  

DOE Patents (OSTI)

An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

Wilson, Mahlon S. (Los Alamos, NM)

2000-01-01T23:59:59.000Z

135

High Energy Novel Cathode / Alloy Automotive Cell  

Energy.gov (U.S. Department of Energy (DOE))

2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

136

High Energy Novel Cathode / Alloy Automotive Cell  

Energy.gov (U.S. Department of Energy (DOE))

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

137

Fuel Cell R&D Pre-Solicitiation Workshop  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of 20-40% depending on stage of development * Potential Topics of Research: * Improved Fuel Cell Membranes * Water Transport Within the Stack * Advanced Cathode Catalysts and...

138

Chemical Degradation: Correlations Between Electrolyzer and Fuel Cell Findings  

Science Journals Connector (OSTI)

Membrane chemical degradation of polymer electrolyte membrane fuel cells (PEMFCs) is summarized in this paper. ... , and cation contamination, are summarized. Localized degradations, including anode versus cathod...

Han Liu; Frank D. Coms; Jingxin Zhang

2009-01-01T23:59:59.000Z

139

Interconnection of bundled solid oxide fuel cells  

DOE Patents (OSTI)

A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

2014-01-14T23:59:59.000Z

140

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Multi-scale solid oxide fuel cell materials modeling  

Science Journals Connector (OSTI)

Performance and degradation of fuel cell components are discussed in a multi-scale ... paper. Electrochemical reactions in a solid oxide fuel cell occur simultaneously as charge and gas pass ... and cathode to pr...

Ji Hoon Kim; Wing Kam Liu; Christopher Lee

2009-10-01T23:59:59.000Z

142

Long-term evaluation of solid oxide fuel cell candidate materials in a 3-cell generic stack test fixture, part III: Stability and microstructure of Ce-(Mn,Co)-spinel coating, AISI441 interconnect, alumina coating, cathode and anode  

Science Journals Connector (OSTI)

Abstract A generic solid oxide fuel cell stack test fixture was developed to evaluate candidate materials and processing under realistic conditions. Part III of the work investigated the stability of Ce-(Mn,Co) spinel coating, AISI441 metallic interconnect, alumina coating, and cell's degradation. After 6000h test, the spinel coating showed densification with some diffusion of Cr. At the metal interface, segregation of Si and Ti was observed, however, no continuous layer formed. The alumina coating for perimeter sealing areas appeared more dense and thick at the air side than the fuel side. Both the spinel and alumina coatings remained bonded. EDS analysis of Cr within the metal showed small decrease in concentration near the coating interface and would expect to cause no issue of Cr depletion. Inter-diffusion of Ni, Fe, and Cr between spot-welded Ni wire and AISI441 interconnect was observed and Cr-oxide scale formed along the circumference of the weld. The microstructure of the anode and cathode was discussed relating to degradation of the top and middle cells. Overall, the Ce-(Mn,Co) spinel coating, alumina coating, and AISI441 steel showed the desired long-term stability and the developed generic stack fixture proved to be a useful tool to validate candidate materials for SOFC.

Yeong-Shyung Chou; Jeffry W. Stevenson; Jung-Pyung Choi

2014-01-01T23:59:59.000Z

143

High Specific Power, Direct Methanol Fuel Cell Stack  

NLE Websites -- All DOE Office Websites (Extended Search)

High Specific Power, Direct Methanol Fuel Cell Stack High Specific Power, Direct Methanol Fuel Cell Stack High Specific Power, Direct Methanol Fuel Cell Stack The present invention is a fuel cell stack including at least one direct methanol fuel cell. Available for thumbnail of Feynman Center (505) 665-9090 Email High Specific Power, Direct Methanol Fuel Cell Stack The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold

144

Cathode for an electrochemical cell  

DOE Patents (OSTI)

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

145

A thin-film/agglomerate model of a proton-exchange-membrane fuel cell cathode catalyst layer with consideration of solid-polymer-electrolyte distribution  

Science Journals Connector (OSTI)

Experimental work on the proton-exchange-membrane fuel cell (PEMFC) has revealed that a better utilization of carbon supported platinum catalyst (Pt/C) hinges on an appropriate...112...]. GDE is prepared by a po...

Ken-Ming Yin

2007-08-01T23:59:59.000Z

146

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Presentation covers stationary fuel cells...

147

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November...

148

Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Overview: 2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November 1, 2011. Fuel Cell...

149

Advanced Cathode Catalysts  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on advanced cathode catalysts, was given by Piotr Zelenay of Los Alamos National laboratory at a February 2007 meeting on new fuel cell projects.

150

Project Sponsors:National Fuel Cell Research Center  

E-Print Network (OSTI)

Project Sponsors:National Fuel Cell Research Center www.nfcrc.uci.edu RESULTS · PEM fuel cell the results of subjecting a hydrogen-anode, air-breathing cathode Proton Exchange Membrane (PEM) fuel cell., and Samuelsen, G. S. (2003). "Experimental Evaluation and Computer Simulation of an Air-Breathing PEM Fuel Cell

Mease, Kenneth D.

151

Proceedings of the Lucerne Fuel Cell Forum 2006 European Solid Oxide Fuel Cell Forum, 3-7 July 2006  

E-Print Network (OSTI)

Proceedings of the Lucerne Fuel Cell Forum 2006 7th European Solid Oxide Fuel Cell Forum, 3-7 July Uncertainties in our understanding of the oxygen reduction mechanism (ORR) at solid oxide fuel cell (SOFC studies have shown that cathodic or anodic dc polarization of the solid oxide fuel cell oxygen electrodes

Yildiz, Bilge

152

Coupled Thermal and Water Management in Polymer-Electrolyte Fuel Cells  

E-Print Network (OSTI)

for porosity and tortuosity fuel-cell inlet conditionson the cathode side of the fuel cell. Water is evaporated indiagram corresponds to the fuel-cell inlet, the bottom to

Weber, Adam Z.; Newman, John

2006-01-01T23:59:59.000Z

153

Using a Quasipotential Transformation for Modeling Diffusion Media in Polymer-Electrolyte Fuel Cells  

E-Print Network (OSTI)

of Performance of PEM Fuel Cells with Conventional andLayers of the Cathode of a PEM Fuel Cell , Journal of thea Microporous Sublayer for PEM Fuel Cells , Journal of Power

Weber, Adam Z.

2008-01-01T23:59:59.000Z

154

Air Breathing Direct Methanol Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Breathing Direct Methanol Fuel Cell Air Breathing Direct Methanol Fuel Cell Air Breathing Direct Methanol Fuel Cell An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol source. Available for thumbnail of Feynman Center (505) 665-9090 Email Air Breathing Direct Methanol Fuel Cell An air breathing direct methanol fuel cell is provided with a membrane electrode assembly, a conductive anode assembly that is permeable to air and directly open to atmospheric air, and a conductive cathode assembly that is permeable to methanol and directly contacting a liquid methanol

155

Annular feed air breathing fuel cell stack  

DOE Patents (OSTI)

A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

Wilson, Mahlon S. (Los Alamos, NM); Neutzler, Jay K. (Peoria, AZ)

1997-01-01T23:59:59.000Z

156

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

157

Cathode Synthesis and Voltage Fade: Designed Solutions Based...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Cathode Synthesis and Voltage Fade: Designed Solutions Based on Theory Cathode Synthesis and Voltage Fade: Designed Solutions Based on Theory 2013 DOE Hydrogen and Fuel Cells...

158

Development of High-Capacity Cathode Materials with Integrated...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Development of High-Capacity Cathode Materials with Integrated Structures Development of High-Capacity Cathode Materials with Integrated Structures 2013 DOE Hydrogen and Fuel Cells...

159

Design and Evaluation of Novel High Capacity Cathode Materials...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and Evaluation of Novel High Capacity Cathode Materials Design and Evaluation of Novel High Capacity Cathode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle...

160

PEM fuel cell monitoring system  

DOE Patents (OSTI)

Method and apparatus for monitoring the performance of H.sub.2 --O.sub.2 PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H.sub.2 sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken.

Meltser, Mark Alexander (Pittsford, NY); Grot, Stephen Andreas (West Henrietta, NY)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

PEM fuel cell monitoring system  

DOE Patents (OSTI)

Method and apparatus are disclosed for monitoring the performance of H{sub 2}--O{sub 2} PEM fuel cells. Outputs from a cell/stack voltage monitor and a cathode exhaust gas H{sub 2} sensor are corrected for stack operating conditions, and then compared to predetermined levels of acceptability. If certain unacceptable conditions coexist, an operator is alerted and/or corrective measures are automatically undertaken. 2 figs.

Meltser, M.A.; Grot, S.A.

1998-06-09T23:59:59.000Z

162

FUEL CELLS DIRECT ALCOHOL FUEL CELLS | Direct Ethylene Glycol Fuel Cells  

Science Journals Connector (OSTI)

Direct ethylene glycol fuel cells, in which the oxidation of ethylene glycol and the reduction of oxygen take place at the anode and the cathode, respectively, are promising candidates as electric power sources of portable devices such as the cellular phone and the laptop computer. The advantages of ethylene glycol are high activity, high energy density, low volatility, and high boiling point compared with other organic fuels such as methanol and ethanol. In this article, the construction of direct ethylene glycol fuel cells, the electrooxidation of ethylene glycol in acid and alkaline solutions, cathode catalysts, and operating conditions such as temperature, pH of the electrolytes, and the concentration of ethylene glycol are described.

Z. Ogumi; K. Miyazaki

2009-01-01T23:59:59.000Z

163

Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} (x=0, 0.3): New cobaltite materials as cathodes for proton conducting solid oxide fuel cell  

SciTech Connect

Misfit-type Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} (x=0, 0.3) oxides were synthesised to be evaluated as possible cathode materials for proton conducting fuel cells (PCFCs) based on BaCe{sub 0.9}Y{sub 0.1}O{sub 3-{delta}} (BCY10) dense ceramic electrolyte. The electrical conductivity value of Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}} ({sigma}{approx}53 S cm{sup -1} at 600 deg. C) is in the range of usually required value for a cathode application (about 50-100 S cm{sup -1}). In order to test the performance of each compound as cathode material, impedance measurements were carried out on Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}}/BaCe{sub 0.9}Y{sub 0.1}O{sub 3-{delta}}/Ca{sub 3-x}La{sub x}Co{sub 4}O{sub 9+{delta}} symmetrical half cells over the temperature range 400-800 deg. C under wet air. A promising electrocatalytic activity has been observed with both compounds Ca{sub 3}Co{sub 4}O{sub 9+{delta}} and Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}}. Factually, the area specific resistance obtained was about 2.2 {Omega} cm{sup 2} at 600 deg. C. - Graphical abstract: Arrehnius plots of the ASR for Ca{sub 3}Co{sub 4}O{sub 9+{delta}} and Ca{sub 2.7}La{sub 0.3}Co{sub 4}O{sub 9+{delta}}.

Ben Yahia, Hamdi [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France); Mauvy, Fabrice, E-mail: mauvy@icmcb-bordeaux.cnrs.f [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France); Grenier, Jean Claude [CNRS, Universite de Bordeaux, ICMCB, 87, Avenue A. Schweitzer, 33608 Pessac Cedex (France)

2010-03-15T23:59:59.000Z

164

Cathode Contact Materials for Anode-Supported Cell Development - Lawrence Berkeley National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Contact Materials for Anode- Cathode Contact Materials for Anode- Supported Cell Development- Lawrence Berkeley National Laboratory Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

165

Symposium on bioelectrochemistry of microorganisms. IV. Biochemical fuel cells.  

Science Journals Connector (OSTI)

...photosynthesis of algae. A possible ad...a few of the bio-fuel cells will be considered...hydrogen- oxygen fuel cell. Pt electrodes...coated with marine algae developed more cathodic...Similarly, the algae yield oxygen which...with conventional fuel cells or solar cells...

K Lewis

1966-03-01T23:59:59.000Z

166

Attenuated degradation of a PEMFC cathode during fuel starvation by using carbon-supported IrO2  

Science Journals Connector (OSTI)

IrO2, a water electrolysis catalyst, has been known to be effective in preventing corrosion of the carbon support in proton exchange membrane fuel cells (PEMFCs). Particulate IrO2 can agglomerate easily, which can decrease substantially the catalytic surface area required for oxygen evolution reaction, causing the loss of catalytic efficiency. Furthermore, agglomerated IrO2 nanoparticles can have an adverse effect on the oxygen reduction reaction by covering the active surface area of the Pt/C cathode catalyst, which is a damaging factor for the intrinsic performance of PEMFC. Carbon-supported iridium oxide, IrO2/C, which can prevent the agglomeration of Ir nanoparticles more effectively, was synthesized to overcome these problems. Compared to the cell with the Pt/C cathode only, the cell with 10wt.% IrO2 particles and Pt/C cathode showed stronger durability during fuel starvation but the cell performance at normal operation decreased severely by 35%. The cell with the same amount of IrO2 dispersed on a carbon support, 10wt.% IrO2/C, showed similar durability during fuel starvation maintaining the cell performance comparable to the cell using a Pt/C cathode only. Carbon-supported IrO2, IrO2/C, was more effective than IrO2 particles in both maintaining the intrinsic performance and improving the cell durability during fuel starvation.

Injoon Jang; Imgon Hwang; Yongsug Tak

2013-01-01T23:59:59.000Z

167

Intermediate Temperature Solid Oxide Fuel Cell Development  

SciTech Connect

Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600 C than conventional manganite or cobaltite cathodes.

S. Elangovan; Scott Barnett; Sossina Haile

2008-06-30T23:59:59.000Z

168

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by...

169

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's...

170

DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 DOE Fuel Cell Technologies Office Record 13012: Fuel Cell System Cost - 2013 This program record from the...

171

Fuel cell system with combustor-heated reformer  

DOE Patents (OSTI)

A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

Pettit, William Henry (Rochester, NY)

2000-01-01T23:59:59.000Z

172

Combinatorial Discovery of Fuel Cell Electrocatalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Discovery of Fuel Cell Discovery of Fuel Cell Electrocatalysts Eugene S. Smotkin University of Puerto Rico @ Rio Piedras Non-Platinum Electrocatalysts Workshop March 21, 2003 Marriot courtyard - Convention Center New Orleans, Louisiana Combinatorial Discovery of Fuel Cell Electrocatalysts Eugene S. Smotkin University of Puerto Rico @ Rio Piedras Non-Platinum Electrocatalysts Workshop March 21, 2003 Marriot courtyard - Convention Center New Orleans, Louisiana Overview „ Parallel Screening methods „ Optical Screening method „ Array fuel cell „ Array synthetic methods „ Partial review of non-Pt cathode work Overview „ Parallel Screening methods „ Optical Screening method „ Array fuel cell „ Array synthetic methods „ Partial review of non-Pt cathode work Optical Screening of Electrocatalyst Libraries

173

Nitrogen-Doped Fullerene as a Potential Catalyst for Hydrogen Fuel Cells  

Science Journals Connector (OSTI)

Nitrogen-Doped Fullerene as a Potential Catalyst for Hydrogen Fuel Cells ... We examine the possibility of nitrogen-doped C60 fullerene (N-C60) as a cathode catalyst for hydrogen fuel cells. ... N-C60 fullerene is a potential cathode catalyst for hydrogen fuel cells. ...

Feng Gao; Guang-Lin Zhao; Shizhong Yang; James J. Spivey

2012-09-19T23:59:59.000Z

174

Fuel Cell Links  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Links Fuel Cell Links The links below are provided as additional resources for fuel-cell-related information. Most of the linked sites are not part of, nor affiliated with, fueleconomy.gov. We do not endorse or vouch for the accuracy of the information found on such sites. Fuel Cell Vehicles and Manufacturers Chevrolet General Motors press release about the Chevrolet Fuel Cell Equinox Ford Ford overview of their hydrogen fuel cell vehicles Honda FCX Clarity official site Hyundai Hyundai press release announcing the upcoming Tucson Fuel Cell Mercedes-Benz Ener-G-Force Fuel-cell-powered concept SUV Nissan Nissan TeRRA concept SUV Toyota Overview of Toyota fuel cell technology Hydrogen- and Fuel-Cell-Related Information and Tools Fuel Cell Vehicles Brief overview of fuel cell vehicles provided by DOE's Alternative Fuels Data Center (AFDC)

175

Parallel and Adaptive Simulation of Fuel Cells Robert Klfkorn1  

E-Print Network (OSTI)

Parallel and Adaptive Simulation of Fuel Cells in 3d Robert Klöfkorn1 , Dietmar Kröner1 , Mario) fuel cells. Hereby, we focus on the simulation done in 3d us- ing modern techniques like higher order and the transport of species in the cathodic gas diffusion layer of the fuel cell. Therefore, from the detailed

Münster, Westfälische Wilhelms-Universität

176

Mathematical modelling of the catalyst layer of a polymer electrolyte fuel cell  

Science Journals Connector (OSTI)

......A. (1999) Electrochemical impedance of the cathode catalyst layer in polymer electrolyte fuel cells. J...charge transfer as well as electrochemistry in the cathode catalyst layer of a PEMFC. Master's Thesis, Virginia Polytechnic Institute......

A. A. Shah; Gwang-Soo Kim; K. Promislow

2007-06-01T23:59:59.000Z

177

LANL Fuel Cell Research 1HFCIT Program Kick-off Meeting, Arlington, VA, February 13-14, 2007  

E-Print Network (OSTI)

Laboratory Hydrogen, Fuel Cells and Infrastructure Technologies Radoslav Adzic Paolina Atanassova Cabot fuel cell (PEFC) cathode Other objectives: · Investigate new catalyst supports and electrode structures physicochemical characterization, electrochemical and fuel cell testing · Optimize catalysts, supports

178

Hydrogen Fuel Cell Vehicles  

E-Print Network (OSTI)

the membrane for a PEM fuel cell would cost $5/ft (1990$) inmass-produced PEM fuel cell could cost $10/kW or less. Totalparameter for PEM fuel cells: thinner membranes cost less

Delucchi, Mark

1992-01-01T23:59:59.000Z

179

Hydrogen Fuel Cell Vehicles  

E-Print Network (OSTI)

$ b materials cost, % a Fuel cell stack cost only. Includesof the cost of fuel-cell stacks, 1990$ Cost item GE Swan cAnnual maintenance cost of fuel cell stack and auxiliaries (

Delucchi, Mark

1992-01-01T23:59:59.000Z

180

Hydrogen Fuel Cell Vehicles  

E-Print Network (OSTI)

Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September byet al. , 1988,1989 HYDROGEN FUEL-CELL VEHICLES: TECHNICALIn the FCEV, the hydrogen fuel cell could supply the "net"

Delucchi, Mark

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Development of Ultra-low Platinum Alloy Cathode Catalyst for...  

Energy Savers (EERE)

Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells These slides were presented...

182

Review article Components manufacturing for solid oxide fuel cells  

E-Print Network (OSTI)

-stabilized zirconia, YSZ) and the electrocatalyst (lanthanum manganite for the cathode and nickel metal for the anode are stressed. Especially for planar cell designs, the chromium contamination of the cathode and interfacial; Processing; Interconnect materials 1. Introduction Worldwide, several developers of solid oxide fuel cell

Gleixner, Stacy

183

Fuel Cells at NASCAR  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cells at NASCAR Ned Stetson U.S. Department of Energy Fuel Cell Technologies Office Catherine Kummer - NASCAR Green Norm Bessette - Acumentrics Question and Answer * Please...

184

Automotive Fuel Cell Corporation  

NLE Websites -- All DOE Office Websites (Extended Search)

with AFCC, a private joint venture company in Canada, formed by combining the automotive fuel cell business of Ballard Power Systems with the fuel cell stack development...

185

Improved Performance of Proton Exchange Membrane Fuel Cells with p-Toluenesulfonic Acid-Doped Co-PPy/C as Cathode Electrocatalyst  

Science Journals Connector (OSTI)

The characteristics and electrocatalytic activities of Co-PPy-TsOH/C were analyzed with various techniques, including Raman spectroscopy, elemental analysis, rotating ring disk electrode analysis, and a single H2?O2 PEMFC, and compared with those of undoped catalyst Co-PPy/C. ... The performance of PEMFCs with Co-PPy-TsOH/C as cathode catalyst is better than that with Co-PPy/C, and the resulting maximum output power density of 203 mW cm?2 is a substantial improvement over the best values reported in the literature with Co-PPy/C-based cathode catalyst. ...

