National Library of Energy BETA

Sample records for fuel blending components

  1. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  2. Certification of alternative aviation fuels and blend components

    SciTech Connect (OSTI)

    Wilson III, George R. ); Edwards, Tim; Corporan, Edwin ); Freerks, Robert L. )

    2013-01-15

    Aviation turbine engine fuel specifications are governed by ASTM International, formerly known as the American Society for Testing and Materials (ASTM) International, and the British Ministry of Defence (MOD). ASTM D1655 Standard Specification for Aviation Turbine Fuels and MOD Defence Standard 91-91 are the guiding specifications for this fuel throughout most of the world. Both of these documents rely heavily on the vast amount of experience in production and use of turbine engine fuels from conventional sources, such as crude oil, natural gas condensates, heavy oil, shale oil, and oil sands. Turbine engine fuel derived from these resources and meeting the above specifications has properties that are generally considered acceptable for fuels to be used in turbine engines. Alternative and synthetic fuel components are approved for use to blend with conventional turbine engine fuels after considerable testing. ASTM has established a specification for fuels containing synthesized hydrocarbons under D7566, and the MOD has included additional requirements for fuels containing synthetic components under Annex D of DS91-91. New turbine engine fuel additives and blend components need to be evaluated using ASTM D4054, Standard Practice for Qualification and Approval of New Aviation Turbine Fuels and Fuel Additives. This paper discusses these specifications and testing requirements in light of recent literature claiming that some biomass-derived blend components, which have been used to blend in conventional aviation fuel, meet the requirements for aviation turbine fuels as specified by ASTM and the MOD. The 'Table 1' requirements listed in both D1655 and DS91-91 are predicated on the assumption that the feedstocks used to make fuels meeting these requirements are from approved sources. Recent papers have implied that commercial jet fuel can be blended with renewable components that are not hydrocarbons (such as fatty acid methyl esters). These are not allowed blend

  3. Ethanol-blended Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ethanol-Blended Fuels A Study Guide and Overview of: * Ethanol's History in the U.S. and Worldwide * Ethanol Science and Technology * Engine Performance * Environmental Effects * Economics and Energy Security The Curriculum This curriculum on ethanol and its use as a fuel was developed by the Clean Fuels Development Coalition in cooperation with the Nebraska Ethanol Board. This material was developed in response to the need for instructional materials on ethanol and its effects on vehicle

  4. Alternative Fuels Data Center: Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blends to someone by E-mail Share Alternative Fuels Data Center: Ethanol Blends on Facebook Tweet about Alternative Fuels Data Center: Ethanol Blends on Twitter Bookmark Alternative Fuels Data Center: Ethanol Blends on Google Bookmark Alternative Fuels Data Center: Ethanol Blends on Delicious Rank Alternative Fuels Data Center: Ethanol Blends on Digg Find More places to share Alternative Fuels Data Center: Ethanol Blends on AddThis.com... More in this section... Ethanol Basics Blends E15

  5. Alternative Fuels Data Center: Biodiesel Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Blends to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Blends on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Blends on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Blends on Google Bookmark Alternative Fuels Data Center: Biodiesel Blends on Delicious Rank Alternative Fuels Data Center: Biodiesel Blends on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Blends on AddThis.com... More in this section... Biodiesel Basics

  6. Low-Level Ethanol Fuel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    This fact sheet addresses: (a) why Clean Cities promotes ethanol blends; (b) how these blends affect emissions; (c) fuel performance and availability; and (d) cost, incentives, and regulations.

  7. Impact of Biodiesel on Fuel System Component Durability

    SciTech Connect (OSTI)

    Terry, B.

    2005-09-01

    A study of the effects of biodiesel blends on fuel system components and the physical characteristics of elastomer materials.

  8. Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HCCI Exhaust Speciation - ORNL Reference Fuel Blends Detailed HCCI Exhaust Speciation - ORNL Reference Fuel Blends *Accurately measure exhaust profile from an HCCI engine with a ...

  9. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications Title A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition...

  10. Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Injection | Department of Energy Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Supercritical dieseline could be used in diesel engines having efficient fuel systems and combustion chamber designs that decrease fuel consumption and mitigate emissions. p-02_anitescu.pdf (339.45 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of

  11. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  12. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally

  13. Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines

    SciTech Connect (OSTI)

    Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

    1999-05-05

    Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

  14. Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) to someone by E-mail Share Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and Mid-Level Blends Testing (August 2009) on Facebook Tweet about Alternative Fuels Data Center: Status Update: New Mid-Level Ethanol Blends Certification Path, UL Meeting, and

  15. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However

  16. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  17. Powertrain Component Inspection from Mid-Level Blends Vehicle Aging Study

    SciTech Connect (OSTI)

    Shoffner, Brent; Johnson, Ryan; Heimrich, Martin J.; Lochte, Michael

    2010-11-01

    The Energy Independence and Security Act of 2007 calls on the nation to significantly increase its use of renewable fuels to meet its transportation energy needs. The law expands the renewable fuel standard to require use of 36 billion gallons of renewable fuel by 2022. Given that ethanol is the most widely used renewable fuel in the U.S. market, ethanol will likely make up a significant portion of the 36-billion-gallon requirement. The vast majority of ethanol used in the United States is blended with gasoline to create E10-gasoline with up to 10% ethanol. The remaining ethanol is sold in the form of E85 - a gasoline blend with as much as 85% ethanol that can only be used in flexible-fuel vehicles (FFVs). Consumption of E85 is at present limited by both the size of the FFV fleet and the number of E85 fueling stations. Gasoline consumption in the United States is currently about 140 billion gallons per year; thus the maximum use of ethanol as E10 is only about 14 billion gallons. While the U.S. Department of Energy (DOE) remains committed to expanding the E85 infrastructure, that market represented less than 1% of the ethanol consumed in 2010 and will not be able to absorb projected volumes of ethanol in the near term. Because of these factors, DOE and others have been assessing the viability of using mid-level ethanol blends (E15 or E20) as a way to accommodate growing volumes of ethanol. The DOE Mid-Level Ethanol Blends Test Program has been under way since 2007, supported jointly by the Office of the Biomass Program and the Vehicle Technologies Program. One of the larger projects, the Catalyst Durability Study, or Vehicle Aging Study, will be completed early in calendar year 2011. The following report describes a subproject of the Vehicle Aging Study in which powertrain components from 18 of the vehicles were examined at Southwest Research Institute under contract to Oak Ridge National Laboratory (ORNL).

  18. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications | Department of Energy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Heavy Alcohols as a Fuel Blending Agent for Compression Ignition Engine Applications Blends of Phytol and diesel (by volume) were compared against baseline diesel experiments and simulations p-21_ramirez.pdf (351.23 KB) More Documents & Publications HD Applications of Significantly Downsized SI Engines Using Alcohol DI for Knock Avoidance Characterization of Dual-Fuel

  19. Identification and quantification of organic chemicals in supplemental fuel blends

    SciTech Connect (OSTI)

    Salter, F.

    1996-12-31

    Continental Cement Company, Inc. (Continental) burns waste fuels to supplement coal in firing the kiln. It is to be expected that federal and state agencies want an accounting of the chemicals burned. As rules and regulations become more plentiful, a company such as Continental must demonstrate that it has made a reasonable attempt to identify and quantify many specific organic compounds. The chemicals on the SARA 313 list can change frequently. Also the number and concentrations of compounds that can disqualify a material from consideration as a supplemental fuel at Continental continues to change. A quick and reliable method of identifying and quantifying organics in waste fuel blends is therefore crucial. Using a Hewlett-Packard 5972 GC/MS system Continental has developed a method of generating values for the total weight of compounds burned. A similar procedure is used to verify that waste streams meet Continental`s acceptance criteria.

  20. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre L. Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2002-07-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. This project complements another ongoing project titled ''Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus Demonstration Project''. The objectives of that research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, they have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, the activities have covered two areas: development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward completion of both experimental systems and a summary of the plan for completion of the project objectives.

  1. DAVID Fuel Cell Components SL | Open Energy Information

    Open Energy Info (EERE)

    manufacture and marketing of components and devices for PEM fuel cells, direct methanol fuel cells (DMFC) and fuel reformers. References: DAVID Fuel Cell Components SL1...

  2. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2004-04-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. Our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. The first two of these areas have resulted in valuable information about the limitations of lubricity and viscosity additives that are presently available in terms of their impact on the viscosity of DME and on wear rates on injector hardware. The third area, that of development of an injector durability test stand, has not resulted in a functioning experiment. Some information is provided in this report to identify the remaining tasks that need to be performed to make the injector stand operational. The key observations from the work are that when blended at 25 wt.% in either diesel fuel or Biodiesel fuel, DME requires more than 5 wt

  3. IMPACT OF DME-DIESEL FUEL BLEND PROPERTIES ON DIESEL FUEL INJECTION SYSTEMS

    SciTech Connect (OSTI)

    Elana M. Chapman; Andre Boehman; Kimberly Wain; Wallis Lloyd; Joseph M. Perez; Donald Stiver; Joseph Conway

    2003-06-01

    The objectives of this research program are to develop information on lubricity and viscosity improvers and their impact on the wear mechanisms in fuel injectors operating on blends of dimethyl ether (DME) and diesel fuel. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In the shuttle bus project, we have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Our strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. In this project, we have sought to develop methods for extending the permissible DME content in the DME-diesel blends without experiencing rapid injector failure due to wear. To date, our activities have covered three areas: examination of the impact of lubricity additives on the viscosity of DME, development of a high-pressure lubricity test apparatus for studies of lubricity and viscosity improvers and development of an injector durability stand for evaluation of wear rates in fuel injectors. This report provides summaries of the progress toward evaluation of the viscosity impacts of lubricity additives, completion of both experimental systems and a summary of the plan for completion of the project objectives.

  4. Impacts of Biodiesel Fuel Blends Oil Dilution on Light-Duty Diesel Engine Operation

    SciTech Connect (OSTI)

    Thornton, M. J.; Alleman, T. L.; Luecke, J.; McCormick, R. L.

    2009-08-01

    Assesses oil dilution impacts on a diesel engine operating with a diesel particle filter, NOx storage, a selective catalytic reduction emission control system, and a soy-based 20% biodiesel fuel blend.

  5. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay Keller of Sandia National Laboratories at the CNG and Hydrogen Lessons Learned Workshop on December 10, 2009 cng_h2_workshop_2_keller.pdf (3.5 MB) More Documents & Publications US DRIVE Hydrogen Codes and Standards Technical Team Roadmap Hydrogen Release Behavior Overview of HyRAM (Hydrogen

  6. Fueling Components Testing and Certification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standards and Codes * National Recognized Standards * Enforceable Docs by 2012 * Code Cycle 2012 Vehicles ∙ Commercialization 2015 ∙ 50,000 by 2017 ∙ Consumer price ∙ 80% in CA Infrastructure ∙ 200 Stations in CA ∙ Accurate and Safe Equipment ∙ Commercial Venture ∙ Station Certification Implementation ∙ Component Certification * Public Awareness * General Education ∙ Technician Training ∙ Safety, Reliability and Accurate Evolving Hydrogen Vehicle Industry 3 Time Line -

  7. Densified edge seals for fuel cell components

    DOE Patents [OSTI]

    DeCasperis, Anthony J.; Roethlein, Richard J.; Breault, Richard D.

    1982-01-01

    A porous fuel cell component, such as an electrode substrate, has a densified edge which forms an improved gas seal during operation when soaked with electrolyte. The edges are made from the same composition as the rest of the component and are made by compressing an increased thickness of this material along the edges during the fabrication process.

  8. Heavy Alcohols as a Fuel Blending Agent for Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoidance Characterization of Dual-Fuel Reactivity Controlled Compression Ignition (RCCI) Using Hydrated Ethanol and Diesel Fuel BiodieselFuelManagementBestPracticesReport.pdf

  9. Mid-Blend Ethanol Fuels – Implementation Perspectives

    Broader source: Energy.gov [DOE]

    Breakout Session 2: Frontiers and Horizons Session 2–B: End Use and Fuel Certification Bill Woebkenberg, Fuels Technical and Regulatory Affairs Senior Engineer, Mercedes-Benz

  10. Detailed HCCI Exhaust Speciation- ORNL Reference Fuel Blends

    Broader source: Energy.gov [DOE]

    ·Accurately measure exhaust profile from an HCCI engine with a variety of fuels and create a better understanding of HCCI engine emissions.

  11. NREL UL Fuel Dispensing Infrastructure Intermediate Blends Performance Testing (Presentation)

    SciTech Connect (OSTI)

    Moriarty, K.; Clark, W.

    2011-01-01

    Presentation provides an overview of NREL's project to determine compatibility and safe performance of installed fuel dispensing infrastructure with E15.

  12. Volatility of Gasoline and Diesel Fuel Blends for Supercritical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Evaluation of Biodiesel Fuels from Supercritical Fluid Processing with the Advanced ...

  13. NMOG Emissions Characterizations and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2011-10-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were

  14. NMOG Emissions Characterization and Estimation for Vehicles Using Ethanol-Blended Fuels

    SciTech Connect (OSTI)

    Sluder, Scott; West, Brian H

    2012-01-01

    Ethanol is a biofuel commonly used in gasoline blends to displace petroleum consumption; its utilization is on the rise in the United States, spurred by the biofuel utilization mandates put in place by the Energy Independence and Security Act of 2007 (EISA). The United States Environmental Protection Agency (EPA) has the statutory responsibility to implement the EISA mandates through the promulgation of the Renewable Fuel Standard. EPA has historically mandated an emissions certification fuel specification that calls for ethanol-free fuel, except for the certification of flex-fuel vehicles. However, since the U.S. gasoline marketplace is now virtually saturated with E10, some organizations have suggested that inclusion of ethanol in emissions certification fuels would be appropriate. The test methodologies and calculations contained in the Code of Federal Regulations for gasoline-fueled vehicles have been developed with the presumption that the certification fuel does not contain ethanol; thus, a number of technical issues would require resolution before such a change could be accomplished. This report makes use of the considerable data gathered during the mid-level blends testing program to investigate one such issue: estimation of non-methane organic gas (NMOG) emissions. The data reported in this paper were gathered from over 600 cold-start Federal Test Procedure (FTP) tests conducted on 68 vehicles representing 21 models from model year 2000 to 2009. Most of the vehicles were certified to the Tier-2 emissions standard, but several older Tier-1 and national low emissions vehicle program (NLEV) vehicles were also included in the study. Exhaust speciation shows that ethanol, acetaldehyde, and formaldehyde dominate the oxygenated species emissions when ethanol is blended into the test fuel. A set of correlations were developed that are derived from the measured non-methane hydrocarbon (NMHC) emissions and the ethanol blend level in the fuel. These correlations were

  15. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2014-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  16. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect (OSTI)

    Andile B. Mzinyati

    2007-09-15

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  17. Low-temperature pyrolysis of coal to produce diesel-fuel blends

    SciTech Connect (OSTI)

    Shafer, T.B.; Jett, O.J.; Wu, J.S.

    1982-10-01

    Low-temperature (623 to 773/sup 0/K) coal pyrolysis was investigated in a bench-scale retort. Factorially designed experiments were conducted to determine the effects of temperature, coal-particle size, and nitrogen flow rate on the yield of liquid products. Yield of condensable organic products relative to the proximate coal volatile matter increased by 3.1 and 6.4 wt % after increasing nitrogen purge flow rate from 0.465 to 1.68 L/min and retort temperature from 623 to 723/sup 0/K, respectively. The liquid product may be suitable for blending with diesel fuel. The viscosity and density of coal liquids produced at 723/sup 0/K were compared with those of diesel fuel. The coal liquids had a higher carbon-to-hydrogen ratio and a lower aliphatic-to-aromatic ratio than premium quality No. 2 diesel fuel. It was recommended that liquids from coal pyrolysis be blended with diesel fuel to determine stability of the mixture and performance of the blend in internal combustion engines.

  18. A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.

    2013-05-10

    spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  19. Fuel Cell Animation- Fuel Cell Components (Text Version)

    Broader source: Energy.gov [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts.

  20. Fueling Components Testing and Certification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fueling Components Testing and Certification Fueling Components Testing and Certification These slides were presented at the Onboard Storage Tank Workshop on April 29, 2010. componentstesting_certification_ostw.pdf (257.49 KB) More Documents & Publications CSA International Certification Discussion Hydrogen Technology Workshop Component and System Qualification Workshop Proceedings CODES & STANDARDS FOR THE HYDROGEN ECONOMY

  1. DOE Technical Targets for Polymer Electrolyte Membrane Fuel Cell Components

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Polymer Electrolyte Membrane Fuel Cell Components DOE Technical Targets for Polymer Electrolyte Membrane Fuel Cell Components These tables list the U.S. Department of Energy (DOE) technical targets for polymer electrolyte membrane (PEM) fuel cell components: membrane electrode assemblies, membranes, electrocatalysts, and bipolar plates. These targets have been developed with input from the U.S. DRIVE Partnership, which includes automotive and energy companies, and

  2. NREL: Hydrogen and Fuel Cells Research - Hydrogen System Component

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation System Component Validation NREL's hydrogen system component validation studies focus on improving the reliability of compressors and other hydrogen system components. Reliable components are needed to ensure the success of hydrogen fueling stations and support the commercial deployment of fuel cell electric vehicles and material handling equipment. NREL's technology validation team is collaborating with industry to test and validate the commercial readiness of hydrogen system

  3. Consumer Choice of E85 Denatured Ethanol Fuel Blend: Price Sensitivity and Cost of Limited Fuel Availability

    SciTech Connect (OSTI)

    Liu, Changzheng; Greene, David

    2014-12-01

    The promotion of greater use of E85, a fuel blend of 85% denatured ethanol, by flex-fuel vehicle owners is an important means of complying with the Renewable Fuel Standard 2. A good understanding of factors affecting E85 demand is necessary for effective policies that promote E85 and for developing models that forecast E85 sales in the United States. In this paper, the sensitivity of aggregate E85 demand to E85 and gasoline prices is estimated, as is the relative availability of E85 versus gasoline. The econometric analysis uses recent data from Minnesota, North Dakota, and Iowa. The more recent data allow a better estimate of nonfleet demand and indicate that the market price elasticity of E85 choice is substantially higher than previously estimated.