Xianxia Yuan; Xin Zeng; Hui-Juan Zhang; Zi-Feng Ma; Chao-Yang Wang

2010-01-21T23:59:59.000Z

186

Fuel Cell Technologies Office: Reversible Fuel Cells Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Reversible Fuel Cells Reversible Fuel Cells Workshop to someone by E-mail Share Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Facebook Tweet about Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Twitter Bookmark Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Google Bookmark Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Delicious Rank Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on Digg Find More places to share Fuel Cell Technologies Office: Reversible Fuel Cells Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings

187

Humidity-independent portable air-hydrogen fuel cells with slotted silicon based gas-distributing plates  

Science Journals Connector (OSTI)

We have studied the characteristics of small-scale air-hydrogen fuel cells (FCs) operating in a free-breathing cathode regime. The cells are provided with a new gas-distributing element on the cathode side, wh...

E. V. Astrova; D. A. Andronikov; M. V. Gorokhov

2010-06-01T23:59:59.000Z

188

Improved Performance of Proton Exchange Membrane Fuel Cells with p-Toluenesulfonic Acid-Doped Co-PPy/C as Cathode Electrocatalyst  

E-Print Network (OSTI)

-PPy/C as Cathode Electrocatalyst Xianxia Yuan,, Xin Zeng, Hui-Juan Zhang, Zi-Feng Ma,*, and Chao-Yang Wang, and Materials Science and Engineering, The PennsylVania State UniVersity, UniVersity Park, PennsylVania 16802 costs and improve activity of non-noble-metal catalysts for oxygen reduction reaction (ORR

189

Fuel Cell Technologies Office: Glossary  

NLE Websites -- All DOE Office Websites (Extended Search)

Glossary Glossary This glossary contains terms and acronyms related to hydrogen and fuel cell technologies. A B C D E F G H I J K L M N O P Q R S T U V W X Y Z - Acronyms A AC Generator (or Alternator) An electric device that produces an electric current that reverses direction many times per second. Also called a synchronous generator. Adsorption The adhesion of the molecules of gases, dissolved substances, or liquids to the surface of the solids or liquids with which they are in contact. Air The mixture of oxygen, nitrogen, and other gases that, with varying amounts of water vapor, forms the atmosphere of the earth. Alkaline Fuel Cell (AFC) A type of hydrogen/oxygen fuel cell in which the electrolyte is concentrated potassium hydroxide (KOH) and the hydroxide ions (OH-) are transported from the cathode to the anode.

190

Fuel cell generating plant  

SciTech Connect

This paper discusses a fuel cell generating plant. It comprises a compressed fuel supply; a fuel cell system including fuel conditioning apparatus and fuel cells; a main fuel conduit for conveying fuel from the fuel supply to the fuel cell system; a turbo compressor having a turbine receiving exhaust products from the fuel cell system and a compressor for compressing air; a main air conduit for conveying air from the compressor to the fuel cell system; an auxiliary burner having a primary burner and a pilot; an auxiliary air conduit for conveying air from the compressed fuel supply to the auxiliary burner; an auxiliary exhaust conduit for conveying exhaust products from the auxiliary burner to the turbine; a check valve located between the fuel supply and the pilot; and a gas accumulator in the auxiliary fuel conduit located between the check valve and the pilot.

Sanderson, R.A.

1990-11-27T23:59:59.000Z

191

Fuel Cell Technologies Office: Fuel Cell Technical Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Cell Technical Cell Technical Publications to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technical Publications on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technical Publications on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technical Publications on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technical Publications on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technical Publications on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technical Publications on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards Market Analysis Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings

192

A NEW PEMFC FLOW FIELD PLATE OPTIMIZATION COMPARISON - ANSYS FLUENT FUEL-CELL SIMULATION.  

E-Print Network (OSTI)

??The performance of a new cathode flow field plate located on a PEM fuel cell was compared to an industry standard and optimal serpentine design (more)

Soueidan, Ahmed Yassin

2012-01-01T23:59:59.000Z

193

An Overview of NREL's Online Data Tool for Fuel Cell System-Derived...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

13012fuelcellsystemcost2013.pdf 6 Fuel Cell Stack & Balance of Plant (BOP) FC Stack Air Back-Pressure Valve Hydrogen Cathode Humidifier Coolant Pump Combustor? Radiator H 2...

194

SYNTHESIS, CHARACTERIZATION AND PERFORMANCE TESTING OF PT- BASED ELECTROCATALYSTS FOR LOW TEMPERATURE PEM FUEL CELLS.  

E-Print Network (OSTI)

??The oxygen reduction reaction (ORR) activity on the cathode plays a significant role in deciding the overall performance of proton exchange membrane (PEM) fuel cells. (more)

Gong, Yanming

2008-01-01T23:59:59.000Z

195

Regenerative fuel cell engineering - FY99  

SciTech Connect

The authors report the work conducted by the ESA-EPE Fuel Cell Engineering Team at Los Alamos National Laboratory during FY99 on regenerative fuel cell system engineering. The work was focused on the evaluation of regenerative fuel cell system components obtained through the RAFCO program. These components included a 5 kW PEM electrolyzer, a two-cell regenerative fuel cell stack, and samples of the electrolyzer membrane, anode, and cathode. The samples of the electrolyzer membrane, anode, and cathode were analyzed to determine their structure and operating characteristics. Tests were conducted on the two-cell regenerative fuel cell stack to characterize its operation as an electrolyzer and as a fuel cell. The 5 kW PEM electrolyzer was tested in the Regenerative Fuel Cell System Test Facility. These tests served to characterize the operation of the electrolyzer and, also, to verify the operation of the newly completed test facility. Future directions for this work in regenerative fuel cell systems are discussed.

Michael A. Inbody; Rodney L. Borup; James C. Hedstrom; Jose Tafoya; Byron Morton; Lois Zook; Nicholas E. Vanderborgh

2000-01-01T23:59:59.000Z

196

Water injected fuel cell system compressor  

DOE Patents (OSTI)

A fuel cell system including a dry compressor for pressurizing air supplied to the cathode side of the fuel cell. An injector sprays a controlled amount of water on to the compressor's rotor(s) to improve the energy efficiency of the compressor. The amount of water sprayed out the rotor(s) is controlled relative to the mass flow rate of air inputted to the compressor.

Siepierski, James S. (Williamsville, NY); Moore, Barbara S. (Victor, NY); Hoch, Martin Monroe (Webster, NY)

2001-01-01T23:59:59.000Z

197

High specific power, direct methanol fuel cell stack  

DOE Patents (OSTI)

The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

Ramsey, John C. (Los Alamos, NM); Wilson, Mahlon S. (Los Alamos, NM)

2007-05-08T23:59:59.000Z

198

Micro-electro-mechanical systems phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

2010-12-21T23:59:59.000Z

199

Micro-electro-mechanical systems phosphoric acid fuel cell  

DOE Patents (OSTI)

A phosphoric acid fuel cell system comprising a porous electrolyte support, a phosphoric acid electrolyte in the porous electrolyte support, a cathode electrode contacting the phosphoric acid electrolyte, and an anode electrode contacting the phosphoric acid electrolyte.

Sopchak, David A. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Kotovsky, Jack (Oakland, CA); Graff, Robert T. (Modesto, CA)

2010-08-17T23:59:59.000Z

200

Mesoporous Nanostructured Nb-Doped Titanium Dioxide Microsphere Catalyst Supports for PEM Fuel Cell Electrodes  

Science Journals Connector (OSTI)

Mesoporous Nanostructured Nb-Doped Titanium Dioxide Microsphere Catalyst Supports for PEM Fuel Cell Electrodes ... The material has been investigated as cathode electrocatalyst support for polymer electrolyte membrane (PEM) fuel cells. ... doped titania; PEMFC; electrocatalyst; mesoporous materials; microspheres ...

Laure Chevallier; Alexander Bauer; Sara Cavaliere; Rob Hui; Jacques Rozire; Deborah J. Jones

2012-03-19T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Investigation of the performance and water transport of a polymer electrolyte membrane (pem) fuel cell  

E-Print Network (OSTI)

Fuel cell performance was obtained as functions of the humidity at the anode and cathode sites, back pressure, flow rate, temperature, and channel depth. The fuel cell used in this work included a membrane and electrode assembly (MEA) which...

Park, Yong Hun

2009-05-15T23:59:59.000Z

202

The effect of Mn on the oxidation behavior and electrical conductivity of Fe17Cr alloys in solid oxide fuel cell cathode atmosphere  

Science Journals Connector (OSTI)

Four Fe17Cr alloys with various Mn contents between 0.0 and 3.0wt.% are prepared for investigation of the effect of Mn content on the oxidation behavior and electrical conductivity of the FeCr alloys for the application of metallic interconnects in solid oxide fuel cells (SOFCs). During the initial oxidation stage (within 1min) at 750C in air, Cr is preferentially oxidized to form a layer of Cr2O3 type oxide in all the alloys, regardless the Mn content, with similar oxidation rate and oxide morphology. The subsequent oxidation of the Mn containing alloys is accelerated caused by the fast outward diffusion of Mn ions across the Cr2O3 type oxide layer to form Mn-rich (Mn, Cr)3O4 and Mn2O3 oxides on the top. After 700h oxidation a multi-layered oxide scale is observed in the Mn containing alloys, which corresponds to a multi-stage oxidation kinetics in the alloys containing 0.5 and 1.0wt.% of Mn. The oxidation rate and ASR of the oxide scale increase with the Mn content in the alloy changes from 0.0 to 3.0wt.%. For the application of metallic interconnects in SOFCs, Mn-free Fe17Cr alloy with conducting Cr free spinel coatings is preferred.

Bin Hua; Yonghong Kong; Wenying Zhang; Jian Pu; Bo Chi; Li Jian

2011-01-01T23:59:59.000Z

203

FUEL CELLS MOLTEN CARBONATE FUEL CELLS | Overview  

Science Journals Connector (OSTI)

The molten carbonate fuel cell (MCFC) emerged during the twentieth century as one of the key fuel cell types. It uses an electrolyte of alkali metal carbonates, operates typically at 650C, and is best suited to hydrocarbon fuels such as natural gas, coal gas, or biogas. The high operating temperature enables such fuels to be fed directly to the MCFC stacks, leading to conversion efficiencies greater than 50%. Molten carbonate fuel cell systems are ideally suited to applications that need continuous base load power. The first commercial systems, at the 300kW scale, are therefore being used in applications such as hospitals and hotels.

A.L. Dicks

2009-01-01T23:59:59.000Z

204

Integral edge seals for phosphoric acid fuel cells  

DOE Patents (OSTI)

A phosphoric acid fuel cell having integral edge seals formed by an elastomer permeating an outer peripheral band contiguous with the outer peripheral edges of the cathode and anode assemblies and the matrix to form an integral edge seal which is reliable, easy to manufacture and has creep characteristics similar to the anode, cathode and matrix assemblies inboard of the seals to assure good electrical contact throughout the life of the fuel cell.

Granata, Jr., Samuel J. (South Greensburg, PA); Woodle, Boyd M. (North Huntingdon Township, Westmoreland County, PA); Dunyak, Thomas J. (Blacksburg, VA)

1992-01-01T23:59:59.000Z

205

Modelling microscale fuel cells.  

E-Print Network (OSTI)

??The focus of this work is to investigate transport phenomena in recently developed microscale fuel cell designs using computational fluid dynamics (CFD). Two microscale fuel (more)

Bazylak, Aimy Ming Jii

2009-01-01T23:59:59.000Z

206

Fuel Cell Technologies Overview  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Cells Key Benefits Very High Efficiency Reduced CO 2 Emissions Reduced Oil Use Reduced Air Pollution Fuel Flexibility * 40 - 60% (electrical) * > 70% (electrical, hybrid fuel...

207

FCT Fuel Cells: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Fuel Cells: Basics on Facebook Tweet about FCT Fuel Cells: Basics on Twitter Bookmark FCT Fuel Cells: Basics on Google Bookmark FCT Fuel Cells: Basics on Delicious Rank FCT Fuel Cells: Basics on Digg Find More places to share FCT Fuel Cells: Basics on AddThis.com... Home Basics Current Technology DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of a fuel cell stack A fuel cell uses the chemical energy of hydrogen to cleanly and efficiently produce electricity with water and heat as byproducts. (How much water?) Fuel cells are unique in terms of the variety of their potential applications; they can provide energy for systems as large as a utility

208

California Fuel Cell Partnership: Alternative Fuels Research  

Energy.gov (U.S. Department of Energy (DOE))

This presentation by Chris White of the California Fuel Cell Partnership provides information about alternative fuels research.

209

Fuel cell membranes and crossover prevention  

DOE Patents (OSTI)

A membrane electrode assembly for use with a direct organic fuel cell containing a formic acid fuel includes a solid polymer electrolyte having first and second surfaces, an anode on the first surface and a cathode on the second surface and electrically linked to the anode. The solid polymer electrolyte has a thickness t:.gtoreq..times..times..times..times. ##EQU00001## where C.sub.f is the formic acid fuel concentration over the anode, D.sub.f is the effective diffusivity of the fuel in the solid polymer electrolyte, K.sub.f is the equilibrium constant for partition coefficient for the fuel into the solid polymer electrolyte membrane, I is Faraday's constant n.sub.f is the number of electrons released when 1 molecule of the fuel is oxidized, and j.sub.f.sup.c is an empirically determined crossover rate of fuel above which the fuel cell does not operate.

Masel, Richard I. (Champaign, IL); York, Cynthia A. (Newington, CT); Waszczuk, Piotr (White Bear Lake, MN); Wieckowski, Andrzej (Champaign, IL)

2009-08-04T23:59:59.000Z

210

Hollow Macroporous Core/Mesoporous Shell Carbon with a Tailored Structure as a Cathode Electrocatalyst Support for Proton Exchange Membrane Fuel Cells  

Science Journals Connector (OSTI)

Although our previous study had demonstrated that much higher electrocatalytic activity toward oxidation of methanol could be achieved by Pt50Ru50 nanoparticles supported on HCMSC as anode catalysts in DMFC than the commercial E-TEK one (i.e., Pt50Ru50 supported on VC),49 it still remained questionable if this material would be suitable to support Pt as a cathode catalyst in PEMFC due to its completely different working environment compared with the anode catalyst in DMFC. ... Aluminum was incorporated into the silicate framework through an impregnation method to produce acidic points on the surface of SCMS silica, which will catalyze polymerization of phenol and paraformaldehyde. ... templates by altering acid catalyst sites for acid-catalyzed polymn. ...

Baizeng Fang; Jung Ho Kim; Cheolgyu Lee; Jong-Sung Yu

2007-12-22T23:59:59.000Z

211

In situ synchrotron x-ray studies of dense thin-film strontium-doped lanthanum manganite solid oxide fuel cell cathodes.  

SciTech Connect

Using a model cathode-electrolyte system composed of epitaxial thin-films of La{sub 1-x}Sr{sub x}MnO{sub 3-{delta}} (LSM) on single crystal yttria-stabilized zirconia (YSZ), we investigated changes in the cation concentration profile in the LSM during heating and under applied potential using grazing incidence x-rays. Pulsed laser deposition (PLD) was used to grow epitaxial LSM(011) on YSZ(111). At room temperature, we find that Sr segregates to form Sr enriched nanoparticles and upon heating the sample to 700 C, Sr is slowly reincorporated into the film. We also find different amounts of Sr segregation as the X-ray beam is moved across the sample. The variation in the amount of Sr segregation is greater on the sample that has been subject to 72 hours of applied potential, suggesting that the electrochemistry plays a role in the Sr segregation.

Chang, K. C.; Ingram, B.; Kavaipatti, B.; Yildiz, B.; Hennessy, D.; Salvador, P.; Leyarovski, N.; You, H.; Carnegie Mellon Univ.; Massachusetts Inst. of Tech.

2009-01-01T23:59:59.000Z

212

Electrocatalysts for Fuel Cells  

Science Journals Connector (OSTI)

...research-article Electrocatalysts for Fuel Cells G. J. K. Acres G. A. Hards The...physical composition of the catalysts used in fuel cells are determined by the type of cell...operating conditions. The six types of fuel cell presently in use or under development...

1996-01-01T23:59:59.000Z

213

DOE Fuel Cell Technologies Office  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE Fuel Cell Technologies Office Fuel Cell Seminar & Energy Exposition Columbus, Ohio Dr. Sunita Satyapal Director Fuel Cell Technologies Office Energy Efficiency and Renewable...

214

Fuel Cells | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cells Fuel Cells Fuel cells are an important enabling technology for the nation's energy portfolio and have the potential to revolutionize the way we power our nation,...

215

HISTORY | Fuel Cells  

Science Journals Connector (OSTI)

Together with the electric motor, dynamo, gas turbine, internal combustion engine, and the fused salt electrolysis of aluminum, the industrial revolution of the nineteenth century brought about the fuel cell the silent or cold combustion of fossil fuels by the electrochemical oxidation with atmospheric oxygen to water and carbon dioxide. Wilhelm Ostwald, in 1894, emphasized the high efficiency and the nonpolluting properties of the direct conversion of chemical energy into electricity in contrast to the then combination of steam engine and dynamo, which reached only about 10% efficiency. Direct coal fuel cells designed for the propulsion of ships, however, have not become a reality so far. Instead of fuel cells and batteries, internal combustion engines determined the nineteenth- and twentieth- century technological landscape. Against the background of the oil crisis and the long-term scarcity of natural gas, crude oil, and coal, new hopes have focused on fuel cell technology, which saw first early splendid applications during the space programs of the 1960s, in submarines since the 1980s, and in experimental zero-emission vehicles (ZEVs) since the 1990s. This article outlines (1) early insights about energy conversion: Grove's cell, direct conversion of coal and indirect fuel cells; (2) historical roots of alkaline fuel cells: the discovery of gas diffusion electrodes; low-pressure alkaline fuel cell conquer spacecrafts and submarines; (3) polymer electrolyte fuel cells: solid polymer technology, electric vehicles, direct methanol fuel-cell, stationary power systems and portable polymer electrolyte membrane fuel cell systems; (4) phosphoric acid fuel cell (PAFC): acid fuel cells, PAFC plants in Japan, gasoline fuel cells; and (5) high-temperature fuel cells: molten carbonate fuel cell and solid oxide fuel cell.

P. Kurzweil

2009-01-01T23:59:59.000Z

216

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents (OSTI)

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

McElroy, James F. (Hamilton, MA); Chludzinski, Paul J. (Swampscott, MA); Dantowitz, Philip (Peabody, MA)

1987-01-01T23:59:59.000Z

217

Fuel cell power supply with oxidant and fuel gas switching  

DOE Patents (OSTI)

This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

1987-04-14T23:59:59.000Z

218

Fuel Cell Buses | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Buses Fuel Cell Buses Download presentation slides from the DOE Fuel Cell Technologies Office webinar "Fuel Cell Buses" held on September 12, 2013. Fuel Cell Buses...

219

Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies to someone by E-mail Share Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Facebook Tweet about Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Twitter Bookmark Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Google Bookmark Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Delicious Rank Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on Digg Find More places to share Fuel Cell Technologies Office: Early Adoption of Fuel Cell Technologies on AddThis.com... Early Adoption of Fuel Cells Early Market Applications for Fuel Cells

220

DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2: Fuel Cell System Cost - 2013 DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System Cost - 2013 This program record from the U.S. Department of Energy's Fuel Cell...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

FUEL CELLS RALLY  

Science Journals Connector (OSTI)

FUEL CELLS RALLY ... No, this car has composite tanks capable of storing 8 kg of hydrogen. ... It's General Motors' Sequel, a fuel-cell concept car unveiled earlier this month at the North American International Auto Show in Detroit. ...

ALEXANDER H. TULLO

2005-01-31T23:59:59.000Z

222

fuel cells | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cells fuel cells Leads No leads are available at this time. The Molecular Bond: October 2014 The Molecular Bond newsletter banner October 2014 FROM THE DIRECTOR Read more...

223

Fuel cell arrangement  

DOE Patents (OSTI)

A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1987-05-12T23:59:59.000Z

224

Webinar: Fuel Cell Buses  

Energy.gov (U.S. Department of Energy (DOE))

Video recording and text version of the webinar titled, Fuel Cell Buses, originally presented on September 12, 2013.

225

Tubular solid oxide fuel cell current collector  

DOE Patents (OSTI)

An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

Bischoff, Brian L. (Knoxville, TN); Sutton, Theodore G. (Kingston, TN); Armstrong, Timothy R. (Clinton, TN)

2010-07-20T23:59:59.000Z

226

Microfluidic fuel cells.  

E-Print Network (OSTI)

??Microfluidic fuel cell architectures are presented in this thesis. This work represents the mechanical and microfluidic portion of a microfluidic biofuel cell project. While the (more)

Kjeang, Erik

2007-01-01T23:59:59.000Z

227

Webinar: Fuel Cell Mobile Lighting  

Energy.gov (U.S. Department of Energy (DOE))

Video recording of the Fuel Cell Technologies Office webinar, Fuel Cell Mobile Lighting, originally presented on November 13, 2012.