  4. Consumer Choice of E85 Denatured Ethanol Fuel Blend: Price Sensitivity and Cost of Limited Fuel Availability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Changzheng; Greene, David

    2014-12-01

    The promotion of greater use of E85, a fuel blend of 85% denatured ethanol, by flex-fuel vehicle owners is an important means of complying with the Renewable Fuel Standard 2. A good understanding of factors affecting E85 demand is necessary for effective policies that promote E85 and for developing models that forecast E85 sales in the United States. In this paper, the sensitivity of aggregate E85 demand to E85 and gasoline prices is estimated, as is the relative availability of E85 versus gasoline. The econometric analysis uses recent data from Minnesota, North Dakota, and Iowa. The more recent data allowmore » a better estimate of nonfleet demand and indicate that the market price elasticity of E85 choice is substantially higher than previously estimated.« less

  5. Preliminary report on blending strategies for inert-matrix fuel recycling in LWRs.

    SciTech Connect (OSTI)

    Hoffman, E. A.; Nuclear Engineering Division

    2005-04-29

    Various recycle strategies have been proposed to manage the inventory of transuranics in commercial spent nuclear fuel (CSNF), with a particular goal of increasing the loading capacity of spent fuel and reprocessing wastes in the Yucca Mountain repository. Transuranic recycling in commercial LWRs can be seen as a viable means of slowing the accumulation of transuranics in the nationwide CSNF stockpile. Furthermore, this type of approach is an important first step in demonstrating the benefits of a nuclear fuel cycle which incorporates recycling, such as envisioned for Generation-IV reactor systems under development. Recycling strategies of this sort are not proposed as an attempt to eliminate the need of a geologic nuclear waste repository, but as a means to enhance the usefulness of the repository currently under construction in the U.S., perhaps circumventing the need for a second facility. A US-DOE Secretarial recommendation on the need for the construction of a second geologic repository is required by 2010. The Advanced Fuel Cycle Initiative (AFCI) has supported a breadth of work to evaluate the ideal transuranic separation and recycle strategy. Previous AFCI studies of LWR-based transmutation have considered the benefits of homogeneously recycling plutonium, plutonium and neptunium, and all transuranic (TRU) species. A study of a wide range of hypothetical separation schemes (Pu, Pu+Np, Pu+Np+Am, etc.) with multi-recycling has also been performed, focusing on the proliferation resistance of the various fuel cycles and fuel handling issues. The direct recycle of the recovered TRU from spent inert-matrix fuel (IMF) into new IMF was found to be quite limited due to the rapid burndown of the fissile plutonium. The IMF is very effective at destroying the fissile fraction of the TRU with destruction rates in excess of 80% of the fissile material without recycling the IMF. Blending strategies have been proposed to mitigate the rapid burndown of the fissile plutonium

  6. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  7. Upcoming H2USA Workshop: Hydrogen Fueling Station Component Listings

    Broader source: Energy.gov [DOE]

    H2USA will host an online workshop about hydrogen fueling station component listings on April 22 from 2 to 3:30 p.m. Eastern Daylight Time. This workshop will focus on the need for components for hydrogen fueling stations to be listed by Nationally Recognized Testing Laboratories (NRTLs).

  8. Compatibility Study for Plastic, Elastomeric, and Metallic Fueling Infrastructure Materials Exposed to Aggressive Formulations of Ethanol-blended Gasoline

    SciTech Connect (OSTI)

    Kass, Michael D; Pawel, Steven J; Theiss, Timothy J; Janke, Christopher James

    2012-07-01

    In 2008 Oak Ridge National Laboratory began a series of experiments to evaluate the compatibility of fueling infrastructure materials with intermediate levels of ethanol-blended gasoline. Initially, the focus was elastomers, metals, and sealants, and the test fuels were Fuel C, CE10a, CE17a and CE25a. The results of these studies were published in 2010. Follow-on studies were performed with an emphasis on plastic (thermoplastic and thermoset) materials used in underground storage and dispenser systems. These materials were exposed to test fuels of Fuel C and CE25a. Upon completion of this effort, it was felt that additional compatibility data with higher ethanol blends was needed and another round of experimentation was performed on elastomers, metals, and plastics with CE50a and CE85a test fuels. Compatibility of polymers typically relates to the solubility of the solid polymer with a solvent. It can also mean susceptibility to chemical attack, but the polymers and test fuels evaluated in this study are not considered to be chemically reactive with each other. Solubility in polymers is typically assessed by measuring the volume swell of the polymer exposed to the solvent of interest. Elastomers are a class of polymers that are predominantly used as seals, and most o-ring and seal manufacturers provide compatibility tables of their products with various solvents including ethanol, toluene, and isooctane, which are components of aggressive oxygenated gasoline as described by the Society of Automotive Engineers (SAE) J1681. These tables include a ranking based on the level of volume swell in the elastomer associated with exposure to a particular solvent. Swell is usually accompanied by a decrease in hardness (softening) that also affects performance. For seal applications, shrinkage of the elastomer upon drying is also a critical parameter since a contraction of volume can conceivably enable leakage to occur. Shrinkage is also indicative of the removal of one or more

  9. Effects of High Octane Ethanol Blends on Four Legacy Flex-Fuel Vehicles, and a Turbocharged GDI Vehicle

    SciTech Connect (OSTI)

    Thomas, John F; West, Brian H; Huff, Shean P

    2015-03-01

    The U.S. Department of Energy (DOE) is supporting engine and vehicle research to investigate the potential of high-octane fuels to improve fuel economy. Ethanol has very high research octane number (RON) and heat of vaporization (HoV), properties that make it an excellent spark ignition engine fuel. The prospects of increasing both the ethanol content and the octane number of the gasoline pool has the potential to enable improved fuel economy in future vehicles with downsized, downsped engines. This report describes a small study to explore the potential performance benefits of high octane ethanol blends in the legacy fleet. There are over 17 million flex-fuel vehicles (FFVs) on the road today in the United States, vehicles capable of using any fuel from E0 to E85. If a future high-octane blend for dedicated vehicles is on the horizon, the nation is faced with the classic chicken-and-egg dilemma. If today’s FFVs can see a performance advantage with a high octane ethanol blend such as E25 or E30, then perhaps consumer demand for this fuel can serve as a bridge to future dedicated vehicles. Experiments were performed with four FFVs using a 10% ethanol fuel (E10) with 88 pump octane, and a market gasoline blended with ethanol to make a 30% by volume ethanol fuel (E30) with 94 pump octane. The research octane numbers were 92.4 for the E10 fuel and 100.7 for the E30 fuel. Two vehicles had gasoline direct injected (GDI) engines, and two featured port fuel injection (PFI). Significant wide open throttle (WOT) performance improvements were measured for three of the four FFVs, with one vehicle showing no change. Additionally, a conventional (non-FFV) vehicle with a small turbocharged direct-injected engine was tested with a regular grade of gasoline with no ethanol (E0) and a splash blend of this same fuel with 15% ethanol by volume (E15). RON was increased from 90.7 for the E0 to 97.8 for the E15 blend. Significant wide open throttle and thermal efficiency performance

  10. Methanol/ethanol/gasoline blend-fuels demonstration with stratified-charge-engine vehicles: Consultant report. Final report

    SciTech Connect (OSTI)

    Pefley, R.; Adelman, H.; Suga, T.

    1980-03-01

    Four 1978 Honda CVCC vehicles have been in regular use by California Energy Commission staff in Sacramento for 12 months. Three of the unmodified vehicles were fueled with alcohol/gasoline blends (5% methanol, 10% methanol, and 10% ethanol) with the fourth remaining on gasoline as a control. The operators did not know which fuels were in the vehicles. At 90-day intervals the cars were returned to the Univerity of Santa Clara for servicing and for emissions and fuel economy testing in accordance with the Federal Test Procedures. The demonstration and testing have established the following: (1) the tested blends cause no significant degradation in exhaust emissions, fuel economy, and driveability; (2) the tested blends cause significant increases in evaporative emissions; (3) analysis of periodic oil samples shows no evidence of accelerated metal wear; and (4) higher than 10% alcohols will require substantial modification to most existing California motor vehicles for acceptable emissions, performance, and fuel economy. Many aspects of using methanol and ethanol fuels, both straight and in blends, in various engine technologies are discussed.

  11. Fuel and Fuel Additive Registration Testing of Ethanol-Diesel Blend for O2Diesel, Inc.

    SciTech Connect (OSTI)

    Fanick, E. R.

    2004-02-01

    O2 Diesel Inc. (formerly AAE Technologies Inc.) tested a heavy duty engine with O2Diesel (diesel fuel with 7.7% ethanol and additives) for regulated emissions and speciation of vapor-phase and semi-volatile hydrocarbon compounds. This testing was performed in support of EPA requirements for registering designated fuels and fuel additives as stipulated by sections 211(b) and 211(e) of the Clean Air Act.

  12. Plasma-Enhanced Combustion of Hydrocarbon Fuels and Fuel Blends Using Nanosecond Pulsed Discharges

    SciTech Connect (OSTI)

    Cappelli, Mark; Mungal, M Godfrey

    2014-10-28

    This project had as its goals the study of fundamental physical and chemical processes relevant to the sustained premixed and non-premixed jet ignition/combustion of low grade fuels or fuels under adverse flow conditions using non-equilibrium pulsed nanosecond discharges.

  13. Electrochemical sensor for monitoring electrochemical potentials of fuel cell components

    DOE Patents [OSTI]

    Kunz, Harold R.; Breault, Richard D.

    1993-01-01

    An electrochemical sensor comprised of wires, a sheath, and a conduit can be utilized to monitor fuel cell component electric potentials during fuel cell shut down or steady state. The electrochemical sensor contacts an electrolyte reservoir plate such that the conduit wicks electrolyte through capillary action to the wires to provide water necessary for the electrolysis reaction which occurs thereon. A voltage is applied across the wires of the electrochemical sensor until hydrogen evolution occurs at the surface of one of the wires, thereby forming a hydrogen reference electrode. The voltage of the fuel cell component is then determined with relation to the hydrogen reference electrode.

  14. Method of forming densified edge seals for fuel cell components

    DOE Patents [OSTI]

    DeCasperis, Anthony J.; Roethlein, Richard J.; Breault, Richard D.

    1981-01-01

    A porous fuel cell component, such as an electrode substrate, has a densified edge which forms an improved gas seal during operation when soaked with electrolyte. The edges are made from the same composition as the rest of the component and are made by compressing an increased thickness of this material along the edges during the fabrication process.

  15. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2010-05-15

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet-stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines. (author)

  16. Chlorinated organic compounds evolved during the combustion of blends of refuse-derived fuels and coals

    SciTech Connect (OSTI)

    Xiaodong Yang; Napier, J.; Sisk, B.; Wei-Ping Pan; Riley, J.T.; Lloyd, W.G.

    1996-12-31

    The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR and MS systems. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GUMS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic; compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

  17. Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate.

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2009-07-21

    Detailed chemical kinetic mechanisms were developed and used to study the oxidation of two large unsaturated esters: methyl-5-decenoate and methyl-9-decenoate. These models were built from a previous methyl decanoate mechanism and were compared with rapeseed oil methyl esters oxidation experiments in a jet stirred reactor. A comparative study of the reactivity of these three oxygenated compounds was performed and the differences in the distribution of the products of the reaction were highlighted showing the influence of the presence and the position of a double bond in the chain. Blend surrogates, containing methyl decanoate, methyl-5-decenoate, methyl-9-decenoate and n-alkanes, were tested against rapeseed oil methyl esters and methyl palmitate/n-decane experiments. These surrogate models are realistic kinetic tools allowing the study of the combustion of biodiesel fuels in diesel and homogeneous charge compression ignition engines.

  18. Autoignition response of n-butanol and its blend with primary reference fuel constituents of gasoline.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Kamal; Zhang, Yu; Sung, Chi -Jen; Pitz, William J.

    2015-04-13

    We study the influence of blending n-butanol on the ignition delay times of n-heptane and iso-octane, the primary reference fuels for gasoline. The ignition delay times are measured using a rapid compression machine, with an emphasis on the low-to-intermediate temperature conditions. The experiments are conducted at equivalence ratios of 0.4 and 1.0, for a compressed pressure of 20 bar, with the temperatures at the end of compression ranging from 613 K to 979 K. The effect of n-butanol addition on the development of the two-stage ignition characteristics for the two primary reference fuels is also examined. The experimental results aremore » compared to predictions obtained using a detailed chemical kinetic mechanism, which has been obtained by a systematic merger of previously reported base models for the combustion of the individual fuel constituents. In conclusion, a sensitivity analysis on the base, and the merged models, is also performed to understand the dependence of autoignition delay times on the model parameters.« less

  19. Emissions with butane/propane blends

    SciTech Connect (OSTI)

    1996-11-01

    This article reports on various aspects of exhaust emissions from a light-duty car converted to operate on liquefied petroleum gas and equipped with an electrically heated catalyst. Butane and butane/propane blends have recently received attention as potentially useful alternative fuels. Butane has a road octane number of 92, a high blending vapor pressure, and has been used to upgrade octane levels of gasoline blends and improve winter cold starts. Due to reformulated gasoline requirements for fuel vapor pressure, however, industry has had to remove increasing amounts of butane form the gasoline pool. Paradoxically, butane is one of the cleanest burning components of gasoline.

  20. Emission Characteristics of a Diesel Engine Operating with In-Cylinder Gasoline and Diesel Fuel Blending

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Curran, Scott; Barone, Teresa L; Lewis Sr, Samuel Arthur; Storey, John Morse; Cho, Kukwon; Wagner, Robert M; Parks, II, James E

    2010-01-01

    Advanced combustion regimes such as homogeneous charge compression ignition (HCCI) and premixed charge compression ignition (PCCI) offer benefits of reduced nitrogen oxides (NOx) and particulate matter (PM) emissions. However, these combustion strategies often generate higher carbon monoxide (CO) and hydrocarbon (HC) emissions. In addition, aldehydes and ketone emissions can increase in these modes. In this study, the engine-out emissions of a compression-ignition engine operating in a fuel reactivity- controlled PCCI combustion mode using in-cylinder blending of gasoline and diesel fuel have been characterized. The work was performed on a 1.9-liter, 4-cylinder diesel engine outfitted with a port fuel injection system to deliver gasoline to the engine. The engine was operated at 2300 rpm and 4.2 bar brake mean effective pressure (BMEP) with the ratio of gasoline to diesel fuel that gave the highest engine efficiency and lowest emissions. Engine-out emissions for aldehydes, ketones and PM were compared with emissions from conventional diesel combustion. Sampling and analysis was carried out following micro-tunnel dilution of the exhaust. Particle geometric mean diameter, number-size distribution, and total number concentration were measured by a scanning mobility particle sizer (SMPS). For the particle mass measurements, samples were collected on Teflon-coated quartz-fiber filters and analyzed gravimetrically. Gaseous aldehydes and ketones were sampled using dinitrophenylhydrazine-coated solid phase extraction cartridges and the extracts were analyzed by liquid chromatography/mass spectrometry (LC/MS). In addition, emissions after a diesel oxidation catalyst (DOC) were also measured to investigate the destruction of CO, HC and formaldehydes by the catalyst.

  1. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    D. Straub; D. Ferguson; K. Casleton; G. Richards

    2006-03-01

    U.S. natural gas composition is expected to be more variable in the future. Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Unconventional gas supplies, like coal-bed methane, are also expected to grow. As a result of these anticipated changes, the composition of fuel sources may vary significantly from existing domestic natural gas supplies. To allow the greatest use of gas supplies, end-use equipment should be able to accommodate the widest possible gas composition. For this reason, the effect of gas composition on combustion behavior is of interest. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 589K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx emissions. These results vary from data reported in the literature for some engine applications and potential reasons for these differences are discussed.

  2. Fuzzy linear programming based optimal fuel scheduling incorporating blending/transloading facilities

    SciTech Connect (OSTI)

    Djukanovic, M.; Babic, B.; Milosevic, B.; Sobajic, D.J.; Pao, Y.H. |

    1996-05-01

    In this paper the blending/transloading facilities are modeled using an interactive fuzzy linear programming (FLP), in order to allow the decision-maker to solve the problem of uncertainty of input information within the fuel scheduling optimization. An interactive decision-making process is formulated in which decision-maker can learn to recognize good solutions by considering all possibilities of fuzziness. The application of the fuzzy formulation is accompanied by a careful examination of the definition of fuzziness, appropriateness of the membership function and interpretation of results. The proposed concept provides a decision support system with integration-oriented features, whereby the decision-maker can learn to recognize the relative importance of factors in the specific domain of optimal fuel scheduling (OFS) problem. The formulation of a fuzzy linear programming problem to obtain a reasonable nonfuzzy solution under consideration of the ambiguity of parameters, represented by fuzzy numbers, is introduced. An additional advantage of the FLP formulation is its ability to deal with multi-objective problems.

  3. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  4. CLASSIFICATION OF THE MGR NON-FUEL COMPONENTS DISPOSAL CONTAINER

    SciTech Connect (OSTI)

    J.A. Ziegler

    1999-08-31

    The purpose of this analysis is to document the Quality Assurance (QA) classification of the Monitored Geologic Repository (MGR) non-fuel components disposal container system structures, systems and components (SSCs) performed by the MGR Safety Assurance Department. This analysis also provides the basis for revision of YMP/90-55Q, Q-List (YMP 1998). The Q-List identifies those MGR SSCs subject to the requirements of DOE/RW-0333P, ''Quality Assurance Requirements and Description'' (QARD) (DOE 1998).

  5. IMHEX fuel cell repeat component manufacturing continuous improvement accomplishments

    SciTech Connect (OSTI)

    Jakaitis, L.A.; Petraglia, V.J.; Bryson, E.S.