228

Highly Dispersed Alloy Cathode Catalyst for Durability  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on alloy cathode catalysts, was given by T. D. Jarvi of UTC Power at a February 2007 meeting on new fuel cell projects.

229

Electrochimica Acta 50 (2005) 53905398 Membraneless laminar flow-based micro fuel cells operating in alkaline,  

E-Print Network (OSTI)

Electrochimica Acta 50 (2005) 5390­5398 Membraneless laminar flow-based micro fuel cells operating) in membraneless, laminar flow-based micro fuel cells (LF-FCs) eliminates several PEM-related issues such as fuel the anode is in acidic media while the cathode is in alkali, or vice versa. Operating a fuel cell under

Kenis, Paul J. A.

230

Electrolysis cell for reprocessing plutonium reactor fuel  

DOE Patents (OSTI)

An electrolytic cell for refining a mixture of metals including spent fuel containing U and Pu contaminated with other metals is claimed. The cell includes a metallic pot containing a metallic pool as one anode at a lower level, a fused salt as the electrolyte at an intermediate level and a cathode and an anode basket in spaced-apart positions in the electrolyte with the cathode and anode being retractable to positions above the electrolyte during which spent fuel may be added to the anode basket. The anode basket is extendable into the lower pool to dissolve at least some metallic contaminants; the anode basket contains the spent fuel acting as a second anode when in the electrolyte.

Miller, W.E.; Steindler, M.J.; Burris, L.

1985-01-04T23:59:59.000Z

231

Fuel Cells & Alternative Fuels | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells & Alternative Fuels Fuel Cells & Alternative Fuels Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and...

232

Magnetron cathodes in plasma electrode pockels cells  

DOE Patents (OSTI)

Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

Rhodes, Mark A. (Pleasanton, CA)

1995-01-01T23:59:59.000Z

233

Fuel Cells Team  

NLE Websites -- All DOE Office Websites (Extended Search)

Judith Valerio at one of our 31 single-cell test stands Fuel Cell Team The FC team focus is R&D on polymer electrolyte membrane (PEM) fuel cells for commercial and military applications. Our program has had ongoing funding in the area of polymer electrolyte fuel cells since 1977 and has been responsible for enabling breakthroughs in the areas of thin film electrodes and air bleed for CO tolerance. For more information on the history of fuel cell research at Los Alamos, please click here. Fuel cells are an important enabling technology for the Hydrogen Economy and have the potential to revolutionize the way we power the nation and the world. The FC team is exploring the potential of fuel cells as energy-efficient, clean, and fuel-flexible alternatives that will

234

Space Resolved, in Operando X-ray Absorption Spectroscopy: Investigations on Both the Anode and Cathode in a Direct Methanol Fuel Cell  

Science Journals Connector (OSTI)

Volker Loos and Gregor Hoogers from Kompetenzzentrum Brennstoffzelle, Umwelt-Campus Birkenfeld, are acknowledged for the in situ cell design, and Klaus Wippermann, FZ Jlich, is thanked for helpful discussions. ...

Ditty Dixon; Anja Habereder; Maryam Farmand; Sebastian Kaserer; Christina Roth; David E. Ramaker

2012-02-27T23:59:59.000Z

235

Fuel cell generator  

DOE Patents (OSTI)

High temperature solid oxide electrolyte fuel cell generators which allow controlled leakage among plural chambers in a sealed housing. Depleted oxidant and fuel are directly reacted in one chamber to combust remaining fuel and preheat incoming reactants. The cells are preferably electrically arranged in a series-parallel configuration.

Isenberg, Arnold O. (Forest Hills, PA)

1983-01-01T23:59:59.000Z

236

Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Joint Fuel Cell Bus Joint Fuel Cell Bus Workshop to someone by E-mail Share Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Facebook Tweet about Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Twitter Bookmark Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Google Bookmark Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Delicious Rank Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on Digg Find More places to share Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings Webinars

237

Fuel Cell Technologies Office: Early Market Applications for Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies to someone by E-mail Share Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Facebook Tweet about Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Twitter Bookmark Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Google Bookmark Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Delicious Rank Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on Digg Find More places to share Fuel Cell Technologies Office: Early Market Applications for Fuel Cell Technologies on AddThis.com...

238

Fuel Cells publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science » Materials Science » Fuel Cells » Fuel Cells Publications Fuel Cells publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Melissa Fox Applied Energy Email Catherine Padro Sensors & Electorchemical Devices Email Fernando Garzon Sensors & Electorchemical Devices Email Piotr Zelenay Sensors & Electorchemical Devices Email Rod Borup Sensors & Electorchemical Devices Email Karen E. Kippen Chemistry Communications Email Like a battery, a fuel cell consists of two electrodes separated by an electrolyte-in polymer electrolyte fuel cells, the separator is made of a thin polymeric membrane. Unlike a battery, a fuel cell does not need recharging-it continues to produce electricity as long as fuel flows

239

Fuel Cells Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage DELIVERY FUEL CELLS STORAGE PRODUCTION TECHNOLOGY VALIDATION CODES & STANDARDS SYSTEMS INTEGRATION / ANALYSES SAFETY EDUCATION RESEARCH & DEVELOPMENT Economy Pat Davis 2 Fuel Cells Technical Goals & Objectives Goal : Develop and demonstrate fuel cell power system technologies for transportation, stationary, and portable applications. 3 Fuel Cells Technical Goals & Objectives Objectives * Develop a 60% efficient, durable, direct hydrogen fuel cell power system for transportation at a cost of $45/kW (including hydrogen storage) by 2010. * Develop a 45% efficient reformer-based fuel cell power system for transportation operating on clean hydrocarbon or alcohol based fuel that meets emissions standards, a start-up time of 30 seconds, and a projected manufactured cost of $45/kW by

240

Solid oxide fuel cell having monolithic core  

DOE Patents (OSTI)

A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

Ackerman, J.P.; Young, J.E.

1983-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

FUEL CELLS SOLID OXIDE FUEL CELLS | Systems  

Science Journals Connector (OSTI)

In this article, some basic arrangements of solid oxide fuel cell (SOFC) systems are described, starting with atmospheric systems using a catalytic burner or a thermal burner and anode gas recycling. For illustrating the potential electrical efficiency of SOFC systems, their combination with a gas turbine and also with a steam turbine (ST) are described. To be able to evaluate the potential of the different systems, first the essential efficiencies relevant to fuel cell systems are defined and then the basics of calculating energy balance are illustrated. Equations are given to describe, for example, the effect of fuel recycling on system fuel utilization and of internal reforming on the necessary air flow for cooling the stack. It is obvious that electrical efficiency depends strongly on cell voltage and fuel utilization. In the case of cells that operate with a high fuel utilization at cell voltages of 800mV, a net electrical efficiency above 55% can be achieved. The combination in a pressurized system with a gas turbine enables efficiencies of up to 70% and combining this system with an additional ST allows efficiencies of up to 75%. However, an investigation into the size of these \\{STs\\} shows that such combined systems make sense only above a gas input of 10MW.

L. Blum; E. Riensche

2009-01-01T23:59:59.000Z

242

Fuel Cells Fact Sheet | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells Fact Sheet Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen fuel cell technology. Fuel Cells More Documents & Publications...

243

NETL: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Coal and Power Systems Fuel Cells SECA Logo Welcome to NETL's Fuel Cells Webpage. In partnership with private industry, educational institutions and national laboratories, we are leading the research, development, and demonstration of high efficiency, fuel flexible solid oxide fuel cells (SOFCs) and coal-based SOFC power generation systems for stationary market large central power plants under the Solid State Energy Conversion Alliance (SECA). The SECA cost reduction goal is to have SOFC systems capable of being manufactured at $400 per kilowatt by 2010. Concurrently, the scale-up, aggregation, and integration of the technology will progress in parallel leading to prototype validation of megawatt (MW)-class fuel flexible products by 2012 and 2015. The SECA coal-based systems goal is the development of large

244

NREL: Learning - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Fuel cells and their ability to cleanly produce electricity from hydrogen and oxygen are what make hydrogen attractive as a "fuel" for transportation use particularly, but also as a general energy carrier for homes and other uses, and for storing and transporting otherwise intermittent renewable energy. Fuel cells function somewhat like a battery-with external fuel being supplied rather than stored electricity-to generate power by chemical reaction rather than combustion. Hydrogen fuel cells, for instance, feed hydrogen gas into an electrode that contains a catalyst, such as platinum, which helps to break up the hydrogen molecules into positively charged hydrogen ions and negatively charged electrons. The electrons flow from the electrode to a terminal that

245

Mechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Boris V. Merinov,*,  

E-Print Network (OSTI)

, at the cathode of a polymer electrolyte membrane fuel cell (PEMFC) is a critical issue for commercial applicationMechanism for Oxygen Reduction Reaction on Pt3Ni Alloy Fuel Cell Cathode Yao Sha, Ted H. Yu, Boris of this type of fuel cells.1-4 The best current catalysts are Pt and Pt-based binary alloys, such as Pt3Ni.5

Goddard III, William A.

246

Reforming of fuel inside fuel cell generator  

DOE Patents (OSTI)

Disclosed is an improved method of reforming a gaseous reformable fuel within a solid oxide fuel cell generator, wherein the solid oxide fuel cell generator has a plurality of individual fuel cells in a refractory container, the fuel cells generating a partially spent fuel stream and a partially spent oxidant stream. The partially spent fuel stream is divided into two streams, spent fuel stream I and spent fuel stream II. Spent fuel stream I is burned with the partially spent oxidant stream inside the refractory container to produce an exhaust stream. The exhaust stream is divided into two streams, exhaust stream I and exhaust stream II, and exhaust stream I is vented. Exhaust stream II is mixed with spent fuel stream II to form a recycle stream. The recycle stream is mixed with the gaseous reformable fuel within the refractory container to form a fuel stream which is supplied to the fuel cells. Also disclosed is an improved apparatus which permits the reforming of a reformable gaseous fuel within such a solid oxide fuel cell generator. The apparatus comprises a mixing chamber within the refractory container, means for diverting a portion of the partially spent fuel stream to the mixing chamber, means for diverting a portion of exhaust gas to the mixing chamber where it is mixed with the portion of the partially spent fuel stream to form a recycle stream, means for injecting the reformable gaseous fuel into the recycle stream, and means for circulating the recycle stream back to the fuel cells.

Grimble, Ralph E. (Finleyville, PA)

1988-01-01T23:59:59.000Z

247

Indirect-fired gas turbine dual fuel cell power cycle  

DOE Patents (OSTI)

A fuel cell and gas turbine combined cycle system which includes dual fuel cell cycles combined with a gas turbine cycle wherein a solid oxide fuel cell cycle operated at a pressure of between 6 to 15 atms tops the turbine cycle and is used to produce CO.sub.2 for a molten carbonate fuel cell cycle which bottoms the turbine and is operated at essentially atmospheric pressure. A high pressure combustor is used to combust the excess fuel from the topping fuel cell cycle to further heat the pressurized gas driving the turbine. A low pressure combustor is used to combust the excess fuel from the bottoming fuel cell to reheat the gas stream passing out of the turbine which is used to preheat the pressurized air stream entering the topping fuel cell before passing into the bottoming fuel cell cathode. The CO.sub.2 generated in the solid oxide fuel cell cycle cascades through the system to the molten carbonate fuel cell cycle cathode.

Micheli, Paul L. (Sacramento, CA); Williams, Mark C. (Morgantown, WV); Sudhoff, Frederick A. (Morgantown, WV)

1996-01-01T23:59:59.000Z

248

Distributed Energy Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Fuel Cells Energy Fuel Cells DOE Hydrogen DOE Hydrogen and and Fuel Cells Fuel Cells Coordination Meeting Fuel Cell Coordination Meeting June 2-3, 2003 Electricity Users Kathi Epping Kathi Epping Objectives & Barriers Distributed Energy OBJECTIVES * Develop a distributed generation PEM fuel cell system operating on natural gas or propane that achieves 40% electrical efficiency and 40,000 hours durability at $400-750/kW by 2010. BARRIERS * Durability * Heat Utilization * Power Electronics * Start-Up Time Targets and Status Integrated Stationary PEMFC Power Systems Operating on Natural Gas or Propane Containing 6 ppm Sulfur 40,000 30,000 15,000 Hours Durability 750 1,250 2,500 $/kWe Cost 40 32 30 % Electrical Efficiency Large (50-250 kW) Systems 40,000 30,000 >6,000 Hours Durability 1,000 1,500 3,000

249

Microcomposite Fuel Cell Membranes  

Energy.gov (U.S. Department of Energy (DOE))

Summary of microcomposite fuel cell membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

250

Fuel Cell Financing Options  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Financing Fuel Cell Installations, August 30, 2011.

251

Fuel Cell Case Study  

Energy.gov (U.S. Department of Energy (DOE))

Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Fuel Cells for Supermarkets, April 4, 2011.

252

Hydrogen Fuel Cells  

Fuel Cell Technologies Publication and Product Library (EERE)

The fuel cell an energy conversion device that can efficiently capture and use the power of hydrogen is the key to making it happen.

253

Method of fabricating a monolithic solid oxide fuel cell  

DOE Patents (OSTI)

In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array.

Minh, Nguyen Q. (Fountain Valley, CA); Horne, Craig R. (Redondo Beach, CA)

1994-01-01T23:59:59.000Z

254

Fuel Cell Development Status  

NLE Websites -- All DOE Office Websites (Extended Search)

Development Status Michael Short Systems Engineering Manager United Technologies Corporation Research Center Hamilton Sundstrand UTC Power UTC Fire & Security Fortune 50 corporation $52.9B in annual sales in 2009 ~60% of Sales are in building technologies Transportation Stationary Fuel Cells Space & Defense * Fuel cell technology leader since 1958 * ~ 550 employees * 768+ Active U.S. patents, more than 300 additional U.S. patents pending * Global leader in efficient, reliable, and sustainable fuel cell solutions UTC Power About Us PureCell ® Model 400 Solution Process Overview Power Conditioner Converts DC power to high-quality AC power 3 Fuel Cell Stack Generates DC power from hydrogen and air 2 Fuel Processor Converts natural gas fuel to hydrogen

255

Fuel Cell Demonstration Program  

SciTech Connect

In an effort to promote clean energy projects and aid in the commercialization of new fuel cell technologies the Long Island Power Authority (LIPA) initiated a Fuel Cell Demonstration Program in 1999 with six month deployments of Proton Exchange Membrane (PEM) non-commercial Beta model systems at partnering sites throughout Long Island. These projects facilitated significant developments in the technology, providing operating experience that allowed the manufacturer to produce fuel cells that were half the size of the Beta units and suitable for outdoor installations. In 2001, LIPA embarked on a large-scale effort to identify and develop measures that could improve the reliability and performance of future fuel cell technologies for electric utility applications and the concept to establish a fuel cell farm (Farm) of 75 units was developed. By the end of October of 2001, 75 Lorax 2.0 fuel cells had been installed at the West Babylon substation on Long Island, making it the first fuel cell demonstration of its kind and size anywhere in the world at the time. Designed to help LIPA study the feasibility of using fuel cells to operate in parallel with LIPA's electric grid system, the Farm operated 120 fuel cells over its lifetime of over 3 years including 3 generations of Plug Power fuel cells (Lorax 2.0, Lorax 3.0, Lorax 4.5). Of these 120 fuel cells, 20 Lorax 3.0 units operated under this Award from June 2002 to September 2004. In parallel with the operation of the Farm, LIPA recruited government and commercial/industrial customers to demonstrate fuel cells as on-site distributed generation. From December 2002 to February 2005, 17 fuel cells were tested and monitored at various customer sites throughout Long Island. The 37 fuel cells operated under this Award produced a total of 712,635 kWh. As fuel cell technology became more mature, performance improvements included a 1% increase in system efficiency. Including equipment, design, fuel, maintenance, installation, and decommissioning the total project budget was approximately $3.7 million.

Gerald Brun

2006-09-15T23:59:59.000Z

256

Serially connected solid oxide fuel cells having monolithic cores  

DOE Patents (OSTI)

A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

Herceg, Joseph E. (Naperville, IL)

1987-01-01T23:59:59.000Z

257

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

Di Croce, A.M.; Draper, R.

1993-11-02T23:59:59.000Z

258

Miniature ceramic fuel cell  

DOE Patents (OSTI)

A miniature power source assembly capable of providing portable electricity is provided. A preferred embodiment of the power source assembly employing a fuel tank, fuel pump and control, air pump, heat management system, power chamber, power conditioning and power storage. The power chamber utilizes a ceramic fuel cell to produce the electricity. Incoming hydro carbon fuel is automatically reformed within the power chamber. Electrochemical combustion of hydrogen then produces electricity.

Lessing, Paul A. (Idaho Falls, ID); Zuppero, Anthony C. (Idaho Falls, ID)

1997-06-24T23:59:59.000Z

259

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe Program Presentations

260

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

August 2013 to someone by E-mail August 2013 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

October 2012 to someone by E-mail October 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: October 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications

262

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

April 2012 to someone by E-mail April 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: April 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives

263

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

3 to someone by E-mail 3 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: May 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe Program Presentations

264

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: June 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe

265

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

September/October 2013 to someone by E-mail September/October 2013 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September/October 2013 on AddThis.com... Publications

266

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

August 2012 to someone by E-mail August 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: August 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

267

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

2 to someone by E-mail 2 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: March 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Archives Subscribe

268

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

3 to someone by E-mail 3 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: February 2013 on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter

269

Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter:  

NLE Websites -- All DOE Office Websites (Extended Search)

September 2012 to someone by E-mail September 2012 to someone by E-mail Share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Facebook Tweet about Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Twitter Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Google Bookmark Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Delicious Rank Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on Digg Find More places to share Fuel Cell Technologies Office: Fuel Cell Technologies Office Newsletter: September 2012 on AddThis.com... Publications Program Publications Technical Publications Educational Publications

270

Energy 101: Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cells Energy 101: Fuel Cells Addthis Description Learn everything you need to know about fuel cells. Topic Hydrogen & Fuel Cells...

271

Types of Fuel Cells | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cells Current Technology Types of Fuel Cells Types of Fuel Cells Fuel cells are classified primarily by the kind of electrolyte they employ. This classification...

272

Fuel Cell Animation | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Animation Fuel Cell Animation This fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts. Hydrogen...

273

Hydrogen and Fuel Cell Activities  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

electrolysis, using renewable electricity * Conventional fuels - including natural gas, propane, diesel 3 | Fuel Cell Technologies Program Source: US DOE 852011...

274

High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes  

E-Print Network (OSTI)

1 High Power Impulse Magnetron Sputtering deposition of Pt inside fuel cell electrodes S Cuynet1 as a cathode of a proton exchange membrane fuel cell. An increase of 80 % at 0.65 V of the PEMFC power density) 272001" #12;2 Proton exchange membrane fuel cells (PEMFC) have the potential to provide

Paris-Sud XI, Université de

275

Modeling of the mixed potential in hydrogen peroxide-based fuel cells  

E-Print Network (OSTI)

Modeling of the mixed potential in hydrogen peroxide-based fuel cells L. An, T.S. Zhao*, Z.H. Chai 28 February 2014 Available online 31 March 2014 Keywords: Fuel cell Hydrogen peroxide Mixed potential (HPOR) at the cathode of hydrogen peroxide-based fuel cells. The complicated physicochemical processes

Zhao, Tianshou

276

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational Study  

E-Print Network (OSTI)

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational be used to make an efficient and relatively inexpensive graphene-based material for hydrogen fuel cells fuel cells for oxygen reduction at the cathode. In an attempt to find a cheap yet efficient catalyst

Krasheninnikov, Arkady V.

277

Fuel Cell Animation- Fuel Cell Stack (Text Version)  

Energy.gov (U.S. Department of Energy (DOE))

This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

278

NREL: Hydrogen and Fuel Cells Research - Fuel Cell Electric Vehicle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Electric Vehicle Evaluations NREL's technology validation team analyzes hydrogen fuel cell electric vehicles (FCEVs) operating in a real-world setting to identify the...

279

Fuel Cell Animation- Fuel Cell Components (Text Version)  

Energy.gov (U.S. Department of Energy (DOE))

This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

280

DOE Fuel Cell Technologies Office Record 14012: Fuel Cell System...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Technologies Office Record Record : 14012 Date: June 12, 2014 Title: Fuel Cell System Cost - 2013 Update to: Record 12020 Originator: Jacob Spendelow and Jason...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Understanding the degradation of Congo red and bacterial diversity in an aircathode microbial fuel cell being evaluated for simultaneous azo dye removal from wastewater and bioelectricity generation  

Science Journals Connector (OSTI)

We investigated the mechanism of Congo red degradation and bacterial diversity in a single-chambered microbial fuel cell (MFC) incorporating a microfiltration membrane and ... a mixture of Congo red and glucose a...