    1996-12-31

    M-C Power is taking a power generation technology that has been proven in the laboratory and is making it a commercially competitive product. There are many areas in which this technology required scale up and refinement to reach the market entry goals for the IMHEX{reg_sign} molten carbonate fuel cell power plant. One of the primary areas that needed to be addressed was the manufacturing of the fuel cell stack. Up to this point, the fuel cell stack and associated components were virtually hand made for each system to be tested. M-C Power has now continuously manufactured the repeat components for three 250 kW stacks. M-C Power`s manufacturing strategy integrated both evolutionary and revolutionary improvements into its comprehensive commercialization effort. M-C Power`s objectives were to analyze and continuously improve stack component manufacturing and assembly techniques consistent with established specifications and commercial scale production requirements. Evolutionary improvements are those which naturally occur as the production rates are increased and experience is gained. Examples of evolutionary (learning curve) improvements included reducing scrap rates and decreasing raw material costs by buying in large quantities. Revolutionary improvements result in significant design and process changes to meet cost and performance requirements of the market entry system. Revolutionary changes often involve identifying new methods and developing designs to accommodate the new process. Based upon our accomplishments, M-C Power was able to reduce the cost of continuously manufactured fuel cell repeat components from the first to third 250 kW stack by 63%. This paper documents the continuous improvement accomplishments realized by M-C Power during IMHEX{reg_sign} fuel cell repeat component manufacturing.

  6. Fuel Tables.indd

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Where shown, (s) Btu value less than 0.05. Notes: Motor gasoline estimates include fuel ethanol blended into motor gasoline. * Totals may not equal sum of components due to ...

  7. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  8. A Multicomponent Blend as a Diesel Fuel Surrogate for Compression Ignition Engine Applications

    SciTech Connect (OSTI)

    Pei, Yuanjiang; Mehl, Marco; Liu, Wei; Lu, Tianfeng; Pitz, William J.; Som, Sibendu

    2015-05-12

    A mixture of n-dodecane and m-xylene is investigated as a diesel fuel surrogate for compression ignition engine applications. Compared to neat n-dodecane, this binary mixture is more representative of diesel fuel because it contains an alkyl-benzene which represents an important chemical class present in diesel fuels. A detailed multi-component mechanism for n-dodecane and m-xylene was developed by combining a previously developed n-dodecane mechanism with a recently developed mechanism for xylenes. The xylene mechanism is shown to reproduce experimental ignition data from a rapid compression machine and shock tube, speciation data from the jet stirred reactor and flame speed data. This combined mechanism was validated by comparing predictions from the model with experimental data for ignition in shock tubes and for reactivity in a flow reactor. The combined mechanism, consisting of 2885 species and 11754 reactions, was reduced to a skeletal mechanism consisting 163 species and 887 reactions for 3D diesel engine simulations. The mechanism reduction was performed using directed relation graph (DRG) with expert knowledge (DRG-X) and DRG-aided sensitivity analysis (DRGASA) at a fixed fuel composition of 77% of n-dodecane and 23% m-xylene by volume. The sample space for the reduction covered pressure of 1 – 80 bar, equivalence ratio of 0.5 – 2.0, and initial temperature of 700 – 1600 K for ignition. The skeletal mechanism was compared with the detailed mechanism for ignition and flow reactor predictions. Finally, the skeletal mechanism was validated against a spray flame dataset under diesel engine conditions documented on the Engine Combustion Network (ECN) website. These multi-dimensional simulations were performed using a Representative Interactive Flame (RIF) turbulent combustion model. Encouraging results were obtained compared to the experiments with regards to the predictions of ignition delay and lift-off length at different ambient temperatures.

  9. Ethyl 3-ethoxybutyrate, a new component of the transportation renewable fuel portfolio

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bunce, Michael P.; Storey, John M. E.; Edmonds, Jennifer W.; Findlay, Robert H.; Ritchie, Stephen M. C.; Eyers, Laurent; McMurry, Zackery A.; Smoot, James C.

    2015-12-01

    The vast majority of energy that powers our global economy is from combustion of fossil fuels with the unintended consequence of increased deposition of carbon dioxide in the atmosphere and oceans. The scientific and technical challenges for the energy sector are to develop renewable energy sources that are sufficient to meet human energy consumption, are economically viable, and are ecologically sustainable. We investigated ethyl 3-ethoxybutyrate (EEB) as a fuel oxygenate in ultra low sulfur diesel (ULSD) with a bench-scale research engine and determined its economic potential as a renewable fuel with technoeconomic modeling using wastewater treatment plant biosolids as themore » feedstock for poly-3-hydroxyalkanoates (PHB), a bacterial storage polymer from which EEB can be synthesized. EEB blended well with ULSD, and cetane values of 10% and 20% v/v EEB-ULSD blends exceeded 40. A diesel internal combustion engine fueled with 5%, 10%, and 20% EEB-ULSD blends met or exceeded all tested transportation diesel fuel emissions criteria. Inedible organic feedstocks may be used to produce PHB; and thus, EEB might contribute to carbon reductions without compromising performance or air pollutant emissions. However, further research is needed to determine its role in the overall fuel portfolio. (C) 2015 Elsevier Ltd. All rights reserved.« less

  10. Performance, Efficiency, and Emissions Characterization of Reciprocating Internal Combustion Engines Fueled with Hydrogen/Natural Gas Blends

    SciTech Connect (OSTI)

    Kirby S. Chapman; Amar Patil

    2007-06-30

    Hydrogen is an attractive fuel source not only because it is abundant and renewable but also because it produces almost zero regulated emissions. Internal combustion engines fueled by compressed natural gas (CNG) are operated throughout a variety of industries in a number of mobile and stationary applications. While CNG engines offer many advantages over conventional gasoline and diesel combustion engines, CNG engine performance can be substantially improved in the lean operating region. Lean operation has a number of benefits, the most notable of which is reduced emissions. However, the extremely low flame propagation velocities of CNG greatly restrict the lean operating limits of CNG engines. Hydrogen, however, has a high flame speed and a wide operating limit that extends into the lean region. The addition of hydrogen to a CNG engine makes it a viable and economical method to significantly extend the lean operating limit and thereby improve performance and reduce emissions. Drawbacks of hydrogen as a fuel source, however, include lower power density due to a lower heating value per unit volume as compared to CNG, and susceptibility to pre-ignition and engine knock due to wide flammability limits and low minimum ignition energy. Combining hydrogen with CNG, however, overcomes the drawbacks inherent in each fuel type. Objectives of the current study were to evaluate the feasibility of using blends of hydrogen and natural gas as a fuel for conventional natural gas engines. The experiment and data analysis included evaluation of engine performance, efficiency, and emissions along with detailed in-cylinder measurements of key physical parameters. This provided a detailed knowledge base of the impact of using hydrogen/natural gas blends. A four-stroke, 4.2 L, V-6 naturally aspirated natural gas engine coupled to an eddy current dynamometer was used to measure the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions

  11. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  12. New Analysis Methods Estimate a Critical Property of Ethanol Fuel Blends (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods developed at NREL disclose the impact of ethanol on gasoline blend heat of vaporization with potential for improved efficiency of spark-ignition engines. More stringent standards for fuel economy, regulation of greenhouse gas emissions, and the mandated increase in the use of renew- able fuel are driving research to improve the efficiency of spark ignition engines. When fuel properties such as octane number and evaporative cooling (heat of vaporization or HOV) are insufficient, they

  13. Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Balance of Plant and Stack Component Integration Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration Presentation by Acumentrics Corporation for Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration March 16, 2010 fuelcell_pre-solicitation_wkshop_mar10_bessette.pdf (1.75 MB) More Documents & Publications The Micro-CHP Technologies Roadmap, December 2003 High Temperature BOP and Fuel Processing Ceramic Fuel Cells (SOFC)

  14. Lightweighting Impacts on Fuel Economy, Cost, and Component Losses

    SciTech Connect (OSTI)

    Brooker, A. D.; Ward, J.; Wang, L.

    2013-01-01

    The Future Automotive Systems Technology Simulator (FASTSim) is the U.S. Department of Energy's high-level vehicle powertrain model developed at the National Renewable Energy Laboratory. It uses a time versus speed drive cycle to estimate the powertrain forces required to meet the cycle. It simulates the major vehicle powertrain components and their losses. It includes a cost model based on component sizing and fuel prices. FASTSim simulated different levels of lightweighting for four different powertrains: a conventional gasoline engine vehicle, a hybrid electric vehicle (HEV), a plug-in hybrid electric vehicle (PHEV), and a battery electric vehicle (EV). Weight reductions impacted the conventional vehicle's efficiency more than the HEV, PHEV and EV. Although lightweighting impacted the advanced vehicles' efficiency less, it reduced component cost and overall costs more. The PHEV and EV are less cost effective than the conventional vehicle and HEV using current battery costs. Assuming the DOE's battery cost target of $100/kWh, however, the PHEV attained similar cost and lightweighting benefits. Generally, lightweighting was cost effective when it costs less than $6/kg of mass eliminated.

  15. U.S. Department of Energy FreedomCAR & Vehicle Technologies Program Advanced Vehicle Testing Activity, Hydrogen/CNG Blended Fuels Performance Testing in a Ford F-150

    SciTech Connect (OSTI)

    James E. Francfort

    2003-11-01

    Federal regulation requires energy companies and government entities to utilize alternative fuels in their vehicle fleets. To meet this need, several automobile manufacturers are producing compressed natural gas (CNG)-fueled vehicles. In addition, several converters are modifying gasoline-fueled vehicles to operate on both gasoline and CNG (Bifuel). Because of the availability of CNG vehicles, many energy company and government fleets have adopted CNG as their principle alternative fuel for transportation. Meanwhile, recent research has shown that blending hydrogen with CNG (HCNG) can reduce emissions from CNG vehicles. However, blending hydrogen with CNG (and performing no other vehicle modifications) reduces engine power output, due to the lower volumetric energy density of hydrogen in relation to CNG. Arizona Public Service (APS) and the U.S. Department of Energy’s Advanced Vehicle Testing Activity (DOE AVTA) identified the need to determine the magnitude of these effects and their impact on the viability of using HCNG in existing CNG vehicles. To quantify the effects of using various blended fuels, a work plan was designed to test the acceleration, range, and exhaust emissions of a Ford F-150 pickup truck operating on 100% CNG and blends of 15 and 30% HCNG. This report presents the results of this testing conducted during May and June 2003 by Electric Transportation Applications (Task 4.10, DOE AVTA Cooperative Agreement DEFC36- 00ID-13859).

  16. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  17. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  18. Catalytic hydroprocessing of coal-derived gasification residues to fuel blending stocks: effect of reaction variables and catalyst on hydrodeoxygenation (HDO), hydrodenitrogenation (HDN), and hydrodesulfurization (HDS)

    SciTech Connect (OSTI)

    Dieter Leckel

    2006-10-15

    Gas liquors, tar oils, and tar products resulting from the coal gasification of a high-temperature Fischer-Tropsch plant can be successfully refined to fuel blending components by the use of severe hydroprocessing conditions. High operating temperatures and pressures combined with low space velocities ensure the deep hydrogenation of refractory oxygen, sulfur, and nitrogen compounds. Hydrodeoxygenation, particularly the removal of phenolic components, hydrodesulfurization, and hydrodenitrogenation were obtained at greater than 99% levels using the NiMo and NiW on {gamma}-Al{sub 2}O{sub 3} catalysts. Maximum deoxygenation activity was achieved using the NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst having a maximum pore size distribution in the range of 110-220{angstrom}. The NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst, which also has a relatively high proportion of smaller pore sizes (35-60 {angstrom}), displays lower hydrogenation activity. 30 refs., 1 fig. 8 tabs.

  19. Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation by Acumentrics Corporation for Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration March 16, 2010 fuelcellpre-solicitationwkshopmar10bessette.pd...

  20. NREL UL E15 Fuel Dispensing Infrastructure Intermediate Blends Performance Testing (Presentation)

    SciTech Connect (OSTI)

    Moriarty, K.; Clark, W.

    2011-02-01

    Presentation provides an overview of NREL's project to determine compatibility and safe performance of installed fuel dispensing infrastructure with E15.

  1. Lowering On-Road Fuel Use: A Component Approach

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tested in New Vehicles z Lights z Air conditioner z Alternator z Some motors, pumps and fans z ... efficiency alternator * Customized control chips for greater fuel economy * ...

  2. Stripping ethanol from ethanol-blended fuels for use in NO.sub.x SCR

    DOE Patents [OSTI]

    Kass, Michael Delos; Graves, Ronald Lee; Storey, John Morse Elliot; Lewis, Sr., Samuel Arthur; Sluder, Charles Scott; Thomas, John Foster

    2007-08-21

    A method to use diesel fuel alchohol micro emulsions (E-diesel) to provide a source of reductant to lower NO.sub.x emissions using selective catalytic reduction. Ethanol is stripped from the micro emulsion and entered into the exhaust gasses upstream of the reducing catalyst. The method allows diesel (and other lean-burn) engines to meet new, lower emission standards without having to carry separate fuel and reductant tanks.

  3. Estimating Impacts of Diesel Fuel Reformulation with Vector-based Blending

    SciTech Connect (OSTI)

    Hadder, G.R.

    2003-01-23

    The Oak Ridge National Laboratory Refinery Yield Model has been used to study the refining cost, investment, and operating impacts of specifications for reformulated diesel fuel (RFD) produced in refineries of the U.S. Midwest in summer of year 2010. The study evaluates different diesel fuel reformulation investment pathways. The study also determines whether there are refinery economic benefits for producing an emissions reduction RFD (with flexibility for individual property values) compared to a vehicle performance RFD (with inflexible recipe values for individual properties). Results show that refining costs are lower with early notice of requirements for RFD. While advanced desulfurization technologies (with low hydrogen consumption and little effect on cetane quality and aromatics content) reduce the cost of ultra low sulfur diesel fuel, these technologies contribute to the increased costs of a delayed notice investment pathway compared to an early notice investment pathway for diesel fuel reformulation. With challenging RFD specifications, there is little refining benefit from producing emissions reduction RFD compared to vehicle performance RFD. As specifications become tighter, processing becomes more difficult, blendstock choices become more limited, and refinery benefits vanish for emissions reduction relative to vehicle performance specifications. Conversely, the emissions reduction specifications show increasing refinery benefits over vehicle performance specifications as specifications are relaxed, and alternative processing routes and blendstocks become available. In sensitivity cases, the refinery model is also used to examine the impact of RFD specifications on the economics of using Canadian synthetic crude oil. There is a sizeable increase in synthetic crude demand as ultra low sulfur diesel fuel displaces low sulfur diesel fuel, but this demand increase would be reversed by requirements for diesel fuel reformulation.

  4. Diesel fuel component contribution to engine emissions and performance. Final report

    SciTech Connect (OSTI)

    Erwin, J.; Ryan, T.W. III; Moulton, D.S.

    1994-11-01

    Contemporary diesel fuel is a blend of several refinery streams chosen to meet specifications. The need to increase yield of transportation fuel from crude oil has resulted in converting increased proportions of residual oil to lighter products. This conversion is accomplished by thermal, catalytic, and hydrocracking of high molecular weight materials rich in aromatic compounds. The current efforts to reformulate California diesel fuel for reduced emissions from existing engines is an example of another driving force affecting refining practice: regulations designed to reduce exhaust emissions. Although derived from petroleum crude oil, reformulated diesel fuel is an alternative to current specification-grade diesel fuel, and this alternative presents opportunities and questions to be resolved by fuel and engine research. Various concerned parties have argued that regulations for fuel reformulation have not been based on an adequate data base. Despite numerous studies, much ambiguity remains about the relationship of exhaust parameters to fuel composition, particularly for diesel fuel. In an effort to gather pertinent data, the automobile industry and the oil refiners have joined forces in the Air Quality Improvement Research Program (AUTO/OIL) to address this question for gasoline. The objective of that work is to define the relationship between gasoline composition and the magnitude and composition of the exhaust emissions. The results of the AUTO/OEL program will also be used, along with other data bases, to define the EPA {open_quotes}complex model{close_quotes} for reformulated gasolines. Valuable insights have been gained for compression ignition engines in the Coordinating Research Council`s VE-1 program, but no program similar to AUTO/OIL has been started for diesel fuel reformulation. A more detailed understanding of the fuel/performance relationship is a readily apparent need.

  5. Preliminary Compatibility Assessment of Metallic Dispenser Materials for Service in Ethanol Fuel Blends

    SciTech Connect (OSTI)

    Pawel, Steven J; Kass, Michael D; Janke, Christopher James

    2009-11-01

    The compatibility of selected metals representative of those commonly used in dispensing systems was evaluated in an aggressive E20 formulation (CE20a) and in synthetic gasoline (Reference Fuel C) in identical testing to facilitate comparison of results. The testing was performed at modestly elevated temperature (nominally 60 C) and with constant fluid flow in an effort to accelerate potential interactions in the screening test. Based on weight change, the general corrosion of all individual coupons exposed in the vapor phase above Reference Fuel C and CE20a as well as all coupons immersed in Reference Fuel C was essentially nil (<0.3 {micro}m/y), with no evidence of localized corrosion such as pitting/crevice corrosion or selective leaching at any location. Modest discoloration was observed on the copper-based alloys (cartridge brass and phosphor bronze), but the associated corrosion films were quite thin and apparently protective. For coupons immersed in CE20a, four different materials exhibited net weight loss over the entire course of the experiment: cartridge brass, phosphor bronze, galvanized steel, and terne-plated steel. None of these exhibited substantial incompatibility with the test fluid, with the largest general corrosion rate calculated from coupon weight loss to be approximately 4 {micro}m/y for the cartridge brass specimens. Selective leaching of zinc (from brass) and tin (from bronze) was observed, as well as the presence of sulfide surface films rich in these elements, suggesting the importance of the role of sulfuric acid in the CE20a formulation. Analysis of weight loss data for the slightly corroded metals indicated that the corrosivity of the test environment decreased with exposure time for brass and bronze and increased for galvanized and terne-plated steel. Other materials immersed in CE20a - type 1020 mild steel, type 1100 aluminum, type 201 nickel, and type 304 stainless steel - each appeared essentially immune to corrosion at the test

  6. Carbonate fuel cell and components thereof for in-situ delayed addition of carbonate electrolyte

    SciTech Connect (OSTI)

    Johnsen, Richard; Yuh, Chao-Yi; Farooque, Mohammad

    2011-05-10

    An apparatus and method in which a delayed carbonate electrolyte is stored in the storage areas of a non-electrolyte matrix fuel cell component and is of a preselected content so as to obtain a delayed time release of the electrolyte in the storage areas in the operating temperature range of the fuel cell.