Jian Sun; Youming Li; Yongyou Hu; Bin Hou

2013-04-01T23:59:59.000Z

282

An advanced fuel cell simulator  

E-Print Network (OSTI)

of Fuel Cells ...................... 4 D. Fuel Cell Power Plant ..................... 4 E. Challenges in Fuel Cell Development ............ 5 F. Previous Work ......................... 6 G. Solar Array Simulators .................... 8 H. Battery... ............................. 54 28 Under-voltage Fault ........................... 55 1 CHAPTER I INTRODUCTION The depleting fossil fuel resources and increasing pollution are leading to the research and development of alternate energy generation techniques like fuel cells...

Acharya, Prabha Ramchandra

2005-11-01T23:59:59.000Z

283

Transitioning from Fuel Cells to Redox Flow Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Transitioning From Fuel Cells to Redox Transitioning From Fuel Cells to Redox Flow Cells T. Zawodzinski and Matt Mench University of Tennessee and ORNL Managed by UT-Battelle for the Department of Energy 2 Acknowledgments $$ DOE-OE EPRI GCEP NSF EPSCOR (TN SCORE) UTK Governor's Chair Fund Partner in Crime Matt Mench Managed by UT-Battelle for the Department of Energy 'Peeling the Onion' Personalized History of PEM Fuel Cells We May Recapitulate This for RFBs Catalysis Test System * Small Single Cell * Large Single Cell * Stack * System Layers of the Onion Hot Topic du Jour * Water Management, Membranes * Late '80's, early '90's * Reformate Tolerance, DMFC's * Mid '90's * High Temp Membranes * Late '90's * Durability * Early '00's Modeling * Membrane/ Water * Cathode * Impedance

284

Direct methanol fuel cell and system  

DOE Patents (OSTI)

A fuel cell having an anode and a cathode and a polymer electrolyte membrane located between anode and cathode gas diffusion backings uses a methanol vapor fuel supply. A permeable polymer electrolyte membrane having a permeability effective to sustain a carbon dioxide flux equivalent to at least 10 mA/cm.sup.2 provides for removal of carbon dioxide produced at the anode by reaction of methanol with water. Another aspect of the present invention includes a superabsorpent polymer material placed in proximity to the anode gas diffusion backing to hold liquid methanol or liquid methanol solution without wetting the anode gas diffusion backing so that methanol vapor from the liquid methanol or liquid methanol-water solution is supplied to the membrane.

Wilson, Mahlon S. (Los Alamos, NM)

2004-10-26T23:59:59.000Z

285

Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructu...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology Showcase Texas Hydrogen Highway - Fuel Cell Hybrid Bus and Fueling Infrastructure Technology...

286

Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Light Duty Fuel Cell Electric Vehicle Hydrogen Fueling Protocol Download the webinar slides from the U.S. Department...

287

Batteries and Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Collage of electric cars, plug, battery research lab Collage of electric cars, plug, battery research lab Batteries and Fuel Cells EETD researchers study the basic science and development of advanced batteries and fuel cells for transportation, electric grid storage, and other stationary applications. This research is aimed at developing more environmentally friendly technologies for generating and storing energy, including better batteries and fuel cells. Li-Ion and Other Advanced Battery Technologies Research conducted here on battery technology is aimed at developing low-cost rechargeable advanced electrochemical batteries for both automotive and stationary applications. The goal of fuel cell research is to provide the technologies for the successful commercialization of polymer-electrolyte and solid oxide fuel

288

Fuel Cell Technologies Office: Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office HOME ABOUT PROGRAM AREAS INFORMATION RESOURCES FINANCIAL OPPORTUNITIES TECHNOLOGIES MARKET TRANSFORMATION NEWS EVENTS EERE Fuel Cell Technologies...

289

Module 5: Fuel Cell Systems  

Energy.gov (U.S. Department of Energy (DOE))

This course covers the systems required to operate a fuel cell engine, the components and functionality of each fuel cell system

290

Fuel Cell Technologies Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

4/3/2012 4/3/2012 eere.energy.gov Fuel Cell Technologies Overview Flow Cell Workshop Washington, DC Dr. Sunita Satyapal & Dr. Dimitrios Papageorgopoulos U.S. Department of Energy Fuel Cell Technologies Program 3/7/2011 Flow Cells for Energy Storage Workshop Purpose To understand the applied research and development needs and the grand challenges for the use of flow cells as energy-storage devices. Objectives 1. Understand the needs for applied research from stakeholders. 2. Gather input for future development of roadmaps and technical targets for flow cells for various applications. 3. Identify grand challenges and prioritize R&D needs. Flow cells combine the unique advantages of batteries and fuel cells and can offer benefits for multiple energy storage applications.

291

Double-band Electrode Channel Flow DEMS Cell > Research Highlights...  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance Alkaline Fuel Cell Membranes Improving Fuel Cell...

292

Factors affecting the discharge lifetime of lithium-molten nitrate thermal battery cells using soluble cathode materials  

Science Journals Connector (OSTI)

The use of soluble cathode materials in molten nitrate electrolyte thermal battery cells presents several problems related to cathode...? rich separator layer.

G. E. McManis; A. N. Fletcher; M. H. Miles

1986-09-01T23:59:59.000Z

293

What's Up With Fuel Cells? | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Up With Fuel Cells? Up With Fuel Cells? What's Up With Fuel Cells? June 8, 2010 - 7:30am Addthis Sean Large Intern with the Office of Energy Efficiency and Renewable Energy We hear a lot about renewables like wind and solar these days, but what's the deal with fuel cells and is there a future in them? The truth is, fuel cells have been around for some time now; the idea originated in the 1840's. Though fuel cells come in a variety of forms, they all work in the same general manner: three sandwiched segments - the anode, the electrolyte and the cathode. At each of these segments two different chemical reactions occur. The net result of the two reactions is that fuel is consumed, and an electrical current is created, which can be used to power electrical devices, normally referred to as the load. The only emissions are water or

294

Fuel cells: A handbook (Revision 3)  

SciTech Connect

Fuel cells are electrochemical devices that convert the chemical energy of reaction directly into electrical energy. In a typical fuel cell, gaseous fuels are fed continuously to the anode (negative electrode) compartment and an oxidant (i.e., oxygen from air) is fed continuously to the cathode (positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. A fuel cell, although having similar components and several characteristics, differs from a typical battery in several respects. The battery is an energy storage device, that is, the maximum energy that is available is determined by the amount of chemical reactant stored within the battery itself. Thus, the battery will cease to produce electrical energy when the chemical reactants are consumed (i.e., discharged). In a secondary battery, the reactants are regenerated by recharging, which involves putting energy into the battery from an external source. The fuel cell, on the other hand, is an energy conversion device which theoretically has the capability of producing electrical energy for as long as the fuel and oxidant are supplied to the electrodes. In reality, degradation or malfunction of components limits the practical operating life of fuel cells.

Hirschenhofer, J.H.; Stauffer, D.B.; Engleman, R.R.

1994-01-01T23:59:59.000Z

295

Fuel cell generator energy dissipator  

DOE Patents (OSTI)

An apparatus and method are disclosed for eliminating the chemical energy of fuel remaining in a fuel cell generator when the electrical power output of the fuel cell generator is terminated. During a generator shut down condition, electrically resistive elements are automatically connected across the fuel cell generator terminals in order to draw current, thereby depleting the fuel

Veyo, Stephen Emery (Murrysville, PA); Dederer, Jeffrey Todd (Valencia, PA); Gordon, John Thomas (Ambridge, PA); Shockling, Larry Anthony (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

296

Special issue to ICMAT 2009, Symposium F: nanostructured materials for electrochemical energy systems: lithium batteries, supercapacitors and fuel cells, June 28-July 3, 2009, Singapore  

Science Journals Connector (OSTI)

The Symposium F on Nanostructured Materials for Electrochemical Energy Systems: Lithium Batteries, Supercapacitors and Fuel Cells provided an excellent opportunity for interdisciplinary ... (cathodes and anodes...

Palani Balaya; San Ping Jiang; Atsuo Yamada

2010-10-01T23:59:59.000Z

297

DOE Fuel Cell Technologies Program Record, Record # 11003, Fuel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Program Record, Record 11003, Fuel Cell Stack Durability DOE Fuel Cell Technologies Program Record, Record 11003, Fuel Cell Stack Durability Dated May 3, 2012, this program...

298

Method for producing electricity from a fuel cell having solid-oxide ionic electrolyte  

DOE Patents (OSTI)

Stabilized quadrivalent cation oxide electrolytes are employed in fuel cells at elevated temperatures with a carbon and/or hydrogen containing fuel anode and an oxygen cathode. The fuel cell is operated at elevated temperatures with conductive metallic coatings as electrodes and desirably having the electrolyte surface blackened. Of particular interest as the quadrivalent oxide is zirconia.

Mason, David M. (Los Altos, CA)

1984-01-01T23:59:59.000Z

299

Fuel Cell Technologies Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

States Energy Advisory Board (STEAB) States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3/14/2012 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov * Introduction - Technology and Market Overview * DOE Program Overview - Mission & Structure - R&D Progress - Demonstration & Deployments * State Activities - Examples of potential opportunities Outline 3 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov Fuel cells - convert chemical energy directly into electrical energy, bypassing inefficiencies associated with thermal energy conversion. Available energy is equal to the Gibbs free energy. Combustion Engines - convert chemical energy into thermal energy and

300

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Methanol adsorbates on the DMFC cathode and their effect on the cell performance  

E-Print Network (OSTI)

Methanol adsorbates on the DMFC cathode and their effect on the cell performance J. Prabhuram, T performance was due to the permeated methanol adsorbates on platinum sites of the cathode, which impede utilized to get rid of the methanol adsorbates from the cathode electrochemically by sweeping from 0 to 1

Zhao, Tianshou

302

Compliant fuel cell system  

DOE Patents (OSTI)

A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY)

2009-12-15T23:59:59.000Z

303

Development of High Energy Cathode Materials | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials Development of High Energy Cathode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

304

Process for Low Cost Domestic Production of LIB Cathode Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Process for Low Cost Domestic Production of LIB Cathode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer...

305

Fuel Cell Power Plants Renewable and Waste Fuels | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Plants Renewable and Waste Fuels Fuel Cell Power Plants Renewable and Waste Fuels Presentation by Frank Wolak, Fuel Cell Energy, at the Waste-to-Energy using Fuel Cells Workshop...

306

Hydrogen & Fuel Cells Program Overview  

E-Print Network (OSTI)

Hydrogen & Fuel Cells Program Overview Dr. Sunita Satyapal Program Manager Hydrogen and Fuel Cells Program U.S. Department of Energy Hydrogen + Fuel Cells 2011 International Conference and Exhibition Vancouver, Canada May 17, 2011 #12;Enable widespread commercialization of hydrogen and fuel cell

307

Breakthrough Vehicle Development - Fuel Cells  

Fuel Cell Technologies Publication and Product Library (EERE)

Document describing research and development program for fuel cell power systems for transportation applications.

308

Fuel Cell Technologies Office: Glossary  

NLE Websites -- All DOE Office Websites (Extended Search)

Glossary to someone by Glossary to someone by E-mail Share Fuel Cell Technologies Office: Glossary on Facebook Tweet about Fuel Cell Technologies Office: Glossary on Twitter Bookmark Fuel Cell Technologies Office: Glossary on Google Bookmark Fuel Cell Technologies Office: Glossary on Delicious Rank Fuel Cell Technologies Office: Glossary on Digg Find More places to share Fuel Cell Technologies Office: Glossary on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Webinars Data Records Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Glossary

309

Fuel Cell Technologies Office: Presentations  

NLE Websites -- All DOE Office Websites (Extended Search)

Presentations to Presentations to someone by E-mail Share Fuel Cell Technologies Office: Presentations on Facebook Tweet about Fuel Cell Technologies Office: Presentations on Twitter Bookmark Fuel Cell Technologies Office: Presentations on Google Bookmark Fuel Cell Technologies Office: Presentations on Delicious Rank Fuel Cell Technologies Office: Presentations on Digg Find More places to share Fuel Cell Technologies Office: Presentations on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings Annual Merit Review Proceedings Workshop & Meeting Proceedings Webinars Data Records Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells

310

Fuel Cell Technologies Office: Durability Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

Durability Working Group Durability Working Group The Durability Working Group meets twice per year to exchange information, create synergies, and collaboratively develop both an understanding of and tools for studying degradation mechanisms of polymer electrolyte fuel cell stacks. Its members include principle investigators and supporting personnel from U.S. Department of Energy (DOE)-funded durability projects. More information on DOE durability activities can be found in the Multi-Year Research, Development, and Demonstration Plan. Description Technical Targets Meetings Contacts Description DOE durability targets for stationary and transportation fuel cells are 40,000 hours and 5,000 hours, respectively, under realistic operating conditions. In the most demanding applications, realistic operating conditions include impurities in the fuel and air, starting and stopping, freezing and thawing, and humidity and load cycles that result in stresses on the chemical and mechanical stability of the fuel cell materials, components, and interfaces. Degradation-exacerbating conditions resulting from cyclic operation include hydrogen starvation, differential pressure imbalance, oxidation-reduction cycling, and oxygen ingress to the anode, resulting in high cathode potentials. Significant progress has been made in determining the degradation mechanisms of fuel cell components and developing improved materials. However, as stated in the 2008 DOE Fuel Cell Solicitation, there is a need for further research and development in the following areas:

311

DOE Hydrogen and Fuel Cells Program: 2004 Annual Progress Report - Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Printable Version 2004 Annual Progress Report IV. Fuel Cells Each individual technical report is available as an individual Adobe Acrobat PDF for easier use. Download Adobe Reader. Fuel Cells Sub-Program Review, Patrick Davis, DOE (PDF 265 KB) A. MEAs and Catalysts Integrated Manufacturing for Advanced Membrane Electrode Assemblies, Emory DeCastro, De Nora (PDF 486 KB) Development of High-Temperature Membranes and Improved Cathode Catalysts Jeremy Meyers, UTC (PDF 595 KB) Advanced MEAs for Enhanced Operating Conditions, Amenable to High Volume Manufacture, Mark Debe, 3M (PDF 372 KB) Back to Top B. Membranes and MEAs High Temperature Polymer Membranes for Fuel Cells, Tom Zawodzinski, Case West Res. University (PDF 356 KB) Electrodes for Hydrogen-Air PEM Fuel Cells, Francisco Uribe, LANL

312

DOE Hydrogen and Fuel Cells Program: 2005 Annual Progress Report - Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Fuel Cells Printable Version 2005 Annual Progress Report VII. Fuel Cells This section of the 2005 Progress Report for the DOE Hydrogen Program focuses on fuel cells. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Fuel Cells Sub-program Overview, Valri Lightner, Department of Energy (PDF 198 KB) A. Membrane Electrode Assemblies (MEA) Integrated Manufacturing for Advanced Membrane Electrode Assemblies, Emory S. De Castro, De Nora N.A., E-TEK Division (PDF 292 KB) Advanced MEAs for Enhanced Operating Conditions, Mark K. Debe, 3M Company (PDF 459 KB) Development of High-temperature Membranes and Improved Cathode Catalysts, Lesia Protsailo, UTC Fuel Cells (PDF 642 KB) Electrocatalyst Supports and Electrode Structures, Eric Brosha, Los

313

Power Management for Alleviation of the Impact on PEM Fuel Cell due to Load Fluctuation  

Science Journals Connector (OSTI)

Transient impact on fuel cell system due to stack current fluctuation sometimes causes severe degradation of some performances such as voltage variation, oxygen starvation, anode/cathode pressure disturbance, membrane dryout and voltage reversal. As ...

Guidong Liu; Wensheng Yu; Zhishou Tu

2006-10-01T23:59:59.000Z

314

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

& & Renewable Energy Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities Pete Devlin Fuel Cell Technologies Program United States Department of Energy Federal Utility Partnership Working Group April 14 th , 2010 2 * DOE Fuel Cell Market Transformation Overview * Overview of CHP Concept * Stationary Fuel Cells for CHP Applications * Partnering and Financing (Sam Logan) * Example Project Outline 3 Fuel Cells: Addressing Energy Challenges Energy Efficiency and Resource Diversity  Fuel cells offer a highly efficient way to use diverse fuels and energy sources. Greenhouse Gas Emissions and Air Pollution:  Fuel cells can be powered by emissions-free fuels that are produced from clean, domestic resources. Stationary Power (including CHP & backup power)

315

High Performance Catalytic Heat Exchanger for SOFC Systems - FuelCell Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Heat Catalytic Heat Exchanger for SOFC Systems-FuelCell Energy Background In a typical solid oxide fuel cell (SOFC) power generation system, hot (~900 °C) effluent gas from a catalytic combustor serves as the heat source within a high-temperature heat exchanger, preheating incoming fresh air for the SOFC's cathode. The catalytic combustor and the cathode air heat exchanger together represent the largest opportunity for cost

316

Analysis of Molten Carbonate Fuel Cell Performance Using a Three-Phase Homogeneous Model  

E-Print Network (OSTI)

temperatures, nickel oxide dissolves in the melt. This slow loss of active material contributes to an increase as compared to nickel oxide. The search for alternate cathode materials could be simplified through the use-phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell MCFC cathode

Popov, Branko N.

317

Development of Thin Film Membrane Assemblies with Novel Nanostructured Electrocatalyst for Next Generation Fuel Cells  

E-Print Network (OSTI)

Development of Thin Film Membrane Assemblies with Novel Nanostructured Electrocatalyst for Next of the efficiency loss (80%) in a fuel cell arises due to the cathode. Oxygen reduction at the cathode requires is to synthesize nanosized Pt-X electrocatalysts for oxygen reduction through pulse and electroless deposition

Popov, Branko N.

318

Handbook of fuel cell performance  

SciTech Connect

The intent of this document is to provide a description of fuel cells, their performances and operating conditions, and the relationship between fuel processors and fuel cells. This information will enable fuel cell engineers to know which fuel processing schemes are most compatible with which fuel cells and to predict the performance of a fuel cell integrated with any fuel processor. The data and estimates presented are for the phosphoric acid and molten carbonate fuel cells because they are closer to commercialization than other types of fuel cells. Performance of the cells is shown as a function of operating temperature, pressure, fuel conversion (utilization), and oxidant utilization. The effect of oxidant composition (for example, air versus O/sub 2/) as well as fuel composition is examined because fuels provided by some of the more advanced fuel processing schemes such as coal conversion will contain varying amounts of H/sub 2/, CO, CO/sub 2/, CH/sub 4/, H/sub 2/O, and sulfur and nitrogen compounds. A brief description of fuel cells and their application to industrial, commercial, and residential power generation is given. The electrochemical aspects of fuel cells are reviewed. The phosphoric acid fuel cell is discussed, including how it is affected by operating conditions; and the molten carbonate fuel cell is discussed. The equations developed will help systems engineers to evaluate the application of the phosphoric acid and molten carbonate fuel cells to commercial, utility, and industrial power generation and waste heat utilization. A detailed discussion of fuel cell efficiency, and examples of fuel cell systems are given.

Benjamin, T.G.; Camara, E.H.; Marianowski, L.G.

1980-05-01T23:59:59.000Z

319

Critical Review Microbial Fuel Cells: Methodology and Technology  

E-Print Network (OSTI)

T E , @ A N D K O R N E E L R A B A E Y @ Hydrogen Energy Center, 212 Sackett Building, Penn State Microbial fuel cell (MFC) research is a rapidly evolving field that lacks established terminology that reach the cathode combine with protons that diffuse from the anode through a separator and oxygen

320

Breaking the Fuel Cell Cost Barrier AMFC Workshop  

E-Print Network (OSTI)

tech materials BOM-based cost barriers ­ 90% of stack cost Cost volatility - Platinum $500/Oz - $2 * present CCM has 265 cm2 active area Work initiated on scalable AMFC stack design & development Lab status #12;Processes in PEM and AEM Membrane Fuel Cells Anode: H2 +2OH- = 2H2O +2e Cathode: 2e + 0.5O2

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Fuel processor for fuel cell power system  

DOE Patents (OSTI)

A catalytic organic fuel processing apparatus, which can be used in a fuel cell power system, contains within a housing a catalyst chamber, a variable speed fan, and a combustion chamber. Vaporized organic fuel is circulated by the fan past the combustion chamber with which it is in indirect heat exchange relationship. The heated vaporized organic fuel enters a catalyst bed where it is converted into a desired product such as hydrogen needed to power the fuel cell. During periods of high demand, air is injected upstream of the combustion chamber and organic fuel injection means to burn with some of the organic fuel on the outside of the combustion chamber, and thus be in direct heat exchange relation with the organic fuel going into the catalyst bed.

Vanderborgh, Nicholas E. (Los Alamos, NM); Springer, Thomas E. (Los Alamos, NM); Huff, James R. (Los Alamos, NM)

1987-01-01T23:59:59.000Z

322

Hydrogen Fueling for Current and Anticipated Fuel Cell Electric...  

Energy Savers (EERE)

for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Hydrogen Fueling for Current and Anticipated Fuel Cell Electric Vehicles (FCEVs) Download presentation slides from...

323

LOW-TEMPERATURE, ANODE-SUPPORTED HIGH POWER DENSITY SOLID OXIDE FUEL CELLS WITH NANOSTRUCTURED ELECTRODES  

SciTech Connect

A simple, approximate analysis of the effect of differing cathode and anode areas on the measurement of cell performance on anode-supported solid oxide fuel cells, wherein the cathode area is smaller than the anode area, is presented. It is shown that the effect of cathode area on cathode polarization, on electrolyte contribution, and on anode resistance, as normalized on the basis of the cathode area, is negligible. There is a small but measurable effect on anode polarization, which results from concentration polarization. Effectively, it is the result of a greater amount of fuel transported to the anode/electrolyte interface in cases wherein the anode area is larger than the cathode area. Experiments were performed on cells made with differing cathode areas and geometries. Cathodic and anodic overpotentials measured using reference electrodes, and the measured ohmic area specific resistances by current interruption, were in good agreement with expectations based on the analysis presented. At 800 C, the maximum power density measured with a cathode area of {approx}1.1 cm{sup 2} was {approx}1.65 W/cm{sup 2} compared to {approx}1.45 W/cm{sup 2} for cathode area of {approx}2 cm{sup 2}, for anode thickness of {approx}1.3 mm, with hydrogen as the fuel and air as the oxidant. At 750 C, the measured maximum power densities were {approx}1.3 W/cm{sup 2} for the cell with cathode area {approx}1.1 cm{sup 2}, and {approx}1.25 W/cm{sup 2} for the cell with cathode area {approx}2 cm{sup 2}.

Anil V. Virkar

2001-06-21T23:59:59.000Z

324

Simulated coal-gas-fueled molten carbonate fuel cell development program  

SciTech Connect

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

325

2011 DOE Hydrogen and Fuel Cells Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

85 85 FY 2011 Annual Progress Report DOE Hydrogen and Fuel Cells Program 3M Company V.B.1 Effect of System Contaminants on PEMFC Performance and Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . 640 V.C.1 Membranes and MEAs for Dry, Hot Operating Conditions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 662 V.C.6 Novel Approaches to Immobilized Heteropoly Acid (HPA) Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 685 V.D.1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 699 V.D.3 Durable Catalysts for Fuel Cell Protection During Transient Conditions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .714

326

Rational Design of Competitive Electrocatalysts for Hydrogen Fuel Cells  

Science Journals Connector (OSTI)

Rational Design of Competitive Electrocatalysts for Hydrogen Fuel Cells ... The large-scale application of one of the most promising clean and renewable sources of energy, hydrogen fuel cells, still awaits efficient and cost-effective electrocatalysts for the oxygen reduction reaction (ORR) occurring on the cathode. ... Among its most challenging and, at the same time, promising aims is the efficient electrocatalysis of reactions in proton exchange membrane fuel cells (PEMFCs) because these devices are clean means for conversion of the chemical energy to electric power. ...

Sergey Stolbov; Marisol Alcntara Ortigoza

2012-01-24T23:59:59.000Z

327

Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery and Delivery and Fueling (Text Alternative Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Google Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Delicious Rank Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on AddThis.com... Publications Program Publications

328

Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure  

NLE Websites -- All DOE Office Websites (Extended Search)

International Hydrogen International Hydrogen Fuel and Pressure Vessel Forum to someone by E-mail Share Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Facebook Tweet about Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Twitter Bookmark Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Google Bookmark Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Delicious Rank Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on Digg Find More places to share Fuel Cell Technologies Office: International Hydrogen Fuel and Pressure Vessel Forum on AddThis.com... Publications Program Publications Technical Publications

329

Fuel Cells at NASCAR | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells at NASCAR Fuel Cells at NASCAR Download presentation slides from the DOE Fuel Cell Technologies Office webinar "Fuel Cells at NASCAR" held on April 17, 2014. Fuel Cells at...

330

Fuel Cell Technologies Office: Joint Fuel Cell Bus Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Bus Workshop Fuel Cell Bus Workshop The U.S. Department of Energy (DOE) and the U.S. Department of Transportation (DOT) held a Fuel Cell Bus Workshop on June 7, 2010 in Washington, D.C. in conjunction with the DOE Hydrogen and Fuel Cell Program Annual Merit Review. The workshop plenary and breakout session brought together technical experts from industry, end users, academia, DOE national laboratories, and other government agencies to address the status and technology needs of fuel cell powered buses. Meeting Summary Joint Fuel Cell Bus Workshop Summary Report Presentations Fuel Cell Bus Workshop Overview & Purpose, Dimitrios Papageorgopoulos, DOE Users Perspective on Advanced Fuel Cell Bus Technology, Nico Bouwkamp, CaFCP and Leslie Eudy, NREL Progress and Challenges for PEM Transit Fleet Applications, Tom Madden, UTC Power, LLC

331

Microfluidic Microbial Fuel Cells for Microstructure Interrogations  

E-Print Network (OSTI)

treatment, sedi- ment or marine fuel cells for fieldmicrobial fuel cells demonstrating marine (left) and soil (1]. Sediment and Marine Microbial fuel cells can also

Parra, Erika Andrea

2010-01-01T23:59:59.000Z

332

Fuel Cells News | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cells News Fuel Cells News October 16, 2014 Webinar October 21: Opportunities for Wide Bandgap Semiconductor Power Electronics for Hydrogen and Fuel Cell Applications The...

333

Microfluidic Microbial Fuel Cells for Microstructure Interrogations  

E-Print Network (OSTI)

Model of hydrogen fuel cell kinetic losses includingschematic of typical hydrogen fuel cell performancephase factors on hydrogen fuel cell theoretical efficiency,

Parra, Erika Andrea

2010-01-01T23:59:59.000Z

334

Fuel Cell Technologies Office Newsletter Archives | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Information Resources Newsletter Fuel Cell Technologies Office Newsletter Archives Fuel Cell Technologies Office Newsletter Archives View previous issues of the Fuel Cell...

335

Pore Formation by In Situ Etching of Nanorod PEM Fuel Cell M. D. Gasda, G. A. Eisman,* and D. Gallz  

E-Print Network (OSTI)

Pore Formation by In Situ Etching of Nanorod PEM Fuel Cell Electrodes M. D. Gasda, G. A. Eisman a significant fraction of the overall cost of the fuel cell system, and much effort has therefore been directed electrolyte membranes for testing as cathode electrodes in fuel cells. The rods were etched within fully

Gall, Daniel

336

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE  

E-Print Network (OSTI)

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE Borhan M dynamic model of a solid oxide fuel cell stack. Using a detailed physical model as a starting point, we (usually air) on the cathode side. Solid-oxide fuel cells (SOFCs) utilize a ceramic oxygen-ion conducting

Sanandaji, Borhan M.

337

Solid oxide fuel cell matrix and modules  

DOE Patents (OSTI)

Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

Riley, Brian (Willimantic, CT)

1990-01-01T23:59:59.000Z

338

Chapter 3 - Fuels for Fuel Cells  

Science Journals Connector (OSTI)

Publisher Summary This chapter deals with various types of liquid fuels and the relevant chemical and physical properties of these fuels as a means of comparison to the fuels of the future. It gives an overview of the manufacture and properties of the common fuels as well as a description of various biofuels. A fuel mixture usually contains a wide range of organic compounds (usually hydrocarbons). The specific mixture of hydrocarbons gives a fuel its characteristic properties, such as boiling point, melting point, density, viscosity, and a host of other properties. Depending on the application (stationary, central power, remote, auxiliary, transportation, military, etc.), there are a wide range of conventional fuels, such as natural gas, liquefied petroleum gas, light distillates, methanol, ethanol, dimethyl ether, naphtha, gasoline, kerosene, jet fuels, diesel, and biodiesel, that could be used in reforming processes to produce hydrogen (or hydrogen-rich synthesis gas) to power fuel cells. Fossils fuels include gaseous fuels, gasoline, kerosene, diesel fuel, and jet fuels. Gaseous fuels include natural gas and liquefied petroleum gas. Types of gasoline include automotive gasoline, aviation gasoline, and gasohol. Some additives added into gasoline are antioxidants, corrosion inhibitors, demulsifiers, anti-icing, dyes and markers, drag reducers, and oxygenates.

James G. Speight

2011-01-01T23:59:59.000Z

339

Air Liquide- Biogas & Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

340

DOE Hydrogen & Fuel Cell Overview  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Natural Gas Power Heat + Cooling Electricity Cooling Natural Gas Natural Gas or Biogas Fuel Cell H Excess power generated by the fuel cell is fed to the grid National...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Alkaline Membrane Fuel Cell Workshop  

Energy.gov (U.S. Department of Energy (DOE))

A workshop on alkaline membrane fuel cells (AMFC) was held May 8-9, 2011, before the 2011 Hydrogen and Fuel Cells Annual Merit Review, at Crystal Gateway Marriott in Arlington, Virginia.

342

2009 Fuel Cell Market Report  

Fuel Cell Technologies Publication and Product Library (EERE)

Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

343

Deactivation and poisoning of fuel cell catalysts  

SciTech Connect

The deactivation and poisoning phenomena reviewed are: the poisoning of anode (fuel electrode) catalyst by carbon monoxide and hydrogen sulfide; the deactivation of the cathode (air electrode) catalyst by sintering; and the deactivation of the cathode by corrosion of the support. The anode catalyst is Pt supported on a conductive, high area carbon black, usually at a loading of 10 w/o. This catalyst is tolerant to some level of carbon monoxide or hydrogen sulfide or both in combination, the level depending on temperature and pressure. Carbon monoxide poisoning has been studied extensively, including detailed adsorption studies at various temperatures and pressures. Predictive models have been developed that effectively predict anode tolerance to carbon monoxide. Much less is known about hydrogen sulfide poisoning. Typical tolerance levels are 2% CO, and 10 ppM H/sub 2/S. The cathode catalyst is typically Pt supported on a graphitic carbon black, usually a furnace black heat-treated to 2700/sup 0/C. The Pt loading is typically 10 w/o, and the dispersion (or percent exposed) as-prepared is typically 30%. The loss of dispersion in use depends on the operational parameters, most especially the cathode potential history, i.e. higher potentials cause more rapid decrease in dispersion. The mechanism of loss of dispersion is not well known. The graphitic carbon support corrodes at a finite rate that is also potential dependent. Support corrosion causes thickening of the eletrolyte film between the gas pores and the catalyst particles, which in turn causes increased diffusional resistance and performance loss. In addition, support corrosion may also cause loss of Pt into the separator. Support corrosion appears to be the life limiting factor for phosphoric acid fuel cells.

Ross, P.N. Jr.

1985-06-01T23:59:59.000Z

344

Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Vehicle Tax Fuel Cell Vehicle Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Google Bookmark Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Delicious Rank Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Vehicle Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Vehicle Tax Credit South Carolina residents that claim the federal fuel cell vehicle tax credit are eligible for a state income tax credit equal to 20% of the

345

Hydrogen & Fuel Cells Program Overview  

Energy.gov (U.S. Department of Energy (DOE))

2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Joint Plenary

346

Fuel Cell Technologies Office: Publications  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Databases Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis...

347

Electrochemical Formation of a Pt/Zn Alloy and Its Use as a Catalyst for Oxygen Reduction Reaction in Fuel Cells  

Science Journals Connector (OSTI)

The oxygen reduction reaction (ORR) occurs on the cathode in a proton exchange membrane fuel cell (PEMFC). ... In addition to the MEAs containing Zn-modified cathodes, MEAs composed of untreated commercially available GDEs with identical catalyst loading and material specifications (i.e., ELAT carbon cloth, Electrochem Inc.) were also prepared in a similar manner and then investigated in a fuel cell testing configuration to evaluate comparatively the effect of the cathode Zn treatment on the fuel cell polarization curves. ... The history, status in recent expts., and prospects for Pt-alloy cathode catalysts are reviewed. ...

Aya Sode; Winton Li; Yanguo Yang; Phillip C. Wong; Elod Gyenge; Keith A. R. Mitchell; Dan Bizzotto

2006-04-12T23:59:59.000Z

348

Indirect-fired gas turbine bottomed with fuel cell  

DOE Patents (OSTI)

An indirect-heated gas turbine cycle is bottomed with a fuel cell cycle with the heated air discharged from the gas turbine being directly utilized at the cathode of the fuel cell for the electricity-producing electrochemical reaction occurring within the fuel cell. The hot cathode recycle gases provide a substantial portion of the heat required for the indirect heating of the compressed air used in the gas turbine cycle. A separate combustor provides the balance of the heat needed for the indirect heating of the compressed air used in the gas turbine cycle. Hot gases from the fuel cell are used in the combustor to reduce both the fuel requirements of the combustor and the NOx emissions therefrom. Residual heat remaining in the air-heating gases after completing the heating thereof is used in a steam turbine cycle or in an absorption refrigeration cycle. Some of the hot gases from the cathode can be diverted from the air-heating function and used in the absorption refrigeration cycle or in the steam cycle for steam generating purposes.

Micheli, Paul L. (Morgantown, WV); Williams, Mark C. (Morgantown, WV); Parsons, Edward L. (Morgantown, WV)

1995-01-01T23:59:59.000Z

349

Fuel Cell Handbook, Fourth Edition  

SciTech Connect

Robust progress has been made in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in January 1994. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultra high efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 6 describe the four major fuel cell types and their performance based on cell operating conditions. The section on polymer electrolyte membrane fuel cells has been added to reflect their emergence as a significant fuel cell technology. Phosphoric acid, molten carbonate, and solid oxide fuel cell technology description sections have been updated from the previous edition. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 7, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 8 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Stauffer, D.B; Hirschenhofer, J.H.; Klett, M.G.; Engleman, R.R.

1998-11-01T23:59:59.000Z

350

Microfluidic Fuel Cells Erik Kjeang  

E-Print Network (OSTI)

Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeå University, 2004 A Dissertation Submitted Supervisory Committee Microfluidic Fuel Cells by Erik Kjeang M.Sc., Umeå University, 2004 Supervisory University External Examiner Microfluidic fuel cell architectures are presented in this thesis. This work

Victoria, University of

351

Hydrogen & Fuel Cells Program Overview  

E-Print Network (OSTI)

Hydrogen & Fuel Cells Program Overview Dr. Sunita Satyapal Program Manager 2011 Annual Merit Review and Peer Evaluation Meeting May 9, 2011 #12;Enable widespread commercialization of hydrogen and fuel cell transportation applications/light duty vehicles Updated Program Plan May 2011 Hydrogen and Fuel Cells Key Goals 2

352

Precious Metal Recovery from Fuel Cell MEA's  

SciTech Connect

One of the next-generation power sources is the proton exchange membrane (PEM) fuel cell, which runs on pure hydrogen or hydrogen-rich reformate. At the heart of the PEM fuel cell is a membrane electrode assembly (MEA). The MEA is a laminate composed of electrode layers sandwiched between outer layers, fabricated from either carbon fiber or fabric and which control the diffusion of reactant gases, and the inner polymer mebrane. Hydrogen is oxidized at the anode to form protons, which migrate through the membrane and react with oxygen at the cathode to form water. In this type of fuel cell, platinum catalyzes the reactions at both electrodes. Realization of a future that includes ubiquitous use of hydrogen fuel cell-powered vehicles will be partially contingent on a process for recycling components of the fuel cell membrane electrode assemblies. In aggregate, the platinum used for the fuel cell will represent a large pool of this precious metal, and the efficient recycling of Pt from MEA's will be a cost-enabling factor for success of this technology. Care must be taken in the reclamation process because of the presence of fluoropolymers in the MEA. While Pt is normally recovered with high yield, the combustion process commonly applied to remove an organic matrix will also liberate a large volume of HF, a gas which is both toxic and corrosive. Carbonyl fluoride, which has a recommended exposure limit of 2ppmv, is another undesirable product of fluoroploymer combustion. In 2003, the Department of Energy awarded Engelhard Corporation an 80% cost share grant for a five-year project budgeted at $5.9MM. The principal objective is reclaiming platinum from fuel cell MEA's without producing fluorine-containing emissions. Over the last three years, Engelhard has approached the problem from several directions in balancing the two goals: a commercially-viable recycling process and an environmentally favorable one. Working with both fresh and aged fuel cells, it has been shown that precious metals can be liberated at high yield using microwave assisted acid digestion, but exposure of the gas diffusion electrode surfaces is required. A low-cost solvent-stripping process has been identified for two geometries of fuel cell MEA's: GDL and GDE. This paper will detail progress made in realizing a practical, "green" process for recovery of Pt from PEM fuel cell MEA's

Lawrence Shore

2006-11-16T23:59:59.000Z

353

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts  

Science Journals Connector (OSTI)

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts ... Catalytic Reactions on the Open-Edge Sites of Nitrogen-Doped Carbon Nanotubes as Cathode Catalyst for Hydrogen Fuel Cells ... Despite significant progress made the past decade on reducing the platinum catalyst loading in the PEMFC electrodes, further ... ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2011-02-24T23:59:59.000Z

354

Performance of a direct ethylene glycol fuel cell with an anion-exchange membrane  

E-Print Network (OSTI)

of an anion-exchange membrane with non-platinum electrocatalysts at both the anode and cathode on the development and performance test of an alkaline direct ethylene glycol fuel cell. The fuel cell consists with the existing electrocatalysts at low temperatures; as a result, the main product of ethanol oxidation reaction

Zhao, Tianshou

355

Distributed Energy Fuel Cells Electricity Users  

E-Print Network (OSTI)

& Barriers Distributed Energy OBJECTIVES · Develop a distributed generation PEM fuel cell system operating of Stationary PEM Fuel Cell Power System Development of Back-up Fuel Cell Power System Development of Materials of PEM Fuel Cell Systems #12;

356

Fuel Cell Handbook, Fifth Edition  

SciTech Connect

Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

Energy and Environmental Solutions

2000-10-31T23:59:59.000Z

357

Low Cost SiOx-Graphite and High Voltage Spinel Cathode | Department...  

Office of Environmental Management (EM)

Cathode Low Cost SiOx-Graphite and High Voltage Spinel Cathode 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

358

Advanced Electrocatalysts for PEM Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

Presentation slides from the DOE Fuel Cell Technologies Office webinar, Advanced Electrocatalysts for PEM Fuel Cells, held February 12, 2013.

359

Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel  

NLE Websites -- All DOE Office Websites (Extended Search)

Market Transformation Market Transformation Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects to someone by E-mail Share Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Facebook Tweet about Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Twitter Bookmark Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Google Bookmark Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Delicious Rank Fuel Cell Technologies Office: Financial Incentives for Hydrogen and Fuel Cell Projects on Digg Find More places to share Fuel Cell Technologies Office: Financial

360

Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen and Fuel Cell Hydrogen and Fuel Cell Tax Exemption to someone by E-mail Share Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Facebook Tweet about Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Twitter Bookmark Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Google Bookmark Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Delicious Rank Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on Digg Find More places to share Alternative Fuels Data Center: Hydrogen and Fuel Cell Tax Exemption on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Hydrogen and Fuel Cell Tax Exemption The following are exempt from state sales tax: 1) any device, equipment, or

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Motor Fuel Cell Motor Vehicle Tax Credit to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Google Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Delicious Rank Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Credit on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Motor Vehicle Tax Credit A tax credit of up to $4,000 is available for the purchase of qualified

362

Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP)  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

National Fuel Cell Bus National Fuel Cell Bus Program (NFCBP) to someone by E-mail Share Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Facebook Tweet about Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Twitter Bookmark Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Google Bookmark Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Delicious Rank Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on Digg Find More places to share Alternative Fuels Data Center: National Fuel Cell Bus Program (NFCBP) on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type National Fuel Cell Bus Program (NFCBP) The goal of the NFCBP is to facilitate the development of commercially

363

Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Fuel Cell Motor Fuel Cell Motor Vehicle Tax Deduction to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Google Bookmark Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Delicious Rank Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Motor Vehicle Tax Deduction on AddThis.com... More in this section... Federal State Advanced Search All Laws & Incentives Sorted by Type Fuel Cell Motor Vehicle Tax Deduction A taxpayer is eligible for a $2,000 tax deduction for the purchase of a

364

Hydrogen Fuel Cell Automobiles  

Science Journals Connector (OSTI)

With gasoline now more than $2.00 a gallon alternate automobiletechnologies will be discussed with greater interest and developed with more urgency. For our government the hydrogen fuel cell-powered automobile is at the top of the list of future technologies. This paper presents a simple description of the principles behind this technology and a brief discussion of the pros and cons. It is also an extension on my previous paper on the physics of the automobile engine.1

Bernard J. Feldman

2005-01-01T23:59:59.000Z

365

Fuel Cell Technologies Office: About  

NLE Websites -- All DOE Office Websites (Extended Search)

About the Fuel Cell Technologies Office About the Fuel Cell Technologies Office The Fuel Cell Technologies Office conducts comprehensive efforts to overcome the technological, economic, and institutional barriers to the widespread commercialization of hydrogen and fuel cells. The office is aligned with the strategic vision and goals of the U.S. Department of Energy (DOE). The office's efforts will help secure U.S. leadership in clean energy technologies and advance U.S. economic competitiveness and scientific innovation. What We Do DOE is the lead federal agency for directing and integrating activities in hydrogen and fuel cell R&D as authorized in the Energy Policy Act of 2005. The Fuel Cell Technologies Office is responsible for coordinating the R&D activities for DOE's Hydrogen and Fuel Cells Program, which includes activities within four DOE offices (Office of Energy Efficiency and Renewable Energy [EERE], Office of Fossil Energy, Office of Nuclear Energy, and Office of Science).