  7. Annual report, FY 1979 Spent fuel and fuel pool component integrity.

    SciTech Connect (OSTI)

    Johnson, A.B. Jr.; Bailey, W.J.; Schreiber, R.E.; Kustas, F.M.

    1980-05-01

    International meetings under the BEFAST program and under INFCE Working Group No. 6 during 1978 and 1979 continue to indicate that no cases of fuel cladding degradation have developed on pool-stored fuel from water reactors. A section from a spent fuel rack stand, exposed for 1.5 y in the Yankee Rowe (PWR) pool had 0.001- to 0.003-in.-deep (25- to 75-..mu..m) intergranular corrosion in weld heat-affected zones but no evidence of stress corrosion cracking. A section of a 304 stainless steel spent fuel storage rack exposed 6.67 y in the Point Beach reactor (PWR) spent fuel pool showed no significant corrosion. A section of 304 stainless steel 8-in.-dia pipe from the Three Mile Island No. 1 (PWR) spent fuel pool heat exchanger plumbing developed a through-wall crack. The crack was intergranular, initiating from the inside surface in a weld heat-affected zone. The zone where the crack occurred was severely sensitized during field welding. The Kraftwerk Union (Erlangen, GFR) disassembled a stainless-steel fuel-handling machine that operated for 12 y in a PWR (boric acid) spent fuel pool. There was no evidence of deterioration, and the fuel-handling machine was reassembled for further use. A spent fuel pool at a Swedish PWR was decontaminated. The procedure is outlined in this report.

  8. Method of producing a diesel fuel blend having a pre-determined flash-point and pre-determined increase in cetane number

    DOE Patents [OSTI]

    Waller, Francis Joseph; Quinn, Robert

    2004-07-06

    The present invention relates to a method of producing a diesel fuel blend having a pre-determined flash-point and a pre-determined increase in cetane number over the stock diesel fuel. Upon establishing the desired flash-point and increase in cetane number, an amount of a first oxygenate with a flash-point less than the flash-point of the stock diesel fuel and a cetane number equal to or greater than the cetane number of the stock diesel fuel is added to the stock diesel fuel in an amount sufficient to achieve the pre-determined increase in cetane number. Thereafter, an amount of a second oxygenate with a flash-point equal to or greater than the flash-point of the stock diesel fuel and a cetane number greater than the cetane number of the stock diesel fuel is added to the stock diesel fuel in an amount sufficient to achieve the pre-determined increase in cetane number.

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Requirement Suppliers that import gasoline for sale in North Carolina must offer fuel that is not pre-blended with fuel alcohol but that is suitable for future blending. Future contract provisions that restrict distributors or retailers from blending gasoline with fuel alcohol are void. (Reference North Carolina General Statutes 75-90, 105-449.60

  10. Biodiesel Blends

    SciTech Connect (OSTI)

    Not Available

    2005-04-01

    A 2-page fact sheet discussing general biodiesel blends and the improvement in engine performance and emissions.

  11. Underground Storage Tanks: New Fuels and Compatibility

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    high octane ethanol blended fuels will require careful consideration of material compatibility issues with existing infrastructure Outline: 1. Ethanol blended fuels ...

  12. Nuclear fuel cycle system simulation tool based on high-fidelity component modeling

    SciTech Connect (OSTI)

    Ames, David E.

    2014-02-01

    The DOE is currently directing extensive research into developing fuel cycle technologies that will enable the safe, secure, economic, and sustainable expansion of nuclear energy. The task is formidable considering the numerous fuel cycle options, the large dynamic systems that each represent, and the necessity to accurately predict their behavior. The path to successfully develop and implement an advanced fuel cycle is highly dependent on the modeling capabilities and simulation tools available for performing useful relevant analysis to assist stakeholders in decision making. Therefore a high-fidelity fuel cycle simulation tool that performs system analysis, including uncertainty quantification and optimization was developed. The resulting simulator also includes the capability to calculate environmental impact measures for individual components and the system. An integrated system method and analysis approach that provides consistent and comprehensive evaluations of advanced fuel cycles was developed. A general approach was utilized allowing for the system to be modified in order to provide analysis for other systems with similar attributes. By utilizing this approach, the framework for simulating many different fuel cycle options is provided. Two example fuel cycle configurations were developed to take advantage of used fuel recycling and transmutation capabilities in waste management scenarios leading to minimized waste inventories.

  13. Comparative Study of Hybrid Powertrains on Fuel Saving, Emissions, and Component Energy Loss in HD Trucks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Zhiming; Finney, Charles; Daw, Charles; LaClair, Tim J.; Smith, David

    2014-09-30

    We compared parallel and series hybrid powertrains on fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving. A comprehensive set of component models describing battery energy, engine fuel efficiency, emissions control, and power demand interactions for heavy duty (HD) hybrids has been integrated with parallel and series hybrid Class 8 trucks in order to identify the technical barriers of these hybrid powertrain technologies. The results show that series hybrid is absolutely negative for fuel economy benefit of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energymore » (i.e. mechanical to electric to mechanical). The current parallel hybrid technology combined with 50% auxiliary load reduction could elevate 5-7% fuel economy of long-haul trucks, but a profound improvement of long-haul truck fuel economy requires additional innovative technologies for reducing aerodynamic drag and rolling resistance losses. The simulated emissions control indicates that hybrid trucks reduce more CO and HC emissions than conventional trucks. The simulated results further indicate that the catalyzed DPF played an important role in CO oxidations. Limited NH3 emissions could be slipped from the Urea SCR, but the average NH3 emissions are below 20 ppm. Meanwhile our estimations show 1.5-1.9% of equivalent fuel-cost penalty due to urea consumption in the simulated SCR cases.« less

  14. Comparative Study of Hybrid Powertrains on Fuel Saving, Emissions, and Component Energy Loss in HD Trucks

    SciTech Connect (OSTI)

    Gao, Zhiming; Finney, Charles; Daw, Charles; LaClair, Tim J.; Smith, David

    2014-09-30

    We compared parallel and series hybrid powertrains on fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving. A comprehensive set of component models describing battery energy, engine fuel efficiency, emissions control, and power demand interactions for heavy duty (HD) hybrids has been integrated with parallel and series hybrid Class 8 trucks in order to identify the technical barriers of these hybrid powertrain technologies. The results show that series hybrid is absolutely negative for fuel economy benefit of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical). The current parallel hybrid technology combined with 50% auxiliary load reduction could elevate 5-7% fuel economy of long-haul trucks, but a profound improvement of long-haul truck fuel economy requires additional innovative technologies for reducing aerodynamic drag and rolling resistance losses. The simulated emissions control indicates that hybrid trucks reduce more CO and HC emissions than conventional trucks. The simulated results further indicate that the catalyzed DPF played an important role in CO oxidations. Limited NH3 emissions could be slipped from the Urea SCR, but the average NH3 emissions are below 20 ppm. Meanwhile our estimations show 1.5-1.9% of equivalent fuel-cost penalty due to urea consumption in the simulated SCR cases.

  15. Comparative Study of Hybrid Powertrains on Fuel Saving, Emissions, and Component Energy Loss in HD Trucks

    SciTech Connect (OSTI)

    Gao, Zhiming; FINNEY, Charles E A; Daw, C Stuart; LaClair, Tim J; Smith, David E

    2014-01-01

    We compared parallel and series hybrid powertrains on fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving. A comprehensive set of component models describing battery energy, engine fuel efficiency, emissions control, and power demand interactions for heavy duty (HD) hybrids has been integrated with parallel and series hybrid Class 8 trucks in order to identify the technical barriers of these hybrid powertrain technologies. The results show that series hybrid is absolutely negative for fuel economy benefit of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical). The current parallel hybrid technology combined with 50% auxiliary load reduction could elevate 5-7% fuel economy of long-haul trucks, but a profound improvement of long-haul truck fuel economy requires additional innovative technologies for reducing aerodynamic drag and rolling resistance losses. The simulated emissions control indicates that hybrid trucks reduce more CO and HC emissions than conventional trucks. The simulated results further indicate that the catalyzed DPF played an important role in CO oxidations. Limited NH3 emissions could be slipped from the Urea SCR, but the average NH3 emissions are below 20 ppm. Meanwhile our estimations show 1.5-1.9% of equivalent fuel-cost penalty due to urea consumption in the simulated SCR cases.

  16. A combustion model for IC engine combustion simulations with multi-component fuels

    SciTech Connect (OSTI)

    Ra, Youngchul; Reitz, Rolf D.

    2011-01-15

    Reduced chemical kinetic mechanisms for the oxidation of representative surrogate components of a typical multi-component automotive fuel have been developed and applied to model internal combustion engines. Starting from an existing reduced mechanism for primary reference fuel (PRF) oxidation, further improvement was made by including additional reactions and by optimizing reaction rate constants of selected reactions. Using a similar approach to that used to develop the reduced PRF mechanism, reduced mechanisms for the oxidation of n-tetradecane, toluene, cyclohexane, dimethyl ether (DME), ethanol, and methyl butanoate (MB) were built and combined with the PRF mechanism to form a multi-surrogate fuel chemistry (MultiChem) mechanism. The final version of the MultiChem mechanism consists of 113 species and 487 reactions. Validation of the present MultiChem mechanism was performed with ignition delay time measurements from shock tube tests and predictions by comprehensive mechanisms available in the literature. A combustion model was developed to simulate engine combustion with multi-component fuels using the present MultiChem mechanism, and the model was applied to simulate HCCI and DI engine combustion. The results show that the present multi-component combustion model gives reliable performance for combustion predictions, as well as computational efficiency improvements through the use of reduced mechanism for multi-dimensional CFD simulations. (author)

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Diesel Fuel Blend Tax Exemption The biodiesel or ethanol portion of blended fuel containing taxable diesel is exempt from the diesel fuel tax. The biodiesel or ethanol fuel blend must be clearly identified on the retail pump, storage tank, and sales invoice in order to be eligible for the exemption. (Reference Texas Statutes, Tax Code 162.2

  18. Vehicle Technologies Office Merit Review 2016: Efficiency-Optimized Duel Fuel Engine with In-Cylinder Gasoline/CNG Blending

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Argonne National Laboratory (ANL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Fuel ...

  19. DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 2: MEAs, Components, and Integration

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solicitation Workshop 1 March 2010 BREAKOUT GROUP 2: MEAS, COMPONENTS AND INTEGRATION PARTICIPANTS NAME ORGANIZATION Jeff Allen Michigan Tech Guido Bender National Renewable Energy Laboratory Don Connors Ballard Material Products James Cross NUVERA Rick Daniels Advent Technologies North America Mark Debe 3M Emory DeCastro BASF Fuel Cell Mohammad Enayotullah Trenergi Corporation Jim Fenton University of Central Florida/FSEC Ashok Gidwani CFD Research Corporation Craig Gittleman General Motors

  20. In-Cylinder Fuel Blending of Gasoline/Diesel for Improved Efficiency and Lowest Possible Emissions on a Multi-Cylinder Light-Duty Diesel Engine

    SciTech Connect (OSTI)

    Curran, Scott; Prikhodko, Vitaly Y; Wagner, Robert M; Parks, II, James E; Cho, Kukwon; Sluder, Scott; Kokjohn, Sage; Reitz, Rolf

    2010-01-01

    In-cylinder fuel blending of gasoline/diesel fuel is investigated on a multi-cylinder light-duty diesel engine as a potential strategy to control in-cylinder fuel reactivity for improved efficiency and lowest possible emissions. This approach was developed and demonstrated at the University of Wisconsin through modeling and single-cylinder engine experiments. The objective of this study is to better understand the potential and challenges of this method on a multi-cylinder engine. More specifically, the effect of cylinder-to-cylinder imbalances, heat rejection, and in-cylinder charge motion as well as the potential limitations imposed by real-world turbo-machinery were investigated on a 1.9-liter four-cylinder engine. This investigation focused on one engine condition, 2300 rpm, 4.2 bar brake mean effective pressure (BMEP). Gasoline was introduced with a port-fuel-injection system. Parameter sweeps included gasoline-to-diesel fuel ratio, intake air mixture temperature, in-cylinder swirl number, and diesel start-of-injection phasing. In addition, engine parameters were trimmed for each cylinder to balance the combustion process for maximum efficiency and lowest emissions. An important observation was the strong influence of intake charge temperature on cylinder pressure rise rate. Experiments were able to show increased thermal efficiency along with dramatic decreases in oxides of nitrogen (NOX) and particulate matter (PM). However, indicated thermal efficiency for the multi-cylinder experiments were less than expected based on modeling and single-cylinder results. The lower indicated thermal efficiency is believed to be due increased heat transfer as compared to the model predictions and suggest a need for improved cylinder-to-cylinder control and increased heat transfer control.

  1. Quality Assessment of Biodiesel and Biodiesel Blends | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assessment of Biodiesel and Biodiesel Blends Quality Assessment of Biodiesel and Biodiesel Blends The results of a quality survey of B20 fuel in the United States were ...

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Blend Dispenser Requirement A retail motor fuel dispenser that dispenses fuel containing more than 10% ethanol by volume must be labeled with the capital letter "E" ...

  3. Emissions of Volatile Particulate Components from Turboshaft Engines running JP-8 and Fischer-Tropsch Fuels

    SciTech Connect (OSTI)

    Cheng, Mengdawn; Corporan, E.; DeWitt, M.; Landgraf, Bradley J

    2009-01-01

    Rotating-wing aircraft or helicopters are heavily used by the US military and also a wide range of commercial applications around the world, but emissions data for this class of engines are limited. In this study, we focus on emissions from T700-GE-700 and T700-GE-701C engines; T700 engine was run with military JP-8 and T701C run with both JP-8 and Fischer-Tropsch (FT) fuels. Each engine was run at three engine power settings from the idle to maximum power in sequence. Exhaust particles measured at the engine exhaust plane (EEP) have a peak mobility diameter less than 50nm in all engine power settings. At a 4-m downstream location, sulfate/sulfur measurements indicate all particulate sulfur exists practically as sulfate, and the particulate sulfur and sulfate contents increased as the engine power increased. The conversion of sulfur to sulfate was found not to be dependent on engine power setting. Analysis also showed that conversion of sulfur to sulfate was not by the adsorption of sulfur dioxide gas on the soot particles and then subsequently oxidized to form sulfate, but by gas-phase conversion of SO2 via OH or O then subsequently forming H2SO4 and condensing on soot particles. Without the sulfur and aromatic components, use of the FT fuel led to significant reduction of soot emissions as compared to that of the JP-8 fuel producing less number of particles than that of the JP-8 fuel; however, the FT fuel produced much higher number concentrations of particles smaller than 7nm than that of JP-8 in all engine power settings. This indicates non-aromatics components in the FT fuel could have contributed to the enhancement of emissions of particles smaller than 7nm. These small particles are volatile, not observed at the EEP, and may be important in playing a role for the formation of secondary particles in the atmosphere or serving as a site for effective cloud nuclei condensation to occur.

  4. The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion | Department of Energy The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI Combustion The Performance of Gasoline Fuels and Surrogates in Gasoline HCCI Combustion Almost 2 dozen gasoline fuels, blending components, and surrogates were evaluated in a single-cylinder HCCI gasoline engine for combustion, emissions, and efficiency performance. p-05_bunting.pdf (495.39 KB) More Documents & Publications APBF Effects on Combustion Fuel-Borne Reductants for NOx

  5. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels, Phase 2: Evaluations of Field Samples and Laboratory Blends

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; LaViolette, M.

    2010-04-01

    Study to measure the flammability of gasoline/ethanol fuel vapors at low ambient temperatures and develop a mathematical model to predict temperatures at which flammable vapors were likely to form.

  6. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  7. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Renewable Fuel Distributor and Vehicle Manufacturer Liability Protection Renewable fuel refiners, suppliers, terminals, wholesalers, distributors, retailers, and motor vehicle manufacturers and dealers are not liable for property damages related to a customer's purchase of renewable fuel, including blends, if the consumer selected the fuel for use. Motor fuel blended with any amount of renewable fuel will not be considered a defective product provided the fuel compiles with motor fuel quality

  8. Development of Kinetic Mechanisms for Next-Generation Fuels and CFD Simulation of Advanced Combustion Engines

    SciTech Connect (OSTI)

    Pitz, William J.; McNenly, Matt J.; Whitesides, Russell; Mehl, Marco; Killingsworth, Nick J.; Westbrook, Charles K.

    2015-12-17

    Predictive chemical kinetic models are needed to represent next-generation fuel components and their mixtures with conventional gasoline and diesel fuels. These kinetic models will allow the prediction of the effect of alternative fuel blends in CFD simulations of advanced spark-ignition and compression-ignition engines. Enabled by kinetic models, CFD simulations can be used to optimize fuel formulations for advanced combustion engines so that maximum engine efficiency, fossil fuel displacement goals, and low pollutant emission goals can be achieved.

  9. Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Ethanol-Gasoline Blends by Addition of Higher Alcohols Improving Ethanol-Gasoline Blends by Addition of Higher Alcohols Mixtures of ethanol, gasoline, and higher alcohols were evaluated to determine if they offer superior performance to ethanol/gasoline blends in meeting the Renewal Fuels Standard II. deer12_ickes.pdf (1.45 MB) More Documents & Publications Vehicle Certification Test Fuel and Ethanol Flex Fuel Quality Impact of ethanol and butanol as oxygenates on

  10. Miscible, multi-component, diesel fuels and methods of bio-oil transformation

    DOE Patents [OSTI]

    Adams, Thomas; Garcia, Manuel; Geller, Dan; Goodrum, John W.; Pendergrass, Joshua T.

    2010-10-26

    Briefly described, embodiments of this disclosure include methods of recovering bio-oil products, fuels, diesel fuels, and the like are disclosed.

  11. Alternative Fuels Data Center | Open Energy Information

    Open Energy Info (EERE)

    and resources to enable the use of alternative fuels, in addition to other petroleum reduction options such as advanced vehicles, fuel blends, idle reduction, and fuel...

  12. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Use and Vehicle Acquisition Requirements State agency fleets with more than 15 vehicles, excluding emergency and law enforcement vehicles, may not purchase or lease a motor vehicle unless the vehicle uses compressed or liquefied natural gas, propane, ethanol or fuel blends of at least 85% ethanol (E85), methanol or fuel blends of at least 85% methanol (M85), biodiesel or fuel blends of at least 20% biodiesel (B20), or electricity (including plug-in hybrid electric vehicles).

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Specifications Ethanol-blended gasoline must conform to ASTM D4814, E85 must conform to ASTM D4806, and biodiesel-blended fuel containing at least 6%, but no more than 20%, ...

  14. Utilization of Minor Actinides as a Fuel Component for Ultra-Long Life Bhr Configurations: Designs, Advantages and Limitations

    SciTech Connect (OSTI)

    Dr. Pavel V. Tsvetkov

    2009-05-20

    This project assessed the advantages and limitations of using minor actinides as a fuel component to achieve ultra-long life Very High Temperature Reactor (VHTR) configurations. Researchers considered and compared the capabilities of pebble-bed and prismatic core designs with advanced actinide fuels to achieve ultra-long operation without refueling. Since both core designs permit flexibility in component configuration, fuel utilization, and fuel management, it is possible to improve fissile properties of minor actinides by neutron spectrum shifting through configuration adjustments. The project studied advanced actinide fuels, which could reduce the long-term radio-toxicity and heat load of high-level waste sent to a geologic repository and enable recovery of the energy contained in spent fuel. The ultra-long core life autonomous approach may reduce the technical need for additional repositories and is capable to improve marketability of the Generation IV VHTR by allowing worldwide deployment, including remote regions and regions with limited industrial resources. Utilization of minor actinides in nuclear reactors facilitates developments of new fuel cycles towards sustainable nuclear energy scenarios.

  15. Vehicle Technologies Office: Intermediate Ethanol Blends Research and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing | Department of Energy Intermediate Ethanol Blends Research and Testing Vehicle Technologies Office: Intermediate Ethanol Blends Research and Testing Ethanol can be combined with gasoline in blends ranging from E10 (10% or less ethanol, 90% gasoline) up to E85 (up to 85% ethanol, 15% gasoline), with those in-between being called "intermediate blends." The U.S. Environmental Protection Agency's Renewable Fuels Standard (under the Energy Policy Act of 2005 and the Energy

  16. Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ft003_mccormick_2011_o.pdf (820.98 KB) More Documents & Publications Performance of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Quality, Performance, and Emission Impacts of

  17. Performance of Biofuels and Biofuel Blends | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting ft003_mccormick_2012_o.pdf (1.47 MB) More Documents & Publications Quality, Performance, and Emission Impacts of Biofuels and Biofuel Blends Performance of Biofuels and Biofuel Blends Recent Research to Address Technical Barriers to Increased Use of Biodiesel

  18. Methodology for modeling the devolatilization of refuse-derived fuel from thermogravimetric analysis of municipal solid waste components

    SciTech Connect (OSTI)

    Fritsky, K.J.; Miller, D.L.; Cernansky, N.P.

    1994-09-01

    A methodology was introduced for modeling the devolatilization characteristics of refuse-derived fuel (RFD) in terms of temperature-dependent weight loss. The basic premise of the methodology is that RDF is modeled as a combination of select municipal solid waste (MSW) components. Kinetic parameters are derived for each component from thermogravimetric analyzer (TGA) data measured at a specific set of conditions. These experimentally derived parameters, along with user-derived parameters, are inputted to model equations for the purpose of calculating thermograms for the components. The component thermograms are summed to create a composite thermogram that is an estimate of the devolatilization for the as-modeled RFD. The methodology has several attractive features as a thermal analysis tool for waste fuels. 7 refs., 10 figs., 3 tabs.

  19. Lean methane premixed laminar flames doped by components of diesel fuel II: n-propylcyclohexane

    SciTech Connect (OSTI)

    Pousse, E.; Porter, R.; Warth, V.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F. [Departement de Chimie-Physique des Reactions, Nancy Universite, CNRS, ENSIC, 1 rue Grandville, BP 20451, 54001 Nancy Cedex (France)

    2010-01-15

    For a better understanding of the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-propylcyclohexane has been investigated. The inlet gases contained 7.1% (molar) methane, 36.8% oxygen, and 0.81% n-propylcyclohexane (C{sub 9}H{sub 18}), corresponding to an equivalence ratio of 0.68 and a C{sub 9}H{sub 18}/CH{sub 4} ratio of 11.4%. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr) using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 17 C{sub 3}-C{sub 5} hydrocarbons, seven C{sub 1}-C{sub 3} oxygenated compounds, and only four cyclic C{sub 6+} compounds, namely benzene, 1,3-cyclohexadiene, cyclohexene, and methylenecyclohexane. A new mechanism for the oxidation of n-propylcyclohexane has been proposed. It allows the proper simulation of profiles of most of the products measured in flames, as well as the satisfactory reproduction of experimental results obtained in a jet-stirred reactor. The main reaction pathways of consumption of n-propylcyclohexane have been derived from rate-of-production analysis. (author)

  20. A lean methane premixed laminar flame doped with components of diesel fuel. I. n-Butylbenzene

    SciTech Connect (OSTI)

    Pousse, E.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F. [Departement de Chimie-Physique des Reactions, Nancy Universite, CNRS, ENSIC, 1 rue Grandville, BP 20451, 54001 Nancy Cedex (France)

    2009-05-15

    To better understand the chemistry involved in the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with n-butylbenzene has been investigated. The inlet gases contained 7.1% (molar) methane, 36.8% oxygen, and 0.96% n-butylbenzene corresponding to an equivalence ratio of 0.74 and a ratio C{sub 10}H{sub 14}/CH{sub 4} of 13.5%. The flame has been stabilized on a burner at a pressure of 6.7 kPa using argon as diluent, with a gas velocity at the burner of 49.2 cm/s at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 16 C{sub 3}-C{sub 5} hydrocarbons, and 7 C{sub 1}-C{sub 3} oxygenated compounds, as well as 20 aromatic products. A new mechanism for the oxidation of n-butylbenzene is proposed whose predictions are in satisfactory agreement with measured species profiles in flames and flow reactor experiments. The main reaction pathways of consumption of n-butylbenzene have been derived from flow rate analyses. (author)

  1. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    DOE Patents [OSTI]

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  2. Fuels Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels Technologies Fuels Technologies Overview of DOE Fuels Technologies R&D activities, including fuels for advanced combustion engines, advanced petroleum-based and non-petroleum based fuels, and biofuels. deer08_stork.pdf (644.47 KB) More Documents & Publications Mid-Level Ethanol Blends Mid-Level Ethanol Blends Test Program Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009

  3. Balance of Plant (BoP) Components Validation for Fuel Cells ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Effect of System and Air Contaminants on PEMFC Performance and Durability Direct Hydrogen PEMFC Manufacturing Cost Estimation for Automotive Applications: Fuel Cell Tech Team ...

  4. The Investigation and Development of Low Cost Hardware Components for Proton-Exchange Membrane Fuel Cells - Final Report

    SciTech Connect (OSTI)

    George A. Marchetti

    1999-12-15

    Proton exchange membrane (PEM) fuel cell components, which would have a low-cost structure in mass production, were fabricated and tested. A fuel cell electrode structure, comprising a thin layer of graphite (50 microns) and a front-loaded platinum catalyst layer (600 angstroms), was shown to produce significant power densities. In addition, a PEM bipolar plate, comprising flexible graphite, carbon cloth flow-fields and an integrated polymer gasket, was fabricated. Power densities of a two-cell unit using this inexpensive bipolar plate architecture were shown to be comparable to state-of-the-art bipolar plates.

  5. Carbon-Type Analysis and Comparison of Original and Reblended FACE Diesel Fuels (FACE 2, FACE 4, and FACE 7)

    SciTech Connect (OSTI)

    Bays, J. Timothy; King, David L.; O'Hagan, Molly J.

    2012-10-01

    This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of Fuels for Advanced Combustion Engines (FACE) diesel blends, FD-2B, FD 4B, and FD-7B, and makes comparison of the new blends with the original FACE diesel blends, FD 2A, FD 4A, and FD-7A, respectively. Generally, FD-2A and FD-2B are more similar than the A and B blends of FD-4 and FD-7. The aromatic carbon content is roughly equivalent, although the new FACE blends have decreased monoaromatic content and increased di- and tri-cycloaromatic content, as well as a higher overall aromatic content, than the original FACE blends. The aromatic components of the new FACE blends generally have a higher alkyl substitution with longer alkyl substituents. The naphthenic and paraffinic contents remained relatively consistent. Based on aliphatic methyl and methylene carbon ratios, cetane numbers for FD-2A and -2B, and FD-7A and -7B are predicted to be consistent, while the cetane number for FD-4B is predicted to be higher than FD-4A. Overall, the new FACE fuel blends are fairly consistent with the original FACE fuel blends, but there are observable differences. In addition to providing important comparative compositional information on reformulated FACE diesel blends, this report also provides important information about the capabilities of the team at Pacific Northwest National Laboratory in the use of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Entities and individuals that receive or manufacture and deliver biodiesel within the state for blending or resale are eligible for a tax deduction for the fuel. (Reference New ...

  7. Elastomer Compatibility Testing of Renewable Diesel Fuels

    SciTech Connect (OSTI)

    Frame, E.; McCormick, R. L.

    2005-11-01

    In this study, the integrity and performance of six elastomers were tested with ethanol-diesel and biodiesel fuel blends.

  8. Preparation and characterization of polymer blend based on sulfonated poly (ether ether ketone) and polyetherimide (SPEEK/PEI) as proton exchange membranes for fuel cells

    SciTech Connect (OSTI)

    Hashim, Nordiana; Ali, Ab Malik Marwan; Lepit, Ajis; Rasmidi, Rosfayanti; Subban, Ri Hanum Yahaya; Yahya, Muhd Zu Azhan

    2015-08-28

    Blends of sulfonated poly (ether ether ketone) (SPEEK) and polyetherimide (PEI) were prepared in five different weight ratios using N-methyl-2-pyrrolidone (NMP) as solvent by the solution cast technique. The degree of sulfonation (DS) of the sulfonated PEEK was determined from deuterated dimethyl sulfoxide (DMSO-d{sub 6}) solution of the purified polymer using {sup 1}H NMR method. The properties studied in the present investigation includes conductivity, water uptake, thermal stability and structure analysis of pure SPEEK as well as SPEEK-PEI polymer blend membranes. The experimental results show that the conductivity of the membranes increased with increase in temperature from 30 to 80°C, except for that of pure SPEEK membrane which increased with temperature from 30 to 60°C while its conductivity decreased with increasing temperature from 60 to 80°C. The conductivity of 70wt.%SPEEK-30wt.%PEI blend membrane at 80% relative humidity (RH) is found to be 1.361 × 10{sup −3} Scm{sup −1} at 30°C and 3.383 × 10{sup −3} Scm{sup −1} at 80°C respectively. It was also found that water uptake and thermal stability of the membranes slightly improved upon blending with PEI. Structure analysis was carried out using Fourier Transform Infrared (FTIR) spectroscopy which revealed considerable interactions between sulfonic acid group of SPEEK and imide groups of PEI. Modification of SPEEK by blending with PEI shows good potential for improving the electrical and physical properties of proton exchange membranes.

  9. Conceptual design report for handling Fort St. Vrain fuel element components

    SciTech Connect (OSTI)

    Gavalya, R.A.

    1993-09-01

    This report presents conceptual designs for containment of high-level wastes (HLW) and low-level wastes (LLW) that will result from disassembly of fuel elements from the High Temperature Gas-Cooled Reactor at the Fort St. Vrain nuclear power plant in Platteville, Colorado. Hexagonal fuel elements will enter the disassembly area as a HLW and exit as either as HLW or LLW. The HLW will consist of spent fuel compacts that have been removed from the hexagonal graphite block. Graphite dust and graphite particles produced during the disassembly process will also be routed to the container that will hold the HLW spent fuel compacts. The LLW will consist of the emptied graphite block. Three alternatives have been introduced for interim storage of the HLW containers after the spent fuel has been loaded. The three alternatives are: (a) store containers where fuel elements are currently being stored, (b) construct a new dry storage facility, and (c) employ Multi-Purpose Canisters (currently in conceptual design stage). Containment of the LLW graphite block will depend on several factors: (a) LLW classification, (b) radiation levels, and (c) volume-reducing technique (if used). Packaging may range from cardboard boxes for incinerable wastes to 55-ton cask inserts for remote-handled wastes. Before final designs for the containment of the HLW and LLW can be developed, several issues need to be addressed: (a) packing factor for fuel compacts in HLW container, (b) storage/disposal of loaded HLW containers, (c) characterization of the emptied graphite blocks, and (d) which technique for volume-reduction purposes (if any) will be used.

  10. Synthesis and Analysis of Alpha Silicon Carbide Components for Encapsulation of Fuel Rods and Pellets

    SciTech Connect (OSTI)

    Kevin M. McHugh; John E. Garnier; George W. Griffith

    2011-09-01

    The chemical, mechanical and thermal properties of silicon carbide (SiC) along with its low neutron activation and stability in a radiation field make it an attractive material for encapsulating fuel rods and fuel pellets. The alpha phase (6H) is particularly stable. Unfortunately, it requires very high temperature processing and is not readily available in fibers or near-net shapes. This paper describes an investigation to fabricate a-SiC as thin films, fibers and near-net-shape products by direct conversion of carbon using silicon monoxide vapor at temperatures less than 1700 C. In addition, experiments to nucleate the alpha phase during pyrolysis of polysilazane, are also described. Structure and composition were characterized using scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction. Preliminary tensile property analysis of fibers was also performed.

  11. Characterization of Solid Oxide Fuel Cell Components Using Electromagnetic Model-Based Sensors

    SciTech Connect (OSTI)

    Zilberstein, Vladimir; Craven, Chris; Goldfine, Neil

    2004-12-28

    In this Phase I SBIR, the contractor demonstrated a number of capabilities of model-based sensors such as MWM sensors and MWM-Arrays. The key results include (1) porosity/microstructure characterization for anodes, (2) potential for cathode material characterization, (3) stress measurements in nickel and cobalt, and (4) potential for stress measurements in non-magnetic materials with a ferromagnetic layer. In addition, potential applications for manufacturing quality control of nonconductive layers using interdigitated electrode dielectrometers have been identified. The results indicate that JENTEK's MWM technology can be used to significantly reduce solid oxide fuel cell production and operating costs in a number of ways. Preliminary investigations of solid oxide fuel cell health monitoring and scale-up issues to address industry needs have also been performed.

  12. MATERIALS COMPATIBILITY OF SNAP FUEL COMPONENTS DURING SHIPMENT IN 9975 PACKAGING

    SciTech Connect (OSTI)

    Vormelker, P

    2006-11-14

    Materials Science and Technology has evaluated materials compatibility for the SNAP (Systems for Nuclear Auxiliary Power) fuel for containment within a 9975 packaging assembly for a shipping period of one year. The evaluation included consideration for potential for water within the convenience can, corrosion from water, galvanic corrosion, tape degradation, and thermal expansion risk. Based on a review of existing literature and assumed conditions, corrosion and/or degradation of the 304 stainless steel (SS) Primary Containment Vessel (PCV) and the 304 stainless steel convenience cans containing the SNAP fuel is not significant to cause failure during the 1 year time shipping period in the 9975 packaging assembly. However, storage beyond the 1 year shipping period has not been validated.

  13. Process for recycling components of a PEM fuel cell membrane electrode assembly

    SciTech Connect (OSTI)

    Shore, Lawrence

    2012-02-28

    The membrane electrode assembly (MEA) of a PEM fuel cell can be recycled by contacting the MEA with a lower alkyl alcohol solvent which separates the membrane from the anode and cathode layers of the assembly. The resulting solution containing both the polymer membrane and supported noble metal catalysts can be heated under mild conditions to disperse the polymer membrane as particles and the supported noble metal catalysts and polymer membrane particles separated by known filtration means.

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Fuel Blend Tax Rate The tax rate on fuel containing ethanol is $0.06 per gallon less than the tax rate on other motor fuels in certain geographic areas. This reduced rate is in effect during months ethanol fuel blends must be sold, transferred, or used to operate motor vehicles to reduce carbon monoxide emissions and attain federal or state air quality standards. (Reference Alaska Statutes 43.40.01

  15. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, Jerry Dale; Thomas, Thomas Russell; Kessinger, Glen F.

    1998-01-01

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission- and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200.degree. C. to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400.degree. C.; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164.degree. C. to 2.degree. C.; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic.

  16. Dry halide method for separating the components of spent nuclear fuels

    DOE Patents [OSTI]

    Christian, J.D.; Thomas, T.R.; Kessinger, G.F.

    1998-06-30

    The invention is a nonaqueous, single method for processing multiple spent nuclear fuel types by separating the fission and transuranic products from the nonradioactive and fissile uranium product. The invention has four major operations: exposing the spent fuels to chlorine gas at temperatures preferably greater than 1200 C to form volatile metal chlorides; removal of the fission product chlorides, transuranic product chlorides, and any nickel chloride and chromium chloride in a molten salt scrubber at approximately 400 C; fractional condensation of the remaining volatile chlorides at temperatures ranging from 164 to 2 C; and regeneration and recovery of the transferred spent molten salt by vacuum distillation. The residual fission products, transuranic products, and nickel- and chromium chlorides are converted to fluorides or oxides for vitrification. The method offers the significant advantages of a single, compact process that is applicable to most of the diverse nuclear fuels, minimizes secondary wastes, segregates fissile uranium from the high level wastes to resolve potential criticality concerns, segregates nonradioactive wastes from the high level wastes for volume reduction, and produces a common waste form glass or glass-ceramic. 3 figs.