366

Hydrogen and Fuel Cell Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

8/5/2011 eere.energy.gov 8/5/2011 eere.energy.gov 5 th International Conference on Polymer Batteries & Fuel Cells Argonne, Illinois Hydrogen and Fuel Cell Activities Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager August 4, 2011 2 | Fuel Cell Technologies Program Source: US DOE 8/5/2011 eere.energy.gov Fuel Cells: Benefits & Market Potential The Role of Fuel Cells Key Benefits Very High Efficiency Reduced CO 2 Emissions * 35-50%+ reductions for CHP systems (>80% with biogas) * 55-90% reductions for light- duty vehicles * up to 60% (electrical) * up to 70% (electrical, hybrid fuel cell / turbine) * up to 85% (with CHP) Reduced Oil Use * >95% reduction for FCEVs (vs. today's gasoline ICEVs)

367

Fuel Cell Technologies Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

IEA HIA Hydrogen Safety Stakeholder IEA HIA Hydrogen Safety Stakeholder Workshop Bethesda, Maryland Fuel Cell Technologies Program Overview Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 10/2/2012 2 | Fuel Cell Technologies Program eere.energy.gov Overview Fuel Cells - An Emerging Global Industry Clean Energy Patent Growth Index [1] shows that fuel cell patents lead in the clean energy field with over 950 fuel cell patents issued in 2011. * Nearly double the second place holder, solar, which has ~540 patents. [1] http://cepgi.typepad.com/files/cepgi-4th-quarter-2011-1.pdf United States 46% Germany 7% Korea 7% Canada 3% Taiwan 1% Great Britain 1% France 1% Other 3% Japan 31% Fuel Cell Patents Geographic Distribution 2002-2011 Top 10 companies: GM, Honda, Samsung,

368

Combined goal gasifier and fuel cell system and method  

DOE Patents (OSTI)

A molten carbonate fuel cell is combined with a catalytic coal or coal char gasifier for providing the reactant gases comprising hydrogen, carbon monoxide and carbon dioxide used in the operation of the fuel cell. These reactant gases are stripped of sulfur compounds and particulate material and are then separated in discrete gas streams for conveyance to appropriate electrodes in the fuel cell. The gasifier is arranged to receive the reaction products generated at the anode of the fuel cell by the electricity-producing electrochemical reaction therein. These reaction products from the anode are formed primarily of high temperature steam and carbon dioxide to provide the steam, the atmosphere and the heat necessary to endothermically pyrolyze the coal or char in the presence of a catalyst. The reaction products generated at the cathode are substantially formed of carbon dioxide which is used to heat air being admixed with the carbon dioxide stream from the gasifier for providing the oxygen required for the reaction in the fuel cell and for driving an expansion device for energy recovery. A portion of this carbon dioxide from the cathode may be recycled into the fuel cell with the air-carbon dioxide mixture.

Gmeindl, Frank D. (Morgantown, WV); Geisbrecht, Rodney A. (New Alexandria, PA)

1990-01-01T23:59:59.000Z

369

Sandia National Laboratories: fuel cell vehicle  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cell vehicle ECIS-Automotive Fuel Cell Corporation: Hydrocarbon Membrane Fuels the Success of Future Generation Vehicles On February 14, 2013, in CRF, Energy, Energy...

370

Sandia National Laboratories: Automotive Fuel Cell Cooperation  

NLE Websites -- All DOE Office Websites (Extended Search)

Automotive Fuel Cell Cooperation ECIS-Automotive Fuel Cell Corporation: Hydrocarbon Membrane Fuels the Success of Future Generation Vehicles On February 14, 2013, in CRF, Energy,...

371

Reversible Fuel Cells Workshop | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Reversible Fuel Cells Workshop Reversible Fuel Cells Workshop The National Renewable Energy Laboratory hosted a workshop addressing the current state-of-the-art of reversible fuel...

372

Layed Perovskite PRBA0.5SR0.5CO205 as High Performance Cathode for Solid Oxide Fuels Using Photon Conducting Electrolyte  

SciTech Connect

The layered perovskite PrBa{sub 0.5}Sr{sub 0.5}Co{sub 2}O{sub 5+{delta}} (PBSC) was investigated as a cathode material for a solid oxide fuel cell using a proton-conducting electrolyte based on BaCe{sub 0.7}Y{sub 0.2}Zr{sub 0.1}O{sub 3-{delta}} (BCYZ). The sintering conditions for the PBSC-BCYZ composite cathode were optimized resulting in the lowest area-specific resistance and apparent activation energy obtained with the cathode sintered at 1200 C for 2h. The maximum power densities of the PBSC-BCYZ/BZCY/NiO-BCYZ cell were 0.179, 0.274, 0.395, and 0.522 Wcm{sup -2} at 550, 600, 650, and 700 C, respectively with a 15{micro}m thick electrolyte. A relatively low cell interfacial polarization resistance of 0.132 {Omega}cm{sup 2} at 700 C indicated that the PBSC-BCYZ could be a good cathode candidate for intermediate temperature SOFCs with proton-conducting electrolyte.

Brinkman, K.

2010-05-05T23:59:59.000Z

373

Platinum supported on titaniumruthenium oxide is a remarkably stable electrocatayst for hydrogen fuel cell vehicles  

Science Journals Connector (OSTI)

...effects of Pt-based alloy catalysts for fuel cell applications...on carbon corrosion of PEMFC electrodes . J Electrochem...carbon monoxide on PEFC catalyst carbon support degradation...2006 ) PEM fuel cell cathode carbon corrosion due to...of carbon support in PEMFC at fuel starvation . ECS...

Javier Parrondo; Taehee Han; Ellazar Niangar; Chunmei Wang; Nilesh Dale; Kev Adjemian; Vijay Ramani

2014-01-01T23:59:59.000Z

374

Alternative Fuels Data Center: Fuel Cell Electric Vehicles  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Cell Electric Vehicles to someone by E-mail Share Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Facebook Tweet about Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Twitter Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Google Bookmark Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Delicious Rank Alternative Fuels Data Center: Fuel Cell Electric Vehicles on Digg Find More places to share Alternative Fuels Data Center: Fuel Cell Electric Vehicles on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations Vehicles Availability Emissions Laws & Incentives Fuel Cell Electric Vehicles

375

Solid oxide fuel cell matrix and modules  

DOE Patents (OSTI)

Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs. 11 figs.

Riley, B.

1988-04-22T23:59:59.000Z

376

Cell Analysis ? High-Energy Density Cathodes and Anodes  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

* Investigate the relationships of structure, morphology and performance of cathode and anode materials. * Explore kinetic barriers and utilize the knowledge gained to design and...

377

Non-Platinum Bimetallic Cathode Electrocatalysts  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on non-platinum bimetallic cathode electrocatalysts, was given by Debbie Myers of Argonne National Laboratory at a February 2007 meeting on new fuel cell projects.

378

Fuel Cell Power Plant Experience Naval Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

clean clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy/ Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC March 29, 2011 FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. *FuelCell Energy, Inc. *Renewable and Liquid Fuels Experience *HTPEM Fuel Cell Stack for Shipboard APU *Solid Oxide Experience and Applications DOE-ONR Workshop FuelCell Energy, the FuelCell Energy logo, Direct FuelCell and "DFC" are all registered trademarks (®) of FuelCell Energy, Inc. FuelCell Energy, Inc. * Premier developer of fuel cell technology - founded in 1969 * Over 50 power installations in North America, Europe, and Asia * Industrial, commercial, utility

379

The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells  

E-Print Network (OSTI)

for water electrolysis) [1,2], hydrogen can be evolved on the cathode under anoxic conditions, usually for the hydrogen evolution reaction (HER) in water electrolysis [13,14]. Hu et al. * Corresponding author. Tel.: þ1The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells Yimin

380

How Fuel Cells Work | Department of Energy  

Energy Savers (EERE)

Fuel Cells Work How Energy Works 30 likes How Fuel Cells Work Fuel cells produce electrical power without any combustion and operate on fuels like hydrogen, natural gas and...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

NREL: Hydrogen and Fuel Cells Research - National Fuel Cell Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

National Fuel Cell Technology Evaluation Center National Fuel Cell Technology Evaluation Center The National Fuel Cell Technology Evaluation Center (NFCTEC) at NREL's Energy Systems Integration Facility (ESIF) plays a crucial role in NREL's independent, third-party analysis of hydrogen fuel cell technologies in real-world operation. The NFCTEC is designed for secure management, storage, and processing of proprietary data from industry. Access to the off-network NFCTEC is limited to NREL's Technology Validation Team, which analyzes detailed data and reports on fuel cell technology status, progress, and technical challenges. Graphic representing NREL's Hydrogen Secure Data Center and the variety of applications from which it gathers data, including fuel cell (FC) stacks, FC backup power, FC forklifts, FC cars, FC buses, and FC prime power, and hydrogen infrastructure.

382

ELECTRODE DEVELOPMENT FOR REVERSIBLE SOLID OXIDE FUEL CELLS  

SciTech Connect

The reversibility of the electrodes for a solid oxide fuel cell with an yttria-stabilized zirconia (YSZ) electrolyte was examined using electrochemical impedance spectroscopy and current interrupt methods. The fuel electrodes were nickel/zirconia cermet and lanthanum-doped strontium titanate/doped ceria composites. The air electrodes were lanthanum strontium ferrite (LSF) and lanthanum strontium copper ferrite (LSCuF). Under the experimental conditions studied all four electrodes were able to operate in both the fuel cell and electrolyzer modes. The titanate/ceria fuel electrode performed substantially better in the electrolyzer mode than state-of-art Ni-YSZ. Moreover, it showed slightly higher activity for water electrolysis as compared to hydrogen oxidation. Air electrodes were less active in the electrolyzer than fuel cell modes. LSF typically provided higher overpotential losses in both modes than copper-substituted LSF. Changes in the defect chemistry of electrode materials under cathodic and anodic polarization are discussed.

Marina, Olga A.; Coffey, Greg W.; Pederson, Larry R.; Rieke, Peter C.; Thomsen, Ed C.; Williams, Mark C.

2004-08-06T23:59:59.000Z

383

Micromachined microbial and photosynthetic fuel cells  

Science Journals Connector (OSTI)

This paper presents two types of fuel cells: a miniature microbial fuel cell (MFC) and a miniature photosynthetic electrochemical cell (PEC). A bulk micromachining process is used to fabricate the fuel cells, and the prototype has an active proton exchange membrane area of 1 cm2. Two different micro-organisms are used as biocatalysts in the anode: (1) Saccharomyces cerevisiae (baker's yeast) is used to catalyze glucose and (2) Phylum Cyanophyta (blue-green algae) is used to produce electrons by a photosynthetic reaction under light. In the dark, the PEC continues to generate power using the glucose produced under light. In the cathode, potassium ferricyanide is used to accept electrons and electric power is produced by the overall redox reactions. The bio-electrical responses of MFCs and PECs are characterized with the open-circuit potential measured at an average value of 300500 mV. Under a 10 ohm load, the power density is measured as 2.3 nW cm?2 and 0.04 nW cm?2 for MFCs and PECs, respectively.

Mu Chiao; Kien B Lam; Liwei Lin

2006-01-01T23:59:59.000Z

384

Graphene Cathode-Based ZnO Nanowire Hybrid Solar Cells  

Science Journals Connector (OSTI)

Graphene Cathode-Based ZnO Nanowire Hybrid Solar Cells ... On the basis of this structure, we then demonstrate graphene cathode-based hybrid solar cells using two different photoactive materials, PbS quantum dots and the conjugated polymer P3HT, with AM 1.5G power conversion efficiencies of 4.2% and 0.5%, respectively, approaching the performance of ITO-based devices with similar architectures. ... graphene; ZnO nanowires; solar cells; ITO ...

Hyesung Park; Sehoon Chang; Joel Jean; Jayce J. Cheng; Paulo T. Araujo; Mingsheng Wang; Moungi G. Bawendi; Mildred S. Dresselhaus; Vladimir Bulovi?; Jing Kong; Silvija Grade?ak

2012-12-03T23:59:59.000Z

385

Fuel Quality Issues in Stationary Fuel Cell Systems  

Energy.gov (U.S. Department of Energy (DOE))

This report, prepared by Argonne National Laboratory, looks at impurities encountered in stationary fuel cell systems, and the effects of the impurities on the fuel cells.

386

DOE Fuel Cell Technologies Program Record, Record # 11003, Fuel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cell Technologies Program Record Record : 11003 Date: March 8, 2011 Title: Fuel Cell Stack Durability Originator: Jacob Spendelow, Dimitrios Papageorgopoulos, and John Garbak...

387

Non-Platinum Bimetallic Cathode Electrocatalysts  

E-Print Network (OSTI)

Non-Platinum Bimetallic Cathode Electrocatalysts Debbie Myers ­ Argonne National Laboratory-platinum cathode electrocatalyst for polymer electrolyte fuel cells to meet DOE targets that: ­ Promotes the direct not contain any proprietary or confidential information #12;Objective and Technical Targets Develop a non

388

Stationary Fuel Cells: Overview of Hydrogen and Fuel Cell Activities  

Energy.gov (U.S. Department of Energy (DOE))

Presentation covers stationary fuel cells and is given at the Spring 2010 Federal Utility Partnership Working Group (FUPWG) meeting in Providence, Rhode Island.

389

NREL: Hydrogen and Fuel Cells Research - Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

equipment in a laboratory setting. NREL scientist applies catalyst layer to a fuel cell through a spray process that delivers a more even distribution of material,...

390

Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell  

NLE Websites -- All DOE Office Websites (Extended Search)

Financial Opportunities Financial Opportunities Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation to someone by E-mail Share Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Facebook Tweet about Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Twitter Bookmark Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Google Bookmark Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Delicious Rank Fuel Cell Technologies Office: Recovery Act Projects Funded for Fuel Cell Market Transformation on Digg

391

Optimization of Fuel Cell System Operating Conditions for Fuel Cell Vehicles  

E-Print Network (OSTI)

An Indirect Methanol Pem Fuel Cell System, SAE 2001, (paperof automotive PEM fuel cell stacks, SAE 2000 (paper numberParasitic Loads in Fuel Cell Vehicles, International Journal

Zhao, Hengbing; Burke, Andy

2008-01-01T23:59:59.000Z

392

Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Delicious Rank Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Availability on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations

393

Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

Hydrogen Hydrogen Printable Version Share this resource Send a link to Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Google Bookmark Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Delicious Rank Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fuel Cell Vehicle Emissions on AddThis.com... More in this section... Hydrogen Basics Benefits & Considerations Stations

394

Proton Conductor based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119  

NLE Websites -- All DOE Office Websites (Extended Search)

based Solid Oxide Fuel Cells based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119 S. (Elango) Elangovan, Joseph Hartvigsen, Insoo Bay, and Feng Zhao High efficiency operation is one of the primary attractions to use solid oxide fuel cells as the energy conversion device. High efficiency requires maximizing of the product of operating voltage and fuel utilization. The maximum possible operating voltage however is limited by the Nernst potential near the fuel exhaust. In oxygen conducting electrolyte based fuel cells (O-SOFC) as the fuel utilization increases, the Nernst potential continues to decrease with the dilution of fuel by the reaction products. In contrast, in a proton conducting electrolyte based fuel cell (P-SOFC) the reaction product is formed on the cathode side allowing for high operating voltage at high fuel

395

Hybrid Fuel Cell Technology Overview  

SciTech Connect

For the purpose of this STI product and unless otherwise stated, hybrid fuel cell systems are power generation systems in which a high temperature fuel cell is combined with another power generating technology. The resulting system exhibits a synergism in which the combination performs with an efficiency far greater than can be provided by either system alone. Hybrid fuel cell designs under development include fuel cell with gas turbine, fuel cell with reciprocating (piston) engine, and designs that combine different fuel cell technologies. Hybrid systems have been extensively analyzed and studied over the past five years by the Department of Energy (DOE), industry, and others. These efforts have revealed that this combination is capable of providing remarkably high efficiencies. This attribute, combined with an inherent low level of pollutant emission, suggests that hybrid systems are likely to serve as the next generation of advanced power generation systems.

None available

2001-05-31T23:59:59.000Z

396

Carbonate fuel cell anodes  

DOE Patents (OSTI)

A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

Donado, R.A.; Hrdina, K.E.; Remick, R.J.

1993-04-27T23:59:59.000Z

397

Engineered Nano-scale Ceramic Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies Technologies Operated by Los Alamos National Security, LLC for NNSA U N C L A S S I F I E D Engineered Nano-scale Ceramic Supports for PEM Fuel Cells Eric L. Brosha, Anthony Burrell, Neil Henson, Jonathan Phillips, and Tommy Rockward Los Alamos National Laboratory Timothy Ward, Plamen Atanassov University of New Mexico Karren More Oak Ridge National Laboratory Fuel Cell Technologies Program Kick-off Meeting September 30 - October 1, 2009 Washington DC Operated by Los Alamos National Security, LLC for NNSA U N C L A S S I F I E D Fuel Cell Technologies Objectives  Develop a ceramic alternative to carbon material supports for a polymer electrolyte fuel cell cathode that exhibits an enhanced resistance to corrosion and Pt coalescence while preserving positive attributes of carbon such as

398

Platinum supported on titaniumruthenium oxide is a remarkably stable electrocatayst for hydrogen fuel cell vehicles  

Science Journals Connector (OSTI)

...dioxide in the cathode exit stream during...exceptionally stable electrocatalyst that yields...PEM fuel cell cathodes during potential cycling...Ti0.7W0.3O2 electrocatalyst for proton-exchange...Popov BN ( 2009 ) Development of a titanium...oxide-supported platinum electrocatalyst for polymer electrolyte...

Javier Parrondo; Taehee Han; Ellazar Niangar; Chunmei Wang; Nilesh Dale; Kev Adjemian; Vijay Ramani

2014-01-01T23:59:59.000Z

399

Platinum supported on titaniumruthenium oxide is a remarkably stable electrocatayst for hydrogen fuel cell vehicles  

Science Journals Connector (OSTI)

...carbon-based electrocatalyst supports due to their...hybridization strategies, some level...cycling, the cathode potential...more stable electrocatalyst than Pt/HSAC...PEM fuel cell cathodes during potential...7W0.3O2 electrocatalyst for proton-exchange...BN ( 2009 ) Development of a titanium...

Javier Parrondo; Taehee Han; Ellazar Niangar; Chunmei Wang; Nilesh Dale; Kev Adjemian; Vijay Ramani

2014-01-01T23:59:59.000Z

400

Novel Composite Cathode Structures  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Relevance * New cathode materials are required to improve the energy density of Li-ion cells for transportation technologies. * The cathode system in this project directly...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Energy 101: Fuel Cell Technology  

K-12 Energy Lesson Plans and Activities Web site (EERE)

This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

402

Air Liquide - Biogas & Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

403

2009 Fuel Cell Market Report  

Energy.gov (U.S. Department of Energy (DOE))

This report provides an overview of 2009 trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance.

404

Sandia National Laboratories: Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

separator, compared to 800 hrs obtained by a commercial standard. Tagged with: Fuel Cells * Hydrogen * SAND2014-15070W Comments are closed. Renewable Energy Wind Energy...

405

Microfluidics for fuel cell applications.  

E-Print Network (OSTI)

??In this work, a microfluidics approach is applied to two fuel cell related projects; the study of deformation and contact angle hysteresis on water invasion (more)

Stewart, Ian

2011-01-01T23:59:59.000Z

406

Serially connected solid oxide fuel cells having monolithic cores  

DOE Patents (OSTI)

Disclosed is a solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output. The cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

Herceg, J.E.

1985-05-20T23:59:59.000Z

407

Method for reducing fuel cell output voltage to permit low power operation  

DOE Patents (OSTI)

Fuel cell performance is degraded by recycling a portion of the cathode exhaust through the cells and, if necessary, also reducing the total air flow to the cells for the purpose of permitting operation below a power level which would otherwise result in excessive voltage.