  17. Bench-Top Engine System for Fast Screening of Alternative Fuels and Fuel Additives

    Broader source: Energy.gov [DOE]

    A bench-top engine testing system was used to fast screen the efficiency of fuel additives or fuel blends on NOx reduction

  18. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  19. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T.

    2011-08-01

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of

  20. Multiple fuel supply system for an internal combustion engine

    DOE Patents [OSTI]

    Crothers, William T.

    1977-01-01

    A multiple fuel supply or an internal combustion engine wherein phase separation of components is deliberately induced. The resulting separation permits the use of a single fuel tank to supply components of either or both phases to the engine. Specifically, phase separation of a gasoline/methanol blend is induced by the addition of a minor amount of water sufficient to guarantee separation into an upper gasoline phase and a lower methanol/water phase. A single fuel tank holds the two-phase liquid with separate fuel pickups and separate level indicators for each phase. Either gasoline or methanol, or both, can be supplied to the engine as required by predetermined parameters. A fuel supply system for a phase-separated multiple fuel supply contained in a single fuel tank is described.

  1. Liquid-Water Uptake and Removal in PEM Fuel-Cell Components

    SciTech Connect (OSTI)

    Das, Prodip K.; Gunterman, Haluna P.; Kwong, Anthony; Weber, Adam Z.

    2011-09-23

    Management of liquid water is critical for optimal fuel-cell operation, especially at low temperatures. It is therefore important to understand the wetting properties and water holdup of the various fuel-cell layers. While the gas-diffusion layer is relatively hydrophobic and exhibits a strong intermediate wettability, the catalyst layer is predominantly hydrophilic. In addition, the water content of the ionomer in the catalyst layer is lower than that of the bulk membrane, and is affected by platinum surfaces. Liquid-water removal occurs through droplets on the surface of the gas-diffusion layer. In order to predict droplet instability and detachment, a force balance is used. While the pressure or drag force on the droplet can be derived, the adhesion or surface-tension force requires measurement using a sliding-angle approach. It is shown that droplets produced by forcing water through the gas-diffusion layer rather than placing them on top of it show much stronger adhesion forces owing to the contact to the subsurface water.

  2. Performance of Biofuels and Biofuel Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of Biofuels and Biofuel Blends Robert McCormick Vehicle Technologies Program Merit Review - Fuels and Lubricants Technologies May 16, 2013 Project ID: FT003 This presentation does not contain any proprietary, confidential, or otherwise restricted information. 2 Overview Timeline Start date: Oct 2012 End date: Sept 2013 Percent complete: 66% Program funded one year at a time Barriers VTP MYPP Fuels & Lubricants Technologies Goals * By 2013 identify light-duty (LD) non-petroleum

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85% or more of alcohol with gasoline; natural gas and liquid fuels domestically produced from natural gas; liquefied petroleum gas (propane); coal-derived liquid fuels; hydrogen; electricity; pure biodiesel (B100); fuels, other than alcohol, derived from biological materials; and P-Series fuels. In addition, the U.S.

  4. HCCI experiments with gasoline surrogate fuels modeled by a semidetailed chemical kinetic model

    SciTech Connect (OSTI)

    Andrae, J.C.G.; Head, R.A.

    2009-04-15

    Experiments in a homogeneous charge compression ignition (HCCI) engine have been conducted with four gasoline surrogate fuel blends. The pure components in the surrogate fuels consisted of n-heptane, isooctane, toluene, ethanol and diisobutylene and fuel sensitivities (RON-MON) in the fuel blends ranged from two to nine. The operating conditions for the engine were p{sub in}=0.1 and 0.2 MPa, T{sub in}=80 and 250 C, {phi}=0.25 in air and engine speed 1200 rpm. A semidetailed chemical kinetic model (142 species and 672 reactions) for gasoline surrogate fuels, validated against ignition data from experiments conducted in shock tubes for gasoline surrogate fuel blends at 1.0{<=} p{<=}5.0MPa, 700{<=} T{<=}1200 K and {phi}=1.0, was successfully used to qualitatively predict the HCCI experiments using a single zone modeling approach. The fuel blends that had higher fuel sensitivity were more resistant to autoignition for low intake temperature and high intake pressure and less resistant to autoignition for high intake temperature and low intake pressure. A sensitivity analysis shows that at high intake temperature the chemistry of the fuels ethanol, toluene and diisobutylene helps to advance ignition. This is consistent with the trend that fuels with the least Negative Temperature Coefficient (NTC) behavior show the highest octane sensitivity, and become less resistant to autoignition at high intake temperatures. For high intake pressure the sensitivity analysis shows that fuels in the fuel blend with no NTC behavior consume OH radicals and acts as a radical scavenger for the fuels with NTC behavior. This is consistent with the observed trend of an increase in RON and fuel sensitivity. With data from shock tube experiments in the literature and HCCI modeling in this work, a correlation between the reciprocal pressure exponent on the ignition delay to the fuel sensitivity and volume percentage of single-stage ignition fuel in the fuel blend was found. Higher fuel

  5. Saturated Monoglyceride Polymorphism and Gel Formation of Biodiesel Blends

    SciTech Connect (OSTI)

    Chupka, Gina; Fouts, Lisa; McCormick, Robert

    2015-11-13

    Crystallization or gel formation of normal paraffins in diesel fuel under cold weather conditions leading to fuel filter clogging is a common problem. Cold weather operability of biodiesel (B100) and blends with diesel fuel presents additional complexity because of the presence of saturated monoglycerides (SMGs) and other relatively polar species. Currently, the cloud point measurement (a measure of when the first component crystallizes out of solution) is used to define the lowest temperature at which the fuel can be used without causing cold weather issues. While filter plugging issues have declined, there still remain intermittent unexpected problems above the cloud point for biodiesel blends. Development of a fundamental understanding of how minor components in biodiesel crystallize, gel, and transform is needed in order to prevent these unexpected issues. We have found that SMGs, a low level impurity present in B100 from the production process, can crystallize out of solution and undergo a solvent-mediated polymorphic phase transformation to a more stable, less soluble form. This causes them to persist at temperatures above the cloud point once they have some out of solution. Additionally, we have found that SMGs can cause other more soluble, lower melting point minor components in the B100 to co-crystallize and come out of solution. Monoolein, another minor component from the production process is an unsaturated monoglyceride with a much lower melting point and higher solubility than SMGs. It is able to form a co-crystal with the SMGs and is found together with the SMGs on plugged filters we have analyzed in our laboratory. An observation of isolated crystals in the lab led us to believe that the SMGs may also be forming a gel-like network with components of the B100 and diesel fuel. During filtration experiments, we have noted that in some cases a solid layer of crystals forms and blocks the filter completely, while in other cases this does not occur

  6. Microbial conversion of synthesis gas components to useful fuels and chemicals

    SciTech Connect (OSTI)

    Madhukar, G.R.; Elmore, B.B.; Huckabay, H.K.

    1996-12-31

    Enriched culture techniques have been used to isolate microbial cultures exhibiting growth on synthesis gas components. Three rod-shaped, gram-positive cultures have been isolated from petroleum-contaminated soil, a cow manure-soil mixture, and sheep rumen fluid. Each culture exhibits growth on carbon monoxide as its primary carbon source, producing alcohols and acids in the fermentation medium. Quantities of up to 7.5, 0.58, and 0.25 g/L of acetate, ethanol, and methanol, respectively, have been produced in batch culture with lesser amounts of acetone, butyric, and propionic acid detected. 15 refs., 5 figs., 3 tabs.

  7. Ethanol Fuel Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in a high-level blend ...

  8. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  9. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Compatibility Requirements for Underground Storage Tanks (USTs) Fueling station owners and operators must notify the appropriate state and local implementing agencies at least 30 days before switching USTs to store ethanol blends greater than 10%, biodiesel blends greater than 20%, or any other regulated fuel the agency has identified. This notification timeframe allows agencies to request information on UST compatibility before the owner or operator stores the fuel. Owners and operators

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Alternative Fuel Vehicle (AFV) Fund The North Carolina State Energy Office administers the Energy Policy Act (EPAct) Credit Banking and Selling Program, which enables the state to generate funds from the sale of EPAct 1992 credits. The funds that EPAct credit sales generate are deposited into the Alternative Fuel Revolving Fund (Fund) for state agencies to offset the incremental costs of purchasing biodiesel blends of at least 20% (B20) or ethanol blends of at least 85%

  12. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  13. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Don Karner; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen–50% CNG fuel.

  14. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend, Ford F-150 -- Operating Summary

    SciTech Connect (OSTI)

    Karner, D.; Francfort, James Edward

    2003-01-01

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy’s Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service’s Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  15. Industrial innovations for tomorrow: Advances in industrial energy-efficiency technologies. Commercial power plant tests blend of refuse-derived fuel and coal to generate electricity

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    MSW can be converted to energy in two ways. One involves the direct burning of MSW to produce steam and electricity. The second converts MSW into refuse-derived fuel (RDF) by reducing the size of the MSW and separating metals, glass, and other inorganic materials. RDF can be densified or mixed with binders to form fuel pellets. As part of a program sponsored by DOE`s Office of Industrial Technologies, the National Renewable Energy Laboratory participated in a cooperative research and development agreement to examine combustion of binder-enhanced, densified refuse-derived fuel (b-d RDF) pellets with coal. Pelletized b-d RDF has been burned in coal combustors, but only in quantities of less than 3% in large utility systems. The DOE project involved the use of b-d RDF in quantities up to 20%. A major goal was to quantify the pollutants released during combustion and measure combustion performance.

  16. Stocks of Motor Gasoline Blending Components

    Gasoline and Diesel Fuel Update (EIA)

    194,259 203,187 212,640 217,489 220,765 226,935 1983-2016 PADD 1 51,306 53,633 57,200 56,763 58,920 62,421 2004-2016 PADD 2 43,744 46,809 50,163 51,441 51,859 54,773 2004-2016 PADD...

  17. Evaluation of Ethanol Blends for PHEVs using Simulation and

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Distillation Curve Method | Department of Energy Supercritical transesterification processing permits efficient fuel system and combustion chamber designs to optimize fuel utilization in diesel engines., p-01_anitescu.pdf (408.75 KB) More Documents & Publications Preparation, Injection and Combustion of Supercritical Fluids Volatility of Gasoline and Diesel Fuel Blends for Supercritical Fuel Injection Algae Biofuels Technology Energy

    This research effort is a part of the

  18. Diesel engine performance and emissions using different fuel/additive combinations

    SciTech Connect (OSTI)

    Sutton, D.L.; Rush, M.W.; Richards, P.

    1988-01-01

    It is probable that diesel fuel quality in Europe will fall as the need to blend conversion components into the diesel pool increases. In particular diesel ignition quality and stability could decrease and carbon residue and aromatic content increase. This paper discusses the effects of worsening fuel quality on combustion, injection characteristics and emissions and the efficacy of appropriate additives in overcoming these effects. Both direct injection and indirect injection engines were used in the investigations.

  19. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2006-05-17

    This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses

  20. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  1. Performance and emissions of non-petroleum fuels in a direct-injection stratified charge Sl engine

    SciTech Connect (OSTI)

    Freeman, L.E.; Chui, G.K.; Roby, R.J.

    1982-10-01

    Seven fuels derived from coal and shale resources were evaluated using a direct-injection stratified charge engine. The fuels were refined to different degrees which ranged from those typical of gasoline blending components to those similar to current gasoline. Results showed that fuels refined to have properties similar to gasoline performed like gasoline. The less refined fuels were limited in performance. The total carbon monoxide and the hydrocarbon emissions varied with the volatility of the fuels. Most fuels with a higher overall distillation curve generally gave higher hydrocarbon and carbon monoxide emissions. The NOx emissions increased with the percent aromatics in the fuels. The hydrocarbon emissions were found to increase with fuel viscosity. Within the range of engine operation, nearly all the fuels evaluated gave satisfactory performance. With some modifications, even the less refined fuels can be potentially suitable for use in this engine.

  2. Methods of making transportation fuel

    DOE Patents [OSTI]

    Roes, Augustinus Wilhelmus Maria; Mo, Weijian; Muylle, Michel Serge Marie; Mandema, Remco Hugo; Nair, Vijay

    2012-04-10

    A method for producing alkylated hydrocarbons is disclosed. Formation fluid is produced from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes olefins. The liquid stream is fractionated to produce at least a second gas stream including hydrocarbons having a carbon number of at least 3. The first gas stream and the second gas stream are introduced into an alkylation unit to produce alkylated hydrocarbons. At least a portion of the olefins in the first gas stream enhance alkylation. The alkylated hydrocarbons may be blended with one or more components to produce transportation fuel.

  3. Fuel Tables.indd

    Gasoline and Diesel Fuel Update (EIA)

    ... 3,709.1 863,909.0 Where shown, (s) Expenditure value less than 0.05. Notes: Total petroleum includes fuel ethanol blended into motor gasoline. * Totals may not equal sum

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Blend Mandate All diesel fuel sold to state agencies, political subdivisions of the state, and public schools for use in on-road motor vehicles must contain at least 5%...

  5. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ethanol Fuel Blend Standard At least 85% of gasoline supplied to a retailer or sold in Hawaii must contain a minimum of 10% ethanol (E10), unless the Director determines that...

  6. Qualification of Alternative Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    seal materials common; Fuels Considered Biodiesel o soy o palm o tallow o algae SVO - ... GTL- Gas-to-liquids Pyrolysis oil Biodiesel Blends - One Success Story Beginning in ...

  7. Blends of chitin and chitosan with polyamide 66

    SciTech Connect (OSTI)

    Gonzalez, V.; Guerrero, C.

    1996-12-31

    For several years, intense interest has been focused on polymer blends in which both components are synthetic polymers. However, few studies have been made on blends in which one component is chitin (QA), or chitosan (QN), the most abundant natural polymers after cellulose. Its chemical structure, based in partially acetilated {beta}-aminosaccharide units, permits the formation of natural blends with proteins and inorganic salts were the intermolecular hydrogen bonds play an important role. The choice of a partner for these natural polymers was made expecting strong interaction between the two polymers. For this reason, on this work, polyamide 66 (P66), has been chosen.

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Special Fuel Definitions The definition of alternative fuel includes liquefied petroleum gas (propane). Special fuel is defined as all combustible gases and liquids that are suitable for powering an internal combustion engine or motor or are used exclusively for heating, industrial, or farm purposes. Special fuels include biodiesel, blended biodiesel, and natural gas products, including liquefied and compressed natural gas. (Reference Indiana Code 6-6-2.5-1 and 6-6-2.5-22

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Tax Exemption Biodiesel blends containing at least 20% biodiesel derived from used cooking oil are exempt from the $0.30 per gallon state fuel excise tax. The exemption does not apply to fuel used in vehicles with a gross vehicle weight rating of 26,001 pounds or more, fuel not sold in retail operations, or fuel sold in operations involving fleet fueling or bulk sales. The exemption expires after December 31, 2019. (Reference Oregon Revised Statutes 319.530

  10. Phase Segregation in Polystyrene?Polylactide Blends

    SciTech Connect (OSTI)

    Leung, Bonnie; Hitchcock, Adam; Brash, John; Scholl, Andreas; Doran, Andrew

    2010-06-09

    Spun-cast films of polystyrene (PS) blended with polylactide (PLA) were visualized and characterized using atomic force microscopy (AFM) and synchrotron-based X-ray photoemission electron microscopy (X-PEEM). The composition of the two polymers in these systems was determined by quantitative chemical analysis of near-edge X-ray absorption signals recorded with X-PEEM. The surface morphology depends on the ratio of the two components, the total polymer concentration, and the temperature of vacuum annealing. For most of the blends examined, PS is the continuous phase with PLA existing in discrete domains or segregated to the air?polymer interface. Phase segregation was improved with further annealing. A phase inversion occurred when films of a 40:60 PS:PLA blend (0.7 wt percent loading) were annealed above the glass transition temperature (Tg) of PLA.

  11. Vehicle Technologies Office: Intermediate Ethanol Blends Research...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intermediate Ethanol Blends Research and Testing Vehicle Technologies Office: Intermediate Ethanol Blends Research and Testing Ethanol can be combined with gasoline in blends ...

  12. Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach

    SciTech Connect (OSTI)

    Zhang, Lei; Kong, Song-Charng

    2010-11-15

    Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

  13. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuels Tax Exemption Sales and use taxes apply to 80% of the proceeds from the sale of fuel blends containing between 1% and 10% biodiesel and the sale of fuels containing 10% ethanol (E10) made between July 1, 2003, and December 31, 2018. If at any time these taxes are imposed at a rate of 1.25%, the tax on biodiesel blends and E10 will then apply to 100% of the proceeds of sales. These taxes do not apply to the proceeds from the sale of biodiesel blends containing more than 10% biodiesel or

  14. Advanced Vehicle Testing Activity: Low-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended hydrogen fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents results of 16,942 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 30% hydrogen/70% CNG fuel.

  15. Advanced Vehicle Testing Activity: High-Percentage Hydrogen/CNG Blend Ford F-150 Operating Summary - January 2003

    SciTech Connect (OSTI)

    Karner, D.; Francfort, J.E.

    2003-01-22

    Over the past two years, Arizona Public Service, a subsidiary of Pinnacle West Capital Corporation, in cooperation with the U.S. Department of Energy's Advanced Vehicle Testing Activity, tested four gaseous fuel vehicles as part of its alternative fueled vehicle fleet. One vehicle operated initially using compressed natural gas (CNG) and later a blend of CNG and hydrogen. Of the other three vehicles, one was fueled with pure hydrogen and two were fueled with a blend of CNG and hydrogen. The three blended-fuel vehicles were originally equipped with either factory CNG engines or factory gasoline engines that were converted to run CNG fuel. The vehicles were variously modified to operate on blended fuel and were tested using 15 to 50% blends of hydrogen (by volume). The pure-hydrogen-fueled vehicle was converted from gasoline fuel to operate on 100% hydrogen. All vehicles were fueled from the Arizona Public Service's Alternative Fuel Pilot Plant, which was developed to dispense gaseous fuels, including CNG, blends of CNG and hydrogen, and pure hydrogen with up to 99.9999% purity. The primary objective of the test was to evaluate the safety and reliability of operating vehicles on hydrogen and blended fuel, and the interface between the vehicles and the hydrogen fueling infrastructure. A secondary objective was to quantify vehicle emissions, cost, and performance. Over a total of 40,000 fleet test miles, no safety issues were found. Also, significant reductions in emissions were achieved by adding hydrogen to the fuel. This report presents the results of 4,695 miles of testing for one of the blended fuel vehicles, a Ford F-150 pickup truck, operating on up to 50% hydrogen-50% CNG fuel.

  16. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fueling Infrastructure Tax Credit for Residents Through the Residential Energy Tax Credit program, qualified residents may receive a tax credit for 25% of alternative fuel infrastructure project costs, up to $750. Qualified residents may receive a tax credit for 50% of project costs, up to $750. Qualified alternative fuels include electricity, natural gas, gasoline blended with at least 85% ethanol (E85), propane, and other fuels that the Oregon Department of Energy approves. A

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    and Infrastructure Tax Credit for Businesses Business owners and others may be eligible for a tax credit of 35% of eligible costs for qualified alternative fuel infrastructure projects, or the incremental or conversion cost of two or more AFVs. Qualified infrastructure includes facilities for mixing, storing, compressing, or dispensing fuels for vehicles operating on alternative fuels. Qualified alternative fuels include electricity, natural gas, gasoline blended with at least 85% ethanol (E85),

  18. On the applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells

    SciTech Connect (OSTI)

    Lara-Curzio, Edgar; Radovic, Miladin; Luttrell, Claire R

    2016-01-01

    The applicability of probabilistic analyses to assess the structural reliability of materials and components for solid-oxide fuel cells (SOFC) is investigated by measuring the failure rate of Ni-YSZ when subjected to a temperature gradient and comparing it with that predicted using the Ceramics Analysis and Reliability Evaluation of Structures (CARES) code. The use of a temperature gradient to induce stresses was chosen because temperature gradients resulting from gas flow patterns generate stresses during SOFC operation that are the likely to control the structural reliability of cell components The magnitude of the predicted failure rate was found to be comparable to that determined experimentally, which suggests that such probabilistic analyses are appropriate for predicting the structural reliability of materials and components for SOFCs. Considerations for performing more comprehensive studies are discussed.

  19. Modeling the Effects of Steam-Fuel Reforming Products on Low Temperature Combustion of n-Heptane

    Broader source: Energy.gov [DOE]

    The effects of blends of base fuel (n-heptane) and fuel-reformed products on the low-temperature combustion process were investigated.

  20. Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels

    SciTech Connect (OSTI)

    Naik, C V; Westbrook, C K

    2009-04-08

    Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Signage The Ohio Turnpike Commission allows businesses to place their logos on directional signs within the right-of-way of state turnpikes. An alternative fuel retailer may include a marking or symbol within their logo indicating that it sells one or more types of alternative fuel. Alternative fuels are defined as E85, fuel blends containing at least 20% biodiesel (B20), natural gas, propane, hydrogen, or any fuel that the U.S. Department of Energy determines, by final rule, to be

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuels Program Impact Studies The Oregon Department of Energy (ODOE) must conduct periodic impact studies related to the biofuels industry in the state. These studies should evaluate such criteria as: jobs created; current and projected feedstock availability; amount of biofuels blends produced and consumed in the state; cost comparison of biofuels blends and petroleum fuel; environmental impacts; and the extent to which Oregon producers import biofuels or biofuels feedstocks from outside the

  3. Measurement of biodiesel blend and conventional diesel spray structure using x-ray radiography.

    SciTech Connect (OSTI)

    Kastengren, A. L.; Powell, C. F.; Wang, Y. J.; IM, K. S.; Wang, J.

    2009-11-01

    The near-nozzle structure of several nonevaporating biodiesel-blend sprays has been studied using X-ray radiography. Radiography allows quantitative measurements of the fuel distribution in sprays to be made with high temporal and spatial resolution. Measurements have been made at different values of injection pressure, ambient density, and with two different nozzle geometries to understand the influences of these parameters on the spray structure of the biodiesel blend. These measurements have been compared with corresponding measurements of Viscor, a diesel calibration fluid, to demonstrate the fuel effects on the spray structure. Generally, the biodiesel-blend spray has a similar structure to the spray of Viscor. For the nonhydroground nozzle used in this study, the biodiesel-blend spray has a slightly slower penetration into the ambient gas than the Viscor spray. The cone angle of the biodiesel-blend spray is generally smaller than that of the Viscor spray, indicating that the biodiesel-blend spray is denser than the Viscor spray. For the hydroground nozzle, both fuels produce sprays with initially wide cone angles that transition to narrow sprays during the steady-state portion of the injection event. These variations in cone angle with time occur later for the biodiesel-blend spray than for the Viscor spray, indicating that the dynamics of the injector needle as it opens are somewhat different for the two fuels.

  4. NREL: State and Local Governments - Renewable Fuel Standards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to RFS effectiveness: Imposing stringency to require use of higher blends of ethanol or alternative fuels. Adopting an implementation plan that can ease measurement and...

  5. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12_szybist.pdf (3.46 MB) More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel Effects on Advanced

  6. JV Task 112-Optimal Ethanol Blend-Level Investigation

    SciTech Connect (OSTI)

    Richard Shockey; Ted Aulich; Bruce Jones; Gary Mead; Paul Steevens

    2008-01-31

    Highway Fuel Economy Test (HWFET) and Federal Test Procedure 75 (FTP-75) tests were conducted on four 2007 model vehicles; a Chevrolet Impala flex-fuel and three non-flex-fuel vehicles: a Ford Fusion, a Toyota Camry, and a Chevrolet Impala. This investigation utilized a range of undenatured ethanol/Tier II gasoline blend levels from 0% to 85%. HWFET testing on ethanol blend levels of E20 in the flex fuel Chevrolet Impala and E30 in the non-flex-fuel Ford Fusion and Toyota Camry resulted in miles-per-gallon (mpg) fuel economy greater than Tier 2 gasoline, while E40 in the non-flex-fuel Chevrolet Impala resulted in an optimum mpg based on per-gallon fuel Btu content. Exhaust emission values for non-methane organic gases (NMOG), carbon monoxide (CO), and nitrogen oxides (NO{sub x}) obtained from both the FTP-75 and the HWFET driving cycles were at or below EPA Tier II, Light-Duty Vehicles, Bin 5 levels for all vehicles tested with one exception. The flex-fuel Chevrolet Impala exceeded the NMOG standard for the FTP-75 on E-20 and Tier II gasoline.

  7. NREL: Transportation Research - Alternative Fuels Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alternative Fuels Characterization Find out about other biomass research projects at NREL. NREL alternative fuels projects help overcome technical barriers and expand markets for renewable, biodegradable vehicle fuels. These liquid fuels include higher-level ethanol blends, butanol, biodiesel, renewable diesel, other biomass-derived fuels, and natural gas. By studying the fuel chemistry as well as combustion and emissions impacts of alternative fuels, NREL helps improve engine efficiency, reduce

  8. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Infrastructure Tax Credit NOTE: This incentive originally expired on December 31, 2013, but was retroactively extended through December 31, 2016, by H.R. 2029. Fueling equipment for natural gas, liquefied petroleum gas (propane), liquefied hydrogen, electricity, E85, or diesel fuel blends containing a minimum of 20% biodiesel installed between January 1, 2015, and December 31, 2016, is eligible for a tax credit of 30% of the cost, not to exceed $30,000. Permitting and inspection

  9. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Clean Cities The mission of Clean Cities is to advance the energy, economic, and environmental security of the United States by supporting local initiatives to adopt practices that reduce the use of petroleum in the transportation sector. Clean Cities carries out this mission through a network of nearly 100 volunteer coalitions, which develop public/private partnerships to promote alternative fuels and advanced vehicles, fuel blends, fuel economy, hybrid vehicles, and idle reduction. Clean

  10. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Federal Fleets Under the Energy Policy Act (EPAct) of 1992, 75% of new light-duty vehicles acquired by covered federal fleets must be alternative fuel vehicles (AFVs). As amended in January 2008, Section 301 of EPAct 1992 defines AFVs to include hybrid electric vehicles, fuel cell vehicles, and advanced lean burn vehicles. Fleets that use fuel blends containing at least 20% biodiesel (B20) may earn credits toward their annual requirements. Federal fleets are also required to use alternative

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Fueling Infrastructure Grants The Minnesota Corn Research & Promotion Council and the Minnesota Department of Agriculture offer funding assistance to fuel retailers for the installation of equipment to dispense ethanol fuel blends ranging from E15 through E85. Grant amounts are based on the extent to which the installation meets project priorities. For more information, refer to the Clean Air Choice E85 Retailer Information website. Point of Contact Kelly Marczak Director American

  12. Missouri Renewable Fuel Standard Brochure

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    The Missouri Renewable Fuel Standard requires ethanol in most gasoline beginning January 1, 2008. ARE YOU READY? TEN THINGS MISSOURI TANK OWNERS AND OPERATORS NEED TO KNOW ABOUT ETHANOL 1. Ethanol is a type of alcohol made usually from corn in Missouri and other states. 2. E10 is a blend of 10% ethanol and 90% unleaded gasoline. E85 is a blend of 75% to 85% fuel ethanol and 25% to 15% unleaded gasoline. Blends between E10 and E85 are not allowed to be sold at retail. 3. Any vehicle or small

  13. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, John P.; Granite, Evan J.; Rupp, Erik C.; Stanko, Dennis C.; Howard, Bret; Pennline, Henry W.

    2011-05-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur, and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide, but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur, resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  14. Effect of palladium dispersion on the capture of toxic components from fuel gas by palladium-alumina sorbents

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Rupp, E.C.; Stanko, D.C.; Howard, B.; Pennline, H.W.

    2011-01-01

    The dispersion and location of Pd in alumina-supported sorbents prepared by different methods was found to influence the performance of the sorbents in the removal of mercury, arsine, and hydrogen selenide from a simulated fuel gas. When Pd is well dispersed in the pores of the support, contact interaction with the support is maximized, Pd is less susceptible to poisoning by sulfur. and the sorbent has better long-term activity for adsorption of arsine and hydrogen selenide. but poorer adsorption capacity for Hg. As the contact interaction between Pd and the support is lessened the Pd becomes more susceptible to poisoning by sulfur. resulting in higher capacity for Hg, but poorer long-term performance for adsorption of arsenic and selenium.

  15. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Labeling Requirements Alternative fuel dispensers must be labeled with information to help consumers make informed decisions about fueling a vehicle, including the name of the fuel and the minimum percentage of the main component of the fuel. Labels may also list the percentage of other fuel components. This requirement applies to, but is not limited to, the following fuel types: methanol, denatured ethanol, and/or other alcohols; mixtures containing 85% or more by volume of

  16. South Texas Blending | Open Energy Information

    Open Energy Info (EERE)

    search Name: South Texas Blending Place: Laredo, Texas Zip: 78045 Product: Biodiesel producer based in Texas. References: South Texas Blending1 This article is a stub....

  17. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Mixture Excise Tax Credit NOTE: This incentive was retroactively extended multiple times, most recently through December 31, 2016, by H.R. 2029. An alternative fuel blender that is registered with the Internal Revenue Service (IRS) may be eligible for a tax incentive on the sale or use of the alternative fuel blend (mixture) for use as a fuel in the blender's trade or business. The credit is in the amount of $0.50 per gallon of alternative fuel used to produce a mixture

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Vehicle (AFV) Parking Space Regulation An individual is not allowed to park a motor vehicle within any parking space specifically designated for public parking and fueling of AFVs unless the motor vehicle is an AFV fueled by electricity, natural gas, methanol, propane, gasoline blended with at least 85% ethanol (E85), or other fuel the Oregon Department of Energy approves. Eligible AFVs must also be in the process of fueling or charging to park in the space. A person found responsible for a

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Requirement for School Buses Every school bus that is capable of operating on diesel fuel must be capable of operating using blends of at least 20% biodiesel (B20). At least 2% of the total volume of fuel purchased annually by local school districts statewide for use in diesel school buses must be a minimum of B20, to the extent that biodiesel blends are available and compatible with the technology of the vehicles and the equipment used. (Reference North Carolina General Statutes 115C-240 and

  20. Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) to someone by E-mail Share Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends Continues (May 2010) on Facebook Tweet about Alternative Fuels Data Center: Status Update: E25 Dispensers Certified, E15 Warranty Upgraded, and Testing on Ethanol Blends

  1. Investigation of Knock limited Compression Ratio of Ethanol Gasoline Blends

    SciTech Connect (OSTI)

    Szybist, James P; Youngquist, Adam D; Wagner, Robert M; Moore, Wayne; Foster, Matthew; Confer, Keith

    2010-01-01

    Ethanol offers significant potential for increasing the compression ratio of SI engines resulting from its high octane number and high latent heat of vaporization. A study was conducted to determine the knock limited compression ratio of ethanol gasoline blends to identify the potential for improved operating efficiency. To operate an SI engine in a flex fuel vehicle requires operating strategies that allow operation on a broad range of fuels from gasoline to E85. Since gasoline or low ethanol blend operation is inherently limited by knock at high loads, strategies must be identified which allow operation on these fuels with minimal fuel economy or power density tradeoffs. A single cylinder direct injection spark ignited engine with fully variable hydraulic valve actuation (HVA) is operated at WOT conditions to determine the knock limited compression ratio (CR) of ethanol fuel blends. The geometric compression ratio is varied by changing pistons, producing CR from 9.2 to 13.66. The effective CR is varied using an electro-hydraulic valvetrain that changed the effective trapped displacement using both Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC). The EIVC and LIVC strategies result in effective CR being reduced while maintaining the geometric expansion ratio. It was found that at substantially similar engine conditions, increasing the ethanol content of the fuel results in higher engine efficiency and higher engine power. These can be partially attributed to a charge cooling effect and a higher heating valve of a stoichiometric mixture for ethanol blends (per unit mass of air). Additional thermodynamic effects on and a mole multiplier are also explored. It was also found that high CR can increase the efficiency of ethanol fuel blends, and as a result, the fuel economy penalty associated with the lower energy content of E85 can be reduced by about a third. Such operation necessitates that the engine be operated in a de-rated manner for

  2. A lean methane premixed laminar flame doped with components of diesel fuel part III: Indane and comparison between n-butylbenzene, n-propylcyclohexane and indane

    SciTech Connect (OSTI)

    Pousse, E.; Tian, Z.Y.; Glaude, P.A.; Fournet, R.; Battin-Leclerc, F. [Laboratoire des Reactions et de Genie des Procedes, CNRS, Nancy Universite, 1 rue Grandville, BP 20451, 54001 NANCY Cedex (France)

    2010-07-15

    To better understand the chemistry of the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with indane has been investigated. The inlet gases contained 7.1% (molar) of methane, 36.8% of oxygen and 0.9% of indane corresponding to an equivalence ratio of 0.67 and a ratio C{sub 10}H{sub 14}/CH{sub 4} of 12.8%. The flame has been stabilized on a burner at a pressure of 6.7 kPa (50 Torr) using argon as diluent, with a gas velocity at the burner of 49.1 cm s{sup -1} at 333 K. Quantified species included the usual methane C{sub 0}-C{sub 2} combustion products, but also 16 C{sub 3}-C{sub 5} non-aromatic hydrocarbons, 6 C{sub 1}-C{sub 3} non-aromatic oxygenated compounds, as well as 22 aromatic products, namely benzene, toluene, xylenes, phenylacetylene, ethylbenzene, styrene, propenylbenzene, allylbenzene, n-propylbenzene, methylstyrenes, ethyltoluenes, trimethylbenzenes, n-butylbenzene, dimethylethylbenzene, indene, methylindenes, methylindane, benzocyclobutene, naphthalene, phenol, benzaldehyde, and benzofuran. A new mechanism for the oxidation of indane was proposed whose predictions were in satisfactory agreement with measured species profiles in both flames and jet-stirred reactor experiments. The main reaction pathways of consumption of indane have been derived from flow rate analyses in the two types of reactors. A comparison of the effect of the addition of three components of diesel fuel, namely indane, n-butylbenzene and n-propylcyclohexane (parts I and II of this series of paper), on the structure of a laminar lean premixed methane flame is also presented. (author)

  3. The Advanced Petroleum-Based Fuels Program DECSE and APBF Overview

    SciTech Connect (OSTI)

    2000-04-11

    The following topics are summarized: Role of fuel blends in controlling engine-out emissions; Effect of fuels and lubricants on emission control devices; and Effect of fuels and lubricants on vehicle emissions and operations.

  4. Fact #588: September 14, 2009 Fuel Economy Changes Due to Ethanol Content

    Broader source: Energy.gov [DOE]

    The fuel economy of a vehicle is dependent on many things, one of which is the fuel used in the vehicle. Two National Laboratories recently studied the effects that ethanol blends have on the fuel...

  5. Knock-limited performance of ethanol blends in a spark-ignition engine

    SciTech Connect (OSTI)

    Ferfecki, F.J.; Sorenson, S.C.

    1981-01-01

    An experimental study was performed to determine the effect of varying percentages of ethanol in fuel using a CFR engine operated at knock-limited compression ratio and maximum power spark timing. Blends of 85 octane primary reference fuel and ethanol in concentrations between 10 and 25% by volume were tested for performance, fuel economy, and exhaust emissions. The results indicated that when the engine was operated at knock-limited conditions at a constant equivalence ratio, the use of ethanol resulted in a reduction in petroleum fuel usage of 10% greater than the volumetric percentage of the ethanol used in the blend. These results were independent of the amount of ethanol used in the blend. Under these conditions, as the ethanol concentration was increased, BMEP and BSHC increased, BSNO and BSCO remained essentially constant, and exhaust temperature decreased.