Reiser, Carl A. (Glastonbury, CT); Landau, Michael B. (West Hartford, CT)

1980-01-01T23:59:59.000Z

408

List of Fuel Cells using Renewable Fuels Incentives | Open Energy  

Open Energy Info (EERE)

Fuel Cells using Renewable Fuels Incentives Fuel Cells using Renewable Fuels Incentives Jump to: navigation, search The following contains the list of 192 Fuel Cells using Renewable Fuels Incentives. CSV (rows 1 - 192) Incentive Incentive Type Place Applicable Sector Eligible Technologies Active Advanced Energy Fund (Ohio) Public Benefits Fund Ohio Commercial Industrial Institutional Residential Utility Biomass CHP/Cogeneration Fuel Cells Fuel Cells using Renewable Fuels Geothermal Electric Hydroelectric energy Landfill Gas Microturbines Municipal Solid Waste Photovoltaics Solar Space Heat Solar Thermal Electric Solar Water Heat Wind energy Yes AlabamaSAVES Revolving Loan Program (Alabama) State Loan Program Alabama Commercial Industrial Institutional Building Insulation Doors Energy Mgmt. Systems/Building Controls

409

Fuel Cell Technologies Office: News  

NLE Websites -- All DOE Office Websites (Extended Search)

News News Recent news stories and press releases related to the Fuel Cell Technologies Office are presented below. To see past news items, refer to the news archives for 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006, 2005, 2004, and 2003. Subscribe to Fuel Cell Technologies Office updates. January 10, 2014 Upcoming Live Discussion on Energy 101: Fuel Cells Join the Energy Department at 2:00 p.m. ET on Thursday, January 16 for the first Energy 101 Google+ Hangout, which will focus on fuel cells. More January 10, 2014 Help Design the Hydrogen Fueling Station of Tomorrow The Energy Department posted a blog yesterday about the Hydrogen Education Foundation's Hydrogen Student Design Contest. More December 20, 2013 Your Holidays...Brought to You by Fuel Cells

410

Hafnium metallocene compounds used as cathode interfacial layers for enhanced electron transfer in organic solar cells  

Science Journals Connector (OSTI)

We have used hafnium metallocene compounds as cathode interfacial layers for organic solar cells [OSCs]. A metallocene compound consists of...6, 6]-phenyl C61 butyric acid methyl ester, bis-(ethylcyclopentadienyl...

Keunhee Park; Seungsik Oh; Donggeun Jung; Heeyeop Chae

2012-01-01T23:59:59.000Z

411

Fuel Cell Power PlantsFuel Cell Power Plants Renewable and Waste Fuels  

E-Print Network (OSTI)

of stationary fuel Premier developer of stationary fuel cell technology -- founded in 1969 · Over 50 efficiency 60% DFC-ERGDFC ERG DFC/Turbine 58 ­ 70% Direct FuelCell (DFC)* 47% Natural Gas Engines Small Gas 30 ­ 42% Turbines * Combined Heat & Power 25 ­35% Micro- (CHP)) fuel cell applications( pp

412

Fuel Cell Catalyst Layers: A Polymer Science Perspective  

Science Journals Connector (OSTI)

With the approaching commercialization of PEM fuel cell technol., developing active, inexpensive non-precious metal ORR catalyst materials to replace currently used Pt-based catalysts is a necessary and essential requirement in order to reduce the overall system cost. ... Polymer electrolyte membranes were catalyzed by direct application of thin film layers cast from solns. of suspended Pt/C catalyst and solubilized Nafion ionomer. ... Identification of dominant transport mechanisms in PEMFC cathode catalyst layers operated under low RH ...

Steven Holdcroft

2013-06-28T23:59:59.000Z

413

Fuel Cell Technologies Program Record 12012: Fuel Cell Bus Targets  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Program Record Fuel Cell Technologies Program Record Record #: 12012 Date: March 2, 2012 Title: Fuel Cell Bus Targets Originator: Jacob Spendelow and Dimitrios Papageorgopoulos Approved by: Sunita Satyapal * Date: September 12, 2012 Item: Performance, cost, and durability targets for fuel cell transit buses are presented in Table 1. These market-driven targets represent technical requirements needed to compete with alternative technologies. They do not represent expectations for the status of the technology in future years. Table 1. Performance, cost, and durability targets for fuel cell transit buses. Units 2012 Status 2016 Target Ultimate Target Bus Lifetime years/miles 5/100,000 1 12/500,000 12/500,000 Power Plant Lifetime 2,3 hours 12,000 18,000 25,000

414

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes &  

E-Print Network (OSTI)

Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure)DescriptionMilestone #12;Hydrogen, Fuel Cells & Infrastructure Technologies ProgramHydrogen, Fuel Cells & Infrastructure Technologies Program Hydrogen Codes & Standards #12;Hydrogen Codes & Standards: Goal & Objectives Goal

415

Water Emissions from Fuel Cell Vehicles | Department of Energy  

Energy Savers (EERE)

Fuel Cells Water Emissions from Fuel Cell Vehicles Water Emissions from Fuel Cell Vehicles Hydrogen fuel cell vehicles (FCVs) emit approximately the same amount of water per...

416

Overview of Fuel Cell Electric Bus Development | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cell Electric Bus Development Overview of Fuel Cell Electric Bus Development Presentation slides from the Fuel Cell Technologies Office webinar ""Fuel Cell Buses"" held...

417

Overview of Hydrogen and Fuel Cell Activities: 2011 IPHE Stationary...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Overview of Hydrogen and Fuel Cell Activities: 2011 IPHE Stationary Fuel Cell Workshop Overview of Hydrogen and Fuel Cell Activities: 2011 IPHE Stationary Fuel Cell Workshop...

418

Comparison of Fuel Cell Technologies: Fact Sheet | Department...  

Energy Savers (EERE)

Office. Comparison of Fuel Cell Technologies More Documents & Publications Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fuel Cells Fact Sheet MCFC and PAFC...

419

Comparison of Fuel Cell Technologies | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Comparison of Fuel Cell Technologies Comparison of Fuel Cell Technologies Each fuel cell technology has advantages and disadvantages. See how fuel cell technologies compare with...

420

Electrode Performance in Reversible Solid Oxide Fuel Cells  

SciTech Connect

The performance of several negative (fuel) and positive (air) electrode compositions for use in reversible solid oxide fuel cells (SOFC) that are capable of operating both as a fuel cell and as an electrolyzer was investigated in half-cell and full-cell tests. Negative electrode compositions studied were a nickel/zirconia cermet (Ni/YSZ) and lanthanum-substituted strontium titanate/ceria composite, whereas positive electrode compositions examined included mixed ion and electron-conducting lanthanum strontium ferrite (LSF), lanthanum strontium copper ferrite (LSCuF), lanthanum strontium cobalt ferrite (LSCoF), and lanthanum strontium manganite (LSM). While titanate/ceria and Ni/YSZ electrodes performed similarly in the fuel cell mode in half-cell tests, losses associated with electrolysis were lower for the titanate/ceria electrode. Positive electrodes all gave higher losses in the electrolysis mode when compared to the fuel cell mode. This behavior was most apparent for mixed-conducting LSF, LSCuF, and LSCoF electrodes, and discernible but smaller for LSM; observations are consistent with expected trends in the interfacial oxygen vacancy concentration under anodic and cathodic polarization. Full-cell tests conducted for cells with a thin electrolyte (7 um YSZ) similarly showed higher polarization losses in the electrolysis than fuel cell direction.

Marina, Olga A.; Pederson, Larry R.; Williams, Mark C.; Coffey, Greg W.; Meinhardt, Kerry D.; Nguyen, Carolyn D.; Thomsen, Ed C.

2007-03-22T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

Compressed Natural Gas Compressed Natural Gas and Hydrogen Fuels Workshop to someone by E-mail Share Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Facebook Tweet about Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Twitter Bookmark Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Google Bookmark Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Delicious Rank Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on Digg Find More places to share Fuel Cell Technologies Office: Compressed Natural Gas and Hydrogen Fuels Workshop on AddThis.com... Publications Program Publications Technical Publications Educational Publications

422

Fuel Cell Kickoff Meeting Agenda  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3:40 Aligned Carbon Nanotube-Based MEA and PEMFC D-J Liu, ANL 4:00 Light Weight Low Cost PEM Fuel Cell Stacks J. Wainright, CWRU 4:20 Adaptive Stack with Subdivided Cells for...

423

Manufacturing Fuel Cell Manhattan Project  

NLE Websites -- All DOE Office Websites (Extended Search)

to to DOE Fuel Cell Manufacturing Workshop 2011 John Christensen, PE NREL Consultant DOE Fuel Cell Market Transformation Support August 11, 2011 Manufacturing Fuel Cell Manhattan Project √ Identify manufacturing cost drivers to achieve affordability √ Identify best practices in fuel cell manufacturing technology √ Identify manufacturing technology gaps √ Identify FC projects to address these gaps MFCMP Objectives Completed Final Report due out Nov 2010 B2PCOE Montana Tech SME's Industry Academia Government FC Consortiums Power ranges * <0.5 kW (man portable / man wearable) * 0.5 kW< Power range < 10 kW (mobile power) Fuels: Hydrogen and reformed hydrocarbons *Packaged Fuels < 0.5 kW * Near term solution * Move through the supply chain like batteries

424

Fuel cell electric power production  

DOE Patents (OSTI)

A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

Hwang, Herng-Shinn (Livingston, NJ); Heck, Ronald M. (Frenchtown, NJ); Yarrington, Robert M. (Westfield, NJ)

1985-01-01T23:59:59.000Z

425

NREL: Hydrogen and Fuel Cells Research - Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen and Fuel Cell Basics Photo of vehicle filling up at renewable hydrogen fueling station. NREL's hydrogen fueling station dispenses hydrogen produced via renewable...

426

Solid oxide fuel cell generator  

DOE Patents (OSTI)

A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

1993-01-01T23:59:59.000Z

427

Oxygen electrode reaction in molten carbonate fuel cells  

SciTech Connect

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

428

DOE Hydrogen and Fuel Cells Program Record, Record # 13008: Industry Deployed Fuel Cell Powered Lift Trucks  

Energy.gov (U.S. Department of Energy (DOE))

This program record from the DOE Hydrogen and Fuel Cells Program focuses on deployments of fuel cell powered lift trucks.

429

FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel  

E-Print Network (OSTI)

Hydrogen is a versatile energy carrier that can be used to power nearly every end-use energy need. The fuel cell -- an energy conversion device that can efficiently capture and use the power of hydrogen the chemical energy in hydrogen to electricity, with pure water and potentially useful heat as the only

430

Energy 101: Fuel Cell Technology  

SciTech Connect

Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

None

2014-03-11T23:59:59.000Z

431

Energy 101: Fuel Cell Technology  

ScienceCinema (OSTI)

Learn how fuel cell technology generates clean electricity from hydrogen to power our buildings and transportation-while emitting nothing but water. This video illustrates the fundamentals of fuel cell technology and its potential to supply our homes, offices, industries, and vehicles with sustainable, reliable energy.

None

2014-06-06T23:59:59.000Z

432

E-Print Network 3.0 - anode-cathode microbial fuel Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

1 2 3 4 5 > >> Page: << < 1 2 3 4 5 > >> 61 Visions on Energy Production Technologies for Finland up to 2030 Summary: turbine G G After- burner Solid oxide fuel cell (SOFC) Anode...

433

Fuel Cells for Robots  

NLE Websites -- All DOE Office Websites (Extended Search)

For Robots For Robots Fuel Cells For Robots Pavlo Rudakevych iRobot Pavlo Rudakevych iRobot Product Needs Product Needs * Military/Police/Search and Rescue - PackBot - Gladiator - ThrowBot/UGCV * Industrial and Oil - CoWorker - MicroRig * Military/Police/Search and Rescue - PackBot - Gladiator - ThrowBot/UGCV * Industrial and Oil - CoWorker - MicroRig PackBot PackBot * Mission capable robots * Rugged, portable tools for minimal casualty engagements * Assisting behaviors * Small size and weight * Mission capable robots * Rugged, portable tools for minimal casualty engagements * Assisting behaviors * Small size and weight System Concept System Concept System Concept System Concept System Concept Continued System Concept Continued * Modular payload bays - 3 primary - 1 head - 4 side pods * Each payload socket supports - Ethernet

434

NETL: Fuel Cells/SECA News - Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells/Solid State Energy Conversion Alliance (SECA) Fuel Cells/Solid State Energy Conversion Alliance (SECA) News Archive SECA Workshop Proceedings, Peer Reviews, and Annual Reports 2013 Archive 2012 Archive 2011 Archive Previous Highlights FuelCell Energy's Stack Boosts Power and Minimizes Degradation FuelCell Energy has developed a new solid oxide fuel cell stack design that boosts the overall power output of the fuel cell stack by nearly 50%. FuelCell Energy also achieved a voltage degradation rate of 1.3% per 1000 hours after testing the fuel cells for 26,000 hours of operation. This breakthrough by FuelCell Energy of greater power from the fuel cell stack while minimizing fuel cell degradation pushes it further towards meeting SECA's goal of a market ready, affordable solid oxide fuel cell ready by the year 2010. (5/05)

435

Fuel Cell Markets Ltd | Open Energy Information  

Open Energy Info (EERE)

Fuel Cell Markets Ltd Place: Buckinghamshire, United Kingdom Zip: SL0 9AQ Sector: Hydro, Hydrogen Product: Fuel Cell Markets was set up to assist companies in the fuel cell and...

436

Hydrogen fuel cells for cars and buses  

Science Journals Connector (OSTI)

The use of hydrogen fuel cells for cars is strongly promoted by the governments of ... . The electrochemical behaviour of the most promising fuel cell (polymer electrolyte membrane fuel cell, PEMFC) is critically...

L. J. J. Janssen

2007-11-01T23:59:59.000Z

437

Hydrogen Fuel Cell Engines and Related Technologies  

Energy.gov (U.S. Department of Energy (DOE))

This course covers hydrogen properties, use and safety, fuel cell technology and its systems, fuel cell engine design and safety, and design and maintenance of a heavy duty fuel cell bus engine.

438

Microfluidic Microbial Fuel Cells for Microstructure Interrogations  

E-Print Network (OSTI)

tion, to the typical PEM fuel cell kinetics, the system alsostudied. As with other PEM fuel cells, it is generally ad-exchange membrane (PEM) fuel cell performance, utilizing

Parra, Erika Andrea

2010-01-01T23:59:59.000Z

439

Ceramic Fuel Cells (SOFC) | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Ceramic Fuel Cells (SOFC) Ceramic Fuel Cells (SOFC) Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011....

440

Solar-Hydrogen Fuel-Cell Vehicles  

E-Print Network (OSTI)

M. A. (1992). Hydrogen Fuel-Cell Vehicles. Re- koebensteinthan both. Solar-hydrogen and fuel-cell vehicles wouldberegulation. Solar-Hydrogen Fuel-Cell Vehicles MarkA. DeLuchi

DeLuchi, Mark A.; Ogden, Joan M.

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Fuel Cells Get New BFF | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cells Get New BFF Fuel Cells Get New BFF Artificial diamonds may lead to affordable, efficient fuel cells Oxygen (red spheres) migrates from one vacancy to another inside the...

442

Fuel Cells - Basics | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Basics Fuel Cells - Basics Photo of a fuel cell stack A fuel cell uses the chemical energy of hydrogen to cleanly and efficiently produce electricity with water and heat as...

443

Fuel Cells Calendar | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fuel Cells Calendar Fuel Cells Calendar Upcoming events for the Fuel Cell Technologies Office are listed below. Find past events. January 2015 < prev next > Sun Mon Tue Wed Thu Fri...

444

Fuel Cell School Buses: Report to Congress  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Fuel Cell Activities, Progress, and Plans: Report to Congress ii December 2008 Fuel Cell School Buses Report to Congress Fuel Cell School Buses: Report to Congress Preface This...

445

Fuel Cells for Transportation | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

DOE R&D Activities Fuel Cells for Transportation Fuel Cells for Transportation Photo of Ford Focus fuel cell car in front of windmills The transportation sector is the single...

446

PEMFC Catalyst Layers: The Role of Micropores and Mesopores on Water Sorption and Fuel Cell Activity  

Science Journals Connector (OSTI)

Polymer electrolyte membranes were catalyzed by direct application of thin film layers cast from solns. of suspended Pt/C catalyst and solubilized Nafion ionomer. ... The improvement in the performance of both CO tolerant anodes and cathodes with enhanced oxygen redn. ... The effect of Nafion loading in the cathode catalyst layer of p exchange membrane fuel cell (PEMFC) electrodes was studied by impedance spectroscopy, cyclic voltammetry, and polarization expts. ...

Tatyana Soboleva; Kourosh Malek; Zhong Xie; Titichai Navessin; Steven Holdcroft

2011-05-16T23:59:59.000Z

447

Dry compliant seal for phosphoric acid fuel cell  

DOE Patents (OSTI)

A dry compliant overlapping seal for a phosphoric acid fuel cell preformed f non-compliant Teflon to make an anode seal frame that encircles an anode assembly, a cathode seal frame that encircles a cathode assembly and a compliant seal frame made of expanded Teflon, generally encircling a matrix assembly. Each frame has a thickness selected to accommodate various tolerances of the fuel cell elements and are either bonded to one of the other frames or to a bipolar or end plate. One of the non-compliant frames is wider than the other frames forming an overlap of the matrix over the wider seal frame, which cooperates with electrolyte permeating the matrix to form a wet seal within the fuel cell that prevents process gases from intermixing at the periphery of the fuel cell and a dry seal surrounding the cell to keep electrolyte from the periphery thereof. The frames may be made in one piece, in L-shaped portions or in strips and have an outer perimeter which registers with the outer perimeter of bipolar or end plates to form surfaces upon which flanges of pan shaped, gas manifolds can be sealed.

Granata, Jr., Samuel J. (South Greensburg, PA); Woodle, Boyd M. (N. Huntingdon Township, Westmoreland County, PA)

1990-01-01T23:59:59.000Z

448

A laser-micromachined polymeric membraneless fuel cell  

Science Journals Connector (OSTI)

This paper presents a laser-micromachined polymeric membraneless fuel cell. The membraneless fuel cell, constructed with three polymethyl methacrylate (PMMA) layers, takes advantage of two laminar flows in a single micro channel to keep the fuel and oxidant streams separated yet in diffusional contact. Laser micromachining was employed to make the flow channel and electrode substrate based on PMMA. The anode and cathode electrodes were fabricated by wet-spraying catalyst inks onto the gold-coated PMMA substrate. The packed fuel cell has been electrochemically characterized by an electrochemical analyser. The membraneless fuel cell works stably with Reynolds numbers ranging from 7.65 to 30.6. At room temperature, the laminar-flow-based micro membraneless fuel cell can reach a maximum power density of 0.58 mW cm?2 with 0.5 M HCOOH in 0.1 M H2SO4 solution as fuel and O2 saturated 0.1 M H2SO4 solution as oxidant. When 0.01 M H2O2 in 0.1 M H2SO4 solution is used as oxidant, a maximum power density of 1.98 mW cm?2 is obtained. The paper reports for the first time the use of hydrogen peroxide in sulfuric acid as the oxidant. The new oxidant composition allows a simple recycling process and better fuel utilization.