  6. Drive cycle analysis of butanol/diesel blends in a light-duty vehicle.

    SciTech Connect (OSTI)

    Miers, S. A.; Carlson, R. W.; McConnell, S. S.; Ng, H. K.; Wallner, T.; LeFeber, J.; Energy Systems; Esper Images Video & Multimedia

    2008-10-01

    The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests.

  7. Modeling the Auto-Ignition of Biodiesel Blends with a Multi-Step Model

    SciTech Connect (OSTI)

    Toulson, Dr. Elisa; Allen, Casey M; Miller, Dennis J; McFarlane, Joanna; Schock, Harold; Lee, Tonghun

    2011-01-01

    There is growing interest in using biodiesel in place of or in blends with petrodiesel in diesel engines; however, biodiesel oxidation chemistry is complicated to directly model and existing surrogate kinetic models are very large, making them computationally expensive. The present study describes a method for predicting the ignition behavior of blends of n-heptane and methyl butanoate, fuels whose blends have been used in the past as a surrogate for biodiesel. The autoignition is predicted using a multistep (8-step) model in order to reduce computational time and make this a viable tool for implementation into engine simulation codes. A detailed reaction mechanism for n-heptane-methyl butanoate blends was used as a basis for validating the multistep model results. The ignition delay trends predicted by the multistep model for the n-heptane-methyl butanoate blends matched well with that of the detailed CHEMKIN model for the majority of conditions tested.

  8. Indiana Brings Alternative Fuels to the Forefront | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of technologies and fuels in both light and heavy-duty vehicles, including natural gas, propane, hybrid electric drive, and E85 (a fuel blend containing up to 85% ethanol)....

  9. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  10. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2009-02-01

    This report (February 2009) is an update of the original version, which was published in October 2008. This report is the result of the U.S. Department of Energy's test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels.

  11. Empirical Study of the Stability of Biodiesel and Biodiesel Blends: Milestone Report

    SciTech Connect (OSTI)

    McCormick, R. L.; Westbrook, S. R.

    2007-05-01

    The objective of this work was to develop a database that supports specific proposals for a stability test and specification for biodiesel and biodiesel blends. B100 samples from 19 biodiesel producers were obtained in December of 2005 and January of 2006 and tested for stability. Eight of these samples were then selected for additional study, including long-term storage tests and blending at 5% and 20% with a number of ultra-low sulfur diesel fuels.

  12. Method to blend separator powders

    SciTech Connect (OSTI)

    Guidotti, Ronald A.; Andazola, Arthur H.; Reinhardt, Frederick W.

    2007-12-04

    A method for making a blended powder mixture, whereby two or more powders are mixed in a container with a liquid selected from nitrogen or short-chain alcohols, where at least one of the powders has an angle of repose greater than approximately 50 degrees. The method is useful in preparing blended powders of Li halides and MgO for use in the preparation of thermal battery separators.

  13. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf (1.43 MB) More Documents & Publications Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 Mid-Level Ethanol Blends Test Program Mid-Level Ethanol Blends

  14. Compliant fuel cell system

    DOE Patents [OSTI]

    Bourgeois, Richard Scott; Gudlavalleti, Sauri

    2009-12-15

    A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

  15. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon

  16. Blender Pump Fuel Survey: CRC Project E-95

    SciTech Connect (OSTI)

    Alleman, T. L.

    2011-07-01

    To increase the number of ethanol blends available in the United States, several states have 'blender pumps' that blend gasoline with flex-fuel vehicle (FFV) fuel. No specification governs the properties of these blended fuels, and little information is available about the fuels sold at blender pumps. No labeling conventions exist, and labeling on the blender pumps surveyed was inconsistent.; The survey samples, collected across the Midwestern United States, included the base gasoline and FFV fuel used in the blends as well as the two lowest blends offered at each station. The samples were tested against the applicable ASTM specifications and for critical operability parameters. Conventional gasoline fuels are limited to 10 vol% ethanol by the U.S. EPA. The ethanol content varied greatly in the samples. Half the gasoline samples contained some ethanol, while the other half contained none. The FFV fuel samples were all within the specification limits. No pattern was observed for the blend content of the higher ethanol content samples at the same station. Other properties tested were specific to higher-ethanol blends. This survey also tested the properties of fuels containing ethanol levels above conventional gasoline but below FFV fuels.

  17. Range Fuels Biorefinery Groundbreaking | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and state legislators who exhibit the kind of leadership you've shown in developing America's new energy future. ... Range Fuels are blending science and technology in order to ...

  18. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-05-18

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  19. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-09-17

    This report summarizes the accomplishments toward project goals during the first twelve months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  20. REFINERY INTEGRATION OF BY-PRODUCTS FROM COAL-DERIVED JET FUELS

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; John Andresen

    2004-04-23

    This report summarizes the accomplishments toward project goals during the first six months of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  1. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Prohibition of the Sale of Ethanol-Blended Gasoline A person or distributor may not offer, sell, or distribute gasoline that contains ethanol at a level greater than 10% (E10) or contains corn-based ethanol as an additive. The prohibition does not take effect until at least ten other states or a number of states with a collective population of 30 million have enacted laws preventing the sale of these fuel blends. (Reference Maine Revised Statutes Title 38, Section 585M and Title 10, Section

  2. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biodiesel Sales Requirements It is unlawful for any person to sell, offer for sale, assist in the sale of, deliver, or permit to be sold or offered for sale any biodiesel, biomass-based diesel, or biomass-based diesel blend unless it meets applicable registration requirements for fuels and additives. Biodiesel must meet Title 40 of the U.S. Code of Federal Regulations, section 79, and ASTM Standard D6751. Biomass-based diesel and biomass-based diesel blends must meet the requirements in Title 42

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Tax Special fuels, including biodiesel, biodiesel blends, biomass-based diesel, biomass-based diesel blends, and liquefied natural gas (LNG), have a reduced tax rate of $0.27 per gallon. Liquefied petroleum gas (LPG or propane) and compressed natural gas (CNG) used to operate a motor vehicle is taxed at a rate of $0.064 and $0.21 per gallon, respectively. For taxation purposes, 126.67 cubic feet of CNG, 36.3 cubic feet (4.2 pounds (lbs.)) of propane, or 6.06 lbs. of LNG is considered equal to

  4. Intrinsically safe moisture blending system

    SciTech Connect (OSTI)

    Hallman Jr., Russell L.; Vanatta, Paul D.

    2012-09-11

    A system for providing an adjustable blend of fluids to an application process is disclosed. The system uses a source of a first fluid flowing through at least one tube that is permeable to a second fluid and that is disposed in a source of the second fluid to provide the adjustable blend. The temperature of the second fluid is not regulated, and at least one calibration curve is used to predict the volumetric mixture ratio of the second fluid with the first fluid from the permeable tube. The system typically includes a differential pressure valve and a backpressure control valve to set the flow rate through the system.

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive WEX fleet card. The program offers a rebate of $0.05 per gallon for purchases of more than 500 gallons of biofuel per month. The rebate is applied at the end of each monthly billing cycle. For more

  6. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Volume Rebate Program - Propel Fuels Propel Fuels offers a rebate to qualified fleet customers for monthly purchases of more than 500 gallons of biodiesel blends and E85. Fleet customers must purchase the fuel directly from Propel public retail locations using the Propel CleanDrive Fleet Card. The program offers a rebate of $0.03 per gallon for purchases of less than 1,000 gallons of biofuel per month, and $0.05 per gallon for purchases of 1,000 gallons or more per month. The rebate is

  7. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non‑Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian H; Clark, Wendy; Graves, Ronald L; Orban, John; Przesmitzki, Steve; Theiss, Timothy J

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2

  8. Refinery Net Input of Motor Gasoline Blending Components (Net)

    U.S. Energy Information Administration (EIA) Indexed Site

    -224,415 -196,460 -205,085 -201,403 -213,659 -206,750 2005-2016 PADD 1 -17,942 -14,705 -15,325 -15,088 -16,507 -15,534 2005-2016 East Coast -17,889 -14,746 -15,326 -15,154 -16,492 -15,493 2005-2016 Appalachian No. 1 -53 41 1 66 -15 -41 2005-2016 PADD 2 -56,553 -48,250 -48,728 -44,224 -48,504 -47,699 2005-2016 Ind., Ill. and Ky. -36,491 -32,814 -31,456 -27,909 -31,097 -30,704 2005-2016 Minn., Wis., N. Dak., S. Dak. -7,599 -5,879 -6,476 -5,086 -5,818 -5,937 2005-2016 Okla., Kans., Mo. -12,463

  9. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. Within the Combustion Laboratory of the Penn State Energy Institute, they have installed and equipped a Navistar V-8 direct-injection turbodiesel engine for measurement of gaseous and particulate emissions and examination of the impact of fuel composition on diesel combustion. They have also reconfigured a high-pressure viscometer for studies of the viscosity, bulk modulus (compressibility) and miscibility of blends of diesel fuel, dimethyl ether and lubricity additives. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have examined blends of an oxygenated fuel additive (a liquid fuel called CETANER{trademark}) produced by Air Products, for comparison with dimethyl ether blended at the same weight of oxygen addition, 2 wt.%. While they have not operated the engine on DME yet, they are now preparing to do so. A fuel system for delivery of DME/Diesel blends has been configured

  10. Electric Drive Component Manufacturing Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Component Manufacturing Facilities Electric Drive Component Manufacturing Facilities 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ...

  11. Electric Drive Component Manufacturing Facilities | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Component Manufacturing Facilities Electric Drive Component Manufacturing Facilities 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ...

  12. Development and Demonstration of Hydrogen and Compressed Natural Gas (H/CNG) Blend Transit Buses: October 15, 2002--September 30, 2004

    SciTech Connect (OSTI)

    Del Toro, A.; Frailey, M.; Lynch, F.; Munshi, S.; Wayne, S.

    2005-11-01

    The report covers literature and laboratory analyses to identify modification requirements of a Cummins Westport B Gas Plus engine for transit buses using a hydrogen/compressed natural fuel blend.

  13. Compression-ignition fuel properties of Fischer-Tropsch syncrude

    SciTech Connect (OSTI)

    Suppes, G.J.; Terry, J.G.; Burkhart, M.L.; Cupps, M.P.

    1998-05-01

    Fischer-Tropsch conversion of natural gas to liquid hydrocarbon fuel typically includes Fischer-Tropsch synthesis followed by refining (hydrocracking and distillation) of the syncrude into mostly diesel or kerosene with some naphtha (a feedstock for gasoline production). Refining is assumed necessary, possibly overlooking the exception fuel qualities of syncrude for more direct utilization as a compression-ignition (CI) fuel. This paper evaluates cetane number, viscosity, cloud-point, and pour-point properties of syncrude and blends of syncrude with blend stocks such as ethanol and diethyl ether. The results show that blends comprised primarily of syncrude are potentially good CI fuels, with pour-point temperature depression being the largest development obstacle. The resulting blends may provide a much-needed and affordable alternative CI fuel. Particularly good market opportunities exist with Environmental Policy Act (EPACT) applications.

  14. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

    2003-04-01

    and challenges have continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. As of late June 2002, it appears that the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head is being installed on the system to alleviate this problem and get the shuttle bus back in operation. In summary, the conversion is completed but there have been operational challenges in the field. They continue to work to make the shuttle bus as reliable to operate on DME-diesel blends as possible.

  15. Mid-Level Ethanol Blends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mid-Level Ethanol Blends Test Program DOE, NREL, and ORNL Team Presented by Keith Knoll Work supported by DOE/EERE Vehicle Technologies Program Annual Merit Review and Peer Evaluation meeting May 19, 2009 Kevin Stork Vehicle Technologies Program Shab Fardanesh and Joan Glickman Office of the Biomass Program This presentation does not contain any proprietary or classified information Project ID: ft_05_knoll Collaborators Kevin Stork DOE OVT Shab Fardanesh DOE OBP Joan Glickman DOE OBP Wendy Clark

  16. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels Tax Alternative fuels are subject to an excise tax at a rate of 0.205 per gasoline gallon equivalent, with a variable component equal to at least 5% of the average wholesale...

  17. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  18. Table B1. Pipe Manufacturer Compatibility with Ethanol Blends

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    B1. Pipe Manufacturer Compatibility with Ethanol Blends Manufacturer Product Model Ethanol Compatibility Piping-All Companies have UL 971 listing for E100 Advantage Earth Products Piping 1.5", 2", 3", 4" E0-E100 Brugg Piping FLEXWELL-HL, SECON-X, NITROFLEX, LPG E0-E100 Franklin Fueling Piping Franklin has third-party certified piping compatible with up to E85. Contact manufacturer for specific part numbers. E0-E85 OPW Piping FlexWorks, KPS, Pisces (discontinued) E0-E100 NOV

  19. Fuel Cell Systems | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells » Fuel Cell Systems Fuel Cell Systems The design of fuel cell systems is complex, and can vary significantly depending upon fuel cell type and application. However, several basic components are found in many fuel cell systems: Fuel cell stack Fuel processor Power conditioners Air compressors Humidifiers Fuel Cell Stack The fuel cell stack is the heart of a fuel cell power system. It generates electricity in the form of direct current (DC) from electro-chemical reactions that take place in

  20. The Impact of Alternative Fuels on Combustion Kinetics

    SciTech Connect (OSTI)

    Pitz, W J; Westbrook, C K

    2009-07-30

    The research targets the development of detailed kinetic models to quantitatively characterize the impact of alternative fuels on the performance of Navy turbines and diesel engines. Such impacts include kinetic properties such as cetane number, flame speed, and emissions as well as physical properties such as the impact of boiling point distributions on fuel vaporization and mixing. The primary focus will be Fischer-Tropsch liquids made from natural gas, coal or biomass. The models will include both the effects of operation with these alternative fuels as well as blends of these fuels with conventional petroleum-based fuels. The team will develop the requisite kinetic rules for specific reaction types and incorporate these into detailed kinetic mechanisms to predict the combustion performance of neat alternative fuels as well as blends of these fuels with conventional fuels. Reduced kinetic models will be then developed to allow solution of the coupled kinetics/transport problems. This is a collaboration between the Colorado School of Mines (CSM) and the Lawrence Livermore National Laboratory (LLNL). The CSM/LLNL team plans to build on the substantial progress made in recent years in developing accurate detailed chemical mechanisms for the oxidation and pyrolysis of conventional fuels. Particular emphasis will be placed upon reactions of the isoalkanes and the daughter radicals, especially tertiary radicals, formed by abstraction from the isoalkanes. The various components of the program are described. We have been developing the kinetic models for two iso-dodecane molecules, using the same kinetic modeling formalisms that were developed for the gasoline and diesel primary reference fuels. These mechanisms, and the thermochemical and transport coefficient submodels for them, are very close to completion at the time of this report, and we expect them to be available for kinetic simulations early in the coming year. They will provide a basis for prediction and

  1. Iowa Nuclear Profile - All Fuels

    U.S. Energy Information Administration (EIA) Indexed Site

    components of the fuel; however, all Municipal Solid Waste summer capacity is classified as Renewable." "Notes: Totals may not equal sum of components due to independent ...

  2. Wisconsin Nuclear Profile - All Fuels

    U.S. Energy Information Administration (EIA) Indexed Site

    components of the fuel; however, all Municipal Solid Waste summer capacity is classified as Renewable." "Notes: Totals may not equal sum of components due to independent ...

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Infrastructure Grants and Loan Guarantees The Rural Energy for America Program (REAP) provides loan guarantees and grants to agricultural producers and rural small businesses to purchase renewable energy systems or make energy efficiency improvements. Eligible renewable energy systems include flexible fuel pumps, or blender pumps, that dispense intermediate ethanol blends. The maximum loan guarantee is $25 million and the maximum grant funding is 25% of project costs. At least 20% of the

  4. Refinery Integration of By-Products from Coal-Derived Jet Fuels

    SciTech Connect (OSTI)

    Leslie R. Rudnick; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

    2005-11-17

    This report summarizes the accomplishments toward project goals during the first six months of the second year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Evaluations to assess the quality of coal based fuel oil are reported. Coal samples have procured and are being assessed for cleaning prior to use in coking studies.

  5. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse; Lewis Sr, Samuel Arthur; Szybist, James P; Thomas, John F; Barone, Teresa L; Eibl, Mary A; Nafziger, Eric J; Kaul, Brian C

    2014-01-01

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  6. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

    2003-04-01

    campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

  7. Development of Fuel-Flexible Combustion Systems Utilizing Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    2008-12-01

    General Electric Global Research will define, develop, and test new fuel nozzle technology concepts for gas turbine operation on a wide spectrum of opportunity fuels and/or fuel blends. This will enable gas turbine operation on ultra-low Btu fuel streams such as very weak natural gas, highly-diluted industrial process gases, or gasified waste streams that are out of the capability range of current turbine systems.

  8. Alternative Fuels Data Center: E15

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    E15 to someone by E-mail Share Alternative Fuels Data Center: E15 on Facebook Tweet about Alternative Fuels Data Center: E15 on Twitter Bookmark Alternative Fuels Data Center: E15 on Google Bookmark Alternative Fuels Data Center: E15 on Delicious Rank Alternative Fuels Data Center: E15 on Digg Find More places to share Alternative Fuels Data Center: E15 on AddThis.com... More in this section... Ethanol Basics Blends E15 E85 Specifications Production & Distribution Feedstocks Related Links

  9. Flexible Fuel Vehicle Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicles & Fuels » Vehicles » Flexible Fuel Vehicle Basics Flexible Fuel Vehicle Basics August 20, 2013 - 9:05am Addthis Photo of a gray van with 'E85 Ethanol' written on the side. Flexible fuel vehicles (FFVs) have an internal combustion engine and are capable of operating on gasoline, E85 (a high-level blend of gasoline and ethanol), or a mixture of both. There are more than 10.6 million flexible fuel vehicles on U.S. roads today. However, many flexible fuel vehicle owners don't realize

  10. 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 00,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) 100,000-Mile Evaluation of Transit Buses Operated on Biodiesel Blends (B20) Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_barnitt.pdf (575.91 KB) More Documents & Publications Recent Research to Address Technical Barriers to Increased Use of Biodiesel Impact