Aidan Li; Siew Hwa Chan; Nam-Trung Nguyen

2007-01-01T23:59:59.000Z

449

Direct Carbon Fuel Cell System Utilizing Solid Carbonaceous Fuels  

SciTech Connect

This 1-year project has achieved most of its objective and successfully demonstrated the viability of the fluidized bed direct carbon fuel cell (FB-DCFC) approach under development by Direct Carbon technologies, LLC, that utilizes solid carbonaceous fuels for power generation. This unique electrochemical technology offers high conversion efficiencies, produces proportionately less CO{sub 2} in capture-ready form, and does not consume or require water for gasification. FB-DCFC employs a specialized solid oxide fuel cell (SOFC) arrangement coupled to a Boudouard gasifier where the solid fuel particles are fluidized and reacted by the anode recycle gas CO{sub 2}. The resulting CO is electrochemically oxidized at the anode. Anode supported SOFC structures employed a porous Ni cermet anode layer, a dense yttria stabilized zirconia membrane, and a mixed conducting porous perovskite cathode film. Several kinds of untreated solid fuels (carbon and coal) were tested in bench scale FBDCFC prototypes for electrochemical performance and stability testing. Single cells of tubular geometry with active areas up to 24 cm{sup 2} were fabricated. The cells achieved high power densities up to 450 mW/cm{sup 2} at 850 C using a low sulfur Alaska coal char. This represents the highest power density reported in the open literature for coal based DCFC. Similarly, power densities up to 175 mW/cm{sup 2} at 850 C were demonstrated with carbon. Electrical conversion efficiencies for coal char were experimentally determined to be 48%. Long-term stability of cell performance was measured under galvanostatic conditions for 375 hours in CO with no degradation whatsoever, indicating that carbon deposition (or coking) does not pose any problems. Similar cell stability results were obtained in coal char tested for 24 hours under galvanostatic conditions with no sign of sulfur poisoning. Moreover, a 50-cell planar stack targeted for 1 kW output was fabricated and tested in 95% CO (balance CO{sub 2}) that simulates the composition of the coal syngas. At 800 C, the stack achieved a power density of 1176 W, which represents the largest power level demonstrated for CO in the literature. Although the FB-DCFC performance results obtained in this project were definitely encouraging and promising for practical applications, DCFC approaches pose significant technical challenges that are specific to the particular DCFC scheme employed. Long term impact of coal contaminants, particularly sulfur, on the stability of cell components and cell performance is a critically important issue. Effective current collection in large area cells is another challenge. Lack of kinetic information on the Boudouard reactivity of wide ranging solid fuels, including various coals and biomass, necessitates empirical determination of such reaction parameters that will slow down development efforts. Scale up issues will also pose challenges during development of practical FB-DCFC prototypes for testing and validation. To overcome some of the more fundamental problems, initiation of federal support for DCFC is critically important for advancing and developing this exciting and promising technology for third generation electricity generation from coal, biomass and other solid fuels including waste.

Turgut Gur

2010-04-30T23:59:59.000Z

450

High efficiency carbonate fuel cell/turbine hybrid power cycle  

SciTech Connect

The hybrid power cycle studies were conducted to identify a high efficiency, economically competitive system. A hybrid power cycle which generates power at an LHV efficiency > 70% was identified that includes an atmospheric pressure direct carbonate fuel cell, a gas turbine, and a steam cycle. In this cycle, natural gas fuel is mixed with recycled fuel cell anode exhaust, providing water for reforming fuel. The mixed gas then flows to a direct carbonate fuel cell which generates about 70% of the power. The portion of the anode exhaust which is not recycled is burned and heat transferred through a heat exchanger (HX) to the compressed air from a gas turbine. The heated compressed air is then heated further in the gas turbine burner and expands through the turbine generating 15% of the power. Half the exhaust from the turbine provides air for the anode exhaust burner. All of the turbine exhaust eventually flows through the fuel cell cathodes providing the O2 and CO2 needed in the electrochemical reaction. Exhaust from the cathodes flows to a steam system (heat recovery steam generator, staged steam turbine generating 15% of the cycle power). Simulation of a 200 MW plant with a hybrid power cycle had an LHV efficiency of 72.6%. Power output and efficiency are insensitive to ambient temperature, compared to a gas turbine combined cycle; NOx emissions are 75% lower. Estimated cost of electricity for 200 MW is 46 mills/kWh, which is competitive with combined cycle where fuel cost is > $5.8/MMBTU. Key requirement is HX; in the 200 MW plant studies, a HX operating at 1094 C using high temperature HX technology currently under development by METC for coal gassifiers was assumed. A study of a near term (20 MW) high efficiency direct carbonate fuel cell/turbine hybrid power cycle has also been completed.

Steinfeld, G.; Maru, H.C. [Energy Research Corp., Danbury, CT (United States); Sanderson, R.A. [Sanderson (Robert) and Associates, Wethersfield, CT (United States)

1996-07-01T23:59:59.000Z

451

A Reversible Planar Solid Oxide Fuel-Fed Electrolysis Cell and Solid Oxide Fuel Cell for Hydrogen and Electricity Production Operating on Natural Gas/Biomass Fuels  

SciTech Connect

A solid oxide fuel-assisted electrolysis technique was developed to co-generate hydrogen and electricity directly from a fuel at a reduced cost of electricity. Solid oxide fuel-assisted electrolysis cells (SOFECs), which were comprised of 8YSZ electrolytes sandwiched between thick anode supports and thin cathodes, were constructed and experimentally evaluated at various operation conditions on lab-level button cells with 2 cm2 per-cell active areas as well as on bench-scale stacks with 30 cm2 and 100 cm2 per-cell active areas. To reduce the concentration overpotentials, pore former systems were developed and engineered to optimize the microstructure and morphology of the Ni+8YSZ-based anodes. Chemically stable cathode materials, which possess good electronic and ionic conductivity and exhibit good electrocatalytic properties in both oxidizing and reducing gas atmospheres, were developed and materials properties were investigated. In order to increase the specific hydrogen production rate and thereby reduce the system volume and capital cost for commercial applications, a hybrid system that integrates the technologies of the SOFEC and the solid-oxide fuel cell (SOFC), was developed and successfully demonstrated at a 1kW scale, co-generating hydrogen and electricity directly from chemical fuels.

Tao, Greg, G.

2007-03-31T23:59:59.000Z

452

fuel cells | OpenEI  

Open Energy Info (EERE)

cells cells Dataset Summary Description Developed for the U.S. Department of Energy's Office of Fuel Cell Technologies by Argonne National Laboratory and RCF Economic and Financial Consulting, Inc., JOBS and economic impacts of Fuel Cells (JOBS FC) is a spreadsheet model that estimates economic impacts from the manufacture and use of select types of fuel cells. Source Argonne Date Released Unknown Date Updated Unknown Keywords fuel cells Job Creation Data application/vnd.openxmlformats-officedocument.spreadsheetml.sheet icon File without Macros. Full version at official link. (xlsx, 2.8 MiB) Quality Metrics Level of Review Some Review Comment Temporal and Spatial Coverage Frequency Time Period License License Open Data Commons Attribution License Comment From Argonne National Lab

453

Fuel Cell Technologies Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Fuel Cell Technologies Program Overview Program Overview Richard Farmer Richard Farmer Acting Acting Program Program Manager Manager Acting Acting Program Program Manager Manager 2010 Annual Merit Review and Peer Evaluation Meeting 2010 Annual Merit Review and Peer Evaluation Meeting (7 June 2010) (7 June 2010) The Administration's Clean Energy Goals 9 9 Double Renewable Double Renewable Energy Capacity by 2012 9 Invest $150 billion over ten years i in energy R&D to transition to a clean energy economy clean energy economy 9 Reduce GHG emissions 83% by 2050 2 t t Æ Æ F l ll ff hi hl ffi i di f l d Fuel Cells Address Our Key Energy Challenges Increasing Energy Increasing Energy Ef ficiency and Resource Diversity Efficiency and Resource Diversity Æ Æ Fuel cells offer a highly efficient way to use diverse fuels and energy sources.

454

Fuel Cell Technologies Office: Hydrogen Technical Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Information Resources Information Resources Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Hydrogen Technical Publications to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Technical Publications on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Technical Publications on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Technical Publications on Google Bookmark Fuel Cell Technologies Office: Hydrogen Technical Publications on Delicious Rank Fuel Cell Technologies Office: Hydrogen Technical Publications on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Technical Publications on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards

455

Fuel Cell Technologies Office: Market Analysis Reports  

NLE Websites -- All DOE Office Websites (Extended Search)

Information Resources Information Resources Printable Version Share this resource Send a link to Fuel Cell Technologies Office: Market Analysis Reports to someone by E-mail Share Fuel Cell Technologies Office: Market Analysis Reports on Facebook Tweet about Fuel Cell Technologies Office: Market Analysis Reports on Twitter Bookmark Fuel Cell Technologies Office: Market Analysis Reports on Google Bookmark Fuel Cell Technologies Office: Market Analysis Reports on Delicious Rank Fuel Cell Technologies Office: Market Analysis Reports on Digg Find More places to share Fuel Cell Technologies Office: Market Analysis Reports on AddThis.com... Publications Program Publications Technical Publications Hydrogen Fuel Cells Safety, Codes & Standards Market Analysis Educational Publications Newsletter

456

DOE Hydrogen and Fuel Cell Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

eere.energy.gov eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U.S. Department of Energy Fuel Cell Technologies Program January 5, 2011 2 | Fuel Cell Technologies Program eere.energy.gov * Overview - Goals & Objectives - Technology Status & Key Challenges * Progress - Research & Development - Deployments - Recovery Act Projects * Budget * Key Publications Agenda: DOE Fuel Cell Technologies Program 3 | Fuel Cell Technologies Program eere.energy.gov Program Mission The mission of the Hydrogen and Fuel Cells Program is to enable the widespread commercialization of a portfolio of hydrogen and fuel cell technologies through basic and applied research, technology development and demonstration, and

457

Technology Validation: Fuel Cell Bus Evaluations | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Validation: Fuel Cell Bus Evaluations Technology Validation: Fuel Cell Bus Evaluations 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and...

458

Webinar: Advanced Electrocatalysts for PEM Fuel Cells  

Energy.gov (U.S. Department of Energy (DOE))

Video recording of the Fuel Cell Technologies Office webinar, Advanced Electrocatalysts for PEM Fuel Cells, originally presented on February 12, 2013.

459

Durable, Low Cost, Improved Fuel Cell Membranes  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on fuel cell membranes, was given by Michel Foure of Arkema at a meeting on new fuel cell projects in February 2007.

460

Overview of Fuel Cell Electric Bus Development  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Overview of Fuel Cell Electric Bus Development Leslie Eudy, National Renewable Energy Laboratory September 12, 2013 2 Why Fuel Cells for Transit Buses? * Reduce transit bus...

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Advancements and Opportunities for Fuel Cells  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advancements and Opportunities for Fuel Cells Fuel Cell Seminar and Energy Exposition Reuben Sarkar U.S. Department of Energy Deputy Assistant Secretary Sustainable Transportation...

462

Canadian Fuel Cell Commercialization Roadmap Update: Progress...  

Open Energy Info (EERE)

Commercialization Roadmap Update: Progress of Canada's Hydrogen and Fuel Cell Industry Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Canadian Fuel Cell...

463

Characterization of Fuel-Cell Diffusion Media  

E-Print Network (OSTI)

47 Figure 4.2 CV of PEM fuel-cell CL that shows hydrogencurrent. Figure 4.2. CV of PEM fuel-cell catalyst layer that

Gunterman, Haluna Penelope Frances

2011-01-01T23:59:59.000Z

464

Nuvera fuel cells for Fincantieri marine vessels  

Science Journals Connector (OSTI)

US-based Nuvera Fuel Cells is working with Italian shipbuilder Fincantieri on a programme to power luxury marine vessels with advanced hydrogen PEM fuel cell technology.

2013-01-01T23:59:59.000Z

465

Market Transformation: Fuel Cell Early Adoption (Presentation...  

Office of Environmental Management (EM)

Fuel Cell Technologies Office Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Safety, Codes, and Standards Education Market...

466

NREL: Hydrogen and Fuel Cells Research - News  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen and Fuel Cells News The following news stories highlight hydrogen and fuel cells research, technologies, and resources. Subscribe to the RSS feed RSS . Learn about RSS....

467

Hydrogen and Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Transportation Hydrogen and Fuel Cells Hydrogen and Fuel Cells EERE leads U.S. researchers and other partners in making transportation cleaner and more efficient through...

468

Fuel Cell & Hydrogen Technologies | Clean Energy | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies SHARE Fuel Cell and Hydrogen Technologies Oak Ridge National Laboratory pursues activities that address the barriers facing the development and deployment of...

469

Hydrogen, Fuel Cells and Infrastructure Technologies Program...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report Hydrogen, Fuel Cells and Infrastructure Technologies Program: 2002 Annual Progress Report...

470

National Fuel Cell and Hydrogen Energy Overview  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Cells Key Benefits Very High Efficiency Reduced CO 2 Emissions Reduced Oil Use Reduced Air Pollution Fuel Flexibility * > 60% (electrical) * > 70% (electrical, hybrid fuel cell...

471

Hydrogen and Fuel Cells Success Stories  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

71 Hydrogen and Fuel Cells Success Stories en Advancing Hydrogen Infrastructure and Fuel Cell Electric Vehicle http:energy.goveeresuccess-storiesarticlesadvancing-hydrogen-in...

472

Fuel Cells - Current Technology | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Current Technology Fuel Cells - Current Technology Today, fuel cells are being developed to power passenger vehicles, commercial buildings, homes, and even small devices such as...

473

Evaluation of Stationary Fuel Cell Deployments, Costs, and Fuels (Presentation)  

SciTech Connect

This presentation summarizes NREL's technology validation of stationary fuel cell systems and presents data on number of deployments, system costs, and fuel types.

Ainscough, C.; Kurtz, J.; Peters, M.; Saur, G.

2013-10-01T23:59:59.000Z

474

Webinar: Hydrogen Fueling for Current and Anticipated Fuel Cell...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

hydrogen delivery, and economic impacts of fuel cells as well as hydrogen and natural gas fueling infrastructure. Marianne will discuss a new tool for estimating the economic...

475

Development of Solid Oxide Fuel Cells Utilizing Alternative Fuels.  

E-Print Network (OSTI)

??This dissertation is a summary of four solid oxide fuel cell (SOFC) research projects which addressed a number of SOFC technologies to use alternative fuels (more)

Labarbera, Mark

2012-01-01T23:59:59.000Z

476

Nanostructured Solid Oxide Fuel Cell Electrodes  

SciTech Connect

The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

Sholklapper, Tal Zvi

2007-12-15T23:59:59.000Z

477

Corrosion resistant PEM fuel cell  

DOE Patents (OSTI)

The present invention contemplates a PEM fuel cell having electrical contact elements (including bipolar plates/septums) comprising a titanium nitride coated light weight metal (e.g., Al or Ti) core, having a passivating, protective metal layer intermediate the core and the titanium nitride. The protective layer forms a barrier to further oxidation/corrosion when exposed to the fuel cell`s operating environment. Stainless steels rich in Cr, Ni, and Mo are particularly effective protective interlayers. 6 figs.

Li, Y.; Meng, W.J.; Swathirajan, S.; Harris, S.J.; Doll, G.L.

1997-04-29T23:59:59.000Z

478

High power density fuel cell comprising an array of microchannels  

DOE Patents (OSTI)

A phosphoric acid fuel cell according to one embodiment includes an array of microchannels defined by a porous electrolyte support structure extending between bottom and upper support layers, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and air electrodes formed along other of the microchannels. A method of making a phosphoric acid fuel cell according to one embodiment includes etching an array of microchannels in a substrate, thereby forming walls between the microchannels; processing the walls to make the walls porous, thereby forming a porous electrolyte support structure; forming anode electrodes along some of the walls; forming cathode electrodes along other of the walls; and filling the porous electrolyte support structure with a phosphoric acid electrolyte. Additional embodiments are also disclosed.

Sopchak, David A; Morse, Jeffrey D; Upadhye, Ravindra S; Kotovsky, Jack; Graff, Robert T

2014-05-06T23:59:59.000Z

479

A new flow field design for polymer electrolyte-based fuel cells C. Xu, T.S. Zhao *  

E-Print Network (OSTI)

of the PEMFC system, including the water management of the cathode, have been studied extensively [1 mass transport rates of reactants and products to and from the catalyst layer and reduces the amount (PEM)-based fuel cells, including hydrogen fed PEMFCs and direct liquid metha- nol fuel cells (DMFCs

Zhao, Tianshou

480

On the effect of gas diffusion layers hydrophobicity on direct methanol fuel cell performance and degradation  

Science Journals Connector (OSTI)

Abstract Degradation and mass transport phenomena management are two of the main issues hindering direct methanol fuel cell commercialization. Water and methanol crossover through the membrane, regulated by both anode and cathode gas diffusion layers hydrophobic properties, is widely studied in the literature, while the effect of mass transport phenomena evolution on the direct methanol fuel cell degradation has not been investigated yet. This work aims to present a combined experimental and modeling analysis on the effect of the gas diffusion layers hydrophobicity on DMFC degradation, through the comparison of performance characterization and degradation tests of two different fuel cells. In one of them, the lower diffusion layer hydrophobicity and the absence of anode microporous layer determines the onset of cathode flooding, negatively affecting performance and degradation. However, the cathode surface area loss is similar between the two fuel cells, meaning that flooding does not involve modifications in cathode permanent degradation mechanisms, but it mainly determines the amplification of the cathode surface area loss effects.

F. Bresciani; C. Rabissi; M. Zago; R. Marchesi; A. Casalegno

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "fuel cell cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Calling All Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

482

Calling All Fuel Cells | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Calling All Fuel Cells Calling All Fuel Cells Calling All Fuel Cells December 7, 2012 - 4:31pm Addthis Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Altergy had more than 60 fuel cells in the immediate Hurricane Sandy disaster area that acted as backup power for cell phone towers. | Photo courtesy of Altergy. Sunita Satyapal Program Manager, Hydrogen & Fuel Cell Technology Program What is a fuel cell? A fuel cell is a device that uses a fuel and oxygen to create electricity by an electrochemical process. A fuel cell can provide energy for systems as large as a utility power station and as small as a laptop computer. During Hurricane Sandy, fuel cells were instrumental in providing backup

483

Sputter-Deposited Pt PEM Fuel Cell Electrodes: Particles vs M. D. Gasda,a  

E-Print Network (OSTI)

,c, * N. Koratkar,d G. A. Eisman,a, * and D. Galla,z a Department of Materials Science and Engineering, b as cathode electrodes in proton exchange membrane PEM fuel cells using Nafion 1135 membranes and Teflon active surface area for the particles compared to the continuous layer. Increasing w in particle cells

Gall, Daniel

484

EERE Announces Notice of Intent to Issue Fuel Cell Technologies Incubator: Innovations in Fuel Cell and Hydrogen Fuels Technologies FOA  

Energy.gov (U.S. Department of Energy (DOE))

EERE intends to issue, on behalf of its Fuel Cell Technologies Office, a Funding Opportunity Announcement (FOA) entitled "Fuel Cell Technologies Incubator: Innovations in Fuel Cell and Hydrogen Fuels Technologies."

485

Overview of Hydrogen Fuel Cell Budget  

NLE Websites -- All DOE Office Websites (Extended Search)

Budget Budget FUEL CELL TECHNOLOGIES PROGRAM Stakeholders Webinar - Budget Briefing Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager February 24, 2011 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov Fuel Cells: For Diverse Applications 3 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov INTRODUCTION: FY 2012 Budget in Brief Continues New Sub-programs for: * Fuel Cell Systems R&D - Consolidates four sub-programs: Fuel Cell Stack Components R&D, Transportation Fuel Cell Systems, Distributed Energy Fuel Cell Systems, and Fuel Processor R&D - Technology-neutral fuel cell systems R&D for diverse applications * Hydrogen Fuel R&D - Consolidates Hydrogen Production & Delivery and Hydrogen Storage activities

486

Catalyst inks and method of application for direct methanol fuel cells  

DOE Patents (OSTI)

Inks are formulated for forming anode and cathode catalyst layers and applied to anode and cathode sides of a membrane for a direct methanol fuel cell. The inks comprise a Pt catalyst for the cathode and a Pt--Ru catalyst for the anode, purified water in an amount 4 to 20 times that of the catalyst by weight, and a perfluorosulfonic acid ionomer in an amount effective to provide an ionomer content in the anode and cathode surfaces of 20% to 80% by volume. The inks are prepared in a two-step process while cooling and agitating the solutions. The final solution is placed in a cooler and continuously agitated while spraying the solution over the anode or cathode surface of the membrane as determined by the catalyst content.

Zelenay, Piotr (Los Alamos, NM); Davey, John (Los Alamos, NM); Ren, Xiaoming (Los Alamos, NM); Gottesfeld, Shimshon (Los Alamos, NM); Thomas, Sharon C. (Vancouver, CA)

2004-02-24T23:59:59.000Z

487

Pt-Based CoreShell Catalyst Architectures for Oxygen Fuel Cell Electrodes  

Science Journals Connector (OSTI)

Currently, platinum nanoparticles are the most used cathode electrode materials to catalyze the sluggish oxygen reduction reaction (ORR, O2 + 4 H+ + 4 e ? 2 H2O) to water in PEMFC systems. ... The development of DFT-based theoretical predictions of efficient ORR catalysts provided progress in our understanding of ORR activity and yielded promising catalyst materials for fuel cell experimentalists. ... This work demonstrates the essential role of particle size and crossover hydrogen on the degrdn. of platinum polymer electrolyte membrane fuel cell (PEMFC) cathodes. ...

Mehtap Oezaslan; Frdric Hasch; Peter Strasser

2013-09-12T23:59:59.000Z

488

Overview of Hydrogen and Fuel Cell Activities: February 2011...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Fuel Cell Activities: February 2011 Hydrogen and Fuel Cell Technical Advisory Committee Meeting Overview of Hydrogen and Fuel Cell Activities: February 2011 Hydrogen and Fuel...